United States
 Environmental Protection
 Agency
Interlaboratory Validation of the Leaching Environmental
Assessment Framework (LEAF) Method 1313 and Method
1316
     Office of Research and Development

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                                                             EPA/600/R-12/623
                                                                September 2012
   Interlaboratory Validation of the Leaching Environmental

Assessment Framework (LEAF) Method 1313 and Method 1316


  Andrew C. Garrabrants1, David S. Kosson1, Leonard Stefanski2, Rossane DeLapp1,
  Paul F.A.B. Seignette3, Hans A. van der Sloot4, Peter Kariher5, and Mark Baldwin6


                              1 Vanderbilt University
                         Civil and Environmental Engineering
                               Nashville, TN 37235

                          2 North Carolina State University
                              Department of Statistics
                                Raleigh, NC 27695

                      3 Energy Research Centre of the Netherlands
                       Biomass, Coal and Environmental Research
                           1755 ZG Petten, the Netherlands

                          4 Hans van der Sloot Consultancy
                          1721 BV Langedijk, the Netherlands

                               5 ARCADIS-US, Inc.
                          Research  Triangle Park, NC 27711

                       6 U.S. Environmental Protection Agency
                     Office of Solid Waste and Emergency Response
                              Washington, DC 20460


                           Category III / Applied Research

                             Contract No. EP-C-09-027
                            Work Assignment No. 3-07
                                  Prepared for
                               Susan A. Thorneloe
                        U.S. Environmental Protection Agency
                         Office of Research and Development
                    National Risk Management Research Laboratory
                     Air Pollution Prevention and Control Division
                          Research Triangle Park, NC 27711

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
                                           Notice

                     The U.S. Environmental Protection Agency through its
                     Office  of Research and Development partially funded
                     and  managed  the  research  described  here  under
                     Contract   Number    EP-C-09-27   coordinated   by
                     ARCADIS-US, Inc.  This report has  been subjected to
                     the Agency's peer and administrative review and has
                     been approved for publication as an EPA document.

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


ACKNOWLEDGMENTS
This interlaboratory validation study was conducted under the United States Environmental Protection
Agency (EPA) Contract Number EP-C-09-27 coordinated by ARCADIS-US, Inc. (ARCADIS).
Organization of the validation study was a collaborative effort of ARCADIS, Vanderbilt University (VU),
EPA Office of Solid Waste and Emergency Response (OSWER) and EPA Office of Research and
Development (ORD). Partial financial support was provided by the U.S. Department of Energy, Office of
Environmental Management under Cooperative Agreement Number DE-FC01-06W07053 entitled 'The
Consortium for Risk Evaluation with Stakeholder Participation  IIP awarded to Vanderbilt University.
Material preparation and distribution were carried out jointly by ARCADIS and VU.  All chemical
analyses of leaching eluate solutions were conducted at VU.  Development and review of statistical
approaches were performed at North Carolina State University.
The authors gratefully acknowledge the following laboratories and contact leads for donating time, effort,
and support as participating laboratories in the validation study:
    Energy Research Centre of the Netherlands, Petten, the Netherlands (Rob Comans)
    DHI, H0rsholm, Denmark (Ole Hjelmar)
    Oak Ridge National Laboratory, Oak Ridge, TN (Catherine Mattus)
    The Ohio State University, Columbus, OH (Zuzana Bohrerova)
    Pacific Northwest National Laboratory, Richland, WA (Eric Pierce and Michelle Valenta)
    Savannah River National Laboratory, Aiken, SC (Charles Crawford and Kimberly Roberts)
    Test America Inc., Nashville, TN (Johnny Mitchell)
    The University of Missouri,  Rolla, MO (Jianmin Wang)
    The University of Wisconsin, Madison, WI (James Tinjum)
    URS Corporation, Inc., Austin, TX (Mandi Richardson)
The authors also thank Gregory Helms (EPA OSWER), Richard Benware (EPA  OSWER), and Susan
Thorneloe (EPA ORD) for guidance and significant contributions to the success  of this program.

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


ABSTRACT
This document summarizes the results of an interlaboratory study conducted to generate precision
estimates for two parallel batch leaching methods which are part of the Leaching Environmental
Assessment Framework (LEAF) and are under review by the U.S. Environmental Protection Agency
(EPA) Office of Solid Waste and Emergency Response for potential inclusion into the EPA's Test
Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846).
    •  Method 1313: Liquid-Solid Partitioning as a Function ofEluate pH using a Parallel Batch
       Extraction Procedure
    •  Method 1316: Liquid-Solid Partitioning as a Function ofLiquid-to-Solid Ratio using a Parallel
       Batch Extraction Procedure.
For each of the two methods, the interlaboratory study targeted ten participating laboratories and three
study materials - a coal combustion fly ash, a cementitious solidified waste analog, and a contaminated
smelter site soil.  Method precision was evaluated using repeatability relative standard deviation (RSDr)
and reproducibility relative standard deviation (RSDR) of eluate concentrations obtained from the
interlaboratory study.
The mean repeatability were determined to be 13% RSDr for Method 1313 and 8% RSDr for Method
1316.  This level of within-laboratory precision means that variation of test replicates from a single
operator would be less than 13% for Method 1313 and 8% for Method  1316. Method repeatability was
consistent with the repeatability found for a European standard (EN) single-batch extraction test, EN
12457-2. Mean method reproducibility was determined to be 28% RSDR for Method 1313 and 19%
RSDR for Method 1316 indicating the potential variation in multi-laboratory results on the same material.
Reproducibility precision was consistent with the reported median reproducibility estimate for EN 12457-
2 and was considerably better than the mean reproducibility value reported for the EPA's Toxicity
Characteristic Leaching Procedure (TCLP; SW-846 Method 1311).
In parallel to the validation of the LEAF methods, the study materials were tested by the Energy Research
Centre of the Netherlands and DHI, Denmark using two European technical specification for pH-
dependence leaching currently in process of standardization through the Comite Europeen de
Normalisation (CEN). Although similar in structure and intent to Method 1313, these two tests differ
from each other and from Method 1313 in the way that the final pH is achieved. Comparisons of the
CEN test data to Method 1313 robust confidence limits showed that there is little to no operational
difference in the pH-dependent leaching results from the three study materials. The findings of this study
provide confidence that Method 1313 and Method 1316 provide the characteristic leaching behavior that
is intended by the LEAF leaching methods with a high degree of precision.
                                              in

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
EXECUTIVE SUMMARY
The potential impact on the environment when a solid material is either disposed or otherwise applied to
the land has traditionally been measured through the use of one or more leaching tests.  The current
United States Environmental Protection Agency (EPA) protocol to classify waste materials as
"hazardous" to the environmental is the Toxicity Characteristic Leaching Procedures (TCLP; EPA,
1992a) which simulates a plausible worst-case mismanagement scenario of co-disposal with municipal
solid waste. While this approach has merits for classification purposes, a more flexible and robust
methodology could provide the EPA and the waste management community with a uniform basis for
leaching characterization that is applicable over a wide range of waste types and release scenarios. Thus,
the EPA Office of Solid Waste and Emergency (OSWER) has initiated a review of the leaching test
methods contained within the Leaching Environmental Assessment Framework (LEAF) for potential
inclusion into EPA's compendium of laboratory methods, Test Methods for Evaluating Solid Waste,
Physical/Chemical Methods, also known as SW-846.  The LEAF methods have been developed in
collaboration between Vanderbilt University (VU), the Energy Research Centre of the Netherlands (ECN)
and DHI with support and guidance from ARCADIS-US, Inc. (ARCADIS) and EPA's Office of Research
and Development (ORD).  As opposed to simulating a particular release scenario, these leaching methods
challenge a solid material to a broad range of leaching conditions that may plausibly occur in the course
of waste management, focusing on those key parameters that control equilibrium and mass transport from
solid materials. The LEAF approach provides considerable flexibility in that no specific leaching
scenario is  imposed, but the methods rather focus on intrinsic leaching characteristics, so that the results
may be applied and used to compare scenarios representing a range of plausible management options.
As part of the review for SW-846, documentation is required regarding the precision (i.e., repeatability
and reproducibility) of the methods  for various types of potential waste materials.  This precision data is
intended to provide perspective on the variation in test method results that may be anticipated (i) when a
single laboratory performs  the method on homogenous replicates of the same material sample, or (ii)
when multiple laboratories perform  the test on replicate samples of a single material. In addition, the
precision data supports the development of regulatory guidance on the use of the method and can be used
to establish criteria for acceptable laboratory method performance. This report summarizes  the results of
an interlaboratory method validation study to generate precision information for two of the four LEAF
leaching methods::
    •   Method 1313: Liquid-Solid Partitioning as a Function ofEluate pH using a Parallel Batch
        Extraction Procedure
    •   Method 1316: Liquid-Solid Partitioning as a Function ofLiquid-to-Solid Ratio using a Parallel
        Batch Extraction Procedure.
These two methods are parallel batch leaching procedures designed to determine the liquid-solid
partitioning between a solid material and a leaching solution under conditions approaching equilibrium
and as a function of final extract pH (Method  1313) or liquid-to-solid ratio (Method 1316).  These
1 Although the LEAF methods are numbered in a manner consistent with SW-846, these methods are currently considered
preliminary versions of EPA Methods which have not yet been endorsed by EPA pending method validation and final review.
                                               IV

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


methods involve preparation of fine-grained subsamples of the study material by sieving and crushing (as
appropriate to yield subsamples with 85% by mass less than specified grain size), parallel batch
extractions of the material using common laboratory equipment, and filtration to prepare eluate solutions2
for chemical analysis. Due to the procedural similarities of these methods, validation of both Method
1313 and Method 1316 is documented in a single report.
The structure of the validation study followed the two-phase approach recommend by EPA's Guidance
for Methods Development and Methods  Validation for the RCRA Program (EPA, 1992b).  The minimum
guidelines for the validation study were  to provide for testing of three materials at six participating
laboratories.  While exact values for materials and laboratories may differ, these guidelines are consistent
with AOAC recommendations for validation studies and the study design suggested in ASTM
International (ASTM) E691 Standard Practice for Conducting an Interlaboratory Study to Determine the
Precision of a Test Method (ASTM 1986).  Recognizing that participating laboratories would donate time
and support for the project and a certain level of attrition would be anticipated, additional laboratories
were targeted in order to provide for a minimum of six laboratories completing any phase of the
validation study. ARCADIS provided project management and served as the validation reference
laboratory due to considerable experience with the test methods (EPA  2006, 2008, 2009).  In order to
minimize variation in test results due to  different analytical techniques and operators, all chemical
analysis was conducted at VU by ICP-OES using EPA Method 6010 (EPA 2010). The study design as
well as all material handling approaches and analytical procedures with data quality indicator (DQI) goals
were written into a quality assurance project plan (QAPP) which was signed and approved by quality
assurance representatives of ARCADIS  and the EPA.
Three materials, that span a range of material types considered relevant by the EPA for waste
management, were chosen for the validation. These materials included a coal combustion fly ash
(material code EaFA), a solidified waste analog (material code SWA) and a contaminated soil from a
smelter facility (material code CFS). Prior to distribution to the participating laboratories, these materials
were processed (e.g., crushed  to specified particle size) and homogenized at either ARCADIS or VU.
Subsamples of homogenized material were  shipped to each laboratory. The total  contents of major,
minor, and trace constituents in each of  study materials were determined at ARCADIS by a combination
of x-ray fluorescence spectroscopy (XRFS) and digestion following EPA Methods 3052 and 3051.
Digestates were chemically analyzed at  VU by inductively coupled plasma-optical emission spectroscopy
(ICP-OES) to determine the total contents in the solid materials.  XRFS data for twelve subsamples of
homogenized material were used to assess the homogeneity of the samples prior to distribution. DQIs for
total contents were well within the goals established in the QAPP for EaFA and SWA.  The initial DQIs
for homogenization of CFS were outside of the desired range; however, removal of carbon from XRFS
list of major analytes improved the DQI for CFS. The rationale for removal of total carbon is that XRFS
is not a preferred method for determination of total carbon which is better analyzed by combustion
methods. With the improvement to the homogeneity DQIs for CFS, all materials were considered
sufficiently homogenous prior to distribution to the participating laboratories.
2 This report uses the LEAF terminology where "eluate" refers to the solution resulting from a leaching test whereas "leachate"
refers to the solution collected from or measured in the field. The distinction between terms is made to minimize confusing when
comparing laboratory data to field data.

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


In the first phase of the validation study, ten participating laboratories were asked to demonstrate method
proficiency by conducting both Method 1313 and Method 1316 in triplicate on a single study material.
During testing, participating laboratories recorded laboratory data in Microsoft® Excel spreadsheets
provided to the laboratories as templates for data collection.  Filtered and preserved eluates solutions from
leaching tests carried out at participating laboratories were shipped to VU for chemical analysis. The
leaching results from individual laboratories were compared to the results of six test replicates conducted
on the same material by ARCADIS serving as a reference laboratory. Nine of the ten initial laboratories
completed the proficiency demonstration phase and all laboratories were passed on to the second phase.
In the second phase testing, participating laboratories were requested to prepare eluate solutions for two
additional materials following the same approach as in first phase.  In all, approximately ten participating
laboratories participated in each phase of the study and generated eluate solutions for 27 to 36 test
replicates3 of either nine eluate solutions for Method 1313 or five eluate solutions for Method 1316.  Data
management and analysis of this large data set was conducted using LeachXS™, a software program
developed specifically for data management, visualization, and modeling of leaching data.
Ten inorganic analytes from each material were chosen for processing to generate statistical and precision
measurements. The list of selected constituents differed based on the leaching behavior of each material,
but included eight constituents (i.e., antimony, arsenic, barium, boron, calcium, molybdenum, selenium
and vanadium) common to all study materials. Leachates generated by  the participating laboratories were
shipped to VU where eluates concentrations were determined by ICP-OES following standard quality
assurance/quality control procedures as specified in the QAPP, including calibration checks, blanks and
analytical spikes. In all, the DQIs for eluate solution analysis were much better than the DQI goals
established in the QAPP and provided confidence that the measured eluate concentrations were valid
within an analytical uncertainty of about 5%.  Method blanks (i.e., extract solutions without solid material
that follow through the leaching test procedure) were checked for potential sources of contamination
during testing.  Although approximately 20% of the eluate solutions were potentially affected by high
concentrations in method blanks and were eligible for removal or "filtering" from the data set, a
comparison the results for filtered and non-filtered data sets showed little to no impact of filtering on
preliminary precision statistics. Therefore, no eluate data was filtered due to method blank
concentrations. Some data was filtered, however, due to identified procedural or operator errors. For
example, Method 1313 data was filtered because (i) high sulfur in all eluate solutions interfering with
barium leaching, (ii) boron contamination  due to caustic stored in borosilicate glass, (iii) obvious errors in
pH measurements most notable at extremes of the pH scale. In all, the amount of data that was "filtered
for cause" was  less than 20% of the total data set and in no case resulted in less than six laboratories
reporting data.
For each method, the results for each material were processed using logic transformation and linear
interpolation/extrapolation of measured extract concentrations to yield a set of data used in statistical
analysis. Statistical measurement included (i) means and standard deviations at each target extraction
specified in the methods, (ii) 95% prediction limits about the mean of the reference laboratory data, (iii)
3 The number of data points collected for each pH target included data from six test replicates conducted by the reference
laboratory plus triplicate analysis conducted by the participating laboratories (e.g., the minimum value of 27 considers 21 data
points from triplicate test runs of the seven participating laboratories plus six test replicates from the reference laboratory).
                                                VI

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


95% robust confidence limits (RCLs) about the median of the laboratory means, (iv) estimates of
repeatability and reproducibility, and (v) the Horwitz ratio (e.g., the ratio of reproducibility relative
standard deviation to that predicted as a function of concentration by the Horwitz equation). Prediction
limits and robust confidence intervals, respectively, showed the ranges of leaching concentration that
would capture 95% of the data for the reference laboratory performing replicate tests and for additional
laboratories testing the same material. In the literature, Horwitz ratios (HorRatR), which adjust for the
natural tendency of analytical methods to have higher relative standard deviations as concentrations
decrease, have been used to provide a cutoff value (i.e., 0.5 < HorRatR < 2.0) for "acceptability" of the
variation associated with an analytical method. However, the Horwitz ratio was used in this study only to
highlight precision results where analytical performance did not adequately describe the observed
variability.
Source of variation in the validation results were based on feedback from the participating laboratories,
precision statistics, and the assessment of Horwitz ratios.  The identified sources of variation included
errors in pH measurement (e.g.,  inadequate pH meter calibration, waiting to measure pH after solid-liquid
phase separation) and material heterogeneity, in some materials, due to time lag between distribution of
study materials and testing.  The median values of Method 1313 precision for eight analytes common to
all three study materials were 13% RSDr for repeatability and 28% RSDR for reproducibility.  Therefore,
single operator replication of Method 1313 would be within 13% while test results for multiple
laboratories performing Method 1313 on the same material would be within 28%.  For Method 1316, the
median precision values  were slightly better for the same set of analytes at 8% RSDr repeatability and
19% RSDR reproducibility indicating that single operator variation would be 8% and the variation in
results from multiple laboratories would be within 19%. Since the EPA does not specify precision criteria
for "acceptability" of a test method, no conclusion regarding the acceptability of these methods could be
made.  However, the repeatability and reproducibility for both methods were consistent with or better
than similar precision estimates  derived for a European standard (EN) single-batch leaching test, EN
12457 part 2 (van der Sloot  et al. 2001) and considerably lower than the mean reproducibility value
reported for TCLP (EPA 1992a). Therefore, Method 1313 and Method 1316 can be performed with the
same or better precision as other currently active standardized leaching procedures.
In parallel to the interlaboratory validation study, research laboratories in the Netherlands and Denmark
measured the pH-dependent leaching of the three study materials using two European technical standard
(TS) leaching tests currently undergoing standardization through the Comite Europeen de Normalisation
(CEN).  These two pH-dependence leaching tests, CEN/TS 14429 and CEN/TS 14997, are similar in
structure and approach to Method 1313; however, minor procedural differences exists between all of
these tests in how pH is controlled in the final eluate and the distribution of pH values across the range of
environmental pH. CEN/TS 14429 allows for initial addition of dilute acid and base solutions in the same
way as Method 1313; however, leaching solutions are introduced in three equal fractions over the first
two hours of the test. This approach applied to wastes in the CEN/TS 14429 test has become the basis for
leaching tests developed under ISO technical committee TC 190 for Soil Quality. Rather than initial acid
or base additions, CEN/TS 14997 specifies the use of automatic pH control to adjust and maintain pH
over the duration of the test. The results of the CEN TS testing were plotted against the 95% robust
confidence limits derived from interlaboratory testing of Method 1313. For nearly 30 metal analytes from
each of the three study materials, CEN leaching test concentrations agreed extremely well with the 95%
robust confidence limits  (RCLs) for Method 1313 indicating little to no difference in the performance of
                                               vn

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


Method 1313 and European pH-dependent leaching tests.  Small deviations for three example analytes
could be explained by material heterogeneity (e.g., aging effects, incomplete dissolution of metal salts in
SWA), oxidation of leaching solutions in open vessels during CEN/TS 14997, or storage of strong
reagents in containers made of incompatible materials. Overall, excellent agreement between the three
tests supports the fact that Method 1313 is an appropriate leaching procedure for determining the pH-
dependent leaching from solid materials.
                                              Vlll

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
ABBREVIATIONS
ANC
ANOVA
ASTM
BNC
CEN
            acid neutralization capacity
            analysis of variance
            ASTM International (formerly American Society for Testing and Materials)
            base neutralization capacity
            European Committee for Standardization (Comite Europeen de Normalisation)
CFS        contaminated field soil
df          degrees of freedom
DHI        DHI, Hersholm, Denmark
DIG        dissolved inorganic carbon
DOC        dissolved organic carbon
DQI(s)      data quality indicator(s)
EaFA       coal combustion fly ash
ECN        Energy Research Centre of the Netherlands (Petten, the Netherlands)
EN         European standard test method
EPA        United States Environmental Protection Agency
EU         European Union
HOPE      high density polyethylene
HorRatR     reproducibility Horwitz ratio
1C          ion chromatography
ICP-MS     inductively coupled plasma-mass spectroscopy
ICP-OES    inductively coupled plasma-optical emission spectroscopy
IQR        interquartile range
ISO        International Organization for Standardization
LEAF       Leaching Environmental Assessment Framework
L/S         liquid-to-solid ratio [mL/g, dry mass basis]
LSP        liquid-solid partitioning
M          median of laboratory means
MAD       median absolute deviation
MDL       method detection limit
ML         minimum level of quantification
MSDS      material safety data sheet
ORD        Office of Research and Development
OSWER     Office of Solid Waste and Emergency Response
ORCR      Office of Resource Conservation and Recovery
PL(s)       prediction limit(s)
PRSDR      predicted reproducibility relative standard deviation
QAPP       quality assurance project plan
QA/QC      quality assurance/quality control

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
RCL(s)     robust confidence limit(s)
RCRA      Resource Conservation and Recovery Act
RL(s)       reproducibility limit(s)
RSD(s)     relative standard deviation(s)
RSDr       repeatability relative standard deviation
RSDR       reproducibility relative standard deviation
sr           standard deviation associated with repeatability
SR          standard deviation associated with reproducibility
SWA       solidified waste analog
SW-846     EPA methods compendium, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods
TC         toxicity characteristic
TS         technical specification
XRFS       x-ray fluorescence spectroscopy

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
TABLE OF CONTENTS

Acknowledgments	ii
Abstract	iii
Executive Summary	iv
Abbreviations	ix
List of Figures	xiv
List of Tables	xv
Introduction	1
Study Objectives	3
Method Descriptions	3
    Method 1313: Liquid-Solid Partitioning as a Function of Eluate pH using a Parallel Batch
    Extraction Procedure	3
    Method 1316: Liquid-Solid Partitioning as a Function of Liquid-Solid using a Parallel Batch
    Extraction Procedure	4
    Data Management of LEAF Test Results	4
Validation Study Overview	4
    Project Organization	5
    Selection and Maintenance of Participating Laboratories	5
    Phase I - Initial Demonstration of Proficiency	6
    Evaluation of Phase I Data and Analyte Selection	6
    Phase II- Generation of Method Validation Results	6
    Calculation of Precision Statistics	6
       95% Prediction Limits (PLs)	7
       95% Robust Confidence Limits (RCLs)	7
       Standard Deviations about the Mean	7
       Coefficient of Variation (CVs)	7
       Horwitz Ratio	7
       Relative Standard Deviations	7
Study Materials	8
    Coal Combustion Fly Ash	8
    Solidified Waste Analog	8
    Contaminated Field Soil	9
    Total Content of Study Materials	9
Analytical Methods	11
    Supplemental Analysis for Reference Laboratory Eluates	12
       Inductively Coupled Plasma - Mass Spectroscopy	12
       Total Carbon Analysis	12
Data Processing	13
    Method Blank Analysis and Data Filtering	13
    Data Transformation and Linear Interpolation/Extrapolation to Target Values	13
Statistical Calculations	14
    95% Prediction Limits (PLs) based on Reference Laboratory Results	14
    95% Robust Confidence Limits (RCLs) based on the Median of Laboratory Mean Data	15
    Estimates of Variance Components and Standard Deviations	16
       Preliminary Calculations and Example ANOVA Table	17
       Variance Components and Standard Deviations	17
                                              XI

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


    Repeatability and Reproducibility	18
    Horwitz Ratio (HorRat)	18
    Reproducibility Limit	19
Phase I Laboratory Feedback (Methods 1313 and 1316)	20
QA/QC Summary	21
    Homogeneity of Study Materials	21
    Analytical QA/QC	22
    Method Blank Analysis	23
    Data Filtering for Cause	23
Analyte Selection and Data Transforms	24
Method 1313 Results and Analysis	26
    Acid/base Neutralization Capacity (Titration Curve)	26
    Statistical Analysis of pH-dependent Leaching	27
       Interpolation/Extrapolation ofLog10-tmnsformedData	29
       Prediction Limit and Robust Confidence Limits	31
       Standard Deviations and Coefficients of Variation	34
       Method 1313 Repeatability and Reproducibility	35
Method 1316 Results and Analysis	41
    pH Response as a Function of L/S	41
    Statistical Analysis of L/S-dependent Leaching Data	42
       Interpolation/Extrapolation ofLog10-transformedData	42
       Prediction Limit and Robust Confidence Limit -based Statistical Analysis	42
       Standard Deviations and Coefficients of Variation	44
       Method 1316 Repeatability and Reproducibility	44
Comparison of Method Precision to Standardized Leaching Methods	50
    TCLP (SW-846 Method 1311) Reproducibility	50
    EN 12457 Validation	50
    Precision Distributions and Comparisons	50
       Precision as a Function of Analyte	51
       Precision as a Function of Test Parameters	51
       Precision as a Function of Material	51
Comparison of Analogous EU Leaching Test Results to Method 1313 Validation Statistics	55
    EU Test Method Descriptions (CEN/TS 14429 and CEN/TS 14497)	55
    Comparison of EU Test Results to Method 1313 Statistics	56
Summary and Conclusions	58
    Procedural Considerations	59
    Data Validation Approach	60
    Repeatability and Reproducibility	60
References	61

Appendices
    Appendix A.  Method 1313
    Appendix B.  Method 1316
    Appendix C.  Quality Assurance Project Plan
    Appendix D.  Blank Analysis and Data Filtering
    Appendix E.  Method 1313 Results
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
    Appendix F. Method 1316 Results
    Appendix G. Comparison of EU pH-dependence Tests to Method 1313 RCLs
    Appendix H. Summary of Analytical QA/QC for Selected Analytes
    Appendix I:  Detailed QA/QC Reports for ICP-OES Analytes4
4 Appendix I contains all of the details of the ICP-OES analysis and QA/QC results for each measured constituent in each
provided analytical solution (i.e., filtered and preserved eluate sample). Therefore, due to its size, the appendix is made available
electronically by request to the authors, through the link to the document page on the EPA website, or as a download at
http: //vanderbilt. edu/leaching.
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
LIST OF FIGURES
Figure 1. Acid/base neutralization capacity for Method 1313 study materials	26
Figure 2. Antimony statistical analysis for Method 1313 Phase I material EaFA	28
Figure 3. Comparison of Method 1313 collected data (left) and interpolated data (right)	29
Figure 4. Linear interpolation of logic-transformed Method 1313 data showing potential for
         increasing data scatter when interpolating along steep slopes	30
Figure 5. Agreement between 95% prediction limits (95% PL) about the mean of the reference
         laboratory data and 95% robust confidence limits (95% RCL) based on the median of
         laboratory means	32
Figure 6. Propagation of variability due to linear interpolation of arsenic concentrations in
         Method 1313 samples of SWA	33
Figure 7. Example standard deviation intervals about the mean and coefficients of variation for
         Method 1313 materials	35
Figure 8. Method 1313 repeatability and reproducibility of antimony	36
Figure 9. Method 1313 repeatability and reproducibility of molybdenum	37
Figure 10. Interpolated data for Method 1313 for chromium in EaFA (left) and antimony in SWA
          (right)	38
Figure 11. Eluate pH for Method 1316 Study Materials	41
Figure 12. Agreement between 95% prediction limits (95% PL) about the mean of the reference
          laboratory data and 95% robust confidence limits (95% RCL) based on the median of
          laboratory means	43
Figure 13. Standard deviation intervals about the mean (left) and coefficients of variation (right)
          for Method 1316 materials	45
Figure 14. Method 1316 repeatability and reproducibility of vanadium	46
Figure 15. Method 1316 repeatability and reproducibility of boron	47
Figure 16. Method precision as a function of selected analytes in comparison to precision values
          reported for EN 12457-2, shown as "EN" (van der Sloot et al. 2001) and TCLP (EPA
          1992a)	52
Figure 17. Method precision as a function of test parameter in comparison to precision values
          reported for EN 12457 (van der Sloot et al. 2001) and TCLP (EPA 1992a)	53
Figure 18. Method precision as a function of material in comparison to precision  values reported
          for EN 12457 (van der Sloot et al. 2001) and TCLP (EPA 1992a)	54
Figure 19. Leaching results from CEN tests compared to Method 1313 RL values	57
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


LIST OF TABLES
Table 1.   Summary of the Number of Targeted and Validation Laboratories	5
Table 2.   Mix Formulation for Solidified Waste Analog (SWA) Material	9
Table 3.   Total Content of Study Materials	10
Table 4.   MDLs and MLs for ICP-OES	11
TableS.   MDLs and MLs for ICP-MS	12
Table 7.   MDLs and MLs for Total Carbon Analysis	13
Table 8.   Constants Cnfor Constructing the Robust Confidence Limits	16
Table 9.   Example ANOVA Table	17
Table 10.  Homogeneity QA/QC for Total Content Derived from XRFS	22
Table 11.  DQI Goals and Overall Results	22
Table 12.  DQIs for ICP-OES Analysis Selected Analytes	23
Table 13.  Overview of Eluates Filtered for Cause	24
Table 14.  Candidate ICP-OES Analytes and Selected Analytes for Statistical Analysis	25
Table 15.  Method 1313 Repeatability (RSDr) across Study Materials	39
Table 16.  Method 1313 Reproducibility (RSDR) across Study Materials	40
Table 17.  Method 1316 Repeatability (RSDr) across Study Materials	48
Table 18.  Method 1316 Reproducibility (RSDR) across Study Materials	49
                                            xv

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
INTRODUCTION
Leaching tests have traditionally been used to estimate the leaching potential of waste or other materials
for situations where the material is placed in a landfill or used on the land.  Leach testing is designed to
assess the potential for contaminant release and the likelihood of groundwater contamination resulting
from land application of wastes and other materials.  In the literature, over 50 different leaching tests have
been identified (van der Sloot et al., 1997) with many individual testing approaches developed for the
evaluation of particular materials or specific management applications.  For example, the United States
Environmental Protection Agency (EPA) currently promulgates Method 1311 (EPA,  1992a), the Toxicity
Characteristic  Leaching Procedure (TCLP), for screening of hazardous wastes and support of land use
decisions. Rather than establishing individual tests for each specific application, a more robust and
flexible approach would allow for broad-based use of a limited set of leaching tests, designed to
determined intrinsic leaching characteristics of wastes and other solid materials, providing leaching
results that can be compared between material types and applied to a wide range of leaching conditions
and release scenarios.
The Leaching Environmental Assessment Framework (LEAF) is a set of leaching test methods, scenario-
based leaching assessment mass transfer models, and information management tools designed to provide
more accurate  estimates of constituent leaching under field conditions than current approaches based on
single-extraction tests.  The  methodology for leaching assessment using LEAF is based on a tiered testing
approach (Kosson et al., 2002) that can account for the impact of environmental conditions on leaching.
Unlike TCLP and other simulation-based approaches currently in wide use, the LEAF leaching tests are
characterization methods intended to generate intrinsic leaching behavior data for a material over a broad
range of test conditions that encompasses the range of plausible waste management conditions. Key
parameters that affect leaching include pH, the ratio of liquid leachant to solid material, and the form
(e.g., particle size) of the waste material. The resulting data can be applied to assess leaching potential
under anticipated field conditions for a range of management scenarios.  Currently, the LEAF test
methods are under review by the EPA Office of Solid Waste and Emergency Response (OSWER) for
inclusion into the EPA's ^est Methods for Evaluating Solid Waste, Physical/Chemical Methods" (SW-
846), the compendium of laboratory methods.  A final stage in the review process is the determination of
method precision, specifically repeatability and reproducibility, through interlaboratory validation to
ensure that method performance is not limited to the individual operator or laboratory that developed the
method.
Method precision is a measure of the variability among test results conducted on the same material or
type of material as defined in ASTM International (ASTM) El 48 8 Standard Practice for Statistical
Procedures to  Use in Developing and Applying Test Methods (ASTM, 2002). Precision is commonly
conveyed in terms of method repeatability and method reproducibility. Repeatability refers to the
closeness of agreement between independent results obtained with the same method on identical test
material, under the same conditions (Currie and Svehla, 1994).  Method repeatability represents a
measure of the expectations of the method to provide similar results of replicate test runs conducted by
the same laboratory expressed through a "within-laboratory" standard deviation. Reproducibility refers to
the closeness of agreement between independent results obtained with the same method on identical test

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


material but under different conditions (Currie and Svehla, 1994).  Method reproducibility provides an
estimate of the variability that might be expected when different laboratories measure the same property
on the same material and is typically expressed as a reproducibility standard deviation.
This report provides method validation results for the following two LEAF leaching methods:1
    • Method 1313:  Liquid-Solid Partitioning as a Function ofEluate pH using a Parallel
                     Batch Extraction Procedure
    • Method 1316:  Liquid-Solid Partitioning as a Function ofLiquid-to-Solid Ratio using a
                     Parallel Batch Extraction Procedure
The validation study for Method 1313  and Method 1316 is based on the two-phase approach suggested by
the EPA's Guidance for Methods Development and Methods Validation for the RCRA Program (EPA
1992b). Within the EPA guidance, there are no pre-established precision criteria for acceptability of a
method; therefore, no conclusion can be made on the acceptability of the LEAF methods based solely on
precision.  However, perspective on a reasonable level of precision may be found in currently accepted
leaching procedures.  For example, interlaboratory studies to provide precision estimates for TCLP
showed a mean reproducibility of 74% relative standard deviation  (RSD) with a range of RSD between 17
and 118% (EPA, 1992a). The intent of the interlaboratory  study for Method 1313 and Method 1316 is to
provide the precision  statistics for these test methods which may be used to support the establishment of
initial performance guidelines and the development of regulatory guidance on the use  of these methods.
Since the  LEAF methods have been developed to determine characteristic or intrinsic  leaching behavior
of a solid  material, the results from a single material should be comparable between similar test methods
designed with the same intent. As part of the validation study, two European laboratories determined the
pH-dependent leaching characteristics  of the study materials using two different pH-dependent leaching
protocols  being developed and adopted by the European environmental community.2 Favorable
comparison of Method  1313 results to the results derived from European Union (EU) pH-dependent
leaching tests is intended to provide support that Method 1313 adequately accomplishes the goal of
providing extraction eluates3 that can be used to determine liquid-solid partitioning of wide variety of
solid material types.
1 Although the LEAF methods are numbered in a manner consistent with SW-846, these methods are currently considered
preliminary versions of EPA Methods which have not yet been endorsed by EPA pending method validation and final review.
2 The comparative European methods are designated as "technical specifications" with a TS designation, indicating a method
definition has resulted from a multi-national consensus process and has been approved by a CEN technical committee.  The TS
designation, however, means that interlaboratory validation studies to assess precision have not yet been conducted and that
public comment and consensus approval by CEN members will be repeated when performance characteristics are available.  A
TS designation does not carry the status of a European standard (EN), but may be adopted as national standard.
3 This report uses the LEAF terminology where "eluate" refers to the solution resulting from a leaching test whereas "leachate"
refers to the solution collected from or measured in the field. The distinction between terms is made to minimize confusion when
comparing laboratory data to field data.

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
STUDY OBJECTIVES
The objectives of the method validation studies were to: (i) determine the method precision through
assessment of method repeatability and reproducibility from extraction results using these methods over a
range of potential waste materials; and (ii) compare the results of Method  1313 to standardized leaching
methods for pH-dependent leaching under development and used in Europe.
METHOD DESCRIPTIONS
The validation results for these two methods are grouped into a single report due to the procedural
similarity of these parallel batch methods and their use in conjunction with one another to assess leaching
potential. Method 1313 and Method 1316 are parallel batch procedures intended to characterize the
liquid-solid partitioning at conditions approaching equilibrium as a function of final extract pH and
liquid-to-solid ratio (L/S), respectively. The test parameters and values specified in these methods have
been described in a background information document on the LEAF leaching methods (Garrabrants et al.,
2010). The following paragraphs briefly describe these methods; full-text versions are presented in
Appendix A (Method 1313) and Appendix B (Method 1316).

Method  1313: Liquid-Solid Partitioning as a Function of Eluate pH using a Parallel Batch
Extraction Procedure
Method 1313 is an equilibrium-based leaching test designed to provide eluate solutions representing the
liquid-solid partitioning (LSP) curve of constituents as a function of eluate pH. The procedure consists of
nine parallel batch extractions at targeted pH values and one extraction at the natural pH4 of the material.
The solid material may require particle size reduction by crushing in order to facilitate the approach to
solid-liquid equilibrium within a reasonable extraction timeframe. Dilute acid or base in deionized water
is added to each extraction according to a pre-test titration in order to achieve final extract pH values at
specified target values ranging between 2 and 13 at an L/S of 10 mL/g-dry. The extraction contact time
ranges from 24 to 72 hours based on the grain size of the "as tested" material (i.e., the material after any
particle size reduction or air drying required to improve the handling of the "as received" material). The
pH and conductivity of the final extract solution are recorded and vacuum- or pressure-assisted filtration
is used to separate the liquid and solid phases prior to chemical analysis of the eluate.  Eluate
concentrations for constituents of interest are plotted as a function of eluate pH allowing for comparison
to quality control and assessment limits. Eluate concentrations may also be interpolated to the target pH
values to provide a uniform basis for comparison of results as the recorded eluate pH is likely to differ
slightly from target values within specified pH tolerances.
4 The natural pH (also referred to as "own pH") is the final eluate pH response of a deionized water extraction of a solid material
(i.e., no acid or base added) conducted at an L/S 10 mL/g-dry.

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


Method 1316: Liquid-Solid Partitioning as a Function of Liquid-Solid using a Parallel Batch
Extraction Procedure
Method 1316 is an equilibrium-based leaching test intended to provide eluate solutions over a range of
L/S values from 10 to 0.5 mL/g-dry using five parallel batch extractions in DI water.  No acid or base is
added to the extractions so that the results can indicate changes in eluate pH with L/S. Particle size
reduction of the solid material may be required in order to facilitate the approach to solid-liquid
equilibrium. The contact time for the extractions ranges from 24 to 72 hours based on grain size. The pH
and conductivity of the final extract solution are recorded.  Solid and liquid phases are separated by
vacuum- or pressure-assisted filtration and prepared for chemical analysis.  This method provides
information on the changes  in equilibrium chemistry (i.e., ionic strength, constituent concentrations) as
the L/S approaches values found within the solid phase pore solution.

Data Management of LEAF Test Results
For each of the LEAF methods, a data template in the form of a Microsoft® Excel spreadsheet is available
and recommended to assist with method execution (e.g., calculations for the amounts of water and acid to
be added to Method 1313 extracts based on sample mass, moisture content and titration curve
information) as well as uniform recording of pertinent bench-scale and analytical data. Each data
template also serves as an upload interface into the materials database contained within LeachXS Lite™,
a limited capability version  of LeachXS™.5
The Lite version of LeachXS is a freely licensed software program, focused primarily on data
management and report facilitation, which was developed, in part, to facilitate EPA coal combustion
residue reports (Sanchez et al., 2006;  Sanchez et al., 2008, Kosson et al., 2009). The  LeachXS Lite
version allows users to import leaching test data from the LEAF methods into a materials database,
compare test results to user  defined indicator lines (e.g., quality control indicators or regulatory limits),
and output Excel spreadsheets as tabular data and consistently formatted graphs for comparison between
data sets (e.g., test replicates of the same material or of different materials). LeachXS Lite can be used
with LEAF testing results from any applicable material and is not restricted to use for coal combustion
residues. The free version does not include the advanced formatting, statistical calculations, or
geochemical and reactive transport modeling capabilities of the full LeachXS version.


VALIDATION STUDY OVERVIEW
A two-phase validation study based on EPA's Guidance for Methods Development and Methods
Validation for the RCRA Program (EPA, 1992b) was completed for each test method. This guidance
document recommends that precision statistics be based on test results from a minimum of three materials
conducted in triplicate by a  minimum of three participating laboratories. The minimum number of
laboratories in the study was deemed too small to produced adequate statistical analysis, so the guideline
of at least  six participating laboratories as recommended in ASTM E691 Standard Practice for
5 The development of the LEAF methods, data templates, and LeachXS Lite™ is the result of collaboration between EPA,
Vanderbilt University, the Energy research Centre of the Netherlands and DLfl (Denmark). These materials are available free of
charge at www. vanderbilt.edu/leaching.

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


Conducting an Interlaboratory Study to Determine the Precision of a Test Method (ASTM, 1987) was
adopted for this study. The design and execution of this validation study was supported by a quality
assurance project plan (QAPP) which described all material handling procedures and data quality goals.
The QAPP is presented Appendix C as approved by the EPA Office of Research and Development.

Project Organization
ARCADIS-US, Inc. (ARCADIS) was selected as the reference laboratory for this study based, in part, on
previous demonstration of proficiency (Sanchez et al., 2006; Sanchez et al., 2008; Kosson et al., 2009).
In order to minimize variations in test method results stemming from different analytical approaches,
equipment and operators, all eluate chemical analysis was conducted at Vanderbilt University (VU) using
inductively coupled plasma-optical emission spectroscopy (ICP-OES). The EPA ORD served as project
manager while the EPA Office of Resource Conservation and Recovery (ORCR) within EPA OSWER
was responsible for maintaining lines of communications with participating laboratories and for gathering
and assembling feedback on the methods from the participating laboratories.

Selection and Maintenance of Participating Laboratories
A wide range of participating laboratories (e.g., academic, government and commercial laboratories) were
asked to donate time, personnel and support for this study. Each laboratory completing the entire
validation study was asked to perform each test method in triplicate on three materials. In parallel, the
reference laboratory submitted six test replicates of each test for chemical analysis.
Based on the pro bono nature of the laboratory participation, a certain level of attrition was expected
throughout the course of the study. Therefore, ten laboratories for each phase of the study were targeted
in order to maintain the minimum of six participating laboratories stated in the ASTM guidance. A
summary of the number of targeted laboratories and the number of laboratories used in the validation
study for each method and material is presented in Table  1.
              Table 1. Summary of the Number of Targeted and Validation Laboratories.
              Method
              Method 1313
Materials
Coal Combustion Fly Ash
Solidified Waste Analog
Contaminated Field Soil
   Target        Validation
Laboratories    Laboratories
    11
    10
    10
10
              Method 1316
Coal Combustion Fly Ash
Solidified Waste Analog
Contaminated Field Soil
    11
    10
    10
10
Each laboratory was identified by a number to provide anonymity when reporting data. During Phase I of
the study, only nine of the ten participating laboratories returned eluates for analysis. Laboratory Three
(L03) was unable to participate due to unanticipated funding problems.  In order to maintain a number of
laboratories that would provide for attrition, an eleventh laboratory was added so that Phase I testing
could be completed with ten participants. For Phase II testing, eight of the remaining ten laboratories
returned samples for analysis. Laboratory Eight (LOS) and Laboratory Two (L02) were unable to return
eluates for one or both Phase II materials citing resource limitations.

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
Phase I - Initial Demonstration of Proficiency
Laboratories initially selected to participate in the study were asked to demonstrate proficiency and
familiarization with the new methods by conducting triplicate test runs of both Method 1313 (nine or ten
extracts per replicate) and Method 1316 (five extracts per replicate) on a single material and submitting
filtered and preserved eluates to VU for chemical analysis. The reference laboratory conducted six test
replicates.  All in-laboratory data (e.g., extract setup calculations, eluate pH and conductivity
measurements) were recorded and entered into Excel data templates by the participating or reference
laboratories. The Excel data templates were provided to the laboratories by the study organizers to ensure
proper archiving of all pertinent test data.  Feedback from participating laboratories, in the form of written
questionnaires and conference call discussions, was used to refine the test methods for Phase II in order to
clarify any unclear procedures or descriptions.

Evaluation of Phase I Data and Analvte Selection
The laboratory data and eluate concentrations resulting from Phase I testing were imported into LeachXS
by VU for initial statistical analysis and data graphing.  Screening to pass participating laboratories on to
Phase II of the study was based on visual comparison of eluate concentrations from participating
laboratories to the results of six test replicates prepared by a reference laboratory. In addition, the results
of Phase I were used to develop initial estimates  and procedures for calculation of variance within and
between laboratories as the  statistical basis for quantifying method precision.

Phase II - Generation of Method Validation Results
Laboratories passing the Phase I portion of the validation were asked to continue participation by testing
two additional materials by  providing filtered eluates and laboratory data from triplicate test runs of both
Method 1313 and Method 1316 conducted on two additional materials.  As in Phase I, all in-laboratory
data (e.g., extract setup calculations, eluate pH and conductivity measurements) were recorded by the
participating laboratories in the form of Excel data templates.

Calculation of Precision Statistics
For each material and test, participating laboratories were required to  complete the laboratory data
sections of the provided Excel data template.  When chemical analysis was complete and  validated by VU
analytical staff, eluate concentrations were amended to the data template which was used  to upload test
method and analytical data into LeachXS. The approach for analysis  of validation data included standard
statistical calculations consistent with the methodologies presented in EPA and ASTM guidance and the
recommendations of the International Standards  Organization (ISO) Accuracy (Trueness and Precision)
of Measurement Methods and Results (ISO, 1994). This data assessment approach was recommended by
collaborators at North Carolina State University  and approved by EPA through the QAPP review process.
The statistical equations were  implemented into a statistics module developed for LeachXS  by
collaborators at ECN. The statistics module allows the user to  merge  datasets from the materials  database
(e.g., each replicate of results from a single test of a method at  a single laboratory is a separate dataset)
and calculate parametric and non-parametric statistics.  The output was saved as an .xml file that then was
uploaded back into LeachXS for data processing and visualization.  Using the standard statistical
functions implemented in LeachXS for this project, the following statistics were derived from interpolated
eluate concentrations and used to describe the validation data:

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
    •   95% Prediction Limits (PLs)
        Prediction limits were calculated using the reference laboratory data and used to create an interval
        above and below the mean of the reference laboratory data. The interval about the mean indicates
        the range within which future data from the reference laboratory would fall at the 95% probability
        level.
    •   95% Robust Confidence Limits (RCLs)
        Confidence Limits using robust statistical approaches (Huber, 1968; Daszykowski et al, 2007)
        were derived and used to create an interval about the median of the laboratory means.  The
        interval represents the range of response for the mean of a laboratory at the 95% probability level.
    •   Standard Deviations about the Mean
        Standard deviations associated with "within laboratory", "between laboratory" and "overall"
        variance factors were derived from the calculations used in a one-way analysis of variance
        (ANOVA). These standard deviations were used to create intervals about the mean of the data set
        to represent the range of uncertainty associated with each variance factor in the ANOVA. Since
        not formal ANOVA was conducted, the significance statistics from the F-distribution was not
        calculated.
    •   Coefficient of Variation (CVs) 6
        Coefficients of variation are presented as standard deviations for "within laboratory", "between
        laboratory" and "overall" variance factors normalized to the mean test output value in order to
        compare relative contributions from these variance sources.

    •   Horwitz Ratio
        The Howitz Ratio is a statistic that was introduced to predict the inherent variability of chemical
        analyses as a function of concentration value (Horwitz and Albert, 2006). The Horwitz Ratio for
        reproducibility (HorRatR) was calculated from the "overall" CV, often associated with
        reproducibility. In this report, the Horwiz Ratio was used only to assess if eluate concentration
        analysis near the method detection limit was a potentially significant source of variability in the
        test results.
    •   Relative Standard Deviations
        The CVs for "within laboratory" and "overall" variance factors are used to represent method
        precision, respectively, as repeatability relative standard deviation (RSDr) and reproducibility
        relative standard deviation (RSDR).
Method precision, based on RSDr and RSDR values, were determined for ten selected analytes in each of
the three study materials.  Using the method precision data for eight analytes common to all study
materials, distributions of method repeatability and  reproducibility results as a function of test parameters
(i.e., pH for Method 1313 and L/S for Method 1316), analytes, and study materials were compared to
precision statistics published for accepted leaching tests.
6 This report uses the terms "coefficients of variation" (CVs) and "relative standard deviations" (RSDs). Although
mathematically equivalent, these terms are used in the report to differentiate the analysis of variance sources (i.e., CVs for
"within laboratory", "between laboratory" and "overall" standard deviations) from measures of method precision determined as
the repeatability relative standard deviation (RSDr) and reproducibility relative standard deviation (RSDR).

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
STUDY MATERIALS
Three study materials - a coal combustion fly ash, a laboratory-formulated solidified waste material and
field contaminated soil - were chosen for the methods validation of Method 1313 and Method 1316 in
order to challenge the method performance for a range of typical waste types. The three materials were
either collected from the  field or created in the laboratory prior to homogenization and distribution to the
participating laboratories.

Coal Combustion Fly Ash
A coal combustion fly ash (identified by material code EaFA) was used as the Phase I test material in
order for participating laboratories to demonstrate proficiency with the test methods. A large sample of
fly ash was collected in twenty-five, 5-gallon buckets from a coal-fired power plant located in the United
States. Samples were homogenized by ARCADIS using coning and quartering techniques. The
homogenized fly ash was returned to  5 gallon buckets and subsamples from three of the 25 buckets were
taken for total content analysis by Method 3052/ICP-OES. Once homogenization was verified through
comparison of total content subsamples, the fly ash was further divided into 1-kg portions placed into 1-L
high density polyethylene (HDPE) containers for distribution to the laboratories.  Six randomly selected
1-L containers (6 kg) were sent to each participating laboratory for triplicate testing of Method 1313 and
Method 1316. The reference laboratory retained 12 randomly selected containers (12 kg), enough
material to conduct six replicates of each test. Major species in the EaFA fly ash include Al, Fe, K, Si,
and total of inorganic and organic carbon  while minor species included B, Ca, Mg, Na, S, and Ti.

Solidified Waste Analog
For Phase  II of the validation study, a cementitious material representing a solidified waste stream was
created at VU and distributed to the study participants. The solidified waste analog (identified by
material code SWA) was comprised of a powdered solid binder (Type I portland cement, class C coal
combustion fly ash, and ground granulated blast furnace  slag) and waste water at a water/binder ratio of
0.41 (m/m). The waste water used was tap water spiked  with powdered metal oxides or metal nitrates of
antimony,  arsenic, barium, chromium, lead and selenium (Fisher Scientific). Final mix formulation in
weight percent of the cured product is shown in Table 2.

The SWA material was mixed with shovels and hoes in an open trough until evenly blended.  The
cementitious material was packed into a series of 10-cm  diameter by 20-cm long cylindrical molds and
cured in a moist environment for at least 28 days. In preparation for batch testing, approximately 72 kg of
cured solidified material was size  reduced to maximum particle size of < 2 mm in a two-stage crushing
process. The entire 72-kg batch of particle-size reduced  material was homogenized in a barrel mixer and
divided into a series of 1-L HDPE jars, each containing approximately 1 kg of material. Six randomly
selected 1-L containers (6 kg) were distributed to each of the participating laboratories while 12 randomly
selected containers (12 kg) were sent to the reference laboratory.  Subsamples from five of the 2-liter jars
were taken for total content analysis by Method 3052/ICP-OES. The major species in SWA included Al,
Ca, Fe, Mg, Si, Na, and total carbon while Sb, As, B, Ba, Cr, P, K, Se, Sr, S, and Ti were detected as
minor species.

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
                   Table 2. Mix Formulation for Solidified Waste Analog (SWA) Material.
Component
^^^^^H
Type I portland cement
Class C fly ash
Blast furnace slag
Tap Water
Na2HAsO4-7H2O
Ba(N03)2
K2CrO4
KC1
Pb(N03)2
Sb2O3
NaSeO4
NaOH
CH3OONa
NaNO3
Na2CO3-H2O
SWA
(% by mass)
6
33
33
26.3
0.11
0.06
0.11
0.06
0.06
0.06
0.08
0.03
0.06
0.01
1.03
Contaminated Field Soil
The other material tested in Phase II of the method validation study was a soil contaminated with heavy
metals collected from a smelter site located in the United States.  Approximately 320 kg of contaminated
field soil (identified by material code CFS) was collected in 5-gallon plastic buckets and shipped to
ARCADIS for processing.  The entire batch of soil was sieved to pass a 2-mm opening in order to remove
large rocks and other refuse and transferred to a clean blue plastic tarp for mixing by coning and
quartering. After homogenization, the soil was divided into 1-L HDPE jars containing approximately 1-
kg each for distribution to the participating laboratories. Each participating laboratory received six
randomly selected jars (6 kg) of soil to be used in testing while the reference laboratory retained 12
randomly selected jars (12 kg). Subsamples from 12 randomly selected containers were taken for total
mercury analysis and an additional three subsamples taken for total content analysis by Method
3052/ICP-OES. Total content analysis of CFS material showed that major species included Al, Ca, Cu,
Fe, K, Si, Na, S, and Zn while minor species included As, Pb, Mg, Mn and Ti.

Total Content of Study Materials
The total contents of constituents in the three study materials are presented in Table 3. For the purposes
of interpreting total content and describing these materials, analytes may be grouped into major, minor,
and trace species as follows:
    •    Major species - analytes with total content of at least 10,000 mg/kg (i.e., 1 % by mass)
    •    Minor species - analytes with total content less than 10,000 mg/kg but at least 1,000 mg/kg
    •    Trace species  - analytes with total content less than 1,000 mg/kg.

Total  contents are based on either x-ray fluorescence spectrometry (XRFS) or a combination of
microwave digestion of solid subsamples, performed by ARCADIS following EPA Method 3052 (EPA
1996) with chemical analysis of digestates conducted by ICP-OES at VU following EPA Method 6010
(EPA 2007b).  All reported total content values for trace and minor species shown in Table 1 were

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Interlaboratory Validation of LEAF Method 1313 and Method 1316

determined by EPA Method 3052/ICP-OES with the exception of boron. Since metaborate is added
during the digestion process in Method 3052, total boron was reported as determined by EPA Method
3051 (EPA2007A).

             Table 3.  Total Content of Study Materials.
Analyte
Aluminum3
Antimony
Arsenic
Barium
Beryllium
Boronb
Cadmium
Calcium3
Carbon, inorganic0
Carbon, organic0
Chromium
Cobalt
Copper
Iron3
Lead
Lithium
Magnesium
Manganese
Molybdenum
Nickel
Phosphorus
Potassium
Selenium
Silicon3
Sodium
Strontium
Sulfur
Thallium
Titanium
Vanadium
Zinc
Symbol
Al
Sb
As
Ba
Be
B
Cd
Ca
TIC
TOC
Cr
Co
Cu
Fe
Pb
Li
Mg
Mn
Mo
Ni
P
K
Se
Si
Na
Sr
S
Tl
Ti
V
Zn
EaFA
mg/kg
130,000
1.5
63
830
15
1,400
3.5
8,700
1,400
148,000
120
62
130
40,000
39
84
3,700
110
15
89
490
18,0003
24
230,000
5,700
610
1,500
0.91
6,200
220
100
SWA
mg/kg
59,000
2,100
1,100
3,000
3.5
3,600
2.6
220,000
2,000
5,000
1,200
18
67
21,000
330
4.3
33,0003
900
7.6
25.0
2,000
7,000
1,300
120,000
40,0003
1,300
8,200
1.1
4,400
100
86
CFS
mg/kg
34,000
490
1,900
810
0.39
610
310
46,000
600
27,000
240
110
60,000a
87,000
6,0003
1.80
5,300
1,700
710
80.0
380
11,0003
52.0
150,000
11,0003
280
64,0003
29.0
2,200
58.0
25,0003
            Notes:
              All total content determinations by digestion using EPA Method 3052 and ICP-OES unless noted.
                 a Total content by XRFS (SOP No. 5003.3)
                 b Total boron by digestion using EPA Method 3051 (EPA, 2007a)
                 0 Total organic and inorganic carbon by catalytic combustion EPA Method 9060 (EPA, 2004)

For the total content of major species in Table 2, total content was determined by XRFS conducted at
ARCADIS on twelve subsamples of homogenized study material using a Philips model PW 2404 XRFS
(PANalytical B.V., Almelo, the Netherlands) following a standard operating procedure (SOP), SOP No.
5003.3, maintained by ARCADIS. The RSDs for the twelve subsamples of study material formed a
measure of the homogeneity of the material  prior to distribution to the participating laboratories.
                                                                                             10

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
ANALYTICAL METHODS
In order to minimize uncertainties associated with participating laboratories applying different analytical
techniques and analytical quality control, each participating laboratory was asked to  ship preserved
analytical solutions (i.e., filtered eluates with 1% by volume Optima grade nitric acid) under chain of
custody to VU for chemical analysis. All eluates were analyzed at VU to minimized variability in the
results associated with individual analytical methods and quality assurance/quality control (QA/QC)
assessments. The  concentrations of metal analytes were measured by ICP-OES (SW-846 Method 6010)
on a Varian ICP Model 720-ES (Agilent Technologies, Santa Clara, CA). Table 4 presents the ICP-OES
analytes and associated method detection limit (MDL) and minimum level of quantification (ML),
determined by the analytical laboratory according to the EPA Technical Support Document for the
Assessment of Detection and Quantitation Approaches (EPA 2003).7
         Table 4.  MDLs and MLs for ICP-OES.
Symbol
Al
Sb
As
Ba
Be
B
Cd
Ca
Cr
Co
MDL
(fig/L)
1.0
7.5
11.0
1.0
1.7
1.0
2.2
2.6
1.2
1.8
ML Symbol
(Hg/L)
3.2
23.9
35.0
3.2
6.0
3.2
7.0
8.3
3.8
5.7
Cu
Fe
Pb
Li
Mg
Mn
Mo
Ni
P
K
MDL
(Mg/L)
3.7
2.0
6.8
1.9
1.0
2.0
1.2
1.8
3.7
1.6
ML
(Mg/L)
11.8
6.4
21.6
6.0
3.2
6.4
3.8
5.7
11.8
5.1
Symbol
Se
Si
Na
Sr
S
Tl
Ti
V
Zn
MDL
(Hg/L)
15.0
1.1
2.5
1.0
6.8
4.6
2.0
1.5
1.0
ML
Oig/L)
47.7
3.5
8.0
3.2
21.6
14.6
6.4
4.8
3.2

Concentrations measured at values less than the MDL were reported as "non-detected," but set to a value
equal to 1A the MDL value for plotting and data analysis. Concentrations measured at less than the ML
but greater than the MDL are reported as "estimated values."
The ICP-OES analytical range for trace metals was calibrated using five-point standard curves whereas
seven-point standard curves were used for major component analytical ranges between approximately 0.1
mg/L and 500 mg/L.  During analysis of solutions, blanks and calibration check standards (~0.5 mg/L)
were monitored every 10 to 20 samples with the requirement that recoveries be within 20% of the
specified value. Analyses were performed on undiluted samples when possible and samples were diluted
gravimetrically to within the targeted analytical range when necessary using 1% (v/v) Optima grade nitric
acid (Fisher Scientific) in deionized water. Yttrium at 10 mg/L was used as an internal  standard.
Analytical matrix spikes were checked for three test positions for each triplicate analysis of a laboratory
7 The analytical data quality indicators for this report are based on the guidelines established by the EPA Office of Water and
include establishing a method detection limit (MDL) and minimum level of quantitation (ML) based on standard deviation of
seven non-consecutive analyses of a low-concentration standard analytical solution. However, the EPA Office of Resource
Conservation and Recovery (ORCR) has recommended that practitioners establish a lower limit of quantitation (LLOQ) for
analytes of concern as a demonstration of quantitation capability at low analyte concentration levels. The LLOQ demonstration
is a performance-based validation of recovery from a spiked analytical solution typically at concentration levels approximating
the lowest calibration standard.
                                                                                                  11

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


data set.  For each analytical matrix spike, a volume of 500 uL of a 10 mg/L standard solution was added
to 5 mL of sample aliquot.

Supplemental Analysis for Reference Laboratory Eluates
For the eluates resulting from the six test replicates conducted by the reference laboratory, the standard
chemical characterization by ICP-OES was supplemented with analysis of Cs, Sn, and U by inductivity
coupled plasma-mass spectroscopy (ICP-MS) and analysis of dissolved inorganic carbon (DIC) and
dissolved organic carbon (DOC) by total carbon analysis. Supplemental analysis was conducted to
address specific regulatory concerns (e.g., Cs, Sn, and U) and to document the dissolution of carbon
species which can significantly influence leaching concentrations.
Prediction limits at the 95% probability level were calculated for all analytes (i.e., supplemental analytes
plus ICP-OES analytes) from chemical analysis of the six reference laboratory test replicates to illustrate
the range of within-laboratory data obtained during the validation study. The full set of analytical data is
presented in Appendices E (Method 1313) and F (Method 1316) for the reference laboratory test results.

Inductively Coupled Plasma - Mass Spectroscopy
ICP-MS analysis following SW-846 Method 6020 (EPA 2007c) was carried out at VU using a Perkin
Elmer model ELAN DRC II (Perkin Elmer, Waltham, MA) in standard mode.  Initially, analyses for 10:1
dilutions were performed to minimize total dissolved loading to the instrument.  Additional dilutions at
100:1 and 1000:1 were analyzed if the calibration range was exceeded with the 10:1 dilution.  Internal
standards consisting of 50 uL of a 10 mg/L indium (for mass range below 150) and bismuth (for mass
range over 150) were added to 10 mL of sample aliquot prior to analysis. MDLs and MLs for ICP-MS
analyses as determined by the analytical laboratory are shown in Table 5.

                              Table 5.  MDLs and MLs for ICP-MS.

Symbol
Cs
Sn
U
MDL
(Hg/L)
0.49
0.70
0.30
ML
(Hg/L)
1.6
2.2
1.0
Total Carbon Analysis
Total carbon analysis following SW-846 Method 9060 (EPA, 2004) for all eluates was performed on a
Shimadzu model TOC-V CPH/CPN (Shimadzu Scientific Instruments Inc., Columbia, MD) to determine
the concentrations of DIC and DOC.  Five-point calibration curves, for both DIC and non-purgeable DOC
analyses, were generated for an analytical range between 5 ppm and 100 ppm with an acceptable
correlation coefficient of at least 0.995. After every 10 samples, an analytical blank and calibration check
standards at approximately 1 mg/L were measured and compared to acceptable QA/QC criteria. The
recovery on standard checks was required to be greater than 85%.  MDLs and MLs for DIC and DOC
analyses as determined by the analytical laboratory are shown in Table 7.
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


                         Table 6.  MDLs and MLs for Total Carbon Analysis.
DATA PROCESSING
Data processing includes all operations used to prepare collected data for use in statistical analyses
including data validation (e.g., assessment of method blanks and associated data filtering) and
transformation and interpolation to target pH values.

Method Blank Analysis and Data Filtering
As specified in both Method 1313 and Method 1316, each laboratory provided analytical solutions
representing method blank extractions (i.e.,  extraction conducted without solid material, but otherwise
carried through the process with the equipment and handling procedures as extractions with solid
material). These method blanks were chemically analyzed by ICP-OES along with the test extractions
and the results were used to identify potential sources of contamination (e.g., contact surfaces,
contaminated reagents) that might bias the results of the test extractions. For cases where the method
blanks or other process variables (e.g., pH, L/S) indicated that analyte concentrations in the test
extractions may have been biased, removal or "filtering" of the corresponding test extraction result from
the statistical analysis was considered. A more detailed discussion of method blank analysis and data
filtering are presented in the results section.

Data Transformation and Linear Interpolation/Extrapolation to Target Values
Statistical analyses were performed on logic transformed concentration results which had been
interpolated to the target pH or L/S values designated in the respective methods.  Log transformation is
common statistical practice to lessen the impacts of extreme data values and render distributions closer to
normal, thereby enhancing the suitability of statistical methods based on the normal distribution.
For Method 1313 data, interpolation of results to the target pH values was  necessary to adjust for the
tolerance in final pH value (± 0.5 pH units)  and the strong effect of pH on  eluate concentration for many
elements. In some cases, extrapolation to either the lowest or highest target value was necessary.
Method 1316 data were reported at the target L/S values so that interpolation had little to no effect, but
was carried out in order to adhere to a uniform data processing procedure.  However, participating
laboratories found it difficult, for some materials, to separate solid and liquid phases in low L/S
extractions so that sufficient eluate volume was recovered for ICP-OES analysis. Thus, eluate solutions
at an L/S value of 0.5 were not returned for  two laboratories for EaFA, seven laboratories for SWA, and
one laboratory for CFS. For these data sets, unrestricted extrapolation to target L/S values would result in
extrapolated used in the statistical analysis where no laboratory data was provided and extrapolation was
limited to only those points within 10% of an L/S value (e.g., ±0.1 L/S at target L/S of 1). Limited
extrapolation prevented creation of interpolated or extrapolated data when a test position eluate was not
submitted for chemical analysis by a participating laboratory.
                                                                                               13

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


In all cases, linear interpolation and extrapolation of the logic transformed data was based on the
concentrations recorded at the two data points nearest to the target value. For example, if data are
returned with eluate pH values of 2.2, 4.2 and 5.2, the eluate concentration values at pH 2.2 and 4.2 are
used to extrapolate to a target pH of 2.0 and interpolate to a target pH of 4.0.
The algorithm for interpolation is as follows:
        Given a set of coordinate data { (xl j^) : / : = !,...«} sorted by the first coordinate (so that xl < x2 <
        ••• < xn) and a target x-value, call it XT, an interpolated/extrapolated j-value, call it JT, is calculated
        as:
        where:
           •   if XT < Xi, then 6T = (y2 ~ Ji) / fe ~ ^i) and aT = j2 ~ ^1-^2 (extrapolation from the two
               points with closest x-values);
           •   if XT > xn, then 6T =(yn ~J»-i) / (xn ~ xn-i)and aT =yn - bixn (extrapolation from the two
               points with closest x-values);
           •   if Xj-i < XT < Xj , then 6T = (y/ ~ Jy-i) / (x}- ~ Xy-^and aT = y}- - b^Xj (interpolation from the
               two closest points surrounding XT).
For each analyte, statistical analysis of interpolated, logic transformed concentration results focused on
determination of the following statistical output.
STATISTICAL CALCULATIONS
All statistical calculations were implemented within a module of LeachXS. The module is designed to
allow the user to aggregate or merge individual data sets (i.e., test replicates) into a single data set in order
to output statistical analyses and/or interpolated/extrapolated data as an .xml file. The .xml file can then
be imported back into the LeachXS materials database for visualization and comparison to other data sets.

95% Prediction Limits (PLs) based on Reference Laboratory Results
Using only the reference  laboratory data set of six test replicates, a prediction interval for the mean of the
data set at each target pH was constructed using standard normal distribution-based prediction approaches
at a 95% prediction level (Rao, 1998; Ellison, 2009).
Suppose that there are n replicate laboratory measurements y\,...,yn. The sample mean (y) and sample
standard deviation^) of these measurements are:
The prediction interval is divided into an upper limit (PLupper) and a lower limit (PLlower) calculated as:

        PLlower =y-t- sJl + l/n
                                                                                                14

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
         Cupper

       where  t is the upper 0.025 critical value from the t distribution with n-l degrees of freedom; the
               area to the right of tis 0.025, often denoted in literature as t (n-\, 0.025).

95% Robust Confidence Limits (RCLs) based on the Median of Laboratory Mean Data.
RCLs are defined as intervals about the median of the laboratory means constructed using robust
confidence limits (Huber, 1968; Daszykowski et al., 2007) delineate the reproducibility operating
characteristics across laboratories. In the case where 95% RCLs are calculated, one would expect 95% of
all laboratories to produce a mean Iogi0-transformed concentration value of three replicates to fall within
these bounds. In order to lessen the impact of outlying results from a small subset of laboratories and,
thus, to also facilitate identification of laboratories producing discrepant results, the limits were calculated
substituting robust measures of location and  scale, the median and median absolute deviation (MAD), for
their more common non-robust counterparts, the mean and standard deviation (Maronna et al., 2006).
This substitution also requires modification of the usual ^-distribution critical values commonly seen in
confidence and prediction intervals to ensure the desired coverage probabilities. The robust limits and the
method of calculating adjusted critical values are described below.
For each laboratory data set, the arithmetic mean of the laboratory replicates is calculated as denoted by
y^--->yn  where the subscript refers to the laboratory number. Note that in most cases n=10 for the
targeted ten participating laboratories, but this number may differ when data are missing or filtered. The
robust confidence limits depend on the median of the laboratory means (M) and the median absolute
deviation MAD of this group of means:

       M= medianj y^,...,yn  },

       MAD = median{| y^ -M|,..., yn -M|}.

The  robust confidence intervals are constructed of an upper limit (RCLupper) and a lower limits (RCLlower)
using the formulae
       RCLlower =M- 1.96 Cn (1.4826)M4Z),
       RCLupper = M +1.96 Cn (1.4826)M4£>,
          where the constants Cn for n = 4,..., 12, 100, 200 are given in Table 8.
The  factor 1.4826 in the formulas for the robust confidence limits scales the MAD so that it is an unbiased
estimator of the population standard deviation in large sample sizes when the data are normally
distributed. The factor 1.96 is the 0.025 upper-tail critical value of the  standard normal distribution
commonly seen in formulas for 95% confidence intervals based on the  sample mean and sample standard
deviation. Although it would be mathematically equivalent to combine the product of Cn,  1.96 and
1.4826 into a single constant, keeping them separate makes evident that interpretation of the constants Cn
in Table 8 as correction factors that: (i) adjust for small sample sizes (in a manner similar to the way that
the ^-distribution critical values adjust for small sample sizes relative to the standard normal critical
values); and (ii) accommodate the fact that limits are constructed using the sample median and sample
MAD (scaled by 1.4826) instead of the sample mean and sample standard deviation as estimators of the
population mean and standard deviation.
                                                                                              15

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
             Table 7.  Constants Cn for Constructing the Robust Confidence Limits.
4 1.6233
5 1.8633
6 1.4433
7 1.5033
8 1.3300
9 1.3500
10 1.2567
11 1.2700
12 1.2100
13 1.2233
14 1.1833
15 1.1833
16 1.1567
20 1.1233
21 1.1233
25 1.1033
26 1.0967
30 1.0833
31 1.0833
40 1.0633
41 1.0633
50 1.0500
51 1.0500
75 1.0300
76 1.0300
100 1.0233
101 1.0233
200 1.0100
201 1.0100

Because the median and scaled MAD values are consistent estimators of the mean and standard deviation
of the normal distribution, the constants Cn are approximately 1 for very large sample sizes. Close
inspection of Table 8 reveals that the constants decrease monotonically to 1 as n increases for all odd
values of n, and for all even values of n, but that the change from neighboring even to odd n is not
decreasing. This phenomenon results from the alternating definition of the median for odd and even
sample sizes and diminishes in magnitude with increasing sample size.
The constants Cn were determined by Monte Carlo simulation so that the limits have the desired coverage
properties when the laboratory means are a random sample from a normal distribution. Specifically, for
each value  of n in Table 8, one million samples of size n were generated from a standard normal
distribution. For each sample, the fractions of the sample values lying between limits of the formM±
1.96 Cn (1.4826) MAD for a dense grid of values Cn were calculated.  These fractions were then averaged
over the one million samples and the value of c was identified that resulted in the average fraction being
closest to 0.95 (and was always within  0.001 of 0.95). The Monte Carlo variation in the reported values
ofCn is less than the number of decimal places displayed.
Although the constants were generated in such a manner that the intervals have a very precise
interpretation for normally distributed data, their robustness (stemming from the use of the median and
MAD) ensures their utility for identifying aberrant values from a set of data more generally then for just
normally distributed data.

Estimates of Variance Components and Standard Deviations
The variance components are estimated using the approach of a standard random effects one-way
ANOVA model in which the laboratories are considered the "treatments."  The notation and formulas that
follow are the same as in the book by Rao (1998; see in particular Section 14.3 and Box 14.2, pp 650-
653).
The "within laboratory" standard deviation is associated with the repeatability of the method and is a
statistical estimate of variability of replicate measurements from the same laboratory based on pooled
information for all laboratories.  Therefore, within-laboratory standard deviation is not specific to any
particular laboratory. The "overall" standard deviation is associated with the reproducibility of the
method and is used to indicate the combined effects of within-laboratory and between-laboratory
variances.
                                                                                              16

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
Preliminary Calculations and Example ANOVA Table
In most cases, t = 10 laboratories and nt =3 or 6 for the participating laboratories and reference laboratory,
respectively. However, these numbers can vary with missing (filtered) data.
Yij = the/th replicate measurement from the rth laboratory, j =l,...,nh i =\,...,t.
Y   =
"*
                    i,
                         Y  =
                         Y   =-
                         "*
                                          r
                                    Y, + = —
                                          77,.
CM =•
              /=1 ;=1   "            ^V                 N

Sums of Squares - Defining Formulas and Calculation Formulas
        SS[TOT] =
                                      \  -CM
                             +)2=  Z

Table 8 shows how the preliminary calculations described above fit into the ANOVA table. The table
proportions the overall or total error into sources of variation and accounts at each level for the degrees of
freedom (df), the sum of square errors and mean square errors.

    Table 8.   Example ANOVA Table
Source of
Variation
Treatments
Error
Total
df
t-1
N-l
N-l
Sum of Squares
SS[T]
SS[E]
SS[TOT]
Mean Squares
MS[T]=SS[T]/4f
MS[E]=SS[E]/4f

F
Fodc = MS[T]/MS[E]

Variance Components and Standard Deviations
The "within laboratory" variance component, vw, is simply the MS[E] term derived in the ANOVA table.
The standard deviation associated with repeatability, sr, is determined as the square root of the within-
laboratory variance component:
The variance component associated with between-laboratory variance is:
          V_MS[T]-MS[E]
                     D
                                                                                           17

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
       where D =
The standard deviation associated with between-laboratory variance, SL, is calculated as the square root of
the between-laboratory variance component:
             )MS[T]-MS[E]
        SL=\        D
In some cases, the between laboratories variance component may be negative and when it is, the variance
value is set to zero. Although there are more complicated ways of dealing with the negative variance
component problem, these approaches are not warranted in this application.
The total or overall variance component is the sum of the within-laboratory and between-laboratory
variance components and the standard deviation associated with the overall variance, SR, is associated
with the method reproducibility:
        SR =
Because the term, SL, includes a divisor normalizing the variance to the average number of observations
per laboratory, the approach is numerically consistent with the approach for calculating repeatability and
reproducibility standard deviations in ASTM E691 Standard Practice for Conducting an Interlaboratory
Study to Determine the Precision of a Test Method (ASTM,  1987).

Repeatability and Reproducibility
The statistic that is associated with the repeatability of a method is the repeatability relative standard
deviation, RSDr, which is calculated as the within-laboratory standard deviation on a percentage basis and
normalized to the overall mean value. The RSDr is numerically equivalent to the within-laboratory
coefficient of variation.

        RSD  =
The statistic that is associated with the reproducibility of a method is the reproducibility relative standard
deviation, RSDR, which is a percentage-based measure of the overall standard deviation to the mean value
and numerically equivalent to the overall coefficient of variation.
Horwitz Ratio (HorRat)
The Horwitz equation is an empirical relationship, based on data from a wide variety of analytical
methods, which indicates how the precision is predicted to change with concentration levels (Horwitz and
Albert, 2006; Mandel, 1991). When applied to the RSDR values, the Horwitz equation takes the form:
                                                                                             18

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


       where  PRSDR is the predicted Horwitz relative standard deviation (%) and
               C is the concentration on a decimal fraction basis (e.g., 1 mg/L = 10~6)
The ratio of the calculated RSDR value to the predicted value (PRSDR) using the Horwitz equation
(Horwitz and Albert, 2006; Mandel, 1991) is the reproducibility Horwitz Ratio (HorRatR).

        TT  „       RSDR
        HorRatD =      R
               R   PRSDR

The Horwitz Ratio is used to account for the natural tendency for analytical replicate standard deviations
to increase as the central concentration value decreases. In analytical chemistry, the HorRat values are
used as a rough estimate of the analytical method precision with HorRatR values between 0.5 and 2.0
typically considered to represent "acceptable" analytical methods (Horwitz and Albert, 2006; Linsinger
and Josephs, 2006). However, in the current method validation study, the observed overall standard
deviation is a combination of the variability imposed by the extraction method (i.e., Method 13 13 or
Method 1316) and the analytical method, as well as the reference material heterogeneity. Thus, the
Horwitz Ratio for reproducibility is used in this report only to assess of whether inherent precision
associated with concentration levels accounts for a majority of the variation in the test results. Thus,
HorRatR values greater than 2.0 do not indicate an unacceptable test method but simply indicate
variability over-and-above that of the analytical method.

Reproducibilitv Limit
The reproducibility limit (K) was used to create an interval of possible results about the mean of the
LEAF method data ( y ) to show the consistency between LEAF methods results and analogous EU
leaching methods.
ISO defines reproducibility limit as "the value less than or equal to which the absolute difference between
two test results obtained under reproducibility conditions may be expected to be within a probability of
95%" (ISO, 1994). The reproducibility limit (R) is derived from the reproducibility standard deviation
according to:
       where  nsthe Student's ^-distribution value required for the \-a level of confidence and the
                   appropriate number of degrees of freedom, and
               SR is the reproducibility standard deviation.

Following the suggestion of Ellison et al. (2009), the value of t was approximated as t=2 to approach the
Student's ^-distribution value limit for a large number of degrees of freedom at the 95% confidence level.
Thus, the R at the 95% confidence limit is calculated as:

        R = 2.8-sR

The reproducibility limit is applicable to data where errors are considered normally distributed and, thus,
the calculation of reproducibility limit was conducted as a Iogi0-tranform.  For each pH target (Method
13 13) or L/S target (Method 1316), the reproducibility limits above and below the mean of the validation
                                                                                              19

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Interlaboratory Validation of LEAF Method 1313 and Method 1316


data (RLupper and RLiower, respectively) were calculated using the validation study mean ( y ) and the
reproducibility standard deviation for the logio-tranformed data (SR:iog):
        RLlower=\og(y)-2.8-S
                               RloB
When compared to the reproducibility limit interval (RL), the results from EU methods that fall within the
reproducibility limit interval about the mean may be considered statistically equivalent to the results of
the LEAF method.
PHASE I LABORATORY FEEDBACK (METHODS 1313 AND 1316)
The objectives of the method validation study Phase I were (i) to allow participating laboratories the
opportunity to demonstrate proficiency in performing Method 1313 and Method 1316 on the EaFA fly
ash material and (ii) to generate feedback from the participating laboratories on the clarity and usability of
the test method and Excel data templates provided for method setup calculations and recording laboratory
data/observations.
Prior to shipment of any samples, participant laboratories were offered the opportunity to participate in a
series of conference call meetings addressing an overview presentation and briefing on the interlaboratory
validation study procedures and details of the test method.8 While not all laboratories participating in all
conference calls, the majority of laboratories participated in at least one conference call. For each
material in each method, a package consisting of a designated quantity of the reference material, material
descriptions and material safety data sheet (MSDS), method validation instructions, and sample tubes and
adhesive labels  for eluate analytical samples and archiving was shipped to each laboratory. Feedback on
the clarity and operability of the test methods was solicited through a request of participating laboratories
to complete an enclosed questionnaire. The primary observations from the information conference call
discussions and questionnaire feedback from the participant laboratories included:
    •   Training - Overviews of the test method procedures,  in the form of a Microsoft PowerPoint®
        presentation delivered during a conference call briefing, proved to be a valued aspect of the study.
        This feedback suggests the future need for some form(s) of training materials (e.g., presentation,
        videos, etc.) to provide an introduction to the methods.
    •   Method Clarity - Several typos and unclear passages  were highlighted. Specific procedural
        clarifications were needed to add tolerances about the contact times for each particle size.
    •   Data Templates - Although the Excel spreadsheets were seen as a useful data management tool,
        several suggestions were received for clarifying the instructions for using each data template.
    •   pH Measurement - More clearly indicating that timely measurement of final eluate pH directly
        after collecting aliquots or after completion of the filtration step was needed.  Initially, some
        laboratories were waiting a prolonged interval (e.g., days) before measuring final pH, which
8 See http: //vanderbilt. edu/leaching for more information on LEAF including test methods, data templates, and data management
approaches.
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


       resulted in an apparent drift in pH in unpreserved samples. A revision to the test method has been
       made to require measurement of final pH within 1 hour of completion of the extraction step.
    •  pH Meter Calibration - In addition to timely pH measurement, an accurately calibrated pH meter
       is crucial. The pH calibration standards used in typical two- or three-point pH meter calibrations
       (e.g., pH values of 4, 7, and 10) do not cover the full pH range required in the test method.  The
       effect of pH measurement inaccuracies is especially evident at extreme values where pH
       measurements may be extrapolated up to 3 pH units beyond common calibration standards.
       Therefore, a wider calibration range is needed with additional pH buffer standards solutions,
       which are available at a variety of pH values between pH 1.68 and 12.45.
    •  Storage of Stock Solutions - Stock solutions of sodium hydroxide or potassium hydroxide should
       not be stored in borosilicate glass containers because of the possibility of solution contamination
       with boron from the leaching of the glass container which can result in interference with data
       interpretation.
As a direct result of these consultations, revisions to the method text and data templates were made
between Phase I and Phase II of the validation study to address typos and suggested clarifications, contact
time interval thresholds, pH measurement timing and calibrations, and compatibility of containers for
stock reagent solutions.  None of these revisions were  considered to have changed the procedure or
affected the results of the validation.  The revised Method 1313 and Method 1316 texts are including as
Appendix A and Appendix B of this report, respectively.


QA/QC SUMMARY
Quality assurance/quality control methodologies in this report include statistical analysis of total contents
replicates, replication and spike recovery analysis during chemical analysis by ICP-OES, method blank
analysis, and general visual data consistency checks. QA/QC ensured that (i) study materials were
adequately homogenized prior to distribution to participating laboratories, (ii) chemical analyses of eluate
samples were of sufficient quality,  (iii) the reported data was not influenced by outside sources of
contamination to a significant degree.

Homogeneity of Study Materials
Homogeneity of collected and processed study material was determined by the RSDs of triplicate total
content analyses following either XRFS or EPA Method 3052/ICP-OES.  The DQI goals for acceptable
homogeneity were that RSD values from XRFS of replicate material subsamples would be less than 10%
for major species, 20% for minor species and 50% for trace species. Table 10 shows the overall mean
RSD and completeness (percentage of measured values complying with the RSD goal) as derived from
XRFS of total content in each of the three study materials.
Both EaFA and SWA meet and exceed the criteria for homogeneity established in the QAPP.  Based
solely on the data shown in Table 10, the 47% RSD for CFS is driven by XRFS analysis of two minor
species - chromium and magnesium - with very large RSD values.  Since magnesium is not used as a
selected analyte, removal of magnesium from the homogeneity assessment results in a mean RSD for
minor analytes in CFS of 25% with a minor analyte completeness of 83% and an overall completeness of
80%. These DQI values for homogeneity were considered close enough to the DQI goals to conclude that
all study materials were homogenous prior to distribution to the participating laboratories.
                                                                                            21

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
     Table 9.   Homogeneity QA/QC for Total Content Derived from XRFS

Analyte Type
Major Species
Minor Species
Trace Species
Total Content
(mg/kg)
> 10,000
< 10,000 to > 1,000
< 1,000
DQIGoal EaFA SWA CFS
for RSD
< 10%
< 20%
< 50%
1.4%
3.9%
23%
1.1%
3.6%
11%
7.4%
47%
34%
Overall Completeness 95% 100% 77%
Analytical OA/OC
DQI goals and overall results for critical measurements are shown in Table 11. The results for precision
were calculated as that overall mean of RSD values for parameters with more than two replicates (i.e.,
ICP-OES and ICP-MS analyses, XRFS, and moisture content).  Completeness was determined as the
percentage of valid measurements meeting DQI goals out of the total number of measurements. The table
shows that the DQI goals established in the QAPP were obtained or exceeded on a global basis in the
validation study except for XRFS analysis as discussed earlier.
For the selected analytes used in the validation study, chemical analysis of eluate solutions was
determined using ICP-OES data; therefore, QA/QC focused primarily on validation of ICP-OES eluate
concentrations. Summary DQI results for ICP-OES analyses for each material by material, analyte and
test are provided in Appendix H while full analytical QA/QC is presented in Appendix I.9
     Table 10. DQI Goals and Overall Results

Measurement
ICP-OES
pH, conductivity
moisture content
XRFS

Method
EPA Method 60 10
Electrode
ASTMD22 16-05
SOP No. 5003.3
Goals
Precision Completeness
±10% >90%
±2% 100%
±10% 100%
±10% 100%
Overall Results
Precision Completeness
2% 99%
2% 100%
0.2% 100%
14% 91%
The breakdown of the DQIs for ICP-OES analysis of eluate solutions by method and material shown in
Table 12 indicates that, although some analytes are more difficult to quantify, data quality is consistently
better than DQI goals for all analytes.  While measurement of some analytes (e.g., antimony, arsenic)
tended toward higher RSDs than that of other analytes (e.g., calcium, barium, boron), the mean RSD for
any and all analytes was less than the DQI goal of 10%.
 Appendix I contains all of the details of the ICP-OES analysis and QA/QC results for each measured constituent in each
provided analytical solution (i.e., filtered and preserved eluate sample). Therefore, due to its size, the appendix is made available
electronically by request to the authors, through the link to the document page on the EPA website, or as a download at
http: //vanderbilt. edu/leaching.
                                                                                               22

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
    Table 11.  DQIs for ICP-OES Analysis Selected Analytes.
Analyte
Antimony
Arsenic
Barium
Boron
Cadmium
Calcium
Chromium
Cobalt
Lead
Molybdenum
Selenium
Vanadium
Mean
RSD
4.2%
3.9%
1.2%
1.4%
1.1%
1.2%
2.6%
2.9%
1.3%
2.6%
2.8%
2.1%
Mean RSD
2.0%
1.7%
0.6%
0.6%
0.4%
0.6%
1.5%
1.4%
0.5%
1.7%
1.6%
1.0%
Completeness
97.4%
97.8%
99.9%
99.9%
99.8%
100.0%
98.5%
99.8%
99.3%
98.7%
98.2%
99.9%
Max Spike
Recovery
118%
120%
120%
118%
118%
117%
117%
118%
112%
119%
120%
118%
Min Spike
Recovery
83%
84%
80%
81%
86%
81%
86%
83%
85%
81%
82%
83%
Materials
EaFA, SWA, CFS
EaFA, SWA, CFS
EaFA, SWA, CFS
EaFA, SWA, CFS
CFS
EaFA, SWA, CFS
EaFA, SWA
EaFA, SWA
CFS
EaFA, SWA, CFS
EaFA, SWA, CFS
EaFA, SWA, CFS
During analysis of eluate solutions, analytical blanks and continuing calibration check standards (-0.5
mg/L) were monitored every 10 to 20 samples.  All calibration checks were within 20% of the specified
value and analytical blanks were measured at less than the ML. Analytical matrix spikes were checked
for three test positions of each set of triplicate eluates with spike recoveries ranging between 80% and
120%. These results are consistent with the goals established in the QAPP and indicate that QA/QC goals
for calibration checks, blanks and analytical spikes were met in all cases.

Method Blank Analysis
The LEAF  test methods specify the procedure for conducting blank extractions (i.e., QAQC extractions
without solid material) in order to assess the importance of potential sources of contamination such as
reagents or equipment surfaces.  During analysis of Phase I eluate concentrations, observable analyte
concentrations were measured in the method blanks  for both Method 1313 and Method 1316.  The
process of determining if these blanks represented a significant impact on the statistical results of this
study is presented in Appendix D.
An algorithm was developed to "filter" the test data  by removing test positions where the associated blank
concentrations were 20% or greater of the eluate concentrations. The algorithm resulted in removal of
less than 20% of the data used in the statistical analysis for each analyte (average 6.9%; standard
deviation of 7.3%).  However, comparison of data spread parameters between filtered and non-filtered
data indicated no overall effect in statistics due to blank analysis data filtering. Therefore, data filtering
based on method blank analysis was not considered  in Phase II of the validation study.

Data Filtering for Cause
While filtering because of high method blank concentration  was not considered to significantly affect the
statistical results, inconsistencies in the comparison  of data were observed which lead to procedural or
other external sources of errors.  For analytes where these error sources were identified (e.g., high sulfur
in L04 samples for the EaFA material for Method 1313 resulting in low barium eluate concentrations due
to precipitation of BaSO4), eluates were "filtered for cause"  as shown in Table 13. The primary sources
of filtering  for cause is improper pH measurement due potentially to calibration to a narrower set of
buffer solutions than the pH range to be analyzed. In all, filtering for cause represented removal of less
than 20% of the data for any analyte in any data set.
                                                                                              23

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
    Table 12.   Overview of Eluates Filtered for Cause
     ethod 1313
   EaFA
A,B, C
A,B, C
                                   High sulfur precipitates BaSO4
                                   NaOH stored in borosilicate glass
Barium
Boron
                                        A,B, C
                                        A,B, C
                      Inconsistent pH measurement
                      Inconsistent pH measurement
T01-T09
T01-T09
                                                               No filtering for cause required
EaFA


SWA
CFS
LOS
L10
Lll
LOS
-
T01-T05 A, B, C All | Inconsistent pH measurement
T01-T05
T01-T05
T01-T05
-
A
A,B, C
A,B, C
-
All
All
All
-
Inconsistent pH measurement
Inconsistent pH measurement
L/S offset due to moisture content
No filtering for cause required
ANALYTE SELECTION AND DATA TRANSFORMS
A screening evaluation of the reference laboratory Method 1313 and Method 1316 data for each of the
three study materials is presented in Table 14. Check marks in the table indicate analytes for reference
laboratory Method 1313 results with no more than 3 test positions below the MDL value or Method 1316
results with no more than 1 test position below the MDL value.  Selected analytes are indicated by yellow
highlighting. Toxicity characteristic (TC) priority metals based on the RCRA program are shown in red.
Based on the ICP-OES results of the reference laboratory concentrations, a set of 10 analytes for each
material was selected for statistical evaluation.
The selection of analytes for statistical analysis considered: (i) relevance to potential risks to human
health and the environment (e.g., TC metals), (ii) representativeness of the range of characteristic pH-
dependent leaching behaviors as a function of pH, and (iii) concentrations at sufficient level to allow a
single undiluted ICP-OES analysis.  Priority was given to analytes present in all three materials so that
comparisons across material types could be made.
                                                                                             24

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Interlaboratory Validation of LEAF Method 1313 and Method 1316
    Table 13. Candidate ICP-OES Analytes and Selected Analytes for Statistical Analysis.
Analyte Symbol
Aluminum Al
Antimony Sb
Arsenic As
Barium Ba
Beryllium Be
Boron B
Cadmium Cd
Calcium Ca
Chromium Cr
Cobalt Co
Copper Cu
Iron Fe
Lead Pb
Lithium Li
Magnesium Mg
Manganese Mn
Molybdenum Mo
Nickel Ni
Phosphorus P
Potassium K
Selenium Se
Silicon Si
Sodium Na
Strontium Sr
Sulfur S
Thallium Tl
Titanium Ti
Vanadium V
Zinc Zn
Total Selected Analytes
M1313 M1313 M1313
EaFA SWA CFS
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316


METHOD 1313 RESULTS AND ANALYSIS

Acid/base Neutralization Capacity (Titration Curve)
One of the outcomes of performing Method 1313 on a material is that the neutralization capacity of the
material is determined by the amount of acid or base added to each extraction and the resultant eluate pH
response.  Figure 1 shows the acid neutralization capacity (ANC) and base neutralization capacity (BNC)
of each of the study materials as a function of the eluate pH for the collected Method 1313 data from the
participating and reference laboratories.
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Figure 1. Acid/base neutralization capacity for Method 1313 study materials.
Note: Data shown for (A) EaFA coal combustion fly ash, (B) SWA solidified waste analog, and (C) CFS contaminated field soil.
Addition of base is indicated by negative values on the y-axis.


Also shown in the figure are color-coded, large open circles which denote the natural pH measurement at
an ANC/BNC equal to 0 mol/kg. ANC indicates the amount of buffer capacity that the material has with
regard to acid addition; conversely the base neutralization capacity BNC is a measure  of the buffering
capacity of the material to base addition. Typically, ANC is reported in moles of acid per kg of material
and BNC is expressed as a negative ANC on a continuum scale.
                                                                                              26
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316


Of the three study materials, the SWA material (Figure IB) is the most alkaline with a natural pH
between pH 12 and 13) whereas both EaFA (Figure 1A) and CFS (Figure 1C) are much less alkaline with
natural pH values between 6.5 and 8. Due to the alkalinity of the SWA material, the amount of acid
required to decrease the final eluate pH of SWA to the lowest target pH of 2.0 was approximately 20
mol/kg. This value is significantly higher than the amounts of acid required to titrate CFS or EaFA to a
target pH of 2.0, respectively, 2 mol/kg and 1 mol/kg.

Statistical Analysis of pH-dependent Leaching
For Phase II of the Method  1313 validation study, the experimental results of Phase I were combined with
those results from conducting Method 1313 on two additional materials,  SWA solidified waste analog and
CFS contaminated field soil, to generate statistics related to method repeatability and reproducibility. The
results of statistical analysis for three study materials tested using Method 1313 (i.e., EaFA coal
combustion fly ash, SWA solidified waste analog, and CFS contaminated field soil) are presented as six-
panel figures in Appendix E. Each figure shows the results of statistical  analysis for a single selected
analyte in each material (e.g., calcium in EaFA, boron in SWA). In the discussion below, selected panels
from these figures are used to illustrate the key observations of the method validation.
Antimony in EaFA study material is presented in Figure 2 for illustrative purposes. The panels in the
figure include:
    Panel  A - Collected data from participating laboratories that have been "filtered for cause" according
             to the blank analysis and filtration rules presented in Appendix D. Open circles around
             certain data points indicate the natural pH for each test replicate.
    Panel  B - Comparison of reference laboratory mean (green dots) and 95% prediction limit (PL; green
             dashed lines) to median of all laboratory means (red squares) and 95% robust confidence
             limit (RCL; red solid lines).  The 95% prediction limits provide the bounds within which
             95% of additional test replicates conducted by the reference laboratory would fall.  The
             95% confidence interval represents that bounds within which the mean concentration value
             from 95% of laboratories would fall.
    Panel  C - Overlay of the RCLs from Panel B against the interpolated/extrapolated data.
    Panel  D - Overall data mean (red dots) with standard deviations intervals about the mean associated
             with "within-laboratory" variance (green short-dashed line), "between-laboratory" variance
             (blue long-dashed line), and overall variance (gold solid line).
    Panel  E - The coefficient of variation corresponding to the "within-laboratory" (green short-dashed
             line), "between-laboratory" (blue long-dashed line) and "overall" (gold solid line) standard
             deviations as a percentage of the mean analyte concentration.
The  sixth panel of each figure is a legend indicating color-coding by participating laboratory and shape-
coding for test replicates applied to the collected (Panel A) and interpolated/extrapolated data (Panel C).
                                                                                              27
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
                                                               0.1  -:
                                                          o
                                                          I
                0.01 -:MDL
                                                             0.001
                                                                                         O  RefMean
                                                                                        	Ref95%PL
                                                                                         •  Median of Lab Means
                                                                                        	95% RCL
                                                                                                10
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                                                       12
                                                        (B)
                                                                                   Target pH
      0.001
                                        10
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                                                    14
 (D)
                            Target pH
          (E)
4     6     8     10
     Target pH
12
                                                                                                           14
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• EaFA-L02-A
• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
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A EaFA-LlO-B
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• EaFa-L09-C
n EaFA-LlO-C
• EaFA-Lll-C
• EaFA-Ref-C
n EaFA-Ref-F
                                                                                                           14
Figure 2. Antimony statistical analysis for Method 1313 Phase I material EaFA.
Note: Data shown for (A) collected data as a function of pH; (B) reference laboratory mean and 95% prediction limits (PL; green,
dashed line) compared to the median of laboratory means and median-based 95% robust confidence limits (RCL; red line); (C)
95% RCL intervals (red lines) shown with respect to interpolated laboratory data; (D) intervals for "overall" (gold line),
"between laboratory" (blue, dashed line) and pooled "within laboratory" (green, dotted line) standard deviation about the mean of
all data; (E) coefficient of variation for upper values of "overall", "between laboratory" and "within laboratory" standard
deviation compared to 5% marker indicating a generalized analytical uncertainty.
                                                                                                              28
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


Interpolation/Extrapolation of Log ia-transfarmed Data
Linear interpolation and extrapolation was chosen for its simplicity and ability to be understood easily
and replicated. However, the method may contribute to the variability of some analytes in a narrow pH
domain where the concentration curve varies over an order of magnitude or more as a function of eluate
pH. Comparison of the data shown in Figure 3 illustrates the effect of interpolation and extrapolation on
organizing the data for statistical analysis.
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Figure 3.  Comparison of Method 1313 collected data (left) and interpolated data (right).
Note: Data shown for (A) Sb in SWA material showing no significant change to variability, (B) Mo in CFS material showing
minor degree of induced variability, and (C) Cr in EaFA showing significant variability as a creation of points in data "trough".
Large red circles highlight examples of significant variability due to the interpretation approach.
                                                                                                   29
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316


Since Method 1313 does not call for automatic pH-control but specifies an allowable pH-tolerance about
a target pH, the collected data (Figure 3A) vary with both pH and concentration.  Interpolation and
extrapolation of results to the target values allowed for statistical analysis at common points in the
response curve of concentration as a function of pH and for comparison of different data sets at common
pH values.
How variability is introduced through the interpolation/extrapolation process can be illustrated using the
Method 1313 aluminum data from the SWA material.  In Figure 4, eluate aluminum concentrations
collected from the participating laboratories are plotted as greyed open dots along with a solid grey line
indicating a visual "best fit" line of the collected  data.  Although not correlated to any particular
mathematical function, the best fit line represents the general function of concentration versus pH to be
referred to as "the function line".  The blue and green lines in the figure indicate potential pairings of data
which might represent candidate pairs for interpolation.
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scatter when interpolating along steep slopes.

The curvature of the function line related to the blue linear interpolation data set is shallow and the points
interpolated to target pH values of 2.0 and 4.0 (blue triangles) display consistency with the clusters of
collected data (grey open dots). However, interpolation along the green line where the curvature of the
function line is steep can result in interpolated points that induce scatter in the data set. Two cases are
shown in the example.
    •   The additional scatter from interpolation may be consistent with the variability of the collected
        data (see interpolated data point for target pH 5.5).  This is likely to occur when the curvature of
        the function line is steep and small experimental errors in pH measurement can result in
        significant variation in collected concentration data.
    •   The introduced scatter due to interpolation may provide variability not provided by the collected
        data (e.g., at target pH 4.0).
Ideally,  interpolation along the overall function line, as opposed to linearly between data points, would
not induce such variability. However, interpolation along the function line would require extensive
knowledge of the function line for each test replicate and, therefore, is not practical for this study. Thus,
                                                                                                30
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


linear interpolation and extrapolation was chosen for its simplicity and transparency despite the potential
to scatter data when interpolation is conducted along steeply curved function lines.

Prediction Limit and Robust Confidence Limits
A selection of mean-based prediction limits for the reference laboratory data and median-based robust
confidence limits for all data are shown in Figure 5 for various study materials.  These graphs cover a
broad spectrum of the statistical results. The full set of graphs is included in Appendix E.
The 95% prediction limits (PL; green dashed line) define a band of data about the reference laboratory
mean (green dot) that delineates a repeatability operating characteristic for the reference laboratory in the
sense that one would expect 95% of all replicate measurements made by the reference laboratory to lie
within these bounds. However, this does not mean that an entire test replicate data set would fall within
the bounds of the prediction limits for each of the nine target pH values since the parallel extractions in
Method 1313 are independent.  The 95% robust confidence limits (RCL; red solid lines) were calculated
by merging all laboratory data, calculating the median of the laboratory means and setting the 95%
confidence interval about that median.
The width of the robust confidence limits, or the  interval between the upper and lower RCL plotted at a
target pH, was approximately a factor of 2 in the pH domains of good repeatability for all analytes.
Greater width was observed for the RCL when (i) the analyte concentration as a function of pH was at a
local minimum (e.g., between pH 5.5 and 7.0 for As), and (ii) when the slope of the change in
logio(concentration) as a function of pH was greater than 5 (e.g., at pH < 4.0 and > 12.0 for As). The
width for the PL generally was either similar to or smaller for the PL as compared to the width of the
RCL for all elements.
In general, there was good agreement between the PL and the RCL which indicates that the reference
laboratory data are consistent with the data set as a whole.  Figure  5 shows that the PL intervals for
calcium in EaFA (Figure 5A left) and arsenic in CFS (Figure 5A right) fall directly within the RCL
intervals and do not extend past the bounds of the RCL. Less agreement was seen for other species
(Figure 5B and C) and associated with measured values near or less than the MDL.
                                                                                              31
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
     1000
     100 -
•S   10 •
             EaFA Ref Mean
             EaFA Ref 95% PL
             EaFA Median of Lab Means
             EaFA 95% RCL
                                                                                  O  CFS Ref Mean
                                                                                	CFS Ref 95% PL
                                                                                  •  CFS Median of Lab Means
                                                                                	CFS95%RCL
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 (A)
                         Target pH
                                                   (A)
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     100 -r
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                                                                           O  EaFA Ref Mean
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                                                                          	EaFA95%RCL
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        100
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                                                                                  SWA Median of Lab Means
                                                                                  SWA 95% RCL
0.001 -r
 (C)
                          Target pH
                                                   (C)
                                                                            Target pH
Figure 5. Agreement between 95% prediction limits (95% PL) about the mean of the reference laboratory
data and 95% robust confidence limits (95% RCL) based on the median of laboratory means.
Note: Data shown for (A) high level agreement, (B) median level agreement, and (C) lowest level of agreement.


Some of the variability seen between PL and RCL data is introduced through the linear
interpolation/extrapolation process.  The propagation of variability due to interpolation of collected data is
clearly shown when looking at Method 1313 data for arsenic in SWA (Figure 6).  In the pH range
                                                                                                        32
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316


between 9 and 12, the collected participating laboratory data for arsenic follows a well-defined "U-
shaped" function line (yellow dashed line in Figure 6A).  Because interpolation is conducted linearly
between target pH values (e.g., 9, 10.5 and 12), the resulting interpolated concentrations (Figure 6B)
spread significantly at pH targets of 10.5 and 12. The data for the reference laboratory are pushed into the
"bowl" of the U-shaped trend at pH 10.5 such that the mean of the reference laboratory data is noticeably
higher than the median of laboratory means for the data set  as whole (see Figure 6C). In addition, the
considerable spread in the interpolated data (Figure 6B) at pH 12 is caused by the interpolation to a nearly
vertical function line.  This spread in the interpolated data results in a broader than expected range of
concentrations and a wider than  expected 95% robust confidence interval at pH 12.
 (A)
                                                        100
                                                     Ul
                                                     I
                                                     <
                                                         10 -•
                                                          1 -r
                                                         0.1 -r
     0.01
      100
                                                        0.01
                                            (B)
   Ol
  o
   O
  'E
       10 -•
1 -i
      0.1 -r
     0.01
             O  RefMean
            	Ref95%PL
             •  Median of Lab Means
            	95%RCL
                    =1=
                               =1=
 (C)
                    468
                         Target pH
                             10
12
                                        14
                                                                                       10
                                                                                            12
                                                                                                  14
                                                                           Target pH
• SWA-L01-A
• SWA-L02-A
• SWA-L04-A
• SWA-L05-A
0 SWA-L06-A
• SWA-L07-A
• SWA-L09-A
0 SWA-L10-A
• SWA-L11-A
• SWA-Ref-A
• SWA-Ref-D
A SWA-L01-B
A SWA-L02-B
A SWA-L04-B
A SWA-L05-B
A SWA-L06-B
A SWA-L07-B
A SWA-L09-B
A SWA-L10-B
A SWA-L11-B
A SWA-Ref-B
A SWA-Ref-E
• SWA-L01-C
• SWA-L02-C
• SWA-L04-C
• SWA-L05-C
D SWA-L06-C
n SWA-L07-C
• SWA-L09-C
D SWA-L10-C
• SWA-L11-C
• SWA-Ref-C
n SWA-Ref-F
Figure 6.  Propagation of variability due to linear interpolation of arsenic concentrations in Method 1313
samples of SWA.
Note: Data shown for (A) collected data showing "tight" function line (yellow dashed line) along a U-shaped trough in the LSP
curve, (B) interpolated data with missing trough due to linear interpolation of reference laboratory data, and (C) in consistency of
95% prediction limits based on reference laboratory data to 95% RCL of all data. Large red circles highlight examples of
significant variability due to the interpretation approach.


While the linearly interpolating/extrapolating data to target values does appear to induce variability in the
data set, the effect is limited to those narrow portions of the pH-dependence release curve with steep
slopes.  Thus, species with Method 1313 results that are not a strong function of pH (e.g., boron, calcium)
and portions of the pH-dependence curves that are relatively insensitive to pH are not affected to a
                                                                                                    33
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316


significant degree. In addition, steep portions of the pH-dependence curve tend to occur at the extremes
of the pH range (e.g., pH 2 and 13) where the pH regime does not represent the majority of environmental
conditions.
Visual comparison of collected and interpolated data for the selected ten analytes and the three test
materials revealed that only nine target pH values between pH 4 and 12 show obvious increased
variability due to interpolation. This represents 4% of the 210 potential pH target values between pH 4
and 12 (i.e., seven target values from ten selected analytes in three study materials).  The minimum and
maximum data points collected for each target pH value and study material were 27 and 36, respectively10
and only a few of these data points at any target pH were affected. All of the affected target pH values
represent minima of the pH-dependence curve which tends toward higher interpolated values (e.g., Figure
5) and a conservative estimate of release (i.e., over-predicts leaching). None of the suspect target values
occur at maxima on the pH dependence curve. Therefore, while the introduction of variability caused by
the linear interpolation/extrapolation of logio transformed data represents an interesting phenomenon of
the method validation approach, the variability has little bearing on the precision of the  method and is
unlikely to significantly influence environmental decisions that are made based on interpolated data.

Standard Deviations and Coefficients of Variation
The standard deviation intervals about the overall data mean indicate the variance in data associated with
(i) within-laboratory statistics associated with repeatability, (ii) between-laboratory statistics, and (iii)
with overall method performance associated with method reproducibility. When compared to the overall
coefficient of variation, the coefficients of variation for the between-laboratory and within-laboratory
standard deviation provide a sense of whether the  overall variability (reproducibility) can be attributed to
within-laboratory (repeatability) or between laboratory variation components. Figure 7 shows standard
deviation above and below the mean value and coefficients of variation for selected analytes in three
study materials.
The within-laboratory standard deviations (repeatability) are generally less than the standard deviations
associated with between-laboratory or overall (reproducibility) standard deviations.  The overall
coefficients of variation range  from approximately 5% to over 100% and, to a large extent, are dependent
on the slope of the pH-dependence curve. The coefficient of variation for between-laboratory standard
deviation is generally higher than the coefficient of variation for within-laboratory standard deviation. Of
the data shown in Figure 7, the coefficients of variation for within-laboratory standard deviation tend to
be relatively consistent with analytical uncertainty (~5% RSD) for calcium in the EaFA and for cadmium
in CFS and molybdenum in SWA where the pH-dependence curve is relatively flat.  Coefficients of
variation increase where the slope of the pH-dependence curve is steep (see Figure 7B at pH 8), when the
extract concentration is near or less than the MDL (see Figure 6B  at pH 10-12) or when operational
difficulties, such as gel formation in SWA at pH < 4, increased analytical sample heterogeneity (see
Figure 7C).
10 The number of data points collected for each pH target included data from six test replicates conducted by the reference
laboratory plus triplicate analysis conducted by the participating laboratories (e.g., the minimum value of 27 considers 21 data
points from triplicate test runs of the seven participating laboratories plus six test replicates from the reference laboratory).
                                                                                                34
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
Calcium (mg/L)
i-
1-' C
I-* O C
o o c

<
B-z»*»
>-- •=

— .

• EaFA Mean
— EaFA Overall SD
	 EaFA Between Lab SD
	 EaFA Within Lab SD

"*"^'

N

S

                                    10
                                         12
                                               14
 (A)
      100 -i-
       10 -•
  E
  I   o.i
  •o
  ID
     0.01 -r
                        Target pH
                 \
 CFS Mean
 CFS Overall SD
-CFS Between LabSD
-CFS Within Lab SD
     M_L_

     MDL
    0.001
                                    10
                                         '''
/
•»' ICP-C

J
'/

ESRSD
8 10 12 1
Target pH
CFS Overall CV
	

CFS Between Lab CV
CFS Within Lab CV








-r«**



^ 4

•'



ft

/

f /

	
D 2 4 6
V
\
***-'"





*y^—

ICP-O

/

ESRSD
8 10 12 V
Target pH
   E
   i
  s
  f
       0.1 -:
0.01 •;
     0.001
                SWA Mean
                SWA Overail SD
               -SWA Between Lab SD
               -SWA Within Lab SD
                                            MDL




E
3
C
01
E

o 10
1 .













,
^->i
>
V
\


_ICP_£ES RSp_ _








Nv^-*'^rfr
^.n " " i^*
,*" **


	




	 SWA Between Lab CV











^^
^

%*%
	



=*——««*—

'r-'^''.-

                                    10
                                         12
                                              14
 (C)
                         Target pH
                                            (C)
                                                                     6    8
                                                                    Target pH
                                                                                      10
                                                                                           12
                                                                                                14
Figure 7.  Example standard deviation intervals about the mean and coefficients of variation for Method 1313
materials.
Method 1313 Repeatability andReproducibility
Using the above mean-based statistics, comparisons of repeatability and reproducibility statistics among
the three study materials (i.e., EaFA, SWA, and CFS) are presented for antimony in Figure 8 and
molybdenum in Figure 9.  Figures for the remaining analytes are presented in Appendix E. In each
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316

figure, the mean, and the overall standard deviation interval about that mean, show the various levels and
forms of the pH-dependent behavior over a broad pH range (Panel A). Both the repeatability relative
standard deviation (RSDr), which is the within-laboratory coefficient of variation, (Panel B) and the
reproducibility relative standard deviation (RSDR) which is the overall coefficient of variation (Panel C)
are plotted as a function of target pH. The Horwitz Ratio for reproducibility relative standard deviation
(HorRatR) is plotted in Panel D for each material as a function of target pH.
     0.001
 (A)
                         Target pH
(B)
                       Target pH
    1000
  & 100 -
   o

  1
   a  10 -
  .Q
  V)

	
CFS RSD-R
EaFARSD-R
SWA RSD-R
         •  ICP-OESRSD
                                   10
                                         12
                                              14
 (C)
                        Target pH
(D)
                       Target pH
Figure 8. Method 1313 repeatability and reproducibility of antimony.
Note: Date shown for (A) overall standard deviation intervals about the mean, (B) repeatability relative standard deviation
(RSRr), (C) reproducibility relative standard deviation (RSDR), (D) Horwitz ratio. Grey dashed line in panels (B) and (C)
indicate 20% and 50% reference lines for repeatability and reproducibility.

The repeatability of Method  1313 for antimony (Figure 8B) is approximately 10-20% for the majority of
the pH range with an increase to 20-100% at low pH for SWA and CFS. Method reproducibility (Figure
8C) shows a similar pattern with reproducibility of 20-50% with SWA reproducibility increasing to about
500% at pH 2.  In the case of SWA,  several participating laboratories mentioned the formation of a gel-
like eluate  at pH values less than 4.  This gel presented difficulties for the participating laboratories during
filtration and for the analytical laboratory during analysis.  Thus, larger standard deviations could be
expected where the gel was observed.
                                                                                                  36
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316


In Figure 9, the repeatability and reproducibility of Method 1313 were consistent with the observations
for antimony. Method repeatability (Figure 9B) ranged from approximately 5% in the alkaline range,
where Mo solubility as a function of pH is relatively flat (Figure 9A), to 20-50% in the acidic range.
Reproducibility values (Figure 9C) were between 20 and 50% over the pH range with values in excess of
100% for SWA gel formation (i.e., at low pH) or when the slope of the pH-dependent function line was
steep (i.e., CFS pH 8-9).
  ~0
       0.1 -r
 (A)
0.01 -r
     0.001
    1000
                        Target pH
                                            (B)
                                                               4     6    8    10
                                                                   Target pH
  S 100  -
  o
  •c
      10  -
  O
 (C)
	 EaFA RSD-R
	 SWA RSD-R

	

; ICP-OE
X
^^

SRSD

^£?



— •* •»/
C7*



A
X
>,
X
"^





^..
— — .

•- —

D 2 4 6 8 10 12 1
Target pH
                                            (D)
                                                                    4     6    8    10
                                                                         Target pH
                                                                                          12
                                                                                               14
Figure 9. Method 1313 repeatability and reproducibility of molybdenum.
Note: Data shown for (A) overall standard deviation intervals about the mean, (B) repeatability relative standard deviation
(RSDr), (C) reproducibility relative standard deviation (RSDR), (D) Horwitz ratio. Grey dashed line in panels (B) and (C)
indicate 20% and 50% reference lines for repeatability and reproducibility.
Calculation of Horwitz ratios showed that the HorRatR values tend to be less than or approximately 2 for
most target pH values and for all analytes.  Higher values of HorRatR can be explained for most cases, by
sample heterogeneities, sample preparation, and gel formation in SWA at low pH, or sections of the pH-
dependent release curve with steep curvature (i.e., high potential for variability introduced through the
interpolation/extrapolation process).
Method precision for Method 1313 is shown in terms of relative standard deviations for repeatability
(Table 15) and reproducibility (Table 16).  For each analyte and pH target, the RSDr or RSDR represents
                                                                                                 37
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
the method precision calculated from the validation data.  The precision data in these summary tables
should not be taken out of context of the LSP trendlines, but should be compared to the pH-dependent
LSP curve data in order to relate method precision for a particular analyte in a study material estimated at
a target pH to the features of the LSP curve. As an example, the comparison between RSDR data for
chromium leaching in EaFA (Table 16) and the interpolated EaFA data for chromium (Figure 10A) shows
that RSDR values pass through a maximum of 205% as trend in the LSP passes through a minimum and
approaches the ML and MDL values. However, for antimony in SWA (Figure 10B), the high variability
in results is obvious for the pH target of 2.0 where gel formation presented difficulties in filtration.
Caution should be exercised when attempting to extend the method precision data presented in Table  15
and Table 16 to other matrices due the association between estimated method precision values and the
shape/slope of the LSP curve.
m .
:?
"Si i -
o
En 1
3
u
.UU1 •
n nnm .

. 	 I

I 	


3
I
(
	


I
' 9
-f
8

n c
I
n


IB
I
)



1 f

	


^a

__ML_
MDL

 EaFA
468
    Target pH
                                  10
12
                                            14
Antimony (mg/L)
S P ~ E
-•• !-•• !-•• O C

• i
I

8
, 1



li




II




iM
ML
MDL

0 2 4 6 8 10 12 1
\A/A Target pH
Figure 10. Interpolated data for Method 1313 for chromium in EaFA (left) and antimony in SWA (right).

Examination of the Method 1313 data has shown that high RSDR value may result from (a) concentration
data near or below the quantitation limit, (b) LSP for an analyte that are a strong function of pH, hence,
small deviations in pH measurement can result in large variation in concentrations, (c) significant
curvature in the LSP trendline, for which linear interpolation of log 10 transformed data may increase
variability, and (d)  sample heterogeneity induced by either material preparation or gel formation in the
SWA extract. For each of the reproducibility RSDR in Table 16 greater than 50%, superscripts are used to
indicate these primary functional explanations associated with these precision values.
In summary, the median RSDr for Method 1313 shown in Table 15 ranges from 3% for calcium in CFS to
66% for chromium in SWA.  The median RSDR presented in Table 16 was slightly higher than the RSDr
ranging from 6% for boron in EaFA to 144% for chromium in SWA. The overall method precision for
Method 1313, taken across all validation data (i.e., all pH targets, all analytes and all materials), was
determined to be 13% RSDr and 28% RSDR.
                                                                                            38
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
Table 14. Method 1313 Repeatability (RSDr) across Study Materials
                                                                     RSDr (%) at Target pH Value
EaFA - Coal Combustion Fly Ash
Analvte
Symbol
Analvte
 Symbol       2.0
Analvte
 Symbol       2.0
13.0        Med
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
29
11
7
3
4
7
5
7
10
12
67
11
8
3
2
34
3
6
21
17
17
14
4
4
4
lOS3-"
11
22
13
10
14
15
4
6
5
89"'c
29
26
16
11
12
18
8
9
9
31
50
12
15
15
11
14
9
3
3
13
38
3
7
11
10
12
21
3
4
10
16
4
4
12
12
9
12
4
10
9
1
4
4
7
11
15
41
5
17
11
NA
4
4
7
SWA - Solidified Waste Analog
13.0        Med
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
129d
59^
65d
28
46
67d
38
106^
41
94",d
26
20
10
6
7
29
10
23
7
29
14
35
11
8
12
74"
16
32
9
10
13
19
7
10
5
99a,c
57
36
5
5
13
20
7
9
8
76a,c
41
15
6
6
8
31
8
7
18
66a'c
37
11
10
10
20
22
11
9
28
53a'b
16
6
5
8
32
34
14
16
36
42
7
5
5
14
2
2
1C
1
6
5
1

1
1
CFS - Contaminated Field Soil
                                                                                                                           18
                                                                                                                           59°
                                                                                                                           10
                                                                                                                           17
Antimony Sb
Arsenic As
Barium Ba
Boron B
Cadmium Cd
Calcium Ca
Lead Pb
Molybdenum Mo
Selenium Se
Vanadium V
8
8
15
6
4
5
6
22
9
8
13
24
13
4
6
4
5
43
6
12
23
29
9
8
18
4
12
22
12
4
18
19
7
7
28
3
17
17
14
4
16
25
6
8
55"
2
26
27
14
3
17
16
4
7
35
2
15
21
9
3
14
9
13
5
51a
3
45
7
9
3
18
12
27
11
49
3
32
4
12
5
43
29
IDS3-"
12
108a
8
152C
15
20
7
13.0        Med
 Notes:  NA = method precision not available (all concentrations set to 1A MDL)
        Superscripts indicate functional explanations for repeatability greater than 50% RSDr:
             a = concentration approaching or below ML                c = significant curvature in LSP trendline (e.g., approaching local minima or maxima)
             b = LSP is strong function of pH at target pH               d = sample heterogeneity due to gel formation in SWA extracts
                                                                                                                                                 39
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
Table 15.  Method 1313 Reproducibility
                                                   across Study Materials
                                                                     RSDR (%) at Target pH Value
EaFA - Coal Combustion Fly Ash
Analyte
              Symbol       2.0
13.0        Med
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
38
64b
9
6
8
14
7
32
52b
27
6T'b
37
20
5
32
57a,c
14
6
27 27
50a'c 41
11 11
6 9
4 5 6 10
100b 205"-° 155b'c 100b'c
8
16
43
32
15
44
32
26
85b 159a'b
32 14
35 32
40 43
30
40
21
5
6
41
51a
9
21
47
25 18 2
28 43 4
28 23 6
7 13 2
9 18 3
28 22 2
24 1 N,
8 7
8 7
40 15 1
SWA - Solidified Waste Analog
Analyte
              Symbol       2.0
13.0        Med
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
508d
75b'd
91d
66d
61d
89d
58d
148^
77d
175"'d
74d
58b,d
20
26
23
70d
26
68d
25
53c'd
43
59"
26
25
28
277"
43
42
27
37
40
41
17
16
23
198"-°
82"
58"'c
19
27
35
47
16
14
25
144a'c
68a'b
41
18
25
31
62C
21
9
29
108a'c
50a
28
19
26
42
124C
38
18
94C
149^
59a
20
20
42
73
122"
51C
110C
115"
227b
8
19
19
47
49
51
136
54
133
102
19
23
22
26
CFS - Contaminated Field Soil
                                                                                                                          13.0        Med
Antimony Sb
Arsenic As
Barium Ba
Boron B
Cadmium Cd
Calcium Ca
Lead Pb
Molybdenum Mo
Selenium Se
Vanadium V
17 19 43
71b 26 37
136a'c 19 26
7 12
11 15
7
16
47
30
14
7
9
25
7
23
31
26
9
63b'c
33
37
20
21
24
14
10 14
233b 132a'b
556
10 19 42 112C 53C
47 35 24 110b'c 114b
11
27
17
20
16
21
19 19
20
19
18 47 74a
25 30 85b
22 35 2803'
9 15 24
68a 114a 158a
6 7 51C
80C 50 350C
30 15 26
28 21 46
25 28 54
 Notes:  NA = method precision not available (all concentrations set to 1A MDL)
        Superscripts indicate functional explanations for reproducibility greater than 50% RSDR:
             a = concentration approaching or below ML                c = significant curvature in LSP trendline (e.g., approaching local minima or maxima)
             b = LSP is strong function of pH at target pH               d = sample heterogeneity due to gel formation in SWA extracts
                                                                                                                                                40
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
METHOD 1316 RESULTS AND ANALYSIS
The Method 1316 results for testing the EaFA fly ash material in Phase I were combined with the results
for SWA solidified waste analog and CFS contaminated field soil testing in Phase II.

pH Response as a Function of L/S
The results of Method 1316 include the natural pH response as a function of L/S as shown in Figure 11
for each of the three study materials. For EaFA (Figure 11A) and CFS (Figure 11C) the natural pH is not
a strong function of L/S ratio and ranges between 6.5 and 8.0.  The natural pH of SWA (Figure 1 IB),
however, increases from approximately 12.7 to nearly 13 as L/S ratios decrease from 10 to  1 mL/g. In
addition, the alkaline nature of SWA is evident from the high pH values at natural pH.
  I
     7 -•
 I
                                                 W
       0.1
                                           •4
                                            10
 (A)
                      L/S (L/kg)
(B)
  a.  8 -•
  IB
  0
     7 -•
      0.1
                                            10
 (C)
                      L/S (L/kg)
                                                      14
                                                      13 -•
      11
                                                       0.1
                      L/S (L/kg)
• L01-A
• L02-A
• L04-A
• L05-A
• L06-A
• L07-A
• L08-A
• L09-A
• L10-A
• Lll-A
• Ref-A
• Ref-D
A L01-B
A L02-B
A L04-B
A L05-B
A L06-B
A L07-B
A L08-B
A L09-B
A L10-B
A Lll-B
A Ref-B
A Ref-E
• L01-C
• L02-C
• L04-C
• L05-C
n L06-C
n L07-C
• L08-C
• L09-C
n L10-C
• Lll-C
• Ref-C
D Ref-F
                                                                                           10
Figure 11. Eluate pH for Method 1316 Study Materials.
Note: (A) EaFA coal combustion fly ash, (B) SWA solidified waste analog, and (C) CFS contaminated field soil.
                                                                                              41
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
Statistical Analysis of L/S-dependent Leaching Data
The results of statistical analysis for three study materials tested using Method 1316 (i.e., EaFA coal
combustion fly ash, SWA solidified waste analog, and CFS contaminated field soil) are presented as six-
panel figures in Appendix F. Each figure shows the results of statistical analysis for a single selected
analyte in each material (e.g., calcium in EaFA, boron in SWA). In the discussion below, selected panels
from these figures will be used to generalize the overall results of the method validation.

Interpolation/Extrapolation ofLogig-transformed Data
Method 1316 data are reported at the target L/S and, therefore, no data interpolation to the target L/S
value was necessary. However, in order to avoid extrapolation of data to a target L/S of 0.5 mL/g when
no data at that target value were reported, extrapolation in the LeachXS statistics module was restricted to
data values within 10% of the target L/S.

Prediction Limit and Robust Confidence Limit -based Statistical Analysis
A selection of mean-based prediction limits for the reference laboratory data and median-based robust
confidence limits for all data is shown in Figure 12 for various study materials.  These graphs cover a
broad spectrum of the statistical results.
For most of the analytes in Method 1316 validation, the 95% PL (green dashed lines) fall within the
bounds of the 95% RCL intervals (red solid lines) and the mean of the reference laboratory data (green
dots) corresponds well with the median of the laboratory means (red squares). In this context, these
observations show that there is good agreement between reference laboratory data and the data set as a
whole. In Figure 12, the panels in rows A and B show agreement at a high level and average level,
respectively.  Such consistency was observed for nearly all CFS and most EaFA analytes. Panels in row
C indicate that, in some cases, the 95% PL limit was greater than the 95% RCL although the agreement
between reference laboratory mean and the data set RCL intervals was reasonable.  This pattern infers
that within-laboratory replication for some analytes in SWA and EaFA materials is the main source of
overall variability in the data. Within-laboratory replication variability was most likely due to
heterogeneity of the study material.
As with the RCL values for Method 1313, the width of the RCL intervals was approximately a factor of 2
for analytes with good repeatability. Greater width was observed for the RCL at low L/S (see antimony
in CFS and boron in EaFA,  both in row B). The width for the PL generally was either similar to or
smaller for the PL than for the RCL for most analytes.
                                                                                              42
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
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Figure 12. Agreement between 95% prediction limits (95% PL) about the mean of the reference laboratory
data and 95% robust confidence limits (95% RCL) based on the median of laboratory means.
Note: Data shown for (A) high level agreement, (B) median level agreement, and (C) lowest level of agreement.
                                                                                                         43
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


Standard Deviations and Coefficients of Variation
Following the analytes in the left side of Figure 12 through the analysis process, the analyte standard
deviation intervals about the mean and coefficients of variation are shown in Figure 13.
The standard deviation intervals about the overall data mean indicate the variance in data associated with
(i) within-laboratory statistics associated with repeatability, (ii) between-laboratory statistics, and (iii)
with overall method performance associated with method reproducibility. The coefficient of variation for
each of these standard deviation values provides a relative measure if the overall variability
(reproducibility) is due to within-laboratory (repeatability) or between laboratory variation components.
In the cases of analytes with good agreement between PL and RCLs (e.g., arsenic in SWA and antimony
in CFS), the within-laboratory standard deviations (repeatability) are less than the variance associated
with between-laboratory or the overall (reproducibility) standard deviations and the between-laboratory
coefficient of variation represents a large portion of the overall variation (Figure 13, row A and B).
However, when the PL interval is wider than the RCL interval (e.g., arsenic in EaFA), the within-
laboratory standard deviation (repeatability) is greater than the between-laboratory standard deviation.
Thus, the within-laboratory coefficient of variation drives the  overall variability (Figure 13, row C).  In
general, the overall coefficient of variation was between 20-50% which is consistent with Method 1313
observations.

Method 1316 Repeatability and Reproducibility
Repeatability and reproducibility values for the three study materials (i.e., EaFA, SWA, and CFS) were
calculated based on the standard deviations and are presented  in Figure 14 and Figure 15 for vanadium
and boron,  respectively.  In each of these figures, the mean and the overall standard deviation interval
about that mean show the various levels and forms of the L/S-dependent behavior (panel A).  The
repeatability relative standard deviation  (RSDr; i.e., the within-laboratory coefficient of variation) and the
reproducibility relative standard deviation (RSDR; i.e., the overall coefficient of variation) are plotted as a
function of L/S in panels B and C.  The reproducibility HorRatR is plotted for each material as a function
of L/S in panel D.
Overall,  repeatability values were approximately 5-20% whereas reproducibility was more variable at 5-
50% for  most analytes.  Reproducibility values for SWA were generally higher than the other two
materials. Given the fact that SWA is a highly alkaline material subject to carbonation over time, the
heterogeneities associated with storing SWA prior to testing may explain the higher reproducibility
values.
                                                                                                44
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Interlaboratory Validation of LEAF Method 1313 and Method 1316

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1316 materials.
Note: Data shown for (A) selenium in SWA, (B) antimony in CFS, and (C) arsenic in EaFA.

The reproducibility Horwitz ratios shown in Figure 14D and Figure 15D are generally less than or
approximately 2 across the L/S range.  For most analytes, the HorRatR values increase above 2 at L/S =
0.5 mL/g which likely is due to procedural difficulties in separating solid and liquids via filtration.
                                                                                                 45
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


Higher values of HorRatR are seen in the SWA material for antimony, barium, boron, calcium and
selenium which can be explained by sample heterogeneities in addition to the above filtration issue.
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Figure 14. Method 1316 repeatability and reproducibility of vanadium.
Note: Data shown for (A) overall standard deviation intervals about the mean, (B) repeatability relative standard deviation
(RSDr), (C) reproducibility relative standard deviation (RSDR), (D) Horwitz ratio. Grey dashed line in panels (B) and (C)
indicate 20% and 50% reference lines for repeatability and reproducibility.
                                                                                                       46
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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Figure 15. Method 1316 repeatability and reproducibility of boron.
Note: Data shown for (A) overall standard deviation intervals about the mean, (B) repeatability relative standard deviation
(RSDr), (C) reproducibility relative standard deviation (RSDR), (D) Horwitz ratio. Grey dashed line in panels (B) and (C)
indicate 20% and 50% reference lines for repeatability and reproducibility.
A summary of Method 1316 repeatability and reproducibility values for each of the analytes in the
validation study are presented as RSDr and RSDR, respectively, in Table 17 and Table 18. The median
RSDr for Method 1316 ranged from 2% for calcium in CFS to 36% for chromium in EaFA while RSDR
ranged from 6% for Ca in CFS to 62% for boron in SWA. Overall, the precision of Method 1316 was
slightly better than Method 1313, most likely due to the fact that pH is not manipulated (i.e., there is no
addition of acid or base), thus, the buffering of the solid material controls pH.  The median precision
estimates for Method 1316, including all L/S target values, all analytes and all study materials, were 8%
RSDrandl9%RSDR.
                                                                                                  47
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
      Table 16. Method 1316 Repeatability (RSDr) across Study Materials.
                                             RSDr (%) at Target L/S Value (mL/g-dry)
      EaFA- Coal Combustion Fly Ash
          Analyte
Symbol
          Analyte      Symbol      0.5
          Analyte      Symbol      0.5
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
15
37
14
17
12
31
101
10
21
17
13
26
8
5
6
34
15
6
8
16
12
30
7
6
6
37
20
7
9
13
24
31
7
7
6
36
19
7
12
22
14
16
5
12
5
46
24
4
7
10
SWA - Solidified Waste Analog
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
5
35
4
13
7
4
16
6
5
3
8
8
10
7
9
9
15
6
4
6
6
11
27
8
5
39
18
4
8
6
8
7
7
5
6
6
NA
5
3
5
10
13
12
8
13
8
NA
7
8
9
CFS - Contaminated Field Soil
Antimony Sb
Arsenic As
Barium Ba
Boron B
Cadmium Cd
Calcium Ca
Lead Pb
Molybdenum Mo
Selenium Se
Vanadium V
7
10
6
3
4
3
3
9
2
8
12
13
4
4
4
2
4
8
3
3
12
12
5
3
4
3
7
10
3
5
13
16
2
6
4
2
10
10
9
3
12 |
15
4
12
4
2 1
4
14
9
4 |
        Notes:   NA = method precision not available (all concentrations set to 1A MDL).
                                                                                                  48
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
Table 17.   Method 1316 Reproducibility
                                                  across Study Materials.
                                              RSDr (%) at Target L/S Value (mL/g-dry)
      EaFA - Coal Combustion Fly Ash
          Analyte
                  Symbol
          Analyte      Symbol      0.5
          Analyte      Symbol      0.5
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
39
45
25
33
22
78
101
36
37
39
15
31
16
7
9
38
29
8
24
22
14
35
12
6
7
37
25
8
24
22
24
35
12
7
8
46
33
8
24
30
20
29
9
13
8
63
43
6
20
29
SWA - Solidified Waste Analog
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
5
65
175
78
42
5
107
59
40
61
24
34
41
62
24
22
41
28
18
11
45
22
103
70
52
70
23
25
21
15
75
19
23
34
8
15
NA
38
20
16
31
22
36
19
15
18
NA
33
21
17
CFS - Contaminated Field Soil
Antimony Sb
Arsenic As
Barium Ba
Boron B
Cadmium Cd
Calcium Ca
Lead Pb
Molybdenum Mo
Selenium Se
Vanadium V
19
24
13
11
10
8
10
19
11
12
17
21
14
9
9
6
12
13
10
12
18
24
15
8
9
5
14
16
7
13
16
32
14
10
10
6
15
18
11
12
22
32
16
29
9
6
17
18
15
13
        Notes:  NA = method precision not available (all concentrations set to 1A MDL).
                                                                                                  49
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
COMPARISON OF METHOD PRECISION TO STANDARDIZED LEACHING METHODS
There are no precision criteria for method acceptance in either the EPA guidance on RCRA program
validation studies or the ASTM standard practice for interlaboratory studies. Therefore, judgments on the
acceptability of the LEAF methods validated in the report cannot be made.  However, the precision
estimates of Method 1313 and Method 1316 (i.e., RSDr and RSDR values) may be compared to the
precision results from accepted and standardized leaching tests in order to provide context as to the level
of precision attained in this validation study.  The following two standardized tests form the basis of
comparison to Method 1313 and Method 1316:

TCLP (SW-846 Method 1311) Reproducibilitv
Reproducibility data is provided in the TCLP method for cadmium, chromium and lead contained in three
study materials - ammonia lime still bottoms, a mixture of American Petroleum Institute separator sludge
and electroplating waste, and fossil fuel fly ash. Each of the three study materials was tested with both
the acetic acid and buffered acetic acid extraction fluids specified in the  test method. In the sense that
TCLP uses an acid  solution to manipulate extract pH, the TCLP procedure is somewhat similar to a single
target value extraction of Method 1313 and it is reasonable to assume that the precision estimates could
be similar.  However, the final pH of the TCLP extraction is not controlled nor recorded so that direct
comparison of leaching results often is not possible. As a result of interlaboratory validation of TCLP,
the mean %RSD for reproducibility was reported as 74% with a range of 17-118% (EPA, 1992a).

EN 12457 Validation
EN 12457 is European Standard consisting of a four-part batch leaching procedure in which particle size
reduced material is  extracted with deionized or demineralized water at room temperature.  Parts 1, 2 and 4
of the standard are single-batch extractions at difference L/S ratios and particle size requirements. Part 3
consists of a two-step test with re-extraction of the recovered material from the first L/S 2.0 mL/g
extraction in a second extraction step at L/S of 8.0 mL/g (cumulatively the L/S is equal to  10 mL/g).  In
comparison to the LEAF methods, EN 12457-2 is most similar to the L/S 10 target extractions in Method
1316 and the natural pH extraction of Method 1313.
The performance characteristics of the single-batch extraction leaching test, EN 12457-2, was validated in
an interlaboratory study using 12-14 laboratories across Europe and seven materials, including municipal
solid waste incinerator filter cake, sewage sludge, contaminated soil, chemical sludge, sand blasting
waste, incinerator bottom ash, and metallurgical slag.  The precision data shown Table 2 of the EN 12457
part 2 (CEN, 2001) method precision section includes relative standard deviations for repeatability and
reproducibility.  The median precision estimates for EN 12457-2 are 10% RSDr and 33% RSDR, with
ranges of 2-77% and 7-124% for repeatability and reproducibility, respectively.

Precision Distributions and Comparisons
The distribution of RSDr and RSDR values for Method 1313 and Method 1316 are shown in the form of
"box and whisker"  plots in Figure 16 through Figure 18. The distributions in these figures were derived
from the method precision results in Table 17 and Table 18. Details on the values used in the distribution
plots are presented  in Appendix E for Method 1313 validation and Appendix F for Method 1316
validation.  In each distribution, the "box" in Figure 15 through Figure 17 represents the IQR (i.e., 25th to
75th percentiles) of the data with a horizontal line within the box displaying the median value. The
                                                                                            50
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


"whiskers" above and below the box indicate the maximum and minimum data in the data set,
respectively.  Also shown in these figures are the distribution of RSD values used to represent TCLP
precision (blue distribution) and the RSDr and RSDR distributions from reported for EN 12457 validation
(red distribution).

Precision as a Function ofAnalyte
In Figure 16, the distributions of Method 1313 and Method 1316 precision estimates are shown as a
function of each analyte. These distributions represent the precision estimates for all study materials and
all test positions (i.e., nine target pH values for Method 1313 and five L/S values for Method 1316) for
each common analyte. The figure shows that when precision is broken down by analyte, the IQRs for all
analytes are similar. However, the extreme values of the distribution for arsenic, barium, molybdenum
and antimony appear to be higher than for the other analytes. The analytical QA/QC for arsenic and
selenium were slightly higher than the other analytes (see Table 12) indicating that, although all analytes
passed basic QA/QC, some interference in eluate analysis might be the cause of wider precision
distributions.  Also, total content analysis indicated greater variability for antimony, barium, and
molybdenum, potentially indicating greater material heterogeneity with respect to these analytes. The
median values of precision and IQRs for Method 1313 and Method 1316 are consistent with the precision
distribution from EN 12457-2.  The IQRs for Method 1313 and Method 1316 precision is considerably
lower than that reported in the TCLP precision data.

Precision as a Function of Test Parameters
The distribution of precision estimates for all analytes and study materials measured for a specific target
test position (i.e., pH values for Method 1313 and L/S values for Method 1316) are shown in Figure 17.
As noted in the Method 1313 results, the highest precision estimates for Method 1313 occur at the
extremes of the  pH range (e.g., pH = 2 or pH = 13.0) where errors in pH measurement are likely and LSP
concentrations may change drastically over a small pH interval. Comparison to standardized leaching test
precision at these pH extremes is not reasonable in that EN and TCLP are most similar to extraction at
natural pH or acid extraction in the near-neutral pH range. Within the near-neutral range, Method 1313
precision compares favorably with EN  12457-2 precision and is much better than the precision reported
for TCLP. Method 1316 repeatability is fairly consistent across the target L/S range; however,
reproducibility shows a wider range of precision for low L/S extractions which may be due to the fact that
there is less data at L/S =0.5 mL/g-dry than at other L/S values. Again, the precision distributions are in
good agreement with those of EN 12457-2 and considerable lower than those of TCLP.

Precision as a Function of Material
Method 1313 and Method 1316 precision data are presented in Figure 18 as a function of study material.
Of the three study materials, SWA showed the highest RSDr and RSDR distributions while EaFA showed
the lowest.  Given the nature of the materials and the fact that SWA was created by mixing contaminants
by hand into a large batch of cementitious materials, these precision values are not surprising.  The
median Method 1313 and Method 1316 data shown in Figure 18 are consistent with the median precision
for EN 12457-2 and well below the mean %RSD value reported for TLCP.
                                                                                             51
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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Figure 16.  Method precision as a function of selected analytes in comparison to precision values reported for EN 12457-2, shown as "EN" (van der

Sloot et al.  2001) and TCLP (EPA 1992a).


Note: Repeatability RSDr (top) and reproducibility RSDR (bottom) shown for Method 1313 (left) and Method 1316 (right). Box and whisker plots show the 25th, 50th (median) and

75th percentiles of precision data with whiskers indicating maximum and minimum values.
                                                                                                                                          52
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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                     L/S (L/kg)
Figure 17. Method precision as a function of test parameter in comparison to precision values reported for EN 12457 (van der Sloot et al. 2001) and
TCLP (EPA 1992a).
Note: Repeatability RSDr (top) and reproducibility RSDR (bottom) shown for Method 1313 (left) and Method 1316 (right). Box and whisker plots show the 25th, 50th (median) and
75th percentiles of precision data with whiskers indicating maximum and minimum values.
                                                                                                                                             53
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
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Figure 18. Method precision as a function of material in comparison to precision values reported for EN 12457 (van der Sloot et al. 2001) and TCLP
(EPA 1992a).
Note: Repeatability RSDr (top) and reproducibility RSDR (bottom) shown for Method 1313 (left) and Method 1316 (right). Box and whisker plots show the 25th, 50th (median) and
75th percentiles of precision data with whiskers indicating maximum and minimum values.
                                                                                                                                           54
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
COMPARISON OF ANALOGOUS EU LEACHING TEST RESULTS TO METHOD 1313
VALIDATION STATISTICS
Two European laboratories, the Energy Research Centre of the Netherlands (ECN) and DHI Denmark,
offered time and effort to conduct European test methods for pH-dependent release for comparison to
Method 1313. The two test methods are technical specifications15 of the Comite Europeen de
Normalisation (CEN). Although initially designed to test waste materials, the approach of these methods
has been adapted under the International Standards Organization (ISO) program for soils and soil
materials (ISO/TS 21267, 2007).

EU Test Method Descriptions (CEN/TS 14429 and CEN/TS 14497)
Separate sample portions are extracted in parallel at a fixed L/S ratio of 10 mL/g in dilute acid or base
solutions in order to reach stationary pH values at the end of the extraction period.  Sample portions of 15,
30, or 60 g (depending on sample heterogeneity and volumes of extractant required for chemical analysis)
are prepared to have a grain size with 95% (m/m) less than 1 mm. Any particle size reduction is
conducted by crushing. At least eight final pH values are required, covering at the minimum the range pH
4 - pH 12 (including the lowest value <4 and the highest value >12). The maximum pH differential
between final pH points shall not exceed  1.5 pH units. The amounts of acid or base needed to cover the
pH range can be derived from the results of a preliminary titration, from available experimental data on
the material to be tested or from an arbitrary division of the predetermined maximum consumption of acid
and base. The tests are carried out at a fixed contact time of 48 hours at which time equilibrium
conditions are assumed for most constituents. The  equilibrium condition is verified by a pH difference of
less than 0.3 pH units between measurements taken after 44 hours and 48 hours.  The results are
expressed in mg/L of constituents for each final pH value.  The quantity of acid or base that is added  is
recorded for each final pH value in moles of FTVkg of dry material with base additions expressed as
negative values.
The primary difference between these two EU methods is how the extraction solution is introduced to the
test portion:
    •   CEN/TS 14429 - Test portions are contacted with extraction solutions in a closed vessel with
        acid/base introduction through initial addition of extraction fluid. At the start of the test, the
        extraction solutions are prepared and divided evenly into three fractions. A fraction of extraction
        solution is added to the extraction bottle at the start of the test,  after 30 minutes, and after 2 hours.
    •   CEN/TS 14497 - Test portions are placed into an open vessel with reagent water and acid/base is
        introduced via automated pH control. The  method specifies that acid or base addition between
15 The comparative European methods are designated as "technical specifications" with a TS designation, denoting a method
definition has resulted from a multi-national consensus process and has been approved by a CEN technical committee.  The TS
designation, however, means that interlaboratory validation studies to assess precision have not yet been conducted and that
public comment and consensus approval by CEN members will be repeated when performance characteristics are available. A
TS designation does not carry the status of a European standard (EN), but may be adopted as national standard.
                                                                                              55
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


       cumulative extraction times of 44 and 48 hours shall not exceed 2% of maximum of the total
       acid/base addition at 48 hours.

Comparison of EU Test Results to Method 1313 Statistics
The EU methods differ little in approach and basic structure from Method 1313.  Eluate concentrations
from CEN/TS 14429 and 14997 are, therefore, expected to be consistent with the results of the Method
1313. Notable procedural differences between EU tests and Method 1313 include (i) open vessels in
CEN/TS  14997 as opposed to closed vessels in Method  1313 and (ii) repeated opening of extraction
bottles during CEN/TS 14429 to add leachant. Open and vented bottles would release gases evolved
during leaching and allow contact of the extraction slurries with the atmosphere, potentially leading to
oxidation of eluates which would otherwise be reducing and neutralization of pH in alkaline slurries due
to carbonation. In addition, open extraction vessels allow for the release of CO2 from carbonated
materials which when trapped within closed vessels could lead to chelation of arsenic and increase  in
measured arsenic concentrations.
EU method results were plotted as a function of eluate pH and compared against the 95% reproducibility
limit (RL) calculated using Method  1313. Figure 19 shows the comparison of EU data to the mean and
RL intervals for a selection of analytes and study materials while the full set of comparisons for a wide
suite of analytes is presented in Appendix G. In general, the  agreement between the pH-dependent
leaching data from  CEN tests and the RL intervals derived from Method 1313 data is very good for most
analytes in the three study materials.
Each row in the Figure 19 contains data for one of the three study materials with the left-hand panel
showing a typical level of agreement between  Method 1313 RL and the CEN data; and the right-hand
panel showing a case with less than  typical agreement. Based, in part, on observations seen in reviewing
Method 1313 data for the participating laboratories, potential sources for the differences in agreement
between EU and  Method 1313 data may include (i) heterogeneity between laboratory samples due to
storage and use at the participating laboratories (see barium in EaFA), (ii)  oxidation of reducing materials
in open extraction vessels during CEN/TS 14997 (see arsenic in SWA), and (iii) storage of caustic
reagents in borosilicate glass (see boron in CFS). Provided that these potential sources of variation are
accounted for, the data from CEN/TS 14429 and 14997 are essentially the same as those determined by
Method 1313.
                                                                                             56
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
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Figure 19. Leaching results from CEN tests compared to Method 1313 RL values.
Note: Data shown for (A) boron in EaFA, (B) barium in EaFA, (C) arsenic in SWA, (D) selenium in SWA, (E) arsenic in CFS
and (F) boron in CFS.
                                                                                                                   57
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
SUMMARY AND CONCLUSIONS
The precision of LEAF Method 1313 and Method 1316 have been derived from interlaboratory testing
using three different study materials.  Method 1313 and Method 1316 are leaching test methods that
characterize the liquid-solid partitioning at equilibrium between a solid material and a contacting leaching
solution as functions of pH or liquid-solid ratio, respectively. The three material types were intended to
challenge the performance of the method over the range of materials seen in waste management activities.
For each test method, ten participating laboratories were asked to provide filtered and preserved eluates
from triplicate tests runs on each of the study materials. Although the number of participating
laboratories varied for each study material, seven to eleven laboratories provided data for each test
method.  ARCADIS-US, Inc. served as a reference laboratory and provided six test replicates of each
material for both methods. Eluates were chemically analyzed by inductively coupled plasma-optical
emission spectroscopy at Vanderbilt University in order to select a list often analytes for further study
based on concentration levels and EPA significance.
The collection and management of the large  data set was achieved using standardized Excel templates in
conjunction with LeachXS data evaluation software.  The results were processed using logic
transformation and linear interpolation/extrapolation to yield a set of data used in statistical analysis.
Statistical measurements of data spread, within-laboratory standard deviation, between-laboratory
standard deviation and overall standard deviation were calculated for ten selected analytes from each
material. The reference laboratory data were used to develop intervals for 95% prediction limits about the
mean which were compared to 95% robust confidence limits about the median of all the means from each
laboratory. For Method 1313 test data, the process of linear interpolation of collected data was shown to
induce variance in some analytes with strongly changing pH-dependence curves. Interpolation was
necessary for normalize collected data, that varied with both pH and concentration, to Method 1313 target
pH values. However, the interpretation approach was not considered to affect the ability of the test to be
used for regulatory purposes as no significant deviation was seen in environmentally relevant pH ranges
(e.g., between pH 5 and pH 9) and at maxima of the pH-dependence curve. Measurement of extreme pH
values, calibration of pH meters to a narrow  pH range, and reagent storage practices were seen as
potential, and more common, sources of variation in test results.
Variance components were calculated based on the equations of a one-way analysis of variance in order
to determine within-laboratory, between-laboratory and overall standard deviations. Repeatability and
reproducibility statistics were derived from the within-laboratory and overall standard deviation values,
respectively.  Using the data from the eight analytes common to all materials, the overall median values
of precision were  estimated as the  repeatability relative standard deviation (RSDr) and reproducibility
relative standard deviation (RSDR). The median values of RSDr were 13% for Method 1313 and 8% for
Method 1316 while the median values of RSDR were 28% for Method 1313 and 19% for Method 1316.
The repeatability values indicate the  expected results variation for a single operator conducting test
replicates on the same materials sample while the reproducibility values represent the variation of test
results for multiple laboratories conducting the test methods on a homogenized sample of material.
These precision values and the interquartile ranges of the repeatability and reproducibility as functions of
selected analytes, independent method parameters (e.g., pH or liquid-solid ratio), and materials were
found to be in agreement with the median precision values reported for validation of the European
                                                                                              58
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Interlaboratory Validation of LEAF Method 1313 and Method 1316


standard EN 12457-2 (van der Sloot et al, 2001). The median RSDR values for both Method 1313 and
Method 1316 were considerably lower than the mean reproducibility RSD reported for TCLP (EPA
1992a).
In order to compare pH-dependence results from Method 1313 to those of similar leaching methods in use
throughout the European Union, two European laboratories were asked to test the validation study
materials using CEN/TS 14429 and CEN/TS 14997.  These pH-dependence leaching methods are
standardized through the Comite Europeen de Normalisation as technical specifications which are
available for adoption as national standards but have yet to undergo interlaboratory validation. The eluate
concentration results of CEN/TS 14429 and 14997 were compared directly with the 95% RCL intervals
from Method 1313. The comparisons showed only minor differences in eluate concentrations for a
minority of analytes which are likely due to sample heterogeneity during storage prior to testing and
oxidation during leaching in open vessels.  In general, the good agreement between Method 1313 and EU
leaching procedures indicated that all three methods adequately characterized the pH-dependent leaching
behavior of constituents in the three study materials.
Based on the method validation results and comparison presented in this report, the following statements
regarding LEAF Method 1313 and Method 1316 may be made:

Procedural Considerations
  •  Accurate pH measurements are essential to the performance of these methods, especially Method
      1313.  Measurement of pH should consider appropriate instrument calibration, standardization with
     buffer solutions that span the resultant extract pH range to the greatest degree possible and proper
     pH measurement techniques. Measurements should be taken as rapidly as practical after gross
     solid-liquid phase separation (e.g., settling or centrifugation) to avoid carbonation of alkaline
     solutions with limited pH buffering capacity.
  •  Reagents should be prepared fresh before each run of these test methods.  If reagents are to be
     stored, containers made from compatible materials must be used (e.g., strong bases should not be
     stored in borosilicate glass if boron is considered to be a constituent of concern).
  •  The data templates are recommended for use with Method 1313 and Method 1316 to provide
     uniform calculations, data collection, and data input into LeachXS which greatly facilitates
     management of large data sets.  LeachXS Lite is a simplified, free version of LeachXS that can
     assist method users with method implementation as well as data management, graphing and
     reporting.
  •  Sample heterogeneity was cited as a potential cause of high variation in precision data for SWA
     material.  Heterogeneity can  result from variations in the solid material (e.g., resulting from hand
     mixing of SWA or incomplete dissolution of metal salts in the matrix), aging of the cured materials,
     or by exposure of leaching solutions to the atmosphere (e.g., oxidation during open vessel leaching
     in CEN/TS 14997). More rigorous solid material handling of the heterogeneous  SWA material and
     changes in the CEN methods to limit exposure of leaching solutions to the atmosphere may lead to
     improvements in leaching data consistency.
                                                                                            59
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
Data Validation Approach
    •  Although the linear interpolation/extrapolation used with Method 1313 may introduce some
       degree of variability to the statistical analysis, the effects are limited to areas of the pH-
       dependence curve with a steep slope or significant curvature.  The introduced variability has been
       shown to occur at local minima in concentration as a function of pH or at extreme (very low or
       very high) pH values which are anticipated to occur infrequently in the environment. Therefore,
       variability induced by linearization is not expected to impact the use of the method as part of
       decision making processes.
    •  The data evaluation methods used (e.g., data filtering, interpolation and extrapolation, statistical
       analysis) appear to be robust and provide a useful basis for evaluation of the results.

Repeatability and Reproducibility
    •  Repeatability of these methods generally is expected to be approximately 5-15% of the mean
       concentration value which is consistent with the variability associated with many chemical
       analytical methods. Reproducibility is expected to be approximately within a factor of 2 (e.g., the
       mean ± 50%) in the pH and L/S domains with good repeatability.  Greater width in Method 1313
       reproducibility relative standard deviation is expected at the extremes of pH and when there are
       steep changes in analyte concentrations as a function of pH.  For Method 1316, the
       reproducibility relative standard deviation is expected to increase at low L/S values.
    •  Observed reproducibility was consistent  with prior experience across multiple laboratories during
       method development.
    •  The repeatability and reproducibility results suggest that sample heterogeneity is likely to be the
       dominant source of variability associated with broader use of these leaching test methods.  As
       sample heterogeneity is an issue intrinsic to the study of waste materials, there should be no
       implications of this finding to the broader use of the LEAF methods.
    •  Commercial and non-commercial laboratories should be readily able to implement Method 1313
       and Method 1316 for a wide range of material types with a degree of repeatability and
       reproducibility consistent with current regulatory leaching methods in the U.S. and Europe.
                                                                                              60
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
REFERENCES

ASTM Standard E691 (1987) "Standard Practice for Conducting an Interlaboratory Study to Determine
the Precision of a Test Method," ASTM International, West Conshohocken, PA, 1987.
ASTM Standard E1488 (2002) "Standard Guide for Statistical Procedures to Use in Developing and
Applying Test Methods," ASTM International, West Conshohocken, PA, 1987.
CEN (2001) EN 12457 Characterization of Waste - Leaching - Compliance Test for Leaching of
Granular Waste Materials and Sludges - Part 2: One stage batch test at a liquid to solid ratio of 10 L/kg
for materials with particle size below 4 mm (with or without size reduction), CEN, Brussels, Belgium.
CEN/TS 14429 (2005) Characterization of Waste - Leaching Behaviour Tests - Influence of pH on
Leaching with Initial Acid/base Addition, CEN, Brussels, Belgium.
CEN/TS 14997 (2005) Characterization of Waste - Leaching Behaviour Tests - Influence of pH on
Leaching with Continuous pH Control, CEN, Brussels, Belgium.
Currie, L.A. and G. Svehla (1994) "Nomenclature for the presentation of results of chemical analysis
(IUPAC recommendations 1994)," Pure and Applied Chemistry, 66(3), 595-608.

Daszykowski, M., K. Kaczmarek, Y. Vander Heyden, and B. Walczak (2007) "Robust statistics in data
analysis - A review of basic concept," Chemometrics and Intelligent Laboratory Systems, 85, 203-219.
Ellison, S.L.R., V.J. Barwick, and T.J.D. Farrant (2009) Practical Statistics for the Analytical Scientist: A
Bench Guide, 2nd Edition, RSC Publishers, Cambridge, UK, 268 pp.
EPA (1992a) SW-846 Method 1311 "Toxicity Characteristic Leaching Procedure," Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency,
http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/1311 .pdf.

EPA (1992b) Guidance for Methods Development and Methods Validation for the RCRA Program. U.S.
Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/pdfs/methdev.pdf
EPA (1996) SW-846 Method 3052 "Microwave Assisted Acid Digestion of Siliceous and Organically
Based Matrices," Test Methods for Evaluating  Solid Waste, Physical/Chemical Methods (SW-846), U.S.
Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/3052.pdf.
EPA (2003) "Technical Support Document for the Assessment of Detection and Quantitation
Approaches", U.S. Environmental Protection Agency, Office of Water, February 2003.
EPA (2004) SW-846 Method 9060 "Total Organic Carbon," Test Methods for Evaluating Solid Waste,
Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency,
http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/9060a.pdf
EPA (2007a) SW-846 Method 3051 "Microwave Assisted Acid Digestion of Sediments, Sludges, Soils,
and Oils," Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S.
Environmental Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/3051 .pdf.

EPA (2007b) SW-846 Method 6010 "Inductively Coupled Plasma-Atomic Emission Spectroscopy," Test
Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental
Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/6010c.pdf.

EPA (2007c) SW-846 Method 6020 "Inductively Coupled Plasma-Mass Spectroscopy," Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency,
http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/6020a.pdf
EPA (2007d) SW-846 Method 9056 "Determination of Inorganic Anions by Ion Chromatography," Test
Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental
Protection Agency, http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/9056a.pdf.
                                                                                           61
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Interlaboratory Validation of LEAF Method 1313 and Method 1316
Garrabrants, A.C., D.S. Kosson, H.A. van der Sloot, F. Sanchez, and O. Hjelmar (2010) "Background
information for the Leaching Environmental Assessment Framework (LEAF) Test Methods," EPA-
600/R-10/170, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division,
December 2010.
Huber, P.J. (1968) "Robust confidence limits," Probability Theory and Related Fields, 10(4), 269-278.

Horwitz, W and R. Albert (2006) "The Horwitz ratio (HorRat): A useful index of method performance
with respect to precision," Journal of AOAC International, 89(4),  1095-1109.

ISO/TS 21267-4 (2007) Soil Quality - Leaching Procedures for Subsequent Chemical and
Ecotoxicological Testing of Soil and Soil Materials - Part 4: Influence of pH on Leaching with Initial
Acid/base Addition, ISO, Geneva, Switzerland.
ISO (1994) ISO 5725-1 Accuracy (Trueness and Precision) of Measurement Methods and Results - Part
1: General Principles and Definitions, International Organization for Standards, Geneva, Switzerland.
Kosson, D.S., F. Sanchez, P. Kariher, L.H. Turner, R. DeLapp, and P. Seignette (2009) "Characterization
of Coal Combustion Residues from Electric Utilities - Leaching and Characterization Data," EPA-600/R-
09/151, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division,
December 2009.
Kosson, D.S, H.A. van der Sloot, F. Sanchez and A.C. Garrabrants (2002) "An integrated framework for
evaluating leaching in waste management and utilization of secondary materials," Environmental
Engineering Science, 19(3), 159-204.
Linsinger, T.P.J. and R.D. Josephs (2006) "Limitations of the application of the Horwitz equation,"
Trends in Analytical Chemistry, 25(11), 1125-1130.
Mandel, J. (1991) "The validation of measurement through interlaboratory studies", Chemometrics and
Intelligent Laboratory Systems, 11, 109-119.
Maronna, R, D. Martin, and V. Yohai (2006) Robust Statistics: Theory and Methods", John Wiley &
Sons, Ltd., Chichester, UK.
Rao, P.V. (1998) Statistical Research Methods in the Life Sciences, Duxbury Press, Pacific Grove CA.
Sanchez, F., R. Keeney, D.  Kosson, and R. DeLapp (2006) "Characterization of Mercury-enriched Coal
Combustion Residues from Electric Utilities using Enhanced Sorbents for Mercury Control," EPA-600/R-
06/008, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division, February
2006.
Sanchez, F., D. Kosson, R.  Keeney, R. DeLapp, L. Turner and P. Kariher (2008) "Characterization of
Coal Combustion Residues from Electric Utilities using Wet Scrubbers for Multi-pollutant  Control,"
EPA-600/R-08/077, U.S. Environmental Protection Agency, Air Pollution Prevention and Control
Division, July 2008.
van der Sloot, H.A., L. Heasman, and P. Quevauviller (1997) Harmonization of Leaching/Extraction
Tests, Elsevier Science, Amsterdam.
van der Sloot, H.A., O. Hjelmar, J. Berre Hansen, J. Woitke, P. Lepom, R. Leschber, B. Bartet, and N.
Debrucker (2001) Validation of CEN/TC 292 Leaching Tests and Eluate Analysis Methods PrEN 12457
Part  1-4, ECN-C-01-117, ENV 13370 and ENV 12506 in Co-operation with CEN/TC 308.
                                                                                            62
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                             Appendix A.     Method 1313
                                        A-i
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


                                 DRAFT METHOD 13131

   LIQUID-SOLID PARTITIONING AS A FUNCTION OF EXTRACT pH USING A PARALLEL
                           BATCH EXTRACTION PROCEDURE
       SW-846 is not intended to be an analytical training manual. Therefore, method
procedures are written based on the assumption that they will be performed by analysts who are
formally trained in at least the basic principles of chemical analysis and in the use of the subject
technology.

       In addition, SW-846 methods, with the exception of required method use for the analysis
of method-defined parameters, are intended to be guidance methods which contain general
information on how to perform an analytical procedure or technique which a laboratory can use
as a basic starting point for generating its own detailed Standard Operating Procedure (SOP),
either for its own general use or for a specific project application.  The performance data
included in this method are for guidance purposes only, and are not intended to be and must not
be used as absolute quality control (QC) acceptance criteria for purposes of laboratory quality
control or accreditation.
1.0    SCOPE AND APPLICATION

       1.1      This method is designed to provide aqueous extracts representing the liquid-
solid partitioning (LSP) curve as a function of pH for inorganic constituents (e.g., metals and
radionuclides), semi-volatile organic constituents (e.g., polycyclic aromatic hydrocarbons or
PAHs) and non-volatile organic constituents (e.g., dissolved organic carbon) in solid materials.
The LSP curve is evaluated as a function of final extract pH at a liquid-to-solid ratio (US) of 10
mL extractant/g dry sample (g-dry) and conditions that approach liquid-solid chemical
equilibrium.  This method also yields the acid/base titration and buffering capacity of the tested
material at an L/S of 10 mL extractant/g-dry sample. The analysis of extracts for dissolved
organic carbon and the solid phase for total organic carbon allow for the evaluation of the
impact of organic carbon release and the influence of dissolved organic carbon on the LSP of
inorganic constituents.

       1.2     This method is intended to be used as part of an environmental leaching
assessment for the evaluation of disposal, beneficial use, treatment effectiveness and site
remediation options. The method is not required by federal regulations to determine whether
waste passes or fails the toxicity characteristic as defined at 40 CFR  261.24.

       1.3     This method is suitable for assessing the leaching potential of a wide range of
solid materials. Examples of solid materials include:  industrial wastes, soils, sludges,
combustion residues, sediments, stabilized materials, construction materials, and mining
wastes.

       1.4     This method is a leaching characterization method that is used to provide
values for intrinsic material parameters that control leaching of inorganic and some organic
1 This method has been derived from the SR002 procedure (Ref. 2) using EPA reviewed and accepted
methodologies (see Refs. 4-6). The method is analogous to pH-dependence methods CEN/TS14429 (Ref. 8) and
CEN/TS14997 (Ref. 9) developed for the Comite Europeen de Normalisation (CEN).
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species under equilibrium conditions. This test method is intended as a means for obtaining a
series of extracts of a solid material (i.e., the eluates), which may be used to estimate the LSP
(e.g., solubility and release) of constituents as a function of pH under the laboratory conditions
described in the method.  Eluate constituent concentrations may be used in conjunction with
information regarding environmental management scenarios to estimate the anticipated
leaching concentrations, and release rate and extent for individual material constituents under
the management conditions evaluated.  Eluate constituent concentrations generated by this
method may also be used along with geochemical speciation modeling to infer the mineral
phases that control the LSP in the pore structure of the solid material.

       1.5     This method is  not applicable for characterizing the release of volatile organic
analytes (e.g., benzene, toluene, xylenes).

       1.6     The relationships between eluate concentrations observed from this method
and field leachate must be considered in the context of the material being tested and the field
scenario being evaluated.  This method provides solutions with concentrations considered
indicative of leachates under field conditions at comparable ranges of pH for the case when the
LSP is controlled by aqueous phase saturation of the constituent of interest.  When LSP is
controlled by the amount of the  constituent present in the solid that may dissolve (i.e., for highly
soluble species), the mass released (mg/kg), rather than the concentration,  is indicative of field
conditions.2

       1.7     The maximum concentration of constituent released over the range of method
pH conditions (2 < pH < 13) may be considered an estimate of the maximum possible release of
the constituent under field leaching conditions for intermediate time frames (because the
method pH range will encompass and typically exceed the field pH range, using pH values both
greater than and less than the field pH range). .

       1.8     The solvents used in this method include dilute solutions of nitric acid (HNO3)
and potassium hydroxide (KOH) in reagent water.

       1.9     Analysts are advised to take reasonable measures to ensure that the sample is
homogenized to the extent practical, prior to employment of this  method.  Particle-size reduction
may provide additional  assurance of sample homogenization and also facilitate achievement of
equilibrium during the test procedure. Table 1 of this method designates a recommended
minimum dry mass of sample to be added to each extraction vessel and the  associated
extraction contact time  as a function particle diameter.  If the heterogeneity of the sample is
suspected as the cause of unacceptable precision in replicate test results or is considered
significant based on professional judgment, the sample mass used in the test procedure may be
increased to a greater minimum dry mass than that shown in Table 1 with the amount of
extractant increased proportionately to maintain the designated US.

       1.10    In the preparation of solid materials for use in this method, particle-size
reduction of samples with a large grain size is performed in order to enhance the approach
towards equilibrium under the designated contact time interval of the  extraction process. The
2 The concentrations of soluble species (e.g., Na, K, Cl, B) may not be controlled by aqueous phase saturation, but by
the liquid-to-solid ratio. In such cases, the mass released is consistent with field conditions and the field leachate
concentrations (mg/L) could be estimated by adjusting the mass release (mg/kg) for the field L/S (L/kg).  Alternatively
for these cases, leachate concentrations may be more consistent with L/S-dependent testing using Method 1314 or
Method 1313.
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extract contact time for samples reduced to a finer maximum particle size will consequently be
shorter (see Table 1).

       1.11     Prior to employing this method, analysts are advised to consult the base
method for each type of procedure that may be employed in the overall analysis (e.g., Methods
9040, 9045, and 9050, and the determinative methods for the target analytes),  QC acceptance
criteria, calculations, and general guidance.  Analysts also should consult the disclaimer
statement at the front of the manual and the information in Chapter Two for guidance on the
intended flexibility in the choice of methods, apparatus, materials, reagents, and supplies, and
on the responsibilities of the analyst for demonstrating that the techniques employed are
appropriate for the analytes of interest, in the matrix of interest, and at the concentration levels
of concern.

       In addition, analysts and data users are advised that, except where explicitly specified in
a regulation, the use of SW-846 methods is not mandatory in response to Federal testing
requirements.  The information contained in this method is provided by EPA as guidance to be
used by the analyst and the regulated community in making judgments necessary to generate
results that meet the data quality objectives for the intended application. Guidance on defining
data quality objectives can be obtained at http://www.epa.gov/QUALITY/qs-docs/g4-final.pdf

       1.12     Use of this method is restricted to use by, or under supervision of, properly
experienced and trained personnel. Each analyst must demonstrate the ability to generate
acceptable results with this method as described in Section 9.5.
2.0    SUMMARY OF METHOD

       This method consists of nine parallel extractions of a particle size-reduced solid material
at target pH values spanning the range from pH 2 to 13, with pH control by adition of dilute acid
or base and reagent water.  A flowchart for performing this method is shown in Figure 1.
Particle-size reduction of the material to be tested is performed according to Table 1.  A
schedule of acid and base additions is formulated from a pre-test titration curve or prior
knowledge indicating the required equivalents/g acid or base to be added to the series of
extraction vessels so as to yield a series of eluates having specified pH values in the range of 2-
13.  In addition to the nine test extractions, three method blanks without solid sample are carried
through the procedure in order to verify that analyte interferences are not introduced as a
consequence of reagent impurities or equipment contamination. The twelve bottles (i.e., nine
test positions and three method blanks) are tumbled in an end-over-end fashion for a specified
contact time, which depends on the particle size of the sample (see Table 1).  At the end of the
specified contact interval,  the liquid and solid phases are roughly separated via settling or
centrifugation. Extract pH and specific conductivity measurements are then made on an aliquot
of the liquid phase and the remaining bulk of the eluate is clarified by either pressure or vacuum
filtration.  Analytical samples of the filtered eluate are collected and preserved as appropriate for
the desired chemical analyses. The eluate concentrations of COPCs are determined and
reported.  In addition, COPC concentrations may be plotted as a function of eluate pH and
compared to quality control and assessment limits for the interpretation of method results.
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3.0    DEFINITIONS

       3.1      Constituent of potential concern (COPC) — A chemical species of interest,
which may or may not be regulated, but may be characteristic of release-controlling properties
of the sample geochemistry.

       3.2      Release — The dissolution or partitioning of a COPC from the solid phase to
the aqueous phase during laboratory testing (or under field conditions). In this method, mass
release is expressed in units of mg COPC/kg dry solid material.

       3.3      Liquid-solid partitioning (LSP) — The distribution of COPCs between the solid
and liquid phases at the conclusion of the extraction.

       3.4      Liquid-to-solid ratio (US) — The fraction of the total liquid volume (including the
moisture contained in the "as used" solid sample) to the dry mass equivalent of the solid
material. L/S is typically expressed in volume units of liquid per dry mass of solid material
(mL/g-dry).

       3.5      "As-tested" sample — The solid sample at the conditions (e.g., moisture content
and particle-size distribution) present at the time of the start of the test procedure. The "as-
tested" conditions will differ from the "as-received" sample conditions if particle-size reduction
and drying were necessarily performed.

       3.6      Dry-mass equivalent — The mass of "as-tested" (i.e., "wet") sample that
equates to the mass of dry solids plus associated moisture, based on the moisture content of
the "as-tested" material.  The dry-mass equivalent is typically expressed in mass units of the
"as-tested" sample (g).

       3.7      Refer to Chapter One and the equipment manufacturers' instructions for
definitions that may be relevant to this procedure.
4.0    INTERFERENCES

       4.1      Solvents, reagents, glassware, and other sample processing hardware may
yield artifacts and/or interferences to sample analysis.  All of these materials must be
demonstrated to be free from interferences under the conditions of the analysis by analyzing
method blanks. Specific selection of reagents and purification of solvents by distillation in all-
glass systems may be necessary. Refer to each method to be used for specific guidance on
quality control procedures and to Chapters Three and Four for general guidance on the cleaning
of laboratory apparatus prior to use.

       4.2      If potassium is a COPC, the use of KOH as a base reagent will interfere with
the determination  of actual potassium release. In this case, sodium hydroxide (NaOH) of the
same grade and normality may be used as a substitute.
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5.0    SAFETY

       5.1     This method does not address all safety issues associated with its use.  The
laboratory is responsible for maintaining a safe work environment and a current awareness file
of OSHA regulations regarding the safe handling of the chemicals listed in this method. A
reference file of material safety data sheets (MSDSs) should be available to all personnel
involved in these analyses.

       5.2    During preparation of extracts and processing of extracts, some waste
materials may generate heat or evolve potentially harmful gases when contacted with acids and
bases. Adequate prior knowledge of the material  being tested should be used to establish
appropriate personal protection and workspace ventilation.
6.0    EQUIPMENT AND SUPPLIES

       The mention of trade names or commercial products in this manual is for illustrative
purposes only, and does not constitute an EPA endorsement or exclusive recommendation for
use. The products and instrument settings cited in SW-846 methods represent those products
and setting used during the method development or subsequently evaluated by the Agency.
Glassware, reagents,  supplies, equipment, and setting other than those listed in this manual
may be employed provided that method performance appropriate for the intended application
has been demonstrated and documented.  This section does not list common laboratory
glassware (e.g., beakers and flasks) which nonetheless may be required to perform the method.

       6.1      Extraction vessels

               6.1.1       Twelve wide-mouth bottles (i.e., nine for test positions plus three for
       method blanks) constructed of inert material, resistant to high and low pHs and
       interaction with COPCs as described in the following sections.

                         6.1.1.1     For the evaluation of inorganic COPCs, bottles made of
               high density polyethylene (HOPE)  (e.g., Nalgene #3140-0250 or equivalent),
               polypropylene (PP), or polyvinyl chloride (PVC) are recommended.

                         6.1.1.2     For the evaluation of non-volatile organic and mixed
               organic/inorganic COPCs, bottles made of glass or Type 316 stainless steel are
               recommended. Polytetra-fluoroethylene (PTFE) is not recommended for non-
               volatile organics due to the sorption of species with high hydrophobicity (e.g.,
               PAHs). Borosilicate glass is recommended over other types of glass, especially
               when inorganic analytes are of concern.

               6.1.2       The extraction vessels must be of sufficient volume to
       accommodate both the solid sample  and an extractant volume, based on an L/S of 10 ±
       0.5 ml_ extractant/g-dry. The head space in the bottle should be minimized to the extent
       possible when semi-volatile organics are COPCs.  For example, Table 1 indicates that
       250-mL volume bottles are recommended when the minimum 20 g-dry mass equivalent
       is contacted with 200 mL of extractant.

               6.1.3       The vessel must have a leak-proof seals that can sustain end-over-
       end tumbling for the duration of the designated contact time.
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               6.1.4      If centrifugation is anticipated to be beneficial for initial phase
       separation, the extraction vessels should be capable of withstanding centrifugation at
       4000 ±100 rpm for a minimum of 10 ± 2 min. Alternately, samples may be extracted in
       bottles that do not meet this centrifugation specification (e.g., Nalgene l-Chem #311-
       0250 or equivalent) and the solid-liquid slurries transferred into appropriate
       centrifugation vessels for phase separation as needed.

       6.2      Balance — Capable of 0.01-g resolution for masses less than 500 g.

       6.3      Rotary tumbler — Capable of rotating the extraction vessels in an end-over-end
fashion at a constant speed of 28 ± 2 rpm (e.g., Environmental Express, Charlestown, SC or
equivalent).

NOTE: The holding capacity of tumblers may vary and modifications (e.g., packing or bottle-
       holding inserts) may be necessary to accommodate the extraction vessels.

       6.4      Filtration apparatus — Pressure or vacuum filtration apparatus composed of
appropriate materials so as to maximize the collection of extracts and minimize loss of the
COPCs (e.g., Nalgene #300-4000 or equivalent) (see Sec.  6.1).

       6.5      Filtration membranes — Composed of polypropylene or equivalent material with
an effective pore size of 0.45-um (e.g., Gelman Sciences GH  Polypro #66548 from Fisher
Scientific or equivalent).

       6.6      pH Meter — Laboratory model with the capability for temperature compensation
(e.g., Accumet 20, Fisher Scientific or equivalent) and a minimum resolution of 0.1 pH units.

       6.7      pH combination electrode — Composed of chemically-resistant materials.

       6.8      Conductivity meter — Laboratory model (e.g., Accumet 20,  Fisher Scientific or
equivalent), with a minimum resolution of 5% of the measured value.

       6.9      Conductivity electrodes — Composed of chemically-resistant materials.

       6.10     Adjustable-volume pipettor — Oxford Benchmate series or equivalent The
necessary delivery range will depend on the buffering capacity of the solid material and
acid/base strength used in the test.

       6.11     Disposable pipettor tips

       6.12     Centrifuge (recommended) — Capable of centrifuging the extraction vessels at
a rate of 4000 ± 100 rpm for 10 ± 2 min.
7.0    REAGENTS AND STANDARDS

       7.1      Reagent-grade chemicals must be used in all tests. Unless otherwise
indicated, it is intended that all reagents conform to the specifications of the Committee on
Analytical Reagents of the American Chemical Society, where such specification are available.
Other grades may be used, provided it is first ascertained that the reagents are of sufficiently
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high purity to permit use without lessening the accuracy of the determination. Inorganic
reagents and extracts should be stored in plastic to prevent interaction of constituents from
glass containers.

       7.2      Reagent water must be interference free.  All references to water in this method
refer to reagent water unless otherwise specified.

       7.3      Nitric acid (2.0 N), HNO3 - Trace-metal grade or better, purchased at strength
or prepared by diluting concentrated nitric acid with reagent water. Alternate normality solutions
may be used as necessary.  In such cases, the amounts of HNO3 solution added to samples
should be adjusted based on the equivalents required in the schedule of acid/base additions
(see Sec. 11.3).

       7.4      Potassium hydroxide (1.0 N),  KOH - ACS grade, purchased at strength or
prepared by diluting concentrated potassium hydroxide solution with reagent water, or otherwise
by dissolving 56.11 g of solid potassium hydroxide in 1 L of reagent water.  Alternate normality
solutions may be used as necessary.  In such cases, the amounts of KOH solution added to
samples should be adjusted based on the equivalents required in the schedule of acid/base
additions (see Sec. 11.3).

       7.5      Consult Methods  9040 and 9050 for additional information regarding the
preparation of reagents required for pH and specific conductance measurements.

8.0     SAMPLE COLLECTION, PRESERVATION, AND STORAGE

       8.1      See the introductory material to Chapter Three "Inorganic Analytes" and
Chapter Four "Organic Analytes."

       8.2      All solid samples  should be collected using an appropriate sampling plan.

       8.3      All containers should be composed of materials that minimize interaction with
COPCs. For further information, see Chapters Three and  Four.

       8.4      Preservatives should not be added to samples before extraction.

       8.5      Samples can be refrigerated, unless refrigeration results in an  irreversible
physical change to the sample.

       8.6      Analytical extracts or leachates should be preserved according to the guidance
given in the individual determinative methods for the COPCs.

       8.7      Extract holding times should be consistent with the holding times specified in
the  individual determinative methods for the COPCs.
9.0    QUALITY CONTROL

       9.1      Refer to Chapter One for guidance on quality assurance (QA) and quality
control (QC) protocols.  When inconsistencies exist between QC guidelines, method-specific
QC criteria take precedence over both technique-specific criteria and those criteria given in
Chapter One, and technique-specific QC criteria take precedence over the criteria in Chapter
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One. Any effort involving the collection of analytical data should include development of a
structured and systematic planning document, such as a Quality Assurance Project Plan
(QAPP) or a Sampling and Analysis Plan (SAP), which translates project objectives and
specifications into directions for those that will implement the project and assess the results.
Each laboratory should maintain a formal quality assurance program. The laboratory should
also maintain records to document the quality of the data generated. All data sheets and quality
control data should be maintained for reference or inspection.

       9.2     In order to demonstrate the purity of reagents and sample contact surfaces,
method blanks should be tested at the extremes of the acid and base additions, as well as when
only reagent water (no acid or base addition) is used for extraction.

       9.3     The analysis of extracts should follow appropriate QC procedures, as specified
in the determinative  methods for the COPCs.  Refer to Chapter One for specific quality  control
procedures.

       9.4     Unless the "as-received" samples  are part of a time-dependent (e.g., aging)
study, solid materials should be processed and tested within one month of their receipt.

     9.5  Initial demonstration of proficiency (IDP)

     Leachate methods are not amenable to typical initial demonstrations of proficiency as
reference materials with known values are  usually  not available.  However, prior to using this
method an analyst should have documented proficiency in the skills required for successful
implementation of the method.  For example, skill should be demonstrated in the use of an
analytical balance, the determination of pH using methods 9040 and 9045 and the
determination of conductance using method 9050.
10.0   CALIBRATION AND STANDARDIZATION

       10.1     The balance should be calibrated and certified at a minimum annually or in
accordance with laboratory policy.

       10.2     Prior to measurement of eluate pH, the pH meter should be calibrated using a
minimum of two standards that bracket the range of pH measurements. Refer to Methods 9040
and 9045 for additional guidance.

       10.3     Prior to measurement of eluate conductivity, the meter should be calibrated
using at least one standard at a value greater than the range of conductivity measurements.
Refer to Method 9050 for additional guidance.
11.0   PREPARATORY PROCEDURES

       A flowchart for the method procedure is presented in Figure 1.  Microsoft Excel data
templates are available to aid in collection and archiving of laboratory and analytical data.3
3 These Excel templates form the basis for uploading method data into the data management program, LeachXS
Lite™. Both the data templates and LeachXS Lite are available at http://vanderbilt.edu/leachinq.
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       11.1     Particle-size reduction (if required)

               11.1.1      In this method, particle-size reduction is used for sample
       homogenization and to prepare large-grained samples for extraction so that the
       approach toward liquid-solid equilibrium is enhanced and mass transport through large
       particles is minimized. A longer extract contact time is required for larger maximum
       particle-size designations.  This  method designates three maximum particle sizes and
       associated contact times (see Table 1). The selection of an appropriate maximum
       particle size from this table should be based on professional judgment regarding the
       practical effort required to size-reduce the solid material.

               11.1.2      Particle-size reduction of "as received" samples may be achieved
       through crushing, milling or grinding with equipment made from chemically-inert
       materials.  During the reduction  process, care should be taken to minimize the loss of
       sample and potentially volatile constituents in the sample.

       NOTE: Crushing of oversize material is preferred to milling or grinding as the later
              techniques may result in heating of the sample material.

               11.1.3      If the moisture content of the "as received" material is greater than
       15% (wet basis), air drying or desiccation may be necessary.  Oven drying is not
       recommended for the preparation of test samples due to the potential for mineral
       alteration and volatility loss.  In all cases, the moisture content of the "as received"
       material should be  recorded.

       NOTE: If the solid  material is susceptible to interaction with the atmosphere (e.g.,
              carbonation, oxidation),  drying should be conducted in an inert environment.

               11.1.4      When the material appears to be of a relatively uniform particle size,
       calculate the percentage less than the sieve size as follows:
                                % Passing = Msieved x 100%
                                            Mfotal
               Where: Msieved = mass of sample passing the sieve (g)
                      Mtotai = mass of total sample (g) (e.g., Msieved + mass not passing sieve)
               11.1.5     The fraction retained by the sieve should be recycled for further
       particle-size reduction until at least 85% of the initial mass has been reduced below the
       designated maximum particle size. Calculate and record the final percentage passing
       the sieve and the designated maximum particle size. For the uncrushable fraction of the
       "as received" material, record the fraction mass and nature (e.g., rock, metal or glass
       shards, etc).

               11.1.6     Store the size-reduced material in an airtight container in order to
       prevent contamination via gas exchange with the atmosphere. Store the container in a
       cool, dark and dry place prior to use.
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       11.2    Determination of solids and moisture content

               11.2.1      In order to provide the dry mass equivalent of the "as-tested"
       material, the solids content of the subject material should be determined.  Often, the
       moisture content of the solid sample is recorded.  In this method, the moisture content is
       determined and recorded on the basis of the "wet" or "as-tested" sample.

       WARNING:  The drying oven should be contained in a hood or otherwise properly
                   ventilated. Significant laboratory contamination or inhalation hazards may
                   result when drying heavily contaminated samples.  Consult the laboratory
                   safety officer for proper handling procedures prior to drying samples that
                   may contain volatile, hazardous, flammable  or explosive materials.

               11.2.2      Place a 5-10-g sample of solid material into a pre-tared dish or
       crucible.  Dry the sample to a constant mass at 105 ± 2 °C. Check for constant mass by
       returning  the dish to the drying oven for twenty four hours, cooling to room temperature
       in a desiccator and re-weighing. The two mass readings  should agree within the larger
       of 0.2% or 0.02 gram.

       NOTE: The oven-dried sample is not used for the extraction and should be properly
              disposed once the dry mass is determined.

               11.2.3      Calculate and report the  solids content as follows:
                                             M
                                              fest
               Where: SC = solids content (g-dry/g)
                      Mdry = mass of oven-dried sample (g-dry)
                      Mtest = mass of "as-tested" sample (g)

               11.2.4    Calculate and report the moisture content (wet basis) as follows:
                                           Mi i  — M i
                                   MP   -   test    drv
                                   IVIOwet -
                                              Mtest
               Where: MC(wet) = moisture content on a wet basis (gH2o/g)
                      Mdry = mass of oven-dried sample (g-dry)
                      Mtest = mass of "as-tested" sample (g)
       11.3    Pre-test titration (if required)

       In order to conduct the parallel batch test in Sec. 12.0, a schedule of acid and base
additions should be formulated from either a pre-test titration or based on prior knowledge of the
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acid/base titration curve of the sample. This section describes the procedure for obtaining a
titration curve of the test material, when sufficient prior knowledge is unavailable.

       If the schedule of acid and base additions will be generated from prior knowledge,
proceed to Sec.  11.4. If the schedule of acid and base additions is already known, proceed to
Sec. 12.0.

       Figures 2-4 show example titration curves for a wide variety of solid materials. Table 2
indicates how these materials may be classified as (a) low alkalinity; (b) moderate alkalinity; or
(c) high alkalinity in terms of the equivalents of acid required for obtaining final extraction pH
values in the range of 2-13.

                11.3.1      Predict the classification of the neutralization behavior of the solid
       material based on professional judgment, preliminary data, or the material examples
       shown  in Table 2 and Figures 2-4.

                11.3.2     Conduct a five-point parallel extraction test using 10-g-dry samples
       of the solid following the pre-test schedule shown in Table 3 for the chosen
       classification. Perform the extraction procedure in Sec. 12.0, omitting the filtration,
       method blanks, and analytical  sample collection.

                11.3.3     Plot the pre-test titration curve (e.g., the extract pH  as a function of
       the equivalents of acid added) considering base equivalents as the negative sign of acid
       equivalents.

                11.3.4     Reiterate the pre-test extraction, if necessary to expand or contract
       the pre-test titration until the 2-13 pH range can be resolved.

       NOTE: Additional pre-test point(s) interpolating or extrapolating from the pre-test
              schedule may be necessary to provide adequate resolution in the titration curve.

                11.3.5     Pre-test titration using provided Microsoft® Excel template

               The  "Pre-Test" worksheet in the accompanying  Excel template may be used to
       calculate pre-test extraction formulations and  plot the pre-test titration curve.  Mandatory
       input data for the template includes:

               a)  particle size of the  "as tested" material (see Sec. 11.1);
               b)  solids content of the "as tested"  material (see Sec. 11.2); and
               c) five acid/base additions based on the predicted response classification of the
                 solid  material  (see  Sec. 11.3).

       Enter the eluate  pH and plot the pre-test titration curve.  Compare the resulting titration
       curve to the target pH values as designated in Table 4.

       11.4    Formulation of acid and base additions schedule

       A schedule of acid  and base additions is used in the main extraction procedure (Sec.
12.0) to set up nine extractions of the  test material  plus three method blanks. Based on either
prior knowledge  of the acid/base titration curve of the sample or the results of the pre-test
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titration procedure in Sec. 11.3, formulate a schedule of test extractions using the example in
Table 4 and the following steps.

               11.4.1      Using the extraction parameters in Table 1, identify the
       recommended minimum dry-mass equivalent associated with the particle size of the "as-
       tested" sample. Calculate and record the amount of "as tested" material equivalent to
       the dry-material mass from Table 1 as follows:
                                       M
                                       lvl
                                         test   gc
               Where: Mtest = mass of "as-tested" solid equivalent to the dry-material mass (g)
                      Mdry = mass of dry material specified in the method (g-dry)
                      SC = solids content of "as-tested" material (g-dry/g)
               11.4.2     Label Column A of the schedule table with consecutive numbers for
       the nine test positions (shown in Table 4 as "TXX" labels) and three method blanks
       (shown in Table 4 as "BXX" labels).

               11.4.3     Select the nine target pH points as shown in Table 5 and enter this
       data into Column B of the schedule table. One of the nine target pH values should be
       with no acid or base addition in order to record the natural pH of the material. The target
       pH points shown in Table 5 allow for substitution of one optional target point if the
       natural pH of the solid material falls within the tolerance of another designated target pH.
       For example, if the natural pH is 11.8 and would satisfy the target pH  of 12.0 ± 0.5, the
       optional target point of 10.5 ± 0.5 should be included.
               11.4.4     For each test position, determine the equivalents of acid or base
       required to meet the target pH from the pre-test titration curve (see
       Sec. 11.3). Enter this data into Column C of the schedule table.  Interpolate
       intermediate acid additions on the pre-test titration curve using linear interpolation or
       other regression techniques.

       NOTE: Linear interpolation will have some inherent error, which  may result in an extract
              pH that falls outside of the target pH tolerance. Additional pre-test points
              interpolating or extrapolating from the pre-test schedule in Table 3 may be
              necessary to provide adequate resolution of the titration curve.

               11.4.5     Enter the acid volumes in Column  D and base volumes in Column E
       of the schedule after converting the equivalents of acid and base to volume as follows:
                                       va/b = -^
                                             Na/b
                                       A-12
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
               Where: Va/b = volume of acid or base to be entered in the schedule table (ml)
                      Eqa/b = equivalents of acid or base selected for the target pH as
                             determined from the pre-test titration curve (meq/g)
                      Na/b = normality of the acid or base solution (meq/mL)
               11.4.6     In Column F of the schedule table, calculate the volume of moisture
       contained in the "as tested" sample as follows:
                                          Mies. X(1-SC)
                                 "W.sample
                                                Pw
               Where: VWsampie = volume of water in the "as tested" sample (ml)
                      Mtest = mass of the "as tested" sample (g)
                      SC = solids content of the "as tested" sample (g-dry/g)
                      pw = density of water (1.0 g/mL at room temperature)
               11.4.7     In Column G of the schedule table, calculate the volume of reagent
       water required to bring each extraction to a US of 10 mL/g-dry solid as follows:
                              VRW = Mdry x LS - VWsamp,e - Va/b
               Where: VRW = volume of reagent water required to complete L/S (ml)
                      Mdry = dry mass equivalent of solid sample (g)
                      LS = liquid-to-dry-solid ratio (10 mL/g)
                      Vw.sampie = volume of water in "as used" sample (ml)
                      Va/b = volume of acid or base for the extraction recipe (ml)
               11.4.8     Method Blanks

               In the schedule table, include three additional extractions for processing
       method blanks. Method blanks extractions are performed using the same equipment,
       reagents, and extraction process as the test positions, but without solid sample. The
       three method blanks should include:

               a) reagent water (B01 in Table 4);
               b) reagent water + maximum volume of acid in the schedule (B02 in Table 4);
                 and
               c) reagent water + maximum volume of base in the schedule (603 in Table 4).

       NOTE: If multiple materials or replicate tests are carried out in parallel, only one set of
              method blanks is necessary.

               11.4.9     Schedule formulation using Excel template
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


               The "Test Data" worksheet in the provided Excel template may be used to
       automatically calculate a schedule of acid and base additions, as well as to plot the
       response eluate pH and conductivity as a function of acid addition. Mandatory input
       data for the template includes:

               a) particle size of the "as tested" material (see Sec.  11.1);
               b) solid content of the "as tested" material (see Sec. 11.2); and
               c) nine acid/base additions determined from the pre-test titration curve with
                 respect to target pH values designated in Table 5.

       Subsequent to the extraction procedure, eluate pH, conductivity, and oxidation/reduction
potential (optional) for up to three replicates may be entered and plotted as a function of acid
added.
12.0   EXTRACTION PROCEDURE

       Use the schedule of acid and base additions (Sec. 11.4) as a guide to set up nine test
extractions and three method blanks as follows:

       12.1     Label nine bottles with test position numbers and three bottles with method
blank labels according to the schedule of acid and base additions (see
Column A in Table 4).

       12.2     Use the extraction parameters in Table 1 to identify the recommended dry-
mass equivalent associated with the particle size of the "as tested" sample. Calculate and
record the amount of "as tested" material equivalent to the identified dry mass from Table 1 as
follows:
                                              SC
       Where: Mtest = mass of "as tested" solid equivalent to g of dry material (g)
              Mdry = mass of dry material specified in method (g)
              SC = solids content of "as tested" material (g/g)
       12.3    Place the dry equivalent mass (± 0.1 g) of the "as tested" sample, calculated
above, into each of the nine test position extraction vessels.

NOTE:  Do NOT put solid material in the method blank extraction vessels.

       12.4    Add the appropriate volume of reagent water (± 5% of target value) to both the
test position and method blank extraction vessels, as specified in the schedule for the L/S
makeup (see Column G in Table 4).

       12.5    Add the appropriate volume of acid or base (± 1 % of target value) to each
vessel, using a continuously adjustable pipettor, as designated in the schedule for acid/base
addition (see Column D and Column E in Table 4).
                                      A-14
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
       12.6    Tighten the leak-proof lid on each bottle and tumble all extraction vessels
(i.e., test positions and method blanks) in an end-over-end fashion at a speed of 28 ± 2
rpm at room temperature (20 ± 2 °C).  The contact time for this method will vary depending on
the sample particle size as shown in Table 1.

NOTE: The  length of the contact time is designed to enhance the approach toward liquid-solid
       equilibrium.  Longer contact times are required for larger particles to compensate for the
       effects of intra-particle diffusion.  See Table 1 for recommended contact times based on
       particle size.

       12.7    Remove the extraction vessels from the rotary tumbler and clarify the solutions
by allowing the bottles to stand for 15 ± 5 min. Alternately, centrifuge the extraction vessels at
4000 ± 100 rpm for 10 ± 2 min.

       12.8    For each extract vessel, decant a minimum volume (~ 5 ml_) of clear,
unpreserved supernatant into a clean container.

       12.9    Measure and record the pH, specific conductivity, and oxidation-reduction
potential (ORP) of the extracts (see Methods 9040, 9045, and 9050).

NOTE:  Measurement of pH, conductivity and ORP should be taken within 15 minutes of eluate
        processing (Sec. 12.8) to avoid neutralization of the  solution due to exposure to carbon
        dioxide, especially when alkaline materials are tested.

NOTE:  The measurement of ORP is optional, but strongly recommended, especially when
        testing materials where oxidation is likely to change  the LSP of COPCs.

       12.10  Separate the solid from the remaining liquid in each extraction vessel by
pressure or vacuum filtration through a clean 0.45-um pore size membrane (Sec. 6.5). The
filtration apparatus may be exchanged for a clean apparatus as often as necessary until all
liquid has been filtered.

NOTE: If COPCs which might be lost under vacuum (e.g., mercury) are suspected, the samples
       should be pressure-filtered using an inert gas (e.g., nitrogen or argon).

       12.11   Immediately, preserve and store the volume(s) of eluate required for chemical
analysis.  Preserve all analytical samples in a manner that is consistent with the determinative
chemical  analyses to be performed.
13.0   DATA ANALYSIS AND CALCULATIONS (EXCEL TEMPLATE)

       13.1     Data reporting

               13.1.1      Figure 5 shows an example of a data sheet that may be used to
       report the concentration results of this method. At a minimum, the basic test report
       should include:

               a) Name of the laboratory
               b) Laboratory technical contact information
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
               c) Date at the start of the test
               d) Name or code of the solid material
               e) Particle size (85 wt% less than)
               f) Type of acid and/or base used in test
               g) Extraction contact time (h)
               h) Ambient temperature during extraction (°C)
               i) Eluate specific information (see Sec. 13.1.2 below)

               13.1.2     The minimum set of data that should be reported for each eluate
       includes:

               a) Eluate sample ID
               b) Mass of "as tested" solid material used (g)
               c) Moisture  content of material used (gH2o/g)
               d) Volume (ml_) and normality (N) of acid and/or base used
               e) Volume of water added (ml_)
               f) Target pH
               g) Measured final eluate pH
               h) Measured eluate conductivity (mS/cm)
               I) Measured ORP (mV) (optional)
               j) Concentrations of all COPCs
               k) Analytical QC qualifiers as appropriate

       13.2     Data interpretation (optional)

               13.2.1     Acid/base neutralization curve

               Plot the pH  of each extract as a function of the equivalents of acid or base
       added per dry gram of material to generate an acid/base  neutralization curve.

       NOTE: For materials in which both acid and base were used, equivalents of base can
              be presented as the opposite sign of acid equivalents (i.e., 5 meq/g-dry of base
              would correspond to -5 meq/g-dry of acid).

               The titration curve can be interpreted  as showing the amount of acid or base
       that is needed to shift the pH of the subject material. This is helpful when evaluating
       field scenarios where the pH of leachates is not buffered  by the acidity or alkalinity of the
       solid  material.

               13.2.2      LSP curve

               An LSP curve can be generated for each COPC following chemical analyses of
       all extracts by plotting the target analyte concentration in  the liquid phase as a function
       of the measured extract pH for each extract. As an  example, Figure 6 illustrates the LSP
       curves for arsenic and selenium from a coal combustion fly ash and indicates the limits
       of quantitation and the natural concentration response.

                          13.2.2.1     The lower limit of quantitation (LLOQ) of the
               determinative method for each COPC may be shown as a horizontal line.
               COPC concentrations below this line  indicate negligible or non-quantitative
               concentrations.
                                      A-16
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
               NOTE: This method is for the generation of extract solution and does not
                      specify any particular analytical method. Since the lower limit of
                      quantitation is highly dependent on both chosen analytical method and
                      the solution matrix, it should be determined as part of an analytical
                      QA/QC plan.

                         13.2.2.2     Natural response is defined as the eluate pH and
               COPC concentration measured when the solid material is extracted with
               reagent water at an US of 10 mL/g-dry. The natural response values can be
               shown on the  LSP curve as a vertical line from the x-axis (at the replicate
               average natural pH) intersected with a horizontal line (at the replicate average
               COPC concentration).  Alternatively, the natural response can be indicated in
               results using a different symbol from other results.

                         13.2.2.3    The values on the curve indicate the eluate
               concentration  of the constituent of interest at an L/S of 10 mL/g-dry over a pH
               range. The shape of the LSP curve is indicative of the speciation of the COPC
               in the solid phase with four characteristic LSP curve shapes (i.e., relative
               locations of maxima and minima) presented schematically in Figure 7.

                         Cationic Species (e.g., Cd) — The LSP curve of cationic species
               typically has a maximum concentration in the acidic pH range that decreases to
               lower values at alkaline pH.

                         Amphoteric Species (e.g., Pb, Cr(lll), Cu.) — The LSP curves tend
               to be similar in shape to cationic LSP curves with greater concentrations in the
               acidic  pH range. However, the concentrations pass through a minimum in the
               near neutral to slightly acid pH range only to increase again for alkaline pH
               values. Typically, the increase at high pH is due to the solubility of hydroxide
               complexes (e.g., [Pb(OH3)]").

                         Oxyanionic Species (e.g.  [AsO4]~, [SeO4]", [MnO4]") — The LSP
               curves often show maxima in the neutral to slightly alkaline range.
               Highly Soluble Species (e.g., Na+, K+, CI") — The LSP curve is only a weak
               function of pH.

                         The idealized LSP curves in Figure 7 can be compared with the
               general shape of the test data to infer the speciation of the COPC in the solid
               matrix. Concentration results from this method may be simulated with
               geochemical speciation models to infer the mineral phases, adsorption
               reactions, and soluble complexes that control the release of the COPC (see
               Ref. 1).
14.0   METHOD PERFORMANCE

       14.1     Performance data and related information are provided in SW-846 methods
only as examples and guidance. The data do not represent required performance criteria for
users of the methods.  Instead, performance criteria should be developed on a project-specific
basis, and the laboratory should establish in-house QC performance criteria for the application
                                      A-17
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


of this method. These performance data are not intended to be and must not be used as
absolute QC acceptance criteria for purposes of laboratory accreditation.

       14.2    Interlaboratory validation of this method was conducted using a coal
combustion fly ash (material code EaFA), a contaminated smelter site soil (material code CFS)
and a solidified waste analog (material code SWA). The median values and inner quartile
ranges (IQRs) for repeatability and reproducibility were determined  for eluate concentration
results  across all study materials  and pH target values (see Table 3).  More details on the
interlaboratory validation may be  found in Ref. 7.

       14.3    Refs. 2 and 3 may provide additional guidance and insight on the use,
performance and application of this method.
15.0   POLLUTION PREVENTION

       15.1    Pollution prevention encompasses any technique that reduces or eliminates the
quantity and/or toxicity of waste at the point of generation. Numerous opportunities for pollution
prevention exist in laboratory operations. The EPA has established a preferred hierarchy of
environmental management techniques that places pollution prevention as the management
option of first choice.  Whenever feasible, laboratory  personnel should use pollution prevention
techniques to address their waste generation. When wastes cannot be feasibly reduced at the
source, the Agency recommends recycling as the next best option.

          15.2   For information about pollution prevention that may be applicable to
laboratories and research institutions consult Less is Better: Laboratory Chemical Management
for Waste Reduction available from the American Chemical Society's Department of
Government Relations and  Science Policy, 1155 16th St., N.W. Washington, D.C. 20036,
http://portal.acs.org/portal/fileFetch/C/WPCP_012290/pdf/WPCP_012290.pdf.
16.0   WASTE MANAGEMENT

       The Environmental Protection Agency requires that laboratory waste management
practices be conducted consistent with all applicable rules and regulations.  The Agency urges
laboratories to protect the air, water, and land by minimizing and controlling all releases from
hoods and bench operations, complying with the letter and spirit of any sewer discharge permits
and regulations, and by complying with all solid and hazardous waste regulations, particularly
the hazardous waste identification rules and land disposal restrictions.  For further information
on waste management, consult The Waste  Management Manual for Laboratory Personnel
available from the American Chemical Society at the address listed in Sec. 14.2.
17.0   REFERENCES

1.      H. A. van der Sloot, P.F.A.B. Seignette, J.C.L. Meeussen, O. Hjelmar and D.S. Kosson,
       (2008), "A Database, Speciation Modeling and Decision Support Tool for Soil, Sludge,
       Sediments, Wastes and Construction Products: LeachXS™- ORCHESTRA," in Venice
       2008:  Second International Symposium on Energy from Biomass and Waste, Venice,
       Italy, 17-20 November 2008 (also see www.leaching.com).
                                     A-18
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


2.      D.S. Kosson, H.A. van der Sloot, F. Sanchez and A.C. Garrabrants (2002) "An
       Integrated Framework for Evaluating Leaching in Waste Management and Utilization of
       Secondary Materials," Environmental  Engineering Science, 19(3) 159-204.

3.      A.C. Garrabrants, D.S. Kosson, H.A. van der Sloot,  F. Sanchez and O. Hjelmar (2010)
       "Background Information for the Leaching Environmental Assessment Framework
       (LEAF) Test Methods," EPA/600/R-10-170, U.S. Environmental Protection Agency,
       Washington, DC, December 2010.

4.      F. Sanchez,  R. Keeney, D.S. Kosson  and R. DeLapp (2006) "Characterization of
       Mercury-Enriched Coal Combustion Residues from  Electric Utilities Using Enhanced
       Sorbents for Mercury Control," EPA-600/R-06/008, U.S. Environmental Protection
       Agency, Washington DC, February 2006.

5.      F. Sanchez,  D.S. Kosson, R. Keeney, R. DeLapp, L. Turner and P. Kariher (2008)
       "Characterization of Coal Combustion Residues from Electric Utilities Using Wet
       Scrubbers for Multi-Pollutant Control," EPA-600/R-08/077, U.S. Environmental
       Protection Agency, Washington DC, July 2008.

6.      D.S. Kosson, F. Sanchez, P. Kariher,  L.H.  Turner, R. DeLapp and P. Seignette (2009)
       "Characterization of Coal Combustion Residues from Electric Utilities - Leaching and
       Characterization Data," EPA-600/R-09/151, U.S. Environmental Protection Agency,
       Washington  DC, December 2009.

7.      A.C. Garrabrants, D.S. Kosson, L.  Stefanski, R.  DeLapp, P.F.A.B. Seignette, H.A. van
       der Sloot, P. Kariher,  and M. Baldwin  (2012) "Interlaboratory Validation of the Leaching
       Environmental Assessment (LEAF) Method 1313 and Method  1316," DRAFT, U.S.
       Environmental Protection Agency,  Washington DC,  April 2012.

8.      CEN/TS 14429 (2005) Characterization of Waste -  Leaching Behaviour Tests -
       Influence of pH on Leaching with Initial Acid/base Addition, Comite Europeen de
       Normalisation, Brussels,  Belgium.

9.      CEN/TS 14429 (2005) Characterization of Waste -  Leaching Behaviour Tests -
       Influence of pH on Leaching with Continuous pH Control, Comite  Europeen de
       Normalisation, Brussels,  Belgium.
18.0  TABLES, DIAGRAMS, FLOWCHARTS, AND VALIDATION DATA

      The following pages contain the tables and figures referenced by this method.
                                     A-19
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


                                     TABLE 1

       EXTRACTION PARAMETERS AS FUNCTION OF MAXIMUM PARTICLE SIZE
Particle Size
(85 wt% less than)
(mm)
0.3
2.0
5.0
US Sieve
Size
50
10
4
Minimum Dry
Mass
(g-dry)
20 ± 0.02
40 ± 0.02
80 ± 0.02
Contact Time
(h)
24 ±2
48 ±2
72 ±2
Suggested
Vessel Size
(mL)
250
500
1000
                                     TABLE 2

                   MATERIAL NEUTRALIZATION CLASSIFICATIONS
Neutralization
Classification
Low Alkalinity
Material Types
soils; sediments; CCR fly ash; CCR bottom ash; coal milling rejects;
MSWI fly ash, MSWI bottom ash; sewage sludge amended soil
 Moderate Alkalinity      soils; wood preserving waste; MSWI bottom ash; steel slag; electric
                       arc furnace dust; MSW compost; nickel sludge; Portland cement
                       mortar
 High Alkalinity
Portland cement clinker; steel blast furnace slag, solidified waste
(fly ash, blastfurnace slag, Portland cement)
   NOTE: CCR = Coal combustion residue
         MSWI = Municipal solid waste incinerator
                                    A-20
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


                                        TABLE 3

                 PRE-TEST TITRATION: ACID EQUIVALENT SCHEDULE
Neutralization
Classification
Low Alkalinity
Moderate Alkalinity
High Alkalinity
Equivalents of Acid (meq/g-dry)
Bottle 1
-2.0
-2.0
0
Bottle 2
-1.0
0
5.0
Bottle 3
0
2.0
10.0
Bottle 4
1.0
5.0
15.0
Bottle 5
2.0
10.0
25.0
   NOTE:  1) Base additions shown as opposite sign of acid equivalents.
          2) Additional pre-test point(s) interpolating or extrapolating from the pre-test schedule
            may be necessary to provide adequate resolution in the titration curve.
                                        TABLE 4

                 EXAMPLE SCHEDULE OF ACID AND BASE ADDITIONS
A
Test
position
T01
T02
T03
T04
T05
T06
T07
T08
T09
B01
B02
603
B
Target
extract
PH
13.0
12.0
10.5
9.0
8.0
Natural
5.5
4.0
2.0
QA/QC
QA/QC
QA/QC
C
Equivalents
of Acid
(meq/g-dry)
-1.10
-0.75
-0.38
-0.15
-0.05
0
0.12
0.90
3.10
0
3.10
-1.10
D
Volume of
2N HNO3
(ml_)
-
-
-
-
-
-
1.20
9.00
31.0
-
31.0
-
E
Volume of
1N KOH
(ml_)
22.0
15.0
7.60
3.0
1.0
-
-
-
-
-
-
22.0
F
Volume of
moisture in
sample
(mL)
2.22
2.22
2.22
2.22
2.22
2.22
2.22
2.22
2.22
-
-
-
G
Volume of
reagent water
(mL)
176
183
190
195
197
198
197
189
167
200
169
178
   NOTE:  1) This schedule is based on "as tested" sample mass of 22.2±0.1 g (i.e., equivalent
            "as tested" mass for a 20.0 g-dry sample at a solids content of 0.90 g-dry/g).
          2) In this example, the natural pH is assumed to be 7.0±0.5.
          3) Test positions marked B01, B02, and BOS are method blanks of reagent water,
            reagent water + maximum acid addition, and reagent water + maximum base
            addition, respectively.

Data modified from Ref. 2.
                                      A-21
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316






                                   TABLE 5




                          FINAL EXTRACT PH TARGETS
pH Target
?
2.0±0.5
4.0±0.5
5.5±0.5
7.0±0.5
8.0±0.5
9.0±0.5
12.0±0.5
13.0±0.5
10.5±0.5
Rationale
Natural pH at L/S 10 mL/g-dry (no acid/base addition)
Provides estimates of total or available COPC content
Lower pH limit of typical management scenario
Typical lower range of industrial waste landfills
Neutral pH region; high release of oxyanions
Endpoint pH of carbonated alkaline materials
Minimum of LSP curve for many cationic and amphoteric COPCs
Maximum in alkaline range for LSP curves of amphoteric COPCs
Upper bound (field conditions) for amphoteric COPCs
Substitution if natural pH falls within range of a mandatory target
                                    TABLE 6




              MEDIAN METHOD PRECISION ACROSS STUDY MATERIALS
                                    Repeatability
Reproducibility
Analyte
Antimony
Arsenic
Barium
Boron
Calcium
Molybdenum
Selenium
Vanadium
Symbol
Sb
As
Ba
B
Ca
Mo
Se
V
Median of Medians
Median
%RSDr
16%
19%
10%
7%
5%
15%
9%
10%
10%
IQR
%RSDr
12-25%
13-24%
7-15%
5-9%
4-11%
6-23%
6-13%
6-12%
4-25%
Median
%RSDR
33%
47%
22%
12%
9%
30%
21%
27%
26%
IQR
% RSDR
24-45%
37-61%
18-36%
8-21%
6-28%
18-46%
18-31%
23-41%
6-61%
        Data taken from Ref. 7.
                                  A-22
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


                                             FIGURE 1

                                     METHOD FLOWCHART
                              Is mate rial at
                              appropriate
                              particle size?
                        Solids/Moisture Content
                             (Section 11.2)
                          Acid/Base Addition
                         Schedule [Section 11.3)
                         Extraction Procedure
                             (Section 11,2)

                            Acid/Base Addition
                            Leach ate pH, EC, Eh
Particle Size Reduction
    (Section 11.1)
                                                              Pre-TestTitration
                                                               (Section 11.3.
           it rat ion
           11.3.1)
                          Documentation
                           and Graphi
                                            A-23
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                  FIGURE 2

                     EXAMPLE TITRATION CURVES FOR SELECTED "LOW ALKALINITY" WASTES
t** -
12 -
A f\ .
ID
I
Q.
3 8"
4 -
2 -
0_

<


3
k

1
2
I 1
1 1
i
A LJX |
A S
A T^ O
A TE] B i A
A ^O •
Al^s CB| n m
A A • A
A H
I I
I I
i
101.



I 2
                                                 Acid Added [meq/g-dry]
            Q Wood Preserving Soil
            • HarborSediment2
            A Coal Fly Ash
nsoil
QHarborSedimentS
A Coal Milling Rejects
DZincSoil
o MSWI Bottom Ash
A Coal Bottom Ash
0 Sewage Amended Soil
« MSWI Bottom Ash 2
A Coal Fly Ash
                                   Some data taken LeachXS database (Ref. 1).
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
     LU
           14
           12  --
           10  -•
            8  -•
            6  --
            4  -'
            2  -•
                                                  FIGURES

                  EXAMPLE TITRATION CURVES FOR SELECTED "MODERATE ALKALINITY" WASTES

                                    I
                                o
s
                                                 0
                                                00
                              00
                        -2
               • Wood Preserving Soil
               »MSW Com post
               o Steel Slag
             Acid Added [meq/g-dry]
            DHarborSedimentS
            OMSWI Bottom Ash 3
            • Arc Furnace Dust (K061)
                                             8
                                                        I
                                                          0
            10
0 MSW Sewage Sludge 2
O Dried Nickel Sludge
• Cement Mortar
12
                                 Some data taken from LeachXS database (Ref. 1).
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
             -5
                                                  FIGURE 4
                     EXAMPLE TITRATION CURVES FOR SELECTED "HIGH ALKALINITY" WASTES
It -
12 -
in r
1 U
I
Q. p .
O
"ro
LU c
LJ.J (-,
J '
n .






i n
A
1

•
4


[
A j

»
•
°00c

:
n D
L A
A

3


n
A
A






i
A
n
y







                 10
15
20
25
                ABIastFurnaceSlag2
              Acid Added [meq/g-dry]
      n Portland CementClinker      • Solidified Waste Simulant
Some data taken from LeachXS database (Ref. 1).
30
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                       FIGURES

                          EXAMPLE DATA REPORT FORMAT
ABC Laboratories
123 Main Street
Anytown, USA
 Contact: John Smith
         (555) 111-1111
EPA METHOD 1313
Report of Analysis
                             Client Contact: Susan Jones
                                         (555) 222-2222

Material Code: XYZ


Material Type: Coal Combustion Fly Ash



Test
Position
T01

















Test
Position
T02

















Date Received: 10/1/20xx
Test Date: 11/1/20xx
Report Date: 12/1/20xx

Replicate
A
Eluate Sample ID
Solid Material
Moisture Content
Water Added
Acid Added
Acid Strength
Base Added
Base Strength
Target pH
Eluate pH
Eluate Conductivity
Eluate ORP

Chemical Analysis
Al
As
Cl

Replicate
A
Eluate Sample ID
Solid Material
Moisture Content
Water Added
Acid Added
Acid Strength
Base Added
Base Strength
Target pH
Eluate pH
Eluate Conductivity
Eluate ORP

Chemical Analysis
Al
As
Cl





Value





Units

Particle Size:
Contact Time:
Lab Temperature:
Acid Used:
Base Used:

Method

88% passing 2-mm sieve
48 hours
21 ±2°C
Nitric acid
Sodium hydroxide

Note








XYZ-1313-T01-A
40.0
0.01
386.0
14.0
2.0
-
1.0
2.0 ±0.5
1.89
12.6
203

Value
216.0
0.64
<4.13

Value

g
g
gH2o/g
mL
mL
N
mL
-
-
mS/c
mv

Units
mg/L
mg/L
mg/L

Units









EPA 9040
EPA 9050

QC
Flag Method
EPA 6020
EPA 6020
U EPA 9056

Method













Date
11/7/20xx
11/7/20xx
11/9/20xx

Note












Dilution
Factor
1000
10
1



XYZ-1313-T02-A
40.0
0.01
400.0
14.0
2.0
-
1.0
4.0 ±0.5
3.86
0.99
180

Value
449.0
0.979
<4.13

g
g
gH2o/g
mL
mL
N
mL
-
-
mS/c
mv

Units
mg/L
mg/L
mg/L









EPA 9040
EPA 9050

QC
Flag Method
EPA 6020
EPA 6020
U EPA 9056









Natural pH



Date
11/7/20xx
11/7/20xx
11/7/20xx












Dilution
Factor
1000
10
1

            QC Flag Key:   U    Value below lower limit of quantitation as reported (< "LLOQ")
                                          A-27
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 Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                    FIGURE 6

 EXAMPLE LSP CURVES FROM A COAL COMBUSTION FLY ASH SHOWING ASSESSMENT
                        ZONES FOR A LANDFILL SCENARIO

_
=^r
CD
JL
<

IUUUU
1000-
100
MCL10-

48
1 -
0.1 -
0.01 -
Onm
.UU I
.. Ml

: 0
n
M
:
I 4


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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                  FIGURE?


              SCHEMATIC LSP CURVES OF CATIONIC, AMPHOTERIC,

                          AND OXYANIONIC SPECIES
og scale
           c
           o
           '-p
           ro
           +J


           §
           c
           o
           O
                0
4      6     8      10

      Leachate  pH
12     14
                            Figure taken from Ref. 2.
                                 A-29
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                             Appendix B.     Method 1313
                                        B-i
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


                                 DRAFT METHOD 13161

  LIQUID-SOLID PARTITIONING AS A FUNCTION OF LIQUID-TO-SOLID RATIO IN SOLID
                 MATERIALS USING A PARALLEL BATCH PROCEDURE
       SW-846 is not intended to be an analytical training manual. Therefore, method
procedures are written based on the assumption that they will be performed by analysts who are
formally trained in at least the basic principles of chemical analysis and in the use of the subject
technology.

       In addition, SW-846 methods, with the exception of required method use for the analysis
of method-defined parameters, are intended to be guidance methods which contain general
information on how to perform an analytical procedure or technique which a laboratory can use
as a basic starting point for generating its own detailed Standard Operating Procedure (SOP),
either for its own general use or for a specific project application.  The performance data
included in this method are for guidance purposes only, and are not intended to be and must not
be used as absolute QC acceptance criteria for purposes of laboratory quality control  or
accreditation.
1.0    SCOPE AND APPLICATION

       1.1      This method is designed to provide the liquid-solid partitioning (LSP) of
inorganic constituents (e.g., metals, radionuclides) and non-volatile organic constituents (e.g.,
polycyclic aromatic hydrocarbons (PAHs), dissolved organic carbon) at the natural pH of the
solid material as a function of liquid-to-solid ratio (US) under conditions that approach liquid-
solid chemical equilibrium. Table 1 shows the range of target L/S values tested under this
method.

       1.2      The eluate concentrations at a low L/S provide insight into pore solution
composition either in a granular bed (e.g., soil column) or in the pore space of low-permeability
material (e.g., solidified monolithic or compacted granular fill).  In addition, analysis of eluates
for dissolved organic carbon and of the solid phase for total organic carbon allow for evaluation
of the impact of organic carbon release and the influence of dissolved organic carbon on the
LSP of inorganic constituents.

       1.3      This method is intended to be used as part of environmental leaching
assessment for the evaluation of disposal, beneficial use, treatment effectiveness and site
remediation. The method is not required by federal regulations to determine whether waste
passes or fails the toxicity characteristic as defined at 40 CFR 261.24.

       1.4      This method is suitable to a wide range of solid materials.  Example solid
materials include industrial wastes, soils, sludges, combustion residues, sediments, stabilized
materials, construction materials,  and mining wastes.
1 This method has been derived from the SR003 procedure (Ref. 1) using EPA reviewed and accepted
methodologies (see Refs. 3-5). The method is analogous to batch L/S-dependence method EN12457 (Ref. 7)
developed for the Comite Europeen de Normalisation (CEN).
                                       B-l
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


       1.5      This method is a leaching characterization method used to provide intrinsic
material parameters that control leaching of inorganic species under equilibrium conditions.
This test method is intended as a means for obtaining an extract (i.e., the eluate) of a solid
material which may be used to estimate the solubility and release of inorganic constituents
under the laboratory conditions described in this method.  Extract concentrations may be used
in conjunction with information regarding environmental management scenarios to estimate
anticipated leaching concentrations, and release rate and extent for individual material
constituents in the management scenarios evaluated.  Extract concentrations may also be used
along with geochemical speciation modeling to infer the mineral phases that control the LSP in
the pore structure of the solid material.

       1.6      This method is not applicable to characterize the release of volatile organic
analytes.

       1.7      This method provides solutions that are considered to be indicative of leachate
under field conditions only where the field leaching pH  and US ranges are encompassed by the
laboratory extract final conditions and the LSP is controlled by aqueous-phase saturation of the
constituent of interest. When LSP is controlled by the amount of the constituent present in the
solid that may dissolve (i.e., for highly soluble species), the mass released (mg/kg), rather than
the concentration, is indicative of field conditions.

       1.8      The solvent used in this method is reagent water

       1.9      Analysts are advised to take reasonable measures to ensure that the sample is
homogenized to the extent practical prior to employment of this method.  Particle-size reduction
may provide additional assurance of sample homogenization. Table 2 designates a minimum
dry equivalent mass of sample to be added to each extraction vessel and the associated
extraction contact time as a function  maximum particle diameter.  If the heterogeneity of the
sample is suspected as the cause  of unacceptable levels of precision in replicate test results or
is considered significant based on  professional judgment, the sample mass used in the test
procedure may be increased to a greater minimum dry equivalent mass than shown in Table 1
with the amount of extractant increased proportionately to maintain the designated US.

       1.10    In the preparation  of solid materials for use in this method, particle-size
reduction of samples with large grain size is  used to enhance the approach towards liquid-solid
equilibrium under the designated contact time interval of the extract process. The extract
contact time for samples reduced to a finer maximum particle size will be shorter.

       1.11     Prior to employing this method, analysts are advised to consult the base
method for each type of procedure that may be employed in the overall analysis (e.g., Methods
9040, 9045), quality control (QC) acceptance criteria, calculations, and general guidance.
Analysts also should consult the disclaimer statement at the front of the manual  and the
information in Chapter Two for guidance on the intended flexibility in the  choice of methods,
apparatus, materials, reagents, and supplies, and on the responsibilities  of the analyst for
demonstrating that the techniques  employed are appropriate for the analytes of interest, in the
matrix of interest,  and at the levels of concern.

       In addition, analysts and data users are advised that, except where explicitly specified in
a regulation, the use of SW-846 methods is not mandatory in response to Federal testing
requirements.  The information contained in this method is provided by EPA as guidance to be
                                       B-2
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


used by the analyst and the regulated community in making judgments necessary to generate
results that meet the data quality objectives for the intended application.
       1.12    Use of this method is restricted to use by, or under supervision of, properly
experienced and trained personnel.  Each analyst must demonstrate the ability to generate
acceptable results with this method as described in Section 9.5.


2.0    SUMMARY OF METHOD

       This method consists of five parallel extractions of a particle-size  reduced solid material
in reagent water over a range of L/S values from 0.5 to 10 mL eluent/g dry material (see Table
1).  In addition to the five test extractions, a method blank without solid sample is carried
through the procedure in order to verify that analyte interferences are not introduced as a
consequence of reagent impurities or equipment contamination (If multiple materials or replicate
tests are carried out in parallel, only one set of method blanks is necessary).  In total, six bottles
(i.e., five test positions and one method blank) are tumbled in an  end-over-end fashion for a
specified contact time based on the maximum particle size of the solid (see Table 2). At the end
of the contact interval, the liquid and solid phases are roughly separated  via settling or
centrifugation.  Extract pH and specific conductance measurements are then taken on an
aliquot of the liquid phase.  The bulk of the  eluate is clarified by pressure or vacuum filtration in
preparation for constituent analysis.  Analytical aliquots of the extracts are collected and
preserved accordingly based on the determinative methods to be performed. The eluate
constituent concentrations are plotted as a  function of L/S and compared to QC and
assessment limits.
3.0    DEFINITIONS

       3.1      Release — The dissolution or partitioning of a constituent of potential concern
(COPC) from the solid phase to the aqueous phase during laboratory testing (or under field
conditions).  In this method, mass release is expressed in units of mg COPC/kg dry solid
material.

       3.2      Constituent of potential concern (COPC) — A chemical species of interest,
which may or may not be regulated, but may be characteristic of release-controlling properties
of the sample geochemistry.

       3.3      Liquid-solid partitioning (LSP)  — The distribution of COPCs between the solid
and liquid phases at the conclusion of the extraction.

       3.4      Liquid-to-solid ratio (L/S) — the fraction of the total liquid volume (including the
moisture contained in the "as used" solid sample) to the dry mass equivalent of the solid
material. L/S is typically expressed in volume  units of liquid per dry mass of solid material
(mL/g-dry).

       3.5      "As-tested" sample — The solid sample at the conditions (e.g., moisture content
and particle-size distribution) present at the time of the start of the test procedure.  The "as-
tested" conditions will differ from the "as-received" sample conditions if particle-size reduction
and drying were necessarily performed.
                                       B-3
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


       3.6      Dry-mass equivalent — The mass of "as-tested" (i.e., "wet") sample that
equates to the mass of dry solids plus associated  moisture, based on the moisture content of
the "as-tested" material. The dry-mass  equivalent is typically expressed in mass units of the
"as-tested" sample (g).

       3.7      Refer to Chapter One and equipment manufacturers' instructions for definitions
that may be relevant to this procedure.


4.0    INTERFERENCES

       4.1      Solvents, reagents, glassware, and other sample processing hardware may
yield artifacts and/or interferences to sample analysis. All of these materials must be
demonstrated to be free from interferences under the conditions of the analysis by analyzing
method blanks.  Specific selection of reagents and purification of solvents by distillation in all-
glass systems may be necessary.  Refer to each method to be used for specific guidance on
quality control procedures and  to Chapters Three  and Four for general guidance on the cleaning
of laboratory apparatus prior to use.


       5.0      SAFETY

       5.1      This method does not address all safety issues associated with its use. The
laboratory is responsible for maintaining a safe work environment and a current awareness file
of OSHA regulations regarding the safe handling of the chemicals listed in this method. A
reference file of material safety data sheets (MSDSs) should be available to all personnel
involved in these analyses.
6.0    EQUIPMENT AND SUPPLIES

       The mention of trade names or commercial products in this manual is for illustrative
purposes only, and does not constitute an EPA endorsement or exclusive recommendation for
use. The products and instrument settings cited in SW-846 methods represent those products
and setting used during the method development or subsequently evaluated by the Agency.
Glassware, reagents, supplies, equipment, and setting other than those listed in this  manual
may be employed provided that method performance appropriate for the intended application
has been demonstrated and documented.

This section does  not list common laboratory glassware (e.g., beakers and flasks).

       6.1      Extraction vessels

               6.1.1      Six wide-mouth bottles (i.e., five for test positions plus one for a
       method blank) constructed of an inert material resistant to high and low pH  conditions or
       interaction with the constituents of interest.

                         6.1.1.1     For the evaluation of inorganic COPCs, bottles
               composed of high density polyethylene (HOPE) (e.g., Nalgene #3140-0250 or
               equivalent), polypropylene (PP), or polyvinyl chloride (PVC) are recommended.
                                      B-4
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


                         6.1.1.2      For the evaluation of non-volatile organic and mixed
               organic/inorganic COPCs, equipment composed of glass or Type 316 stainless
               steel is recommended.  PTFE is not recommended for non-volatile organics,
               due sorption of species with high hydrophobicity (e.g., PAHs). Borosilicate
               glass is recommended over other types of glass, especially when inorganic
               analytes are of concern.

               6.1.2.     The extraction vessels must be of sufficient volume to
       accommodate both the solid sample and an extractant volume based on the schedule of
       L/S values shown in Table 1. For example, a 500-mL bottle is recommended when 100
       g dry equivalent mass is contacted with 200 ml_ of eluent (see T03 in Table 1).

               6.1.3      The vessels must have a leak-proof seals that can sustain end-over-
       end tumbling for the duration of the designated contact time.

               6.1.4      If centrifugation is anticipated to be beneficial for initial phase
       separation, the extraction vessels should be capable of withstanding centrifugation at
       4000 ±100 rpm for a minimum of 10 ± 2 min. Alternately, samples may be extracted in
       bottles that do not meet this  centrifugation specification (e.g., Nalgene l-Chem #311-
       0250 or equivalent) and the solid-liquid slurries transferred into appropriate
       centrifugation vessels for phase separation as needed.

       6.2     Balance — Capable of 0.01-g resolution for masses less than 500 g.

       6.3     Rotary tumbler — Capable of rotating the extraction vessels in an end-over-end
fashion at a constant speed of 28 ±  2 rpm (e.g., Environmental Express, Charlestown, SC or
equivalent).

NOTE: The  holding capacity of tumblers may vary and modifications (e.g., packing or bottle-
        holding inserts) may be necessary to accommodate the extraction vessels.

       6.4     Filtration apparatus — Pressure or vacuum filtration apparatus composed of
appropriate materials so as to maximize the collection of extracts and minimize loss of the
COPCs (e.g., Nalgene #300-4000 or equivalent) (see Sec. 6.1).

       6.5     Filtration membranes — Composed of polypropylene or equivalent material with
an effective pore size of 0.45-um (e.g., Gelman Sciences GH Polypro #66548 from Fisher
Scientific or equivalent).

       6.6     pH Meter — Laboratory model with the capability for temperature compensation
(e.g., Accumet 20, Fisher Scientific or  equivalent) and a  minimum resolution of 0.1 pH units.

       6.7     pH combination electrode — Composed of chemically-resistant materials.

       6.8     Conductivity meter — Laboratory model (e.g., Accumet 20, Fisher Scientific or
equivalent), with a minimum resolution of 5% of the measured value.

       6.9     Conductivity electrodes — Composed of chemically-resistant materials.
                                      B-5
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


       6.10     Adjustable-volume pipettor — Oxford Benchmate series or equivalent The
necessary delivery range will depend on the buffering capacity of the solid material and
acid/base strength used in the test.

       6.11     Disposable pipettor tips.

       6.12     Centrifuge (recommended) — Capable of centrifuging the extraction vessels at
a rate of 4000 ± 100 rpm for 10 ± 2 min.
7.0    REAGENTS AND STANDARDS

       7.1      Reagent-grade chemicals must be used in all tests.  Unless otherwise
indicated, it is intended that all reagents conform to the specifications of the Committee on
Analytical Reagents of the American Chemical Society, where such specification are available.
Other grades may be used, provided it is first ascertained that the reagents are of sufficiently
high purity to permit use without lessening the accuracy of the determination.  Inorganic
reagents and extracts should be stored in plastic to prevent interaction of constituents from
glass containers.

       7.2      Reagent water must be interference free. All references to water in this method
refer to reagent water unless otherwise specified.

       7.3      Consult Methods 9040 and 9050 for additional information regarding the
preparation of reagents required for pH and specific conductance measurements.
8.0    SAMPLE COLLECTION, PRESERVATION, AND STORAGE

       8.1      See the introductory material to Chapter Three "Inorganic Analytes" and
Chapter Four "Organic Analytes."

       8.2      All solid samples should be collected using an appropriate sampling plan.

       8.3      All containers should be composed of materials that minimize interaction with
solution COPCs. For further information, see Chapters Three and Four.

       8.4      Preservatives should not be added to samples before extraction.

       8.5      Samples can be refrigerated, unless refrigeration results in an irreversible
physical change to the sample.

       8.6      Analytical extracts or leachates should be preserved according to the guidance
given in the individual determinative methods for the COPCs.

       8.7      Extract holding times should be consistent with the holding times specified in
the individual determinative methods for the COPCs.
                                      B-6
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


9.0    QUALITY CONTROL

       9.1      Refer to Chapter One for guidance on quality assurance (QA) and quality
control (QC) protocols.  When inconsistencies exist between QC guidelines, method-specific
QC criteria take precedence over both technique-specific criteria and those criteria given in
Chapter One, and technique-specific QC criteria take precedence over the criteria in Chapter
One.  Any effort involving the collection  of analytical data should include development of a
structured and systematic planning document, such as a Quality Assurance Project Plan
(QAPP) or a Sampling and Analysis Plan (SAP), which translates project objectives and
specifications into directions for those that will implement the project and assess the results.
Each  laboratory should maintain a formal quality assurance program.  The laboratory should
also maintain records to document the quality of the data generated. All data sheets and quality
control data should be maintained for reference or inspection.

       9.2      In order to demonstrate the purity of reagents and sample contact surfaces, a
method blank (e.g., a bottle without solid material but with eluent carried through the extraction,
filtration and analytical sample preparation process) should be tested.

       9.3      The analysis of extracts should follow appropriate QC procedures, as specified
in the determinative methods for the COPCs.  Refer to Chapter One for specific quality control
procedures.

       9.4      Solid materials should be tested within one month of receipt unless the project
requires that the "as-received" samples are tested sooner (e.g., the material is part of a time-
dependent study or the material may change during storage due to oxidation or carbonation).

       9.5      Initial demonstration of proficiency (IDP)

     Leachate methods are not amenable to typical initial demonstrations of proficiency as
reference materials with known values are usually not available. However,  prior to using this
method an analyst should have documented proficiency in the skills required for successful
implementation of the method.  For example, skill should be demonstrated in the use of an
analytical balance, the determination of pH using methods 9040 and 9045 and the
determination of conductance using method 9050.
10.0   CALIBRATION AND STANDARDIZATION

       10.1     The balance should be calibrated and certified at a minimum annually or in
accordance with laboratory policy.

       10.2     Prior to measurement of eluate pH, the pH meter should be calibrated using a
minimum of two standards that bracket the range of pH measurements. Refer to Methods 9040
and 9045 for additional guidance.

       10.3     Prior to measurement of eluate conductivity, the meter should be calibrated
using at least one standard at a value greater than the range of conductivity measurements.
Refer to Method 9050 for additional guidance.
                                      B-7
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


11.0   PREPARATORY PROCEDURES

       A flowchart of the method is presented in Figure 1.  Microsoft Excel data templates are
available to aid in collection and archiving of laboratory and analytical data.2
       11.1    Particle-size reduction (if required)

               11.1.1      In this method, particle-size reduction is used to prepare large-
       grained samples for extraction so that the approach toward liquid-solid equilibrium is
       enhanced and mass transport through large particles is minimized.  A longer extract
       contact time is required for larger maximum particle-size designations. This method
       designates three maximum particle sizes and associated contact times (see Table 2).
       The selection of an appropriate maximum particle size from this table should be based
       on professional judgment regarding the practical effort required to size reduce the solid
       material.

               11.1.2     Particle-size reduction of "as received" sample  may be achieved
       through crushing, milling or grinding with equipment made from chemically inert
       materials. During the reduction process, care should be taken to minimize loss of
       sample and potentially volatile constituents in the sample.

       NOTE: Crushing of oversize material is preferred to milling or grinding as the later
              techniques may result in  heating of the sample material.

               11.1.3     If the moisture content of the "as-received" material is greater than
       15% (wet basis), air drying or desiccation may be necessary. Oven drying is not
       recommended for preparation of  test samples due to the potential for mineral alteration.
       In all cases, the moisture content of the "as received" material should be recorded.

       NOTE: If the solid material is susceptible to interaction with the atmosphere (e.g.,
              carbonation, oxidation), drying should be conducted in an inert environment.

               11.1.4     When the material  seems to be of a relatively uniform particle size,
       calculate the percentage less than the sieve size as follows:
                                           M •   ^
                                Passing  =   sieved   x  100  %
                                            M total
               Where: Msieved = mass of sample passing the sieve (g)
                      Mtotai = mass of total sample (g) (e.g., Msieved + mass not passing sieve)
               11.1.5     The fraction retained by the sieve should be recycled for further
       particle-size reduction until at least 85% of the initial mass has been reduced below the
       designated maximum particle size. Calculate and record the final percentage passing
2 These Excel templates form the basis for uploading method data into the data management program, LeachXS
Lite™. Both the data templates and LeachXS Lite are available at http://vanderbilt.edu/leachinq.
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
       the sieve and the designated maximum particle size.  For the uncrushable fraction of the
       "as received" material, record the fraction mass and nature (e.g., rock, metal or glass
       shards, etc).

               11.1.6     Store the size-reduced material in an airtight container in order to
       prevent contamination via gas exchange with the atmosphere.  Store the container in a
       cool, dark and dry place prior to use.
       11.2    Determination of solids and moisture content

               11.2.1     In order to provide the dry mass equivalent of the "as-tested"
       material, the solids content of the subject material should be determined. Often, the
       moisture content of the solid sample is recorded.  In this method, the moisture content is
       determined and recorded on the basis of the "wet" or  "as-tested" sample.

       WARNING:  The drying oven should be contained in a hood or otherwise properly
                   ventilated. Significant laboratory contamination or inhalation hazards may
                   result when drying heavily contaminated samples. Consult the laboratory
                   safety officer for proper handling procedures prior to drying samples that
                   may contain volatile, hazardous, flammable or explosive materials.

               11.2.2     Place a 5-10-g sample of solid material into a pre-tared dish or
       crucible.  Dry the sample to a constant mass at 105 ± 2 °C.  Check for constant mass by
       returning  the dish to the drying oven for twenty four hours, cooling to room temperature
       in a desiccator and re-weighing. The two mass readings should agree within the larger
       of 0.2% or 0.02 gram.

       NOTE: The oven-dried sample is not used for the extraction and should be properly
              disposed of once the dry mass is determined.

               11.2.3     Calculate and report the solids content as follows:
                                       SC =
                                            M
                                              'dry
                                            Mfest
               Where: SC = solids content (g-dry/g)
                      Mdry = mass of oven-dried sample (g-dry)
                      Mtest = mass of "as-tested" sample (g)

               11.2.4    Calculate and report the moisture content (wet basis) as follows:
                                         _ M.es. - Mdry
                                     'wet ~    .
                                              IVltest
                                       B-9
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
               Where: MC(wet) = moisture content on a wet basis (gH2o/g)
                      Mdry = mass of oven-dried sample (g-dry)
                      Mtest = mass of "as-tested" sample (g)
       11.3    Extraction setup schedule (Microsoft® Excel template provided)

               An Excel template accompanies this method and may be used to set up the
       extraction schedule.  If using the provided template, disregard Sec. 11.3 and proceed to
       the extraction procedure Sec. 11.4.

               11.3.1      Using the schedule shown in Table 1 as a guide, set  up five test
       extractions and one method blank. The mass of solids in an extraction may be scaled to
       minimize headspace in each extraction vessel. However, the volume of eluent should
       always be based on the target US in Column B of Table 1.

               11.3.2     Calculate and record the amount of "as-tested" material equivalent
       to the dry mass in Column D of Table 1 as follows:
                                       M
                                         test   gc
               Where: Mtest = mass of "as-tested" solid equivalent to the dry-material mass (g)
                      Mdry = mass of dry material specified in the method (g-dry)
                      SC = solids content of "as-tested" material (g-dry/g)
               11.3.3     Calculate and record the volume of moisture contained in the "as-
       tested" sample in Column E of Table 1 as follows:
                                          Mies. X(1-SC)
                                 "W.sample
                                                P\N
               Where: VWsampie = volume of water in the "as tested" sample (ml)
                      Mtest = mass of the "as tested" sample (g)
                      SC = solids content of the "as tested" sample (g-dry/g)
                      pw = density of water (1.0 g/mL at room temperature)
               11.3.4     Calculate and record the volume of reagent water required to bring
       each extraction to the target US in Column F of Table 1 as follows:
                                VRW  = Mdry X LS - VWsamp,e
                                       B-10
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
               Where:  VRW = volume of reagent water required to complete L/S (ml)
                      Mdry = dry mass equivalent of solid sample (g)
                      LS = liquid-to-dry-solid ratio (10 mL/g)
                             = volume of water in "as used" sample (ml)
               The size of the extraction bottle should be sufficient to contain the combined
       volume of solid material and eluent, ideally with a minimum amount of headspace.


12.0   EXTRACTION PROCEDURE

       12.1     Label five bottles with test position numbers and an additional bottle as a
method blank according to Column A in Table 1.

       12.2     Place the dry-mass equivalent (± 0.1 g) of "as-tested" sample as shown in
Column D in Table 1 into each of the five test position extraction vessels.

NOTE: Do not put solid material in the method blank extraction vessel

       12.3     Add the appropriate volume ( ± 0.5 ml_) of reagent water to both the test
position and method blank extraction vessels as specified in Column F of Table 1.

       12.4     Tighten the leak-proof lid on  each bottle and tumble all extractions (i.e., test
positions and method blanks) in an end-over-end fashion at a speed of 28 ± 2 rpm at room
temperature (20 ± 2 °C).  The contact  time for this method will vary  depending on the maximum
particle size  as shown in Table 2.

NOTE: The  length of the contact time is designed to enhance the approach toward liquid-solid
       equilibrium. Longer contact times are required for larger particles to compensate for the
       effects of intra-particle diffusion. See Table 2 for required contact times based on the
       maximum particle size.

       12.5     Remove the extraction vessels from the rotary tumbler and clarify the extracts
by allowing the bottles to stand for 15  ± 5 min.  Alternately,  centrifuge the extraction vessels at
4000 ± 100 rpm for 10 ± 2 min.

NOTE: If clarification is significantly incomplete after settling or centrifugation, eluate
       measurements for pH,  conductivity, and oxidization-reduction potential (ORP) may be
       taken on filtered samples.  In this case, perform the filtration in 12.7 prior to eluate
       measurement in 12.6 and note the deviation from the written procedure.

CAUTION: Following separation from the solid phase, eluate samples lack the buffering
           provided by the solid phase and therefore may  be susceptible to pH change
           resulting from interaction with air.

       12.6     For each extraction vessel, decant a minimum volume (~ 5 mL) of clear,
unpreserved supernatant into a clean  container.

       12.7     Measure and record the pH,  specific conductivity, and oxidation-reduction
potential  (ORP) of the extracts (see Methods 9040, 9045, and 9050).
                                      B-ll
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
NOTE:  Measurement of pH, conductivity and ORP should be taken within 15 minutes of eluate
        processing (Sec. 12.8) to avoid neutralization of the solution due to exposure to carbon
        dioxide, especially when alkaline materials are tested.

NOTE:  The measurement of ORP is optional, but strongly recommended, especially when
        testing materials where oxidation is likely to change the LSP of COPCs.

       12.8     Separate the solid from the remaining liquid in each extraction vessel by
pressure or vacuum filtration through a clean 0.45-um pore size membrane (Sec. 6.5). The
filtration apparatus may be exchanged for a clean apparatus as often as necessary until all
liquid has been filtered.

       12.8     Immediately, preserve and store the volume(s) of eluate required for chemical
analysis. Preserve all analytical samples in a manner that is consistent with the determinative
chemical analyses to be performed.
13.0   DATA ANALYSIS AND CALCULATIONS (EXCEL TEMPLATE PROVIDED)

       13.1     Data reporting

               13.1.1      Figure 2 shows an example of a data sheet that may be used to
       report the concentration results of this method. This example is included in the Excel
       template. At a minimum, the basic test report should include:

               a) Name of the laboratory
               b) Laboratory contact information
               c)  Date at the start of the test
               d) Name or code of the solid material
               e) Particle size (85 wt% less than)
               f) Ambient temperature during extraction (°C)
               g) Extraction contact time (h)
               h) Eluate specific information (see Sec. 13.1.2 below)

               13.1.2      The minimum set of data that should be reported for each eluate
       includes:

               a) Eluate sample ID
               b) Target L/S (mL/g-dry)
               c)  Mass of "as tested" solid material used (g)
               d) Moisture content of material used (gH2o/g)
               e) Volume of eluent used (mL)
               f) Measured final eluate pH
               g) Measured eluate conductivity (mS/cm)
               h) Measured ORP (mV) (optional)
               i) Concentrations of all COPCs
               j) Analytical QC qualifiers as appropriate

       13.2     Data interpretation and presentation (optional)
                                     B-12
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
               13.2.1     LSP curve

                         13.2.1.1    A constituent LSP curve can be generated for each
               COPC after chemical analysis of all extracts by plotting the constituent
               concentration in the liquid phase as a function of L/S used for each extraction.
               The curve indicates the equilibrium concentration of the COPC as a function of
               L/S at the natural pH.

                         13.2.1.2    The lower limit of quantitation (LLOQ) for the analytical
               technique for each COPC may be shown as a horizontal line. COPC
               concentrations below this line  indicate negligible or non-quantitative
               concentrations.

               NOTE:  The LLOQ is highly matrix dependent and should be determined as
                      part of a QA/QC plan.

                         13.2.1.3    Figure 3 provides example LSP curves as a function of
               L/S for a coal combustion fly ash and a coal combustion flue gas desulfurization
               filter cake.
14.0   METHOD PERFORMANCE

       14.1     Performance data and related information are provided in SW-846 methods
only as examples and guidance. The data do not represent required performance criteria for
users of the methods.  Instead,  performance criteria should be developed on a project-specific
basis, and the laboratory should establish in-house QC performance criteria for the application
of this method. These performance data are not intended to be and must not be used as
absolute QC acceptance criteria for purposes of laboratory accreditation.

       14.2     Interlaboratory validation of this method was conducted using a coal
combustion fly ash (material code EaFA), a contaminated smelter site soil (material code CFS)
and a solidified waste analog (material code SWA).  The median values and inner quartile
ranges (IQRs) for repeatability and reproducibility were determined for eluate concentration
results across all study materials and pH target values (see Table 3). More details on the
interlaboratory validation may be found in Ref. 6.

       14.3     Refs. 1 and 2 may provide additional guidance and insight on the use,
performance and application of  this method.
15.0   POLLUTION PREVENTION

       15.1     Pollution prevention encompasses any technique that reduces or eliminates the
quantity and/or toxicity of waste at the point of generation.  Numerous opportunities for pollution
prevention exist in laboratory operations. The EPA has established a preferred hierarchy of
environmental management techniques that places pollution prevention as the management
option of first choice.  Whenever feasible, laboratory personnel should use pollution prevention
techniques to address their waste generation. When wastes cannot be feasibly reduced at the
source, the Agency recommends recycling as the next best option.
                                      B-13
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


       15.2    For information about pollution prevention that may be applicable to
laboratories and research institutions consult Less is Better: Laboratory Chemical Management
for Waste Reduction available from the American Chemical Society's Department of
Government Relations and Science Policy, 1155 16th St., N.W. Washington, D.C. 20036,
http://portal.acs.org/portal/fileFetch/C/WPCP_012290/pdf/WPCP_012290.pdf.


16.0   WASTE MANAGEMENT

       The Environmental Protection Agency requires that laboratory waste management
practices be conducted consistent with all applicable rules and regulations.  The Agency urges
laboratories to protect the air, water, and land by minimizing and controlling all releases from
hoods and bench operations, complying with the letter and spirit of any sewer discharge permits
and regulations, and by complying with all solid and hazardous waste regulations, particularly
the hazardous waste identification rules and land disposal restrictions. For further information
on waste management, consult The Waste Management Manual for Laboratory Personnel
available from the American Chemical Society at the address listed in Sec. 15.2.


17.0   REFERENCES

1.      D.S. Kosson, H.A. van der Sloot, F. Sanchez and A.C. Garrabrants (2002) "An
       Integrated Framework for Evaluating Leaching in Waste Management and Utilization of
       Secondary Materials," Environmental Engineering Science, 19(3) 159-204.

2.      A.C. Garrabrants, D.S. Kosson, H.A. van der Sloot, F. Sanchez and O. Hjelmar (2010)
       "Background Information for the Leaching Environmental Assessment Framework
       (LEAF) Test Methods," EPA/600/R-10-170, U.S. Environmental Protection Agency,
       Washington, DC, December 2010.

3.      F. Sanchez,  R. Keeney, D.S. Kosson and R. DeLapp (2006) "Characterization of
       Mercury-Enriched Coal Combustion Residues from Electric Utilities Using  Enhanced
       Sorbents for Mercury Control," EPA-600/R-06/008, U.S. Environmental Protection
       Agency, Washington DC,  February 2006.

4.      F. Sanchez,  D.S. Kosson, R. Keeney, R. DeLapp, L. Turner and P. Kariher (2008)
       "Characterization of Coal Combustion Residues from Electric Utilities Using Wet
       Scrubbers for Multi-Pollutant Control," EPA-600/R-08/077, U.S. Environmental
       Protection Agency, Washington DC, July 2008.

5.      D.S. Kosson, F. Sanchez, P. Kariher, L.H. Turner, R. DeLapp and P. Seignette (2009)
       "Characterization of Coal Combustion Residues from Electric Utilities - Leaching and
       Characterization Data," EPA-600/R-09/151, U.S. Environmental Protection Agency,
       Washington  DC, December 2009.

6.      A.C. Garrabrants, D.S. Kosson, L. Stefanski, R. DeLapp, P.F.A.B. Seignette, H.A. van
       der Sloot, P. Kariher, and M. Baldwin (2012) "Interlaboratory Validation of the Leaching
       Environmental Assessment (LEAF) Method 1313 and Method 1316," DRAFT, U.S.
       Environmental Protection Agency, Washington DC, April  2012.
                                     B-14
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


7.     EN12457 (2001) Characterization of Waste - Leaching - Compliance Test for Leaching
      of Granular Waste Materials and Sludges, Comite Europeen de Normalisation, Brussels,
      Belgium.


18.0  TABLES, DIAGRAMS, FLOWCHARTS, AND VALIDATION DATA

      The following pages contain the tables and figures referenced by this method
                                    B-15
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316


                                     TABLE 1

                   EXAMPLE SCHEDULE FOR EXTRACTION SETUP
A
Test
Position
T01
T02
T03
T04
T05
BOS
Total
B
Target
LS
10.0
5.0
2.0
1.0
0.5
QC

C
Minimum Dry
Mass
(g-dry)
20
40
100
200
400
-
-
D
Mass of
"As-Tested"
Sample
(g)
22.2
44.4
111.1
222.2
444.4

844.4
E
Moisture in
"As-Tested"
Sample
(mL)
2.2
4.4
11.1
22.2
44.4


F
Volume of
Reagent
Water
(mL)
198
196
189
178
156
200
1120
G
Recommended
Bottle Size
(mL)
250
250
500
500
1000
250

     NOTE: 1) This schedule assumes a target liquid volume of 200 mL.
           2) This schedule is based on "as tested" solids content of 0.90 g-dry/g.
           3) Test position marked B01  is a method blank of reagent water.

     Table data modified from Ref. 1.
                                     TABLE 2

       EXTRACTION PARAMETERS AS FUNCTION OF MAXIMUM PARTICLE SIZE
Particle Size
(85% less than)
(mm)
0.3
2.0
5.0
US Sieve
Size

50
10
4
Minimum
Dry Mass
(g-dry)
20 ±0.05
40 ±0.1
80 ±0.1

Contact Time
(h)
24 ±2
48 ±2
72 ±2
Recommended
Vessel size
(mL)
250
500
1000
                                    B-16
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                  TABLE 3
          MEDIAN METHOD PRECISION ACROSS STUDY MATERIALS
                                   Repeatability
Reproducibility
Analyte
Antimony
Arsenic
Barium
Boron
Calcium
Molybdenum
Selenium
Vanadium
Symbol
Sb
As
Ba
B
Ca
Mo
Se
V
Median of Medians
Median
%RSDr
12%
15%
7%
7%
6%
7%
8%
6%
7%
IQR
%RSDr
8-13%
12-28%
5-9%
5-10%
3-7%
6-9%
4-9%
4-12%
3-28%
Median
%RSDR
21%
31%
16%
13%
8%
18%
20%
16%
17%
IQR
% RSDR
17-27%
23-34%
13-30%
9-34%
7-19%
11-31%
13-24%
13-26%
7-34%
        Data taken from Ref. 6.
                                 B-17
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                       FIGURE 1

                                 METHOD FLOWCHART
<                     Material of     ^s^
                       Interest       ^r
                      Is mate rial at
                      appropriate
                      particle size?
                      yes
Particle Size Reduction
    {Section 11.1)
                                  Solids/Moisture Content
                                        (Section 11.2)
                                      LS Ratio Schedule
                                       (Section 11.3)
                                    Extraction Procedure
                                         (Section 12)

                                        Extraction Setup
                                      Leachate pH, EC, Eh
                                     Sample Preservation
                                      Extract Analysis
                                 Documentation and
                                      Graphing
                                       B-18
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                           FIGURE 2

                            EXAMPLE DATA REPORTING SHEET
     ABC Laboratories
      123 Main Street
       Anytown, USA
     Contact: John Smith
           (555) 111-1111
       EPA METHOD 1316
       Report of Analysis
                                    Client Contact: Susan Jones
                                                (555) 222-2222

Material Code: FAX


Material Type: Coal Combustion Fly Ash



Test
Position
T01













Test
Position
T02













Date Received: 10/1/20xx
Test Start Date: 11/1/20xx
Report Date: 12/1/20xx

Replicate
A
Eluate Sample ID
Solid Material
Moisture Content
Water Added
Target L/S
Eluate pH
Eluate Conductivity
Eluate ORP

Chemical Analysis
Al
As
Cl

Replicate
A
Eluate Sample ID
Solid Material
Moisture Content
Water Added
Target L/S
Eluate pH
Eluate Conductivity
Eluate ORP

Chemical Analysis
Al
As
Cl





Value





Units

Particle Size:
Contact Time:
Lab Temperature:
Eluent Used:


Method

88% passing 2-mm sieve
860 g
21 ±2°C
ASTM Type II Water


Note








XYZ-1316-T01-A
40.0
0.01
386.0
10.0
1.89
12.6
203

Value
216.0
7.64
<4.13

Value

g
gH2o/g
2mL
mL/g-dry
-
mS/cm
mv

Units
mg/L
mg/L
mg/L

Units





EPA 9040
EPA 9050

QC
Flag Method
EPA 6020
EPA 6020
U EPA 9056

Method









Date
11/7/20xx
11/7/20xx
11/9/20xx

Note








Dilution
Factor
1000
10
1



XYZ-1316-T02-A
20.0
0.01
400.0
5.0
3.86
0.99
180

Value
449.0
97.9
<4.13

g
gH2o/g
mL
mL/g-
d_
mS/cm
mv

Units
mg/L
mg/L
mg/L





EPA 9040
EPA 9050

QC
Flag Method
EPA 6020
EPA 6020
U EPA 9056









Date
11/7/20xx
11/7/20xx
11/7/20xx








Dilution
Factor
1000
10
1

            QC Flag Key:    U
Value below lower limit of quantitation as reported (< "LLOQ")
                                          B-19
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                   FIGURES



   EXAMPLE CONCENTRATON RESULTS FROM A COAL COMBUSTION FLY ASH AND

                    FLUE-GAS DESULFURIZATION FILTER CAKE
     I
     Q.
     LU
\l. '
11 '
10 •
9 -

•

7 .
•1 •














.•• *





, , ,
* FGD Filter Cake
• Fly Ash
,,,.,,,,,,,
iuu -
10 •
1 -
. I
0.001 -
0.0001 -
nnnm
" • •
1 1
[jj
; * •

! ML!

ri-ou riiLKi i^dne
• Fly Ash



1

i MDL
1 1

1 i



    a)
2468    10

 LS Ratio [mUg-dry]
                                         b)
                                 2    4    6    8    10

                                  LS Ratio [mUg-dry]
IUUU •
100 -
10 -
t 1
E ni
3 U.I
'o
™ n ni -
0.001 •
•I 1
1
!
!
1 ML
; r/oi
1




|

















• FGD Filler Cake
• Fly Ash


Iiuuuu -
1000 -
100 -
i 10-
£
1 0.1 -
ttl
•§ 0.01 -
o_
n nni -
n nnni .
'
;••.
I «


, ML
h raor


•
s








II
( i


• -GJ Filter Cake
• Fly Ash

	 L 	
1
• i i 1 1 1 1 1 1 i . . 1 1 1 1 1 1
,(J(JU 1 u.uuu i •
02468 10 02468 10
c) LS Ratio [mL/g-dry] d) LS Ratio [mL/g-dry]
1UUU
100 -
0)
a in
•— ' 1U
E
2
0.1 -



: •
,-f
:ML

; MtJL









.U I
024
• FGDFilterCake
• Fly Ash






n





i
IUUUU
!1000 -
5"
05 inn -
i, ' '
| 10 •
"5
eo -\ .
01 .

• .
: * T

ML

•



MDL







I

• FGD Filter Cake
• Fly Ash

U.U 1 :
68 10 02468 10
    e)
LS Ratio [mL/g-dry]
                        t)
LS Ratio [mUg-dry]
                                  B-20
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                    Appendix C.     Quality Assurance Project Plan
                                         C-i
-------
v°/EPA
QAPP for the EPA Interlaboratory
Validation Study of Proposed
SW846 Leaching Methods

Quality Assurance Project Plan
Category III / Technology Development
Draft

Contract No. EP-C-09-027
Work Assignment No. 2-7

November 2011
                                                                 C-l
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        Interlaboratorv Validation of LEAF Method 1313 and Method 1316
                                               10/25/2011
 Peter Kari her
 ARCAD!SU.S.,lnc
 Work Assignment Leader
                                                     Date
QAPP for the EPA Interlaboratory
Validation Study of Proposed SW846
Leaching Methods
Quality Assurance Project Plan
Category III /Technology Development
Final
                                               10/25/2011
Libby
ARCADIS UX Inc.
Quality Assurance Officer
                                                     Date
Susan Thorneloe
U.S. Environmental Protection Agency
Work Assignment Manac
                                                 11/22/11
                                                     Date
RicharcTShores
U.S. Environmental Protection Agency
Chief, Emissions Characterization & PpeventionJBranch
                                                     Date
Robert Bright
U.S. Environmental Protection AgetfCy
Quality Assurance Representative
                                                     Date
Prepared for.
Susan Thorneloe
U.S. Environmental Protection Agency
National Risk Management Research Laboratory
Air Pollution Prevention and Control Division
Atmospheric Protection Branch
Research Triangle Partt, NC 27711

Prepared by:
ARCADIS U.S., Inc.
4915 Prospectus Drive
Suite F
Durham
North Carolina 27713
Tel 919 544 4535
Fax 919 544 5690

Our Ref.:
RN990272.0007

Dale:
November 2011
                                                                                                            C-2
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                                                                                    Project No.: RN990272.0007
                                                                                    Revision: 0
                                                                                    Date: November 2011
                                                                                    Page: i
Appendices                                                                                       ii

List of Figures                                                                                    iii

List of Acronyms and Abbreviations                                                              iii

Distribution List                                                                                  vi

1.  Project Objectives and Organization                                                            1
      1.1    Purpose                                                                                1
      1.2    Project Objectives                                                                        2

2.  Project Organization                                                                           4

3.  Experimental Approach                                                                        9
      3.1    Task I: Preparing Homogenized CCR                                                       11
      3.2    Task II: Leaching of the CCR by Reference Laboratory and the Intercomparison Laboratories         14
      3.3    Task III: Determination of the Reproducibility of Each Method                                    16
      3.4    Task IV: Testing of Select Materials for Leaching by SW-846 Methods 1311 (TCLP) and 1312
            (SPLP)                                                                                16
      3.5    Task V: Testing of Fly Ashes and Cement Kiln Dust for Radionuclide Testing by Germanium
            Detector                                                                               17

4.  Sampling Procedures                                                                         18
      4.1    Sample Custody Procedures                                                              18
      4.2    CCR, and Leaching Reference Material Samples                                              19
            4.2.1   Physical and Chemical Characterization Samples                                      19
            4.2.2   Leaching Study Samples                                                           20
      4.3    Leachate Collection                                                                      20

5.  Testing and Measurement Protocols to be Used for Reference Material Characterization
    and Eluate Characterization                                                                   23
      5.1    Physical Characterization                                                                 23
            5.1.1   pH and Conductivity                                                              23
                                                                                                 C-3
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Interlaboratorv Validation of LEAF Method 1313 and Method 1316
                                                                                    Project No.: RN990272.0007
                                                                                    Revision: 0
                                                                                    Date: November 2011
                                                                                    Page: ii
            5.1.2   Moisture Content and Loss on Ignition (LOI)                                           23
      5.2    Chemical Characterization                                                                24
            5.2.1   Dissolved Organic Carbon / Dissolved Inorganic Carbon (DOC/DIC) and Elemental
                   Carbon / Organic Carbon (EC/OC)                                                  24
            5.2.2   Mercury by Thermal Decomposition and Cold Vapor Atomic Adsorption (TD-CVAA)
                   Method 7473                                                                    25
            5.2.3   Other Metals (ICP)                                                               25
            5.2.4   X-Ray Fluorescence (XRF)                                                         29
            5.2.5   XRF Detection Limits                                                             30
            5.2.6   Radionuclide Testing of CCRs using Ge-Detector                                      32

6.  Quality Assurance/Quality Control                                                            34
      6.1    Data Quality Indicator Goals                                                               34
      6.2    QC Sample Types                                                                       35

7.  Data Reduction, Validation, and Reporting                                                     36
      7.1    Data Analysis                                                                          36
      7.2    Chemical (ICP, XRF, AE-OES, OC/EC) and Physical (Moisture) Characterization                   41
      7.3    Radionuclide Characterization                                                             42

8.  Assessments                                                                                 44

9.  References                                                                                   46
Appendices
Appendix A    Participating Laboratories
Appendix B    Example Method Template Spreadsheet
Appendix C    Documentation Sent to Each Participating Laboratory
                                                                                                 C-4
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                                                                                    Project No.: RN990272.0007
                                                                                    Revision: 0
                                                                                    Date: November 2011
                                                                                    Page:  iii
List of Tables
Table 3-1.   MDLs and RLs of the Metals to be Evaluated during the Validation Study                           12
Table 3-2.   Characterization Testing to Establish Homogeneity of the CCR                                   13
Table 3-3.   Tentative Schedule for Interlaboratory Validation of Pre Method 1313 and Pre Method 1316            16
Table 4-1.   Final Extract pH Targets                                                                   20
Table 4-2.   Example Schedule for Extraction Setup                                                       21
Table 5-1.   MDL and MLQ of Total Organic Carbon Analyzer                                               24
Table 5-2.   Method Detection Limits (MDLs) and Minimum Level of Quantification (ML) for ICP-OES Analysis
           on Liquid Samples*                                                                       28
Table 5-3.   XRF Reporting and Detection Limits                                                          31
Table 6-1.   Data Quality Indicator Goals                                                                34
Table 8-1.   PEA Parameters and Ranges                                                               44
List of Figures
Figure 2-1.  Project Organizational Chart


List of Acronyms and Abbreviations
AA         atomic adsorption
ANOVA     analysis of variance
APPCD     Air Pollution Prevention and Control Division
ARCADIS   ARCADIS, U.S.,  Inc.
CCR(s)     coal combustion  residue(s)
CCV        continuing calibration verification
COPC(s)    constituents) of potential concern
CVAA      cold vapor atomic adsorption
DIG        dissolved inorganic carbon
DOC        dissolved organic carbon
                                                                                                 C-5
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                                                                                Project No.: RN990272.0007
                                                                                Revision: 0
                                                                                Date: November 2011
                                                                                Page: iv
DQI        data quality indicator
EC        elemental carbon
EPA       U.S. Environmental Protection Agency
FGD       flue-gas desulfurization
FWHM     full width at half maximum
g          gram
HPGe      high purity germanium
1C         inorganic carbon
ICP        inductively couple plasma
ICV        initial calibration verification
LOI        loss on ignition
MDA       minimum detectable activity
MDL       method detection limit
ml        milliliter
ML        minimum level of quantification
MLQ       minimum level of quantification
MS        mass-spectrometry
NA        not applicable
NCSU      North Carolina State University
NIST       National Institute of Science and Technology
NPOC      non-purgeable organic carbon
OC        organic carbon
OES       optical emission spectroscopy
ORCR      Office of Resource Conservation and Recovery
ORD       Office of Research and Development
OSR       Office of Solid Waste
QAPP      quality assurance project plan
RL        reporting limit
RPD       relative percent difference
RSD       relative standard deviation
SPLP      synthetic precipitation leaching procedure
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SW-846    EPA Test Methods for Evaluating Solid Waste, Physical/Chemical Methods
TCLP      toxicity characteristic leaching procedure
TD        thermal decomposition
ISA       technical system audit
XRF       X-ray fluorescence spectrometry
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Distribution List

Copies of this plan and all revisions will be initially sent to the following individuals. It is the responsibility of
the U.S. Environmental Protection Agency (EPA) Work Assignment Manager and of the ARCADIS, U.S.,
Inc. (ARCADIS) Work Assignment Leader to make copies of the plan available to all field personnel.

Susan Thorneloe, EPA Work Assignment Manager. Office of Research and Development, National Risk
Management Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park,
NC.

Phone:(919)541-2709
Email: thorneloe.susan@epa.gov

Robert Wright, EPA Quality Assurance Officer. Office of Research and Development, National Risk
Management Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park,
NC.

Phone:(919)541-4502
Email: wright.bob@epa.gov

Peter Kariher, ARCADIS Work Assignment Leader. Research Triangle Park, NC.

Phone:(919)541-5740
Email: peter.kariher@arcadis-us.com

Libby Nessley, ARCADIS Quality Assurance Officer. Durham, NC.

Phone: (919) 544-4535 x258
Email: libby.nesslev@arcadis-us.com

Dr. David Kosson, Methods Development. Vanderbilt University, Nashville, TN.

Phone:(615)322-1064
Email: David.Kosson@vanderbilt.edu
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Dr. Florence Sanchez, Methods Development. Vanderbilt University, Nashville, TN.

Phone:(615)322-5135
E-mail: Florence.Sanchez@vanderbilt.edu

Dr. Andrew Garrabrants, Methods Development. Vanderbilt University, Nashville, TN.

Phone:(615)322-7226
Email: Andrew.Garrabrants@vanderbilt.edu

Dr. Hans van der Sloot, Methods Development. Hans van der Sloot Consultancy, The Netherlands.

Phone:+31 (0)226-341607
Email: hans@vanderslootconsultancy.nl

Dr. Leonard A Stefanski, Statistical Consultant. North Carolina State University, Raleigh, NC.

Phone:(919)515-1945
Email: stefanski@stat.ncsu.edu
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1.  Project Objectives and Organization

1.1    Purpose

The Air Pollution Prevention and Control Division (APPCD) of EPA's Office of Research and Development
(ORD) is conducting research to evaluate potential leaching and cross media transfers of mercury and other
constituents of potential concern (COPCs) resulting from the management of coal combustion residues
(CCRs) resulting from wider use of state-of-the art air pollution control technology. This research was cited
as a priority in EPA's Mercury Roadmap (http://www.epa.gov/mercury/roadmap.htm') to ensure that one
environmental problem is not being traded for another. The objective is to understand the fate of mercury
and other COPCs and ensure that emissions being controlled in the flue gas at power plants are not later
being released depending upon how the CCRs are managed.

As part of this research effort, individual leaching test methods have been developed for inclusion into
SW846. These methods were adapted by Dr. David Kosson, Dr. Florence Sanchez, and Dr. Andrew
Garrabrants of Vanderbilt University, and their consultant, Dr. Hans van der Sloot from The Netherlands,
from the publication titled An Integrated Framework for Evaluating Leaching in Waste Management and
Utilization of Secondary Materials (Kosson et al., 2002, Environmental Engineering  Science, Volume  19,
Number 3,159-203). Four test methods have been developed as preliminary versions of EPA methods1 and
can be found at http://www.vanderbilt.edu/leaching/downloads.html. The four leaching test methods include:

1.   Pre Method 1313: Liquid-Solid Partitioning as a Function of Extract pH for Constituents in Solid
    Materials using a Parallel Batch Extraction Procedure

2.   Pre Method 1314: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio for Constituents in  Solid
    Materials using an Dp-flow Percolation Column Procedure

3.   Pre Method 1315: Mass Transfer Rates of Constituents in Monolithic or Compacted Granular Materials
    using a Semi-dynamic Tank Leaching Procedure

4.   Pre Method 1316: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio for Constituents in  Solid
    Materials using a Parallel Batch Extraction Procedure
1 Preliminary Version denotes that this method has not been endorsed by EPA but is under consideration for inclusion
into SW-846.
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Multilaboratory validation data is necessary for a method to be considered for inclusion in SW-846 (per
Guidance for Methods Development and Validation for the RCRA Program). This Quality Assurance Project
Plan (QAPP) is being written to  cover the EPA Interlaboratory Validation Study of the above four proposed
SW-846 leaching methods. A separate interlaboratory study will be performed for each of the four methods
separately. Due to similarities in equipment and procedures, the first methods to be tested are Pre Method
1313 and Pre Method 1316.

1.2    Project Objectives

US EPA's Office of Resource Conservation and Recovery (ORCR) formerly the Office of Solid Waste (OSW)
requires that an interlaboratory validation be conducted for a  method to be considered for inclusion into
SW-846. This QAPP will detail the process by which each of the four proposed leaching methods will be
validated by at least five, and up to ten, different laboratories  to establish reproducibility.

The determination of laboratory reproducibility is the final stage in the method development process, prior to
the submission of the method for ORCR review. By reproducibility, the Agency means that multiple
operators and multiple laboratories should be able to obtain comparable performance data on split samples
using the method. It is necessary to demonstrate that satisfactory method performance is not limited to the
individual operator or laboratory that developed the method. The minimum number of laboratories that are
needed to participate in  a multilaboratory method validation is three, with preferably more. Developers of
new  methods need to do a limited multilaboratory evaluation  and provide the individual laboratory and
summary performance data in the method submission.

This  QAPP is a replacement of  the QAPP approved on June  21, 2010 (QTRAK# 03069-A00244).  This
QAPP will provide details of the following tasks:

•    Preparation and characterization of the CCR by APPCD's on-site laboratory support contractor,
     ARCADIS, prior to distributing to each laboratory participating in the validation study (Task 1)

•    Leaching of CCR and other method validation materials (by the proposed SW846 method) by
     ARCADIS (to establish the baseline results) and by each participating laboratory. All leachates will be
     submitted to Vanderbilt University for analysis (Task 2)

•    Determination of the reproducibility (variability between laboratories), repeatability (single-operator
     precision) and accuracy of each method (Task 3)

•    Leaching of 5 fly ash, 3 scrubber sludge, the 3 other validation materials (foundry sand, solid waste
     analog, and contaminated  field soil),  and a cement kiln dust sample using SW-846 Method 1311
     "Toxicity Characteristic Leaching Procedure" (EPA, 1992) and SW-846 Method 1312 "Synthetic
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Precipitation Leaching Procedure" (EPA, 1994) with analysis for metals by ICP-OES for comparison
with the proposed new leaching methods (Task 4)

Vanderbilt will perform radionuclide testing on 35 fly ash samples, 6 flue-gas desulfurization (FGD)
gypsum and 1 cement kiln dust samples to determine uranium species and concentrations by the
measurement of Beta and Gamma decay particles (Task 5)
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2.  Project Organization
The organizational chart for this project is shown in Figure 2-1. The roles and responsibilities of the project
personnel are discussed in the following paragraphs. In addition, contact information is also provided.
Appendix A identifies the nine laboratories participating in this interlaboratory validation study.
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                   QA Officer
             Libby Nessley, ARCADIS
                                                                          Interlaboratory Validation
                                                                              Studv Particioants
                                                                         Representing:
                                                                            •  EPA Laboratories
                                                                            •  DOE Laboratories
                                                                            •  Commercial Laboratories
                 Safety Officer
             Jerry Revis, ARCADIS
                                        Peter Kariher, ARCADIS
        Rosanne Delapp, Vanderbilt
                                                      Leaching Sample
                                                         Generation
Eric Morris, ARCADIS
                             Methods Development /
                                   Fvalnatinn
                             David Kosson, Vanderbilt
                           Florence Sanchez, Vanderbilt
                          Andrew Garrabrants, Vanderbilt
                          Hans van der Sloot, Consultant
                  ICPMS Analytical Manager
                  Kathryn Smith, Test America
Figure 2-1.    Project Organizational Chart
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EPA Work Assignment Manager. Susan Thorneloe: The EPA WA Manager is responsible for
communicating the scope of work, and is the primary party responsible for review and approval of this QAPP
and all other deliverables under this work assignment. The EPA WA Manager is responsible for providing
ARCADIS with the various CCR to be used for this interlaboratory validation study. Ms. Thorneloe will also
send requests to a number of EPA, DOE and commercial laboratories asking for participation in this
interlaboratory study, and will be responsible for making the final selection of which laboratories will be
included in the study. She will receive the laboratory data packages, and oversee the evaluation of the
results by Vanderbilt, ARCADIS, and the NCSU statistician.
Phone: (919)541-2709
E-mail: thorneloe.susan@epamail.epa.gov

EPA QA  Representative.  Robert Wright: The EPA QA Representative will be responsible for reviewing
and approving this QAPP.  This project has been assigned a QA category III and may be audited by EPA
QA. Mr. Wright is responsible for coordinating any EPA audits.
Phone (919) 541-4502
E-mail: wright.bob@epamail.epa.gov

ARCADIS Work Assignment Leader. Peter Kariher: The ARCADIS WA Leader is responsible for
preparing project deliverables and managing the work assignment. He will ensure the project meets
scheduled milestones and  stays within budgetary constraints agreed upon by EPA. The WA Leader is also
responsible for communicating any delays in scheduling  or changes in cost to the EPA WA Manager as
soon as possible. Mr. Kariher, along with Dr. Kosson (Vanderbilt) and Dr. Stefanski (NCSU) will review the
laboratory data packages.
Phone (919) 541-5740
E-mail: peter.kariher@arcadis-us.com

ARCADIS Inorganic Laboratory Manager. Peter Kariher: In addition to being the WA Leader, Peter
Kariher is also responsible for the operation of EPA's in-house Inorganic Laboratory. Mr. Kariher is
responsible for preparation of this QAPP, and will prepare the homogenized CCR(s)  to be used in the
interlaboratory validation study. He will perform the characterization and leaching of each CCR by Pre-
Methods  1313 and 1316 prior to distributing the CCR to the labs for comparative analysis. Mr. Kariher will
operate the mercury analyzer and ion chromatograph, and forthe leaching studies and mercury and metals
analyses, will be supported by one technician: John Foley. Mr. Kariher will perform SW-846 Method 3052
digestion  of solid CCR samples and also be responsible  for mercury analysis of samples  by CVAA. John
Foley will perform the  leaching tests.  Mr. Kariher will submit the remaining Method 3052 digestates to the
subcontract analytical laboratory,  Test America-Savannah for ICP/MS analysis of the other target metals. He
will also be involved with the EPA WAM and the Vanderbilt University methods developers in evaluating the
results.
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Phone (919) 541-5740
E-mail: peter.kariher@arcadis-us.com

Test America-Savannah Analytical Manager. Kathryn Smith: Ms. Smith will review and validate the
ICP/MS results for total content digest samples and report them to Mr. Kariher.
Phone (912) 354-7858
E-mail: kathye.smith@testamericainc.com

ARCADIS Designated QA Officer. Lib by Nessley: The ARCADIS QA Manager, Libby Nessley, has been
assigned  QA responsibilities for this work assignment. Ms. Nessley will be responsible for reviewing this
QAPP prior to submission to EPA QA for review. Ms. Nessley will perform an internal data quality audit on at
least 10% of the ARCADIS reported data. In addition, she will perform a Technical System Audit (TSA) if
requested by the EPA WAM or the ARCADIS WAL. All QA/QC  related problems will be reported directly to
the ARCADIS WAL, Peter Kariher.
Phone:(919)544-4535
E-mail: libby.nesslev@arcadis-us.com

Vanderbilt University. Methods Development. Professors David Kosson. Florence Sanchez. Andrew
Garrabrants. and Rossane Delapp; Consultant. Methods Development. Hans van der Sloot: Dr.
Kosson in cooperation with Dr. Florence Sanchez, Dr. Andrew Garrabrants, and Dr. Hans van der Sloot
developed the leachability methods being evaluated during this interlaboratory validation study. All leachates
will be sent to Vanderbilt University for analysis by ICP-OES. Ms. Rossane Delapp will assist in the analysis
of the leachates for determination of the non-mercury metals concentrations and will develop the LeachXS
Lite analytical database for sample data viewing and reporting.  Ms. Delapp will also be responsible for the
reference lab application of Pre-Methods 1313, 1314,1315 and 1316. Drs. Kosson, Sanchez, Garrabrants,
and van der Sloot will be available to consult with the EPA WAM and ARCADIS Inorganic Laboratory
Manager  regarding the evaluation of the interlaboratory comparative results for each of the proposed
SW846 methods. Dr. Kosson, Dr. Garrabrants, Mr. Kariher (ARCADIS) and Dr. Stefanski (NCSU) will review
the laboratory data packages.
Dr. David Kosson
Phone:(615)322-1064
E-mail: David.Kosson@vanderbilt.edu
Dr. Florence Sanchez
Phone:(615)322-5135
E-mail: Florence.Sanchez@vanderbilt.edu
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Dr. Andrew Garrabrants
Phone:(615)322-7226
E-mail: Andrew.Garrabrants@vanderbilt.edu
Dr. Hans van der Sloot
Phone:+31 (0)226-341607
E-mail: hans@vanderslootconsultancy.nl
Ms. Rossane Delapp
Phone: (615)322-1064
E-mail: rossane.c.delapp@vanderbilt.edu

ARCADIS Project Manager. Johannes Lee: The ARCADIS Project Manager, Johannes Lee, has been
assigned financial, contractual and managerial responsibilities for this work assignment. Mr. Lee will be
responsible for communications with the EPA project officer, the oversight of financial status, and fulfilling
contractual requirements.
Phone: (919)544-4535
E-mail: iohannes.lee@arcadis-us.com

ARCADIS Safety Officer. Jerry Revis: The ARCADIS Safety Officer, Jerry Revis, has been assigned the
safety supervisor responsibilities for this work assignment. Mr. Revis will be responsible for reviewing safety
plans, performing periodic safety inspections, communicating with the EPA safety office, and oversight of
safety operations.
Phone:(919)544-4535
E-mail: ierry.revis@arcadis-us.com

North Carolina State University (NCSU). Statistical Consultant. Dr. Leonard A Stefanski: Dr. Stefanski
will provide statistical consultation on the planning and implementation of interlaboratory study to ensure
validity of the collected data. He will also provide advice on the choice and application of statistical methods
used to analyze the study data, and on the interpretation of results obtained from the statistical analyses. Dr.
Stefanski will report to Mr. Wright, the EPA QA Representative. He will assist Dr. Kosson (Vanderbilt) and
Mr. Kariher (ARCADIS) in reviewing the laboratory data packages.
Phone:919-515-1945
E-mail: stefanski@stat.ncsu.edu
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3.  Experimental Approach

This interlaboratory comparison will include a comparison of leaching test methods performance by a
reference laboratory (either ARCADIS or Vanderbilt) and minimum of six participant laboratories (see
Appendix A; nine participant laboratories are currently planned) based on testing of three different materials
for each leaching test method to be evaluated. The goal of this study is to determine intra-laboratory and
inter-laboratory reproducibility for the four test methods under development.   Following is a list of key
elements for regulatory methods development as specified in the SW-846 guidance document, and the
applicability of each element for this study:

        Element 1: Identification of Scope and Application and Regulatory Need

        The methods being developed through this study are intended to provide improved leaching
        characterization of wastes and other materials for use and disposal under a range of field exposure
        conditions by considering the materials physical characteristics that effect water flow (e.g., granular
        or monolithic and thus controlling whether water flows through or around the material), and potential
        field conditions (i.e., pH, water contact mode, liquid-solid ratio). These methods are planned to be
        applicable for assessments where use of other leaching test methods are not statutorily required.

        Element 2: QA/QC Requirements

        QA/QC requirements for each  method under development are indicated within each method
        description and are consistent with SW-846 requirements. QA/QC requirements for this study are
        indicated in this QAPP.

        Element 3: Analytical Approach

        This study is to evaluate leaching tests (e.g., aqueous extraction tests) that are operationally defined
        and intended to provide  estimation of underlying physical and chemical phenomena controlling
        constituent release from a solid material to contacting water. Thus, the method of analysis selected
        for leaching test eluates (i.e., ICP-OES) was a method that was suitably efficient and sensitive for
        the purposes of this study (see Section 5.2.3). Additional characterization of materials to be tested
        is being carried out using other analytical techniques (see Section 5).

        Element 4: Method/Instrument Sensitivity

        Method/instrument sensitivity is based on the chemical  analysis technique for leaching test eluates
        that is selected. This study uses previously standardized methods for chemical analysis.
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Element 5: Method Optimization and Ruqqedness Testing

An extensive study has been completed that provides an evaluation of related test methods
development and optimization based on compilation and evaluation of results from international
studies (van der Sloot, et al. 2010). This program is consistent with those findings.

Element 6: Accuracy, Precision and Repeatability (Clean Matrix)

Determination of accuracy is not possible for leaching tests because they are operationally defined
and there is no absolute correct value that can be verified using an independent characterization
technique. Precision and repeatability for a clean matrix is not possible because of the nature of the
materials being evaluated.  Instead, intra-laboratory and inter-laboratory repeatability and
reproducibility is determined.

Element 7: Effect of Interferences

Method interferences for leaching test  methods are either (i) difficulties in physical handling of
materials and liquid-solid separation as part of the test method, or (ii) analytical interferences
observed during chemical analysis of leaching test eluates.  Physical handling and liquid-solid
separation difficulties will be noted based on the experience of the participant and reference
laboratories.  Analytical interferences will be observed based on the analytical QA/QC program (See
Section 5) but are not expected based on prior experience testing similar materials.

Elements: Matrix Suitability

Not applicable.

Element 9: Quantitation  and Detection Limits

Determination of quantitation and detection  limits is not a goal of this study.  Quantitiation and
detection limits for the chemical analysis techniques to be used in this study are provided in Section
5.

Element 10: Laboratory  Reproducibility

This element is the primary focus of this study and addressed as part of this QAPP.
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        Element 11: Document Submission and Workgroup Evaluation

        Data reduction and evaluation is specified in this QAPP. The result will be separate detailed reports
        documenting results for each test method.  An EPA methods workgroup has been formed for these
        methods following the SW-846 procedures. Mark Baldwin (EPA-OSWR) is the project's liaison with
        the SW-846 methods workgroup.
The experimental design addresses determining within and between laboratory reproducibility for a set of
four leaching test methods.  An unbalanced factorial design is being used with appropriate analysis of
variance statistical techniques used for data evaluation (see Section 7).   Each method will be challenged
using three distinctly different materials (coal fly ash, blended Portland cement mortar that includes coal fly
ash,  metals contaminated soil), selected to reflect a broad range of material properties. Six analytes will be
selected for each material to serve as the basis for evaluation. Each analyte will be selected to represent the
range of leaching behavior (e.g., concentration as a function of pH and liquid-solid ratio) typically observed
for the material being evaluated and be readily detected using a single analytical method (i.e., ICO-OES).
Each method is being treated as a separate evaluation from the other methods. Each  material evaluated
will also be treated statistically as independent evaluations because of the wide range  in leaching behavior
of individual constituents from material to material (these variations can span several orders of magnitude).
Within the statistical design for each method evaluated, the principal factor is testing laboratory (a minimum
of 6 independent laboratories and a reference laboratory).  The selection of a minimum of 6 independent
laboratories is consistent with ASTM recommendations (ASTM, 1988). The reference laboratory and each
independent laboratory will carry out the designated test method 6 times and 3 times, respectively, on each
material to determine intra-laboratory reproducibility and inter-laboratory reproducibility based on intra-
laboratory and inter-laboratory variance.  Individual laboratory bias will be evaluated based on deviation from
the mean values observed across all laboratories and the statistical significance of the deviation.  Each
analyte will be treated independently for statistical analysis purposes.

The following discussion is specific to a coal fly ash as an example of the approach that will be used for
preparation and evaluation of all materials selected for the study. Coal fly ash from a single facility will be the
first material used in this study.

3.1    Task I: Preparing  Homogenized CCR

An energy facility, which participated with EPA in an earlier study, has agreed to provide twenty-five,  5-
gallon buckets of raw ash for this interlaboratory validation study. The raw ash  being supplied this time is
from the same facility that was included in an EPA study focused on leaching characterization of a range of
CCRs, thus providing extensive useful information on approximate testing results (EPA, 2009). ICP-OES
was used to analyze these samples. A list of eight metals have been selected (As, Sb, Ba, B, Ca, Cr, Co,
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Mo, Se, and V) as the focus of the intercomparison study, and their method detection limits (MDL) and
quantitation or reporting limits (RL) are shown in Table 3-1. From the previous work, graphs have been
generated showing the pH dependent concentration of each metal.

This section details how this CCR will be homogenized, split, and tested to ensure that each participating
laboratory receives like samples for analysis.

Table 3-1.    MDLs and RLs of the Metals to be Evaluated during the Validation Study
Metal
As
Sb
Ba
B
Ca
Cr
Co
Mo
Se
V
MDL
(ug/L)
11.0
8.00
1.00
1.00
2.6
1.00
1.00
1.2
15.0
1.5
RL
(ug/L)
35.0
25.4
3.18
3.18
8.3
3.18
3.18
3.8
47.7
4.8
A core sample will be taken from 12 of the 25 homogenized buckets and tested to establish homogeneity
and to provide characterization data of the CCR. A summary of this testing is shown in Table 3-2. Detailed
descriptions of each testing procedure are presented in Section 5. The initial homogeneity testing will be
performed using the XRF analysis as the screening technique. Total mercury by thermal decomposition
using the Lumex and total digestion methods will be used to further evaluate the CCR leaching reference
material. Although further homogenization occurs for each method - as detailed below - this initial core
sampling and characterization testing is used to verify that the starting material (which will be used for all
validation testing) is indeed homogeneous. Previous  results suggest that silicon, a major constituent of this
fly ash, will differ by less than 1 %. Other constituents can vary by up to 25%. Wider variation between core
sample results would indicate that additional homogenization between buckets would be required before
proceeding.
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Table 3-2.   Characterization Testing to Establish Homogeneity of the CCR
      Method                    Analytes                          Number of Replicates
    XRF / solids            Total metals content (%)               Single pellet of twelve core samples
   Lumex / solids             Total mercury (Hg)               Triplicate analysis of each core sample
Method 3052 / liquids            Total metals                      Four cores, selected randomly
Method 3051 / liquids            Total boron (B)                     Four cores, selected randomly
Method 1313 / liquids        Leaching behavior by pH           Aliquots of the four, randomly selected cores
   EC/OC*/ solids         Elemental and organic carbon              Twelve cores, selected randomly
* Elemental carbon/organic carbon needed for accurate XRF calculations
The percent relative standard deviation (RSD) will be calculated with an RSD<10% for major constituents
and RSD<20% for trace constituents considered sufficient homogeneity for use in  the study.

Each of the proposed SW846 methods will be tested with this ash as the CCR. The detailed procedure for
the further homogenization (to ensure that each laboratory is receiving the exact same material for each
method being tested) and distribution  for testing for each method  is detailed below.

Method 1313: Approximately 40 kg (two 5-gallon pails) of material will be combined into a single mixing
drum, mixed and then subdivided into approximately 1-kg (1 L)  subsamples.  Subdivision of the mixed batch
into portions will be by coring or a similar method to ensure that potential stratification of the mixed batch
does not bias the individual subsamples. The result of the homogenization will be approximately  forty 1-L
subsamples in 1-L wide mouth HOPE containers with screw top lids. Each participating laboratory will
receive two randomly-selected 1-L subsamples for the purpose of carrying out 3 replicate Method 1313 tests
on the designated material. Four randomly selected 1-L subsamples will be used to conduct 6 replicate
Method 1313 tests by the referee laboratory (ARCADIS). The remaining unused subsamples will be
archived. For Phase I testing, the designated material is a coal fly ash.

Method 1314: Approximately 60 kg (three 5-gallon pails) of material will be combined into a single mixing
drum. Each batch will be mixed and then subdivided into approximately sixty 1-kg  (1-L) subsamples.
Subdivision of the mixed batch into subsamples will be by coring or similar method to insure that potential
mixed batch stratification does not bias the individual subsamples. This homogenization process will result in
approximately sixty 1-L subsamples in 1-L wide mouth HOPE containers with screw top lids. Each
participating laboratory will receive four randomly-selected 1-L subsamples for the purpose of carrying out 3
replicate Method 1314 tests on the designated material. Eight randomly selected 1-L subsamples will be
used to carry  out 6 replicate Method 1314 tests by the referee laboratory (Vanderbilt). The remaining unused
subsamples will be archived. For Phase I testing, the designated material is a coal fly ash.

Method 1315: Approximately 100  kg (five 5-gallon pails) of material will be combined to at most two batches
to be blended in mixing drum. Each batch  will be mixed and then subdivided  into approximately one hundred
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1-kg (1-L) subsamples. Subdivision of the mixed batch into subsamples will be by coring or similar method to
insure that potential mixed batch stratification does not bias the individual subsamples. This procedure will
result in approximately one hundred 1-L subsamples in 1-L wide mouth HOPE containers with screw top
lids. Eight randomly selected 1-L subsamples will be provided to each participating laboratory for purpose of
carrying out 3 replicate Method 1315 tests on the designated material. Sixteen randomly selected 1-L
subsamples will be used to carry out 6 replicate Method 1315 tests by the referee laboratory (Vanderbilt).
The remaining unused subsamples will be archived. For Phase I testing, the designated  material is a coal fly
ash.

Method 1316: Approximately 60 kg (three 5-gallon pails) of material will be combined into a single mixing
drum. Each batch will be mixed and then subdivided into approximately one hundred 1-kg (1-L) subsamples.
Subdivision of the mixed batch into subsamples will be by coring or similar method to insure that potential
mixed batch stratification does not bias the individual subsamples. The homogenization process will result in
approximately sixty 1 -L subsamples in 1 -L wide mouth HOPE containers with screw top lids.  Four randomly
selected 1-L subsamples will be provided to each participating laboratory for purpose of carrying out 3
replicate Method 1316 tests on the designated  material. Eight randomly selected 1-L subsamples will be
used to carry out 6 replicate Method 1316 tests by the referee laboratory (ARCADIS). The remaining unused
subsamples will be archived. For Phase I testing, the designated material is a coal fly ash.

Overall Implications: Thirteen 5-gallon buckets of coal fly ash will be used; 260 1-L wide mouth HOPE jars
are needed.

Use of Spiked Samples

Spiking of field generated samples with constituents of concern is generally not recommended because of
the difficulty of achieving (i) uniform distribution of the constituent spike, and (ii) speciation of the spiked
constituent within reference  material that is representative of the speciation of the same constituent originally
present. However, spiking of a laboratory-generated reference material (e.g., cement stabilized waste form)
for specific constituents of interest is practical because the added spikes will be the primary source of the
constituent of interest and uniform distribution can be  achieved during the slurry mixing process used to
create the sample material. Any spiked samples utilized in this study will be approved by the  EPA WAM and
fully documented in the project report.

3.2  Task II: Leaching of the CCR by Reference Laboratory and the Intercomparison Laboratories

ARCADIS, having extensive experience in these leaching methodologies as documented in earlier studies,
will be responsible for producing the reference  leaching data. Six of the cores (as described in Section 3.1
for the characterization testing) will be randomly selected as the replicates to be analyzed by the reference
laboratory (ARCADIS or Vanderbilt) by the proposed SW846 method. These results will be compared to the
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historical data available for this ash (as described in Section 3.1) to establish the reference results for the
method being validated.

Each laboratory will be provided with the following:

1.   An introductory letter reiterating the purpose of this study and the laboratory's participation

2.   A copy of the SW846 method being validated

3.   An amount of homogenized CCR which is adequate to conduct three test replicates

4.   Method template spreadsheet

5.   As recommended by ORCR, each  lab will be asked to have their extractions performed by a single
    operator on a single instrument in a single batch to minimize variability inherent to the determinative
    method; all leaching test eluates will be analyzed by ICP-OES for selected constituents by Vanderbilt to
    minimize variability associated with the metals analysis step since the focus of this study is on the
    leaching test methods not chemical analysis.

The spreadsheet is very user-friendly and walks the participant through each step of the method and
provides a standardized mechanism  for data entry into a database for this study as well as comparing
results of the materials tested in this study to results obtained from other studies. Appendix B contains a
printout of the pages in the Method 1313 spreadsheet showing the  instructions and each of the data entry
sheets. Appendix C contains examples of the introductory letter, instruction sheet, questionnaires for
Methods 1313 and  1316, chain-of-custody form, and a page of sample labels sent to each participating
laboratory.

Each laboratory will be asked to perform the each of the four proposed methods in triplicate (e.g., 9 pH
levels + 3 blanks per test = 36 leachates for Method 1313) within one month. The leachates are to be
forwarded to Vanderbilt for analysis.  In  addition, they are to forward the completed data package to the EPA
WAM and Vanderbilt, which will include:

•   The completed electronic data report forms (provided as Microsoft® Excel spreadsheets)

•   Photocopies or printouts of all  raw data, laboratory notebook documentation, calculations, results and
    comments
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•   A completed questionnaire indicating any deviations from the prescribed method that were necessary,
    methodology clarifications needed or suggested, personnel time required to complete the method, and
    any other suggestions.

The tentative schedule for the interlaboratory validation of the method is shown in Table 3-3.

Table 3-3.   Tentative Schedule for Interlaboratory Validation of Proposed SW-846 Methods
                     Milestone                              Tentative Date
     Receive ash from previously participating facility              Complete in 2010
        Initial characterization and baseline testing                 Completed in 2010
           Lab's receive material for testing                Completed in 2010 and 2011
      Labs send leachates to Vanderbilt for analysis                November 2011
          Vanderbilt provides results to EPA                     December 2011
       Provide final reports for the methods testing                 January 2012


3.3    Task III: Determination of the Reproducibility of Each Method

Following receipt of the completed data packages from each participating laboratory and the results of the
leachate analyses from Vanderbilt, statistical determination of the reproducibility (variability between
laboratories) and repeatability (single-operator precision) of each method will be determined. Leach testing
results and feedback will be compiled with like data from other laboratories  performing the same method,
and will be submitted as part of a supportive data  package for EPA ORCR method approval.

3.4    Task IV:  Testing of Select Materials for Leaching by SW-846 Methods 1311 (TCLP) and 1312 (SPLP)

Testing of some  selected CCRs and the materials from the interlaboratory methods validation study will be
performed by ARCADIS using SW-846 Methods 1311 "Toxicity Characteristic Leaching Procedure (TCLP)"
and 1312 "Synthetic Precipitation Leaching Procedure (SPLP)" for comparison with the proposed new SW-
846 methods.  Leachate will be sent to Vanderbilt for analysis by ICP-OES. Results from these experiments
will  be used to show the comparability of leaching behavior between these tests and the proposed new SW-
846 methods.  TCLP uses a glacial acetic acid and sodium hydroxide buffer solution with a pH of 4.93 ±
0.05 (Extraction Fluid #1) at a 20 to 1  solid to liquid ratio. SPLP uses a weak sulfuric and nitric acid solution
with a pH of 4.2 ± 0.05 (Extraction Fluid #1) at a 20 to 1 liquid to solid ratio to simulate  leaching for samples
east of the Mississippi river. Samples will be tumbled for 18 hours and filtered to remove the solids.  The
extract will be preserved with 1% nitric acid and analyzed by Vanderbilt University using ICP-OES. Table 3-
4 lists the samples currently selected for TCLP and SPLP testing.
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Table 3-4. Sample Testing List for TCLP and SPLP
Sample Name
CaFA
EaFA
KFA
UFA
ZFA
YSD
MAD
DGD
CKD
SWA
CFS
JaFS
CKD
Sample Type
Fly Ash
Fly Ash
Fly Ash
Fly Ash
Fly Ash
Spray Dryer Ash
FGD + Fly Ash Mix
Scrubber Sludge
Scrubber Sludge
Solid Waste Analog
Contaminated Field Soil
Brass Foundry Sands
Cement Kiln Dust
3.5   Task V: Testing of Fly Ashes and Cement Kiln Dust for Radionuclide Testing by Germanium Detector

Vanderbilt will perform radionuclide testing on 35 fly ash samples and 1 cement kiln dust sample to
determine uranium species and concentrations by the measurement of Beta and Gamma decay particles
using a Germanium (Ge) detector made by ???.
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4. Sampling Procedures

The following subsections describe the sampling procedures to be used for each task. Whenever possible,
standard methods will be followed. In some cases, draft methods may be evaluated and implemented. Each
method to be used will be cited and any deviations from the methods will be documented.

4.1    Sample Custody Procedures

The detailed procedures for preparing and distributing the homogenized CCR were presented in Section 3.1.
The following types of samples will be generated during these tests:

1.  Solid samples for leaching and radionuclide testing:  fly ash, solid waste analog, contaminated field soil,
    brass foundry sands, scrubber sludge, and cement kiln dust

2.  Post -leaching and post-thermal desorption of the CCR (solid samples)

3.  Leachate samples (liquid samples) for Hg and other metals analysis

Each sample generated will be analyzed in-house or by outside laboratories. Chain-of-custody (COC)
procedures will be required, which will include signing and dating of COCs to indicate receipt of samples,
and archived of all COCs with other project documentation. CCRs will be logged as they are received by the
ARCADIS WAL, Mr. Peter Kariher. Information regarding where each CCR originated and any other
descriptive information available will be recorded in a dedicated laboratory notebook by Mr.  Kariher. A core
sample will be taken from each 5-gallon bucket of homogenized material and processed for physical and
chemical characterization (see Section 3.1). All samples will be properly contained and identified with a
unique sample ID and sample label. Chain-of-custody forms will be generated for all samples prior to
transfer for analysis.

The sample labeling convention used to identify a particular solution consists of numerical identifiers for the
material, lab, test method, and test position along with an alphabetical identifier for the test replicate. The
layout for the sample label convention is as follows:

                      Maa-LJbJb-131c-Tcfcf-e           (Test Positions T01 through T09)

                      Maa-LJbJb-131c-Bdd-e           (QA/QC Blanks B01-B03)

        "aa" is a two-digit number starting at zero that identifies the test material (e.g., the Phase I
             material is M01),
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        "bb" is a two-digit number starting at zero that identifies the participating laboratory (assigned
             randomly by EPA-ORCR),
        'c" is a single digit number that completes the test method ID (i.e., 1313,1314, 1315,1316,
             TCLP, or SPLP),
        "dd" is a two-digit number starting at zero that identifies the test position or QA/QC blank.

        "e" is a single letter representing the test replicate (i.e., A, B or C).

Four sets of completed labels were provided to be used for labeling extraction vessels (for the tree replicates
and a fourth set for replacements as needed) and two sets of 50-mL analytical samples.

For example. M01-L02-1313-B02-C would represent Phase I material being validated by the laboratory
randomly identified as "02". The sample is from Method 1313,  is blank 02, and replicate C.

Handling of CCR samples for the leaching tests (Task III) is described in detail in each of the proposed
SW846 methods. These methods can be  found on the Vanderbilt University website at
http://www.vanderbilt.edu/leaching/downloads.html.

4.2    CCR, and Leaching Reference Material  Samples

As mentioned, the objective of this validation study is to obtain information on  the reproducibility of the
preliminary versions of EPA methods for leaching Al, Sb, Ba, B, Cr, Co, Mg, and Zn from CCRs. The facility
descriptions will include information on the history/origin of each method validation sample, facility process
description, sample type, sampling location,  sampling time and method, coal type, operating condition, and
sample storage condition. Section 4.1 describes  the sampling  custody procedure.

4.2.1  Physical and Chemical Characterization Samples

A core sample will be taken from twelve of the 5-gallon buckets of the homogenized method validation
material (as described in Section 3.1) and subjected to physical characterization measurements. These 12
core samples will be mixed together using a riffle splitter prior to XRF pellet  preparation and analysis.  To
ensure a good homogeneity of the final composite sample that will be used  for the XRF characterization, the
first two composite samples exiting the splitter will be reintroduced at the top of the splitter. This procedure will
be repeated at least 6 times. At the end, the two  resulting homogeneous composite samples will be combined
in the same sample container and stored until XRF testing. Method 3052 samples will also be  performed on
each of the method validation materials to determine variability for trace elements.
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4.2.2  Leaching Study Samples

Method validation materials used for leaching studies will not require size reduction to acquire an adequate
sample for testing due to the small particle size inherent in fly ash. The size reduction method is outlined in
the leaching test methods (http://www.vanderbilt.edu/leachinq/downloads.html'). If the method validation
materials are altered in any way prior to leaching studies, a representative sample will be submitted for
physical and chemical characterization.

4.3   Leachate Collection

Each of the proposed SW-846 test methods will be used to conduct a leaching study. The proposed
methods can be found on the Vanderbilt University website at
http://www.vanderbilt.edu/leachinq/downloads.html. Table 4-1 shows the extraction schedule and the range
of tested pHs as outlined in the first study to be conducted on the Preliminary Version of EPA Method 1313:
Liquid-Solid Partitioning as a Function of Extract pH for Constituents in Solid Materials using a Parallel Batch
Extraction Procedure.

Table 4-1.   Final Extract pH Targets for Method  1313
   pH Target                               Rationale
   Will Vary*              Natural pH at LS 10 mL/g-dry (no acid/base addition)
    2.0±0.5               Provides estimates of total or available COPC content
    4.0±0.5                  Lower pH limit of typical management scenario
    5.5±0.5                  Typical lower range of industrial waste landfills
    7.0±0.5                   Neutral pH region; high release of oxyanions
    8.0±0.5                  Endpoint pH of carbonated alkaline materials
    9.0±0.5          Minimum of LSP curve for many cationic and amphoteric COPCs
   12.0±0.5         Maximum in alkaline range for LSP curves of amphoteric COPCs
   13.0±0.5              Upper bound (field conditions) for amphoteric COPCs
   10.5±0.5          Substitution if natural pH falls  within range of a mandatory target
This is the pH of the material as received with  only deionized water added (i.e., no acid or base addition).
Table 4-2 shows an example schedule for the extraction setup to be conducted on the Preliminary Version
of EPA Method 1316: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio for Constituents in Solid
Materials using a Parallel Batch Extraction Procedure.
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Table 4-2.    Example Schedule for Method 1316 Extraction Setup
A

Test
Position
T01
T02
T03
T04
T05
B01
Total
NOTE: 1)
B

Target
LS
10.0
5.0
2.0
1.0
0.5
QC

This schedule
c

Minimum Dry
Mass
(g-dry)
20
40
100
200
400
-
-
assumes a target
D
Mass of
"As-Tested1
Sample
(g)
22.2
44.4
111
222
444

844
liquid volume
E
Moisture in
"As-Tested"
Sample
(mL)
2.2
4.4
11.1
22.2
44.4


of 200 ml.
F
Volume of
Reagent
Water
(mL)
198
196
189
178
156
200
1120

G

Recommended
Bottle Size
(mL)
250
250
500
500
1000
250


         2)  This schedule is based on "as tested" solids content of 0.90 g-dry/g.
         3)  Test position marked B01 is a method blank of reagent water.
 To demonstrate the versatility and robustness of the proposed new leach test methods, various solid
 materials other than CCRs were chosen for testing.  Table 4-3 shows the proposed test methods and each
 of the materials to be tested. Table 4-4 gives a brief description of the various solid materials to be tested.

Table 4-3.    Materials to be used with the Proposed New Leach Tests
   Method
Materials
     1313        Fly Ash (EaFA), CFS (Contaminated Field Soil), and SWA (Solid Waste
                                          Analog)
     1314           CFS (Contaminated Field Soil) and JaFS (Brass Foundry Sands)
     1315            SWA (Solid Waste Analog) and CFS (Contaminated Field Soil)
     1316        Fly Ash (EaFA), CFS (Contaminated Field Soil), and SWA (Solid Waste
                                          Analog)
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Table 4-3.   Description of Materials for the Proposed New Leach Testing

   Material                                 Description
     EaFA         Fly ash from a 2.4 G Watt power plant burning eastern-bituminous coal
     CFS        Contaminated field soil collected from an active copper and lead smelting
                                               site
     SWA         Solid waste analog material containing Type I portland cement, class C
                  coal combustion fly ash, and ground granulated blast furnace slag) and
                  wastewater at a water/binder ratio of 0.41 (m/g). The wastewater used
                  was tap water spiked with powdered metal oxides or metal nitrates of
                 antimony, arsenic, barium, chromium, lead and selenium. This combined
                 material was used to produce both solid monoliths and ground for 2-mm
                                              power
     1316        Fly Ash (EaFA), CFS (Contaminated Field Soil), and SWA (Solid Waste
                                             Analog)
     1316        Fly Ash (EaFA), CFS (Contaminated Field Soil), and SWA (Solid Waste
                                             Analog)
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5.  Testing and Measurement Protocols to be Used for Reference Material Characterization and
    Eluate Characterization

As part of the initial characterization of the raw fly ash CCR, ARCADIS will conduct physical and chemical
characterization analyses. In addition, total metals will be analyzed by Test America, and the metals in the
leaching extracts will be analyzed by Vanderbilt University. Whenever possible, standard methods will be
used to perform required measurements. Standard methods are cited in each applicable section. Where
standard methods are not available, operating procedures will be written to describe activities. In situations
where method development is ongoing, activities and method changes will be thoroughly documented in
dedicated laboratory notebooks.

5.1    Physical Characterization

5.1.1  pH and Conductivity

pH and conductivity will be measured on all aqueous extracts by the laboratory (reference and participant
laboratories) carrying out the leaching test method. Conductivity is a measure of the ability of an aqueous
solution to carry an electric current. This ability is dependent upon the presence of ions; on their total
concentration, mobility, and variance; and on the temperature of the measurement.

pH of the leachates will be measured by using a combined pH electrode. A 3-point calibration will be done
using National Institute of Science and Technology (MIST) traceable pH buffer solutions. The pH meter will
be accurate and reproducible to 0.1  pH units with a range of 0 to 14.

Conductivity of the leachates will be measured using a standard conductivity probe. The conductivity probe
will be calibrated using appropriate standard conductivity solutions for the conductivity range of concern.
Conductivity meters are typically accurate to +1% and have a precision of +1%. The procedure to measure
pH and conductivity will be as follows:

Following a gross separation of the solid and liquid phases by centrifugation or settling, a minimum volume
of the supernatant to measure the solution pH and conductivity will be taken and poured in a test tube. The
remaining liquid will be separated by pressure filtration and filtrates will be appropriately labeled, preserved,
and stored for subsequent chemical analysis.

5.1.2  Moisture Content and Loss on Ignition (LOI)

Moisture content of the raw fly ash CCR will be determined using ASTM D 2216-05 (ASTM 2005) by
ARCADIS. This method, however, is not applicable to the materials containing gypsum (calcium sulfate
dihydrate or other compounds having significant amounts of hydrated water), since this material slowly
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dehydrates at the standard drying temperature (110°C). This slow dehydration results in the formation of
another compound (calcium sulfate hemihydrate) which is not normally present in natural material. The
ASTM method allows cooling at 60 °C to prevent the conversion and will be used to determine the moisture
content of materials containing gypsum.

Loss on ignition (LOI) will be performed on the raw fly ash CCR by placing dried samples in a furnace at
750 °C for 1 hour and measuring the mass lost during the combustion using ASTM D7348-08 (ASTM 2008).

5.2   Chemical Characterization

5.2.1  Dissolved Organic Carbon / Dissolved Inorganic Carbon (DOC/DIC) and Elemental Carbon / Organic Carbon
      (EC/OC)

Analyses of total dissolved organic carbon (DOC) and dissolved inorganic carbon (DIG) will be performed on
the  leachates as part of the baseline characterization by Vanderbilt University on a Shimadzu model TOC-V
CPH/CPN combustion catalytic oxidation NDIR analyzer. Five-point calibration curves, for both inorganic
(1C) and non-purgeable organic carbon (NPOC) analyses, are generated for an analytical range between 5
ppm and  100 ppm and are accepted with a correlation coefficient of at least 0.995. Reagent grade
potassium hydrogen phthalate  is used as the NPOC standard and sodium hydrogen carbonate is used as
the  1C standard. An analytical blank and check standard at approximately 10 ppm are run every 10 samples.
The standard is required to be within 15% of the specified value. A new calibration curve is generated if the
check standard measurement does not meet specification. A volume of approximately 16 ml of undiluted
sample is loaded for analysis. Inorganic carbon analysis is performed first for the analytical blank and
standard  and then the samples. Total carbon (non-purgeable organic carbon) analysis follows with addition
of 2M hydrochloric acid to a pH of 2 and a sparge gas flow rate of 50 mL/min. Method detection  limit (MDL)
and minimum level of quantification (MLQ) are shown in Table 5-1.

Table 5-1.   MDL and MLQ of Total  Organic Carbon Analyzer
                            MDL (ppm)              MLQ (ppm)
         1C                    0.07                   0.20
       NPOC                  0.09                   0.20
Elemental carbon (EC) and organic carbon (OC) will be determined on the solids by ARCADIS using a
Sunset Laboratory Carbon Aerosol Analysis Lab Instrument in EPA RTP Laboratory E-581 A. This method is
defined in NIOSH Method 5040 (CDC 2003). This equipment uses a furnace to heat the sample and
combust the carbon to carbon dioxide. The carbon dioxide is reduced to methane and a FID is used to
quantify the carbon emitted as the sample is heated from ambient to 870 °C over four heating steps.
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Samples are prepared by weighing 3 grams of the CCR into a 500 ml Nalgene high-density polyethylene
bottle. A 37 mm tarred pre-baked quartz filter is loaded into a 2.5 |jm participate sampler and attached to the
bottle. The particulate sampler is connected to a vacuum source and a rotometerto control the flow at 4
liters per minute. The CCR material is aspirated onto the quartz filter for 5 minutes and the filter is reweighed
to determine the mass loading. Duplicate filters are prepared for each material. Three analyses are
performed on each filter. Blank filters are provided to determine background levels.

5.2.2  Mercury by Thermal Decomposition and Cold Vapor Atomic Adsorption (TD-CVAA) Method 7473

As part of the baseline characterization, mercury analysis of the solid materials will be carried out by
ARCADIS using a thermal decomposition cold vapor atomic adsorption (TC/CVAA) according the EPA SW-
846 Method 7473  (EPA 1998).

The Lumex RA-915+ Mercury Analyzer is a portable instrument capable of measuring mercury
concentrations in air, liquids, and solids. Developed for use by the Russian Navy to detect elemental
mercury leaks on submarines (mercury is used as ballast), the analyzer is capable of measuring 1 ng/m3.
The instrument contains an internal sample pump, multi-pass optical cell and Zeeman Effect atomic
adsorption detector tuned to a wavelength of 253.7 nm for the detection of mercury. The Zeeman effect
atomic adsorption (AA) detector modulates the frequency of the source to eliminate matrix effects from air
samples and enhance the detector sensitivity for mercury. An optional RP-91C high temperature (>750 °C)
furnace can be used to convert any mercury species to elemental mercury for post combustion detection of
total mercury in the solids. Since the detector can only measure elemental mercury directly, this technique is
based on the thermal decomposition properties of mercury, as  only elemental mercury can exist at these
high temperatures. Under high temperatures, any oxidized mercury compounds are converted to elemental
mercury.

To perform a mercury analysis on a solid sample, the solid of known mass is weighed into a quartz or
stainless steel combustion boat. The combustion boat is then inserted into the furnace combustion chamber
and as the elemental mercury is evolved from the sample, the detector measures the mass of mercury. The
mass of mercury is directly proportional to the area under the peak, similar to the quantitation principle used
in gas chromatography. By dividing the mass of mercury by the mass of sample introduced to the
instrument, a mercury concentration can  be derived. For wet samples, a moisture measurement of the solid
must be determined  to correct the mercury content to a dry basis.

5.2.3  Other Metals (ICP)

Test America Laboratories in Savannah,  GA, will analyze a sample of the raw fly ash for the metal species
total content using an Agilent ICP-MS with octopole reaction system (ORS). Vanderbilt University
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(Department of Civil and Environmental Engineering) will analyze the metals content of the leachates using
a Varian inductively couple plasma optical emission spectroscopy (ICP-OES).

Test America will conduct their total metal analyzes on an ICP-MS using EPA SW-846 Method 6020A (EPA
2007d). Metals and estimated instrument detection limits are listed in the method. The ICP will be profiled
and calibrated for the target compounds and specific instrument detection limits will be determined. Mixed
calibration standards will be prepared at least 5 levels. Each target compound will also be analyzed
separately to determine possible spectral interference or the presence of impurities. Two types of blanks will
be run with each batch of samples. A calibration blank is used to establish the analytical curve and the
method blank is used to identify possible contamination from varying amounts of the acids used  in the
sample processing. Additional daily QC checks include an Initial Calibration Verification (ICV)  and a
Continuing  Calibration Verification (CCV). The ICV is prepared by combining target elements from a
standard source different than that of the calibration standard and at a concentration within the linear
working range of the instrument. The CCV is prepared in the same acid matrix using the same standards
used for calibration at a concentration near the mid-point of the calibration curve. A calibration blank and a
CCV or ICV are analyzed after every tenth sample and at the end of each batch of samples. The CCV and
ICV results must verify that the instrument is within 10% of the initial calibration with an RSD < 5% from
replicate integrations. Procedures to incorporate the analysis of a MS/MSD for these CCR samples will be
evaluated.

Vanderbilt University (Department of Civil and Environmental Engineering) will also conduct ICP-MS
analyses on the reference laboratory leaching test eluates. This will provide a statistical assessment of
precision for constituents that are not analyzed for in eluates by the participant laboratories. This will provide
precision (intralaboratory, by  ICP-MS and ICP-OES) for all elements of concern and reproducibility
(interlaboratory, by ICP-OES) fora representative set of constituents. Inferences may be possible
concerning the interlaboratory reproducibility for other elements, depending on the relative contributions to
variance, between intralaboratory and interlaboratory effects.

A Perkin Elmer model ELAN  DRC II will be used in both standard and dynamic reaction chamber (DRC)
modes. Standard analysis mode will be used for all analytes except for As and Se, which will be  run in DRC
mode with 0.5 mL/min of oxygen as the reaction gas. Seven-point standard curves will be used for an
analytical range between approximately 0.5 ug/L and 500 ug/L and completed before each analysis.
Analytical blanks and analytical check standards at approximately 50 ug/L will be run every 10 to 20
samples and are required to be within 15% of the specified value. Samples for analysis will be diluted
gravimetrically to within the targeted analytical range using 1% v/v Optima grade nitric acid (Fisher
Scientific). Initially, analyses for 10:1 dilutions will be performed to minimize total dissolved loading to the
instrument. Additional dilutions at 100:1 and  1000:1 will be analyzed if the calibration range is  exceeded with
the 10:1 dilution. 50 uL of a 10 mg/L internal standard consisting of indium (In) (for mass range below 150)
and bismuth (Bi) (for mass range over 150) will be added to 10 mL of sample aliquot prior to analysis.
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Analytical matrix spikes will be completed for one of each of the replicate eluates from Method 1313. For
each analytical matrix spike, a volume between 10 |jl_ and 100 |jl_ of a 10 mg/L standard solution will be
added to 10 ml of sample aliquot.

ICP-OES Analyses

ICP-OES analyses of aqueous samples from laboratory leaching tests will be carried out at Vanderbilt
University (Department of Civil and Environmental Engineering) using a Varian ICP Model 720-ES. Five-
point standard curves will be used for an analytical range between approximately 0.1 mg/L and 25 mg/L for
trace metals. Seven-point standard curves will be used for an analytical range between approximately 0.1
mg/L and 500 mg/L for minerals. Analytical blanks and analytical check standards at approximately 0.5 mg/L
will be run every 10 to 20 samples and are required to be within 15% of the specified value. Initially,
analyses will be performed on undiluted samples to minimize total dissolved loading to the instrument.
Samples for analysis will be diluted gravimetrically to within the targeted analytical range using 1 % v/v
Optima grade nitric acid (Fisher Scientific) if the maximum calibration is exceeded. Yttrium at 10 mg/L will be
used as the internal standard. Analytical matrix spikes will be completed for three test positions from one of
the replicate eluates from Method 1313. For each analytical matrix spike, a volume of 500 uL of a 10 mg/L
standard solution will be added to 5 mL of sample aliquot.

Table 5-2 provides the element analyzed, method detection limit (MDL), and minimum level of quantification
(ML). Analyte concentrations measured that are  less than the ML and greater than the MDL are reported as
estimated value using the instrument response.
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Table 5-2.   Method Detection Limits (MDLs) and Minimum Level of Quantification (ML) for ICP-OES Analysis on
            Liquid Samples*
Symbol
Al
Sb
As
Ba
Be
B
Cd
Ca
Cr
Co
Cu
Fe
Pb
Li
Mg
Mn
Mo
Ni
K
P
Se
Si
Ag
Na
Sr
S
Tl
Sn
Ti
V
Zn
Zr
Units
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
MDL
1.00
8.00
15.0
1.00
5.00
1.00
6.00
3.50
1.00
1.00
4.1
2.90
7.00
6.00
1.00
3.60
1.00
2.20
1.50
6.2
17.0
2.80
18.00
3.50
1.00
8.30
5.00
17.0
6.40
1.30
2.50
2.70
ML
3.18
25.4
47.7
3.18
15.9
3.18
19.1
11.1
3.18
3.18
13.0
9.22
22.3
19.1
3.18
11.4
3.18
7.00
4.77
19.7
54.1
8.90
57.2
11.1
3.18
26.4
15.9
54.1
20.3
4.13
7.95
8.59
* All elements indicated in Table 5.2 will be analyzed, however, only elements indicated in bold are reported as part of the
leaching studies.
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5.2.4  X-Ray Fluorescence (XRF)

X-Ray Fluorescence Spectrometry is used in the USEPA RTP, NC laboratories to analyze a sample of the
raw fly ash for the determination of total content for the major elements. A Philips model PW2404
wavelength dispersive instrument, equipped with a PW2540 VRC sample changer, is used for these
analyses. The manufacturer's software suite, "SuperQ", is used to operate the instrument, collect the data,
and perform quantification.

The instrument was calibrated using a manufacturer-supplied set of calibration standards at the time of
installation of the software plus a new X-ray tube. On a monthly basis, manufacturer-supplied drift correction
standards are used to create an updated drift correction factor for each potential analytical line. On a
monthly basis, a dedicated suite of QC samples are analyzed before and after the drift correction procedure.
This data is used to update and maintain the  instrument's QC charts. The SOP for this QC procedure (SOP
No. 5003.3; "Procedure for the Philips PW2404 XRF Monthly Drift Correction, Quality Control Stability
Check, QC Chart Update, and Database Backup.") is maintained in a 3-ring binder located at the control
module for the spectrometer, along with all other operational SOPs. Any deviations from these QC
parameters will be documented to the EPA WAM.

The software suite's "Measure and Analyze"  program collects and stores the sample data. This program has
two basic modes of operation, "scan" and "channels". The scan mode is used to collect the bulk of the data.
It operates in a stepwise scanning mode and uses the manufacturer supplied "IQ+" program to define
operating parameters. IQ+ scans the available wavelength range using a series of 10 sub-scans that vary in
terms of detector, radiant power, collimator crystal, and wavelength. While the instrument incorporates a
sample rotation capability, this is not used by IQ+ since the time spent at any one wavelength is only a
fraction of the pellet rotation time.

The channel mode is  typically reserved for trace work. In this mode, the instrument moves to a specific
wavelength and goniometer position and collects data for defined periods of time.  These data collection
periods are typically long enough to make use of the sample rotation function worth while. Other instrument
operation parameters, such as tube power and crystal, are taken from the scan function parameters. The
data collected in the channel mode is then incorporated into the sample's data file. The intent is to improve
detection limits for certain trace elements that are often of interest at a small cost in analytical time.

Quantification is performed post-data collection using the program, "IQ+". IQ+ is a "first principles"
quantification program that includes complex calculations to account for a wide variety of sample-specific
parameters.  For this reason, sample-specific calibrations are not necessary. This program calculates both
peak heights and baseline values. The difference is then used, after adjustment by drift correction factors,
for elemental quantification versus the calibration data. Interelement effects are possible and the software
includes a library of such parameters. Data from secondary lines may be used for quantification where
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interelement effects are significant or the primary peak is overloading the DAQ. Where the difference
between the calculated peak height and baseline are of low quality, the program will not identify a peak and
will not report results. IQ+ permits the inclusion of data from other sources by manual entry. Carbon is an
example of this for these samples. Entry of other source data for elements indeterminable by XRF improves
the mass balance.

5.2.5  XRF Detection Limits

Table 5-3  presents detection limit data in two forms, which are not mutually exclusive. The reporting limit is
built into the software and reflects the manufacturer's willingness to report low-level data.  Data listed under
"detection limit" are based upon the short-term reproducibility of replicate analyses and are sample matrix
specific. These calculations are likely to report higher detection limits for macro elements than what would
be calculated where the same element is present at trace levels. In this data set, calcium  is a likely example
of this.
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Table 5-3. XRF Reporting and Detection Limits
Analyte Reporting Limit, (jg/g
Al
As
Ba
Br
Ca
Cd
Ce
Cl
Co
Cr
Cu
F
Fe
Ga
Ge
K
La
Mg
Mn
Mo
Na
Nb
Ni
Pb
Px
Rb
Sc
Se
Si
Sr
Sx
Ti
V
W
Y
Zn
Zr
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
Detection Limit %, 2a (wt. %)
0.016
0.038
0.0084
0.02
0.1
0.064
0.022
0.0046
0.0024
0.0028
0.0014
0.082
0.034
0.0016
0.0014
0.0048
0.0054
0.01
0.0032
0.0026
0.0076
0.0018
0.0048
0.0034
0.004
0.0016
0.0016
0.0018
0.092
0.0016
0.05
0.003
0.0038
0.0036
0.0018
0.0014
0.0024
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5.2.6  Radionuclide Testing of CCRs using Ge-Detector

Fly ash, gypsum, and other CCRs were collected and assessed to determine their specific activity [Bq/kg].
Samples were taken from a variety of different sources to compare trends in radioactivity, such as that of
bituminous and sub-bituminous CCRs. Samples will be analyzed using two High Purity Germanium (HPGe)
photon detector with low energy detection capabilities, in a common geometry.

Detector 1: Ortec model GMX35P4 high purity germanium coaxial detector, 55.6 mm diameter, 79 mm
length, 0.5 mm beryllium window, rated resolution 2.1 keV at 1332 keV, 31.5% relative efficiency at 1332
keV, GammaVision version 6.01 analytical software, 2003.

Detector 2: Canberra model BE3830 high purity germanium coaxial detector, 70 mm diameter, 30 mm
length, 0.6 mm beryllium window, rated resolution 1.6 keV at 1332 keV, 27.9% relative efficiency at 1332
keV, Genie 2000 version 32.1 analytical software, 2009.

Project samples of fly ash and other coal  combustion residues are received as dry materials and will be
placed in plastic vials of approximately 250 ml and sealed to allow ingrowth of radon gas into equilibrium
with its parent nuclide, as peaks from the radon  progeny are key to identification of the parent nuclide.
Sample containers are placed on the coaxial germanium photon detector systems and counted with shields
closed.  Traceable calibration standards in the same geometry had previously been counted on these
systems to establish system calibrations.  Samples are counted  for times determined to be adequate to
attain reasonable Minimum Detectable Activity (MDA) levels, 8 hours for fly ash and  12 hours for other
residues. Results are given as values of activity  per unit mass of sample, with associated uncertainties and
MDA values. As MDAs are derived by pre-established regions on the gamma spectroscopy spectra which
varies sample by sample, MDAs for a given nuclide on a particular system are  slightly different for each
sample  but are generally consistent on a  given detector for a stated geometry and count time. Fly ash
samples are counted for 8 hrs,  while all other samples are counted for 12 hr periods. The background
characteristics of a number of photopeaks essential to the detection of U-238 and Th-232 decay series were
determined over several weeks, and MDA levels were determined for each of the relevant regions.

The following  photopeaks are used to determine activity in the U-238 decay series:

186keV(Ra-226)
295keV(Pb-214)
352keV(Pb-214)
609keV(Bi-214)
1754keV(Bi-214)

The following  photopeaks are used to determine activity in the Th-232 decay series:

583 keV (TI-208)
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911 keV (Ac-228)
Other photopeaks are evaluated regularly as naturally occurring peaks:
511 keV (various)
662keV(Cs-137)
1460keV(K-40)
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6. Quality Assurance/Quality Control

6.1    Data Quality Indicator Goals

Data quality indicator (DQI) goals for critical measurements in terms of accuracy, precision and
completeness are shown in Table 6-1. In addition, critical data quality indicator goals are inclusion of at least
6 independent laboratories in addition to the referee laboratory and 3 materials for each leaching test
method evaluated.

These goals are based on past performance and will be assessed as the project is completed. Any
deviations from these stated DQIs will be documented to the EPA WAM.

Table 6-1.   Data Quality Indicator Goals
Measurement
ICP-OES constituents (e.g., As, B, Ba,
Ca, Co, Cr, Mo, Sb, Se, V)
Concentration
pH, conductivity
Moisture
Hg
XRF
ICP/MS
Method
ICP-OES
Electrode
ASTM D2216-05
7470
SOP No. 5003.3
6020
Accuracy
±10%
±2%
NA
±10%
±2%
±10%
Precision
±10%
±2%
±10%
±10%
±10%
±10%
Completeness
>90%
100%
100%
90%
100%
90%
NA= not applicable.

For the ICP-OES, accuracy is assessed using calibration verifications and laboratory control samples.
Precision is assessed by replicate measurements. For the pH measurements, a standard of known pH will
be checked prior to taking sample measurements. Precision is assessed by replicate measurements. There
is not a standard reference material for moisture accuracy. Precision will again be assessed by replicate
measurements.

In addition to the DQI goals shown in Table 6-1, homogeneity of the reference material will be considered
acceptable if the following criteria are met by XRF. Major constituents are elements found at concentrations
of more than 1%.

•   RSD<10% for major constituents (greater than 1 % total content)

•   RSD<20% for minor constituents (greater than 0.1 to 1 % total content)
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•   RSD<50% for trace constituents (less than 0.1 % total content.

Accuracy will be determined by calculating the percent bias from a known standard. Precision will be
calculated as relative percent difference (RPD) between duplicate values and relative standard deviation
(RSD) for parameters that have more than two replicates. Completeness is defined as the percentage of
measurements that meet DQI goals of the total number measurements taken.

6.2   QC Sample Types

Types of QC samples used in this project will include blanks, spiked samples, replicates, and mass balance
tests on the leaching reference material. For physical characterization testing, duplicate samples of the
CCR, leaching reference material will be processed through each analysis. The initial criteria will be
determined on the screening data (the six replicates conducted by the ARCADIS referee laboratory) through
a statistical review. This is done by looking at the leaching curves and bounding the data by the 5th and 95th
percentiles as predicted by linear interpolations. The individual criteria will be determined by OCRC, ORD,
Vanderbilt, and ARCADIS when they conduct this same statistical review on the data collected by each
laboratory.. As recommended by ORCR, each lab will be asked to have their extractions performed by a
single operator on a single instrument in a single batch to minimize variability inherent to the determinative
method; all leaching test eluates will be analyzed by ICP-OES for selected constituents  by Vanderbilt to
minimize variability associated with the metals analysis step since the focus of this study is on the leaching
test methods not chemical analysis.

The EPA Metrology  laboratory completes periodic and requested calibrations as described in SOPs and
standard methods for equipment such as balances.
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7. Data Reduction, Validation, and Reporting

7.1    Data Analysis

Interlaboratory comparisons of each method and material will be based on sets of analytes that are (i)
representative of the range of characteristic behaviors anticipated for the material being tested and the test
method being evaluated, and (ii) either analyzed as part of the laboratory procedure (e.g., pH) or analyzed
as part of a single ICP-OES analytical method. Thus, it is anticipated that although some analytes will be
common amongst different test materials being used in the interlaboratory comparisons, the complete set of
analytes will likely be different for each test material because of different characteristic behaviors (e.g., as a
function of pH and  LS) and leaching concentrations relative to analytical detection limits. At least 6 analytes
will be used as the basis for evaluation for each test material with priority given to analytes that are of
regulatory interest and those that are major constituents of each test material. An initial set of analytes for
each test material will be selected based on prior knowledge of the type of each test material selected (e.g.,
coal fly ash, cement stabilized waste, blast furnace slag). The final set of analytes for each test material will
be selected based  on the test method results obtained by the referee laboratory with the concurrence of the
project team, including the EPA QA Representative, and prior to beginning analysis of samples from the
participant laboratories.

The basis of the interlaboratory comparisons will be the dependent variables that are intended to be the
information derived from each test procedure using the set of constituents selected for the test material
being tested. The set of dependent variables for each test method are specified in the sub-sections that
follow. The variance of the following additional analytes will be evaluated as reported by the referee
laboratory and each participant laboratory to provide insights into material variability and methods
implementation: moisture content, eluate pH, eluate conductivity.

Method 1313

The primary information to be derived from this test method  is (i) the pH dependent leaching behavior of
constituents of interest, and (ii) the pH titration curve of the material. The dependent variables that will serve
as the basis for evaluation will be (i) material natural pH (as defined in the test method), (ii) eluate analyte
concentration as determined forthe method target pH values (i.e., 2.0, 4.0, 5.5, 7.0, 8.0, 9.0,12.0,13.0,
natural pH, 10.5), and (iii) equivalents of acid or base required to be added to achieve the method target pH
values (i.e., the pH titration curve). Variation in the actual pH about the target pH value of each eluate but
within the tolerances specified  in the test method will require interpolation or extrapolation of measured
analyte concentration values to the precise target value. The initial method will be linear interpolation of the
analyte concentration to the target pH value based on the log transform of the analyte concentration from the
eluates having the  nearest pH value greater than and less than the target value.  If this method is found to
provide poor representation of the overall pH dependent behavior of the analyte, then other interpolation
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methods such as cubic splines or fifth-order polynomial fitting will be considered. The decision on the
interpolation method will be based on the results obtained from the referee laboratory, prior to initiating
evaluation of data from the participant laboratories. The same approach will be used for interpolation
required to determine the equivalents of acid or base needed to be added to obtain the target eluate pH
values. An ANOVA statistical evaluation (see below for ANOVA specification) will be used to evaluate the
contributions to variance and method precision for the discrete values of the dependent variables at each
target value  of the appropriate independent variable.

An alternate method of data  interpretation of the dependent variables will be based on the functional
relationship of the dependent variable to the specified independent variable (i.e., analyte concentration  as a
function of pH or eluate pH as a function of acid or base addition). Thus, potential functional relationships
(e.g., fifth order polynomials) will be regressed to the data set to provide a defined function to represent the
overall result for each analyte. The contributions to variance in the resulting function then would serve as the
basis for evaluating the method precision (see below for specification of statistical analysis of functional
relationships).

Method 1314

The  primary information to be derived from this test method is (i) the eluate pH and analyte concentration as
a function of LS, and (ii) the cumulative  release (i.e., mg of analyte per kg of material leached) of each
analyte as a function of LS. The analyte concentration measured for eluates obtained at cumulative LS
values of 0.2 and 0.5 can also be considered estimates of pore water composition and  compared with
similar estimates obtained from Method 1316. This interlaboratory comparison will be based on a complete
characterization sampling scheme (Option  A as specified in section 12.5.1.1 of the test method). The
dependent variables that will serve as the basis for evaluation will be (i) eluate pH as determined at the
method target LS values (i.e., 0.2, 0.5,1.0,1.5, 2.0, 4.5, 5.0, 9.5, 10.0), (ii) eluate analyte concentration as
determined at the method target LS values, and (iii) cumulative analyte release as determined at the method
target LS values. Variation in the actual LS about the target LS value of each eluate but within the tolerances
specified in the test method will require  interpolation or extrapolation of measured analyte concentration
values to the precise target value. The initial method of interpolation considered will be linear interpolation of
the analyte concentration to the target LS value based on the log transform of the analyte concentration from
the eluates having the nearest  LS value greater than and less than the target value. If this method is found
to provide poor representation of the overall LS dependent behavior of the analyte, then other interpolation
methods such as cubic splines or exponential decay or error function curves will be considered. A common
approach will be used for interpolation of eluate pH to the target LS values. The decision on the interpolation
method to be used will be based on the results obtained from the referee laboratory and prior to initiating
evaluation of data from the participant laboratories. An ANOVA statistical evaluation (see below for ANOVA
specification) will be used to  evaluate the contributions to variance and  method precision for the discrete
values of the dependent variables at each target value of the appropriate independent variable.
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An alternate method of data interpretation of the dependent variables will be based on the functional
relationship of the dependent variable to the specified independent variable (i.e., analyte concentration as a
function of LS or cumulative release as a function of LS). Thus, potential functional relationships (e.g.,
exponential decay, error function or polynomial functions) will be regressed to the data set to provide a
defined function to represent the overall result for each analyte. The  contributions to variance in the resulting
function then would serve as the basis for evaluating the method precision (see below for specification of
statistical analysis of functional relationships).

Method 1315

The primary information to be derived from this test method is (i) the eluate pH and analyte flux as a function
of time, (ii) the cumulative release (i.e., mg of analyte perm2 of material leached based on the external
geometric surface area of exposed faces) of each analyte as a function of time, and (iii) the mean observed
diffusivity2 of each analyte when diffusion controlled  release is indicated (see Section  13.2 of Method 1315).
The dependent variables that will serve as the basis for evaluation will be (i) eluate pH as determined at
each method leaching interval (i.e., cumulative leaching times of 0.08,1.0, 2.0, 7.0, 14.0, 28.0, 42.0, 49.0
and 63.0 days; see Table 1 of Method 1315),  (ii) eluate analyte concentration as determined for each
method leaching interval, (iii) cumulative analyte release for each leaching interval, (iv) analyte mean flux
over each leaching interval, and (v) observed  diffusivity for each analyte when applicable. Interpolation for
determined concentrations and derived values of cumulative release and flux should not be necessary as
long as leaching intervals are maintained within tolerances specified in the test method.  An analysis of
variance (ANOVA) statistical evaluation (see below) will be used to evaluate the contributions to variance
and method precision for the discrete values of the dependent variables at each target value of the
appropriate independent variable.

Method 1316

The primary information to be derived from this test method is (i) the eluate pH and analyte concentration as
a function of LS, and (ii) the release (i.e., mg of analyte per kg of material leached) of each analyte as a
function of LS. The dependent variables that will serve as the basis for evaluation will be (i) eluate pH as
determined at the method target LS values (i.e., 0.5,1.0, 2.0, 5.0,10.0), (ii) eluate analyte concentration as
determined at the method target LS values, (iii) analyte release as determined at the method target LS
values, and (iv) an estimate of analyte concentration at LS value of 0.2 which can also be compared with the
2 There will be up to 9 individual observations of observed diffusivity (one for each leaching interval) from each replicate
of each application of Method 1315 for each specified analyte. Thus, a mean and standard deviation will be reported for
each observed diffusivity value.
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analyte concentration at LS value of 0.2 from Method 1314. Discrete values of each analyte are measured at
each LS value and therefore interpolation will not be needed; however extrapolation of the functional
relationship of analyte concentration as a function of LS will be needed to estimate the concentration at LS
of 0.2.  Extrapolation of analyte concentration as a function of LS to LS of 0.2 will be accomplished by
regressing a functional relationship (e.g., linear, exponential or polynomial) to measured analyte
concentrations in eluates from other LS values. Different functional relationships may be necessary for
different analytes. The decision on the interpolation method to be used will be based on the results obtained
from the referee laboratory and prior to initiating evaluation of data from the participant laboratories. An
ANOVA statistical evaluation (see below) will be used to evaluate the contributions to variance and method
precision for the discrete values of the dependent variables at each target value of the appropriate
independent variable.

Statistical Analysis of Variance

The basic method of data analysis is provided as follows in the context of Method 1313 for a single analyte
and a single material. The same approach will be used for Methods 1314,1315 and 1316, as well as for
multiple materials. It assumes that the interpolation to target measurement values (i.e., target pH values for
Method 1313 and target LS values for Method 1314)  has been performed and determined to be acceptable
as described  in the section titled "Outlier Identification and Model Assumption Checking." In the definitions
given as follows, the convention is that a "measurement" refers to a log-transformed analyte concentration or
other dependent variable value:

Y..k =kth measurement at the fh target pH for the ith lab,

where

    /' = l,...,M (M =numberof labs in the study, where the reference lab is the Mth),

    j = 1,...,9 (the number of pH levels), and

    k = 1,2,3 for participant labs 1 through  M -l;k = 1,...,6 for the reference lab M

The statistical model underlying the analysis of variance is a mixed-effects model with fixed effects for pH
level, and random effects for labs and lab-by-pH interactions. Specifically,
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where

    /u and aj are fixed effects, to model the overall mean response at different pH levels,

    /? and  Yi; are random effects that model differences among labs, and

    si j k is a  random error term that models variation among replicates within a particular lab and pH
    combination.

The standard assumptions for the model are that /?., yt j  and si; k are independent normal random
variables with zero means and variances 
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methods of interpolation, say via linear, polynomial, and spline curve fitting. If the results are sensitive to the
calibration method, then it is anticipated that a spline method will supplant the proposed linear interpolation.
The interpolation also introduces a secondary source of departure from the basic analysis of variance model
assumptions in the form of dependence between the interpolated measurements. This can be assessed
using advanced modeling features of Proc Mixed in SAS.

Outlier Identification. Possible outliers will be identified using standard methods of plotting residuals and
comparing laboratory-specific summary measures of variability.  It should be emphasized that in a study of
this nature (interlaboratory study) there are multiple notions of what constitutes an "outlier" and these also
manifest themselves as other forms of model violations. For example, the random error term in the statistical
model is usually assumed to have the same variance at all pH levels where it is known that the variance is
different at different pH levels (and is also assumed to be the same at all laboratories). This is directly
checked by comparing between pH and within lab sample variances which can also be accomplished using
advanced features of SAS's Proc Mixed procedure. A lab with a much greater variance than other those of
other labs is a candidate for being declared an outlying lab. Regardless of how alleged outliers are identified,
their impact on the statistical results is most definitively assessed by direct comparison of statistical results
obtained via separate analyses using the full data set and the "cleaned" data set (with outliers removed).

More Advanced Modeling Options. For Method 1313, we are interpolating to the target pH values to have a
consistent comparison of measured concentrations in eluates. Although this approach appears to work quite
well for the fly ash data obtained so far, this may not prove to  be the case with future materials. If this occurs,
the approach would be changed  to compare "curves" rather than individual values,  thus changing to
functional analysis (where "functional" refers to the types  of curve fits used, such as polynomials)._The basic
idea is to fit a smooth curve to the analyte concentration as a function of pH (using the realized pH values)
and then to compare the curves so obtained within labs (to assess repeatability) and among labs (to assess
reproducibility). The basic methods and techniques of functional data analysis are described in the seminal
book by Ramsay and Silverman (1997).

7.2   Chemical (ICP, XRF, AE-OES, OC/EC) and Physical (Moisture) Characterization

These data are reduced and reports are generated automatically by the instrument software or through
spreadsheets. The primary analyst will review 100% of the report for completeness and to ensure that
quality control checks meet established criteria. If QC checks do not meet acceptance criteria, sample
analysis must be repeated. A secondary review will be performed by the  Inorganic Laboratory Manager and
Vanderbilt University to validate the analytical report. If appropriate, certain chemical characterization data
will be compared to the XRF analyses. In addition, the ARCADIS QA Officer will review at least 10% of the
raw data generated by ARCADIS for completeness. Analytical data will be summarized in periodic reports to
the ARCADIS WAL. The procedures for reduction, validation and reporting of the leaching experiments
(Task III) are outlined in the methods (http://www.vanderbilt.edu/leachinq/downloads.html). ARCADIS WAL
                                                                                             C-50
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is responsible for the implementation of these procedures. ARCADIS and Vanderbilt University will be
responsible for publishing results and reports. QA/QC activities will be mentioned in any published materials.
A data quality report will be provided in the final report of this investigation.

Data generated for the leachate analysis and total composition are entered into a standard Excel
spreadsheet to ease uploading into the Vanderbilt metals database from the ICP-MS and other analyses.
This data along with QA/QC information can be viewed using the "LeachXS Lite" software program
developed by Vanderbilt University and the Energy Research Centre of the Netherlands. This software tool
will allow users to view the metals leaching information  based on sample type, facility configuration, or CCR
coal type, or validation laboratory. This data viewer and database program will be available to the public on-
line when complete. In addition, all data generated from the interlaboratory validation study will be archived
by APPCD along with other project documentation.

7.3   Radionuclide Characterization

A Quality Assurance (QA) program involving verification of energy and Full Width at Half Maximum (FWHM)
for several key photopeaks will be implemented. The calibration standard used to establish the system
efficiency as a function of energy will be counted for 5 minutes daily.  The photopeak energy, full width at
half-maximum (FWHM) and  net peak area for Cs-137 (662 keV) will be measured and plotted, with the
FWHM for the 1332 keV peak of Co-60, for both detector systems. Any value occurring outside of 3
standard deviations of the mean (established in a preliminary study of about 20 measurements) must be
immediately recounted. If the recount values are within 3 standard deviations, the system may be used for
sample counting; if not an investigation into the detector reliability must be performed and a diagnosis and
correction of any problems carried out before samples are counted on this system.
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8. Assessments

Assessments and audits are an integral part of a quality system. This project is assigned a QA Category III
and, while desirable, does not require a planned technical systems audit (ISA). The ARCADIS QA Officer
may conduct a ISA at the request of either the EPA WAM or the ARCADIS WAL. Internal assessments will
be performed by project personnel to ensure acquired data meet data quality indicator goals established in
Section 6.

There are currently no planned performance evaluation audits but Table 8-1 lists the measurement
parameters and expected ranges should EPA determine a PEA should be provided.

Table 8-1.   PEA Parameters and Ranges
Analyte or Measurement
As, B,


Ba, Ca, Co, Cr, Mo, Sb, Se, V
Hg
PH
Method
ICP-OES/3052/6020A
7470A
Electrode
Expected Range
1-100 |jg/ml_
0.25to10ug/L
0-14
The ARCADIS QA Officer will perform an internal data quality audit on at least 10% of the reported data.
Reported results will be verified by performing calculations using raw data and information recorded in
laboratory notebooks.
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9. References

ASTM, 1988. Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a
Test Method, Designation: E 691-87 American Society for Testing and Materials, 1988.

ASTM, 2005. Standard test methods for laboratory determination of water (moisture) content of soil and rock
by mass, Method D 2216-05, American Society for Testing and Materials, 2005

ASTM, 2008. Standard test methods for loss on ignition (LOI) of solid combustion residues, Method D 7348-
08, American Society for Testing and Materials, 2008.

ASTM, 2009. Standard test methods for carbon black—total and external surface area by nitrogen
adsorption, Method D 6556-09, American Society for Testing and Materials, 2009.

CDC 2003. Diesel particulate matter (as elemental carbon), Method 5040, Centers for Disease Control,
NIOSH Manual of Analytical Methods (NMAM), Fourth Edition, 2003.

EPA, 1992. Method 1311  "Toxicity Characteristic Leaching Procedure". Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods (SW-846)  U.S. Environmental Protection Agency, 1992.

EPA, 1994. Method 1312 "Synthetic Precipitation Leaching Procedure". Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods (SW-846)  U.S. Environmental Protection Agency, 1994.

EPA, 1996a. Method 3052 "Microwave Assisted Acid Digestion of Siliceous and Organically Based
Matrices". Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846) U.S.
Environmental Protection Agency,  1996.

EPA, 1998. Method 7473, "Mercury in Solids and Solutions by Thermal Decomposition, Amalgamation, and
Atomic Absorption Spectrophotometry." Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods (SW-846). U.S. Environmental Protection Agency, 1998.

EPA, 2002a. Characterization and  Management of Residues from Coal-Fired Power Plants, Interim Report.
EPA-600/R-02, 083, U.S. Environmental Protection Agency,  December 2002.

EPA, 2002b. Reply to comments on EPA/OSWs Proposed Approach to Environmental Assessment of
CCRs. Discussed March 5, 2002.

EPA, 2006a. Sanchez,  F., R. Keeney, D. S. Kosson, and R. Delapp, 2006. Characterization of Mercury-
Enriched Coal Combustion Residues from Electric Utilities Using Enhanced Sorbents for Mercury Control,
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                                                                               Revision: 0
                                                                               Date: November 2011
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EPA-600/R-06/008. Prepared for the U.S. Environmental Protection Agency-Air Pollution Prevention and
Control Division, Contract No. EP-C-04-023, Work Assignment 1-31, February 2006.
www.epa.gov/nrmrl/pubs/600r06008/600r06008.pdf (Accessed November 12, 2009)

EPA, 2006b. Standard Operating Procedure for the Determination of Hexavalent Chromium in Ambient Air
Analyzed by Ion Chromatography (1C). December 2006. Internet address:
http://www.epa.gov/ttn/amtic/airtox.html (Accessed November 12, 2009)

EPA, 2007a. 2005 Urban Air Toxics Monitoring Program (UATMP) - Hexavalent Chromium, U.S.
Environmental Protection Agency, EPA-454/R-07-005, February 2007.

EPA, 2007b. Method 9056A "Determination of Inorganic Anions by Ion Chromatography". Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency,
February 2007.

EPA, 2007c. Method 601OC "Inductively Coupled Plasma-Atomic Emission Spectrometry". Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency,
February 2007.

EPA, 2007d. Method 6020A "Inductively Coupled Mass Spectrometry". Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency, February 2007.

EPA, 2008. Sanchez, F., R. Keeney, D. S. Kosson, and R. Delapp, 2006. Characterization of Mercury-
Enriched Coal Combustion Residues from Electric Utilities Using Wet Scrubbers for Multi-Pollutant Control,
EPA-600/R-08/077. Prepared for the U.S. Environmental Protection Agency-Air Pollution Prevention and
Control Division, Contract No. EP-C-04-023, Work Assignment 4-26, July 2008.
http://www.epa.gov/nrmrl/pubs/600r08077/600r08077.htm (Accessed October 18, 2011)

EPA 2009, Kosson, D., F. Sanchez, P. Kariher,  L.H. Turner, R. Delapp and P. Seignette. Characterization of
Coal Combustion Residues from Electric Utilities - Leaching and Characterization Data. U.S. Environmental
Protection Agency, EPA-600/R-09/151,  December 2009.

EPA. Guidance for Methods Development and Validation for the RCRA Program.
http://www.epa.gov/epawaste/hazard/testmethods/pdfs/methdev.pdf, accessed October 18, 2011.

Kosson, D.S., van derSloot, H.A., Sanchez, F. and Garrabrants, A.C., 2002a. An Integrated Framework for
Evaluating Leaching in Waste Management and Utilization of Secondary Materials. Environmental
Engineering Science 19(3):159-204, 2002.
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Ramsay, J.O. and Silverman, B.W. (1997). Functional Data Analysis. Springer-Verlag (New York).
van der Sloot, et al., 2010 (draft).  Evaluation of Ruggedness Testing Needs for the Percolation Test, pH
Dependence Leaching Test and Monolith Leaching Tests based on Existing Information. The Energy
Research Centre of The Netherlands.
                                                                                             C-57
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                                       Appendix A
                               Laboratory Shipping Address
Name
Affiliation
Shipping Address
James M. Tinjum
University
of
Wisconsin-
Madison
James M. Tinjum, P.E., Ph.D.
University of Wisconsin-Madison
Department of Civil and Environmental Engineering
2214 Engineering Hall
1415 Engineering Drive
Madison, Wl 53706
Mandi Richardson
URS Corp.
Mandi Richardson
URS Corporation
9400 Amberglen Blvd.
Austin, TX 78729
Jianmin Wang
Missouri
University
of Science
and
Technology
Jianmin Wang
Dept. of Civil, Architectural & Environmental Engineering
223 Butler Carlton Hall University of Missouri-Rolla
(UMR)
Rolla, MO 65409
Zuzana Bohrerova
The Ohio
State
University
Zuzana Bohrerova
The Ohio State University
470 Hitchcock Hall
2070 Neil Avenue
Columbus, OH 43210-1275
Catherine Mattus
DOE- Oak
Ridge
National
Laboratory
Catherine Mattus
Oak Ridge National Laboratory
P. OBox2008
1 Bethel Valley Road
Oak Ridge, TN 37831-6181
Eric Pierce
DOE-
Pacific
Northwest
National
Laboratory
Eric M. Pierce
790 6th Street
Richland, WA 99338
                                                                               C-58
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Charles Crawford
DOE-
Savannah
River
National
Laboratory
Charles L. Crawford
Savannah River National Laboratory
Bldg. 773-42A
Savannah River Site
Aiken, SC 29808

Needs to have an internal number attached to the box:

P0# OT0580
Hwidong Kim
University
of Florida
Hwidong Kim
220 Black Hall
Department of Environmental Engineering & Sciences
University of Florida
Gainesville, FL, 32611.
Johnny Mitchell
Test
America
(TVA)
Johnny Mitchell
TestAmerica Laboratories - Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Rosanne Delapp
Vanderbilt
University
Rosanne Delapp
Vanderbilt University
Jacobs Hall 149
400 24th Avenue South
Nashville, TN 37235
Prof. Dr. Rob N.J.
Comans
ECN
Dr. Rob N.J. Comans
ECN Biomass, Coal and Environmental Research
Energy research Centre of the Netherlands
Westerduinweg 3, NL-1755 LE  PETTEN
Neatherlands
Ole Hjelmar
DHI
Ole Hjelmar
DHI
Urban & Industrial Dept.
Agern Alle 5
DK-2970 H0rsholm
Denmark
Jenet T. Hattaway
University
of North
Carolina
Charlotte
Civil & Environmental Engineering
University of North Carolina Charlotte
Cameron Bldg. Rm 267
9201 University City Blvd.
Charlotte, NC 28223-0002
                                                                               C-59
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                  PRELIMINARY VERSION of EPA METHOD 1313

    Liquid-Solid Partitioning as a Function of Extract pH using Parallel Batch Extractions
                      -TM
               LeachXS   Lite Data Template - Version 1.1, January 2010
PROJECT/MATERIAL TITLE SHEET
PROJECT INFORMATION
Project Code

Project Sponsor

Project Description

Material Code
Material Replicate

Material Originator

Material Description

Test Method Lab

Contact

Analytical Lab

Contact
DATABASE INFORMATIOr
Name of Database
Material Code
Material Class
Material Subclass


SIGNATURES
Data Compiler:
Data Reviewer:
Approved by:
LeachXS™ Lite Upload:















Date Complete

Phone

Date Complete

Phone
J







Date:
Date:
Date:
Date:


                                         Page 1
                     C-60
Draft Method 1313 Template Rev 0
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COAL COMBUSTION RESIDUE CLASSIFICATIONS
PROJECT & MATERIAL CODES
             Project Code
           Material Code
        Material Replicate
LeachXS Database Information
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
        Name of Database
           Material Code

RESIDUE DESCRIPTION
            CCR Category I
                   Auto-inserted from "Title Sheet"
                   Auto-inserted from "Title Sheet"
                       Fly Ash Type
                   Residue Handling
                 Citation \please specify
SOURCE DESCRIPTION
               Coal Type |
             Coal Region
                 Facility \please specify
       Facility Description
PROCESS DESCRIPTION
       Particulate Capture [
           Scrubber Type [
    FGD Scrubber Additive [
              NOxControlF
              SO3 ControlF
      Hg Sorbent Injection [
                                                                                                C-61
-------
                   PRE METHOD 1313 LeachXS™ Lite Data Template

MOISTURE CONTENT (WET BASIS) AND SOLIDS CONTENT INSTRUCTIONS

    Step 1: Enter the project, material and replicate codes as well as the name of the technician
    conducting the test.

    Step 2: Measure and record the mass of an empty drying or suitable weighing dish as well as
    the dish containing 5-10 g the "wet" sample. Record data and time of measurement. Place
    dish and sample into over at 105±5 °C for a minimum of 24 hr.

    Step 3: Remove dish and sample from oven and allow to cool to room temperature in a
    desiccator. Measure and record the mass of the dish and dry sample. Place the dish and
    sample back into the oven for at least another 24-hr period.

    Step 4: Repeat cooling and measurement procedure as shown in Step 3 until constant mass
    of the dish and sample is accheived. Record this mass and the final date and time.  Discard
    the sample.

    Step 5: Moisture and solids content are calculated automatically.  Mean SC cell may be
    linked to the solids content cells in Pre-Test data and Test Data sheets.  Alternately, copy the
    Mean SC cell value to these sheets.
                                                                                           C-62
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                              PRE METHOD 1313 LeachXS   Lite Data Template
MOISTURE CONTENT (WET BASIS) AND SOLIDS CONTENT INSTRUCTIONS
r        Project
      Material
 Test Replicate
Code    Description (optional)
        Auto-inserted from "Title Sheet"
        Auto-inserted from "Title Sheet"
                              Empty Dish [g]
                            Dish + Sample [g]
                        Dish + Dry Sample [g]
                 Check (Dish + Dry Sample) [g]
Moisture Content (MC) [g-water/g]
Solids Content (SC) [g-dry/g]








MOISTURE CONTENT (WET BASIS) AND SOLIDS CONTENT INSTRUCTIONS

                 Code    Description (optional)                     Test conducted by:
        Project
      Material
 Test Replicate
        Auto-inserted from "Title Sheet"
        Auto-inserted from "Title Sheet"
                                             Dish-1
                                                       Dish-2
                                                                Dish-3
                              Empty Dish [g]
                            Dish + Sample [g]
                        Dish + Dry Sample [g]
                 Check (Dish + Dry Sample) [g]

             Moisture Content (MC) [g-water/g]
                   Solids Content (SC) [g-dry/g]
MOISTURE CONTENT (WET BASIS) AND SOLIDS CONTENT INSTRUCTIONS

                 Code    Description (optional)                     Test conducted by:
        Project
      Material
 Test Replicate
        Auto-inserted from "Title Sheet"
        Auto-inserted from "Title Sheet"
                                             Dish-1     Dish-2
                                                                Dish-3
                              Empty Dish [g]
                            Dish + Sample [g]
                        Dish + Dry Sample [g]
                 Check (Dish + Dry Sample) [g]

             Moisture Content (MC) [g-water/g]
                   Solids Content (SC) [g-dry/g]
                                                                                                                 C-63
-------
                                                ,TM
                     PreMethod 1313 LeachXSMV1 Lite Data Template

PRE-TEST TITRATION INSTRUCTIONS
     Step 1: Enter the project, material and replicate codes as well as the technician name.  In
     order to initiate test extration setup, enter the maximum particle size, solids content, and
     reagent type and normality.
     Step 2: Enter target acid or base additions from prior knowledge or from prediction of
     neutralization classifications in Draft Method 1313 Table 2 (note: base equivalents have a
     negative sign).

     Step 3: Prepare five bottles, labelled P01 through  P05, with solid material. Add reagent
     water and acid or base to the bottles according to the Schedule of Acid and Base Additions.
     Enter date and time that agitation of extracts begins.

     Step 4: At the conclusion of the test, enter date and time that agitation ends.  Record
     leachate pH. The pre-test titration curve for the material will be plotted automatically
     (note: axis adjustments may be necessary).

     Step 5: From the pre-test titration, select the additions of acid and  base required to
     complete the list of target pH (see Draft Method 1313 Table 5) plotted as horizontal blue
     dashed lines. These acid/base additions are  to be entered into the "Test Data" sheet to
     create the Schedule of Acid and Base Additions.
                                                                                         C-64
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                                                    PreMethod 1313 LeachXS
METHOD 1313 PRE-TESTTITRATION
                                                                                                                                                         Extraction Information
                       Code
            Project
           Material
      Test Replicate
          Test Start
           Test End
Description (optional)
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
                                                                              Test conducted by:
                       Date
                                  Time
         Required Contact Time :
           [hr]
                                                            Solids Information
                                   Particle Size (85 wt% less than)
                                  Minimum Dry Equivalent Mass *
                                      Solids Content (default = 1)
                           Mass of "As Tested" Material / Extraction
                                                     * Data based on Draft Method 1313 Table 1.
J mm
 g-dry
] g-dry/g
                 LS Ratio
 Liquid Volume / Extraction
Recommended Bottle Size *
             Temperature
                                       Acid Normality
                                            Base Type
                                       Base Normality
10
200
250

mL/g-dry
ml
ml
°C
                               Schedule of Acid and Base Addition (±0.05)
                   Test Position     P01        P02       P03        P04
     "As Tested" Solid [g]  (±0.05g)      -
        Reagent Water [ml] (±5%)      -
         Acid Volume [ml] (±1%)      '-
         Base Volume [ml] (±1%)      -
                                             P05
                                                     additional extracts as needed
                                                        P06        P07        P08
                                                                                         P09
                                                                                                   P10
                                                                                                                     Total Solid
                                                                                                                   Total Water
                                                                                                                     Total Acid
                                                                                                                     Total Base
           Acid Addition [meq/g]
                      Eluate pH
Eluate pH

12 -
10 -
8 -
6 -
4 -
2 -





A Targets
X Natural pH








-3 -2.5 -2 -1.5 -1 -0.5 0 0.5 1 1.5
Acid Addition [meq/g]


2 2.5 3
                                                                                     Acid Addition
                                                                                      Required
                                                                                    [meg/g-dry]  pH Target
                                                                                Rationale
0










2.0
4.0
5.5
7.0
8.0
9.0
12.0
13.0
10.5
1
±0.5
±0.5
±0.5
±0.5
±0.5
±0.5
±0.5
±0.5
±0.5
Natural pH at LS 10 mL/g-dry (no acid/base addition)
Provides total or available content of COPCs
Lower pH limit of typical management scenario
Typical lower range of industrial waste landfills
Neutral pH region; high release of oxyanions
Endpoint pH of carbonated alkaline materials
Minimum of LSP curve for many cationic and amphoteric COPCs
Maximum in alkaline range for LSP curves of amphoteric COPCs
Upper bound (field conditions) for amphoteric COPCs
Substitution if natural pH falls within range of a mandatory pH target
                                                                                                                                                                   C-65
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                                                          TM
                               PreMethod 1313 LeachXS"vl Lite Data Template
Table 1    Extraction Parameters as a Function of Particle Size
Particle
Size
(85% less
[mm]
0.3
2
5
US Sieve
Size
than)

50
10
4
Minimum
Dry
Equivalent
[g-dry]
20±0.02
40±0.02
80±0.02
Contact
Time

[h]
24±2
48±2
72±2
Suggested
Vessel
Size
[ml]
250
500
1000
Table 3    Pre-Test Tiration Schedule
Neutralization
Classification
Low Alkalinity
Moderate Alkalinity
High Alkalinity
P01
-2
-2
0
Acid or Base Addition [meq/g-dry]
P02 P03 P04
-101
025
5 10 15
P05
2
10
25
Additional data points (e.g., T06, T07, T08 ...) may be needed to provide titration curve resolution
                                                                                           C-66
-------
                                                -TM
                    PRE METHOD 1313 LeachXS   Lite Data Template

EXTRACTION TEST INSTRUCTIONS
     Step 1: Enter the project, material and replicate codes as well as the technician name. To
     initiate test setup, enter the maximum particle size, solids content, and reagent type and
     normality

     Step 2: Enter target acid or base additions from prior knowledge or from the pre-test
     titration  (note: base equivalents have a negative sign).
    ^^^^^^^^^^H             •
     Step 3: Add solid material to nine bottles, labelled T01 through T09. Label an additional
     three bottles as blanks (B01, B02, and BOS). Add Dl water and acid or base to eleven
     bottles (i.e,., TOx and BOx bottles) according to the Schedule of Acid and Base Additions.
     Enter date/time that extract agitation begins.

     Note: If the acid or base is too dilute, large volume addition will be necessary.  The acid or
     base normality may be adjusted for individual extractions.
     Step 4: At the conclusion of the test, enter date and time that agitation ends. Record
     leachate information. Leachate pH and electrical conductivity (EC) will be plotted
     automatically (note: axis adjustments may be necessary).
     Step 5: If the pH of the extract is within the target range and an analytical sample is to be
     saved, enter the letter "a" in the last row (font converts "a" to a check mark). If the extract
     will not be saved for chemical analysis, enter the letter "r" in the last row (font converts "r"
     toanX).
                                                                                       C-67
-------
                                                                                        TM
                                                          PRE METHOD 1313 LeachXS   Lite Data Template
METHOD 1313 EXTRACTION DATA
                      Code
            Project
           Material
      Test Replicate
          Test Start
           Test End
                          Description (optional)
                          Auto-inserted from "Title Sheet"
                          Auto-inserted from "Title Sheet"
            Test conducted by:|_
                       Date
                                 Time
                                   Solids Information
                  Maximum Particle Size |	| mm
          Minimum Dry Equivalent Mass *            g-dry
              Solids Content (default = 1)          ] g-dry/g
   Mass of "As Tested" Material / Extraction          I g
                 LS Ratio
 Liquid Volume / Extraction
Recommended Bottle Size *
Extraction Information
               mL/g-dry
               ml
               ml
         Required Contact Time '
                                    hr
* Data based on Draft Method 1313 Table 1.
                                                                                                                        Temperature[
           Acid Normality
               Base Type
           Base Normality
                          Schedule of Acid and Base Addition
             Test Position     T01      T02       T03
"As Tested" Solid [g] (±0.05g)
   Reagent Water [ml] (±5%)
    Acid Volume [ml] (±1%)
    Base Volume [ml] (±1%)
   Acid Normality [meq/mL]
   Base Normality [meq/mL]
                                                               T04
                                                                        T05
                                                                                  T06
                                                                                            T07
                                                                                                     T08
                                                                                                               T09
                                                                                                                         B01
-
—
_
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
no solid
-
—
_
no solid
-
—
_
no solid
-
—
_
                   Target pH
           Acid Addition [meq/g]
                     EluatepH
              Eluate EC [mS/cm]
                 EluateEh[mV]
              Meets pH criteria?
                        Notes
                                13.0±0.5  12.0±0.5   10.5±0.5   9.0±0.5    8.0±0.5    7.0±0.5   5.5±0.5    4.0±0.5    2.0±0.5
                                                                                                                   Water
                                                                                                                            Nominal Reagent Information
                                                                                                                                   B02
                                                                                                                              Acid
                                                                                                                                       Base
                                                                                                                                               Enter "a" for "yes" or
                                                                                                                                                  "r" for "no".
-------
                                                                                         TM
                                                          PRE METHOD 1313 LeachXS    Lite Data Template
METHOD 1313 EXTRACTION DATA
                                                                                                                                     Extraction Information
                       Code
            Project
           Material
      Test Replicate
          Test Start
           Test End
Description (optional)
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
            Test conducted by:[_
                       Date
                                 Time
         Required Contact Time'
                  Test Position
     "As Tested" Solid [g] (±0.05g)
        Reagent Water [ml] (±5%)
         Acid Volume [ml] (±1%)
         Base Volume [ml] (±1%)
        Acid Normality [meq/mL]
        Base Normality [meq/mL]

                   Target pH
           Acid Addition [meq/g]
                      Eluate pH
              Eluate EC [mS/cm]
                 Eluate Eh [mV]
         Save? (enter "a" or "r"
                        Notes
          hr
                                   Solids Information
                  Maximum Particle Size |	| mm
          Minimum Dry Equivalent Mass *           g-dry
              Solids Content (default = 1) |          \ g-dry/g
   Mass of "As Tested" Material / Extraction          I g

* Data based on Draft Method 1313 Table 1.
                 LS Ratio
 Liquid Volume / Extraction
Recommended Bottle Size *
                                                                                                                                              10
                                                                                               Temperature[
                 Nominal Reagent Information
               Acid Type
           Acid Normality
               Base Type
           Base Normality
                               Schedule of Acid and Base Addition
                                  T01      T02      T03       T04
                                                                         T05
                                                                                  T06
                                                                                            T07
                                                                                                      T08
                                                                                                                T09
                                                                                                                          B01
                                                                                                                                   B02
                                                                                                                                             B03
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
no solid
-
-
-
:
no solid
-
-
-
:
no solid
-
-
-
:
 13.0±0.5  12.0±0.5   10.5±0.5   9.0±0.5    8.0±0.5    7.0±0.5    5.5±0.5   4.0±0.5    2.0±0.5
                                                                                                              Base
                                                                                                    Note:  If multiple
                                                                                                    replicate tests are
                                                                                                    carried out in
                                                                                                    parallel, only one set
                                                                                                    of method blanks is
                                                                                                    necessary.
                                                                                                                                                              C-69
-------
                                                                                         TM
                                                          PRE METHOD 1313 LeachXS    Lite Data Template
METHOD 1313 EXTRACTION DATA
                                                                                                                                     Extraction Information
                       Code
            Project
           Material
      Test Replicate
          Test Start
           Test End
Description (optional)
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
            Test conducted by:[_
                       Date
                                 Time
         Required Contact Time'
                  Test Position
     "As Tested" Solid [g] (±0.05g)
        Reagent Water [ml] (±5%)
         Acid Volume [ml] (±1%)
         Base Volume [ml] (±1%)
        Acid Normality [meq/mL]
        Base Normality [meq/mL]

                   Target pH
           Acid Addition [meq/g]
                      Eluate pH
              Eluate EC [mS/cm]
                 Eluate Eh [mV]
         Save? (enter "a" or "r"
                        Notes
          hr
                                   Solids Information
                  Maximum Particle Size |	| mm
          Minimum Dry Equivalent Mass *           g-dry
              Solids Content (default = 1) |          \ g-dry/g
   Mass of "As Tested" Material / Extraction          I g

* Data based on Draft Method 1313 Table 1.
                 LS Ratio
 Liquid Volume / Extraction
Recommended Bottle Size *
                                                                                                                                              10
                                                                                               Temperature[
                 Nominal Reagent Information
               Acid Type
           Acid Normality
               Base Type
           Base Normality
                               Schedule of Acid and Base Addition
                                  T01      T02      T03       T04
                                                                         T05
                                                                                  T06
                                                                                            T07
                                                                                                      T08
                                                                                                                T09
                                                                                                                          B01
                                                                                                                                   B02
                                                                                                                                             B03
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
no solid
-
-
-
:
no solid
-
-
-
:
no solid
-
-
-
:
 13.0±0.5  12.0±0.5   10.5±0.5   9.0±0.5    8.0±0.5    7.0±0.5    5.5±0.5   4.0±0.5    2.0±0.5
                                                                                                              Base
                                                                                                    Note:  If multiple
                                                                                                    replicate tests are
                                                                                                    carried out in
                                                                                                    parallel, only one set
                                                                                                    of method blanks is
                                                                                                    necessary.
                                                                                                                                                              C-70
-------
                                                                                  TM
                                                   PRE METHOD 1313 LeachXS   Lite Data Template
Table 4
Extraction Parameters as a Function of Particle Size
Table 5    Final Extract pH Targets
Maximum
Particle
Size
[mm]
0.3
2
5
US Sieve
Size


50
10
4
Minimum
Dry
Equivalent
[g-dry]
20±0.02
40±0.02
80±0.02
Contact
Time

[h]
24±2
48±2
72±2
Suggested
Vessel
Size
[mL]
250
500
1000
                                                                      pH Target Rationale
                                                                        varies  Natural pH at LS 10 mL/g-dry (no acid/base addition)
                                                                       2.0±0.5  Provides total or available COPC content
                                                                       4.0±0.5  Lower pH limit of typical management scenario
                                                                       5.5±0.5  Typical lower range of industrial waste landfills
                                                                       7.0±0.5  Neutral pH region; high release of oxyanions
                                                                       8.0±0.5  Endpoint for carbonated alkaline materials
                                                                       9.0±0.5  Minimum of LSP curve for many cationic and amphoteric COPCs
                                                                       12.0±0.5 Maximum in alkaline range for LSP curves of amphoteric COPCs
                                                                       13.0±0.5 Upper bound (field conditions) for amphoteric COPCs
                                                                       10.5±0.5 Substitution if natural pH falls within another mandatory target

M_
1 O .

1 n -
_ Q .
Q_
$
ro
3 R -
UJ b













1 -0.5 0 0.5
Acid Added [meq/g-dry]


•
-*-






1


A
B
C







                                                                                        1000 -r
                                                                                 .o
                                                                                 (0
                                                                                 •c
                                                                                 o
                                                                                 o
                                                                                         100 •
                                                                                          10 •
                                                                                           1 •
                                                                                          0.1
                                                                                             -1            -0.5           0

                                                                                                       Acid Added [meq/g-dry]
                                                                                                                          0.5
                                                                                                                                                    C-71
-------
                    PreMethod 1313 LeachXS™ Lite Data Template

SELECTION OF ANALYTICAL SOLUTIONS
    This page is for selection of a final set of nine extractions per test replicate from the "Lab
    Extractions" data. All data is manually input by the user based on if extraction meet the pH
    criteria.
                                                                                   C-72
-------
METHOD 1313 SELECTED ANALYTICAL SOLUTIONS

                              Description (optional)
                              Auto-inserted from "Title Sheet1
                              Auto-inserted from "Title Sheet1
      Test Replicate I
                                                 Max Particle Size
                                                   Solids Content
                                                    Temperature
                          selected from drop-down menu
                          selected from drop-down menu
                                                                                                                                                                BOS
Test Position
Test Start Date
Extraction Duration [hr]
"As Tested" Solid [g]
Reagent Water [ml]
Acid Volume [ml]
Base Volume [ml]
Acid Normality [meq/mL]
Base Normality [meq/mL]
Acid Addition [meq/g]
Eluate pH
EluateEC[mS/cm]
Eluate Eh [mV]
Remarks
T01 T02 T03 T04 T05 TOG T07 T08 T09 B01 B02 BOS


































































































































































Water Acid Base













                                                                                                                                                                       I
      Test Replicate I
                                                 Max Particle Size
                                                   Solids Content
                                                    Temperature
    Acid Type
    Base Type
Lab Technician
selected from drop-down menu
selected from drop-down menu
Test Position
Test Start Date
Extraction Duration [hr]
"As Tested" Solid [g]
Reagent Water [mL]
Acid Volume [ml]
Base Volume [mL]
Acid Normality [meq/mL]
Base Normality [meq/mL]
Acid Addition [meq/g]
Eluate pH
Eluate EC [mS/cm]
Eluate Eh [mV]
Remarks
TOl T02 T03 T04 T05 T06 T07 T08 T09 B01 B02 B03


































































































































































Water Acid Base












                                                                                                                                                                       I
                                                 Max Particle Size
                                                   Solids Content
                                                    Temperature
    Acid Type
    Base Type
Lab Technician
selected from drop-down menu
selected from drop-down menu
Test Position
Test Start Date
Extraction Duration [hr]
"As Tested" Solid [g]
Reagent Water [mL]
Acid Volume [mL]
Base Volume [mL]
Acid Normality [meq/mL]
Base Normality [meq/mL]
Acid Addition [meq/g]
Eluate pH
Eluate EC [mS/cm]
Eluate Eh [mV]
Remarks
TOl T02 T03 T04 T05 TOG T07 T08 T09 B01 B02 BOS


































































































































































Water Acid Base












                                                                                                                                                                C-73
-------
                                                                            TM
                                                PreMethod 1313 LeachXS'"" Lite Data Template
Table 5     Final Extract pH Targets
 pH Target  Rationale
   varies    Natural pH at LS 10 mL/g-dry (no acid/base addition)
  2.0±0.5   Provides total or available COPC content
  4.0±0.5   Lower pH limit of typical management scenario
  5.5±0.5   Typical lower range of industrial waste landfills
  7.0±0.5   Neutral pH region; high release of oxyanions
  8.0±0.5   Endpoint for carbonated alkaline materials
  9.0±0.5   Minimum of LSP curve for many cationic and amphoteric COPCs
  12.0±0.5  Maximum in alkaline range for LSP curves of amphoteric COPCs
  13.0±0.5  Upper bound (field conditions) for amphoteric COPCs	
  10.5±0.5  Substitution if natural pH falls within another mandatory target

M_
1 O -

1 n -

X o
Q_
CO
LJJ

2.
H










1 -0.5 0 0.5
Acid Added [meq/g-dry]


•
-*-






1


A
B
C







1000 •
^ 100 •
.0
co
> 10-
o
•c
o
o
1 -
0.1 •
— <
I
•-A
1 B
-*-c






1 -0.5 0 0.5



Acid Added [meq/g-dry]
                                                                                                                                                    C-74
-------
                              Pre Method 1313 LeachXS   Lite Data Template
METHOD 1313 MASTER DATA LIST
                                                                            Value greater than calibration
                                                                            Value between MDL and ML


Project ID
Material ID
Test ID






Sample ID
-1313-T01-A
-1313-T02-A
-1313-T03-A
-1313-T04-A
-1313-T05-A
-1313-T06-A
-1313-T07-A
-1313-T08-A
-1313-T09-A
-1313-T01-B
-1313-T02-B
-1313-T03-B
-1313-T04-B
-1313-T05-B
-1313-T06-B
-1313-T07-B
-1313-T08-B
-1313-T09-B
-1313-T01-C
-1313-T02-C
-1313-T03-C
-1313-T04-C
-1313-T05-C
-1313-T06-C
-1313-T07-C
-1313-T08-C
-1313-T09-C
-1313-B01-A
-1313-B02-A
-1313-B03-A
Code


1313




"As Tested"
Solid
g



























-


Description (optional) u Value less than MDL
Auto-inserted from "Title Sheet" Ul/2 Value less than MDL (shown at 1/2 MDL) MDL
Auto-inserted from "Title Sheet" ML
Acid Type Base Type Analytical Method
Test Rep A
Test Rep B
Test Rep C



Analysis Date

Analytical Lab Name
Eluate Composition
Moisture Water Acid Acid Base Base Acid Eluate Eluate Eluate
Content Added Added Stength Added Stength Added pH Cond. ORP
g-H2O/g mL mL N mL N meq/g-dry s.u. mS/cm mV



























-

























































































-
































                                                                                                                                                                  C-75
-------
PreMethod 1313 LeachXS   Lite Data Template
PreMethod 1313 LeachXS   Lite Data Template
                                                                                                                     C-76
-------
PreMethod 1313 LeachXS
                                       C-77
-------
PreMethod 1313 LeachXS
                                                    C-78
-------
C-79
-------
                                WASHINGTON, D.C, 20400
Dear Leach Validation Participant,
       Welcome to the Phase I validation of PreMethods 1313 (pH dependent leach test) and
1316 (L/S ratio leach test). These methods represent a significant step forward in the science of
modeling material leaching into the environment. As a participatory laboratory, your assistance
in this effort will help ensure these methods are incorporated in EPA's publicly available method
compendium Test Methods for Evaluating Solid Waste Physical/Chemical Methods (SW-846).

       As you review the methods, along with the instructions and materials enclosed in this
package, I would like to highlight a couple of key points. First, please make sure you downloand
and review the most current version of PreMethods 1313 and 1316 along with the laboratory
instruction sheet (enclosed) before running the methods (see www.vandcrhilt.edu/leaching).
Some minor changes and clarifications were recently made to the methods to help improve their
usability. Second, please check the list of materials provided on the instruction sheet to ensure
your kit is complete.  Lastly, please note that since you will be shipping the extracted elluates to
Vanderbilt University for analysis, it is important that you follow the preservation instructions to
ensure accurate results.

       From the start of this interlaboratory validation effort, one of our top priorities is  to make
sure we are being responsive to the needs of our participating labs. As such, please do not
hesitate to contact me with any problem, issue, or concern you may have throughout this process.
You can contact me by phone at 703-308-0157 or by email at baldwin.mark(g),epa.gov. Again on
behalf of the EPA, 1 would like to thank you and your laboratory for your invaluable contribution
to this validation effort.
                                      Mark Baldwin
-------
Phase I of Method 1313/Method 1316 Validation
The subject material for Phase I of the Method 1313/Method 1316 inter-laboratory validation study is a coal
combustion fly ash. A generic MSDS for coal fly ash is included with the material shipment.
The subject material may be treated as a well homogenized sample with 85% < 0.3 mm particle size.  Thus:
   •   the minimum equivalent dry mass for Method 1313 and Method 1316 will be 20 g-dry and all
       extractions may be conducted in 250-mL bottles with the exception of two low liquid-solid (LS) ratio
       test positions, 1316-T04 and T05, which will likely require higher amounts of solid materials in a 500
       mL bottles in order to  ensure 50 mL analytical solutions
   •   no particle size reduction or sieve analysis is required for this Phase I sample
Although the titration curve should be developed as part of the method validation, baseline characterization
has shown the titration curve for the Phase I material to be very sensitive to acid addition in the neutral
range. Extreme care should be taken to provide exact volumes of acid addition during (i) the pre-test
titration in order to produce an accurate titration curve and (ii) the extraction step in order to reproduce an
acceptable final pH.  Test positions that meet pH tolerances should be processed for chemical analysis and
only those test positions that do not meet test position pH tolerances need to be rerun.
The kit supplied for the Phase I validation study includes:
   •   Four sets of completed bottle labels for each test replicate
   •   One chain of custody form
   •   Two questionnaires (one for each Method 1313 and Method 1316)
The sample labeling convention used to identify a particular solution consists of numerical identifiers for the
material, lab, test method,  and test position along with an alphabetical identifier for the test replicate.  The
layout for the sample label convention is as follows:
                     MadLbb-ttlc-Tdd-e         (Test Positions T01 through T09)
                     MaaUb-l3lc-Edd-e         (QA/QC Blanks B01-B03)
       "aa " is a two-digit number starting at zero that identifies the test material (e.g., the Phase I material is
            MOl),
       "bb " is a two-digit number starting at zero that identifies the participating laboratory (assigned
            randomly by EPA-ORCR),
       "c " is a single digit number that completes the test method ID (i.e., 1313 or 1316),
       "dd" is a two-digit number starting at zero that identifies the test position or QA/QC blank.
       "e " is a single letter representing the test replicate (i.e., A, B or C).
Four sets of completed labels  are provided to be used for labeling extraction vessels and two sets of 50-mL
analytical samples.  The remaining fourth set may be reserved for replacements as needed.
Instructions for Phase I Validation
                                                                                           C-81
-------
On or before June 7, 2010:
   1.  Prepare 3 test replicates of extracts for the supplied sample material according to the most current
       versions of Method 1313 and Method 13161. Use the Excel data templates to calculate extract
       "recipes" and return a completed Excel data template to the Vanderbilt project lead, Andy
       Garrabrants (A.Garrabrants@vanderbilt.edu) via email. Each method should be conducted as
       specified in the method draft to the extent possible; however, any necessary deviations should be
       recorded and a log of deviations returned with the Excel data template.
   2.  For each test position and QA/QC blank,  collect two 50-mL analytical samples in the DigiTubes
       provided. Preserve each analytical sample with Optima grade (or similar purity) nitric acid to a final
       concentration of 1% (v/v). Each analytical sample should have a label (prefilled and provided)
       corresponding to its test position (e.g., T01-T09) and test replicate (e.g, A, B, and C).
   3.  Return one set test positions and QA/QC  blanks in 50-mL DigiTubes for each Method 1313 and
       Method 1316 to Vanderbilt University for chemical analysis and retain the remaining set of samples
       onsite at least until the end of Phase I testing.
       Shipments should be sent no later than June 7, 2010 and a completed chain of custody form
       (provided) should be included.  Please ship samples (Monday through Thursday pickup only as
       Vanderbilt cannot accept Saturday deliveries) to following address:
          Civil & Environmental Engineering
          Vanderbilt University
          c/o Rossane DeLapp
          Jacobs Hall 149
          400 24th Avenue South
          Nashville, TN 3723 5
          (615)322-3189
       Please inform the ORCR study lead, Mark Baldwin (Baldwin.Mark@epa.gov), and Vanderbilt lead,
       Andy Garrabrants (A.Garrabrants@vanderbilt.edu), of your intended ship date so that arrangements
       may be made to receive the shipment.
   4.  Complete the method feedback questionnaire for each test method (available at
       www.vanderbilt.edu/leaching/downloads.html) and return it to Mark Baldwin by email no later than
       June 7, 2010.
Programmatic and technical questions may be directed to the ORCR lead, Mark Baldwin
(Baldwin.Mark@epa.gov. 703-308-0157).
1 The latest versions of these test methods and data templates may be downloaded at
www.vanderbilt.edu/leaching/downloads.html. Although the procedures themselves are not changed in any way, the method
drafts dated April 26, 2010 contain minor clarifications to the method which are intended to improve understanding of the method
                                                                                          C-82
-------
Arcadis Geraghty and Miller
4915 Prospectus Drive
Durham, NC 27713
(919) 544-4535
                                                     CHAIN OF CUSTODY RECORD
                                                           Project Description:

                                                        Arcadis G&M charge # :
                                                         Responsible EPA Party:
                                                       Responsible Arcadis Party:
                                                                              Phase I Lab Validation (or 1313 and 131! Page	1_

                                                                              RN990271.0007.00001
                                                                              Mark Baldwin
                                                                              Peter Kariher 	
 Sample ID
Method 1313 Solid Material
Method 1316 Solid Material
 Date
Collected
Sample Description
                    04/26/10  11 Liter HOPE container of lab validaton material
                    04/26/10  1 Liter HOPE container ol lab validaton material
                                                                        approximately 1 kg
                                                                        approximately 1 kg
 Sample ID
Number of
Containers
 Special Instructions
    Samples collected by:

              (signature)


  Samples relinquished by:

              (signature)


     Samples received by:

              (signature)
                            Peter H. Kariher
                                                                                                          SW-846 Method 1313
                                                                                                          SW-846 Method 1316
                                                                                                           Analyses Required
                                                                                          Report results to:   Vanderblll yniversily_


                                                                                                   (phone)  	


                                                                                                      (fax)  	
                                                                                                                    Samples shipped to:
                                                                                                                            Civrl & Hnvironmenliil [:ll;!ineenng

                                                                                                                            Viimlerbih University

                                                                                                                            e/n Rossune Del.Lipp

                                                                                                                            Jacuhs Mall I'W

                                                                                                                            4IX) It'" Avenue Smith

                                                                                                                            Nashville. TIM .17235
                                                                      Dale:      4/26/2010
                                                                                                      Date shipped:
                                                                                                                                                     4/26/2010
                                                                                                                                                                                        C-83
-------
     Interlaboratorv Validation of LEAF Method 1313 and Method 1316
M01-L01-1313-T01-A       M01-L01-1313-T01-B      M01-L01-1313-T01-C
M01-L01-1313-T02-A       M01-L01-1313-T02-B      M01-L01-1313-T02-C
M01-L01-1313-T03-A       M01-L01-1313-T03-B       M01-L01-1313-T03-C
M01-L01-1313-T04-A       M01-L01-1313-T04-B       M01-L01-1313-T04-C
M01-L01-1313-T05-A       M01-L01-1313-T05-B       M01-L01-1313-T05-C
M01-L01-1313-T06-A       M01-L01-1313-T06-B       M01-L01-1313-T06-C
M01-L01-1313-T07-A      M01-L01-1313-T07-B       M01-L01-1313-T07-C
M01-L01-1313-T08-A      M01-L01-1313-T08-B       M01-L01-1313-T08-C
M01-L01-1313-T09-A      M01-LOM313-T09-B       M01-L01-1313-T09-C
M01-L01-1313-B01-A      M01-L01-1313-B01-B       M01-L01-1313-B01-C
                                                               C-84
-------
                   Method Feedback Questionnaire

METHOD 1313: Liquid-Solid Partitioning as a Function of Eluate pH using a
                            Parallel Batch Procedure
1. Please indicate the amount of time (in professional hours) required to complete the following
  steps of Method 1313:

       Material Preparation (e.g., air drying, particle-size reduction, sieving)  	hrs

       Pre-test Titration                                               	hrs

       Extraction Setup (e.g., solids, water, acid/base additions)             	hrs

       Eluate Processing (e.g., pH/cond, filtration, analytical prep)           	hrs
2.  How would you rate the overall usability of Method 1313?
3.  In total, how much time (in professional hours) was required to process three test replicates
   of the test material using Method 1313?
4. Were the overall goals and instructions provided with the sample material clearly laid out and
  easy to follow?  If not, please suggest specific sections of the method where clarifications
  could be made.
Method Feedback Questionnaire - Method 1313                                 Page 1 of 3
                                                                                C-85
-------
5.  Were the procedures in the method draft clearly laid out and easy to follow? If not, please
   suggest specific sections of the method where clarifications could be made.
6.  Was the Excel data template clearly laid out and easy to follow? If not, please suggest
   specific sections of the data template where clarifications could be made.
7.  In preparing solid samples for the method, what difficulties (if any) were encountered? How
   were these difficulties overcome?
8.  While defining the pre-test titration curve, what difficulties (if any) were encountered?  How
   were these difficulties overcome?
   When using the Excel data template sheets, what difficulties (if any) were encountered?  How
   were these difficulties overcome?
Method Feedback Questionnaire - Method 1313                                  Page 2 of 3
                                                                                     C-86
-------
10. What difficulties (if any) did you encounter with acquiring or operating the required
   equipment?
11. How much time did it take technical personnel to become familiar with the method?
12. Please provide any general feedback (e.g., comments, edits, questions, software glitches, or
   concerns) below.  Include any suggested modifications to the test procedure, the Excel data
   template or to the method draft.
Method Feedback Questionnaire - Method 1313                                  Page 3 of 3
                                                                                   C-87
-------
                   Method Feedback Questionnaire

   METHOD 1316: Liquid-Solid Partitioning as a Function of Liquid-Solid
                     Ratio using a Parallel Batch Procedure
1. Please indicate the amount of time (in professional hours) required to complete the following
  steps of Method 1316:

       Material Preparation (e.g., air drying, particle-size reduction, sieving)   	hrs

       Extraction Setup (e.g., solids, water, acid/base additions)             	hrs
       Eluate Processing (e.g., pH/cond, filtration, analytical prep)           	hrs
2.  How would you rate the overall usability of Method 1316?
3.  In total, how much time (in professional hours) was required to process three test replicates
   of the test material using Method 1316?
4. Were the overall goals and instructions provided with the sample material clearly laid out and
  easy to follow? If not, please suggest specific sections of the method where clarifications
  could be made.
Method Feedback Questionnaire - Method 1316                                Page 1 of 3
                                                                                C-88
-------
5.  Were the procedures in the method draft clearly laid out and easy to follow?  If not, please
   suggest specific sections of the method where clarifications could be made.
6.  Was the Excel data template clearly laid out and easy to follow? If not, please suggest
   specific sections of the data template where clarifications could be made.
7.  In preparing solid samples for the method, what difficulties (if any) were encountered? How
   were these difficulties overcome?
   When using the Excel data template sheets, what difficulties (if any) were encountered? How
   were these difficulties overcome?
9.  What difficulties (if any) did you encounter with acquiring or operating the required
   equipment?
Method Feedback Questionnaire - Method 1316                                  Page 2 of 3
                                                                                     C-89
-------
10. How much time did it take technical personnel to become familiar with the method?
11. Please provide any general feedback (e.g., comments, edits, questions, software glitches, or
   concerns) below.  Include any suggested modifications to the test procedure, the Excel data
   template or to the method draft.
Method Feedback Questionnaire - Method 1316                                 Page 3 of 3
                                                                                   C-90
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                    Appendix D.     Blank Analysis and Data Filtering
TABLE OF CONTENTS
Method 1313 Method Blanks and Data Filtering	D-l
   Phase I Method Blanks	D-l
   Phase I Data Filtering	D-3
       Filtering for Cause	D-3
       Effect of Phase I Data Filtering on Statistical Analysis	D-5
   Phase II Method Blanks	D-8
   Phase II Data Filtering	D-8
   Method 1313 Filtration Summary	D-8
Method 1316 Method BLanks and Data Filtering	D-ll
   Phase I Method Blanks	D-ll
   Phase I Data Filtering	D-ll
   Phase II Method Blanks	D-13
   Phase II Data Filtering	D-16
   Method 1316 Filtering Summary	D-17
                                           D-i
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


                             Blank Analysis and Data Filtering

During the review of Phase I of Method 1313 and Method 1316 data, there were some data points and
some data sets that were visually different than the bulk of the data.  In addition, significant
concentrations of some analytes were noted in the method blank eluates (extractions conducted with all
reagents and procedures but without the subject material) which indicated some degree of external
contamination. Therefore, a process was developed for filtering data that was considered "valid" based
on either (i) known or suspected errors in performing the method or in following the validation study
instructions, or (ii) interpretation of the blank concentrations and their effect on eluate concentrations.

Method 1313 Method Blanks and Data Filtering

Phase I Method Blanks
Method 1313 specifies that three method blank extractions should be conducted, preserved for analysis
and interpreted as support that measured concentrations in the method test are not influenced by external
sources of contamination. These three method blanks include:

    •  B01 - a method blank simulating the natural extraction condition (i.e., reagent water with no acid
       or base added),
    •  B02 - a method blank simulating the pH 2.0 target extraction without solid sample (i.e., same
       amount of acid added to reagent water), and
    •  B03 - a method blank simulating the pH 13.0 target extraction without solid sample (i.e., same
       amount of base added to reagent water).

Prior to analysis, all analytical solutions were preserved for ICP-OES analysis with Optima grade nitric
acid to a final concentration of 1% (v/v).

Method blanks, for selected analytes of Method 1313 conducted on the Phase I EaFA material, are shown
in Figure 1.  In the figure, the maximum concentrations of method blanks with values above ICP-OES
detection limits are shown. For the purposes of comparison, the minimum measured concentrations for
each analyte are shown in the figure.

Several labs had higher than expected concentrations of some targeted constituents.  Evaluation of the
three method blanks show that contamination may introduced through the reagent water (e.g., antimony  in
L04 and LOS), the acid used in the extraction (e.g., calcium in L04) or the base used in the extraction
(e.g., boron in reference laboratory R(A-C)).  Regardless of the source, contamination from external
sources was seen as a potential influence on the validation statistics especially when extract
concentrations were low.
                                                                                            D-l
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316



_i
_E
c
o
E o.oi •
i
4
Minimum


• Max B01 (water)
• Max B02 (acid)
• Max BOB (base)
.

II






r


r




r




n


n

                                                           |  o.i..


|
J



Inl






n
1
n^ \\


n





• Max B01 (water)
DMax B02 (acid)
DMax B03 (base)

Minimum
Sample
Concentration _p_
11
           12456789   10   11  R(A-C)R(D-F)
                              Lab ID
                                               12456789   10  11  R(A-C) R(D-F)
                                                                    Lab ID
  _E
  E
  3
  •C




1 JLo „
• Max BUI (water)
• Max B02 (acid)
D Max B03 (base)



J]
                                                           o  0.1-
                                                                                    Minimum Sample Concentration
           12456789   10   11  R(A-C)R(D-F)
                              Lab ID
                                                                   124567
                                                                                                  10   11 R(A-C) R(D-F)
                                                                                       Lab ID
Calcium (mg/L)
I § P
-i l-i l-i l-i C
Minimum Sa
q
i
mple Concentration
1

\i
-
In
i
i

• Max B01 (water)
• Max B02 (acid)

•
r
|-r

1
^
"S n , .
Chromium (m
i 1 t

1
• Max B01 (water)
• Max B02 (acid)
• Max B03 (base)


Iri
n •
JULjjJj D
           12456789   10   11  R(A-C)R(D-F)
                              Lab ID
                                                 1   2    4   5   6   7    8   9   10   11 R(A-C) R(D-F)
                                                                    Lab ID
          I
       Minimum
        Sample
_f]	Concent ration



0.1 •
0.01 •



Minimum San
r
a
r
ip e Concentral
n
i
on
dl


Jj
• Max B01 (water)
• Max B02 (acid)
DMax B03 (base)


JI
            12456789   10   11  R(A-C)R(D-F)
                              Lab ID
                                                 12456789   10   11 R(A-C)R(D-F)
                                                                    Lab ID
            Minimum
             Sample
           Concentratic
           n   n
                                        £
                                        ¥
                                        ^   o.oi 4-
                                                                                   Minimum Sample Concentration
           12456789   10   11  R(A-C)R(D-F)
                              Lab ID
                                                 12456789   10   11 R(A-C)R(D-F)
                                                                    Lab ID
Figure 1.  Maximum method blank concentrations for Method 1313 Phase I EaFA material. Note: B01 refers
to method blank of reagent water, B02 refers to method blank of reagent water with the highest level of acid
addition, and BOS refers to method blank of reagent water with the highest level of base addition. All solutions were
preserved for chemical analysis with Optima grade nitric acid at 1% (v/v).
                                                                                                                D-2
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


Phase I Data Filtering
An algorithm was developed to filter (remove) data from the data set if the concentration of an analyte in
the corresponding blank was greater than 20 percent of the measured concentration in the test method
eluate. This data filtering process was conducted to avoid confounding statistical analysis of the test
results in analytical solutions where background contamination (e.g., through reagent water or acid/base
reagents) represents a significant portion of the measured concentration. Table 1 presents the pH and
replicates of data that did not pass the algorithm  for checking blank concentrations to measured
concentration values.

Filtering for Cause
Some data was filtered due to interferences introduced to the data set through procedural mistakes or
laboratory practices.  These interferences are not shown directly through blank analysis, but are identified
by reviewing the collected data as a whole and through analysis of measured concentrations over the
spectrum on ICP-OES analytes. Data sets where known causes of Method 1313 interferences were
identified were filtered for cause.  The following observations and data filtrations were made:

    •   Measured concentrations of boron from  reference lab test samples and method blanks for
        replicate A, B and C were significantly higher that all other reported data.  After discussion of
        reagent storage protocols with the laboratory representative, the source of boron concentration in
        the test samples was determined to come from storage  of strong base reagents in borosilicate
        glass containers. Therefore, the boron data for pH 13 from the reference laboratory replicates A-
        C was filtered from the overall data set.

    •   High sulfur concentrations were measured in all Laboratory 4  method blanks (e.g., L04 acid, base
        and deionized water blanks). Sulfur contamination could result in interference with barium
        determinations in analytical samples due to precipitation of BaSO4. Further  check showed that all
        test solutions from L04 had similar sulfur concentrations. Therefore, all L04 Ba results were
        filtered for cause.
                                                                                              D-3
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Table 1. Table of Filtered Test Positions Based on Blank Concentrations (20% critical value)

Lab ID
Lab-01
Lab-02
Lab-04
Lab-05
Lab-06
Lab-07
Lab-08
Lab-09
Lab-10
Lab- 11
Ref
Arsenic
pH
Reps


7.0
5.5
4.0
8.0
7.0
5.5
4.0
A,B,C
A, C
A,C
A,B,C
A,B,C
A,B,C
A,B, C

7.0
5.5
B
A

8.0
7.0
5.5
4.0
8.0
7.0
5.5
4.0
A,B, C
A,B,C
A,B, C
A,B, C
A,B,C
A,B, C
A,B,C
A,B, C

7.0
5.5
4.0
A, B, C,
F
A, B, C,
D,F
A, B, C,
D,E,F
Boron
pH

Reps



9.0




10.5

13.0
12.0
A,B, C
A,B,C
Cobalt
pH
8.0
Reps
A,B


9.0
8.0
8.0
8.0
9.0
8.0
9.0
8.0
8.0
A
B, C
B,C
B
B,C
B, C
B,C
B
A,B
B, C
B, C, D,
E,F
Chromium
pH
5.5
4.0
Reps
A
A

5.5
B

5.5
5.5
5.5
5.5
7.0
5.5
B
C
A,C
A
A
B

5.5
A, C
Molybdenum
pH Reps
4.0 C




8.0

12.0
7.0
13.0

13.0
Antimony
pH
4.0
Reps
A,B,C


5.5
4.0
2.0
7.0
5.5
4.0
5.5
4.0
A,B,C
C
A
B
B, C
A,B,C
A,B
A,B,C
A,B
A,B, C

5.5
4.0
2.0
12.0
5.5
4.0
2.0
A, C
A,B,C
A,B, C
A,B
A,B,C
A,B, C
A,C
A,B, C
B,C

12.0
5.5
4.0
A,B, C
A, B, C,
D,E,F
A, B, C,
D,E,F
B
Selenium
pH
Reps

4.0
4.0
4.0
4.0
B
A,B,C
A,B, C
A,B,C

4.0
5.5
4.0
7.0
5.5
4.0
4.0
5.5
4.0
A,B,C
A,B, C
A,B,C
A
A,B, C
A,B,C
A,B, C
C
A,B,C
                                                                                                                                  D-4
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


Effect of Phase I Data Filtering on Statistical Analysis
The overall effect of data filtering on the number of observations available for statistical analysis is shown
in Tables 2 by analyte and Table 3 by pH target point.  These tables provide a summary of filtered values
including the number of observations used in statistical analysis for each analyte and each target pH
value.
Table 2. Data Point Summary by Analyte after Blank Filtering and Filtering for Cause.
By Analyte
Collected
Filtered
Used in Analysis
As
324
60
264
B
324
6
318
Ba
324
27
297
Ca
324
0
324
Co
324
24
300
Cr
324
12
312
Mo
324
1
323
Sb
324
63
261
Se
324
33
291
V
324
0
324
Table 3. Data Point Summary by Analyte and Target pH after Blank Filtering and Filtering for Cause.
By Target pH
Collected @ pH
13.0
12.0
10.5
9.0
8.0
7.0
5.5
4.0
2.0
Sum
As
36
36
36
36
36
27
19
19
19
36
264
B
36
33
33
36
36
36
36
36
36
36
318
Ba
36
33
33
33
33
33
33
33
33
33
297
Ca
36
36
36
36
36
36
36
36
36
36
324
Co
36
36
36
34
29
21
36
36
36
36
300
Cr
36
36
36
36
36
36
35
26
35
36
312
Mo
36
36
36
36
36
36
36
36
35
36
323
Sb
36
30
24
36
36
35
32
17
20
31
261
Se
36
36
36
36
36
36
35
29
11
36
291
V
36
36
36
36
36
36
36
36
36
36
324
Subsequent to data filtering, statistical analysis was carried out on both unfiltered and filtered data to
determine the impact of data filtering on final results and conclusions. The impact of the overall effect of
filtering data is illustrated by comparing mean-based and median-based statistics between filtered and
non-filtered data sets.  Figures 2 and 3 show the overall standard deviation interval about the mean (left)
and 95% robust confidence interval about the median of lab means (right) for the eight analytes with data
points filtered either for cause or because of blank analyses. Although filtration of arsenic data appears to
have the greatest effect of all median-based statistics, the effect on mean-based statistics is on par with the
other analytes.  Overall, this comparison indicates that even a considerable amount of filtration has only a
minor effect on statistical analysis and is unlikely to change the outcomes of the validation study.
Therefore, in light of the  significant effort required to filter the collected data into a filtered data set,
filtration was no conducted for Method 1313 Phase II materials.
                                                                                              D-5
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
  d
       0.1 -T
     0.001
      100
  r~,  10 -;
  10
  CD
     0.1
                                                                                    10    12
                       Target pH
 Target pH
                                                                                               14
                       Target pH
Target pH
Figure 2. The effect of data filtration of Method 1313 Phase I EaFA results of mean-based (left) and median-

based (right) statistical output.
                                                                                                D-6
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
        10
         i -•
     0.01
                            Ed FA Me
                         	EaFA Overall SD
                         »  EaFA Mean (filtered)
                          — EaFA Overall SD (filtered)
                                                                                        10    12    14
                         Target pH
Target pH
     0.01
                                                         0.01
                         Target pH
 Target pH
Figure 3.  The effect of data filtration of Method 1313 Phase I EaFA results of mean-based (left) and median-
based (right) statistical output.
                                                                                                     D-7
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Phase II Method Blanks
Recommendations of the Phase I study were that participating laboratories advancing to Phase II were
asked to monitor their supply of reagent water and ensure that reagents were freshly prepared. As a
result, the number of maximum blank concentrations above detection limits for Phase II SWA material
(Figure 4) and CFS (Figure 5) were considerably less than in Phase II. Although no filtration based on
method blank analysis was conducted, the presentation of maximum method blank concentrations shown
in Figures 4 and 5 infer that very little filtration would have been necessary and any potential impact of
statistical analysis these materials would be less than that seen in Phase I.

Phase II Data Filtering
For Method 1313 Phase II SWA material, one test position from each of two participating laboratories
was filtered due to inconsistent pH values. All three replicates of test position T03 for L02 and T05 for
LOS were filtered for cause. Based on the conclusion of the comparison of filtered versus non-filtered
data conducted for Phase I, presentation of filtered versus non-filtered statistics for this minor data
filtering was not warranted.

No data was filtered for cause for the Phase II CFS material.

Method 1313 Filtration Summary
Based on the above analyses, the final filtration scheme for Method 1313 data is shown in Table 4. With
the exception of these data, all collected data was used in the statistical analysis for validation of Method
1313.

Table 4  Final Filtered Data for Method 1313 Statistical Analysis.
{Material ||Filtered Data I
^^^
SWA
CFS
• All L04 barium data (high sulfur)
• Boron for reference lab pH 13 (base storage)
• L02 T03 replicates A, B, and C (pH)
• LOS T05 replicates A, B, and C (pH)
None
                                                                                            D-8
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

Antimony (m
i 1 i

IT
:






31. - , •

• Max B01 (water)
• Max B02 (acid)
DMax B03 (base)
M n mum
Sampe
Concentrat on

"S
& 01-
.a
c
V
£
• MaxBOl(watsr)
• Max B02 (acid)
DMax BOB (base)
M nimiin
Samp e Concentration

n .
1245679 10 11 R(A-C) 1245679 10 11 R(A-C)
Lab ID Lab ID
•3 o.i •
01
E
~ 0.01 •
re
CO

• Max B01 (water)
• Max B02 (acid)
• Max B03 (base)

M nimiim Samp e Concentration
n
In „ m n •
Boron (mg/L)
1 1 £

•n-n
• Max B01 (water)
• Max B02 (acid)
• Max BOB (base)
-

1 r-p|
jii m


ll
1245679 10 11 R(A-C) 1245679 10 11 R(A-C)
Lab ID Lab ID

O)
^ 0.1 •
5 o.oi •



"
-
-1
r
If
Minimum
Sample
Concentration
1
1—
'

• Max B01 (water)
• Max B02 (acid)
DMax B03 (base)


m
nium (mg/L)
I p
.E
u
• Max B01 (water)
• Max B02 (acid)
• Max B03 (base)




fill
c r Fl
_n LLU Minimum Sampe Concentration ^L
1245679 10 11 R(A-C) 1245679 10 11 R(A-C)
Lab ID Lab ID

Cobalt (mg/
i 1 i


• Max B01 (water)
• Max B02 (acid)
DMax B03 (base)

fl
"a
Molybdenum (n
§ 1 t

•
ml I
• Max B01 (water)
• Max B02 (acid)
n Max B03 (base)


Mn
Sa

mple
i-Ti-i T mi HT TFrf rh n
1245679 10 11 R(A-C) 1245679 10 11 R(A-C)
Lab ID Lab ID

Ol
|
V
(A
M n mum Sampe Concentration


• Max B01 (water)
• Max B02 (acid)
• Max B03 (base)

inl
^
¥
re

• Max B01
(water)
• Max B02
(acid)
Minimum Sam e Concentration



rf^ m1 nn • • m
124567
                Lab ID
                                      10   11  R(A-C)
                                                             1245679    10   11  R(A-C)
                                                                             Lab ID
Figure 4.  Maximum method blank concentrations for Method 1313 Phase II SWA material. Note: B01 refers
to method blank of reagent water, B02 refers to method blank of reagent water with the highest level of acid
addition, and BOS refers to method blank of reagent water with the highest level of base addition. All solutions were
preserved for chemical analysis with Optima grade nitric acid at 1% (v/v).
                                                                                                   D-9
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
^
Antimony (mg
1 1 t
• Max B01 (water)
• Max B02 (acid)
• Max BOB (base)

r Sample ~~M |~~| •
Concentration 1



G"
O)
u "-1
1
<
• Max B01 (water)
• Max B02 (acid)
Q Max BOB (base)

M nimum
Sample
m TT 11
1 4 6 7 9 10 11 R(A-C) 1 4 6 7 9 10 11 R(A-C)
Lab ID Lab ID

^
~&
•=
£ o.oi •
• Max B01 (water)
pi 1-1 «Max B02 (acid)
• Max B03 (base)

r-i
,_ , Minimum
m 2-5L n
Boron (mg/L)
1 1 £
• Max B01 (water)
• Max B02 (acid)
• Max BOB (base)

M n mum Sampe Concentrat on
_
J~ r-i- r-ru.
El In
1 4 6 7 9 10 11 R(A-C) 1 4 6 7 9 10 11 R(A-C)
Lab ID Lab ID
^ 0-1'
£
¥
•o
(0
u
• Max B01 (water)
• Max B02 (acid)
• Max B03 (base)



1 Minimum Sample Concentration _ Ml


O)
E 1 •

_o
(0
0 0.01 •
M nimum Sample Concentrat on

• Max B01 (water)
• Max B02 (acid)
DMax B03 (base)
n
n
rim [fHiff m
1 4 6 7 9 10 11 R(A-C) 1 4 6 7 9 10 11 R(A-C)
Lab ID Lab ID
_i
"S
i"
5
• Max B01 (water)
• MaxBOZ(acd)
DMax B03 (base)

_ Minimum Sample Concentration _ fTl
_i
^
Molybdenum (n
'
J 0 f
• Max BOl (water)
• Max B02 (acid)
n Max B03 (base)

n
rH | M n mum Samp e Concentration
rrfT n "Ji rfi n rrn rffi
1 4 6 7 9 10 11 R(A-C) 1 4 6 7 9 10 11 R(A-C)
Lab ID Lab ID
_i
•a
E_
| 0.1-
C
V
V
(A
• Max B01 (water)
• MaxBOZ(acd)
• Max B03 (base)

Minimum Sample Concentration

J1
I
-%
re
>
• Max BOl
(water)
• Max B02

Minimum Samp e Concentration

1 n
                     6     7     9     10    11   R(A-C)
                          Lab ID
1     4     6     7     9     10    11   R(A-C)
               Lab ID
Figure 5. Maximum method blank concentrations for Method 1313 Phase II CFS material. Note: BOl refers
to method blank of reagent water, B02 refers to method blank of reagent water with the highest level of acid
addition, and BOS refers to method blank of reagent water with the highest level of base addition. All solutions were
preserved for chemical analysis with Optima grade nitric acid at 1% (v/v).
                                                                                                 D-10
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

METHOD 1316 METHOD BLANKS AND DATA FILTERING

Phase I Method Blanks
Since the solid material in Method 1316 is contacted only with reagent water, the single method blank for
each replicate of the test is a reagent water sample carried through the extraction process. Method blanks
for Phase I EaFA material are shown in Figure 6 along with the minimum test sample concentration from
all participating labs. In all  cases, the maximum method blank is no more than 1/10 the concentration of
the minimum analytical sample, indicating that no blank filtering due to external sources of contamination
would be necessary.

Phase I Data Filtering
As with Method 1313 Phase I, no data from Method 1316 Phase I on the EaFA material was filtered due
to the method blank analysis. However, inspection of the collected data from all participating laboratory
highlighted instances where pH measurement of eluates affects the concentration results of the Method
1316 data. The measured pH for all EaFA test samples is shown in Figure 7 along with examples of the
degree to which variation in the recorded pH influences the concentration of analytes from the test. In the
figure, three suspect data sets are highlighted with lines connecting the data in the set:

    •   LOS replicates A (fuchsia solid), B (fuchsia dashed) and C (fuchsia dotted)
    •   L10 replicate A (aqua solid)
    •   LI 1 replicates A (olive solid), B (olive dashed) and C (olive dotted)

These data sets were identified  because the pH of the test replicate taken as a whole lie outside the band
on the pH response of the entire dataset. However, no statistical process was taken to identify these data
sets as outliers.  Variations in pH are likely to be due to errors in pH meter calibration, standardization to
known buffer solutions, or measurement procedure.

While the source of the pH variation is unknown, the effect of pH on the concentrations measured in
Method 1316 is evident. For species where pH does not significantly affect concentration, there is little
effect of pH measurement variation on the measured concentration in Method 1316 samples (see panel B
in Figure 7). However, the suspect data is shown as outlying data when pH strongly influences analyte
concentrations (see panels C and D in Figure 7).  Given the pH data and effects shown in Figure 7, the
three data sets were filtered  from the data used for the statistical analysis of Method 1316.
                                                                                           D-ll
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Antimony (mg/L)
I
* t~* *
DMaxBOlfwatsr)!
Minimum Sample Concentrat on

n _ • n n
Arsenic (mg/L)
1 P
^ I-* t-
Minimum Sample Concentration

|«MaxB01(water)|

n nn
1245679 10 11 R(A-C) 1245679 10
Lab ID Lab ID
urn (mg/L)
I
-i i-i 1-
s
Minimum Sample Concentration
• MaxB01(water)|


n
ron (mg/L)
3 h
^ l-i i
CO
11 R(A-C)
Minim,, mt.m Lrnnr.ntr.tinn • MaX B01 (WatEr) |


Hnn nnnn
1245679 10 11 R(A-C) 1245679 10
Lab ID Lab ID
100 •
5 io •
01
-^ 1 •
E
3
3

Minimum Sample Concentration "Max B01 (water)|



r— , n n n
n n n n n n
nium (mg/L)
I p
o "-"-1
.c
u
• Max

i — i
11 R(A-C)
301 (water) |

Minimum Sam le Concentration


1245679 10 11 R(A-C) 1245679 10
Lab ID Lab ID
bait (mg/L)
I p
3
• MaxB01(water)|

Minimum Collected Concentration


r~,
Molybdenum (mgj
i 1 °
11 R(A-C)
Minimum Sample Concentration
| BMax B01 (watsr) |


n Hi. 1 1
1245679 10 11 R(A-C) 1245679 10
Lab ID Lab ID
1 -. 	 . 1 -* 	
Selenium (mg/L)
=
-i i-i
" Minimum Sample Concentration
• Max B01 (water) |

n n
nn nn
sdium (mg/L)
= P
-i l-i
5
n nm •
II
11 R(A-C)
| BMax B01 (water)|
Minimum Sample Concentration


n n n . I 1


in
          124
                      5    6   7   9   10   11  R(A-C)
                          Lab ID
1245679   10   11  R(A-C)
                Lab ID
Figure 6. Maximum method blank concentrations for Method 1316 Phase I EaFA material. Note: All
solutions were preserved for chemical analysis with Optima grade nitric acid at 1% (v/v).
                                                                                               D-12
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
        i         	
 (A)
                    1           10
                      L/S (L/kg)
                                          100
                (B)
                                   1           10
                                     L/S (L/kg)
                                                         100
      10 -F
  01
       1 -:
     0.01
                   4-
4-
                       10 T
        0.1
 (0
                    1          10
                      L/S (L/kg)
                                          100
                (D)
                                     1          10
                                      L/S (L/kg)
                                                                                        100
Figure 7. Effect of suspect Method 1316 pH measurement on EaFA concentration results. (A) eluate pH with
lines connecting data with suspect measurements, (B) boron showing no observed effect, (C) antimony showing
moderate effect, and (D) cobalt showing significant effect.

Phase II Method Blanks
Analysis of method blanks for Method 1316 Phase II SWA (Figure 8) and CFS (Figure 9) show that
filtration due to blank concentrations may be warranted for a few species. For SWA, L02 methods blanks
indicated calcium concentrations in excess of the minimum test sample concentration measure for all
laboratories while L10 methods blanks showed a significant spike in cobalt. In method blanks for CFS,
the method blanks for all laboratories with the exception of the reference laboratory had molybdenum
within 1/10 of the minimum test sample concentration; however, it is unlikely that all samples would be
filtered if the data was processed through the blank filtration algorithm used in Method 1313. Overall,
this blank screening analysis for Method 1316 Phase II materials did not indicate that blank filtration was
necessary.
                                                                                            D-13
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316

•5
O

Minimum Sam le
Concentration
• Max B01 (water)]




nn
1 2
10 T 	
Barium (mg/L)
Arsenic (mg/L)
I P ^ g
Minimum Sample Concentration

| BMax BO

1 (water)]



4 5 6 7 9 10 11 R(A^) 1245679 10 11
Lab ID Lab ID
	 1 1 -c 	

• Max B01 (water)]


1 2


Calcium
i 1 t
™ M

Boron (mg/
I §
-11-11-

M 	 urn Sample Concentration mltalBO


R(A-C)

(water) 1

(iLnnd (1
4 5 6 7 9 10 11 R(A-C) 1245679 10 11
Lab ID Lab ID
nimum Sample Concentration
• MaxBOl(water)]
J|

A
1 2
^ 0.1 •
•3
±i
re
u
n n
n \\
mium (mg/L)
i °
-11-11-
o
5
|-|
R(A-C)
DMax B01 (watsr) |
Minimum Sample Concentration




n
4 5 6 7 9 10 11 R(A-C) 1245679 10 11
Lab ID Lab ID
|nMaxB01(watsr)|




1 2
100 j 	

Selenium (mg/L
2 S „ E

| o.i.
1
c
•S
2 0 01 •
"o
z
R(A-C)
1 OMax B01 (watsr) |
, Minimum Sample Concentration


n n r. n n
4 5 6 7 9 10 11 R(A-C) 1245679 10 11
Lab ID Lab ID
	 1 1 -c 	
M nimum Sample Concentration







• Max B01 (water) |



2-
E
3
5
R(A-C)
| BMax B01 (water)]
Minimum Sample Concentration




n n rn n n
          1245679   10   11  R(A-C)
                          Lab ID
1245679   10   11  R(A-C)
                Lab ID
Figure 8. Maximum method blank concentrations for Method 1316 Phase II SWA material. Note: All
solutions were preserved for chemical analysis with Optima grade nitric acid at 1% (v/v).
                                                                                               D-14
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
^
•s
Antimony (m
1 1 I

urn (mg/L)
p
1
10 n
Cadmium (mg/L)
1 P
J. |_L |_L
1 -|
_l
£
•o
(0


nium(mg/L)
1 P

V
(A
n nm •
• Max B01 (water)]


Minimum Sam le Concentration

1 4 6 7 9 10 11 R(A-C)
Lab ID
Minimum Sample Concentration "Max B01 l

^
1 4 6 7 9 10 11 R(A-C)
Lab ID
Minimum Collected Conception 'MaX B01 (water'l


I
1 4 6 7 9 10 11 R(A-C)
Lab ID
Minimum Sample Cnnrentratinn
| BMaxBOl (water) |


1
1 4 6 7 9 10 11 R(A-C)
Lab ID

• Max B01 (water) 1

Minimum Sample Concentration



Arsenic (mg/
i 1 £


Dl
C
g
CO
1000 -i

100 •
_l
01 10 •
¥ 1
'o
a 0.1.
i -|
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1
c
«
2 o 01 •
>.
o
Z

adium (mg/L)
5 P
5
n nm •

|«MaxB01(water)|

Minimum Sample Concentration


1 4 6 7 9 10 11 R(A-C)
Lab ID
Minimum Sample Concentration




1 4 6 7 9 10 11 R(A-C)
Lab ID



n H n n n r, „
1 4 6 7 9 10 11 R(A-C)
Lab ID
1 BMax B01 (watsr)l



• n n • • • •
1 4 6 7 9 10 11 R(A-C)
Lab ID
| BMax B01 (water)]

Mimmumsamp|econcentratjon

n
           1    4    6    7    9     10   11   R(A-C)
                          Lab ID
6     7     9    10    11   R(A-C)
     Lab ID
Figure 9. Maximum method blank concentrations for Method 1316 Phase II CFS material. Note: All solutions
were preserved for chemical analysis with Optima grade nitric acid at 1% (v/v).
                                                                                               D-15
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


Phase II Data Filtering
Although no data was filtered because of blank analysis for Method 1316 Phase II samples in either SWA
or CFS materials, some data was filtered for cause.  The LOS laboratory data recorded in the method data
template indicated that LOS did not account for the significant amount of water entrained in the sample
when conducting Method 1316. Thus, the final L/S of each extraction point is higher that would be
expected and outside the specification required in the method.  The shift in L/S along the horizontal axis
can be seen graphically for the pink data (LOS) in Figure 8.
    13.5
     13
    12.5
                                                   1000
 (A)
                    1           10
                      L/S (L/kg)
                                           100
                (B)
                                    1           10
                                      L/S (L/kg)
                                                                                          100
      10
  01
  £    1 -t
      0.1 -:
  o
     0.01
                    4-
4-
                                                   10000 -F
                  oi  1000 -:
                  E
                                                     100 -:
                                                      10
4-
4-
        0.1
 (C)
                    1           10
                      L/S (L/kg)
                                           100
                                                        0.1
                (D)
                                    1          10
                                      L/S (L/kg)
                                                                                          100
Figure 10. Effect of suspect Method 1316 L/S on SWA concentration results. (A) eluate pH with lines
connecting data with suspect measurements, (B) arsenic showing no observed effect, (C) molybdenum showing no
observed effect, and (D) selenium showing no observed effect.

The data in Figure 8 indicates that the shift in L/S of the LOS data does not affect the general trend of the
data set for either pH or analyte concentration. Linear interpolation for the collected data to the target L/S
points would result in data points consistent with the other participating laboratories. However, the LOS
data was considered to not comply with the specifications of Method 1316 and, thus, the LOS data for all
replicates of SWA material were filtered for cause from all analytes.
                                                                                              D-16
-------
 Intel-laboratory Validation of LEAF Method 1313 and Method 1316
 Method 1316 Filtering Summary
 Based on the above analyses, the final filtration scheme for Method 1316 data is shown in Table 5.  With
 the exception of these data, all collected data was used in the statistical analysis for validation of Method
 1316.

 Table 5 Final Filtered Data for Method 1316 Statistical Analysis.
•Material    llFiltered Data
 EaFA            •  LOS replicates A, B, C for all analytes (pH)
                  •  L10 replicate A for all analytes (pH)
                  •  LI 1 replicates A, B, and C for all analytes (pH)
                  •  LOS replicates A, B, C for all analytes (L/S)
SWA
CFS
                None
                                                                                            D-17
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                          Appendix E.     Method 1313 Results
TABLE OF CONTENTS
Method 1313 Statistical Analysis for Selected Analytes	E-l
   EaFAFlyAsh	E-l
   SWA Solidified Waste Analog	E-ll
   CFS Contaminated Field Soil	E-21
Method 1313 Reference Laboratory Eluate Results (ICP-OES and Supplemental Analysis)	E-31
   EaFAFlyAsh	E-31
   SWA Solidified Waste Analog	E-36
   CFS Contaminated Field Soil	E-41
Method 1313 Repeatability and Reproducibility	E-46
   Material Comparison Graphs	E-46
   Precision Distribution Data	E-54
                                          E-i
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                    (B)
• EaFA-LOl-A
• EaFA-L02-A
• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A
• EaFA-LlO-C
• EaFA-Lll-A
• EaFA-Ref-A
o EaFA-Ref-D
A EaFA-LOl-B
A EaFA-L02-B
A EaFA-L04-B
A EaFA-L05-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Lll-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
• EaFA-L05-C
n EaFA-L06-C
n EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
D EaFA-LlO-C
• EaFA-Lll-C
• EaFA-Ref-C
n EaFA-Ref-F
     0.001
                                                                                       10
                                         12    14
 (D)
                         Target pH
(E)
                        Target pH
Figure 1.  Antimony statistical analysis for Method 1313 Phase I material EaFA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    E-l
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
  ~   10 -;
   01
   u
  'E
                       O  RefMean
                       • — Ref 95% PL
                       •  Median of Lab Means
                         95% RCL
     0.01
                                                                                         10
                                                    12    14
 (A)
                            PH
          (B)
                                  Target pH
 (C)
     0.01
^
O
• EaFA-LOl-A
• EaFA-L02-A
• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A
• EaFA-LlO-C
• Ea FA-LI 1-A
• EaFA-Ref-A
o EaFA-Ref-D
A EaFA-LOl-B
A EaFA-L02-B
A EaFA-L04-B
A EaFA-L05-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Lll-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
• EaFA-L05-C
n EaFA-L06-C
n EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
n EaFA-LlO-C
• EaFA-Lll-C
• EaFA-Ref-C
D EaFA-Ref-F
                                     10
12    14
                         Target pH
     0.01
 (D)
468
    Target pH
                                     10    12
      14
          (E)
80 -
£ 60 -
o
w dn
jo 40 -
20 -






i
\
\



/"




>V\
\




	


^^ ^^^^.



02468
Target pH
Overall CV
•Between Lab CV
•Within Lab CV




^




10 12 1
Figure 2.  Arsenic statistical analysis for Method 1313 Phase I material EaFA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                     E-2
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                            10 -E-
 (A)
                             PH
                                                    (B)
                                                                             Target pH
 (C)
     0.001
        10
• EaFA-LOl-A
• EaFA-L02-A
• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A
• EaFA-LlO-C
• EaFA-Lll-A
• EaFA-Ref-A
• EaFA-Ref-D
AEaFA-LOl-B
AEaFA-L02-B
AEaFA-L04-B
AEaFA-L05-B
AEaFA-L06-B
AEaFA-L07-B
AEaFA-L08-B
AEaFa-L09-B
AEaFA-LlO-B
AEaFA-Lll-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
• EaFA-L05-C
n EaFA-L06-C
D EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
D EaFA-LlO-C
• EaFA-Lll-C
• EaFA-Ref-C
DEaFA-Ref-F
                     4     6    8     10
                          Target pH
                                          12    14
  E
  _3

  £
       0.1
      0.01  -
     0.001
                 Mean
                 Overall SD
                •Between LabSD
                •Within Lab SD
                                               ML
                                              MDL
                                                        ,  60 -•
(D)
                           6    8
                          Target pH
                                     10
12   14
                                                     (E)
                                                                            Target pH
Figure 3. Barium statistical analysis for Method 1313 Phase I material EaFA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall"  (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                      E-3
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
        10
   oi
  £   0.1 -
   o
  £
      0.01 -
     0.001
                                              ML
                                              MDL
1 .
Boron (mg/L)
1 § °
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t=*


O Ref Me
	 Ref 95°/
D Median


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n
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of Lab Means
L









te_^_— -TE —H--M










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MDL
                                     10
12   14
10
12    14
 (A)
                             PH
         (B)
                                  Target pH

1 .
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£• n 1 -
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• EaFA-LOl-A
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• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A
• EaFA-LlO-C
• EaFA-Lll-A
• EaFA-Ref-A
o EaFA-Ref-D
A EaFA-LOl-B
A EaFA-L02-B
A EaFA-L04-B
A EaFA-L05-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Lll-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
• EaFA-L05-C
n EaFA-L06-C
n EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
n EaFA-LlO-C
• EaFA-Lll-C
• EaFA-Ref-C
n EaFA-Ref-F
 (C)
          0     2    4     6     8    10   12    14
                         Target pH
1 .
^^
_l
•"^
Dl
£• n 1 -
|
0.01 •
n nm .
(



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— «'




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— 9




ML
MDL
                                                        100 T
                                                      O
                                     10
12   14
 (D)
                         Target pH
          (E)
                                                     2     _._
Figure 4.  Boron statistical analysis for Method 1313 Phase I material EaFA. (A) collected data as a function of
pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means
and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown with
respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and pooled
"within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation for upper
values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating a
generalized analytical uncertainty.
                                                                                                    E-4
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Dl


|

|o
IS
U
      1000

       100

        10
         1 •
 (A)
Ol
^>
£

I
u
 0.01

0.001



 1000

  100

  10
                                               ML
                                               MDL
                                                     o

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                                                    '"
                                                          0.01
                                                          0.001
                                                                   O  Ref Mean
                                                                  	Ref 95% PL
                                                                   •  Median of Lab Means
                                                                  	95% RCL
                                                                                                    ML
                                                                                                   MDL
                                                                            4-
                                                                                  4-
                                      10
                                         12    14
                             PH
                                                   (B)
                                                                             6     8
                                                                            Target pH
10
12   14
         1 •
 (C)
   Ol
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    0.01

   0.001



    1000

     100

      10
                                               ML
                                               MDL
• EaFA-LOl-A
• EaFA-L02-A
• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A
• EaFA-LlO-C
• EaFA-Lll-A
• EaFA-Ref-A
o EaFA-Ref-D
AEaFA-LOl-B
AEaFA-L02-B
AEaFA-L04-B
A EaFA-L05-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Lll-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
• EaFA-L05-C
DEaFA-L06-C
DEaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
DEaFA-LlO-C
• EaFA-Lll-C
• EaFA-Ref-C
DEaFA-Ref-F
                                      10    12
                                               14
                          Target pH
      0.01 - <=
     0.001
 (D)
i
!
[
•
^— H


*— •-


Mean
Overall SD
Between Lab SD
Within Lab SD
— •— «



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s

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~f T MDL
i i i
3 ;

I 4 6 8 10 12 1
Target pH
                                                   (E)
                                                                         468
                                                                             Target pH
                                                                                       10    12
                                                                                                   14
Figure 5. Calcium statistical analysis for Method 1313 Phase I material EaFA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                      E-5
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
     0.0001
 (A)
 (C)
   0)
  ^>
   £

   o
0.1 -
      0.01 -
     0.001
                             PH
                                             (B)
                                                                      Target pH
• EaFA-LOl-A
• EaFA-L02-A
• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A
• EaFA-LlO-C
• EaFA-Lll-A
• EaFA-Ref-A
• EaFA-Ref-D
AEaFA-LOl-B
AEaFA-L02-B
AEaFA-L04-B
AEaFA-L05-B
AEaFA-L06-B
AEaFA-L07-B
AEaFA-L08-B
AEaFa-L09-B
AEaFA-LlO-B
AEaFA-Lll-B
AEaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
• EaFA-L05-C
n EaFA-L06-C
D EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
n EaFA-LlO-C
• EaFA-Lll-C
• EaFA-Ref-C
DEaFA-Ref-F
                      4    6    8    10
                          Target pH
                                    12    14
                                                        1000
           £

           o
                2    4
 (D)
                    6     8    10
                  Target pH
12   14
                                             (E)
10     12    14
Figure 6.  Chromium statistical analysis for Method 1313 Phase I material EaFA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    E-6
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
     0.0001
 (C)
   Ol
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      0.001 • •
     0.0001
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                                                       .
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                                                               0     2     4    6     8     10    12    14
                                                          0.001 -
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• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A
• EaFA-LlO-C
• EaFA-Lll-A
• EaFA-Ref-A
o EaFA-Ref-D
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A EaFA-L06-B
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A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Lll-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
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• EaFA-L04-C
• EaFA-L05-C
n EaFA-L06-C
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• EaFA-L08-C
• EaFa-L09-C
D EaFA-LlO-C
• EaFA-Lll-C
• EaFA-Ref-C
D EaFA-Ref-F
                                      10
12   14
                          Target pH

^> 100 -
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A
• EaFA-LlO-C
• EaFA-Lll-A
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• EaFA-Ref-D
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A EaFA-L04-B
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A EaFA-L08-B
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• EaFA-LOl-C
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• EaFA-L08-C
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Figure 8.  Molybdenum statistical analysis for Method 1313 Phase I material EaFA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    E-8
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
     0.01
 (A)
                            PH
(B)
                        Target pH
       10 T
• EaFA-LOl-A
• EaFA-L02-A
• EaFA-L04-A
• EaFA-L05-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A
• EaFA-LlO-C
• EaFA-Lll-A
• EaFA-Ref-A
o EaFA-Ref-D
A EaFA-LOl-B
A EaFA-L02-B
A EaFA-L04-B
A EaFA-L05-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Lll-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
• EaFA-L05-C
D EaFA-L06-C
D EaFA-L07-C
• EaFA-L08-C
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-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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• EaFA-LOl-A
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• EaFA-L06-A
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• EaFA-L08-A
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• EaFA-LlO-C
• EaFA-Lll-A
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A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Lll-B
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• EaFA-LOl-C
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• EaFA-L04-C
• EaFA-L05-C
n EaFA-L06-C
n EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
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Figure 10. Vanadium statistical analysis for Method 1313 Phase I material EaFA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     E-10
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
 (D)
Antimony (mg/L)
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• SWA-L07-A
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• SWA-L10-A
• SWA-L11-A
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A SWA-L11-B
A SWA-Ref-B
A SWA-Ref-E
• SWA-L01-C
• SWA-L02-C
• SWA-L04-C
• SWA-L05-C
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                                                        1000 -F-
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                                    10    12
14
Figure 11. Antimony statistical analysis for Method 1313 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line)  standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    E-ll
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                           100
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                                                        160

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                                                                       468
                                                                            Target pH
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• SWA-L06-A
• SWA-L07-A
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• SWA-L10-A
• SWA-L11-A
• SWA-Ref-A
• SWA-Ref-D
A SWA-L01-B
A SWA-L02-B
A SWA-L04-B
A SWA-L05-B
A SWA-L06-B
A SWA-L07-B
A SWA-L09-B
A SWA-L10-B
A SWA-L11-B
A SWA-Ref-B
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• SWA-L01-C
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                                                                    Overall CV
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 (D)
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                                                   (E)
                                                                       4     6    8     10
                                                                            Target pH
                                                                                                12    14
Figure 12. Arsenic statistical analysis for Method 1313 Phase II material SWA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                      E-12
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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Figure 13. Barium statistical analysis for Method 1313 Phase II material SWA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                      E-13
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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• SWA-L04-A
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• SWA-L07-A
• SWA-L09-A
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• SWA-L01-C
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                                                                                               12
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Figure 14. Boron statistical analysis for Method 1313 Phase II material SWA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                    E-14
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 15. Calcium statistical analysis for Method 1313 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                   E-15
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                                             0  Ref Mean
                                                                            	Ref 95% PL
                                                                             •  Median of Lab Means
                                                                                95% RCL
     0.0001
 (A)
 (C)
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(B)
                         Target pH
• SWA-L01-A
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• SWA-L09-A
• SWA-L10-A
• SWA-L11-A
• SWA-Ref-A
• SWA-Ref-D
A SWA-L01-B
A SWA-L02-B
A SWA-L04-B
A SWA-L05-B
A SWA-L06-B
A SWA-L07-B
A SWA-L09-B
A SWA-L10-B
A SWA-L11-B
A SWA-Ref-B
A SWA-Ref-E
• SWA-L01-C
• SWA-L02-C
• SWA-L04-C
• SWA-L05-C
n SWA-L06-C
n SWA-L07-C
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                                      10    12    14
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Figure 16. Chromium statistical analysis for Method 1313 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall"  (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to  5% marker
indicating a generalized analytical uncertainty.
                                                                                                    E-16
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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0    2     4     6    8    10   12    14
               Target pH
     0.0001
• SWA-LOl-A
• SWA-L02-A
• SWA-L04-A
• SWA-L05-A
• SWA-L06-A
• SWA-L07-A
• SWA-L09-A
• SWA-L10-A
• SWA-L11-A
• SWA-Ref-A
• SWA-Ref-D
A SWA-L01-B
A SWA-L02-B
A SWA-L04-B
A SWA-L05-B
A SWA-L06-B
A SWA-L07-B
A SWA-L09-B
A SWA-L10-B
A SWA-L11-B
A SWA-Ref-B
A SWA-Ref-E
• SWA-L01-C
• SWA-L02-C
• SWA-L04-C
• SWA-L05-C
D SWA-L06-C
D SWA-L07-C
• SWA-L09-C
D SWA-L10-C
• SWA-L11-C
• SWA-Ref-C
D SWA-Ref-F
 (C)
                           6     8
                          Target pH
  o
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     0.001 T
    0.0001
 (D)
                           68
                         Target pH
               (E)
                                      Target pH
Figure 17.  Cobalt statistical analysis for Method 1313 Phase II material SWA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line),  "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                   E-17
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                                                       RefMe
                                                                                  	Ref 95% PL
                                                                                    •  Median of Lab Means
                                                                                       95% RCL
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• SWA-L09-A
• SWA-L10-A
• SWA-L11-A
• SWA-Ref-A
o SWA-Ref-D
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A SWA-L07-B
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A SWA-L10-B
ASWA-L11-B
A SWA-Ref-B
A SWA-Ref-E
• SWA-L01-C
• SWA-L02-C
• SWA-L04-C
• SWA-L05-C
D SWA-L06-C
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Figure 18. Molybdenum statistical analysis for Method 1313 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     E-18
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
     1000
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• SWA-L07-A
• SWA-L09-A
• SWA-L10-A
• SWA-L11-A
• SWA-Ref-A
• SWA-Ref-D
A SWA-L01-B
A SWA-L02-B
A SWA-L04-B
A SWA-L05-B
A SWA-L06-B
A SWA-L07-B
A SWA-L09-B
A SWA-L10-B
A SWA-L11-B
A SWA-Ref-B
A SWA-Ref-E
• SWA-L01-C
• SWA-L02-C
• SWA-L04-C
• SWA-L05-C
D SWA-L06-C
n SWA-L07-C
• SWA-L09-C
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                     4    6     8    10
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
   0)
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• SWA-L01-A
• SWA-L02-A
• SWA-L04-A
• SWA-L05-A
• SWA-L06-A
• SWA-L07-A
• SWA-L09-A
• SWA-L10-A
• SWA-L11-A
• SWA-Ref-A
• SWA-Ref-D
A SWA-L01-B
A SWA-L02-B
A SWA-L04-B
A SWA-L05-B
A SWA-L06-B
A SWA-L07-B
A SWA-L09-B
A SWA-L10-B
A SWA-L11-B
A SWA-Ref-B
A SWA-Ref-E
• SWA-L01-C
• SWA-L02-C
• SWA-L04-C
• SWA-L05-C
D SWA-L06-C
D SWA-L07-C
• SWA-L09-C
n SWA-L10-C
• SWA-L11-C
• SWA-Ref-C
n SWA-Ref-F
                     4     6    8     10
                          Target pH
                                     12    14
                                                        1000
 (D)
                          Target pH
                                              (E)
Figure 20. Vanadium statistical analysis for Method 1313 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    E-20
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
   O)
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      0.01
                                                   0.001
                                      10    12    14
                                                                                    O  RefMean
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                                                                                    •  Median of Lab Means
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                                                              246
                                                                       Target pH
                                         10    12    14
• CFS-L01-A
• CFS-L04-A
o CFS-L06-A
0 CFS-L07-A
• CFS-L09-A
0 CFS-L10-A
• CFS-L11-A
• CFS-Ref-A
o CFS-Ref-D
A CFS-L01-B
A CFS-L04-B
A CFS-L06-B
A CFS-L07-B
A CFS-L09-B
A CFS-L10-B
A CFS-L11-B
A CFS-Ref-B
A CFS-Ref-E
• CFS-L01-C
• CFS-L04-C
n CFS-L06-C
D CFS-L07-C
• CFS-L09-C
n CFS-L10-C
• CFS-L11-C
• CFS-Ref-C
n CFS-Ref-F
 (D)
                     4     6     8
                         Target pH
                               10    12
14
                                               (E)
 6     8    10
Target pH
                                                                                               12
                                                                                              14
Figure 21. Antimony statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     E-21
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                          100 T
                                                       ~   10 •;
 (A)
  ^   10  -•
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(B)
                          Target pH
                                    •  Mean
                                      Overall SD
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                                  	Within Lab SD
                               O  RefMean
                              	Ref 95% PL
                               •  Median of Lab Means
                                  95% RCL
                                                                         =1=
                                                                              =1=
                                                                                    =1=
                                                                                          =1=
                                                                                                   MDL
                    4     6    8     10
                         Target pH
                                                                                                12
14
• CFS-L01-A
• CFS-L04-A
o CFS-L06-A
o CFS-L07-A
• CFS-L09-A
0 CFS-L10-A
• CFS-L11-A
• CFS-Ref-A
o CFS-Ref-D
A CFS-L01-B
A CFS-L04-B
A CFS-L06-B
A CFS-L07-B
A CFS-L09-B
A CFS-L10-B
A CFS-L11-B
A CFS-Ref-B
A CFS-Ref-E
• CFS-L01-C
• CFS-L04-C
n CFS-L06-C
n CFS-L07-C
• CFS-L09-C
n CFS-L10-C
• CFS-L11-C
• CFS-Ref-C
n CFS-Ref-F
                                                        ,  60 -•
 (D)
                          Target pH
(E)
                        Target pH
Figure 22. Arsenic statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                     E-22
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
  -    0.1 -r
   0)
   (5
  00
       0.01 ••
      0.001
     0.0001
                                      10
 (A)
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 (C)
                          Target pH
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 (D)
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O  RefMean
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   Median of Lab Means
  - 95% RCL
        4-
4-
12   14
              10   12
           14
          (B)
                                   Target pH
• CFS-L01-A
• CFS-L04-A
o CFS-L06-A
o CFS-L07-A
• CFS-L09-A
0 CFS-L10-A
• CFS-L11-A
• CFS-Ref-A
o CFS-Ref-D
A CFS-L01-B
A CFS-L04-B
A CFS-L06-B
A CFS-L07-B
A CFS-L09-B
A CFS-L10-B
A CFS-L11-B
A CFS-Ref-B
A CFS-Ref-E
• CFS-L01-C
• CFS-L04-C
n CFS-L06-C
n CFS-L07-C
• CFS-L09-C
n CFS-L10-C
• CFS-L11-C
• CFS-Ref-C
n CFS-Ref-F
          (E)

Barium (°/o
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Figure 23. Barium statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                     E-23
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
   Ol
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     0.001
 (A)
   Ol

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     0.001
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                          Ref Mean
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                       •  Median of Lab Means
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                                                                    -H
                                                                                                    ML
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12    14
                             PH
          (B)
468
    Target pH
10
12   14
• CFS-L01-A
• CFS-L04-A
0 CFS-L06-A
0 CFS-L07-A
• CFS-L09-A
0 CFS-L10-A
• CFS-L11-A
• CFS-Ref-A
o CFS-Ref-D
A CFS-L01-B
A CFS-L04-B
A CFS-L06-B
A CFS-L07-B
A CFS-L09-B
A CFS-L10-B
A CFS-L11-B
A CFS-Ref-B
A CFS-Ref-E
• CFS-L01-C
• CFS-L04-C
n CFS-L06-C
n CFS-L07-C
• CFS-L09-C
n CFS-L10-C
• CFS-L11-C
• CFS-Ref-C
n CFS-Ref-F
                      4    6     8    10
                          Target pH
12    14
              •  Mean
               — Overall SD
                 Between Lab SD
                 Within Lab SD
    ML
                                              . MQL
                                      10
12    14
 (D)
                          Target pH
          (E)


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Figure 24. Boron statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a function of
pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means
and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown with
respect to interpolated lab data; (D) intervals for "overall"  (gold line),  "between lab" (blue, dashed line) and pooled
"within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation for upper
values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating a
generalized analytical uncertainty.
                                                                                                      E-24
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                      O)
                                                      E
                                                          o.i t
                                                     •o
                                                      IS
                                                         0.01 -t
                                                        0.001
                                                    (B)
                                                                             Target pH
• CFS-L01-A
• CFS-L04-A
• CFS-L06-A
o CFS-L07-A
• CFS-L09-A
0 CFS-L10-A
• CFS-L11-A
• CFS-Ref-A
o CFS-Ref-D
A CFS-L01-B
A CFS-L04-B
A CFS-L06-B
A CFS-L07-B
A CFS-L09-B
A CFS-L10-B
A CFS-L11-B
A CFS-Ref-B
A CFS-Ref-E
• CFS-L01-C
• CFS-L04-C
D CFS-L06-C
D CFS-L07-C
• CFS-L09-C
D CFS-L10-C
• CFS-L11-C
• CFS-Ref-C
D CFS-Ref-F
                                                        1000
    0.001
(D)
                     4     6     8
                         Target pH
                                    10    12
14
                                                    (E)
468
    Target pH
                                                                                        10    12
                                                                                                  14
Figure 25. Cadmium statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                   E-25
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
1000 -
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                                         12
14
Figure 26.  Calcium statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D)  intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line)  standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                   E-26
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
 (A)
 (C)
  O)
  E
                                                      O)
                                                      E
                                     10    12    14
                             PH
(B)
                                                          0.01 -r
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• CFS-L01-A
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o CFS-L06-A
0 CFS-L07-A
• CFS-L09-A
0 CFS-L10-A
• CFS-L11-A
• CFS-Ref-A
• CFS-Ref-D
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A CFS-L06-B
A CFS-L07-B
A CFS-L09-B
A CFS-L10-B
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A CFS-Ref-B
A CFS-Ref-E
• CFS-L01-C
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n CFS-L06-C
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Figure 27. Lead statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a function of
pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means
and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown with
respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and pooled
"within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation for upper
values of "overall", "between lab"  and "within lab" standard deviation compared to 5% marker indicating a
generalized analytical uncertainty.
                                                                                                    E-27
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                           10
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 (c)
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Figure 28. Molybdenum statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line)  standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    E-28
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                           10
   Cl
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                                                                 ^ ^Ref Mean
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                                                                  •  Median of Lab Means
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Figure 29. Selenium statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     E-29
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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                                           14
Figure 30. Vanadium statistical analysis for Method 1313 Phase II material CFS. (A) collected data as a

function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median

of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)

shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)

and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of

variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker

indicating a generalized analytical uncertainty.
                                                                                                     E-30
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Aluminum (mg/L)
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-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

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                                                                                          E-32
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316



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                                                                                          E-33
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

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                                                                                          E-34
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


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                                                                                          E-35
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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Figure 36. Reference lab data and 95% prediction limits for Method 1313 Phase II SWA material.
                                                                                           E-36
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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                                                                                          E-37
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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                                                                                          E-38
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

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                                                                                                E-39
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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                                                                                            E-40
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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                                                                                           E-41
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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                                                                                          E-43
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316





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                                                                                               E-44
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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                                                                                           E-45
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 46.  Antimony repeatability and reproducibility in Method 1313 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                  E-46
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
         • ICP-OES RSD
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Figure 41. Arsenic repeatability and reproducibility in Method 1313 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                  E-47
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 48.  Barium repeatability and reproducibility in Method 1313 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                  E-48
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 49.  Boron repeatability and reproducibility in Method 1313 materials: (A) reproducibility standard

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approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)

compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                  E-49
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                   E-50
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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to approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                   E-51
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
10000

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Figure 52.  Selenium repeatability and reproducibility in Method 1313 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                   E-52
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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0 -
c







\
,---'
•**
ICP-OES RSD
) ;



. \
\ <



_^ ^
' V ^

	 CFSRSD(r)
	 EaFARSD(r)
	 SWA RSD(r)





	 —



'^
^^

1 4 6 8 10 12 1
Target pH
                   4     6    8     10
                        Target pH
                                                                                            12
                                                        14
Figure 53.  Vanadium repeatability and reproducibility in Method 1313 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                  E-53
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Table 1. Method 1313 Repeatability (RSDr) for Common Analytes in All Study Materials


1 RSDr Distribution Percentiles (%) 1

1 Analyte •Symbolll Mean II Min II 25th II Median II 75th II Max 1
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Molybdenum Mo
Selenium Se
Vanadium V
23
20
21
8
12
19
11
13
8
8
4
3
2
3
4
3
12
13
7
5
3
6
6
6
16
19
10
7
5
15
9
10
25
24
15
9
11
22
13
12
129
59
108
28
60
106
41
94
Table 2. Method 1313 Reproducibility (RSDR) for Common Analytes in All Study Materials
                                     RSDR Distribution Percentiles (%)
1 Analyte •Symbolll Mean II Min II 25th 1
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Molybdenum Mo
Selenium Se
Vanadium V
55
52
44
20
27
39
26
36
17
24
9
5
4
7
7
13
24
37
18
8
6
18
18
23
HffilPff
33
47
22
12
9
30
21
27
MEM
45
61
36
21
28
45
31
41
•TC7TE
508
124
280
110
133
148
77
175
                                                                                          E-54
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Table 3. Method 1313 Repeatability (RSDr) by pH Target


1 RSDr Distribution Percentiles (%) 1

1 pH II Mean II Min II 25th II Median II 75th II Max 1
2.0
4.0
5.5
7.0
8.0
9.0
10.5
12.0
13.0
30
16
14
12
12
10
10
13
26
3
2
4
o
J
2
2
o
J
3
4
7
6
8
5
7
6
5
5
9
11
11
11
11
11
9
9
11
16
42
21
18
16
15
12
12
15
27
129
67
35
36
27
30
28
36
108
Table 4. Method 1313 Reproducibility (RSDR) by pH Target


1 RSDR Distribution Percentiles (%) 1

1 pH II Mean II Min II 25th II Median II 75th II Max 1
2.0
4.0
5.5
7.0
8.0
9.0
10.5
12.0
13.0
74
31
29
25
27
26
30
37
57
6
4
5
5
5
5
6
7
8
16
18
20
16
14
14
15
15
24
49
25
28
24
23
21
25
22
46
76
44
38
33
35
29
32
47
58
508
74
59
58
110
114
124
122
280
                                                                                        E-55
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Table 5. Method 1313 Repeatability (RSDr) by Study Material


1 RSDr Distribution Percentiles (%) 1

1 Material II Mean II Min II 25th II Median II 75th II Max 1
EaFA
SWA
CFS
11
23
14
2
5
2
4
8
6
10
14
9
14
28
17
67
129
108
Table 6. Method 1313 Reproducibility
                                         by Study Material


1 RSDR Distribution Percentiles (%) 1

1 Material! Mean II Min II 25th II Median II 75th II Max 1
EaFA
SWA
CFS
25
36
32
4
9
5
9
23
15
22
39
23
35
61
33
68
508
280
                                                                                          E-56
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                          Appendix F.     Method 1316 Results
TABLE OF CONTENTS
Method 1316 Statistical Analysis for Selected Analytes	F-l
   EaFAFlyAsh	F-l
   SWA Solidified Waste Analog	F-ll
   CFS Contaminated Field Soil	F-21
Method 1316 Reference Laboratory Eluate Results (ICP-OES and Supplemental Analysis)	F-31
   EaFAFlyAsh	F-31
   SWA Solidified Waste Analog	F-36
   CFS Contaminated Field Soil	F-40
Method 1316 Repeatability and Reproducibility	F-45
   Material Comparison Graphs	F-45
   Precision Distribution Data	F-54
                                          F-i
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
iu •
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s 1
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< 0.01 •

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•
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1


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 (A)
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L/S (I/kg)
10   (B)
                                                                            L/S (L/kg)
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   01
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       0.1 T
     0.001
           : ML_

      0.01 -; MDL
• EaFA-LOl-A
• EaFA-L02-A
• EaFA-L04-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A

• EaFA-Ref-A
• EaFA-Ref-D
A EaFA-LOl-B
A EaFA-L02-B
A EaFA-L04-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
D EaFA-L06-C
n EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
n EaFA-LlO-C
• EaFA-Ref-C
n EaFA-Ref-F
          0.1
                       10
 (C)
                         L/S (L/kg)
   01
   o
1 .
n 1 .


.01 -

rim .

e=ra


• Mean
	 Between Lab SD
	 Within Lab SD


'^^
ML

MDL


          0.1
                       10
 (D)
                         L/S (L/kg)
                           (E)
                                                  L/S (L/kg)
Figure 1.  Antimony statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     F-l
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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 0.1 -:
0.01
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                        10
                                                            1  T
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                                                 0.1 -:
                                                         0.01
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                                                           	Ref 95% PL
                                                            •  Median of Lab Means
                                                           	95%RCL
                                                                                        	--ML
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                                                (B)
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• EaFa-L09-A

• EaFA-Ref-A
• EaFA-Ref-D
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A EaFA-L02-B
A EaFA-L04-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
n EaFA-L06-C
n EaFA-L07-C
• EaFA-L08-C
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n EaFA-LlO-C
• EaFA-Ref-C
• EaFA-Ref-F
         0.1
 (c)
                        1
                    L/S (L/kg)
10
1 •
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 (D)
    1
L/S (L/kg)
10
                                                            0.1
                                                (E)
                                                                            1
                                                                       L/S (L/kg)
                                                    10
Figure 2. Arsenic statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line),  "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                      F-2
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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• EaFA-L04-A A EaFA-L04-B • EaFA-L04-C
o EaFA-L06-A A EaFA-L06-B n EaFA-L06-C
o EaFA-L07-A A EaFA-L07-B n EaFA-L07-C
• EaFA-L08-A A EaFA-L08-B • EaFA-L08-C
• EaFa-L09-A A EaFa-L09-B • EaFa-L09-C
A EaFA-LlO-B n EaFA-LlO-C
• EaFA-Ref-A A EaFA-Ref-B • EaFA-Ref-C
o EaFA-Ref-D A EaFA-Ref-E n EaFA-Ref-F
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L/S(L/kg) /c) L/S(L/kg)
 (D)

Figure 3.  Barium statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C)  95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                    F-3
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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• EaFA-LOl-A A EaFA-LOl-B • EaFA-LOl-C
• EaFA-L02-A A EaFA-L02-B • EaFA-L02-C
• EaFA-L04-A A EaFA-L04-B • EaFA-L04-C
0 EaFA-L06-A A EaFA-L06-B n EaFA-L06-C
o EaFA-L07-A A EaFA-L07-B D EaFA-L07-C
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A EaFA-LlO-B n EaFA-LlO-C
• EaFA-Ref-A A EaFA-Ref-B • EaFA-Ref-C
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Overall CV
	 Between Lab CV
	 Within Lab CV
A
\\ s
^>\ ^s
X
1 1C
L/S (L/kg)
Figure 4. Boron statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a function of
pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means
and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown with
respect to interpolated lab data; (D) intervals for "overall" (gold line),  "between lab" (blue, dashed line) and pooled
"within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation for upper
values of "overall", "between lab"  and "within lab" standard deviation compared to 5% marker indicating a
generalized analytical uncertainty.
                                                                                                     F-4
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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• EaFA-L02-A
• EaFA-L04-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A

• EaFA-Ref-A
• EaFA-Ref-D
A EaFA-LOl-B
A EaFA-L02-B
A EaFA-L04-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
n EaFA-L06-C
D EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
n EaFA-LlO-C
• EaFA-Ref-C
• EaFA-Ref-F

mn -


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10
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 (D)
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    (E)
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L/S (L/kg)
10
Figure 5.  Calcium statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                     F-5
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


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u

0.001 •



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 (A)
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                           (B)
                                                   L/S (L/kg)
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       0.1 •
      0.01 -
     0.001
• EaFA-LOl-A
• EaFA-L02-A
• EaFA-L04-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A

• EaFA-Ref-A
• EaFA-Ref-D
A EaFA-LOl-B
A EaFA-L02-B
A EaFA-L04-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
n EaFA-L06-C
D EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
n EaFA-LlO-C
• EaFA-Ref-C
• EaFA-Ref-F
 (C)
                         L/S (L/kg)
   Ol
  ^>
   E

   o
       0.1 •
      0.01 -
     0.001
                                              MDL
          0.1
 (D)
    1
L/S (L/kg)
10
Figure 6.  Chromium statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     F-6
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
   Ol
   E
       0.1 -:
      0.01 -:
     0.001
                                               ML
                                              MDL
                                                       Ol
                                                       o
                                                       u
          0.1  •:
         0.01  •;
         0.001
          0.1
10
                     Ref Mean
                    -Ref 95% PL
                     Median of Lab Means
                    -95%RCL
0.1
 (A)
                          L/S (L/kg)
    (B)
                             L/S (L/kg)
   o
   u
     0.001
      0.01 •
• EaFA-LOl-A
• EaFA-L02-A
• EaFA-L04-A
• EaFA-L06-A
• EaFA-L07-A
• EaFA-L08-A
• EaFa-L09-A

• EaFA-Ref-A
• EaFA-Ref-D
A EaFA-LOl-B
A EaFA-L02-B
A EaFA-L04-B
A EaFA-L06-B
A EaFA-L07-B
A EaFA-L08-B
A EaFa-L09-B
A EaFA-LlO-B
A EaFA-Ref-B
A EaFA-Ref-E
• EaFA-LOl-C
• EaFA-L02-C
• EaFA-L04-C
n EaFA-L06-C
n EaFA-L07-C
• EaFA-L08-C
• EaFa-L09-C
n EaFA-LlO-C
• EaFA-Ref-C
• EaFA-Ref-F
 (C)
                          L/S (L/kg)
   Dl
   E
       0.1 •
      0.01 -
     0.001
 (D)
                                                                             L/S (L/kg)
Figure 7. Cobalt statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a function of
pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means
and median-based 95% robust confidence limits (RCL;  red line); (C) 95% RCL intervals (red lines) shown with
respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and pooled
"within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation for upper
values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating a
generalized analytical uncertainty.
                                                                                                      F-7
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 8.  Molybdenum statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a
function ofpR; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line)  standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     F-8
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 9. Selenium statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line),  "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                      F-9
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

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Figure 10. Vanadium statistical analysis for Method 1316 Phase I material EaFA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line)  standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    F-10
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
        10
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Figure 11.  Antimony statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                  F-ll
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 12.  Arsenic statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line),  "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                   F-12
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 13. Barium statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                      F-13
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 14. Boron statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                     F-14
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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Figure 15. Calcium statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                      F-15
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
        10
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Figure 16. Chromium statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     F-16
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 17. Cobalt statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line),  "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                     F-17
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 18. Molybdenum statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    F-18
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 19. Selenium statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     F-19
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 20.  Vanadium statistical analysis for Method 1316 Phase II material SWA. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                   F-20
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316



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Figure 21. Antimony statistical analysis for Method 1316 Phase II material CFS. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    F-21
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 22. Arsenic statistical analysis for Method 1316 Phase II material CFS. (A) collected data as a function
of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
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pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker  indicating
a generalized analytical uncertainty.
                                                                                                     F-22
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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Figure 23. Barium statistical analysis for Method 1316 Phase II material CFS. (A) collected data as a function
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means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
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pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
                                                                                                    F-23
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 24. Boron statistical analysis for Method 1316 Phase II material CFS. (A) collected data as a function of
pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means
and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown with
respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and pooled
"within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation for upper
values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating a
generalized analytical uncertainty.
                                                                                                     F-24
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
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• CFS-L04-A
• CFS-L06-A
o CFS-L07-A
• CFS-L09-A
0 CFS-L10-A
o CFS-L11-A
• CFS-Ref-A
o CFS-Ref-D
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• CFS-L01-C
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n CFS-L06-C
n CFS-L07-C
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n CFS-L10-C
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10
Figure 25. Cadmium statistical analysis for Method 1316 Phase II material CFS. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the
median of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL
intervals (red lines) shown with respect to interpolated lab data; (D) intervals for "overall" (gold line),
"between lab" (blue, dashed line) and pooled "within labs" (green, dotted line) standard deviation about the
mean of all data; (E) coefficient of variation for upper values of "overall", "between lab" and "within lab"
standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
                                                                                               F-25
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

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• CFS-L07-A A CFS-L07-B n CFS-L07-C
• CFS-L09-A A CFS-L09-B • CFS-L09-C
• CFS-L10-A A CFS-L10-B D CFS-L10-C
• CFS-L11-A A CFS-L11-B D CFS-L11-C
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-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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0 CFS-L10-A
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• CFS-Ref-A
o CFS-Ref-D
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A CFS-L10-B
A CFS-L11-B
A CFS-Ref-B
A CFS-Ref-E
• CFS-L01-C
• CFS-L04-C
n CFS-L06-C
n CFS-L07-C
• CFS-L09-C
n CFS-L10-C
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n CFS-Ref-F
          0.1
 (D)
    1
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10
0.1
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10
Figure 27. Lead statistical analysis for Method 1316 Phase II material CFS. (A) collected data as a function of
pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means
and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown with
respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and pooled
"within labs" (green, dotted line) standard deviation about the mean of all  data; (E) coefficient of variation for upper
values of "overall", "between lab"  and "within lab" standard deviation compared to 5% marker indicating a
generalized analytical uncertainty.
                                                                                                    F-27
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


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Figure 28. Molybdenum statistical analysis for Method 1316 Phase II material CFS. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    F-28
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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o CFS-L07-A
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Figure 29. Selenium statistical analysis for Method 1316 Phase II material CFS. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                     F-29
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
A)
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Figure 30. Vanadium statistical analysis for Method 1316 Phase II material CFS. (A) collected data as a
function of pH; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line)  standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
                                                                                                    F-30
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
ninum (mg/L)
1 P
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Figure 31. Reference lab data and 95% prediction limits for Method 1316 Phase I EaFA material.
                                                                                          F-31
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cesium (mg/L)
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Figure 32. Reference lab data and 95% prediction limits for Method 1316 Phase I EaFA material.
                                                                                          F-32
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Lithium (mg/L)
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anganese (mg/L)
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Figure 33. Reference lab data and 95% prediction limits for Method 1316 Phase I EaFA material.
                                                                                          F-33
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 34. Reference lab data and 95% prediction limits for Method 1316 Phase I EaFA material.
                                                                                          F-34
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

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Figure 35. Reference lab data and 95% prediction limits for Method 1316 Phase I EaFA material.
                                                                                            F-35
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
Aluminum (mg/L)
I P o - =
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Figure 36. Reference lab data and 95% prediction limits for Method 1316 Phase II SWA material.
                                                                                          F-36
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

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Figure 37. Reference lab data and 95% prediction limits for Method 1316 Phase II SWA material.
                                                                                           F-37
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
5 1 -
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Figure 38. Reference lab data and 95% prediction limits for Method 1316 Phase II SWA material.
                                                                                           F-38
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


10 -



0.01 -
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Figure 39. Reference lab data and 95% prediction limits for Method 1316 Phase II SWA material.
                                                                                                 F-39
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
ninum (mg/L)
1 P
i
: - — Ref 95% PL
: CFS-Ref-A
CFS-Ref-B
CFS-Ref-C
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imony (mg/L)
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Figure 40. Reference lab data and 95% prediction limits for Method 1316 Phase II CFS material.
                                                                                          F-40
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cesium (mg/L)
1 1 § P
h-1 h-1 h-1 h-1 1-
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Figure 41. Reference lab data and 95% prediction limits for Method 1316 Phase II CFS material.
                                                                                          F-41
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Figure 42.  Reference lab data and 95% prediction limits for Method 1316 Phase II CFS material.
                                                                                                  F-42
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

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Figure 43. Reference lab data and 95% prediction limits for Method 1316 Phase II CFS material.
                                                                                          F-43
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

G"

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Figure 44. Reference lab data and 95% prediction limits for Method 1316 Phase II CFS material.
                                                                                            F-44
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
   Dl
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  S3
  <   0.01 •
     0.001
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m .

1 .







	 CFSRSD(r)
	 EaFARSD(r)
	 SWARSD(r)




ICP-OES RSD



— ___
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i 	 1 	 1 — i — i — i i i i
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                             Jf

                             I
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                                                   10
                                 10
                                                          6 ••
                                                          4 ••
                                                \
                                                                           L/S (L/kg)
Figure 45.  Antimony repeatability and reproducibility in Method 1316 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                   F-45
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
iuu •
^N

IS
£
10

\^" 	 Xx
^j — _r- — y
*** -^
• ICP-OES RSD
	 CFSRSD(r)
	 EaFARSD(r)
	 SWA RSD(r)
                                                          0.1
 (A)
                        L/S (L/kg)
(B)
                           1
                       L/S (L/kg)
10
                                                         10
                                                     I   6
                                                     u
                                                     'c   4
                                                     w
                                                     I
                                                         2 •-
                                                           0.1
 (C)
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(D)
                            1
                        L/S (L/kg)
10
Figure 46.  Arsenic repeatability and reproducibility in Method 1316 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                  F-46
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                       1000
                                                     >• 100 - :
                                                         10 -:
 (A)
     0.001
    1000
	 CFSRSD(r)
	 EaFARSD(r)
	 SWARSD(r)





ICP-OES RSD




^





^
1
	 	 l^r_

                                                           0.1
                         L/S (L/kg)
(B)
                            1
                        L/S (L/kg)
10
 (C)
                        L/S (L/kg)
(D)
                        L/S (L/kg)
Figure 47.  Barium repeatability and reproducibility in Method 1316 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                  F-47
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                        100
                                                 IB
                                                 4J
                                                 s
                                                 Q.
                                                 01
                                                 tf
                                                 00
                                                             ICP-OES RSD
                                                           0.1
 (A)
                         L/S (L/kg)
                                              (B)
                                                                          1
                                                                      L/S (L/kg)
                                                   10
    100
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  a.
10 -:
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       0.1
 (C)
                       1
                   L/S (L/kg)
10
                                              (D)
                                                                           L/S (L/kg)
Figure 48.  Boron repeatability and reproducibility in Method 1316 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                   F-48
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                        100
                                                     J3
                                                     JS   10
                                                     8
                                                     Q.
; 	 CFSRSD(r)
1 	 EaFARSD(r)
1 	 SWARSD(r)



• ICP-OES RSD



X
-^•x
J — 1 1 1 1 1



/

1 	 1 	 1 — 1 — 1 — 1 1 1 1
                                                           0.1
 (A)
                         L/S (L/kg)
(B)
                            1
                        L/S (L/kg)
10
 (C)
                        L/S (L/kg)
(D)
                        L/S (L/kg)
Figure 49.  Calcium repeatability and reproducibility in Method 1316 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                  F-49
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
             • CFSMean
               CFSS(R)
             A EaFA Mean
               EaFAS(R)
             • SWA Mean
             —SWA S(R)
                                                        100
                                                      I
                                                      5
                             o
                                     ICP-OES RSD

          0.1
 (A)
    1
L/S (L/kg)
0.1
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    1
L/S (L/kg)
10
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 (C)
                        L/S (L/kg)
                           (D)
                                                   L/S (L/kg)
Figure 50. Molybdenum repeatability and reproducibility in Method 1316 materials: (A) reproducibility
standard deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared
to approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                    F-50
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                        100
                                                      J3
                                                      JS  10
                                                      n
      0.01
                                                                            \


                                                             ICP-OES RSD

                                                           0.1
 (A)
                         L/S (L/kg)
                            (B)
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                                                   L/S (L/kg)
                                                   10
    100
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L/S (L/kg)
10
0.1
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                                                                           L/S (L/kg)
10
Figure 51.  Selenium repeatability and reproducibility in Method 1316 materials: (A) reproducibility standard
deviation interval about the mean of all data, (B) repeatability relative standard deviation (RSDr) compared to
approximate analytical uncertainty (ICP-OES RSD), (B) reproducibility relative standard deviation (RSDR)
compared to approximate analytical uncertainty (ICP-OES RSD), and (D) reproducibility Horwitz ratio (HorRatR).
                                                                                                   F-51
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
             • CFSMean

             —CFSS(R)

             A EaFA Mean

             — EaFAS(R)

             • SWA Mean

               SWA SIR)
                                                         100
                                                       5
                                                          10 -:
Q.
01
u.
     0.001
                                                                                                 X
                                                                                                   X

              ICP-OESRSD
                                -
                                                            0.1
 (A)
                         L/S (L/kg)
    (B)
                                1

                            L/S (L/kg)
                                              10
     100
   u

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   E
   a.
      10 -;

          ICP-OES RSD
      
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Table 1. Method 1316 Repeatability (RSDr) for Common Analytes in All Study Materials


1 RSDr Distribution Percentiles (%) 1

1 Analyte •Symbolll Mean II Min II 25th II Median II 75th II Max 1
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Molybdenum Mo
Selenium Se
Vanadium V
12
19
8
8
6
8
8
9
5
7
2
3
2
4
2
3
8
12
4
5
o
3
6
4
4
12
15
7
7
6
7
8
6
13
28
9
10
7
9
9
12
24
37
27
17
13
14
21
22
Table 2. Method 1316 Reproducibility (RSDR) for Common Analytes in All Study Materials
                                     RSDR Distribution Percentiles (%)
1 Analyte •Symbolll Mean II Min II 25th 1
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Molybdenum Mo
Selenium Se
Vanadium V
26
31
35
26
15
22
20
22
5
19
9
6
5
6
7
11
17
23
13
8
7
11
13
12
HffilPff
20
31
16
13
8
18
20
16
MEM
27
34
31
34
19
31
24
26
•TC7TE
75
65
175
78
52
59
40
61
                                                                                          F-53
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Table 3. Method 1316 Repeatability (RSDr) by L/S Target (mL/g-dry)
       0.5
                             RSDr Distribution Percentiles (%)
            II Mean  II  Min  II  25th  II Median II   75th  II  Max  I
11
         15
           37
       1.0
                                                   26
       2.0
                                        12
                    30
       5.0
                                        11
                    31
      10.0
10
10
13
16
Table 4. Method 1316 Reproducibility (RSDR) by L/S Target (mL/g-dry)


1 RSDR Distribution Percentiles (%) 1

1 L/S II Mean II Min 1
0.5
1.0
2.0
5.0
10.0
38
20
25
21
20
5
6
5
6
6
m&M
17
10
11
11
14
J^jfiTilBTI
34
17
17
17
20
msm
43
24
24
26
29
1 Max 1
175
62
103
75
36
                                                                                           F-54
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Table 5. Method 1316 Repeatability (RSDr) by Study Material


1 RSDr Distribution Percentiles (%) 1

1 Material II Mean II Min II 25th II Median II 75th II Max 1
EaFA
SWA
CFS
13
8
7
4
3
2
7
5
3
11
7
6
16
9
11
37
35
16
Table 6. Method 1316 Reproducibility
                                         by Study Material


1 RSDR Distribution Percentiles (%) 1

1 Material! Mean II Min II 25th II Median II 75th II Max 1
EaFA
SWA
CFS
20
39
15
6
5
5
9
20
10
21
29
14
29
47
18
45
175
32
                                                                                           F-55
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
     Appendix G.    Comparison of EU pH-dependence Tests to Method 1313 RCLs
TABLE OF CONTENTS
EaFAFlyAsh	F-l
SWA Solidified Waste Analog	F-5
CFS Contaminated Field Soil	F-9
                                      G-i
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                                   •  EaFA-Lll-14429-A

                                                                   A  EaFA-Lll-14429-B

                                                                   •  EaFA-Lll-14429-C

                                                                   0  EaFA-Lll-14997-A

                                                                      EaFA-L12-14997-A

                                                                   A  EaFA-L12-14997-B

                                                                      EaFA-L12-14997-C

                                                                 	EaFAM1313RL

                                                                 	EaFA M1313 Mean

                                                                   O  own pH
                                            12    14
Figure 1. Comparison of CEN/TS 14429 and CEN/TS 14997 results on Phase I EaFA material to the Mean
and reproducibility Limit (PL) Interval for Method 1313.
                                                                                                       G-l
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
      0.001
                                       10    12    14
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                                                             0.001 -
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                                                             100
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                                                                                     PH
                                                            0.001
                                                                                              10    12    14
  •  EaFA-Lll-14429-A

  A  EaFA-Lll-14429-B

  •  EaFA-Lll-14429-C

  0  EaFA-Lll-14997-A

  •  EaFA-L12-14997-A

  A  EaFA-L12-14997-B

  •  EaFA-L12-14997-C

	EaFAM1313RL

	EaFA M1313 Mean

  O  own pH
Figure 2. CEN/TS 14429 and CEN/TS 14997 results for EaFA material compared to the Method 1313 mean
and reproducibility limit intervals (RLs).
                                                                                                          G-2
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                                                                      14
                                                                   •  EaFA-Lll-14429-A

                                                                   A  EaFA-Lll-14429-B

                                                                   •  EaFA-Lll-14429-C

                                                                   O  EaFA-Lll-14997-A

                                                                      EaFA-L12-14997-A

                                                                   A  EaFA-L12-14997-B

                                                                      EaFA-L12-14997-C

                                                                  	EaFAM1313RL

                                                                  	EaFA M1313 Mean

                                                                   O  own pH
                                                 14
Figure 3. CEN/TS 14429 and CEN/TS 14997 results for EaFA material compared to the Method 1313 mean
and reproducibility limit intervals (RLs).
                                                                                                       G-3
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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^af"
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                                                                                                    14
                                                                   •  SWA-L11-14429-A
                                                                   A  SWA-L11-14429-B
                                                                   0  SWA-L11-14429-C
                                                                   0  SWA-L11-14997-A
                                                                   •  SWA-L12-14997-A
                                                                   A  SWA-L12-14997-B
                                                                   D  SWA-L12-14997-C
                                                                  - SWA M13 13 Mean
                                                                  -- SWAM1313RL
                                                                   O  own pH
Figure 5.  CEN/TS 14429 and CEN/TS 14997 results for SWA material compared to the Method 1313 mean
and reproducibility limit intervals (RLs).
                                                                                                     G-5
-------
Interlaboratory Validation of LEAF Method 1313 and Method 1316
                                                                                                    14
                                                                   •  SWA-L11-14429-A
                                                                   A  SWA-L11-14429-B
                                                                   D  SWA-L11-14429-C
                                                                   0  SWA-L11-14997-A
                                                                   •  SWA-L12-14997-A
                                                                   A  SWA-L12-14997-B
                                                                   D  SWA-L12-14997-C
                                                                  - SWA M13 13 Mean
                                                                  -- SWAM1313RL
                                                                   O  own pH
Figure 6.  CEN/TS 14429 and CEN/TS 14997 results for SWA material compared to the Method 1313 mean
and reproducibility limit intervals (RLs).
                                                                                                     G-6
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Manganese (mg/L)
b P c
I-1 I-1 I-1 O C

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0 SWA-L11-14997-A
• SWA-L12-14997-A
A SWA-L12-14997-B
D SWA-L12-14997-C
	 SWA M13 13 Mean
	 SWAM1313RL
O own pH
8 10 12 1
0 2 4 6 8 10 12 14
PH
Figure 7.  CEN/TS 14429 and CEN/TS 14997 results for SWA material compared to the Method 1313 mean
and reproducibility limit intervals (RLs).
                                                                                         G-7
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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A SWA-L11-14429-B
D SWA-L11-14429-C
0 SWA-L11-14997-A
• SWA-L12-14997-A
A SWA-L12-14997-B
0 SWA-L12-14997-C
	 SWA M13 13 Mean
	 SWAM1313RL
O own pH
i 10 12 1
0 2 4 6 8 10 12 14
PH
Figure 8.  CEN/TS 14429 and CEN/TS 14997 results for SWA material compared to the Method 1313 mean
and reproducibility limit intervals (RLs).
                                                                                         G-8
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
      1000
I
a
     0.0001
     10000

      1000

       100

        10

         1

       0.1

      0.01

     0.001
                                           MDL
 •  CFS-L11-14429-A

 A  CFS-L11-14429-B

 •  CFS-L11-14429-C

 O  CFS-L11-14997-A

	CFSM1313 Mean

	CFSM1313 RL

 O  own pH
                           6     8
                             PH
                                     10
                                           12    14
Figure 9.  CEN/TS 14429 and CEN/TS 14997 results for CFS material compared to the Method 1313 mean
and reproducibility limit intervals (RLs).
                                                                                                    G-9
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
  '1
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- CFS M1313 Mean



-- CFSM1313RL



 O  own pH
                2    4     6    8    10    12    14

                             PH
Figure 10. CEN/TS 14429 and CEN/TS 14997 results for CFS material compared to the Method 1313 mean

and reproducibility limit intervals (RLs).
                                                                                                    G-10
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
        100 T
         10
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   0.1


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                                                             • CFS-L11-14429-A


                                                             A CFS-L11-14429-B


                                                             • CFS-L11-14429-C


                                                             O CFS-L11-14997-A


                                                           	CFSM1313Mean


                                                           	CFSM1313RL


                                                             O own pH
Figure 11. CEN/TS 14429 and CEN/TS 14997 results for CFS material compared to the Method 1313 mean
and reproducibility limit intervals (RLs).
                                                                                                    G-ll
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sodium (mg/L)
3 P 0 C
3 O . I-1 O C
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p c
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0 2 4 6 8 10 12 14
• CFS-L11-14429-A
A CFS-L11-14429-B
• CFS-L11-14429-C
O CFS-L11-14997-A
	 CFSM1313Mean
	 CFSM1313RL
O own pH

i 10 12 1
                         PH


Figure 12.  CEN/TS 14429 and CEN/TS 14997 results for CFS material compared to the Method 1313 mean
and reproducibility limit intervals (RLs).
                                                                                       G-12
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
          Appendix H.    Summary of Analytical QA/QC for Selected Analytes
                                       H-i
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
EaFA Coal Combustion Fly Ash
Method 1313
                            Overall Mean RSD    2.5%
                          Stdev of Mean RSDs    1.4%
                    Overall Mean Completeness     98%

                          Max Spike Recovery    118%
                           Min Spike Recovery     81%
Antimony
Sb
Lab#
L01
L02
L04
LOS
L06
L07
108
L09
L10
L11
Ref
Mean
Mean
RSD
6.2%
5.0%
5.6%
5.8%
4.5%
5.6%
6.6%
5.5%
5.7%
5.6%
5.5%
5.6%
Stdev
RSD Complete
1.4% 100.0%
2.7%
2.9%
2.7%
3.0%
3.1%
3.3%
3.2%
2.8%
2.8%
3.0%

96.3%
96.3%
96.3%
100.0%
96.3%
96.3%
92.6%
96.3%
92.6%
96.3%
96.3%
Spike Spike
Rec Max Rec Min
105% 101%
1 1 3%
1 1 5%
98%
100%
112%
101%
104%
102%
1 1 0%
102%
115%
106%
107%
94%
95%
97%
100%
102%
92%
97%
92%
92% Max-Min
Arsenic
As
Lab#
L01
L02
L04
L05
L06
L07
108
L09
L10
L11
Ref
Mean

Mean
RSD
4.7%
4.3%
3.5%
3.4%
4.5%
4.2%
4.8%
3.5%
4.0%
4.5%
3.8%
4.1%


Stdev
RSD Complete
3.6% 96.3%
2.8%
3.1%
2.9%
3.0%
3.2%
3.2%
2.7%
3.9%
3.6%
2.6%

96.3%
100.0%
100.0%
96.3%
96.3%
96.3%
100.0%
92.6%
96.3%
98.1%
97.2%


Spike Spike
Rec Max Rec Min
105% 101%
112%
116%
93%
102%
101%
102%
100%
100%
108%
101%
116%
101%
107%
91%
96%
96%
98%
98%
90%
99%
89%
89% Max-Min
                                                                                   H-l
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
EaFA Coal Combustion Fly Ash
Method 1313
Boron
B
Lab#
L01
L02
L04
LOS
L06
L07
LOS
L09
L10
L11
Ref
Mean

Mean
RSD
0.9%
2.3%
0.9%
1 .3%
2.6%
2.1%
2.5%
1 .2%
1.1%
0.8%
0.9%
1 .5%


Stdev
RSD Complete
0.8% 100.0%
2.1%
0.6%
1 .2%
2.7%
2.3%
2.4%
0.8%
0.8%
0.6%
0.5%

100.0%
100.0%
96.3%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
99.7%


Spike Spike
Rec Max Rec Min
88% 81%
109%
86%
97%
100%
91%
91%
99%
92%
95%
104%
1 09%
95%
81%
86%
87%
84%
85%
84%
87%
89%
82%
81%
         Barium
         Ba
         Calcium
         Ca
                 Lab#
                    L01
                    L02
                    L04
                    L05
                    L06
                    L07
                    LOS
                    L09
                    L10
                    L11
                    Ref
                     Mean
                 Lab#
                    L01
                    L02
                    L04
                    L05
                    L06
                    L07
                    LOS
                    L09
                    L10
                    L11
                    Ref
                     Mean
Mean
RSD
  0.7%
  2.1%
  1.5%
  0.7%
  2.6%
  2.0%
  2.2%
  0.6%
  0.7%
  0.7%
  0.8%
  1.3%
Mean
RSD
  0.8%
  2.0%
  0.6%
  0.6%
  2.6%
  2.0%
  2.1%
  0.7%
  1.0%
  0.7%
  0.7%
  1.2%
Stdev
 RSD
  0.9%
  2.4%
  2.2%
  0.7%
  2.8%
  2.5%
  2.6%
  0.5%
  0.8%
  0.5%
  0.6%
Stdev
 RSD
  1.0%
  2.2%
  0.4%
  0.7%
  2.8%
  2.5%
  2.7%
  0.5%
  1.3%
  0.3%
  0.4%
Complete
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
Complete
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
Spike
Rec Max
88%
109%
86%
97%
100%
91%
91%
99%
92%
95%
104%
1 09%
Spike
Rec Max
96%
101%
108%
93%
92%
111%
88%
92%
91%
95%
92%
111%
Spike
Rec Max
83%
90%
88%
86%
95%
99%
89%
87%
89%
90%
91%
99%
Spike
Rec Min
81%
95%
81%
86%
87%
84%
85%
84%
87%
89%
82%
81% Max-Min
Spike
Rec Min
90%
89%
100%
91%
86%
87%
87%
88%
81%
84%
83%
81% Max-Min
Spike
Rec Min
81%
85%
81%
85%
89%
87%
85%
81%
82%
86%
84%
81% Max-Min
                                                                                   H-2
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
EaFA Coal Combustion Fly Ash
Method 1313
Chromium
Cr
Lab#
L01
L02
L04
LOS
L06
L07
LOS
L09
L10
L11
Ref
Mean

Mean
RSD
1 .8%
2.9%
1.1%
2.0%
3.3%
3.2%
3.6%
1 .0%
1 .7%
1 .2%
1 .0%
2.0%

Stdev
RSD
2.7%
2.6%
1 .4%
2.6%
3.1%
3.7%
3.1%
0.9%
2.4%
1 .8%
0.8%



Complete
100.0%
100.0%
100.0%
100.0%
100.0%
96.3%
100.0%
100.0%
55.6%
100.0%
100.0%
96.0%

Spike
Rec Max
104%
106%
108%
98%
98%
98%
97%
103%
99%
107%
99%
1 08%

Spike
Rec Min
99%
100%
102%
94%
94%
94%
95%
100%
89%
95%
91%
89% Max-Min
Cobalt
Co
Lab#
L01
L02
L04
L05
L06
L07
LOS
L09
L10
L11
Ref
Mean

Mean
RSD
1 .7%
3.8%
1 .6%
1 .7%
3.6%
2.2%
2.8%
1 .8%
2.8%
2.3%
1 .9%
2.3%


Stdev
RSD Complete
1.1% 100.0%
3.8%
1 .3%
1 .4%
2.6%
2.4%
2.2%
2.1%
2.8%
2.3%
1 .7%

96.3%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
99.7%


Spike Spike
Rec Max Rec Min
109% 105%
108%
107%
100%
99%
112%
98%
104%
101%
106%
102%
112%
103%
100%
96%
96%
94%
97%
101%
91%
96%
92%
91% Max-Min
Molybdenum
Mo
Lab#
L01
L02
L04
L05
L06
L07
LOS
L09
L10
L11
Ref
Mean
Mean
RSD
1 .2%
2.6%
0.8%
0.9%
2.8%
2.0%
2.9%
1 .2%
0.9%
1 .2%
0.8%
1 .5%
Stdev
RSD Complete
1.1% 100.0%
2.8%
0.5%
0.8%
2.7%
2.2%
3.0%
0.7%
0.7%
1 .2%
0.5%

96.3%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
99.7%
Spike Spike
Rec Max Rec Min
94% 92%
108%
97%
90%
100%
106%
90%
103%
92%
98%
108%
1 08%
90%
89%
87%
83%
86%
87%
97%
84%
87%
89%
83%
                                                                                  H-3
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
EaFA Coal Combustion Fly Ash
Method 1313
Selenium
Se
Lab#
L01
L02
L04
LOS
L06
L07
LOS
L09
L10
L11
Ref
Mean
Vanadium
V

Mean
RSD
3.0%
3.4%
2.8%
2.7%
4.1%
3.4%
3.1%
2.9%
3.3%
3.3%
2.5%
3.1%



Stdev
RSD
2.8%
3.0%
3.2%
2.4%
3.0%
2.9%
2.9%
2.9%
2.3%
3.0%
1 .7%





Complete
96.3%
92.6%
96.3%
100.0%
96.3%
100.0%
96.3%
96.3%
100.0%
96.3%
100.0%
97.5%


Mean RSC Stdev RSC Completeness
L01
L02
L04
LOS
L06
L07
LOS
L09
L10
L11
Ref
Mean
1 .2%
2.6%
1 .2%
1 .2%
2.9%
2.4%
2.2%
1 .0%
1 .0%
1 .5%
1 .5%
1 .7%
1 .3%
2.5%
1 .2%
0.8%
2.7%
2.2%
2.0%
0.5%
0.6%
1.1%
1 .2%

100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%

Spike
Rec Max
91%
1 1 0%
114%
87%
98%
87%
90%
96%
88%
91%
105%
114%


Rec Max
97%
108%
103%
93%
101%
93%
92%
104%
91%
101%
1 1 8%
118%

Spike
Rec Min
88%
83%
105%
84%
84%
85%
86%
88%
83%
82%
92%
82% Max-Min


Rec Min
95%
93%
96%
91%
93%
90%
90%
101%
82%
90%
92%
82% Max-Min
                                                                                  H-4
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
SWA Solidified Waste Analog
Method 1313
                             Overall Mean RSD     1.9%
                           Stdev of Mean RSDs     0.9%
                     Overall Mean Completeness     100%

                           Max Spike Recovery     119%
                            Min Spike Recovery      82%
Antimony
Sb
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
2.0%
2.4%
2.2%
1 .4%
2.5%
1 .7%
1 .9%
1 .9%
3.2%
1 .7%
2.1%
Stdev
RSD Complete
2.3% 100.0%
2.5%
2.7%
1 .4%
2.0%
1 .9%
2.3%
1 .6%
2.6%
1 .6%

100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Max Rec Min
116% 103%
100%
99%
106%
107%
103%
107%
111%
106%
1 1 7%
117%
96%
92%
101%
89%
91%
94%
106%
99%
95%
89% Max-Min
Arsenic
As
Lab#
L01
L02
L04
L05
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
2.7%
2.9%
3.1%
2.6%
2.9%
3.1%
2.7%
3.7%
4.0%
2.5%
3.0%

Stdev
RSD
2.5%
2.4%
2.9%
2.6%
2.9%
2.5%
2.2%
2.7%
3.3%
2.5%



Complete
100.0%
100.0%
96.4%
100.0%
96.7%
100.0%
100.0%
100.0%
96.3%
100.0%
99.0%

Spike
Rec Max
96%
112%
111%
95%
1 1 9%
1 1 9%
88%
106%
101%
109%
119%

Spike
Rec Min
85%
99%
107%
90%
118%
109%
84%
98%
96%
85%
84% Max-Min
                                                                                     H-5
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
SWA Solidified Waste Analog
Method 1313
Boron
B
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
0.7%
1 .2%
0.7%
1 .2%
1 .6%
0.8%
0.8%
1 .6%
2.2%
0.9%
1.1%

Stdev
RSD
0.6%
0.8%
0.4%
1 .5%
1 .8%
0.7%
1.1%
1 .6%
2.0%
1 .0%



Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%

Spike
Rec Max
95%
105%
1 1 8%
95%
1 1 8%
116%
102%
106%
99%
108%
118%

Spike
Rec Min
93%
103%
112%
91%
114%
94%
92%
91%
92%
92%
91%
         Barium
         Ba
         Calcium
         Ca
                 Lab#
                    L01
                    L02
                    L04
                    L05
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
                     Mean
                 Lab#
                    L01
                    L02
                    L04
                    L05
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
                     Mean
Mean
RSD
  1.6%
  1.2%
  0.6%
  1.2%
  1.6%
  0.8%
  1.1%
  1.2%
  1.5%
  0.9%
  1.1%
Mean
RSD
  0.8%
  1.1%
  0.8%
  1.2%
  1.8%
  0.8%
  0.9%
  1.0%
  1.5%
  0.8%
  1.1%
Stdev
 RSD
  4.3%
  1.1%
  0.4%
  1.6%
  1.7%
  0.6%
  2.1%
  1.7%
  1.5%
  1.0%
Stdev
 RSD
  0.7%
  1.1%
  0.4%
  1.3%
  2.0%
  0.7%
  1.2%
  0.9%
  1.8%
  0.7%
Complete
   96.3%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
   99.7%
Complete
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
Spike
Rec Max
95%
105%
1 1 8%
95%
1 1 8%
116%
102%
106%
99%
108%
118%
Spike
Rec Max
88%
96%
107%
90%
102%
102%
101%
98%
108%
105%
1 08%
Spike
Rec Max
91%
99%
97%
91%
95%
86%
1 1 7%
98%
85%
95%
117%
Spike
Rec Min
93%
103%
112%
91%
114%
94%
92%
91%
92%
92%
91% Max-Min
Spike
Rec Min
87%
91%
99%
87%
96%
86%
98%
88%
85%
93%
85% Max-Min
Spike
Rec Min
90%
92%
87%
87%
86%
84%
92%
85%
82%
83%
82% Max-Min
                                                                                   H-6
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
SWA Solidified Waste Analog
Method 1313
Chromium
Cr
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
3.9%
3.0%
3.2%
1 .9%
2.5%
3.0%
2.7%
3.5%
2.2%
1 .5%
2.6%

Stdev
RSD
3.3%
3.3%
3.2%
1 .8%
2.6%
3.3%
2.8%
2.9%
2.1%
2.1%



Complete
100.0%
96.3%
100.0%
100.0%
100.0%
96.3%
100.0%
92.6%
100.0%
100.0%
98.7%

Spike
Rec Max
92%
103%
1 1 5%
98%
1 1 7%
103%
90%
111%
114%
105%
117%

Spike
Rec Min
90%
99%
111%
92%
109%
93%
86%
98%
102%
92%
86% Max-Min
Cobalt
Co
Lab#
L01
L02
L04
L05
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
2.2%
2.2%
2.5%
3.1%
2.5%
2.6%
1 .0%
3.0%
2.1%
2.7%
2.4%

Stdev
RSD
2.4%
2.3%
2.3%
2.3%
2.1%
2.7%
0.7%
2.4%
2.5%
2.7%



Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%

Spike
Rec Max
99%
100%
1 1 7%
93%
1 1 8%
100%
101%
1 1 0%
107%
103%
118%

Spike
Rec Min
98%
97%
111%
92%
109%
92%
98%
98%
102%
92%
92% Max-Min
        Molybdenum
        Mo                Mean     Stdev
                 Lab#       RSD     RSD   Complete
                    L01       2.8%     2.7%   100.0%
                    L02       4.0%     3.0%   96.3%
                    L04       2.2%     2.8%   100.0%
                    L05       2.8%     2.2%   96.3%
                    L06       3.6%     3.1%   100.0%
                    L07       2.7%     2.6%   100.0%
                    L09       3.4%     2.9%   100.0%
                    L10       3.8%     3.2%   96.3%
                    L11       4.6%     3.3%   96.3%
                    Ref       3.4%     2.7%   98.1%
                     Mean    3.3%            98.3%
 Spike    Spike
Rec Max  Rec Min
   103%     103%
   109%
   119%
    99%
   119%
   107%
   105%
   113%
   105%
   104%
   119%
104%
112%
 96%
111%
 92%
102%
 99%
 94%
 92%
 92% Max-Min
                                                                                 H-7
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
SWA Solidified Waste Analog
Method 1313
Selenium
Se
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean
Vanadium
V
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
0.6%
1.1%
0.6%
1 .4%
2.0%
0.7%
0.8%
1 .2%
1 .7%
0.6%
1 .0%

Mean
RSD
1 .2%
1 .8%
1.1%
2.0%
2.2%
1 .3%
1 .4%
2.0%
2.3%
1 .2%
1 .6%

Stdev
RSD
0.6%
0.8%
0.4%
2.2%
2.7%
0.7%
1 .3%
1 .7%
2.0%
2.7%


Stdev
RSD
0.8%
1.1%
0.7%
2.0%
1 .8%
0.8%
1 .0%
1 .9%
2.2%
0.8%



Complete
100.0%
100.0%
100.0%
100.0%
96.7%
100.0%
100.0%
100.0%
100.0%
100.0%
99.7%


Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike
Rec Max
93%
88%
91%
97%
105%
99%
1 1 5%
99%
92%
105%
115%
Spike
Rec Max
100%
1 1 3%
1 1 8%
92%
1 1 8%
106%
100%
114%
102%
107%
118%
Spike
Rec Min
85%
83%
87%
91%
94%
86%
105%
87%
86%
87%
83% Max-Min
Spike
Rec Min
99%
103%
113%
88%
110%
100%
97%
100%
88%
94%
88% Max-Min
                                                                                     H-8
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
CFS Contaminated Field Soil
Method 1313
                             Overall Mean RSD     2.8%
                           Stdev of Mean RSDs     1.9%
                     Overall Mean Completeness      98%

                           Max Spike Recovery     118%
                            Min Spike Recovery      82%
Antimony
Sb
Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
4.6%
6.1%
6.6%
6.6%
7.2%
5.5%
7.1%
6.6%
6.3%
Stdev
RSD Complete
3.1% 92.6%
3.5%
2.8%
3.2%
3.1%
2.9%
3.7%
2.8%

92.6%
96.3%
92.6%
92.6%
93.3%
92.6%
94.4%
93.5%
Spike Spike
Rec Max Rec Min
117% 111%
1 1 8%
116%
1 1 5%
109%
98%
94%
93%
118%
114%
111%
109%
98%
91%
87%
83%
83% Max-Min
Arsenic
As
Lab#
L01
L04
L06
L07
L09
L10
L11
Ref


Mean
RSD
4.7%
3.7%
3.4%
3.4%
4.1%
3.0%
4.3%
4.7%
4.0%


Stdev
RSD Complete
3.2% 96.3%
2.8%
2.4%
2.6%
3.4%
3.1%
3.1%
3.2%

100.0%
100.0%
100.0%
96.3%
96.7%
100.0%
98.1%
98.4%


Spike Spike
Rec Max Rec Min
107% 105%
1 1 8%
112%
1 1 7%
111%
102%
95%
93%
118%
117%
112%
101%
103%
94%
87%
87%
87% Max-Min
                                                                                     H-9
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
CFS Contaminated Field Soil
Method 1313
         Barium
         Ba
                  Lab#
                    L01
                    L04
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
                   Mean
         Cadmiun
         Cd
                  Lab#
                    L01
                    L04
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
                   Mean
Mean
RSD
1 .7%
1 .7%
2.1%
1 .3%
1 .2%
1.1%
1 .7%
1 .7%
1 .6%
Mean
RSD
0.8%
1 .4%
1 .6%
0.9%
1 .3%
0.7%
1 .2%
1 .2%
1.1%
Mean
RSD
1 .4%
1 .4%
1 .5%
1 .5%
1.1%
1.1%
1.1%
1.1%
1 .2%
Stdev
RSD Complete
1.4% 100.0%
1.0% 100.0%
2.6% 96.3%
0.9% 100.0%
0.8% 100.0%
0.9% 100.0%
1.8% 100.0%
1.4% 100.0%
99.6%
Stdev
RSD Complete
0.8% 100.0%
1.3% 100.0%
2.0% 100.0%
0.7% 100.0%
1.8% 100.0%
0.4% 100.0%
1.4% 100.0%
1.1% 100.0%
100.0%
Stdev
RSD Complete
2.1% 100.0%
1.1% 100.0%
1.7% 100.0%
1.5% 100.0%
0.9% 100.0%
1 .5% 96.7%
1.4% 100.0%
0.8% 100.0%
99.6%
Spike
Rec Max
108%
114%
1 1 8%
1 1 0%
108%
1 1 7%
94%
96%
118%
Spike
Rec Max
90%
88%
94%
94%
108%
104%
89%
111%
111%
Spike
Rec Max
1 1 8%
1 1 5%
1 1 3%
1 1 0%
106%
96%
97%
97%
118%
Spike
Rec Min
101%
108%
102%
104%
100%
110%
89%
89%
89% Max-Min
Spike
Rec Min
82%
83%
85%
89%
98%
97%
85%
101%
82% Max-Min
Spike
Rec Min
110%
109%
107%
105%
95%
92%
94%
86%
86% Max-Min
                                                                                   H-10
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
CFS Contaminated Field Soil
Method 1313
         Calcium
         Ca
         Lead
         Pb
                  Lab#
                    L01
                    L04
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
                   Mean
         Molybdenum
         Mo
                  Lab#
                    L01
                    L04
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
                    Mean
Mean
RSD
1.1%
0.7%
1 .4%
0.7%
0.6%
0.8%
1 .0%
1 .0%
0.9%
Mean
RSD
0.9%
1 .4%
2.7%
1 .2%
1.1%
1 .6%
1 .4%
1 .7%
1 .5%
Mean
RSD
3.2%
3.4%
3.7%
3.1%
4.0%
4.3%
4.1%
3.3%
3.6%
Stdev
RSD Complete
1.7% 100.0%
0.7% 100.0%
1.7% 100.0%
0.5% 100.0%
0.3% 100.0%
0.4% 100.0%
1.5% 100.0%
0.9% 100.0%
100.0%
Stdev
RSD Complete
0.2% 100.0%
1.4% 100.0%
2.8% 96.3%
1.1% 100.0%
0.9% 100.0%
1.8% 100.0%
1.5% 100.0%
1.8% 100.0%
99.6%
Stdev
RSD Complete
3.1% 100.0%
3.3% 96.3%
4.0% 92.6%
3.1% 100.0%
4.1% 92.6%
4.2% 93.3%
3.8% 96.3%
3.1% 98.1%
96.4%
Spike
Rec Max
90%
92%
88%
90%
92%
87%
89%
92%
92%
Spike
Rec Max
112%
98%
95%
92%
103%
97%
102%
100%
112%
Spike
Rec Max
111%
101%
91%
100%
93%
93%
89%
107%
111%
Spike
Rec Min
89%
86%
82%
86%
85%
84%
83%
84%
82% Max-Min
Spike
Rec Min
94%
88%
89%
84%
99%
89%
95%
85%
84% Max-Min
Spike
Rec Min
103%
96%
87%
91%
90%
88%
86%
97%
86% Max-Min
                                                                                   H-ll
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
CFS Contaminated Field Soil
Method 1313
Selenium
Se
Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
4.9%
4.7%
4.3%
3.9%
5.5%
5.0%
6.1%
4.9%
4.9%

Stdev
RSD
2.7%
3.6%
2.1%
3.0%
3.2%
3.3%
2.9%
1 .8%



Complete
96.3%
96.3%
100.0%
92.6%
96.3%
93.3%
92.6%
100.0%
96.4%

Spike
Rec Max
99%
1 1 7%
112%
112%
100%
92%
90%
103%
117%

Spike
Rec Min
96%
111%
107%
96%
97%
87%
87%
95%
87%
Vanadium
V
Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
3.7%
2.9%
3.4%
3.7%
3.1%
3.8%
2.4%
2.9%
3.2%

Stdev
RSD
2.5%
2.1%
2.2%
2.6%
1 .8%
3.2%
1 .9%
1 .6%



Complete
96.3%
100.0%
100.0%
100.0%
100.0%
96.7%
100.0%
100.0%
99.2%

Spike
Rec Max
1 1 5%
1 1 7%
112%
1 1 8%
104%
97%
104%
106%
118%

Spike
Rec Min
106%
110%
104%
110%
94%
89%
98%
96%
89% Max-Min
                                                                                   H-12
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
EaFA Coal Combustion Fly Ash
Method 1316
                            Overall Mean RSD     3.0%
                          Stdev of Mean RSDs     1.6%
                     Overall Mean Completeness     99%

                          Max Spike Recovery    120%
                           Min Spike Recovery     80%
Antimony
Sb
Lab#
L01
L02
L04
LOS
L06
L07
LOS
L09
L10
L11
Ref
Mean

Mean
RSD
4.6%
3.8%
4.1%
4.9%
4.7%
3.8%
3.9%
5.0%
4.4%
4.1%
6.2%
4.7%

Stdev
RSD
2.3%
2.0%
2.5%
2.6%
2.0%
2.5%
2.9%
2.3%
2.6%
2.7%
2.2%



Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%

Spike
Rec Max
104%
1 1 7%
1 1 7%
116%
106%
107%
109%
104%
95%
104%
102%
117%

Spike
Rec Min
93%
110%
110%
102%
102%
105%
105%
100%
88%
99%
96%
88% Max-Min
Arsenic
As
Lab#
L01
L02
L04
L05
L06
L07
LOS
L09
L10
L11
Ref
Mean

Mean
RSD
7.5%
5.2%
5.6%
6.4%
6.1%
5.4%
5.4%
5.9%
6.1%
5.6%
4.8%
5.7%

Stdev
RSD
2.7%
3.1%
3.4%
4.2%
2.7%
3.1%
2.3%
2.6%
3.3%
3.0%
3.0%



Complete
100.0%
93.3%
93.3%
91.7%
93.3%
93.3%
100.0%
100.0%
93.3%
91.7%
91.7%
94.4%

Spike
Rec Max
104%
1 1 5%
1 1 7%
1 1 3%
111%
109%
109%
104%
100%
103%
1 1 7%
117%

Spike
Rec Min
94%
109%
112%
101%
104%
106%
105%
98%
92%
102%
98%
92% Max-Min
                                                                                  H-13
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
EaFA Coal Combustion Fly Ash
Method 1316
Boron
B
Lab#
L01
L02
L04
LOS
L06
L07
LOS
L09
L10
L11
Ref
Mean

Mean
RSD
1 .4%
2.4%
1 .5%
1 .8%
1.1%
1 .4%
2.7%
2.0%
2.1%
1 .4%
1 .3%
1 .7%


Stdev
RSD Complete
0.9% 100.0%
2.6%
0.5%
1 .7%
0.9%
0.8%
2.9%
2.2%
1 .6%
0.7%
0.8%

100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%


Spike Spike
Rec Max Rec Min
86% 81%
92%
91%
108%
94%
101%
90%
87%
90%
92%
104%
1 08%
88%
87%
87%
88%
87%
85%
84%
84%
87%
88%
81%
         Barium
         Ba
         Calcium
         Ca
                 Lab#
                    L01
                    L02
                    L04
                    L05
                    L06
                    L07
                    LOS
                    L09
                    L10
                    L11
                    Ref
                     Mean
                 Lab#
                    L01
                    L02
                    L04
                    L05
                    L06
                    L07
                    LOS
                    L09
                    L10
                    L11
                    Ref
                     Mean
Mean
RSD
  1.0%
  1.9%
  0.8%
  0.8%
  1.4%
  1.1%
  2.3%
  1.9%
  1.7%
  0.7%
  0.8%
  1.3%
Mean
RSD
  1.1%
  1.5%
  1.0%
  0.9%
  1.6%
  1.0%
  2.4%
  2.0%
  1.5%
  0.8%
  0.8%
  1.3%
Stdev
 RSD
  1.0%
  2.1%
  0.5%
  0.6%
  2.2%
  1.1%
  3.2%
  2.8%
  1.8%
  0.4%
  1.1%
Stdev
 RSD
  1.1%
  1.4%
  0.7%
  0.5%
  2.3%
  1.0%
  3.3%
  2.5%
  1.9%
  0.5%
  1.2%
Complete
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
Complete
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
Spike
Rec Max
86%
92%
91%
108%
94%
101%
90%
87%
90%
92%
104%
1 08%
Spike
Rec Max
93%
104%
114%
101%
99%
100%
97%
94%
85%
96%
97%
114%
Spike
Rec Max
97%
91%
90%
90%
90%
85%
95%
89%
90%
93%
93%
97%
Spike
Rec Min
81%
88%
87%
87%
88%
87%
85%
84%
84%
87%
88%
81% Max-Min
Spike
Rec Min
83%
98%
110%
92%
94%
98%
95%
91%
80%
92%
94%
80% Max-Min
Spike
Rec Min
91%
85%
86%
83%
83%
82%
85%
82%
83%
88%
83%
82% Max-Min
                                                                                  H-14
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
EaFA Coal Combustion Fly Ash
Method 1316
Chromium
Cr
Lab#
L01
L02
L04
LOS
L06
L07
LOS
L09
L10
L11
Ref
Mean

Mean
RSD
5.0%
4.9%
4.1%
5.8%
4.3%
5.1%
5.4%
4.4%
4.8%
1 .0%
3.0%
4.2%

Stdev
RSD
2.5%
2.4%
2.2%
2.5%
2.5%
2.9%
3.2%
2.6%
2.6%
0.5%
1 .6%



Complete
100.0%
93.3%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
99.4%

Spike
Rec Max
102%
112%
111%
109%
108%
107%
103%
103%
91%
100%
111%
112%

Spike
Rec Min
92%
105%
106%
100%
101%
104%
101%
100%
86%
95%
101%
86% Max-Min
Cobalt
Co
Lab#
L01
L02
L04
L05
L06
L07
LOS
L09
L10
L11
Ref
Mean

Mean
RSD
4.1%
4.1%
3.3%
2.7%
2.9%
3.1%
3.3%
3.3%
3.4%
5.0%
3.4%
3.5%

Stdev
RSD
2.6%
2.8%
1 .9%
2.1%
2.2%
2.2%
3.0%
2.0%
2.9%
2.2%
1 .8%



Complete
100.0%
93.3%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
99.4%

Spike
Rec Max
105%
111%
109%
1 1 0%
107%
106%
103%
103%
92%
101%
111%
111%

Spike
Rec Min
95%
107%
103%
100%
101%
102%
101%
99%
87%
96%
101%
87% Max-Min
Molybdenum
Mo
Lab#
L01
L02
L04
L05
L06
L07
LOS
L09
L10
L11
Ref
Mean
Mean
RSD
1.1%
2.1%
1 .0%
0.9%
1 .4%
1.1%
2.2%
1 .7%
1 .5%
0.8%
0.9%
1 .3%
Stdev
RSD Complete
1.2% 100.0%
2.2%
0.7%
0.8%
2.2%
1 .0%
3.0%
2.5%
1 .9%
0.5%
1 .2%

100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Max Rec Min
89% 83%
1 1 0%
102%
105%
93%
95%
96%
95%
96%
88%
99%
110%
92%
94%
99%
82%
81%
83%
82%
87%
86%
91%
81% Max-Min
                                                                                 H-15
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
EaFA Coal Combustion Fly Ash
Method 1316
Selenium
Se
Lab#
L01
L02
L04
LOS
L06
L07
LOS
L09
L10
L11
Ref
Mean
Vanadium
V
Lab#
L01
L02
L04
LOS
L06
L07
LOS
L09
L10
L11
Ref
Mean

Mean
RSD
2.3%
4.6%
2.3%
2.9%
2.9%
2.2%
2.7%
2.5%
2.4%
2.7%
3.0%
2.8%

Mean
RSD
1 .3%
2.1%
1 .6%
1.1%
1 .8%
1 .7%
2.7%
2.5%
2.0%
1 .9%
1 .9%
1 .9%

Stdev
RSD
1 .3%
3.3%
0.9%
1 .5%
1.1%
1 .8%
3.2%
1 .9%
2.5%
1 .2%
1 .8%


Stdev
RSD
0.8%
2.1%
1 .0%
1 .0%
1 .9%
0.9%
3.3%
2.6%
2.0%
1 .0%
1 .3%



Complete
100.0%
93.3%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
99.4%


Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike
Rec Max
97%
120%
1 1 0%
111%
106%
106%
107%
102%
95%
102%
94%
120%
Spike
Rec Max
100%
112%
112%
1 1 0%
109%
109%
104%
108%
90%
100%
111%
112%
Spike
Rec Min
86%
102%
103%
101%
100%
100%
99%
96%
86%
96%
87%
86% Max-Min
Spike
Rec Min
91%
105%
107%
99%
103%
106%
102%
103%
84%
96%
101%
84% Max-Min
                                                                                 H-16
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
SWA Solidified Waste Analog
Method 1316
                             Overall Mean RSD     1.5%
                           Stdev of Mean RSDs     0.7%
                     Overall Mean Completeness     100%

                           Max Spike Recovery     120%
                            Min Spike Recovery      83%
Antimony
Sb
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
0.8%
1 .3%
1 .5%
1.1%
1 .4%
1 .2%
0.7%
0.9%
3.5%
1 .8%
1 .4%

Stdev
RSD
0.3%
0.9%
1 .3%
0.8%
1.1%
0.9%
0.3%
0.5%
3.1%
1 .5%



Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%

Spike
Rec Max
95%
99%
114%
98%
92%
105%
92%
101%
93%
104%
114%

Spike
Rec Min
92%
95%
110%
91%
86%
84%
88%
92%
87%
99%
84%
Arsenic
As
Lab#
L01
L02
L04
L05
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
1 .0%
1.1%
1 .0%
1 .4%
0.9%
0.6%
1 .0%
1 .0%
0.9%
2.1%
1 .2%


Stdev
RSD Complete
0.4% 100.0%
0.6%
0.6%
1 .3%
0.5%
0.3%
0.8%
0.6%
0.4%
2.0%

100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%


Spike Spike
Rec Max Rec Min
109% 88%
91%
97%
92%
92%
102%
92%
101%
99%
105%
1 09%
85%
87%
88%
87%
84%
90%
90%
93%
100%
84% Max-Min
                                                                                    H-17
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
SWA Solidified Waste Analog
Method 1316
Boron
B
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
1 .0%
0.9%
0.9%
1 .0%
0.6%
0.7%
0.6%
1 .0%
0.5%
2.0%
1 .0%


Stdev
RSD Complete
0.3% 100.0%
0.4%
0.6%
0.7%
0.5%
0.4%
0.3%
0.7%
0.2%
1 .9%

100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%


Spike Spike
Rec Max Rec Min
108% 106%
104%
104%
107%
1 1 8%
101%
98%
93%
94%
105%
118%
94%
96%
86%
97%
91%
90%
88%
90%
89%
86%
         Barium
         Ba
         Calcium
         Ca
                 Lab#
                    L01
                    L02
                    L04
                    L05
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
                     Mean
                 Lab#
                    L01
                    L02
                    L04
                    L05
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
                     Mean
Mean
RSD
  1.4%
  0.7%
  2.2%
  1.4%
  1.2%
  0.9%
  1.0%
  0.9%
  0.5%
  2.7%
  1.4%
Mean
RSD
  1.2%
  1.2%
  1.3%
  1.8%
  1.9%
  1.7%
  2.4%
  1.0%
  0.5%
  3.1%
  1.8%
Stdev
 RSD
  1.3%
  0.4%
  2.4%
  1.8%
  1.2%
  0.8%
  0.6%
  0.7%
  0.5%
  2.1%
Stdev
 RSD
  0.9%
  0.7%
  1.0%
  1.4%
  1.5%
  1.8%
  2.6%
  0.6%
  0.3%
  2.7%
Complete
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
Complete
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
Spike
Rec Max
108%
104%
104%
107%
1 1 8%
101%
98%
93%
94%
105%
118%
Spike
Rec Max
86%
94%
120%
95%
94%
94%
95%
104%
100%
93%
120%
Spike
Rec Max
105%
92%
1 1 5%
94%
93%
93%
89%
112%
95%
90%
115%
Spike
Rec Min
106%
94%
96%
86%
97%
91%
90%
88%
90%
89%
86% Max-Min
Spike
Rec Min
85%
85%
117%
90%
93%
85%
86%
95%
90%
85%
85% Max-Min
Spike
Rec Min
101%
87%
92%
91%
88%
85%
87%
92%
91%
86%
85% Max-Min
                                                                                  H-18
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
SWA Solidified Waste Analog
Method 1316
Chromium
Cr
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
1 .0%
0.9%
1 .3%
1 .4%
0.9%
0.8%
0.8%
0.7%
1 .0%
3.3%
1 .4%


Stdev
RSD Complete
0.7% 100.0%
0.4%
0.9%
1 .3%
0.3%
0.5%
0.4%
0.4%
0.4%
3.0%

100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%


Spike Spike
Rec Max Rec Min
103% 90%
109%
102%
98%
108%
103%
95%
112%
92%
87%
112%
92%
89%
94%
91%
99%
89%
108%
88%
86%
86% Max-Min
Cobalt
Co
Lab#
L01
L02
L04
L05
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
3.8%
2.3%
7.7%
0.0%
3.8%
5.2%
7.4%
2.6%
0.0%
1 .8%
3.3%

Stdev
RSD
0.3%
1 .0%
3.5%
0.0%
0.0%
2.1%
4.5%
1 .9%
0.0%
0.0%



Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%

Spike
Rec Max
105%
105%
116%
92%
1 1 3%
93%
100%
111%
100%
112%
116%

Spike
Rec Min
101%
95%
108%
89%
110%
83%
93%
93%
99%
103%
83% Max-Min
Molybdenum
Mo
Lab#
L01
L02
L04
L05
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
0.7%
0.9%
1.1%
1 .4%
0.7%
1.1%
0.7%
1.1%
0.8%
1 .9%
1.1%

Stdev
RSD
0.4%
0.4%
0.6%
1.1%
0.3%
0.9%
0.4%
1 .0%
0.5%
1 .7%



Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%

Spike
Rec Max
112%
95%
1 1 7%
111%
1 1 7%
99%
103%
90%
100%
1 1 3%
117%

Spike
Rec Min
110%
89%
111%
106%
112%
92%
88%
84%
98%
105%
84% Max-Min
                                                                                    H-19
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
SWA Solidified Waste Analog
Method 1316
Selenium
Se
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean
Vanadium
V
Lab#
L01
L02
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
0.6%
0.8%
0.6%
0.9%
0.7%
0.5%
0.6%
0.8%
0.4%
1 .7%
0.8%

Mean
RSD
0.7%
0.9%
1.1%
1 .5%
1 .0%
0.7%
0.8%
0.7%
1.1%
1 .7%
1.1%

Stdev
RSD
0.3%
0.5%
0.3%
0.9%
0.4%
0.3%
0.3%
0.6%
0.1%
0.0%


Stdev
RSD
0.4%
0.5%
0.6%
1 .3%
0.6%
0.5%
0.3%
0.4%
0.5%
1 .6%



Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%


Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike
Rec Max
1 1 3%
96%
1 1 8%
92%
96%
98%
101%
85%
109%
99%
118%
Spike
Rec Max
105%
107%
112%
104%
1 1 5%
92%
102%
95%
94%
111%
115%
Spike
Rec Min
85%
88%
102%
86%
87%
87%
92%
83%
87%
95%
83% Max-Min
Spike
Rec Min
103%
103%
105%
94%
108%
83%
94%
90%
94%
101%
83% Max-Min
                                                                                    H-20
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
CFS Contaminated Field Soil
Method 1316
                             Overall Mean RSD     3.0%
                           Stdev of Mean RSDs     2.2%
                     Overall Mean Completeness      98%

                           Max Spike Recovery     115%
                            Min Spike Recovery      82%
Antimony
Sb
Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
6.0%
4.9%
5.2%
5.3%
5.6%
5.7%
5.7%
6.8%
5.8%
Stdev
RSD Complete
3.3% 93.3%
3.4%
3.7%
3.0%
2.5%
3.5%
2.9%
3.5%

93.3%
93.3%
93.3%
93.3%
93.3%
93.3%
91.7%
93.0%
Spike Spike
Rec Max Rec Min
102% 100%
105%
101%
98%
103%
1 1 0%
89%
1 1 3%
113%
103%
96%
96%
101%
97%
87%
99%
87% Max-Min
Arsenic
As
Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
6.8%
7.4%
6.0%
4.4%
5.1%
6.5%
4.8%
4.5%
5.5%


Stdev
RSD Complete
3.3% 93.3%
2.5%
2.6%
2.6%
2.3%
3.7%
2.2%
2.9%

93.3%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
98.5%


Spike Spike
Rec Max Rec Min
106% 102%
108%
104%
98%
103%
1 1 3%
90%
1 1 3%
113%
102%
99%
96%
101%
99%
89%
99%
89% Max-Min
                                                                                    H-21
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
CFS Contaminated Field Soil
Method 1316
B









Barium
Ba









Cadmium
Cd










Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean


Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean


Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
0.7%
1.1%
0.8%
1 .2%
0.6%
1 .0%
1 .7%
1 .9%
1 .2%

Mean
RSD
0.4%
0.7%
0.6%
1 .2%
0.6%
0.8%
1.1%
1 .2%
0.9%

Mean
RSD
0.6%
0.5%
0.5%
1 .3%
0.7%
0.7%
0.8%
1 .5%
0.9%
Stdev
RSD Complete
0.5% 100.0%
0.6% 100.0%
0.4% 100.0%
1.4% 100.0%
0.4% 100.0%
0.5% 100.0%
1.2% 100.0%
1.3% 100.0%
100.0%

Stdev
RSD Complete
0.3% 100.0%
0.6% 100.0%
0.3% 100.0%
1.6% 100.0%
0.4% 100.0%
0.3% 100.0%
1.0% 100.0%
1.1% 100.0%
100.0%

Stdev
RSD Complete
0.4% 100.0%
0.3% 100.0%
0.3% 100.0%
1.8% 100.0%
0.4% 100.0%
0.3% 100.0%
0.5% 100.0%
1.4% 100.0%
100.0%
Spike
Rec Max
97%
99%
98%
104%
104%
95%
92%
108%
1 08%
Spike
Rec Max
96%
90%
109%
107%
108%
105%
94%
1 1 5%
115%
Spike
Rec Max
1 1 0%
96%
90%
103%
96%
99%
103%
103%
110%
Spike
Rec Min
95%
97%
94%
93%
102%
93%
87%
93%
87% Max-Min
Spike
Rec Min
92%
87%
104%
97%
106%
98%
84%
100%
84% Max-Min
Spike
Rec Min
95%
89%
87%
85%
88%
95%
98%
90%
85% Max-Min
                                                                                   H-22
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
CFS Contaminated Field Soil
Method 1316
         Lead
         Pb
                 Lab#
                    L01
                    L04
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
                     Mean
         Molybdenum
         Mo
                 Lab#
                    L01
                    L04
                    L06
                    L07
                    L09
                    L10
                    L11
                    Ref
Mean
RSD
  0.8%
  0.8%
  0.7%
  1.4%
  0.6%
  1.0%
  1.1%
  1.9%
  1.1%
                     Mean
Mean
RSD
  6.3%
  5.5%
  5.4%
  6.3%
  4.7%
  4.3%
  6.1%
  5.7%
  5.6%
Stdev
 RSD
  0.4%
  0.7%
  0.4%
  1.3%
  0.4%
  0.4%
  0.8%
  2.4%
Complete
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
  100.0%
   95.8%
   99.1%
Stdev
 RSD
  5.0%
  2.8%
  2.5%
  2.0%
  2.5%
  2.7%
  3.3%
  2.8%
Complete
   93.3%
  100.0%
  100.0%
  100.0%
   93.3%
  100.0%
   93.3%
   95.8%
   96.9%
Spike
Rec Max
88%
92%
89%
89%
92%
91%
92%
90%
92%
Spike
Rec Max
87%
87%
87%
95%
94%
98%
105%
98%
1 05%
Spike
Rec Max
98%
103%
98%
96%
101%
106%
98%
114%
114%
Spike
Rec Min
83%
88%
85%
85%
87%
85%
82%
86%
82% Max-Min
Spike
Rec Min
83%
82%
83%
86%
93%
89%
90%
83%
82% Max-Min
Spike
Rec Min
94%
100%
92%
94%
99%
97%
94%
98%
92% Max-Min
                                                                                  H-23
-------
   Intel-laboratory Validation of LEAF Method 1313 and Method 1316
CFS Contaminated Field Soil
Method 1316
Selenium
Se
Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean
Vanadium
V
Lab#
L01
L04
L06
L07
L09
L10
L11
Ref
Mean

Mean
RSD
3.8%
4.9%
4.2%
4.9%
4.9%
4.4%
4.9%
5.2%
4.7%

Mean
RSD
4.4%
2.6%
3.5%
4.5%
3.7%
3.6%
3.0%
3.2%
3.5%

Stdev
RSD
2.3%
3.4%
3.5%
3.2%
3.2%
2.4%
2.9%
2.4%


Stdev
RSD
2.6%
1 .7%
2.1%
3.0%
1 .7%
2.1%
2.4%
1 .9%



Complete
100.0%
93.3%
93.3%
93.3%
93.3%
100.0%
93.3%
95.8%
95.4%


Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike
Rec Max
101%
104%
98%
100%
101%
105%
94%
109%
1 09%
Spike
Rec Max
97%
103%
97%
95%
101%
1 1 0%
101%
114%
114%
Spike
Rec Min
96%
102%
91%
95%
100%
93%
92%
97%
91% Max-Min
Spike
Rec Min
93%
101%
93%
93%
99%
96%
99%
98%
93% Max-Min
                                                                                   H-24
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
                 Appendix I.     QA/QC Reports for Analytical Samples


TABLE OF CONTENTS	I-i

INTRODUCTION	1-1

ORGANIZATION OF THE QA/QC TABLES	1-1

DESCRIPTION OF THE COLUMNS IN THE ANALYTICAL QA/QC TABLES	1-1

Method 1313: Liquid-Solid Partitioning as a Function of Eluate pH using a Parallel Batch
Extraction Procedure
EaFA - Coal Combustion Fly Ash	1-4
   L01	1-4
   L02	1-33
   L04	1-62
   LOS	1-91
   L06	1-120
   L07	1-149
   L08	1-178
   L09	1-207
   L10	1-236
   Lll	1-265
   Ref	1-294
SWA - Solidified Waste Analog	7-552
   L01	1-352
   L02	1-381
   L04	1-410
   L05	1-439
   L06	1-468
   L07	1-497
   L09	1-526
   L10	1-555
   Lll	1-584
   Ref	1-613
CFS - Contaminated Field Soil.	7-677
   L01	1-671
   L04	1-700
   L06	1-729
   L07	1-758
   L09	1-787
   L10	1-816
   Lll	1-845
   Ref	1-874
                                         I-i
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Method 1316: Liquid-Solid Partitioning as a Function of Liquid-Solid using a Parallel Batch
Extraction Procedure

EaFA - Coal Combustion Fly Ash	1-932
    L01	1-932
    L02	1-961
    L04	1-990
    LOS	1-1019
    L06	1-1048
    L07	1-1077
    L08	1-1106
    L09	1-1135
    L10	1-1164
    Lll	1-1193
    Ref	1-1222
SWA - Solidified Waste Analog	1-1280
    L01	1-1280
    L02	1-1309
    L04	1-1338
    LOS	1-1367
    L06	1-1396
    L07	1-1425
    L09	1-1454
    L10	1-1483
    Lll	1-1512
    Ref	1-1541
CFS - Contaminated Field Soil.	1-1599
    L01	1-1599
    L04	1-1628
    L06	1-1657
    L07	1-1686
    L09	1-1715
    L10	1-1744
    Lll	1-1773
    Ref	1-1802
                                            I-ii
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


INTRODUCTION

The tables in this appendix present the quality assurance/quality control results for the analytical
measurement of eluate concentrations from the preserved eluates submitted by each of the validation
laboratories. The data shown in this appendix is applicable only to the analytical solutions measured by
inductively coupled plasma - optical emissions  spectrometry (ICP-OES) performed by Vanderbilt
University (VU). The analytical methods, instrument calibration, and analytical QA/QC program
followed throughout this project are detailed in the main report.

ORGANIZATION OF THE QA/QC TABLES

Each table in the appendix represents the final eluate solution concentrations for a single element from a
single laboratory. The tables are ordered alphabetically by element symbol (e.g., "Al" for aluminum or
"Sb" for antimony) for each validation laboratory code (e.g., "L01" for Laboratory 1 or "LRef' for
reference laboratory) within each the leaching method (i.e., Method 1313 versus Method 1316).  The
information within each table is ordered by the test position number within each leaching method.

DESCRIPTION OF THE COLUMNS IN THE ANALYTICAL QA/QC TABLES

The following is a description of the columns in each table in the appendix.

Element (1st Column)
Element symbol identifiers based on the periodic chart.

Sample (2nd Column)
Coded identifier for each sample comprised of the following items  separated by dashes:
        •   material code (e.g., "CFS", "SWA", or "JaFS")
        •   laboratory code  (e.g., "L01" for Laboratory 1 or "LRef for reference laboratory)
        •   method code (e.g., "1314" for Method 1314)
        •   test position number (e.g., "T01" for first eluate of the test)
        •   replicate letter (e.g., "A" for first test run)

Dilution Factor (3rd Column)
The dilution factor for the analytical sample measured in the instrument or the multiplier associated with
calculating final eluate concentrations from analytical sample concentration. Typically for ICP-OES, full
strength analytical samples are measured and the resultant dilution  factor is "1". However, dilution
factors of at least "10" are common for inductively coupled plasma - mass spectrometry (ICP-MS)
analysis in order to  minimize interferences from analytical solutions with high sodium and potassium
content.

Sample Cone, in ug/L (4th Column)
The concentration of the analytical sample in (ig/L as measured by  the analytical method specified in the
14th Column.
                                                                                           1-1
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316

Qualifier (5th Column)
A quality control qualifier used to flag analytical samples that are below the quantification or detection
limits.  The following table of qualifiers was used.
   [Qualifier    ^Meaning
                   Estimated value between the MDL and ML values
    U             Non-detected values below the MDL
    Ul/2          Non-detected values below the MDL set to 1A the MDL for graphing purposes
Internal Review (6th Column)
A column used by the Vanderbilt University Laboratory Manager to mark issues with QA/QC for internal
checks.

ICP-OES Cone. (7th Column)
The final eluate concentration used in the validation study determined by multiplying the analytical
sample concentration (4th Column) by the dilution factor (3rd Column).

RSD (8th Column)
Relative standard deviation of the three analytical measurements of the sample analytical sample
calculated automatically through instrument software. The RSD does not represent the relative standard
deviation of replicate analysis using triplicate samples.

MDL (9th Column)
The method detection limit (MDL) in (ig/L for the analysis using the analytical method specified in the
14th Column.  The value is calculated by the VU laboratory manager based on the standard deviation of
analysis of seven low-level standard solutions measured on seven non-consecutive days and the Student's
^-distribution value for the seven replicates at the 99% confidence level (EPA, 2003).

                                  MDL = S{n=7}xt{n_l=6^a=099}
       where S(n=7) is the standard deviation of seven non-consecutive measurements (|ig/L), and
              t(n-i=6,i-a=o.99) is the Student ^-distribution value for seven replicates at the 99% confidence
              level (3.14267).

ML (IP111 Column)
The estimated minimum level of quantification (ML) in (ig/L for the analysis using the analytical method
specified in the 14th Column. The value is calculated by the VU laboratory manager based on the
previously calculated MDL (EPA, 2003).


                                           = 3.\8xMDL

                                                                                             1-2
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316


Spike Cone. (11th Column) and Spike Volume (12th Column)
The concentration in (ig/L of the standard solution used to spike analytical samples and the volume of the
standard solution added to each analytical sample. When multiplied, these values provide the theoretical
mass of an element that is spiked into an analytical sample.
                                          -r     \v       L
                               M QA/QC spike ~ ^ std X\ f/ std X , , '
       where MQA/QC spike is the theoretical mass of spiked into the analytical sample (|ig),
              Cstd is the concentration of the standard solution ((ig/L), and
              Vstd is the volume of the standard solution added to the analytical sample (\\L).

Spike Cone. q3th Column)
The concentration of the spiked analytical solution in (ig/L as measured by the analytical method
specified in the 14th Column.

Spike Recovery (14th Column)
The percentage of spiked mass recovered during analysis of the spiked solution. The spike recovery is
calculated by the VU laboratory manager using the following formula:
                             V- QA/QC spike  *- sample ) X * QA/QC spike
                                                            XlOO%
                                         QA/AC spike
       where CQA/QCspike is the concentration of the spiked analytical sample (|ig/L),
              Csampie is the concentration of the analytical sample in the 4th Column ((ig/L), and
              VQA/QC sptke is the final volume of the spiked analytical sample (L).

Instrument (15th Column)
The instrument used for the analytical measurement (e.g., "VU ICP-OES" denotes that the instrument was
the Vanderbilt University Varian 620 ICP-OES).

Date/Time (16th Column)
The date and time that the analytical sample measurement was recorded by the instrument software.  This
column is used to uniquely identify each analysis and does not reflect the data and time of spiked solution
measurement.

Filename (17th Column)
The name of the instrument output file where the analytical data is stored.
                                                                                             1-3
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al EaFA-L01-1313-T01-A 1
Al EaFA-L01-1313-T02-A 1
Al EaFA-L01-1313-T03-A 1
Al EaFA-L01-1313-T04-A 1
Al EaFA-L01-1313-T05-A 1
Al EaFA-L01-1313-T06-A 1
Al EaFA-L01-1313-T07-A 1
Al EaFA-L01-1313-T08-A 1
Al EaFA-L01-1313-T09-A 1
Al EaFA-L01-1313-T01-B 1
Al EaFA-L01-1313-T02-B 1
Al EaFA-L01-1313-T03-B 1
Al EaFA-L01-1313-T04-B 1
Al EaFA-L01-1313-T05-B 1
Al EaFA-L01-1313-T06-B 1
Al EaFA-L01-1313-T07-B 1
Al EaFA-L01-1313-T08-B 1
Al EaFA-L01-1313-T09-B 1
Al EaFA-L01-1313-T01-C 1
Al EaFA-L01-1313-T02-C 1
Al EaFA-L01-1313-T03-C 1
Al EaFA-L01-1313-T04-C 1
Al EaFA-L01-1313-T05-C 1
Al EaFA-L01-1313-T06-C 1
Al EaFA-L01-1313-T07-C 1
Al EaFA-L01-1313-T08-C 1
Al EaFA-L01-1313-T09-C 1
Al EaFA-L01-1313-B01-A 1
Al EaFA-L01-1313-B02-A 1
Al EaFA-L01-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
4.33E+04
3.22E+04
2.03E+04
8.48E+03
1.37E+03
1.15E+02
2.29E+03
2.94E+04
1.34E+05
3.84E+04
3.18E+04
1.97E+04
8.19E+03
1.36E+03
1.36E+02
2.82E+03
3.04E+04
1.33E+05
3.75E+04
2.83E+04
2.18E+04
8.28E+03
1.30E+03
1.18E+02
2.31 E+03
2.71E+04
1.29E+05
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.33E+04 1.2E+00 1.0E+00 3.2E+00
3.22E+04 1.6E+00 1.0E+00 3.2E+00
2.03E+04 2.2E-01 1.0E+00 3.2E+00 1000 100
8.48E+03 1.3E-01 1.0E+00 3.2E+00
1.37E+03 4.6E+00 1.0E+00 3.2E+00
1.15E+02 1.2E+00 1.0E+00 3.2E+00
2.29E+03 2.7E-01 1.0E+00 3.2E+00
2.94E+04 2.0E-01 1.0E+00 3.2E+00
1.34E+05 4.0E-01 1.0E+00 3.2E+00
3.84E+04 1.2E+00 1.0E+00 3.2E+00
3.18E+04 1.4E+00 1.0E+00 3.2E+00
1.97E+04 6.9E-01 1.0E+00 3.2E+00 1000 100
8.19E+03 2.7E-01 1.0E+00 3.2E+00
1.36E+03 2.8E-01 1.0E+00 3.2E+00
1.36E+02 2.0E+00 1.0E+00 3.2E+00
2.82E+03 6.7E-01 1.0E+00 3.2E+00
3.04E+04 1.9E-01 1.0E+00 3.2E+00
1.33E+05 2.6E-01 1.0E+00 3.2E+00
3.75E+04 1.5E+00 1.0E+00 3.2E+00
2.83E+04 4.8E-01 1.0E+00 3.2E+00
2.18E+04 4.7E-01 1.0E+00 3.2E+00 1000 100
8.28E+03 1.1E+00 1.0E+00 3.2E+00
1.30E+03 6.5E-01 1.0E+00 3.2E+00
1.18E+02 1.6E+00 1.0E+00 3.2E+00
2.31 E+03 8.5E-01 1.0E+00 3.2E+00
2.71 E+04 1.2E+00 1.0E+00 3.2E+00
1.29E+05 6.8E-01 1.0E+00 3.2E+00
5.00E-01 1.0E+01 1.0E+00 3.2E+00
5.00E-01 2.1E+01 1.0E+00 3.2E+00
5.00E-01 2.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
2.13E+04 94% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
2.07E+04 97% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
2.27E+04 91% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                                      1-4
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L01-1313-T01-A 1
Sb EaFA-L01-1313-T02-A 1
Sb EaFA-L01-1313-T03-A 1
Sb EaFA-L01-1313-T04-A 1
Sb EaFA-L01-1313-T05-A 1
Sb EaFA-L01-1313-T06-A 1
Sb EaFA-L01-1313-T07-A 1
Sb EaFA-L01-1313-T08-A 1
Sb EaFA-L01-1313-T09-A 1
Sb EaFA-L01-1313-T01-B 1
Sb EaFA-L01-1313-T02-B 1
Sb EaFA-L01-1313-T03-B 1
Sb EaFA-L01-1313-T04-B 1
Sb EaFA-L01-1313-T05-B 1
Sb EaFA-L01-1313-T06-B 1
Sb EaFA-L01-1313-T07-B 1
Sb EaFA-L01-1313-T08-B 1
Sb EaFA-L01-1313-T09-B 1
Sb EaFA-L01-1313-T01-C 1
Sb EaFA-L01-1313-T02-C 1
Sb EaFA-L01-1313-T03-C 1
Sb EaFA-L01-1313-T04-C 1
Sb EaFA-L01-1313-T05-C 1
Sb EaFA-L01-1313-T06-C 1
Sb EaFA-L01-1313-T07-C 1
Sb EaFA-L01-1313-T08-C 1
Sb EaFA-L01-1313-T09-C 1
Sb EaFA-L01-1313-B01-A 1
Sb EaFA-L01-1313-B02-A 1
Sb EaFA-L01-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
2.97E+02
1.93E+02
2.58E+02
1.93E+02
2.28E+02
2.33E+02
8.10E+01
3.44E+01
3.75E+00 U1/2
2.29E+02
1.31E+02
1.94E+02
2.01 E+02
2.02E+02
1.76E+02
6.91E+01
2.04E+01 E
3.75E+00 U1/2
2.73E+02
1.47E+02
2.09E+02
1.87E+02
2.04E+02
1.82E+02
6.74E+01
2.67E+01
3.75E+00 U1/2
8.66E+00 E
1.90E+01 E
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.97E+02 5.2E+00 7.5E+00 2.4E+01
1.93E+02 1.2E+01 7.5E+00 2.4E+01
2.58E+02 6.9E+00 7.5E+00 2.4E+01 10 325
1.93E+02 4.8E+00 7.5E+00 2.4E+01
2.28E+02 3.1E+00 7.5E+00 2.4E+01
2.33E+02 2.4E+01 7.5E+00 2.4E+01
8.10E+01 2.8E+01 7.5E+00 2.4E+01
3.44E+01 1.2E+01 7.5E+00 2.4E+01
3.75E+00 7.3E+02 7.5E+00 2.4E+01
2.29E+02 6.0E+00 7.5E+00 2.4E+01
1.31 E+02 8.0E+00 7.5E+00 2.4E+01
1.94E+02 8.9E+00 7.5E+00 2.4E+01 10 325
2.01 E+02 9.0E+00 7.5E+00 2.4E+01
2.02E+02 7.1E+00 7.5E+00 2.4E+01
1.76E+02 1.4E+01 7.5E+00 2.4E+01
6.91 E+01 1.3E+01 7.5E+00 2.4E+01
2.04E+01 2.3E+01 7.5E+00 2.4E+01
3.75E+00 3.9E+02 7.5E+00 2.4E+01
2.73E+02 1.3E+01 7.5E+00 2.4E+01
1.47E+02 1.9E+01 7.5E+00 2.4E+01
2.09E+02 7.2E+00 7.5E+00 2.4E+01 10 325
1.87E+02 6.1E+00 7.5E+00 2.4E+01
2.04E+02 1.3E+01 7.5E+00 2.4E+01
1.82E+02 6.0E+00 7.5E+00 2.4E+01
6.74E+01 3.5E+01 7.5E+00 2.4E+01
2.67E+01 8.5E+01 7.5E+00 2.4E+01
3.75E+00 3.4E+01 7.5E+00 2.4E+01
8.66E+00 9.1 E+02 7.5E+00 2.4E+01
1.90E+01 7.0E+00 7.5E+00 2.4E+01
3.75E+00 4.6E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.68E+03 105% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
3.55E+03 103% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
3.51E+03 101% VUICP-OES 6/9/10 1 1:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                             1-5
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone.
1 ug/L
As EaFA-L01-1313-T01-A 1 1.31E+04
As EaFA-L01-1313-T02-A 1 9.09E+02
As EaFA-L01-1313-T03-A 1 9.94E+02
As EaFA-L01-1313-T04-A 1 6.53E+02
As EaFA-L01-1313-T05-A 1 3.47E+02
As EaFA-L01-1313-T06-A 1 1.69E+02
As EaFA-L01-1313-T07-A 1 1.62E+02
As EaFA-L01-1313-T08-A 1 1.45E+02
As EaFA-L01-1313-T09-A 1 4.28E+03
As EaFA-L01-1313-T01-B 1 1.19E+04
As EaFA-L01-1313-T02-B 1 9.18E+02
As EaFA-L01-1313-T03-B 1 1.11E+03
As EaFA-L01-1313-T04-B 1 6.24E+02
As EaFA-L01-1313-T05-B 1 3.59E+02
As EaFA-L01-1313-T06-B 1 1.13E+02
As EaFA-L01-1313-T07-B 1 1.45E+02
As EaFA-L01-1313-T08-B 1 1.73E+02
As EaFA-L01-1313-T09-B 1 3.91E+03
As EaFA-L01-1313-T01-C 1 1.18E+04
As EaFA-L01-1313-T02-C 1 7.70E+02
As EaFA-L01-1313-T03-C 1 1 .24E+03
As EaFA-L01-1313-T04-C 1 6.18E+02
As EaFA-L01-1313-T05-C 1 3.35E+02
As EaFA-L01-1313-T06-C 1 1.04E+02
As EaFA-L01-1313-T07-C 1 1.30E+02
As EaFA-L01-1313-T08-C 1 1.36E+02
As EaFA-L01-1313-T09-C 1 4.18E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.31E+04 8.5E-01 1.1E+01 3.5E+01
9.09E+02 7.9E-01 1.1E+01 3.5E+01
9.94E+02 2.1E+00 1.1E+01 3.5E+01 10 325
6.53E+02 4.2E+00 1.1E+01 3.5E+01
3.47E+02 9.4E+00 1.1E+01 3.5E+01
1.69E+02 9.8E+00 1.1E+01 3.5E+01
1.62E+02 9.1E+00 1.1E+01 3.5E+01
1.45E+02 7.3E+00 1.1E+01 3.5E+01
4.28E+03 9.0E-01 1.1E+01 3.5E+01
1.19E+04 1.7E+00 1.1E+01 3.5E+01
9.18E+02 2.8E+00 1.1E+01 3.5E+01
1.11E+03 1.6E+00 1.1E+01 3.5E+01 10 325
6.24E+02 4.2E+00 1.1E+01 3.5E+01
3.59E+02 5.7E+00 1.1E+01 3.5E+01
1.13E+02 1.0E+01 1.1E+01 3.5E+01
1.45E+02 8.3E+00 1.1E+01 3.5E+01
1.73E+02 8.2E+00 1.1E+01 3.5E+01
3.91E+03 3.0E-01 1.1E+01 3.5E+01
1.18E+04 8.8E-01 1.1E+01 3.5E+01
7.70E+02 2.6E+00 1.1E+01 3.5E+01
1.24E+03 2.0E+00 1.1E+01 3.5E+01 10 325
6.18E+02 5.8E+00 1.1E+01 3.5E+01
3.35E+02 3.5E+00 1.1E+01 3.5E+01
1.04E+02 1.6E+01 1.1E+01 3.5E+01
1.30E+02 1.5E+01 1.1E+01 3.5E+01
1.36E+02 8.4E+00 1.1E+01 3.5E+01
4.18E+03 5.7E-01 1.1E+01 3.5E+01
As EaFA-L01-1313-B01-A 1 5.50E+00 U1/2 5.50E+00 8.6E+01 1.1E+01 3.5E+01
As EaFA-L01-1313-B02-A 1 5.50E+00 U1/2 5.50E+00 1.2E+03 1.1E+01 3.5E+01
As EaFA-L01-1313-B03-A 1 3.56E+01
3.56E+01 1.1E+02 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
4.40E+03 105% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
4.41E+03 102% VU ICP-OES 6/9/10 11 :19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
4.52E+03 101% VUICP-OES 6/9/10 1 1:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                             1-6
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qu
B EaFA-L01-1313-T01-A 1 4.95E+03
B EaFA-L01-1313-T02-A 1 4.50E+03
B EaFA-L01-1313-T03-A 1 4.29E+03
B EaFA-L01-1313-T04-A 1 4.55E+03
B EaFA-L01-1313-T05-A 1 4.30E+03
B EaFA-L01-1313-T06-A 1 4.73E+03
B EaFA-L01-1313-T07-A 1 4.33E+03
B EaFA-L01-1313-T08-A 1 3.77E+03
B EaFA-L01-1313-T09-A 1 2.77E+03
B EaFA-L01-1313-T01-B 1 4.66E+03
B EaFA-L01-1313-T02-B 1 4.33E+03
B EaFA-L01-1313-T03-B 1 4.29E+03
B EaFA-L01-1313-T04-B 1 4.22E+03
B EaFA-L01-1313-T05-B 1 4.34E+03
B EaFA-L01-1313-T06-B 1 4.52E+03
B EaFA-L01-1313-T07-B 1 3.92E+03
B EaFA-L01-1313-T08-B 1 3.81 E+03
B EaFA-L01-1313-T09-B 1 2.85E+03
B EaFA-L01-1313-T01-C 1 4.66E+03
B EaFA-L01-1313-T02-C 1 4.05E+03
B EaFA-L01-1313-T03-C 1 4.31 E+03
B EaFA-L01-1313-T04-C 1 4.38E+03
B EaFA-L01-1313-T05-C 1 4. 11 E+03
B EaFA-L01-1313-T06-C 1 4.37E+03
B EaFA-L01-1313-T07-C 1 3.87E+03
B EaFA-L01-1313-T08-C 1 3.58E+03
B EaFA-L01-1313-T09-C 1 2.75E+03
B EaFA-L01-1313-B01-A 1 8.97E+01
B EaFA-L01-1313-B02-A 1 9.08E+01
B EaFA-L01-1313-B03-A 1 2.93E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.95E+03 1.0E+00 1.0E+00 3.2E+00
4.50E+03 4.5E-01 1.0E+00 3.2E+00
4.29E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
4.55E+03 7.0E-01 1.0E+00 3.2E+00
4.30E+03 4.5E+00 1.0E+00 3.2E+00
4.73E+03 5.7E-01 1.0E+00 3.2E+00
4.33E+03 2.9E-01 1.0E+00 3.2E+00
3.77E+03 5.9E-01 1.0E+00 3.2E+00
2.77E+03 4.4E-01 1.0E+00 3.2E+00
4.66E+03 1.7E+00 1.0E+00 3.2E+00
4.33E+03 8.0E-02 1.0E+00 3.2E+00
4.29E+03 1.0E+00 1.0E+00 3.2E+00 1000 100
4.22E+03 1.5E+00 1.0E+00 3.2E+00
4.34E+03 9.1E-01 1.0E+00 3.2E+00
4.52E+03 1.2E+00 1.0E+00 3.2E+00
3.92E+03 7.2E-01 1.0E+00 3.2E+00
3.81 E+03 3.0E-01 1.0E+00 3.2E+00
2.85E+03 3.8E-01 1.0E+00 3.2E+00
4.66E+03 1.1E+00 1.0E+00 3.2E+00
4.05E+03 8.1E-01 1.0E+00 3.2E+00
4.31E+03 9.2E-01 1.0E+00 3.2E+00 1000 100
4.38E+03 2.4E-01 1.0E+00 3.2E+00
4.11E+03 5.7E-01 1.0E+00 3.2E+00
4.37E+03 1.4E+00 1.0E+00 3.2E+00
3.87E+03 1.1E+00 1.0E+00 3.2E+00
3.58E+03 1.6E+00 1.0E+00 3.2E+00
2.75E+03 4.9E-01 1.0E+00 3.2E+00
8.97E+01 2.9E+00 1.0E+00 3.2E+00
9.08E+01 7.4E-01 1.0E+00 3.2E+00
2.93E+01 4.9E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
5.18E+03 88% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
5.10E+03 81% VUICP-OES 6/9/10 11 :19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
5.16E+03 86% VUICP-OES 6/9/10 1 1:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                             1-7
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFA-L01-1313-T01-A 1
Ba EaFA-L01-1313-T02-A 1
Ba EaFA-L01-1313-T03-A 1
Ba EaFA-L01-1313-T04-A 1
Ba EaFA-L01-1313-T05-A 1
Ba EaFA-L01-1313-T06-A 1
Ba EaFA-L01-1313-T07-A 1
Ba EaFA-L01-1313-T08-A 1
Ba EaFA-L01-1313-T09-A 1
Ba EaFA-L01-1313-T01-B 1
Ba EaFA-L01-1313-T02-B 1
Ba EaFA-L01-1313-T03-B 1
Ba EaFA-L01-1313-T04-B 1
Ba EaFA-L01-1313-T05-B 1
Ba EaFA-L01-1313-T06-B 1
Ba EaFA-L01-1313-T07-B 1
Ba EaFA-L01-1313-T08-B 1
Ba EaFA-L01-1313-T09-B 1
Ba EaFA-L01-1313-T01-C 1
Ba EaFA-L01-1313-T02-C 1
Ba EaFA-L01-1313-T03-C 1
Ba EaFA-L01-1313-T04-C 1
Ba EaFA-L01-1313-T05-C 1
Ba EaFA-L01-1313-T06-C 1
Ba EaFA-L01-1313-T07-C 1
Ba EaFA-L01-1313-T08-C 1
Ba EaFA-L01-1313-T09-C 1
Ba EaFA-L01-1313-B01-A 1
Ba EaFA-L01-1313-B02-A 1
Ba EaFA-L01-1313-B03-A 1
Sample
Cone. Qualifier
1.35E+03
9.72E+02
7.87E+02
6.21 E+02
3.29E+02
2.42E+02
2.27E+02
2.72E+02
9.74E+02
1.52E+03
9.61 E+02
7.46E+02
5.98E+02
3.27E+02
2.47E+02
2.30E+02
2.67E+02
9.43E+02
1 .36E+03
8.60E+02
6.24E+02
5.95E+02
2.99E+02
2.42E+02
2.12E+02
2.49E+02
9.48E+02
5.00E-01 U1/2
1.01E+01
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.35E+03 7.1E-01 1. OE+00 3.2E+00
9.72E+02 8.0E-01 1. OE+00 3.2E+00
7.87E+02 9.9E-02 1. OE+00 3.2E+00 10 325
6.21 E+02 1.8E-01 1. OE+00 3.2E+00
3.29E+02 4.5E+00 1. OE+00 3.2E+00
2.42E+02 3.7E-01 1. OE+00 3.2E+00
2.27E+02 1.9E-01 1. OE+00 3.2E+00
2.72E+02 4.4E-01 1. OE+00 3.2E+00
9.74E+02 6.1E-01 1. OE+00 3.2E+00
1.52E+03 1.8E+00 1. OE+00 3.2E+00
9.61 E+02 9.7E-01 1. OE+00 3.2E+00
7.46E+02 5.9E-01 1. OE+00 3.2E+00 10 325
5.98E+02 1.6E-01 1. OE+00 3.2E+00
3.27E+02 4.4E-01 1. OE+00 3.2E+00
2.47E+02 1.4E-01 1. OE+00 3.2E+00
2.30E+02 4.7E-01 1. OE+00 3.2E+00
2.67E+02 1.6E-01 1 .OE+00 3.2E+00
9.43E+02 1.1E-01 1 .OE+00 3.2E+00
1.36E+03 1. OE+00 1 .OE+00 3.2E+00
8.60E+02 2.7E-01 1 .OE+00 3.2E+00
6.24E+02 5.3E-01 1 .OE+00 3.2E+00 10 325
5.95E+02 8.0E-01 1 .OE+00 3.2E+00
2.99E+02 3.2E-01 1 .OE+00 3.2E+00
2.42E+02 2.6E-01 1 .OE+00 3.2E+00
2.12E+02 1.1E+00 1.0E+00 3.2E+00
2.49E+02 1.4E+00 1 .OE+00 3.2E+00
9.48E+02 3.6E-01 1 .OE+00 3.2E+00
5.00E-01 3.4E+01 1 .OE+00 3.2E+00
1.01E+01 1.4E+01 1. OE+00 3.2E+00
5.00E-01 2.9E+00 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.91E+03 96% VUICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
3.68E+03 90% VUICP-OES 6/9/10 11 :19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
3.54E+03 90% VUICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L01-1313-T01-A 1
Be EaFA-L01-1313-T02-A 1
Be EaFA-L01-1313-T03-A 1
Be EaFA-L01-1313-T04-A 1
Be EaFA-L01-1313-T05-A 1
Be EaFA-L01-1313-T06-A 1
Be EaFA-L01-1313-T07-A 1
Be EaFA-L01-1313-T08-A 1
Be EaFA-L01-1313-T09-A 1
Be EaFA-L01-1313-T01-B 1
Be EaFA-L01-1313-T02-B 1
Be EaFA-L01-1313-T03-B 1
Be EaFA-L01-1313-T04-B 1
Be EaFA-L01-1313-T05-B 1
Be EaFA-L01-1313-T06-B 1
Be EaFA-L01-1313-T07-B 1
Be EaFA-L01-1313-T08-B 1
Be EaFA-L01-1313-T09-B 1
Be EaFA-L01-1313-T01-C 1
Be EaFA-L01-1313-T02-C 1
Be EaFA-L01-1313-T03-C 1
Be EaFA-L01-1313-T04-C 1
Be EaFA-L01-1313-T05-C 1
Be EaFA-L01-1313-T06-C 1
Be EaFA-L01-1313-T07-C 1
Be EaFA-L01-1313-T08-C 1
Be EaFA-L01-1313-T09-C 1
Be EaFA-L01-1313-B01-A 1
Be EaFA-L01-1313-B02-A 1
Be EaFA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
2.26E+01
1.24E+02
2.64E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
2.56E+01
1.26E+02
2.63E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
2.09E+01
1.15E+02
2.53E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 5.2E+02 1.9E+00 6.0E+00
9.50E-01 2.2E+02 1.9E+00 6.0E+00 10 325
9.50E-01 2.3E+01 1.9E+00 6.0E+00
9.50E-01 3.3E+02 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
2.26E+01 2.1E+00 1.9E+00 6.0E+00
1.24E+02 2.7E-01 1.9E+00 6.0E+00
2.64E+02 2.3E-01 1.9E+00 6.0E+00
9.50E-01 2.5E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 8.4E+01 1.9E+00 6.0E+00 10 325
9.50E-01 6.9E+01 1.9E+00 6.0E+00
9.50E-01 9.8E+01 1.9E+00 6.0E+00
9.50E-01 2.7E+02 1.9E+00 6.0E+00
2.56E+01 1.2E+00 1.9E+00 6.0E+00
1.26E+02 3.8E-01 1.9E+00 6.0E+00
2.63E+02 1.1E+00 1.9E+00 6.0E+00
9.50E-01 8.5E+00 1.9E+00 6.0E+00
9.50E-01 2.1E+03 1.9E+00 6.0E+00
9.50E-01 7.2E+01 1.9E+00 6.0E+00 10 325
9.50E-01 7.2E+01 1.9E+00 6.0E+00
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
2.09E+01 6.8E-01 1.9E+00 6.0E+00
1.15E+02 1.3E+00 1.9E+00 6.0E+00
2.53E+02 1.3E+00 1.9E+00 6.0E+00
9.50E-01 3.6E+01 1.9E+00 6.0E+00
9.50E-01 3.0E+02 1.9E+00 6.0E+00
9.50E-01 9.5E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.50E+03 108% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
3.40E+03 105% VUICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:26AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:29AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:36AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:37 AM EPA Interlab L01 1313-1316 EaFA
3.38E+03 104% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                             1-9
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-L01-1313-T01-A 1
Cd EaFA-L01-1313-T02-A 1
Cd EaFA-L01-1313-T03-A 1
Cd EaFA-L01-1313-T04-A 1
Cd EaFA-L01-1313-T05-A 1
Cd EaFA-L01-1313-T06-A 1
Cd EaFA-L01-1313-T07-A 1
Cd EaFA-L01-1313-T08-A 1
Cd EaFA-L01-1313-T09-A 1
Cd EaFA-L01-1313-T01-B 1
Cd EaFA-L01-1313-T02-B 1
Cd EaFA-L01-1313-T03-B 1
Cd EaFA-L01-1313-T04-B 1
Cd EaFA-L01-1313-T05-B 1
Cd EaFA-L01-1313-T06-B 1
Cd EaFA-L01-1313-T07-B 1
Cd EaFA-L01-1313-T08-B 1
Cd EaFA-L01-1313-T09-B 1
Cd EaFA-L01-1313-T01-C 1
Cd EaFA-L01-1313-T02-C 1
Cd EaFA-L01-1313-T03-C 1
Cd EaFA-L01-1313-T04-C 1
Cd EaFA-L01-1313-T05-C 1
Cd EaFA-L01-1313-T06-C 1
Cd EaFA-L01-1313-T07-C 1
Cd EaFA-L01-1313-T08-C 1
Cd EaFA-L01-1313-T09-C 1
Cd EaFA-L01-1313-B01-A 1
Cd EaFA-L01-1313-B02-A 1
Cd EaFA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.34E+01
2.84E+01
3.32E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.00E+01
2.84E+01
3.27E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
2.88E+01
2.56E+01
3.17E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.4E+01 2.2E+00 7.0E+00
1.10E+00 1.3E+01 2.2E+00 7.0E+00
1.10E+00 9.6E-01 2.2E+00 7.0E+00 10 325
1.10E+00 7.7E+00 2.2E+00 7.0E+00
1.10E+00 1.7E+01 2.2E+00 7.0E+00
1.10E+00 2.1E+01 2.2E+00 7.0E+00
3.34E+01 2.3E+00 2.2E+00 7.0E+00
2.84E+01 1.0E+00 2.2E+00 7.0E+00
3.32E+01 7.9E-01 2.2E+00 7.0E+00
1.10E+00 5.8E+00 2.2E+00 7.0E+00
1.10E+00 1.1E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+01 2.2E+00 7.0E+00 10 325
1.10E+00 2.2E+00 2.2E+00 7.0E+00
1.10E+00 9.5E+00 2.2E+00 7.0E+00
1.10E+00 4.4E+00 2.2E+00 7.0E+00
3.00E+01 7.9E-01 2.2E+00 7.0E+00
2.84E+01 2.3E+00 2.2E+00 7.0E+00
3.27E+01 1.3E+00 2.2E+00 7.0E+00
1.10E+00 6.1E+00 2.2E+00 7.0E+00
1.10E+00 2.8E+01 2.2E+00 7.0E+00
1.10E+00 1.3E+01 2.2E+00 7.0E+00 10 325
1.10E+00 8.3E+00 2.2E+00 7.0E+00
1.10E+00 1.1E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+01 2.2E+00 7.0E+00
2.88E+01 2.8E+00 2.2E+00 7.0E+00
2.56E+01 9.2E-01 2.2E+00 7.0E+00
3.17E+01 6.0E-01 2.2E+00 7.0E+00
1.10E+00 7.4E+00 2.2E+00 7.0E+00
1.10E+00 7.0E+00 2.2E+00 7.0E+00
1.10E+00 2.8E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.66E+03 113% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
3.54E+03 109% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
3.52E+03 108% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-10
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qu
1 1 ug/L
Ca EaFA-L01-1313-T01-A 1 1.43E+04
Ca EaFA-L01-1313-T02-A 1 5.15E+04
Ca EaFA-L01-1313-T03-A 1 1.07E+05
Ca EaFA-L01-1313-T04-A 1 1.36E+05
Ca EaFA-L01-1313-T05-A 1 1.45E+05
Ca EaFA-L01-1313-T06-A 1 1.72E+05
Ca EaFA-L01-1313-T07-A 1 1.61E+05
Ca EaFA-L01-1313-T08-A 1 1.51E+05
Ca EaFA-L01-1313-T09-A 1 1.34E+05
Ca EaFA-L01-1313-T01-B 1 1.31E+04
Ca EaFA-L01-1313-T02-B 1 5.32E+04
Ca EaFA-L01-1313-T03-B 1 1.07E+05
Ca EaFA-L01-1313-T04-B 1 1.29E+05
Ca EaFA-L01-1313-T05-B 1 1.44E+05
Ca EaFA-L01-1313-T06-B 1 1.60E+05
Ca EaFA-L01-1313-T07-B 1 1.41E+05
Ca EaFA-L01-1313-T08-B 1 1.47E+05
Ca EaFA-L01-1313-T09-B 1 1.34E+05
Ca EaFA-L01-1313-T01-C 1 1.28E+04
Ca EaFA-L01-1313-T02-C 1 5.30E+04
Ca EaFA-L01-1313-T03-C 1 1.04E+05
Ca EaFA-L01-1313-T04-C 1 1.34E+05
Ca EaFA-L01-1313-T05-C 1 1.36E+05
Ca EaFA-L01-1313-T06-C 1 1.60E+05
Ca EaFA-L01-1313-T07-C 1 1.39E+05
Ca EaFA-L01-1313-T08-C 1 1.36E+05
Ca EaFA-L01-1313-T09-C 1 1.30E+05
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.43E+04 1.1E+00 2.6E+00 8.3E+00
5.15E+04 1.1E+00 2.6E+00 8.3E+00
1.07E+05 7.7E-01 2.6E+00 8.3E+00 1000 100
1.36E+05 5.5E-01 2.6E+00 8.3E+00
1.45E+05 5.2E+00 2.6E+00 8.3E+00
1.72E+05 6.1E-01 2.6E+00 8.3E+00
1.61E+05 5.0E-01 2.6E+00 8.3E+00
1.51E+05 2.9E-01 2.6E+00 8.3E+00
1.34E+05 5.4E-01 2.6E+00 8.3E+00
1.31E+04 1.6E+00 2.6E+00 8.3E+00
5.32E+04 1.3E+00 2.6E+00 8.3E+00
1.07E+05 5.5E-01 2.6E+00 8.3E+00 1000 100
1.29E+05 3.2E-01 2.6E+00 8.3E+00
1.44E+05 3.1E-01 2.6E+00 8.3E+00
1.60E+05 4.9E-02 2.6E+00 8.3E+00
1.41E+05 5.4E-01 2.6E+00 8.3E+00
1.47E+05 4.6E-01 2.6E+00 8.3E+00
1.34E+05 4.6E-01 2.6E+00 8.3E+00
1.28E+04 1.2E+00 2.6E+00 8.3E+00
5.30E+04 2.7E-01 2.6E+00 8.3E+00
1.04E+05 9.7E-01 2.6E+00 8.3E+00 1000 100
1.34E+05 1.2E+00 2.6E+00 8.3E+00
1.36E+05 4.2E-01 2.6E+00 8.3E+00
1.60E+05 1.4E-01 2.6E+00 8.3E+00
1.39E+05 6.0E-01 2.6E+00 8.3E+00
1.36E+05 1.4E+00 2.6E+00 8.3E+00
1.30E+05 2.7E-01 2.6E+00 8.3E+00
Ca EaFA-L01-1313-B01-A 1 1.30E+OOU1/2 1.30E+00 2.9E+02 2.6E+00 8.3E+00
Ca EaFA-L01-1313-B02-A 1 1.30E+OOU1/2 1.30E+00 8.8E+01 2.6E+00 8.3E+00
Ca EaFA-L01-1313-B03-A 1 1.30E+OOU1/2 1.30E+00 1.2E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
1.08E+05 82% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
1.08E+05 81% VUICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
1.05E+05 83% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-11
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr EaFA-L01-1313-T01-A 1
Cr EaFA-L01-1313-T02-A 1
Cr EaFA-L01-1313-T03-A 1
Cr EaFA-L01-1313-T04-A 1
Cr EaFA-L01-1313-T05-A 1
Cr EaFA-L01-1313-T06-A 1
Cr EaFA-L01-1313-T07-A 1
Cr EaFA-L01-1313-T08-A 1
Cr EaFA-L01-1313-T09-A 1
Cr EaFA-L01-1313-T01-B 1
Cr EaFA-L01-1313-T02-B 1
Cr EaFA-L01-1313-T03-B 1
Cr EaFA-L01-1313-T04-B 1
Cr EaFA-L01-1313-T05-B 1
Cr EaFA-L01-1313-T06-B 1
Cr EaFA-L01-1313-T07-B 1
Cr EaFA-L01-1313-T08-B 1
Cr EaFA-L01-1313-T09-B 1
Cr EaFA-L01-1313-T01-C 1
Cr EaFA-L01-1313-T02-C 1
Cr EaFA-L01-1313-T03-C 1
Cr EaFA-L01-1313-T04-C 1
Cr EaFA-L01-1313-T05-C 1
Cr EaFA-L01-1313-T06-C 1
Cr EaFA-L01-1313-T07-C 1
Cr EaFA-L01-1313-T08-C 1
Cr EaFA-L01-1313-T09-C 1
Cr EaFA-L01-1313-B01-A 1
Cr EaFA-L01-1313-B02-A 1
Cr EaFA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
7.45E+02
4.08E+02
3.23E+02
1.62E+02
1.06E+02
1.41E+01
1.66E+00 E
1.69E+02
1.81E+03
5.26E+02
3.01 E+02
2.07E+02
1.56E+02
1.07E+02
1.84E+01
3.37E+00 E
1.84E+02
1.81E+03
5.16E+02
2.58E+02
2.27E+02
1.54E+02
1.05E+02
1.44E+01
2.73E+00 E
1.54E+02
1.75E+03
6.00E-01 U1/2
6.00E-01 U1/2
1.38E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.45E+02 1.4E+00 1.2E+00 3.8E+00
4.08E+02 1.3E+00 1.2E+00 3.8E+00
3.23E+02 8.6E-01 1.2E+00 3.8E+00 10 325
1.62E+02 9.5E-01 1.2E+00 3.8E+00
1.06E+02 6.9E+00 1.2E+00 3.8E+00
1.41E+01 1.1E+01 1.2E+00 3.8E+00
1.66E+00 3.6E+01 1.2E+00 3.8E+00
1.69E+02 2.4E-01 1.2E+00 3.8E+00
1.81E+03 4.2E-02 1.2E+00 3.8E+00
5.26E+02 1.2E+00 1.2E+00 3.8E+00
3.01 E+02 1.3E+00 1.2E+00 3.8E+00
2.07E+02 4.4E-01 1.2E+00 3.8E+00 10 325
1.56E+02 1.0E+00 1.2E+00 3.8E+00
1.07E+02 7.5E-01 1.2E+00 3.8E+00
1.84E+01 9.7E+00 1.2E+00 3.8E+00
3.37E+00 1.7E+01 1.2E+00 3.8E+00
1.84E+02 1.5E-01 1.2E+00 3.8E+00
1.81E+03 1.4E-01 1.2E+00 3.8E+00
5.16E+02 8.6E-01 1.2E+00 3.8E+00
2.58E+02 5.3E-01 1.2E+00 3.8E+00
2.27E+02 5.2E-01 1.2E+00 3.8E+00 10 325
1.54E+02 1.2E+00 1.2E+00 3.8E+00
1.05E+02 1.1E+00 1.2E+00 3.8E+00
1.44E+01 3.0E+00 1.2E+00 3.8E+00
2.73E+00 5.3E+01 1.2E+00 3.8E+00
1.54E+02 1.3E+00 1.2E+00 3.8E+00
1.75E+03 8.8E-02 1.2E+00 3.8E+00
6.00E-01 4.4E+02 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
1.38E+00 3.0E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.70E+03 104% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
3.44E+03 99% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
3.46E+03 100% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-12
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-L01-1313-T01-A 1
Co EaFA-L01-1313-T02-A 1
Co EaFA-L01-1313-T03-A 1
Co EaFA-L01-1313-T04-A 1
Co EaFA-L01-1313-T05-A 1
Co EaFA-L01-1313-T06-A 1
Co EaFA-L01-1313-T07-A 1
Co EaFA-L01-1313-T08-A 1
Co EaFA-L01-1313-T09-A 1
Co EaFA-L01-1313-T01-B 1
Co EaFA-L01-1313-T02-B 1
Co EaFA-L01-1313-T03-B 1
Co EaFA-L01-1313-T04-B 1
Co EaFA-L01-1313-T05-B 1
Co EaFA-L01-1313-T06-B 1
Co EaFA-L01-1313-T07-B 1
Co EaFA-L01-1313-T08-B 1
Co EaFA-L01-1313-T09-B 1
Co EaFA-L01-1313-T01-C 1
Co EaFA-L01-1313-T02-C 1
Co EaFA-L01-1313-T03-C 1
Co EaFA-L01-1313-T04-C 1
Co EaFA-L01-1313-T05-C 1
Co EaFA-L01-1313-T06-C 1
Co EaFA-L01-1313-T07-C 1
Co EaFA-L01-1313-T08-C 1
Co EaFA-L01-1313-T09-C 1
Co EaFA-L01-1313-B01-A 1
Co EaFA-L01-1313-B02-A 1
Co EaFA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.44E+00 E
6.61E+01
2.36E+02
2.15E+02
4.66E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
3.36E+00 E
5.34E+01
2.17E+02
2.17E+02
4.62E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
4.64E+00 E
5.96E+01
2.11E+02
1.99E+02
4.53E+02
2.23E+00 E
4.66E+00 E
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.9E+01 1.8E+00 5.7E+00
9.00E-01 3.4E+01 1.8E+00 5.7E+00
9.00E-01 3.8E+02 1.8E+00 5.7E+00 10 325
9.00E-01 5.5E+01 1.8E+00 5.7E+00
2.44E+00 2.2E+01 1.8E+00 5.7E+00
6.61E+01 2.7E+00 1.8E+00 5.7E+00
2.36E+02 1.5E+00 1.8E+00 5.7E+00
2.15E+02 1.4E+00 1.8E+00 5.7E+00
4.66E+02 8.0E-01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00 10 325
9.00E-01 1.4E+01 1.8E+00 5.7E+00
3.36E+00 3.3E+01 1.8E+00 5.7E+00
5.34E+01 3.6E+00 1.8E+00 5.7E+00
2.17E+02 1.2E+00 1.8E+00 5.7E+00
2.17E+02 9.1E-01 1.8E+00 5.7E+00
4.62E+02 3.4E-01 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 2.2E+01 1.8E+00 5.7E+00 10 325
9.00E-01 9.3E+01 1.8E+00 5.7E+00
4.64E+00 5.9E+01 1.8E+00 5.7E+00
5.96E+01 3.0E+00 1.8E+00 5.7E+00
2.11E+02 1.4E+00 1.8E+00 5.7E+00
1.99E+02 2.7E+00 1.8E+00 5.7E+00
4.53E+02 4.4E-01 1.8E+00 5.7E+00
2.23E+00 3.6E+03 1.8E+00 5.7E+00
4.66E+00 1.1E+02 1.8E+00 5.7E+00
9.00E-01 9.6E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.53E+03 109% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
3.41E+03 105% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
3.42E+03 105% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-13
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFA-L01-1313-T01-A 1
Cu EaFA-L01-1313-T02-A 1
Cu EaFA-L01-1313-T03-A 1
Cu EaFA-L01-1313-T04-A 1
Cu EaFA-L01-1313-T05-A 1
Cu EaFA-L01-1313-T06-A 1
Cu EaFA-L01-1313-T07-A 1
Cu EaFA-L01-1313-T08-A 1
Cu EaFA-L01-1313-T09-A 1
Cu EaFA-L01-1313-T01-B 1
Cu EaFA-L01-1313-T02-B 1
Cu EaFA-L01-1313-T03-B 1
Cu EaFA-L01-1313-T04-B 1
Cu EaFA-L01-1313-T05-B 1
Cu EaFA-L01-1313-T06-B 1
Cu EaFA-L01-1313-T07-B 1
Cu EaFA-L01-1313-T08-B 1
Cu EaFA-L01-1313-T09-B 1
Cu EaFA-L01-1313-T01-C 1
Cu EaFA-L01-1313-T02-C 1
Cu EaFA-L01-1313-T03-C 1
Cu EaFA-L01-1313-T04-C 1
Cu EaFA-L01-1313-T05-C 1
Cu EaFA-L01-1313-T06-C 1
Cu EaFA-L01-1313-T07-C 1
Cu EaFA-L01-1313-T08-C 1
Cu EaFA-L01-1313-T09-C 1
Cu EaFA-L01-1313-B01-A 1
Cu EaFA-L01-1313-B02-A 1
Cu EaFA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
7.64E+01
5.03E+00 E
7.26E+00 E
1.06E+01 E
9.16E+00 E
1.28E+01
6.21 E+02
1.88E+03
2.93E+03
6.49E+01
5.03E+00 E
1.85E+00 U1/2
1.46E+01
9.09E+00 E
1.09E+01 E
6.77E+02
1.93E+03
2.98E+03
5.85E+01
5.32E+00 E
7.70E+00 E
1.15E+01 E
1.15E+01 E
6.16E+00 E
5.73E+02
1.74E+03
2.87E+03
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.64E+01 4.6E+00 3.7E+00 1.2E+01
5.03E+00 5.7E+01 3.7E+00 1.2E+01
7.26E+00 1.9E+01 3.7E+00 1.2E+01 10 325
1.06E+01 5.3E+01 3.7E+00 1.2E+01
9.16E+00 6.9E+01 3.7E+00 1.2E+01
1.28E+01 9.3E+00 3.7E+00 1.2E+01
6.21 E+02 2.4E-01 3.7E+00 1.2E+01
1.88E+03 1.3E+00 3.7E+00 1.2E+01
2.93E+03 4.9E-01 3.7E+00 1.2E+01
6.49E+01 5.4E+00 3.7E+00 1.2E+01
5.03E+00 2.6E+01 3.7E+00 1.2E+01
1.85E+00 1.6E+02 3.7E+00 1.2E+01 10 325
1.46E+01 5.9E+01 3.7E+00 1.2E+01
9.09E+00 3.4E+01 3.7E+00 1.2E+01
1.09E+01 2.4E+01 3.7E+00 1.2E+01
6.77E+02 8.8E-01 3.7E+00 1.2E+01
1.93E+03 1.3E+00 3.7E+00 1.2E+01
2.98E+03 4.4E-01 3.7E+00 1.2E+01
5.85E+01 6.2E+00 3.7E+00 1.2E+01
5.32E+00 5.7E+01 3.7E+00 1.2E+01
7.70E+00 5.3E+00 3.7E+00 1.2E+01 10 325
1.15E+01 5.1E+01 3.7E+00 1.2E+01
1.15E+01 2.1E+01 3.7E+00 1.2E+01
6.16E+00 3.8E+01 3.7E+00 1.2E+01
5.73E+02 3.4E-01 3.7E+00 1.2E+01
1.74E+03 2.0E+00 3.7E+00 1.2E+01
2.87E+03 5.9E-01 3.7E+00 1.2E+01
1.85E+00 7.5E+01 3.7E+00 1.2E+01
1.85E+00 1.9E+02 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.35E+03 103% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
3.19E+03 98% VUICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
3.21E+03 99% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-14
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L01-1313-T01-A 1
Fe EaFA-L01-1313-T02-A 1
Fe EaFA-L01-1313-T03-A 1
Fe EaFA-L01-1313-T04-A 1
Fe EaFA-L01-1313-T05-A 1
Fe EaFA-L01-1313-T06-A 1
Fe EaFA-L01-1313-T07-A 1
Fe EaFA-L01-1313-T08-A 1
Fe EaFA-L01-1313-T09-A 1
Fe EaFA-L01-1313-T01-B 1
Fe EaFA-L01-1313-T02-B 1
Fe EaFA-L01-1313-T03-B 1
Fe EaFA-L01-1313-T04-B 1
Fe EaFA-L01-1313-T05-B 1
Fe EaFA-L01-1313-T06-B 1
Fe EaFA-L01-1313-T07-B 1
Fe EaFA-L01-1313-T08-B 1
Fe EaFA-L01-1313-T09-B 1
Fe EaFA-L01-1313-T01-C 1
Fe EaFA-L01-1313-T02-C 1
Fe EaFA-L01-1313-T03-C 1
Fe EaFA-L01-1313-T04-C 1
Fe EaFA-L01-1313-T05-C 1
Fe EaFA-L01-1313-T06-C 1
Fe EaFA-L01-1313-T07-C 1
Fe EaFA-L01-1313-T08-C 1
Fe EaFA-L01-1313-T09-C 1
Fe EaFA-L01-1313-B01-A 1
Fe EaFA-L01-1313-B02-A 1
Fe EaFA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.99E+01
1.41E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
8.71 E+00
3.85E+02
4.15E+04
3.25E+01
6.19E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.10E+01
4.33E+02
4.08E+04
4.13E+01
1.95E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.87E+00 E
3.54E+02
4.08E+04
1.00E+00 U1/2
2.79E+01
1.07E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.99E+01 2.9E+00 2.0E+00 6.4E+00
1.41E+01 2.3E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 6.6E+00 2.0E+00 6.4E+00
8.71 E+00 4.7E+00 2.0E+00 6.4E+00
3.85E+02 3.1E-01 2.0E+00 6.4E+00
4.15E+04 2.3E-01 2.0E+00 6.4E+00
3.25E+01 2.9E+00 2.0E+00 6.4E+00
6.19E+01 2.1E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.10E+01 2.9E-01 2.0E+00 6.4E+00
4.33E+02 6.9E-01 2.0E+00 6.4E+00
4.08E+04 3.9E-01 2.0E+00 6.4E+00
4.13E+01 3.3E+00 2.0E+00 6.4E+00
1.95E+01 2.4E+00 2.0E+00 6.4E+00
1.00E+00 3.1E+02 2.0E+00 6.4E+00 1000 100
1.00E+00 2.2E+00 2.0E+00 6.4E+00
1.00E+00 8.6E-01 2.0E+00 6.4E+00
1.00E+00 9.4E+00 2.0E+00 6.4E+00
4.87E+00 7.0E+00 2.0E+00 6.4E+00
3.54E+02 8.7E-01 2.0E+00 6.4E+00
4.08E+04 2.1E-02 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
2.79E+01 2.2E+01 2.0E+00 6.4E+00
1.07E+01 1.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
1.09E+03 109% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
1.06E+03 106% VUICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:26AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:29AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:36AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:37 AM EPA Interlab L01 1313-1316 EaFA
1.06E+03 106% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-15
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L01-1313-T01-A 1
Pb EaFA-L01-1313-T02-A 1
Pb EaFA-L01-1313-T03-A 1
Pb EaFA-L01-1313-T04-A 1
Pb EaFA-L01-1313-T05-A 1
Pb EaFA-L01-1313-T06-A 1
Pb EaFA-L01-1313-T07-A 1
Pb EaFA-L01-1313-T08-A 1
Pb EaFA-L01-1313-T09-A 1
Pb EaFA-L01-1313-T01-B 1
Pb EaFA-L01-1313-T02-B 1
Pb EaFA-L01-1313-T03-B 1
Pb EaFA-L01-1313-T04-B 1
Pb EaFA-L01-1313-T05-B 1
Pb EaFA-L01-1313-T06-B 1
Pb EaFA-L01-1313-T07-B 1
Pb EaFA-L01-1313-T08-B 1
Pb EaFA-L01-1313-T09-B 1
Pb EaFA-L01-1313-T01-C 1
Pb EaFA-L01-1313-T02-C 1
Pb EaFA-L01-1313-T03-C 1
Pb EaFA-L01-1313-T04-C 1
Pb EaFA-L01-1313-T05-C 1
Pb EaFA-L01-1313-T06-C 1
Pb EaFA-L01-1313-T07-C 1
Pb EaFA-L01-1313-T08-C 1
Pb EaFA-L01-1313-T09-C 1
Pb EaFA-L01-1313-B01-A 1
Pb EaFA-L01-1313-B02-A 1
Pb EaFA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.03E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.34E+02
1.80E+01 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.26E+02
9.58E+00 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.29E+02
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.03E+01 3.8E+01 6.8E+00 2.2E+01
3.40E+00 3.6E+01 6.8E+00 2.2E+01
3.40E+00 5.8E+01 6.8E+00 2.2E+01 10 325
3.40E+00 1.6E+02 6.8E+00 2.2E+01
3.40E+00 1.1E+03 6.8E+00 2.2E+01
3.40E+00 8.8E+01 6.8E+00 2.2E+01
3.40E+00 2.1E+02 6.8E+00 2.2E+01
3.40E+00 4.9E+00 6.8E+00 2.2E+01
1.34E+02 1.4E+00 6.8E+00 2.2E+01
1.80E+01 1.4E+02 6.8E+00 2.2E+01
3.40E+00 1.6E+03 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01 10 325
3.40E+00 7.4E+01 6.8E+00 2.2E+01
3.40E+00 1.2E+02 6.8E+00 2.2E+01
3.40E+00 1.6E+02 6.8E+00 2.2E+01
3.40E+00 9.1E+01 6.8E+00 2.2E+01
3.40E+00 7.6E+04 6.8E+00 2.2E+01
1.26E+02 7.5E+00 6.8E+00 2.2E+01
9.58E+00 4.7E+01 6.8E+00 2.2E+01
3.40E+00 9.6E+01 6.8E+00 2.2E+01
3.40E+00 9.2E+01 6.8E+00 2.2E+01 10 325
3.40E+00 6.1E+01 6.8E+00 2.2E+01
3.40E+00 1.6E+02 6.8E+00 2.2E+01
3.40E+00 1.7E+03 6.8E+00 2.2E+01
3.40E+00 2.5E+02 6.8E+00 2.2E+01
3.40E+00 6.7E+01 6.8E+00 2.2E+01
1.29E+02 6.0E+00 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 6.2E+01 6.8E+00 2.2E+01
3.40E+00 2.0E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.35E+03 103% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
3.26E+03 100% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:26AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:29AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:36AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:37 AM EPA Interlab L01 1313-1316 EaFA
3.24E+03 99% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-16
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
Li EaFA-L01-1313-T01-A 1 2.97E+03
Li EaFA-L01-1313-T02-A 1 4.03E+03
Li EaFA-L01-1313-T03-A 1 4.65E+03
Li EaFA-L01-1313-T04-A 1 4.98E+03
Li EaFA-L01-1313-T05-A 1 5.11E+03
Li EaFA-L01-1313-T06-A 1 5.72E+03
Li EaFA-L01-1313-T07-A 1 4.79E+03
Li EaFA-L01-1313-T08-A 1 3.69E+03
Li EaFA-L01-1313-T09-A 1 2.27E+03
Li EaFA-L01-1313-T01-B 1 2.97E+03
Li EaFA-L01-1313-T02-B 1 3.94E+03
Li EaFA-L01-1313-T03-B 1 4.48E+03
Li EaFA-L01-1313-T04-B 1 4.77E+03
Li EaFA-L01-1313-T05-B 1 5.07E+03
Li EaFA-L01-1313-T06-B 1 5.38E+03
Li EaFA-L01-1313-T07-B 1 4.29E+03
Li EaFA-L01-1313-T08-B 1 3.59E+03
Li EaFA-L01-1313-T09-B 1 2.27E+03
Li EaFA-L01-1313-T01-C 1 2.96E+03
Li EaFA-L01-1313-T02-C 1 3.68E+03
Li EaFA-L01-1313-T03-C 1 4.54E+03
Li EaFA-L01-1313-T04-C 1 4.90E+03
Li EaFA-L01-1313-T05-C 1 4.83E+03
Li EaFA-L01-1313-T06-C 1 5.41 E+03
Li EaFA-L01-1313-T07-C 1 4.22E+03
Li EaFA-L01-1313-T08-C 1 3.35E+03
Li EaFA-L01-1313-T09-C 1 2.19E+03
Li EaFA-L01-1313-B01-A 1 8.26E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.97E+03 8.5E-01 1.9E+00 6.0E+00
4.03E+03 1.0E+00 1.9E+00 6.0E+00
4.65E+03 2.7E-01 1.9E+00 6.0E+00 10 325
4.98E+03 6.1E-01 1.9E+00 6.0E+00
5.11 E+03 3.8E+00 1.9E+00 6.0E+00
5.72E+03 8.4E-01 1.9E+00 6.0E+00
4.79E+03 2.5E-01 1.9E+00 6.0E+00
3.69E+03 4.7E-01 1.9E+00 6.0E+00
2.27E+03 2.3E-01 1.9E+00 6.0E+00
2.97E+03 2.0E+00 1.9E+00 6.0E+00
3.94E+03 1.1E+00 1.9E+00 6.0E+00
4.48E+03 3.1E-01 1.9E+00 6.0E+00 10 325
4.77E+03 3.9E-01 1.9E+00 6.0E+00
5.07E+03 2.7E-01 1.9E+00 6.0E+00
5.38E+03 2.4E-01 1.9E+00 6.0E+00
4.29E+03 2.4E-01 1.9E+00 6.0E+00
3.59E+03 2.4E-01 1.9E+00 6.0E+00
2.27E+03 5.9E-01 1.9E+00 6.0E+00
2.96E+03 9.1E-01 1.9E+00 6.0E+00
3.68E+03 4.9E-01 1.9E+00 6.0E+00
4.54E+03 4.5E-01 1.9E+00 6.0E+00 10 325
4.90E+03 6.9E-01 1.9E+00 6.0E+00
4.83E+03 2.8E-01 1.9E+00 6.0E+00
5.41 E+03 5.1E-01 1.9E+00 6.0E+00
4.22E+03 6.8E-01 1.9E+00 6.0E+00
3.35E+03 1.5E+00 1.9E+00 6.0E+00
2.19E+03 7.3E-01 1.9E+00 6.0E+00
8.26E+00 9.8E+00 1.9E+00 6.0E+00
Li EaFA-L01-1313-B02-A 1 5.37E+00 E 5.37E+00 4.9E+00 1.9E+00 6.0E+00
Li EaFA-L01-1313-B03-A 1 9.50E-01 U1/2 9.50E-01 2.1E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
8.10E+03 106% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
8.00E+03 108% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
8.40E+03 119% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-17
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFA-L01-1313-T01-A 1
Mn EaFA-L01-1313-T02-A 1
Mn EaFA-L01-1313-T03-A 1
Mn EaFA-L01-1313-T04-A 1
Mn EaFA-L01-1313-T05-A 1
Mn EaFA-L01-1313-T06-A 1
Mn EaFA-L01-1313-T07-A 1
Mn EaFA-L01-1313-T08-A 1
Mn EaFA-L01-1313-T09-A 1
Mn EaFA-L01-1313-T01-B 1
Mn EaFA-L01-1313-T02-B 1
Mn EaFA-L01-1313-T03-B 1
Mn EaFA-L01-1313-T04-B 1
Mn EaFA-L01-1313-T05-B 1
Mn EaFA-L01-1313-T06-B 1
Mn EaFA-L01-1313-T07-B 1
Mn EaFA-L01-1313-T08-B 1
Mn EaFA-L01-1313-T09-B 1
Mn EaFA-L01-1313-T01-C 1
Mn EaFA-L01-1313-T02-C 1
Mn EaFA-L01-1313-T03-C 1
Mn EaFA-L01-1313-T04-C 1
Mn EaFA-L01-1313-T05-C 1
Mn EaFA-L01-1313-T06-C 1
Mn EaFA-L01-1313-T07-C 1
Mn EaFA-L01-1313-T08-C 1
Mn EaFA-L01-1313-T09-C 1
Mn EaFA-L01-1313-B01-A 1
Mn EaFA-L01-1313-B02-A 1
Mn EaFA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.88E+01
4.58E+02
9.34E+02
1.17E+03
1.71E+03
1.00E+00 U1/2
2.20E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
2.88E+01
3.63E+02
8.43E+02
1.16E+03
1.72E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.57E+01
3.96E+02
8.39E+02
1 .08E+03
1 .66E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 7.6E+01 2.0E+00 6.4E+00 10 325
1.00E+00 5.4E+00 2.0E+00 6.4E+00
2.88E+01 4.7E+00 2.0E+00 6.4E+00
4.58E+02 4.0E-01 2.0E+00 6.4E+00
9.34E+02 5.9E-01 2.0E+00 6.4E+00
1.17E+03 5.9E-01 2.0E+00 6.4E+00
1.71E+03 2.6E-01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
2.20E+00 9.0E-01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.1E+01 2.0E+00 6.4E+00
2.88E+01 1.6E-01 2.0E+00 6.4E+00
3.63E+02 8.2E-01 2.0E+00 6.4E+00
8.43E+02 1.5E+00 2.0E+00 6.4E+00
1.16E+03 3.7E-01 2.0E+00 6.4E+00
1.72E+03 2.8E-01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 2.3E+02 2.0E+00 6.4E+00 10 325
1.00E+00 3.1E+00 2.0E+00 6.4E+00
2.57E+01 5.6E-01 2.0E+00 6.4E+00
3.96E+02 8.1E-01 2.0E+00 6.4E+00
8.39E+02 1.3E+00 2.0E+00 6.4E+00
1.08E+03 2.1E+00 2.0E+00 6.4E+00
1.66E+03 1.8E-01 2.0E+00 6.4E+00
1.00E+00 5.4E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.39E+03 104% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
3.29E+03 101% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:21 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
3.28E+03 101% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-18
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFA-L01-1313-T01-A 1
Mg EaFA-L01-1313-T02-A 1
Mg EaFA-L01-1313-T03-A 1
Mg EaFA-L01-1313-T04-A 1
Mg EaFA-L01-1313-T05-A 1
Mg EaFA-L01-1313-T06-A 1
Mg EaFA-L01-1313-T07-A 1
Mg EaFA-L01-1313-T08-A 1
Mg EaFA-L01-1313-T09-A 1
Mg EaFA-L01-1313-T01-B 1
Mg EaFA-L01-1313-T02-B 1
Mg EaFA-L01-1313-T03-B 1
Mg EaFA-L01-1313-T04-B 1
Mg EaFA-L01-1313-T05-B 1
Mg EaFA-L01-1313-T06-B 1
Mg EaFA-L01-1313-T07-B 1
Mg EaFA-L01-1313-T08-B 1
Mg EaFA-L01-1313-T09-B 1
Mg EaFA-L01-1313-T01-C 1
Mg EaFA-L01-1313-T02-C 1
Mg EaFA-L01-1313-T03-C 1
Mg EaFA-L01-1313-T04-C 1
Mg EaFA-L01-1313-T05-C 1
Mg EaFA-L01-1313-T06-C 1
Mg EaFA-L01-1313-T07-C 1
Mg EaFA-L01-1313-T08-C 1
Mg EaFA-L01-1313-T09-C 1
Mg EaFA-L01-1313-B01-A 1
Mg EaFA-L01-1313-B02-A 1
Mg EaFA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
4.55E+02
3.31 E+03
4.65E+03
7.99E+03
8.21 E+03
7.83E+03
1.43E+04
5.00E-01 U1/2
5.00E-01 U1/2
4.72E+02
3.22E+03
4.66E+03
7.38E+03
7.14E+03
7.78E+03
1.44E+04
5.00E-01 U1/2
5.00E-01 U1/2
3.63E+02
3.47E+03
4.54E+03
7.26E+03
7.01 E+03
7.25E+03
1.40E+04
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 2.5E+02 1.0E+00 3.2E+00
5.00E-01 2.0E+01 1.0E+00 3.2E+00
4.55E+02 1.2E+00 1.0E+00 3.2E+00 1000 100
3.31 E+03 7.6E-01 1.0E+00 3.2E+00
4.65E+03 4.4E+00 1.0E+00 3.2E+00
7.99E+03 7.6E-01 1.0E+00 3.2E+00
8.21 E+03 4.3E-01 1.0E+00 3.2E+00
7.83E+03 8.2E-01 1.0E+00 3.2E+00
1.43E+04 3.4E-01 1.0E+00 3.2E+00
5.00E-01 8.0E+01 1.0E+00 3.2E+00
5.00E-01 1.6E+01 1.0E+00 3.2E+00
4.72E+02 3.0E+00 1.0E+00 3.2E+00 1000 100
3.22E+03 8.6E-01 1.0E+00 3.2E+00
4.66E+03 8.1E-01 1.0E+00 3.2E+00
7.38E+03 4.8E-01 1.0E+00 3.2E+00
7.14E+03 3.8E-01 1.0E+00 3.2E+00
7.78E+03 1.1E+00 1.0E+00 3.2E+00
1.44E+04 9.5E-01 1.0E+00 3.2E+00
5.00E-01 5.3E+02 1.0E+00 3.2E+00
5.00E-01 8.1E+00 1.0E+00 3.2E+00
3.63E+02 8.3E-01 1.0E+00 3.2E+00 1000 100
3.47E+03 1.4E+00 1.0E+00 3.2E+00
4.54E+03 3.7E-01 1.0E+00 3.2E+00
7.26E+03 9.7E-01 1.0E+00 3.2E+00
7.01 E+03 1.0E+00 1.0E+00 3.2E+00
7.25E+03 2.1E+00 1.0E+00 3.2E+00
1.40E+04 3.6E-01 1.0E+00 3.2E+00
5.00E-01 5.5E+02 1.0E+00 3.2E+00
5.00E-01 3.0E+02 1.0E+00 3.2E+00
5.00E-01 7.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
1.47E+03 102% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
1.59E+03 112% VUICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
1.34E+03 98% VUICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-19
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo EaFA-L01-1313-T01-A 1
Mo EaFA-L01-1313-T02-A 1
Mo EaFA-L01-1313-T03-A 1
Mo EaFA-L01-1313-T04-A 1
Mo EaFA-L01-1313-T05-A 1
Mo EaFA-L01-1313-T06-A 1
Mo EaFA-L01-1313-T07-A 1
Mo EaFA-L01-1313-T08-A 1
Mo EaFA-L01-1313-T09-A 1
Mo EaFA-L01-1313-T01-B 1
Mo EaFA-L01-1313-T02-B 1
Mo EaFA-L01-1313-T03-B 1
Mo EaFA-L01-1313-T04-B 1
Mo EaFA-L01-1313-T05-B 1
Mo EaFA-L01-1313-T06-B 1
Mo EaFA-L01-1313-T07-B 1
Mo EaFA-L01-1313-T08-B 1
Mo EaFA-L01-1313-T09-B 1
Mo EaFA-L01-1313-T01-C 1
Mo EaFA-L01-1313-T02-C 1
Mo EaFA-L01-1313-T03-C 1
Mo EaFA-L01-1313-T04-C 1
Mo EaFA-L01-1313-T05-C 1
Mo EaFA-L01-1313-T06-C 1
Mo EaFA-L01-1313-T07-C 1
Mo EaFA-L01-1313-T08-C 1
Mo EaFA-L01-1313-T09-C 1
Mo EaFA-L01-1313-B01-A 1
Mo EaFA-L01-1313-B02-A 1
Mo EaFA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
4.72E+03
4.45E+03
4.46E+03
4.08E+03
3.91 E+03
3.75E+03
2.21E+02
1.34E+02
6.21 E+02
4.49E+03
4.21 E+03
4.01 E+03
3.96E+03
3.93E+03
3.48E+03
1.45E+02
1.31 E+02
5.80E+02
4.53E+03
3.89E+03
4.13E+03
4.09E+03
3.71 E+03
3.40E+03
1.50E+02
1.23E+02
6.03E+02
1.63E+00 E
2.67E+01
1.37E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.72E+03 1.6E+00 1.2E+00 3.8E+00
4.45E+03 1.0E+00 1.2E+00 3.8E+00
4.46E+03 5.3E-01 1.2E+00 3.8E+00 10 325
4.08E+03 1.1E+00 1.2E+00 3.8E+00
3.91 E+03 5.7E+00 1.2E+00 3.8E+00
3.75E+03 7.0E-01 1.2E+00 3.8E+00
2.21 E+02 1.2E+00 1.2E+00 3.8E+00
1.34E+02 1.2E+00 1.2E+00 3.8E+00
6.21 E+02 5.0E-01 1.2E+00 3.8E+00
4.49E+03 1.2E+00 1.2E+00 3.8E+00
4.21E+03 2.1E+00 1.2E+00 3.8E+00
4.01E+03 1.0E+00 1.2E+00 3.8E+00 10 325
3.96E+03 7.7E-01 1.2E+00 3.8E+00
3.93E+03 6.2E-01 1.2E+00 3.8E+00
3.48E+03 8.0E-01 1.2E+00 3.8E+00
1.45E+02 1.1E+00 1.2E+00 3.8E+00
1.31E+02 2.6E+00 1.2E+00 3.8E+00
5.80E+02 2.6E-01 1.2E+00 3.8E+00
4.53E+03 1.9E+00 1.2E+00 3.8E+00
3.89E+03 3.8E-01 1.2E+00 3.8E+00
4.13E+03 8.7E-01 1.2E+00 3.8E+00 10 325
4.09E+03 3.2E-01 1.2E+00 3.8E+00
3.71 E+03 1.2E-01 1.2E+00 3.8E+00
3.40E+03 9.7E-01 1.2E+00 3.8E+00
1.50E+02 2.0E+00 1.2E+00 3.8E+00
1.23E+02 1.2E+00 1.2E+00 3.8E+00
6.03E+02 7.8E-01 1.2E+00 3.8E+00
1.63E+00 1.1 E+02 1.2E+00 3.8E+00
2.67E+01 1.7E+02 1.2E+00 3.8E+00
1.37E+01 2.5E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
7.49E+03 93% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
7.06E+03 94% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
7.13E+03 92% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-20
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFA-L01-1313-T01-A 1
Ni EaFA-L01-1313-T02-A 1
Ni EaFA-L01-1313-T03-A 1
Ni EaFA-L01-1313-T04-A 1
Ni EaFA-L01-1313-T05-A 1
Ni EaFA-L01-1313-T06-A 1
Ni EaFA-L01-1313-T07-A 1
Ni EaFA-L01-1313-T08-A 1
Ni EaFA-L01-1313-T09-A 1
Ni EaFA-L01-1313-T01-B 1
Ni EaFA-L01-1313-T02-B 1
Ni EaFA-L01-1313-T03-B 1
Ni EaFA-L01-1313-T04-B 1
Ni EaFA-L01-1313-T05-B 1
Ni EaFA-L01-1313-T06-B 1
Ni EaFA-L01-1313-T07-B 1
Ni EaFA-L01-1313-T08-B 1
Ni EaFA-L01-1313-T09-B 1
Ni EaFA-L01-1313-T01-C
Ni EaFA-L01-1313-T02-C
Ni EaFA-L01-1313-T03-C
Ni EaFA-L01-1313-T04-C
Ni EaFA-L01-1313-T05-C
Ni EaFA-L01-1313-T06-C
Ni EaFA-L01-1313-T07-C
Ni EaFA-L01-1313-T08-C
Ni EaFA-L01-1313-T09-C
Ni EaFA-L01-1313-B01-A
Ni EaFA-L01-1313-B02-A
Ni EaFA-L01-1313-B03-A
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.25E+00
1.53E+02
5.95E+02
5.34E+02
7.88E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
7.22E+00
1.14E+02
5.45E+02
5.31 E+02
7.79E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
7.25E+00
1.33E+02
5.26E+02
4.87E+02
7.63E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.2E+01 1.8E+00 5.7E+00
9.00E-01 3.1E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00 10 325
9.00E-01 5.1E+01 1.8E+00 5.7E+00
9.25E+00 2.2E+01 1.8E+00 5.7E+00
1.53E+02 1.0E+00 1.8E+00 5.7E+00
5.95E+02 4.0E-01 1.8E+00 5.7E+00
5.34E+02 1.2E+00 1.8E+00 5.7E+00
7.88E+02 3.5E-01 1.8E+00 5.7E+00
9.00E-01 3.9E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 3.5E+02 1.8E+00 5.7E+00 10 325
9.00E-01 1.2E+03 1.8E+00 5.7E+00
7.22E+00 3.5E+01 1.8E+00 5.7E+00
1.14E+02 1.7E+00 1.8E+00 5.7E+00
5.45E+02 1.9E+00 1.8E+00 5.7E+00
5.31 E+02 6.3E-01 1.8E+00 5.7E+00
7.79E+02 2.9E-01 1.8E+00 5.7E+00
9.00E-01 5.4E+02 1.8E+00 5.7E+00
9.00E-01 1.1 E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00 10 325
9.00E-01 2.8E+02 1.8E+00 5.7E+00
7.25E+00 7.1E+01 1.8E+00 5.7E+00
1.33E+02 8.9E-01 1.8E+00 5.7E+00
5.26E+02 2.0E+00 1.8E+00 5.7E+00
4.87E+02 1.5E+00 1.8E+00 5.7E+00
7.63E+02 7.4E-01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 2.2E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.52E+03 108% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
3.40E+03 105% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
3.39E+03 104% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                           1-21
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qu
1 1 ug/L
P EaFA-L01-1313-T01-A 1 1.56E+02
P EaFA-L01-1313-T02-A 1 8.28E+00 E
P EaFA-L01-1313-T03-A 1 2.77E+01
P EaFA-L01-1313-T04-A 1 9.52E+01
P EaFA-L01-1313-T05-A 1 6.42E+01
P EaFA-L01-1313-T06-A 1 2.06E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.56E+02 2.5E+00 3.7E+00 1.2E+01
8.28E+00 1.8E+02 3.7E+00 1 .2E+01
2.77E+01 1.0E+01 3.7E+00 1 .2E+01 1000 100
9.52E+01 6.7E+00 3.7E+00 1 .2E+01
6.42E+01 2.1E+00 3.7E+00 1 .2E+01
2.06E+01 3.8E+01 3.7E+00 1 .2E+01
P EaFA-L01-1313-T07-A 1 1.85E+OOU1/2 1.85E+00 2.1E+01 3.7E+00 1 .2E+01
P EaFA-L01-1313-T08-A 1 3.68E+01
P EaFA-L01-1313-T09-A 1 5.30E+03
P EaFA-L01-1313-T01-B 1 1.57E+02
P EaFA-L01-1313-T02-B 1 2.06E+01
P EaFA-L01-1313-T03-B 1 6.36E+01
P EaFA-L01-1313-T04-B 1 7.53E+01
P EaFA-L01-1313-T05-B 1 5.97E+01
P EaFA-L01-1313-T06-B 1 2.00E+01
3.68E+01 1.8E+01 3.7E+00 1.2E+01
5.30E+03 1.8E-01 3.7E+00 1.2E+01
1.57E+02 3.5E+00 3.7E+00 1.2E+01
2.06E+01 3.1E+01 3.7E+00 1.2E+01
6.36E+01 2.2E+01 3.7E+00 1.2E+01 1000 100
7.53E+01 8.4E+00 3.7E+00 1.2E+01
5.97E+01 1.0E+01 3.7E+00 1.2E+01
2.00E+01 3.5E+01 3.7E+00 1.2E+01
P EaFA-L01-1313-T07-B 1 1.85E+OOU1/2 1.85E+00 2.4E+03 3.7E+00 1.2E+01
P EaFA-L01-1313-T08-B 1 4.70E+01
P EaFA-L01-1313-T09-B 1 4.68E+03
P EaFA-L01-1313-T01-C 1 1.68E+02
P EaFA-L01-1313-T02-C 1 1.01E+01 E
P EaFA-L01-1313-T03-C 1 4.71E+01
P EaFA-L01-1313-T04-C 1 6.41E+01
P EaFA-L01-1313-T05-C 1 6.74E+01
P EaFA-L01-1313-T06-C 1 1.97E+01
4.70E+01 1.6E+01 3.7E+00 1.2E+01
4.68E+03 1.3E-01 3.7E+00 1.2E+01
1.68E+02 3.6E+00 3.7E+00 1.2E+01
1.01E+01 3.2E+01 3.7E+00 1.2E+01
4.71E+01 2.1E+01 3.7E+00 1.2E+01 1000 100
6.41 E+01 7.0E+00 3.7E+00 1.2E+01
6.74E+01 3.9E+00 3.7E+00 1.2E+01
1.97E+01 5.3E+01 3.7E+00 1.2E+01
P EaFA-L01-1313-T07-C 1 1.85E+OOU1/2 1.85E+00 2.5E+01 3.7E+00 1.2E+01
P EaFA-L01-1313-T08-C 1 3.75E+01
P EaFA-L01-1313-T09-C 1 5.03E+03
3.75E+01 1.9E+01 3.7E+00 1.2E+01
5.03E+03 2.7E-01 3.7E+00 1.2E+01
P EaFA-L01-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 3.0E+02 3.7E+00 1.2E+01
P EaFA-L01-1313-B02-A 1 1.48E+01
P EaFA-L01-1313-B03-A 1 3.42E+01
1.48E+01 1.6E+02 3.7E+00 1.2E+01
3.42E+01 5.8E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
1 .12E+03 109% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
1.13E+03 107% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:26AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
1.13E+03 108% VU ICP-OES 6/9/10 11 :39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-22
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
1 ug/L
K EaFA-L01-1313-T01-A 1 1.87E+06
K EaFA-L01-1313-T02-A 1 4.60E+05
K EaFA-L01-1313-T03-A 1 1.75E+05
K EaFA-L01-1313-T04-A 1 1.06E+05
K EaFA-L01-1313-T05-A 1 6.49E+04
K EaFA-L01-1313-T06-A 1 2.42E+04
K EaFA-L01-1313-T07-A 1 2.17E+04
K EaFA-L01-1313-T08-A 1 1.82E+04
K EaFA-L01-1313-T09-A 1 2.18E+04
K EaFA-L01-1313-T01-B 1 1.86E+06
K EaFA-L01-1313-T02-B 1 4.54E+05
K EaFA-L01-1313-T03-B 1 1.53E+05
K EaFA-L01-1313-T04-B 1 1.02E+05
K EaFA-L01-1313-T05-B 1 6.49E+04
K EaFA-L01-1313-T06-B 1 2.29E+04
K EaFA-L01-1313-T07-B 1 1.97E+04
K EaFA-L01-1313-T08-B 1 1.78E+04
K EaFA-L01-1313-T09-B 1 2.14E+04
K EaFA-L01-1313-T01-C 1 1.80E+06
K EaFA-L01-1313-T02-C 1 3.93E+05
K EaFA-L01-1313-T03-C 1 1.69E+05
K EaFA-L01-1313-T04-C 1 1.04E+05
K EaFA-L01-1313-T05-C 1 6.12E+04
K EaFA-L01-1313-T06-C 1 2.31E+04
K EaFA-L01-1313-T07-C 1 1.93E+04
K EaFA-L01-1313-T08-C 1 1.67E+04
K EaFA-L01-1313-T09-C 1 2.12E+04
K EaFA-L01-1313-B01-A 1 1.11E+01
K EaFA-L01-1313-B02-A 1 1.86E+06
K EaFA-L01-1313-B03-A 1 1.40E+06
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.87E+06 9.2E-01 1.6E+00 5.1E+00
4.60E+05 1.1E+00 1.6E+00 5.1E+00
1.75E+05 7.0E-01 1.6E+00 5.1E+00 1000 100
1.06E+05 2.4E-01 1.6E+00 5.1E+00
6.49E+04 4.2E+00 1.6E+00 5.1E+00
2.42E+04 3.5E-01 1.6E+00 5.1E+00
2.17E+04 3.8E-01 1.6E+00 5.1E+00
1.82E+04 5.8E-01 1.6E+00 5.1E+00
2.18E+04 3.2E-01 1.6E+00 5.1E+00
1.86E+06 8.9E-01 1.6E+00 5.1E+00
4.54E+05 8.3E-01 1.6E+00 5.1E+00
1.53E+05 7.9E-01 1.6E+00 5.1E+00 1000 100
1.02E+05 2.3E-01 1.6E+00 5.1E+00
6.49E+04 8.9E-01 1.6E+00 5.1E+00
2.29E+04 2.1E-01 1.6E+00 5.1E+00
1.97E+04 1.3E-01 1.6E+00 5.1E+00
1.78E+04 3.7E-01 1.6E+00 5.1E+00
2.14E+04 4.1E-01 1.6E+00 5.1E+00
1.80E+06 3.9E-01 1.6E+00 5.1E+00
3.93E+05 4.3E-01 1.6E+00 5.1E+00
1.69E+05 5.3E-01 1.6E+00 5.1E+00 1000 100
1.04E+05 5.0E-01 1.6E+00 5.1E+00
6.12E+04 6.7E-01 1.6E+00 5.1E+00
2.31 E+04 5.5E-01 1.6E+00 5.1E+00
1.93E+04 6.5E-01 1.6E+00 5.1E+00
1.67E+04 1.0E+00 1.6E+00 5.1E+00
2.12E+04 8.1E-01 1.6E+00 5.1E+00
1.11E+01 1.1E+01 1.6E+00 5.1E+00
1.86E+06 1.6E+01 1.6E+00 5.1E+00
1.40E+06 7.0E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
1.76E+05 83% VUICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
1.54E+05 92% VUICP-OES 6/9/10 11 :19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
1.70E+05 88% VUICP-OES 6/9/10 1 1:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-23
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
1 ug/L
Se EaFA-L01-1313-T01-A 1 8.17E+03
Se EaFA-L01-1313-T02-A 1 6.11E+03
Se EaFA-L01-1313-T03-A 1 5.35E+03
Se EaFA-L01-1313-T04-A 1 3.63E+03
Se EaFA-L01-1313-T05-A 1 2.25E+03
Se EaFA-L01-1313-T06-A 1 1.23E+03
Se EaFA-L01-1313-T07-A 1 1.99E+02
Se EaFA-L01-1313-T08-A 1 9.22E+01
Se EaFA-L01-1313-T09-A 1 1.24E+03
Se EaFA-L01-1313-T01-B 1 7.61E+03
Se EaFA-L01-1313-T02-B 1 5.77E+03
Se EaFA-L01-1313-T03-B 1 4.72E+03
Se EaFA-L01-1313-T04-B 1 3.60E+03
Se EaFA-L01-1313-T05-B 1 2.24E+03
Se EaFA-L01-1313-T06-B 1 1.08E+03
Se EaFA-L01-1313-T07-B 1 1.54E+02
Se EaFA-L01-1313-T08-B 1 9.38E+01
Se EaFA-L01-1313-T09-B 1 1.16E+03
Se EaFA-L01-1313-T01-C 1 7.64E+03
Se EaFA-L01-1313-T02-C 1 5.12E+03
Se EaFA-L01-1313-T03-C 1 4.97E+03
Se EaFA-L01-1313-T04-C 1 3.60E+03
Se EaFA-L01-1313-T05-C 1 2.20E+03
Se EaFA-L01-1313-T06-C 1 1 .03E+03
Se EaFA-L01-1313-T07-C 1 1 .25E+02
Se EaFA-L01-1313-T08-C 1 8.94E+01
Se EaFA-L01-1313-T09-C 1 1.19E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
8.17E+03 1.1E+00 1.5E+01 4.8E+01
6.11E+03 2.7E-01 1.5E+01 4.8E+01
5.35E+03 2.5E-01 1.5E+01 4.8E+01 10 325
3.63E+03 1.5E+00 1.5E+01 4.8E+01
2.25E+03 6.9E+00 1.5E+01 4.8E+01
1.23E+03 3.5E+00 1.5E+01 4.8E+01
1.99E+02 7.8E+00 1.5E+01 4.8E+01
9.22E+01 4.1E+01 1.5E+01 4.8E+01
1.24E+03 2.2E+00 1.5E+01 4.8E+01
7.61 E+03 2.8E+00 1.5E+01 4.8E+01
5.77E+03 1.6E+00 1.5E+01 4.8E+01
4.72E+03 7.2E-01 1.5E+01 4.8E+01 10 325
3.60E+03 1.7E+00 1.5E+01 4.8E+01
2.24E+03 1.4E+00 1.5E+01 4.8E+01
1.08E+03 1.1E+00 1.5E+01 4.8E+01
1.54E+02 2.8E+01 1.5E+01 4.8E+01
9.38E+01 1.7E+01 1.5E+01 4.8E+01
1.16E+03 2.3E+00 1 .5E+01 4.8E+01
7.64E+03 2.3E+00 1 .5E+01 4.8E+01
5.12E+03 3.4E-01 1 .5E+01 4.8E+01
4.97E+03 9.9E-01 1 .5E+01 4.8E+01 10 325
3.60E+03 2.4E+00 1 .5E+01 4.8E+01
2.20E+03 1.3E-01 1 .5E+01 4.8E+01
1.03E+03 4.4E+00 1 .5E+01 4.8E+01
1.25E+02 3.2E+01 1 .5E+01 4.8E+01
8.94E+01 1.0E+01 1.5E+01 4.8E+01
1.19E+03 1.2E+00 1.5E+01 4.8E+01
Se EaFA-L01-1313-B01-A 1 7.50E+00 U1/2 7.50E+00 4.9E+01 1.5E+01 4.8E+01
Se EaFA-L01-1313-B02-A 1 7.50E+00 U1/2 7.50E+00 1.9E+02 1.5E+01 4.8E+01
Se EaFA-L01-1313-B03-A 1 7.50E+00 U1/2 7.50E+00 2.9E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
8.23E+03 89% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
7.67E+03 91% VUICP-OES 6/9/10 11 :19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
7.84E+03 88% VUICP-OES 6/9/10 1 1:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-24
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si EaFA-L01-1313-T01-A 1
Si EaFA-L01-1313-T02-A 1
Si EaFA-L01-1313-T03-A 1
Si EaFA-L01-1313-T04-A 1
Si EaFA-L01-1313-T05-A 1
Si EaFA-L01-1313-T06-A 1
Si EaFA-L01-1313-T07-A 1
Si EaFA-L01-1313-T08-A 1
Si EaFA-L01-1313-T09-A 1
Si EaFA-L01-1313-T01-B 1
Si EaFA-L01-1313-T02-B 1
Si EaFA-L01-1313-T03-B 1
Si EaFA-L01-1313-T04-B 1
Si EaFA-L01-1313-T05-B 1
Si EaFA-L01-1313-T06-B 1
Si EaFA-L01-1313-T07-B 1
Si EaFA-L01-1313-T08-B 1
Si EaFA-L01-1313-T09-B 1
Si EaFA-L01-1313-T01-C 1
Si EaFA-L01-1313-T02-C 1
Si EaFA-L01-1313-T03-C 1
Si EaFA-L01-1313-T04-C 1
Si EaFA-L01-1313-T05-C 1
Si EaFA-L01-1313-T06-C 1
Si EaFA-L01-1313-T07-C 1
Si EaFA-L01-1313-T08-C 1
Si EaFA-L01-1313-T09-C 1
Si EaFA-L01-1313-B01-A 1
Si EaFA-L01-1313-B02-A 1
Si EaFA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.25E+04
4.36E+03
5.91 E+02
3.36E+02
6.55E+02
3.27E+03
9.62E+03
2.00E+04
6.93E+04
1.80E+04
3.23E+03
4.57E+02
3.29E+02
6.67E+02
2.26E+03
8.39E+03
2.03E+04
6.98E+04
1.79E+04
2.87E+03
6.44E+02
3.37E+02
6.29E+02
2.46E+03
7.98E+03
1.86E+04
6.79E+04
3.54E+01
2.38E+03
7.81 E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.25E+04 1.1E+00 1.1E+00 3.5E+00
4.36E+03 9.5E-01 1.1E+00 3.5E+00
5.91E+02 2.4E-01 1.1E+00 3.5E+00 1000 100
3.36E+02 1.6E+00 1.1E+00 3.5E+00
6.55E+02 5.0E+00 1.1E+00 3.5E+00
3.27E+03 4.7E-01 1.1E+00 3.5E+00
9.62E+03 3.7E-01 1.1E+00 3.5E+00
2.00E+04 4.7E-01 1.1E+00 3.5E+00
6.93E+04 3.3E-01 1.1E+00 3.5E+00
1.80E+04 1.5E+00 1.1E+00 3.5E+00
3.23E+03 1.7E+00 1.1E+00 3.5E+00
4.57E+02 7.0E-01 1.1E+00 3.5E+00 1000 100
3.29E+02 2.7E-01 1.1E+00 3.5E+00
6.67E+02 1.2E+00 1.1E+00 3.5E+00
2.26E+03 5.1E-01 1.1E+00 3.5E+00
8.39E+03 4.1E-01 1.1E+00 3.5E+00
2.03E+04 2.8E-01 1.1E+00 3.5E+00
6.98E+04 2.7E-01 1.1E+00 3.5E+00
1.79E+04 1.0E+00 1.1E+00 3.5E+00
2.87E+03 3.4E-01 1.1E+00 3.5E+00
6.44E+02 5.0E-01 1.1E+00 3.5E+00 1000 100
3.37E+02 8.6E-01 1.1E+00 3.5E+00
6.29E+02 1.7E+00 1.1E+00 3.5E+00
2.46E+03 3.5E-01 1.1E+00 3.5E+00
7.98E+03 1.6E+00 1.1E+00 3.5E+00
1.86E+04 1.5E+00 1.1E+00 3.5E+00
6.79E+04 3.4E-01 1.1E+00 3.5E+00
3.54E+01 9.3E+00 1.1E+00 3.5E+00
2.38E+03 1.1E+01 1.1E+00 3.5E+00
7.81 E+02 1.9E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
1.69E+03 110% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
1.52E+03 106% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
1.68E+03 104% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-25
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFA-L01-1313-T01-A 1
Na EaFA-L01-1313-T02-A 1
Na EaFA-L01-1313-T03-A 1
Na EaFA-L01-1313-T04-A 1
Na EaFA-L01-1313-T05-A 1
Na EaFA-L01-1313-T06-A 1
Na EaFA-L01-1313-T07-A 1
Na EaFA-L01-1313-T08-A 1
Na EaFA-L01-1313-T09-A 1
Na EaFA-L01-1313-T01-B 1
Na EaFA-L01-1313-T02-B 1
Na EaFA-L01-1313-T03-B 1
Na EaFA-L01-1313-T04-B 1
Na EaFA-L01-1313-T05-B 1
Na EaFA-L01-1313-T06-B 1
Na EaFA-L01-1313-T07-B 1
Na EaFA-L01-1313-T08-B 1
Na EaFA-L01-1313-T09-B 1
Na EaFA-L01-1313-T01-C 1
Na EaFA-L01-1313-T02-C 1
Na EaFA-L01-1313-T03-C 1
Na EaFA-L01-1313-T04-C 1
Na EaFA-L01-1313-T05-C 1
Na EaFA-L01-1313-T06-C 1
Na EaFA-L01-1313-T07-C 1
Na EaFA-L01-1313-T08-C 1
Na EaFA-L01-1313-T09-C 1
Na EaFA-L01-1313-B01-A 1
Na EaFA-L01-1313-B02-A 1
Na EaFA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.33E+04
7.40E+03
6.34E+03
5.77E+03
5.48E+03
5.62E+03
4.82E+03
3.93E+03
3.09E+03
2.13E+04
7.21 E+03
5.64E+03
5.58E+03
5.49E+03
5.29E+03
4.36E+03
3.83E+03
3.10E+03
2.08E+04
6.47E+03
5.83E+03
5.71 E+03
5.19E+03
5.32E+03
4.29E+03
3.63E+03
3.04E+03
8.50E+00
2.60E+00 E
5.33E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.33E+04 1.0E+00 2.5E+00 8.0E+00
7.40E+03 9.6E-01 2.5E+00 8.0E+00
6.34E+03 4.7E-01 2.5E+00 8.0E+00 1000 100
5.77E+03 3.5E-01 2.5E+00 8.0E+00
5.48E+03 4.2E+00 2.5E+00 8.0E+00
5.62E+03 7.6E-01 2.5E+00 8.0E+00
4.82E+03 1.5E-01 2.5E+00 8.0E+00
3.93E+03 3.2E-01 2.5E+00 8.0E+00
3.09E+03 2.3E-01 2.5E+00 8.0E+00
2.13E+04 1.4E+00 2.5E+00 8.0E+00
7.21 E+03 1.1E+00 2.5E+00 8.0E+00
5.64E+03 4.4E-01 2.5E+00 8.0E+00 1000 100
5.58E+03 5.5E-01 2.5E+00 8.0E+00
5.49E+03 2.1E-01 2.5E+00 8.0E+00
5.29E+03 5.1E-01 2.5E+00 8.0E+00
4.36E+03 7.5E-01 2.5E+00 8.0E+00
3.83E+03 2.8E-01 2.5E+00 8.0E+00
3.10E+03 8.2E-01 2.5E+00 8.0E+00
2.08E+04 9.3E-01 2.5E+00 8.0E+00
6.47E+03 6.1E-02 2.5E+00 8.0E+00
5.83E+03 5.0E-01 2.5E+00 8.0E+00 1000 100
5.71 E+03 9.2E-01 2.5E+00 8.0E+00
5.19E+03 4.7E-01 2.5E+00 8.0E+00
5.32E+03 3.4E-01 2.5E+00 8.0E+00
4.29E+03 6.4E-01 2.5E+00 8.0E+00
3.63E+03 8.9E-01 2.5E+00 8.0E+00
3.04E+03 3.5E-01 2.5E+00 8.0E+00
8.50E+00 2.3E+00 2.5E+00 8.0E+00
2.60E+00 2.4E+00 2.5E+00 8.0E+00
5.33E+02 5.5E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
7.41E+03 107% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:18 AM EPA Interlab L01 1313-1316 EaFA
6.57E+03 93% VU ICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:23 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
6.80E+03 96% VU ICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-26
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone.
1 ug/L
EaFA-L01-1313-T01-A 1 1.65E+03
EaFA-L01-1313-T02-A 1 1.78E+03
EaFA-L01-1313-T03-A 1 2.00E+03
EaFA-L01-1313-T04-A 1 1.98E+03
EaFA-L01-1313-T05-A 1 1.98E+03
EaFA-L01-1313-T06-A 1 2.33E+03
EaFA-L01-1313-T07-A 1 2.76E+03
EaFA-L01-1313-T08-A 1 2.99E+03
EaFA-L01-1313-T09-A 1 5.30E+03
EaFA-L01-1313-T01-B 1 1.41E+03
EaFA-L01-1313-T02-B 1 1.67E+03
EaFA-L01-1313-T03-B 1 1.79E+03
EaFA-L01-1313-T04-B 1 1.93E+03
EaFA-L01-1313-T05-B 1 1.99E+03
EaFA-L01-1313-T06-B 1 2.18E+03
EaFA-L01-1313-T07-B 1 2.36E+03
EaFA-L01-1313-T08-B 1 3.01 E+03
EaFA-L01-1313-T09-B 1 5.31 E+03
EaFA-L01-1313-T01-C 1 1.39E+03
EaFA-L01-1313-T02-C 1 1.56E+03
EaFA-L01-1313-T03-C 1 1.80E+03
EaFA-L01-1313-T04-C 1 1.99E+03
EaFA-L01-1313-T05-C 1 1.91 E+03
EaFA-L01-1313-T06-C 1 2.15E+03
EaFA-L01-1313-T07-C 1 2.27E+03
EaFA-L01-1313-T08-C 1 2.76E+03
EaFA-L01-1313-T09-C 1 5.13E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.65E+03 1.4E+00 1.0E+00 3.2E+00
1.78E+03 9.6E-01 1.0E+00 3.2E+00
2.00E+03 7.2E-01 1.0E+00 3.2E+00 1000 100
1.98E+03 6.2E-01 1.0E+00 3.2E+00
1.98E+03 5.5E+00 1.0E+00 3.2E+00
2.33E+03 5.8E-01 1.0E+00 3.2E+00
2.76E+03 4.4E-01 1.0E+00 3.2E+00
2.99E+03 5.6E-01 1.0E+00 3.2E+00
5.30E+03 3.2E-01 1.0E+00 3.2E+00
1.41 E+03 1.3E+00 1.0E+00 3.2E+00
1.67E+03 1.4E+00 1.0E+00 3.2E+00
1.79E+03 1.0E+00 1.0E+00 3.2E+00 1000 100
1.93E+03 7.3E-01 1.0E+00 3.2E+00
1.99E+03 9.0E-01 1.0E+00 3.2E+00
2.18E+03 8.2E-01 1.0E+00 3.2E+00
2.36E+03 4.8E-01 1.0E+00 3.2E+00
3.01 E+03 7.9E-01 1.0E+00 3.2E+00
5.31 E+03 8.2E-01 1.0E+00 3.2E+00
1.39E+03 1.3E+00 1.0E+00 3.2E+00
1.56E+03 7.5E-01 1.0E+00 3.2E+00
1.80E+03 6.7E-01 1.0E+00 3.2E+00 1000 100
1.99E+03 4.3E-01 1.0E+00 3.2E+00
1.91 E+03 2.7E-01 1.0E+00 3.2E+00
2.15E+03 5.4E-01 1.0E+00 3.2E+00
2.27E+03 1.1E+00 1.0E+00 3.2E+00
2.76E+03 1.8E+00 1.0E+00 3.2E+00
5.13E+03 4.8E-01 1.0E+00 3.2E+00
EaFA-L01-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 4.0E+01 1.0E+00 3.2E+00
EaFA-L01-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 1.8E+01 1.0E+00 3.2E+00
EaFA-L01-1313-B03-A 1 5.00E-01 U1/2 5.00E-01 9.0E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
2.84E+03 84% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
2.64E+03 85% VUICP-OES 6/9/10 11 :19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
2.63E+03 83% VUICP-OES 6/9/10 1 1:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-27
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S EaFA-L01-1313-T01-A 1
S EaFA-L01-1313-T02-A 1
S EaFA-L01-1313-T03-A 1
S EaFA-L01-1313-T04-A 1
S EaFA-L01-1313-T05-A 1
S EaFA-L01-1313-T06-A 1
S EaFA-L01-1313-T07-A 1
S EaFA-L01-1313-T08-A 1
S EaFA-L01-1313-T09-A 1
S EaFA-L01-1313-T01-B 1
S EaFA-L01-1313-T02-B 1
S EaFA-L01-1313-T03-B 1
S EaFA-L01-1313-T04-B 1
S EaFA-L01-1313-T05-B 1
S EaFA-L01-1313-T06-B 1
S EaFA-L01-1313-T07-B 1
S EaFA-L01-1313-T08-B 1
S EaFA-L01-1313-T09-B 1
S EaFA-L01-1313-T01-C 1
S EaFA-L01-1313-T02-C 1
S EaFA-L01-1313-T03-C 1
S EaFA-L01-1313-T04-C 1
S EaFA-L01-1313-T05-C 1
S EaFA-L01-1313-T06-C 1
S EaFA-L01-1313-T07-C 1
S EaFA-L01-1313-T08-C 1
S EaFA-L01-1313-T09-C 1
S EaFA-L01-1313-B01-A 1
S EaFA-L01-1313-B02-A 1
S EaFA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.98E+05
1.65E+05
1.63E+05
1.63E+05
1.59E+05
1.64E+05
1.26E+05
9.93E+04
5.41 E+04
1.86E+05
1.61E+05
1.55E+05
1.57E+05
1.58E+05
1.56E+05
1.13E+05
9.84E+04
5.50E+04
1.87E+05
1.47E+05
1.61E+05
1.63E+05
1.50E+05
1.57E+05
1.11E+05
9.21 E+04
5.31 E+04
3.40E+00 U1/2
3.40E+00 U1/2
1.31E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.98E+05 1.1E+00 6.8E+00 2.2E+01
1.65E+05 8.8E-01 6.8E+00 2.2E+01
1.63E+05 7.5E-02 6.8E+00 2.2E+01 1000 100
1.63E+05 5.3E-01 6.8E+00 2.2E+01
1.59E+05 4.8E+00 6.8E+00 2.2E+01
1.64E+05 5.4E-01 6.8E+00 2.2E+01
1.26E+05 2.7E-01 6.8E+00 2.2E+01
9.93E+04 4.4E-01 6.8E+00 2.2E+01
5.41 E+04 5.8E-01 6.8E+00 2.2E+01
1.86E+05 1.6E+00 6.8E+00 2.2E+01
1.61E+05 1.3E+00 6.8E+00 2.2E+01
1.55E+05 3.9E-01 6.8E+00 2.2E+01 1000 100
1.57E+05 7.8E-02 6.8E+00 2.2E+01
1.58E+05 2.5E-01 6.8E+00 2.2E+01
1.56E+05 1.7E-01 6.8E+00 2.2E+01
1.13E+05 4.6E-01 6.8E+00 2.2E+01
9.84E+04 9.0E-02 6.8E+00 2.2E+01
5.50E+04 2.5E-01 6.8E+00 2.2E+01
1.87E+05 8.7E-01 6.8E+00 2.2E+01
1.47E+05 5.0E-01 6.8E+00 2.2E+01
1.61E+05 4.6E-01 6.8E+00 2.2E+01 1000 100
1.63E+05 8.6E-01 6.8E+00 2.2E+01
1.50E+05 4.3E-01 6.8E+00 2.2E+01
1.57E+05 1.0E-01 6.8E+00 2.2E+01
1.11E+05 9.8E-01 6.8E+00 2.2E+01
9.21E+04 1.2E+00 6.8E+00 2.2E+01
5.31 E+04 2.2E-01 6.8E+00 2.2E+01
3.40E+00 2.7E+02 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
1.31E+01 2.0E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
1.64E+05 88% VUICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
1.56E+05 83% VUICP-OES 6/9/10 11 :19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
1.62E+05 94% VUICP-OES 6/9/10 1 1:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-28
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-L01-1313-T01-A 1
Tl EaFA-L01-1313-T02-A 1
Tl EaFA-L01-1313-T03-A 1
Tl EaFA-L01-1313-T04-A 1
Tl EaFA-L01-1313-T05-A 1
Tl EaFA-L01-1313-T06-A 1
Tl EaFA-L01-1313-T07-A 1
Tl EaFA-L01-1313-T08-A 1
Tl EaFA-L01-1313-T09-A 1
Tl EaFA-L01-1313-T01-B 1
Tl EaFA-L01-1313-T02-B 1
Tl EaFA-L01-1313-T03-B 1
Tl EaFA-L01-1313-T04-B 1
Tl EaFA-L01-1313-T05-B 1
Tl EaFA-L01-1313-T06-B 1
Tl EaFA-L01-1313-T07-B 1
Tl EaFA-L01-1313-T08-B 1
Tl EaFA-L01-1313-T09-B 1
Tl EaFA-L01-1313-T01-C 1
Tl EaFA-L01-1313-T02-C 1
Tl EaFA-L01-1313-T03-C 1
Tl EaFA-L01-1313-T04-C 1
Tl EaFA-L01-1313-T05-C 1
Tl EaFA-L01-1313-T06-C 1
Tl EaFA-L01-1313-T07-C 1
Tl EaFA-L01-1313-T08-C 1
Tl EaFA-L01-1313-T09-C 1
Tl EaFA-L01-1313-B01-A 1
Tl EaFA-L01-1313-B02-A 1
Tl EaFA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.40E+01
4.77E+01
7.40E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.42E+01
3.56E+01
7.63E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
3.16E+01
3.73E+01
7.82E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 1.4E+02 4.6E+00 1.5E+01
2.30E+00 1.8E+02 4.6E+00 1.5E+01
2.30E+00 1.4E+02 4.6E+00 1.5E+01 10 325
2.30E+00 2.5E+02 4.6E+00 1.5E+01
2.30E+00 2.5E+01 4.6E+00 1.5E+01
2.30E+00 7.3E+01 4.6E+00 1.5E+01
2.40E+01 2.0E+01 4.6E+00 1 .5E+01
4.77E+01 9.0E+00 4.6E+00 1 .5E+01
7.40E+01 7.7E+00 4.6E+00 1 .5E+01
2.30E+00 2.9E+01 4.6E+00 1 .5E+01
2.30E+00 4.6E+01 4.6E+00 1 .5E+01
2.30E+00 3.8E+02 4.6E+00 1 .5E+01 10 325
2.30E+00 1.9E+02 4.6E+00 1 .5E+01
2.30E+00 8.1E+01 4.6E+00 1 .5E+01
2.30E+00 5.8E+01 4.6E+00 1 .5E+01
2.42E+01 3.1E+01 4.6E+00 1 .5E+01
3.56E+01 2.1E+01 4.6E+00 1.5E+01
7.63E+01 6.5E+00 4.6E+00 1.5E+01
2.30E+00 7.1E+02 4.6E+00 1.5E+01
2.30E+00 6.0E+01 4.6E+00 1 .5E+01
2.30E+00 3.0E+01 4.6E+00 1 .5E+01 10 325
2.30E+00 3.8E+01 4.6E+00 1 .5E+01
2.30E+00 6.4E+01 4.6E+00 1 .5E+01
2.30E+00 1.2E+03 4.6E+00 1.5E+01
3.16E+01 3.5E+01 4.6E+00 1.5E+01
3.73E+01 1.4E+01 4.6E+00 1.5E+01
7.82E+01 5.6E+00 4.6E+00 1.5E+01
2.30E+00 9.2E+01 4.6E+00 1.5E+01
2.30E+00 1.5E+02 4.6E+00 1.5E+01
2.30E+00 7.0E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.22E+03 99% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
3.15E+03 97% VUICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:26AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:29AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:36AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:37 AM EPA Interlab L01 1313-1316 EaFA
3.12E+03 96% VUICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-29
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L01-1313-T01-A 1
Ti EaFA-L01-1313-T02-A 1
Ti EaFA-L01-1313-T03-A 1
Ti EaFA-L01-1313-T04-A 1
Ti EaFA-L01-1313-T05-A 1
Ti EaFA-L01-1313-T06-A 1
Ti EaFA-L01-1313-T07-A 1
Ti EaFA-L01-1313-T08-A 1
Ti EaFA-L01-1313-T09-A 1
Ti EaFA-L01-1313-T01-B 1
Ti EaFA-L01-1313-T02-B 1
Ti EaFA-L01-1313-T03-B 1
Ti EaFA-L01-1313-T04-B 1
Ti EaFA-L01-1313-T05-B 1
Ti EaFA-L01-1313-T06-B 1
Ti EaFA-L01-1313-T07-B 1
Ti EaFA-L01-1313-T08-B 1
Ti EaFA-L01-1313-T09-B 1
Ti EaFA-L01-1313-T01-C 1
Ti EaFA-L01-1313-T02-C 1
Ti EaFA-L01-1313-T03-C 1
Ti EaFA-L01-1313-T04-C 1
Ti EaFA-L01-1313-T05-C 1
Ti EaFA-L01-1313-T06-C 1
Ti EaFA-L01-1313-T07-C 1
Ti EaFA-L01-1313-T08-C 1
Ti EaFA-L01-1313-T09-C 1
Ti EaFA-L01-1313-B01-A 1
Ti EaFA-L01-1313-B02-A 1
Ti EaFA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.27E+01
1.08E+04
1.00E+00 U1/2
1.66E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.30E+01
9.16E+03
4.96E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.22E+01
1.05E+04
1.00E+00 U1/2
1.00E+00 U1/2
2.30E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+00 2.0E+00 6.4E+00
1.00E+00 4.5E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 2.1E+02 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 6.5E+01 2.0E+00 6.4E+00
1.27E+01 3.4E+00 2.0E+00 6.4E+00
1.08E+04 2.8E-01 2.0E+00 6.4E+00
1.00E+00 9.8E+01 2.0E+00 6.4E+00
1.66E+01 4.9E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+02 2.0E+00 6.4E+00 10 325
1.00E+00 6.6E+01 2.0E+00 6.4E+00
1.00E+00 5.6E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
1.00E+00 5.8E+01 2.0E+00 6.4E+00
1.30E+01 4.8E+00 2.0E+00 6.4E+00
9.16E+03 6.6E-01 2.0E+00 6.4E+00
4.96E+00 9.9E+00 2.0E+00 6.4E+00
1.00E+00 4.6E+02 2.0E+00 6.4E+00
1.00E+00 7.0E+01 2.0E+00 6.4E+00 10 325
1.00E+00 2.2E+02 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.22E+01 3.2E+00 2.0E+00 6.4E+00
1.05E+04 4.6E-01 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00
2.30E+00 8.8E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.42E+03 105% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:00 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/102:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
3.32E+03 102% VUICP-OES 6/9/10 11:19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:26AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:29AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:36AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:37 AM EPA Interlab L01 1313-1316 EaFA
3.31E+03 102% VUICP-OES 6/9/10 11:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 11:51 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                           1-30
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
V EaFA-L01-1313-T01-A 1 6.31 E+03
V EaFA-L01-1313-T02-A 1 3.02E+03
V EaFA-L01-1313-T03-A 1 2.15E+03
V EaFA-L01-1313-T04-A 1 7.93E+02
V EaFA-L01-1313-T05-A 1 3.95E+02
V EaFA-L01-1313-T06-A 1 3.21E+02
V EaFA-L01-1313-T07-A 1 9.86E+01
V EaFA-L01-1313-T08-A 1 1.07E+02
V EaFA-L01-1313-T09-A 1 6.00E+03
V EaFA-L01-1313-T01-B 1 5.73E+03
V EaFA-L01-1313-T02-B 1 2.49E+03
V EaFA-L01-1313-T03-B 1 1.74E+03
V EaFA-L01-1313-T04-B 1 7.72E+02
V EaFA-L01-1313-T05-B 1 3.97E+02
V EaFA-L01-1313-T06-B 1 2.35E+02
V EaFA-L01-1313-T07-B 1 7.98E+01
V EaFA-L01-1313-T08-B 1 1.05E+02
V EaFA-L01-1313-T09-B 1 6.01 E+03
V EaFA-L01-1313-T01-C 1 5.69E+03
V EaFA-L01-1313-T02-C 1 2.31E+03
V EaFA-L01-1313-T03-C 1 2.18E+03
V EaFA-L01-1313-T04-C 1 7.79E+02
V EaFA-L01-1313-T05-C 1 3.72E+02
V EaFA-L01-1313-T06-C 1 2.38E+02
V EaFA-L01-1313-T07-C 1 8.01E+01
V EaFA-L01-1313-T08-C 1 9.98E+01
V EaFA-L01-1313-T09-C 1 5.82E+03
V EaFA-L01-1313-B01-A 1 9.84E+00
V EaFA-L01-1313-B02-A 1 8.67E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.31 E+03 4.7E-01 1.5E+00 4.8E+00
3.02E+03 8.6E-01 1.5E+00 4.8E+00
2.15E+03 9.5E-01 1.5E+00 4.8E+00 10 325
7.93E+02 3.9E-01 1.5E+00 4.8E+00
3.95E+02 7.3E+00 1.5E+00 4.8E+00
3.21 E+02 6.0E-01 1.5E+00 4.8E+00
9.86E+01 5.8E-01 1.5E+00 4.8E+00
1.07E+02 9.0E-01 1.5E+00 4.8E+00
6.00E+03 6.0E-01 1.5E+00 4.8E+00
5.73E+03 1.1E+00 1.5E+00 4.8E+00
2.49E+03 1.4E+00 1.5E+00 4.8E+00
1.74E+03 1.1E+00 1.5E+00 4.8E+00 10 325
7.72E+02 1.6E+00 1.5E+00 4.8E+00
3.97E+02 2.1E+00 1.5E+00 4.8E+00
2.35E+02 2.1E+00 1.5E+00 4.8E+00
7.98E+01 7.1E-01 1.5E+00 4.8E+00
1.05E+02 6.0E-01 1.5E+00 4.8E+00
6.01 E+03 6.3E-01 1.5E+00 4.8E+00
5.69E+03 1.4E+00 1.5E+00 4.8E+00
2.31 E+03 1.0E+00 1.5E+00 4.8E+00
2.18E+03 1.0E+00 1.5E+00 4.8E+00 10 325
7.79E+02 3.6E-01 1.5E+00 4.8E+00
3.72E+02 1.1E+00 1.5E+00 4.8E+00
2.38E+02 1.0E+00 1.5E+00 4.8E+00
8.01 E+01 8.8E-01 1.5E+00 4.8E+00
9.98E+01 9.6E-01 1.5E+00 4.8E+00
5.82E+03 2.5E-01 1.5E+00 4.8E+00
9.84E+00 2.8E+01 1.5E+00 4.8E+00
8.67E+00 4.5E+00 1.5E+00 4.8E+00
V EaFA-L01-1313-B03-A 1 7.50E-01 U1/2 7.50E-01 1.2E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
5.31E+03 97% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:16 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
4.88E+03 97% VUICP-OES 6/9/10 11 :19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:24AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
5.27E+03 95% VUICP-OES 6/9/10 1 1:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                           1-31
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone.
1 1 ug/L
Zn EaFA-L01-1313-T01-A 1 1.60E+02
Zn EaFA-L01-1313-T02-A 1 7.84E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.60E+02 5.6E-01 1.0E+00 3.2E+00
7.84E+00 4.7E+00 1.0E+00 3.2E+00
Zn EaFA-L01-1313-T03-A 1 5.00E-01 U1/2 5.00E-01 1.1E+02 1.0E+00 3.2E+00 10 325
Zn EaFA-L01-1313-T04-A 1 6.71E+01
Zn EaFA-L01-1313-T05-A 1 4.08E+01
Zn EaFA-L01-1313-T06-A 1 2.03E+01
Zn EaFA-L01-1313-T07-A 1 1.23E+03
Zn EaFA-L01-1313-T08-A 1 1.16E+03
Zn EaFA-L01-1313-T09-A 1 1.63E+03
Zn EaFA-L01-1313-T01-B 1 4.06E+02
Zn EaFA-L01-1313-T02-B 1 3.27E+02
Zn EaFA-L01-1313-T03-B 1 2.27E+02
Zn EaFA-L01-1313-T04-B 1 6.54E+01
Zn EaFA-L01-1313-T05-B 1 4.12E+01
Zn EaFA-L01-1313-T06-B 1 2.38E+01
Zn EaFA-L01-1313-T07-B 1 1.30E+03
Zn EaFA-L01-1313-T08-B 1 1.30E+03
Zn EaFA-L01-1313-T09-B 1 1 .69E+03
Zn EaFA-L01-1313-T01-C 1 1.71E+02
Zn EaFA-L01-1313-T02-C 1 2.39E+01
Zn EaFA-L01-1313-T03-C 1 2.46E+01
Zn EaFA-L01-1313-T04-C 1 2.25E+01
Zn EaFA-L01-1313-T05-C 1 2.38E+01
Zn EaFA-L01-1313-T06-C 1 3.46E+01
Zn EaFA-L01-1313-T07-C 1 1.13E+03
Zn EaFA-L01-1313-T08-C 1 1.07E+03
Zn EaFA-L01-1313-T09-C 1 1.57E+03
Zn EaFA-L01-1313-B01-A 1 3.23E+00
Zn EaFA-L01-1313-B02-A 1 2.13E+01
Zn EaFA-L01-1313-B03-A 1 3.80E+00
6.71 E+01 3.4E+02 1.0E+00 3.2E+00
4.08E+01 3.7E+01 1.0E+00 3.2E+00
2.03E+01 4.1E+00 1.0E+00 3.2E+00
1.23E+03 8.9E-01 1.0E+00 3.2E+00
1.16E+03 5.6E-01 1.0E+00 3.2E+00
1.63E+03 7.1E-01 1.0E+00 3.2E+00
4.06E+02 2.0E+00 1.0E+00 3.2E+00
3.27E+02 6.0E-01 1.0E+00 3.2E+00
2.27E+02 6.4E-01 1.0E+00 3.2E+00 10 325
6.54E+01 1.7E+00 1.0E+00 3.2E+00
4.12E+01 2.8E+00 1.0E+00 3.2E+00
2.38E+01 2.8E+00 1.0E+00 3.2E+00
1.30E+03 4.5E-02 1.0E+00 3.2E+00
1.30E+03 5.0E-01 1.0E+00 3.2E+00
1.69E+03 6.4E-01 1.0E+00 3.2E+00
1.71E+02 3.3E-01 1.0E+00 3.2E+00
2.39E+01 9.7E+00 1.0E+00 3.2E+00
2.46E+01 5.3E+00 1.0E+00 3.2E+00 10 325
2.25E+01 2.6E+00 1.0E+00 3.2E+00
2.38E+01 5.3E+00 1.0E+00 3.2E+00
3.46E+01 5.0E-01 1.0E+00 3.2E+00
1.13E+03 9.3E-01 1.0E+00 3.2E+00
1.07E+03 1.0E+00 1.0E+00 3.2E+00
1.57E+03 7.1E-01 1.0E+00 3.2E+00
3.23E+00 2.7E+01 1.0E+00 3.2E+00
2.13E+01 1.2E+01 1.0E+00 3.2E+00
3.80E+00 6.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/9/10 10:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:53 AM EPA Interlab L01 1313-1316 EaFA
3.55E+03 109% VU ICP-OES 6/9/10 10:55 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:18 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:20 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:OOAM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:01 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:22 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 2:23 PM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:16AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:18AM EPA Interlab L01 1313-1316 EaFA
3.65E+03 105% VU ICP-OES 6/9/10 11 :19 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:21 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:23AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:24 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:26 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:27 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:29 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:36 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:37 AM EPA Interlab L01 1313-1316 EaFA
3.45E+03 105% VU ICP-OES 6/9/10 1 1:39 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:41 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:42 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:48 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 11:50 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/1011:51 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:46 AM EPA Interlab L01 1313-1316 EaFA
VUICP-OES 6/9/10 10:48 AM EPA Interlab L01 1313-1316 EaFA
VU ICP-OES 6/9/10 10:50 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                            1-32
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al EaFA-L02-1313-T01-A 1
Al EaFA-L02-1313-T02-A 1
Al EaFA-L02-1313-T03-A 1
Al EaFA-L02-1313-T04-A 1
Al EaFA-L02-1313-T05-A 1
Al EaFA-L02-1313-T06-A 1
Al EaFA-L02-1313-T07-A 1
Al EaFA-L02-1313-T08-A 1
Al EaFA-L02-1313-T09-A 1
Al EaFA-L02-1313-T01-B 1
Al EaFA-L02-1313-T02-B 1
Al EaFA-L02-1313-T03-B 1
Al EaFA-L02-1313-T04-B 1
Al EaFA-L02-1313-T05-B 1
Al EaFA-L02-1313-T06-B 1
Al EaFA-L02-1313-T07-B 1
Al EaFA-L02-1313-T08-B 1
Al EaFA-L02-1313-T09-B 1
Al EaFA-L02-1313-T01-C 1
Al EaFA-L02-1313-T02-C 1
Al EaFA-L02-1313-T03-C 1
Al EaFA-L02-1313-T04-C 1
Al EaFA-L02-1313-T05-C 1
Al EaFA-L02-1313-T06-C 1
Al EaFA-L02-1313-T07-C 1
Al EaFA-L02-1313-T08-C 1
Al EaFA-L02-1313-T09-C 1
Al EaFA-L02-1313-B01-A 1
Al EaFA-L02-1313-B02-A 1
Al EaFA-L02-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
3.73E+04
2.94E+04
2.03E+04
4.62E+03
2.70E+02
1.64E+02
1.72E+02
3.06E+04
1.19E+05
3.75E+04
3.10E+04
2.17E+04
4.15E+03
5.02E+02
1.34E+02
5.40E+02
2.92E+04
1.17E+05
3.29E+04
2.90E+04
2.07E+04
4.48E+03
6.31 E+02
1.39E+02
2.14E+02
2.96E+04
1.07E+05
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.73E+04 8.4E-01 1.0E+00 3.2E+00
2.94E+04 4.3E-01 1.0E+00 3.2E+00
2.03E+04 5.7E+00 1.0E+00 3.2E+00 1000 100
4.62E+03 3.4E+00 1.0E+00 3.2E+00
2.70E+02 4.5E+00 1.0E+00 3.2E+00
1.64E+02 3.4E+00 1.0E+00 3.2E+00
1.72E+02 7.5E+00 1.0E+00 3.2E+00
3.06E+04 5.4E-01 1.0E+00 3.2E+00
1.19E+05 8.9E-01 1.0E+00 3.2E+00
3.75E+04 7.3E-01 1.0E+00 3.2E+00
3.10E+04 1.1E+00 1.0E+00 3.2E+00
2.17E+04 5.0E-01 1.0E+00 3.2E+00 1000 100
4.15E+03 8.9E-01 1.0E+00 3.2E+00
5.02E+02 2.5E-01 1.0E+00 3.2E+00
1.34E+02 1.0E+02 1.0E+00 3.2E+00
5.40E+02 4.2E+01 1.0E+00 3.2E+00
2.92E+04 2.6E+00 1.0E+00 3.2E+00
1.17E+05 1.7E-01 1.0E+00 3.2E+00
3.29E+04 8.0E+01 1.0E+00 3.2E+00
2.90E+04 8.1E+01 1.0E+00 3.2E+00
2.07E+04 1.3E+00 1.0E+00 3.2E+00 1000 100
4.48E+03 4.8E-01 1.0E+00 3.2E+00
6.31 E+02 3.9E-01 1.0E+00 3.2E+00
1.39E+02 1.6E+00 1.0E+00 3.2E+00
2.14E+02 8.5E-01 1.0E+00 3.2E+00
2.96E+04 7.2E+00 1.0E+00 3.2E+00
1.07E+05 1.9E+01 1.0E+00 3.2E+00
5.00E-01 7.2E+00 1.0E+00 3.2E+00
5.00E-01 1.1E+01 1.0E+00 3.2E+00
5.00E-01 1.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.12E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.26E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.16E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:OOAMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:08AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:10AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:12AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:13AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:15AMEPAInterlabL02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:33AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:35AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:36AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:38AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:40AMEPAInterlabL02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                                     1-33
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone.
1 1 ug/L
Sb EaFA-L02-1313-T01-A 1 2.12E+02
Sb EaFA-L02-1313-T02-A 1 1.86E+02
Sb EaFA-L02-1313-T03-A 1 1.72E+02
Sb EaFA-L02-1313-T04-A 1 2.26E+02
Sb EaFA-L02-1313-T05-A 1 2.30E+02
Sb EaFA-L02-1313-T06-A 1 1.51E+02
Sb EaFA-L02-1313-T07-A 1 1.74E+02
Sb EaFA-L02-1313-T08-A 1 3.81 E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.12E+02 1.6E+01 7.5E+00 2.4E+01
1.86E+02 1.5E+01 7.5E+00 2.4E+01
1.72E+02 1.5E+01 7.5E+00 2.4E+01 10 325
2.26E+02 1.3E+01 7.5E+00 2.4E+01
2.30E+02 3.6E+00 7.5E+00 2.4E+01
1.51E+02 1.7E+01 7.5E+00 2.4E+01
1.74E+02 7.2E+00 7.5E+00 2.4E+01
3.81 E+01 3.0E+01 7.5E+00 2.4E+01
Sb EaFA-L02-1313-T09-A 1 3.75E+00 U1/2 3.75E+00 3.7E+01 7.5E+00 2.4E+01
Sb EaFA-L02-1313-T01-B 1 2.27E+02
Sb EaFA-L02-1313-T02-B 1 2.02E+02
Sb EaFA-L02-1313-T03-B 1 1.95E+02
Sb EaFA-L02-1313-T04-B 1 1.99E+02
Sb EaFA-L02-1313-T05-B 1 2.03E+02
Sb EaFA-L02-1313-T06-B 1 1.95E+02
Sb EaFA-L02-1313-T07-B 1 1.20E+02
Sb EaFA-L02-1313-T08-B 1 2.96E+01
2.27E+02 2.2E+00 7.5E+00 2.4E+01
2.02E+02 7.4E+00 7.5E+00 2.4E+01
1.95E+02 6.4E+00 7.5E+00 2.4E+01 10 325
1.99E+02 2.0E+01 7.5E+00 2.4E+01
2.03E+02 5.6E+00 7.5E+00 2.4E+01
1.95E+02 8.6E+01 7.5E+00 2.4E+01
1.20E+02 1.0E+02 7.5E+00 2.4E+01
2.96E+01 3.5E+01 7.5E+00 2.4E+01
Sb EaFA-L02-1313-T09-B 1 3.75E+00 U1/2 3.75E+00 3.0E+01 7.5E+00 2.4E+01
Sb EaFA-L02-1313-T01-C 1 1.90E+02
Sb EaFA-L02-1313-T02-C 1 1.81E+02
Sb EaFA-L02-1313-T03-C 1 2.02E+02
Sb EaFA-L02-1313-T04-C 1 1.75E+02
Sb EaFA-L02-1313-T05-C 1 2.06E+02
Sb EaFA-L02-1313-T06-C 1 1.82E+02
Sb EaFA-L02-1313-T07-C 1 1.61E+02
Sb EaFA-L02-1313-T08-C 1 3.73E+01
1.90E+02 9.9E+01 7.5E+00 2.4E+01
1.81E+02 1.4E+02 7.5E+00 2.4E+01
2.02E+02 4.8E+00 7.5E+00 2.4E+01 10 325
1.75E+02 1.6E+01 7.5E+00 2.4E+01
2.06E+02 5.4E+00 7.5E+00 2.4E+01
1.82E+02 1.6E+01 7.5E+00 2.4E+01
1.61E+02 1.6E+01 7.5E+00 2.4E+01
3.73E+01 9.8E+00 7.5E+00 2.4E+01
Sb EaFA-L02-1313-T09-C 1 3.75E+00 U1/2 3.75E+00 8.7E+01 7.5E+00 2.4E+01
Sb EaFA-L02-1313-B01-A 1 1.80E+01 E 1.80E+01 1.1E+02 7.5E+00 2.4E+01
Sb EaFA-L02-1313-B02-A 1 3.75E+00 U1/2 3.75E+00 3.8E+02 7.5E+00 2.4E+01
Sb EaFA-L02-1313-B03-A 1 1.96E+01 E 1.96E+01 1.4E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.64E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.65E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.86E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-34
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone.
1 ug/L
As EaFA-L02-1313-T01-A 1 6.39E+03
As EaFA-L02-1313-T02-A 1 1.40E+03
As EaFA-L02-1313-T03-A 1 1.33E+03
As EaFA-L02-1313-T04-A 1 5.97E+02
As EaFA-L02-1313-T05-A 1 1.67E+02
As EaFA-L02-1313-T06-A 1 1.12E+02
As EaFA-L02-1313-T07-A 1 1.45E+02
As EaFA-L02-1313-T08-A 1 1.24E+02
As EaFA-L02-1313-T09-A 1 4.78E+02
As EaFA-L02-1313-T01-B 1 6.32E+03
As EaFA-L02-1313-T02-B 1 1.53E+03
As EaFA-L02-1313-T03-B 1 1.45E+03
As EaFA-L02-1313-T04-B 1 5.55E+02
As EaFA-L02-1313-T05-B 1 1.86E+02
As EaFA-L02-1313-T06-B 1 1.11E+02
As EaFA-L02-1313-T07-B 1 1.29E+02
As EaFA-L02-1313-T08-B 1 9.01 E+01
As EaFA-L02-1313-T09-B 1 4.62E+02
As EaFA-L02-1313-T01-C 1 6.19E+03
As EaFA-L02-1313-T02-C 1 1 .38E+03
As EaFA-L02-1313-T03-C 1 1 .38E+03
As EaFA-L02-1313-T04-C 1 5.86E+02
As EaFA-L02-1313-T05-C 1 2.30E+02
As EaFA-L02-1313-T06-C 1 9.02E+01
As EaFA-L02-1313-T07-C 1 1.21E+02
As EaFA-L02-1313-T08-C 1 1 .25E+02
As EaFA-L02-1313-T09-C 1 4.78E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.39E+03 1.4E+00 1.1 E+01 3.5E+01
1.40E+03 1.6E+00 1.1 E+01 3.5E+01
1.33E+03 6.6E+00 1.1 E+01 3.5E+01 10 325
5.97E+02 7.9E-01 1.1 E+01 3.5E+01
1.67E+02 1.5E+01 1.1 E+01 3.5E+01
1.12E+02 1.7E+01 1.1E+01 3.5E+01
1.45E+02 5.0E+00 1.1 E+01 3.5E+01
1.24E+02 1.3E+01 1.1 E+01 3.5E+01
4.78E+02 1.5E+00 1.1 E+01 3.5E+01
6.32E+03 1.5E-01 1.1 E+01 3.5E+01
1.53E+03 3.2E+00 1.1 E+01 3.5E+01
1.45E+03 2.5E+00 1.1 E+01 3.5E+01 10 325
5.55E+02 3.4E+00 1.1 E+01 3.5E+01
1.86E+02 1.2E+01 1.1 E+01 3.5E+01
1.11E+02 1.3E+02 1.1 E+01 3.5E+01
1.29E+02 7.8E+01 1.1 E+01 3.5E+01
9.01E+01 7.5E+00 1.1E+01 3.5E+01
4.62E+02 2.8E-01 1.1E+01 3.5E+01
6.19E+03 8.4E+01 1.1E+01 3.5E+01
1.38E+03 9.3E+01 1.1E+01 3.5E+01
1.38E+03 1.8E+00 1.1E+01 3.5E+01 10 325
5.86E+02 4.3E+00 1.1E+01 3.5E+01
2.30E+02 1.3E+01 1.1E+01 3.5E+01
9.02E+01 2.4E+01 1.1E+01 3.5E+01
1.21E+02 9.3E+00 1.1E+01 3.5E+01
1.25E+02 1.7E+01 1.1E+01 3.5E+01
4.78E+02 1.1E+01 1.1E+01 3.5E+01
As EaFA-L02-1313-B01-A 1 1 .93E+01 E 1 .93E+01 2.9E+01 1.1E+01 3.5E+01
As EaFA-L02-1313-B02-A 1 5.50E+00 U1/2 5.50E+00 1.3E+03 1.1E+01 3.5E+01
As EaFA-L02-1313-B03-A 1 1.64E+01 E 1.64E+01 5.4E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.74E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.72E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.01E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-35
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone.
B EaFA-L02-1313-T01-A 1 3.03E+03
B EaFA-L02-1313-T02-A 1 3.66E+03
B EaFA-L02-1313-T03-A 1 3.53E+03
B EaFA-L02-1313-T04-A 1 3.94E+03
B EaFA-L02-1313-T05-A 1 4.26E+03
B EaFA-L02-1313-T06-A 1 4.27E+03
B EaFA-L02-1313-T07-A 1 4.46E+03
B EaFA-L02-1313-T08-A 1 3.74E+03
B EaFA-L02-1313-T09-A 1 2.98E+03
B EaFA-L02-1313-T01-B 1 3.03E+03
B EaFA-L02-1313-T02-B 1 3.59E+03
B EaFA-L02-1313-T03-B 1 3.75E+03
B EaFA-L02-1313-T04-B 1 4.02E+03
B EaFA-L02-1313-T05-B 1 4.21 E+03
B EaFA-L02-1313-T06-B 1 4.24E+03
B EaFA-L02-1313-T07-B 1 4.18E+03
B EaFA-L02-1313-T08-B 1 3.63E+03
B EaFA-L02-1313-T09-B 1 2.98E+03
B EaFA-L02-1313-T01-C 1 2.72E+03
B EaFA-L02-1313-T02-C 1 3.54E+03
B EaFA-L02-1313-T03-C 1 3.62E+03
B EaFA-L02-1313-T04-C 1 4.00E+03
B EaFA-L02-1313-T05-C 1 4.31E+03
B EaFA-L02-1313-T06-C 1 4.57E+03
B EaFA-L02-1313-T07-C 1 4.75E+03
B EaFA-L02-1313-T08-C 1 3.66E+03
B EaFA-L02-1313-T09-C 1 2.67E+03
B EaFA-L02-1313-B01-A 1 7.66E+01
B EaFA-L02-1313-B02-A 1 6.34E+01
B EaFA-L02-1313-B03-A 1 6.26E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.03E+03 1.6E+00 1.0E+00 3.2E+00
3.66E+03 7.3E-01 1.0E+00 3.2E+00
3.53E+03 7.9E+00 1.0E+00 3.2E+00 1000 100
3.94E+03 2.0E+00 1.0E+00 3.2E+00
4.26E+03 2.7E-01 1.0E+00 3.2E+00
4.27E+03 1.9E+00 1.0E+00 3.2E+00
4.46E+03 6.5E+00 1.0E+00 3.2E+00
3.74E+03 6.8E-01 1.0E+00 3.2E+00
2.98E+03 3.2E-01 1.0E+00 3.2E+00
3.03E+03 1.1E+00 1.0E+00 3.2E+00
3.59E+03 1.3E+00 1.0E+00 3.2E+00
3.75E+03 1.9E+00 1.0E+00 3.2E+00 1000 100
4.02E+03 1.2E+00 1.0E+00 3.2E+00
4.21E+03 6.9E-01 1.0E+00 3.2E+00
4.24E+03 7.0E+01 1.0E+00 3.2E+00
4.18E+03 6.6E+01 1.0E+00 3.2E+00
3.63E+03 2.4E+00 1.0E+00 3.2E+00
2.98E+03 9.0E-01 1.0E+00 3.2E+00
2.72E+03 7.6E+01 1.0E+00 3.2E+00
3.54E+03 8.5E+01 1.0E+00 3.2E+00
3.62E+03 9.1E-01 1.0E+00 3.2E+00 1000 100
4.00E+03 1.6E+00 1.0E+00 3.2E+00
4.31 E+03 5.4E-01 1.0E+00 3.2E+00
4.57E+03 1.7E+00 1.0E+00 3.2E+00
4.75E+03 1.1E+00 1.0E+00 3.2E+00
3.66E+03 4.4E+00 1.0E+00 3.2E+00
2.67E+03 1.8E+01 1.0E+00 3.2E+00
7.66E+01 2.2E+00 1.0E+00 3.2E+00
6.34E+01 1.4E+00 1.0E+00 3.2E+00
6.26E+01 3.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.54E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.71 E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.71E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-36
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFA-L02-1313-T01-A 1
Ba EaFA-L02-1313-T02-A 1
Ba EaFA-L02-1313-T03-A 1
Ba EaFA-L02-1313-T04-A 1
Ba EaFA-L02-1313-T05-A 1
Ba EaFA-L02-1313-T06-A 1
Ba EaFA-L02-1313-T07-A 1
Ba EaFA-L02-1313-T08-A 1
Ba EaFA-L02-1313-T09-A 1
Ba EaFA-L02-1313-T01-B 1
Ba EaFA-L02-1313-T02-B 1
Ba EaFA-L02-1313-T03-B 1
Ba EaFA-L02-1313-T04-B 1
Ba EaFA-L02-1313-T05-B 1
Ba EaFA-L02-1313-T06-B 1
Ba EaFA-L02-1313-T07-B 1
Ba EaFA-L02-1313-T08-B 1
Ba EaFA-L02-1313-T09-B 1
Ba EaFA-L02-1313-T01-C 1
Ba EaFA-L02-1313-T02-C 1
Ba EaFA-L02-1313-T03-C 1
Ba EaFA-L02-1313-T04-C 1
Ba EaFA-L02-1313-T05-C 1
Ba EaFA-L02-1313-T06-C 1
Ba EaFA-L02-1313-T07-C 1
Ba EaFA-L02-1313-T08-C 1
Ba EaFA-L02-1313-T09-C 1
Ba EaFA-L02-1313-B01-A 1
Ba EaFA-L02-1313-B02-A 1
Ba EaFA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.32E+03
1.19E+03
1.42E+03
3.97E+02
2.67E+02
2.80E+02
2.77E+02
2.86E+02
8.47E+02
2.36E+03
1.06E+03
1.60E+03
3.97E+02
2.71E+02
2.58E+02
2.69E+02
3.15E+02
8.57E+02
2.08E+03
1 J7E+03
5.54E+02
4.08E+02
2.73E+02
2.93E+02
3.06E+02
2.73E+02
8.20E+02
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.32E+03 6.6E-01 1.0E+00 3.2E+00
1.19E+03 5.0E-01 1.0E+00 3.2E+00
1.42E+03 6.5E+00 1.0E+00 3.2E+00 10 325
3.97E+02 3.1E+00 1.0E+00 3.2E+00
2.67E+02 4.8E-01 1.0E+00 3.2E+00
2.80E+02 1.1E+00 1.0E+00 3.2E+00
2.77E+02 6.7E+00 1.0E+00 3.2E+00
2.86E+02 1.4E-01 1.0E+00 3.2E+00
8.47E+02 6.9E-01 1.0E+00 3.2E+00
2.36E+03 6.7E-01 1.0E+00 3.2E+00
1.06E+03 1.4E+00 1.0E+00 3.2E+00
1.60E+03 5.5E-01 1.0E+00 3.2E+00 10 325
3.97E+02 3.9E-01 1.0E+00 3.2E+00
2.71E+02 2.2E-01 1.0E+00 3.2E+00
2.58E+02 7.7E+01 1.0E+00 3.2E+00
2.69E+02 5.4E+01 1.0E+00 3.2E+00
3.15E+02 2.6E+00 1 .OE+00 3.2E+00
8.57E+02 1.9E-01 1 .OE+00 3.2E+00
2.08E+03 8.0E+01 1 .OE+00 3.2E+00
1.77E+03 9.0E+01 1 .OE+00 3.2E+00
5.54E+02 2.5E+00 1 .OE+00 3.2E+00 10 325
4.08E+02 3.1E-01 1 .OE+00 3.2E+00
2.73E+02 1.3E-01 1 .OE+00 3.2E+00
2.93E+02 5.0E-01 1 .OE+00 3.2E+00
3.06E+02 2.9E-01 1 .OE+00 3.2E+00
2.73E+02 5.1E+00 1 .OE+00 3.2E+00
8.20E+02 1.2E+01 1 .OE+00 3.2E+00
5.00E-01 2.1E+01 1. OE+00 3.2E+00
5.00E-01 7.7E+01 1. OE+00 3.2E+00
5.00E-01 5.7E+00 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.45E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.50E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.82E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-37
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L02-1313-T01-A 1
Be EaFA-L02-1313-T02-A 1
Be EaFA-L02-1313-T03-A 1
Be EaFA-L02-1313-T04-A 1
Be EaFA-L02-1313-T05-A 1
Be EaFA-L02-1313-T06-A 1
Be EaFA-L02-1313-T07-A 1
Be EaFA-L02-1313-T08-A 1
Be EaFA-L02-1313-T09-A 1
Be EaFA-L02-1313-T01-B 1
Be EaFA-L02-1313-T02-B 1
Be EaFA-L02-1313-T03-B 1
Be EaFA-L02-1313-T04-B 1
Be EaFA-L02-1313-T05-B 1
Be EaFA-L02-1313-T06-B 1
Be EaFA-L02-1313-T07-B 1
Be EaFA-L02-1313-T08-B 1
Be EaFA-L02-1313-T09-B 1
Be EaFA-L02-1313-T01-C 1
Be EaFA-L02-1313-T02-C 1
Be EaFA-L02-1313-T03-C 1
Be EaFA-L02-1313-T04-C 1
Be EaFA-L02-1313-T05-C 1
Be EaFA-L02-1313-T06-C 1
Be EaFA-L02-1313-T07-C 1
Be EaFA-L02-1313-T08-C 1
Be EaFA-L02-1313-T09-C 1
Be EaFA-L02-1313-B01-A 1
Be EaFA-L02-1313-B02-A 1
Be EaFA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
2.42E+00 E
1.29E+02
2.56E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
4.33E+00 E
1.27E+02
2.56E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
2.60E+00 E
1.25E+02
2.45E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 6.2E+01 1.9E+00 6.0E+00
9.50E-01 7.9E+02 1.9E+00 6.0E+00 10 325
9.50E-01 5.6E+02 1.9E+00 6.0E+00
9.50E-01 6.3E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
2.42E+00 1.7E+01 1.9E+00 6.0E+00
1.29E+02 5.4E-01 1.9E+00 6.0E+00
2.56E+02 3.4E-01 1.9E+00 6.0E+00
9.50E-01 9.2E+01 1.9E+00 6.0E+00
9.50E-01 9.8E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00 10 325
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.50E-01 3.9E+02 1.9E+00 6.0E+00
9.50E-01 7.6E+02 1.9E+00 6.0E+00
4.33E+00 6.7E+01 1.9E+00 6.0E+00
1.27E+02 2.6E+00 1.9E+00 6.0E+00
2.56E+02 1.7E-01 1.9E+00 6.0E+00
9.50E-01 2.6E+02 1.9E+00 6.0E+00
9.50E-01 3.4E+02 1.9E+00 6.0E+00
9.50E-01 3.7E+02 1.9E+00 6.0E+00 10 325
9.50E-01 3.4E+02 1.9E+00 6.0E+00
9.50E-01 5.0E+02 1.9E+00 6.0E+00
9.50E-01 3.7E+02 1.9E+00 6.0E+00
2.60E+00 6.3E+00 1.9E+00 6.0E+00
1.25E+02 5.6E+00 1.9E+00 6.0E+00
2.45E+02 6.0E+00 1.9E+00 6.0E+00
9.50E-01 6.1E+02 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.40E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.38E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.59E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:1 0AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:1 2 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:35AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:36AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:38AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:40AMEPAInterlabL02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-38
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-L02-1313-T01-A 1
Cd EaFA-L02-1313-T02-A 1
Cd EaFA-L02-1313-T03-A 1
Cd EaFA-L02-1313-T04-A 1
Cd EaFA-L02-1313-T05-A 1
Cd EaFA-L02-1313-T06-A 1
Cd EaFA-L02-1313-T07-A 1
Cd EaFA-L02-1313-T08-A 1
Cd EaFA-L02-1313-T09-A 1
Cd EaFA-L02-1313-T01-B 1
Cd EaFA-L02-1313-T02-B 1
Cd EaFA-L02-1313-T03-B 1
Cd EaFA-L02-1313-T04-B 1
Cd EaFA-L02-1313-T05-B 1
Cd EaFA-L02-1313-T06-B 1
Cd EaFA-L02-1313-T07-B 1
Cd EaFA-L02-1313-T08-B 1
Cd EaFA-L02-1313-T09-B 1
Cd EaFA-L02-1313-T01-C 1
Cd EaFA-L02-1313-T02-C 1
Cd EaFA-L02-1313-T03-C 1
Cd EaFA-L02-1313-T04-C 1
Cd EaFA-L02-1313-T05-C 1
Cd EaFA-L02-1313-T06-C 1
Cd EaFA-L02-1313-T07-C 1
Cd EaFA-L02-1313-T08-C 1
Cd EaFA-L02-1313-T09-C 1
Cd EaFA-L02-1313-B01-A 1
Cd EaFA-L02-1313-B02-A 1
Cd EaFA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
2.37E+01
3.19E+01
3.08E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.91E+01
3.11E+01
3.15E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
2.53E+01
3.09E+01
2.94E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 6.7E+01 2.2E+00 7.0E+00
1.10E+00 3.7E+01 2.2E+00 7.0E+00
1.10E+00 4.6E+01 2.2E+00 7.0E+00 10 325
1.10E+00 1.9E+01 2.2E+00 7.0E+00
1.10E+00 3.7E+01 2.2E+00 7.0E+00
1.10E+00 1.0E+02 2.2E+00 7.0E+00
2.37E+01 6.2E+00 2.2E+00 7.0E+00
3.19E+01 1.5E+00 2.2E+00 7.0E+00
3.08E+01 1.1E+00 2.2E+00 7.0E+00
1.10E+00 3.2E+01 2.2E+00 7.0E+00
1.10E+00 7.3E+01 2.2E+00 7.0E+00
1.10E+00 2.8E+01 2.2E+00 7.0E+00 10 325
1.10E+00 2.7E+01 2.2E+00 7.0E+00
1.10E+00 1.0E+01 2.2E+00 7.0E+00
1.10E+00 9.1E+01 2.2E+00 7.0E+00
1.91E+01 6.5E+01 2.2E+00 7.0E+00
3.11E+01 3.4E+00 2.2E+00 7.0E+00
3.15E+01 3.8E-01 2.2E+00 7.0E+00
1.10E+00 6.9E+01 2.2E+00 7.0E+00
1.10E+00 7.5E+00 2.2E+00 7.0E+00
1.10E+00 1.6E+01 2.2E+00 7.0E+00 10 325
1.10E+00 9.5E+01 2.2E+00 7.0E+00
1.10E+00 9.9E+01 2.2E+00 7.0E+00
1.10E+00 9.6E+01 2.2E+00 7.0E+00
2.53E+01 5.2E+00 2.2E+00 7.0E+00
3.09E+01 6.2E+00 2.2E+00 7.0E+00
2.94E+01 9.8E+00 2.2E+00 7.0E+00
1.10E+00 1.8E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+01 2.2E+00 7.0E+00
1.10E+00 9.6E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.48E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.49E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.66E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-39
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
1 1 ug/L
Ca EaFA-L02-1313-T01-A 1 1.79E+04
Ca EaFA-L02-1313-T02-A 1 4.85E+04
Ca EaFA-L02-1313-T03-A 1 7.67E+04
Ca EaFA-L02-1313-T04-A 1 1.32E+05
Ca EaFA-L02-1313-T05-A 1 1.54E+05
Ca EaFA-L02-1313-T06-A 1 1.61E+05
Ca EaFA-L02-1313-T07-A 1 1.70E+05
Ca EaFA-L02-1313-T08-A 1 1.53E+05
Ca EaFA-L02-1313-T09-A 1 1.41E+05
Ca EaFA-L02-1313-T01-B 1 1.83E+04
Ca EaFA-L02-1313-T02-B 1 4.77E+04
Ca EaFA-L02-1313-T03-B 1 8.08E+04
Ca EaFA-L02-1313-T04-B 1 1.33E+05
Ca EaFA-L02-1313-T05-B 1 1.52E+05
Ca EaFA-L02-1313-T06-B 1 1.52E+05
Ca EaFA-L02-1313-T07-B 1 1.51E+05
Ca EaFA-L02-1313-T08-B 1 1.50E+05
Ca EaFA-L02-1313-T09-B 1 1.41E+05
Ca EaFA-L02-1313-T01-C 1 1.70E+04
Ca EaFA-L02-1313-T02-C 1 4.77E+04
Ca EaFA-L02-1313-T03-C 1 7.74E+04
Ca EaFA-L02-1313-T04-C 1 1.29E+05
Ca EaFA-L02-1313-T05-C 1 1.52E+05
Ca EaFA-L02-1313-T06-C 1 1.68E+05
Ca EaFA-L02-1313-T07-C 1 1.73E+05
Ca EaFA-L02-1313-T08-C 1 1.46E+05
Ca EaFA-L02-1313-T09-C 1 1.30E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.79E+04 4.5E-01 2.6E+00 8.3E+00
4.85E+04 5.2E-01 2.6E+00 8.3E+00
7.67E+04 5.5E+00 2.6E+00 8.3E+00 1000 100
1.32E+05 3.4E+00 2.6E+00 8.3E+00
1.54E+05 5.4E-01 2.6E+00 8.3E+00
1.61E+05 1.4E+00 2.6E+00 8.3E+00
1.70E+05 6.3E+00 2.6E+00 8.3E+00
1.53E+05 2.7E-01 2.6E+00 8.3E+00
1.41E+05 1.5E-01 2.6E+00 8.3E+00
1.83E+04 7.3E-01 2.6E+00 8.3E+00
4.77E+04 9.9E-01 2.6E+00 8.3E+00
8.08E+04 1.5E+00 2.6E+00 8.3E+00 1000 100
1.33E+05 4.7E-01 2.6E+00 8.3E+00
1.52E+05 5.9E-01 2.6E+00 8.3E+00
1.52E+05 7.8E+01 2.6E+00 8.3E+00
1.51E+05 4.6E+01 2.6E+00 8.3E+00
1.50E+05 2.2E+00 2.6E+00 8.3E+00
1.41E+05 6.2E-01 2.6E+00 8.3E+00
1.70E+04 8.1E+01 2.6E+00 8.3E+00
4.77E+04 8.9E+01 2.6E+00 8.3E+00
7.74E+04 1.9E+00 2.6E+00 8.3E+00 1000 100
1.29E+05 2.8E-01 2.6E+00 8.3E+00
1.52E+05 3.5E-01 2.6E+00 8.3E+00
1.68E+05 2.0E-01 2.6E+00 8.3E+00
1.73E+05 2.4E-01 2.6E+00 8.3E+00
1.46E+05 6.3E+00 2.6E+00 8.3E+00
1.30E+05 1.1E+01 2.6E+00 8.3E+00
Ca EaFA-L02-1313-B01-A 1 1.30E+OOU1/2 1.30E+00 3.7E+02 2.6E+00 8.3E+00
Ca EaFA-L02-1313-B02-A 1 6.39E+00 E 6.39E+00 2.0E+02 2.6E+00 8.3E+00
Ca EaFA-L02-1313-B03-A 1 1.30E+OOU1/2 1.30E+00 3.3E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.76E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.16E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.83E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:OOAMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:08AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:10AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:12AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:13AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:15AMEPAInterlabL02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:33AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:35AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:36AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:38AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:40AMEPAInterlabL02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-40
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr EaFA-L02-1313-T01-A 1
Cr EaFA-L02-1313-T02-A 1
Cr EaFA-L02-1313-T03-A 1
Cr EaFA-L02-1313-T04-A 1
Cr EaFA-L02-1313-T05-A 1
Cr EaFA-L02-1313-T06-A 1
Cr EaFA-L02-1313-T07-A 1
Cr EaFA-L02-1313-T08-A 1
Cr EaFA-L02-1313-T09-A 1
Cr EaFA-L02-1313-T01-B 1
Cr EaFA-L02-1313-T02-B 1
Cr EaFA-L02-1313-T03-B 1
Cr EaFA-L02-1313-T04-B 1
Cr EaFA-L02-1313-T05-B 1
Cr EaFA-L02-1313-T06-B 1
Cr EaFA-L02-1313-T07-B 1
Cr EaFA-L02-1313-T08-B 1
Cr EaFA-L02-1313-T09-B 1
Cr EaFA-L02-1313-T01-C 1
Cr EaFA-L02-1313-T02-C 1
Cr EaFA-L02-1313-T03-C 1
Cr EaFA-L02-1313-T04-C 1
Cr EaFA-L02-1313-T05-C 1
Cr EaFA-L02-1313-T06-C 1
Cr EaFA-L02-1313-T07-C 1
Cr EaFA-L02-1313-T08-C 1
Cr EaFA-L02-1313-T09-C 1
Cr EaFA-L02-1313-B01-A 1
Cr EaFA-L02-1313-B02-A 1
Cr EaFA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
5.93E+02
4.51 E+02
3.70E+02
2.56E+02
6.59E+01
2.12E+01
2.57E+00 E
1.82E+02
1.80E+03
5.98E+02
4.84E+02
4.16E+02
2.40E+02
6.13E+01
1.52E+01
1.50E+00 E
1.68E+02
1.80E+03
5.28E+02
4.34E+02
4.26E+02
2.32E+02
6.40E+01
1.70E+01
3.14E+00 E
1.84E+02
1.67E+03
6.00E-01 U1/2
6.00E-01 U1/2
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.93E+02 6.9E-01 1.2E+00 3.8E+00
4.51 E+02 3.8E-01 1.2E+00 3.8E+00
3.70E+02 7.3E+00 1.2E+00 3.8E+00 10 325
2.56E+02 2.8E+00 1.2E+00 3.8E+00
6.59E+01 4.6E+00 1.2E+00 3.8E+00
2.12E+01 9.9E+00 1.2E+00 3.8E+00
2.57E+00 9.5E+01 1.2E+00 3.8E+00
1.82E+02 6.4E-01 1.2E+00 3.8E+00
1.80E+03 8.3E-01 1.2E+00 3.8E+00
5.98E+02 7.9E-01 1.2E+00 3.8E+00
4.84E+02 7.7E-01 1.2E+00 3.8E+00
4.16E+02 2.8E-01 1.2E+00 3.8E+00 10 325
2.40E+02 6.5E-01 1.2E+00 3.8E+00
6.13E+01 1.3E+00 1.2E+00 3.8E+00
1.52E+01 9.0E+01 1.2E+00 3.8E+00
1.50E+00 8.9E+01 1.2E+00 3.8E+00
1.68E+02 3.0E+00 1.2E+00 3.8E+00
1.80E+03 1.0E+00 1.2E+00 3.8E+00
5.28E+02 7.8E+01 1.2E+00 3.8E+00
4.34E+02 8.8E+01 1.2E+00 3.8E+00
4.26E+02 1.9E+00 1.2E+00 3.8E+00 10 325
2.32E+02 6.9E-01 1.2E+00 3.8E+00
6.40E+01 5.0E+00 1.2E+00 3.8E+00
1.70E+01 4.3E+00 1.2E+00 3.8E+00
3.14E+00 1.6E+01 1.2E+00 3.8E+00
1.84E+02 5.3E+00 1.2E+00 3.8E+00
1.67E+03 1.1E+01 1.2E+00 3.8E+00
6.00E-01 1.8E+02 1.2E+00 3.8E+00
6.00E-01 2.8E+03 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.64E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.67E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.88E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:OOAMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:08AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:10AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:12AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:13AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:15AMEPAInterlabL02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:33AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:35AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:36AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:38AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:40AMEPAInterlabL02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-41
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-L02-1313-T01-A 1
Co EaFA-L02-1313-T02-A 1
Co EaFA-L02-1313-T03-A 1
Co EaFA-L02-1313-T04-A 1
Co EaFA-L02-1313-T05-A 1
Co EaFA-L02-1313-T06-A 1
Co EaFA-L02-1313-T07-A 1
Co EaFA-L02-1313-T08-A 1
Co EaFA-L02-1313-T09-A 1
Co EaFA-L02-1313-T01-B 1
Co EaFA-L02-1313-T02-B 1
Co EaFA-L02-1313-T03-B 1
Co EaFA-L02-1313-T04-B 1
Co EaFA-L02-1313-T05-B 1
Co EaFA-L02-1313-T06-B 1
Co EaFA-L02-1313-T07-B 1
Co EaFA-L02-1313-T08-B 1
Co EaFA-L02-1313-T09-B 1
Co EaFA-L02-1313-T01-C 1
Co EaFA-L02-1313-T02-C 1
Co EaFA-L02-1313-T03-C 1
Co EaFA-L02-1313-T04-C 1
Co EaFA-L02-1313-T05-C 1
Co EaFA-L02-1313-T06-C 1
Co EaFA-L02-1313-T07-C 1
Co EaFA-L02-1313-T08-C 1
Co EaFA-L02-1313-T09-C 1
Co EaFA-L02-1313-B01-A 1
Co EaFA-L02-1313-B02-A 1
Co EaFA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
5.10E+00 E
4.43E+01
2.09E+02
2.15E+02
4.04E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
1.02E+01
5.94E+01
2.05E+02
2.11E+02
4.01 E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
3.83E+00 E
6.09E+01
2.23E+02
2.04E+02
3.76E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 5.0E+01 1.8E+00 5.7E+00
9.00E-01 2.8E+01 1.8E+00 5.7E+00
9.00E-01 2.4E+01 1.8E+00 5.7E+00 10 325
9.00E-01 8.9E+01 1.8E+00 5.7E+00
5.10E+00 2.9E+01 1.8E+00 5.7E+00
4.43E+01 3.4E+00 1.8E+00 5.7E+00
2.09E+02 7.0E+00 1.8E+00 5.7E+00
2.15E+02 1.2E+00 1.8E+00 5.7E+00
4.04E+02 4.9E-01 1.8E+00 5.7E+00
9.00E-01 6.9E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+01 1.8E+00 5.7E+00
9.00E-01 5.1E+01 1.8E+00 5.7E+00 10 325
9.00E-01 6.1E+01 1.8E+00 5.7E+00
1.02E+01 5.0E+01 1.8E+00 5.7E+00
5.94E+01 9.7E+01 1.8E+00 5.7E+00
2.05E+02 5.9E+01 1.8E+00 5.7E+00
2.11E+02 2.7E+00 1.8E+00 5.7E+00
4.01 E+02 5.1E-01 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 3.3E+01 1.8E+00 5.7E+00
9.00E-01 2.8E+01 1.8E+00 5.7E+00 10 325
9.00E-01 1.3E+02 1.8E+00 5.7E+00
3.83E+00 2.8E+01 1.8E+00 5.7E+00
6.09E+01 1.9E+00 1.8E+00 5.7E+00
2.23E+02 9.3E-01 1.8E+00 5.7E+00
2.04E+02 4.3E+00 1.8E+00 5.7E+00
3.76E+02 1.1E+01 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 8.3E+01 1.8E+00 5.7E+00
9.00E-01 2.1 E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.34E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.38E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.50E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-42
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFA-L02-1313-T01-A 1
Cu EaFA-L02-1313-T02-A 1
Cu EaFA-L02-1313-T03-A 1
Cu EaFA-L02-1313-T04-A 1
Cu EaFA-L02-1313-T05-A 1
Cu EaFA-L02-1313-T06-A 1
Cu EaFA-L02-1313-T07-A 1
Cu EaFA-L02-1313-T08-A 1
Cu EaFA-L02-1313-T09-A 1
Cu EaFA-L02-1313-T01-B 1
Cu EaFA-L02-1313-T02-B 1
Cu EaFA-L02-1313-T03-B 1
Cu EaFA-L02-1313-T04-B 1
Cu EaFA-L02-1313-T05-B 1
Cu EaFA-L02-1313-T06-B 1
Cu EaFA-L02-1313-T07-B 1
Cu EaFA-L02-1313-T08-B 1
Cu EaFA-L02-1313-T09-B 1
Cu EaFA-L02-1313-T01-C 1
Cu EaFA-L02-1313-T02-C 1
Cu EaFA-L02-1313-T03-C 1
Cu EaFA-L02-1313-T04-C 1
Cu EaFA-L02-1313-T05-C 1
Cu EaFA-L02-1313-T06-C 1
Cu EaFA-L02-1313-T07-C 1
Cu EaFA-L02-1313-T08-C 1
Cu EaFA-L02-1313-T09-C 1
Cu EaFA-L02-1313-B01-A 1
Cu EaFA-L02-1313-B02-A 1
Cu EaFA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.85E+00 U1/2
1.85E+00 U1/2
5.53E+00 E
5.14E+00 E
4.26E+00 E
1.85E+00 U1/2
4.48E+01
2.03E+03
2.98E+03
1.42E+01
7.80E+00 E
1.85E+00 U1/2
6.65E+00 E
1.02E+01 E
8.46E+00 E
1.18E+02
1.99E+03
3.00E+03
1.66E+01
1.02E+01 E
5.80E+00 E
1.85E+00 U1/2
4.40E+00 E
1.85E+00 U1/2
5.02E+01
1.99E+03
3.00E+03
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 3.6E+01 3.7E+00 1.2E+01
1.85E+00 1.6E+02 3.7E+00 1.2E+01
5.53E+00 1.5E+02 3.7E+00 1.2E+01 10 325
5.14E+00 1.6E+02 3.7E+00 1.2E+01
4.26E+00 3.3E+01 3.7E+00 1.2E+01
1.85E+00 7.7E+01 3.7E+00 1.2E+01
4.48E+01 7.1E+00 3.7E+00 1.2E+01
2.03E+03 5.2E-01 3.7E+00 1.2E+01
2.98E+03 7.5E-01 3.7E+00 1.2E+01
1.42E+01 1.5E+01 3.7E+00 1.2E+01
7.80E+00 5.9E+01 3.7E+00 1.2E+01
1.85E+00 6.4E+04 3.7E+00 1.2E+01 10 325
6.65E+00 5.2E+01 3.7E+00 1.2E+01
1.02E+01 6.7E+01 3.7E+00 1.2E+01
8.46E+00 1.5E+02 3.7E+00 1.2E+01
1.18E+02 3.5E+01 3.7E+00 1.2E+01
1.99E+03 2.1E+00 3.7E+00 1.2E+01
3.00E+03 3.5E-01 3.7E+00 1.2E+01
1.66E+01 1.6E+02 3.7E+00 1.2E+01
1.02E+01 7.1E+01 3.7E+00 1.2E+01
5.80E+00 1.3E+02 3.7E+00 1.2E+01 10 325
1.85E+00 6.4E+01 3.7E+00 1.2E+01
4.40E+00 1.1E+02 3.7E+00 1.2E+01
1.85E+00 1.1E+02 3.7E+00 1.2E+01
5.02E+01 1.7E+01 3.7E+00 1.2E+01
1.99E+03 7.1E+00 3.7E+00 1.2E+01
3.00E+03 4.8E+00 3.7E+00 1.2E+01
1.85E+00 7.5E+02 3.7E+00 1.2E+01
1.85E+00 1.5E+02 3.7E+00 1.2E+01
1.85E+00 3.2E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.24E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.26E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.42E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-43
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L02-1313-T01-A 1
Fe EaFA-L02-1313-T02-A 1
Fe EaFA-L02-1313-T03-A 1
Fe EaFA-L02-1313-T04-A 1
Fe EaFA-L02-1313-T05-A 1
Fe EaFA-L02-1313-T06-A 1
Fe EaFA-L02-1313-T07-A 1
Fe EaFA-L02-1313-T08-A 1
Fe EaFA-L02-1313-T09-A 1
Fe EaFA-L02-1313-T01-B 1
Fe EaFA-L02-1313-T02-B 1
Fe EaFA-L02-1313-T03-B 1
Fe EaFA-L02-1313-T04-B 1
Fe EaFA-L02-1313-T05-B 1
Fe EaFA-L02-1313-T06-B 1
Fe EaFA-L02-1313-T07-B 1
Fe EaFA-L02-1313-T08-B 1
Fe EaFA-L02-1313-T09-B 1
Fe EaFA-L02-1313-T01-C 1
Fe EaFA-L02-1313-T02-C 1
Fe EaFA-L02-1313-T03-C 1
Fe EaFA-L02-1313-T04-C 1
Fe EaFA-L02-1313-T05-C 1
Fe EaFA-L02-1313-T06-C 1
Fe EaFA-L02-1313-T07-C 1
Fe EaFA-L02-1313-T08-C 1
Fe EaFA-L02-1313-T09-C 1
Fe EaFA-L02-1313-B01-A 1
Fe EaFA-L02-1313-B02-A 1
Fe EaFA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.92E+01
1.37E+01
1.01E+01
5.24E+00 E
1.00E+00 U1/2
9.14E+00
5.24E+00 E
5.64E+02
2.65E+04
1.00E+01
1.31E+01
1.14E+01
1.00E+00 U1/2
1.00E+00 U1/2
2.73E+00 E
2.80E+00 E
5.24E+02
2.60E+04
2.04E+01
2.07E+01
3.79E+00 E
6.79E+00
3.15E+00 E
5.88E+00 E
4.67E+00 E
5.69E+02
2.60E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.92E+01 2.8E+00 2.0E+00 6.4E+00
1.37E+01 3.0E-01 2.0E+00 6.4E+00
1.01E+01 7.6E+00 2.0E+00 6.4E+00 1000 100
5.24E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 6.0E+00 2.0E+00 6.4E+00
9.14E+00 6.6E+00 2.0E+00 6.4E+00
5.24E+00 1.3E+01 2.0E+00 6.4E+00
5.64E+02 3.7E-01 2.0E+00 6.4E+00
2.65E+04 7.7E-01 2.0E+00 6.4E+00
1.00E+01 3.9E+00 2.0E+00 6.4E+00
1.31E+01 1.6E+00 2.0E+00 6.4E+00
1.14E+01 5.2E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
2.73E+00 2.7E+02 2.0E+00 6.4E+00
2.80E+00 1.7E+02 2.0E+00 6.4E+00
5.24E+02 1.9E+00 2.0E+00 6.4E+00
2.60E+04 7.4E-01 2.0E+00 6.4E+00
2.04E+01 1.3E+02 2.0E+00 6.4E+00
2.07E+01 1.4E+02 2.0E+00 6.4E+00
3.79E+00 1.1E+01 2.0E+00 6.4E+00 1000 100
6.79E+00 3.0E+00 2.0E+00 6.4E+00
3.15E+00 1.6E+01 2.0E+00 6.4E+00
5.88E+00 7.9E+00 2.0E+00 6.4E+00
4.67E+00 2.6E+00 2.0E+00 6.4E+00
5.69E+02 7.7E+00 2.0E+00 6.4E+00
2.60E+04 3.6E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 4.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-44
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L02-1313-T01-A 1
Pb EaFA-L02-1313-T02-A 1
Pb EaFA-L02-1313-T03-A 1
Pb EaFA-L02-1313-T04-A 1
Pb EaFA-L02-1313-T05-A 1
Pb EaFA-L02-1313-T06-A 1
Pb EaFA-L02-1313-T07-A 1
Pb EaFA-L02-1313-T08-A 1
Pb EaFA-L02-1313-T09-A 1
Pb EaFA-L02-1313-T01-B 1
Pb EaFA-L02-1313-T02-B 1
Pb EaFA-L02-1313-T03-B 1
Pb EaFA-L02-1313-T04-B 1
Pb EaFA-L02-1313-T05-B 1
Pb EaFA-L02-1313-T06-B 1
Pb EaFA-L02-1313-T07-B 1
Pb EaFA-L02-1313-T08-B 1
Pb EaFA-L02-1313-T09-B 1
Pb EaFA-L02-1313-T01-C 1
Pb EaFA-L02-1313-T02-C 1
Pb EaFA-L02-1313-T03-C 1
Pb EaFA-L02-1313-T04-C 1
Pb EaFA-L02-1313-T05-C 1
Pb EaFA-L02-1313-T06-C 1
Pb EaFA-L02-1313-T07-C 1
Pb EaFA-L02-1313-T08-C 1
Pb EaFA-L02-1313-T09-C 1
Pb EaFA-L02-1313-B01-A 1
Pb EaFA-L02-1313-B02-A 1
Pb EaFA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
5.16E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
5.38E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
5.08E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 1.9E+02 6.8E+00 2.2E+01
3.40E+00 5.0E+01 6.8E+00 2.2E+01
3.40E+00 5.1E+01 6.8E+00 2.2E+01 10 325
3.40E+00 2.6E+01 6.8E+00 2.2E+01
3.40E+00 7.9E+01 6.8E+00 2.2E+01
3.40E+00 4.4E+01 6.8E+00 2.2E+01
3.40E+00 1.0E+02 6.8E+00 2.2E+01
3.40E+00 1.2E+01 6.8E+00 2.2E+01
5.16E+01 1.4E+01 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
3.40E+00 6.4E+01 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01 10 325
3.40E+00 4.5E+01 6.8E+00 2.2E+01
3.40E+00 4.8E+01 6.8E+00 2.2E+01
3.40E+00 4.2E+01 6.8E+00 2.2E+01
3.40E+00 9.2E+01 6.8E+00 2.2E+01
3.40E+00 6.1E+01 6.8E+00 2.2E+01
5.38E+01 9.1E+00 6.8E+00 2.2E+01
3.40E+00 8.3E+01 6.8E+00 2.2E+01
3.40E+00 4.0E+01 6.8E+00 2.2E+01
3.40E+00 5.7E+01 6.8E+00 2.2E+01 10 325
3.40E+00 6.9E+01 6.8E+00 2.2E+01
3.40E+00 1.9E+01 6.8E+00 2.2E+01
3.40E+00 4.4E+01 6.8E+00 2.2E+01
3.40E+00 1.8E+01 6.8E+00 2.2E+01
3.40E+00 5.3E+01 6.8E+00 2.2E+01
5.08E+01 1.5E+01 6.8E+00 2.2E+01
3.40E+00 7.0E+01 6.8E+00 2.2E+01
3.40E+00 8.6E+01 6.8E+00 2.2E+01
3.40E+00 2.5E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.26E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.29E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.40E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:OOAMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:08AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:10AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:12AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:13AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:15AMEPAInterlabL02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-45
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFA-L02-1313-T01-A 1
Li EaFA-L02-1313-T02-A 1
Li EaFA-L02-1313-T03-A 1
Li EaFA-L02-1313-T04-A 1
Li EaFA-L02-1313-T05-A 1
Li EaFA-L02-1313-T06-A 1
Li EaFA-L02-1313-T07-A 1
Li EaFA-L02-1313-T08-A 1
Li EaFA-L02-1313-T09-A 1
Li EaFA-L02-1313-T01-B 1
Li EaFA-L02-1313-T02-B 1
Li EaFA-L02-1313-T03-B 1
Li EaFA-L02-1313-T04-B 1
Li EaFA-L02-1313-T05-B 1
Li EaFA-L02-1313-T06-B 1
Li EaFA-L02-1313-T07-B 1
Li EaFA-L02-1313-T08-B 1
Li EaFA-L02-1313-T09-B 1
Li EaFA-L02-1313-T01-C 1
Li EaFA-L02-1313-T02-C 1
Li EaFA-L02-1313-T03-C 1
Li EaFA-L02-1313-T04-C 1
Li EaFA-L02-1313-T05-C 1
Li EaFA-L02-1313-T06-C 1
Li EaFA-L02-1313-T07-C 1
Li EaFA-L02-1313-T08-C 1
Li EaFA-L02-1313-T09-C 1
Li EaFA-L02-1313-B01-A 1
Li EaFA-L02-1313-B02-A 1
Li EaFA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.30E+03
2.98E+03
3.05E+03
3.94E+03
4.27E+03
4.24E+03
4.33E+03
2.92E+03
1.91E+03
2.34E+03
2.96E+03
3.32E+03
3.94E+03
4.20E+03
5.15E+03
4.96E+03
2.88E+03
1.90E+03
1.80E+03
2.41 E+03
3.21 E+03
3.85E+03
4.19E+03
4.43E+03
4.41 E+03
2.73E+03
1.71 E+03
9.51 E+00
8.45E+00
7.81 E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+03 4.6E-01 1.9E+00 6.0E+00
2.98E+03 3.3E-01 1.9E+00 6.0E+00
3.05E+03 6.9E+00 1.9E+00 6.0E+00 10 325
3.94E+03 1.9E+00 1.9E+00 6.0E+00
4.27E+03 3.2E-02 1.9E+00 6.0E+00
4.24E+03 1.4E+00 1.9E+00 6.0E+00
4.33E+03 6.4E+00 1.9E+00 6.0E+00
2.92E+03 6.0E-01 1.9E+00 6.0E+00
1.91 E+03 2.9E-01 1.9E+00 6.0E+00
2.34E+03 4.3E-01 1.9E+00 6.0E+00
2.96E+03 1.1 E+00 1.9E+00 6.0E+00
3.32E+03 6.9E-01 1.9E+00 6.0E+00 10 325
3.94E+03 4.8E-01 1.9E+00 6.0E+00
4.20E+03 3.6E-01 1.9E+00 6.0E+00
5.15E+03 8.0E+01 1.9E+00 6.0E+00
4.96E+03 6.7E+01 1.9E+00 6.0E+00
2.88E+03 3.2E+00 1.9E+00 6.0E+00
1.90E+03 5.1E-01 1.9E+00 6.0E+00
1.80E+03 8.3E+01 1.9E+00 6.0E+00
2.41 E+03 9.0E+01 1.9E+00 6.0E+00
3.21E+03 2.1E+00 1.9E+00 6.0E+00 10 325
3.85E+03 2.4E-01 1.9E+00 6.0E+00
4.19E+03 5.9E-01 1.9E+00 6.0E+00
4.43E+03 4.8E-01 1.9E+00 6.0E+00
4.41 E+03 9.8E-02 1.9E+00 6.0E+00
2.73E+03 3.0E+00 1.9E+00 6.0E+00
1.71 E+03 1.3E+01 1.9E+00 6.0E+00
9.51E+00 2.0E+01 1.9E+00 6.0E+00
8.45E+00 3.8E+00 1.9E+00 6.0E+00
7.81 E+00 1.6E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.31E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.29E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.58E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:OOAMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:08AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:10AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:12AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:13AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:15AMEPAInterlabL02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:33AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:35AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:36AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:38AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:40AMEPAInterlabL02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-46
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFA-L02-1313-T01-A 1
Mn EaFA-L02-1313-T02-A 1
Mn EaFA-L02-1313-T03-A 1
Mn EaFA-L02-1313-T04-A 1
Mn EaFA-L02-1313-T05-A 1
Mn EaFA-L02-1313-T06-A 1
Mn EaFA-L02-1313-T07-A 1
Mn EaFA-L02-1313-T08-A 1
Mn EaFA-L02-1313-T09-A 1
Mn EaFA-L02-1313-T01-B 1
Mn EaFA-L02-1313-T02-B 1
Mn EaFA-L02-1313-T03-B 1
Mn EaFA-L02-1313-T04-B 1
Mn EaFA-L02-1313-T05-B 1
Mn EaFA-L02-1313-T06-B 1
Mn EaFA-L02-1313-T07-B 1
Mn EaFA-L02-1313-T08-B 1
Mn EaFA-L02-1313-T09-B 1
Mn EaFA-L02-1313-T01-C 1
Mn EaFA-L02-1313-T02-C 1
Mn EaFA-L02-1313-T03-C 1
Mn EaFA-L02-1313-T04-C 1
Mn EaFA-L02-1313-T05-C 1
Mn EaFA-L02-1313-T06-C 1
Mn EaFA-L02-1313-T07-C 1
Mn EaFA-L02-1313-T08-C 1
Mn EaFA-L02-1313-T09-C 1
Mn EaFA-L02-1313-B01-A 1
Mn EaFA-L02-1313-B02-A 1
Mn EaFA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.21 E+00 E
1.04E+02
3.44E+02
8.30E+02
1.14E+03
1.65E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
7.40E+00
1.34E+02
3.99E+02
7.79E+02
1.12E+03
1.65E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.79E+00
1.17E+02
4.22E+02
8.58E+02
1 .09E+03
1 .40E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 5.2E+01 2.0E+00 6.4E+00
1.00E+00 7.2E+01 2.0E+00 6.4E+00 10 325
6.21 E+00 6.5E+00 2.0E+00 6.4E+00
1.04E+02 5.5E-01 2.0E+00 6.4E+00
3.44E+02 1.8E+00 2.0E+00 6.4E+00
8.30E+02 5.7E+00 2.0E+00 6.4E+00
1.14E+03 3.2E-01 2.0E+00 6.4E+00
1.65E+03 4.3E-01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00 10 325
7.40E+00 7.5E+00 2.0E+00 6.4E+00
1.34E+02 3.5E-01 2.0E+00 6.4E+00
3.99E+02 7.0E+01 2.0E+00 6.4E+00
7.79E+02 4.7E+01 2.0E+00 6.4E+00
1.12E+03 2.1 E+00 2.0E+00 6.4E+00
1.65E+03 5.5E-01 2.0E+00 6.4E+00
1.00E+00 2.1E+02 2.0E+00 6.4E+00
1.00E+00 3.3E+02 2.0E+00 6.4E+00
1.00E+00 5.6E+01 2.0E+00 6.4E+00 10 325
6.79E+00 2.8E+00 2.0E+00 6.4E+00
1.17E+02 4.9E-01 2.0E+00 6.4E+00
4.22E+02 8.1E-01 2.0E+00 6.4E+00
8.58E+02 3.3E-01 2.0E+00 6.4E+00
1.09E+03 4.9E+00 2.0E+00 6.4E+00
1.40E+03 2.5E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.00E+00 2.3E+02 2.0E+00 6.4E+00
1.00E+00 5.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.25E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.23E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.39E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-47
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone.
1 ug/L
Mg EaFA-L02-1313-T01-A 1 1.03E+01
Mg EaFA-L02-1313-T02-A 1 1.82E+01
Mg EaFA-L02-1313-T03-A 1 6.06E+01
Mg EaFA-L02-1313-T04-A 1 3.69E+03
Mg EaFA-L02-1313-T05-A 1 6.81 E+03
Mg EaFA-L02-1313-T06-A 1 7.69E+03
Mg EaFA-L02-1313-T07-A 1 8.30E+03
Mg EaFA-L02-1313-T08-A 1 8.18E+03
Mg EaFA-L02-1313-T09-A 1 1.38E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.03E+01 4.0E+01 1.0E+00 3.2E+00
1.82E+01 3.6E+01 1.0E+00 3.2E+00
6.06E+01 1.6E+01 1.0E+00 3.2E+00 1000 100
3.69E+03 4.2E+00 1.0E+00 3.2E+00
6.81 E+03 1.4E+00 1.0E+00 3.2E+00
7.69E+03 1.3E+00 1.0E+00 3.2E+00
8.30E+03 6.6E+00 1.0E+00 3.2E+00
8.18E+03 6.0E-01 1.0E+00 3.2E+00
1.38E+04 7.4E-01 1.0E+00 3.2E+00
Mg EaFA-L02-1313-T01-B 1 2.82E+00 E 2.82E+00 1 .2E+02 1.0E+00 3.2E+00
Mg EaFA-L02-1313-T02-B 1 1.21E+01
Mg EaFA-L02-1313-T03-B 1 6.77E+01
Mg EaFA-L02-1313-T04-B 1 3.77E+03
Mg EaFA-L02-1313-T05-B 1 6.72E+03
Mg EaFA-L02-1313-T06-B 1 7.55E+03
Mg EaFA-L02-1313-T07-B 1 7.82E+03
Mg EaFA-L02-1313-T08-B 1 7.99E+03
Mg EaFA-L02-1313-T09-B 1 1.39E+04
1.21 E+01 9.9E+00 1.0E+00 3.2E+00
6.77E+01 1.1E+01 1.0E+00 3.2E+00 1000 100
3.77E+03 4.1E-01 1.0E+00 3.2E+00
6.72E+03 1.7E-01 1.0E+00 3.2E+00
7.55E+03 8.0E+01 1.0E+00 3.2E+00
7.82E+03 7.2E+01 1.0E+00 3.2E+00
7.99E+03 2.9E+00 1.0E+00 3.2E+00
1.39E+04 2.5E-01 1.0E+00 3.2E+00
Mg EaFA-L02-1313-T01-C 1 5.00E-01 U1/2 5.00E-01 9.3E+02 1.0E+00 3.2E+00
Mg EaFA-L02-1313-T02-C 1 5.00E-01 U1/2 5.00E-01 2.6E+02 1.0E+00 3.2E+00
Mg EaFA-L02-1313-T03-C 1 6.81 E+01
Mg EaFA-L02-1313-T04-C 1 3.69E+03
Mg EaFA-L02-1313-T05-C 1 6.72E+03
Mg EaFA-L02-1313-T06-C 1 8.20E+03
Mg EaFA-L02-1313-T07-C 1 8.70E+03
Mg EaFA-L02-1313-T08-C 1 7.64E+03
Mg EaFA-L02-1313-T09-C 1 1.19E+04
6.81E+01 3.8E+00 1.0E+00 3.2E+00 1000 100
3.69E+03 1.2E-01 1.0E+00 3.2E+00
6.72E+03 8.1E-01 1.0E+00 3.2E+00
8.20E+03 9.3E-01 1.0E+00 3.2E+00
8.70E+03 3.8E-01 1.0E+00 3.2E+00
7.64E+03 2.9E+00 1.0E+00 3.2E+00
1.19E+04 2.2E+01 1.0E+00 3.2E+00
Mg EaFA-L02-1313-B01-A 1 2.43E+00 E 2.43E+00 2.7E+01 1.0E+00 3.2E+00
Mg EaFA-L02-1313-B02-A 1 1.91E+OOE 1.91E+00 1.6E+02 1.0E+00 3.2E+00
Mg EaFA-L02-1313-B03-A 1 9.19E+00
9.19E+00 4.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-48
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo EaFA-L02-1313-T01-A 1
Mo EaFA-L02-1313-T02-A 1
Mo EaFA-L02-1313-T03-A 1
Mo EaFA-L02-1313-T04-A 1
Mo EaFA-L02-1313-T05-A 1
Mo EaFA-L02-1313-T06-A 1
Mo EaFA-L02-1313-T07-A 1
Mo EaFA-L02-1313-T08-A 1
Mo EaFA-L02-1313-T09-A 1
Mo EaFA-L02-1313-T01-B 1
Mo EaFA-L02-1313-T02-B 1
Mo EaFA-L02-1313-T03-B 1
Mo EaFA-L02-1313-T04-B 1
Mo EaFA-L02-1313-T05-B 1
Mo EaFA-L02-1313-T06-B 1
Mo EaFA-L02-1313-T07-B 1
Mo EaFA-L02-1313-T08-B 1
Mo EaFA-L02-1313-T09-B 1
Mo EaFA-L02-1313-T01-C 1
Mo EaFA-L02-1313-T02-C 1
Mo EaFA-L02-1313-T03-C 1
Mo EaFA-L02-1313-T04-C 1
Mo EaFA-L02-1313-T05-C 1
Mo EaFA-L02-1313-T06-C 1
Mo EaFA-L02-1313-T07-C 1
Mo EaFA-L02-1313-T08-C 1
Mo EaFA-L02-1313-T09-C 1
Mo EaFA-L02-1313-B01-A 1
Mo EaFA-L02-1313-B02-A 1
Mo EaFA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
4.33E+03
4.34E+03
4.01 E+03
4.01 E+03
3.86E+03
3.45E+03
1.51 E+03
1.42E+02
2.06E+02
4.39E+03
4.25E+03
4.35E+03
3.97E+03
3.80E+03
3.22E+03
9.62E+02
1.37E+02
2.00E+02
3.96E+03
4.08E+03
4.25E+03
3.89E+03
3.84E+03
3.52E+03
1.47E+03
1.43E+02
1.87E+02
4.02E+00
1.32E+00 E
2.08E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.33E+03 2.1E-01 1.2E+00 3.8E+00
4.34E+03 8.3E-01 1.2E+00 3.8E+00
4.01E+03 7.9E+00 1.2E+00 3.8E+00 10 325
4.01 E+03 3.2E+00 1.2E+00 3.8E+00
3.86E+03 3.0E-01 1.2E+00 3.8E+00
3.45E+03 2.1E+00 1.2E+00 3.8E+00
1.51 E+03 6.6E+00 1.2E+00 3.8E+00
1.42E+02 9.2E-01 1.2E+00 3.8E+00
2.06E+02 1.5E-01 1.2E+00 3.8E+00
4.39E+03 5.9E-01 1.2E+00 3.8E+00
4.25E+03 1.7E+00 1.2E+00 3.8E+00
4.35E+03 3.1E-01 1.2E+00 3.8E+00 10 325
3.97E+03 7.3E-01 1.2E+00 3.8E+00
3.80E+03 6.6E-01 1.2E+00 3.8E+00
3.22E+03 7.8E+01 1.2E+00 3.8E+00
9.62E+02 5.6E+01 1.2E+00 3.8E+00
1.37E+02 3.7E+00 1.2E+00 3.8E+00
2.00E+02 1.5E+00 1.2E+00 3.8E+00
3.96E+03 7.8E+01 1.2E+00 3.8E+00
4.08E+03 7.6E+01 1.2E+00 3.8E+00
4.25E+03 1.2E+00 1.2E+00 3.8E+00 10 325
3.89E+03 1.4E+00 1.2E+00 3.8E+00
3.84E+03 5.5E-01 1.2E+00 3.8E+00
3.52E+03 9.9E-01 1.2E+00 3.8E+00
1.47E+03 5.5E-01 1.2E+00 3.8E+00
1.43E+02 5.4E+00 1.2E+00 3.8E+00
1.87E+02 1.1E+01 1.2E+00 3.8E+00
4.02E+00 1.5E+01 1.2E+00 3.8E+00
1.32E+00 2.8E+02 1.2E+00 3.8E+00
2.08E+01 2.3E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.20E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.26E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.77E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-49
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFA-L02-1313-T01-A 1
Ni EaFA-L02-1313-T02-A 1
Ni EaFA-L02-1313-T03-A 1
Ni EaFA-L02-1313-T04-A 1
Ni EaFA-L02-1313-T05-A 1
Ni EaFA-L02-1313-T06-A 1
Ni EaFA-L02-1313-T07-A 1
Ni EaFA-L02-1313-T08-A 1
Ni EaFA-L02-1313-T09-A 1
Ni EaFA-L02-1313-T01-B 1
Ni EaFA-L02-1313-T02-B 1
Ni EaFA-L02-1313-T03-B 1
Ni EaFA-L02-1313-T04-B 1
Ni EaFA-L02-1313-T05-B 1
Ni EaFA-L02-1313-T06-B 1
Ni EaFA-L02-1313-T07-B 1
Ni EaFA-L02-1313-T08-B 1
Ni EaFA-L02-1313-T09-B 1
Ni EaFA-L02-1313-T01-C
Ni EaFA-L02-1313-T02-C
Ni EaFA-L02-1313-T03-C
Ni EaFA-L02-1313-T04-C
Ni EaFA-L02-1313-T05-C
Ni EaFA-L02-1313-T06-C
Ni EaFA-L02-1313-T07-C
Ni EaFA-L02-1313-T08-C
Ni EaFA-L02-1313-T09-C
Ni EaFA-L02-1313-B01-A
Ni EaFA-L02-1313-B02-A
Ni EaFA-L02-1313-B03-A
Sample Internal
Cone. Qualifier Review
ug/L I
2.21E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
3.48E+00 E
2.34E+01
1.07E+02
5.04E+02
5.42E+02
7.39E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.88E+00 E
3.88E+01
1.38E+02
4.85E+02
5.40E+02
7.38E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
3.09E+01
1.46E+02
5.22E+02
5.18E+02
6.95E+02
9.00E-01 U1/2
2.40E+00 E
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.21E+00 2.9E+02 1.8E+00 5.7E+00
9.00E-01 2.0E+03 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00 10 325
3.48E+00 2.6E+01 1.8E+00 5.7E+00
2.34E+01 2.3E+01 1.8E+00 5.7E+00
1.07E+02 5.5E+00 1.8E+00 5.7E+00
5.04E+02 7.0E+00 1.8E+00 5.7E+00
5.42E+02 9.6E-01 1.8E+00 5.7E+00
7.39E+02 5.6E-01 1.8E+00 5.7E+00
9.00E-01 1.2E+04 1.8E+00 5.7E+00
9.00E-01 1.2E+03 1.8E+00 5.7E+00
9.00E-01 4.6E+02 1.8E+00 5.7E+00 10 325
2.88E+00 1.6E+02 1.8E+00 5.7E+00
3.88E+01 6.8E-01 1.8E+00 5.7E+00
1.38E+02 8.3E+01 1.8E+00 5.7E+00
4.85E+02 5.5E+01 1.8E+00 5.7E+00
5.40E+02 2.2E+00 1.8E+00 5.7E+00
7.38E+02 7.4E-01 1.8E+00 5.7E+00
9.00E-01 4.4E+01 1.8E+00 5.7E+00
9.00E-01 4.9E+01 1.8E+00 5.7E+00
9.00E-01 4.7E+01 1.8E+00 5.7E+00 10 325
9.00E-01 2.5E+02 1.8E+00 5.7E+00
3.09E+01 1.1E+01 1.8E+00 5.7E+00
1.46E+02 1.2E+00 1.8E+00 5.7E+00
5.22E+02 1.1E+00 1.8E+00 5.7E+00
5.18E+02 5.3E+00 1.8E+00 5.7E+00
6.95E+02 1.0E+01 1.8E+00 5.7E+00
9.00E-01 8.4E+02 1.8E+00 5.7E+00
2.40E+00 4.4E+01 1.8E+00 5.7E+00
9.00E-01 5.1E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.36E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.38E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.52E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-50
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qu
1 1 ug/L
P EaFA-L02-1313-T01-A 1 6.93E+01
P EaFA-L02-1313-T02-A 1 6.84E+01
P EaFA-L02-1313-T03-A 1 5.89E+01
P EaFA-L02-1313-T04-A 1 9.86E+01
P EaFA-L02-1313-T05-A 1 4.13E+01
P EaFA-L02-1313-T06-A 1 6.14E+01
P EaFA-L02-1313-T07-A 1 5.62E+01
P EaFA-L02-1313-T08-A 1 5.15E+01
P EaFA-L02-1313-T09-A 1 6.56E+02
P EaFA-L02-1313-T01-B 1 6.58E+01
P EaFA-L02-1313-T02-B 1 5.65E+01
P EaFA-L02-1313-T03-B 1 7.20E+01
P EaFA-L02-1313-T04-B 1 1.16E+02
P EaFA-L02-1313-T05-B 1 6.73E+01
P EaFA-L02-1313-T06-B 1 1.52E+01
P EaFA-L02-1313-T07-B 1 1.75E+01
P EaFA-L02-1313-T08-B 1 3.64E+01
P EaFA-L02-1313-T09-B 1 6.64E+02
P EaFA-L02-1313-T01-C 1 4.67E+01
P EaFA-L02-1313-T02-C 1 5.54E+01
P EaFA-L02-1313-T03-C 1 6.01 E+01
P EaFA-L02-1313-T04-C 1 1.04E+02
P EaFA-L02-1313-T05-C 1 9.16E+01
P EaFA-L02-1313-T06-C 1 6.16E+01
P EaFA-L02-1313-T07-C 1 5.44E+01
P EaFA-L02-1313-T08-C 1 6.54E+01
P EaFA-L02-1313-T09-C 1 6.92E+02
P EaFA-L02-1313-B01-A 1 2.73E+01
P EaFA-L02-1313-B02-A 1 2.57E+01
P EaFA-L02-1313-B03-A 1 4.07E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.93E+01 2.0E+01 3.7E+00 1.2E+01
6.84E+01 2.0E+01 3.7E+00 1 .2E+01
5.89E+01 2.5E+01 3.7E+00 1 .2E+01 1000 100
9.86E+01 6.3E+00 3.7E+00 1 .2E+01
4.13E+01 2.4E+01 3.7E+00 1 .2E+01
6.14E+01 1.2E+01 3.7E+00 1 .2E+01
5.62E+01 3.2E+00 3.7E+00 1.2E+01
5.15E+01 1.3E+01 3.7E+00 1.2E+01
6.56E+02 2.8E-01 3.7E+00 1.2E+01
6.58E+01 1.3E+00 3.7E+00 1.2E+01
5.65E+01 6.2E+00 3.7E+00 1.2E+01
7.20E+01 7.0E+00 3.7E+00 1.2E+01 1000 100
1.16E+02 4.8E+00 3.7E+00 1.2E+01
6.73E+01 1.1 E+01 3.7E+00 1.2E+01
1.52E+01 2.7E+01 3.7E+00 1.2E+01
1.75E+01 3.5E+01 3.7E+00 1.2E+01
3.64E+01 2.5E+00 3.7E+00 1.2E+01
6.64E+02 1.2E+00 3.7E+00 1.2E+01
4.67E+01 4.4E+01 3.7E+00 1.2E+01
5.54E+01 2.9E+01 3.7E+00 1.2E+01
6.01E+01 2.8E+00 3.7E+00 1.2E+01 1000 100
1.04E+02 1.4E+00 3.7E+00 1.2E+01
9.16E+01 1.2E+01 3.7E+00 1.2E+01
6.16E+01 8.6E+00 3.7E+00 1.2E+01
5.44E+01 1.3E+01 3.7E+00 1.2E+01
6.54E+01 5.5E+00 3.7E+00 1.2E+01
6.92E+02 1.1 E+01 3.7E+00 1.2E+01
2.73E+01 2.5E+01 3.7E+00 1.2E+01
2.57E+01 6.2E+00 3.7E+00 1.2E+01
4.07E+01 1.0E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.11E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-51
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
1 ug/L
K EaFA-L02-1313-T01-A 1 1.66E+06
K EaFA-L02-1313-T02-A 1 4.68E+05
K EaFA-L02-1313-T03-A 1 2.04E+05
K EaFA-L02-1313-T04-A 1 1.07E+05
K EaFA-L02-1313-T05-A 1 5.81E+04
K EaFA-L02-1313-T06-A 1 2.48E+04
K EaFA-L02-1313-T07-A 1 2.54E+04
K EaFA-L02-1313-T08-A 1 1.97E+04
K EaFA-L02-1313-T09-A 1 2.12E+04
K EaFA-L02-1313-T01-B 1 1.68E+06
K EaFA-L02-1313-T02-B 1 4.54E+05
K EaFA-L02-1313-T03-B 1 2.25E+05
K EaFA-L02-1313-T04-B 1 1.03E+05
K EaFA-L02-1313-T05-B 1 5.26E+04
K EaFA-L02-1313-T06-B 1 2.23E+04
K EaFA-L02-1313-T07-B 1 2.18E+04
K EaFA-L02-1313-T08-B 1 1.93E+04
K EaFA-L02-1313-T09-B 1 2.12E+04
K EaFA-L02-1313-T01-C 1 1 JOE+06
K EaFA-L02-1313-T02-C 1 5.07E+05
K EaFA-L02-1313-T03-C 1 2.18E+05
K EaFA-L02-1313-T04-C 1 1 .OOE+05
K EaFA-L02-1313-T05-C 1 5.60E+04
K EaFA-L02-1313-T06-C 1 2.60E+04
K EaFA-L02-1313-T07-C 1 2.63E+04
K EaFA-L02-1313-T08-C 1 1 .85E+04
K EaFA-L02-1313-T09-C 1 1 .93E+04
K EaFA-L02-1313-B01-A 1 1.01E+01
K EaFA-L02-1313-B02-A 1 2.71E+01
K EaFA-L02-1313-B03-A 1 1 .69E+06
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.66E+06 8.8E-02 1.6E+00 5.1E+00
4.68E+05 4.9E-01 1.6E+00 5.1E+00
2.04E+05 6.8E+00 1.6E+00 5.1E+00 1000 100
1.07E+05 3.0E+00 1.6E+00 5.1E+00
5.81 E+04 2.8E-01 1.6E+00 5.1E+00
2.48E+04 1.4E+00 1.6E+00 5.1E+00
2.54E+04 6.8E+00 1.6E+00 5.1E+00
1.97E+04 7.8E-01 1.6E+00 5.1E+00
2.12E+04 2.2E-01 1.6E+00 5.1E+00
1.68E+06 6.9E-01 1.6E+00 5.1E+00
4.54E+05 1.3E+00 1.6E+00 5.1E+00
2.25E+05 1.7E+00 1.6E+00 5.1E+00 1000 100
1.03E+05 7.4E-01 1.6E+00 5.1E+00
5.26E+04 4.0E-01 1.6E+00 5.1E+00
2.23E+04 7.9E+01 1.6E+00 5.1E+00
2.18E+04 4.8E+01 1.6E+00 5.1E+00
1.93E+04 3.3E+00 1.6E+00 5.1E+00
2.12E+04 1.8E-01 1.6E+00 5.1E+00
1.70E+06 7.5E+01 1.6E+00 5.1E+00
5.07E+05 8.5E+01 1.6E+00 5.1E+00
2.18E+05 2.0E+00 1.6E+00 5.1E+00 1000 100
1.00E+05 3.1E-01 1.6E+00 5.1E+00
5.60E+04 1.1E-01 1.6E+00 5.1E+00
2.60E+04 8.2E-01 1.6E+00 5.1E+00
2.63E+04 5.9E-01 1.6E+00 5.1E+00
1.85E+04 5.1E+00 1.6E+00 5.1E+00
1.93E+04 1.2E+01 1.6E+00 5.1E+00
1.01E+01 1.8E+01 1.6E+00 5.1E+00
2.71E+01 1.5E+01 1.6E+00 5.1E+00
1.69E+06 1.1E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.04E+05 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.26E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.19E+05 81% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-52
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se EaFA-L02-1313-T01-A 1
Se EaFA-L02-1313-T02-A 1
Se EaFA-L02-1313-T03-A 1
Se EaFA-L02-1313-T04-A 1
Se EaFA-L02-1313-T05-A 1
Se EaFA-L02-1313-T06-A 1
Se EaFA-L02-1313-T07-A 1
Se EaFA-L02-1313-T08-A 1
Se EaFA-L02-1313-T09-A 1
Se EaFA-L02-1313-T01-B 1
Se EaFA-L02-1313-T02-B 1
Se EaFA-L02-1313-T03-B 1
Se EaFA-L02-1313-T04-B 1
Se EaFA-L02-1313-T05-B 1
Se EaFA-L02-1313-T06-B 1
Se EaFA-L02-1313-T07-B 1
Se EaFA-L02-1313-T08-B 1
Se EaFA-L02-1313-T09-B 1
Se EaFA-L02-1313-T01-C 1
Se EaFA-L02-1313-T02-C 1
Se EaFA-L02-1313-T03-C 1
Se EaFA-L02-1313-T04-C 1
Se EaFA-L02-1313-T05-C 1
Se EaFA-L02-1313-T06-C 1
Se EaFA-L02-1313-T07-C 1
Se EaFA-L02-1313-T08-C 1
Se EaFA-L02-1313-T09-C 1
Se EaFA-L02-1313-B01-A 1
Se EaFA-L02-1313-B02-A 1
Se EaFA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
6.88E+03
6.26E+03
5.14E+03
3.43E+03
1.83E+03
1.05E+03
4.93E+02
8.05E+01
1.98E+02
6.99E+03
6.29E+03
5.63E+03
3.28E+03
1.69E+03
9.81 E+02
4.07E+02
7.03E+01
2.19E+02
6.67E+03
5.91 E+03
5.64E+03
3.40E+03
1 J9E+03
1.11 E+03
5.08E+02
9.63E+01
2.02E+02
7.50E+00 U1/2
1.83E+01 E
7.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.88E+03 1.2E+00 1.5E+01 4.8E+01
6.26E+03 2.0E+00 1.5E+01 4.8E+01
5.14E+03 7.2E+00 1.5E+01 4.8E+01 10 325
3.43E+03 5.2E+00 1.5E+01 4.8E+01
1.83E+03 1.4E+00 1.5E+01 4.8E+01
1.05E+03 5.5E+00 1.5E+01 4.8E+01
4.93E+02 1.2E+01 1.5E+01 4.8E+01
8.05E+01 2.9E+00 1.5E+01 4.8E+01
1.98E+02 2.0E+00 1.5E+01 4.8E+01
6.99E+03 1.2E-01 1.5E+01 4.8E+01
6.29E+03 1.6E+00 1.5E+01 4.8E+01
5.63E+03 4.4E-01 1.5E+01 4.8E+01 10 325
3.28E+03 3.7E-01 1.5E+01 4.8E+01
1.69E+03 2.2E+00 1.5E+01 4.8E+01
9.81E+02 8.1E+01 1.5E+01 4.8E+01
4.07E+02 6.6E+01 1.5E+01 4.8E+01
7.03E+01 4.2E+01 1 .5E+01 4.8E+01
2.19E+02 9.9E-01 1 .5E+01 4.8E+01
6.67E+03 8.3E+01 1 .5E+01 4.8E+01
5.91 E+03 9.0E+01 1 .5E+01 4.8E+01
5.64E+03 2.4E+00 1 .5E+01 4.8E+01 10 325
3.40E+03 1.8E-01 1 .5E+01 4.8E+01
1.79E+03 2.1E+00 1 .5E+01 4.8E+01
1.11 E+03 2.7E+00 1.5E+01 4.8E+01
5.08E+02 8.3E+00 1 .5E+01 4.8E+01
9.63E+01 1.8E+01 1 .5E+01 4.8E+01
2.02E+02 1.7E+01 1 .5E+01 4.8E+01
7.50E+00 5.9E+02 1 .5E+01 4.8E+01
1.83E+01 4.6E+01 1 .5E+01 4.8E+01
7.50E+00 1.0E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.31 E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.34E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.21E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-53
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone.
1 1 ug/L
Si EaFA-L02-1313-T01-A 1 1.30E+04
Si EaFA-L02-1313-T02-A 1 6.25E+03
Si EaFA-L02-1313-T03-A 1 1.67E+03
Si EaFA-L02-1313-T04-A 1 4.46E+02
Si EaFA-L02-1313-T05-A 1 1.19E+03
Si EaFA-L02-1313-T06-A 1 2.23E+03
Si EaFA-L02-1313-T07-A 1 6.71E+03
Si EaFA-L02-1313-T08-A 1 2.12E+04
Si EaFA-L02-1313-T09-A 1 6.82E+04
Si EaFA-L02-1313-T01-B 1 1.31E+04
Si EaFA-L02-1313-T02-B 1 6.31E+03
Si EaFA-L02-1313-T03-B 1 1.85E+03
Si EaFA-L02-1313-T04-B 1 4.57E+02
Si EaFA-L02-1313-T05-B 1 1.27E+03
Si EaFA-L02-1313-T06-B 1 2.38E+03
Si EaFA-L02-1313-T07-B 1 5.80E+03
Si EaFA-L02-1313-T08-B 1 2.06E+04
Si EaFA-L02-1313-T09-B 1 6.75E+04
Si EaFA-L02-1313-T01-C 1 1.20E+04
Si EaFA-L02-1313-T02-C 1 6.04E+03
Si EaFA-L02-1313-T03-C 1 1.65E+03
Si EaFA-L02-1313-T04-C 1 4.41E+02
Si EaFA-L02-1313-T05-C 1 1.27E+03
Si EaFA-L02-1313-T06-C 1 2.59E+03
Si EaFA-L02-1313-T07-C 1 6.50E+03
Si EaFA-L02-1313-T08-C 1 2.16E+04
Si EaFA-L02-1313-T09-C 1 6.71E+04
Si EaFA-L02-1313-B01-A 1 3.19E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.30E+04 9.0E-01 1.1E+00 3.5E+00
6.25E+03 6.0E-01 1.1E+00 3.5E+00
1.67E+03 6.4E+00 1.1E+00 3.5E+00 1000 100
4.46E+02 3.7E+00 1.1E+00 3.5E+00
1.19E+03 1.1E+00 1.1E+00 3.5E+00
2.23E+03 1.8E+00 1.1E+00 3.5E+00
6.71 E+03 7.1E+00 1.1E+00 3.5E+00
2.12E+04 4.3E-01 1.1E+00 3.5E+00
6.82E+04 1.2E+00 1.1E+00 3.5E+00
1.31E+04 9.7E-01 1.1E+00 3.5E+00
6.31 E+03 1.1E+00 1.1E+00 3.5E+00
1.85E+03 8.8E-01 1.1E+00 3.5E+00 1000 100
4.57E+02 6.6E-01 1.1E+00 3.5E+00
1.27E+03 3.7E-01 1.1E+00 3.5E+00
2.38E+03 7.8E+01 1.1E+00 3.5E+00
5.80E+03 5.4E+01 1.1E+00 3.5E+00
2.06E+04 2.5E+00 1.1E+00 3.5E+00
6.75E+04 2.5E-01 1.1E+00 3.5E+00
1.20E+04 7.9E+01 1.1E+00 3.5E+00
6.04E+03 8.3E+01 1.1E+00 3.5E+00
1.65E+03 2.1E+00 1.1E+00 3.5E+00 1000 100
4.41 E+02 6.0E-01 1.1E+00 3.5E+00
1.27E+03 2.3E-01 1.1E+00 3.5E+00
2.59E+03 5.1E-01 1.1E+00 3.5E+00
6.50E+03 2.8E-01 1.1E+00 3.5E+00
2.16E+04 5.2E+00 1.1E+00 3.5E+00
6.71 E+04 3.4E+00 1.1E+00 3.5E+00
3.19E+01 1.4E+01 1.1E+00 3.5E+00
Si EaFA-L02-1313-B02-A 1 5.50E-01 U1/2 5.50E-01 1.1E+02 1.1E+00 3.5E+00
Si EaFA-L02-1313-B03-A 1 6.83E+03
6.83E+03 4.0E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.68E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.71E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.74E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-54
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFA-L02-1313-T01-A 1
Na EaFA-L02-1313-T02-A 1
Na EaFA-L02-1313-T03-A 1
Na EaFA-L02-1313-T04-A 1
Na EaFA-L02-1313-T05-A 1
Na EaFA-L02-1313-T06-A 1
Na EaFA-L02-1313-T07-A 1
Na EaFA-L02-1313-T08-A 1
Na EaFA-L02-1313-T09-A 1
Na EaFA-L02-1313-T01-B 1
Na EaFA-L02-1313-T02-B 1
Na EaFA-L02-1313-T03-B 1
Na EaFA-L02-1313-T04-B 1
Na EaFA-L02-1313-T05-B 1
Na EaFA-L02-1313-T06-B 1
Na EaFA-L02-1313-T07-B 1
Na EaFA-L02-1313-T08-B 1
Na EaFA-L02-1313-T09-B 1
Na EaFA-L02-1313-T01-C 1
Na EaFA-L02-1313-T02-C 1
Na EaFA-L02-1313-T03-C 1
Na EaFA-L02-1313-T04-C 1
Na EaFA-L02-1313-T05-C 1
Na EaFA-L02-1313-T06-C 1
Na EaFA-L02-1313-T07-C 1
Na EaFA-L02-1313-T08-C 1
Na EaFA-L02-1313-T09-C 1
Na EaFA-L02-1313-B01-A 1
Na EaFA-L02-1313-B02-A 1
Na EaFA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
6.67E+03
6.15E+03
5.46E+03
5.89E+03
6.00E+03
5.63E+03
5.77E+03
4.21 E+03
3.38E+03
6.60E+03
6.02E+03
5.90E+03
5.85E+03
5.75E+03
5.05E+03
4.90E+03
4.11E+03
3.29E+03
5.80E+03
5.70E+03
5.54E+03
5.73E+03
5.86E+03
5.90E+03
5.98E+03
3.96E+03
3.06E+03
1.25E+00 U1/2
1.25E+00 U1/2
5.67E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.67E+03 6.5E-01 2.5E+00 8.0E+00
6.15E+03 7.4E-01 2.5E+00 8.0E+00
5.46E+03 7.6E+00 2.5E+00 8.0E+00 1000 100
5.89E+03 3.0E+00 2.5E+00 8.0E+00
6.00E+03 3.2E-01 2.5E+00 8.0E+00
5.63E+03 9.1E-01 2.5E+00 8.0E+00
5.77E+03 7.3E+00 2.5E+00 8.0E+00
4.21 E+03 2.8E-01 2.5E+00 8.0E+00
3.38E+03 7.7E-02 2.5E+00 8.0E+00
6.60E+03 8.9E-01 2.5E+00 8.0E+00
6.02E+03 1.1E+00 2.5E+00 8.0E+00
5.90E+03 5.5E-01 2.5E+00 8.0E+00 1000 100
5.85E+03 7.2E-01 2.5E+00 8.0E+00
5.75E+03 4.2E-01 2.5E+00 8.0E+00
5.05E+03 8.0E+01 2.5E+00 8.0E+00
4.90E+03 6.2E+01 2.5E+00 8.0E+00
4.11E+03 2.8E+00 2.5E+00 8.0E+00
3.29E+03 5.6E-01 2.5E+00 8.0E+00
5.80E+03 8.2E+01 2.5E+00 8.0E+00
5.70E+03 9.4E+01 2.5E+00 8.0E+00
5.54E+03 2.2E+00 2.5E+00 8.0E+00 1000 100
5.73E+03 3.2E-01 2.5E+00 8.0E+00
5.86E+03 2.1E-01 2.5E+00 8.0E+00
5.90E+03 9.9E-01 2.5E+00 8.0E+00
5.98E+03 3.3E-01 2.5E+00 8.0E+00
3.96E+03 4.4E+00 2.5E+00 8.0E+00
3.06E+03 1.2E+01 2.5E+00 8.0E+00
1.25E+00 1.2E+02 2.5E+00 8.0E+00
1.25E+00 1.6E+00 2.5E+00 8.0E+00
5.67E+02 5.3E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.41 E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.88E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.47E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:OOAMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:08AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:10AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:12AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:13AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:15AMEPAInterlabL02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:33AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:35AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:36AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:38AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:40AMEPAInterlabL02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-55
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
EaFA-L02-1313-T01-A 1
EaFA-L02-1313-T02-A 1
EaFA-L02-1313-T03-A 1
EaFA-L02-1313-T04-A 1
EaFA-L02-1313-T05-A 1
EaFA-L02-1313-T06-A 1
EaFA-L02-1313-T07-A 1
EaFA-L02-1313-T08-A 1
EaFA-L02-1313-T09-A 1
EaFA-L02-1313-T01-B 1
EaFA-L02-1313-T02-B 1
EaFA-L02-1313-T03-B 1
EaFA-L02-1313-T04-B 1
EaFA-L02-1313-T05-B 1
EaFA-L02-1313-T06-B 1
EaFA-L02-1313-T07-B 1
EaFA-L02-1313-T08-B 1
EaFA-L02-1313-T09-B 1
EaFA-L02-1313-T01-C 1
EaFA-L02-1313-T02-C 1
EaFA-L02-1313-T03-C 1
EaFA-L02-1313-T04-C 1
EaFA-L02-1313-T05-C 1
EaFA-L02-1313-T06-C 1
EaFA-L02-1313-T07-C 1
EaFA-L02-1313-T08-C 1
EaFA-L02-1313-T09-C 1
EaFA-L02-1313-B01-A 1
EaFA-L02-1313-B02-A 1
EaFA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.40E+03
1.65E+03
1.70E+03
2.06E+03
2.21E+03
2.31 E+03
2.70E+03
3.26E+03
5.43E+03
1.42E+03
1.65E+03
1.85E+03
2.06E+03
2.19E+03
2.17E+03
2.39E+03
3.16E+03
5.44E+03
1 .29E+03
1 .64E+03
1 J8E+03
2.00E+03
2.20E+03
2.43E+03
2. 81 E+03
3.11E+03
5.25E+03
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.40E+03 9.7E-01 1.0E+00 3.2E+00
1.65E+03 8.8E-01 1.0E+00 3.2E+00
1.70E+03 8.1E+00 1.0E+00 3.2E+00 1000 100
2.06E+03 2.7E+00 1.0E+00 3.2E+00
2.21 E+03 5.1E-01 1.0E+00 3.2E+00
2.31 E+03 1.8E+00 1.0E+00 3.2E+00
2.70E+03 7.1E+00 1.0E+00 3.2E+00
3.26E+03 2.2E+00 1.0E+00 3.2E+00
5.43E+03 3.2E-01 1.0E+00 3.2E+00
1.42E+03 5.7E-01 1.0E+00 3.2E+00
1.65E+03 2.0E+00 1.0E+00 3.2E+00
1.85E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
2.06E+03 8.7E-01 1.0E+00 3.2E+00
2.19E+03 3.5E-01 1.0E+00 3.2E+00
2.17E+03 7.1E+01 1.0E+00 3.2E+00
2.39E+03 2.2E+01 1.0E+00 3.2E+00
3.16E+03 7.5E-01 1.0E+00 3.2E+00
5.44E+03 1.2E-01 1.0E+00 3.2E+00
1.29E+03 7.8E+01 1.0E+00 3.2E+00
1.64E+03 7.6E+01 1.0E+00 3.2E+00
1.78E+03 1.4E+00 1.0E+00 3.2E+00 1000 100
2.00E+03 1.7E+00 1.0E+00 3.2E+00
2.20E+03 3.1E-01 1.0E+00 3.2E+00
2.43E+03 8.7E-01 1.0E+00 3.2E+00
2.81E+03 5.2E-01 1.0E+00 3.2E+00
3. 11 E+03 5.9E+00 1.0E+00 3.2E+00
5.25E+03 1.3E+00 1.0E+00 3.2E+00
5.00E-01 3.9E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+02 1.0E+00 3.2E+00
5.00E-01 1.1E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.66E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.69E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.85E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-56
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qu
1 1 ug/L
S EaFA-L02-1313-T01-A 1 1.90E+05
S EaFA-L02-1313-T02-A 1 1.74E+05
S EaFA-L02-1313-T03-A 1 1.56E+05
S EaFA-L02-1313-T04-A 1 1.73E+05
S EaFA-L02-1313-T05-A 1 1.75E+05
S EaFA-L02-1313-T06-A 1 1.64E+05
S EaFA-L02-1313-T07-A 1 1.59E+05
S EaFA-L02-1313-T08-A 1 1.06E+05
S EaFA-L02-1313-T09-A 1 6.57E+04
S EaFA-L02-1313-T01-B 1 1.92E+05
S EaFA-L02-1313-T02-B 1 1.75E+05
S EaFA-L02-1313-T03-B 1 1.71E+05
S EaFA-L02-1313-T04-B 1 1.72E+05
S EaFA-L02-1313-T05-B 1 1.71E+05
S EaFA-L02-1313-T06-B 1 1.53E+05
S EaFA-L02-1313-T07-B 1 1.38E+05
S EaFA-L02-1313-T08-B 1 1.07E+05
S EaFA-L02-1313-T09-B 1 6.58E+04
S EaFA-L02-1313-T01-C 1 1.78E+05
S EaFA-L02-1313-T02-C 1 1.73E+05
S EaFA-L02-1313-T03-C 1 1.70E+05
S EaFA-L02-1313-T04-C 1 1.73E+05
S EaFA-L02-1313-T05-C 1 1.77E+05
S EaFA-L02-1313-T06-C 1 1.79E+05
S EaFA-L02-1313-T07-C 1 1.68E+05
S EaFA-L02-1313-T08-C 1 1.07E+05
S EaFA-L02-1313-T09-C 1 6.32E+04
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.90E+05 6.9E-01 6.8E+00 2.2E+01
1.74E+05 6.7E-01 6.8E+00 2.2E+01
1.56E+05 6.3E+00 6.8E+00 2.2E+01 1000 100
1.73E+05 2.8E+00 6.8E+00 2.2E+01
1.75E+05 5.1E-01 6.8E+00 2.2E+01
1.64E+05 1.8E+00 6.8E+00 2.2E+01
1.59E+05 6.6E+00 6.8E+00 2.2E+01
1.06E+05 3.0E-01 6.8E+00 2.2E+01
6.57E+04 6.9E-01 6.8E+00 2.2E+01
1.92E+05 1.1E+00 6.8E+00 2.2E+01
1.75E+05 1.0E+00 6.8E+00 2.2E+01
1.71E+05 3.9E-01 6.8E+00 2.2E+01 1000 100
1.72E+05 3.9E-01 6.8E+00 2.2E+01
1.71E+05 3.4E-01 6.8E+00 2.2E+01
1.53E+05 7.9E+01 6.8E+00 2.2E+01
1.38E+05 5.7E+01 6.8E+00 2.2E+01
1.07E+05 2.6E+00 6.8E+00 2.2E+01
6.58E+04 2.7E-01 6.8E+00 2.2E+01
1.78E+05 8.2E+01 6.8E+00 2.2E+01
1.73E+05 9.0E+01 6.8E+00 2.2E+01
1.70E+05 2.2E+00 6.8E+00 2.2E+01 1000 100
1.73E+05 2.4E-01 6.8E+00 2.2E+01
1.77E+05 7.2E-02 6.8E+00 2.2E+01
1.79E+05 7.2E-01 6.8E+00 2.2E+01
1.68E+05 2.3E-01 6.8E+00 2.2E+01
1.07E+05 5.1E+00 6.8E+00 2.2E+01
6.32E+04 9.0E+00 6.8E+00 2.2E+01
S EaFA-L02-1313-B01-A 1 3.40E+00 U1/2 3.40E+00 4.3E+01 6.8E+00 2.2E+01
S EaFA-L02-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 2.1E+01 6.8E+00 2.2E+01
S EaFA-L02-1313-B03-A 1 6.11E+01
6.11E+01 1.1E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .57E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.72E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.71E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-57
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-L02-1313-T01-A 1
Tl EaFA-L02-1313-T02-A 1
Tl EaFA-L02-1313-T03-A 1
Tl EaFA-L02-1313-T04-A 1
Tl EaFA-L02-1313-T05-A 1
Tl EaFA-L02-1313-T06-A 1
Tl EaFA-L02-1313-T07-A 1
Tl EaFA-L02-1313-T08-A 1
Tl EaFA-L02-1313-T09-A 1
Tl EaFA-L02-1313-T01-B 1
Tl EaFA-L02-1313-T02-B 1
Tl EaFA-L02-1313-T03-B 1
Tl EaFA-L02-1313-T04-B 1
Tl EaFA-L02-1313-T05-B 1
Tl EaFA-L02-1313-T06-B 1
Tl EaFA-L02-1313-T07-B 1
Tl EaFA-L02-1313-T08-B 1
Tl EaFA-L02-1313-T09-B 1
Tl EaFA-L02-1313-T01-C 1
Tl EaFA-L02-1313-T02-C 1
Tl EaFA-L02-1313-T03-C 1
Tl EaFA-L02-1313-T04-C 1
Tl EaFA-L02-1313-T05-C 1
Tl EaFA-L02-1313-T06-C 1
Tl EaFA-L02-1313-T07-C 1
Tl EaFA-L02-1313-T08-C 1
Tl EaFA-L02-1313-T09-C 1
Tl EaFA-L02-1313-B01-A 1
Tl EaFA-L02-1313-B02-A 1
Tl EaFA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.28E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
5.32E+00 E
7.19E+00 E
1.87E+01
2.15E+01
5.03E+01
8.44E+01
2.30E+00 U1/2
6.27E+00 E
2.30E+00 U1/2
5.12E+00 E
2.30E+00 U1/2
8.65E+00 E
2.35E+01
5.99E+01
7.37E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
1.19E+01 E
6.93E+00 E
1.52E+01
2.14E+01
5.57E+01
7.01E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.28E+01 2.9E+01 4.6E+00 1 .5E+01
2.30E+00 3.9E+02 4.6E+00 1 .5E+01
2.30E+00 9.5E+00 4.6E+00 1 .5E+01 10 325
5.32E+00 9.2E+01 4.6E+00 1 .5E+01
7.19E+00 2.0E+02 4.6E+00 1 .5E+01
1.87E+01 3.5E+01 4.6E+00 1 .5E+01
2.15E+01 2.6E+01 4.6E+00 1.5E+01
5.03E+01 1.5E+01 4.6E+00 1.5E+01
8.44E+01 4.9E+00 4.6E+00 1.5E+01
2.30E+00 1.3E+02 4.6E+00 1.5E+01
6.27E+00 1.5E+02 4.6E+00 1.5E+01
2.30E+00 4.1E+01 4.6E+00 1.5E+01 10 325
5.12E+00 1.2E+02 4.6E+00 1.5E+01
2.30E+00 2.3E+02 4.6E+00 1.5E+01
8.65E+00 1.7E+02 4.6E+00 1.5E+01
2.35E+01 1.6E+02 4.6E+00 1.5E+01
5.99E+01 1.3E+01 4.6E+00 1.5E+01
7.37E+01 1.3E+01 4.6E+00 1.5E+01
2.30E+00 1.3E+02 4.6E+00 1.5E+01
2.30E+00 1.4E+02 4.6E+00 1.5E+01
2.30E+00 1.5E+03 4.6E+00 1.5E+01 10 325
1.19E+01 1.2E+02 4.6E+00 1.5E+01
6.93E+00 7.7E+01 4.6E+00 1.5E+01
1.52E+01 7.3E+01 4.6E+00 1.5E+01
2.14E+01 3.8E+01 4.6E+00 1.5E+01
5.57E+01 2.1E+01 4.6E+00 1.5E+01
7.01 E+01 1.4E+01 4.6E+00 1.5E+01
2.30E+00 9.7E+03 4.6E+00 1.5E+01
2.30E+00 1.4E+03 4.6E+00 1.5E+01
2.30E+00 1.5E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.23E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.22E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.32E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-58
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L02-1313-T01-A 1
Ti EaFA-L02-1313-T02-A 1
Ti EaFA-L02-1313-T03-A 1
Ti EaFA-L02-1313-T04-A 1
Ti EaFA-L02-1313-T05-A 1
Ti EaFA-L02-1313-T06-A 1
Ti EaFA-L02-1313-T07-A 1
Ti EaFA-L02-1313-T08-A 1
Ti EaFA-L02-1313-T09-A 1
Ti EaFA-L02-1313-T01-B 1
Ti EaFA-L02-1313-T02-B 1
Ti EaFA-L02-1313-T03-B 1
Ti EaFA-L02-1313-T04-B 1
Ti EaFA-L02-1313-T05-B 1
Ti EaFA-L02-1313-T06-B 1
Ti EaFA-L02-1313-T07-B 1
Ti EaFA-L02-1313-T08-B 1
Ti EaFA-L02-1313-T09-B 1
Ti EaFA-L02-1313-T01-C 1
Ti EaFA-L02-1313-T02-C 1
Ti EaFA-L02-1313-T03-C 1
Ti EaFA-L02-1313-T04-C 1
Ti EaFA-L02-1313-T05-C 1
Ti EaFA-L02-1313-T06-C 1
Ti EaFA-L02-1313-T07-C 1
Ti EaFA-L02-1313-T08-C 1
Ti EaFA-L02-1313-T09-C 1
Ti EaFA-L02-1313-B01-A 1
Ti EaFA-L02-1313-B02-A 1
Ti EaFA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.23E+01
7.68E+02
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
9.59E+00
7.81 E+02
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.25E+01
7.76E+02
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 8.5E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+02 2.0E+00 6.4E+00
1.00E+00 6.1E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 5.4E+01 2.0E+00 6.4E+00
1.00E+00 6.8E+01 2.0E+00 6.4E+00
1.00E+00 3.2E+02 2.0E+00 6.4E+00
1.23E+01 2.2E+00 2.0E+00 6.4E+00
7.68E+02 1.4E-01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00 10 325
1.00E+00 3.7E+01 2.0E+00 6.4E+00
1.00E+00 6.6E+02 2.0E+00 6.4E+00
1.00E+00 6.9E+01 2.0E+00 6.4E+00
1.00E+00 1.1 E+02 2.0E+00 6.4E+00
9.59E+00 6.6E+00 2.0E+00 6.4E+00
7.81 E+02 1.3E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+02 2.0E+00 6.4E+00
1.00E+00 6.6E+01 2.0E+00 6.4E+00
1.00E+00 6.8E+02 2.0E+00 6.4E+00 10 325
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+02 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.25E+01 1.3E+01 2.0E+00 6.4E+00
7.76E+02 9.9E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 2.7E+02 2.0E+00 6.4E+00
1.00E+00 4.7E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.37E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.49E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:1 0AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:1 2 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:1 3 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:1 5 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AMEPAInterlabL02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-59
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFA-L02-1313-T01-A 1
V EaFA-L02-1313-T02-A 1
V EaFA-L02-1313-T03-A 1
V EaFA-L02-1313-T04-A 1
V EaFA-L02-1313-T05-A 1
V EaFA-L02-1313-T06-A 1
V EaFA-L02-1313-T07-A 1
V EaFA-L02-1313-T08-A 1
V EaFA-L02-1313-T09-A 1
V EaFA-L02-1313-T01-B 1
V EaFA-L02-1313-T02-B 1
V EaFA-L02-1313-T03-B 1
V EaFA-L02-1313-T04-B 1
V EaFA-L02-1313-T05-B 1
V EaFA-L02-1313-T06-B 1
V EaFA-L02-1313-T07-B 1
V EaFA-L02-1313-T08-B 1
V EaFA-L02-1313-T09-B 1
V EaFA-L02-1313-T01-C 1
V EaFA-L02-1313-T02-C 1
V EaFA-L02-1313-T03-C 1
V EaFA-L02-1313-T04-C 1
V EaFA-L02-1313-T05-C 1
V EaFA-L02-1313-T06-C 1
V EaFA-L02-1313-T07-C 1
V EaFA-L02-1313-T08-C 1
V EaFA-L02-1313-T09-C 1
V EaFA-L02-1313-B01-A 1
V EaFA-L02-1313-B02-A 1
V EaFA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
4.65E+03
3.64E+03
3.15E+03
5.56E+02
3.15E+02
2.41 E+02
1.67E+02
1.05E+02
5.10E+03
4.71 E+03
3.63E+03
3.39E+03
5.34E+02
2.89E+02
2.23E+02
1.41 E+02
9.57E+01
5.03E+03
4.23E+03
3.44E+03
3.29E+03
5.50E+02
3.05E+02
2.43E+02
1.58E+02
1.04E+02
4.48E+03
7.50E-01 U1/2
7.50E-01 U1/2
2.36E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.65E+03 1.5E+00 1.5E+00 4.8E+00
3.64E+03 1.0E+00 1.5E+00 4.8E+00
3.15E+03 8.0E+00 1.5E+00 4.8E+00 10 325
5.56E+02 3.5E+00 1.5E+00 4.8E+00
3.15E+02 8.5E-01 1.5E+00 4.8E+00
2.41 E+02 2.1E+00 1.5E+00 4.8E+00
1.67E+02 5.5E+00 1.5E+00 4.8E+00
1.05E+02 1.9E+00 1.5E+00 4.8E+00
5.10E+03 2.3E-01 1.5E+00 4.8E+00
4.71 E+03 5.2E-01 1.5E+00 4.8E+00
3.63E+03 7.3E-01 1.5E+00 4.8E+00
3.39E+03 1.3E+00 1.5E+00 4.8E+00 10 325
5.34E+02 1.3E+00 1.5E+00 4.8E+00
2.89E+02 8.7E-01 1.5E+00 4.8E+00
2.23E+02 7.9E+01 1.5E+00 4.8E+00
1.41 E+02 5.6E+01 1.5E+00 4.8E+00
9.57E+01 2.5E+00 1.5E+00 4.8E+00
5.03E+03 3.5E-01 1.5E+00 4.8E+00
4.23E+03 7.5E+01 1.5E+00 4.8E+00
3.44E+03 7.6E+01 1.5E+00 4.8E+00
3.29E+03 1.1E+00 1.5E+00 4.8E+00 10 325
5.50E+02 1.5E+00 1.5E+00 4.8E+00
3.05E+02 1.2E+00 1.5E+00 4.8E+00
2.43E+02 4.4E-01 1.5E+00 4.8E+00
1.58E+02 1.3E+00 1.5E+00 4.8E+00
1.04E+02 5.2E+00 1.5E+00 4.8E+00
4.48E+03 2.2E+01 1.5E+00 4.8E+00
7.50E-01 1.6E+02 1.5E+00 4.8E+00
7.50E-01 2.0E+02 1.5E+00 4.8E+00
2.36E+00 3.6E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.35E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.41 E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.81E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                            1-60
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn EaFA-L02-1313-T01-A 1
Zn EaFA-L02-1313-T02-A 1
Zn EaFA-L02-1313-T03-A 1
Zn EaFA-L02-1313-T04-A 1
Zn EaFA-L02-1313-T05-A 1
Zn EaFA-L02-1313-T06-A 1
Zn EaFA-L02-1313-T07-A 1
Zn EaFA-L02-1313-T08-A 1
Zn EaFA-L02-1313-T09-A 1
Zn EaFA-L02-1313-T01-B 1
Zn EaFA-L02-1313-T02-B 1
Zn EaFA-L02-1313-T03-B 1
Zn EaFA-L02-1313-T04-B 1
Zn EaFA-L02-1313-T05-B 1
Zn EaFA-L02-1313-T06-B 1
Zn EaFA-L02-1313-T07-B 1
Zn EaFA-L02-1313-T08-B 1
Zn EaFA-L02-1313-T09-B 1
Zn EaFA-L02-1313-T01-C 1
Zn EaFA-L02-1313-T02-C 1
Zn EaFA-L02-1313-T03-C 1
Zn EaFA-L02-1313-T04-C 1
Zn EaFA-L02-1313-T05-C 1
Zn EaFA-L02-1313-T06-C 1
Zn EaFA-L02-1313-T07-C 1
Zn EaFA-L02-1313-T08-C 1
Zn EaFA-L02-1313-T09-C 1
Zn EaFA-L02-1313-B01-A 1
Zn EaFA-L02-1313-B02-A 1
Zn EaFA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
4.98E+01
6.62E+00
1.47E+01
4.12E+00
8.33E+00
1.27E+01
7.08E+02
1.22E+03
1.57E+03
4.62E+01
1.81E+01
2.47E+00 E
5.28E+00
6.50E+00
1.64E+01
6.99E+02
1.18E+03
1 .57E+03
3.24E+01
4.96E+00
4.48E+00
1.32E+01
5.32E+00
2.20E+01
7.22E+02
1.18E+03
1 .55E+03
5.00E-01 U1/2
5.00E-01 U1/2
6.14E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.98E+01 3.5E+00 1.0E+00 3.2E+00
6.62E+00 3.4E+00 1.0E+00 3.2E+00
1.47E+01 4.3E+00 1.0E+00 3.2E+00 10 325
4.12E+00 2.4E+01 1.0E+00 3.2E+00
8.33E+00 1.5E+01 1.0E+00 3.2E+00
1.27E+01 1.6E+01 1.0E+00 3.2E+00
7.08E+02 6.5E+00 1.0E+00 3.2E+00
1.22E+03 1.0E+00 1.0E+00 3.2E+00
1.57E+03 1.2E+00 1.0E+00 3.2E+00
4.62E+01 1.2E+00 1.0E+00 3.2E+00
1.81E+01 5.1E+00 1.0E+00 3.2E+00
2.47E+00 1.5E+01 1.0E+00 3.2E+00 10 325
5.28E+00 6.9E+00 1.0E+00 3.2E+00
6.50E+00 9.6E+00 1.0E+00 3.2E+00
1.64E+01 8.0E+01 1.0E+00 3.2E+00
6.99E+02 5.7E+01 1.0E+00 3.2E+00
1.18E+03 2.1E+00 1.0E+00 3.2E+00
1.57E+03 1.0E+00 1 .OE+00 3.2E+00
3.24E+01 7.9E+01 1 .OE+00 3.2E+00
4.96E+00 8.6E+01 1 .OE+00 3.2E+00
4.48E+00 1.4E+01 1 .OE+00 3.2E+00 10 325
1.32E+01 2.6E+00 1 .OE+00 3.2E+00
5.32E+00 3.2E+01 1 .OE+00 3.2E+00
2.20E+01 2.8E+00 1 .OE+00 3.2E+00
7.22E+02 1.7E-01 1 .OE+00 3.2E+00
1.18E+03 1.1E+01 1.0E+00 3.2E+00
1.55E+03 3.7E+00 1 .OE+00 3.2E+00
5.00E-01 6.4E+01 1. OE+00 3.2E+00
5.00E-01 5.3E+00 1. OE+00 3.2E+00
6.14E+00 1.9E+01 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.47E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.46E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.63E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 10:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:37 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:39 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:42 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:44 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:45 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:47 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:49 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:58 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:00 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:02 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:03 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:08 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:10 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:12 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:13 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:15 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:20 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:22 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/1011:31 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:33 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:35 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:36 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:38 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:40 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:30 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:32 AM EPA Interlab L02 1313-1316 EaFA
6/4/10 10:34 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                           1-61
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al EaFA-L04-1313-T01-A 1 4.36E+04
Al EaFA-L04-1313-T02-A 1 3.53E+04
Al EaFA-L04-1313-T03-A 1 2.40E+04
Al EaFA-L04-1313-T04-A 1 1.19E+04
Al EaFA-L04-1313-T05-A 1 9.64E+02
Al EaFA-L04-1313-T06-A 1 1.62E+02
Al EaFA-L04-1313-T07-A 1 9.97E+02
Al EaFA-L04-1313-T08-A 1 3.61 E+04
Al EaFA-L04-1313-T09-A 1 1.16E+05
Al EaFA-L04-1313-T01-B 1 4.44E+04
Al EaFA-L04-1313-T02-B 1 3.64E+04
Al EaFA-L04-1313-T03-B 1 2.41E+04
Al EaFA-L04-1313-T04-B 1 6.78E+03
Al EaFA-L04-1313-T05-B 1 8.03E+02
Al EaFA-L04-1313-T06-B 1 1.37E+02
Al EaFA-L04-1313-T07-B 1 1.02E+03
Al EaFA-L04-1313-T08-B 1 3.26E+04
Al EaFA-L04-1313-T09-B 1 1.12E+05
Al EaFA-L04-1313-T01-C 1 4.55E+04
Al EaFA-L04-1313-T02-C 1 3.61 E+04
Al EaFA-L04-1313-T03-C 1 2.42E+04
Al EaFA-L04-1313-T04-C 1 6.87E+03
Al EaFA-L04-1313-T05-C 1 9.91 E+02
Al EaFA-L04-1313-T06-C 1 1.57E+02
Al EaFA-L04-1313-T07-C 1 3.88E+02
Al EaFA-L04-1313-T08-C 1 3.21E+04
Al EaFA-L04-1313-T09-C 1 1.12E+05
Al EaFA-L04-1313-B01-A 1 5.00E-01 U1/2
Al EaFA-L04-1313-B02-A 1 6.19E+00
Al EaFA-L04-1313-B03-A 1 3.66E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.36E+04 8.2E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.53E+04 4.4E-01 1 .OE+00 3.2E+00 1000 100 3.62E+04 98% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
2.40E+04 5.6E-01 1 .OE+00 3.2E+00
1.19E+04 2.8E-01 1 .OE+00 3.2E+00
9.64E+02 1.3E+00 1 .OE+00 3.2E+00
1.62E+02 1.5E+00 1 .OE+00 3.2E+00
9.97E+02 1.7E-01 1 .OE+00 3.2E+00
3.61E+04 2.4E-01 1 .OE+00 3.2E+00
1.16E+05 7.7E-01 1 .OE+00 3.2E+00
4.44E+04 5.2E-01 1 .OE+00 3.2E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.64E+04 6.8E-01 1 .OE+00 3.2E+00 1000 100 3.74E+04 93% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
2.41E+04 5.7E-01 1 .OE+00 3.2E+00
6.78E+03 5.6E-01 1 .OE+00 3.2E+00
8.03E+02 6.5E-01 1 .OE+00 3.2E+00
1.37E+02 1.5E+00 1 .OE+00 3.2E+00
1.02E+03 9.3E-01 1 .OE+00 3.2E+00
3.26E+04 3.9E-01 1 .OE+00 3.2E+00
1.12E+05 1.9E+00 1. OE+00 3.2E+00
4.55E+04 9.8E-02 1 .OE+00 3.2E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
3.61E+04 5.0E-01 1 .OE+00 3.2E+00 1000 100 3.71E+04 93% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
2.42E+04 3.1E-01 1 .OE+00 3.2E+00
6.87E+03 2.7E-01 1 .OE+00 3.2E+00
9.91 E+02 6.5E-01 1 .OE+00 3.2E+00
1.57E+02 1.4E+00 1 .OE+00 3.2E+00
3.88E+02 5.3E-01 1 .OE+00 3.2E+00
3.21 E+04 6.9E-01 1 .OE+00 3.2E+00
1.12E+05 7.2E-01 1 .OE+00 3.2E+00
5.00E-01 2.7E+01 1 .OE+00 3.2E+00
6.19E+00 1.2E+01 1. OE+00 3.2E+00
3.66E+01 5.5E+00 1 .OE+00 3.2E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                                     1-62
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb EaFA-L04-1313-T01-A 1 2.71E+02
Sb EaFA-L04-1313-T02-A 1 1.55E+02
Sb EaFA-L04-1313-T03-A 1 1.91E+02
Sb EaFA-L04-1313-T04-A 1 1.65E+02
Sb EaFA-L04-1313-T05-A 1 1.68E+02
Sb EaFA-L04-1313-T06-A 1 1.62E+02
Sb EaFA-L04-1313-T07-A 1 8.27E+01
Sb EaFA-L04-1313-T08-A 1 1.79E+01 E
Sb EaFA-L04-1313-T09-A 1 3.75E+00 U1/2
Sb EaFA-L04-1313-T01-B 1 2.45E+02
Sb EaFA-L04-1313-T02-B 1 1.54E+02
Sb EaFA-L04-1313-T03-B 1 1.76E+02
Sb EaFA-L04-1313-T04-B 1 1.98E+02
Sb EaFA-L04-1313-T05-B 1 2.15E+02
Sb EaFA-L04-1313-T06-B 1 1.91E+02
Sb EaFA-L04-1313-T07-B 1 8.41 E+01
Sb EaFA-L04-1313-T08-B 1 3.57E+01
Sb EaFA-L04-1313-T09-B 1 3.75E+00 U1/2
Sb EaFA-L04-1313-T01-C 1 2.74E+02
Sb EaFA-L04-1313-T02-C 1 1 .46E+02
Sb EaFA-L04-1313-T03-C 1 1 .84E+02
Sb EaFA-L04-1313-T04-C 1 1 .93E+02
Sb EaFA-L04-1313-T05-C 1 1.61E+02
Sb EaFA-L04-1313-T06-C 1 1 .94E+02
Sb EaFA-L04-1313-T07-C 1 1 .OOE+02
Sb EaFA-L04-1313-T08-C 1 1 .90E+01 E
Sb EaFA-L04-1313-T09-C 1 3.75E+00 U1/2
Sb EaFA-L04-1313-B01-A 1 9.97E+00 E
Sb EaFA-L04-1313-B02-A 1 3.75E+00 U1/2
Sb EaFA-L04-1313-B03-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.71E+02 6.2E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
1.55E+02 2.8E+01 7.5E+00 2.4E+01 10 325 3.64E+03 107% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
1.91E+02 1.8E+00 7.5E+00 2.4E+01
1.65E+02 1.5E+00 7.5E+00 2.4E+01
1.68E+02 1.6E+01 7.5E+00 2.4E+01
1.62E+02 1.5E+01 7.5E+00 2.4E+01
8.27E+01 9.0E+00 7.5E+00 2.4E+01
1.79E+01 5.5E+01 7.5E+00 2.4E+01
3.75E+00 6.0E+01 7.5E+00 2.4E+01
2.45E+02 1.5E+01 7.5E+00 2.4E+01
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
1.54E+02 1.4E+01 7.5E+00 2.4E+01 10 325 3.88E+03 115% VU ICP-OES 6/24/10 1 1:33 AM EPA Interlab L04 1313-1316 EaFA
1.76E+02 1.4E+01 7.5E+00 2.4E+01
1.98E+02 1.6E+01 7.5E+00 2.4E+01
2.15E+02 6.5E+00 7.5E+00 2.4E+01
1.91E+02 1.6E+01 7.5E+00 2.4E+01
8.41E+01 3.1E+01 7.5E+00 2.4E+01
3.57E+01 4.3E+01 7.5E+00 2.4E+01
3.75E+00 1.5E+02 7.5E+00 2.4E+01
2.74E+02 9.3E+00 7.5E+00 2.4E+01
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
1.46E+02 1.1E+01 7.5E+00 2.4E+01 10 325 3.66E+03 108% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
1.84E+02 5.6E+00 7.5E+00 2.4E+01
1.93E+02 7.0E+00 7.5E+00 2.4E+01
1.61E+02 1.5E+01 7.5E+00 2.4E+01
1.94E+02 1.1E+01 7.5E+00 2.4E+01
1. OOE+02 3.3E+01 7.5E+00 2.4E+01
1.90E+01 4.2E+02 7.5E+00 2.4E+01
3.75E+00 7.2E+01 7.5E+00 2.4E+01
9.97E+00 1.0E+02 7.5E+00 2.4E+01
3.75E+00 7.3E+02 7.5E+00 2.4E+01
3.75E+00 1.2E+02 7.5E+00 2.4E+01
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-63
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
As Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
As EaFA-L04-1313-T01-A 1 1.22E+04
As EaFA-L04-1313-T02-A 1 1.14E+03
As EaFA-L04-1313-T03-A 1 1.12E+03
As EaFA-L04-1313-T04-A 1 7.18E+02
As EaFA-L04-1313-T05-A 1 2.73E+02
As EaFA-L04-1313-T06-A 1 1.30E+02
As EaFA-L04-1313-T07-A 1 1.24E+02
As EaFA-L04-1313-T08-A 1 1.32E+02
As EaFA-L04-1313-T09-A 1 1.07E+03
As EaFA-L04-1313-T01-B 1 1.17E+04
As EaFA-L04-1313-T02-B 1 1.15E+03
As EaFA-L04-1313-T03-B 1 1.01E+03
As EaFA-L04-1313-T04-B 1 5.88E+02
As EaFA-L04-1313-T05-B 1 2.83E+02
As EaFA-L04-1313-T06-B 1 1.23E+02
As EaFA-L04-1313-T07-B 1 1.68E+02
As EaFA-L04-1313-T08-B 1 1.35E+02
As EaFA-L04-1313-T09-B 1 6.26E+02
As EaFA-L04-1313-T01-C 1 1.25E+04
As EaFA-L04-1313-T02-C 1 1.14E+03
As EaFA-L04-1313-T03-C 1 1.11E+03
As EaFA-L04-1313-T04-C 1 5.48E+02
As EaFA-L04-1313-T05-C 1 2.42E+02
As EaFA-L04-1313-T06-C 1 1.13E+02
As EaFA-L04-1313-T07-C 1 1.22E+02
As EaFA-L04-1313-T08-C 1 1.36E+02
As EaFA-L04-1313-T09-C 1 9.12E+02
As EaFA-L04-1313-B01-A 1 3.09E+01 E
As EaFA-L04-1313-B02-A 1 3.26E+01 E
As EaFA-L04-1313-B03-A 1 4.09E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.22E+04 8.4E-01 1.1E+01 3.5E+01
1.14E+03 1.1E+00 1.1E+01 3.5E+01 10 325
1.12E+03 1.8E+00 1.1E+01 3.5E+01
7.18E+02 1.4E-01 1.1E+01 3.5E+01
2.73E+02 3.6E+00 1.1E+01 3.5E+01
1.30E+02 1.3E+01 1.1E+01 3.5E+01
1.24E+02 5.6E+00 1.1E+01 3.5E+01
1.32E+02 2.4E+00 1.1E+01 3.5E+01
1.07E+03 9.0E-01 1.1E+01 3.5E+01
1.17E+04 2.1E-01 1.1E+01 3.5E+01
1.15E+03 1.2E+00 1.1E+01 3.5E+01 10 325
1.01E+03 6.4E-01 1.1E+01 3.5E+01
5.88E+02 4.0E+00 1.1E+01 3.5E+01
2.83E+02 6.3E+00 1.1E+01 3.5E+01
1.23E+02 9.8E+00 1.1E+01 3.5E+01
1.68E+02 1.0E+01 1.1E+01 3.5E+01
1.35E+02 6.0E+00 1.1E+01 3.5E+01
6.26E+02 1.7E+00 1.1E+01 3.5E+01
1.25E+04 2.9E-01 1.1E+01 3.5E+01
1.14E+03 1.4E+00 1.1E+01 3.5E+01 10 325
1.11E+03 9.4E-01 1.1E+01 3.5E+01
5.48E+02 5.8E+00 1.1E+01 3.5E+01
2.42E+02 3.7E+00 1.1E+01 3.5E+01
1.13E+02 2.3E+01 1.1E+01 3.5E+01
1.22E+02 8.5E+00 1.1E+01 3.5E+01
1.36E+02 9.4E+00 1.1E+01 3.5E+01
9.12E+02 8.6E-01 1.1E+01 3.5E+01
3.09E+01 2.8E+00 1.1E+01 3.5E+01
3.26E+01 7.7E+01 1.1E+01 3.5E+01
4.09E+01 3.3E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
4.68E+03 109% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
4.92E+03 116% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
4.63E+03 107% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-64
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B EaFA-L04-1313-T01-A 1 4.99E+03
B EaFA-L04-1313-T02-A 1 4.52E+03
B EaFA-L04-1313-T03-A 1 4.44E+03
B EaFA-L04-1313-T04-A 1 4.48E+03
B EaFA-L04-1313-T05-A 1 4.61 E+03
B EaFA-L04-1313-T06-A 1 4.61 E+03
B EaFA-L04-1313-T07-A 1 4.67E+03
B EaFA-L04-1313-T08-A 1 3.58E+03
B EaFA-L04-1313-T09-A 1 2.76E+03
B EaFA-L04-1313-T01-B 1 4.91 E+03
B EaFA-L04-1313-T02-B 1 4.59E+03
B EaFA-L04-1313-T03-B 1 4.42E+03
B EaFA-L04-1313-T04-B 1 4.45E+03
B EaFA-L04-1313-T05-B 1 4.46E+03
B EaFA-L04-1313-T06-B 1 4.65E+03
B EaFA-L04-1313-T07-B 1 4.70E+03
B EaFA-L04-1313-T08-B 1 3.65E+03
B EaFA-L04-1313-T09-B 1 2.75E+03
B EaFA-L04-1313-T01-C 1 5.21E+03
B EaFA-L04-1313-T02-C 1 4.53E+03
B EaFA-L04-1313-T03-C 1 4.45E+03
B EaFA-L04-1313-T04-C 1 4.33E+03
B EaFA-L04-1313-T05-C 1 4.47E+03
B EaFA-L04-1313-T06-C 1 4.58E+03
B EaFA-L04-1313-T07-C 1 4.96E+03
B EaFA-L04-1313-T08-C 1 3.63E+03
B EaFA-L04-1313-T09-C 1 2.72E+03
B EaFA-L04-1313-B01-A 1 3.63E+01
B EaFA-L04-1313-B02-A 1 2.76E+01
B EaFA-L04-1313-B03-A 1 2.95E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.99E+03 4.9E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
4.52E+03 6.8E-01 1 .OE+00 3.2E+00 1000 100 5.39E+03 86% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
4.44E+03 1.4E+00 1 .OE+00 3.2E+00
4.48E+03 3.8E-01 1 .OE+00 3.2E+00
4.61E+03 2.2E-01 1 .OE+00 3.2E+00
4.61 E+03 1. OE+00 1 .OE+00 3.2E+00
4.67E+03 6.6E-01 1 .OE+00 3.2E+00
3.58E+03 7.8E-01 1 .OE+00 3.2E+00
2.76E+03 5.8E-01 1 .OE+00 3.2E+00
4.91 E+03 3.6E-01 1 .OE+00 3.2E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
4.59E+03 5.8E-01 1 .OE+00 3.2E+00 1000 100 5.42E+03 83% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
4.42E+03 2.5E+00 1 .OE+00 3.2E+00
4.45E+03 2.2E+00 1 .OE+00 3.2E+00
4.46E+03 1.8E+00 1 .OE+00 3.2E+00
4.65E+03 1.4E+00 1 .OE+00 3.2E+00
4.70E+03 1.8E-01 1 .OE+00 3.2E+00
3.65E+03 1.3E-01 1 .OE+00 3.2E+00
2.75E+03 9.7E-01 1 .OE+00 3.2E+00
5.21 E+03 5.4E-01 1 .OE+00 3.2E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
4.53E+03 6.7E-01 1 .OE+00 3.2E+00 1000 100 5.34E+03 81%VUICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
4.45E+03 1.7E+00 1. OE+00 3.2E+00
4.33E+03 6.0E-01 1. OE+00 3.2E+00
4.47E+03 5.2E-01 1. OE+00 3.2E+00
4.58E+03 1.5E+00 1. OE+00 3.2E+00
4.96E+03 4.7E-01 1. OE+00 3.2E+00
3.63E+03 7.5E-01 1. OE+00 3.2E+00
2.72E+03 5.7E-01 1. OE+00 3.2E+00
3.63E+01 2.3E+00 1. OE+00 3.2E+00
2.76E+01 1.8E+00 1. OE+00 3.2E+00
2.95E+01 1.9E+00 1. OE+00 3.2E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-65
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba EaFA-L04-1313-T01-A 1 7.05E+01
Ba EaFA-L04-1313-T02-A 1 1.17E+02
Ba EaFA-L04-1313-T03-A 1 1.28E+02
Ba EaFA-L04-1313-T04-A 1 2.93E+02
Ba EaFA-L04-1313-T05-A 1 3.46E+02
Ba EaFA-L04-1313-T06-A 1 3.35E+02
Ba EaFA-L04-1313-T07-A 1 3.21 E+02
Ba EaFA-L04-1313-T08-A 1 2.08E+02
Ba EaFA-L04-1313-T09-A 1 2.06E+02
Ba EaFA-L04-1313-T01-B 1 6.02E+01
Ba EaFA-L04-1313-T02-B 1 1.22E+02
Ba EaFA-L04-1313-T03-B 1 1.35E+02
Ba EaFA-L04-1313-T04-B 1 3.99E+02
Ba EaFA-L04-1313-T05-B 1 3.62E+02
Ba EaFA-L04-1313-T06-B 1 3.52E+02
Ba EaFA-L04-1313-T07-B 1 3.21E+02
Ba EaFA-L04-1313-T08-B 1 2.86E+02
Ba EaFA-L04-1313-T09-B 1 2.42E+02
Ba EaFA-L04-1313-T01-C 1 6.27E+01
Ba EaFA-L04-1313-T02-C 1 1 .44E+02
Ba EaFA-L04-1313-T03-C 1 1 .99E+02
Ba EaFA-L04-1313-T04-C 1 4.31E+02
Ba EaFA-L04-1313-T05-C 1 3.47E+02
Ba EaFA-L04-1313-T06-C 1 3.07E+02
Ba EaFA-L04-1313-T07-C 1 3.56E+02
Ba EaFA-L04-1313-T08-C 1 2. 91 E+02
Ba EaFA-L04-1313-T09-C 1 2.33E+02
Ba EaFA-L04-1313-B01-A 1 1 .22E+00 E
Ba EaFA-L04-1313-B02-A 1 6.07E+00
Ba EaFA-L04-1313-B03-A 1 8.00E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.05E+01 1.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
1.17E+02 5.6E-01 1 .OE+00 3.2E+00 10 325 3.40E+03 101% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
1.28E+02 1.3E+00 1 .OE+00 3.2E+00
2.93E+02 1.8E+00 1 .OE+00 3.2E+00
3.46E+02 8.9E-01 1. OE+00 3.2E+00
3.35E+02 3.7E-01 1. OE+00 3.2E+00
3.21 E+02 3.4E-01 1. OE+00 3.2E+00
2.08E+02 2.9E+00 1. OE+00 3.2E+00
2.06E+02 1.0E+01 1. OE+00 3.2E+00
6.02E+01 4.2E-01 1. OE+00 3.2E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
1.22E+02 3.4E-01 1.0E+00 3.2E+00 10 325 3.63E+03 108% VU ICP-OES 6/24/10 1 1:33 AM EPA Interlab L04 1313-1316 EaFA
1.35E+02 1.2E+00 1. OE+00 3.2E+00
3.99E+02 8.4E-01 1. OE+00 3.2E+00
3.62E+02 8.9E-01 1. OE+00 3.2E+00
3.52E+02 4.4E-01 1. OE+00 3.2E+00
3.21 E+02 2.8E-01 1. OE+00 3.2E+00
2.86E+02 3.0E-01 1. OE+00 3.2E+00
2.42E+02 2.7E+00 1. OE+00 3.2E+00
6.27E+01 3.6E-01 1. OE+00 3.2E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
1.44E+02 3.8E+00 1.0E+00 3.2E+00 10 325 3.39E+03 100% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
1.99E+02 1.7E-01 1. OE+00 3.2E+00
4.31 E+02 4.4E-01 1. OE+00 3.2E+00
3.47E+02 2.1E-01 1. OE+00 3.2E+00
3.07E+02 4.6E-01 1. OE+00 3.2E+00
3.56E+02 3.7E-01 1. OE+00 3.2E+00
2.91 E+02 5.2E-01 1. OE+00 3.2E+00
2.33E+02 3.6E+00 1. OE+00 3.2E+00
1.22E+00 2.3E+01 1. OE+00 3.2E+00
6.07E+00 3.2E+00 1. OE+00 3.2E+00
8.00E+00 2.1E+00 1.0E+00 3.2E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-66
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be EaFA-L04-1313-T01-A 1 2.40E+00 E
Be EaFA-L04-1313-T02-A 1 9.50E-01 U1/2
Be EaFA-L04-1313-T03-A 1 9.50E-01 U1/2
Be EaFA-L04-1313-T04-A 1 9.50E-01 U1/2
Be EaFA-L04-1313-T05-A 1 9.50E-01 U1/2
Be EaFA-L04-1313-T06-A 1 9.50E-01 U1/2
Be EaFA-L04-1313-T07-A 1 9.47E+00
Be EaFA-L04-1313-T08-A 1 1.34E+02
Be EaFA-L04-1313-T09-A 1 2.37E+02
Be EaFA-L04-1313-T01-B 1 9.50E-01 U1/2
Be EaFA-L04-1313-T02-B 1 9.50E-01 U1/2
Be EaFA-L04-1313-T03-B 1 9.50E-01 U1/2
Be EaFA-L04-1313-T04-B 1 9.50E-01 U1/2
Be EaFA-L04-1313-T05-B 1 9.50E-01 U1/2
Be EaFA-L04-1313-T06-B 1 9.50E-01 U1/2
Be EaFA-L04-1313-T07-B 1 9.25E+00
Be EaFA-L04-1313-T08-B 1 1.30E+02
Be EaFA-L04-1313-T09-B 1 2.37E+02
Be EaFA-L04-1313-T01-C 1 2.18E+00 E
Be EaFA-L04-1313-T02-C 1 9.50E-01 U1/2
Be EaFA-L04-1313-T03-C 1 9.50E-01 U1/2
Be EaFA-L04-1313-T04-C 1 9.50E-01 U1/2
Be EaFA-L04-1313-T05-C 1 9.50E-01 U1/2
Be EaFA-L04-1313-T06-C 1 9.50E-01 U1/2
Be EaFA-L04-1313-T07-C 1 4.70E+00 E
Be EaFA-L04-1313-T08-C 1 1.30E+02
Be EaFA-L04-1313-T09-C 1 2.35E+02
Be EaFA-L04-1313-B01-A 1 9.50E-01 U1/2
Be EaFA-L04-1313-B02-A 1 9.50E-01 U1/2
Be EaFA-L04-1313-B03-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.40E+00 1.2E+01 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
9.50E-01 4.8E+01 1 .9E+00 6.0E+00 10 325 3.51E+03 108% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
9.50E-01 9.6E+01 1 .9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 3.7E+02 1 .9E+00 6.0E+00
9.50E-01 7.8E+01 1 .9E+00 6.0E+00
9.47E+00 4.8E+00 1 .9E+00 6.0E+00
1.34E+02 5.8E-01 1 .9E+00 6.0E+00
2.37E+02 3.4E-01 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
9.50E-01 4.6E+01 1.9E+00 6.0E+00 10 325 3.72E+03 1 14% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
9.50E-01 8.2E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 8.3E+01 1.9E+00 6.0E+00
9.50E-01 2.5E+01 1.9E+00 6.0E+00
9.25E+00 2.0E+00 1.9E+00 6.0E+00
1.30E+02 4.3E-01 1.9E+00 6.0E+00
2.37E+02 5.3E-01 1.9E+00 6.0E+00
2.18E+00 1.1E+01 1.9E+00 6.0E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
9.50E-01 1.1E+02 1.9E+00 6.0E+00 10 325 3.49E+03 107% VU ICP-OES 6/24/10 11 :51 AM EPA Interlab L04 1313-1316 EaFA
9.50E-01 7.6E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 4.1E+01 1.9E+00 6.0E+00
9.50E-01 4.5E+02 1 .9E+00 6.0E+00
4.70E+00 1.0E+01 1.9E+00 6.0E+00
1.30E+02 6.6E-01 1 .9E+00 6.0E+00
2.35E+02 1.1E+00 1 .9E+00 6.0E+00
9.50E-01 2.3E+02 1 .9E+00 6.0E+00
9.50E-01 7.7E+01 1 .9E+00 6.0E+00
9.50E-01 3.3E+01 1 .9E+00 6.0E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-67
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cd Sample Dilution Cone. Qualifier Revi
ug/L
Cd EaFA-L04-1313-T01-A 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T02-A 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T03-A 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T04-A 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T05-A 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T06-A 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T07-A 1 3.74E+01
Cd EaFA-L04-1313-T08-A 1 2.90E+01
Cd EaFA-L04-1313-T09-A 1 3.15E+01
Cd EaFA-L04-1313-T01-B 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T02-B 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T03-B 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T04-B 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T05-B 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T06-B 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T07-B 1 3.71 E+01
Cd EaFA-L04-1313-T08-B 1 3.00E+01
Cd EaFA-L04-1313-T09-B 1 3.09E+01
Cd EaFA-L04-1313-T01-C 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T02-C 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T03-C 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T04-C 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T05-C 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T06-C 1 1.10E+OOU1/2
Cd EaFA-L04-1313-T07-C 1 3.43E+01
Cd EaFA-L04-1313-T08-C 1 2.99E+01
Cd EaFA-L04-1313-T09-C 1 3.15E+01
Cd EaFA-L04-1313-B01-A 1 1.10E+OOU1/2
Cd EaFA-L04-1313-B02-A 1 1.10E+OOU1/2
Cd EaFA-L04-1313-B03-A 1 1.10E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.8E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
1.10E+00 1.1E+02 2.2E+00 7.0E+00 10 325 3.51E+03 108% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
1.10E+00 4.6E+02 2.2E+00 7.0E+00
1.10E+00 1.2E+03 2.2E+00 7.0E+00
1.10E+00 4.3E+01 2.2E+00 7.0E+00
1.10E+00 5.8E+02 2.2E+00 7.0E+00
3.74E+01 1.7E+00 2.2E+00 7.0E+00
2.90E+01 3.2E+00 2.2E+00 7.0E+00
3.15E+01 6.0E-01 2.2E+00 7.0E+00
1.10E+00 5.2E+00 2.2E+00 7.0E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
1.10E+00 4.8E+02 2.2E+00 7.0E+00 10 325 3.75E+03 115% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
1.10E+00 7.1E+02 2.2E+00 7.0E+00
1.10E+00 4.1E+02 2.2E+00 7.0E+00
1.10E+00 3.1E+02 2.2E+00 7.0E+00
1.10E+00 1.8E+01 2.2E+00 7.0E+00
3.71E+01 1.3E+00 2.2E+00 7.0E+00
3.00E+01 1.1E+00 2.2E+00 7.0E+00
3.09E+01 1.9E+00 2.2E+00 7.0E+00
1.10E+00 6.4E+01 2.2E+00 7.0E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
1.10E+00 2.5E+02 2.2E+00 7.0E+00 10 325 3.51E+03 108% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
1.10E+00 2.1E+01 2.2E+00 7.0E+00
1.10E+00 2.7E+02 2.2E+00 7.0E+00
1.10E+00 1.0E+03 2.2E+00 7.0E+00
1.10E+00 2.2E+01 2.2E+00 7.0E+00
3.43E+01 2.1E+00 2.2E+00 7.0E+00
2.99E+01 1.4E+00 2.2E+00 7.0E+00
3.15E+01 1.3E+00 2.2E+00 7.0E+00
1.10E+00 1.7E+01 2.2E+00 7.0E+00
1.10E+00 1.4E+03 2.2E+00 7.0E+00
1.10E+00 6.7E+01 2.2E+00 7.0E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-68
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca EaFA-L04-1313-T01-A 1 1.36E+04
Ca EaFA-L04-1313-T02-A 1 4.05E+04
Ca EaFA-L04-1313-T03-A 1 9.18E+04
Ca EaFA-L04-1313-T04-A 1 1.23E+05
Ca EaFA-L04-1313-T05-A 1 1.43E+05
Ca EaFA-L04-1313-T06-A 1 1.54E+05
Ca EaFA-L04-1313-T07-A 1 1.56E+05
Ca EaFA-L04-1313-T08-A 1 1.33E+05
Ca EaFA-L04-1313-T09-A 1 1.21E+05
Ca EaFA-L04-1313-T01-B 1 1.47E+04
Ca EaFA-L04-1313-T02-B 1 3.92E+04
Ca EaFA-L04-1313-T03-B 1 8.95E+04
Ca EaFA-L04-1313-T04-B 1 1.25E+05
Ca EaFA-L04-1313-T05-B 1 1.41E+05
Ca EaFA-L04-1313-T06-B 1 1.55E+05
Ca EaFA-L04-1313-T07-B 1 1.58E+05
Ca EaFA-L04-1313-T08-B 1 1.35E+05
Ca EaFA-L04-1313-T09-B 1 1.20E+05
Ca EaFA-L04-1313-T01-C 1 1.40E+04
Ca EaFA-L04-1313-T02-C 1 3.92E+04
Ca EaFA-L04-1313-T03-C 1 9.32E+04
Ca EaFA-L04-1313-T04-C 1 1.22E+05
Ca EaFA-L04-1313-T05-C 1 1.39E+05
Ca EaFA-L04-1313-T06-C 1 1.52E+05
Ca EaFA-L04-1313-T07-C 1 1.68E+05
Ca EaFA-L04-1313-T08-C 1 1.35E+05
Ca EaFA-L04-1313-T09-C 1 1.20E+05
Ca EaFA-L04-1313-B01-A 1 1.86E+02
Ca EaFA-L04-1313-B02-A 1 1.28E+03
Ca EaFA-L04-1313-B03-A 1 1.38E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.36E+04 6.4E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
4.05E+04 1.6E-01 2.6E+00 8.3E+00 1000 100 4.14E+04 83% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
9.18E+04 8.6E-01 2.6E+00 8.3E+00
1.23E+05 5.0E-01 2.6E+00 8.3E+00
1.43E+05 7.9E-01 2.6E+00 8.3E+00
1.54E+05 2.4E-01 2.6E+00 8.3E+00
1.56E+05 5.4E-01 2.6E+00 8.3E+00
1.33E+05 6.1E-01 2.6E+00 8.3E+00
1.21E+05 3.4E-01 2.6E+00 8.3E+00
1.47E+04 2.1E+00 2.6E+00 8.3E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.92E+04 2.0E-01 2.6E+00 8.3E+00 1000 100 4.01E+04 88% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
8.95E+04 4.4E-01 2.6E+00 8.3E+00
1.25E+05 7.7E-01 2.6E+00 8.3E+00
1.41E+05 7.0E-01 2.6E+00 8.3E+00
1.55E+05 7.7E-01 2.6E+00 8.3E+00
1.58E+05 5.8E-01 2.6E+00 8.3E+00
1.35E+05 4.4E-01 2.6E+00 8.3E+00
1.20E+05 5.7E-01 2.6E+00 8.3E+00
1.40E+04 1.3E+00 2.6E+00 8.3E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
3.92E+04 5.9E-01 2.6E+00 8.3E+00 1000 100 4.00E+04 81% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
9.32E+04 5.3E-01 2.6E+00 8.3E+00
1.22E+05 4.0E-01 2.6E+00 8.3E+00
1.39E+05 3.4E-01 2.6E+00 8.3E+00
1.52E+05 6.8E-01 2.6E+00 8.3E+00
1.68E+05 5.5E-01 2.6E+00 8.3E+00
1.35E+05 7.7E-01 2.6E+00 8.3E+00
1.20E+05 6.0E-01 2.6E+00 8.3E+00
1.86E+02 6.9E+00 2.6E+00 8.3E+00
1.28E+03 1.0E+00 2.6E+00 8.3E+00
1.38E+02 4.3E+01 2.6E+00 8.3E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-69
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qualifier
ug/L
Cr EaFA-L04-1313-T01-A 1 5.40E+02
Cr EaFA-L04-1313-T02-A 1 3.32E+02
Cr EaFA-L04-1313-T03-A 1 2.58E+02
Cr EaFA-L04-1313-T04-A 1 1.90E+02
Cr EaFA-L04-1313-T05-A 1 9.70E+01
Cr EaFA-L04-1313-T06-A 1 1.94E+01
Cr EaFA-L04-1313-T07-A 1 3.61E+00 E
Cr EaFA-L04-1313-T08-A 1 2.52E+02
Cr EaFA-L04-1313-T09-A 1 1.61E+03
Cr EaFA-L04-1313-T01-B 1 5.65E+02
Cr EaFA-L04-1313-T02-B 1 3.39E+02
Cr EaFA-L04-1313-T03-B 1 2.66E+02
Cr EaFA-L04-1313-T04-B 1 1.73E+02
Cr EaFA-L04-1313-T05-B 1 8.08E+01
Cr EaFA-L04-1313-T06-B 1 1.87E+01
Cr EaFA-L04-1313-T07-B 1 2.24E+00 E
Cr EaFA-L04-1313-T08-B 1 2.15E+02
Cr EaFA-L04-1313-T09-B 1 1.61E+03
Cr EaFA-L04-1313-T01-C 1 5.76E+02
Cr EaFA-L04-1313-T02-C 1 3.52E+02
Cr EaFA-L04-1313-T03-C 1 2.56E+02
Cr EaFA-L04-1313-T04-C 1 1.74E+02
Cr EaFA-L04-1313-T05-C 1 9.35E+01
Cr EaFA-L04-1313-T06-C 1 2.45E+01
Cr EaFA-L04-1313-T07-C 1 2.14E+00 E
Cr EaFA-L04-1313-T08-C 1 2.01E+02
Cr EaFA-L04-1313-T09-C 1 1.61E+03
Cr EaFA-L04-1313-B01-A 1 6.00E-01 U1/2
Cr EaFA-L04-1313-B02-A 1 6.00E-01 U1/2
Cr EaFA-L04-1313-B03-A 1 8.48E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.40E+02 3.2E-01 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.32E+02 8.8E-01 1 .2E+00 3.8E+00 10 325 3.64E+03 102% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
2.58E+02 2.9E-01 1.2E+00 3.8E+00
1.90E+02 5.6E-01 1.2E+00 3.8E+00
9.70E+01 1.9E+00 1.2E+00 3.8E+00
1.94E+01 5.8E+00 1.2E+00 3.8E+00
3.61 E+00 6.6E+01 1.2E+00 3.8E+00
2.52E+02 4.0E-01 1.2E+00 3.8E+00
1.61E+03 6.5E-02 1.2E+00 3.8E+00
5.65E+02 1.0E+00 1.2E+00 3.8E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.39E+02 4.1E-01 1.2E+00 3.8E+00 10 325 3.85E+03 108% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
2.66E+02 7.7E-02 1.2E+00 3.8E+00
1.73E+02 3.0E-01 1.2E+00 3.8E+00
8.08E+01 1.5E+00 1.2E+00 3.8E+00
1.87E+01 1.3E+01 1.2E+00 3.8E+00
2.24E+00 5.3E+01 1.2E+00 3.8E+00
2.15E+02 5.3E-01 1.2E+00 3.8E+00
1.61E+03 5.4E-01 1.2E+00 3.8E+00
5.76E+02 1.0E+00 1.2E+00 3.8E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
3.52E+02 8.1E-01 1.2E+00 3.8E+00 10 325 3.65E+03 102% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
2.56E+02 3.4E-01 1.2E+00 3.8E+00
1.74E+02 1.1 E+00 1.2E+00 3.8E+00
9.35E+01 1.3E+00 1.2E+00 3.8E+00
2.45E+01 2.6E+00 1.2E+00 3.8E+00
2.14E+00 7.2E+00 1.2E+00 3.8E+00
2.01 E+02 4.9E-01 1.2E+00 3.8E+00
1.61E+03 4.7E-01 1.2E+00 3.8E+00
6.00E-01 5.8E+01 1.2E+00 3.8E+00
6.00E-01 1.1 E+02 1.2E+00 3.8E+00
8.48E+00 3.5E+01 1.2E+00 3.8E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-70
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Co Sample Dilution Cone. Qualifier Revi
ug/L
Co EaFA-L04-1313-T01-A 1 9.00E-01 U1/2
Co EaFA-L04-1313-T02-A 1 9.00E-01 U1/2
Co EaFA-L04-1313-T03-A 1 9.00E-01 U1/2
Co EaFA-L04-1313-T04-A 1 3.39E+00 E
Co EaFA-L04-1313-T05-A 1 8.06E+00
Co EaFA-L04-1313-T06-A 1 4.67E+01
Co EaFA-L04-1313-T07-A 1 2.36E+02
Co EaFA-L04-1313-T08-A 1 2.02E+02
Co EaFA-L04-1313-T09-A 1 3.84E+02
Co EaFA-L04-1313-T01-B 1 9.00E-01 U1/2
Co EaFA-L04-1313-T02-B 1 9.00E-01 U1/2
Co EaFA-L04-1313-T03-B 1 9.00E-01 U1/2
Co EaFA-L04-1313-T04-B 1 9.00E-01 U1/2
Co EaFA-L04-1313-T05-B 1 7.41 E+00
Co EaFA-L04-1313-T06-B 1 5.74E+01
Co EaFA-L04-1313-T07-B 1 2.35E+02
Co EaFA-L04-1313-T08-B 1 2.03E+02
Co EaFA-L04-1313-T09-B 1 3.75E+02
Co EaFA-L04-1313-T01-C 1 9.00E-01 U1/2
Co EaFA-L04-1313-T02-C 1 9.00E-01 U1/2
Co EaFA-L04-1313-T03-C 1 9.00E-01 U1/2
Co EaFA-L04-1313-T04-C 1 9.00E-01 U1/2
Co EaFA-L04-1313-T05-C 1 4.76E+00 E
Co EaFA-L04-1313-T06-C 1 3.82E+01
Co EaFA-L04-1313-T07-C 1 2.35E+02
Co EaFA-L04-1313-T08-C 1 2.02E+02
Co EaFA-L04-1313-T09-C 1 3.74E+02
Co EaFA-L04-1313-B01-A 1 9.00E-01 U1/2
Co EaFA-L04-1313-B02-A 1 9.00E-01 U1/2
Co EaFA-L04-1313-B03-A 1 1.81 E+00 E
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.0E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 1.3E+02 1.8E+00 5.7E+00 10 325 3.26E+03 100% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 1.1E+02 1.8E+00 5.7E+00
3.39E+00 1.1E+02 1.8E+00 5.7E+00
8.06E+00 3.8E+01 1.8E+00 5.7E+00
4.67E+01 3.1 E+00 1.8E+00 5.7E+00
2.36E+02 7.6E-01 1.8E+00 5.7E+00
2.02E+02 1.9E-01 1.8E+00 5.7E+00
3.84E+02 6.4E-01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 4.8E+01 1.8E+00 5.7E+00 10 325 3.48E+03 107% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 1.1E+03 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
7.41 E+00 1.6E+01 1.8E+00 5.7E+00
5.74E+01 3.2E+00 1.8E+00 5.7E+00
2.35E+02 1.4E+00 1.8E+00 5.7E+00
2.03E+02 8.7E-01 1.8E+00 5.7E+00
3.75E+02 8.6E-01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 1.9E+02 1.8E+00 5.7E+00 10 325 3.28E+03 101% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 8.9E+01 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
4.76E+00 5.8E+01 1.8E+00 5.7E+00
3.82E+01 1.9E+00 1.8E+00 5.7E+00
2.35E+02 8.8E-01 1.8E+00 5.7E+00
2.02E+02 3.6E-01 1.8E+00 5.7E+00
3.74E+02 4.4E-01 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 3.1E+02 1.8E+00 5.7E+00
1.81 E+00 6.6E+01 1.8E+00 5.7E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                           1-71
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cu Sample Dilution Cone. Qualifier Revi
ug/L
Cu EaFA-L04-1313-T01-A 1 8.48E+01
Cu EaFA-L04-1313-T02-A 1 1.85E+OOU1/2
Cu EaFA-L04-1313-T03-A 1 1.85E+OOU1/2
Cu EaFA-L04-1313-T04-A 1 8.95E+00 E
Cu EaFA-L04-1313-T05-A 1 4.55E+00 E
Cu EaFA-L04-1313-T06-A 1 8.58E+00 E
Cu EaFA-L04-1313-T07-A 1 2.39E+02
Cu EaFA-L04-1313-T08-A 1 2.00E+03
Cu EaFA-L04-1313-T09-A 1 2.74E+03
Cu EaFA-L04-1313-T01-B 1 1.42E+01
Cu EaFA-L04-1313-T02-B 1 1.85E+OOU1/2
Cu EaFA-L04-1313-T03-B 1 1.85E+OOU1/2
Cu EaFA-L04-1313-T04-B 1 6.23E+00 E
Cu EaFA-L04-1313-T05-B 1 8.48E+00 E
Cu EaFA-L04-1313-T06-B 1 1.30E+01
Cu EaFA-L04-1313-T07-B 1 2.04E+02
Cu EaFA-L04-1313-T08-B 1 1.97E+03
Cu EaFA-L04-1313-T09-B 1 2.77E+03
Cu EaFA-L04-1313-T01-C 1 1.85E+OOU1/2
Cu EaFA-L04-1313-T02-C 1 4.48E+00 E
Cu EaFA-L04-1313-T03-C 1 3.95E+00 E
Cu EaFA-L04-1313-T04-C 1 1.85E+OOU1/2
Cu EaFA-L04-1313-T05-C 1 1.04E+01 E
Cu EaFA-L04-1313-T06-C 1 9.57E+00 E
Cu EaFA-L04-1313-T07-C 1 7.31 E+01
Cu EaFA-L04-1313-T08-C 1 1.94E+03
Cu EaFA-L04-1313-T09-C 1 2.74E+03
Cu EaFA-L04-1313-B01-A 1 1.85E+OOU1/2
Cu EaFA-L04-1313-B02-A 1 1.03E+01 E
Cu EaFA-L04-1313-B03-A 1 8.60E+00 E
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.48E+01 1.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
1.85E+00 1.8E+02 3.7E+00 1.2E+01 10 325 3.26E+03 100% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
1.85E+00 4.7E+02 3.7E+00 1.2E+01
8.95E+00 7.5E+01 3.7E+00 1.2E+01
4.55E+00 1.9E+02 3.7E+00 1.2E+01
8.58E+00 6.2E+01 3.7E+00 1.2E+01
2.39E+02 1.8E+00 3.7E+00 1.2E+01
2.00E+03 9.8E-01 3.7E+00 1.2E+01
2.74E+03 1.0E+00 3.7E+00 1.2E+01
1.42E+01 5.5E+01 3.7E+00 1.2E+01
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
1.85E+00 2.9E+02 3.7E+00 1.2E+01 10 325 3.48E+03 107% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
1.85E+00 1.0E+02 3.7E+00 1.2E+01
6.23E+00 1.2E+01 3.7E+00 1.2E+01
8.48E+00 3.3E+01 3.7E+00 1.2E+01
1.30E+01 4.6E+01 3.7E+00 1.2E+01
2.04E+02 2.7E+00 3.7E+00 1.2E+01
1.97E+03 1.3E+00 3.7E+00 1.2E+01
2.77E+03 1.3E+00 3.7E+00 1.2E+01
1.85E+00 2.4E+03 3.7E+00 1.2E+01
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
4.48E+00 1.3E+02 3.7E+00 1.2E+01 10 325 3.26E+03 100% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
3.95E+00 1.3E+02 3.7E+00 1.2E+01
1.85E+00 2.4E+02 3.7E+00 1.2E+01
1.04E+01 4.4E+01 3.7E+00 1.2E+01
9.57E+00 4.8E+01 3.7E+00 1.2E+01
7.31 E+01 5.8E+00 3.7E+00 1.2E+01
1.94E+03 1.3E+00 3.7E+00 1.2E+01
2.74E+03 9.9E-02 3.7E+00 1.2E+01
1.85E+00 6.9E+01 3.7E+00 1.2E+01
1.03E+01 1.6E+01 3.7E+00 1.2E+01
8.60E+00 6.4E+01 3.7E+00 1.2E+01
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-72
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe EaFA-L04-1313-T01-A 1 6.41 E+01
Fe EaFA-L04-1313-T02-A 1 1.51 E+01
Fe EaFA-L04-1313-T03-A 1 7.09E+00
Fe EaFA-L04-1313-T04-A 1 1.00E+OOU1/2
Fe EaFA-L04-1313-T05-A 1 1.00E+OOU1/2
Fe EaFA-L04-1313-T06-A 1 1.00E+OOU1/2
Fe EaFA-L04-1313-T07-A 1 1.00E+OOU1/2
Fe EaFA-L04-1313-T08-A 1 6.50E+02
Fe EaFA-L04-1313-T09-A 1 2.98E+04
Fe EaFA-L04-1313-T01-B 1 1.84E+01
Fe EaFA-L04-1313-T02-B 1 1.55E+01
Fe EaFA-L04-1313-T03-B 1 6.68E+00
Fe EaFA-L04-1313-T04-B 1 2.80E+00 E
Fe EaFA-L04-1313-T05-B 1 1.00E+OOU1/2
Fe EaFA-L04-1313-T06-B 1 2.50E+00 E
Fe EaFA-L04-1313-T07-B 1 4.01 E+01
Fe EaFA-L04-1313-T08-B 1 5.08E+02
Fe EaFA-L04-1313-T09-B 1 2.67E+04
Fe EaFA-L04-1313-T01-C 1 1.39E+01
Fe EaFA-L04-1313-T02-C 1 1.28E+01
Fe EaFA-L04-1313-T03-C 1 4.04E+00 E
Fe EaFA-L04-1313-T04-C 1 1.00E+OOU1/2
Fe EaFA-L04-1313-T05-C 1 1.00E+OOU1/2
Fe EaFA-L04-1313-T06-C 1 1.00E+OOU1/2
Fe EaFA-L04-1313-T07-C 1 2.98E+00 E
Fe EaFA-L04-1313-T08-C 1 5.00E+02
Fe EaFA-L04-1313-T09-C 1 2.83E+04
Fe EaFA-L04-1313-B01-A 1 1.00E+OOU1/2
Fe EaFA-L04-1313-B02-A 1 1.43E+01
Fe EaFA-L04-1313-B03-A 1 9.81 E+00
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.41E+01 2.3E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
1.51E+01 3.3E+00 2.0E+00 6.4E+00 1000 100 1 .03E+03 101% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
7.09E+00 4.4E+00 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
6.50E+02 1.3E+00 2.0E+00 6.4E+00
2.98E+04 3.1E-01 2.0E+00 6.4E+00
1.84E+01 3.2E+00 2.0E+00 6.4E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
1.55E+01 2.4E+00 2.0E+00 6.4E+00 1000 100 1 .09E+03 108% VU ICP-OES 6/24/10 11 :33 AM EPA Interlab L04 1313-1316 EaFA
6.68E+00 1.0E+01 2.0E+00 6.4E+00
2.80E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00
2.50E+00 2.3E+01 2.0E+00 6.4E+00
4.01 E+01 1.6E+00 2.0E+00 6.4E+00
5.08E+02 9.3E-01 2.0E+00 6.4E+00
2.67E+04 6.3E-01 2.0E+00 6.4E+00
1.39E+01 3.0E+00 2.0E+00 6.4E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
1.28E+01 1.4E+00 2.0E+00 6.4E+00 1000 100 1.02E+03 101% VU ICP-OES 6/24/10 11 :51 AM EPA Interlab L04 1313-1316 EaFA
4.04E+00 4.1 E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
2.98E+00 7.6E+00 2.0E+00 6.4E+00
5.00E+02 1.3E-01 2.0E+00 6.4E+00
2.83E+04 6.9E-01 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.43E+01 2.0E+00 2.0E+00 6.4E+00
9.81 E+00 5.8E+00 2.0E+00 6.4E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-73
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Pb Sample Dilution Cone. Qualifier Revi
ug/L
Pb EaFA-L04-1313-T01-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T02-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T03-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T04-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T05-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T06-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T07-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T08-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T09-A 1 3.24E+01
Pb EaFA-L04-1313-T01-B 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T02-B 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T03-B 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T04-B 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T05-B 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T06-B 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T07-B 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T08-B 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T09-B 1 1 J7E+01 E
Pb EaFA-L04-1313-T01-C 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T02-C 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T03-C 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T04-C 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T05-C 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T06-C 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T07-C 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T08-C 1 3.40E+00 U1/2
Pb EaFA-L04-1313-T09-C 1 3.23E+01
Pb EaFA-L04-1313-B01-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-B02-A 1 3.40E+00 U1/2
Pb EaFA-L04-1313-B03-A 1 3.40E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 2.0E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.40E+00 8.4E+01 6.8E+00 2.2E+01 10 325 3.27E+03 100% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
3.40E+00 6.8E+01 6.8E+00 2.2E+01
3.40E+00 3.4E+04 6.8E+00 2.2E+01
3.40E+00 5.4E+01 6.8E+00 2.2E+01
3.40E+00 2.5E+02 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
3.40E+00 6.8E+01 6.8E+00 2.2E+01
3.24E+01 1.2E+01 6.8E+00 2.2E+01
3.40E+00 3.0E+02 6.8E+00 2.2E+01
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.40E+00 1.2E+02 6.8E+00 2.2E+01 10 325 3.48E+03 107% VU ICP-OES 6/24/10 1 1:33 AM EPA Interlab L04 1313-1316 EaFA
3.40E+00 4.3E+01 6.8E+00 2.2E+01
3.40E+00 3.9E+01 6.8E+00 2.2E+01
3.40E+00 3.1E+02 6.8E+00 2.2E+01
3.40E+00 5.3E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
1.77E+01 2.6E+01 6.8E+00 2.2E+01
3.40E+00 2.5E+02 6.8E+00 2.2E+01
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA I nterlabL04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA I nterlabL04 1313-1316 EaFA
3.40E+00 4.3E+02 6.8E+00 2.2E+01 10 325 3.25E+03 100% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
3.40E+00 3.4E+01 6.8E+00 2.2E+01
3.40E+00 3.5E+01 6.8E+00 2.2E+01
3.40E+00 8.2E+01 6.8E+00 2.2E+01
3.40E+00 2.5E+02 6.8E+00 2.2E+01
3.40E+00 4.0E+01 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.23E+01 5.8E+00 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.40E+00 7.7E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+01 6.8E+00 2.2E+01
VUICP-OES 6/24/10 11:53 AM EPA I nterlabL04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA I nterlabL04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA I nterlabL04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA I nterlabL04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA I nterlabL04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA I nterlabL04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA I nterlabL04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-74
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li EaFA-L04-1313-T01-A 1 2.48E+03
Li EaFA-L04-1313-T02-A 1 3.13E+03
Li EaFA-L04-1313-T03-A 1 3.54E+03
Li EaFA-L04-1313-T04-A 1 3.66E+03
Li EaFA-L04-1313-T05-A 1 3.80E+03
Li EaFA-L04-1313-T06-A 1 3.83E+03
Li EaFA-L04-1313-T07-A 1 3.69E+03
Li EaFA-L04-1313-T08-A 1 2.34E+03
Li EaFA-L04-1313-T09-A 1 1.54E+03
Li EaFA-L04-1313-T01-B 1 2.50E+03
Li EaFA-L04-1313-T02-B 1 3.23E+03
Li EaFA-L04-1313-T03-B 1 3.48E+03
Li EaFA-L04-1313-T04-B 1 3.62E+03
Li EaFA-L04-1313-T05-B 1 3.74E+03
Li EaFA-L04-1313-T06-B 1 3.90E+03
Li EaFA-L04-1313-T07-B 1 3.72E+03
Li EaFA-L04-1313-T08-B 1 2.43E+03
Li EaFA-L04-1313-T09-B 1 1.55E+03
Li EaFA-L04-1313-T01-C 1 2.54E+03
Li EaFA-L04-1313-T02-C 1 3.17E+03
Li EaFA-L04-1313-T03-C 1 3.53E+03
Li EaFA-L04-1313-T04-C 1 3.52E+03
Li EaFA-L04-1313-T05-C 1 3.66E+03
Li EaFA-L04-1313-T06-C 1 3.76E+03
Li EaFA-L04-1313-T07-C 1 3.94E+03
Li EaFA-L04-1313-T08-C 1 2.43E+03
Li EaFA-L04-1313-T09-C 1 1.53E+03
Li EaFA-L04-1313-B01-A 1 2.78E+00 E
Li EaFA-L04-1313-B02-A 1 9.50E-01 U1/2
Li EaFA-L04-1313-B03-A 1 2.67E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.48E+03 6.2E-01 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.13E+03 2.6E-01 1 .9E+00 6.0E+00 10 325 6.04E+03 90% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
3.54E+03 9.6E-01 1 .9E+00 6.0E+00
3.66E+03 5.3E-01 1 .9E+00 6.0E+00
3.80E+03 7.5E-01 1 .9E+00 6.0E+00
3.83E+03 5.1E-01 1 .9E+00 6.0E+00
3.69E+03 6.2E-01 1 .9E+00 6.0E+00
2.34E+03 6.9E-01 1 .9E+00 6.0E+00
1.54E+03 8.7E-01 1 .9E+00 6.0E+00
2.50E+03 1.2E-01 1 .9E+00 6.0E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.23E+03 1.7E-01 1 .9E+00 6.0E+00 10 325 6.33E+03 95% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
3.48E+03 1.7E-01 1 .9E+00 6.0E+00
3.62E+03 1.1E+00 1 .9E+00 6.0E+00
3.74E+03 1.2E+00 1 .9E+00 6.0E+00
3.90E+03 7.0E-01 1 .9E+00 6.0E+00
3.72E+03 2.8E-01 1 .9E+00 6.0E+00
2.43E+03 2.1E-01 1 .9E+00 6.0E+00
1.55E+03 8.7E-01 1 .9E+00 6.0E+00
2.54E+03 8.6E-01 1 .9E+00 6.0E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
3.17E+03 8.2E-01 1 .9E+00 6.0E+00 10 325 6.09E+03 90% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
3.53E+03 5.5E-01 1 .9E+00 6.0E+00
3.52E+03 2.1E-01 1 .9E+00 6.0E+00
3.66E+03 4.1E-01 1 .9E+00 6.0E+00
3.76E+03 6.9E-01 1 .9E+00 6.0E+00
3.94E+03 3.2E-01 1 .9E+00 6.0E+00
2.43E+03 5.6E-01 1 .9E+00 6.0E+00
1.53E+03 2.3E-01 1 .9E+00 6.0E+00
2.78E+00 5.4E+01 1 .9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
2.67E+00 2.1E+01 1.9E+00 6.0E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-75
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn EaFA-L04-1313-T01-A 1 5.34E+00 E
Mn EaFA-L04-1313-T02-A 1 1.00E+OOU1/2
Mn EaFA-L04-1313-T03-A 1 1.00E+OOU1/2
Mn EaFA-L04-1313-T04-A 1 3.21E+00 E
Mn EaFA-L04-1313-T05-A 1 5.40E+01
Mn EaFA-L04-1313-T06-A 1 3.49E+02
Mn EaFA-L04-1313-T07-A 1 9.13E+02
Mn EaFA-L04-1313-T08-A 1 1.12E+03
Mn EaFA-L04-1313-T09-A 1 1.54E+03
Mn EaFA-L04-1313-T01-B 1 1.00E+OOU1/2
Mn EaFA-L04-1313-T02-B 1 1.00E+OOU1/2
Mn EaFA-L04-1313-T03-B 1 2.74E+00 E
Mn EaFA-L04-1313-T04-B 1 7.02E+00
Mn EaFA-L04-1313-T05-B 1 7.58E+01
Mn EaFA-L04-1313-T06-B 1 4.22E+02
Mn EaFA-L04-1313-T07-B 1 9.08E+02
Mn EaFA-L04-1313-T08-B 1 1.11E+03
Mn EaFA-L04-1313-T09-B 1 1.53E+03
Mn EaFA-L04-1313-T01-C 1 1.00E+OOU1/2
Mn EaFA-L04-1313-T02-C 1 1.00E+OOU1/2
Mn EaFA-L04-1313-T03-C 1 2.89E+00 E
Mn EaFA-L04-1313-T04-C 1 6.66E+00
Mn EaFA-L04-1313-T05-C 1 5.14E+01
Mn EaFA-L04-1313-T06-C 1 3.27E+02
Mn EaFA-L04-1313-T07-C 1 9.30E+02
Mn EaFA-L04-1313-T08-C 1 1.10E+03
Mn EaFA-L04-1313-T09-C 1 1.52E+03
Mn EaFA-L04-1313-B01-A 1 1.00E+OOU1/2
Mn EaFA-L04-1313-B02-A 1 2.29E+00 E
Mn EaFA-L04-1313-B03-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.34E+00 4.0E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.2E+02 2.0E+00 6.4E+00
3.21E+00 3.3E+00 2.0E+00 6.4E+00
5.40E+01 1.0E+00 2.0E+00 6.4E+00
3.49E+02 2.7E-01 2.0E+00 6.4E+00
9.13E+02 5.8E-01 2.0E+00 6.4E+00
1.12E+03 4.3E-01 2.0E+00 6.4E+00
1.54E+03 1.1E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00 10 325
2.74E+00 1.1E+01 2.0E+00 6.4E+00
7.02E+00 1.4E+00 2.0E+00 6.4E+00
7.58E+01 7.8E-01 2.0E+00 6.4E+00
4.22E+02 4.4E-01 2.0E+00 6.4E+00
9.08E+02 8.0E-01 2.0E+00 6.4E+00
1.11E+03 2.4E-01 2.0E+00 6.4E+00
1.53E+03 8.9E-01 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 6.9E+01 2.0E+00 6.4E+00 10 325
2.89E+00 5.1E+00 2.0E+00 6.4E+00
6.66E+00 3.0E+00 2.0E+00 6.4E+00
5.14E+01 3.1E-01 2.0E+00 6.4E+00
3.27E+02 1.0E-01 2.0E+00 6.4E+00
9.30E+02 8.7E-01 2.0E+00 6.4E+00
1.10E+03 4.7E-01 2.0E+00 6.4E+00
1.52E+03 7.4E-02 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
2.29E+00 1.2E+00 2.0E+00 6.4E+00
1.00E+00 2.6E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.31E+03 102% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.51E+03 108% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
3.29E+03 101% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-76
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg EaFA-L04-1313-T01-A 1 4.84E+00
Mg EaFA-L04-1313-T02-A 1 2.83E+01
Mg EaFA-L04-1313-T03-A 1 1.46E+02
Mg EaFA-L04-1313-T04-A 1 3.17E+03
Mg EaFA-L04-1313-T05-A 1 5.68E+03
Mg EaFA-L04-1313-T06-A 1 7.79E+03
Mg EaFA-L04-1313-T07-A 1 8.23E+03
Mg EaFA-L04-1313-T08-A 1 7.52E+03
Mg EaFA-L04-1313-T09-A 1 1.30E+04
Mg EaFA-L04-1313-T01-B 1 2.11E+OOE
Mg EaFA-L04-1313-T02-B 1 6.85E+01
Mg EaFA-L04-1313-T03-B 1 4.16E+02
Mg EaFA-L04-1313-T04-B 1 3.73E+03
Mg EaFA-L04-1313-T05-B 1 6.23E+03
Mg EaFA-L04-1313-T06-B 1 7.89E+03
Mg EaFA-L04-1313-T07-B 1 8.46E+03
Mg EaFA-L04-1313-T08-B 1 7.62E+03
Mg EaFA-L04-1313-T09-B 1 1.26E+04
Mg EaFA-L04-1313-T01-C 1 1.30E+01
Mg EaFA-L04-1313-T02-C 1 7.57E+01
Mg EaFA-L04-1313-T03-C 1 4.68E+02
Mg EaFA-L04-1313-T04-C 1 3.63E+03
Mg EaFA-L04-1313-T05-C 1 5.67E+03
Mg EaFA-L04-1313-T06-C 1 7.70E+03
Mg EaFA-L04-1313-T07-C 1 8.99E+03
Mg EaFA-L04-1313-T08-C 1 7.57E+03
Mg EaFA-L04-1313-T09-C 1 1.26E+04
Mg EaFA-L04-1313-B01-A 1 6.59E+01
Mg EaFA-L04-1313-B02-A 1 2.16E+02
Mg EaFA-L04-1313-B03-A 1 1.91E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.84E+00 6.2E+01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
2.83E+01 2.2E+01 1 .OE+00 3.2E+00 1000 100 1.01E+03 99% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
1.46E+02 9.1E+00 1. OE+00 3.2E+00
3.17E+03 5.3E-01 1. OE+00 3.2E+00
5.68E+03 1.2E+00 1. OE+00 3.2E+00
7.79E+03 6.1E-01 1.0E+00 3.2E+00
8.23E+03 1. OE+00 1. OE+00 3.2E+00
7.52E+03 6.2E-01 1. OE+00 3.2E+00
1.30E+04 9.7E-01 1. OE+00 3.2E+00
2.11E+00 2.7E+02 1.0E+00 3.2E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
6.85E+01 1.4E+01 1.0E+00 3.2E+00 1000 100 1.12E+03 105% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
4.16E+02 2.3E+00 1. OE+00 3.2E+00
3.73E+03 1.4E+00 1. OE+00 3.2E+00
6.23E+03 1.7E+00 1. OE+00 3.2E+00
7.89E+03 8.3E-01 1. OE+00 3.2E+00
8.46E+03 5.4E-01 1. OE+00 3.2E+00
7.62E+03 1.8E+00 1. OE+00 3.2E+00
1.26E+04 9.2E-01 1. OE+00 3.2E+00
1.30E+01 4.9E+01 1. OE+00 3.2E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
7.57E+01 1.3E+01 1.0E+00 3.2E+00 1000 100 1.05E+03 98% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
4.68E+02 2.3E+00 1. OE+00 3.2E+00
3.63E+03 1. OE+00 1. OE+00 3.2E+00
5.67E+03 6.3E-01 1. OE+00 3.2E+00
7.70E+03 2.5E-01 1. OE+00 3.2E+00
8.99E+03 7.6E-01 1. OE+00 3.2E+00
7.57E+03 4.4E-02 1. OE+00 3.2E+00
1.26E+04 6.7E-01 1. OE+00 3.2E+00
6.59E+01 8.1E+00 1. OE+00 3.2E+00
2.16E+02 3.1E+00 1.0E+00 3.2E+00
1.91E+01 5.3E+01 1. OE+00 3.2E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-77
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo EaFA-L04-1313-T01-A 1 4.25E+03
Mo EaFA-L04-1313-T02-A 1 3.99E+03
Mo EaFA-L04-1313-T03-A 1 4.01 E+03
Mo EaFA-L04-1313-T04-A 1 3.90E+03
Mo EaFA-L04-1313-T05-A 1 3.67E+03
Mo EaFA-L04-1313-T06-A 1 3.28E+03
Mo EaFA-L04-1313-T07-A 1 3.52E+02
Mo EaFA-L04-1313-T08-A 1 1.24E+02
Mo EaFA-L04-1313-T09-A 1 2.43E+02
Mo EaFA-L04-1313-T01-B 1 4.16E+03
Mo EaFA-L04-1313-T02-B 1 4.10E+03
Mo EaFA-L04-1313-T03-B 1 4.02E+03
Mo EaFA-L04-1313-T04-B 1 3.85E+03
Mo EaFA-L04-1313-T05-B 1 3.68E+03
Mo EaFA-L04-1313-T06-B 1 3.25E+03
Mo EaFA-L04-1313-T07-B 1 3.30E+02
Mo EaFA-L04-1313-T08-B 1 1.21E+02
Mo EaFA-L04-1313-T09-B 1 2.10E+02
Mo EaFA-L04-1313-T01-C 1 4.23E+03
Mo EaFA-L04-1313-T02-C 1 4.02E+03
Mo EaFA-L04-1313-T03-C 1 3.99E+03
Mo EaFA-L04-1313-T04-C 1 3.77E+03
Mo EaFA-L04-1313-T05-C 1 3.59E+03
Mo EaFA-L04-1313-T06-C 1 3.25E+03
Mo EaFA-L04-1313-T07-C 1 6.49E+02
Mo EaFA-L04-1313-T08-C 1 1.12E+02
Mo EaFA-L04-1313-T09-C 1 2.17E+02
Mo EaFA-L04-1313-B01-A 1 7.57E+00
Mo EaFA-L04-1313-B02-A 1 8.34E+00
Mo EaFA-L04-1313-B03-A 1 1.05E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.25E+03 3.7E-01 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.99E+03 2.7E-01 1 .2E+00 3.8E+00 10 325 6.89E+03 89% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
4.01 E+03 4.2E-01 1.2E+00 3.8E+00
3.90E+03 3.7E-01 1.2E+00 3.8E+00
3.67E+03 1.1E+00 1.2E+00 3.8E+00
3.28E+03 1.2E+00 1.2E+00 3.8E+00
3.52E+02 1.6E+00 1.2E+00 3.8E+00
1.24E+02 3.4E-01 1.2E+00 3.8E+00
2.43E+02 5.6E-01 1.2E+00 3.8E+00
4.16E+03 1.0E+00 1.2E+00 3.8E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
4.10E+03 8.9E-01 1.2E+00 3.8E+00 10 325 7.24E+03 97% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
4.02E+03 1.7E+00 1.2E+00 3.8E+00
3.85E+03 1.4E+00 1.2E+00 3.8E+00
3.68E+03 3.6E-01 1.2E+00 3.8E+00
3.25E+03 1.8E-01 1.2E+00 3.8E+00
3.30E+02 9.7E-01 1.2E+00 3.8E+00
1.21E+02 8.8E-01 1.2E+00 3.8E+00
2.10E+02 1.6E+00 1.2E+00 3.8E+00
4.23E+03 6.3E-01 1.2E+00 3.8E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
4.02E+03 5.5E-01 1.2E+00 3.8E+00 10 325 6.98E+03 91% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
3.99E+03 2.7E-01 1.2E+00 3.8E+00
3.77E+03 1.3E+00 1.2E+00 3.8E+00
3.59E+03 4.7E-01 1.2E+00 3.8E+00
3.25E+03 5.0E-01 1.2E+00 3.8E+00
6.49E+02 1.2E+00 1.2E+00 3.8E+00
1.12E+02 1.0E+00 1.2E+00 3.8E+00
2.17E+02 9.5E-01 1.2E+00 3.8E+00
7.57E+00 3.0E+01 1.2E+00 3.8E+00
8.34E+00 3.0E+01 1.2E+00 3.8E+00
1.05E+01 3.9E+01 1.2E+00 3.8E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-78
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ni Sample Dilution Cone. Qualifier Revi
ug/L
Ni EaFA-L04-1313-T01-A 1 4.25E+00 E
Ni EaFA-L04-1313-T02-A 1 9.00E-01 U1/2
Ni EaFA-L04-1313-T03-A 1 9.00E-01 U1/2
Ni EaFA-L04-1313-T04-A 1 3.09E+00 E
Ni EaFA-L04-1313-T05-A 1 1.39E+01
Ni EaFA-L04-1313-T06-A 1 1.04E+02
Ni EaFA-L04-1313-T07-A 1 6.07E+02
Ni EaFA-L04-1313-T08-A 1 5.06E+02
Ni EaFA-L04-1313-T09-A 1 7.08E+02
Ni EaFA-L04-1313-T01-B 1 5.55E+00 E
Ni EaFA-L04-1313-T02-B 1 9.00E-01 U1/2
Ni EaFA-L04-1313-T03-B 1 9.00E-01 U1/2
Ni EaFA-L04-1313-T04-B 1 3.06E+00 E
Ni EaFA-L04-1313-T05-B 1 1.80E+01
Ni EaFA-L04-1313-T06-B 1 1.35E+02
Ni EaFA-L04-1313-T07-B 1 6.07E+02
Ni EaFA-L04-1313-T08-B 1 5.14E+02
Ni EaFA-L04-1313-T09-B 1 7.00E+02
Ni EaFA-L04-1313-T01-C 1 7.37E+00
Ni EaFA-L04-1313-T02-C 1 9.00E-01 U1/2
Ni EaFA-L04-1313-T03-C 1 9.00E-01 U1/2
Ni EaFA-L04-1313-T04-C 1 9.00E-01 U1/2
Ni EaFA-L04-1313-T05-C 1 1.41E+01
Ni EaFA-L04-1313-T06-C 1 9.50E+01
Ni EaFA-L04-1313-T07-C 1 5.91 E+02
Ni EaFA-L04-1313-T08-C 1 5.13E+02
Ni EaFA-L04-1313-T09-C 1 6.96E+02
Ni EaFA-L04-1313-B01-A 1 9.00E-01 U1/2
Ni EaFA-L04-1313-B02-A 1 9.00E-01 U1/2
Ni EaFA-L04-1313-B03-A 1 4.73E+00 E
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.25E+00 1.4E+02 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 8.7E+01 1.8E+00 5.7E+00 10 325 3.42E+03 105% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 1.8E+01 1.8E+00 5.7E+00
3.09E+00 5.3E+01 1.8E+00 5.7E+00
1.39E+01 3.3E+01 1.8E+00 5.7E+00
1.04E+02 8.1E+00 1.8E+00 5.7E+00
6.07E+02 1.9E+00 1.8E+00 5.7E+00
5.06E+02 7.9E-01 1.8E+00 5.7E+00
7.08E+02 6.4E-01 1.8E+00 5.7E+00
5.55E+00 8.3E+01 1.8E+00 5.7E+00
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 5.4E+02 1.8E+00 5.7E+00 10 325 3.66E+03 112% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 8.9E+02 1.8E+00 5.7E+00
3.06E+00 6.8E+01 1.8E+00 5.7E+00
1.80E+01 2.2E+01 1.8E+00 5.7E+00
1.35E+02 3.2E+00 1.8E+00 5.7E+00
6.07E+02 3.9E-01 1.8E+00 5.7E+00
5.14E+02 1.0E+00 1.8E+00 5.7E+00
7.00E+02 1.1E+00 1.8E+00 5.7E+00
7.37E+00 5.6E+01 1.8E+00 5.7E+00
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 7.4E+03 1.8E+00 5.7E+00 10 325 3.42E+03 105% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
9.00E-01 1.8E+02 1.8E+00 5.7E+00
9.00E-01 3.2E+02 1.8E+00 5.7E+00
1.41E+01 9.3E+00 1.8E+00 5.7E+00
9.50E+01 1.4E+00 1.8E+00 5.7E+00
5.91 E+02 6.7E-01 1.8E+00 5.7E+00
5.13E+02 6.1E-01 1.8E+00 5.7E+00
6.96E+02 5.5E-01 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 8.4E+01 1.8E+00 5.7E+00
4.73E+00 3.7E+01 1.8E+00 5.7E+00
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-79
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P EaFA-L04-1313-T01-A 1 1.45E+02
P EaFA-L04-1313-T02-A 1 6.04E+01
P EaFA-L04-1313-T03-A 1 1.16E+01 E
P EaFA-L04-1313-T04-A 1 1.26E+02
P EaFA-L04-1313-T05-A 1 3.43E+01
P EaFA-L04-1313-T06-A 1 1.05E+02
P EaFA-L04-1313-T07-A 1 1.85E+OOU1/2
P EaFA-L04-1313-T08-A 1 4.95E+01
P EaFA-L04-1313-T09-A 1 1.61E+03
P EaFA-L04-1313-T01-B 1 2.11E+02
P EaFA-L04-1313-T02-B 1 9.07E+01
P EaFA-L04-1313-T03-B 1 1.16E+02
P EaFA-L04-1313-T04-B 1 1.42E+02
P EaFA-L04-1313-T05-B 1 1.21E+02
P EaFA-L04-1313-T06-B 1 9.63E+01
P EaFA-L04-1313-T07-B 1 4.75E+01
P EaFA-L04-1313-T08-B 1 9.38E+01
P EaFA-L04-1313-T09-B 1 9.34E+02
P EaFA-L04-1313-T01-C 1 2.15E+02
P EaFA-L04-1313-T02-C 1 9.72E+01
P EaFA-L04-1313-T03-C 1 1.02E+02
P EaFA-L04-1313-T04-C 1 1.63E+02
P EaFA-L04-1313-T05-C 1 9.89E+01
P EaFA-L04-1313-T06-C 1 8.47E+01
P EaFA-L04-1313-T07-C 1 8.71 E+01
P EaFA-L04-1313-T08-C 1 8.18E+01
P EaFA-L04-1313-T09-C 1 1.40E+03
P EaFA-L04-1313-B01-A 1 4.95E+01
P EaFA-L04-1313-B02-A 1 1.58E+02
P EaFA-L04-1313-B03-A 1 6.62E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.45E+02 3.7E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
6.04E+01 3.4E+01 3.7E+00 1.2E+01 1000 100 1 .07E+03 101% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
1.16E+01 7.4E+01 3.7E+00 1.2E+01
1.26E+02 2.7E+01 3.7E+00 1.2E+01
3.43E+01 7.8E+01 3.7E+00 1.2E+01
1.05E+02 4.3E+00 3.7E+00 1.2E+01
1.85E+00 2.8E+01 3.7E+00 1.2E+01
4.95E+01 1.3E+01 3.7E+00 1.2E+01
1.61E+03 4.2E-01 3.7E+00 1.2E+01
2.11E+02 1.4E+01 3.7E+00 1.2E+01
VU ICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
9.07E+01 9.8E+00 3.7E+00 1.2E+01 1000 100 1.21E+03 1 12% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
1.16E+02 1.1E+01 3.7E+00 1.2E+01
1.42E+02 1.2E+01 3.7E+00 1.2E+01
1.21E+02 3.6E+00 3.7E+00 1.2E+01
9.63E+01 7.3E+00 3.7E+00 1.2E+01
4.75E+01 7.2E+01 3.7E+00 1.2E+01
9.38E+01 5.5E+00 3.7E+00 1.2E+01
9.34E+02 7.5E-01 3.7E+00 1.2E+01
2.15E+02 1.4E+00 3.7E+00 1.2E+01
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
9.72E+01 4.3E+01 3.7E+00 1.2E+01 1000 100 1.14E+03 104% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
1.02E+02 8.8E+00 3.7E+00 1.2E+01
1.63E+02 6.2E+00 3.7E+00 1.2E+01
9.89E+01 2.0E+01 3.7E+00 1.2E+01
8.47E+01 1.9E+00 3.7E+00 1.2E+01
8.71E+01 3.2E+01 3.7E+00 1.2E+01
8.18E+01 1.0E+01 3.7E+00 1.2E+01
1.40E+03 9.2E-02 3.7E+00 1.2E+01
4.95E+01 8.4E+01 3.7E+00 1.2E+01
1.58E+02 3.0E+00 3.7E+00 1.2E+01
6.62E+01 3.2E+01 3.7E+00 1.2E+01
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-80
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K EaFA-L04-1313-T01-A 1 5.65E+04
K EaFA-L04-1313-T02-A 1 3.38E+04
K EaFA-L04-1313-T03-A 1 2.72E+04
K EaFA-L04-1313-T04-A 1 2.59E+04
K EaFA-L04-1313-T05-A 1 2.54E+04
K EaFA-L04-1313-T06-A 1 2.44E+04
K EaFA-L04-1313-T07-A 1 2.46E+04
K EaFA-L04-1313-T08-A 1 1.74E+04
K EaFA-L04-1313-T09-A 1 2.02E+04
K EaFA-L04-1313-T01-B 1 5.65E+04
K EaFA-L04-1313-T02-B 1 3.47E+04
K EaFA-L04-1313-T03-B 1 2.70E+04
K EaFA-L04-1313-T04-B 1 2.52E+04
K EaFA-L04-1313-T05-B 1 2.47E+04
K EaFA-L04-1313-T06-B 1 2.50E+04
K EaFA-L04-1313-T07-B 1 2.49E+04
K EaFA-L04-1313-T08-B 1 1.77E+04
K EaFA-L04-1313-T09-B 1 1.97E+04
K EaFA-L04-1313-T01-C 1 5.77E+04
K EaFA-L04-1313-T02-C 1 3.39E+04
K EaFA-L04-1313-T03-C 1 2.71E+04
K EaFA-L04-1313-T04-C 1 2.52E+04
K EaFA-L04-1313-T05-C 1 2.46E+04
K EaFA-L04-1313-T06-C 1 2.44E+04
K EaFA-L04-1313-T07-C 1 2.64E+04
K EaFA-L04-1313-T08-C 1 1.78E+04
K EaFA-L04-1313-T09-C 1 1.98E+04
K EaFA-L04-1313-B01-A 1 1.61E+01
K EaFA-L04-1313-B02-A 1 3.00E+01
K EaFA-L04-1313-B03-A 1 2.57E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.65E+04 6.0E-01 1 .6E+00 5.1E+00
3.38E+04 1.1E-01 1 .6E+00 5.1E+00 1000 100
2.72E+04 4.9E-01 1 .6E+00 5.1E+00
2.59E+04 1.1E-01 1 .6E+00 5.1E+00
2.54E+04 1.2E+00 1 .6E+00 5.1E+00
2.44E+04 7.3E-01 1 .6E+00 5.1E+00
2.46E+04 4.2E-01 1 .6E+00 5.1E+00
1.74E+04 2.3E-02 1 .6E+00 5.1E+00
2.02E+04 1.7E-01 1 .6E+00 5.1E+00
5.65E+04 4.3E-01 1 .6E+00 5.1E+00
3.47E+04 7.6E-01 1 .6E+00 5.1E+00 1000 100
2.70E+04 9.1E-02 1 .6E+00 5.1E+00
2.52E+04 1.1E+00 1 .6E+00 5.1E+00
2.47E+04 1.2E+00 1 .6E+00 5.1E+00
2.50E+04 3.8E-01 1 .6E+00 5.1E+00
2.49E+04 8.3E-01 1 .6E+00 5.1E+00
1.77E+04 3.8E-01 1 .6E+00 5.1E+00
1.97E+04 1.0E+00 1 .6E+00 5.1E+00
5.77E+04 4.8E-01 1 .6E+00 5.1E+00
3.39E+04 6.6E-01 1 .6E+00 5.1E+00 1000 100
2.71E+04 3.4E-01 1.6E+00 5.1E+00
2.52E+04 1.4E+00 1.6E+00 5.1E+00
2.46E+04 6.0E-01 1.6E+00 5.1E+00
2.44E+04 8.3E-01 1.6E+00 5.1E+00
2.64E+04 6.2E-01 1.6E+00 5.1E+00
1.78E+04 4.3E-01 1.6E+00 5.1E+00
1.98E+04 1.1E+00 1.6E+00 5.1E+00
1.61E+01 1.5E+01 1.6E+00 5.1E+00
3.00E+01 2.9E+00 1.6E+00 5.1E+00
2.57E+02 1.2E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.46E+04 85% VUICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.55E+04 84% VUICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
3.47E+04 81% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                           1-81
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Se Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Se EaFA-L04-1313-T01-A 1 8.20E+03
Se EaFA-L04-1313-T02-A 1 6.49E+03
Se EaFA-L04-1313-T03-A 1 5.76E+03
Se EaFA-L04-1313-T04-A 1 4.37E+03
Se EaFA-L04-1313-T05-A 1 2.10E+03
Se EaFA-L04-1313-T06-A 1 1.22E+03
Se EaFA-L04-1313-T07-A 1 2.60E+02
Se EaFA-L04-1313-T08-A 1 1.09E+02
Se EaFA-L04-1313-T09-A 1 4.53E+02
Se EaFA-L04-1313-T01-B 1 8.25E+03
Se EaFA-L04-1313-T02-B 1 6.79E+03
Se EaFA-L04-1313-T03-B 1 5.78E+03
Se EaFA-L04-1313-T04-B 1 3.85E+03
Se EaFA-L04-1313-T05-B 1 2.05E+03
Se EaFA-L04-1313-T06-B 1 1.17E+03
Se EaFA-L04-1313-T07-B 1 2.89E+02
Se EaFA-L04-1313-T08-B 1 1.16E+02
Se EaFA-L04-1313-T09-B 1 3.06E+02
Se EaFA-L04-1313-T01-C 1 8.43E+03
Se EaFA-L04-1313-T02-C 1 6.64E+03
Se EaFA-L04-1313-T03-C 1 5.85E+03
Se EaFA-L04-1313-T04-C 1 3.85E+03
Se EaFA-L04-1313-T05-C 1 2.05E+03
Se EaFA-L04-1313-T06-C 1 1 .22E+03
Se EaFA-L04-1313-T07-C 1 3.58E+02
Se EaFA-L04-1313-T08-C 1 1.14E+02
Se EaFA-L04-1313-T09-C 1 4.09E+02
Se EaFA-L04-1313-B01-A 1 7.50E+00 U1/2
Se EaFA-L04-1313-B02-A 1 7.50E+00 U1/2
Se EaFA-L04-1313-B03-A 1 8.90E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.20E+03 1.5E+00 1 .5E+01 4.8E+01
6.49E+03 4.8E-01 1 .5E+01 4.8E+01 10 325
5.76E+03 4.7E-01 1 .5E+01 4.8E+01
4.37E+03 1.1E+00 1 .5E+01 4.8E+01
2.10E+03 3.0E+00 1.5E+01 4.8E+01
1.22E+03 1.5E+00 1.5E+01 4.8E+01
2.60E+02 4.0E+00 1.5E+01 4.8E+01
1.09E+02 1.8E+01 1.5E+01 4.8E+01
4.53E+02 3.5E+00 1.5E+01 4.8E+01
8.25E+03 4.9E-01 1.5E+01 4.8E+01
6.79E+03 1.4E+00 1.5E+01 4.8E+01 10 325
5.78E+03 3.0E-01 1.5E+01 4.8E+01
3.85E+03 2.4E+00 1.5E+01 4.8E+01
2.05E+03 1.8E+00 1.5E+01 4.8E+01
1.17E+03 2.6E+00 1.5E+01 4.8E+01
2.89E+02 4.2E+00 1.5E+01 4.8E+01
1.16E+02 1.6E+01 1.5E+01 4.8E+01
3.06E+02 3.5E+00 1.5E+01 4.8E+01
8.43E+03 4.0E-01 1.5E+01 4.8E+01
6.64E+03 7.7E-01 1.5E+01 4.8E+01 10 325
5.85E+03 1.1E+00 1.5E+01 4.8E+01
3.85E+03 1.2E-01 1.5E+01 4.8E+01
2.05E+03 2.2E-01 1.5E+01 4.8E+01
1.22E+03 1.9E+00 1.5E+01 4.8E+01
3.58E+02 5.3E+00 1.5E+01 4.8E+01
1.14E+02 1.7E+01 1.5E+01 4.8E+01
4.09E+02 6.3E+00 1.5E+01 4.8E+01
7.50E+00 3.0E+03 1.5E+01 4.8E+01
7.50E+00 9.0E+01 1.5E+01 4.8E+01
8.90E+01 4.2E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
9.89E+03 105% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
1.05E+04 114% VU ICP-OES 6/24/1 0 1 1 :33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
1.01E+04 106% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-82
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Si Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Si EaFA-L04-1313-T01-A 1 1.73E+04
Si EaFA-L04-1313-T02-A 1 4.07E+03
Si EaFA-L04-1313-T03-A 1 9.44E+02
Si EaFA-L04-1313-T04-A 1 3.72E+02
Si EaFA-L04-1313-T05-A 1 8.21E+02
Si EaFA-L04-1313-T06-A 1 2.15E+03
Si EaFA-L04-1313-T07-A 1 7.57E+03
Si EaFA-L04-1313-T08-A 1 2.27E+04
Si EaFA-L04-1313-T09-A 1 6.30E+04
Si EaFA-L04-1313-T01-B 1 1.63E+04
Si EaFA-L04-1313-T02-B 1 4.27E+03
Si EaFA-L04-1313-T03-B 1 9.70E+02
Si EaFA-L04-1313-T04-B 1 3.99E+02
Si EaFA-L04-1313-T05-B 1 9.80E+02
Si EaFA-L04-1313-T06-B 1 2.54E+03
Si EaFA-L04-1313-T07-B 1 7.75E+03
Si EaFA-L04-1313-T08-B 1 2.09E+04
Si EaFA-L04-1313-T09-B 1 6.24E+04
Si EaFA-L04-1313-T01-C 1 1.74E+04
Si EaFA-L04-1313-T02-C 1 4.16E+03
Si EaFA-L04-1313-T03-C 1 7.59E+02
Si EaFA-L04-1313-T04-C 1 3.81E+02
Si EaFA-L04-1313-T05-C 1 7.43E+02
Si EaFA-L04-1313-T06-C 1 2.06E+03
Si EaFA-L04-1313-T07-C 1 7.27E+03
Si EaFA-L04-1313-T08-C 1 2.06E+04
Si EaFA-L04-1313-T09-C 1 6.22E+04
Si EaFA-L04-1313-B01-A 1 4.38E+01
Si EaFA-L04-1313-B02-A 1 4.29E+01
Si EaFA-L04-1313-B03-A 1 6.34E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.73E+04 3.3E-01 1.1E+00 3.5E+00
4.07E+03 3.6E-01 1.1E+00 3.5E+00 1000 100
9.44E+02 6.7E-01 1.1E+00 3.5E+00
3.72E+02 4.0E-01 1.1E+00 3.5E+00
8.21E+02 6.4E-01 1.1E+00 3.5E+00
2.15E+03 7.8E-01 1.1E+00 3.5E+00
7.57E+03 1.4E-01 1.1E+00 3.5E+00
2.27E+04 6.7E-01 1.1E+00 3.5E+00
6.30E+04 1.8E-01 1.1E+00 3.5E+00
1.63E+04 3.6E-01 1.1E+00 3.5E+00
4.27E+03 1.0E-01 1.1E+00 3.5E+00 1000 100
9.70E+02 5.0E-01 1.1E+00 3.5E+00
3.99E+02 1.7E+00 1.1E+00 3.5E+00
9.80E+02 1.2E+00 1.1E+00 3.5E+00
2.54E+03 1.2E+00 1.1E+00 3.5E+00
7.75E+03 2.6E-01 1.1E+00 3.5E+00
2.09E+04 1.1E-01 1.1E+00 3.5E+00
6.24E+04 5.1E-01 1.1E+00 3.5E+00
1.74E+04 2.9E-01 1.1E+00 3.5E+00
4.16E+03 6.1E-01 1.1E+00 3.5E+00 1000 100
7.59E+02 1.5E-01 1.1E+00 3.5E+00
3.81E+02 3.6E-01 1.1E+00 3.5E+00
7.43E+02 8.9E-01 1.1E+00 3.5E+00
2.06E+03 8.4E-01 1.1E+00 3.5E+00
7.27E+03 3.6E-01 1.1E+00 3.5E+00
2.06E+04 3.3E-01 1.1E+00 3.5E+00
6.22E+04 4.9E-01 1.1E+00 3.5E+00
4.38E+01 5.8E+00 1.1E+00 3.5E+00
4.29E+01 4.0E+00 1.1E+00 3.5E+00
6.34E+01 1.6E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
4.93E+03 86% VUICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
5.16E+03 89% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
5.01E+03 85% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-83
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Na Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Na EaFA-L04-1313-T01-A 1 3.68E+05
Na EaFA-L04-1313-T02-A 1 1.56E+05
Na EaFA-L04-1313-T03-A 1 5.66E+04
Na EaFA-L04-1313-T04-A 1 3.54E+04
Na EaFA-L04-1313-T05-A 1 1.56E+04
Na EaFA-L04-1313-T06-A 1 5.45E+03
Na EaFA-L04-1313-T07-A 1 5.20E+03
Na EaFA-L04-1313-T08-A 1 3.42E+03
Na EaFA-L04-1313-T09-A 1 2.74E+03
Na EaFA-L04-1313-T01-B 1 3.67E+05
Na EaFA-L04-1313-T02-B 1 1.54E+05
Na EaFA-L04-1313-T03-B 1 5.55E+04
Na EaFA-L04-1313-T04-B 1 2.93E+04
Na EaFA-L04-1313-T05-B 1 1.51E+04
Na EaFA-L04-1313-T06-B 1 5.50E+03
Na EaFA-L04-1313-T07-B 1 5.43E+03
Na EaFA-L04-1313-T08-B 1 3.62E+03
Na EaFA-L04-1313-T09-B 1 2.62E+03
Na EaFA-L04-1313-T01-C 1 3.66E+05
Na EaFA-L04-1313-T02-C 1 1.44E+05
Na EaFA-L04-1313-T03-C 1 5.29E+04
Na EaFA-L04-1313-T04-C 1 2.93E+04
Na EaFA-L04-1313-T05-C 1 1.50E+04
Na EaFA-L04-1313-T06-C 1 5.46E+03
Na EaFA-L04-1313-T07-C 1 5.74E+03
Na EaFA-L04-1313-T08-C 1 3.70E+03
Na EaFA-L04-1313-T09-C 1 2.73E+03
Na EaFA-L04-1313-B01-A 1 3.35E+01
Na EaFA-L04-1313-B02-A 1 9.02E+01
Na EaFA-L04-1313-B03-A 1 3.72E+05
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.68E+05 3.7E-01 2.5E+00 8.0E+00
1.56E+05 2.6E-01 2.5E+00 8.0E+00 1000 100
5.66E+04 1.6E+00 2.5E+00 8.0E+00
3.54E+04 6.3E-01 2.5E+00 8.0E+00
1.56E+04 3.1E-01 2.5E+00 8.0E+00
5.45E+03 7.0E-01 2.5E+00 8.0E+00
5.20E+03 2.8E-01 2.5E+00 8.0E+00
3.42E+03 5.9E-01 2.5E+00 8.0E+00
2.74E+03 7.3E-01 2.5E+00 8.0E+00
3.67E+05 8.6E-01 2.5E+00 8.0E+00
1.54E+05 5.7E-01 2.5E+00 8.0E+00 1000 100
5.55E+04 8.6E-01 2.5E+00 8.0E+00
2.93E+04 8.5E-01 2.5E+00 8.0E+00
1.51E+04 1.5E+00 2.5E+00 8.0E+00
5.50E+03 6.8E-01 2.5E+00 8.0E+00
5.43E+03 3.7E-01 2.5E+00 8.0E+00
3.62E+03 5.0E-01 2.5E+00 8.0E+00
2.62E+03 2.7E-01 2.5E+00 8.0E+00
3.66E+05 4.2E-01 2.5E+00 8.0E+00
1.44E+05 6.2E-01 2.5E+00 8.0E+00 1000 100
5.29E+04 6.7E-01 2.5E+00 8.0E+00
2.93E+04 3.6E-01 2.5E+00 8.0E+00
1.50E+04 2.7E-01 2.5E+00 8.0E+00
5.46E+03 1.3E+00 2.5E+00 8.0E+00
5.74E+03 3.8E-01 2.5E+00 8.0E+00
3.70E+03 8.4E-01 2.5E+00 8.0E+00
2.73E+03 2.6E-01 2.5E+00 8.0E+00
3.35E+01 7.6E-01 2.5E+00 8.0E+00
9.02E+01 9.6E-01 2.5E+00 8.0E+00
3.72E+05 1.3E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
1.57E+05 89% VUICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:1 7 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
1.55E+05 85% VUICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
1.45E+05 87% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-84
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-L04-1313-T01-A 1 1.38E+03
EaFA-L04-1313-T02-A 1 1.48E+03
EaFA-L04-1313-T03-A 1 1.76E+03
EaFA-L04-1313-T04-A 1 1.96E+03
EaFA-L04-1313-T05-A 1 2.10E+03
EaFA-L04-1313-T06-A 1 2.17E+03
EaFA-L04-1313-T07-A 1 2.63E+03
EaFA-L04-1313-T08-A 1 2.99E+03
EaFA-L04-1313-T09-A 1 4.68E+03
EaFA-L04-1313-T01-B 1 1.35E+03
EaFA-L04-1313-T02-B 1 1.42E+03
EaFA-L04-1313-T03-B 1 1.74E+03
EaFA-L04-1313-T04-B 1 1.90E+03
EaFA-L04-1313-T05-B 1 2.02E+03
EaFA-L04-1313-T06-B 1 2.20E+03
EaFA-L04-1313-T07-B 1 2.63E+03
EaFA-L04-1313-T08-B 1 2.90E+03
EaFA-L04-1313-T09-B 1 4.58E+03
EaFA-L04-1313-T01-C 1 1.32E+03
EaFA-L04-1313-T02-C 1 1.42E+03
EaFA-L04-1313-T03-C 1 1.75E+03
EaFA-L04-1313-T04-C 1 1.87E+03
EaFA-L04-1313-T05-C 1 2.02E+03
EaFA-L04-1313-T06-C 1 2.21E+03
EaFA-L04-1313-T07-C 1 2.72E+03
EaFA-L04-1313-T08-C 1 2.93E+03
EaFA-L04-1313-T09-C 1 4.60E+03
EaFA-L04-1313-B01-A 1 1.39E+OOE
EaFA-L04-1313-B02-A 1 5.17E+00
EaFA-L04-1313-B03-A 1 4.84E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.38E+03 4.4E-01 1 .OE+00 3.2E+00
1.48E+03 1. OE+00 1 .OE+00 3.2E+00 1000 100
1.76E+03 9.3E-01 1 .OE+00 3.2E+00
1.96E+03 6.1E-01 1 .OE+00 3.2E+00
2.10E+03 1.5E+00 1 .OE+00 3.2E+00
2.17E+03 4.3E-01 1 .OE+00 3.2E+00
2.63E+03 2.2E-01 1 .OE+00 3.2E+00
2.99E+03 8.2E-01 1 .OE+00 3.2E+00
4.68E+03 7.7E-01 1 .OE+00 3.2E+00
1.35E+03 7.8E-01 1 .OE+00 3.2E+00
1.42E+03 4.1E-01 1 .OE+00 3.2E+00 1000 100
1.74E+03 1.6E+00 1 .OE+00 3.2E+00
1.90E+03 1.6E+00 1 .OE+00 3.2E+00
2.02E+03 3.8E-01 1 .OE+00 3.2E+00
2.20E+03 2.0E-01 1 .OE+00 3.2E+00
2.63E+03 5.0E-01 1 .OE+00 3.2E+00
2.90E+03 1.8E-01 1 .OE+00 3.2E+00
4.58E+03 9.2E-01 1 .OE+00 3.2E+00
1.32E+03 2.3E-01 1 .OE+00 3.2E+00
1.42E+03 6.7E-01 1 .OE+00 3.2E+00 1000 100
1.75E+03 4.9E-01 1. OE+00 3.2E+00
1.87E+03 1.6E+00 1. OE+00 3.2E+00
2.02E+03 3.9E-01 1. OE+00 3.2E+00
2.21E+03 6.9E-01 1.0E+00 3.2E+00
2.72E+03 3.6E-01 1. OE+00 3.2E+00
2.93E+03 4.6E-01 1. OE+00 3.2E+00
4.60E+03 1. OE+00 1. OE+00 3.2E+00
1.39E+00 4.3E+01 1. OE+00 3.2E+00
5.17E+00 1.9E+01 1. OE+00 3.2E+00
4.84E+00 1.5E+01 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
2.31E+03 83% VUICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
2.34E+03 92% VUICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
2.28E+03 86% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-85
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
S Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
S EaFA-L04-1313-T01-A 1 3.22E+06
S EaFA-L04-1313-T02-A 1 2.89E+06
S EaFA-L04-1313-T03-A 1 2.76E+06
S EaFA-L04-1313-T04-A 1 2.75E+06
S EaFA-L04-1313-T05-A 1 2.55E+06
S EaFA-L04-1313-T06-A 1 2.70E+06
S EaFA-L04-1313-T07-A 1 2.35E+06
S EaFA-L04-1313-T08-A 1 1.56E+06
S EaFA-L04-1313-T09-A 1 9.17E+05
S EaFA-L04-1313-T01-B 1 3.23E+06
S EaFA-L04-1313-T02-B 1 2.82E+06
S EaFA-L04-1313-T03-B 1 2.75E+06
S EaFA-L04-1313-T04-B 1 2.72E+06
S EaFA-L04-1313-T05-B 1 2.61E+06
S EaFA-L04-1313-T06-B 1 2.70E+06
S EaFA-L04-1313-T07-B 1 2.35E+06
S EaFA-L04-1313-T08-B 1 1.60E+06
S EaFA-L04-1313-T09-B 1 8.98E+05
S EaFA-L04-1313-T01-C 1 3.12E+06
S EaFA-L04-1313-T02-C 1 2.64E+06
S EaFA-L04-1313-T03-C 1 2.71E+06
S EaFA-L04-1313-T04-C 1 2.62E+06
S EaFA-L04-1313-T05-C 1 2.61E+06
S EaFA-L04-1313-T06-C 1 2.55E+06
S EaFA-L04-1313-T07-C 1 2.54E+06
S EaFA-L04-1313-T08-C 1 1.60E+06
S EaFA-L04-1313-T09-C 1 8.89E+05
S EaFA-L04-1313-B01-A 1 2.56E+06
S EaFA-L04-1313-B02-A 1 2.54E+06
S EaFA-L04-1313-B03-A 1 3.18E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.22E+06 7.7E-01 6.8E+00 2.2E+01
2.89E+06 2.1E-01 6.8E+00 2.2E+01 1000 500
2.76E+06 3.9E-01 6.8E+00 2.2E+01
2.75E+06 3.3E-01 6.8E+00 2.2E+01
2.55E+06 1.2E+00 6.8E+00 2.2E+01
2.70E+06 1.7E-01 6.8E+00 2.2E+01
2.35E+06 3.0E-01 6.8E+00 2.2E+01
1.56E+06 8.4E-01 6.8E+00 2.2E+01
9.17E+05 9.3E-02 6.8E+00 2.2E+01
3.23E+06 1.8E-01 6.8E+00 2.2E+01
2.82E+06 6.3E-01 6.8E+00 2.2E+01 1000 500
2.75E+06 2.6E-01 6.8E+00 2.2E+01
2.72E+06 1.2E+00 6.8E+00 2.2E+01
2.61E+06 9.9E-01 6.8E+00 2.2E+01
2.70E+06 7.0E-01 6.8E+00 2.2E+01
2.35E+06 3.1E-01 6.8E+00 2.2E+01
1.60E+06 7.7E-01 6.8E+00 2.2E+01
8.98E+05 1.1E+00 6.8E+00 2.2E+01
3.12E+06 3.0E-01 6.8E+00 2.2E+01
2.64E+06 1.1E+00 6.8E+00 2.2E+01 1000 500
2.71E+06 3.0E-01 6.8E+00 2.2E+01
2.62E+06 4.6E-01 6.8E+00 2.2E+01
2.61E+06 3.7E-01 6.8E+00 2.2E+01
2.55E+06 7.0E-01 6.8E+00 2.2E+01
2.54E+06 4.5E-01 6.8E+00 2.2E+01
1.60E+06 8.0E-01 6.8E+00 2.2E+01
8.89E+05 6.3E-01 6.8E+00 2.2E+01
2.56E+06 4.7E-01 6.8E+00 2.2E+01
2.54E+06 1.0E+00 6.8E+00 2.2E+01
3.18E+06 1.5E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
2.90E+06 87% VUICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
2.82E+06 87% VUICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
2.65E+06 81% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-86
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl EaFA-L04-1313-T01-A 1 1.36E+01 E
Tl EaFA-L04-1313-T02-A 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T03-A 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T04-A 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T05-A 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T06-A 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T07-A 1 3.34E+01
Tl EaFA-L04-1313-T08-A 1 4.92E+01
Tl EaFA-L04-1313-T09-A 1 6.67E+01
Tl EaFA-L04-1313-T01-B 1 1.77E+01
Tl EaFA-L04-1313-T02-B 1 1.39E+01 E
Tl EaFA-L04-1313-T03-B 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T04-B 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T05-B 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T06-B 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T07-B 1 3.46E+01
Tl EaFA-L04-1313-T08-B 1 4.88E+01
Tl EaFA-L04-1313-T09-B 1 6.72E+01
Tl EaFA-L04-1313-T01-C 1 1.25E+01 E
Tl EaFA-L04-1313-T02-C 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T03-C 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T04-C 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T05-C 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T06-C 1 2.30E+00 U1/2
Tl EaFA-L04-1313-T07-C 1 2.92E+01
Tl EaFA-L04-1313-T08-C 1 4.52E+01
Tl EaFA-L04-1313-T09-C 1 6.87E+01
Tl EaFA-L04-1313-B01-A 1 2.30E+00 U1/2
Tl EaFA-L04-1313-B02-A 1 2.30E+00 U1/2
Tl EaFA-L04-1313-B03-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.36E+01 4.6E+01 4.6E+00 1.5E+01
2.30E+00 2.9E+02 4.6E+00 1.5E+01 10 325
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 2.4E+02 4.6E+00 1.5E+01
2.30E+00 5.6E+02 4.6E+00 1.5E+01
2.30E+00 6.2E+02 4.6E+00 1.5E+01
3.34E+01 6.8E+01 4.6E+00 1.5E+01
4.92E+01 1.1E+01 4.6E+00 1.5E+01
6.67E+01 8.0E+00 4.6E+00 1.5E+01
1.77E+01 1.0E+02 4.6E+00 1.5E+01
1.39E+01 6.9E+01 4.6E+00 1.5E+01 10 325
2.30E+00 3.0E+01 4.6E+00 1.5E+01
2.30E+00 5.3E+01 4.6E+00 1.5E+01
2.30E+00 2.3E+02 4.6E+00 1.5E+01
2.30E+00 3.8E+02 4.6E+00 1.5E+01
3.46E+01 1.5E+01 4.6E+00 1.5E+01
4.88E+01 1.4E+01 4.6E+00 1.5E+01
6.72E+01 8.6E+00 4.6E+00 1.5E+01
1.25E+01 1.1E+02 4.6E+00 1.5E+01
2.30E+00 4.8E+02 4.6E+00 1.5E+01 10 325
2.30E+00 2.3E+04 4.6E+00 1.5E+01
2.30E+00 8.3E+01 4.6E+00 1.5E+01
2.30E+00 3.7E+02 4.6E+00 1.5E+01
2.30E+00 1.6E+02 4.6E+00 1.5E+01
2.92E+01 8.0E+00 4.6E+00 1.5E+01
4.52E+01 4.6E+00 4.6E+00 1.5E+01
6.87E+01 1.7E+00 4.6E+00 1.5E+01
2.30E+00 3.5E+02 4.6E+00 1.5E+01
2.30E+00 7.7E+01 4.6E+00 1.5E+01
2.30E+00 5.7E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.16E+03 97% VUICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.37E+03 103% VU ICP-OES 6/24/10 1 1 :33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
3.20E+03 98% VUICP-OES 6/24/1011:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-87
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ti Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Ti EaFA-L04-1313-T01-A 1 4.22E+00 E
Ti EaFA-L04-1313-T02-A 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T03-A 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T04-A 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T05-A 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T06-A 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T07-A 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T08-A 1 1.59E+01
Ti EaFA-L04-1313-T09-A 1 1.83E+03
Ti EaFA-L04-1313-T01-B 1 2.28E+00 E
Ti EaFA-L04-1313-T02-B 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T03-B 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T04-B 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T05-B 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T06-B 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T07-B 1 1.57E+01
Ti EaFA-L04-1313-T08-B 1 1.19E+01
Ti EaFA-L04-1313-T09-B 1 1.05E+03
Ti EaFA-L04-1313-T01-C 1 2.16E+00 E
Ti EaFA-L04-1313-T02-C 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T03-C 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T04-C 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T05-C 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T06-C 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T07-C 1 1.00E+OOU1/2
Ti EaFA-L04-1313-T08-C 1 1.06E+01
Ti EaFA-L04-1313-T09-C 1 1.51E+03
Ti EaFA-L04-1313-B01-A 1 1.00E+OOU1/2
Ti EaFA-L04-1313-B02-A 1 1.00E+OOU1/2
Ti EaFA-L04-1313-B03-A 1 2.18E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.22E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 7.9E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00
1.00E+00 6.8E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 7.5E+01 2.0E+00 6.4E+00
1.59E+01 5.5E+00 2.0E+00 6.4E+00
1.83E+03 7.7E-01 2.0E+00 6.4E+00
2.28E+00 2.1E+00 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 8.9E+01 2.0E+00 6.4E+00
1.57E+01 5.2E+00 2.0E+00 6.4E+00
1.19E+01 4.1E+00 2.0E+00 6.4E+00
1.05E+03 4.4E-01 2.0E+00 6.4E+00
2.16E+00 5.8E+01 2.0E+00 6.4E+00
1.00E+00 7.0E+01 2.0E+00 6.4E+00 10 325
1.00E+00 6.1E+01 2.0E+00 6.4E+00
1.00E+00 7.6E+01 2.0E+00 6.4E+00
1.00E+00 8.9E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00
1.06E+01 4.0E+00 2.0E+00 6.4E+00
1.51E+03 2.4E-01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
2.18E+00 1.9E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.06E+03 94% VUICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.24E+03 100% VU ICP-OES 6/24/10 1 1 :33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
3.04E+03 94% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-8
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
V Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
V EaFA-L04-1313-T01-A 1 5.79E+03
V EaFA-L04-1313-T02-A 1 2.82E+03
V EaFA-L04-1313-T03-A 1 2.51E+03
V EaFA-L04-1313-T04-A 1 9.08E+02
V EaFA-L04-1313-T05-A 1 3.22E+02
V EaFA-L04-1313-T06-A 1 2.30E+02
V EaFA-L04-1313-T07-A 1 8.83E+01
V EaFA-L04-1313-T08-A 1 9.64E+01
V EaFA-L04-1313-T09-A 1 5.45E+03
V EaFA-L04-1313-T01-B 1 5.55E+03
V EaFA-L04-1313-T02-B 1 2.88E+03
V EaFA-L04-1313-T03-B 1 2.50E+03
V EaFA-L04-1313-T04-B 1 6.77E+02
V EaFA-L04-1313-T05-B 1 3.29E+02
V EaFA-L04-1313-T06-B 1 2.30E+02
V EaFA-L04-1313-T07-B 1 8.62E+01
V EaFA-L04-1313-T08-B 1 8.91 E+01
V EaFA-L04-1313-T09-B 1 5.16E+03
V EaFA-L04-1313-T01-C 1 5.72E+03
V EaFA-L04-1313-T02-C 1 2.88E+03
V EaFA-L04-1313-T03-C 1 2.26E+03
V EaFA-L04-1313-T04-C 1 6.31 E+02
V EaFA-L04-1313-T05-C 1 2.96E+02
V EaFA-L04-1313-T06-C 1 2.24E+02
V EaFA-L04-1313-T07-C 1 1.03E+02
V EaFA-L04-1313-T08-C 1 8.33E+01
V EaFA-L04-1313-T09-C 1 5.34E+03
V EaFA-L04-1313-B01-A 1 7.50E-01 U1/2
V EaFA-L04-1313-B02-A 1 2.60E+00 E
V EaFA-L04-1313-B03-A 1 3.96E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.79E+03 3.3E-01 1 .5E+00 4.8E+00
2.82E+03 2.9E-01 1 .5E+00 4.8E+00 10 325
2.51E+03 8.2E-01 1 .5E+00 4.8E+00
9.08E+02 6.9E-01 1 .5E+00 4.8E+00
3.22E+02 2.0E+00 1 .5E+00 4.8E+00
2.30E+02 2.4E+00 1 .5E+00 4.8E+00
8.83E+01 5.9E+00 1 .5E+00 4.8E+00
9.64E+01 1.8E+00 1 .5E+00 4.8E+00
5.45E+03 5.4E-01 1 .5E+00 4.8E+00
5.55E+03 6.2E-01 1 .5E+00 4.8E+00
2.88E+03 3.9E-01 1 .5E+00 4.8E+00 10 325
2.50E+03 1.5E+00 1 .5E+00 4.8E+00
6.77E+02 4.9E-01 1 .5E+00 4.8E+00
3.29E+02 1.4E+00 1 .5E+00 4.8E+00
2.30E+02 4.8E-01 1 .5E+00 4.8E+00
8.62E+01 1.4E+00 1 .5E+00 4.8E+00
8.91 E+01 3.0E+00 1 .5E+00 4.8E+00
5.16E+03 4.9E-01 1 .5E+00 4.8E+00
5.72E+03 6.2E-01 1 .5E+00 4.8E+00
2.88E+03 1.2E+00 1 .5E+00 4.8E+00 10 325
2.26E+03 4.8E-01 1.5E+00 4.8E+00
6.31 E+02 4.5E-01 1.5E+00 4.8E+00
2.96E+02 9.1E-01 1.5E+00 4.8E+00
2.24E+02 1.2E+00 1.5E+00 4.8E+00
1.03E+02 2.0E+00 1.5E+00 4.8E+00
8.33E+01 1.3E+00 1.5E+00 4.8E+00
5.34E+03 3.5E-01 1.5E+00 4.8E+00
7.50E-01 2.3E+01 1.5E+00 4.8E+00
2.60E+00 3.4E+01 1.5E+00 4.8E+00
3.96E+00 5.9E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
5.95E+03 96% VUICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
6.23E+03 103% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
6.02E+03 97% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-89
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Zn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Zn EaFA-L04-1313-T01-A 1 2.29E+02
Zn EaFA-L04-1313-T02-A 1 2.87E+00 E
Zn EaFA-L04-1313-T03-A 1 5.00E-01 U1/2
Zn EaFA-L04-1313-T04-A 1 5.00E-01 U1/2
Zn EaFA-L04-1313-T05-A 1 5.00E-01 U1/2
Zn EaFA-L04-1313-T06-A 1 1.38E+01
Zn EaFA-L04-1313-T07-A 1 1.26E+03
Zn EaFA-L04-1313-T08-A 1 1.10E+03
Zn EaFA-L04-1313-T09-A 1 1.47E+03
Zn EaFA-L04-1313-T01-B 1 1.72E+02
Zn EaFA-L04-1313-T02-B 1 7.44E+00
Zn EaFA-L04-1313-T03-B 1 2.55E+00 E
Zn EaFA-L04-1313-T04-B 1 5.00E-01 U1/2
Zn EaFA-L04-1313-T05-B 1 3.97E+00
Zn EaFA-L04-1313-T06-B 1 1.83E+01
Zn EaFA-L04-1313-T07-B 1 1.26E+03
Zn EaFA-L04-1313-T08-B 1 1.12E+03
Zn EaFA-L04-1313-T09-B 1 1.44E+03
Zn EaFA-L04-1313-T01-C 1 1.44E+02
Zn EaFA-L04-1313-T02-C 1 6.90E+00
Zn EaFA-L04-1313-T03-C 1 6.04E+00
Zn EaFA-L04-1313-T04-C 1 5.00E-01 U1/2
Zn EaFA-L04-1313-T05-C 1 3.15E+00 E
Zn EaFA-L04-1313-T06-C 1 1.39E+01
Zn EaFA-L04-1313-T07-C 1 1.09E+03
Zn EaFA-L04-1313-T08-C 1 1.12E+03
Zn EaFA-L04-1313-T09-C 1 1.44E+03
Zn EaFA-L04-1313-B01-A 1 5.00E-01 U1/2
Zn EaFA-L04-1313-B02-A 1 1.15E+01
Zn EaFA-L04-1313-B03-A 1 1.34E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.29E+02 5.3E-01 1 .OE+00 3.2E+00
2.87E+00 3.5E+01 1 .OE+00 3.2E+00 10 325
5.00E-01 3.6E+01 1 .OE+00 3.2E+00
5.00E-01 2.7E+01 1 .OE+00 3.2E+00
5.00E-01 1.7E+01 1. OE+00 3.2E+00
1.38E+01 5.8E+00 1 .OE+00 3.2E+00
1.26E+03 7.1E-01 1 .OE+00 3.2E+00
1.10E+03 7.2E-01 1. OE+00 3.2E+00
1.47E+03 2.4E-01 1 .OE+00 3.2E+00
1.72E+02 7.0E-01 1 .OE+00 3.2E+00
7.44E+00 1.4E+01 1 .OE+00 3.2E+00 10 325
2.55E+00 1.8E+01 1 .OE+00 3.2E+00
5.00E-01 8.6E+01 1 .OE+00 3.2E+00
3.97E+00 2.2E+01 1 .OE+00 3.2E+00
1.83E+01 3.3E+00 1 .OE+00 3.2E+00
1.26E+03 6.4E-01 1 .OE+00 3.2E+00
1.12E+03 5.0E-01 1. OE+00 3.2E+00
1.44E+03 1.5E+00 1 .OE+00 3.2E+00
1.44E+02 1.2E+00 1 .OE+00 3.2E+00
6.90E+00 7.6E+00 1 .OE+00 3.2E+00 10 325
6.04E+00 1.5E+01 1 .OE+00 3.2E+00
5.00E-01 8.2E+01 1. OE+00 3.2E+00
3.15E+00 8.1E+00 1.0E+00 3.2E+00
1.39E+01 9.6E-01 1. OE+00 3.2E+00
1.09E+03 6.5E-01 1. OE+00 3.2E+00
1.12E+03 8.6E-01 1. OE+00 3.2E+00
1.44E+03 7.0E-01 1. OE+00 3.2E+00
5.00E-01 2.2E+01 1. OE+00 3.2E+00
1.15E+01 8.7E+00 1. OE+00 3.2E+00
1.34E+01 3.3E-01 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 6/24/10 11:09 AM EPA Interlab L04 1313-1316 EaFA
3.51E+03 108% VU ICP-OES 6/24/10 11:10 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:12 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:13 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:15 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:17 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:18 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:20 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:22 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:32 AM EPA Interlab L04 1313-1316 EaFA
3.75E+03 115% VU ICP-OES 6/24/10 11:33 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:35 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:36 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:38 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:40 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/1011:41 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:43 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:45 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:50 AM EPA Interlab L04 1313-1316 EaFA
3.52E+03 108% VU ICP-OES 6/24/10 11:51 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:53 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:55 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:56 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:58 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:59 AM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:01 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:03 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:04 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:05 AM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 11:07 AM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                            1-90
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al EaFA-L05-1313-T01-A 1 3.46E+04
Al EaFA-L05-1313-T02-A 1 2.88E+04
Al EaFA-L05-1313-T03-A 1 2.08E+04
Al EaFA-L05-1313-T04-A 1 8.07E+03
Al EaFA-L05-1313-T05-A 1 3.45E+02
Al EaFA-L05-1313-T06-A 1 7.57E+01
Al EaFA-L05-1313-T07-A 1 7.49E+01
Al EaFA-L05-1313-T08-A 1 4.07E+04
Al EaFA-L05-1313-T09-A 1 1.05E+05
Al EaFA-L05-1313-T01-B 1 3.21E+04
Al EaFA-L05-1313-T02-B 1 3.00E+04
Al EaFA-L05-1313-T03-B 1 2.12E+04
Al EaFA-L05-1313-T04-B 1 9.00E+03
Al EaFA-L05-1313-T05-B 1 4.13E+02
Al EaFA-L05-1313-T06-B 1 7.34E+01
Al EaFA-L05-1313-T07-B 1 1.49E+02
Al EaFA-L05-1313-T08-B 1 4.19E+04
Al EaFA-L05-1313-T09-B 1 1.13E+05
Al EaFA-L05-1313-T01-C 1 3.47E+04
Al EaFA-L05-1313-T02-C 1 3.12E+04
Al EaFA-L05-1313-T03-C 1 2.39E+04
Al EaFA-L05-1313-T04-C 1 8.18E+03
Al EaFA-L05-1313-T05-C 1 2.10E+02
Al EaFA-L05-1313-T06-C 1 3.29E+02
Al EaFA-L05-1313-T07-C 1 7.48E+01
Al EaFA-L05-1313-T08-C 1 3.98E+04
Al EaFA-L05-1313-T09-C 1 1.10E+05
Al EaFA-L05-1313-B01-A 1 5.00E-01 U1/2
Al EaFA-L05-1313-B02-A 1 5.00E-01 U1/2
Al EaFA-L05-1313-B03-A 1 5.00E-01 U1/2
Al EaFA-L05-1313-B01-B 1 5.00E-01 U1/2
Al EaFA-L05-1313-B02-B 1 5.00E-01 U1/2
Al EaFA-L05-1313-B03-B 1 5.00E-01 U1/2
Al EaFA-L05-1313-B01-C 1 5.00E-01 U1/2
Al EaFA-L05-1313-B02-C 1 5.00E-01 U1/2
Al EaFA-L05-1313-B03-C 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.46E+04 3.5E-01 1 .OE+00 3.2E+00
2.88E+04 7.5E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
2.08E+04 4.5E-01 1 .OE+00 3.2E+00 1000 100 2.17E+04 92% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
8.07E+03 5.4E-01 1 .OE+00 3.2E+00
3.45E+02 1.1E+00 1 .OE+00 3.2E+00
7.57E+01 7.3E-01 1 .OE+00 3.2E+00
7.49E+01 2.1E+00 1 .OE+00 3.2E+00
4.07E+04 3.0E-01 1 .OE+00 3.2E+00
1.05E+05 8.0E-01 1 .OE+00 3.2E+00
3.21 E+04 6.9E-01 1 .OE+00 3.2E+00
3.00E+04 4.9E-01 1 .OE+00 3.2E+00
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
2.12E+04 4.2E-01 1 .OE+00 3.2E+00 1000 100 2.20E+04 88% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
9.00E+03 3.9E-01 1 .OE+00 3.2E+00
4.13E+02 2.8E+00 1 .OE+00 3.2E+00
7.34E+01 2.1E+00 1 .OE+00 3.2E+00
1.49E+02 5.3E-01 1 .OE+00 3.2E+00
4.19E+04 5.5E-01 1 .OE+00 3.2E+00
1.13E+05 6.4E-01 1 .OE+00 3.2E+00
3.47E+04 6.2E-01 1 .OE+00 3.2E+00
3.12E+04 8.0E-02 1 .OE+00 3.2E+00
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
2.39E+04 3.9E-01 1 .OE+00 3.2E+00 1000 100 2.49E+04 101% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
8.18E+03 5.2E-01 1 .OE+00 3.2E+00
2.10E+02 9.9E-01 1 .OE+00 3.2E+00
3.29E+02 1.4E+01 1 .OE+00 3.2E+00
7.48E+01 4.5E+00 1 .OE+00 3.2E+00
3.98E+04 6.9E-01 1 .OE+00 3.2E+00
1.10E+05 8.8E-01 1. OE+00 3.2E+00
5.00E-01 6.8E+01 1 .OE+00 3.2E+00
5.00E-01 7.9E+01 1 .OE+00 3.2E+00
5.00E-01 2.7E+02 1 .OE+00 3.2E+00
5.00E-01 2.2E+01 1 .OE+00 3.2E+00
5.00E-01 1.6E+02 1 .OE+00 3.2E+00
5.00E-01 4.7E+01 1 .OE+00 3.2E+00
5.00E-01 2.1E+01 1. OE+00 3.2E+00
5.00E-01 3.9E+02 1 .OE+00 3.2E+00
5.00E-01 6.8E+02 1 .OE+00 3.2E+00
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                                    1-91
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Sb Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Sb EaFA-L05-1313-T01-A 1 1.78E+02
Sb EaFA-L05-1313-T02-A 1 1.29E+02
Sb EaFA-L05-1313-T03-A 1 1.47E+02
Sb EaFA-L05-1313-T04-A 1 1.73E+02
Sb EaFA-L05-1313-T05-A 1 1.92E+02
Sb EaFA-L05-1313-T06-A 1 1.28E+02
Sb EaFA-L05-1313-T07-A 1 1.52E+02
Sb EaFA-L05-1313-T08-A 1 2.74E+01
Sb EaFA-L05-1313-T09-A 1 9.59E+00 E
Sb EaFA-L05-1313-T01-B 1 1.77E+02
Sb EaFA-L05-1313-T02-B 1 1.40E+02
Sb EaFA-L05-1313-T03-B 1 1.45E+02
Sb EaFA-L05-1313-T04-B 1 1.59E+02
Sb EaFA-L05-1313-T05-B 1 1.49E+02
Sb EaFA-L05-1313-T06-B 1 1.52E+02
Sb EaFA-L05-1313-T07-B 1 1.14E+02
Sb EaFA-L05-1313-T08-B 1 4.60E+01
Sb EaFA-L05-1313-T09-B 1 3.75E+00 U1/2
Sb EaFA-L05-1313-T01-C 1 2.00E+02
Sb EaFA-L05-1313-T02-C 1 1 .49E+02
Sb EaFA-L05-1313-T03-C 1 1 .95E+02
Sb EaFA-L05-1313-T04-C 1 1 .40E+02
Sb EaFA-L05-1313-T05-C 1 1.47E+02
Sb EaFA-L05-1313-T06-C 1 1.24E+02
Sb EaFA-L05-1313-T07-C 1 1.58E+02
Sb EaFA-L05-1313-T08-C 1 1.88E+01 E
Sb EaFA-L05-1313-T09-C 1 3.75E+00 U1/2
Sb EaFA-L05-1313-B01-A 1 1.77E+01 E
Sb EaFA-L05-1313-B02-A 1 3.75E+00 U1/2
Sb EaFA-L05-1313-B03-A 1 3.75E+00 U1/2
Sb EaFA-L05-1313-B01-B 1 1.75E+01 E
Sb EaFA-L05-1313-B02-B 1 3.75E+00 U1/2
Sb EaFA-L05-1313-B03-B 1 3.75E+00 U1/2
Sb EaFA-L05-1313-B01-C 1 7.55E+00 E
Sb EaFA-L05-1313-B02-C 1 3.75E+00 U1/2
Sb EaFA-L05-1313-B03-C 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.78E+02 6.7E+00 7.5E+00 2.4E+01
1.29E+02 2.2E+01 7.5E+00 2.4E+01
1.47E+02 5.9E+00 7.5E+00 2.4E+01 10 325
1.73E+02 9.4E+00 7.5E+00 2.4E+01
1.92E+02 1.0E+01 7.5E+00 2.4E+01
1.28E+02 1.4E+01 7.5E+00 2.4E+01
1.52E+02 2.8E+00 7.5E+00 2.4E+01
2.74E+01 3.8E+01 7.5E+00 2.4E+01
9.59E+00 4.0E+01 7.5E+00 2.4E+01
1.77E+02 1.2E+01 7.5E+00 2.4E+01
1.40E+02 3.0E+00 7.5E+00 2.4E+01
1.45E+02 6.0E+00 7.5E+00 2.4E+01 10 325
1.59E+02 1.7E+00 7.5E+00 2.4E+01
1.49E+02 2.3E+00 7.5E+00 2.4E+01
1.52E+02 1.3E+01 7.5E+00 2.4E+01
1.14E+02 1.7E+01 7.5E+00 2.4E+01
4.60E+01 2.5E+01 7.5E+00 2.4E+01
3.75E+00 1.4E+02 7.5E+00 2.4E+01
2.00E+02 5.9E+00 7.5E+00 2.4E+01
1.49E+02 3.3E+00 7.5E+00 2.4E+01
1.95E+02 8.5E+00 7.5E+00 2.4E+01 10 325
1.40E+02 7.0E+00 7.5E+00 2.4E+01
1.47E+02 1.7E+01 7.5E+00 2.4E+01
1.24E+02 4.6E+00 7.5E+00 2.4E+01
1.58E+02 8.6E+00 7.5E+00 2.4E+01
1.88E+01 6.0E+01 7.5E+00 2.4E+01
3.75E+00 1.7E+02 7.5E+00 2.4E+01
1.77E+01 7.6E+01 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
3.75E+00 6.0E+01 7.5E+00 2.4E+01
1.75E+01 2.2E+01 7.5E+00 2.4E+01
3.75E+00 1.1E+02 7.5E+00 2.4E+01
3.75E+00 2.7E+02 7.5E+00 2.4E+01
7.55E+00 6.7E+01 7.5E+00 2.4E+01
3.75E+00 1.1E+02 7.5E+00 2.4E+01
3.75E+00 3.7E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.20E+03 94% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.29E+03 97% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.37E+03 98% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                            1-92
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
As Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
As EaFA-L05-1313-T01-A 1 6.57E+03
As EaFA-L05-1313-T02-A 1 9.06E+02
As EaFA-L05-1313-T03-A 1 8.52E+02
As EaFA-L05-1313-T04-A 1 4.68E+02
As EaFA-L05-1313-T05-A 1 1.76E+02
As EaFA-L05-1313-T06-A 1 8.16E+01
As EaFA-L05-1313-T07-A 1 1.07E+02
As EaFA-L05-1313-T08-A 1 1.51E+02
As EaFA-L05-1313-T09-A 1 3.57E+03
As EaFA-L05-1313-T01-B 1 7.33E+03
As EaFA-L05-1313-T02-B 1 9.08E+02
As EaFA-L05-1313-T03-B 1 1.18E+03
As EaFA-L05-1313-T04-B 1 4.33E+02
As EaFA-L05-1313-T05-B 1 1.53E+02
As EaFA-L05-1313-T06-B 1 9.86E+01
As EaFA-L05-1313-T07-B 1 9.81 E+01
As EaFA-L05-1313-T08-B 1 1.40E+02
As EaFA-L05-1313-T09-B 1 3.71 E+03
As EaFA-L05-1313-T01-C 1 7.55E+03
As EaFA-L05-1313-T02-C 1 8.93E+02
As EaFA-L05-1313-T03-C 1 1.35E+03
As EaFA-L05-1313-T04-C 1 4.79E+02
As EaFA-L05-1313-T05-C 1 1.15E+02
As EaFA-L05-1313-T06-C 1 1.10E+02
As EaFA-L05-1313-T07-C 1 1.11E+02
As EaFA-L05-1313-T08-C 1 1.37E+02
As EaFA-L05-1313-T09-C 1 3.89E+03
As EaFA-L05-1313-B01-A 1 3.84E+01
As EaFA-L05-1313-B02-A 1 3.34E+01 E
As EaFA-L05-1313-B03-A 1 5.80E+01
As EaFA-L05-1313-B01-B 1 4.36E+01
As EaFA-L05-1313-B02-B 1 3.57E+01
As EaFA-L05-1313-B03-B 1 4.67E+01
As EaFA-L05-1313-B01-C 1 3.32E+01 E
As EaFA-L05-1313-B02-C 1 2.34E+01 E
As EaFA-L05-1313-B03-C 1 2.94E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.57E+03 8.9E-01 1.1 E+01 3.5E+01
9.06E+02 1.1E+00 1.1 E+01 3.5E+01
8.52E+02 3.4E+00 1.1E+01 3.5E+01 10 325
4.68E+02 3.2E+00 1.1 E+01 3.5E+01
1.76E+02 6.4E+00 1.1 E+01 3.5E+01
8.16E+01 1.8E+01 1.1E+01 3.5E+01
1.07E+02 6.2E+00 1.1 E+01 3.5E+01
1.51E+02 8.2E-01 1.1 E+01 3.5E+01
3.57E+03 9.9E-01 1.1 E+01 3.5E+01
7.33E+03 4.4E-01 1.1 E+01 3.5E+01
9.08E+02 2.5E+00 1.1 E+01 3.5E+01
1.18E+03 1.0E+00 1.1E+01 3.5E+01 10 325
4.33E+02 4.4E+00 1.1 E+01 3.5E+01
1.53E+02 1.5E+01 1.1 E+01 3.5E+01
9.86E+01 2.1E+01 1.1E+01 3.5E+01
9.81E+01 2.6E+00 1.1E+01 3.5E+01
1.40E+02 1.3E+01 1.1 E+01 3.5E+01
3.71E+03 3.2E-01 1.1E+01 3.5E+01
7.55E+03 5.1E-01 1.1 E+01 3.5E+01
8.93E+02 6.2E+00 1.1 E+01 3.5E+01
1.35E+03 1.8E+00 1.1E+01 3.5E+01 10 325
4.79E+02 2.6E-01 1.1E+01 3.5E+01
1.15E+02 5.3E+00 1.1E+01 3.5E+01
1.10E+02 1.3E+01 1.1 E+01 3.5E+01
1.11E+02 8.4E+00 1.1 E+01 3.5E+01
1.37E+02 6.2E+00 1.1 E+01 3.5E+01
3.89E+03 3.7E-01 1.1 E+01 3.5E+01
3.84E+01 3.2E+01 1.1 E+01 3.5E+01
3.34E+01 6.2E+01 1.1 E+01 3.5E+01
5.80E+01 3.4E+01 1.1 E+01 3.5E+01
4.36E+01 3.4E+01 1.1 E+01 3.5E+01
3.57E+01 6.4E+01 1.1 E+01 3.5E+01
4.67E+01 4.0E+01 1.1 E+01 3.5E+01
3.32E+01 3.6E+01 1.1E+01 3.5E+01
2.34E+01 5.0E+01 1.1E+01 3.5E+01
2.94E+01 3.4E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.86E+03 93% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
4.14E+03 91% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
4.38E+03 93% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                            1-93
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
B Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
B EaFA-L05-1313-T01-A 1 4.69E+03
B EaFA-L05-1313-T02-A 1 4.52E+03
B EaFA-L05-1313-T03-A 1 3.93E+03
B EaFA-L05-1313-T04-A 1 4.42E+03
B EaFA-L05-1313-T05-A 1 4.58E+03
B EaFA-L05-1313-T06-A 1 4.91 E+03
B EaFA-L05-1313-T07-A 1 4.96E+03
B EaFA-L05-1313-T08-A 1 3.79E+03
B EaFA-L05-1313-T09-A 1 3.06E+03
B EaFA-L05-1313-T01-B 1 4.51 E+03
B EaFA-L05-1313-T02-B 1 4.37E+03
B EaFA-L05-1313-T03-B 1 4.32E+03
B EaFA-L05-1313-T04-B 1 4.22E+03
B EaFA-L05-1313-T05-B 1 4.42E+03
B EaFA-L05-1313-T06-B 1 4.71 E+03
B EaFA-L05-1313-T07-B 1 4.78E+03
B EaFA-L05-1313-T08-B 1 3.74E+03
B EaFA-L05-1313-T09-B 1 2.92E+03
B EaFA-L05-1313-T01-C 1 4.51 E+03
B EaFA-L05-1313-T02-C 1 4.36E+03
B EaFA-L05-1313-T03-C 1 4.31 E+03
B EaFA-L05-1313-T04-C 1 4.26E+03
B EaFA-L05-1313-T05-C 1 4.31 E+03
B EaFA-L05-1313-T06-C 1 4.66E+03
B EaFA-L05-1313-T07-C 1 4.59E+03
B EaFA-L05-1313-T08-C 1 3.65E+03
B EaFA-L05-1313-T09-C 1 2.94E+03
B EaFA-L05-1313-B01-A 1 5.00E-01 U1/2
B EaFA-L05-1313-B02-A 1 5.00E-01 U1/2
B EaFA-L05-1313-B03-A 1 5.00E-01 U1/2
B EaFA-L05-1313-B01-B 1 5.00E-01 U1/2
B EaFA-L05-1313-B02-B 1 5.00E-01 U1/2
B EaFA-L05-1313-B03-B 1 5.00E-01 U1/2
B EaFA-L05-1313-B01-C 1 5.00E-01 U1/2
B EaFA-L05-1313-B02-C 1 5.00E-01 U1/2
B EaFA-L05-1313-B03-C 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.69E+03 3.8E-01 1 .OE+00 3.2E+00
4.52E+03 2.0E-01 1 .OE+00 3.2E+00
3.93E+03 2.7E+00 1 .OE+00 3.2E+00 1000 100
4.42E+03 3.5E-01 1 .OE+00 3.2E+00
4.58E+03 5.5E-01 1 .OE+00 3.2E+00
4.91 E+03 3.1E-01 1 .OE+00 3.2E+00
4.96E+03 6.6E-01 1 .OE+00 3.2E+00
3.79E+03 5.5E-01 1 .OE+00 3.2E+00
3.06E+03 1.1E+00 1 .OE+00 3.2E+00
4.51 E+03 1.4E+00 1 .OE+00 3.2E+00
4.37E+03 5.4E-01 1 .OE+00 3.2E+00
4.32E+03 2.3E+00 1 .OE+00 3.2E+00 1000 100
4.22E+03 1.2E+00 1 .OE+00 3.2E+00
4.42E+03 2.4E+00 1 .OE+00 3.2E+00
4.71 E+03 1.9E+00 1 .OE+00 3.2E+00
4.78E+03 1.3E+00 1 .OE+00 3.2E+00
3.74E+03 7.6E-01 1 .OE+00 3.2E+00
2.92E+03 1.3E+00 1 .OE+00 3.2E+00
4.51 E+03 9.4E-01 1 .OE+00 3.2E+00
4.36E+03 1.1E+00 1 .OE+00 3.2E+00
4.31E+03 6.5E-01 1 .OE+00 3.2E+00 1000 100
4.26E+03 1.9E+00 1. OE+00 3.2E+00
4.31 E+03 8.5E-01 1. OE+00 3.2E+00
4.66E+03 1.3E+01 1. OE+00 3.2E+00
4.59E+03 3.3E-01 1. OE+00 3.2E+00
3.65E+03 1.8E+00 1. OE+00 3.2E+00
2.94E+03 5.9E-01 1. OE+00 3.2E+00
5.00E-01 1.7E+02 1. OE+00 3.2E+00
5.00E-01 5.2E+00 1. OE+00 3.2E+00
5.00E-01 1.2E+01 1. OE+00 3.2E+00
5.00E-01 4.4E-01 1. OE+00 3.2E+00
5.00E-01 1.4E+00 1. OE+00 3.2E+00
5.00E-01 1.6E+00 1. OE+00 3.2E+00
5.00E-01 1.4E+00 1. OE+00 3.2E+00
5.00E-01 9.1E-01 1. OE+00 3.2E+00
5.00E-01 3.1E+00 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
4.79E+03 86% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
5.29E+03 97% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
5.18E+03 87% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                            1-94
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ba Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Ba EaFA-L05-1313-T01-A 1 1.55E+03
Ba EaFA-L05-1313-T02-A 1 9.93E+02
Ba EaFA-L05-1313-T03-A 1 8.75E+02
Ba EaFA-L05-1313-T04-A 1 5.75E+02
Ba EaFA-L05-1313-T05-A 1 3.67E+02
Ba EaFA-L05-1313-T06-A 1 3.16E+02
Ba EaFA-L05-1313-T07-A 1 3.27E+02
Ba EaFA-L05-1313-T08-A 1 3.38E+02
Ba EaFA-L05-1313-T09-A 1 9.94E+02
Ba EaFA-L05-1313-T01-B 1 1.28E+03
Ba EaFA-L05-1313-T02-B 1 1.04E+03
Ba EaFA-L05-1313-T03-B 1 7.77E+02
Ba EaFA-L05-1313-T04-B 1 6.28E+02
Ba EaFA-L05-1313-T05-B 1 3.93E+02
Ba EaFA-L05-1313-T06-B 1 3.27E+02
Ba EaFA-L05-1313-T07-B 1 3.68E+02
Ba EaFA-L05-1313-T08-B 1 3.30E+02
Ba EaFA-L05-1313-T09-B 1 9.93E+02
Ba EaFA-L05-1313-T01-C 1 1 .33E+03
Ba EaFA-L05-1313-T02-C 1 9.54E+02
Ba EaFA-L05-1313-T03-C 1 9.55E+02
Ba EaFA-L05-1313-T04-C 1 5.14E+02
Ba EaFA-L05-1313-T05-C 1 3.87E+02
Ba EaFA-L05-1313-T06-C 1 3.38E+02
Ba EaFA-L05-1313-T07-C 1 3.46E+02
Ba EaFA-L05-1313-T08-C 1 3.36E+02
Ba EaFA-L05-1313-T09-C 1 9.50E+02
Ba EaFA-L05-1313-B01-A 1 5.00E-01 U1/2
Ba EaFA-L05-1313-B02-A 1 2.11E+OOE
Ba EaFA-L05-1313-B03-A 1 1.11E+OOE
Ba EaFA-L05-1313-B01-B 1 5.00E-01 U1/2
Ba EaFA-L05-1313-B02-B 1 5.00E-01 U1/2
Ba EaFA-L05-1313-B03-B 1 1.15E+OOE
Ba EaFA-L05-1313-B01-C 1 5.00E-01 U1/2
Ba EaFA-L05-1313-B02-C 1 5.00E-01 U1/2
Ba EaFA-L05-1313-B03-C 1 1.32E+OOE
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.55E+03 4.8E-01 1 .OE+00 3.2E+00
9.93E+02 1. OE+00 1 .OE+00 3.2E+00
8.75E+02 3.9E-01 1 .OE+00 3.2E+00 10 325
5.75E+02 4.8E-01 1 .OE+00 3.2E+00
3.67E+02 4.4E-01 1. OE+00 3.2E+00
3.16E+02 4.8E-01 1. OE+00 3.2E+00
3.27E+02 3.5E-01 1. OE+00 3.2E+00
3.38E+02 2.3E-01 1. OE+00 3.2E+00
9.94E+02 2.3E+00 1. OE+00 3.2E+00
1.28E+03 4.0E-01 1. OE+00 3.2E+00
1.04E+03 3.0E-01 1. OE+00 3.2E+00
7.77E+02 4.4E-01 1. OE+00 3.2E+00 10 325
6.28E+02 6.1E-01 1. OE+00 3.2E+00
3.93E+02 6.8E-02 1. OE+00 3.2E+00
3.27E+02 5.4E-01 1. OE+00 3.2E+00
3.68E+02 1. OE+00 1. OE+00 3.2E+00
3.30E+02 5.7E-01 1. OE+00 3.2E+00
9.93E+02 8.7E-01 1. OE+00 3.2E+00
1.33E+03 2.8E-01 1. OE+00 3.2E+00
9.54E+02 1.4E-01 1. OE+00 3.2E+00
9.55E+02 4.8E-01 1. OE+00 3.2E+00 10 325
5.14E+02 3.3E-01 1. OE+00 3.2E+00
3.87E+02 5.3E-01 1. OE+00 3.2E+00
3.38E+02 1.1E+01 1. OE+00 3.2E+00
3.46E+02 8.2E-01 1. OE+00 3.2E+00
3.36E+02 4.5E-01 1. OE+00 3.2E+00
9.50E+02 3.6E-01 1. OE+00 3.2E+00
5.00E-01 8.0E+00 1. OE+00 3.2E+00
2.11E+00 1.1E+01 1. OE+00 3.2E+00
1.11E+00 9.9E+00 1. OE+00 3.2E+00
5.00E-01 2.7E+00 1. OE+00 3.2E+00
5.00E-01 5.7E+00 1. OE+00 3.2E+00
1.15E+00 1.3E+01 1. OE+00 3.2E+00
5.00E-01 3.5E+00 1. OE+00 3.2E+00
5.00E-01 9.4E+00 1. OE+00 3.2E+00
1.32E+00 1.9E+01 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.84E+03 91% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.80E+03 93% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.91E+03 91% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                            1-95
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Be Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Be EaFA-L05-1313-T01-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-T02-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-T03-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-T04-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-T05-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-T06-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-T07-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-T08-A 1 1.45E+02
Be EaFA-L05-1313-T09-A 1 2.39E+02
Be EaFA-L05-1313-T01-B 1 9.50E-01 U1/2
Be EaFA-L05-1313-T02-B 1 9.50E-01 U1/2
Be EaFA-L05-1313-T03-B 1 9.50E-01 U1/2
Be EaFA-L05-1313-T04-B 1 9.50E-01 U1/2
Be EaFA-L05-1313-T05-B 1 9.50E-01 U1/2
Be EaFA-L05-1313-T06-B 1 9.50E-01 U1/2
Be EaFA-L05-1313-T07-B 1 1.98E+OOE
Be EaFA-L05-1313-T08-B 1 1.47E+02
Be EaFA-L05-1313-T09-B 1 2.48E+02
Be EaFA-L05-1313-T01-C 1 9.50E-01 U1/2
Be EaFA-L05-1313-T02-C 1 9.50E-01 U1/2
Be EaFA-L05-1313-T03-C 1 9.50E-01 U1/2
Be EaFA-L05-1313-T04-C 1 9.50E-01 U1/2
Be EaFA-L05-1313-T05-C 1 9.50E-01 U1/2
Be EaFA-L05-1313-T06-C 1 4.80E+00 E
Be EaFA-L05-1313-T07-C 1 9.50E-01 U1/2
Be EaFA-L05-1313-T08-C 1 1.47E+02
Be EaFA-L05-1313-T09-C 1 2.47E+02
Be EaFA-L05-1313-B01-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-B02-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-B03-A 1 9.50E-01 U1/2
Be EaFA-L05-1313-B01-B 1 9.50E-01 U1/2
Be EaFA-L05-1313-B02-B 1 9.50E-01 U1/2
Be EaFA-L05-1313-B03-B 1 9.50E-01 U1/2
Be EaFA-L05-1313-B01-C 1 9.50E-01 U1/2
Be EaFA-L05-1313-B02-C 1 9.50E-01 U1/2
Be EaFA-L05-1313-B03-C 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1 .9E+00 6.0E+00
9.50E-01 4.3E+01 1 .9E+00 6.0E+00 10 325
9.50E-01 1.4E+02 1 .9E+00 6.0E+00
9.50E-01 8.0E+02 1 .9E+00 6.0E+00
9.50E-01 3.9E+01 1 .9E+00 6.0E+00
9.50E-01 3.7E+01 1 .9E+00 6.0E+00
1.45E+02 2.3E-01 1 .9E+00 6.0E+00
2.39E+02 9.5E-01 1 .9E+00 6.0E+00
9.50E-01 8.1E+00 1 .9E+00 6.0E+00
9.50E-01 2.5E+02 1 .9E+00 6.0E+00
9.50E-01 1.2E+02 1 .9E+00 6.0E+00 10 325
9.50E-01 1.8E+02 1 .9E+00 6.0E+00
9.50E-01 1.9E+02 1 .9E+00 6.0E+00
9.50E-01 3.9E+01 1 .9E+00 6.0E+00
1.98E+00 5.9E+00 1 .9E+00 6.0E+00
1.47E+02 7.3E-01 1.9E+00 6.0E+00
2.48E+02 5.1E-01 1.9E+00 6.0E+00
9.50E-01 4.1E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1 .9E+00 6.0E+00
9.50E-01 7.6E+03 1 .9E+00 6.0E+00 10 325
9.50E-01 3.2E+02 1 .9E+00 6.0E+00
9.50E-01 2.4E+02 1 .9E+00 6.0E+00
4.80E+00 1.4E+01 1 .9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
1.47E+02 7.4E-01 1 .9E+00 6.0E+00
2.47E+02 1.0E+00 1 .9E+00 6.0E+00
9.50E-01 2.1E+01 1.9E+00 6.0E+00
9.50E-01 5.1E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+03 1.9E+00 6.0E+00
9.50E-01 2.6E+02 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.21E+03 99% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.27E+03 100% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.39E+03 104% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                            1-96
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Cd Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Cd EaFA-L05-1313-T01-A 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T02-A 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T03-A 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T04-A 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T05-A 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T06-A 1 1.09E+01
Cd EaFA-L05-1313-T07-A 1 1.47E+01
Cd EaFA-L05-1313-T08-A 1 3.04E+01
Cd EaFA-L05-1313-T09-A 1 3.39E+01
Cd EaFA-L05-1313-T01-B 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T02-B 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T03-B 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T04-B 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T05-B 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T06-B 1 8.11E+00
Cd EaFA-L05-1313-T07-B 1 2.16E+01
Cd EaFA-L05-1313-T08-B 1 3.07E+01
Cd EaFA-L05-1313-T09-B 1 3.49E+01
Cd EaFA-L05-1313-T01-C 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T02-C 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T03-C 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T04-C 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T05-C 1 1.10E+OOU1/2
Cd EaFA-L05-1313-T06-C 1 2.36E+01
Cd EaFA-L05-1313-T07-C 1 7.96E+00
Cd EaFA-L05-1313-T08-C 1 3.14E+01
Cd EaFA-L05-1313-T09-C 1 3.53E+01
Cd EaFA-L05-1313-B01-A 1 1.10E+OOU1/2
Cd EaFA-L05-1313-B02-A 1 1.10E+OOU1/2
Cd EaFA-L05-1313-B03-A 1 1.10E+OOU1/2
Cd EaFA-L05-1313-B01-B 1 1.10E+OOU1/2
Cd EaFA-L05-1313-B02-B 1 1.10E+OOU1/2
Cd EaFA-L05-1313-B03-B 1 1.10E+OOU1/2
Cd EaFA-L05-1313-B01-C 1 1.10E+OOU1/2
Cd EaFA-L05-1313-B02-C 1 1.10E+OOU1/2
Cd EaFA-L05-1313-B03-C 1 1.10E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 2.2E+02 2.2E+00 7.0E+00
1.10E+00 2.0E+02 2.2E+00 7.0E+00
1.10E+00 3.3E+01 2.2E+00 7.0E+00 10 325
1.10E+00 3.0E+02 2.2E+00 7.0E+00
1.10E+00 3.5E+01 2.2E+00 7.0E+00
1.09E+01 9.2E-01 2.2E+00 7.0E+00
1.47E+01 3.9E+00 2.2E+00 7.0E+00
3.04E+01 1.3E+00 2.2E+00 7.0E+00
3.39E+01 1.4E+00 2.2E+00 7.0E+00
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 4.0E+02 2.2E+00 7.0E+00
1.10E+00 3.2E+01 2.2E+00 7.0E+00 10 325
1.10E+00 5.0E+01 2.2E+00 7.0E+00
1.10E+00 3.8E+03 2.2E+00 7.0E+00
8.11E+00 5.2E+00 2.2E+00 7.0E+00
2.16E+01 7.5E-01 2.2E+00 7.0E+00
3.07E+01 1.5E+00 2.2E+00 7.0E+00
3.49E+01 1.1E+00 2.2E+00 7.0E+00
1.10E+00 2.9E+02 2.2E+00 7.0E+00
1.10E+00 1.5E+03 2.2E+00 7.0E+00
1.10E+00 5.0E+01 2.2E+00 7.0E+00 10 325
1.10E+00 3.5E+01 2.2E+00 7.0E+00
1.10E+00 3.6E+01 2.2E+00 7.0E+00
2.36E+01 1.1E+01 2.2E+00 7.0E+00
7.96E+00 2.8E+00 2.2E+00 7.0E+00
3.14E+01 1.1E+00 2.2E+00 7.0E+00
3.53E+01 1.6E+00 2.2E+00 7.0E+00
1.10E+00 2.1E+01 2.2E+00 7.0E+00
1.10E+00 5.8E+01 2.2E+00 7.0E+00
1.10E+00 5.6E+02 2.2E+00 7.0E+00
1.10E+00 1.0E+02 2.2E+00 7.0E+00
1.10E+00 3.1E+02 2.2E+00 7.0E+00
1.10E+00 8.2E+01 2.2E+00 7.0E+00
1.10E+00 4.5E+01 2.2E+00 7.0E+00
1.10E+00 1.7E+02 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.17E+03 97% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.28E+03 101% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.37E+03 104% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                            1-97
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ca Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Ca EaFA-L05-1313-T01-A 1 1.62E+04
Ca EaFA-L05-1313-T02-A 1 5.20E+04
Ca EaFA-L05-1313-T03-A 1 8.24E+04
Ca EaFA-L05-1313-T04-A 1 1.16E+05
Ca EaFA-L05-1313-T05-A 1 1.40E+05
Ca EaFA-L05-1313-T06-A 1 1.58E+05
Ca EaFA-L05-1313-T07-A 1 1.61E+05
Ca EaFA-L05-1313-T08-A 1 1.40E+05
Ca EaFA-L05-1313-T09-A 1 1.33E+05
Ca EaFA-L05-1313-T01-B 1 1.41E+04
Ca EaFA-L05-1313-T02-B 1 5.27E+04
Ca EaFA-L05-1313-T03-B 1 8.45E+04
Ca EaFA-L05-1313-T04-B 1 1.11E+05
Ca EaFA-L05-1313-T05-B 1 1.29E+05
Ca EaFA-L05-1313-T06-B 1 1.57E+05
Ca EaFA-L05-1313-T07-B 1 1.56E+05
Ca EaFA-L05-1313-T08-B 1 1.38E+05
Ca EaFA-L05-1313-T09-B 1 1.33E+05
Ca EaFA-L05-1313-T01-C 1 1.43E+04
Ca EaFA-L05-1313-T02-C 1 5.16E+04
Ca EaFA-L05-1313-T03-C 1 8.58E+04
Ca EaFA-L05-1313-T04-C 1 1.19E+05
Ca EaFA-L05-1313-T05-C 1 1.35E+05
Ca EaFA-L05-1313-T06-C 1 1.55E+05
Ca EaFA-L05-1313-T07-C 1 1.57E+05
Ca EaFA-L05-1313-T08-C 1 1.41E+05
Ca EaFA-L05-1313-T09-C 1 1.35E+05
Ca EaFA-L05-1313-B01-A 1 2.84E+01
Ca EaFA-L05-1313-B02-A 1 1.10E+01
Ca EaFA-L05-1313-B03-A 1 2.32E+01
Ca EaFA-L05-1313-B01-B 1 1.10E+01
Ca EaFA-L05-1313-B02-B 1 2.48E+01
Ca EaFA-L05-1313-B03-B 1 2.79E+01
Ca EaFA-L05-1313-B01-C 1 2.87E+01
Ca EaFA-L05-1313-B02-C 1 1.39E+01
Ca EaFA-L05-1313-B03-C 1 2.33E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.62E+04 4.3E-01 2.6E+00 8.3E+00
5.20E+04 6.3E-01 2.6E+00 8.3E+00
8.24E+04 9.5E-02 2.6E+00 8.3E+00 1000 100
1.16E+05 7.9E-01 2.6E+00 8.3E+00
1.40E+05 1.0E+00 2.6E+00 8.3E+00
1.58E+05 1.7E-01 2.6E+00 8.3E+00
1.61E+05 5.5E-02 2.6E+00 8.3E+00
1.40E+05 5.6E-01 2.6E+00 8.3E+00
1.33E+05 6.9E-01 2.6E+00 8.3E+00
1.41E+04 5.8E-01 2.6E+00 8.3E+00
5.27E+04 5.3E-01 2.6E+00 8.3E+00
8.45E+04 5.7E-01 2.6E+00 8.3E+00 1000 100
1.11E+05 7.6E-01 2.6E+00 8.3E+00
1.29E+05 2.5E-01 2.6E+00 8.3E+00
1.57E+05 9.1E-01 2.6E+00 8.3E+00
1.56E+05 1.1E+00 2.6E+00 8.3E+00
1.38E+05 2.1E-01 2.6E+00 8.3E+00
1.33E+05 1.2E-01 2.6E+00 8.3E+00
1.43E+04 5.0E-01 2.6E+00 8.3E+00
5.16E+04 3.6E-02 2.6E+00 8.3E+00
8.58E+04 4.7E-01 2.6E+00 8.3E+00 1000 100
1.19E+05 4.3E-01 2.6E+00 8.3E+00
1.35E+05 3.7E-01 2.6E+00 8.3E+00
1.55E+05 1.1E+01 2.6E+00 8.3E+00
1.57E+05 6.6E-01 2.6E+00 8.3E+00
1.41E+05 5.5E-01 2.6E+00 8.3E+00
1.35E+05 7.3E-01 2.6E+00 8.3E+00
2.84E+01 1.6E+01 2.6E+00 8.3E+00
1.10E+01 7.3E+01 2.6E+00 8.3E+00
2.32E+01 1.0E+01 2.6E+00 8.3E+00
1.10E+01 6.9E+01 2.6E+00 8.3E+00
2.48E+01 3.2E+01 2.6E+00 8.3E+00
2.79E+01 9.5E+00 2.6E+00 8.3E+00
2.87E+01 1.5E+01 2.6E+00 8.3E+00
1.39E+01 3.4E+01 2.6E+00 8.3E+00
2.33E+01 2.3E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
8.32E+04 85% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
8.53E+04 86% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
8.66E+04 86% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                            1-98
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Cr Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Cr EaFA-L05-1313-T01-A 1 3.59E+02
Cr EaFA-L05-1313-T02-A 1 2.48E+02
Cr EaFA-L05-1313-T03-A 1 1.88E+02
Cr EaFA-L05-1313-T04-A 1 1.56E+02
Cr EaFA-L05-1313-T05-A 1 8.42E+01
Cr EaFA-L05-1313-T06-A 1 1.03E+01
Cr EaFA-L05-1313-T07-A 1 8.81 E+00
Cr EaFA-L05-1313-T08-A 1 5.26E+02
Cr EaFA-L05-1313-T09-A 1 1.74E+03
Cr EaFA-L05-1313-T01-B 1 3.54E+02
Cr EaFA-L05-1313-T02-B 1 2.55E+02
Cr EaFA-L05-1313-T03-B 1 2.05E+02
Cr EaFA-L05-1313-T04-B 1 1.38E+02
Cr EaFA-L05-1313-T05-B 1 8.52E+01
Cr EaFA-L05-1313-T06-B 1 1.13E+01
Cr EaFA-L05-1313-T07-B 1 4.08E+00
Cr EaFA-L05-1313-T08-B 1 6.03E+02
Cr EaFA-L05-1313-T09-B 1 1.80E+03
Cr EaFA-L05-1313-T01-C 1 4.13E+02
Cr EaFA-L05-1313-T02-C 1 2.78E+02
Cr EaFA-L05-1313-T03-C 1 2.44E+02
Cr EaFA-L05-1313-T04-C 1 1.54E+02
Cr EaFA-L05-1313-T05-C 1 6.13E+01
Cr EaFA-L05-1313-T06-C 1 4.87E+00
Cr EaFA-L05-1313-T07-C 1 1.34E+01
Cr EaFA-L05-1313-T08-C 1 4.38E+02
Cr EaFA-L05-1313-T09-C 1 1.82E+03
Cr EaFA-L05-1313-B01-A 1 6.00E-01 U1/2
Cr EaFA-L05-1313-B02-A 1 6.00E-01 U1/2
Cr EaFA-L05-1313-B03-A 1 6.00E-01 U1/2
Cr EaFA-L05-1313-B01-B 1 6.00E-01 U1/2
Cr EaFA-L05-1313-B02-B 1 6.00E-01 U1/2
Cr EaFA-L05-1313-B03-B 1 6.00E-01 U1/2
Cr EaFA-L05-1313-B01-C 1 6.00E-01 U1/2
Cr EaFA-L05-1313-B02-C 1 6.00E-01 U1/2
Cr EaFA-L05-1313-B03-C 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.59E+02 9.7E-01 1 .2E+00 3.8E+00
2.48E+02 1.2E+00 1 .2E+00 3.8E+00
1.88E+02 6.2E-01 1 .2E+00 3.8E+00 10 325
1.56E+02 4.6E-01 1.2E+00 3.8E+00
8.42E+01 1.4E+00 1.2E+00 3.8E+00
1.03E+01 1.2E+01 1.2E+00 3.8E+00
8.81 E+00 1.3E+01 1.2E+00 3.8E+00
5.26E+02 2.6E-01 1.2E+00 3.8E+00
1.74E+03 7.5E-01 1.2E+00 3.8E+00
3.54E+02 1.2E+00 1.2E+00 3.8E+00
2.55E+02 9.3E-01 1.2E+00 3.8E+00
2.05E+02 3.7E-01 1.2E+00 3.8E+00 10 325
1.38E+02 1.5E+00 1.2E+00 3.8E+00
8.52E+01 1.4E+00 1.2E+00 3.8E+00
1.13E+01 1.3E+01 1.2E+00 3.8E+00
4.08E+00 2.5E+01 1.2E+00 3.8E+00
6.03E+02 1.4E+00 1.2E+00 3.8E+00
1.80E+03 1.9E-01 1.2E+00 3.8E+00
4.13E+02 5.1E-01 1.2E+00 3.8E+00
2.78E+02 5.1E-01 1.2E+00 3.8E+00
2.44E+02 5.8E-01 1.2E+00 3.8E+00 10 325
1.54E+02 1.5E+00 1.2E+00 3.8E+00
6.13E+01 1.3E+00 1.2E+00 3.8E+00
4.87E+00 4.5E+00 1.2E+00 3.8E+00
1.34E+01 4.4E+00 1.2E+00 3.8E+00
4.38E+02 4.7E-01 1.2E+00 3.8E+00
1.82E+03 2.6E-01 1.2E+00 3.8E+00
6.00E-01 1.5E+02 1.2E+00 3.8E+00
6.00E-01 6.5E+01 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.00E-01 1.7E+02 1.2E+00 3.8E+00
6.00E-01 9.7E+01 1.2E+00 3.8E+00
6.00E-01 3.6E+02 1.2E+00 3.8E+00
6.00E-01 5.7E+01 1.2E+00 3.8E+00
6.00E-01 7.3E+01 1.2E+00 3.8E+00
6.00E-01 1.8E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.26E+03 94% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.35E+03 97% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.44E+03 98% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                            1-99
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Co Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Co EaFA-L05-1313-T01-A 1 9.00E-01 U1/2
Co EaFA-L05-1313-T02-A 1 9.00E-01 U1/2
Co EaFA-L05-1313-T03-A 1 9.00E-01 U1/2
Co EaFA-L05-1313-T04-A 1 9.00E-01 U1/2
Co EaFA-L05-1313-T05-A 1 6.72E+00
Co EaFA-L05-1313-T06-A 1 1.53E+02
Co EaFA-L05-1313-T07-A 1 1.76E+02
Co EaFA-L05-1313-T08-A 1 2.18E+02
Co EaFA-L05-1313-T09-A 1 3.86E+02
Co EaFA-L05-1313-T01-B 1 9.00E-01 U1/2
Co EaFA-L05-1313-T02-B 1 9.00E-01 U1/2
Co EaFA-L05-1313-T03-B 1 9.00E-01 U1/2
Co EaFA-L05-1313-T04-B 1 9.00E-01 U1/2
Co EaFA-L05-1313-T05-B 1 4.97E+00 E
Co EaFA-L05-1313-T06-B 1 1.39E+02
Co EaFA-L05-1313-T07-B 1 1.91E+02
Co EaFA-L05-1313-T08-B 1 2.18E+02
Co EaFA-L05-1313-T09-B 1 4.06E+02
Co EaFA-L05-1313-T01-C 1 9.00E-01 U1/2
Co EaFA-L05-1313-T02-C 1 9.00E-01 U1/2
Co EaFA-L05-1313-T03-C 1 9.00E-01 U1/2
Co EaFA-L05-1313-T04-C 1 9.00E-01 U1/2
Co EaFA-L05-1313-T05-C 1 1.65E+01
Co EaFA-L05-1313-T06-C 1 1.76E+02
Co EaFA-L05-1313-T07-C 1 1.40E+02
Co EaFA-L05-1313-T08-C 1 2.20E+02
Co EaFA-L05-1313-T09-C 1 3.95E+02
Co EaFA-L05-1313-B01-A 1 9.00E-01 U1/2
Co EaFA-L05-1313-B02-A 1 9.00E-01 U1/2
Co EaFA-L05-1313-B03-A 1 9.00E-01 U1/2
Co EaFA-L05-1313-B01-B 1 9.00E-01 U1/2
Co EaFA-L05-1313-B02-B 1 9.00E-01 U1/2
Co EaFA-L05-1313-B03-B 1 9.00E-01 U1/2
Co EaFA-L05-1313-B01-C 1 9.00E-01 U1/2
Co EaFA-L05-1313-B02-C 1 9.00E-01 U1/2
Co EaFA-L05-1313-B03-C 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 7.1E+02 1.8E+00 5.7E+00
9.00E-01 4.3E+01 1.8E+00 5.7E+00
9.00E-01 9.2E+01 1.8E+00 5.7E+00 10 325
9.00E-01 8.4E+01 1.8E+00 5.7E+00
6.72E+00 7.0E+01 1.8E+00 5.7E+00
1.53E+02 3.0E-01 1.8E+00 5.7E+00
1.76E+02 2.1E+00 1.8E+00 5.7E+00
2.18E+02 9.2E-01 1.8E+00 5.7E+00
3.86E+02 6.0E-01 1.8E+00 5.7E+00
9.00E-01 3.3E+01 1.8E+00 5.7E+00
9.00E-01 2.3E+02 1.8E+00 5.7E+00
9.00E-01 2.7E+01 1.8E+00 5.7E+00 10 325
9.00E-01 1.9E+02 1.8E+00 5.7E+00
4.97E+00 4.4E+01 1.8E+00 5.7E+00
1.39E+02 2.5E+00 1.8E+00 5.7E+00
1.91E+02 2.8E+00 1.8E+00 5.7E+00
2.18E+02 8.9E-01 1.8E+00 5.7E+00
4.06E+02 2.6E-01 1.8E+00 5.7E+00
9.00E-01 4.2E+01 1.8E+00 5.7E+00
9.00E-01 8.5E+01 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00 10 325
9.00E-01 6.3E+01 1.8E+00 5.7E+00
1.65E+01 4.8E+00 1.8E+00 5.7E+00
1.76E+02 1.0E+01 1.8E+00 5.7E+00
1.40E+02 1.3E+00 1.8E+00 5.7E+00
2.20E+02 1.0E+00 1.8E+00 5.7E+00
3.95E+02 7.6E-02 1.8E+00 5.7E+00
9.00E-01 6.7E+01 1.8E+00 5.7E+00
9.00E-01 6.8E+01 1.8E+00 5.7E+00
9.00E-01 7.1E+02 1.8E+00 5.7E+00
9.00E-01 5.3E+01 1.8E+00 5.7E+00
9.00E-01 4.3E+02 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 6.5E+01 1.8E+00 5.7E+00
9.00E-01 9.9E+01 1.8E+00 5.7E+00
9.00E-01 8.1E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.13E+03 96% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.19E+03 98% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1012:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.26E+03 100% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          I-100
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Cu Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Cu EaFA-L05-1313-T01-A 1 2.65E+01
Cu EaFA-L05-1313-T02-A 1 4.77E+00 E
Cu EaFA-L05-1313-T03-A 1 8.12E+00 E
Cu EaFA-L05-1313-T04-A 1 7.12E+00 E
Cu EaFA-L05-1313-T05-A 1 1.02E+01 E
Cu EaFA-L05-1313-T06-A 1 1.20E+01
Cu EaFA-L05-1313-T07-A 1 9.97E+00 E
Cu EaFA-L05-1313-T08-A 1 2.29E+03
Cu EaFA-L05-1313-T09-A 1 3.05E+03
Cu EaFA-L05-1313-T01-B 1 2.87E+01
Cu EaFA-L05-1313-T02-B 1 1.85E+OOU1/2
Cu EaFA-L05-1313-T03-B 1 3.78E+00 E
Cu EaFA-L05-1313-T04-B 1 7.86E+00 E
Cu EaFA-L05-1313-T05-B 1 7.03E+00 E
Cu EaFA-L05-1313-T06-B 1 5.70E+00 E
Cu EaFA-L05-1313-T07-B 1 2.11E+01
Cu EaFA-L05-1313-T08-B 1 2.32E+03
Cu EaFA-L05-1313-T09-B 1 3.07E+03
Cu EaFA-L05-1313-T01-C 1 2.96E+01
Cu EaFA-L05-1313-T02-C 1 4.47E+00 E
Cu EaFA-L05-1313-T03-C 1 7.23E+00 E
Cu EaFA-L05-1313-T04-C 1 5.49E+00 E
Cu EaFA-L05-1313-T05-C 1 7.57E+00 E
Cu EaFA-L05-1313-T06-C 1 6.33E+01
Cu EaFA-L05-1313-T07-C 1 1.21E+01
Cu EaFA-L05-1313-T08-C 1 2.18E+03
Cu EaFA-L05-1313-T09-C 1 3.08E+03
Cu EaFA-L05-1313-B01-A 1 1.85E+OOU1/2
Cu EaFA-L05-1313-B02-A 1 1.85E+OOU1/2
Cu EaFA-L05-1313-B03-A 1 1.85E+OOU1/2
Cu EaFA-L05-1313-B01-B 1 1.85E+OOU1/2
Cu EaFA-L05-1313-B02-B 1 1.85E+OOU1/2
Cu EaFA-L05-1313-B03-B 1 1.85E+OOU1/2
Cu EaFA-L05-1313-B01-C 1 1.85E+OOU1/2
Cu EaFA-L05-1313-B02-C 1 1.85E+OOU1/2
Cu EaFA-L05-1313-B03-C 1 1.85E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.65E+01 2.5E+01 3.7E+00 1.2E+01
4.77E+00 4.0E+01 3.7E+00 1.2E+01
8.12E+00 2.5E+01 3.7E+00 1.2E+01 10 325
7.12E+00 1.4E+01 3.7E+00 1.2E+01
1.02E+01 1.8E+01 3.7E+00 1.2E+01
1.20E+01 2.2E+01 3.7E+00 1.2E+01
9.97E+00 1.2E+01 3.7E+00 1.2E+01
2.29E+03 6.8E-01 3.7E+00 1.2E+01
3.05E+03 7.7E-01 3.7E+00 1.2E+01
2.87E+01 9.2E+00 3.7E+00 1.2E+01
1.85E+00 5.5E+01 3.7E+00 1.2E+01
3.78E+00 5.7E+01 3.7E+00 1.2E+01 10 325
7.86E+00 4.3E+01 3.7E+00 1.2E+01
7.03E+00 3.1E+01 3.7E+00 1.2E+01
5.70E+00 4.0E+01 3.7E+00 1.2E+01
2.11E+01 9.4E+00 3.7E+00 1.2E+01
2.32E+03 9.2E-01 3.7E+00 1.2E+01
3.07E+03 1.9E-01 3.7E+00 1.2E+01
2.96E+01 9.0E+00 3.7E+00 1.2E+01
4.47E+00 5.9E+01 3.7E+00 1.2E+01
7.23E+00 5.8E+01 3.7E+00 1.2E+01 10 325
5.49E+00 5.0E+01 3.7E+00 1.2E+01
7.57E+00 3.2E+01 3.7E+00 1.2E+01
6.33E+01 2.3E+01 3.7E+00 1.2E+01
1.21E+01 2.1E+01 3.7E+00 1.2E+01
2.18E+03 7.5E-01 3.7E+00 1.2E+01
3.08E+03 3.4E-01 3.7E+00 1.2E+01
1.85E+00 7.4E+01 3.7E+00 1.2E+01
1.85E+00 1.3E+04 3.7E+00 1.2E+01
1.85E+00 2.2E+02 3.7E+00 1.2E+01
1.85E+00 4.2E+02 3.7E+00 1.2E+01
1.85E+00 1.0E+02 3.7E+00 1.2E+01
1.85E+00 8.9E+01 3.7E+00 1.2E+01
1.85E+00 1.7E+03 3.7E+00 1.2E+01
1.85E+00 7.2E+02 3.7E+00 1.2E+01
1.85E+00 1.9E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.05E+03 94% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.12E+03 96% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.17E+03 97% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-101
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Fe Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Fe EaFA-L05-1313-T01-A 1 3.21E+01
Fe EaFA-L05-1313-T02-A 1 1.13E+01
Fe EaFA-L05-1313-T03-A 1 6.18E+00 E
Fe EaFA-L05-1313-T04-A 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T05-A 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T06-A 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T07-A 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T08-A 1 1.09E+03
Fe EaFA-L05-1313-T09-A 1 3.07E+04
Fe EaFA-L05-1313-T01-B 1 3.91 E+01
Fe EaFA-L05-1313-T02-B 1 1.20E+01
Fe EaFA-L05-1313-T03-B 1 4.94E+00 E
Fe EaFA-L05-1313-T04-B 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T05-B 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T06-B 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T07-B 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T08-B 1 1.24E+03
Fe EaFA-L05-1313-T09-B 1 3.50E+04
Fe EaFA-L05-1313-T01-C 1 3.45E+01
Fe EaFA-L05-1313-T02-C 1 1.19E+01
Fe EaFA-L05-1313-T03-C 1 4.00E+00 E
Fe EaFA-L05-1313-T04-C 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T05-C 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T06-C 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T07-C 1 1.00E+OOU1/2
Fe EaFA-L05-1313-T08-C 1 9.61 E+02
Fe EaFA-L05-1313-T09-C 1 3.33E+04
Fe EaFA-L05-1313-B01-A 1 1.00E+OOU1/2
Fe EaFA-L05-1313-B02-A 1 1.00E+OOU1/2
Fe EaFA-L05-1313-B03-A 1 3.19E+00 E
Fe EaFA-L05-1313-B01-B 1 1.00E+OOU1/2
Fe EaFA-L05-1313-B02-B 1 1.00E+OOU1/2
Fe EaFA-L05-1313-B03-B 1 2.47E+00 E
Fe EaFA-L05-1313-B01-C 1 1.00E+OOU1/2
Fe EaFA-L05-1313-B02-C 1 1.00E+OOU1/2
Fe EaFA-L05-1313-B03-C 1 2.64E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.21E+01 1.4E+00 2.0E+00 6.4E+00
1.13E+01 3.1E+00 2.0E+00 6.4E+00
6.18E+00 5.7E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 5.9E+01 2.0E+00 6.4E+00
1.09E+03 6.4E-01 2.0E+00 6.4E+00
3.07E+04 2.0E-01 2.0E+00 6.4E+00
3.91 E+01 1.4E+00 2.0E+00 6.4E+00
1.20E+01 1.5E+00 2.0E+00 6.4E+00
4.94E+00 2.4E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 8.3E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.24E+03 5.1E-01 2.0E+00 6.4E+00
3.50E+04 2.8E-01 2.0E+00 6.4E+00
3.45E+01 2.7E-01 2.0E+00 6.4E+00
1.19E+01 3.4E+00 2.0E+00 6.4E+00
4.00E+00 1.4E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 4.9E+02 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 7.8E+01 2.0E+00 6.4E+00
1.00E+00 6.7E+01 2.0E+00 6.4E+00
9.61 E+02 1.0E+00 2.0E+00 6.4E+00
3.33E+04 8.3E-01 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
3.19E+00 5.4E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+04 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
2.47E+00 5.0E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 3.2E+01 2.0E+00 6.4E+00
2.64E+00 1.4E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
9.58E+02 95% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
9.86E+02 98% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+03 100% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-102
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Pb Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Pb EaFA-L05-1313-T01-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T02-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T03-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T04-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T05-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T06-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T07-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T08-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T09-A 1 1.21E+02
Pb EaFA-L05-1313-T01-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T02-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T03-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T04-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T05-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T06-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T07-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T08-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T09-B 1 1 .33E+02
Pb EaFA-L05-1313-T01-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T02-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T03-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T04-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T05-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T06-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T07-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T08-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-T09-C 1 1 .25E+02
Pb EaFA-L05-1313-B01-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-B02-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-B03-A 1 3.40E+00 U1/2
Pb EaFA-L05-1313-B01-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-B02-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-B03-B 1 3.40E+00 U1/2
Pb EaFA-L05-1313-B01-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-B02-C 1 3.40E+00 U1/2
Pb EaFA-L05-1313-B03-C 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 1.5E+01 6.8E+00 2.2E+01
3.40E+00 5.7E+01 6.8E+00 2.2E+01
3.40E+00 6.5E+00 6.8E+00 2.2E+01 10 325
3.40E+00 4.6E+01 6.8E+00 2.2E+01
3.40E+00 7.6E+03 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 7.1E+01 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
1.21E+02 2.6E+00 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01
3.40E+00 3.9E+01 6.8E+00 2.2E+01
3.40E+00 2.0E+01 6.8E+00 2.2E+01 10 325
3.40E+00 1.9E+01 6.8E+00 2.2E+01
3.40E+00 3.5E+01 6.8E+00 2.2E+01
3.40E+00 2.5E+01 6.8E+00 2.2E+01
3.40E+00 2.1E+01 6.8E+00 2.2E+01
3.40E+00 5.4E+01 6.8E+00 2.2E+01
1.33E+02 5.1E+00 6.8E+00 2.2E+01
3.40E+00 3.9E+02 6.8E+00 2.2E+01
3.40E+00 4.4E+01 6.8E+00 2.2E+01
3.40E+00 3.4E+01 6.8E+00 2.2E+01 10 325
3.40E+00 6.9E+01 6.8E+00 2.2E+01
3.40E+00 2.8E+02 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
3.40E+00 3.3E+01 6.8E+00 2.2E+01
3.40E+00 4.6E+01 6.8E+00 2.2E+01
1.25E+02 4.6E+00 6.8E+00 2.2E+01
3.40E+00 4.6E+01 6.8E+00 2.2E+01
3.40E+00 8.6E+01 6.8E+00 2.2E+01
3.40E+00 5.1E+01 6.8E+00 2.2E+01
3.40E+00 1.4E+01 6.8E+00 2.2E+01
3.40E+00 7.3E+01 6.8E+00 2.2E+01
3.40E+00 6.4E+01 6.8E+00 2.2E+01
3.40E+00 1.9E+01 6.8E+00 2.2E+01
3.40E+00 3.3E+01 6.8E+00 2.2E+01
3.40E+00 6.6E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
2.99E+03 92% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.10E+03 95% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.16E+03 97% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-103
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Li Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Li EaFA-L05-1313-T01-A 1 1.99E+03
Li EaFA-L05-1313-T02-A 1 2.58E+03
Li EaFA-L05-1313-T03-A 1 2.71E+03
Li EaFA-L05-1313-T04-A 1 2.87E+03
Li EaFA-L05-1313-T05-A 1 3.48E+03
Li EaFA-L05-1313-T06-A 1 3.77E+03
Li EaFA-L05-1313-T07-A 1 3.80E+03
Li EaFA-L05-1313-T08-A 1 2.38E+03
Li EaFA-L05-1313-T09-A 1 1.67E+03
Li EaFA-L05-1313-T01-B 1 1.92E+03
Li EaFA-L05-1313-T02-B 1 2.65E+03
Li EaFA-L05-1313-T03-B 1 2.69E+03
Li EaFA-L05-1313-T04-B 1 2.96E+03
Li EaFA-L05-1313-T05-B 1 3.35E+03
Li EaFA-L05-1313-T06-B 1 3.70E+03
Li EaFA-L05-1313-T07-B 1 3.77E+03
Li EaFA-L05-1313-T08-B 1 2.36E+03
Li EaFA-L05-1313-T09-B 1 1.58E+03
Li EaFA-L05-1313-T01-C 1 2.04E+03
Li EaFA-L05-1313-T02-C 1 2.69E+03
Li EaFA-L05-1313-T03-C 1 3.00E+03
Li EaFA-L05-1313-T04-C 1 2.98E+03
Li EaFA-L05-1313-T05-C 1 3.42E+03
Li EaFA-L05-1313-T06-C 1 3.68E+03
Li EaFA-L05-1313-T07-C 1 3.73E+03
Li EaFA-L05-1313-T08-C 1 2.37E+03
Li EaFA-L05-1313-T09-C 1 1.64E+03
Li EaFA-L05-1313-B01-A 1 3.72E+00 E
Li EaFA-L05-1313-B02-A 1 4.47E+00 E
Li EaFA-L05-1313-B03-A 1 3.30E+00 E
Li EaFA-L05-1313-B01-B 1 3.41E+00 E
Li EaFA-L05-1313-B02-B 1 3.30E+00 E
Li EaFA-L05-1313-B03-B 1 3.24E+00 E
Li EaFA-L05-1313-B01-C 1 3.27E+00 E
Li EaFA-L05-1313-B02-C 1 4.80E+00 E
Li EaFA-L05-1313-B03-C 1 4.18E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.99E+03 6.8E-01 1 .9E+00 6.0E+00
2.58E+03 9.2E-01 1 .9E+00 6.0E+00
2.71E+03 6.0E-01 1 .9E+00 6.0E+00 10 325
2.87E+03 1.0E+00 1 .9E+00 6.0E+00
3.48E+03 3.2E-01 1 .9E+00 6.0E+00
3.77E+03 5.4E-01 1 .9E+00 6.0E+00
3.80E+03 6.6E-01 1 .9E+00 6.0E+00
2.38E+03 5.1E-01 1 .9E+00 6.0E+00
1.67E+03 3.9E-01 1 .9E+00 6.0E+00
1.92E+03 2.6E-01 1 .9E+00 6.0E+00
2.65E+03 6.6E-01 1 .9E+00 6.0E+00
2.69E+03 5.2E-01 1 .9E+00 6.0E+00 10 325
2.96E+03 7.7E-01 1 .9E+00 6.0E+00
3.35E+03 7.2E-01 1 .9E+00 6.0E+00
3.70E+03 3.8E-01 1 .9E+00 6.0E+00
3.77E+03 1.0E+00 1 .9E+00 6.0E+00
2.36E+03 6.4E-01 1 .9E+00 6.0E+00
1.58E+03 7.1E-01 1 .9E+00 6.0E+00
2.04E+03 7.1E-01 1 .9E+00 6.0E+00
2.69E+03 2.1E-01 1 .9E+00 6.0E+00
3.00E+03 4.2E-01 1 .9E+00 6.0E+00 10 325
2.98E+03 2.1E-01 1 .9E+00 6.0E+00
3.42E+03 5.8E-01 1.9E+00 6.0E+00
3.68E+03 1.2E+01 1.9E+00 6.0E+00
3.73E+03 8.5E-01 1.9E+00 6.0E+00
2.37E+03 6.0E-01 1.9E+00 6.0E+00
1.64E+03 7.4E-01 1.9E+00 6.0E+00
3.72E+00 2.7E+01 1.9E+00 6.0E+00
4.47E+00 1.1E+01 1.9E+00 6.0E+00
3.30E+00 2.6E+01 1.9E+00 6.0E+00
3.41 E+00 4.2E+01 1.9E+00 6.0E+00
3.30E+00 2.0E+01 1.9E+00 6.0E+00
3.24E+00 8.1 E+00 1.9E+00 6.0E+00
3.27E+00 6.4E+01 1.9E+00 6.0E+00
4.80E+00 1.6E+01 1.9E+00 6.0E+00
4.18E+00 2.1E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
5.49E+03 86% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
5.47E+03 86% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
5.84E+03 87% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-104
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn EaFA-L05-1313-T01-A 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T02-A 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T03-A 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T04-A 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T05-A 1 8.49E+01
Mn EaFA-L05-1313-T06-A 1 5.82E+02
Mn EaFA-L05-1313-T07-A 1 6.20E+02
Mn EaFA-L05-1313-T08-A 1 9.97E+02
Mn EaFA-L05-1313-T09-A 1 1.53E+03
Mn EaFA-L05-1313-T01-B 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T02-B 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T03-B 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T04-B 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T05-B 1 8.04E+01
Mn EaFA-L05-1313-T06-B 1 5.36E+02
Mn EaFA-L05-1313-T07-B 1 6.28E+02
Mn EaFA-L05-1313-T08-B 1 9.78E+02
Mn EaFA-L05-1313-T09-B 1 1.59E+03
Mn EaFA-L05-1313-T01-C 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T02-C 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T03-C 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T04-C 1 1.00E+OOU1/2
Mn EaFA-L05-1313-T05-C 1 1.42E+02
Mn EaFA-L05-1313-T06-C 1 5.48E+02
Mn EaFA-L05-1313-T07-C 1 5.59E+02
Mn EaFA-L05-1313-T08-C 1 1.04E+03
Mn EaFA-L05-1313-T09-C 1 1.59E+03
Mn EaFA-L05-1313-B01-A 1 1.00E+OOU1/2
Mn EaFA-L05-1313-B02-A 1 1.00E+OOU1/2
Mn EaFA-L05-1313-B03-A 1 1.00E+OOU1/2
Mn EaFA-L05-1313-B01-B 1 1.00E+OOU1/2
Mn EaFA-L05-1313-B02-B 1 1.00E+OOU1/2
Mn EaFA-L05-1313-B03-B 1 1.00E+OOU1/2
Mn EaFA-L05-1313-B01-C 1 1.00E+OOU1/2
Mn EaFA-L05-1313-B02-C 1 1.00E+OOU1/2
Mn EaFA-L05-1313-B03-C 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.6E+00 2.0E+00 6.4E+00
1.00E+00 9.1E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+02 2.0E+00 6.4E+00 10 325
1.00E+00 1.9E+01 2.0E+00 6.4E+00
8.49E+01 2.1E+00 2.0E+00 6.4E+00
5.82E+02 1.1E+00 2.0E+00 6.4E+00
6.20E+02 7.3E-01 2.0E+00 6.4E+00
9.97E+02 1.2E-01 2.0E+00 6.4E+00
1.53E+03 4.2E-01 2.0E+00 6.4E+00
1.00E+00 7.6E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00 10 325
1.00E+00 2.1E+01 2.0E+00 6.4E+00
8.04E+01 9.4E-01 2.0E+00 6.4E+00
5.36E+02 1.4E+00 2.0E+00 6.4E+00
6.28E+02 8.9E-01 2.0E+00 6.4E+00
9.78E+02 3.3E-01 2.0E+00 6.4E+00
1.59E+03 1.8E-01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 8.2E+01 2.0E+00 6.4E+00
1.00E+00 6.6E+02 2.0E+00 6.4E+00 10 325
1.00E+00 6.2E+00 2.0E+00 6.4E+00
1.42E+02 8.2E-01 2.0E+00 6.4E+00
5.48E+02 9.9E+00 2.0E+00 6.4E+00
5.59E+02 1.0E+00 2.0E+00 6.4E+00
1.04E+03 4.6E-01 2.0E+00 6.4E+00
1.59E+03 2.0E-01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 6.2E-01 2.0E+00 6.4E+00
1.00E+00 9.6E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 4.4E+02 2.0E+00 6.4E+00
1.00E+00 1.3E+03 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.03E+03 93% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.13E+03 96% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.19E+03 98% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-105
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mg Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mg EaFA-L05-1313-T01-A 1 5.00E-01 U1/2
Mg EaFA-L05-1313-T02-A 1 5.00E-01 U1/2
Mg EaFA-L05-1313-T03-A 1 5.13E+01
Mg EaFA-L05-1313-T04-A 1 3.33E+03
Mg EaFA-L05-1313-T05-A 1 5.49E+03
Mg EaFA-L05-1313-T06-A 1 7.17E+03
Mg EaFA-L05-1313-T07-A 1 7.16E+03
Mg EaFA-L05-1313-T08-A 1 8.17E+03
Mg EaFA-L05-1313-T09-A 1 1.29E+04
Mg EaFA-L05-1313-T01-B 1 5.00E-01 U1/2
Mg EaFA-L05-1313-T02-B 1 5.00E-01 U1/2
Mg EaFA-L05-1313-T03-B 1 5.73E+01
Mg EaFA-L05-1313-T04-B 1 3.45E+03
Mg EaFA-L05-1313-T05-B 1 5.03E+03
Mg EaFA-L05-1313-T06-B 1 7.01 E+03
Mg EaFA-L05-1313-T07-B 1 6.87E+03
Mg EaFA-L05-1313-T08-B 1 8.10E+03
Mg EaFA-L05-1313-T09-B 1 1.34E+04
Mg EaFA-L05-1313-T01-C 1 5.00E-01 U1/2
Mg EaFA-L05-1313-T02-C 1 5.00E-01 U1/2
Mg EaFA-L05-1313-T03-C 1 8.21E+01
Mg EaFA-L05-1313-T04-C 1 3.35E+03
Mg EaFA-L05-1313-T05-C 1 5.19E+03
Mg EaFA-L05-1313-T06-C 1 6.61 E+03
Mg EaFA-L05-1313-T07-C 1 6.96E+03
Mg EaFA-L05-1313-T08-C 1 8.19E+03
Mg EaFA-L05-1313-T09-C 1 1.31E+04
Mg EaFA-L05-1313-B01-A 1 5.00E-01 U1/2
Mg EaFA-L05-1313-B02-A 1 5.00E-01 U1/2
Mg EaFA-L05-1313-B03-A 1 5.00E-01 U1/2
Mg EaFA-L05-1313-B01-B 1 5.00E-01 U1/2
Mg EaFA-L05-1313-B02-B 1 5.00E-01 U1/2
Mg EaFA-L05-1313-B03-B 1 5.00E-01 U1/2
Mg EaFA-L05-1313-B01-C 1 5.00E-01 U1/2
Mg EaFA-L05-1313-B02-C 1 5.00E-01 U1/2
Mg EaFA-L05-1313-B03-C 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 3.0E+01 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
5.13E+01 1.6E+01 1.0E+00 3.2E+00 1000 100
3.33E+03 8.5E-01 1.0E+00 3.2E+00
5.49E+03 5.5E-02 1.0E+00 3.2E+00
7.17E+03 9.6E-01 1.0E+00 3.2E+00
7.16E+03 5.7E-01 1.0E+00 3.2E+00
8.17E+03 8.8E-01 1.0E+00 3.2E+00
1.29E+04 8.4E-01 1.0E+00 3.2E+00
5.00E-01 2.3E+01 1.0E+00 3.2E+00
5.00E-01 8.0E+01 1.0E+00 3.2E+00
5.73E+01 1.6E+01 1.0E+00 3.2E+00 1000 100
3.45E+03 8.1E-01 1.0E+00 3.2E+00
5.03E+03 9.8E-01 1.0E+00 3.2E+00
7.01 E+03 4.6E-01 1.0E+00 3.2E+00
6.87E+03 6.9E-01 1.0E+00 3.2E+00
8.10E+03 3.1E-01 1.0E+00 3.2E+00
1.34E+04 9.5E-01 1.0E+00 3.2E+00
5.00E-01 6.9E+00 1.0E+00 3.2E+00
5.00E-01 4.1E+02 1.0E+00 3.2E+00
8.21 E+01 1.0E+01 1.0E+00 3.2E+00 1000 100
3.35E+03 4.1E-01 1.0E+00 3.2E+00
5.19E+03 8.6E-01 1.0E+00 3.2E+00
6.61 E+03 9.8E+00 1.0E+00 3.2E+00
6.96E+03 1.2E+00 1.0E+00 3.2E+00
8.19E+03 5.9E-01 1.0E+00 3.2E+00
1.31E+04 1.6E+00 1.0E+00 3.2E+00
5.00E-01 1.6E+01 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
5.00E-01 5.8E+01 1.0E+00 3.2E+00
5.00E-01 3.2E+01 1.0E+00 3.2E+00
5.00E-01 2.3E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
5.00E-01 1.8E+01 1.0E+00 3.2E+00
5.00E-01 2.6E+01 1.0E+00 3.2E+00
5.00E-01 6.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
1.00E+03 95% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
1.06E+03 100% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1012:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.09E+03 101% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-106
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mo Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mo EaFA-L05-1313-T01-A 1 3.95E+03
Mo EaFA-L05-1313-T02-A 1 4.01 E+03
Mo EaFA-L05-1313-T03-A 1 3.74E+03
Mo EaFA-L05-1313-T04-A 1 3.73E+03
Mo EaFA-L05-1313-T05-A 1 3.72E+03
Mo EaFA-L05-1313-T06-A 1 2.29E+03
Mo EaFA-L05-1313-T07-A 1 1.94E+03
Mo EaFA-L05-1313-T08-A 1 1.17E+02
Mo EaFA-L05-1313-T09-A 1 5.68E+02
Mo EaFA-L05-1313-T01-B 1 4.03E+03
Mo EaFA-L05-1313-T02-B 1 4.01 E+03
Mo EaFA-L05-1313-T03-B 1 3.80E+03
Mo EaFA-L05-1313-T04-B 1 3.60E+03
Mo EaFA-L05-1313-T05-B 1 3.34E+03
Mo EaFA-L05-1313-T06-B 1 2.40E+03
Mo EaFA-L05-1313-T07-B 1 1.44E+03
Mo EaFA-L05-1313-T08-B 1 1.18E+02
Mo EaFA-L05-1313-T09-B 1 5.47E+02
Mo EaFA-L05-1313-T01-C 1 4.03E+03
Mo EaFA-L05-1313-T02-C 1 4.08E+03
Mo EaFA-L05-1313-T03-C 1 3.99E+03
Mo EaFA-L05-1313-T04-C 1 3.78E+03
Mo EaFA-L05-1313-T05-C 1 3.45E+03
Mo EaFA-L05-1313-T06-C 1 1.18E+03
Mo EaFA-L05-1313-T07-C 1 2.29E+03
Mo EaFA-L05-1313-T08-C 1 1.32E+02
Mo EaFA-L05-1313-T09-C 1 5.66E+02
Mo EaFA-L05-1313-B01-A 1 1.04E+01
Mo EaFA-L05-1313-B02-A 1 8.14E+00
Mo EaFA-L05-1313-B03-A 1 1.72E+01
Mo EaFA-L05-1313-B01-B 1 1.35E+01
Mo EaFA-L05-1313-B02-B 1 6.99E+00
Mo EaFA-L05-1313-B03-B 1 1.44E+01
Mo EaFA-L05-1313-B01-C 1 1.35E+01
Mo EaFA-L05-1313-B02-C 1 4.36E+00
Mo EaFA-L05-1313-B03-C 1 1.11E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.95E+03 2.0E-01 1 .2E+00 3.8E+00
4.01 E+03 8.8E-01 1 .2E+00 3.8E+00
3.74E+03 2.8E-01 1 .2E+00 3.8E+00 10 325
3.73E+03 2.3E-01 1.2E+00 3.8E+00
3.72E+03 1.7E+00 1.2E+00 3.8E+00
2.29E+03 6.8E-01 1.2E+00 3.8E+00
1.94E+03 3.6E-01 1.2E+00 3.8E+00
1.17E+02 2.2E+00 1.2E+00 3.8E+00
5.68E+02 1.1E+00 1.2E+00 3.8E+00
4.03E+03 1.1E+00 1.2E+00 3.8E+00
4.01 E+03 1.7E-01 1.2E+00 3.8E+00
3.80E+03 1.9E-01 1.2E+00 3.8E+00 10 325
3.60E+03 5.4E-01 1.2E+00 3.8E+00
3.34E+03 1.0E+00 1.2E+00 3.8E+00
2.40E+03 3.2E-01 1.2E+00 3.8E+00
1.44E+03 5.2E-01 1.2E+00 3.8E+00
1.18E+02 1.2E+00 1.2E+00 3.8E+00
5.47E+02 6.4E-01 1.2E+00 3.8E+00
4.03E+03 1.0E+00 1.2E+00 3.8E+00
4.08E+03 8.6E-01 1.2E+00 3.8E+00
3.99E+03 5.2E-01 1.2E+00 3.8E+00 10 325
3.78E+03 1.4E+00 1.2E+00 3.8E+00
3.45E+03 6.0E-01 1.2E+00 3.8E+00
1.18E+03 1.2E+01 1.2E+00 3.8E+00
2.29E+03 1.0E+00 1.2E+00 3.8E+00
1.32E+02 1.8E+00 1.2E+00 3.8E+00
5.66E+02 4.6E-01 1.2E+00 3.8E+00
1.04E+01 6.2E+00 1.2E+00 3.8E+00
8.14E+00 1.7E+01 1.2E+00 3.8E+00
1.72E+01 1.3E+01 1.2E+00 3.8E+00
1.35E+01 1.9E+01 1.2E+00 3.8E+00
6.99E+00 9.3E+01 1.2E+00 3.8E+00
1.44E+01 1.7E+00 1.2E+00 3.8E+00
1.35E+01 2.3E+01 1.2E+00 3.8E+00
4.36E+00 7.6E+01 1.2E+00 3.8E+00
1.11E+01 3.6E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
6.65E+03 90% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
6.63E+03 87% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
6.89E+03 89% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-107
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ni Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Ni EaFA-L05-1313-T01-A 1 9.00E-01 U1/2
Ni EaFA-L05-1313-T02-A 1 1.98E+OOE
Ni EaFA-L05-1313-T03-A 1 9.00E-01 U1/2
Ni EaFA-L05-1313-T04-A 1 3.06E+00 E
Ni EaFA-L05-1313-T05-A 1 2.20E+01
Ni EaFA-L05-1313-T06-A 1 3.42E+02
Ni EaFA-L05-1313-T07-A 1 4.02E+02
Ni EaFA-L05-1313-T08-A 1 5.09E+02
Ni EaFA-L05-1313-T09-A 1 6.87E+02
Ni EaFA-L05-1313-T01-B 1 9.00E-01 U1/2
Ni EaFA-L05-1313-T02-B 1 9.00E-01 U1/2
Ni EaFA-L05-1313-T03-B 1 9.00E-01 U1/2
Ni EaFA-L05-1313-T04-B 1 9.00E-01 U1/2
Ni EaFA-L05-1313-T05-B 1 1.96E+01
Ni EaFA-L05-1313-T06-B 1 3.00E+02
Ni EaFA-L05-1313-T07-B 1 4.54E+02
Ni EaFA-L05-1313-T08-B 1 5.13E+02
Ni EaFA-L05-1313-T09-B 1 7.05E+02
Ni EaFA-L05-1313-T01-C 1 2.50E+00 E
Ni EaFA-L05-1313-T02-C 1 9.00E-01 U1/2
Ni EaFA-L05-1313-T03-C 1 9.00E-01 U1/2
Ni EaFA-L05-1313-T04-C 1 9.00E-01 U1/2
Ni EaFA-L05-1313-T05-C 1 5.14E+01
Ni EaFA-L05-1313-T06-C 1 4.45E+02
Ni EaFA-L05-1313-T07-C 1 3.14E+02
Ni EaFA-L05-1313-T08-C 1 5.21E+02
Ni EaFA-L05-1313-T09-C 1 7.01 E+02
Ni EaFA-L05-1313-B01-A 1 9.00E-01 U1/2
Ni EaFA-L05-1313-B02-A 1 9.00E-01 U1/2
Ni EaFA-L05-1313-B03-A 1 9.00E-01 U1/2
Ni EaFA-L05-1313-B01-B 1 9.00E-01 U1/2
Ni EaFA-L05-1313-B02-B 1 9.00E-01 U1/2
Ni EaFA-L05-1313-B03-B 1 9.00E-01 U1/2
Ni EaFA-L05-1313-B01-C 1 9.00E-01 U1/2
Ni EaFA-L05-1313-B02-C 1 9.00E-01 U1/2
Ni EaFA-L05-1313-B03-C 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 5.5E+01 1.8E+00 5.7E+00
1.98E+00 1.4E+02 1.8E+00 5.7E+00
9.00E-01 3.6E+02 1.8E+00 5.7E+00 10 325
3.06E+00 1.6E+02 1.8E+00 5.7E+00
2.20E+01 1.1E+01 1.8E+00 5.7E+00
3.42E+02 2.0E-01 1.8E+00 5.7E+00
4.02E+02 4.1E-01 1.8E+00 5.7E+00
5.09E+02 5.6E-01 1.8E+00 5.7E+00
6.87E+02 4.6E-01 1.8E+00 5.7E+00
9.00E-01 2.5E+02 1.8E+00 5.7E+00
9.00E-01 5.5E+02 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00 10 325
9.00E-01 1.8E+02 1.8E+00 5.7E+00
1.96E+01 7.2E+00 1.8E+00 5.7E+00
3.00E+02 8.5E-01 1.8E+00 5.7E+00
4.54E+02 1.5E+00 1.8E+00 5.7E+00
5.13E+02 1.1E+00 1.8E+00 5.7E+00
7.05E+02 2.9E-01 1.8E+00 5.7E+00
2.50E+00 2.1 E+02 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 1.5E+03 1.8E+00 5.7E+00 10 325
9.00E-01 1.9E+03 1.8E+00 5.7E+00
5.14E+01 5.8E+00 1.8E+00 5.7E+00
4.45E+02 1.2E+01 1.8E+00 5.7E+00
3.14E+02 2.5E+00 1.8E+00 5.7E+00
5.21 E+02 1.2E+00 1.8E+00 5.7E+00
7.01 E+02 3.4E-01 1.8E+00 5.7E+00
9.00E-01 2.0E+03 1.8E+00 5.7E+00
9.00E-01 1.1 E+02 1.8E+00 5.7E+00
9.00E-01 6.8E+02 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 4.7E+02 1.8E+00 5.7E+00
9.00E-01 3.7E+02 1.8E+00 5.7E+00
9.00E-01 2.4E+02 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 8.3E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.05E+03 94% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.15E+03 97% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1012:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.24E+03 100% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-108
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
P Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
P EaFA-L05-1313-T01-A 1 5.06E+01
P EaFA-L05-1313-T02-A 1 1.70E+01
P EaFA-L05-1313-T03-A 1 2.72E+01
P EaFA-L05-1313-T04-A 1 6.14E+01
P EaFA-L05-1313-T05-A 1 1.51E+01
P EaFA-L05-1313-T06-A 1 5.09E+00 E
P EaFA-L05-1313-T07-A 1 1.48E+01
P EaFA-L05-1313-T08-A 1 4.54E+01
P EaFA-L05-1313-T09-A 1 3.93E+03
P EaFA-L05-1313-T01-B 1 6.49E+01
P EaFA-L05-1313-T02-B 1 1.42E+01
P EaFA-L05-1313-T03-B 1 2.59E+01
P EaFA-L05-1313-T04-B 1 2.78E+01
P EaFA-L05-1313-T05-B 1 2.48E+01
P EaFA-L05-1313-T06-B 1 7.85E+00 E
P EaFA-L05-1313-T07-B 1 9.80E+00 E
P EaFA-L05-1313-T08-B 1 4.89E+01
P EaFA-L05-1313-T09-B 1 4.29E+03
P EaFA-L05-1313-T01-C 1 6.20E+01
P EaFA-L05-1313-T02-C 1 2.14E+01
P EaFA-L05-1313-T03-C 1 3.73E+01
P EaFA-L05-1313-T04-C 1 5.11E+01
P EaFA-L05-1313-T05-C 1 1.95E+01
P EaFA-L05-1313-T06-C 1 1.44E+01
P EaFA-L05-1313-T07-C 1 1.54E+01
P EaFA-L05-1313-T08-C 1 4.29E+01
P EaFA-L05-1313-T09-C 1 4.31 E+03
P EaFA-L05-1313-B01-A 1 7.30E+00 E
P EaFA-L05-1313-B02-A 1 1.85E+OOU1/2
P EaFA-L05-1313-B03-A 1 4.88E+01
P EaFA-L05-1313-B01-B 1 3.75E+00 E
P EaFA-L05-1313-B02-B 1 1.85E+OOU1/2
P EaFA-L05-1313-B03-B 1 6.44E+01
P EaFA-L05-1313-B01-C 1 1.02E+01 E
P EaFA-L05-1313-B02-C 1 1.85E+OOU1/2
P EaFA-L05-1313-B03-C 1 5.98E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.06E+01 1.3E+01 3.7E+00 1.2E+01
1.70E+01 5.6E+01 3.7E+00 1.2E+01
2.72E+01 5.1E+01 3.7E+00 1.2E+01 1000 100
6.14E+01 1.4E+01 3.7E+00 1.2E+01
1.51E+01 3.8E+01 3.7E+00 1.2E+01
5.09E+00 1.0E+02 3.7E+00 1.2E+01
1.48E+01 6.8E+01 3.7E+00 1.2E+01
4.54E+01 1.0E+01 3.7E+00 1.2E+01
3.93E+03 2.2E-01 3.7E+00 1.2E+01
6.49E+01 9.6E+00 3.7E+00 1.2E+01
1.42E+01 4.8E+01 3.7E+00 1.2E+01
2.59E+01 6.3E+01 3.7E+00 1.2E+01 1000 100
2.78E+01 1.3E+01 3.7E+00 1.2E+01
2.48E+01 5.5E+01 3.7E+00 1.2E+01
7.85E+00 6.4E+01 3.7E+00 1.2E+01
9.80E+00 1.0E+02 3.7E+00 1.2E+01
4.89E+01 3.7E+00 3.7E+00 1.2E+01
4.29E+03 5.0E-01 3.7E+00 1.2E+01
6.20E+01 4.4E+00 3.7E+00 1.2E+01
2.14E+01 1.5E+01 3.7E+00 1.2E+01
3.73E+01 2.2E+01 3.7E+00 1.2E+01 1000 100
5.11E+01 3.6E+00 3.7E+00 1.2E+01
1.95E+01 4.1E+01 3.7E+00 1.2E+01
1.44E+01 5.2E+01 3.7E+00 1.2E+01
1.54E+01 3.2E+01 3.7E+00 1.2E+01
4.29E+01 1.1E+01 3.7E+00 1.2E+01
4.31 E+03 5.4E-01 3.7E+00 1.2E+01
7.30E+00 4.9E+01 3.7E+00 1.2E+01
1.85E+00 1.1E+05 3.7E+00 1.2E+01
4.88E+01 3.4E+01 3.7E+00 1.2E+01
3.75E+00 1.1E+02 3.7E+00 1.2E+01
1.85E+00 1.1E+02 3.7E+00 1.2E+01
6.44E+01 7.6E-01 3.7E+00 1.2E+01
1.02E+01 7.4E+01 3.7E+00 1.2E+01
1.85E+00 4.1E+01 3.7E+00 1.2E+01
5.98E+01 1.2E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
9.58E+02 93% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
9.90E+02 96% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.01E+03 97% VUICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-109
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L |
K EaFA-L05-1313-T01-A 1 1.55E+06
K EaFA-L05-1313-T02-A 1 3.74E+05
K EaFA-L05-1313-T03-A 1 1.79E+05
K EaFA-L05-1313-T04-A 1 1.06E+05
K EaFA-L05-1313-T05-A 1 6.21E+04
K EaFA-L05-1313-T06-A 1 2.38E+04
K EaFA-L05-1313-T07-A 1 2.38E+04
K EaFA-L05-1313-T08-A 1 1.72E+04
K EaFA-L05-1313-T09-A 1 1.87E+04
K EaFA-L05-1313-T01-B 1 1.52E+06
K EaFA-L05-1313-T02-B 1 3.64E+05
K EaFA-L05-1313-T03-B 1 1.76E+05
K EaFA-L05-1313-T04-B 1 1.08E+05
K EaFA-L05-1313-T05-B 1 6.07E+04
K EaFA-L05-1313-T06-B 1 2.29E+04
K EaFA-L05-1313-T07-B 1 2.34E+04
K EaFA-L05-1313-T08-B 1 1.71E+04
K EaFA-L05-1313-T09-B 1 1.88E+04
K EaFA-L05-1313-T01-C 1 1.54E+06
K EaFA-L05-1313-T02-C 1 3.80E+05
K EaFA-L05-1313-T03-C 1 1.83E+05
K EaFA-L05-1313-T04-C 1 1.07E+05
K EaFA-L05-1313-T05-C 1 6.17E+04
K EaFA-L05-1313-T06-C 1 2.33E+04
K EaFA-L05-1313-T07-C 1 2.33E+04
K EaFA-L05-1313-T08-C 1 1.72E+04
K EaFA-L05-1313-T09-C 1 1.89E+04
K EaFA-L05-1313-B01-A 1 8.55E+01
K EaFA-L05-1313-B02-A 1 2.35E+02
K EaFA-L05-1313-B03-A 1 1.58E+06
K EaFA-L05-1313-B01-B 1 1.79E+02
K EaFA-L05-1313-B02-B 1 1.98E+02
K EaFA-L05-1313-B03-B 1 1.56E+06
K EaFA-L05-1313-B01-C 1 1.19E+02
K EaFA-L05-1313-B02-C 1 1.93E+02
K EaFA-L05-1313-B03-C 1 1 .58E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.55E+06 1.1E-01 1.6E+00 5.1E+00
3.74E+05 1.0E+00 1 .6E+00 5.1E+00
1.79E+05 8.2E-01 1 .6E+00 5.1E+00 1000 100
1.06E+05 4.4E-01 1 .6E+00 5.1E+00
6.21 E+04 1.9E-01 1 .6E+00 5.1E+00
2.38E+04 8.2E-01 1 .6E+00 5.1E+00
2.38E+04 9.5E-01 1 .6E+00 5.1E+00
1.72E+04 1.8E-01 1 .6E+00 5.1E+00
1.87E+04 2.3E-01 1 .6E+00 5.1E+00
1.52E+06 5.3E-01 1 .6E+00 5.1E+00
3.64E+05 3.6E-01 1 .6E+00 5.1E+00
1.76E+05 7.2E-01 1 .6E+00 5.1E+00 1000 100
1.08E+05 5.1E-01 1.6E+00 5.1E+00
6.07E+04 6.1E-01 1 .6E+00 5.1E+00
2.29E+04 3.4E-01 1 .6E+00 5.1E+00
2.34E+04 1.6E+00 1 .6E+00 5.1E+00
1.71 E+04 4.4E-01 1 .6E+00 5.1E+00
1.88E+04 4.7E-01 1 .6E+00 5.1E+00
1.54E+06 4.4E-01 1 .6E+00 5.1E+00
3.80E+05 2.5E+00 1 .6E+00 5.1E+00
1.83E+05 2.6E-01 1 .6E+00 5.1E+00 1000 100
1.07E+05 4.4E-01 1.6E+00 5.1E+00
6.17E+04 2.8E-01 1.6E+00 5.1E+00
2.33E+04 9.0E+00 1.6E+00 5.1E+00
2.33E+04 7.4E-01 1.6E+00 5.1E+00
1.72E+04 4.4E-01 1.6E+00 5.1E+00
1.89E+04 7.7E-01 1.6E+00 5.1E+00
8.55E+01 1.3E+00 1.6E+00 5.1E+00
2.35E+02 1.2E+00 1.6E+00 5.1E+00
1.58E+06 1.8E+00 1.6E+00 5.1E+00
1.79E+02 9.7E-01 1.6E+00 5.1E+00
1.98E+02 2.7E+00 1.6E+00 5.1E+00
1.56E+06 1.4E+00 1.6E+00 5.1E+00
1.19E+02 8.2E-01 1.6E+00 5.1E+00
1.93E+02 1.6E+00 1.6E+00 5.1E+00
1.58E+06 3.9E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
1.80E+05 87% VUICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
1.77E+05 83% VUICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.84E+05 88% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-110
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Se Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Se EaFA-L05-1313-T01-A 1 6.64E+03
Se EaFA-L05-1313-T02-A 1 5.30E+03
Se EaFA-L05-1313-T03-A 1 4.40E+03
Se EaFA-L05-1313-T04-A 1 3.23E+03
Se EaFA-L05-1313-T05-A 1 1.59E+03
Se EaFA-L05-1313-T06-A 1 5.75E+02
Se EaFA-L05-1313-T07-A 1 5.47E+02
Se EaFA-L05-1313-T08-A 1 1.02E+02
Se EaFA-L05-1313-T09-A 1 1.14E+03
Se EaFA-L05-1313-T01-B 1 6.67E+03
Se EaFA-L05-1313-T02-B 1 5.43E+03
Se EaFA-L05-1313-T03-B 1 4.66E+03
Se EaFA-L05-1313-T04-B 1 3.10E+03
Se EaFA-L05-1313-T05-B 1 1.45E+03
Se EaFA-L05-1313-T06-B 1 5.64E+02
Se EaFA-L05-1313-T07-B 1 4.34E+02
Se EaFA-L05-1313-T08-B 1 9.32E+01
Se EaFA-L05-1313-T09-B 1 1.21E+03
Se EaFA-L05-1313-T01-C 1 6.74E+03
Se EaFA-L05-1313-T02-C 1 5.68E+03
Se EaFA-L05-1313-T03-C 1 5.13E+03
Se EaFA-L05-1313-T04-C 1 3.12E+03
Se EaFA-L05-1313-T05-C 1 1.14E+03
Se EaFA-L05-1313-T06-C 1 4.11E+02
Se EaFA-L05-1313-T07-C 1 5.66E+02
Se EaFA-L05-1313-T08-C 1 1.00E+02
Se EaFA-L05-1313-T09-C 1 1.25E+03
Se EaFA-L05-1313-B01-A 1 3.33E+01 E
Se EaFA-L05-1313-B02-A 1 3.84E+01 E
Se EaFA-L05-1313-B03-A 1 7.50E+00 U1/2
Se EaFA-L05-1313-B01-B 1 3.60E+01 E
Se EaFA-L05-1313-B02-B 1 3.99E+01 E
Se EaFA-L05-1313-B03-B 1 7.50E+00 U1/2
Se EaFA-L05-1313-B01-C 1 2.39E+01 E
Se EaFA-L05-1313-B02-C 1 2.53E+01 E
Se EaFA-L05-1313-B03-C 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.64E+03 6.4E-01 1 .5E+01 4.8E+01
5.30E+03 1.1E+00 1 .5E+01 4.8E+01
4.40E+03 1.6E+00 1 .5E+01 4.8E+01 10 325
3.23E+03 1.6E+00 1 .5E+01 4.8E+01
1.59E+03 1.5E+00 1.5E+01 4.8E+01
5.75E+02 5.8E+00 1.5E+01 4.8E+01
5.47E+02 1.5E+00 1.5E+01 4.8E+01
1.02E+02 1.0E+01 1.5E+01 4.8E+01
1.14E+03 1.7E+00 1.5E+01 4.8E+01
6.67E+03 1.0E+00 1.5E+01 4.8E+01
5.43E+03 8.3E-01 1.5E+01 4.8E+01
4.66E+03 1.8E+00 1.5E+01 4.8E+01 10 325
3.10E+03 1.1E+00 1.5E+01 4.8E+01
1.45E+03 4.3E+00 1.5E+01 4.8E+01
5.64E+02 7.3E+00 1.5E+01 4.8E+01
4.34E+02 6.9E+00 1.5E+01 4.8E+01
9.32E+01 7.6E+00 1.5E+01 4.8E+01
1.21E+03 5.6E-01 1.5E+01 4.8E+01
6.74E+03 5.5E-01 1.5E+01 4.8E+01
5.68E+03 1.0E+00 1.5E+01 4.8E+01
5.13E+03 9.9E-01 1.5E+01 4.8E+01 10 325
3.12E+03 1.9E-01 1.5E+01 4.8E+01
1.14E+03 1.9E+00 1.5E+01 4.8E+01
4.11E+02 2.0E+01 1.5E+01 4.8E+01
5.66E+02 5.8E+00 1.5E+01 4.8E+01
1.00E+02 3.4E+00 1.5E+01 4.8E+01
1.25E+03 1.5E+00 1.5E+01 4.8E+01
3.33E+01 2.1E+01 1.5E+01 4.8E+01
3.84E+01 6.7E+01 1.5E+01 4.8E+01
7.50E+00 6.8E+01 1.5E+01 4.8E+01
3.60E+01 5.9E+01 1.5E+01 4.8E+01
3.99E+01 7.8E+01 1.5E+01 4.8E+01
7.50E+00 5.8E+02 1.5E+01 4.8E+01
2.39E+01 6.8E+01 1.5E+01 4.8E+01
2.53E+01 7.7E+01 1.5E+01 4.8E+01
7.50E+00 2.1E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
7.23E+03 87% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
7.39E+03 84% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
7.88E+03 85% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-111
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Si Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Si EaFA-L05-1313-T01-A 1 9.02E+03
Si EaFA-L05-1313-T02-A 1 3.25E+03
Si EaFA-L05-1313-T03-A 1 1.22E+03
Si EaFA-L05-1313-T04-A 1 2.71E+02
Si EaFA-L05-1313-T05-A 1 8.07E+02
Si EaFA-L05-1313-T06-A 1 3.60E+03
Si EaFA-L05-1313-T07-A 1 4.30E+03
Si EaFA-L05-1313-T08-A 1 2.44E+04
Si EaFA-L05-1313-T09-A 1 5.77E+04
Si EaFA-L05-1313-T01-B 1 9.79E+03
Si EaFA-L05-1313-T02-B 1 3.09E+03
Si EaFA-L05-1313-T03-B 1 1.25E+03
Si EaFA-L05-1313-T04-B 1 2.25E+02
Si EaFA-L05-1313-T05-B 1 7.04E+02
Si EaFA-L05-1313-T06-B 1 3.36E+03
Si EaFA-L05-1313-T07-B 1 4.38E+03
Si EaFA-L05-1313-T08-B 1 2.49E+04
Si EaFA-L05-1313-T09-B 1 6.51E+04
Si EaFA-L05-1313-T01-C 1 1.07E+04
Si EaFA-L05-1313-T02-C 1 3.41E+03
Si EaFA-L05-1313-T03-C 1 1.02E+03
Si EaFA-L05-1313-T04-C 1 2.64E+02
Si EaFA-L05-1313-T05-C 1 1.00E+03
Si EaFA-L05-1313-T06-C 1 3.89E+03
Si EaFA-L05-1313-T07-C 1 3.80E+03
Si EaFA-L05-1313-T08-C 1 2.49E+04
Si EaFA-L05-1313-T09-C 1 6.23E+04
Si EaFA-L05-1313-B01-A 1 5.50E-01 U1/2
Si EaFA-L05-1313-B02-A 1 5.50E-01 U1/2
Si EaFA-L05-1313-B03-A 1 2.37E+02
Si EaFA-L05-1313-B01-B 1 5.50E-01 U1/2
Si EaFA-L05-1313-B02-B 1 5.50E-01 U1/2
Si EaFA-L05-1313-B03-B 1 3.37E+02
Si EaFA-L05-1313-B01-C 1 5.50E-01 U1/2
Si EaFA-L05-1313-B02-C 1 5.50E-01 U1/2
Si EaFA-L05-1313-B03-C 1 2.53E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.02E+03 7.4E-01 1.1E+00 3.5E+00
3.25E+03 8.1E-01 1.1E+00 3.5E+00
1.22E+03 5.2E-01 1.1E+00 3.5E+00 1000 100
2.71E+02 1.9E+00 1.1E+00 3.5E+00
8.07E+02 4.2E-01 1.1E+00 3.5E+00
3.60E+03 8.6E-01 1.1E+00 3.5E+00
4.30E+03 4.0E-01 1.1E+00 3.5E+00
2.44E+04 1.4E-01 1.1E+00 3.5E+00
5.77E+04 7.0E-01 1.1E+00 3.5E+00
9.79E+03 8.1E-01 1.1E+00 3.5E+00
3.09E+03 9.3E-01 1.1E+00 3.5E+00
1.25E+03 1.4E+00 1.1E+00 3.5E+00 1000 100
2.25E+02 9.1E-01 1.1E+00 3.5E+00
7.04E+02 1.0E+00 1.1E+00 3.5E+00
3.36E+03 6.0E-01 1.1E+00 3.5E+00
4.38E+03 1.2E+00 1.1E+00 3.5E+00
2.49E+04 6.0E-01 1.1E+00 3.5E+00
6.51E+04 5.7E-01 1.1E+00 3.5E+00
1.07E+04 4.1E-01 1.1E+00 3.5E+00
3.41E+03 4.1E-01 1.1E+00 3.5E+00
1.02E+03 2.5E-01 1.1E+00 3.5E+00 1000 100
2.64E+02 6.8E-01 1.1E+00 3.5E+00
1.00E+03 9.3E-01 1.1E+00 3.5E+00
3.89E+03 1.3E+01 1.1E+00 3.5E+00
3.80E+03 8.7E-01 1.1E+00 3.5E+00
2.49E+04 1.1E+00 1.1E+00 3.5E+00
6.23E+04 3.4E-01 1.1E+00 3.5E+00
5.50E-01 6.7E+00 1.1E+00 3.5E+00
5.50E-01 1.2E+01 1.1E+00 3.5E+00
2.37E+02 8.4E+00 1.1E+00 3.5E+00
5.50E-01 3.0E+01 1.1E+00 3.5E+00
5.50E-01 3.2E+01 1.1E+00 3.5E+00
3.37E+02 1.1E+01 1.1E+00 3.5E+00
5.50E-01 4.3E+01 1.1E+00 3.5E+00
5.50E-01 1.5E+01 1.1E+00 3.5E+00
2.53E+02 2.9E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
2.20E+03 98% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
2.21E+03 96% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
2.03E+03 101% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-112
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Na Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Na EaFA-L05-1313-T01-A 1 1.28E+04
Na EaFA-L05-1313-T02-A 1 7.26E+03
Na EaFA-L05-1313-T03-A 1 6.39E+03
Na EaFA-L05-1313-T04-A 1 6.35E+03
Na EaFA-L05-1313-T05-A 1 6.44E+03
Na EaFA-L05-1313-T06-A 1 6.51 E+03
Na EaFA-L05-1313-T07-A 1 6.54E+03
Na EaFA-L05-1313-T08-A 1 4.38E+03
Na EaFA-L05-1313-T09-A 1 3.75E+03
Na EaFA-L05-1313-T01-B 1 1.28E+04
Na EaFA-L05-1313-T02-B 1 7.30E+03
Na EaFA-L05-1313-T03-B 1 6.38E+03
Na EaFA-L05-1313-T04-B 1 6.48E+03
Na EaFA-L05-1313-T05-B 1 6.29E+03
Na EaFA-L05-1313-T06-B 1 6.33E+03
Na EaFA-L05-1313-T07-B 1 6.45E+03
Na EaFA-L05-1313-T08-B 1 4.33E+03
Na EaFA-L05-1313-T09-B 1 3.55E+03
Na EaFA-L05-1313-T01-C 1 1.27E+04
Na EaFA-L05-1313-T02-C 1 7.24E+03
Na EaFA-L05-1313-T03-C 1 6.71 E+03
Na EaFA-L05-1313-T04-C 1 6.38E+03
Na EaFA-L05-1313-T05-C 1 6.32E+03
Na EaFA-L05-1313-T06-C 1 6.33E+03
Na EaFA-L05-1313-T07-C 1 6.34E+03
Na EaFA-L05-1313-T08-C 1 4.33E+03
Na EaFA-L05-1313-T09-C 1 3.58E+03
Na EaFA-L05-1313-B01-A 1 2.43E+01
Na EaFA-L05-1313-B02-A 1 2.64E+01
Na EaFA-L05-1313-B03-A 1 6.65E+03
Na EaFA-L05-1313-B01-B 1 1.85E+01
Na EaFA-L05-1313-B02-B 1 2.21E+01
Na EaFA-L05-1313-B03-B 1 6.61 E+03
Na EaFA-L05-1313-B01-C 1 2.70E+01
Na EaFA-L05-1313-B02-C 1 2.26E+01
Na EaFA-L05-1313-B03-C 1 6.93E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.28E+04 4.5E-01 2.5E+00 8.0E+00
7.26E+03 5.9E-01 2.5E+00 8.0E+00
6.39E+03 4.0E-01 2.5E+00 8.0E+00 1000 100
6.35E+03 2.6E-01 2.5E+00 8.0E+00
6.44E+03 6.6E-01 2.5E+00 8.0E+00
6.51E+03 3.2E-01 2.5E+00 8.0E+00
6.54E+03 7.8E-01 2.5E+00 8.0E+00
4.38E+03 7.0E-01 2.5E+00 8.0E+00
3.75E+03 1.0E-01 2.5E+00 8.0E+00
1.28E+04 3.9E-01 2.5E+00 8.0E+00
7.30E+03 4.0E-01 2.5E+00 8.0E+00
6.38E+03 2.5E-01 2.5E+00 8.0E+00 1000 100
6.48E+03 8.3E-01 2.5E+00 8.0E+00
6.29E+03 7.0E-01 2.5E+00 8.0E+00
6.33E+03 1.0E+00 2.5E+00 8.0E+00
6.45E+03 1.2E+00 2.5E+00 8.0E+00
4.33E+03 3.6E-01 2.5E+00 8.0E+00
3.55E+03 3.1E-01 2.5E+00 8.0E+00
1.27E+04 4.0E-01 2.5E+00 8.0E+00
7.24E+03 6.4E-02 2.5E+00 8.0E+00
6.71E+03 4.0E-01 2.5E+00 8.0E+00 1000 100
6.38E+03 5.0E-01 2.5E+00 8.0E+00
6.32E+03 5.6E-01 2.5E+00 8.0E+00
6.33E+03 1.2E+01 2.5E+00 8.0E+00
6.34E+03 4.0E-01 2.5E+00 8.0E+00
4.33E+03 9.9E-01 2.5E+00 8.0E+00
3.58E+03 7.1E-01 2.5E+00 8.0E+00
2.43E+01 4.2E-01 2.5E+00 8.0E+00
2.64E+01 8.8E-01 2.5E+00 8.0E+00
6.65E+03 2.2E+00 2.5E+00 8.0E+00
1.85E+01 2.9E+00 2.5E+00 8.0E+00
2.21 E+01 3.2E+00 2.5E+00 8.0E+00
6.61 E+03 1.2E+00 2.5E+00 8.0E+00
2.70E+01 1.7E+00 2.5E+00 8.0E+00
2.26E+01 2.9E+00 2.5E+00 8.0E+00
6.93E+03 5.7E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
7.33E+03 94% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
7.45E+03 107% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
7.66E+03 95% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-113
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-L05-1313-T01-A 1 1.35E+03
EaFA-L05-1313-T02-A 1 1.52E+03
EaFA-L05-1313-T03-A 1 1.61E+03
EaFA-L05-1313-T04-A 1 1.81E+03
EaFA-L05-1313-T05-A 1 2.07E+03
EaFA-L05-1313-T06-A 1 2.38E+03
EaFA-L05-1313-T07-A 1 2.40E+03
EaFA-L05-1313-T08-A 1 3.19E+03
EaFA-L05-1313-T09-A 1 4.57E+03
EaFA-L05-1313-T01-B 1 1.19E+03
EaFA-L05-1313-T02-B 1 1.53E+03
EaFA-L05-1313-T03-B 1 1.65E+03
EaFA-L05-1313-T04-B 1 1.73E+03
EaFA-L05-1313-T05-B 1 1.84E+03
EaFA-L05-1313-T06-B 1 2.29E+03
EaFA-L05-1313-T07-B 1 2.36E+03
EaFA-L05-1313-T08-B 1 3.19E+03
EaFA-L05-1313-T09-B 1 4.68E+03
EaFA-L05-1313-T01-C 1 1.32E+03
EaFA-L05-1313-T02-C 1 1.59E+03
EaFA-L05-1313-T03-C 1 1.75E+03
EaFA-L05-1313-T04-C 1 1.84E+03
EaFA-L05-1313-T05-C 1 1.98E+03
EaFA-L05-1313-T06-C 1 2.35E+03
EaFA-L05-1313-T07-C 1 2.28E+03
EaFA-L05-1313-T08-C 1 3.14E+03
EaFA-L05-1313-T09-C 1 4.68E+03
EaFA-L05-1313-B01-A 1 5.00E-01 U1/2
EaFA-L05-1313-B02-A 1 5.00E-01 U1/2
EaFA-L05-1313-B03-A 1 5.00E-01 U1/2
EaFA-L05-1313-B01-B 1 5.00E-01 U1/2
EaFA-L05-1313-B02-B 1 5.00E-01 U1/2
EaFA-L05-1313-B03-B 1 1.25E+OOE
EaFA-L05-1313-B01-C 1 5.00E-01 U1/2
EaFA-L05-1313-B02-C 1 5.00E-01 U1/2
EaFA-L05-1313-B03-C 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.35E+03 1.9E-01 1 .OE+00 3.2E+00
1.52E+03 7.9E-01 1 .OE+00 3.2E+00
1.61E+03 2.2E-01 1 .OE+00 3.2E+00 1000 100
1.81E+03 5.5E-01 1 .OE+00 3.2E+00
2.07E+03 1.3E+00 1 .OE+00 3.2E+00
2.38E+03 1.2E+00 1 .OE+00 3.2E+00
2.40E+03 1. OE+00 1 .OE+00 3.2E+00
3.19E+03 2.1E-01 1 .OE+00 3.2E+00
4.57E+03 6.2E-01 1 .OE+00 3.2E+00
1.19E+03 1.5E+00 1. OE+00 3.2E+00
1.53E+03 2.4E-01 1 .OE+00 3.2E+00
1.65E+03 4.6E-01 1 .OE+00 3.2E+00 1000 100
1.73E+03 1. OE+00 1 .OE+00 3.2E+00
1.84E+03 8.1E-01 1 .OE+00 3.2E+00
2.29E+03 1.7E+00 1 .OE+00 3.2E+00
2.36E+03 7.8E-01 1 .OE+00 3.2E+00
3.19E+03 5.7E-01 1 .OE+00 3.2E+00
4.68E+03 5.6E-01 1 .OE+00 3.2E+00
1.32E+03 5.5E-01 1 .OE+00 3.2E+00
1.59E+03 7.2E-01 1 .OE+00 3.2E+00
1.75E+03 6.5E-01 1 .OE+00 3.2E+00 1000 100
1.84E+03 1.4E+00 1. OE+00 3.2E+00
1.98E+03 9.4E-01 1. OE+00 3.2E+00
2.35E+03 9.9E+00 1. OE+00 3.2E+00
2.28E+03 1.1E+00 1. OE+00 3.2E+00
3.14E+03 1.7E+00 1. OE+00 3.2E+00
4.68E+03 2.0E-01 1. OE+00 3.2E+00
5.00E-01 1.3E+03 1. OE+00 3.2E+00
5.00E-01 3.3E+01 1. OE+00 3.2E+00
5.00E-01 2.2E+02 1. OE+00 3.2E+00
5.00E-01 4.3E+02 1. OE+00 3.2E+00
5.00E-01 7.3E+02 1. OE+00 3.2E+00
1.25E+00 8.1E+01 1. OE+00 3.2E+00
5.00E-01 9.4E+01 1. OE+00 3.2E+00
5.00E-01 3.3E+03 1. OE+00 3.2E+00
5.00E-01 1.3E+02 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
2.46E+03 84% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
2.54E+03 89% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
2.57E+03 83% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-114
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
S Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
S EaFA-L05-1313-T01-A 1 1.71E+05
S EaFA-L05-1313-T02-A 1 1.62E+05
S EaFA-L05-1313-T03-A 1 1.53E+05
S EaFA-L05-1313-T04-A 1 1.60E+05
S EaFA-L05-1313-T05-A 1 1.65E+05
S EaFA-L05-1313-T06-A 1 1.63E+05
S EaFA-L05-1313-T07-A 1 1.64E+05
S EaFA-L05-1313-T08-A 1 9.98E+04
S EaFA-L05-1313-T09-A 1 6.18E+04
S EaFA-L05-1313-T01-B 1 1.75E+05
S EaFA-L05-1313-T02-B 1 1.63E+05
S EaFA-L05-1313-T03-B 1 1.57E+05
S EaFA-L05-1313-T04-B 1 1.58E+05
S EaFA-L05-1313-T05-B 1 1.54E+05
S EaFA-L05-1313-T06-B 1 1.64E+05
S EaFA-L05-1313-T07-B 1 1.60E+05
S EaFA-L05-1313-T08-B 1 1.02E+05
S EaFA-L05-1313-T09-B 1 6.18E+04
S EaFA-L05-1313-T01-C 1 1.75E+05
S EaFA-L05-1313-T02-C 1 1.65E+05
S EaFA-L05-1313-T03-C 1 1.64E+05
S EaFA-L05-1313-T04-C 1 1.63E+05
S EaFA-L05-1313-T05-C 1 1.63E+05
S EaFA-L05-1313-T06-C 1 1.60E+05
S EaFA-L05-1313-T07-C 1 1.62E+05
S EaFA-L05-1313-T08-C 1 9.92E+04
S EaFA-L05-1313-T09-C 1 6.34E+04
S EaFA-L05-1313-B01-A 1 1.53E+01 E
S EaFA-L05-1313-B02-A 1 3.40E+00 U1/2
S EaFA-L05-1313-B03-A 1 9.45E+02
S EaFA-L05-1313-B01-B 1 1.88E+01 E
S EaFA-L05-1313-B02-B 1 1.37E+01 E
S EaFA-L05-1313-B03-B 1 1.24E+03
S EaFA-L05-1313-B01-C 1 1.67E+01 E
S EaFA-L05-1313-B02-C 1 3.40E+00 U1/2
S EaFA-L05-1313-B03-C 1 1.07E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.71E+05 4.6E-01 6.8E+00 2.2E+01
1.62E+05 7.1E-01 6.8E+00 2.2E+01
1.53E+05 1.3E-01 6.8E+00 2.2E+01 1000 100
1.60E+05 1.0E+00 6.8E+00 2.2E+01
1.65E+05 1.0E+00 6.8E+00 2.2E+01
1.63E+05 2.0E-01 6.8E+00 2.2E+01
1.64E+05 1.1E-01 6.8E+00 2.2E+01
9.98E+04 4.2E-01 6.8E+00 2.2E+01
6.18E+04 1.4E-01 6.8E+00 2.2E+01
1.75E+05 3.6E-01 6.8E+00 2.2E+01
1.63E+05 5.1E-01 6.8E+00 2.2E+01
1.57E+05 3.6E-01 6.8E+00 2.2E+01 1000 100
1.58E+05 4.7E-01 6.8E+00 2.2E+01
1.54E+05 2.8E-02 6.8E+00 2.2E+01
1.64E+05 5.0E-01 6.8E+00 2.2E+01
1.60E+05 1.1E+00 6.8E+00 2.2E+01
1.02E+05 7.1E-01 6.8E+00 2.2E+01
6.18E+04 3.5E-01 6.8E+00 2.2E+01
1.75E+05 2.9E-01 6.8E+00 2.2E+01
1.65E+05 2.5E-01 6.8E+00 2.2E+01
1.64E+05 2.8E-01 6.8E+00 2.2E+01 1000 100
1.63E+05 6.8E-01 6.8E+00 2.2E+01
1.63E+05 6.2E-01 6.8E+00 2.2E+01
1.60E+05 1.3E+01 6.8E+00 2.2E+01
1.62E+05 1.1E+00 6.8E+00 2.2E+01
9.92E+04 1.0E+00 6.8E+00 2.2E+01
6.34E+04 1.7E-01 6.8E+00 2.2E+01
1.53E+01 5.5E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+03 6.8E+00 2.2E+01
9.45E+02 2.4E+01 6.8E+00 2.2E+01
1.88E+01 3.4E+01 6.8E+00 2.2E+01
1.37E+01 5.8E+01 6.8E+00 2.2E+01
1.24E+03 1.3E+00 6.8E+00 2.2E+01
1.67E+01 5.6E+01 6.8E+00 2.2E+01
3.40E+00 2.1E+02 6.8E+00 2.2E+01
1.07E+03 3.1E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
1.54E+05 82% VUICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
1.58E+05 87% VUICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.65E+05 86% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-115
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl EaFA-L05-1313-T01-A 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T02-A 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T03-A 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T04-A 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T05-A 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T06-A 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T07-A 1 7.12E+00 E
Tl EaFA-L05-1313-T08-A 1 4.49E+01
Tl EaFA-L05-1313-T09-A 1 7.65E+01
Tl EaFA-L05-1313-T01-B 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T02-B 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T03-B 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T04-B 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T05-B 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T06-B 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T07-B 1 2.00E+01
Tl EaFA-L05-1313-T08-B 1 5.04E+01
Tl EaFA-L05-1313-T09-B 1 6.88E+01
Tl EaFA-L05-1313-T01-C 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T02-C 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T03-C 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T04-C 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T05-C 1 2.30E+00 U1/2
Tl EaFA-L05-1313-T06-C 1 3.11E+01
Tl EaFA-L05-1313-T07-C 1 4.88E+00 E
Tl EaFA-L05-1313-T08-C 1 5.31E+01
Tl EaFA-L05-1313-T09-C 1 8.25E+01
Tl EaFA-L05-1313-B01-A 1 2.30E+00 U1/2
Tl EaFA-L05-1313-B02-A 1 2.30E+00 U1/2
Tl EaFA-L05-1313-B03-A 1 2.30E+00 U1/2
Tl EaFA-L05-1313-B01-B 1 2.30E+00 U1/2
Tl EaFA-L05-1313-B02-B 1 2.30E+00 U1/2
Tl EaFA-L05-1313-B03-B 1 2.30E+00 U1/2
Tl EaFA-L05-1313-B01-C 1 2.30E+00 U1/2
Tl EaFA-L05-1313-B02-C 1 2.30E+00 U1/2
Tl EaFA-L05-1313-B03-C 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 1.0E+02 4.6E+00 1.5E+01
2.30E+00 2.5E+01 4.6E+00 1.5E+01
2.30E+00 1.2E+02 4.6E+00 1.5E+01 10 325
2.30E+00 5.0E+01 4.6E+00 1.5E+01
2.30E+00 1.4E+02 4.6E+00 1.5E+01
2.30E+00 2.2E+02 4.6E+00 1.5E+01
7.12E+00 1.5E+02 4.6E+00 1.5E+01
4.49E+01 1.6E+01 4.6E+00 1.5E+01
7.65E+01 3.2E+00 4.6E+00 1.5E+01
2.30E+00 8.8E+02 4.6E+00 1.5E+01
2.30E+00 5.8E+01 4.6E+00 1.5E+01
2.30E+00 9.3E+01 4.6E+00 1.5E+01 10 325
2.30E+00 2.0E+01 4.6E+00 1.5E+01
2.30E+00 5.0E+01 4.6E+00 1.5E+01
2.30E+00 2.3E+02 4.6E+00 1.5E+01
2.00E+01 1.9E+01 4.6E+00 1.5E+01
5.04E+01 2.7E+01 4.6E+00 1.5E+01
6.88E+01 1.2E+01 4.6E+00 1.5E+01
2.30E+00 9.7E+01 4.6E+00 1.5E+01
2.30E+00 2.9E+01 4.6E+00 1.5E+01
2.30E+00 6.7E+01 4.6E+00 1.5E+01 10 325
2.30E+00 2.7E+01 4.6E+00 1.5E+01
2.30E+00 2.2E+01 4.6E+00 1.5E+01
3.11E+01 4.5E+01 4.6E+00 1.5E+01
4.88E+00 1.9E+02 4.6E+00 1.5E+01
5.31 E+01 1.1E+01 4.6E+00 1.5E+01
8.25E+01 2.2E+00 4.6E+00 1.5E+01
2.30E+00 4.7E+01 4.6E+00 1.5E+01
2.30E+00 1.6E+01 4.6E+00 1.5E+01
2.30E+00 3.4E+01 4.6E+00 1.5E+01
2.30E+00 2.1 E+01 4.6E+00 1.5E+01
2.30E+00 2.0E+01 4.6E+00 1.5E+01
2.30E+00 4.9E+01 4.6E+00 1.5E+01
2.30E+00 2.9E+01 4.6E+00 1.5E+01
2.30E+00 1.4E+01 4.6E+00 1.5E+01
2.30E+00 3.1 E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
2.99E+03 92% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.06E+03 94% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.13E+03 96% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-116
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ti Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Ti EaFA-L05-1313-T01-A 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T02-A 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T03-A 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T04-A 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T05-A 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T06-A 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T07-A 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T08-A 1 1.45E+01
Ti EaFA-L05-1313-T09-A 1 8.02E+03
Ti EaFA-L05-1313-T01-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T02-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T03-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T04-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T05-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T06-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T07-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T08-B 1 1.49E+01
Ti EaFA-L05-1313-T09-B 1 8.31 E+03
Ti EaFA-L05-1313-T01-C 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T02-C 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T03-C 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T04-C 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T05-C 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T06-C 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T07-C 1 1.00E+OOU1/2
Ti EaFA-L05-1313-T08-C 1 1.37E+01
Ti EaFA-L05-1313-T09-C 1 7.50E+03
Ti EaFA-L05-1313-B01-A 1 1.00E+OOU1/2
Ti EaFA-L05-1313-B02-A 1 1.00E+OOU1/2
Ti EaFA-L05-1313-B03-A 1 2.62E+00 E
Ti EaFA-L05-1313-B01-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-B02-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-B03-B 1 1.00E+OOU1/2
Ti EaFA-L05-1313-B01-C 1 1.00E+OOU1/2
Ti EaFA-L05-1313-B02-C 1 1.00E+OOU1/2
Ti EaFA-L05-1313-B03-C 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.6E+00 2.0E+00 6.4E+00
1.00E+00 7.9E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00 10 325
1.00E+00 2.0E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 8.6E+00 2.0E+00 6.4E+00
1.45E+01 2.8E+00 2.0E+00 6.4E+00
8.02E+03 1.2E-01 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00
1.00E+00 6.3E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 4.6E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.49E+01 4.3E+00 2.0E+00 6.4E+00
8.31 E+03 4.5E-01 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.37E+01 3.5E+00 2.0E+00 6.4E+00
7.50E+03 6.7E-01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 6.3E+01 2.0E+00 6.4E+00
2.62E+00 4.9E+00 2.0E+00 6.4E+00
1.00E+00 6.1E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+00 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
2.95E+03 91% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.02E+03 93% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.04E+03 93% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-117
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
V Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
V EaFA-L05-1313-T01-A 1 3.96E+03
V EaFA-L05-1313-T02-A 1 2.42E+03
V EaFA-L05-1313-T03-A 1 2.04E+03
V EaFA-L05-1313-T04-A 1 5.85E+02
V EaFA-L05-1313-T05-A 1 2.53E+02
V EaFA-L05-1313-T06-A 1 1.38E+02
V EaFA-L05-1313-T07-A 1 1.38E+02
V EaFA-L05-1313-T08-A 1 1.16E+02
V EaFA-L05-1313-T09-A 1 5.43E+03
V EaFA-L05-1313-T01-B 1 4.30E+03
V EaFA-L05-1313-T02-B 1 2.43E+03
V EaFA-L05-1313-T03-B 1 2.37E+03
V EaFA-L05-1313-T04-B 1 5.99E+02
V EaFA-L05-1313-T05-B 1 2.28E+02
V EaFA-L05-1313-T06-B 1 1.41E+02
V EaFA-L05-1313-T07-B 1 1.19E+02
V EaFA-L05-1313-T08-B 1 1.24E+02
V EaFA-L05-1313-T09-B 1 5.94E+03
V EaFA-L05-1313-T01-C 1 4.40E+03
V EaFA-L05-1313-T02-C 1 2.62E+03
V EaFA-L05-1313-T03-C 1 2.45E+03
V EaFA-L05-1313-T04-C 1 5.67E+02
V EaFA-L05-1313-T05-C 1 1.93E+02
V EaFA-L05-1313-T06-C 1 1.20E+02
V EaFA-L05-1313-T07-C 1 1.44E+02
V EaFA-L05-1313-T08-C 1 1.09E+02
V EaFA-L05-1313-T09-C 1 5.84E+03
V EaFA-L05-1313-B01-A 1 1.34E+01
V EaFA-L05-1313-B02-A 1 6.31 E+00
V EaFA-L05-1313-B03-A 1 1.15E+01
V EaFA-L05-1313-B01-B 1 8.09E+00
V EaFA-L05-1313-B02-B 1 7.51 E+00
V EaFA-L05-1313-B03-B 1 1.09E+01
V EaFA-L05-1313-B01-C 1 8.50E+00
V EaFA-L05-1313-B02-C 1 8.07E+00
V EaFA-L05-1313-B03-C 1 8.52E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.96E+03 6.5E-01 1 .5E+00 4.8E+00
2.42E+03 1.1E+00 1 .5E+00 4.8E+00
2.04E+03 8.0E-02 1 .5E+00 4.8E+00 10 325
5.85E+02 7.1E-01 1 .5E+00 4.8E+00
2.53E+02 1.3E+00 1 .5E+00 4.8E+00
1.38E+02 1.2E+00 1 .5E+00 4.8E+00
1.38E+02 7.5E-01 1 .5E+00 4.8E+00
1.16E+02 1.0E+00 1.5E+00 4.8E+00
5.43E+03 3.4E-01 1 .5E+00 4.8E+00
4.30E+03 9.5E-01 1 .5E+00 4.8E+00
2.43E+03 6.0E-01 1 .5E+00 4.8E+00
2.37E+03 7.4E-01 1 .5E+00 4.8E+00 10 325
5.99E+02 1.7E+00 1 .5E+00 4.8E+00
2.28E+02 2.1E+00 1 .5E+00 4.8E+00
1.41E+02 1.8E+00 1.5E+00 4.8E+00
1.19E+02 1.6E+00 1.5E+00 4.8E+00
1.24E+02 2.4E+00 1 .5E+00 4.8E+00
5.94E+03 5.3E-01 1 .5E+00 4.8E+00
4.40E+03 5.4E-01 1 .5E+00 4.8E+00
2.62E+03 6.7E-01 1 .5E+00 4.8E+00
2.45E+03 3.0E-01 1 .5E+00 4.8E+00 10 325
5.67E+02 2.3E+00 1.5E+00 4.8E+00
1.93E+02 1.6E+00 1.5E+00 4.8E+00
1.20E+02 1.1E+01 1.5E+00 4.8E+00
1.44E+02 2.8E+00 1.5E+00 4.8E+00
1.09E+02 1.3E+00 1.5E+00 4.8E+00
5.84E+03 1.4E-01 1.5E+00 4.8E+00
1.34E+01 2.9E+00 1.5E+00 4.8E+00
6.31 E+00 2.8E+01 1.5E+00 4.8E+00
1.15E+01 1.6E+01 1.5E+00 4.8E+00
8.09E+00 2.1E+01 1.5E+00 4.8E+00
7.51 E+00 2.2E+01 1.5E+00 4.8E+00
1.09E+01 2.8E+01 1.5E+00 4.8E+00
8.50E+00 1.3E+01 1.5E+00 4.8E+00
8.07E+00 9.7E+00 1.5E+00 4.8E+00
8.52E+00 2.7E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
5.04E+03 92% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
5.32E+03 91% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
5.47E+03 93% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-118
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Zn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Zn EaFA-L05-1313-T01-A 1 1.04E+02
Zn EaFA-L05-1313-T02-A 1 5.17E+00
Zn EaFA-L05-1313-T03-A 1 4.38E+00
Zn EaFA-L05-1313-T04-A 1 5.30E+00
Zn EaFA-L05-1313-T05-A 1 6.74E+00
Zn EaFA-L05-1313-T06-A 1 2.06E+02
Zn EaFA-L05-1313-T07-A 1 3.81 E+02
Zn EaFA-L05-1313-T08-A 1 1.18E+03
Zn EaFA-L05-1313-T09-A 1 1.55E+03
Zn EaFA-L05-1313-T01-B 1 1.08E+02
Zn EaFA-L05-1313-T02-B 1 5.10E+00
Zn EaFA-L05-1313-T03-B 1 3.41 E+00
Zn EaFA-L05-1313-T04-B 1 1.13E+OOE
Zn EaFA-L05-1313-T05-B 1 5.67E+00
Zn EaFA-L05-1313-T06-B 1 1.37E+02
Zn EaFA-L05-1313-T07-B 1 6.96E+02
Zn EaFA-L05-1313-T08-B 1 1.19E+03
Zn EaFA-L05-1313-T09-B 1 1.57E+03
Zn EaFA-L05-1313-T01-C 1 9.25E+01
Zn EaFA-L05-1313-T02-C 1 6.50E+00
Zn EaFA-L05-1313-T03-C 1 1.49E+OOE
Zn EaFA-L05-1313-T04-C 1 3.49E+00
Zn EaFA-L05-1313-T05-C 1 1.17E+01
Zn EaFA-L05-1313-T06-C 1 8.02E+02
Zn EaFA-L05-1313-T07-C 1 1.44E+02
Zn EaFA-L05-1313-T08-C 1 1.20E+03
Zn EaFA-L05-1313-T09-C 1 1.56E+03
Zn EaFA-L05-1313-B01-A 1 3.86E+00
Zn EaFA-L05-1313-B02-A 1 1.45E+01
Zn EaFA-L05-1313-B03-A 1 1.07E+01
Zn EaFA-L05-1313-B01-B 1 4.01E+00
Zn EaFA-L05-1313-B02-B 1 9.40E+00
Zn EaFA-L05-1313-B03-B 1 8.00E+00
Zn EaFA-L05-1313-B01-C 1 7.18E+00
Zn EaFA-L05-1313-B02-C 1 8.53E+00
Zn EaFA-L05-1313-B03-C 1 1.72E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.04E+02 1.6E+00 1 .OE+00 3.2E+00
5.17E+00 7.1 E+00 1 .OE+00 3.2E+00
4.38E+00 3.3E+00 1 .OE+00 3.2E+00 10 325
5.30E+00 8.5E+00 1 .OE+00 3.2E+00
6.74E+00 7.0E+00 1 .OE+00 3.2E+00
2.06E+02 6.7E-01 1 .OE+00 3.2E+00
3.81 E+02 5.5E-01 1 .OE+00 3.2E+00
1.18E+03 8.7E-01 1 .OE+00 3.2E+00
1.55E+03 9.4E-01 1 .OE+00 3.2E+00
1.08E+02 2.8E-01 1 .OE+00 3.2E+00
5.10E+00 1.6E+01 1. OE+00 3.2E+00
3.41E+00 1.1E+01 1.0E+00 3.2E+00 10 325
1.13E+00 6.5E+01 1. OE+00 3.2E+00
5.67E+00 6.9E+00 1 .OE+00 3.2E+00
1.37E+02 1.5E+00 1 .OE+00 3.2E+00
6.96E+02 1.1 E+00 1 .OE+00 3.2E+00
1.19E+03 1.1E+00 1.0E+00 3.2E+00
1.57E+03 6.6E-01 1 .OE+00 3.2E+00
9.25E+01 2.3E+00 1 .OE+00 3.2E+00
6.50E+00 1.4E+01 1 .OE+00 3.2E+00
1.49E+00 6.3E+01 1 .OE+00 3.2E+00 10 325
3.49E+00 4.5E+01 1 .OE+00 3.2E+00
1.17E+01 6.9E-01 1. OE+00 3.2E+00
8.02E+02 9.8E+00 1. OE+00 3.2E+00
1.44E+02 9.0E-01 1. OE+00 3.2E+00
1.20E+03 7.5E-01 1. OE+00 3.2E+00
1.56E+03 6.5E-01 1. OE+00 3.2E+00
3.86E+00 1.4E+01 1. OE+00 3.2E+00
1.45E+01 8.9E+00 1. OE+00 3.2E+00
1.07E+01 6.6E+00 1. OE+00 3.2E+00
4.01 E+00 1.2E+01 1. OE+00 3.2E+00
9.40E+00 1.1E+01 1. OE+00 3.2E+00
8.00E+00 3.9E+00 1. OE+00 3.2E+00
7.18E+00 9.2E+00 1. OE+00 3.2E+00
8.53E+00 5.3E+00 1. OE+00 3.2E+00
1.72E+01 2.0E+00 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 7/29/10 11:56 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
3.28E+03 101% VU ICP-OES 7/29/10 1:40 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:04 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:21 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
3.38E+03 104% VU ICP-OES 7/29/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:27 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:46 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 7/29/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.46E+03 106% VU ICP-OES 7/29/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:50 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:55 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:53 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 11:55 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:19 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 12:44 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-119
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al EaFA-L06-1313-T01-A 1
Al EaFA-L06-1313-T02-A 1
Al EaFA-L06-1313-T03-A 1
Al EaFA-L06-1313-T04-A 1
Al EaFA-L06-1313-T05-A 1
Al EaFA-L06-1313-T06-A 1
Al EaFA-L06-1313-T07-A 1
Al EaFA-L06-1313-T08-A 1
Al EaFA-L06-1313-T09-A 1
Al EaFA-L06-1313-T01-B 1
Al EaFA-L06-1313-T02-B 1
Al EaFA-L06-1313-T03-B 1
Al EaFA-L06-1313-T04-B 1
Al EaFA-L06-1313-T05-B 1
Al EaFA-L06-1313-T06-B 1
Al EaFA-L06-1313-T07-B 1
Al EaFA-L06-1313-T08-B 1
Al EaFA-L06-1313-T09-B 1
Al EaFA-L06-1313-T01-C 1
Al EaFA-L06-1313-T02-C 1
Al EaFA-L06-1313-T03-C 1
Al EaFA-L06-1313-T04-C 1
Al EaFA-L06-1313-T05-C 1
Al EaFA-L06-1313-T06-C 1
Al EaFA-L06-1313-T07-C 1
Al EaFA-L06-1313-T08-C 1
Al EaFA-L06-1313-T09-C 1
Al EaFA-L06-1313-B01-A 1
Al EaFA-L06-1313-B02-A 1
Al EaFA-L06-1313-B03-A 1
Al EaFA-L06-1313-B01-B 1
Al EaFA-L06-1313-B02-B 1
Al EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
3.77E+04
3.41 E+04
2.08E+04
1.22E+04
2.32E+03
1.09E+02
1.35E+04
5.62E+04
1.14E+05
3.30E+04
3.86E+04
2.06E+04
3.92E+03
6.58E+02
1.16E+02
5.64E+02
2.82E+04
1.16E+05
3.90E+04
3.44E+04
2.26E+04
4.35E+03
6.98E+02
1.35E+02
6.15E+02
2.91 E+04
1.15E+05
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.77E+04 7.5E+00 1.0E+00 3.2E+00
3.41 E+04 7.9E-01 1.0E+00 3.2E+00
2.08E+04 3.8E-01 1.0E+00 3.2E+00 1000 100
1.22E+04 1.2E-01 1.0E+00 3.2E+00
2.32E+03 1.9E-01 1.0E+00 3.2E+00
1.09E+02 1.6E+00 1.0E+00 3.2E+00
1.35E+04 9.0E-01 1.0E+00 3.2E+00
5.62E+04 7.3E-01 1.0E+00 3.2E+00
1.14E+05 3.1E+00 1.0E+00 3.2E+00
3.30E+04 2.4E+01 1.0E+00 3.2E+00
3.86E+04 5.3E-01 1.0E+00 3.2E+00
2.06E+04 7.7E+00 1.0E+00 3.2E+00 1000 100
3.92E+03 2.8E+00 1.0E+00 3.2E+00
6.58E+02 9.4E+00 1.0E+00 3.2E+00
1.16E+02 2.6E+00 1.0E+00 3.2E+00
5.64E+02 1.1E+00 1.0E+00 3.2E+00
2.82E+04 2.4E+00 1.0E+00 3.2E+00
1.16E+05 6.8E+01 1.0E+00 3.2E+00
3.90E+04 2.8E+00 1.0E+00 3.2E+00
3.44E+04 7.0E-01 1.0E+00 3.2E+00
2.26E+04 6.2E-01 1.0E+00 3.2E+00 1000 100
4.35E+03 6.4E-01 1.0E+00 3.2E+00
6.98E+02 2.0E+00 1.0E+00 3.2E+00
1.35E+02 4.8E+00 1.0E+00 3.2E+00
6.15E+02 6.9E+00 1.0E+00 3.2E+00
2.91 E+04 3.3E+00 1.0E+00 3.2E+00
1.15E+05 1.1E+01 1.0E+00 3.2E+00
5.00E-01 7.1E+00 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
5.00E-01 3.9E+01 1.0E+00 3.2E+00
5.00E-01 6.8E+00 1.0E+00 3.2E+00
5.00E-01 3.6E+00 1.0E+00 3.2E+00
5.00E-01 7.4E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.18E+04 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.16E+04 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.35E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                                   1-120
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L06-1313-T01-A 1
Sb EaFA-L06-1313-T02-A 1
Sb EaFA-L06-1313-T03-A 1
Sb EaFA-L06-1313-T04-A 1
Sb EaFA-L06-1313-T05-A 1
Sb EaFA-L06-1313-T06-A 1
Sb EaFA-L06-1313-T07-A 1
Sb EaFA-L06-1313-T08-A 1
Sb EaFA-L06-1313-T09-A 1
Sb EaFA-L06-1313-T01-B 1
Sb EaFA-L06-1313-T02-B 1
Sb EaFA-L06-1313-T03-B 1
Sb EaFA-L06-1313-T04-B 1
Sb EaFA-L06-1313-T05-B 1
Sb EaFA-L06-1313-T06-B 1
Sb EaFA-L06-1313-T07-B 1
Sb EaFA-L06-1313-T08-B 1
Sb EaFA-L06-1313-T09-B 1
Sb EaFA-L06-1313-T01-C 1
Sb EaFA-L06-1313-T02-C 1
Sb EaFA-L06-1313-T03-C 1
Sb EaFA-L06-1313-T04-C 1
Sb EaFA-L06-1313-T05-C 1
Sb EaFA-L06-1313-T06-C 1
Sb EaFA-L06-1313-T07-C 1
Sb EaFA-L06-1313-T08-C 1
Sb EaFA-L06-1313-T09-C 1
Sb EaFA-L06-1313-B01-A 1
Sb EaFA-L06-1313-B02-A 1
Sb EaFA-L06-1313-B03-A 1
Sb EaFA-L06-1313-B01-B 1
Sb EaFA-L06-1313-B02-B 1
Sb EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
2.69E+02
1.52E+02
1.92E+02
2.12E+02
2.13E+02
1.64E+02
1.21E+02
2.37E+01 E
3.75E+00 U1/2
2.71 E+02
1.38E+02
1.71 E+02
1.67E+02
1.47E+02
1.48E+02
1.16E+02
2.97E+01
3.75E+00 U1/2
2.96E+02
1.24E+02
1.76E+02
1.55E+02
1.63E+02
1.43E+02
1.15E+02
3.75E+00 U1/2
3.75E+00 U1/2
2.95E+01
2.68E+01
2.41E+01
1.99E+01 E
1.11E+01 E
1.47E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.69E+02 8.7E+00 7.5E+00 2.4E+01
1.52E+02 1.1E+01 7.5E+00 2.4E+01
1.92E+02 1.0E+01 7.5E+00 2.4E+01 10 325
2.12E+02 1.3E+00 7.5E+00 2.4E+01
2.13E+02 1.7E+01 7.5E+00 2.4E+01
1.64E+02 1.7E+01 7.5E+00 2.4E+01
1.21 E+02 2.3E+01 7.5E+00 2.4E+01
2.37E+01 2.7E+01 7.5E+00 2.4E+01
3.75E+00 8.2E+01 7.5E+00 2.4E+01
2.71 E+02 3.3E+01 7.5E+00 2.4E+01
1.38E+02 1.1E+01 7.5E+00 2.4E+01
1.71E+02 1.5E+01 7.5E+00 2.4E+01 10 325
1.67E+02 1.8E+01 7.5E+00 2.4E+01
1.47E+02 6.3E+00 7.5E+00 2.4E+01
1.48E+02 1.6E+01 7.5E+00 2.4E+01
1.16E+02 2.9E+01 7.5E+00 2.4E+01
2.97E+01 3.1E+01 7.5E+00 2.4E+01
3.75E+00 4.0E+01 7.5E+00 2.4E+01
2.96E+02 9.9E+00 7.5E+00 2.4E+01
1.24E+02 1.6E+00 7.5E+00 2.4E+01
1.76E+02 2.9E+00 7.5E+00 2.4E+01 10 325
1.55E+02 1.7E+01 7.5E+00 2.4E+01
1.63E+02 3.6E+00 7.5E+00 2.4E+01
1.43E+02 2.7E+01 7.5E+00 2.4E+01
1.15E+02 1.6E+01 7.5E+00 2.4E+01
3.75E+00 1.2E+02 7.5E+00 2.4E+01
3.75E+00 2.5E+01 7.5E+00 2.4E+01
2.95E+01 7.2E+01 7.5E+00 2.4E+01
2.68E+01 1.2E+02 7.5E+00 2.4E+01
2.41 E+01 5.4E+01 7.5E+00 2.4E+01
1.99E+01 3.1 E+01 7.5E+00 2.4E+01
1.11 E+01 3.9E+01 7.5E+00 2.4E+01
1.47E+01 1.0E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.33E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.43E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.26E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-121
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As EaFA-L06-1313-T01-A 1
As EaFA-L06-1313-T02-A 1
As EaFA-L06-1313-T03-A 1
As EaFA-L06-1313-T04-A 1
As EaFA-L06-1313-T05-A 1
As EaFA-L06-1313-T06-A 1
As EaFA-L06-1313-T07-A 1
As EaFA-L06-1313-T08-A 1
As EaFA-L06-1313-T09-A 1
As EaFA-L06-1313-T01-B 1
As EaFA-L06-1313-T02-B 1
As EaFA-L06-1313-T03-B 1
As EaFA-L06-1313-T04-B 1
As EaFA-L06-1313-T05-B 1
As EaFA-L06-1313-T06-B 1
As EaFA-L06-1313-T07-B 1
As EaFA-L06-1313-T08-B 1
As EaFA-L06-1313-T09-B 1
As EaFA-L06-1313-T01-C 1
As EaFA-L06-1313-T02-C 1
As EaFA-L06-1313-T03-C 1
As EaFA-L06-1313-T04-C 1
As EaFA-L06-1313-T05-C 1
As EaFA-L06-1313-T06-C 1
As EaFA-L06-1313-T07-C 1
As EaFA-L06-1313-T08-C 1
As EaFA-L06-1313-T09-C 1
As EaFA-L06-1313-B01-A 1
As EaFA-L06-1313-B02-A 1
As EaFA-L06-1313-B03-A 1
As EaFA-L06-1313-B01-B 1
As EaFA-L06-1313-B02-B 1
As EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
1.42E+04
1.42E+03
1.24E+03
1.04E+03
4.66E+02
4.47E+01
1.05E+02
8.85E+01
2.36E+03
1.28E+04
1.74E+03
8.13E+02
3.38E+02
1.48E+02
4.46E+01
6.63E+01
8.91E+01
2.12E+03
1 .35E+04
1 .57E+03
8.38E+02
3.96E+02
1 .84E+02
3.63E+01
6.98E+01
9.01E+01
2.27E+03
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
1.52E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.42E+04 8.3E+00 1.1E+01 3.5E+01
1.42E+03 1.6E+00 1.1E+01 3.5E+01
1.24E+03 1.8E+00 1.1E+01 3.5E+01 10 325
1.04E+03 2.1E+00 1.1E+01 3.5E+01
4.66E+02 1.5E+00 1.1E+01 3.5E+01
4.47E+01 2.9E+01 1.1E+01 3.5E+01
1.05E+02 2.7E+00 1.1E+01 3.5E+01
8.85E+01 1.6E+01 1.1E+01 3.5E+01
2.36E+03 3.3E+00 1.1E+01 3.5E+01
1.28E+04 3.9E+01 1.1E+01 3.5E+01
1.74E+03 1.3E+00 1.1E+01 3.5E+01
8.13E+02 9.1E+00 1.1E+01 3.5E+01 10 325
3.38E+02 6.9E+00 1.1E+01 3.5E+01
1.48E+02 6.6E+00 1.1E+01 3.5E+01
4.46E+01 2.4E+01 1.1E+01 3.5E+01
6.63E+01 1.4E+01 1.1E+01 3.5E+01
8.91E+01 2.2E+01 1.1E+01 3.5E+01
2.12E+03 7.4E+01 1.1E+01 3.5E+01
1.35E+04 3.3E+00 1.1E+01 3.5E+01
1.57E+03 1.1E+00 1.1E+01 3.5E+01
8.38E+02 1.4E+00 1.1E+01 3.5E+01 10 325
3.96E+02 2.0E+00 1.1E+01 3.5E+01
1.84E+02 4.8E+00 1.1E+01 3.5E+01
3.63E+01 5.3E+01 1.1E+01 3.5E+01
6.98E+01 4.0E+01 1.1E+01 3.5E+01
9.01E+01 2.3E+01 1.1E+01 3.5E+01
2.27E+03 2.1E+01 1.1E+01 3.5E+01
5.50E+00 8.3E+01 1.1E+01 3.5E+01
5.50E+00 2.8E+02 1.1E+01 3.5E+01
5.50E+00 5.1E+02 1.1E+01 3.5E+01
5.50E+00 5.1E+02 1.1E+01 3.5E+01
5.50E+00 2.8E+01 1.1E+01 3.5E+01
1.52E+01 2.2E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.38E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.14E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.96E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-122
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B EaFA-L06-1313-T01-A 1
B EaFA-L06-1313-T02-A 1
B EaFA-L06-1313-T03-A 1
B EaFA-L06-1313-T04-A 1
B EaFA-L06-1313-T05-A 1
B EaFA-L06-1313-T06-A 1
B EaFA-L06-1313-T07-A 1
B EaFA-L06-1313-T08-A 1
B EaFA-L06-1313-T09-A 1
B EaFA-L06-1313-T01-B 1
B EaFA-L06-1313-T02-B 1
B EaFA-L06-1313-T03-B 1
B EaFA-L06-1313-T04-B 1
B EaFA-L06-1313-T05-B 1
B EaFA-L06-1313-T06-B 1
B EaFA-L06-1313-T07-B 1
B EaFA-L06-1313-T08-B 1
B EaFA-L06-1313-T09-B 1
B EaFA-L06-1313-T01-C 1
B EaFA-L06-1313-T02-C 1
B EaFA-L06-1313-T03-C 1
B EaFA-L06-1313-T04-C 1
B EaFA-L06-1313-T05-C 1
B EaFA-L06-1313-T06-C 1
B EaFA-L06-1313-T07-C 1
B EaFA-L06-1313-T08-C 1
B EaFA-L06-1313-T09-C 1
B EaFA-L06-1313-B01-A 1
B EaFA-L06-1313-B02-A 1
B EaFA-L06-1313-B03-A 1
B EaFA-L06-1313-B01-B 1
B EaFA-L06-1313-B02-B 1
B EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
4.25E+03
4.03E+03
3.89E+03
4.40E+03
4.06E+03
4.39E+03
3.89E+03
3.47E+03
2.82E+03
4.48E+03
4.08E+03
3.79E+03
3.83E+03
3.83E+03
4.38E+03
4.74E+03
3.64E+03
2.80E+03
4.66E+03
3.76E+03
4.13E+03
4.22E+03
4.35E+03
4.56E+03
4.63E+03
3.53E+03
2.85E+03
7.71E+01
4.76E+01
5.17E+01
3.81E+01
2.44E+01
2.87E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.25E+03 7.8E+00 1.0E+00 3.2E+00
4.03E+03 7.4E-01 1.0E+00 3.2E+00
3.89E+03 3.7E-01 1.0E+00 3.2E+00 1000 100
4.40E+03 1.4E+00 1.0E+00 3.2E+00
4.06E+03 4.7E-01 1.0E+00 3.2E+00
4.39E+03 1.1E+00 1.0E+00 3.2E+00
3.89E+03 8.8E-01 1.0E+00 3.2E+00
3.47E+03 4.7E-01 1.0E+00 3.2E+00
2.82E+03 2.5E+00 1.0E+00 3.2E+00
4.48E+03 4.3E+01 1.0E+00 3.2E+00
4.08E+03 4.8E-01 1.0E+00 3.2E+00
3.79E+03 6.3E+00 1.0E+00 3.2E+00 1000 100
3.83E+03 6.2E-01 1.0E+00 3.2E+00
3.83E+03 8.8E+00 1.0E+00 3.2E+00
4.38E+03 1.5E+00 1.0E+00 3.2E+00
4.74E+03 1.2E+00 1.0E+00 3.2E+00
3.64E+03 2.9E+00 1.0E+00 3.2E+00
2.80E+03 5.9E+01 1.0E+00 3.2E+00
4.66E+03 2.7E+00 1.0E+00 3.2E+00
3.76E+03 6.9E-01 1.0E+00 3.2E+00
4.13E+03 1.3E+00 1.0E+00 3.2E+00 1000 100
4.22E+03 8.6E-01 1.0E+00 3.2E+00
4.35E+03 3.8E-01 1.0E+00 3.2E+00
4.56E+03 6.9E+00 1.0E+00 3.2E+00
4.63E+03 8.0E+00 1.0E+00 3.2E+00
3.53E+03 2.5E+00 1.0E+00 3.2E+00
2.85E+03 2.5E+01 1.0E+00 3.2E+00
7.71 E+01 5.5E+00 1.0E+00 3.2E+00
4.76E+01 4.5E+00 1.0E+00 3.2E+00
5.17E+01 1.2E+01 1.0E+00 3.2E+00
3.81 E+01 3.5E+00 1.0E+00 3.2E+00
2.44E+01 3.6E+00 1.0E+00 3.2E+00
2.87E+01 1.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.76E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.80E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.03E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-123
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFA-L06-1313-T01-A 1
Ba EaFA-L06-1313-T02-A 1
Ba EaFA-L06-1313-T03-A 1
Ba EaFA-L06-1313-T04-A 1
Ba EaFA-L06-1313-T05-A 1
Ba EaFA-L06-1313-T06-A 1
Ba EaFA-L06-1313-T07-A 1
Ba EaFA-L06-1313-T08-A 1
Ba EaFA-L06-1313-T09-A 1
Ba EaFA-L06-1313-T01-B 1
Ba EaFA-L06-1313-T02-B 1
Ba EaFA-L06-1313-T03-B 1
Ba EaFA-L06-1313-T04-B 1
Ba EaFA-L06-1313-T05-B 1
Ba EaFA-L06-1313-T06-B 1
Ba EaFA-L06-1313-T07-B 1
Ba EaFA-L06-1313-T08-B 1
Ba EaFA-L06-1313-T09-B 1
Ba EaFA-L06-1313-T01-C 1
Ba EaFA-L06-1313-T02-C 1
Ba EaFA-L06-1313-T03-C 1
Ba EaFA-L06-1313-T04-C 1
Ba EaFA-L06-1313-T05-C 1
Ba EaFA-L06-1313-T06-C 1
Ba EaFA-L06-1313-T07-C 1
Ba EaFA-L06-1313-T08-C 1
Ba EaFA-L06-1313-T09-C 1
Ba EaFA-L06-1313-B01-A 1
Ba EaFA-L06-1313-B02-A 1
Ba EaFA-L06-1313-B03-A 1
Ba EaFA-L06-1313-B01-B 1
Ba EaFA-L06-1313-B02-B 1
Ba EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
2.34E+03
1.34E+03
1.30E+03
8.26E+02
3.89E+02
3.07E+02
2.85E+02
3.65E+02
9.22E+02
2.41 E+03
1.35E+03
7.31 E+02
3.46E+02
2.63E+02
2.76E+02
3.07E+02
3.08E+02
9.07E+02
2.40E+03
1 .26E+03
7.20E+02
3.62E+02
2.99E+02
2.82E+02
2.88E+02
3.01 E+02
9.11E+02
5.00E-01 U1/2
5.00E-01 U1/2
1 .92E+00 E
5.00E-01 U1/2
5.00E-01 U1/2
2.17E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.34E+03 7.2E+00 1.0E+00 3.2E+00
1.34E+03 9.0E-01 1.0E+00 3.2E+00
1.30E+03 5.2E-01 1.0E+00 3.2E+00 10 325
8.26E+02 3.8E-01 1.0E+00 3.2E+00
3.89E+02 2.6E-01 1.0E+00 3.2E+00
3.07E+02 8.0E-01 1.0E+00 3.2E+00
2.85E+02 6.2E-01 1.0E+00 3.2E+00
3.65E+02 8.4E-01 1.0E+00 3.2E+00
9.22E+02 2.6E+00 1.0E+00 3.2E+00
2.41 E+03 3.2E+01 1.0E+00 3.2E+00
1.35E+03 3.2E-01 1.0E+00 3.2E+00
7.31E+02 8.5E+00 1.0E+00 3.2E+00 10 325
3.46E+02 2.9E+00 1.0E+00 3.2E+00
2.63E+02 9.9E+00 1.0E+00 3.2E+00
2.76E+02 1.9E+00 1.0E+00 3.2E+00
3.07E+02 4.3E-01 1.0E+00 3.2E+00
3.08E+02 2.8E+00 1 .OE+00 3.2E+00
9.07E+02 7.3E+01 1 .OE+00 3.2E+00
2.40E+03 3.2E+00 1 .OE+00 3.2E+00
1.26E+03 5.2E-01 1 .OE+00 3.2E+00
7.20E+02 6.0E-01 1 .OE+00 3.2E+00 10 325
3.62E+02 7.7E-01 1 .OE+00 3.2E+00
2.99E+02 3.8E-01 1 .OE+00 3.2E+00
2.82E+02 5.6E+00 1 .OE+00 3.2E+00
2.88E+02 7.3E+00 1 .OE+00 3.2E+00
3.01 E+02 2.8E+00 1 .OE+00 3.2E+00
9. 11 E+02 1.2E+01 1. OE+00 3.2E+00
5.00E-01 8.6E+01 1 .OE+00 3.2E+00
5.00E-01 3.7E+02 1. OE+00 3.2E+00
1.92E+00 6.4E+00 1. OE+00 3.2E+00
5.00E-01 1.4E+02 1. OE+00 3.2E+00
5.00E-01 1.5E+02 1. OE+00 3.2E+00
2.17E+00 1.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.10E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.72E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.53E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-124
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L06-1313-T01-A 1
Be EaFA-L06-1313-T02-A 1
Be EaFA-L06-1313-T03-A 1
Be EaFA-L06-1313-T04-A 1
Be EaFA-L06-1313-T05-A 1
Be EaFA-L06-1313-T06-A 1
Be EaFA-L06-1313-T07-A 1
Be EaFA-L06-1313-T08-A 1
Be EaFA-L06-1313-T09-A 1
Be EaFA-L06-1313-T01-B 1
Be EaFA-L06-1313-T02-B 1
Be EaFA-L06-1313-T03-B 1
Be EaFA-L06-1313-T04-B 1
Be EaFA-L06-1313-T05-B 1
Be EaFA-L06-1313-T06-B 1
Be EaFA-L06-1313-T07-B 1
Be EaFA-L06-1313-T08-B 1
Be EaFA-L06-1313-T09-B 1
Be EaFA-L06-1313-T01-C 1
Be EaFA-L06-1313-T02-C 1
Be EaFA-L06-1313-T03-C 1
Be EaFA-L06-1313-T04-C 1
Be EaFA-L06-1313-T05-C 1
Be EaFA-L06-1313-T06-C 1
Be EaFA-L06-1313-T07-C 1
Be EaFA-L06-1313-T08-C 1
Be EaFA-L06-1313-T09-C 1
Be EaFA-L06-1313-B01-A 1
Be EaFA-L06-1313-B02-A 1
Be EaFA-L06-1313-B03-A 1
Be EaFA-L06-1313-B01-B 1
Be EaFA-L06-1313-B02-B 1
Be EaFA-L06-1313-B03-B 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
8.66E+01
1.72E+02
2.47E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
5.98E+00 E
1.21E+02
2.39E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
6.09E+00
1.20E+02
2.41 E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.6E+01 1.9E+00 6.0E+00
9.50E-01 9.1E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00 10 325
9.50E-01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 7.8E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
8.66E+01 7.1E-01 1.9E+00 6.0E+00
1.72E+02 1.2E+00 1.9E+00 6.0E+00
2.47E+02 2.7E+00 1.9E+00 6.0E+00
9.50E-01 4.1E+00 1.9E+00 6.0E+00
9.50E-01 2.7E+02 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00 10 325
9.50E-01 5.6E+02 1.9E+00 6.0E+00
9.50E-01 6.4E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
5.98E+00 3.9E+00 1.9E+00 6.0E+00
1.21 E+02 3.1E+00 1.9E+00 6.0E+00
2.39E+02 7.5E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 2.1 E+02 1.9E+00 6.0E+00
9.50E-01 2.2E+02 1.9E+00 6.0E+00 10 325
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
6.09E+00 1.0E+01 1.9E+00 6.0E+00
1.20E+02 2.6E+00 1.9E+00 6.0E+00
2.41 E+02 4.3E+01 1.9E+00 6.0E+00
9.50E-01 2.9E+02 1.9E+00 6.0E+00
9.50E-01 1.1 E+02 1.9E+00 6.0E+00
9.50E-01 8.6E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+03 1.9E+00 6.0E+00
9.50E-01 4.3E+02 1.9E+00 6.0E+00
9.50E-01 6.8E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.19E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.32E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.17E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-125
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-L06-1313-T01-A 1
Cd EaFA-L06-1313-T02-A 1
Cd EaFA-L06-1313-T03-A 1
Cd EaFA-L06-1313-T04-A 1
Cd EaFA-L06-1313-T05-A 1
Cd EaFA-L06-1313-T06-A 1
Cd EaFA-L06-1313-T07-A 1
Cd EaFA-L06-1313-T08-A 1
Cd EaFA-L06-1313-T09-A 1
Cd EaFA-L06-1313-T01-B 1
Cd EaFA-L06-1313-T02-B 1
Cd EaFA-L06-1313-T03-B 1
Cd EaFA-L06-1313-T04-B 1
Cd EaFA-L06-1313-T05-B 1
Cd EaFA-L06-1313-T06-B 1
Cd EaFA-L06-1313-T07-B 1
Cd EaFA-L06-1313-T08-B 1
Cd EaFA-L06-1313-T09-B 1
Cd EaFA-L06-1313-T01-C 1
Cd EaFA-L06-1313-T02-C 1
Cd EaFA-L06-1313-T03-C 1
Cd EaFA-L06-1313-T04-C 1
Cd EaFA-L06-1313-T05-C 1
Cd EaFA-L06-1313-T06-C 1
Cd EaFA-L06-1313-T07-C 1
Cd EaFA-L06-1313-T08-C 1
Cd EaFA-L06-1313-T09-C 1
Cd EaFA-L06-1313-B01-A 1
Cd EaFA-L06-1313-B02-A 1
Cd EaFA-L06-1313-B03-A 1
Cd EaFA-L06-1313-B01-B 1
Cd EaFA-L06-1313-B02-B 1
Cd EaFA-L06-1313-B03-B 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
2.94E+01
2.61E+01
3.09E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.37E+01
2.81E+01
3.04E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.13E+01
2.74E+01
3.10E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 4.6E+01 2.2E+00 7.0E+00
1.10E+00 3.6E+00 2.2E+00 7.0E+00
1.10E+00 3.7E+01 2.2E+00 7.0E+00 10 325
1.10E+00 5.2E+00 2.2E+00 7.0E+00
1.10E+00 2.3E+01 2.2E+00 7.0E+00
1.10E+00 6.6E+01 2.2E+00 7.0E+00
2.94E+01 9.5E-01 2.2E+00 7.0E+00
2.61 E+01 1.4E+00 2.2E+00 7.0E+00
3.09E+01 2.5E+00 2.2E+00 7.0E+00
1.10E+00 3.4E+01 2.2E+00 7.0E+00
1.10E+00 1.8E+01 2.2E+00 7.0E+00
1.10E+00 2.4E+01 2.2E+00 7.0E+00 10 325
1.10E+00 1.9E+01 2.2E+00 7.0E+00
1.10E+00 1.5E+01 2.2E+00 7.0E+00
1.10E+00 7.8E+02 2.2E+00 7.0E+00
3.37E+01 1.6E+00 2.2E+00 7.0E+00
2.81 E+01 9.6E-01 2.2E+00 7.0E+00
3.04E+01 8.4E+01 2.2E+00 7.0E+00
1.10E+00 2.8E+01 2.2E+00 7.0E+00
1.10E+00 3.1 E+01 2.2E+00 7.0E+00
1.10E+00 1.4E+01 2.2E+00 7.0E+00 10 325
1.10E+00 2.3E+01 2.2E+00 7.0E+00
1.10E+00 1.6E+01 2.2E+00 7.0E+00
1.10E+00 1.5E+02 2.2E+00 7.0E+00
3.13E+01 8.4E+00 2.2E+00 7.0E+00
2.74E+01 1.7E+00 2.2E+00 7.0E+00
3.10E+01 4.0E+01 2.2E+00 7.0E+00
1.10E+00 2.9E+01 2.2E+00 7.0E+00
1.10E+00 1.6E+01 2.2E+00 7.0E+00
1.10E+00 8.9E+01 2.2E+00 7.0E+00
1.10E+00 2.0E+01 2.2E+00 7.0E+00
1.10E+00 1.2E+01 2.2E+00 7.0E+00
1.10E+00 4.4E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.22E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.34E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.20E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-126
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca EaFA-L06-1313-T01-A 1
Ca EaFA-L06-1313-T02-A 1
Ca EaFA-L06-1313-T03-A 1
Ca EaFA-L06-1313-T04-A 1
Ca EaFA-L06-1313-T05-A 1
Ca EaFA-L06-1313-T06-A 1
Ca EaFA-L06-1313-T07-A 1
Ca EaFA-L06-1313-T08-A 1
Ca EaFA-L06-1313-T09-A 1
Ca EaFA-L06-1313-T01-B 1
Ca EaFA-L06-1313-T02-B 1
Ca EaFA-L06-1313-T03-B 1
Ca EaFA-L06-1313-T04-B 1
Ca EaFA-L06-1313-T05-B 1
Ca EaFA-L06-1313-T06-B 1
Ca EaFA-L06-1313-T07-B 1
Ca EaFA-L06-1313-T08-B 1
Ca EaFA-L06-1313-T09-B 1
Ca EaFA-L06-1313-T01-C 1
Ca EaFA-L06-1313-T02-C 1
Ca EaFA-L06-1313-T03-C 1
Ca EaFA-L06-1313-T04-C 1
Ca EaFA-L06-1313-T05-C 1
Ca EaFA-L06-1313-T06-C 1
Ca EaFA-L06-1313-T07-C 1
Ca EaFA-L06-1313-T08-C 1
Ca EaFA-L06-1313-T09-C 1
Ca EaFA-L06-1313-B01-A 1
Ca EaFA-L06-1313-B02-A 1
Ca EaFA-L06-1313-B03-A 1
Ca EaFA-L06-1313-B01-B 1
Ca EaFA-L06-1313-B02-B 1
Ca EaFA-L06-1313-B03-B 1
Sample I
Cone. Qualifier
ug/L I
1.17E+04
4.11E+04
8.05E+04
1.19E+05
1.35E+05
1.62E+05
1.45E+05
1.49E+05
1.36E+05
1.24E+04
3.84E+04
9.62E+04
1.23E+05
1.31E+05
1.58E+05
1.72E+05
1.41E+05
1.35E+05
1.27E+04
3.46E+04
1.03E+05
1.27E+05
1.49E+05
1.65E+05
1.64E+05
1.38E+05
1.36E+05
1.86E+01
1.83E+01
6.85E+01
1.82E+01
2.17E+01
7.38E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.17E+04 8.3E+00 2.6E+00 8.3E+00
4.11E+04 7.9E-01 2.6E+00 8.3E+00
8.05E+04 2.9E-01 2.6E+00 8.3E+00 1000 100
1.19E+05 6.7E-01 2.6E+00 8.3E+00
1.35E+05 7.0E-01 2.6E+00 8.3E+00
1.62E+05 1.0E+00 2.6E+00 8.3E+00
1.45E+05 8.8E-01 2.6E+00 8.3E+00
1.49E+05 5.7E-01 2.6E+00 8.3E+00
1.36E+05 2.6E+00 2.6E+00 8.3E+00
1.24E+04 2.7E+01 2.6E+00 8.3E+00
3.84E+04 5.2E-01 2.6E+00 8.3E+00
9.62E+04 8.7E+00 2.6E+00 8.3E+00 1000 100
1.23E+05 2.7E+00 2.6E+00 8.3E+00
1.31E+05 8.9E+00 2.6E+00 8.3E+00
1.58E+05 1.8E+00 2.6E+00 8.3E+00
1.72E+05 1.7E-01 2.6E+00 8.3E+00
1.41E+05 3.3E+00 2.6E+00 8.3E+00
1.35E+05 7.1E+01 2.6E+00 8.3E+00
1.27E+04 3.5E+00 2.6E+00 8.3E+00
3.46E+04 3.3E-01 2.6E+00 8.3E+00
1.03E+05 1.1E+00 2.6E+00 8.3E+00 1000 100
1.27E+05 3.3E-01 2.6E+00 8.3E+00
1.49E+05 8.6E-01 2.6E+00 8.3E+00
1.65E+05 6.1E+00 2.6E+00 8.3E+00
1.64E+05 7.3E+00 2.6E+00 8.3E+00
1.38E+05 2.7E+00 2.6E+00 8.3E+00
1.36E+05 1.2E+01 2.6E+00 8.3E+00
1.86E+01 3.0E+01 2.6E+00 8.3E+00
1.83E+01 4.2E+01 2.6E+00 8.3E+00
6.85E+01 2.7E+01 2.6E+00 8.3E+00
1.82E+01 1.7E+01 2.6E+00 8.3E+00
2.17E+01 3.6E+01 2.6E+00 8.3E+00
7.38E+01 5.9E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.14E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.72E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .04E+05 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-127
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone.
1 ug/L
Cr EaFA-L06-1313-T01-A 1 6.39E+02
Cr EaFA-L06-1313-T02-A 1 3.83E+02
Cr EaFA-L06-1313-T03-A 1 2.96E+02
Cr EaFA-L06-1313-T04-A 1 2.31E+02
Cr EaFA-L06-1313-T05-A 1 1.34E+02
Cr EaFA-L06-1313-T06-A 1 1.74E+01
Cr EaFA-L06-1313-T07-A 1 4.99E+01
Cr EaFA-L06-1313-T08-A 1 7.84E+02
Cr EaFA-L06-1313-T09-A 1 1.72E+03
Cr EaFA-L06-1313-T01-B 1 6.12E+02
Cr EaFA-L06-1313-T02-B 1 4.26E+02
Cr EaFA-L06-1313-T03-B 1 2.80E+02
Cr EaFA-L06-1313-T04-B 1 2.08E+02
Cr EaFA-L06-1313-T05-B 1 8.97E+01
Cr EaFA-L06-1313-T06-B 1 1.63E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.39E+02 8.9E+00 1.2E+00 3.8E+00
3.83E+02 8.4E-01 1.2E+00 3.8E+00
2.96E+02 3.9E-01 1.2E+00 3.8E+00 10 325
2.31 E+02 6.9E-01 1.2E+00 3.8E+00
1.34E+02 3.1E-01 1.2E+00 3.8E+00
1.74E+01 2.1E+00 1.2E+00 3.8E+00
4.99E+01 9.8E-01 1.2E+00 3.8E+00
7.84E+02 1.2E+00 1.2E+00 3.8E+00
1.72E+03 2.8E+00 1.2E+00 3.8E+00
6.12E+02 1.8E+01 1.2E+00 3.8E+00
4.26E+02 2.9E-01 1.2E+00 3.8E+00
2.80E+02 8.7E+00 1.2E+00 3.8E+00 10 325
2.08E+02 3.2E+00 1.2E+00 3.8E+00
8.97E+01 9.8E+00 1.2E+00 3.8E+00
1.63E+01 5.7E+00 1.2E+00 3.8E+00
Cr EaFA-L06-1313-T07-B 1 1.28E+OOE 1.28E+00 1 .5E+02 1.2E+00 3.8E+00
Cr EaFA-L06-1313-T08-B 1 1.64E+02
Cr EaFA-L06-1313-T09-B 1 1.68E+03
Cr EaFA-L06-1313-T01-C 1 6.15E+02
Cr EaFA-L06-1313-T02-C 1 3.80E+02
Cr EaFA-L06-1313-T03-C 1 2.91E+02
Cr EaFA-L06-1313-T04-C 1 2.01E+02
Cr EaFA-L06-1313-T05-C 1 1.07E+02
Cr EaFA-L06-1313-T06-C 1 2.41E+01
1.64E+02 2.9E+00 1.2E+00 3.8E+00
1.68E+03 5.3E+01 1.2E+00 3.8E+00
6.15E+02 2.6E+00 1.2E+00 3.8E+00
3.80E+02 3.4E-01 1.2E+00 3.8E+00
2.91E+02 1.1E+00 1.2E+00 3.8E+00 10 325
2.01 E+02 2.2E-01 1.2E+00 3.8E+00
1.07E+02 1.4E+00 1.2E+00 3.8E+00
2.41 E+01 7.6E+00 1.2E+00 3.8E+00
Cr EaFA-L06-1313-T07-C 1 6.00E-01 U1/2 6.00E-01 2.9E+02 1.2E+00 3.8E+00
Cr EaFA-L06-1313-T08-C 1 1.78E+02
Cr EaFA-L06-1313-T09-C 1 1.69E+03
1.78E+02 2.1E+00 1.2E+00 3.8E+00
1.69E+03 1.3E+01 1.2E+00 3.8E+00
Cr EaFA-L06-1313-B01-A 1 6.00E-01 U1/2 6.00E-01 1.0E+02 1.2E+00 3.8E+00
Cr EaFA-L06-1313-B02-A 1 6.00E-01 U1/2 6.00E-01 3.0E+02 1.2E+00 3.8E+00
Cr EaFA-L06-1313-B03-A 1 6.86E+00
6.86E+00 3.6E+01 1.2E+00 3.8E+00
Cr EaFA-L06-1313-B01-B 1 6.00E-01 U1/2 6.00E-01 1.6E+03 1.2E+00 3.8E+00
Cr EaFA-L06-1313-B02-B 1 6.00E-01 U1/2 6.00E-01 2.0E+02 1.2E+00 3.8E+00
Cr EaFA-L06-1313-B03-B 1 6.83E+00
6.83E+00 6.5E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.40E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.47E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-128
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-L06-1313-T01-A 1
Co EaFA-L06-1313-T02-A 1
Co EaFA-L06-1313-T03-A 1
Co EaFA-L06-1313-T04-A 1
Co EaFA-L06-1313-T05-A 1
Co EaFA-L06-1313-T06-A 1
Co EaFA-L06-1313-T07-A 1
Co EaFA-L06-1313-T08-A 1
Co EaFA-L06-1313-T09-A 1
Co EaFA-L06-1313-T01-B 1
Co EaFA-L06-1313-T02-B 1
Co EaFA-L06-1313-T03-B 1
Co EaFA-L06-1313-T04-B 1
Co EaFA-L06-1313-T05-B 1
Co EaFA-L06-1313-T06-B 1
Co EaFA-L06-1313-T07-B 1
Co EaFA-L06-1313-T08-B 1
Co EaFA-L06-1313-T09-B 1
Co EaFA-L06-1313-T01-C 1
Co EaFA-L06-1313-T02-C 1
Co EaFA-L06-1313-T03-C 1
Co EaFA-L06-1313-T04-C 1
Co EaFA-L06-1313-T05-C 1
Co EaFA-L06-1313-T06-C 1
Co EaFA-L06-1313-T07-C 1
Co EaFA-L06-1313-T08-C 1
Co EaFA-L06-1313-T09-C 1
Co EaFA-L06-1313-B01-A 1
Co EaFA-L06-1313-B02-A 1
Co EaFA-L06-1313-B03-A 1
Co EaFA-L06-1313-B01-B 1
Co EaFA-L06-1313-B02-B 1
Co EaFA-L06-1313-B03-B 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
6.99E+01
1.95E+02
2.26E+02
4.02E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.65E+00 E
6.56E+01
2.47E+02
1.99E+02
4.00E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
4.45E+00 E
5.89E+01
2.36E+02
1.97E+02
4.01 E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.1E+01 1.8E+00 5.7E+00
9.00E-01 6.1E+01 1.8E+00 5.7E+00
9.00E-01 4.8E+01 1.8E+00 5.7E+00 10 325
9.00E-01 4.8E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+03 1.8E+00 5.7E+00
6.99E+01 2.7E+00 1.8E+00 5.7E+00
1.95E+02 3.6E-01 1.8E+00 5.7E+00
2.26E+02 1.1E+00 1.8E+00 5.7E+00
4.02E+02 3.1E+00 1.8E+00 5.7E+00
9.00E-01 7.7E+01 1.8E+00 5.7E+00
9.00E-01 1.3E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+01 1.8E+00 5.7E+00 10 325
9.00E-01 9.5E+01 1.8E+00 5.7E+00
2.65E+00 1.1 E+02 1.8E+00 5.7E+00
6.56E+01 4.4E+00 1.8E+00 5.7E+00
2.47E+02 1.4E+00 1.8E+00 5.7E+00
1.99E+02 3.0E+00 1.8E+00 5.7E+00
4.00E+02 7.2E+01 1.8E+00 5.7E+00
9.00E-01 1.1 E+02 1.8E+00 5.7E+00
9.00E-01 4.4E+01 1.8E+00 5.7E+00
9.00E-01 3.5E+01 1.8E+00 5.7E+00 10 325
9.00E-01 5.7E+01 1.8E+00 5.7E+00
4.45E+00 5.5E+00 1.8E+00 5.7E+00
5.89E+01 8.9E+00 1.8E+00 5.7E+00
2.36E+02 6.8E+00 1.8E+00 5.7E+00
1.97E+02 2.4E+00 1.8E+00 5.7E+00
4.01 E+02 8.7E+00 1.8E+00 5.7E+00
9.00E-01 8.2E+01 1.8E+00 5.7E+00
9.00E-01 2.4E+01 1.8E+00 5.7E+00
9.00E-01 3.1 E+02 1.8E+00 5.7E+00
9.00E-01 3.8E+01 1.8E+00 5.7E+00
9.00E-01 2.1E+01 1.8E+00 5.7E+00
9.00E-01 6.0E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.13E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.22E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.11E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-129
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFA-L06-1313-T01-A 1
Cu EaFA-L06-1313-T02-A 1
Cu EaFA-L06-1313-T03-A 1
Cu EaFA-L06-1313-T04-A 1
Cu EaFA-L06-1313-T05-A 1
Cu EaFA-L06-1313-T06-A 1
Cu EaFA-L06-1313-T07-A 1
Cu EaFA-L06-1313-T08-A 1
Cu EaFA-L06-1313-T09-A 1
Cu EaFA-L06-1313-T01-B 1
Cu EaFA-L06-1313-T02-B 1
Cu EaFA-L06-1313-T03-B 1
Cu EaFA-L06-1313-T04-B 1
Cu EaFA-L06-1313-T05-B 1
Cu EaFA-L06-1313-T06-B 1
Cu EaFA-L06-1313-T07-B 1
Cu EaFA-L06-1313-T08-B 1
Cu EaFA-L06-1313-T09-B 1
Cu EaFA-L06-1313-T01-C 1
Cu EaFA-L06-1313-T02-C 1
Cu EaFA-L06-1313-T03-C 1
Cu EaFA-L06-1313-T04-C 1
Cu EaFA-L06-1313-T05-C 1
Cu EaFA-L06-1313-T06-C 1
Cu EaFA-L06-1313-T07-C 1
Cu EaFA-L06-1313-T08-C 1
Cu EaFA-L06-1313-T09-C 1
Cu EaFA-L06-1313-B01-A 1
Cu EaFA-L06-1313-B02-A 1
Cu EaFA-L06-1313-B03-A 1
Cu EaFA-L06-1313-B01-B 1
Cu EaFA-L06-1313-B02-B 1
Cu EaFA-L06-1313-B03-B 1
Sample Inter
Cone. Qualifier Revi
ug/L
8.34E+01
4.05E+00 E
5.02E+00 E
5.46E+00 E
1.85E+00 U1/2
1.85E+00 U1/2
1.67E+03
2.34E+03
2.90E+03
7.01E+01
2.00E+01
1.85E+00 U1/2
5.63E+00 E
1.85E+00 U1/2
8.09E+00 E
1.35E+02
1.94E+03
2.89E+03
9.20E+01
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
4.82E+00 E
7.66E+00 E
1.39E+02
1.92E+03
2.91 E+03
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.34E+01 9.8E+00 3.7E+00 1.2E+01
4.05E+00 2.7E+02 3.7E+00 1.2E+01
5.02E+00 1.3E+02 3.7E+00 1.2E+01 10 325
5.46E+00 2.9E+04 3.7E+00 1.2E+01
1.85E+00 1.4E+02 3.7E+00 1.2E+01
1.85E+00 2.9E+02 3.7E+00 1.2E+01
1.67E+03 1.1E+00 3.7E+00 1.2E+01
2.34E+03 1.7E+00 3.7E+00 1.2E+01
2.90E+03 3.7E+00 3.7E+00 1.2E+01
7.01E+01 2.1E+01 3.7E+00 1.2E+01
2.00E+01 6.2E+01 3.7E+00 1.2E+01
1.85E+00 1.1E+02 3.7E+00 1.2E+01 10 325
5.63E+00 2.0E+01 3.7E+00 1.2E+01
1.85E+00 3.9E+02 3.7E+00 1.2E+01
8.09E+00 1.3E+02 3.7E+00 1.2E+01
1.35E+02 4.3E+00 3.7E+00 1.2E+01
1.94E+03 1.3E+00 3.7E+00 1.2E+01
2.89E+03 4.7E+01 3.7E+00 1.2E+01
9.20E+01 4.4E+00 3.7E+00 1.2E+01
1.85E+00 9.7E+01 3.7E+00 1.2E+01
1.85E+00 3.0E+01 3.7E+00 1.2E+01 10 325
1.85E+00 3.2E+02 3.7E+00 1.2E+01
4.82E+00 1.1E+02 3.7E+00 1.2E+01
7.66E+00 5.2E+01 3.7E+00 1.2E+01
1.39E+02 6.7E+00 3.7E+00 1.2E+01
1.92E+03 4.5E+00 3.7E+00 1.2E+01
2.91 E+03 4.4E+01 3.7E+00 1.2E+01
1.85E+00 8.5E+01 3.7E+00 1.2E+01
1.85E+00 1.4E+02 3.7E+00 1.2E+01
1.85E+00 6.2E+01 3.7E+00 1.2E+01
1.85E+00 9.1E+02 3.7E+00 1.2E+01
1.85E+00 2.7E+02 3.7E+00 1.2E+01
1.85E+00 3.1E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.06E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.07E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-130
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L06-1313-T01-A 1
Fe EaFA-L06-1313-T02-A 1
Fe EaFA-L06-1313-T03-A 1
Fe EaFA-L06-1313-T04-A 1
Fe EaFA-L06-1313-T05-A 1
Fe EaFA-L06-1313-T06-A 1
Fe EaFA-L06-1313-T07-A 1
Fe EaFA-L06-1313-T08-A 1
Fe EaFA-L06-1313-T09-A 1
Fe EaFA-L06-1313-T01-B 1
Fe EaFA-L06-1313-T02-B 1
Fe EaFA-L06-1313-T03-B 1
Fe EaFA-L06-1313-T04-B 1
Fe EaFA-L06-1313-T05-B 1
Fe EaFA-L06-1313-T06-B 1
Fe EaFA-L06-1313-T07-B 1
Fe EaFA-L06-1313-T08-B 1
Fe EaFA-L06-1313-T09-B 1
Fe EaFA-L06-1313-T01-C 1
Fe EaFA-L06-1313-T02-C 1
Fe EaFA-L06-1313-T03-C 1
Fe EaFA-L06-1313-T04-C 1
Fe EaFA-L06-1313-T05-C 1
Fe EaFA-L06-1313-T06-C 1
Fe EaFA-L06-1313-T07-C 1
Fe EaFA-L06-1313-T08-C 1
Fe EaFA-L06-1313-T09-C 1
Fe EaFA-L06-1313-B01-A 1
Fe EaFA-L06-1313-B02-A 1
Fe EaFA-L06-1313-B03-A 1
Fe EaFA-L06-1313-B01-B 1
Fe EaFA-L06-1313-B02-B 1
Fe EaFA-L06-1313-B03-B 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.29E+01
2.54E+01
8.76E+00
2.43E+00 E
1.00E+00 U1/2
3.46E+01
1.80E+02
2.40E+03
3.56E+04
2.30E+01
2.66E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.50E+02
3.53E+04
2.54E+01
2.10E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.61 E+02
3.55E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.52E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.42E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.29E+01 1.4E+01 2.0E+00 6.4E+00
2.54E+01 2.1E+00 2.0E+00 6.4E+00
8.76E+00 3.6E+00 2.0E+00 6.4E+00 1000 100
2.43E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
3.46E+01 8.6E-01 2.0E+00 6.4E+00
1.80E+02 2.9E-01 2.0E+00 6.4E+00
2.40E+03 4.7E-01 2.0E+00 6.4E+00
3.56E+04 2.4E+00 2.0E+00 6.4E+00
2.30E+01 2.0E+01 2.0E+00 6.4E+00
2.66E+01 1.9E+00 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.8E+00 2.0E+00 6.4E+00
1.00E+00 7.1E+01 2.0E+00 6.4E+00
1.00E+00 3.7E+01 2.0E+00 6.4E+00
1.00E+00 5.1E+00 2.0E+00 6.4E+00
4.50E+02 1.0E+00 2.0E+00 6.4E+00
3.53E+04 6.5E+01 2.0E+00 6.4E+00
2.54E+01 6.2E+00 2.0E+00 6.4E+00
2.10E+01 2.2E+00 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 5.7E+01 2.0E+00 6.4E+00
1.00E+00 7.8E+01 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+01 2.0E+00 6.4E+00
4.61 E+02 4.3E+00 2.0E+00 6.4E+00
3.55E+04 3.7E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
1.00E+00 3.8E+02 2.0E+00 6.4E+00
1.52E+01 9.8E+00 2.0E+00 6.4E+00
1.00E+00 8.5E+00 2.0E+00 6.4E+00
1.00E+00 5.6E+01 2.0E+00 6.4E+00
1.42E+01 1.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.86E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-131
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L06-1313-T01-A 1
Pb EaFA-L06-1313-T02-A 1
Pb EaFA-L06-1313-T03-A 1
Pb EaFA-L06-1313-T04-A 1
Pb EaFA-L06-1313-T05-A 1
Pb EaFA-L06-1313-T06-A 1
Pb EaFA-L06-1313-T07-A 1
Pb EaFA-L06-1313-T08-A 1
Pb EaFA-L06-1313-T09-A 1
Pb EaFA-L06-1313-T01-B 1
Pb EaFA-L06-1313-T02-B 1
Pb EaFA-L06-1313-T03-B 1
Pb EaFA-L06-1313-T04-B 1
Pb EaFA-L06-1313-T05-B 1
Pb EaFA-L06-1313-T06-B 1
Pb EaFA-L06-1313-T07-B 1
Pb EaFA-L06-1313-T08-B 1
Pb EaFA-L06-1313-T09-B 1
Pb EaFA-L06-1313-T01-C 1
Pb EaFA-L06-1313-T02-C 1
Pb EaFA-L06-1313-T03-C 1
Pb EaFA-L06-1313-T04-C 1
Pb EaFA-L06-1313-T05-C 1
Pb EaFA-L06-1313-T06-C 1
Pb EaFA-L06-1313-T07-C 1
Pb EaFA-L06-1313-T08-C 1
Pb EaFA-L06-1313-T09-C 1
Pb EaFA-L06-1313-B01-A 1
Pb EaFA-L06-1313-B02-A 1
Pb EaFA-L06-1313-B03-A 1
Pb EaFA-L06-1313-B01-B 1
Pb EaFA-L06-1313-B02-B 1
Pb EaFA-L06-1313-B03-B 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.55E+01 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
9.17E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
9.52E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.01E+02
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.55E+01 8.6E+01 6.8E+00 2.2E+01
3.40E+00 5.2E+01 6.8E+00 2.2E+01
3.40E+00 6.5E+01 6.8E+00 2.2E+01 10 325
3.40E+00 3.1E+01 6.8E+00 2.2E+01
3.40E+00 8.1E+01 6.8E+00 2.2E+01
3.40E+00 2.8E+01 6.8E+00 2.2E+01
3.40E+00 2.1E+01 6.8E+00 2.2E+01
3.40E+00 2.3E+01 6.8E+00 2.2E+01
9.17E+01 4.1E+00 6.8E+00 2.2E+01
3.40E+00 1.0E+03 6.8E+00 2.2E+01
3.40E+00 1.9E+01 6.8E+00 2.2E+01
3.40E+00 6.5E+01 6.8E+00 2.2E+01 10 325
3.40E+00 5.0E+01 6.8E+00 2.2E+01
3.40E+00 1.7E+01 6.8E+00 2.2E+01
3.40E+00 1.2E+01 6.8E+00 2.2E+01
3.40E+00 5.1E+00 6.8E+00 2.2E+01
3.40E+00 3.0E+01 6.8E+00 2.2E+01
9.52E+01 1.1E+02 6.8E+00 2.2E+01
3.40E+00 2.8E+02 6.8E+00 2.2E+01
3.40E+00 3.7E+00 6.8E+00 2.2E+01
3.40E+00 2.8E+01 6.8E+00 2.2E+01 10 325
3.40E+00 3.3E+01 6.8E+00 2.2E+01
3.40E+00 8.6E+01 6.8E+00 2.2E+01
3.40E+00 3.9E+01 6.8E+00 2.2E+01
3.40E+00 1.8E+01 6.8E+00 2.2E+01
3.40E+00 2.5E+01 6.8E+00 2.2E+01
1.01E+02 1.1E+01 6.8E+00 2.2E+01
3.40E+00 5.1E+01 6.8E+00 2.2E+01
3.40E+00 2.7E+01 6.8E+00 2.2E+01
3.40E+00 6.3E+01 6.8E+00 2.2E+01
3.40E+00 5.5E+01 6.8E+00 2.2E+01
3.40E+00 4.2E+01 6.8E+00 2.2E+01
3.40E+00 3.3E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.10E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.21E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.09E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-132
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFA-L06-1313-T01-A 1
Li EaFA-L06-1313-T02-A 1
Li EaFA-L06-1313-T03-A 1
Li EaFA-L06-1313-T04-A 1
Li EaFA-L06-1313-T05-A 1
Li EaFA-L06-1313-T06-A 1
Li EaFA-L06-1313-T07-A 1
Li EaFA-L06-1313-T08-A 1
Li EaFA-L06-1313-T09-A 1
Li EaFA-L06-1313-T01-B 1
Li EaFA-L06-1313-T02-B 1
Li EaFA-L06-1313-T03-B 1
Li EaFA-L06-1313-T04-B 1
Li EaFA-L06-1313-T05-B 1
Li EaFA-L06-1313-T06-B 1
Li EaFA-L06-1313-T07-B 1
Li EaFA-L06-1313-T08-B 1
Li EaFA-L06-1313-T09-B 1
Li EaFA-L06-1313-T01-C 1
Li EaFA-L06-1313-T02-C 1
Li EaFA-L06-1313-T03-C 1
Li EaFA-L06-1313-T04-C 1
Li EaFA-L06-1313-T05-C 1
Li EaFA-L06-1313-T06-C 1
Li EaFA-L06-1313-T07-C 1
Li EaFA-L06-1313-T08-C 1
Li EaFA-L06-1313-T09-C 1
Li EaFA-L06-1313-B01-A 1
Li EaFA-L06-1313-B02-A 1
Li EaFA-L06-1313-B03-A 1
Li EaFA-L06-1313-B01-B 1
Li EaFA-L06-1313-B02-B 1
Li EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
2.51 E+03
2.93E+03
3.27E+03
3.49E+03
3.55E+03
3.86E+03
2.77E+03
2.14E+03
1.58E+03
2.36E+03
2.96E+03
3.21 E+03
3.32E+03
3.33E+03
3.75E+03
3.81 E+03
2.42E+03
1.54E+03
2.49E+03
2.64E+03
3.42E+03
3.48E+03
3.79E+03
3.94E+03
3.68E+03
2.35E+03
1.58E+03
2.55E+00 E
9.50E-01 U1/2
9.50E-01 U1/2
2.31 E+00 E
9.50E-01 U1/2
9.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.51 E+03 7.5E+00 1.9E+00 6.0E+00
2.93E+03 7.9E-01 1.9E+00 6.0E+00
3.27E+03 6.3E-01 1.9E+00 6.0E+00 10 325
3.49E+03 3.3E-01 1.9E+00 6.0E+00
3.55E+03 4.4E-01 1.9E+00 6.0E+00
3.86E+03 9.1E-01 1.9E+00 6.0E+00
2.77E+03 7.9E-01 1.9E+00 6.0E+00
2.14E+03 6.3E-01 1.9E+00 6.0E+00
1.58E+03 2.7E+00 1.9E+00 6.0E+00
2.36E+03 4.6E+01 1.9E+00 6.0E+00
2.96E+03 7.6E-01 1.9E+00 6.0E+00
3.21E+03 8.6E+00 1.9E+00 6.0E+00 10 325
3.32E+03 3.4E+00 1.9E+00 6.0E+00
3.33E+03 1.1E+01 1.9E+00 6.0E+00
3.75E+03 2.7E+00 1.9E+00 6.0E+00
3.81 E+03 5.1E-01 1.9E+00 6.0E+00
2.42E+03 3.7E+00 1.9E+00 6.0E+00
1.54E+03 7.3E+01 1.9E+00 6.0E+00
2.49E+03 2.4E+00 1.9E+00 6.0E+00
2.64E+03 4.5E-01 1.9E+00 6.0E+00
3.42E+03 9.0E-01 1.9E+00 6.0E+00 10 325
3.48E+03 6.2E-01 1.9E+00 6.0E+00
3.79E+03 2.3E-01 1.9E+00 6.0E+00
3.94E+03 5.7E+00 1.9E+00 6.0E+00
3.68E+03 7.6E+00 1.9E+00 6.0E+00
2.35E+03 2.5E+00 1.9E+00 6.0E+00
1.58E+03 1.6E+01 1.9E+00 6.0E+00
2.55E+00 3.4E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00
2.31 E+00 2.5E+01 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.00E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.24E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.15E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-133
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFA-L06-1313-T01-A 1
Mn EaFA-L06-1313-T02-A 1
Mn EaFA-L06-1313-T03-A 1
Mn EaFA-L06-1313-T04-A 1
Mn EaFA-L06-1313-T05-A 1
Mn EaFA-L06-1313-T06-A 1
Mn EaFA-L06-1313-T07-A 1
Mn EaFA-L06-1313-T08-A 1
Mn EaFA-L06-1313-T09-A 1
Mn EaFA-L06-1313-T01-B 1
Mn EaFA-L06-1313-T02-B 1
Mn EaFA-L06-1313-T03-B 1
Mn EaFA-L06-1313-T04-B 1
Mn EaFA-L06-1313-T05-B 1
Mn EaFA-L06-1313-T06-B 1
Mn EaFA-L06-1313-T07-B 1
Mn EaFA-L06-1313-T08-B 1
Mn EaFA-L06-1313-T09-B 1
Mn EaFA-L06-1313-T01-C 1
Mn EaFA-L06-1313-T02-C 1
Mn EaFA-L06-1313-T03-C 1
Mn EaFA-L06-1313-T04-C 1
Mn EaFA-L06-1313-T05-C 1
Mn EaFA-L06-1313-T06-C 1
Mn EaFA-L06-1313-T07-C 1
Mn EaFA-L06-1313-T08-C 1
Mn EaFA-L06-1313-T09-C 1
Mn EaFA-L06-1313-B01-A 1
Mn EaFA-L06-1313-B02-A 1
Mn EaFA-L06-1313-B03-A 1
Mn EaFA-L06-1313-B01-B 1
Mn EaFA-L06-1313-B02-B 1
Mn EaFA-L06-1313-B03-B 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.21E+01
4.30E+02
8.96E+02
1.21E+03
1.57E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.70E+00 E
6.26E+01
4.31 E+02
8.70E+02
1.02E+03
1.55E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.30E+00 E
7.33E+01
3.94E+02
8.29E+02
1.01E+03
1 .56E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 8.2E+01 2.0E+00 6.4E+00 10 325
1.00E+00 6.6E+01 2.0E+00 6.4E+00
1.21E+01 8.5E-01 2.0E+00 6.4E+00
4.30E+02 6.3E-01 2.0E+00 6.4E+00
8.96E+02 7.9E-01 2.0E+00 6.4E+00
1.21E+03 7.0E-01 2.0E+00 6.4E+00
1.57E+03 2.3E+00 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00 10 325
4.70E+00 5.6E+00 2.0E+00 6.4E+00
6.26E+01 7.5E+00 2.0E+00 6.4E+00
4.31 E+02 1.2E+00 2.0E+00 6.4E+00
8.70E+02 8.2E-01 2.0E+00 6.4E+00
1.02E+03 2.5E+00 2.0E+00 6.4E+00
1.55E+03 7.3E+01 2.0E+00 6.4E+00
1.00E+00 4.1E+00 2.0E+00 6.4E+00
1.00E+00 8.1E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00 10 325
4.30E+00 2.9E+00 2.0E+00 6.4E+00
7.33E+01 7.3E-01 2.0E+00 6.4E+00
3.94E+02 5.6E+00 2.0E+00 6.4E+00
8.29E+02 5.1E+00 2.0E+00 6.4E+00
1.01E+03 2.5E+00 2.0E+00 6.4E+00
1.56E+03 1.3E+01 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 6.2E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+02 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.01 E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.12E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.99E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:1 1 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-134
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFA-L06-1313-T01-A 1
Mg EaFA-L06-1313-T02-A 1
Mg EaFA-L06-1313-T03-A 1
Mg EaFA-L06-1313-T04-A 1
Mg EaFA-L06-1313-T05-A 1
Mg EaFA-L06-1313-T06-A 1
Mg EaFA-L06-1313-T07-A 1
Mg EaFA-L06-1313-T08-A 1
Mg EaFA-L06-1313-T09-A 1
Mg EaFA-L06-1313-T01-B 1
Mg EaFA-L06-1313-T02-B 1
Mg EaFA-L06-1313-T03-B 1
Mg EaFA-L06-1313-T04-B 1
Mg EaFA-L06-1313-T05-B 1
Mg EaFA-L06-1313-T06-B 1
Mg EaFA-L06-1313-T07-B 1
Mg EaFA-L06-1313-T08-B 1
Mg EaFA-L06-1313-T09-B 1
Mg EaFA-L06-1313-T01-C 1
Mg EaFA-L06-1313-T02-C 1
Mg EaFA-L06-1313-T03-C 1
Mg EaFA-L06-1313-T04-C 1
Mg EaFA-L06-1313-T05-C 1
Mg EaFA-L06-1313-T06-C 1
Mg EaFA-L06-1313-T07-C 1
Mg EaFA-L06-1313-T08-C 1
Mg EaFA-L06-1313-T09-C 1
Mg EaFA-L06-1313-B01-A 1
Mg EaFA-L06-1313-B02-A 1
Mg EaFA-L06-1313-B03-A 1
Mg EaFA-L06-1313-B01-B 1
Mg EaFA-L06-1313-B02-B 1
Mg EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
5.00E-01 U1/2
5.00E-01 U1/2
5.73E+01
2.69E+03
4.07E+03
7.86E+03
7.52E+03
9.47E+03
1.42E+04
5.00E-01 U1/2
4.66E+00
1.65E+03
3.82E+03
5.62E+03
7.93E+03
9.25E+03
7.73E+03
1.40E+04
5.00E-01 U1/2
5.00E-01 U1/2
1.72E+03
3.93E+03
6.47E+03
8.43E+03
8.71 E+03
7.70E+03
1.43E+04
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
2.24E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 1.8E+02 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
5.73E+01 3.0E+01 1.0E+00 3.2E+00 1000 100
2.69E+03 1.2E+00 1.0E+00 3.2E+00
4.07E+03 3.1E-01 1.0E+00 3.2E+00
7.86E+03 6.6E-01 1.0E+00 3.2E+00
7.52E+03 5.8E-01 1.0E+00 3.2E+00
9.47E+03 1.4E+00 1.0E+00 3.2E+00
1.42E+04 1.1E+00 1.0E+00 3.2E+00
5.00E-01 3.3E+01 1.0E+00 3.2E+00
4.66E+00 2.6E+02 1.0E+00 3.2E+00
1.65E+03 8.9E+00 1.0E+00 3.2E+00 1000 100
3.82E+03 3.3E+00 1.0E+00 3.2E+00
5.62E+03 9.7E+00 1.0E+00 3.2E+00
7.93E+03 1.8E+00 1.0E+00 3.2E+00
9.25E+03 5.7E-01 1.0E+00 3.2E+00
7.73E+03 2.4E+00 1.0E+00 3.2E+00
1.40E+04 6.8E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00
5.00E-01 1.0E+02 1.0E+00 3.2E+00
1.72E+03 7.9E-01 1.0E+00 3.2E+00 1000 100
3.93E+03 1.2E+00 1.0E+00 3.2E+00
6.47E+03 2.5E+00 1.0E+00 3.2E+00
8.43E+03 4.5E+00 1.0E+00 3.2E+00
8.71 E+03 6.1E+00 1.0E+00 3.2E+00
7.70E+03 2.5E+00 1.0E+00 3.2E+00
1.43E+04 1.9E+01 1.0E+00 3.2E+00
5.00E-01 7.1E+01 1.0E+00 3.2E+00
5.00E-01 5.4E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+02 1.0E+00 3.2E+00
5.00E-01 2.0E+01 1.0E+00 3.2E+00
5.00E-01 3.6E+01 1.0E+00 3.2E+00
2.24E+00 3.9E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.64E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.53E+03 81% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-135
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo EaFA-L06-1313-T01-A 1
Mo EaFA-L06-1313-T02-A 1
Mo EaFA-L06-1313-T03-A 1
Mo EaFA-L06-1313-T04-A 1
Mo EaFA-L06-1313-T05-A 1
Mo EaFA-L06-1313-T06-A 1
Mo EaFA-L06-1313-T07-A 1
Mo EaFA-L06-1313-T08-A 1
Mo EaFA-L06-1313-T09-A 1
Mo EaFA-L06-1313-T01-B 1
Mo EaFA-L06-1313-T02-B 1
Mo EaFA-L06-1313-T03-B 1
Mo EaFA-L06-1313-T04-B 1
Mo EaFA-L06-1313-T05-B 1
Mo EaFA-L06-1313-T06-B 1
Mo EaFA-L06-1313-T07-B 1
Mo EaFA-L06-1313-T08-B 1
Mo EaFA-L06-1313-T09-B 1
Mo EaFA-L06-1313-T01-C 1
Mo EaFA-L06-1313-T02-C 1
Mo EaFA-L06-1313-T03-C 1
Mo EaFA-L06-1313-T04-C 1
Mo EaFA-L06-1313-T05-C 1
Mo EaFA-L06-1313-T06-C 1
Mo EaFA-L06-1313-T07-C 1
Mo EaFA-L06-1313-T08-C 1
Mo EaFA-L06-1313-T09-C 1
Mo EaFA-L06-1313-B01-A 1
Mo EaFA-L06-1313-B02-A 1
Mo EaFA-L06-1313-B03-A 1
Mo EaFA-L06-1313-B01-B 1
Mo EaFA-L06-1313-B02-B 1
Mo EaFA-L06-1313-B03-B 1
Sample I
Cone. Qualifier
ug/L I
4.39E+03
3.98E+03
3.99E+03
4.02E+03
3.72E+03
3.09E+03
1.29E+02
9.65E+01
4.17E+02
3.92E+03
4.03E+03
3.56E+03
3.44E+03
3.16E+03
3.01 E+03
4.85E+02
1.20E+02
3.91 E+02
4.40E+03
3.59E+03
3.83E+03
3.65E+03
3.62E+03
3.05E+03
4.74E+02
1.20E+02
4.00E+02
1.94E+00 E
3.48E+00 E
9.21 E+00
2.71E+00 E
6.00E-01 U1/2
1.25E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.39E+03 8.6E+00 1.2E+00 3.8E+00
3.98E+03 4.2E-01 1.2E+00 3.8E+00
3.99E+03 6.6E-01 1.2E+00 3.8E+00 10 325
4.02E+03 4.0E-01 1.2E+00 3.8E+00
3.72E+03 9.3E-01 1.2E+00 3.8E+00
3.09E+03 8.3E-01 1.2E+00 3.8E+00
1.29E+02 1.7E+00 1.2E+00 3.8E+00
9.65E+01 2.0E+00 1.2E+00 3.8E+00
4.17E+02 2.8E+00 1.2E+00 3.8E+00
3.92E+03 1.7E+01 1.2E+00 3.8E+00
4.03E+03 9.3E-01 1.2E+00 3.8E+00
3.56E+03 7.9E+00 1.2E+00 3.8E+00 10 325
3.44E+03 1.8E+00 1.2E+00 3.8E+00
3.16E+03 7.9E+00 1.2E+00 3.8E+00
3.01 E+03 5.9E-01 1.2E+00 3.8E+00
4.85E+02 1.7E+00 1.2E+00 3.8E+00
1.20E+02 1.1 E+00 1.2E+00 3.8E+00
3.91 E+02 7.2E+01 1.2E+00 3.8E+00
4.40E+03 2.0E+00 1.2E+00 3.8E+00
3.59E+03 1.4E+00 1.2E+00 3.8E+00
3.83E+03 1.2E+00 1.2E+00 3.8E+00 10 325
3.65E+03 6.8E-01 1.2E+00 3.8E+00
3.62E+03 1.3E+00 1.2E+00 3.8E+00
3.05E+03 5.5E+00 1.2E+00 3.8E+00
4.74E+02 7.9E+00 1.2E+00 3.8E+00
1.20E+02 4.6E+00 1.2E+00 3.8E+00
4.00E+02 1.7E+01 1.2E+00 3.8E+00
1.94E+00 1.3E+02 1.2E+00 3.8E+00
3.48E+00 4.7E+01 1.2E+00 3.8E+00
9.21 E+00 1.1E+01 1.2E+00 3.8E+00
2.71 E+00 1.1 E+02 1.2E+00 3.8E+00
6.00E-01 6.8E+02 1.2E+00 3.8E+00
1.25E+01 2.4E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.92E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.81E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.54E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-136
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFA-L06-1313-T01-A 1
Ni EaFA-L06-1313-T02-A 1
Ni EaFA-L06-1313-T03-A 1
Ni EaFA-L06-1313-T04-A 1
Ni EaFA-L06-1313-T05-A 1
Ni EaFA-L06-1313-T06-A 1
Ni EaFA-L06-1313-T07-A 1
Ni EaFA-L06-1313-T08-A 1
Ni EaFA-L06-1313-T09-A 1
Ni EaFA-L06-1313-T01-B 1
Ni EaFA-L06-1313-T02-B 1
Ni EaFA-L06-1313-T03-B 1
Ni EaFA-L06-1313-T04-B 1
Ni EaFA-L06-1313-T05-B 1
Ni EaFA-L06-1313-T06-B 1
Ni EaFA-L06-1313-T07-B 1
Ni EaFA-L06-1313-T08-B 1
Ni EaFA-L06-1313-T09-B 1
Ni EaFA-L06-1313-T01-C 1
Ni EaFA-L06-1313-T02-C 1
Ni EaFA-L06-1313-T03-C 1
Ni EaFA-L06-1313-T04-C 1
Ni EaFA-L06-1313-T05-C 1
Ni EaFA-L06-1313-T06-C 1
Ni EaFA-L06-1313-T07-C 1
Ni EaFA-L06-1313-T08-C 1
Ni EaFA-L06-1313-T09-C 1
Ni EaFA-L06-1313-B01-A 1
Ni EaFA-L06-1313-B02-A 1
Ni EaFA-L06-1313-B03-A 1
Ni EaFA-L06-1313-B01-B 1
Ni EaFA-L06-1313-B02-B 1
Ni EaFA-L06-1313-B03-B 1
Sample Internal
Cone. Qualifier Review
ug/L I
5.73E+00
9.00E-01 U1/2
6.00E+00
9.00E-01 U1/2
5.76E+00
1.58E+02
5.08E+02
5.28E+02
7.27E+02
4.37E+00 E
5.45E+00 E
4.17E+00 E
4.87E+00 E
1.84E+01
1.50E+02
6.18E+02
5.10E+02
7.14E+02
5.13E+00 E
9.00E-01 U1/2
3.46E+00 E
9.00E-01 U1/2
2.27E+01
1.41E+02
5.91 E+02
5.01 E+02
7.16E+02
9.00E-01 U1/2
9.00E-01 U1/2
2.59E+00 E
2.75E+00 E
9.00E-01 U1/2
3.24E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.73E+00 5.6E+01 1.8E+00 5.7E+00
9.00E-01 3.9E+02 1.8E+00 5.7E+00
6.00E+00 1.0E+02 1.8E+00 5.7E+00 10 325
9.00E-01 2.9E+01 1.8E+00 5.7E+00
5.76E+00 5.9E+01 1.8E+00 5.7E+00
1.58E+02 2.4E+00 1.8E+00 5.7E+00
5.08E+02 1.2E+00 1.8E+00 5.7E+00
5.28E+02 6.3E-01 1.8E+00 5.7E+00
7.27E+02 2.6E+00 1.8E+00 5.7E+00
4.37E+00 1.2E+02 1.8E+00 5.7E+00
5.45E+00 7.1E+01 1.8E+00 5.7E+00
4.17E+00 1.0E+02 1.8E+00 5.7E+00 10 325
4.87E+00 9.2E+01 1.8E+00 5.7E+00
1.84E+01 2.2E+01 1.8E+00 5.7E+00
1.50E+02 2.8E+00 1.8E+00 5.7E+00
6.18E+02 1.3E+00 1.8E+00 5.7E+00
5.10E+02 3.2E+00 1.8E+00 5.7E+00
7.14E+02 7.2E+01 1.8E+00 5.7E+00
5.13E+00 1.2E+02 1.8E+00 5.7E+00
9.00E-01 9.7E+01 1.8E+00 5.7E+00
3.46E+00 7.6E+01 1.8E+00 5.7E+00 10 325
9.00E-01 4.8E+02 1.8E+00 5.7E+00
2.27E+01 2.0E+01 1.8E+00 5.7E+00
1.41 E+02 4.8E+00 1.8E+00 5.7E+00
5.91 E+02 7.5E+00 1.8E+00 5.7E+00
5.01 E+02 2.7E+00 1.8E+00 5.7E+00
7.16E+02 1.1E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 5.2E+01 1.8E+00 5.7E+00
2.59E+00 1.7E+02 1.8E+00 5.7E+00
2.75E+00 7.5E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
3.24E+00 1.1 E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.18E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.26E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.16E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-137
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qu
1 1 ug/L
P EaFA-L06-1313-T01-A 1 2.30E+02
P EaFA-L06-1313-T02-A 1 8.23E+01
P EaFA-L06-1313-T03-A 1 8.83E+01
P EaFA-L06-1313-T04-A 1 1.92E+02
P EaFA-L06-1313-T05-A 1 1.13E+02
P EaFA-L06-1313-T06-A 1 7.16E+01
P EaFA-L06-1313-T07-A 1 6.83E+01
P EaFA-L06-1313-T08-A 1 8.93E+01
P EaFA-L06-1313-T09-A 1 3.01 E+03
P EaFA-L06-1313-T01-B 1 1.74E+02
P EaFA-L06-1313-T02-B 1 6.36E+01
P EaFA-L06-1313-T03-B 1 1.01E+02
P EaFA-L06-1313-T04-B 1 9.32E+01
P EaFA-L06-1313-T05-B 1 7.91E+01
P EaFA-L06-1313-T06-B 1 6.45E+01
P EaFA-L06-1313-T07-B 1 5.32E+01
P EaFA-L06-1313-T08-B 1 9.21E+01
P EaFA-L06-1313-T09-B 1 2.80E+03
P EaFA-L06-1313-T01-C 1 2.43E+02
P EaFA-L06-1313-T02-C 1 5.57E+01
P EaFA-L06-1313-T03-C 1 1.01E+02
P EaFA-L06-1313-T04-C 1 9.32E+01
P EaFA-L06-1313-T05-C 1 7.27E+01
P EaFA-L06-1313-T06-C 1 6.94E+01
P EaFA-L06-1313-T07-C 1 5.82E+01
P EaFA-L06-1313-T08-C 1 8.02E+01
P EaFA-L06-1313-T09-C 1 2.97E+03
P EaFA-L06-1313-B01-A 1 3.68E+01
P EaFA-L06-1313-B02-A 1 4.13E+01
P EaFA-L06-1313-B03-A 1 5.18E+01
P EaFA-L06-1313-B01-B 1 4.76E+01
P EaFA-L06-1313-B02-B 1 3.72E+01
P EaFA-L06-1313-B03-B 1 5.23E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.30E+02 7.1E+00 3.7E+00 1.2E+01
8.23E+01 4.4E+00 3.7E+00 1 .2E+01
8.83E+01 7.6E+00 3.7E+00 1 .2E+01 1000 100
1.92E+02 2.5E+00 3.7E+00 1 .2E+01
1.13E+02 4.4E+00 3.7E+00 1 .2E+01
7.16E+01 9.8E+00 3.7E+00 1 .2E+01
6.83E+01 5.2E+00 3.7E+00 1.2E+01
8.93E+01 1.7E+00 3.7E+00 1.2E+01
3.01 E+03 2.5E+00 3.7E+00 1.2E+01
1.74E+02 2.2E+01 3.7E+00 1.2E+01
6.36E+01 4.9E+00 3.7E+00 1.2E+01
1.01E+02 1.2E+01 3.7E+00 1.2E+01 1000 100
9.32E+01 6.9E+00 3.7E+00 1.2E+01
7.91 E+01 3.4E+00 3.7E+00 1.2E+01
6.45E+01 9.8E+00 3.7E+00 1.2E+01
5.32E+01 4.7E+00 3.7E+00 1.2E+01
9.21 E+01 8.4E+00 3.7E+00 1.2E+01
2.80E+03 7.1 E+01 3.7E+00 1.2E+01
2.43E+02 5.1E+00 3.7E+00 1.2E+01
5.57E+01 1.5E+01 3.7E+00 1.2E+01
1.01E+02 9.8E+00 3.7E+00 1.2E+01 1000 100
9.32E+01 7.7E-01 3.7E+00 1.2E+01
7.27E+01 9.1E+00 3.7E+00 1.2E+01
6.94E+01 1.2E+01 3.7E+00 1.2E+01
5.82E+01 1.2E+01 3.7E+00 1.2E+01
8.02E+01 7.7E+00 3.7E+00 1.2E+01
2.97E+03 1.3E+01 3.7E+00 1.2E+01
3.68E+01 6.4E+00 3.7E+00 1.2E+01
4.13E+01 1.3E+01 3.7E+00 1.2E+01
5.18E+01 1.3E+01 3.7E+00 1.2E+01
4.76E+01 7.1E+00 3.7E+00 1.2E+01
3.72E+01 2.7E+00 3.7E+00 1.2E+01
5.23E+01 2.0E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .05E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11 E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .08E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-138
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
1 ug/L
K EaFA-L06-1313-T01-A 1 6.37E+04
K EaFA-L06-1313-T02-A 1 3.76E+04
K EaFA-L06-1313-T03-A 1 2.82E+04
K EaFA-L06-1313-T04-A 1 2.75E+04
K EaFA-L06-1313-T05-A 1 2.62E+04
K EaFA-L06-1313-T06-A 1 2.69E+04
K EaFA-L06-1313-T07-A 1 2.12E+04
K EaFA-L06-1313-T08-A 1 1.86E+04
K EaFA-L06-1313-T09-A 1 2.23E+04
K EaFA-L06-1313-T01-B 1 5.90E+04
K EaFA-L06-1313-T02-B 1 3.92E+04
K EaFA-L06-1313-T03-B 1 2.64E+04
K EaFA-L06-1313-T04-B 1 2.55E+04
K EaFA-L06-1313-T05-B 1 2.41E+04
K EaFA-L06-1313-T06-B 1 2.64E+04
K EaFA-L06-1313-T07-B 1 2.80E+04
K EaFA-L06-1313-T08-B 1 1.94E+04
K EaFA-L06-1313-T09-B 1 2.26E+04
K EaFA-L06-1313-T01-C 1 6.20E+04
K EaFA-L06-1313-T02-C 1 3.51E+04
K EaFA-L06-1313-T03-C 1 2.84E+04
K EaFA-L06-1313-T04-C 1 2.70E+04
K EaFA-L06-1313-T05-C 1 2.75E+04
K EaFA-L06-1313-T06-C 1 2.78E+04
K EaFA-L06-1313-T07-C 1 2.67E+04
K EaFA-L06-1313-T08-C 1 1.91E+04
K EaFA-L06-1313-T09-C 1 2.25E+04
K EaFA-L06-1313-B01-A 1 2.74E+01
K EaFA-L06-1313-B02-A 1 1 .25E+01
K EaFA-L06-1313-B03-A 1 4.03E+02
K EaFA-L06-1313-B01-B 1 1 .38E+01
K EaFA-L06-1313-B02-B 1 1 .50E+01
K EaFA-L06-1313-B03-B 1 3.48E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.37E+04 7.9E+00 1.6E+00 5.1E+00
3.76E+04 8.6E-01 1.6E+00 5.1E+00
2.82E+04 5.5E-01 1.6E+00 5.1E+00 1000 100
2.75E+04 3.8E-01 1.6E+00 5.1E+00
2.62E+04 8.2E-01 1.6E+00 5.1E+00
2.69E+04 9.7E-01 1.6E+00 5.1E+00
2.12E+04 6.8E-01 1.6E+00 5.1E+00
1.86E+04 9.9E-01 1.6E+00 5.1E+00
2.23E+04 3.2E+00 1.6E+00 5.1E+00
5.90E+04 3.9E+01 1.6E+00 5.1E+00
3.92E+04 1.0E+00 1.6E+00 5.1E+00
2.64E+04 9.6E+00 1.6E+00 5.1E+00 1000 100
2.55E+04 2.3E+00 1.6E+00 5.1E+00
2.41 E+04 1.1E+01 1.6E+00 5.1E+00
2.64E+04 2.4E+00 1.6E+00 5.1E+00
2.80E+04 4.4E-01 1.6E+00 5.1E+00
1.94E+04 3.2E+00 1.6E+00 5.1E+00
2.26E+04 7.5E+01 1.6E+00 5.1E+00
6.20E+04 2.4E+00 1.6E+00 5.1E+00
3.51 E+04 5.4E-02 1.6E+00 5.1E+00
2.84E+04 7.3E-01 1.6E+00 5.1E+00 1000 100
2.70E+04 7.0E-01 1.6E+00 5.1E+00
2.75E+04 4.6E-01 1.6E+00 5.1E+00
2.78E+04 5.4E+00 1.6E+00 5.1E+00
2.67E+04 8.1E+00 1.6E+00 5.1E+00
1.91 E+04 2.7E+00 1.6E+00 5.1E+00
2.25E+04 1.3E+01 1.6E+00 5.1E+00
2.74E+01 5.7E+00 1.6E+00 5.1E+00
1.25E+01 1.2E+01 1.6E+00 5.1E+00
4.03E+02 8.1E+00 1.6E+00 5.1E+00
1.38E+01 2.1E+01 1.6E+00 5.1E+00
1.50E+01 1.2E+01 1.6E+00 5.1E+00
3.48E+02 8.3E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.91E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.73E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.92E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-139
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qu
1 1 ug/L
Se EaFA-L06-1313-T01-A 1 7.68E+03
Se EaFA-L06-1313-T02-A 1 6.07E+03
Se EaFA-L06-1313-T03-A 1 5.01E+03
Se EaFA-L06-1313-T04-A 1 4.23E+03
Se EaFA-L06-1313-T05-A 1 2.76E+03
Se EaFA-L06-1313-T06-A 1 9.36E+02
Se EaFA-L06-1313-T07-A 1 1.35E+02
Se EaFA-L06-1313-T08-A 1 6.99E+01
Se EaFA-L06-1313-T09-A 1 8.22E+02
Se EaFA-L06-1313-T01-B 1 7.18E+03
Se EaFA-L06-1313-T02-B 1 6.40E+03
Se EaFA-L06-1313-T03-B 1 4.49E+03
Se EaFA-L06-1313-T04-B 1 2.59E+03
Se EaFA-L06-1313-T05-B 1 1.45E+03
Se EaFA-L06-1313-T06-B 1 8.54E+02
Se EaFA-L06-1313-T07-B 1 2.76E+02
Se EaFA-L06-1313-T08-B 1 9.81E+01
Se EaFA-L06-1313-T09-B 1 7.27E+02
Se EaFA-L06-1313-T01-C 1 7.40E+03
Se EaFA-L06-1313-T02-C 1 5.71E+03
Se EaFA-L06-1313-T03-C 1 4.82E+03
Se EaFA-L06-1313-T04-C 1 2.85E+03
Se EaFA-L06-1313-T05-C 1 1 .60E+03
Se EaFA-L06-1313-T06-C 1 8.61E+02
Se EaFA-L06-1313-T07-C 1 2.75E+02
Se EaFA-L06-1313-T08-C 1 1 .OOE+02
Se EaFA-L06-1313-T09-C 1 7.68E+02
Se EaFA-L06-1313-B01-A 1 1 .69E+01 E
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
7.68E+03 8.3E+00 1.5E+01 4.8E+01
6.07E+03 1.2E+00 1.5E+01 4.8E+01
5.01 E+03 8.9E-01 1.5E+01 4.8E+01 10 325
4.23E+03 2.7E-01 1.5E+01 4.8E+01
2.76E+03 1.9E+00 1.5E+01 4.8E+01
9.36E+02 2.6E+00 1.5E+01 4.8E+01
1.35E+02 1.3E+01 1.5E+01 4.8E+01
6.99E+01 2.1E+01 1.5E+01 4.8E+01
8.22E+02 3.0E+00 1.5E+01 4.8E+01
7.18E+03 3.5E+01 1.5E+01 4.8E+01
6.40E+03 1.1E+00 1.5E+01 4.8E+01
4.49E+03 9.3E+00 1.5E+01 4.8E+01 10 325
2.59E+03 3.6E+00 1.5E+01 4.8E+01
1.45E+03 1.0E+01 1.5E+01 4.8E+01
8.54E+02 4.9E+00 1.5E+01 4.8E+01
2.76E+02 5.6E+00 1.5E+01 4.8E+01
9.81E+01 2.4E+01 1 .5E+01 4.8E+01
7.27E+02 7.3E+01 1 .5E+01 4.8E+01
7.40E+03 4.1E+00 1 .5E+01 4.8E+01
5.71 E+03 9.8E-01 1 .5E+01 4.8E+01
4.82E+03 4.2E-01 1 .5E+01 4.8E+01 10 325
2.85E+03 2.3E+00 1 .5E+01 4.8E+01
1.60E+03 2.2E+00 1 .5E+01 4.8E+01
8.61 E+02 3.2E+00 1 .5E+01 4.8E+01
2.75E+02 7.9E+00 1 .5E+01 4.8E+01
1. OOE+02 1.4E+01 1.5E+01 4.8E+01
7.68E+02 1.3E+01 1 .5E+01 4.8E+01
1.69E+01 1.8E+02 1 .5E+01 4.8E+01
Se EaFA-L06-1313-B02-A 1 7.50E+00 U1/2 7.50E+00 3.8E+01 1 .5E+01 4.8E+01
Se EaFA-L06-1313-B03-A 1 1 .68E+01 E
Se EaFA-L06-1313-B01-B 1 1.61E+01 E
1.68E+01 8.0E+01 1.5E+01 4.8E+01
1.61E+01 6.9E+01 1.5E+01 4.8E+01
Se EaFA-L06-1313-B02-B 1 7.50E+00 U1/2 7.50E+00 7.7E+02 1.5E+01 4.8E+01
Se EaFA-L06-1313-B03-B 1 7.50E+00 U1/2 7.50E+00 2.3E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.75E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.68E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.60E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-140
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si EaFA-L06-1313-T01-A 1
Si EaFA-L06-1313-T02-A 1
Si EaFA-L06-1313-T03-A 1
Si EaFA-L06-1313-T04-A 1
Si EaFA-L06-1313-T05-A 1
Si EaFA-L06-1313-T06-A 1
Si EaFA-L06-1313-T07-A 1
Si EaFA-L06-1313-T08-A 1
Si EaFA-L06-1313-T09-A 1
Si EaFA-L06-1313-T01-B 1
Si EaFA-L06-1313-T02-B 1
Si EaFA-L06-1313-T03-B 1
Si EaFA-L06-1313-T04-B 1
Si EaFA-L06-1313-T05-B 1
Si EaFA-L06-1313-T06-B 1
Si EaFA-L06-1313-T07-B 1
Si EaFA-L06-1313-T08-B 1
Si EaFA-L06-1313-T09-B 1
Si EaFA-L06-1313-T01-C 1
Si EaFA-L06-1313-T02-C 1
Si EaFA-L06-1313-T03-C 1
Si EaFA-L06-1313-T04-C 1
Si EaFA-L06-1313-T05-C 1
Si EaFA-L06-1313-T06-C 1
Si EaFA-L06-1313-T07-C 1
Si EaFA-L06-1313-T08-C 1
Si EaFA-L06-1313-T09-C 1
Si EaFA-L06-1313-B01-A 1
Si EaFA-L06-1313-B02-A 1
Si EaFA-L06-1313-B03-A 1
Si EaFA-L06-1313-B01-B 1
Si EaFA-L06-1313-B02-B 1
Si EaFA-L06-1313-B03-B 1
Sample I
Cone. Qualifier
ug/L I
2.21E+04
4.52E+03
1.68E+03
3.99E+02
5.67E+02
2.58E+03
1.29E+04
3.66E+04
6.80E+04
1.95E+04
5.13E+03
3.58E+02
3.60E+02
7.86E+02
2.41 E+03
6.47E+03
1.81E+04
6.73E+04
2.31 E+04
4.71 E+03
3.78E+02
3.66E+02
9.18E+02
2.14E+03
6.64E+03
1.85E+04
6.70E+04
5.50E-01 U1/2
5.50E-01 U1/2
3.93E+02
5.50E-01 U1/2
5.50E-01 U1/2
2.43E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.21 E+04 7.7E+00 1.1E+00 3.5E+00
4.52E+03 8.3E-01 1.1E+00 3.5E+00
1.68E+03 1.8E-01 1.1E+00 3.5E+00 1000 100
3.99E+02 6.0E-01 1.1E+00 3.5E+00
5.67E+02 4.1E-01 1.1E+00 3.5E+00
2.58E+03 2.7E-01 1.1E+00 3.5E+00
1.29E+04 6.5E-01 1.1E+00 3.5E+00
3.66E+04 5.2E-01 1.1E+00 3.5E+00
6.80E+04 2.8E+00 1.1E+00 3.5E+00
1.95E+04 2.7E+01 1.1E+00 3.5E+00
5.13E+03 5.0E-01 1.1E+00 3.5E+00
3.58E+02 9.0E+00 1.1E+00 3.5E+00 1000 100
3.60E+02 2.1E+00 1.1E+00 3.5E+00
7.86E+02 1.0E+01 1.1E+00 3.5E+00
2.41 E+03 1.3E+00 1.1E+00 3.5E+00
6.47E+03 6.3E-01 1.1E+00 3.5E+00
1.81E+04 2.9E+00 1.1E+00 3.5E+00
6.73E+04 4.5E+01 1.1E+00 3.5E+00
2.31 E+04 3.0E+00 1.1E+00 3.5E+00
4.71 E+03 1.2E+00 1.1E+00 3.5E+00
3.78E+02 6.6E-01 1.1E+00 3.5E+00 1000 100
3.66E+02 9.7E-01 1.1E+00 3.5E+00
9.18E+02 9.9E-01 1.1E+00 3.5E+00
2.14E+03 4.9E+00 1.1E+00 3.5E+00
6.64E+03 7.8E+00 1.1E+00 3.5E+00
1.85E+04 2.7E+00 1.1E+00 3.5E+00
6.70E+04 2.6E+01 1.1E+00 3.5E+00
5.50E-01 1.9E+01 1.1E+00 3.5E+00
5.50E-01 2.2E+01 1.1E+00 3.5E+00
3.93E+02 1.4E+01 1.1E+00 3.5E+00
5.50E-01 1.7E+01 1.1E+00 3.5E+00
5.50E-01 3.3E+01 1.1E+00 3.5E+00
2.43E+02 8.3E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.57E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.41E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .34E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-141
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFA-L06-1313-T01-A 1
Na EaFA-L06-1313-T02-A 1
Na EaFA-L06-1313-T03-A 1
Na EaFA-L06-1313-T04-A 1
Na EaFA-L06-1313-T05-A 1
Na EaFA-L06-1313-T06-A 1
Na EaFA-L06-1313-T07-A 1
Na EaFA-L06-1313-T08-A 1
Na EaFA-L06-1313-T09-A 1
Na EaFA-L06-1313-T01-B 1
Na EaFA-L06-1313-T02-B 1
Na EaFA-L06-1313-T03-B 1
Na EaFA-L06-1313-T04-B 1
Na EaFA-L06-1313-T05-B 1
Na EaFA-L06-1313-T06-B 1
Na EaFA-L06-1313-T07-B 1
Na EaFA-L06-1313-T08-B 1
Na EaFA-L06-1313-T09-B 1
Na EaFA-L06-1313-T01-C 1
Na EaFA-L06-1313-T02-C 1
Na EaFA-L06-1313-T03-C 1
Na EaFA-L06-1313-T04-C 1
Na EaFA-L06-1313-T05-C 1
Na EaFA-L06-1313-T06-C 1
Na EaFA-L06-1313-T07-C 1
Na EaFA-L06-1313-T08-C 1
Na EaFA-L06-1313-T09-C 1
Na EaFA-L06-1313-B01-A 1
Na EaFA-L06-1313-B02-A 1
Na EaFA-L06-1313-B03-A 1
Na EaFA-L06-1313-B01-B 1
Na EaFA-L06-1313-B02-B 1
Na EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
3.17E+05
1.58E+05
5.75E+04
3.72E+04
2.24E+04
5.37E+03
4.13E+03
3.34E+03
2.96E+03
2.52E+05
1.66E+05
4.12E+04
2.40E+04
1.34E+04
5.26E+03
5.41 E+03
3.64E+03
3.07E+03
3.26E+05
1.50E+05
4.45E+04
2.60E+04
1.51E+04
5.53E+03
5.31 E+03
3.54E+03
3.10E+03
2.30E+01
2.28E+01
3.22E+05
2.13E+01
2.16E+01
3.09E+05
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.17E+05 5.2E+00 2.5E+00 8.0E+00
1.58E+05 8.5E-01 2.5E+00 8.0E+00
5.75E+04 2.5E-01 2.5E+00 8.0E+00 1000 100
3.72E+04 1.6E+00 2.5E+00 8.0E+00
2.24E+04 5.7E-01 2.5E+00 8.0E+00
5.37E+03 5.7E-01 2.5E+00 8.0E+00
4.13E+03 1.5E+00 2.5E+00 8.0E+00
3.34E+03 4.1E-01 2.5E+00 8.0E+00
2.96E+03 2.9E+00 2.5E+00 8.0E+00
2.52E+05 1.9E+01 2.5E+00 8.0E+00
1.66E+05 5.0E-01 2.5E+00 8.0E+00
4.12E+04 7.6E+00 2.5E+00 8.0E+00 1000 100
2.40E+04 3.5E+00 2.5E+00 8.0E+00
1.34E+04 1.0E+01 2.5E+00 8.0E+00
5.26E+03 2.1E+00 2.5E+00 8.0E+00
5.41 E+03 6.0E-01 2.5E+00 8.0E+00
3.64E+03 4.1E+00 2.5E+00 8.0E+00
3.07E+03 7.5E+01 2.5E+00 8.0E+00
3.26E+05 3.1E+00 2.5E+00 8.0E+00
1.50E+05 4.4E-01 2.5E+00 8.0E+00
4.45E+04 1.0E+00 2.5E+00 8.0E+00 1000 100
2.60E+04 6.8E-01 2.5E+00 8.0E+00
1.51E+04 4.4E-01 2.5E+00 8.0E+00
5.53E+03 5.0E+00 2.5E+00 8.0E+00
5.31 E+03 8.1E+00 2.5E+00 8.0E+00
3.54E+03 2.4E+00 2.5E+00 8.0E+00
3.10E+03 1.4E+01 2.5E+00 8.0E+00
2.30E+01 7.0E-01 2.5E+00 8.0E+00
2.28E+01 4.2E+00 2.5E+00 8.0E+00
3.22E+05 8.1E+00 2.5E+00 8.0E+00
2.13E+01 1.5E+00 2.5E+00 8.0E+00
2.16E+01 2.6E+00 2.5E+00 8.0E+00
3.09E+05 6.6E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.84E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.20E+04 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.53E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-142
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
EaFA-L06-1313-T01-A 1
EaFA-L06-1313-T02-A 1
EaFA-L06-1313-T03-A 1
EaFA-L06-1313-T04-A 1
EaFA-L06-1313-T05-A 1
EaFA-L06-1313-T06-A 1
EaFA-L06-1313-T07-A 1
EaFA-L06-1313-T08-A 1
EaFA-L06-1313-T09-A 1
EaFA-L06-1313-T01-B 1
EaFA-L06-1313-T02-B 1
EaFA-L06-1313-T03-B 1
EaFA-L06-1313-T04-B 1
EaFA-L06-1313-T05-B 1
EaFA-L06-1313-T06-B 1
EaFA-L06-1313-T07-B 1
EaFA-L06-1313-T08-B 1
EaFA-L06-1313-T09-B 1
EaFA-L06-1313-T01-C 1
EaFA-L06-1313-T02-C 1
EaFA-L06-1313-T03-C 1
EaFA-L06-1313-T04-C 1
EaFA-L06-1313-T05-C 1
EaFA-L06-1313-T06-C 1
EaFA-L06-1313-T07-C 1
EaFA-L06-1313-T08-C 1
EaFA-L06-1313-T09-C 1
EaFA-L06-1313-B01-A 1
EaFA-L06-1313-B02-A 1
EaFA-L06-1313-B03-A 1
EaFA-L06-1313-B01-B 1
EaFA-L06-1313-B02-B 1
EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
1.44E+03
1.57E+03
1.76E+03
1.86E+03
1.91E+03
2.25E+03
2.60E+03
3.88E+03
5.28E+03
1.22E+03
1.65E+03
1.82E+03
1.98E+03
1.95E+03
2.30E+03
2.85E+03
2.94E+03
5.18E+03
1 .56E+03
1 .45E+03
1 .97E+03
2.04E+03
2.21E+03
2.43E+03
2.67E+03
2.90E+03
5.26E+03
5.00E-01 U1/2
5.00E-01 U1/2
2.13E+00 E
5.00E-01 U1/2
5.00E-01 U1/2
1.81E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.44E+03 7.9E+00 1.0E+00 3.2E+00
1.57E+03 1.9E-01 1.0E+00 3.2E+00
1.76E+03 6.5E-01 1.0E+00 3.2E+00 1000 100
1.86E+03 7.2E-01 1.0E+00 3.2E+00
1.91E+03 5.7E-01 1.0E+00 3.2E+00
2.25E+03 7.5E-01 1.0E+00 3.2E+00
2.60E+03 1.2E+00 1.0E+00 3.2E+00
3.88E+03 1.3E+00 1.0E+00 3.2E+00
5.28E+03 2.5E+00 1.0E+00 3.2E+00
1.22E+03 1.8E+01 1.0E+00 3.2E+00
1.65E+03 7.5E-01 1.0E+00 3.2E+00
1.82E+03 7.9E+00 1.0E+00 3.2E+00 1000 100
1.98E+03 1.6E+00 1.0E+00 3.2E+00
1.95E+03 7.7E+00 1.0E+00 3.2E+00
2.30E+03 1.4E+00 1.0E+00 3.2E+00
2.85E+03 1.4E+00 1.0E+00 3.2E+00
2.94E+03 9.6E-01 1.0E+00 3.2E+00
5.18E+03 3.0E+01 1.0E+00 3.2E+00
1.56E+03 2.5E+00 1.0E+00 3.2E+00
1.45E+03 9.5E-01 1.0E+00 3.2E+00
1.97E+03 1.2E+00 1.0E+00 3.2E+00 1000 100
2.04E+03 2.3E-01 1.0E+00 3.2E+00
2.21E+03 9.0E-01 1.0E+00 3.2E+00
2.43E+03 5.4E+00 1.0E+00 3.2E+00
2.67E+03 6.2E+00 1.0E+00 3.2E+00
2.90E+03 2.3E+00 1.0E+00 3.2E+00
5.26E+03 5.2E+01 1.0E+00 3.2E+00
5.00E-01 2.1E+02 1.0E+00 3.2E+00
5.00E-01 2.3E+01 1.0E+00 3.2E+00
2.13E+00 4.1E+01 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
5.00E-01 4.1E+02 1.0E+00 3.2E+00
1.81E+00 1.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.64E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.79E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.84E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-143
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S EaFA-L06-1313-T01-A 1
S EaFA-L06-1313-T02-A 1
S EaFA-L06-1313-T03-A 1
S EaFA-L06-1313-T04-A 1
S EaFA-L06-1313-T05-A 1
S EaFA-L06-1313-T06-A 1
S EaFA-L06-1313-T07-A 1
S EaFA-L06-1313-T08-A 1
S EaFA-L06-1313-T09-A 1
S EaFA-L06-1313-T01-B 1
S EaFA-L06-1313-T02-B 1
S EaFA-L06-1313-T03-B 1
S EaFA-L06-1313-T04-B 1
S EaFA-L06-1313-T05-B 1
S EaFA-L06-1313-T06-B 1
S EaFA-L06-1313-T07-B 1
S EaFA-L06-1313-T08-B 1
S EaFA-L06-1313-T09-B 1
S EaFA-L06-1313-T01-C 1
S EaFA-L06-1313-T02-C 1
S EaFA-L06-1313-T03-C 1
S EaFA-L06-1313-T04-C 1
S EaFA-L06-1313-T05-C 1
S EaFA-L06-1313-T06-C 1
S EaFA-L06-1313-T07-C 1
S EaFA-L06-1313-T08-C 1
S EaFA-L06-1313-T09-C 1
S EaFA-L06-1313-B01-A 1
S EaFA-L06-1313-B02-A 1
S EaFA-L06-1313-B03-A 1
S EaFA-L06-1313-B01-B 1
S EaFA-L06-1313-B02-B 1
S EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
1.87E+05
1.81E+05
1.70E+05
1.75E+05
1.71E+05
1.72E+05
1.14E+05
9.30E+04
6.22E+04
1.73E+05
1.85E+05
1.65E+05
1.62E+05
1.58E+05
1.70E+05
1.62E+05
1.05E+05
6.14E+04
1.86E+05
1.67E+05
1.78E+05
1.73E+05
1.80E+05
1.79E+05
1.57E+05
1.04E+05
6.24E+04
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.87E+05 8.1E+00 6.8E+00 2.2E+01
1.81E+05 6.3E-01 6.8E+00 2.2E+01
1.70E+05 5.9E-01 6.8E+00 2.2E+01 1000 100
1.75E+05 3.8E-01 6.8E+00 2.2E+01
1.71E+05 1.2E-01 6.8E+00 2.2E+01
1.72E+05 5.8E-01 6.8E+00 2.2E+01
1.14E+05 7.7E-01 6.8E+00 2.2E+01
9.30E+04 9.1E-01 6.8E+00 2.2E+01
6.22E+04 2.8E+00 6.8E+00 2.2E+01
1.73E+05 3.5E+01 6.8E+00 2.2E+01
1.85E+05 3.1E-01 6.8E+00 2.2E+01
1.65E+05 8.6E+00 6.8E+00 2.2E+01 1000 100
1.62E+05 2.7E+00 6.8E+00 2.2E+01
1.58E+05 9.5E+00 6.8E+00 2.2E+01
1.70E+05 2.2E+00 6.8E+00 2.2E+01
1.62E+05 6.9E-01 6.8E+00 2.2E+01
1.05E+05 3.0E+00 6.8E+00 2.2E+01
6.14E+04 7.3E+01 6.8E+00 2.2E+01
1.86E+05 3.0E+00 6.8E+00 2.2E+01
1.67E+05 7.5E-01 6.8E+00 2.2E+01
1.78E+05 3.0E-01 6.8E+00 2.2E+01 1000 100
1.73E+05 1.0E+00 6.8E+00 2.2E+01
1.80E+05 6.4E-01 6.8E+00 2.2E+01
1.79E+05 5.2E+00 6.8E+00 2.2E+01
1.57E+05 7.4E+00 6.8E+00 2.2E+01
1.04E+05 2.6E+00 6.8E+00 2.2E+01
6.24E+04 1.4E+01 6.8E+00 2.2E+01
3.40E+00 1.2E+01 6.8E+00 2.2E+01
3.40E+00 8.7E+00 6.8E+00 2.2E+01
3.40E+00 6.3E+00 6.8E+00 2.2E+01
3.40E+00 1.5E+01 6.8E+00 2.2E+01
3.40E+00 8.8E+00 6.8E+00 2.2E+01
3.40E+00 3.2E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .71 E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .66E+05 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 J9E+05 81 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-144
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-L06-1313-T01-A 1
Tl EaFA-L06-1313-T02-A 1
Tl EaFA-L06-1313-T03-A 1
Tl EaFA-L06-1313-T04-A 1
Tl EaFA-L06-1313-T05-A 1
Tl EaFA-L06-1313-T06-A 1
Tl EaFA-L06-1313-T07-A 1
Tl EaFA-L06-1313-T08-A 1
Tl EaFA-L06-1313-T09-A 1
Tl EaFA-L06-1313-T01-B 1
Tl EaFA-L06-1313-T02-B 1
Tl EaFA-L06-1313-T03-B 1
Tl EaFA-L06-1313-T04-B 1
Tl EaFA-L06-1313-T05-B 1
Tl EaFA-L06-1313-T06-B 1
Tl EaFA-L06-1313-T07-B 1
Tl EaFA-L06-1313-T08-B 1
Tl EaFA-L06-1313-T09-B 1
Tl EaFA-L06-1313-T01-C 1
Tl EaFA-L06-1313-T02-C 1
Tl EaFA-L06-1313-T03-C 1
Tl EaFA-L06-1313-T04-C 1
Tl EaFA-L06-1313-T05-C 1
Tl EaFA-L06-1313-T06-C 1
Tl EaFA-L06-1313-T07-C 1
Tl EaFA-L06-1313-T08-C 1
Tl EaFA-L06-1313-T09-C 1
Tl EaFA-L06-1313-B01-A 1
Tl EaFA-L06-1313-B02-A 1
Tl EaFA-L06-1313-B03-A 1
Tl EaFA-L06-1313-B01-B 1
Tl EaFA-L06-1313-B02-B 1
Tl EaFA-L06-1313-B03-B 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.37E+00 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
4.74E+01
4.79E+01
7.56E+01
9.86E+00 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
1.27E+01 E
4.25E+01
5.08E+01
7.10E+01
1.24E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
3.44E+01
4.96E+01
7.36E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.37E+00 8.2E+00 4.6E+00 1 .5E+01
2.30E+00 1.9E+02 4.6E+00 1 .5E+01
2.30E+00 2.5E+02 4.6E+00 1 .5E+01 10 325
2.30E+00 7.9E+01 4.6E+00 1 .5E+01
2.30E+00 1.8E+02 4.6E+00 1 .5E+01
2.30E+00 2.0E+02 4.6E+00 1 .5E+01
4.74E+01 3.5E+00 4.6E+00 1 .5E+01
4.79E+01 1.4E+01 4.6E+00 1 .5E+01
7.56E+01 1.2E+01 4.6E+00 1 .5E+01
9.86E+00 2.2E+03 4.6E+00 1.5E+01
2.30E+00 9.5E+01 4.6E+00 1.5E+01
2.30E+00 2.9E+01 4.6E+00 1.5E+01 10 325
2.30E+00 3.5E+01 4.6E+00 1.5E+01
2.30E+00 5.3E+02 4.6E+00 1.5E+01
1.27E+01 4.2E+01 4.6E+00 1.5E+01
4.25E+01 1.6E+01 4.6E+00 1.5E+01
5.08E+01 1.1E+01 4.6E+00 1.5E+01
7.10E+01 1.3E+02 4.6E+00 1.5E+01
1.24E+01 6.4E+01 4.6E+00 1.5E+01
2.30E+00 5.2E+01 4.6E+00 1.5E+01
2.30E+00 7.2E+01 4.6E+00 1.5E+01 10 325
2.30E+00 7.6E+02 4.6E+00 1.5E+01
2.30E+00 3.0E+02 4.6E+00 1.5E+01
2.30E+00 4.7E+01 4.6E+00 1 .5E+01
3.44E+01 3.0E+01 4.6E+00 1 .5E+01
4.96E+01 2.0E+01 4.6E+00 1 .5E+01
7.36E+01 1.4E+01 4.6E+00 1 .5E+01
2.30E+00 1.8E+02 4.6E+00 1 .5E+01
2.30E+00 2.4E+01 4.6E+00 1 .5E+01
2.30E+00 3.8E+02 4.6E+00 1 .5E+01
2.30E+00 3.6E+02 4.6E+00 1.5E+01
2.30E+00 6.3E+01 4.6E+00 1.5E+01
2.30E+00 1.3E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.08E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.21E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.10E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-145
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L06-1313-T01-A 1
Ti EaFA-L06-1313-T02-A 1
Ti EaFA-L06-1313-T03-A 1
Ti EaFA-L06-1313-T04-A 1
Ti EaFA-L06-1313-T05-A 1
Ti EaFA-L06-1313-T06-A 1
Ti EaFA-L06-1313-T07-A 1
Ti EaFA-L06-1313-T08-A 1
Ti EaFA-L06-1313-T09-A 1
Ti EaFA-L06-1313-T01-B 1
Ti EaFA-L06-1313-T02-B 1
Ti EaFA-L06-1313-T03-B 1
Ti EaFA-L06-1313-T04-B 1
Ti EaFA-L06-1313-T05-B 1
Ti EaFA-L06-1313-T06-B 1
Ti EaFA-L06-1313-T07-B 1
Ti EaFA-L06-1313-T08-B 1
Ti EaFA-L06-1313-T09-B 1
Ti EaFA-L06-1313-T01-C 1
Ti EaFA-L06-1313-T02-C 1
Ti EaFA-L06-1313-T03-C 1
Ti EaFA-L06-1313-T04-C 1
Ti EaFA-L06-1313-T05-C 1
Ti EaFA-L06-1313-T06-C 1
Ti EaFA-L06-1313-T07-C 1
Ti EaFA-L06-1313-T08-C 1
Ti EaFA-L06-1313-T09-C 1
Ti EaFA-L06-1313-B01-A 1
Ti EaFA-L06-1313-B02-A 1
Ti EaFA-L06-1313-B03-A 1
Ti EaFA-L06-1313-B01-B 1
Ti EaFA-L06-1313-B02-B 1
Ti EaFA-L06-1313-B03-B 1
Sample Inter
Cone. Qualifier Revi
ug/L
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.71 E+00
2.66E+01
4.64E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.29E+01
4.29E+03
2.13E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.23E+01
4.59E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 7.2E+01 2.0E+00 6.4E+00
1.00E+00 7.2E+02 2.0E+00 6.4E+00
1.00E+00 7.4E+02 2.0E+00 6.4E+00 10 325
1.00E+00 9.8E+01 2.0E+00 6.4E+00
1.00E+00 4.5E+02 2.0E+00 6.4E+00
1.00E+00 4.3E+02 2.0E+00 6.4E+00
6.71 E+00 9.9E+00 2.0E+00 6.4E+00
2.66E+01 2.9E+00 2.0E+00 6.4E+00
4.64E+03 2.5E+00 2.0E+00 6.4E+00
1.00E+00 7.7E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+03 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00 10 325
1.00E+00 3.4E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.29E+01 4.9E+00 2.0E+00 6.4E+00
4.29E+03 6.8E+01 2.0E+00 6.4E+00
2.13E+00 4.2E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 6.0E+02 2.0E+00 6.4E+00 10 325
1.00E+00 9.4E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+02 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 9.1E+02 2.0E+00 6.4E+00
1.23E+01 1.0E+00 2.0E+00 6.4E+00
4.59E+03 3.8E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 3.9E+02 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.17E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.27E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.12E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-146
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFA-L06-1313-T01-A 1
V EaFA-L06-1313-T02-A 1
V EaFA-L06-1313-T03-A 1
V EaFA-L06-1313-T04-A 1
V EaFA-L06-1313-T05-A 1
V EaFA-L06-1313-T06-A 1
V EaFA-L06-1313-T07-A 1
V EaFA-L06-1313-T08-A 1
V EaFA-L06-1313-T09-A 1
V EaFA-L06-1313-T01-B 1
V EaFA-L06-1313-T02-B 1
V EaFA-L06-1313-T03-B 1
V EaFA-L06-1313-T04-B 1
V EaFA-L06-1313-T05-B 1
V EaFA-L06-1313-T06-B 1
V EaFA-L06-1313-T07-B 1
V EaFA-L06-1313-T08-B 1
V EaFA-L06-1313-T09-B 1
V EaFA-L06-1313-T01-C 1
V EaFA-L06-1313-T02-C 1
V EaFA-L06-1313-T03-C 1
V EaFA-L06-1313-T04-C 1
V EaFA-L06-1313-T05-C 1
V EaFA-L06-1313-T06-C 1
V EaFA-L06-1313-T07-C 1
V EaFA-L06-1313-T08-C 1
V EaFA-L06-1313-T09-C 1
V EaFA-L06-1313-B01-A 1
V EaFA-L06-1313-B02-A 1
V EaFA-L06-1313-B03-A 1
V EaFA-L06-1313-B01-B 1
V EaFA-L06-1313-B02-B 1
V EaFA-L06-1313-B03-B 1
Sample
Cone. Qualifier
ug/L
5.36E+03
2.82E+03
3.00E+03
1.28E+03
5.04E+02
1.94E+02
8.96E+01
1.14E+02
5.97E+03
5.58E+03
3.02E+03
1.23E+03
3.84E+02
2.15E+02
1.65E+02
8.42E+01
8.56E+01
5.93E+03
6.02E+03
2.72E+03
1.29E+03
4.31 E+02
2.42E+02
1.51 E+02
8.75E+01
8.84E+01
5.93E+03
7.50E-01 U1/2
7.50E-01 U1/2
3.38E+00 E
7.50E-01 U1/2
7.50E-01 U1/2
2.05E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.36E+03 8.5E+00 1.5E+00 4.8E+00
2.82E+03 4.9E-01 1.5E+00 4.8E+00
3.00E+03 1.9E-01 1.5E+00 4.8E+00 10 325
1.28E+03 6.0E-01 1.5E+00 4.8E+00
5.04E+02 6.2E-01 1.5E+00 4.8E+00
1.94E+02 6.3E-01 1.5E+00 4.8E+00
8.96E+01 4.7E-01 1.5E+00 4.8E+00
1.14E+02 8.3E-01 1.5E+00 4.8E+00
5.97E+03 2.8E+00 1.5E+00 4.8E+00
5.58E+03 2.0E+01 1.5E+00 4.8E+00
3.02E+03 4.4E-01 1.5E+00 4.8E+00
1.23E+03 7.8E+00 1.5E+00 4.8E+00 10 325
3.84E+02 3.0E+00 1.5E+00 4.8E+00
2.15E+02 8.0E+00 1.5E+00 4.8E+00
1.65E+02 1.8E+00 1.5E+00 4.8E+00
8.42E+01 2.7E+00 1.5E+00 4.8E+00
8.56E+01 4.7E+00 1.5E+00 4.8E+00
5.93E+03 7.2E+01 1.5E+00 4.8E+00
6.02E+03 2.4E+00 1.5E+00 4.8E+00
2.72E+03 8.7E-01 1.5E+00 4.8E+00
1.29E+03 1.7E+00 1.5E+00 4.8E+00 10 325
4.31 E+02 1.6E+00 1.5E+00 4.8E+00
2.42E+02 2.0E+00 1.5E+00 4.8E+00
1.51 E+02 7.4E+00 1.5E+00 4.8E+00
8.75E+01 5.1E+00 1.5E+00 4.8E+00
8.84E+01 3.1E+00 1.5E+00 4.8E+00
5.93E+03 2.6E+01 1.5E+00 4.8E+00
7.50E-01 2.2E+02 1.5E+00 4.8E+00
7.50E-01 2.1 E+02 1.5E+00 4.8E+00
3.38E+00 5.1E+01 1.5E+00 4.8E+00
7.50E-01 1.3E+02 1.5E+00 4.8E+00
7.50E-01 4.7E+02 1.5E+00 4.8E+00
2.05E+00 1.3E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.00E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.51E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.32E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-147
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone.
1 1 ug/L
Zn EaFA-L06-1313-T01-A 1 2.50E+02
Zn EaFA-L06-1313-T02-A 1 1.84E+01
Zn EaFA-L06-1313-T03-A 1 5.40E+00
Zn EaFA-L06-1313-T04-A 1 8.08E+00
Zn EaFA-L06-1313-T05-A 1 1.33E+01
Zn EaFA-L06-1313-T06-A 1 2.81 E+01
Zn EaFA-L06-1313-T07-A 1 1.17E+03
Zn EaFA-L06-1313-T08-A 1 1.21E+03
Zn EaFA-L06-1313-T09-A 1 1.59E+03
Zn EaFA-L06-1313-T01-B 1 2.43E+02
Zn EaFA-L06-1313-T02-B 1 4.57E+01
Zn EaFA-L06-1313-T03-B 1 4.64E+00
Zn EaFA-L06-1313-T04-B 1 5.85E+00
Zn EaFA-L06-1313-T05-B 1 8.25E+00
Zn EaFA-L06-1313-T06-B 1 3.06E+01
Zn EaFA-L06-1313-T07-B 1 1.25E+03
Zn EaFA-L06-1313-T08-B 1 1.16E+03
Zn EaFA-L06-1313-T09-B 1 1 .53E+03
Zn EaFA-L06-1313-T01-C 1 2.50E+02
Zn EaFA-L06-1313-T02-C 1 1 .87E+01
Zn EaFA-L06-1313-T03-C 1 7.78E+00
Zn EaFA-L06-1313-T04-C 1 5.10E+00
Zn EaFA-L06-1313-T05-C 1 9.53E+00
Zn EaFA-L06-1313-T06-C 1 2.25E+01
Zn EaFA-L06-1313-T07-C 1 1.19E+03
Zn EaFA-L06-1313-T08-C 1 1.15E+03
Zn EaFA-L06-1313-T09-C 1 1 .54E+03
Zn EaFA-L06-1313-B01-A 1 6.98E+00
Zn EaFA-L06-1313-B02-A 1 1.10E+01
Zn EaFA-L06-1313-B03-A 1 1 .27E+01
Zn EaFA-L06-1313-B01-B 1 9.92E+00
Zn EaFA-L06-1313-B02-B 1 1 .09E+01
Zn EaFA-L06-1313-B03-B 1 1 .84E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.50E+02 6.9E+00 1.0E+00 3.2E+00
1.84E+01 2.3E+00 1.0E+00 3.2E+00
5.40E+00 1.1 E+01 1.0E+00 3.2E+00 10 325
8.08E+00 4.6E+00 1.0E+00 3.2E+00
1.33E+01 3.5E+00 1.0E+00 3.2E+00
2.81 E+01 1.8E+00 1.0E+00 3.2E+00
1.17E+03 1.4E+00 1.0E+00 3.2E+00
1.21E+03 4.6E-01 1.0E+00 3.2E+00
1.59E+03 1.0E+00 1.0E+00 3.2E+00
2.43E+02 1.5E+01 1.0E+00 3.2E+00
4.57E+01 2.5E+00 1.0E+00 3.2E+00
4.64E+00 7.6E+00 1.0E+00 3.2E+00 10 325
5.85E+00 9.8E+00 1.0E+00 3.2E+00
8.25E+00 2.2E+01 1.0E+00 3.2E+00
3.06E+01 5.8E+00 1.0E+00 3.2E+00
1.25E+03 1.4E+00 1.0E+00 3.2E+00
1.16E+03 1.5E+00 1.0E+00 3.2E+00
1.53E+03 6.0E+01 1.0E+00 3.2E+00
2.50E+02 3.2E+00 1.0E+00 3.2E+00
1.87E+01 5.7E+00 1.0E+00 3.2E+00
7.78E+00 1.5E+01 1.0E+00 3.2E+00 10 325
5.10E+00 1.5E+01 1.0E+00 3.2E+00
9.53E+00 8.8E+00 1.0E+00 3.2E+00
2.25E+01 4.9E+00 1.0E+00 3.2E+00
1.19E+03 6.5E+00 1.0E+00 3.2E+00
1.15E+03 4.6E+00 1.0E+00 3.2E+00
1.54E+03 1.2E+01 1.0E+00 3.2E+00
6.98E+00 7.6E+00 1.0E+00 3.2E+00
1.10E+01 1.4E+01 1.0E+00 3.2E+00
1.27E+01 4.4E+00 1.0E+00 3.2E+00
9.92E+00 7.2E+00 1.0E+00 3.2E+00
1.09E+01 1.2E+01 1.0E+00 3.2E+00
1.84E+01 1.1 E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.36E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.47E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 2:36 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:41 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:43 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:45 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:05 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:48 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:03 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:04 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:06 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/103:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:13 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:14 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:21 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:08 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:24 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:09 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/104:11 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:34 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:31 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:56 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:58 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 2:59 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                          1-148
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al EaFA-L07-1313-T01-A 1
Al EaFA-L07-1313-T02-A 1
Al EaFA-L07-1313-T03-A 1
Al EaFA-L07-1313-T04-A 1
Al EaFA-L07-1313-T05-A 1
Al EaFA-L07-1313-T06-A 1
Al EaFA-L07-1313-T07-A 1
Al EaFA-L07-1313-T08-A 1
Al EaFA-L07-1313-T09-A 1
Al EaFA-L07-1313-T01-B 1
Al EaFA-L07-1313-T02-B 1
Al EaFA-L07-1313-T03-B 1
Al EaFA-L07-1313-T04-B 1
Al EaFA-L07-1313-T05-B 1
Al EaFA-L07-1313-T06-B 1
Al EaFA-L07-1313-T07-B 1
Al EaFA-L07-1313-T08-B 1
Al EaFA-L07-1313-T09-B 1
Al EaFA-L07-1313-T01-C 1
Al EaFA-L07-1313-T02-C 1
Al EaFA-L07-1313-T03-C 1
Al EaFA-L07-1313-T04-C 1
Al EaFA-L07-1313-T05-C 1
Al EaFA-L07-1313-T06-C 1
Al EaFA-L07-1313-T07-C 1
Al EaFA-L07-1313-T08-C 1
Al EaFA-L07-1313-T09-C 1
Al EaFA-L07-1313-B01-A 1
Al EaFA-L07-1313-B02-A 1
Al EaFA-L07-1313-B03-A 1
Al EaFA-L07-1313-B01-B 1
Al EaFA-L07-1313-B02-B 1
Al EaFA-L07-1313-B03-B 1
Al EaFA-L07-1313-B01-C 1
Al EaFA-L07-1313-B02-C 1
Al EaFA-L07-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
2.46E+04
3.18E+04
2.24E+04
6.83E+03
6.17E+02
1.00E+02
1.03E+03
3.63E+04
1.33E+05
3.41 E+04
3.24E+04
2.19E+04
3.39E+03
3.94E+02
1.83E+02
1.01E+03
4.58E+04
1.30E+05
3.26E+04
2.98E+04
2.01 E+04
6.15E+03
6.00E+02
1.58E+02
9.80E+02
3.61 E+04
1.26E+05
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.46E+04 4.1E-01 1.0E+00 3.2E+00
3.18E+04 9.2E-01 1.0E+00 3.2E+00
2.24E+04 5.5E-01 1.0E+00 3.2E+00 1000 100
6.83E+03 5.9E+00 1.0E+00 3.2E+00
6.17E+02 3.7E-01 1.0E+00 3.2E+00
1.00E+02 1.4E+00 1.0E+00 3.2E+00
1.03E+03 7.3E-01 1.0E+00 3.2E+00
3.63E+04 2.6E-01 1.0E+00 3.2E+00
1.33E+05 7.1E-01 1.0E+00 3.2E+00
3.41 E+04 6.9E+00 1.0E+00 3.2E+00
3.24E+04 2.1E-01 1.0E+00 3.2E+00
2.19E+04 6.0E+00 1.0E+00 3.2E+00 1000 100
3.39E+03 4.6E+00 1.0E+00 3.2E+00
3.94E+02 7.0E-01 1.0E+00 3.2E+00
1.83E+02 9.8E-01 1.0E+00 3.2E+00
1.01E+03 4.4E+00 1.0E+00 3.2E+00
4.58E+04 3.4E-01 1.0E+00 3.2E+00
1.30E+05 1.0E+00 1.0E+00 3.2E+00
3.26E+04 5.4E-01 1.0E+00 3.2E+00
2.98E+04 3.2E-01 1.0E+00 3.2E+00
2.01E+04 3.6E-02 1.0E+00 3.2E+00 1000 100
6.15E+03 7.0E+00 1.0E+00 3.2E+00
6.00E+02 2.9E-01 1.0E+00 3.2E+00
1.58E+02 1.8E+03 1.0E+00 3.2E+00
9.80E+02 6.3E-01 1.0E+00 3.2E+00
3.61 E+04 4.5E-01 1.0E+00 3.2E+00
1.26E+05 8.7E-01 1.0E+00 3.2E+00
5.00E-01 1.0E+01 1.0E+00 3.2E+00
5.00E-01 6.1E+00 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
5.00E-01 6.3E+00 1.0E+00 3.2E+00
5.00E-01 1.9E+01 1.0E+00 3.2E+00
5.00E-01 4.9E+00 1.0E+00 3.2E+00
5.00E-01 4.6E+00 1.0E+00 3.2E+00
5.00E-01 6.5E+00 1.0E+00 3.2E+00
5.00E-01 1.0E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.34E+04 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.28E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.10E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                                   1-149
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L07-1313-T01-A 1
Sb EaFA-L07-1313-T02-A 1
Sb EaFA-L07-1313-T03-A 1
Sb EaFA-L07-1313-T04-A 1
Sb EaFA-L07-1313-T05-A 1
Sb EaFA-L07-1313-T06-A 1
Sb EaFA-L07-1313-T07-A 1
Sb EaFA-L07-1313-T08-A 1
Sb EaFA-L07-1313-T09-A 1
Sb EaFA-L07-1313-T01-B 1
Sb EaFA-L07-1313-T02-B 1
Sb EaFA-L07-1313-T03-B 1
Sb EaFA-L07-1313-T04-B 1
Sb EaFA-L07-1313-T05-B 1
Sb EaFA-L07-1313-T06-B 1
Sb EaFA-L07-1313-T07-B 1
Sb EaFA-L07-1313-T08-B 1
Sb EaFA-L07-1313-T09-B 1
Sb EaFA-L07-1313-T01-C 1
Sb EaFA-L07-1313-T02-C 1
Sb EaFA-L07-1313-T03-C 1
Sb EaFA-L07-1313-T04-C 1
Sb EaFA-L07-1313-T05-C 1
Sb EaFA-L07-1313-T06-C 1
Sb EaFA-L07-1313-T07-C 1
Sb EaFA-L07-1313-T08-C 1
Sb EaFA-L07-1313-T09-C 1
Sb EaFA-L07-1313-B01-A 1
Sb EaFA-L07-1313-B02-A 1
Sb EaFA-L07-1313-B03-A 1
Sb EaFA-L07-1313-B01-B 1
Sb EaFA-L07-1313-B02-B 1
Sb EaFA-L07-1313-B03-B 1
Sb EaFA-L07-1313-B01-C 1
Sb EaFA-L07-1313-B02-C 1
Sb EaFA-L07-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
2.69E+02
1.49E+02
2.07E+02
1.83E+02
2.03E+02
2.03E+02
6.99E+01
4.69E+01
3.75E+00 U1/2
1.85E+02
1.45E+02
1.75E+02
2.14E+02
2.07E+02
1.67E+02
6.89E+01
1.53E+01 E
3.75E+00 U1/2
2.15E+02
1.40E+02
1.93E+02
1.95E+02
2.16E+02
2.15E+02
9.03E+01
3.11E+01
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.15E+01
1.43E+01 E
1.89E+01 E
2.57E+01
3.75E+00 U1/2
3.75E+00 U1/2
1.17E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.69E+02 2.9E+01 7.5E+00 2.4E+01
1.49E+02 1.4E+01 7.5E+00 2.4E+01
2.07E+02 1.1E+01 7.5E+00 2.4E+01 10 325
1.83E+02 2.2E+01 7.5E+00 2.4E+01
2.03E+02 4.8E+00 7.5E+00 2.4E+01
2.03E+02 6.1E+00 7.5E+00 2.4E+01
6.99E+01 2.3E+01 7.5E+00 2.4E+01
4.69E+01 1.5E+01 7.5E+00 2.4E+01
3.75E+00 2.7E+02 7.5E+00 2.4E+01
1.85E+02 1.1E+01 7.5E+00 2.4E+01
1.45E+02 2.7E+00 7.5E+00 2.4E+01
1.75E+02 1.4E+01 7.5E+00 2.4E+01 10 325
2.14E+02 1.4E+01 7.5E+00 2.4E+01
2.07E+02 3.9E+00 7.5E+00 2.4E+01
1.67E+02 1.2E+01 7.5E+00 2.4E+01
6.89E+01 3.5E+01 7.5E+00 2.4E+01
1.53E+01 5.3E+01 7.5E+00 2.4E+01
3.75E+00 1.9E+02 7.5E+00 2.4E+01
2.15E+02 1.3E+01 7.5E+00 2.4E+01
1.40E+02 1.4E+00 7.5E+00 2.4E+01
1.93E+02 1.4E+01 7.5E+00 2.4E+01 10 325
1.95E+02 9.8E+00 7.5E+00 2.4E+01
2.16E+02 1.1E+01 7.5E+00 2.4E+01
2.15E+02 1.6E+02 7.5E+00 2.4E+01
9.03E+01 2.3E+01 7.5E+00 2.4E+01
3.11E+01 4.7E+00 7.5E+00 2.4E+01
3.75E+00 2.8E+03 7.5E+00 2.4E+01
3.75E+00 3.1E+02 7.5E+00 2.4E+01
3.75E+00 1.9E+02 7.5E+00 2.4E+01
3.15E+01 4.3E+01 7.5E+00 2.4E+01
1.43E+01 1.6E+02 7.5E+00 2.4E+01
1.89E+01 5.3E+01 7.5E+00 2.4E+01
2.57E+01 1.1E+02 7.5E+00 2.4E+01
3.75E+00 1.4E+03 7.5E+00 2.4E+01
3.75E+00 2.0E+02 7.5E+00 2.4E+01
1.17E+01 5.9E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.46E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.83E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-150
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As EaFA-L07-1313-T01-A 1
As EaFA-L07-1313-T02-A 1
As EaFA-L07-1313-T03-A 1
As EaFA-L07-1313-T04-A 1
As EaFA-L07-1313-T05-A 1
As EaFA-L07-1313-T06-A 1
As EaFA-L07-1313-T07-A 1
As EaFA-L07-1313-T08-A 1
As EaFA-L07-1313-T09-A 1
As EaFA-L07-1313-T01-B 1
As EaFA-L07-1313-T02-B 1
As EaFA-L07-1313-T03-B 1
As EaFA-L07-1313-T04-B 1
As EaFA-L07-1313-T05-B 1
As EaFA-L07-1313-T06-B 1
As EaFA-L07-1313-T07-B 1
As EaFA-L07-1313-T08-B 1
As EaFA-L07-1313-T09-B 1
As EaFA-L07-1313-T01-C 1
As EaFA-L07-1313-T02-C 1
As EaFA-L07-1313-T03-C 1
As EaFA-L07-1313-T04-C 1
As EaFA-L07-1313-T05-C 1
As EaFA-L07-1313-T06-C 1
As EaFA-L07-1313-T07-C 1
As EaFA-L07-1313-T08-C 1
As EaFA-L07-1313-T09-C 1
As EaFA-L07-1313-B01-A 1
As EaFA-L07-1313-B02-A 1
As EaFA-L07-1313-B03-A 1
As EaFA-L07-1313-B01-B 1
As EaFA-L07-1313-B02-B 1
As EaFA-L07-1313-B03-B 1
As EaFA-L07-1313-B01-C 1
As EaFA-L07-1313-B02-C 1
As EaFA-L07-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
7.01 E+03
8.68E+02
1.40E+03
6.56E+02
2.23E+02
9.42E+01
8.25E+01
1.42E+02
2.91 E+03
6.94E+03
8.31 E+02
1.31 E+03
4.68E+02
1.77E+02
8.93E+01
9.83E+01
1.24E+02
1 .84E+03
7.25E+03
8.38E+02
1.31 E+03
6.11E+02
2. 81 E+02
1 .20E+02
9.71E+01
1 .33E+02
2.18E+03
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
1.79E+01 E
5.50E+00 U1/2
1.27E+01 E
5.50E+00 U1/2
1.35E+01 E
1.16E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.01 E+03 7.6E-01 1.1E+01 3.5E+01
8.68E+02 2.8E+00 1.1E+01 3.5E+01
1.40E+03 3.4E-01 1.1E+01 3.5E+01 10 325
6.56E+02 5.9E+00 1.1E+01 3.5E+01
2.23E+02 4.7E+00 1.1E+01 3.5E+01
9.42E+01 2.2E+01 1.1E+01 3.5E+01
8.25E+01 8.2E+00 1.1E+01 3.5E+01
1.42E+02 1.9E+00 1.1E+01 3.5E+01
2.91 E+03 2.8E-01 1.1E+01 3.5E+01
6.94E+03 7.6E+00 1.1E+01 3.5E+01
8.31E+02 9.1E-01 1.1E+01 3.5E+01
1.31E+03 5.6E+00 1.1E+01 3.5E+01 10 325
4.68E+02 4.9E+00 1.1E+01 3.5E+01
1.77E+02 8.2E+00 1.1E+01 3.5E+01
8.93E+01 1.4E+01 1.1E+01 3.5E+01
9.83E+01 1.3E+01 1.1E+01 3.5E+01
1.24E+02 1.2E+01 1.1E+01 3.5E+01
1.84E+03 1.6E+00 1.1E+01 3.5E+01
7.25E+03 9.2E-01 1.1E+01 3.5E+01
8.38E+02 3.0E+00 1.1E+01 3.5E+01
1.31E+03 1.0E+00 1.1E+01 3.5E+01 10 325
6.11E+02 1.3E+01 1.1E+01 3.5E+01
2.81E+02 1.3E+01 1.1E+01 3.5E+01
1.20E+02 5.8E+02 1.1E+01 3.5E+01
9.71E+01 1.4E+01 1.1E+01 3.5E+01
1.33E+02 9.7E+00 1.1E+01 3.5E+01
2.18E+03 8.7E-01 1.1E+01 3.5E+01
5.50E+00 2.1E+02 1.1E+01 3.5E+01
5.50E+00 7.3E+01 1.1E+01 3.5E+01
5.50E+00 5.3E+02 1.1E+01 3.5E+01
1.79E+01 6.6E+01 1.1E+01 3.5E+01
5.50E+00 2.6E+02 1.1E+01 3.5E+01
1.27E+01 1.2E+02 1.1E+01 3.5E+01
5.50E+00 2.7E+02 1.1E+01 3.5E+01
1.35E+01 1.5E+02 1.1E+01 3.5E+01
1.16E+01 6.3E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.59E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.58E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.41E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-151
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B EaFA-L07-1313-T01-A 1
B EaFA-L07-1313-T02-A 1
B EaFA-L07-1313-T03-A 1
B EaFA-L07-1313-T04-A 1
B EaFA-L07-1313-T05-A 1
B EaFA-L07-1313-T06-A 1
B EaFA-L07-1313-T07-A 1
B EaFA-L07-1313-T08-A 1
B EaFA-L07-1313-T09-A 1
B EaFA-L07-1313-T01-B 1
B EaFA-L07-1313-T02-B 1
B EaFA-L07-1313-T03-B 1
B EaFA-L07-1313-T04-B 1
B EaFA-L07-1313-T05-B 1
B EaFA-L07-1313-T06-B 1
B EaFA-L07-1313-T07-B 1
B EaFA-L07-1313-T08-B 1
B EaFA-L07-1313-T09-B 1
B EaFA-L07-1313-T01-C 1
B EaFA-L07-1313-T02-C 1
B EaFA-L07-1313-T03-C 1
B EaFA-L07-1313-T04-C 1
B EaFA-L07-1313-T05-C 1
B EaFA-L07-1313-T06-C 1
B EaFA-L07-1313-T07-C 1
B EaFA-L07-1313-T08-C 1
B EaFA-L07-1313-T09-C 1
B EaFA-L07-1313-B01-A 1
B EaFA-L07-1313-B02-A 1
B EaFA-L07-1313-B03-A 1
B EaFA-L07-1313-B01-B 1
B EaFA-L07-1313-B02-B 1
B EaFA-L07-1313-B03-B 1
B EaFA-L07-1313-B01-C 1
B EaFA-L07-1313-B02-C 1
B EaFA-L07-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
4.41 E+03
4.39E+03
4.31 E+03
3.95E+03
4.32E+03
4.38E+03
4.43E+03
3.64E+03
2.84E+03
4.08E+03
4.29E+03
3.96E+03
3.99E+03
4.30E+03
4.33E+03
4.59E+03
3.84E+03
2. 81 E+03
4.27E+03
4.21 E+03
4.08E+03
3.68E+03
4.20E+03
4.76E+03
4.39E+03
3.67E+03
2.89E+03
1 .40E+01
1.37E+01
2.05E+01
4.11E+01
2.66E+01
2.88E+01
3.02E+01
1.92E+01
2.19E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.41 E+03 1.7E+00 1.0E+00 3.2E+00
4.39E+03 2.5E-01 1.0E+00 3.2E+00
4.31E+03 1.3E+00 1.0E+00 3.2E+00 1000 100
3.95E+03 6.2E+00 1.0E+00 3.2E+00
4.32E+03 3.1E-01 1.0E+00 3.2E+00
4.38E+03 3.3E-01 1.0E+00 3.2E+00
4.43E+03 1.1E-01 1.0E+00 3.2E+00
3.64E+03 7.1E-01 1.0E+00 3.2E+00
2.84E+03 6.6E-01 1.0E+00 3.2E+00
4.08E+03 7.2E+00 1.0E+00 3.2E+00
4.29E+03 4.0E-01 1.0E+00 3.2E+00
3.96E+03 6.3E+00 1.0E+00 3.2E+00 1000 100
3.99E+03 4.3E+00 1.0E+00 3.2E+00
4.30E+03 8.4E-01 1.0E+00 3.2E+00
4.33E+03 8.2E-01 1.0E+00 3.2E+00
4.59E+03 5.5E+00 1.0E+00 3.2E+00
3.84E+03 2.9E-01 1.0E+00 3.2E+00
2.81E+03 9.8E-01 1.0E+00 3.2E+00
4.27E+03 1.6E+00 1.0E+00 3.2E+00
4.21 E+03 6.3E-01 1.0E+00 3.2E+00
4.08E+03 2.0E+00 1.0E+00 3.2E+00 1000 100
3.68E+03 4.6E+00 1.0E+00 3.2E+00
4.20E+03 2.6E+00 1.0E+00 3.2E+00
4.76E+03 1.3E+02 1.0E+00 3.2E+00
4.39E+03 4.7E-01 1.0E+00 3.2E+00
3.67E+03 3.5E-01 1.0E+00 3.2E+00
2.89E+03 4.3E-01 1.0E+00 3.2E+00
1.40E+01 9.8E+00 1.0E+00 3.2E+00
1.37E+01 1.2E+00 1.0E+00 3.2E+00
2.05E+01 6.5E+00 1.0E+00 3.2E+00
4.11E+01 5.3E+00 1.0E+00 3.2E+00
2.66E+01 3.5E+00 1.0E+00 3.2E+00
2.88E+01 3.6E+00 1.0E+00 3.2E+00
3.02E+01 5.3E-01 1.0E+00 3.2E+00
1.92E+01 2.9E+00 1.0E+00 3.2E+00
2.19E+01 1.7E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.15E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.84E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.00E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/101:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-152
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qu
1 1 ug/L
Ba EaFA-L07-1313-T01-A 1 2.09E+02
Ba EaFA-L07-1313-T02-A 1 9.60E+02
Ba EaFA-L07-1313-T03-A 1 8.09E+02
Ba EaFA-L07-1313-T04-A 1 5.46E+02
Ba EaFA-L07-1313-T05-A 1 2.82E+02
Ba EaFA-L07-1313-T06-A 1 2.86E+02
Ba EaFA-L07-1313-T07-A 1 2.71E+02
Ba EaFA-L07-1313-T08-A 1 2.82E+02
Ba EaFA-L07-1313-T09-A 1 9.80E+02
Ba EaFA-L07-1313-T01-B 1 1.14E+03
Ba EaFA-L07-1313-T02-B 1 9.29E+02
Ba EaFA-L07-1313-T03-B 1 7.47E+02
Ba EaFA-L07-1313-T04-B 1 3.94E+02
Ba EaFA-L07-1313-T05-B 1 2.67E+02
Ba EaFA-L07-1313-T06-B 1 2.68E+02
Ba EaFA-L07-1313-T07-B 1 2.72E+02
Ba EaFA-L07-1313-T08-B 1 3.07E+02
Ba EaFA-L07-1313-T09-B 1 8.90E+02
Ba EaFA-L07-1313-T01-C 1 9.74E+02
Ba EaFA-L07-1313-T02-C 1 8.46E+02
Ba EaFA-L07-1313-T03-C 1 7.01E+02
Ba EaFA-L07-1313-T04-C 1 5.02E+02
Ba EaFA-L07-1313-T05-C 1 2.89E+02
Ba EaFA-L07-1313-T06-C 1 2.90E+02
Ba EaFA-L07-1313-T07-C 1 2.75E+02
Ba EaFA-L07-1313-T08-C 1 2.83E+02
Ba EaFA-L07-1313-T09-C 1 9.26E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.09E+02 4.3E-01 1. OE+00 3.2E+00
9.60E+02 3.6E-01 1. OE+00 3.2E+00
8.09E+02 9.0E-01 1. OE+00 3.2E+00 10 325
5.46E+02 6.5E+00 1. OE+00 3.2E+00
2.82E+02 4.6E-01 1. OE+00 3.2E+00
2.86E+02 5.1E-01 1. OE+00 3.2E+00
2.71 E+02 8.5E-01 1. OE+00 3.2E+00
2.82E+02 4.3E-01 1. OE+00 3.2E+00
9.80E+02 1.1E-01 1. OE+00 3.2E+00
1.14E+03 6.9E+00 1. OE+00 3.2E+00
9.29E+02 7.4E-01 1. OE+00 3.2E+00
7.47E+02 5.7E+00 1. OE+00 3.2E+00 10 325
3.94E+02 5.0E+00 1. OE+00 3.2E+00
2.67E+02 2.8E-01 1. OE+00 3.2E+00
2.68E+02 1.8E-01 1. OE+00 3.2E+00
2.72E+02 5.1E+00 1.0E+00 3.2E+00
3.07E+02 3.7E-01 1 .OE+00 3.2E+00
8.90E+02 1.3E+00 1 .OE+00 3.2E+00
9.74E+02 1.2E+00 1 .OE+00 3.2E+00
8.46E+02 3.0E-01 1 .OE+00 3.2E+00
7.01E+02 9.5E-01 1 .OE+00 3.2E+00 10 325
5.02E+02 8.2E+00 1 .OE+00 3.2E+00
2.89E+02 4.7E-01 1 .OE+00 3.2E+00
2.90E+02 1.3E+02 1 .OE+00 3.2E+00
2.75E+02 5.2E-01 1 .OE+00 3.2E+00
2.83E+02 2.4E-01 1 .OE+00 3.2E+00
9.26E+02 1. OE+00 1 .OE+00 3.2E+00
Ba EaFA-L07-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 4.5E+02 1 .OE+00 3.2E+00
Ba EaFA-L07-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 8.1E+01 1.0E+00 3.2E+00
Ba EaFA-L07-1313-B03-A 1 1 J5E+00 E
1.75E+00 9.8E+00 1. OE+00 3.2E+00
Ba EaFA-L07-1313-B01-B 1 5.00E-01 U1/2 5.00E-01 1.0E+02 1. OE+00 3.2E+00
Ba EaFA-L07-1313-B02-B 1 1.06E+OOE
Ba EaFA-L07-1313-B03-B 1 1.85E+OOE
1.06E+00 5.5E+00 1. OE+00 3.2E+00
1.85E+00 8.3E+00 1. OE+00 3.2E+00
Ba EaFA-L07-1313-B01-C 1 5.00E-01 U1/2 5.00E-01 3.0E+01 1. OE+00 3.2E+00
Ba EaFA-L07-1313-B02-C 1 5.00E-01 U1/2 5.00E-01 5.2E+01 1. OE+00 3.2E+00
Ba EaFA-L07-1313-B03-C 1 1.57E+OOE
1.57E+00 7.6E+00 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.71 E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.35E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.52E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/101:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-153
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L07-1313-T01-A 1
Be EaFA-L07-1313-T02-A 1
Be EaFA-L07-1313-T03-A 1
Be EaFA-L07-1313-T04-A 1
Be EaFA-L07-1313-T05-A 1
Be EaFA-L07-1313-T06-A 1
Be EaFA-L07-1313-T07-A 1
Be EaFA-L07-1313-T08-A 1
Be EaFA-L07-1313-T09-A 1
Be EaFA-L07-1313-T01-B 1
Be EaFA-L07-1313-T02-B 1
Be EaFA-L07-1313-T03-B 1
Be EaFA-L07-1313-T04-B 1
Be EaFA-L07-1313-T05-B 1
Be EaFA-L07-1313-T06-B 1
Be EaFA-L07-1313-T07-B 1
Be EaFA-L07-1313-T08-B 1
Be EaFA-L07-1313-T09-B 1
Be EaFA-L07-1313-T01-C 1
Be EaFA-L07-1313-T02-C 1
Be EaFA-L07-1313-T03-C 1
Be EaFA-L07-1313-T04-C 1
Be EaFA-L07-1313-T05-C 1
Be EaFA-L07-1313-T06-C 1
Be EaFA-L07-1313-T07-C 1
Be EaFA-L07-1313-T08-C 1
Be EaFA-L07-1313-T09-C 1
Be EaFA-L07-1313-B01-A 1
Be EaFA-L07-1313-B02-A 1
Be EaFA-L07-1313-B03-A 1
Be EaFA-L07-1313-B01-B 1
Be EaFA-L07-1313-B02-B 1
Be EaFA-L07-1313-B03-B 1
Be EaFA-L07-1313-B01-C 1
Be EaFA-L07-1313-B02-C 1
Be EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.29E+00
1.32E+02
2.55E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.54E+00
1.47E+02
2.50E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.11E+00
1.32E+02
2.48E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.1E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+03 1.9E+00 6.0E+00
9.50E-01 5.6E+02 1.9E+00 6.0E+00 10 325
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 5.8E+02 1.9E+00 6.0E+00
9.29E+00 3.2E+00 1.9E+00 6.0E+00
1.32E+02 4.8E-01 1.9E+00 6.0E+00
2.55E+02 1.4E-01 1.9E+00 6.0E+00
9.50E-01 2.1E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 7.8E+01 1.9E+00 6.0E+00 10 325
9.50E-01 9.2E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.54E+00 7.7E+00 1.9E+00 6.0E+00
1.47E+02 3.3E-01 1.9E+00 6.0E+00
2.50E+02 8.5E-01 1.9E+00 6.0E+00
9.50E-01 1.8E+01 1.9E+00 6.0E+00
9.50E-01 3.7E+01 1.9E+00 6.0E+00
9.50E-01 3.4E+02 1.9E+00 6.0E+00 10 325
9.50E-01 6.9E+01 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.11E+00 3.7E+00 1.9E+00 6.0E+00
1.32E+02 2.8E-01 1.9E+00 6.0E+00
2.48E+02 1.5E+00 1.9E+00 6.0E+00
9.50E-01 5.1E+02 1.9E+00 6.0E+00
9.50E-01 5.9E+01 1.9E+00 6.0E+00
9.50E-01 3.7E+03 1.9E+00 6.0E+00
9.50E-01 4.5E+02 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 3.5E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.27E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.66E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.15E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-154
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-L07-1313-T01-A 1
Cd EaFA-L07-1313-T02-A 1
Cd EaFA-L07-1313-T03-A 1
Cd EaFA-L07-1313-T04-A 1
Cd EaFA-L07-1313-T05-A 1
Cd EaFA-L07-1313-T06-A 1
Cd EaFA-L07-1313-T07-A 1
Cd EaFA-L07-1313-T08-A 1
Cd EaFA-L07-1313-T09-A 1
Cd EaFA-L07-1313-T01-B 1
Cd EaFA-L07-1313-T02-B 1
Cd EaFA-L07-1313-T03-B 1
Cd EaFA-L07-1313-T04-B 1
Cd EaFA-L07-1313-T05-B 1
Cd EaFA-L07-1313-T06-B 1
Cd EaFA-L07-1313-T07-B 1
Cd EaFA-L07-1313-T08-B 1
Cd EaFA-L07-1313-T09-B 1
Cd EaFA-L07-1313-T01-C 1
Cd EaFA-L07-1313-T02-C 1
Cd EaFA-L07-1313-T03-C 1
Cd EaFA-L07-1313-T04-C 1
Cd EaFA-L07-1313-T05-C 1
Cd EaFA-L07-1313-T06-C 1
Cd EaFA-L07-1313-T07-C 1
Cd EaFA-L07-1313-T08-C 1
Cd EaFA-L07-1313-T09-C 1
Cd EaFA-L07-1313-B01-A 1
Cd EaFA-L07-1313-B02-A 1
Cd EaFA-L07-1313-B03-A 1
Cd EaFA-L07-1313-B01-B 1
Cd EaFA-L07-1313-B02-B 1
Cd EaFA-L07-1313-B03-B 1
Cd EaFA-L07-1313-B01-C 1
Cd EaFA-L07-1313-B02-C 1
Cd EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.37E+01
2.61E+01
2.99E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.55E+01
2.52E+01
2.91E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.36E+01
2.60E+01
2.88E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.9E+01 2.2E+00 7.0E+00
1.10E+00 1.2E+01 2.2E+00 7.0E+00
1.10E+00 5.4E+00 2.2E+00 7.0E+00 10 325
1.10E+00 8.9E+00 2.2E+00 7.0E+00
1.10E+00 1.7E+01 2.2E+00 7.0E+00
1.10E+00 4.4E+01 2.2E+00 7.0E+00
3.37E+01 2.0E+00 2.2E+00 7.0E+00
2.61 E+01 3.5E-01 2.2E+00 7.0E+00
2.99E+01 1.5E+00 2.2E+00 7.0E+00
1.10E+00 1.4E+01 2.2E+00 7.0E+00
1.10E+00 8.4E+00 2.2E+00 7.0E+00
1.10E+00 6.6E+00 2.2E+00 7.0E+00 10 325
1.10E+00 2.3E+01 2.2E+00 7.0E+00
1.10E+00 2.0E+01 2.2E+00 7.0E+00
1.10E+00 2.4E+01 2.2E+00 7.0E+00
3.55E+01 7.8E+00 2.2E+00 7.0E+00
2.52E+01 1.9E+00 2.2E+00 7.0E+00
2.91 E+01 2.2E+00 2.2E+00 7.0E+00
1.10E+00 1.2E+01 2.2E+00 7.0E+00
1.10E+00 1.3E+01 2.2E+00 7.0E+00
1.10E+00 2.3E+01 2.2E+00 7.0E+00 10 325
1.10E+00 1.6E+01 2.2E+00 7.0E+00
1.10E+00 1.9E+01 2.2E+00 7.0E+00
1.10E+00 5.0E-01 2.2E+00 7.0E+00
3.36E+01 1.7E+00 2.2E+00 7.0E+00
2.60E+01 8.9E-01 2.2E+00 7.0E+00
2.88E+01 8.5E-01 2.2E+00 7.0E+00
1.10E+00 1.7E+01 2.2E+00 7.0E+00
1.10E+00 5.5E+00 2.2E+00 7.0E+00
1.10E+00 3.6E+01 2.2E+00 7.0E+00
1.10E+00 1.7E+01 2.2E+00 7.0E+00
1.10E+00 1.6E+01 2.2E+00 7.0E+00
1.10E+00 1.4E+01 2.2E+00 7.0E+00
1.10E+00 7.9E+00 2.2E+00 7.0E+00
1.10E+00 8.4E+00 2.2E+00 7.0E+00
1.10E+00 3.6E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.27E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.56E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.15E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/101:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-155
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
1 1 ug/L
Ca EaFA-L07-1313-T01-A 1 1.31E+04
Ca EaFA-L07-1313-T02-A 1 5.28E+04
Ca EaFA-L07-1313-T03-A 1 9.68E+04
Ca EaFA-L07-1313-T04-A 1 1.26E+05
Ca EaFA-L07-1313-T05-A 1 1.49E+05
Ca EaFA-L07-1313-T06-A 1 1.58E+05
Ca EaFA-L07-1313-T07-A 1 1.59E+05
Ca EaFA-L07-1313-T08-A 1 1.46E+05
Ca EaFA-L07-1313-T09-A 1 1.36E+05
Ca EaFA-L07-1313-T01-B 1 1.71E+04
Ca EaFA-L07-1313-T02-B 1 5.29E+04
Ca EaFA-L07-1313-T03-B 1 8.90E+04
Ca EaFA-L07-1313-T04-B 1 1.30E+05
Ca EaFA-L07-1313-T05-B 1 1.56E+05
Ca EaFA-L07-1313-T06-B 1 1.62E+05
Ca EaFA-L07-1313-T07-B 1 1.66E+05
Ca EaFA-L07-1313-T08-B 1 1.48E+05
Ca EaFA-L07-1313-T09-B 1 1.35E+05
Ca EaFA-L07-1313-T01-C 1 1.74E+04
Ca EaFA-L07-1313-T02-C 1 5.16E+04
Ca EaFA-L07-1313-T03-C 1 9.18E+04
Ca EaFA-L07-1313-T04-C 1 1.12E+05
Ca EaFA-L07-1313-T05-C 1 1.49E+05
Ca EaFA-L07-1313-T06-C 1 1.63E+05
Ca EaFA-L07-1313-T07-C 1 1.60E+05
Ca EaFA-L07-1313-T08-C 1 1.46E+05
Ca EaFA-L07-1313-T09-C 1 1.36E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.31E+04 7.1E-01 2.6E+00 8.3E+00
5.28E+04 5.6E-01 2.6E+00 8.3E+00
9.68E+04 4.2E-01 2.6E+00 8.3E+00 1000 100
1.26E+05 5.0E+00 2.6E+00 8.3E+00
1.49E+05 9.5E-01 2.6E+00 8.3E+00
1.58E+05 5.7E-01 2.6E+00 8.3E+00
1.59E+05 6.6E-01 2.6E+00 8.3E+00
1.46E+05 4.4E-01 2.6E+00 8.3E+00
1.36E+05 2.8E-01 2.6E+00 8.3E+00
1.71E+04 7.3E+00 2.6E+00 8.3E+00
5.29E+04 4.1E-01 2.6E+00 8.3E+00
8.90E+04 6.8E+00 2.6E+00 8.3E+00 1000 100
1.30E+05 4.8E+00 2.6E+00 8.3E+00
1.56E+05 4.8E-01 2.6E+00 8.3E+00
1.62E+05 7.1E-01 2.6E+00 8.3E+00
1.66E+05 6.4E+00 2.6E+00 8.3E+00
1.48E+05 1.6E-01 2.6E+00 8.3E+00
1.35E+05 1.5E+00 2.6E+00 8.3E+00
1.74E+04 1.3E+00 2.6E+00 8.3E+00
5.16E+04 9.1E-02 2.6E+00 8.3E+00
9.18E+04 7.7E-01 2.6E+00 8.3E+00 1000 100
1.12E+05 8.1E+00 2.6E+00 8.3E+00
1.49E+05 3.4E-01 2.6E+00 8.3E+00
1.63E+05 1.4E+02 2.6E+00 8.3E+00
1.60E+05 2.5E-01 2.6E+00 8.3E+00
1.46E+05 4.6E-01 2.6E+00 8.3E+00
1.36E+05 3.9E-01 2.6E+00 8.3E+00
Ca EaFA-L07-1313-B01-A 1 6.32E+00 E 6.32E+00 3.1E+01 2.6E+00 8.3E+00
Ca EaFA-L07-1313-B02-A 1 6.33E+00 E 6.33E+00 8.2E+01 2.6E+00 8.3E+00
Ca EaFA-L07-1313-B03-A 1 3.16E+01
Ca EaFA-L07-1313-B01-B 1 2.56E+01
3.16E+01 2.9E+01 2.6E+00 8.3E+00
2.56E+01 1.1E+01 2.6E+00 8.3E+00
Ca EaFA-L07-1313-B02-B 1 5.69E+00 E 5.69E+00 6.4E+01 2.6E+00 8.3E+00
Ca EaFA-L07-1313-B03-B 1 3.46E+01
Ca EaFA-L07-1313-B01-C 1 4.79E+01
Ca EaFA-L07-1313-B02-C 1 8.68E+00
3.46E+01 2.9E+01 2.6E+00 8.3E+00
4.79E+01 2.1E+01 2.6E+00 8.3E+00
8.68E+00 4.6E+01 2.6E+00 8.3E+00
Ca EaFA-L07-1313-B03-C 1 1.30E+OOU1/2 1.30E+00 2.1E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.00E+04 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.27E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-156
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr EaFA-L07-1313-T01-A 1
Cr EaFA-L07-1313-T02-A 1
Cr EaFA-L07-1313-T03-A 1
Cr EaFA-L07-1313-T04-A 1
Cr EaFA-L07-1313-T05-A 1
Cr EaFA-L07-1313-T06-A 1
Cr EaFA-L07-1313-T07-A 1
Cr EaFA-L07-1313-T08-A 1
Cr EaFA-L07-1313-T09-A 1
Cr EaFA-L07-1313-T01-B 1
Cr EaFA-L07-1313-T02-B 1
Cr EaFA-L07-1313-T03-B 1
Cr EaFA-L07-1313-T04-B 1
Cr EaFA-L07-1313-T05-B 1
Cr EaFA-L07-1313-T06-B 1
Cr EaFA-L07-1313-T07-B 1
Cr EaFA-L07-1313-T08-B 1
Cr EaFA-L07-1313-T09-B 1
Cr EaFA-L07-1313-T01-C 1
Cr EaFA-L07-1313-T02-C 1
Cr EaFA-L07-1313-T03-C 1
Cr EaFA-L07-1313-T04-C 1
Cr EaFA-L07-1313-T05-C 1
Cr EaFA-L07-1313-T06-C 1
Cr EaFA-L07-1313-T07-C 1
Cr EaFA-L07-1313-T08-C 1
Cr EaFA-L07-1313-T09-C 1
Cr EaFA-L07-1313-B01-A 1
Cr EaFA-L07-1313-B02-A 1
Cr EaFA-L07-1313-B03-A 1
Cr EaFA-L07-1313-B01-B 1
Cr EaFA-L07-1313-B02-B 1
Cr EaFA-L07-1313-B03-B 1
Cr EaFA-L07-1313-B01-C 1
Cr EaFA-L07-1313-B02-C 1
Cr EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
4.03E+02
2.71E+02
2.23E+02
1.33E+02
4.64E+01
9.80E+00
6.00E-01 U1/2
2.47E+02
1.75E+03
3.93E+02
2.95E+02
2.21E+02
1.32E+02
4.29E+01
1.37E+01
6.00E-01 U1/2
3.64E+02
1.73E+03
3.65E+02
2.55E+02
1.98E+02
1.14E+02
4.75E+01
1.33E+01
1.71E+00 E
2.45E+02
1.76E+03
6.00E-01 U1/2
6.00E-01 U1/2
3.05E+00 E
6.00E-01 U1/2
6.00E-01 U1/2
1.86E+00 E
6.00E-01 U1/2
6.00E-01 U1/2
3.54E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.03E+02 3.4E-01 1.2E+00 3.8E+00
2.71 E+02 4.3E-01 1.2E+00 3.8E+00
2.23E+02 3.5E-01 1.2E+00 3.8E+00 10 325
1.33E+02 6.0E+00 1.2E+00 3.8E+00
4.64E+01 2.2E+00 1.2E+00 3.8E+00
9.80E+00 2.0E+01 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
2.47E+02 2.9E-01 1.2E+00 3.8E+00
1.75E+03 2.4E-01 1.2E+00 3.8E+00
3.93E+02 6.8E+00 1.2E+00 3.8E+00
2.95E+02 4.1E-01 1.2E+00 3.8E+00
2.21E+02 6.3E+00 1.2E+00 3.8E+00 10 325
1.32E+02 5.4E+00 1.2E+00 3.8E+00
4.29E+01 2.1E+00 1.2E+00 3.8E+00
1.37E+01 1.1E+01 1.2E+00 3.8E+00
6.00E-01 1.4E+03 1.2E+00 3.8E+00
3.64E+02 1.7E-01 1.2E+00 3.8E+00
1.73E+03 1.9E+00 1.2E+00 3.8E+00
3.65E+02 7.9E-01 1.2E+00 3.8E+00
2.55E+02 2.9E-01 1.2E+00 3.8E+00
1.98E+02 1.6E-01 1.2E+00 3.8E+00 10 325
1.14E+02 7.5E+00 1.2E+00 3.8E+00
4.75E+01 2.6E+00 1.2E+00 3.8E+00
1.33E+01 1.6E+02 1.2E+00 3.8E+00
1.71E+00 5.4E+01 1.2E+00 3.8E+00
2.45E+02 3.4E-01 1.2E+00 3.8E+00
1.76E+03 6.4E-01 1.2E+00 3.8E+00
6.00E-01 2.4E+02 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
3.05E+00 6.1E+01 1.2E+00 3.8E+00
6.00E-01 2.1 E+02 1.2E+00 3.8E+00
6.00E-01 2.1 E+02 1.2E+00 3.8E+00
1.86E+00 8.9E+01 1.2E+00 3.8E+00
6.00E-01 6.6E+01 1.2E+00 3.8E+00
6.00E-01 4.5E+02 1.2E+00 3.8E+00
3.54E+00 4.1E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.40E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.37E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.25E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-157
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-L07-1313-T01-A 1
Co EaFA-L07-1313-T02-A 1
Co EaFA-L07-1313-T03-A 1
Co EaFA-L07-1313-T04-A 1
Co EaFA-L07-1313-T05-A 1
Co EaFA-L07-1313-T06-A 1
Co EaFA-L07-1313-T07-A 1
Co EaFA-L07-1313-T08-A 1
Co EaFA-L07-1313-T09-A 1
Co EaFA-L07-1313-T01-B 1
Co EaFA-L07-1313-T02-B 1
Co EaFA-L07-1313-T03-B 1
Co EaFA-L07-1313-T04-B 1
Co EaFA-L07-1313-T05-B 1
Co EaFA-L07-1313-T06-B 1
Co EaFA-L07-1313-T07-B 1
Co EaFA-L07-1313-T08-B 1
Co EaFA-L07-1313-T09-B 1
Co EaFA-L07-1313-T01-C 1
Co EaFA-L07-1313-T02-C 1
Co EaFA-L07-1313-T03-C 1
Co EaFA-L07-1313-T04-C 1
Co EaFA-L07-1313-T05-C 1
Co EaFA-L07-1313-T06-C 1
Co EaFA-L07-1313-T07-C 1
Co EaFA-L07-1313-T08-C 1
Co EaFA-L07-1313-T09-C 1
Co EaFA-L07-1313-B01-A 1
Co EaFA-L07-1313-B02-A 1
Co EaFA-L07-1313-B03-A 1
Co EaFA-L07-1313-B01-B 1
Co EaFA-L07-1313-B02-B 1
Co EaFA-L07-1313-B03-B 1
Co EaFA-L07-1313-B01-C 1
Co EaFA-L07-1313-B02-C 1
Co EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
5.47E+00 E
7.11E+01
2.31 E+02
1.92E+02
4.22E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
1.08E+01
5.64E+01
2.42E+02
2.02E+02
4.01 E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
5.26E+00 E
5.65E+01
2.27E+02
1.91 E+02
3.96E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 5.4E+01 1.8E+00 5.7E+00
9.00E-01 5.7E+01 1.8E+00 5.7E+00
9.00E-01 1.1 E+02 1.8E+00 5.7E+00 10 325
9.00E-01 6.5E+01 1.8E+00 5.7E+00
5.47E+00 5.5E+01 1.8E+00 5.7E+00
7.11E+01 2.4E+00 1.8E+00 5.7E+00
2.31 E+02 5.1E-01 1.8E+00 5.7E+00
1.92E+02 1.0E+00 1.8E+00 5.7E+00
4.22E+02 3.3E-01 1.8E+00 5.7E+00
9.00E-01 5.3E+01 1.8E+00 5.7E+00
9.00E-01 3.8E+01 1.8E+00 5.7E+00
9.00E-01 9.5E+01 1.8E+00 5.7E+00 10 325
9.00E-01 1.5E+01 1.8E+00 5.7E+00
1.08E+01 1.4E+01 1.8E+00 5.7E+00
5.64E+01 2.6E+00 1.8E+00 5.7E+00
2.42E+02 6.3E+00 1.8E+00 5.7E+00
2.02E+02 8.4E-01 1.8E+00 5.7E+00
4.01 E+02 7.3E-01 1.8E+00 5.7E+00
9.00E-01 1.0E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+01 1.8E+00 5.7E+00
9.00E-01 4.6E+01 1.8E+00 5.7E+00 10 325
9.00E-01 2.6E+01 1.8E+00 5.7E+00
5.26E+00 5.8E+01 1.8E+00 5.7E+00
5.65E+01 4.3E+03 1.8E+00 5.7E+00
2.27E+02 6.5E-01 1.8E+00 5.7E+00
1.91 E+02 1.4E+00 1.8E+00 5.7E+00
3.96E+02 1.6E-01 1.8E+00 5.7E+00
9.00E-01 1.3E+01 1.8E+00 5.7E+00
9.00E-01 7.4E+01 1.8E+00 5.7E+00
9.00E-01 7.4E+01 1.8E+00 5.7E+00
9.00E-01 7.0E+01 1.8E+00 5.7E+00
9.00E-01 6.1E+01 1.8E+00 5.7E+00
9.00E-01 6.3E+01 1.8E+00 5.7E+00
9.00E-01 5.3E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+01 1.8E+00 5.7E+00
9.00E-01 7.6E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.15E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.65E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.04E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-158
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFA-L07-1313-T01-A 1
Cu EaFA-L07-1313-T02-A 1
Cu EaFA-L07-1313-T03-A 1
Cu EaFA-L07-1313-T04-A 1
Cu EaFA-L07-1313-T05-A 1
Cu EaFA-L07-1313-T06-A 1
Cu EaFA-L07-1313-T07-A 1
Cu EaFA-L07-1313-T08-A 1
Cu EaFA-L07-1313-T09-A 1
Cu EaFA-L07-1313-T01-B 1
Cu EaFA-L07-1313-T02-B 1
Cu EaFA-L07-1313-T03-B 1
Cu EaFA-L07-1313-T04-B 1
Cu EaFA-L07-1313-T05-B 1
Cu EaFA-L07-1313-T06-B 1
Cu EaFA-L07-1313-T07-B 1
Cu EaFA-L07-1313-T08-B 1
Cu EaFA-L07-1313-T09-B 1
Cu EaFA-L07-1313-T01-C 1
Cu EaFA-L07-1313-T02-C 1
Cu EaFA-L07-1313-T03-C 1
Cu EaFA-L07-1313-T04-C 1
Cu EaFA-L07-1313-T05-C 1
Cu EaFA-L07-1313-T06-C 1
Cu EaFA-L07-1313-T07-C 1
Cu EaFA-L07-1313-T08-C 1
Cu EaFA-L07-1313-T09-C 1
Cu EaFA-L07-1313-B01-A 1
Cu EaFA-L07-1313-B02-A 1
Cu EaFA-L07-1313-B03-A 1
Cu EaFA-L07-1313-B01-B 1
Cu EaFA-L07-1313-B02-B 1
Cu EaFA-L07-1313-B03-B 1
Cu EaFA-L07-1313-B01-C 1
Cu EaFA-L07-1313-B02-C 1
Cu EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
5.29E+00 E
7.79E+00 E
1.18E+01
9.28E+00 E
1.33E+01
1.37E+01
2.51 E+02
1.98E+03
2.92E+03
4.30E+01
7.85E+00 E
1.08E+01 E
1.12E+01 E
1.11E+01 E
1.26E+01
2.55E+02
2.06E+03
2.88E+03
4.65E+01
9.83E+00 E
9.53E+00 E
1.09E+01 E
1.21E+01
1.32E+01
2.41 E+02
1.96E+03
2.94E+03
1.85E+00 U1/2
1.85E+00 U1/2
6.57E+00 E
1.85E+00 U1/2
1.85E+00 U1/2
7.17E+00 E
1.85E+00 U1/2
1.85E+00 U1/2
5.92E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.29E+00 3.8E+01 3.7E+00 1.2E+01
7.79E+00 5.2E+01 3.7E+00 1.2E+01
1.18E+01 5.1E+00 3.7E+00 1.2E+01 10 325
9.28E+00 3.1E+01 3.7E+00 1.2E+01
1.33E+01 1.4E+01 3.7E+00 1.2E+01
1.37E+01 2.2E+01 3.7E+00 1.2E+01
2.51 E+02 1.3E+00 3.7E+00 1.2E+01
1.98E+03 5.4E-01 3.7E+00 1.2E+01
2.92E+03 1.2E+00 3.7E+00 1.2E+01
4.30E+01 1.3E+01 3.7E+00 1.2E+01
7.85E+00 7.5E+01 3.7E+00 1.2E+01
1.08E+01 1.7E+01 3.7E+00 1.2E+01 10 325
1.12E+01 1.7E+01 3.7E+00 1.2E+01
1.11E+01 4.6E+01 3.7E+00 1.2E+01
1.26E+01 2.3E+01 3.7E+00 1.2E+01
2.55E+02 1.0E+01 3.7E+00 1.2E+01
2.06E+03 1.5E+00 3.7E+00 1.2E+01
2.88E+03 1.8E+00 3.7E+00 1.2E+01
4.65E+01 4.3E+00 3.7E+00 1.2E+01
9.83E+00 8.6E+01 3.7E+00 1.2E+01
9.53E+00 4.1E+01 3.7E+00 1.2E+01 10 325
1.09E+01 5.9E+01 3.7E+00 1.2E+01
1.21E+01 4.9E+01 3.7E+00 1.2E+01
1.32E+01 7.2E+01 3.7E+00 1.2E+01
2.41 E+02 1.5E+00 3.7E+00 1.2E+01
1.96E+03 8.5E-01 3.7E+00 1.2E+01
2.94E+03 6.7E-01 3.7E+00 1.2E+01
1.85E+00 7.5E+01 3.7E+00 1.2E+01
1.85E+00 7.1E+01 3.7E+00 1.2E+01
6.57E+00 4.0E+01 3.7E+00 1.2E+01
1.85E+00 1.1 E+02 3.7E+00 1.2E+01
1.85E+00 1.6E+02 3.7E+00 1.2E+01
7.17E+00 7.6E+01 3.7E+00 1.2E+01
1.85E+00 1.1 E+02 3.7E+00 1.2E+01
1.85E+00 1.4E+02 3.7E+00 1.2E+01
5.92E+00 7.1E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.15E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.16E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.05E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-159
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L07-1313-T01-A 1
Fe EaFA-L07-1313-T02-A 1
Fe EaFA-L07-1313-T03-A 1
Fe EaFA-L07-1313-T04-A 1
Fe EaFA-L07-1313-T05-A 1
Fe EaFA-L07-1313-T06-A 1
Fe EaFA-L07-1313-T07-A 1
Fe EaFA-L07-1313-T08-A 1
Fe EaFA-L07-1313-T09-A 1
Fe EaFA-L07-1313-T01-B 1
Fe EaFA-L07-1313-T02-B 1
Fe EaFA-L07-1313-T03-B 1
Fe EaFA-L07-1313-T04-B 1
Fe EaFA-L07-1313-T05-B 1
Fe EaFA-L07-1313-T06-B 1
Fe EaFA-L07-1313-T07-B 1
Fe EaFA-L07-1313-T08-B 1
Fe EaFA-L07-1313-T09-B 1
Fe EaFA-L07-1313-T01-C 1
Fe EaFA-L07-1313-T02-C 1
Fe EaFA-L07-1313-T03-C 1
Fe EaFA-L07-1313-T04-C 1
Fe EaFA-L07-1313-T05-C 1
Fe EaFA-L07-1313-T06-C 1
Fe EaFA-L07-1313-T07-C 1
Fe EaFA-L07-1313-T08-C 1
Fe EaFA-L07-1313-T09-C 1
Fe EaFA-L07-1313-B01-A 1
Fe EaFA-L07-1313-B02-A 1
Fe EaFA-L07-1313-B03-A 1
Fe EaFA-L07-1313-B01-B 1
Fe EaFA-L07-1313-B02-B 1
Fe EaFA-L07-1313-B03-B 1
Fe EaFA-L07-1313-B01-C 1
Fe EaFA-L07-1313-B02-C 1
Fe EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
2.77E+01
5.15E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.20E+02
4.14E+04
4.11E+01
2.71 E+01
4.77E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.75E+01
1.00E+00 U1/2
1.01E+03
3.73E+04
4.63E+01
2.75E+01
8.90E+00
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.39E+02
3.77E+04
1.00E+00 U1/2
1.00E+00 U1/2
7.74E+00
1.00E+00 U1/2
1.00E+00 U1/2
9.59E+00
1.00E+00 U1/2
1.00E+00 U1/2
9.01 E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.5E+01 2.0E+00 6.4E+00
2.77E+01 1.2E+00 2.0E+00 6.4E+00
5.15E+00 5.5E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 3.6E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 8.0E+00 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
6.20E+02 8.7E-01 2.0E+00 6.4E+00
4.14E+04 2.7E-01 2.0E+00 6.4E+00
4.11 E+01 5.6E+00 2.0E+00 6.4E+00
2.71 E+01 2.0E+00 2.0E+00 6.4E+00
4.77E+00 1.0E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 5.2E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.75E+01 3.7E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+03 2.0E+00 6.4E+00
1.01E+03 7.8E-01 2.0E+00 6.4E+00
3.73E+04 8.3E-01 2.0E+00 6.4E+00
4.63E+01 1.9E+00 2.0E+00 6.4E+00
2.75E+01 1.8E+00 2.0E+00 6.4E+00
8.90E+00 3.1E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 8.5E+01 2.0E+00 6.4E+00
1.00E+00 9.9E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+02 2.0E+00 6.4E+00
6.39E+02 9.6E-01 2.0E+00 6.4E+00
3.77E+04 2.8E-01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
7.74E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
9.59E+00 3.4E+00 2.0E+00 6.4E+00
1.00E+00 3.1 E+01 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
9.01 E+00 3.0E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-160
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L07-1313-T01-A 1
Pb EaFA-L07-1313-T02-A 1
Pb EaFA-L07-1313-T03-A 1
Pb EaFA-L07-1313-T04-A 1
Pb EaFA-L07-1313-T05-A 1
Pb EaFA-L07-1313-T06-A 1
Pb EaFA-L07-1313-T07-A 1
Pb EaFA-L07-1313-T08-A 1
Pb EaFA-L07-1313-T09-A 1
Pb EaFA-L07-1313-T01-B 1
Pb EaFA-L07-1313-T02-B 1
Pb EaFA-L07-1313-T03-B 1
Pb EaFA-L07-1313-T04-B 1
Pb EaFA-L07-1313-T05-B 1
Pb EaFA-L07-1313-T06-B 1
Pb EaFA-L07-1313-T07-B 1
Pb EaFA-L07-1313-T08-B 1
Pb EaFA-L07-1313-T09-B 1
Pb EaFA-L07-1313-T01-C 1
Pb EaFA-L07-1313-T02-C 1
Pb EaFA-L07-1313-T03-C 1
Pb EaFA-L07-1313-T04-C 1
Pb EaFA-L07-1313-T05-C 1
Pb EaFA-L07-1313-T06-C 1
Pb EaFA-L07-1313-T07-C 1
Pb EaFA-L07-1313-T08-C 1
Pb EaFA-L07-1313-T09-C 1
Pb EaFA-L07-1313-B01-A 1
Pb EaFA-L07-1313-B02-A 1
Pb EaFA-L07-1313-B03-A 1
Pb EaFA-L07-1313-B01-B 1
Pb EaFA-L07-1313-B02-B 1
Pb EaFA-L07-1313-B03-B 1
Pb EaFA-L07-1313-B01-C 1
Pb EaFA-L07-1313-B02-C 1
Pb EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.15E+02
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
8.50E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
8.36E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 5.0E+01 6.8E+00 2.2E+01
3.40E+00 5.7E+01 6.8E+00 2.2E+01
3.40E+00 1.2E+01 6.8E+00 2.2E+01 10 325
3.40E+00 5.7E+01 6.8E+00 2.2E+01
3.40E+00 5.2E+01 6.8E+00 2.2E+01
3.40E+00 3.2E+01 6.8E+00 2.2E+01
3.40E+00 3.9E+01 6.8E+00 2.2E+01
3.40E+00 2.1E+01 6.8E+00 2.2E+01
1.15E+02 4.7E+00 6.8E+00 2.2E+01
3.40E+00 4.5E+01 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01
3.40E+00 6.0E+01 6.8E+00 2.2E+01 10 325
3.40E+00 2.9E+01 6.8E+00 2.2E+01
3.40E+00 3.9E+01 6.8E+00 2.2E+01
3.40E+00 6.4E+01 6.8E+00 2.2E+01
3.40E+00 4.5E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+01 6.8E+00 2.2E+01
8.50E+01 3.8E+00 6.8E+00 2.2E+01
3.40E+00 1.7E+02 6.8E+00 2.2E+01
3.40E+00 7.9E+00 6.8E+00 2.2E+01
3.40E+00 4.5E+01 6.8E+00 2.2E+01 10 325
3.40E+00 1.0E+01 6.8E+00 2.2E+01
3.40E+00 1.4E+01 6.8E+00 2.2E+01
3.40E+00 9.7E+00 6.8E+00 2.2E+01
3.40E+00 1.3E+01 6.8E+00 2.2E+01
3.40E+00 1.6E+01 6.8E+00 2.2E+01
8.36E+01 1.8E+00 6.8E+00 2.2E+01
3.40E+00 4.8E+01 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.40E+00 1.8E+02 6.8E+00 2.2E+01
3.40E+00 5.4E+01 6.8E+00 2.2E+01
3.40E+00 3.7E+01 6.8E+00 2.2E+01
3.40E+00 7.3E+01 6.8E+00 2.2E+01
3.40E+00 3.0E+01 6.8E+00 2.2E+01
3.40E+00 6.3E+01 6.8E+00 2.2E+01
3.40E+00 8.7E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.09E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.63E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.99E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/101:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-161
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
1 1 ug/L
Li EaFA-L07-1313-T01-A 1 2.15E+03
Li EaFA-L07-1313-T02-A 1 2.89E+03
Li EaFA-L07-1313-T03-A 1 3.24E+03
Li EaFA-L07-1313-T04-A 1 3.18E+03
Li EaFA-L07-1313-T05-A 1 3.41 E+03
Li EaFA-L07-1313-T06-A 1 3.53E+03
Li EaFA-L07-1313-T07-A 1 3.33E+03
Li EaFA-L07-1313-T08-A 1 2.28E+03
Li EaFA-L07-1313-T09-A 1 1.49E+03
Li EaFA-L07-1313-T01-B 1 2.02E+03
Li EaFA-L07-1313-T02-B 1 2.85E+03
Li EaFA-L07-1313-T03-B 1 2.95E+03
Li EaFA-L07-1313-T04-B 1 3.21E+03
Li EaFA-L07-1313-T05-B 1 3.55E+03
Li EaFA-L07-1313-T06-B 1 3.57E+03
Li EaFA-L07-1313-T07-B 1 3.46E+03
Li EaFA-L07-1313-T08-B 1 2.17E+03
Li EaFA-L07-1313-T09-B 1 1.48E+03
Li EaFA-L07-1313-T01-C 1 2.14E+03
Li EaFA-L07-1313-T02-C 1 2.81E+03
Li EaFA-L07-1313-T03-C 1 3.02E+03
Li EaFA-L07-1313-T04-C 1 2.81E+03
Li EaFA-L07-1313-T05-C 1 3.40E+03
Li EaFA-L07-1313-T06-C 1 5.52E+03
Li EaFA-L07-1313-T07-C 1 3.34E+03
Li EaFA-L07-1313-T08-C 1 2.27E+03
Li EaFA-L07-1313-T09-C 1 1.50E+03
Li EaFA-L07-1313-B01-A 1 1.52E+01
Li EaFA-L07-1313-B02-A 1 1.51E+01
Li EaFA-L07-1313-B03-A 1 1.45E+01
Li EaFA-L07-1313-B01-B 1 1.56E+01
Li EaFA-L07-1313-B02-B 1 1.39E+01
Li EaFA-L07-1313-B03-B 1 1.75E+01
Li EaFA-L07-1313-B01-C 1 1.44E+01
Li EaFA-L07-1313-B02-C 1 1.58E+01
Li EaFA-L07-1313-B03-C 1 1.73E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.15E+03 8.2E-01 1.9E+00 6.0E+00
2.89E+03 6.5E-01 1.9E+00 6.0E+00
3.24E+03 4.6E-01 1.9E+00 6.0E+00 10 325
3.18E+03 7.9E+00 1.9E+00 6.0E+00
3.41 E+03 4.5E-01 1.9E+00 6.0E+00
3.53E+03 5.9E-01 1.9E+00 6.0E+00
3.33E+03 8.6E-01 1.9E+00 6.0E+00
2.28E+03 5.1E-01 1.9E+00 6.0E+00
1.49E+03 5.2E-01 1.9E+00 6.0E+00
2.02E+03 7.1E+00 1.9E+00 6.0E+00
2.85E+03 4.3E-01 1.9E+00 6.0E+00
2.95E+03 5.7E+00 1.9E+00 6.0E+00 10 325
3.21 E+03 5.3E+00 1.9E+00 6.0E+00
3.55E+03 3.4E-01 1.9E+00 6.0E+00
3.57E+03 3.1E-01 1.9E+00 6.0E+00
3.46E+03 3.9E+00 1.9E+00 6.0E+00
2.17E+03 3.3E-01 1.9E+00 6.0E+00
1.48E+03 2.0E+00 1.9E+00 6.0E+00
2.14E+03 1.6E+00 1.9E+00 6.0E+00
2.81 E+03 7.7E-02 1.9E+00 6.0E+00
3.02E+03 5.4E-01 1.9E+00 6.0E+00 10 325
2.81 E+03 1.1E+01 1.9E+00 6.0E+00
3.40E+03 6.0E-01 1.9E+00 6.0E+00
5.52E+03 1.3E+02 1.9E+00 6.0E+00
3.34E+03 8.1E-01 1.9E+00 6.0E+00
2.27E+03 2.3E-01 1.9E+00 6.0E+00
1.50E+03 6.8E-01 1.9E+00 6.0E+00
1.52E+01 7.1E+00 1.9E+00 6.0E+00
1.51E+01 9.1E+00 1.9E+00 6.0E+00
1.45E+01 7.5E+00 1.9E+00 6.0E+00
1.56E+01 8.4E+00 1.9E+00 6.0E+00
1.39E+01 8.8E+00 1.9E+00 6.0E+00
1.75E+01 3.4E+00 1.9E+00 6.0E+00
1.44E+01 6.1E+00 1.9E+00 6.0E+00
1.58E+01 1.0E+00 1.9E+00 6.0E+00
1.73E+01 3.7E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.07E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.87E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.76E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-162
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFA-L07-1313-T01-A 1
Mn EaFA-L07-1313-T02-A 1
Mn EaFA-L07-1313-T03-A 1
Mn EaFA-L07-1313-T04-A 1
Mn EaFA-L07-1313-T05-A 1
Mn EaFA-L07-1313-T06-A 1
Mn EaFA-L07-1313-T07-A 1
Mn EaFA-L07-1313-T08-A 1
Mn EaFA-L07-1313-T09-A 1
Mn EaFA-L07-1313-T01-B 1
Mn EaFA-L07-1313-T02-B 1
Mn EaFA-L07-1313-T03-B 1
Mn EaFA-L07-1313-T04-B 1
Mn EaFA-L07-1313-T05-B 1
Mn EaFA-L07-1313-T06-B 1
Mn EaFA-L07-1313-T07-B 1
Mn EaFA-L07-1313-T08-B 1
Mn EaFA-L07-1313-T09-B 1
Mn EaFA-L07-1313-T01-C 1
Mn EaFA-L07-1313-T02-C 1
Mn EaFA-L07-1313-T03-C 1
Mn EaFA-L07-1313-T04-C 1
Mn EaFA-L07-1313-T05-C 1
Mn EaFA-L07-1313-T06-C 1
Mn EaFA-L07-1313-T07-C 1
Mn EaFA-L07-1313-T08-C 1
Mn EaFA-L07-1313-T09-C 1
Mn EaFA-L07-1313-B01-A 1
Mn EaFA-L07-1313-B02-A 1
Mn EaFA-L07-1313-B03-A 1
Mn EaFA-L07-1313-B01-B 1
Mn EaFA-L07-1313-B02-B 1
Mn EaFA-L07-1313-B03-B 1
Mn EaFA-L07-1313-B01-C 1
Mn EaFA-L07-1313-B02-C 1
Mn EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
9.43E+01
4.67E+02
8.76E+02
1.15E+03
1.69E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.50E+00
1.51E+02
4.24E+02
8.83E+02
1.19E+03
1.65E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
8.83E+01
3.93E+02
8.70E+02
1.15E+03
1 .65E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00 10 325
1.00E+00 5.6E+00 2.0E+00 6.4E+00
9.43E+01 1.5E+00 2.0E+00 6.4E+00
4.67E+02 5.8E-01 2.0E+00 6.4E+00
8.76E+02 6.6E-01 2.0E+00 6.4E+00
1.15E+03 6.5E-01 2.0E+00 6.4E+00
1.69E+03 1.1E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 4.9E+01 2.0E+00 6.4E+00 10 325
6.50E+00 6.3E+00 2.0E+00 6.4E+00
1.51E+02 5.5E-01 2.0E+00 6.4E+00
4.24E+02 1.1E+00 2.0E+00 6.4E+00
8.83E+02 5.1E+00 2.0E+00 6.4E+00
1.19E+03 5.1E-01 2.0E+00 6.4E+00
1.65E+03 8.7E-01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 4.2E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.4E+01 2.0E+00 6.4E+00
8.83E+01 2.8E-01 2.0E+00 6.4E+00
3.93E+02 1.4E+02 2.0E+00 6.4E+00
8.70E+02 1.1E+00 2.0E+00 6.4E+00
1.15E+03 4.8E-01 2.0E+00 6.4E+00
1.65E+03 3.7E-01 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 8.8E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 5.6E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.21E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.16E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.11E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/101:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-163
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFA-L07-1313-T01-A 1
Mg EaFA-L07-1313-T02-A 1
Mg EaFA-L07-1313-T03-A 1
Mg EaFA-L07-1313-T04-A 1
Mg EaFA-L07-1313-T05-A 1
Mg EaFA-L07-1313-T06-A 1
Mg EaFA-L07-1313-T07-A 1
Mg EaFA-L07-1313-T08-A 1
Mg EaFA-L07-1313-T09-A 1
Mg EaFA-L07-1313-T01-B 1
Mg EaFA-L07-1313-T02-B 1
Mg EaFA-L07-1313-T03-B 1
Mg EaFA-L07-1313-T04-B 1
Mg EaFA-L07-1313-T05-B 1
Mg EaFA-L07-1313-T06-B 1
Mg EaFA-L07-1313-T07-B 1
Mg EaFA-L07-1313-T08-B 1
Mg EaFA-L07-1313-T09-B 1
Mg EaFA-L07-1313-T01-C 1
Mg EaFA-L07-1313-T02-C 1
Mg EaFA-L07-1313-T03-C 1
Mg EaFA-L07-1313-T04-C 1
Mg EaFA-L07-1313-T05-C 1
Mg EaFA-L07-1313-T06-C 1
Mg EaFA-L07-1313-T07-C 1
Mg EaFA-L07-1313-T08-C 1
Mg EaFA-L07-1313-T09-C 1
Mg EaFA-L07-1313-B01-A 1
Mg EaFA-L07-1313-B02-A 1
Mg EaFA-L07-1313-B03-A 1
Mg EaFA-L07-1313-B01-B 1
Mg EaFA-L07-1313-B02-B 1
Mg EaFA-L07-1313-B03-B 1
Mg EaFA-L07-1313-B01-C 1
Mg EaFA-L07-1313-B02-C 1
Mg EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
1.31E+02
3.21 E+03
6.21 E+03
7.59E+03
8.63E+03
8.12E+03
1.49E+04
5.00E-01 U1/2
5.00E-01 U1/2
1.36E+02
3.44E+03
7.03E+03
7.75E+03
8.86E+03
8.55E+03
1.44E+04
5.00E-01 U1/2
5.00E-01 U1/2
1.11E+02
2.80E+03
6.14E+03
7.52E+03
8.66E+03
8.08E+03
1.44E+04
5.00E-01 U1/2
5.00E-01 U1/2
6.25E+00
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 1.1 E+03 1.0E+00 3.2E+00
5.00E-01 1.3E+02 1.0E+00 3.2E+00
1.31E+02 4.4E+00 1.0E+00 3.2E+00 1000 100
3.21 E+03 7.2E+00 1.0E+00 3.2E+00
6.21 E+03 9.4E-01 1.0E+00 3.2E+00
7.59E+03 2.3E-01 1.0E+00 3.2E+00
8.63E+03 9.3E-01 1.0E+00 3.2E+00
8.12E+03 5.2E-01 1.0E+00 3.2E+00
1.49E+04 8.5E-01 1.0E+00 3.2E+00
5.00E-01 1.7E+02 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00
1.36E+02 2.1E+00 1.0E+00 3.2E+00 1000 100
3.44E+03 5.1E+00 1.0E+00 3.2E+00
7.03E+03 6.1E-01 1.0E+00 3.2E+00
7.75E+03 4.6E-01 1.0E+00 3.2E+00
8.86E+03 2.6E+00 1.0E+00 3.2E+00
8.55E+03 5.5E-01 1.0E+00 3.2E+00
1.44E+04 2.9E+00 1.0E+00 3.2E+00
5.00E-01 5.9E+02 1.0E+00 3.2E+00
5.00E-01 3.4E+02 1.0E+00 3.2E+00
1.11E+02 7.1E+00 1.0E+00 3.2E+00 1000 100
2.80E+03 4.3E+00 1.0E+00 3.2E+00
6.14E+03 5.1E-01 1.0E+00 3.2E+00
7.52E+03 1.4E+02 1.0E+00 3.2E+00
8.66E+03 1.7E+00 1.0E+00 3.2E+00
8.08E+03 5.0E-01 1.0E+00 3.2E+00
1.44E+04 5.4E-01 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
5.00E-01 9.9E+01 1.0E+00 3.2E+00
6.25E+00 1.4E+02 1.0E+00 3.2E+00
5.00E-01 3.8E+01 1.0E+00 3.2E+00
5.00E-01 4.6E+01 1.0E+00 3.2E+00
5.00E-01 5.6E+02 1.0E+00 3.2E+00
5.00E-01 4.3E+01 1.0E+00 3.2E+00
5.00E-01 8.4E+01 1 .OE+00 3.2E+00
5.00E-01 2.6E+01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.16E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .08E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/101:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-164
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo EaFA-L07-1313-T01-A 1
Mo EaFA-L07-1313-T02-A 1
Mo EaFA-L07-1313-T03-A 1
Mo EaFA-L07-1313-T04-A 1
Mo EaFA-L07-1313-T05-A 1
Mo EaFA-L07-1313-T06-A 1
Mo EaFA-L07-1313-T07-A 1
Mo EaFA-L07-1313-T08-A 1
Mo EaFA-L07-1313-T09-A 1
Mo EaFA-L07-1313-T01-B 1
Mo EaFA-L07-1313-T02-B 1
Mo EaFA-L07-1313-T03-B 1
Mo EaFA-L07-1313-T04-B 1
Mo EaFA-L07-1313-T05-B 1
Mo EaFA-L07-1313-T06-B 1
Mo EaFA-L07-1313-T07-B 1
Mo EaFA-L07-1313-T08-B 1
Mo EaFA-L07-1313-T09-B 1
Mo EaFA-L07-1313-T01-C 1
Mo EaFA-L07-1313-T02-C 1
Mo EaFA-L07-1313-T03-C 1
Mo EaFA-L07-1313-T04-C 1
Mo EaFA-L07-1313-T05-C 1
Mo EaFA-L07-1313-T06-C 1
Mo EaFA-L07-1313-T07-C 1
Mo EaFA-L07-1313-T08-C 1
Mo EaFA-L07-1313-T09-C 1
Mo EaFA-L07-1313-B01-A 1
Mo EaFA-L07-1313-B02-A 1
Mo EaFA-L07-1313-B03-A 1
Mo EaFA-L07-1313-B01-B 1
Mo EaFA-L07-1313-B02-B 1
Mo EaFA-L07-1313-B03-B 1
Mo EaFA-L07-1313-B01-C 1
Mo EaFA-L07-1313-B02-C 1
Mo EaFA-L07-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
4.06E+03
4.12E+03
4.13E+03
3.79E+03
3.68E+03
3.12E+03
2.94E+02
1.27E+02
4.80E+02
3.70E+03
4.01 E+03
3.72E+03
3.62E+03
3.63E+03
3.17E+03
3.12E+02
1.21E+02
3.61 E+02
4.03E+03
4.01 E+03
3.89E+03
3.36E+03
3.68E+03
3.49E+03
3.16E+02
1.29E+02
4.06E+02
6.00E-01 U1/2
6.00E-01 U1/2
6.00E-01 U1/2
6.00E-01 U1/2
6.00E-01 U1/2
2.49E+00 E
6.00E-01 U1/2
1.60E+00 E
2.01 E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.06E+03 4.4E-01 1.2E+00 3.8E+00
4.12E+03 9.5E-01 1.2E+00 3.8E+00
4.13E+03 5.7E-01 1.2E+00 3.8E+00 10 325
3.79E+03 4.5E+00 1.2E+00 3.8E+00
3.68E+03 7.4E-01 1.2E+00 3.8E+00
3.12E+03 6.8E-01 1.2E+00 3.8E+00
2.94E+02 7.6E-01 1.2E+00 3.8E+00
1.27E+02 3.0E+00 1.2E+00 3.8E+00
4.80E+02 4.4E-01 1.2E+00 3.8E+00
3.70E+03 7.7E+00 1.2E+00 3.8E+00
4.01 E+03 4.4E-01 1.2E+00 3.8E+00
3.72E+03 6.1E+00 1.2E+00 3.8E+00 10 325
3.62E+03 4.5E+00 1.2E+00 3.8E+00
3.63E+03 6.0E-01 1.2E+00 3.8E+00
3.17E+03 1.3E+00 1.2E+00 3.8E+00
3.12E+02 6.2E+00 1.2E+00 3.8E+00
1.21 E+02 1.2E+00 1.2E+00 3.8E+00
3.61 E+02 7.1E-01 1.2E+00 3.8E+00
4.03E+03 2.3E-01 1.2E+00 3.8E+00
4.01 E+03 7.5E-01 1.2E+00 3.8E+00
3.89E+03 7.4E-01 1.2E+00 3.8E+00 10 325
3.36E+03 5.6E+00 1.2E+00 3.8E+00
3.68E+03 7.8E-01 1.2E+00 3.8E+00
3.49E+03 1.5E+02 1.2E+00 3.8E+00
3.16E+02 4.1E-01 1.2E+00 3.8E+00
1.29E+02 1.1 E+00 1.2E+00 3.8E+00
4.06E+02 6.1E-01 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.00E-01 7.6E+01 1.2E+00 3.8E+00
6.00E-01 9.7E+01 1.2E+00 3.8E+00
6.00E-01 3.7E+01 1.2E+00 3.8E+00
6.00E-01 2.6E+02 1.2E+00 3.8E+00
2.49E+00 7.6E+01 1.2E+00 3.8E+00
6.00E-01 2.5E+02 1.2E+00 3.8E+00
1.60E+00 1.4E+02 1.2E+00 3.8E+00
2.01 E+00 2.0E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.92E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.17E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.73E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-165
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFA-L07-1313-T01-A 1
Ni EaFA-L07-1313-T02-A 1
Ni EaFA-L07-1313-T03-A 1
Ni EaFA-L07-1313-T04-A 1
Ni EaFA-L07-1313-T05-A 1
Ni EaFA-L07-1313-T06-A 1
Ni EaFA-L07-1313-T07-A 1
Ni EaFA-L07-1313-T08-A 1
Ni EaFA-L07-1313-T09-A 1
Ni EaFA-L07-1313-T01-B 1
Ni EaFA-L07-1313-T02-B 1
Ni EaFA-L07-1313-T03-B 1
Ni EaFA-L07-1313-T04-B 1
Ni EaFA-L07-1313-T05-B 1
Ni EaFA-L07-1313-T06-B 1
Ni EaFA-L07-1313-T07-B 1
Ni EaFA-L07-1313-T08-B 1
Ni EaFA-L07-1313-T09-B 1
Ni EaFA-L07-1313-T01-C 1
Ni EaFA-L07-1313-T02-C 1
Ni EaFA-L07-1313-T03-C 1
Ni EaFA-L07-1313-T04-C 1
Ni EaFA-L07-1313-T05-C 1
Ni EaFA-L07-1313-T06-C 1
Ni EaFA-L07-1313-T07-C 1
Ni EaFA-L07-1313-T08-C 1
Ni EaFA-L07-1313-T09-C 1
Ni EaFA-L07-1313-B01-A 1
Ni EaFA-L07-1313-B02-A 1
Ni EaFA-L07-1313-B03-A 1
Ni EaFA-L07-1313-B01-B 1
Ni EaFA-L07-1313-B02-B 1
Ni EaFA-L07-1313-B03-B 1
Ni EaFA-L07-1313-B01-C 1
Ni EaFA-L07-1313-B02-C 1
Ni EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.28E+01
1.60E+02
5.93E+02
4.81 E+02
7.34E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
4.32E+00 E
4.49E+01
1.36E+02
6.15E+02
4.85E+02
7.12E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.30E+01
1.27E+02
5.87E+02
4.77E+02
7.03E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
3.51 E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
2.25E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.4E+02 1.8E+00 5.7E+00
9.00E-01 3.3E+02 1.8E+00 5.7E+00
9.00E-01 2.3E+03 1.8E+00 5.7E+00 10 325
9.00E-01 5.2E+02 1.8E+00 5.7E+00
2.28E+01 5.6E+00 1.8E+00 5.7E+00
1.60E+02 8.4E-01 1.8E+00 5.7E+00
5.93E+02 1.3E+00 1.8E+00 5.7E+00
4.81 E+02 1.0E+00 1.8E+00 5.7E+00
7.34E+02 1.4E-01 1.8E+00 5.7E+00
9.00E-01 1.1E+03 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00
9.00E-01 8.4E+01 1.8E+00 5.7E+00 10 325
4.32E+00 1.9E+02 1.8E+00 5.7E+00
4.49E+01 3.0E+00 1.8E+00 5.7E+00
1.36E+02 3.6E+00 1.8E+00 5.7E+00
6.15E+02 5.4E+00 1.8E+00 5.7E+00
4.85E+02 3.1E-01 1.8E+00 5.7E+00
7.12E+02 1.1E+00 1.8E+00 5.7E+00
9.00E-01 9.9E+01 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 2.3E+02 1.8E+00 5.7E+00 10 325
9.00E-01 3.6E+02 1.8E+00 5.7E+00
2.30E+01 1.9E+01 1.8E+00 5.7E+00
1.27E+02 1.8E+02 1.8E+00 5.7E+00
5.87E+02 7.6E-01 1.8E+00 5.7E+00
4.77E+02 5.8E-01 1.8E+00 5.7E+00
7.03E+02 2.5E-01 1.8E+00 5.7E+00
9.00E-01 2.4E+01 1.8E+00 5.7E+00
9.00E-01 4.5E+02 1.8E+00 5.7E+00
9.00E-01 4.9E+02 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 3.8E+02 1.8E+00 5.7E+00
3.51 E+00 1.8E+02 1.8E+00 5.7E+00
9.00E-01 1.1 E+02 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
2.25E+00 1.8E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.15E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.15E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.03E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-166
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qu
1 1 ug/L
P EaFA-L07-1313-T01-A 1 6.82E+01
P EaFA-L07-1313-T02-A 1 5.03E+01
P EaFA-L07-1313-T03-A 1 6.60E+01
P EaFA-L07-1313-T04-A 1 1.01E+02
P EaFA-L07-1313-T05-A 1 5.44E+01
P EaFA-L07-1313-T06-A 1 2.99E+01
P EaFA-L07-1313-T07-A 1 4.21 E+01
P EaFA-L07-1313-T08-A 1 5.73E+01
P EaFA-L07-1313-T09-A 1 3.54E+03
P EaFA-L07-1313-T01-B 1 9.59E+01
P EaFA-L07-1313-T02-B 1 5.09E+01
P EaFA-L07-1313-T03-B 1 6.56E+01
P EaFA-L07-1313-T04-B 1 9.33E+01
P EaFA-L07-1313-T05-B 1 5.18E+01
P EaFA-L07-1313-T06-B 1 3.69E+01
P EaFA-L07-1313-T07-B 1 4.65E+01
P EaFA-L07-1313-T08-B 1 7.09E+01
P EaFA-L07-1313-T09-B 1 2.42E+03
P EaFA-L07-1313-T01-C 1 1.16E+02
P EaFA-L07-1313-T02-C 1 4.41 E+01
P EaFA-L07-1313-T03-C 1 6.36E+01
P EaFA-L07-1313-T04-C 1 8.09E+01
P EaFA-L07-1313-T05-C 1 5.29E+01
P EaFA-L07-1313-T06-C 1 1.74E+01
P EaFA-L07-1313-T07-C 1 4.38E+01
P EaFA-L07-1313-T08-C 1 6.72E+01
P EaFA-L07-1313-T09-C 1 2.73E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.82E+01 1.1 E+01 3.7E+00 1.2E+01
5.03E+01 7.0E+00 3.7E+00 1 .2E+01
6.60E+01 7.7E+00 3.7E+00 1 .2E+01 1000 100
1.01E+02 9.7E+00 3.7E+00 1 .2E+01
5.44E+01 7.7E+00 3.7E+00 1 .2E+01
2.99E+01 3.6E+01 3.7E+00 1 .2E+01
4.21 E+01 8.5E+00 3.7E+00 1.2E+01
5.73E+01 9.9E+00 3.7E+00 1.2E+01
3.54E+03 3.5E-01 3.7E+00 1.2E+01
9.59E+01 1.5E+01 3.7E+00 1.2E+01
5.09E+01 2.2E+01 3.7E+00 1.2E+01
6.56E+01 1.6E+01 3.7E+00 1.2E+01 1000 100
9.33E+01 1.5E+01 3.7E+00 1.2E+01
5.18E+01 1.2E+01 3.7E+00 1.2E+01
3.69E+01 1.5E+01 3.7E+00 1.2E+01
4.65E+01 1.8E+01 3.7E+00 1.2E+01
7.09E+01 6.2E+00 3.7E+00 1.2E+01
2.42E+03 1.7E+00 3.7E+00 1.2E+01
1.16E+02 1.1E+01 3.7E+00 1.2E+01
4.41E+01 1.7E+01 3.7E+00 1.2E+01
6.36E+01 2.1E+01 3.7E+00 1.2E+01 1000 100
8.09E+01 1.3E+01 3.7E+00 1.2E+01
5.29E+01 1.3E+01 3.7E+00 1.2E+01
1.74E+01 1.7E+02 3.7E+00 1.2E+01
4.38E+01 2.7E+01 3.7E+00 1.2E+01
6.72E+01 5.3E+00 3.7E+00 1.2E+01
2.73E+03 6.6E-01 3.7E+00 1.2E+01
P EaFA-L07-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 3.0E+02 3.7E+00 1.2E+01
P EaFA-L07-1313-B02-A 1 1.51 E+01
P EaFA-L07-1313-B03-A 1 1.36E+01
P EaFA-L07-1313-B01-B 1 8.52E+00 E
P EaFA-L07-1313-B02-B 1 6.56E+00 E
P EaFA-L07-1313-B03-B 1 2.02E+01
P EaFA-L07-1313-B01-C 1 5.31E+00 E
P EaFA-L07-1313-B02-C 1 3.86E+00 E
1.51E+01 3.1E+01 3.7E+00 1.2E+01
1.36E+01 5.7E+01 3.7E+00 1.2E+01
8.52E+00 9.1 E+01 3.7E+00 1.2E+01
6.56E+00 1.2E+02 3.7E+00 1.2E+01
2.02E+01 4.7E+01 3.7E+00 1.2E+01
5.31 E+00 1.3E+02 3.7E+00 1.2E+01
3.86E+00 1.0E+02 3.7E+00 1.2E+01
P EaFA-L07-1313-B03-C 1 1.85E+OOU1/2 1.85E+00 4.2E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .04E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-167
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
1 ug/L
K EaFA-L07-1313-T01-A 1 5.04E+04
K EaFA-L07-1313-T02-A 1 3.46E+04
K EaFA-L07-1313-T03-A 1 2.91E+04
K EaFA-L07-1313-T04-A 1 2.61E+04
K EaFA-L07-1313-T05-A 1 2.58E+04
K EaFA-L07-1313-T06-A 1 2.64E+04
K EaFA-L07-1313-T07-A 1 2.64E+04
K EaFA-L07-1313-T08-A 1 1.95E+04
K EaFA-L07-1313-T09-A 1 2.38E+04
K EaFA-L07-1313-T01-B 1 4.73E+04
K EaFA-L07-1313-T02-B 1 3.42E+04
K EaFA-L07-1313-T03-B 1 2.64E+04
K EaFA-L07-1313-T04-B 1 2.59E+04
K EaFA-L07-1313-T05-B 1 2.68E+04
K EaFA-L07-1313-T06-B 1 2.68E+04
K EaFA-L07-1313-T07-B 1 2.74E+04
K EaFA-L07-1313-T08-B 1 1.92E+04
K EaFA-L07-1313-T09-B 1 2.31E+04
K EaFA-L07-1313-T01-C 1 5.09E+04
K EaFA-L07-1313-T02-C 1 3.37E+04
K EaFA-L07-1313-T03-C 1 2.72E+04
K EaFA-L07-1313-T04-C 1 2.28E+04
K EaFA-L07-1313-T05-C 1 2.55E+04
K EaFA-L07-1313-T06-C 1 2.35E+04
K EaFA-L07-1313-T07-C 1 2.64E+04
K EaFA-L07-1313-T08-C 1 1 .96E+04
K EaFA-L07-1313-T09-C 1 2.29E+04
K EaFA-L07-1313-B01-A 1 1.18E+01
K EaFA-L07-1313-B02-A 1 9.73E+00
K EaFA-L07-1313-B03-A 1 1 .93E+02
K EaFA-L07-1313-B01-B 1 1 .43E+01
K EaFA-L07-1313-B02-B 1 1 .30E+01
K EaFA-L07-1313-B03-B 1 1 .94E+02
K EaFA-L07-1313-B01-C 1 1.31E+01
K EaFA-L07-1313-B02-C 1 1 .25E+01
K EaFA-L07-1313-B03-C 1 1 .84E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.04E+04 7.6E-01 1.6E+00 5.1E+00
3.46E+04 1.7E-01 1.6E+00 5.1E+00
2.91E+04 5.9E-01 1.6E+00 5.1E+00 1000 100
2.61 E+04 6.0E+00 1.6E+00 5.1E+00
2.58E+04 1.4E-01 1.6E+00 5.1E+00
2.64E+04 9.9E-01 1.6E+00 5.1E+00
2.64E+04 7.7E-01 1.6E+00 5.1E+00
1.95E+04 8.9E-01 1.6E+00 5.1E+00
2.38E+04 4.9E-01 1.6E+00 5.1E+00
4.73E+04 8.0E+00 1.6E+00 5.1E+00
3.42E+04 9.7E-01 1.6E+00 5.1E+00
2.64E+04 6.6E+00 1.6E+00 5.1E+00 1000 100
2.59E+04 5.6E+00 1.6E+00 5.1E+00
2.68E+04 9.4E-01 1.6E+00 5.1E+00
2.68E+04 2.3E-01 1.6E+00 5.1E+00
2.74E+04 4.8E+00 1.6E+00 5.1E+00
1.92E+04 5.7E-01 1.6E+00 5.1E+00
2.31E+04 2.1E+00 1.6E+00 5.1E+00
5.09E+04 1.1E+00 1.6E+00 5.1E+00
3.37E+04 2.3E-01 1.6E+00 5.1E+00
2.72E+04 1.2E-01 1.6E+00 5.1E+00 1000 100
2.28E+04 9.4E+00 1.6E+00 5.1E+00
2.55E+04 1.6E-01 1.6E+00 5.1E+00
2.35E+04 1.4E+02 1.6E+00 5.1E+00
2.64E+04 9.6E-01 1.6E+00 5.1E+00
1.96E+04 6.0E-01 1.6E+00 5.1E+00
2.29E+04 3.3E-01 1.6E+00 5.1E+00
1.18E+01 5.1E+01 1.6E+00 5.1E+00
9.73E+00 1.1E+01 1.6E+00 5.1E+00
1.93E+02 5.3E+00 1.6E+00 5.1E+00
1.43E+01 2.7E+01 1.6E+00 5.1E+00
1.30E+01 2.2E+01 1.6E+00 5.1E+00
1.94E+02 2.8E+00 1.6E+00 5.1E+00
1.31E+01 9.0E+00 1.6E+00 5.1E+00
1.25E+01 2.1E+01 1.6E+00 5.1E+00
1.84E+02 3.2E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.01 E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.74E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.81E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/101:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-168
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se EaFA-L07-1313-T01-A 1
Se EaFA-L07-1313-T02-A 1
Se EaFA-L07-1313-T03-A 1
Se EaFA-L07-1313-T04-A 1
Se EaFA-L07-1313-T05-A 1
Se EaFA-L07-1313-T06-A 1
Se EaFA-L07-1313-T07-A 1
Se EaFA-L07-1313-T08-A 1
Se EaFA-L07-1313-T09-A 1
Se EaFA-L07-1313-T01-B 1
Se EaFA-L07-1313-T02-B 1
Se EaFA-L07-1313-T03-B 1
Se EaFA-L07-1313-T04-B 1
Se EaFA-L07-1313-T05-B 1
Se EaFA-L07-1313-T06-B 1
Se EaFA-L07-1313-T07-B 1
Se EaFA-L07-1313-T08-B 1
Se EaFA-L07-1313-T09-B 1
Se EaFA-L07-1313-T01-C 1
Se EaFA-L07-1313-T02-C 1
Se EaFA-L07-1313-T03-C 1
Se EaFA-L07-1313-T04-C 1
Se EaFA-L07-1313-T05-C 1
Se EaFA-L07-1313-T06-C 1
Se EaFA-L07-1313-T07-C 1
Se EaFA-L07-1313-T08-C 1
Se EaFA-L07-1313-T09-C 1
Se EaFA-L07-1313-B01-A 1
Se EaFA-L07-1313-B02-A 1
Se EaFA-L07-1313-B03-A 1
Se EaFA-L07-1313-B01-B 1
Se EaFA-L07-1313-B02-B 1
Se EaFA-L07-1313-B03-B 1
Se EaFA-L07-1313-B01-C 1
Se EaFA-L07-1313-B02-C 1
Se EaFA-L07-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
6.65E+03
5.62E+03
5.06E+03
3.29E+03
1.63E+03
9.35E+02
1.81E+02
8.34E+01
9.27E+02
6.42E+03
5.71 E+03
4.77E+03
2.84E+03
1.56E+03
1.01 E+03
1 JOE+02
3.66E+01 E
6.14E+02
6.66E+03
5.49E+03
4.71 E+03
2.95E+03
1.81 E+03
1.13E+03
1 J7E+02
9.43E+01
7.16E+02
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.65E+03 1.2E+00 1.5E+01 4.8E+01
5.62E+03 1.4E+00 1.5E+01 4.8E+01
5.06E+03 7.4E-01 1.5E+01 4.8E+01 10 325
3.29E+03 6.2E+00 1.5E+01 4.8E+01
1.63E+03 1.0E+00 1.5E+01 4.8E+01
9.35E+02 1.7E+00 1.5E+01 4.8E+01
1.81E+02 2.1E+01 1.5E+01 4.8E+01
8.34E+01 1.0E+01 1.5E+01 4.8E+01
9.27E+02 1.3E+00 1.5E+01 4.8E+01
6.42E+03 7.1E+00 1.5E+01 4.8E+01
5.71 E+03 2.2E-01 1.5E+01 4.8E+01
4.77E+03 5.8E+00 1.5E+01 4.8E+01 10 325
2.84E+03 4.0E+00 1.5E+01 4.8E+01
1.56E+03 1.7E+00 1.5E+01 4.8E+01
1.01 E+03 2.1E+00 1.5E+01 4.8E+01
1.70E+02 1.3E+01 1.5E+01 4.8E+01
3.66E+01 6.7E+01 1 .5E+01 4.8E+01
6.14E+02 2.9E+00 1 .5E+01 4.8E+01
6.66E+03 1.7E+00 1 .5E+01 4.8E+01
5.49E+03 1.8E+00 1 .5E+01 4.8E+01
4.71E+03 3.2E-01 1 .5E+01 4.8E+01 10 325
2.95E+03 8.6E+00 1 .5E+01 4.8E+01
1.81 E+03 9.2E-01 1 .5E+01 4.8E+01
1.13E+03 1.7E+02 1 .5E+01 4.8E+01
1.77E+02 1.4E+01 1 .5E+01 4.8E+01
9.43E+01 1.5E+01 1 .5E+01 4.8E+01
7.16E+02 3.3E+00 1 .5E+01 4.8E+01
7.50E+00 1.1E+02 1 .5E+01 4.8E+01
7.50E+00 1.3E+02 1.5E+01 4.8E+01
7.50E+00 1.3E+02 1.5E+01 4.8E+01
7.50E+00 2.0E+02 1.5E+01 4.8E+01
7.50E+00 1.3E+03 1.5E+01 4.8E+01
7.50E+00 3.3E+02 1.5E+01 4.8E+01
7.50E+00 6.7E+02 1.5E+01 4.8E+01
7.50E+00 2.5E+01 1.5E+01 4.8E+01
7.50E+00 5.5E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.83E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.60E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.46E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/101:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-169
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone.
1 1 ug/L
Si EaFA-L07-1313-T01-A 1 1.30E+03
Si EaFA-L07-1313-T02-A 1 3.49E+03
Si EaFA-L07-1313-T03-A 1 1.16E+03
Si EaFA-L07-1313-T04-A 1 3.64E+02
Si EaFA-L07-1313-T05-A 1 1.07E+03
Si EaFA-L07-1313-T06-A 1 2.78E+03
Si EaFA-L07-1313-T07-A 1 6.69E+03
Si EaFA-L07-1313-T08-A 1 2.31E+04
Si EaFA-L07-1313-T09-A 1 7.03E+04
Si EaFA-L07-1313-T01-B 1 9.02E+03
Si EaFA-L07-1313-T02-B 1 3.39E+03
Si EaFA-L07-1313-T03-B 1 9.45E+02
Si EaFA-L07-1313-T04-B 1 4.45E+02
Si EaFA-L07-1313-T05-B 1 1.40E+03
Si EaFA-L07-1313-T06-B 1 2.53E+03
Si EaFA-L07-1313-T07-B 1 6.79E+03
Si EaFA-L07-1313-T08-B 1 2.79E+04
Si EaFA-L07-1313-T09-B 1 6.85E+04
Si EaFA-L07-1313-T01-C 1 9.86E+03
Si EaFA-L07-1313-T02-C 1 3.64E+03
Si EaFA-L07-1313-T03-C 1 1.28E+03
Si EaFA-L07-1313-T04-C 1 3.49E+02
Si EaFA-L07-1313-T05-C 1 1.21E+03
Si EaFA-L07-1313-T06-C 1 2.60E+03
Si EaFA-L07-1313-T07-C 1 6.85E+03
Si EaFA-L07-1313-T08-C 1 2.32E+04
Si EaFA-L07-1313-T09-C 1 6.88E+04
Si EaFA-L07-1313-B01-A 1 4.05E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.30E+03 3.5E-01 1.1E+00 3.5E+00
3.49E+03 2.0E-01 1.1E+00 3.5E+00
1.16E+03 4.9E-01 1.1E+00 3.5E+00 1000 100
3.64E+02 6.7E+00 1.1E+00 3.5E+00
1.07E+03 3.1E-01 1.1E+00 3.5E+00
2.78E+03 4.6E-01 1.1E+00 3.5E+00
6.69E+03 1.7E-01 1.1E+00 3.5E+00
2.31 E+04 1.1E-01 1.1E+00 3.5E+00
7.03E+04 3.0E-01 1.1E+00 3.5E+00
9.02E+03 7.4E+00 1.1E+00 3.5E+00
3.39E+03 4.0E-01 1.1E+00 3.5E+00
9.45E+02 5.4E+00 1.1E+00 3.5E+00 1000 100
4.45E+02 5.9E+00 1.1E+00 3.5E+00
1.40E+03 9.7E-01 1.1E+00 3.5E+00
2.53E+03 1.3E+00 1.1E+00 3.5E+00
6.79E+03 5.5E+00 1.1E+00 3.5E+00
2.79E+04 1.9E-01 1.1E+00 3.5E+00
6.85E+04 1.2E+00 1.1E+00 3.5E+00
9.86E+03 8.5E-01 1.1E+00 3.5E+00
3.64E+03 3.2E-01 1.1E+00 3.5E+00
1.28E+03 5.7E-02 1.1E+00 3.5E+00 1000 100
3.49E+02 1.1E+01 1.1E+00 3.5E+00
1.21E+03 5.1E-01 1.1E+00 3.5E+00
2.60E+03 1.5E+02 1.1E+00 3.5E+00
6.85E+03 8.8E-01 1.1E+00 3.5E+00
2.32E+04 3.5E-01 1.1E+00 3.5E+00
6.88E+04 5.7E-01 1.1E+00 3.5E+00
4.05E+01 2.0E+02 1.1E+00 3.5E+00
Si EaFA-L07-1313-B02-A 1 5.50E-01 U1/2 5.50E-01 3.4E+01 1.1E+00 3.5E+00
Si EaFA-L07-1313-B03-A 1 5.50E-01 U1/2 5.50E-01 1.2E+03 1.1E+00 3.5E+00
Si EaFA-L07-1313-B01-B 1 5.50E-01 U1/2 5.50E-01 5.4E+01 1.1E+00 3.5E+00
Si EaFA-L07-1313-B02-B 1 5.50E-01 U1/2 5.50E-01 2.9E+02 1.1E+00 3.5E+00
Si EaFA-L07-1313-B03-B 1 5.67E+00
5.67E+00 5.5E+01 1.1E+00 3.5E+00
Si EaFA-L07-1313-B01-C 1 5.50E-01 U1/2 5.50E-01 5.7E+01 1.1E+00 3.5E+00
Si EaFA-L07-1313-B02-C 1 5.50E-01 U1/2 5.50E-01 2.4E+02 1.1E+00 3.5E+00
Si EaFA-L07-1313-B03-C 1 1.67E+OOE 1.67E+00 2.2E+02 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.10E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.96E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.19E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-170
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone.
1 1 ug/L
Na EaFA-L07-1313-T01-A 1 3.26E+05
Na EaFA-L07-1313-T02-A 1 1.22E+05
Na EaFA-L07-1313-T03-A 1 5.43E+04
Na EaFA-L07-1313-T04-A 1 2.84E+04
Na EaFA-L07-1313-T05-A 1 1.28E+04
Na EaFA-L07-1313-T06-A 1 5.38E+03
Na EaFA-L07-1313-T07-A 1 5.14E+03
Na EaFA-L07-1313-T08-A 1 3.74E+03
Na EaFA-L07-1313-T09-A 1 3.11E+03
Na EaFA-L07-1313-T01-B 1 2.96E+05
Na EaFA-L07-1313-T02-B 1 1.19E+05
Na EaFA-L07-1313-T03-B 1 4.98E+04
Na EaFA-L07-1313-T04-B 1 2.37E+04
Na EaFA-L07-1313-T05-B 1 1.10E+04
Na EaFA-L07-1313-T06-B 1 5.43E+03
Na EaFA-L07-1313-T07-B 1 5.37E+03
Na EaFA-L07-1313-T08-B 1 3.62E+03
Na EaFA-L07-1313-T09-B 1 3.05E+03
Na EaFA-L07-1313-T01-C 1 3.03E+05
Na EaFA-L07-1313-T02-C 1 1.19E+05
Na EaFA-L07-1313-T03-C 1 5.15E+04
Na EaFA-L07-1313-T04-C 1 2.52E+04
Na EaFA-L07-1313-T05-C 1 1.28E+04
Na EaFA-L07-1313-T06-C 1 5.42E+03
Na EaFA-L07-1313-T07-C 1 5.21E+03
Na EaFA-L07-1313-T08-C 1 3.72E+03
Na EaFA-L07-1313-T09-C 1 3.11E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.26E+05 2.4E-02 2.5E+00 8.0E+00
1.22E+05 6.5E-01 2.5E+00 8.0E+00
5.43E+04 3.9E-01 2.5E+00 8.0E+00 1000 100
2.84E+04 6.4E+00 2.5E+00 8.0E+00
1.28E+04 6.1E-01 2.5E+00 8.0E+00
5.38E+03 8.2E-01 2.5E+00 8.0E+00
5.14E+03 3.0E-01 2.5E+00 8.0E+00
3.74E+03 1.2E+00 2.5E+00 8.0E+00
3.11E+03 4.5E-01 2.5E+00 8.0E+00
2.96E+05 4.6E+00 2.5E+00 8.0E+00
1.19E+05 3.0E-01 2.5E+00 8.0E+00
4.98E+04 5.2E+00 2.5E+00 8.0E+00 1000 100
2.37E+04 5.2E+00 2.5E+00 8.0E+00
1.10E+04 4.4E-01 2.5E+00 8.0E+00
5.43E+03 3.5E-01 2.5E+00 8.0E+00
5.37E+03 4.6E+00 2.5E+00 8.0E+00
3.62E+03 2.5E-01 2.5E+00 8.0E+00
3.05E+03 2.2E+00 2.5E+00 8.0E+00
3.03E+05 9.1E-01 2.5E+00 8.0E+00
1.19E+05 2.6E-01 2.5E+00 8.0E+00
5.15E+04 8.5E-01 2.5E+00 8.0E+00 1000 100
2.52E+04 1. OE+01 2.5E+00 8.0E+00
1.28E+04 1.5E-01 2.5E+00 8.0E+00
5.42E+03 1.3E+02 2.5E+00 8.0E+00
5.21 E+03 1.0E+00 2.5E+00 8.0E+00
3.72E+03 4.5E-01 2.5E+00 8.0E+00
3.11 E+03 1.1E+00 2.5E+00 8.0E+00
Na EaFA-L07-1313-B01-A 1 3.85E+00 E 3.85E+00 2.7E+00 2.5E+00 8.0E+00
Na EaFA-L07-1313-B02-A 1 3.36E+00 E 3.36E+00 1 .4E+01 2.5E+00 8.0E+00
Na EaFA-L07-1313-B03-A 1 3.09E+05
3.09E+05 3.3E+00 2.5E+00 8.0E+00
Na EaFA-L07-1313-B01-B 1 5.64E+00 E 5.64E+00 7.1E+00 2.5E+00 8.0E+00
Na EaFA-L07-1313-B02-B 1 3.82E+00 E 3.82E+00 2.2E+00 2.5E+00 8.0E+00
Na EaFA-L07-1313-B03-B 1 3.20E+05
3.20E+05 1.4E-01 2.5E+00 8.0E+00
Na EaFA-L07-1313-B01-C 1 3.79E+00 E 3.79E+00 1 .OE+01 2.5E+00 8.0E+00
Na EaFA-L07-1313-B02-C 1 3.42E+00 E 3.42E+00 7.3E+00 2.5E+00 8.0E+00
Na EaFA-L07-1313-B03-C 1 3.16E+05
3.16E+05 2.5E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.52E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.10E+04 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.25E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-171
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone.
1 ug/L
EaFA-L07-1313-T01-A 1 1.07E+03
EaFA-L07-1313-T02-A 1 1.71E+03
EaFA-L07-1313-T03-A 1 1.85E+03
EaFA-L07-1313-T04-A 1 1.91E+03
EaFA-L07-1313-T05-A 1 2.09E+03
EaFA-L07-1313-T06-A 1 2.23E+03
EaFA-L07-1313-T07-A 1 2.72E+03
EaFA-L07-1313-T08-A 1 3.27E+03
EaFA-L07-1313-T09-A 1 5.56E+03
EaFA-L07-1313-T01-B 1 1.38E+03
EaFA-L07-1313-T02-B 1 1.71E+03
EaFA-L07-1313-T03-B 1 1.72E+03
EaFA-L07-1313-T04-B 1 1.91E+03
EaFA-L07-1313-T05-B 1 2.19E+03
EaFA-L07-1313-T06-B 1 2.25E+03
EaFA-L07-1313-T07-B 1 2.80E+03
EaFA-L07-1313-T08-B 1 3.53E+03
EaFA-L07-1313-T09-B 1 5.37E+03
EaFA-L07-1313-T01-C 1 1 .40E+03
EaFA-L07-1313-T02-C 1 1 .64E+03
EaFA-L07-1313-T03-C 1 1 J3E+03
EaFA-L07-1313-T04-C 1 1 .68E+03
EaFA-L07-1313-T05-C 1 2.08E+03
EaFA-L07-1313-T06-C 1 2.23E+03
EaFA-L07-1313-T07-C 1 2.71E+03
EaFA-L07-1313-T08-C 1 3.26E+03
EaFA-L07-1313-T09-C 1 5.41E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.07E+03 2.7E-01 1.0E+00 3.2E+00
1.71E+03 8.9E-01 1.0E+00 3.2E+00
1.85E+03 7.8E-01 1.0E+00 3.2E+00 1000 100
1.91E+03 4.4E+00 1.0E+00 3.2E+00
2.09E+03 1.3E+00 1.0E+00 3.2E+00
2.23E+03 3.5E-01 1.0E+00 3.2E+00
2.72E+03 1.1E+00 1.0E+00 3.2E+00
3.27E+03 6.1E-01 1.0E+00 3.2E+00
5.56E+03 7.2E-01 1.0E+00 3.2E+00
1.38E+03 7.3E+00 1.0E+00 3.2E+00
1.71E+03 3.7E-01 1.0E+00 3.2E+00
1.72E+03 6.7E+00 1.0E+00 3.2E+00 1000 100
1.91E+03 4.7E+00 1.0E+00 3.2E+00
2.19E+03 2.9E-01 1.0E+00 3.2E+00
2.25E+03 1.0E+00 1.0E+00 3.2E+00
2.80E+03 5.8E+00 1.0E+00 3.2E+00
3.53E+03 1.1E+00 1.0E+00 3.2E+00
5.37E+03 3.0E+00 1.0E+00 3.2E+00
1.40E+03 5.6E-01 1.0E+00 3.2E+00
1.64E+03 9.6E-02 1.0E+00 3.2E+00
1.73E+03 5.8E-01 1.0E+00 3.2E+00 1000 100
1.68E+03 5.6E+00 1.0E+00 3.2E+00
2.08E+03 1.2E+00 1.0E+00 3.2E+00
2.23E+03 1.5E+02 1.0E+00 3.2E+00
2.71E+03 1.0E+00 1.0E+00 3.2E+00
3.26E+03 1.3E+00 1.0E+00 3.2E+00
5.41 E+03 3.9E-01 1.0E+00 3.2E+00
EaFA-L07-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 1.6E+01 1.0E+00 3.2E+00
EaFA-L07-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 7.2E+00 1.0E+00 3.2E+00
EaFA-L07-1313-B03-A 1 5.00E-01 U1/2 5.00E-01 1.9E+02 1.0E+00 3.2E+00
EaFA-L07-1313-B01-B 1 5.00E-01 U1/2 5.00E-01 3.9E+01 1.0E+00 3.2E+00
EaFA-L07-1313-B02-B 1 5.00E-01 U1/2 5.00E-01 1.8E+01 1.0E+00 3.2E+00
EaFA-L07-1313-B03-B 1 5.00E-01 U1/2 5.00E-01 2.7E+02 1.0E+00 3.2E+00
EaFA-L07-1313-B01-C 1 5.00E-01 U1/2 5.00E-01 1.7E+01 1.0E+00 3.2E+00
EaFA-L07-1313-B02-C 1 5.00E-01 U1/2 5.00E-01 4.9E+01 1.0E+00 3.2E+00
EaFA-L07-1313-B03-C 1 5.00E-01 U1/2 5.00E-01 9.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.71E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.68E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.59E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-172
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
1 ug/L
S EaFA-L07-1313-T01-A 1 1.83E+05
S EaFA-L07-1313-T02-A 1 1.76E+05
S EaFA-L07-1313-T03-A 1 1.74E+05
S EaFA-L07-1313-T04-A 1 1.65E+05
S EaFA-L07-1313-T05-A 1 1.69E+05
S EaFA-L07-1313-T06-A 1 1.67E+05
S EaFA-L07-1313-T07-A 1 1.43E+05
S EaFA-L07-1313-T08-A 1 1.03E+05
S EaFA-L07-1313-T09-A 1 6.13E+04
S EaFA-L07-1313-T01-B 1 1.73E+05
S EaFA-L07-1313-T02-B 1 1.73E+05
S EaFA-L07-1313-T03-B 1 1.62E+05
S EaFA-L07-1313-T04-B 1 1.65E+05
S EaFA-L07-1313-T05-B 1 1.72E+05
S EaFA-L07-1313-T06-B 1 1.69E+05
S EaFA-L07-1313-T07-B 1 1.49E+05
S EaFA-L07-1313-T08-B 1 9.81 E+04
S EaFA-L07-1313-T09-B 1 6. 11 E+04
S EaFA-L07-1313-T01-C 1 1.86E+05
S EaFA-L07-1313-T02-C 1 1.71E+05
S EaFA-L07-1313-T03-C 1 1.65E+05
S EaFA-L07-1313-T04-C 1 1.47E+05
S EaFA-L07-1313-T05-C 1 1.68E+05
S EaFA-L07-1313-T06-C 1 1.58E+05
S EaFA-L07-1313-T07-C 1 1.45E+05
S EaFA-L07-1313-T08-C 1 1.03E+05
S EaFA-L07-1313-T09-C 1 6.27E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.83E+05 6.9E-01 6.8E+00 2.2E+01
1.76E+05 3.3E-01 6.8E+00 2.2E+01
1.74E+05 3.2E-01 6.8E+00 2.2E+01 1000 100
1.65E+05 6.2E+00 6.8E+00 2.2E+01
1.69E+05 6.6E-01 6.8E+00 2.2E+01
1.67E+05 6.7E-01 6.8E+00 2.2E+01
1.43E+05 7.1E-01 6.8E+00 2.2E+01
1.03E+05 7.3E-01 6.8E+00 2.2E+01
6.13E+04 2.6E-01 6.8E+00 2.2E+01
1.73E+05 7.6E+00 6.8E+00 2.2E+01
1.73E+05 4.8E-01 6.8E+00 2.2E+01
1.62E+05 5.9E+00 6.8E+00 2.2E+01 1000 100
1.65E+05 4.8E+00 6.8E+00 2.2E+01
1.72E+05 2.5E-01 6.8E+00 2.2E+01
1.69E+05 2.1E-01 6.8E+00 2.2E+01
1.49E+05 5.5E+00 6.8E+00 2.2E+01
9.81 E+04 3.9E-01 6.8E+00 2.2E+01
6.11E+04 9.4E-01 6.8E+00 2.2E+01
1.86E+05 1.1E+00 6.8E+00 2.2E+01
1.71E+05 2.9E-01 6.8E+00 2.2E+01
1.65E+05 3.2E-01 6.8E+00 2.2E+01 1000 100
1.47E+05 9.3E+00 6.8E+00 2.2E+01
1.68E+05 4.7E-01 6.8E+00 2.2E+01
1.58E+05 1.4E+02 6.8E+00 2.2E+01
1.45E+05 8.3E-01 6.8E+00 2.2E+01
1.03E+05 6.0E-01 6.8E+00 2.2E+01
6.27E+04 4.0E-01 6.8E+00 2.2E+01
S EaFA-L07-1313-B01-A 1 3.40E+00 U1/2 3.40E+00 3.5E+01 6.8E+00 2.2E+01
S EaFA-L07-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 3.4E+01 6.8E+00 2.2E+01
S EaFA-L07-1313-B03-A 1 8.89E+00 E 8.89E+00 1.0E+02 6.8E+00 2.2E+01
S EaFA-L07-1313-B01-B 1 3.40E+00 U1/2 3.40E+00 6.7E+01 6.8E+00 2.2E+01
S EaFA-L07-1313-B02-B 1 3.40E+00 U1/2 3.40E+00 2.8E+01 6.8E+00 2.2E+01
S EaFA-L07-1313-B03-B 1 3.40E+00 U1/2 3.40E+00 4.6E+02 6.8E+00 2.2E+01
S EaFA-L07-1313-B01-C 1 3.40E+00 U1/2 3.40E+00 3.0E+01 6.8E+00 2.2E+01
S EaFA-L07-1313-B02-C 1 3.40E+00 U1/2 3.40E+00 7.2E+01 6.8E+00 2.2E+01
S EaFA-L07-1313-B03-C 1 7.46E+00 E 7.46E+00 1.4E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 J5E+05 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .63E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .66E+05 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-173
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-L07-1313-T01-A 1
Tl EaFA-L07-1313-T02-A 1
Tl EaFA-L07-1313-T03-A 1
Tl EaFA-L07-1313-T04-A 1
Tl EaFA-L07-1313-T05-A 1
Tl EaFA-L07-1313-T06-A 1
Tl EaFA-L07-1313-T07-A 1
Tl EaFA-L07-1313-T08-A 1
Tl EaFA-L07-1313-T09-A 1
Tl EaFA-L07-1313-T01-B 1
Tl EaFA-L07-1313-T02-B 1
Tl EaFA-L07-1313-T03-B 1
Tl EaFA-L07-1313-T04-B 1
Tl EaFA-L07-1313-T05-B 1
Tl EaFA-L07-1313-T06-B 1
Tl EaFA-L07-1313-T07-B 1
Tl EaFA-L07-1313-T08-B 1
Tl EaFA-L07-1313-T09-B 1
Tl EaFA-L07-1313-T01-C 1
Tl EaFA-L07-1313-T02-C 1
Tl EaFA-L07-1313-T03-C 1
Tl EaFA-L07-1313-T04-C 1
Tl EaFA-L07-1313-T05-C 1
Tl EaFA-L07-1313-T06-C 1
Tl EaFA-L07-1313-T07-C 1
Tl EaFA-L07-1313-T08-C 1
Tl EaFA-L07-1313-T09-C 1
Tl EaFA-L07-1313-B01-A 1
Tl EaFA-L07-1313-B02-A 1
Tl EaFA-L07-1313-B03-A 1
Tl EaFA-L07-1313-B01-B 1
Tl EaFA-L07-1313-B02-B 1
Tl EaFA-L07-1313-B03-B 1
Tl EaFA-L07-1313-B01-C 1
Tl EaFA-L07-1313-B02-C 1
Tl EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.52E+01
3.02E+01
7.15E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.04E+01
4.26E+01
6.97E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.33E+01
3.50E+01
7.37E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 4.2E+02 4.6E+00 1.5E+01
2.30E+00 2.0E+02 4.6E+00 1.5E+01
2.30E+00 5.6E+01 4.6E+00 1.5E+01 10 325
2.30E+00 1.2E+02 4.6E+00 1.5E+01
2.30E+00 5.9E+01 4.6E+00 1.5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.52E+01 2.8E+01 4.6E+00 1 .5E+01
3.02E+01 2.1E+01 4.6E+00 1 .5E+01
7.15E+01 5.9E+00 4.6E+00 1 .5E+01
2.30E+00 4.6E+01 4.6E+00 1 .5E+01
2.30E+00 9.3E+01 4.6E+00 1 .5E+01
2.30E+00 6.4E+01 4.6E+00 1 .5E+01 10 325
2.30E+00 5.2E+01 4.6E+00 1 .5E+01
2.30E+00 4.2E+02 4.6E+00 1 .5E+01
2.30E+00 1.2E+02 4.6E+00 1 .5E+01
2.04E+01 3.3E+01 4.6E+00 1 .5E+01
4.26E+01 3.4E+00 4.6E+00 1.5E+01
6.97E+01 5.2E+00 4.6E+00 1.5E+01
2.30E+00 2.7E+01 4.6E+00 1.5E+01
2.30E+00 3.3E+01 4.6E+00 1 .5E+01
2.30E+00 2.9E+01 4.6E+00 1 .5E+01 10 325
2.30E+00 1.0E+02 4.6E+00 1 .5E+01
2.30E+00 8.8E+01 4.6E+00 1 .5E+01
2.30E+00 8.7E+00 4.6E+00 1.5E+01
2.33E+01 2.8E+01 4.6E+00 1.5E+01
3.50E+01 5.2E+00 4.6E+00 1.5E+01
7.37E+01 7.1E+00 4.6E+00 1.5E+01
2.30E+00 2.2E+00 4.6E+00 1.5E+01
2.30E+00 8.8E+00 4.6E+00 1.5E+01
2.30E+00 1.9E+02 4.6E+00 1.5E+01
2.30E+00 4.0E+01 4.6E+00 1.5E+01
2.30E+00 9.2E+01 4.6E+00 1.5E+01
2.30E+00 5.7E+01 4.6E+00 1.5E+01
2.30E+00 5.5E+01 4.6E+00 1.5E+01
2.30E+00 4.6E+01 4.6E+00 1.5E+01
2.30E+00 2.8E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.03E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.53E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.95E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-174
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L07-1313-T01-A 1
Ti EaFA-L07-1313-T02-A 1
Ti EaFA-L07-1313-T03-A 1
Ti EaFA-L07-1313-T04-A 1
Ti EaFA-L07-1313-T05-A 1
Ti EaFA-L07-1313-T06-A 1
Ti EaFA-L07-1313-T07-A 1
Ti EaFA-L07-1313-T08-A 1
Ti EaFA-L07-1313-T09-A 1
Ti EaFA-L07-1313-T01-B 1
Ti EaFA-L07-1313-T02-B 1
Ti EaFA-L07-1313-T03-B 1
Ti EaFA-L07-1313-T04-B 1
Ti EaFA-L07-1313-T05-B 1
Ti EaFA-L07-1313-T06-B 1
Ti EaFA-L07-1313-T07-B 1
Ti EaFA-L07-1313-T08-B 1
Ti EaFA-L07-1313-T09-B 1
Ti EaFA-L07-1313-T01-C 1
Ti EaFA-L07-1313-T02-C 1
Ti EaFA-L07-1313-T03-C 1
Ti EaFA-L07-1313-T04-C 1
Ti EaFA-L07-1313-T05-C 1
Ti EaFA-L07-1313-T06-C 1
Ti EaFA-L07-1313-T07-C 1
Ti EaFA-L07-1313-T08-C 1
Ti EaFA-L07-1313-T09-C 1
Ti EaFA-L07-1313-B01-A 1
Ti EaFA-L07-1313-B02-A 1
Ti EaFA-L07-1313-B03-A 1
Ti EaFA-L07-1313-B01-B 1
Ti EaFA-L07-1313-B02-B 1
Ti EaFA-L07-1313-B03-B 1
Ti EaFA-L07-1313-B01-C 1
Ti EaFA-L07-1313-B02-C 1
Ti EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.47E+01
6.14E+03
2.03E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
7.91 E+00
1.00E+00 U1/2
1.72E+01
3.23E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.38E+01
3.80E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.43E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.0E+01 2.0E+00 6.4E+00
1.00E+00 6.7E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+02 2.0E+00 6.4E+00 10 325
1.00E+00 2.3E+02 2.0E+00 6.4E+00
1.00E+00 5.2E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 2.5E+02 2.0E+00 6.4E+00
1.47E+01 4.2E+00 2.0E+00 6.4E+00
6.14E+03 5.7E-01 2.0E+00 6.4E+00
2.03E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 7.4E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00 10 325
1.00E+00 9.9E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+03 2.0E+00 6.4E+00
7.91 E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.72E+01 5.8E+00 2.0E+00 6.4E+00
3.23E+03 1.2E+00 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.00E+00 4.2E+02 2.0E+00 6.4E+00 10 325
1.00E+00 6.9E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.38E+01 6.1E-01 2.0E+00 6.4E+00
3.80E+03 4.5E-01 2.0E+00 6.4E+00
1.00E+00 6.7E+01 2.0E+00 6.4E+00
1.00E+00 7.6E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+02 2.0E+00 6.4E+00
2.43E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+04 2.0E+00 6.4E+00
1.00E+00 5.3E+02 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 3.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.18E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.16E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.08E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1 :53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-175
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFA-L07-1313-T01-A 1
V EaFA-L07-1313-T02-A 1
V EaFA-L07-1313-T03-A 1
V EaFA-L07-1313-T04-A 1
V EaFA-L07-1313-T05-A 1
V EaFA-L07-1313-T06-A 1
V EaFA-L07-1313-T07-A 1
V EaFA-L07-1313-T08-A 1
V EaFA-L07-1313-T09-A 1
V EaFA-L07-1313-T01-B 1
V EaFA-L07-1313-T02-B 1
V EaFA-L07-1313-T03-B 1
V EaFA-L07-1313-T04-B 1
V EaFA-L07-1313-T05-B 1
V EaFA-L07-1313-T06-B 1
V EaFA-L07-1313-T07-B 1
V EaFA-L07-1313-T08-B 1
V EaFA-L07-1313-T09-B 1
V EaFA-L07-1313-T01-C 1
V EaFA-L07-1313-T02-C 1
V EaFA-L07-1313-T03-C 1
V EaFA-L07-1313-T04-C 1
V EaFA-L07-1313-T05-C 1
V EaFA-L07-1313-T06-C 1
V EaFA-L07-1313-T07-C 1
V EaFA-L07-1313-T08-C 1
V EaFA-L07-1313-T09-C 1
V EaFA-L07-1313-B01-A 1
V EaFA-L07-1313-B02-A 1
V EaFA-L07-1313-B03-A 1
V EaFA-L07-1313-B01-B 1
V EaFA-L07-1313-B02-B 1
V EaFA-L07-1313-B03-B 1
V EaFA-L07-1313-B01-C 1
V EaFA-L07-1313-B02-C 1
V EaFA-L07-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
4.41 E+03
2.63E+03
2.89E+03
7.98E+02
3.53E+02
2.09E+02
7.11E+01
9.92E+01
6.09E+03
4.00E+03
2.54E+03
2.52E+03
5.08E+02
2.97E+02
2.21E+02
7.29E+01
1.02E+02
5.92E+03
4.29E+03
2.62E+03
2.88E+03
7.34E+02
3.85E+02
2.91 E+02
7.31E+01
9.91E+01
6.04E+03
7.50E-01 U1/2
7.50E-01 U1/2
7.50E-01 U1/2
7.50E-01 U1/2
7.50E-01 U1/2
7.50E-01 U1/2
7.50E-01 U1/2
7.50E-01 U1/2
7.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.41 E+03 1.0E+00 1.5E+00 4.8E+00
2.63E+03 1.2E+00 1.5E+00 4.8E+00
2.89E+03 1.2E+00 1.5E+00 4.8E+00 10 325
7.98E+02 5.3E+00 1.5E+00 4.8E+00
3.53E+02 7.4E-01 1.5E+00 4.8E+00
2.09E+02 1.5E+00 1.5E+00 4.8E+00
7.11E+01 2.4E+00 1.5E+00 4.8E+00
9.92E+01 2.0E+00 1.5E+00 4.8E+00
6.09E+03 2.5E-01 1.5E+00 4.8E+00
4.00E+03 6.5E+00 1.5E+00 4.8E+00
2.54E+03 9.0E-01 1.5E+00 4.8E+00
2.52E+03 6.3E+00 1.5E+00 4.8E+00 10 325
5.08E+02 5.1E+00 1.5E+00 4.8E+00
2.97E+02 1.5E+00 1.5E+00 4.8E+00
2.21E+02 1.3E+00 1.5E+00 4.8E+00
7.29E+01 7.4E+00 1.5E+00 4.8E+00
1.02E+02 2.2E+00 1.5E+00 4.8E+00
5.92E+03 2.0E+00 1.5E+00 4.8E+00
4.29E+03 2.0E+00 1.5E+00 4.8E+00
2.62E+03 2.4E-01 1.5E+00 4.8E+00
2.88E+03 6.7E-01 1.5E+00 4.8E+00 10 325
7.34E+02 6.3E+00 1.5E+00 4.8E+00
3.85E+02 1.0E+00 1.5E+00 4.8E+00
2.91 E+02 1.5E+02 1.5E+00 4.8E+00
7.31 E+01 3.2E+00 1.5E+00 4.8E+00
9.91 E+01 1.3E+00 1.5E+00 4.8E+00
6.04E+03 3.5E-01 1.5E+00 4.8E+00
7.50E-01 6.3E+01 1.5E+00 4.8E+00
7.50E-01 4.6E+02 1.5E+00 4.8E+00
7.50E-01 1.5E+02 1.5E+00 4.8E+00
7.50E-01 1.6E+02 1.5E+00 4.8E+00
7.50E-01 4.5E+02 1.5E+00 4.8E+00
7.50E-01 4.6E+03 1.5E+00 4.8E+00
7.50E-01 1.2E+02 1.5E+00 4.8E+00
7.50E-01 5.3E+01 1.5E+00 4.8E+00
7.50E-01 2.3E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.88E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.53E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.82E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-176
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn EaFA-L07-1313-T01-A 1
Zn EaFA-L07-1313-T02-A 1
Zn EaFA-L07-1313-T03-A 1
Zn EaFA-L07-1313-T04-A 1
Zn EaFA-L07-1313-T05-A 1
Zn EaFA-L07-1313-T06-A 1
Zn EaFA-L07-1313-T07-A 1
Zn EaFA-L07-1313-T08-A 1
Zn EaFA-L07-1313-T09-A 1
Zn EaFA-L07-1313-T01-B 1
Zn EaFA-L07-1313-T02-B 1
Zn EaFA-L07-1313-T03-B 1
Zn EaFA-L07-1313-T04-B 1
Zn EaFA-L07-1313-T05-B 1
Zn EaFA-L07-1313-T06-B 1
Zn EaFA-L07-1313-T07-B 1
Zn EaFA-L07-1313-T08-B 1
Zn EaFA-L07-1313-T09-B 1
Zn EaFA-L07-1313-T01-C 1
Zn EaFA-L07-1313-T02-C 1
Zn EaFA-L07-1313-T03-C 1
Zn EaFA-L07-1313-T04-C 1
Zn EaFA-L07-1313-T05-C 1
Zn EaFA-L07-1313-T06-C 1
Zn EaFA-L07-1313-T07-C 1
Zn EaFA-L07-1313-T08-C 1
Zn EaFA-L07-1313-T09-C 1
Zn EaFA-L07-1313-B01-A 1
Zn EaFA-L07-1313-B02-A 1
Zn EaFA-L07-1313-B03-A 1
Zn EaFA-L07-1313-B01-B 1
Zn EaFA-L07-1313-B02-B 1
Zn EaFA-L07-1313-B03-B 1
Zn EaFA-L07-1313-B01-C 1
Zn EaFA-L07-1313-B02-C 1
Zn EaFA-L07-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.37E+00 E
4.01 E+00
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
2.11E+01
1.25E+03
1.08E+03
1.59E+03
7.88E+01
2.31 E+00 E
5.00E-01 U1/2
5.00E-01 U1/2
1.69E+00 E
1.38E+01
1.29E+03
1.10E+03
1.52E+03
8.67E+01
4.44E+00
3.84E+01
5.00E-01 U1/2
5.00E-01 U1/2
1.95E+01
1.25E+03
1.08E+03
1.51E+03
5.00E-01 U1/2
5.00E-01 U1/2
1.09E+01
5.00E-01 U1/2
1.17E+00 E
9.92E+00
2.84E+00 E
5.00E-01 U1/2
8.35E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.37E+00 3.4E+01 1.0E+00 3.2E+00
4.01E+00 2.7E+01 1.0E+00 3.2E+00
5.00E-01 3.5E+02 1.0E+00 3.2E+00 10 325
5.00E-01 4.6E+02 1.0E+00 3.2E+00
5.00E-01 1.3E+02 1.0E+00 3.2E+00
2.11E+01 3.6E+00 1.0E+00 3.2E+00
1.25E+03 1.0E+00 1.0E+00 3.2E+00
1.08E+03 4.5E-01 1.0E+00 3.2E+00
1.59E+03 5.4E-01 1.0E+00 3.2E+00
7.88E+01 6.4E+00 1.0E+00 3.2E+00
2.31 E+00 4.1E+01 1.0E+00 3.2E+00
5.00E-01 1.1E+02 1.0E+00 3.2E+00 10 325
5.00E-01 1.8E+02 1.0E+00 3.2E+00
1.69E+00 2.5E+01 1.0E+00 3.2E+00
1.38E+01 6.3E+00 1.0E+00 3.2E+00
1.29E+03 7.1 E+00 1.0E+00 3.2E+00
1.10E+03 2.1E-01 1.0E+00 3.2E+00
1.52E+03 2.5E+00 1.0E+00 3.2E+00
8.67E+01 2.0E-01 1.0E+00 3.2E+00
4.44E+00 1.7E+01 1.0E+00 3.2E+00
3.84E+01 2.3E+00 1.0E+00 3.2E+00 10 325
5.00E-01 9.0E+01 1.0E+00 3.2E+00
5.00E-01 2.5E+02 1.0E+00 3.2E+00
1.95E+01 3.8E+02 1.0E+00 3.2E+00
1.25E+03 4.6E-01 1.0E+00 3.2E+00
1.08E+03 4.4E-01 1.0E+00 3.2E+00
1.51E+03 1.2E+00 1.0E+00 3.2E+00
5.00E-01 4.2E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+02 1.0E+00 3.2E+00
1.09E+01 6.6E+00 1.0E+00 3.2E+00
5.00E-01 9.8E+01 1.0E+00 3.2E+00
1.17E+00 5.0E+01 1.0E+00 3.2E+00
9.92E+00 3.7E+00 1.0E+00 3.2E+00
2.84E+00 2.8E+01 1.0E+00 3.2E+00
5.00E-01 5.2E+01 1.0E+00 3.2E+00
8.35E+00 1.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.28E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.16E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.17E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:58 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:00 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:01 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:03 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:05 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:06 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:08 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:21 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:23 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:26 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:28 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:33 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:44 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:46 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:47 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:49 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:51 PM EPA Interlab L07 1313-1316 EaFA
6/9/10 2:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:54 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:56 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:57 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:50 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:51 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 1:53 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:16 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:18 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:39 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:41 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 2:43 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                          1-177
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al EaFA-L08-1313-T01-A 1 3.54E+04
Al EaFA-L08-1313-T02-A 1 2.91E+04
Al EaFA-L08-1313-T03-A 1 1.93E+04
Al EaFA-L08-1313-T04-A 1 6.93E+03
Al EaFA-L08-1313-T05-A 1 8.26E+02
Al EaFA-L08-1313-T06-A 1 1.35E+02
Al EaFA-L08-1313-T07-A 1 4.39E+02
Al EaFA-L08-1313-T08-A 1 1.31E+04
Al EaFA-L08-1313-T09-A 1 8.94E+04
Al EaFA-L08-1313-T01-B 1 3.42E+04
Al EaFA-L08-1313-T02-B 1 2.54E+04
Al EaFA-L08-1313-T03-B 1 1.84E+04
Al EaFA-L08-1313-T04-B 1 7.35E+03
Al EaFA-L08-1313-T05-B 1 7.20E+02
Al EaFA-L08-1313-T06-B 1 1.24E+02
Al EaFA-L08-1313-T07-B 1 2.85E+02
Al EaFA-L08-1313-T08-B 1 1.41E+04
Al EaFA-L08-1313-T09-B 1 8.06E+04
Al EaFA-L08-1313-T01-C 1 3.72E+04
Al EaFA-L08-1313-T02-C 1 2.79E+04
Al EaFA-L08-1313-T03-C 1 1.91E+04
Al EaFA-L08-1313-T04-C 1 1.86E+03
Al EaFA-L08-1313-T05-C 1 7.91 E+02
Al EaFA-L08-1313-T06-C 1 1.42E+02
Al EaFA-L08-1313-T07-C 1 2.74E+02
Al EaFA-L08-1313-T08-C 1 1.29E+04
Al EaFA-L08-1313-T09-C 1 5.04E+04
Al EaFA-L08-1313-B01-A 1 5.00E-01 U1/2
Al EaFA-L08-1313-B02-A 1 5.00E-01 U1/2
Al EaFA-L08-1313-B03-A 1 5.00E-01 U1/2
Al EaFA-L08-1313-B01-B 1 5.00E-01 U1/2
Al EaFA-L08-1313-B02-B 1 5.00E-01 U1/2
Al EaFA-L08-1313-B03-B 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.54E+04 1.2E+00 1 .OE+00 3.2E+00
2.91E+04 3.9E-02 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
1.93E+04 1.2E+00 1 .OE+00 3.2E+00 1000 100 2.02E+04 89% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
6.93E+03 4.0E-01 1 .OE+00 3.2E+00
8.26E+02 4.4E-01 1 .OE+00 3.2E+00
1.35E+02 2.0E+00 1 .OE+00 3.2E+00
4.39E+02 1.2E+01 1 .OE+00 3.2E+00
1.31E+04 6.7E-01 1 .OE+00 3.2E+00
8.94E+04 5.2E+01 1 .OE+00 3.2E+00
3.42E+04 7.8E+00 1 .OE+00 3.2E+00
2.54E+04 4.0E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
1.84E+04 4.0E+00 1 .OE+00 3.2E+00 1000 100 1 .93E+04 84% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
7.35E+03 1.1E+00 1 .OE+00 3.2E+00
7.20E+02 1.1E+01 1. OE+00 3.2E+00
1.24E+02 4.4E-01 1 .OE+00 3.2E+00
2.85E+02 2.7E+00 1 .OE+00 3.2E+00
1.41E+04 4.5E-01 1 .OE+00 3.2E+00
8.06E+04 6.5E+01 1 .OE+00 3.2E+00
3.72E+04 4.6E-01 1 .OE+00 3.2E+00
2.79E+04 1.7E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
1.91E+04 2.1E-01 1. OE+00 3.2E+00 1000 100 2.00E+04 98% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
1.86E+03 1.5E+02 1 .OE+00 3.2E+00
7.91 E+02 1.2E+00 1 .OE+00 3.2E+00
1.42E+02 5.5E-01 1 .OE+00 3.2E+00
2.74E+02 7.6E-01 1 .OE+00 3.2E+00
1.29E+04 1.9E+00 1 .OE+00 3.2E+00
5.04E+04 1.2E+02 1 .OE+00 3.2E+00
5.00E-01 9.8E+00 1 .OE+00 3.2E+00
5.00E-01 2.8E+01 1 .OE+00 3.2E+00
5.00E-01 1.4E+01 1. OE+00 3.2E+00
5.00E-01 9.7E+00 1 .OE+00 3.2E+00
5.00E-01 1.9E+01 1. OE+00 3.2E+00
5.00E-01 9.0E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                                   1-178
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Sb Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Sb EaFA-L08-1313-T01-A 1 2.80E+02
Sb EaFA-L08-1313-T02-A 1 2.23E+02
Sb EaFA-L08-1313-T03-A 1 2.62E+02
Sb EaFA-L08-1313-T04-A 1 2.86E+02
Sb EaFA-L08-1313-T05-A 1 2.44E+02
Sb EaFA-L08-1313-T06-A 1 2.28E+02
Sb EaFA-L08-1313-T07-A 1 1.23E+02
Sb EaFA-L08-1313-T08-A 1 4.76E+01
Sb EaFA-L08-1313-T09-A 1 3.75E+00 U1/2
Sb EaFA-L08-1313-T01-B 1 2.70E+02
Sb EaFA-L08-1313-T02-B 1 1.79E+02
Sb EaFA-L08-1313-T03-B 1 2.09E+02
Sb EaFA-L08-1313-T04-B 1 2.63E+02
Sb EaFA-L08-1313-T05-B 1 2.42E+02
Sb EaFA-L08-1313-T06-B 1 2.13E+02
Sb EaFA-L08-1313-T07-B 1 1.40E+02
Sb EaFA-L08-1313-T08-B 1 4.76E+01
Sb EaFA-L08-1313-T09-B 1 3.75E+00 U1/2
Sb EaFA-L08-1313-T01-C 1 2.94E+02
Sb EaFA-L08-1313-T02-C 1 1 .62E+02
Sb EaFA-L08-1313-T03-C 1 2.40E+02
Sb EaFA-L08-1313-T04-C 1 5.47E+01
Sb EaFA-L08-1313-T05-C 1 2.39E+02
Sb EaFA-L08-1313-T06-C 1 2.41E+02
Sb EaFA-L08-1313-T07-C 1 1.63E+02
Sb EaFA-L08-1313-T08-C 1 5.48E+01
Sb EaFA-L08-1313-T09-C 1 3.75E+00 U1/2
Sb EaFA-L08-1313-B01-A 1 3.75E+00 U1/2
Sb EaFA-L08-1313-B02-A 1 3.75E+00 U1/2
Sb EaFA-L08-1313-B03-A 1 2.12E+01 E
Sb EaFA-L08-1313-B01-B 1 3.75E+00 U1/2
Sb EaFA-L08-1313-B02-B 1 3.75E+00 U1/2
Sb EaFA-L08-1313-B03-B 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.80E+02 9.1E+00 7.5E+00 2.4E+01
2.23E+02 5.9E+00 7.5E+00 2.4E+01
2.62E+02 3.9E+00 7.5E+00 2.4E+01 10 325
2.86E+02 7.7E+00 7.5E+00 2.4E+01
2.44E+02 1.7E+01 7.5E+00 2.4E+01
2.28E+02 2.7E+00 7.5E+00 2.4E+01
1.23E+02 7.3E+00 7.5E+00 2.4E+01
4.76E+01 5.9E+00 7.5E+00 2.4E+01
3.75E+00 8.8E+01 7.5E+00 2.4E+01
2.70E+02 1.5E+00 7.5E+00 2.4E+01
1.79E+02 8.5E+00 7.5E+00 2.4E+01
2.09E+02 9.9E+00 7.5E+00 2.4E+01 10 325
2.63E+02 9.4E+00 7.5E+00 2.4E+01
2.42E+02 2.0E+01 7.5E+00 2.4E+01
2.13E+02 8.4E+00 7.5E+00 2.4E+01
1.40E+02 1.8E+01 7.5E+00 2.4E+01
4.76E+01 3.6E+01 7.5E+00 2.4E+01
3.75E+00 9.6E+03 7.5E+00 2.4E+01
2.94E+02 2.5E+00 7.5E+00 2.4E+01
1.62E+02 9.2E+00 7.5E+00 2.4E+01
2.40E+02 1.3E+01 7.5E+00 2.4E+01 10 325
5.47E+01 1.9E+02 7.5E+00 2.4E+01
2.39E+02 6.3E+00 7.5E+00 2.4E+01
2.41 E+02 7.8E+00 7.5E+00 2.4E+01
1.63E+02 8.4E+00 7.5E+00 2.4E+01
5.48E+01 2.3E+01 7.5E+00 2.4E+01
3.75E+00 4.6E+01 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
3.75E+00 9.5E+01 7.5E+00 2.4E+01
2.12E+01 1.6E+02 7.5E+00 2.4E+01
3.75E+00 8.6E+02 7.5E+00 2.4E+01
3.75E+00 6.4E+02 7.5E+00 2.4E+01
3.75E+00 2.3E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:40AM EPA Interlab LOS 1313-1316 EaFA
3.50E+03 100% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:43AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:46AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:48AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.44E+03 100% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1 :41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.52E+03 101% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1 :44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-179
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
As Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
As EaFA-L08-1313-T01-A 1 1.07E+04
As EaFA-L08-1313-T02-A 1 9.53E+02
As EaFA-L08-1313-T03-A 1 6.44E+02
As EaFA-L08-1313-T04-A 1 9.18E+02
As EaFA-L08-1313-T05-A 1 3.68E+02
As EaFA-L08-1313-T06-A 1 1.50E+02
As EaFA-L08-1313-T07-A 1 1.72E+02
As EaFA-L08-1313-T08-A 1 1.42E+02
As EaFA-L08-1313-T09-A 1 2.09E+03
As EaFA-L08-1313-T01-B 1 9.89E+03
As EaFA-L08-1313-T02-B 1 7.61 E+02
As EaFA-L08-1313-T03-B 1 6.41 E+02
As EaFA-L08-1313-T04-B 1 9.32E+02
As EaFA-L08-1313-T05-B 1 3.36E+02
As EaFA-L08-1313-T06-B 1 1.64E+02
As EaFA-L08-1313-T07-B 1 1.78E+02
As EaFA-L08-1313-T08-B 1 1.58E+02
As EaFA-L08-1313-T09-B 1 1.19E+03
As EaFA-L08-1313-T01-C 1 1.01E+04
As EaFA-L08-1313-T02-C 1 8.06E+02
As EaFA-L08-1313-T03-C 1 6.87E+02
As EaFA-L08-1313-T04-C 1 2.26E+02
As EaFA-L08-1313-T05-C 1 4.09E+02
As EaFA-L08-1313-T06-C 1 1.62E+02
As EaFA-L08-1313-T07-C 1 1.97E+02
As EaFA-L08-1313-T08-C 1 1.39E+02
As EaFA-L08-1313-T09-C 1 3.68E+02
As EaFA-L08-1313-B01-A 1 5.50E+00 U1/2
As EaFA-L08-1313-B02-A 1 5.50E+00 U1/2
As EaFA-L08-1313-B03-A 1 2.33E+01 E
As EaFA-L08-1313-B01-B 1 5.50E+00 U1/2
As EaFA-L08-1313-B02-B 1 5.50E+00 U1/2
As EaFA-L08-1313-B03-B 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.07E+04 8.1E-01 1.1E+01 3.5E+01
9.53E+02 1.4E+00 1.1E+01 3.5E+01
6.44E+02 1.4E+00 1.1E+01 3.5E+01 10 325
9.18E+02 2.4E+00 1.1E+01 3.5E+01
3.68E+02 5.2E+00 1.1E+01 3.5E+01
1.50E+02 9.8E+00 1.1E+01 3.5E+01
1.72E+02 1.4E+01 1.1E+01 3.5E+01
1.42E+02 8.4E+00 1.1E+01 3.5E+01
2.09E+03 1.1E+01 1.1E+01 3.5E+01
9.89E+03 9.1E+00 1.1E+01 3.5E+01
7.61 E+02 4.8E+00 1.1E+01 3.5E+01
6.41E+02 6.6E+00 1.1E+01 3.5E+01 10 325
9.32E+02 4.2E+00 1.1E+01 3.5E+01
3.36E+02 1.0E+01 1.1E+01 3.5E+01
1.64E+02 5.5E+00 1.1E+01 3.5E+01
1.78E+02 1.7E+01 1.1E+01 3.5E+01
1.58E+02 6.5E-01 1.1E+01 3.5E+01
1.19E+03 4.2E+01 1.1E+01 3.5E+01
1.01E+04 6.3E-01 1.1E+01 3.5E+01
8.06E+02 2.0E+00 1.1E+01 3.5E+01
6.87E+02 1.9E+00 1.1E+01 3.5E+01 10 325
2.26E+02 1.6E+02 1.1E+01 3.5E+01
4.09E+02 3.9E+00 1.1E+01 3.5E+01
1.62E+02 5.7E+00 1.1E+01 3.5E+01
1.97E+02 1.8E+01 1.1E+01 3.5E+01
1.39E+02 1.1E+01 1.1E+01 3.5E+01
3.68E+02 1.3E+02 1.1E+01 3.5E+01
5.50E+00 2.4E+02 1.1E+01 3.5E+01
5.50E+00 6.4E+02 1.1E+01 3.5E+01
2.33E+01 7.6E+01 1.1E+01 3.5E+01
5.50E+00 9.3E+01 1.1E+01 3.5E+01
5.50E+00 3.8E+02 1.1E+01 3.5E+01
5.50E+00 2.4E+02 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
3.90E+03 100% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.82E+03 98% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.99E+03 102% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-180
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
B Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
B EaFA-L08-1313-T01-A 1 4.61 E+03
B EaFA-L08-1313-T02-A 1 4.02E+03
B EaFA-L08-1313-T03-A 1 4.21E+03
B EaFA-L08-1313-T04-A 1 4.00E+03
B EaFA-L08-1313-T05-A 1 4.25E+03
B EaFA-L08-1313-T06-A 1 4.22E+03
B EaFA-L08-1313-T07-A 1 4.07E+03
B EaFA-L08-1313-T08-A 1 3.70E+03
B EaFA-L08-1313-T09-A 1 2.73E+03
B EaFA-L08-1313-T01-B 1 4.50E+03
B EaFA-L08-1313-T02-B 1 3.77E+03
B EaFA-L08-1313-T03-B 1 3.97E+03
B EaFA-L08-1313-T04-B 1 4.06E+03
B EaFA-L08-1313-T05-B 1 3.92E+03
B EaFA-L08-1313-T06-B 1 4.39E+03
B EaFA-L08-1313-T07-B 1 4.46E+03
B EaFA-L08-1313-T08-B 1 3.73E+03
B EaFA-L08-1313-T09-B 1 2.82E+03
B EaFA-L08-1313-T01-C 1 4.64E+03
B EaFA-L08-1313-T02-C 1 4.03E+03
B EaFA-L08-1313-T03-C 1 4.13E+03
B EaFA-L08-1313-T04-C 1 3.95E+03
B EaFA-L08-1313-T05-C 1 4.24E+03
B EaFA-L08-1313-T06-C 1 4.33E+03
B EaFA-L08-1313-T07-C 1 4.68E+03
B EaFA-L08-1313-T08-C 1 3.59E+03
B EaFA-L08-1313-T09-C 1 2.82E+03
B EaFA-L08-1313-B01-A 1 7.53E+01
B EaFA-L08-1313-B02-A 1 4.80E+01
B EaFA-L08-1313-B03-A 1 5.84E+01
B EaFA-L08-1313-B01-B 1 3.07E+01
B EaFA-L08-1313-B02-B 1 1.88E+01
B EaFA-L08-1313-B03-B 1 8.07E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.61 E+03 4.8E-01 1 .OE+00 3.2E+00
4.02E+03 2.6E-01 1 .OE+00 3.2E+00
4.21E+03 7.4E-01 1 .OE+00 3.2E+00 1000 100
4.00E+03 2.2E+00 1 .OE+00 3.2E+00
4.25E+03 1.7E+00 1 .OE+00 3.2E+00
4.22E+03 3.4E+00 1 .OE+00 3.2E+00
4.07E+03 1.3E+01 1 .OE+00 3.2E+00
3.70E+03 1.0E-01 1 .OE+00 3.2E+00
2.73E+03 4.1E+01 1 .OE+00 3.2E+00
4.50E+03 8.0E+00 1 .OE+00 3.2E+00
3.77E+03 4.3E+00 1 .OE+00 3.2E+00
3.97E+03 8.0E-01 1 .OE+00 3.2E+00 1000 100
4.06E+03 8.5E-01 1 .OE+00 3.2E+00
3.92E+03 7.5E+00 1 .OE+00 3.2E+00
4.39E+03 6.2E-01 1 .OE+00 3.2E+00
4.46E+03 3.6E+00 1 .OE+00 3.2E+00
3.73E+03 1.1E+00 1 .OE+00 3.2E+00
2.82E+03 2.1E+01 1 .OE+00 3.2E+00
4.64E+03 4.3E-01 1 .OE+00 3.2E+00
4.03E+03 2.2E+00 1 .OE+00 3.2E+00
4.13E+03 4.4E-01 1 .OE+00 3.2E+00 1000 100
3.95E+03 1.4E+02 1. OE+00 3.2E+00
4.24E+03 9.6E-01 1. OE+00 3.2E+00
4.33E+03 6.0E-01 1. OE+00 3.2E+00
4.68E+03 1. OE+00 1. OE+00 3.2E+00
3.59E+03 2.1E+00 1. OE+00 3.2E+00
2.82E+03 8.3E+01 1. OE+00 3.2E+00
7.53E+01 4.4E+00 1. OE+00 3.2E+00
4.80E+01 1.2E+01 1. OE+00 3.2E+00
5.84E+01 1.3E+00 1. OE+00 3.2E+00
3.07E+01 9.8E+00 1. OE+00 3.2E+00
1.88E+01 1.6E+01 1. OE+00 3.2E+00
8.07E+00 1.8E+02 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
5.07E+03 87% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
4.88E+03 91% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
4.98E+03 85% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-181
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ba Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Ba EaFA-L08-1313-T01-A 1 1.72E+03
Ba EaFA-L08-1313-T02-A 1 1.63E+03
Ba EaFA-L08-1313-T03-A 1 9.27E+02
Ba EaFA-L08-1313-T04-A 1 7.06E+02
Ba EaFA-L08-1313-T05-A 1 3.09E+02
Ba EaFA-L08-1313-T06-A 1 2.59E+02
Ba EaFA-L08-1313-T07-A 1 2.53E+02
Ba EaFA-L08-1313-T08-A 1 2.82E+02
Ba EaFA-L08-1313-T09-A 1 1.02E+03
Ba EaFA-L08-1313-T01-B 1 1.49E+03
Ba EaFA-L08-1313-T02-B 1 9.85E+02
Ba EaFA-L08-1313-T03-B 1 1.29E+03
Ba EaFA-L08-1313-T04-B 1 6.76E+02
Ba EaFA-L08-1313-T05-B 1 2.80E+02
Ba EaFA-L08-1313-T06-B 1 2.61E+02
Ba EaFA-L08-1313-T07-B 1 2.72E+02
Ba EaFA-L08-1313-T08-B 1 2.61E+02
Ba EaFA-L08-1313-T09-B 1 8.04E+02
Ba EaFA-L08-1313-T01-C 1 1 .93E+03
Ba EaFA-L08-1313-T02-C 1 1 .36E+03
Ba EaFA-L08-1313-T03-C 1 1 .25E+03
Ba EaFA-L08-1313-T04-C 1 1 J6E+02
Ba EaFA-L08-1313-T05-C 1 3.37E+02
Ba EaFA-L08-1313-T06-C 1 2.81E+02
Ba EaFA-L08-1313-T07-C 1 2.91E+02
Ba EaFA-L08-1313-T08-C 1 2.72E+02
Ba EaFA-L08-1313-T09-C 1 4.56E+02
Ba EaFA-L08-1313-B01-A 1 5.00E-01 U1/2
Ba EaFA-L08-1313-B02-A 1 5.00E-01 U1/2
Ba EaFA-L08-1313-B03-A 1 5.00E-01 U1/2
Ba EaFA-L08-1313-B01-B 1 5.00E-01 U1/2
Ba EaFA-L08-1313-B02-B 1 5.00E-01 U1/2
Ba EaFA-L08-1313-B03-B 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.72E+03 1.1E+00 1.0E+00 3.2E+00
1.63E+03 3.1E-01 1 .OE+00 3.2E+00
9.27E+02 6.1E-01 1 .OE+00 3.2E+00 10 325
7.06E+02 6.7E-01 1 .OE+00 3.2E+00
3.09E+02 1.8E-01 1. OE+00 3.2E+00
2.59E+02 8.9E-01 1. OE+00 3.2E+00
2.53E+02 1.3E+01 1. OE+00 3.2E+00
2.82E+02 1.9E-01 1. OE+00 3.2E+00
1.02E+03 1.7E+01 1. OE+00 3.2E+00
1.49E+03 8.5E+00 1. OE+00 3.2E+00
9.85E+02 3.9E+00 1. OE+00 3.2E+00
1.29E+03 5.4E+00 1. OE+00 3.2E+00 10 325
6.76E+02 1.8E+00 1. OE+00 3.2E+00
2.80E+02 9.3E+00 1. OE+00 3.2E+00
2.61 E+02 7.1E-01 1. OE+00 3.2E+00
2.72E+02 3.1E+00 1. OE+00 3.2E+00
2.61 E+02 7.2E-02 1. OE+00 3.2E+00
8.04E+02 4.3E+01 1. OE+00 3.2E+00
1.93E+03 9.3E-02 1. OE+00 3.2E+00
1.36E+03 1.4E+00 1. OE+00 3.2E+00
1.25E+03 3.9E-01 1. OE+00 3.2E+00 10 325
1.76E+02 1.5E+02 1. OE+00 3.2E+00
3.37E+02 1.9E-01 1. OE+00 3.2E+00
2.81 E+02 6.4E-02 1. OE+00 3.2E+00
2.91 E+02 5.8E-01 1. OE+00 3.2E+00
2.72E+02 2.6E+00 1. OE+00 3.2E+00
4.56E+02 1.3E+02 1. OE+00 3.2E+00
5.00E-01 6.2E+00 1. OE+00 3.2E+00
5.00E-01 1.0E+01 1. OE+00 3.2E+00
5.00E-01 1.4E+01 1. OE+00 3.2E+00
5.00E-01 1.5E+01 1. OE+00 3.2E+00
5.00E-01 1.6E+01 1. OE+00 3.2E+00
5.00E-01 3.4E+00 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:40AM EPA Interlab LOS 1313-1316 EaFA
3.80E+03 88% VUICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:43AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:46AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:48AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
4.11E+03 87% VUICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1 :41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
4.09E+03 87% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1 :44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-182
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Be Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Be EaFA-L08-1313-T01-A 1 9.50E-01 U1/2
Be EaFA-L08-1313-T02-A 1 9.50E-01 U1/2
Be EaFA-L08-1313-T03-A 1 9.50E-01 U1/2
Be EaFA-L08-1313-T04-A 1 9.50E-01 U1/2
Be EaFA-L08-1313-T05-A 1 9.50E-01 U1/2
Be EaFA-L08-1313-T06-A 1 9.50E-01 U1/2
Be EaFA-L08-1313-T07-A 1 5.99E+00 E
Be EaFA-L08-1313-T08-A 1 9.70E+01
Be EaFA-L08-1313-T09-A 1 2.20E+02
Be EaFA-L08-1313-T01-B 1 9.50E-01 U1/2
Be EaFA-L08-1313-T02-B 1 9.50E-01 U1/2
Be EaFA-L08-1313-T03-B 1 9.50E-01 U1/2
Be EaFA-L08-1313-T04-B 1 9.50E-01 U1/2
Be EaFA-L08-1313-T05-B 1 9.50E-01 U1/2
Be EaFA-L08-1313-T06-B 1 9.50E-01 U1/2
Be EaFA-L08-1313-T07-B 1 4.32E+00 E
Be EaFA-L08-1313-T08-B 1 1.01E+02
Be EaFA-L08-1313-T09-B 1 1.80E+02
Be EaFA-L08-1313-T01-C 1 9.50E-01 U1/2
Be EaFA-L08-1313-T02-C 1 9.50E-01 U1/2
Be EaFA-L08-1313-T03-C 1 9.50E-01 U1/2
Be EaFA-L08-1313-T04-C 1 9.50E-01 U1/2
Be EaFA-L08-1313-T05-C 1 9.50E-01 U1/2
Be EaFA-L08-1313-T06-C 1 9.50E-01 U1/2
Be EaFA-L08-1313-T07-C 1 4.54E+00 E
Be EaFA-L08-1313-T08-C 1 9.89E+01
Be EaFA-L08-1313-T09-C 1 1.15E+02
Be EaFA-L08-1313-B01-A 1 9.50E-01 U1/2
Be EaFA-L08-1313-B02-A 1 9.50E-01 U1/2
Be EaFA-L08-1313-B03-A 1 9.50E-01 U1/2
Be EaFA-L08-1313-B01-B 1 9.50E-01 U1/2
Be EaFA-L08-1313-B02-B 1 9.50E-01 U1/2
Be EaFA-L08-1313-B03-B 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.8E+01 1.9E+00 6.0E+00
9.50E-01 2.9E+02 1 .9E+00 6.0E+00
9.50E-01 1.0E+03 1 .9E+00 6.0E+00 10 325
9.50E-01 3.8E+02 1 .9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1 .9E+00 6.0E+00
5.99E+00 1.5E+01 1 .9E+00 6.0E+00
9.70E+01 3.4E-01 1 .9E+00 6.0E+00
2.20E+02 2.9E+01 1 .9E+00 6.0E+00
9.50E-01 7.9E+01 1 .9E+00 6.0E+00
9.50E-01 1.8E+02 1 .9E+00 6.0E+00
9.50E-01 2.7E+02 1 .9E+00 6.0E+00 10 325
9.50E-01 9.0E+01 1 .9E+00 6.0E+00
9.50E-01 1.2E+02 1 .9E+00 6.0E+00
9.50E-01 1.4E+02 1 .9E+00 6.0E+00
4.32E+00 7.6E+00 1.9E+00 6.0E+00
1.01E+02 3.0E-01 1.9E+00 6.0E+00
1.80E+02 6.6E+01 1.9E+00 6.0E+00
9.50E-01 3.5E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00 10 325
9.50E-01 6.8E+01 1 .9E+00 6.0E+00
9.50E-01 7.8E+01 1 .9E+00 6.0E+00
9.50E-01 2.6E+02 1 .9E+00 6.0E+00
4.54E+00 8.0E+00 1.9E+00 6.0E+00
9.89E+01 2.8E+00 1 .9E+00 6.0E+00
1.15E+02 1.1E+02 1.9E+00 6.0E+00
9.50E-01 9.8E+01 1 .9E+00 6.0E+00
9.50E-01 1.7E+02 1 .9E+00 6.0E+00
9.50E-01 5.0E+02 1 .9E+00 6.0E+00
9.50E-01 3.3E+01 1 .9E+00 6.0E+00
9.50E-01 1.3E+02 1 .9E+00 6.0E+00
9.50E-01 7.6E+01 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
3.38E+03 104% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:50AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.32E+03 102% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.38E+03 104% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-183
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Cd Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Cd EaFA-L08-1313-T01-A 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T02-A 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T03-A 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T04-A 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T05-A 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T06-A 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T07-A 1 3.03E+01
Cd EaFA-L08-1313-T08-A 1 3.13E+01
Cd EaFA-L08-1313-T09-A 1 3.03E+01
Cd EaFA-L08-1313-T01-B 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T02-B 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T03-B 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T04-B 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T05-B 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T06-B 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T07-B 1 3.13E+01
Cd EaFA-L08-1313-T08-B 1 3.18E+01
Cd EaFA-L08-1313-T09-B 1 2.59E+01
Cd EaFA-L08-1313-T01-C 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T02-C 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T03-C 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T04-C 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T05-C 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T06-C 1 1.10E+OOU1/2
Cd EaFA-L08-1313-T07-C 1 3.16E+01
Cd EaFA-L08-1313-T08-C 1 3.16E+01
Cd EaFA-L08-1313-T09-C 1 1.18E+01
Cd EaFA-L08-1313-B01-A 1 1.10E+OOU1/2
Cd EaFA-L08-1313-B02-A 1 1.10E+OOU1/2
Cd EaFA-L08-1313-B03-A 1 1.10E+OOU1/2
Cd EaFA-L08-1313-B01-B 1 1.10E+OOU1/2
Cd EaFA-L08-1313-B02-B 1 1.10E+OOU1/2
Cd EaFA-L08-1313-B03-B 1 1.10E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 6.8E+01 2.2E+00 7.0E+00
1.10E+00 2.3E+00 2.2E+00 7.0E+00
1.10E+00 5.0E+01 2.2E+00 7.0E+00 10 325
1.10E+00 7.6E+01 2.2E+00 7.0E+00
1.10E+00 8.4E+01 2.2E+00 7.0E+00
1.10E+00 1.9E+01 2.2E+00 7.0E+00
3.03E+01 1.1E+01 2.2E+00 7.0E+00
3.13E+01 2.8E+00 2.2E+00 7.0E+00
3.03E+01 1.4E+01 2.2E+00 7.0E+00
1.10E+00 9.4E+01 2.2E+00 7.0E+00
1.10E+00 6.9E+01 2.2E+00 7.0E+00
1.10E+00 3.3E+01 2.2E+00 7.0E+00 10 325
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 5.8E+01 2.2E+00 7.0E+00
1.10E+00 7.8E+01 2.2E+00 7.0E+00
3.13E+01 8.2E-01 2.2E+00 7.0E+00
3.18E+01 1.8E+00 2.2E+00 7.0E+00
2.59E+01 4.0E+01 2.2E+00 7.0E+00
1.10E+00 9.9E+01 2.2E+00 7.0E+00
1.10E+00 5.7E+01 2.2E+00 7.0E+00
1.10E+00 6.6E+00 2.2E+00 7.0E+00 10 325
1.10E+00 1.2E+01 2.2E+00 7.0E+00
1.10E+00 3.8E+01 2.2E+00 7.0E+00
1.10E+00 4.4E+01 2.2E+00 7.0E+00
3.16E+01 2.7E+00 2.2E+00 7.0E+00
3.16E+01 4.6E+00 2.2E+00 7.0E+00
1.18E+01 1.4E+02 2.2E+00 7.0E+00
1.10E+00 3.5E+01 2.2E+00 7.0E+00
1.10E+00 6.4E+01 2.2E+00 7.0E+00
1.10E+00 8.2E+01 2.2E+00 7.0E+00
1.10E+00 9.3E+01 2.2E+00 7.0E+00
1.10E+00 4.1E+01 2.2E+00 7.0E+00
1.10E+00 1.5E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
3.35E+03 103% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.29E+03 101% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.35E+03 103% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-184
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ca Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Ca EaFA-L08-1313-T01-A 1 1.35E+04
Ca EaFA-L08-1313-T02-A 1 4.07E+04
Ca EaFA-L08-1313-T03-A 1 8.27E+04
Ca EaFA-L08-1313-T04-A 1 1.26E+05
Ca EaFA-L08-1313-T05-A 1 1.44E+05
Ca EaFA-L08-1313-T06-A 1 1.56E+05
Ca EaFA-L08-1313-T07-A 1 1.47E+05
Ca EaFA-L08-1313-T08-A 1 1.41E+05
Ca EaFA-L08-1313-T09-A 1 1.15E+05
Ca EaFA-L08-1313-T01-B 1 1.27E+04
Ca EaFA-L08-1313-T02-B 1 4.08E+04
Ca EaFA-L08-1313-T03-B 1 8.35E+04
Ca EaFA-L08-1313-T04-B 1 1.23E+05
Ca EaFA-L08-1313-T05-B 1 1.32E+05
Ca EaFA-L08-1313-T06-B 1 1.54E+05
Ca EaFA-L08-1313-T07-B 1 1.63E+05
Ca EaFA-L08-1313-T08-B 1 1.41E+05
Ca EaFA-L08-1313-T09-B 1 9.86E+04
Ca EaFA-L08-1313-T01-C 1 1.45E+04
Ca EaFA-L08-1313-T02-C 1 4.20E+04
Ca EaFA-L08-1313-T03-C 1 8.65E+04
Ca EaFA-L08-1313-T04-C 1 3.07E+04
Ca EaFA-L08-1313-T05-C 1 1.43E+05
Ca EaFA-L08-1313-T06-C 1 1.52E+05
Ca EaFA-L08-1313-T07-C 1 1.66E+05
Ca EaFA-L08-1313-T08-C 1 1.40E+05
Ca EaFA-L08-1313-T09-C 1 4.81 E+04
Ca EaFA-L08-1313-B01-A 1 1.30E+OOU1/2
Ca EaFA-L08-1313-B02-A 1 4.03E+00 E
Ca EaFA-L08-1313-B03-A 1 5.96E+01
Ca EaFA-L08-1313-B01-B 1 7.31E+00 E
Ca EaFA-L08-1313-B02-B 1 5.03E+00 E
Ca EaFA-L08-1313-B03-B 1 1.84E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.35E+04 7.6E-01 2.6E+00 8.3E+00
4.07E+04 3.0E-01 2.6E+00 8.3E+00
8.27E+04 1.4E+00 2.6E+00 8.3E+00 1000 100
1.26E+05 1.3E+00 2.6E+00 8.3E+00
1.44E+05 5.0E-01 2.6E+00 8.3E+00
1.56E+05 7.7E-01 2.6E+00 8.3E+00
1.47E+05 1.3E+01 2.6E+00 8.3E+00
1.41E+05 6.3E-01 2.6E+00 8.3E+00
1.15E+05 8.4E+00 2.6E+00 8.3E+00
1.27E+04 8.4E+00 2.6E+00 8.3E+00
4.08E+04 3.7E+00 2.6E+00 8.3E+00
8.35E+04 4.5E+00 2.6E+00 8.3E+00 1000 100
1.23E+05 3.6E-01 2.6E+00 8.3E+00
1.32E+05 9.9E+00 2.6E+00 8.3E+00
1.54E+05 7.2E-01 2.6E+00 8.3E+00
1.63E+05 2.7E+00 2.6E+00 8.3E+00
1.41E+05 3.6E-01 2.6E+00 8.3E+00
9.86E+04 3.9E+01 2.6E+00 8.3E+00
1.45E+04 2.0E-01 2.6E+00 8.3E+00
4.20E+04 1.4E+00 2.6E+00 8.3E+00
8.65E+04 7.2E-01 2.6E+00 8.3E+00 1000 100
3.07E+04 1.5E+02 2.6E+00 8.3E+00
1.43E+05 3.6E-01 2.6E+00 8.3E+00
1.52E+05 4.2E-01 2.6E+00 8.3E+00
1.66E+05 7.3E-01 2.6E+00 8.3E+00
1.40E+05 2.3E+00 2.6E+00 8.3E+00
4.81 E+04 1.3E+02 2.6E+00 8.3E+00
1.30E+00 4.0E+02 2.6E+00 8.3E+00
4.03E+00 6.5E+01 2.6E+00 8.3E+00
5.96E+01 3.4E+01 2.6E+00 8.3E+00
7.31 E+00 4.5E+01 2.6E+00 8.3E+00
5.03E+00 2.1E+01 2.6E+00 8.3E+00
1.84E+01 1.4E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
8.36E+04 86% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
8.44E+04 85% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
8.74E+04 89% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-185
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Cr Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Cr EaFA-L08-1313-T01-A 1 4.58E+02
Cr EaFA-L08-1313-T02-A 1 4.31 E+02
Cr EaFA-L08-1313-T03-A 1 3.31 E+02
Cr EaFA-L08-1313-T04-A 1 1.82E+02
Cr EaFA-L08-1313-T05-A 1 7.55E+01
Cr EaFA-L08-1313-T06-A 1 1.13E+01
Cr EaFA-L08-1313-T07-A 1 1.81E+OOE
Cr EaFA-L08-1313-T08-A 1 5.17E+01
Cr EaFA-L08-1313-T09-A 1 1.63E+03
Cr EaFA-L08-1313-T01-B 1 4.54E+02
Cr EaFA-L08-1313-T02-B 1 3.60E+02
Cr EaFA-L08-1313-T03-B 1 2.67E+02
Cr EaFA-L08-1313-T04-B 1 1.74E+02
Cr EaFA-L08-1313-T05-B 1 7.21E+01
Cr EaFA-L08-1313-T06-B 1 1.15E+01
Cr EaFA-L08-1313-T07-B 1 6.00E-01 U1/2
Cr EaFA-L08-1313-T08-B 1 5.56E+01
Cr EaFA-L08-1313-T09-B 1 1.48E+03
Cr EaFA-L08-1313-T01-C 1 5.68E+02
Cr EaFA-L08-1313-T02-C 1 3.98E+02
Cr EaFA-L08-1313-T03-C 1 3.19E+02
Cr EaFA-L08-1313-T04-C 1 1.91 E+02
Cr EaFA-L08-1313-T05-C 1 8.19E+01
Cr EaFA-L08-1313-T06-C 1 1.45E+01
Cr EaFA-L08-1313-T07-C 1 1.34E+OOE
Cr EaFA-L08-1313-T08-C 1 5.15E+01
Cr EaFA-L08-1313-T09-C 1 1.64E+03
Cr EaFA-L08-1313-B01-A 1 6.00E-01 U1/2
Cr EaFA-L08-1313-B02-A 1 6.00E-01 U1/2
Cr EaFA-L08-1313-B03-A 1 2.19E+00 E
Cr EaFA-L08-1313-B01-B 1 6.00E-01 U1/2
Cr EaFA-L08-1313-B02-B 1 6.00E-01 U1/2
Cr EaFA-L08-1313-B03-B 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.58E+02 9.4E-01 1 .2E+00 3.8E+00
4.31 E+02 6.1E-01 1 .2E+00 3.8E+00
3.31E+02 1.7E+00 1 .2E+00 3.8E+00 10 325
1.82E+02 2.5E-01 1.2E+00 3.8E+00
7.55E+01 2.0E+00 1.2E+00 3.8E+00
1.13E+01 9.4E+00 1.2E+00 3.8E+00
1.81E+00 8.0E+01 1.2E+00 3.8E+00
5.17E+01 1.9E+00 1.2E+00 3.8E+00
1.63E+03 4.9E+00 1.2E+00 3.8E+00
4.54E+02 8.1E+00 1.2E+00 3.8E+00
3.60E+02 4.1E+00 1.2E+00 3.8E+00
2.67E+02 5.6E+00 1.2E+00 3.8E+00 10 325
1.74E+02 1.2E+00 1.2E+00 3.8E+00
7.21 E+01 9.2E+00 1.2E+00 3.8E+00
1.15E+01 8.7E+00 1.2E+00 3.8E+00
6.00E-01 6.4E+02 1.2E+00 3.8E+00
5.56E+01 2.3E+00 1.2E+00 3.8E+00
1.48E+03 1.7E+01 1.2E+00 3.8E+00
5.68E+02 5.3E-01 1.2E+00 3.8E+00
3.98E+02 1.5E+00 1.2E+00 3.8E+00
3.19E+02 8.3E-01 1.2E+00 3.8E+00 10 325
1.91 E+02 1.6E+02 1.2E+00 3.8E+00
8.19E+01 9.1E-01 1.2E+00 3.8E+00
1.45E+01 6.7E+00 1.2E+00 3.8E+00
1.34E+00 8.4E+01 1.2E+00 3.8E+00
5.15E+01 2.2E+00 1.2E+00 3.8E+00
1.64E+03 8.8E+01 1.2E+00 3.8E+00
6.00E-01 6.7E+01 1.2E+00 3.8E+00
6.00E-01 2.3E+02 1.2E+00 3.8E+00
2.19E+00 2.9E+01 1.2E+00 3.8E+00
6.00E-01 2.4E+02 1.2E+00 3.8E+00
6.00E-01 1.8E+02 1.2E+00 3.8E+00
6.00E-01 2.5E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
3.45E+03 96% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.34E+03 95% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.46E+03 97% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-186
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Co Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Co EaFA-L08-1313-T01-A 1 9.00E-01 U1/2
Co EaFA-L08-1313-T02-A 1 9.00E-01 U1/2
Co EaFA-L08-1313-T03-A 1 9.00E-01 U1/2
Co EaFA-L08-1313-T04-A 1 9.00E-01 U1/2
Co EaFA-L08-1313-T05-A 1 5.17E+00 E
Co EaFA-L08-1313-T06-A 1 5.91 E+01
Co EaFA-L08-1313-T07-A 1 2.03E+02
Co EaFA-L08-1313-T08-A 1 1.94E+02
Co EaFA-L08-1313-T09-A 1 4.19E+02
Co EaFA-L08-1313-T01-B 1 9.00E-01 U1/2
Co EaFA-L08-1313-T02-B 1 9.00E-01 U1/2
Co EaFA-L08-1313-T03-B 1 9.00E-01 U1/2
Co EaFA-L08-1313-T04-B 1 9.00E-01 U1/2
Co EaFA-L08-1313-T05-B 1 4.06E+00 E
Co EaFA-L08-1313-T06-B 1 6.65E+01
Co EaFA-L08-1313-T07-B 1 2.17E+02
Co EaFA-L08-1313-T08-B 1 1.97E+02
Co EaFA-L08-1313-T09-B 1 3.60E+02
Co EaFA-L08-1313-T01-C 1 9.00E-01 U1/2
Co EaFA-L08-1313-T02-C 1 9.00E-01 U1/2
Co EaFA-L08-1313-T03-C 1 9.00E-01 U1/2
Co EaFA-L08-1313-T04-C 1 9.00E-01 U1/2
Co EaFA-L08-1313-T05-C 1 5.07E+00 E
Co EaFA-L08-1313-T06-C 1 5.49E+01
Co EaFA-L08-1313-T07-C 1 2.21E+02
Co EaFA-L08-1313-T08-C 1 1.92E+02
Co EaFA-L08-1313-T09-C 1 1.75E+02
Co EaFA-L08-1313-B01-A 1 9.00E-01 U1/2
Co EaFA-L08-1313-B02-A 1 9.00E-01 U1/2
Co EaFA-L08-1313-B03-A 1 9.00E-01 U1/2
Co EaFA-L08-1313-B01-B 1 9.00E-01 U1/2
Co EaFA-L08-1313-B02-B 1 9.00E-01 U1/2
Co EaFA-L08-1313-B03-B 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 8.3E+01 1.8E+00 5.7E+00
9.00E-01 9.4E+01 1.8E+00 5.7E+00
9.00E-01 8.0E+01 1.8E+00 5.7E+00 10 325
9.00E-01 3.0E+03 1.8E+00 5.7E+00
5.17E+00 3.2E+01 1.8E+00 5.7E+00
5.91 E+01 6.2E-01 1.8E+00 5.7E+00
2.03E+02 1.2E+01 1.8E+00 5.7E+00
1.94E+02 8.6E-01 1.8E+00 5.7E+00
4.19E+02 1.4E+01 1.8E+00 5.7E+00
9.00E-01 1.0E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00 10 325
9.00E-01 4.7E+01 1.8E+00 5.7E+00
4.06E+00 5.6E+01 1.8E+00 5.7E+00
6.65E+01 2.9E+00 1.8E+00 5.7E+00
2.17E+02 3.1E+00 1.8E+00 5.7E+00
1.97E+02 4.0E-01 1.8E+00 5.7E+00
3.60E+02 4.2E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 3.9E+01 1.8E+00 5.7E+00
9.00E-01 6.0E+01 1.8E+00 5.7E+00 10 325
9.00E-01 2.9E+01 1.8E+00 5.7E+00
5.07E+00 2.6E+01 1.8E+00 5.7E+00
5.49E+01 5.6E+00 1.8E+00 5.7E+00
2.21 E+02 1.3E+00 1.8E+00 5.7E+00
1.92E+02 2.4E+00 1.8E+00 5.7E+00
1.75E+02 1.3E+02 1.8E+00 5.7E+00
9.00E-01 3.7E+01 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 2.7E+01 1.8E+00 5.7E+00
9.00E-01 2.9E+02 1.8E+00 5.7E+00
9.00E-01 8.8E+01 1.8E+00 5.7E+00
9.00E-01 8.9E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
3.16E+03 97% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.14E+03 97% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.17E+03 98% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-187
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Cu Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Cu EaFA-L08-1313-T01-A 1 1.72E+01
Cu EaFA-L08-1313-T02-A 1 6.05E+00 E
Cu EaFA-L08-1313-T03-A 1 5.29E+00 E
Cu EaFA-L08-1313-T04-A 1 9.27E+00 E
Cu EaFA-L08-1313-T05-A 1 1.23E+01
Cu EaFA-L08-1313-T06-A 1 1.22E+01
Cu EaFA-L08-1313-T07-A 1 1.16E+02
Cu EaFA-L08-1313-T08-A 1 1.80E+03
Cu EaFA-L08-1313-T09-A 1 2.58E+03
Cu EaFA-L08-1313-T01-B 1 1.41E+01
Cu EaFA-L08-1313-T02-B 1 7.12E+00 E
Cu EaFA-L08-1313-T03-B 1 1.85E+OOU1/2
Cu EaFA-L08-1313-T04-B 1 7.51E+00 E
Cu EaFA-L08-1313-T05-B 1 5.46E+00 E
Cu EaFA-L08-1313-T06-B 1 8.91E+00 E
Cu EaFA-L08-1313-T07-B 1 8.15E+01
Cu EaFA-L08-1313-T08-B 1 1.81E+03
Cu EaFA-L08-1313-T09-B 1 2.09E+03
Cu EaFA-L08-1313-T01-C 1 4.20E+01
Cu EaFA-L08-1313-T02-C 1 1.85E+OOU1/2
Cu EaFA-L08-1313-T03-C 1 1.85E+OOU1/2
Cu EaFA-L08-1313-T04-C 1 1.85E+OOU1/2
Cu EaFA-L08-1313-T05-C 1 1.85E+OOU1/2
Cu EaFA-L08-1313-T06-C 1 6.26E+00 E
Cu EaFA-L08-1313-T07-C 1 7.72E+01
Cu EaFA-L08-1313-T08-C 1 1.82E+03
Cu EaFA-L08-1313-T09-C 1 1.49E+03
Cu EaFA-L08-1313-B01-A 1 1.85E+OOU1/2
Cu EaFA-L08-1313-B02-A 1 1.85E+OOU1/2
Cu EaFA-L08-1313-B03-A 1 1.85E+OOU1/2
Cu EaFA-L08-1313-B01-B 1 1.85E+OOU1/2
Cu EaFA-L08-1313-B02-B 1 1.85E+OOU1/2
Cu EaFA-L08-1313-B03-B 1 1.85E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.72E+01 1.6E+01 3.7E+00 1.2E+01
6.05E+00 6.5E+01 3.7E+00 1.2E+01
5.29E+00 2.0E+01 3.7E+00 1.2E+01 10 325
9.27E+00 4.3E+01 3.7E+00 1.2E+01
1.23E+01 1.5E+01 3.7E+00 1.2E+01
1.22E+01 1.5E+01 3.7E+00 1.2E+01
1.16E+02 6.5E+00 3.7E+00 1.2E+01
1.80E+03 1.3E+00 3.7E+00 1.2E+01
2.58E+03 1.4E+01 3.7E+00 1.2E+01
1.41E+01 1.1E+01 3.7E+00 1.2E+01
7.12E+00 1.1E+02 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01 10 325
7.51 E+00 5.6E+01 3.7E+00 1.2E+01
5.46E+00 6.5E+01 3.7E+00 1.2E+01
8.91 E+00 6.0E+01 3.7E+00 1.2E+01
8.15E+01 4.4E+00 3.7E+00 1.2E+01
1.81E+03 5.3E-01 3.7E+00 1.2E+01
2.09E+03 4.8E+01 3.7E+00 1.2E+01
4.20E+01 2.3E+01 3.7E+00 1.2E+01
1.85E+00 5.2E+02 3.7E+00 1.2E+01
1.85E+00 1.4E+02 3.7E+00 1.2E+01 10 325
1.85E+00 3.6E+02 3.7E+00 1.2E+01
1.85E+00 4.3E+02 3.7E+00 1.2E+01
6.26E+00 5.8E+01 3.7E+00 1.2E+01
7.72E+01 9.3E+00 3.7E+00 1.2E+01
1.82E+03 6.8E-01 3.7E+00 1.2E+01
1.49E+03 8.1E+01 3.7E+00 1.2E+01
1.85E+00 2.4E+02 3.7E+00 1.2E+01
1.85E+00 4.0E+02 3.7E+00 1.2E+01
1.85E+00 2.7E+03 3.7E+00 1.2E+01
1.85E+00 4.6E+02 3.7E+00 1.2E+01
1.85E+00 4.5E+01 3.7E+00 1.2E+01
1.85E+00 1.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
3.12E+03 96% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.06E+03 94% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.11E+03 96% VUICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-188
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Fe Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Fe EaFA-L08-1313-T01-A 1 2.30E+01
Fe EaFA-L08-1313-T02-A 1 2.81E+01
Fe EaFA-L08-1313-T03-A 1 7.52E+00
Fe EaFA-L08-1313-T04-A 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T05-A 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T06-A 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T07-A 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T08-A 1 2.83E+02
Fe EaFA-L08-1313-T09-A 1 4.09E+04
Fe EaFA-L08-1313-T01-B 1 1.42E+01
Fe EaFA-L08-1313-T02-B 1 2.79E+01
Fe EaFA-L08-1313-T03-B 1 4.98E+00 E
Fe EaFA-L08-1313-T04-B 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T05-B 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T06-B 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T07-B 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T08-B 1 2.91E+02
Fe EaFA-L08-1313-T09-B 1 3.27E+04
Fe EaFA-L08-1313-T01-C 1 4.00E+01
Fe EaFA-L08-1313-T02-C 1 2.32E+01
Fe EaFA-L08-1313-T03-C 1 4.20E+00 E
Fe EaFA-L08-1313-T04-C 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T05-C 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T06-C 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T07-C 1 1.00E+OOU1/2
Fe EaFA-L08-1313-T08-C 1 3.18E+02
Fe EaFA-L08-1313-T09-C 1 1.62E+04
Fe EaFA-L08-1313-B01-A 1 1.00E+OOU1/2
Fe EaFA-L08-1313-B02-A 1 1.00E+OOU1/2
Fe EaFA-L08-1313-B03-A 1 1.55E+01
Fe EaFA-L08-1313-B01-B 1 1.00E+OOU1/2
Fe EaFA-L08-1313-B02-B 1 1.00E+OOU1/2
Fe EaFA-L08-1313-B03-B 1 2.13E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+01 2.2E+00 2.0E+00 6.4E+00
2.81E+01 9.2E-01 2.0E+00 6.4E+00
7.52E+00 2.3E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
2.83E+02 4.6E-01 2.0E+00 6.4E+00
4.09E+04 2.8E+00 2.0E+00 6.4E+00
1.42E+01 1.6E+01 2.0E+00 6.4E+00
2.79E+01 4.4E+00 2.0E+00 6.4E+00
4.98E+00 1.0E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 6.1E+00 2.0E+00 6.4E+00
2.91 E+02 8.0E-01 2.0E+00 6.4E+00
3.27E+04 2.7E+01 2.0E+00 6.4E+00
4.00E+01 7.0E-01 2.0E+00 6.4E+00
2.32E+01 4.0E+00 2.0E+00 6.4E+00
4.20E+00 6.9E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 5.6E+00 2.0E+00 6.4E+00
1.00E+00 4.6E+00 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00
3.18E+02 2.3E+00 2.0E+00 6.4E+00
1.62E+04 1.0E+02 2.0E+00 6.4E+00
1.00E+00 6.7E+00 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.55E+01 2.2E+00 2.0E+00 6.4E+00
1.00E+00 6.1E+00 2.0E+00 6.4E+00
1.00E+00 4.9E+01 2.0E+00 6.4E+00
2.13E+00 2.4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
1.05E+03 105% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:46AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:48AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:50AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
1.03E+03 103% VUICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
1.05E+03 104% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-189
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Pb Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Pb EaFA-L08-1313-T01-A 1 1.33E+01 E
Pb EaFA-L08-1313-T02-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T03-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T04-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T05-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T06-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T07-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T08-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T09-A 1 1.50E+02
Pb EaFA-L08-1313-T01-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T02-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T03-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T04-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T05-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T06-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T07-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T08-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T09-B 1 9.98E+01
Pb EaFA-L08-1313-T01-C 1 1 .58E+01 E
Pb EaFA-L08-1313-T02-C 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T03-C 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T04-C 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T05-C 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T06-C 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T07-C 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T08-C 1 3.40E+00 U1/2
Pb EaFA-L08-1313-T09-C 1 5.50E+01
Pb EaFA-L08-1313-B01-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-B02-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-B03-A 1 3.40E+00 U1/2
Pb EaFA-L08-1313-B01-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-B02-B 1 3.40E+00 U1/2
Pb EaFA-L08-1313-B03-B 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+01 6.2E+01 6.8E+00 2.2E+01
3.40E+00 2.0E+02 6.8E+00 2.2E+01
3.40E+00 7.6E+01 6.8E+00 2.2E+01 10 325
3.40E+00 5.1E+01 6.8E+00 2.2E+01
3.40E+00 2.5E+02 6.8E+00 2.2E+01
3.40E+00 2.0E+02 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
3.40E+00 2.3E+02 6.8E+00 2.2E+01
1.50E+02 1.1E+01 6.8E+00 2.2E+01
3.40E+00 3.4E+03 6.8E+00 2.2E+01
3.40E+00 4.3E+01 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01 10 325
3.40E+00 5.1E+01 6.8E+00 2.2E+01
3.40E+00 4.1E+03 6.8E+00 2.2E+01
3.40E+00 5.2E+02 6.8E+00 2.2E+01
3.40E+00 4.7E+02 6.8E+00 2.2E+01
3.40E+00 8.1E+03 6.8E+00 2.2E+01
9.98E+01 5.1E+01 6.8E+00 2.2E+01
1.58E+01 8.1E+01 6.8E+00 2.2E+01
3.40E+00 8.3E+01 6.8E+00 2.2E+01
3.40E+00 6.9E+01 6.8E+00 2.2E+01 10 325
3.40E+00 9.7E+01 6.8E+00 2.2E+01
3.40E+00 7.9E+02 6.8E+00 2.2E+01
3.40E+00 1.8E+02 6.8E+00 2.2E+01
3.40E+00 1.6E+02 6.8E+00 2.2E+01
3.40E+00 2.7E+02 6.8E+00 2.2E+01
5.50E+01 1.5E+02 6.8E+00 2.2E+01
3.40E+00 6.9E+01 6.8E+00 2.2E+01
3.40E+00 2.0E+02 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 5.3E+00 6.8E+00 2.2E+01
3.40E+00 6.2E+02 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:40AM EPA Interlab LOS 1313-1316 EaFA
3.19E+03 98% VUICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:43AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:46AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:50AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.11E+03 96% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.18E+03 98% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-190
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Li Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Li EaFA-L08-1313-T01-A 1 2.10E+03
Li EaFA-L08-1313-T02-A 1 2.79E+03
Li EaFA-L08-1313-T03-A 1 3.05E+03
Li EaFA-L08-1313-T04-A 1 3.31 E+03
Li EaFA-L08-1313-T05-A 1 3.44E+03
Li EaFA-L08-1313-T06-A 1 3.46E+03
Li EaFA-L08-1313-T07-A 1 3.15E+03
Li EaFA-L08-1313-T08-A 1 2.49E+03
Li EaFA-L08-1313-T09-A 1 1.12E+03
Li EaFA-L08-1313-T01-B 1 1.96E+03
Li EaFA-L08-1313-T02-B 1 2.66E+03
Li EaFA-L08-1313-T03-B 1 2.90E+03
Li EaFA-L08-1313-T04-B 1 3.20E+03
Li EaFA-L08-1313-T05-B 1 3.12E+03
Li EaFA-L08-1313-T06-B 1 3.46E+03
Li EaFA-L08-1313-T07-B 1 3.47E+03
Li EaFA-L08-1313-T08-B 1 2.49E+03
Li EaFA-L08-1313-T09-B 1 9.66E+02
Li EaFA-L08-1313-T01-C 1 2.06E+03
Li EaFA-L08-1313-T02-C 1 2.68E+03
Li EaFA-L08-1313-T03-C 1 2.99E+03
Li EaFA-L08-1313-T04-C 1 8.23E+02
Li EaFA-L08-1313-T05-C 1 3.40E+03
Li EaFA-L08-1313-T06-C 1 3.41 E+03
Li EaFA-L08-1313-T07-C 1 3.50E+03
Li EaFA-L08-1313-T08-C 1 2.43E+03
Li EaFA-L08-1313-T09-C 1 5.75E+02
Li EaFA-L08-1313-B01-A 1 5.07E+01
Li EaFA-L08-1313-B02-A 1 4.97E+01
Li EaFA-L08-1313-B03-A 1 5.00E+01
Li EaFA-L08-1313-B01-B 1 5.14E+01
Li EaFA-L08-1313-B02-B 1 5.10E+01
Li EaFA-L08-1313-B03-B 1 5.17E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.10E+03 6.7E-01 1 .9E+00 6.0E+00
2.79E+03 2.2E-01 1 .9E+00 6.0E+00
3.05E+03 1.2E+00 1 .9E+00 6.0E+00 10 325
3.31 E+03 4.0E-01 1 .9E+00 6.0E+00
3.44E+03 5.3E-01 1 .9E+00 6.0E+00
3.46E+03 1.7E+00 1 .9E+00 6.0E+00
3.15E+03 1.3E+01 1 .9E+00 6.0E+00
2.49E+03 1.0E-01 1 .9E+00 6.0E+00
1.12E+03 3.2E+01 1 .9E+00 6.0E+00
1.96E+03 8.2E+00 1 .9E+00 6.0E+00
2.66E+03 3.6E+00 1 .9E+00 6.0E+00
2.90E+03 5.3E+00 1 .9E+00 6.0E+00 10 325
3.20E+03 2.9E+00 1 .9E+00 6.0E+00
3.12E+03 9.7E+00 1 .9E+00 6.0E+00
3.46E+03 5.8E-01 1 .9E+00 6.0E+00
3.47E+03 2.5E+00 1 .9E+00 6.0E+00
2.49E+03 5.8E-01 1 .9E+00 6.0E+00
9.66E+02 5.9E+01 1 .9E+00 6.0E+00
2.06E+03 5.7E-01 1 .9E+00 6.0E+00
2.68E+03 9.9E-01 1 .9E+00 6.0E+00
2.99E+03 2.7E-01 1 .9E+00 6.0E+00 10 325
8.23E+02 1.5E+02 1 .9E+00 6.0E+00
3.40E+03 1.3E-01 1.9E+00 6.0E+00
3.41 E+03 2.9E-01 1.9E+00 6.0E+00
3.50E+03 6.8E-01 1.9E+00 6.0E+00
2.43E+03 3.6E+00 1.9E+00 6.0E+00
5.75E+02 1.2E+02 1.9E+00 6.0E+00
5.07E+01 2.2E+00 1.9E+00 6.0E+00
4.97E+01 2.1E+00 1.9E+00 6.0E+00
5.00E+01 1.9E+00 1.9E+00 6.0E+00
5.14E+01 2.4E+00 1.9E+00 6.0E+00
5.10E+01 6.2E-01 1.9E+00 6.0E+00
5.17E+01 1.0E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
5.74E+03 83% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
5.73E+03 87% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
5.77E+03 85% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-191
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn EaFA-L08-1313-T01-A 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T02-A 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T03-A 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T04-A 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T05-A 1 6.99E+01
Mn EaFA-L08-1313-T06-A 1 4.47E+02
Mn EaFA-L08-1313-T07-A 1 8.54E+02
Mn EaFA-L08-1313-T08-A 1 1.02E+03
Mn EaFA-L08-1313-T09-A 1 1.40E+03
Mn EaFA-L08-1313-T01-B 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T02-B 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T03-B 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T04-B 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T05-B 1 6.94E+01
Mn EaFA-L08-1313-T06-B 1 4.65E+02
Mn EaFA-L08-1313-T07-B 1 9.21E+02
Mn EaFA-L08-1313-T08-B 1 1.07E+03
Mn EaFA-L08-1313-T09-B 1 1.18E+03
Mn EaFA-L08-1313-T01-C 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T02-C 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T03-C 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T04-C 1 1.00E+OOU1/2
Mn EaFA-L08-1313-T05-C 1 7.45E+01
Mn EaFA-L08-1313-T06-C 1 4.12E+02
Mn EaFA-L08-1313-T07-C 1 9.48E+02
Mn EaFA-L08-1313-T08-C 1 1.04E+03
Mn EaFA-L08-1313-T09-C 1 7.13E+02
Mn EaFA-L08-1313-B01-A 1 1.00E+OOU1/2
Mn EaFA-L08-1313-B02-A 1 1.00E+OOU1/2
Mn EaFA-L08-1313-B03-A 1 1.00E+OOU1/2
Mn EaFA-L08-1313-B01-B 1 1.00E+OOU1/2
Mn EaFA-L08-1313-B02-B 1 1.00E+OOU1/2
Mn EaFA-L08-1313-B03-B 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 8.1E+01 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00 10 325
1.00E+00 8.0E+00 2.0E+00 6.4E+00
6.99E+01 1.1E+00 2.0E+00 6.4E+00
4.47E+02 7.3E-01 2.0E+00 6.4E+00
8.54E+02 1.1E+01 2.0E+00 6.4E+00
1.02E+03 3.5E-01 2.0E+00 6.4E+00
1.40E+03 3.1E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 7.0E+01 2.0E+00 6.4E+00 10 325
1.00E+00 8.5E+00 2.0E+00 6.4E+00
6.94E+01 9.3E+00 2.0E+00 6.4E+00
4.65E+02 3.2E-01 2.0E+00 6.4E+00
9.21E+02 3.2E+00 2.0E+00 6.4E+00
1.07E+03 8.4E-01 2.0E+00 6.4E+00
1.18E+03 6.4E+01 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00 10 325
1.00E+00 3.1E+03 2.0E+00 6.4E+00
7.45E+01 8.3E-01 2.0E+00 6.4E+00
4.12E+02 6.3E-01 2.0E+00 6.4E+00
9.48E+02 5.5E-01 2.0E+00 6.4E+00
1.04E+03 2.5E+00 2.0E+00 6.4E+00
7.13E+02 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 4.3E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
3.32E+03 102% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.23E+03 99% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.30E+03 102% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-192
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mg Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mg EaFA-L08-1313-T01-A 1 1.52E+OOE
Mg EaFA-L08-1313-T02-A 1 2.89E+00 E
Mg EaFA-L08-1313-T03-A 1 6.30E+01
Mg EaFA-L08-1313-T04-A 1 2.76E+03
Mg EaFA-L08-1313-T05-A 1 5.57E+03
Mg EaFA-L08-1313-T06-A 1 7.11E+03
Mg EaFA-L08-1313-T07-A 1 7.02E+03
Mg EaFA-L08-1313-T08-A 1 7.00E+03
Mg EaFA-L08-1313-T09-A 1 1.07E+04
Mg EaFA-L08-1313-T01-B 1 1.62E+OOE
Mg EaFA-L08-1313-T02-B 1 1.20E+OOE
Mg EaFA-L08-1313-T03-B 1 1.06E+02
Mg EaFA-L08-1313-T04-B 1 2.86E+03
Mg EaFA-L08-1313-T05-B 1 5.27E+03
Mg EaFA-L08-1313-T06-B 1 7.22E+03
Mg EaFA-L08-1313-T07-B 1 7.90E+03
Mg EaFA-L08-1313-T08-B 1 7.10E+03
Mg EaFA-L08-1313-T09-B 1 1.12E+04
Mg EaFA-L08-1313-T01-C 1 4.25E+00
Mg EaFA-L08-1313-T02-C 1 5.00E-01 U1/2
Mg EaFA-L08-1313-T03-C 1 1.19E+02
Mg EaFA-L08-1313-T04-C 1 7.57E+02
Mg EaFA-L08-1313-T05-C 1 5.88E+03
Mg EaFA-L08-1313-T06-C 1 7.15E+03
Mg EaFA-L08-1313-T07-C 1 8.05E+03
Mg EaFA-L08-1313-T08-C 1 6.92E+03
Mg EaFA-L08-1313-T09-C 1 5.77E+03
Mg EaFA-L08-1313-B01-A 1 5.00E-01 U1/2
Mg EaFA-L08-1313-B02-A 1 5.00E-01 U1/2
Mg EaFA-L08-1313-B03-A 1 5.00E-01 U1/2
Mg EaFA-L08-1313-B01-B 1 5.00E-01 U1/2
Mg EaFA-L08-1313-B02-B 1 5.00E-01 U1/2
Mg EaFA-L08-1313-B03-B 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.52E+00 3.1E+02 1 .OE+00 3.2E+00
2.89E+00 2.1E+02 1 .OE+00 3.2E+00
6.30E+01 5.6E+00 1 .OE+00 3.2E+00 1000 100
2.76E+03 9.5E-01 1. OE+00 3.2E+00
5.57E+03 5.1E-01 1.0E+00 3.2E+00
7.11E+03 3.2E-01 1. OE+00 3.2E+00
7.02E+03 1.4E+01 1. OE+00 3.2E+00
7.00E+03 3.8E-01 1. OE+00 3.2E+00
1.07E+04 4.2E+01 1. OE+00 3.2E+00
1.62E+00 3.6E+02 1. OE+00 3.2E+00
1.20E+00 5.0E+02 1. OE+00 3.2E+00
1.06E+02 1.1E+01 1.0E+00 3.2E+00 1000 100
2.86E+03 2.4E+00 1. OE+00 3.2E+00
5.27E+03 1.1E+01 1. OE+00 3.2E+00
7.22E+03 3.8E-01 1. OE+00 3.2E+00
7.90E+03 2.9E+00 1. OE+00 3.2E+00
7.10E+03 7.5E-01 1. OE+00 3.2E+00
1.12E+04 2.3E+01 1. OE+00 3.2E+00
4.25E+00 2.2E+02 1. OE+00 3.2E+00
5.00E-01 1.1E+02 1. OE+00 3.2E+00
1.19E+02 8.4E+00 1. OE+00 3.2E+00 1000 100
7.57E+02 1.6E+02 1. OE+00 3.2E+00
5.88E+03 7.9E-01 1. OE+00 3.2E+00
7.15E+03 4.3E-01 1. OE+00 3.2E+00
8.05E+03 3.7E-01 1. OE+00 3.2E+00
6.92E+03 2.4E+00 1. OE+00 3.2E+00
5.77E+03 1.2E+02 1. OE+00 3.2E+00
5.00E-01 6.5E+01 1. OE+00 3.2E+00
5.00E-01 9.7E+01 1. OE+00 3.2E+00
5.00E-01 3.9E+03 1. OE+00 3.2E+00
5.00E-01 1.9E+02 1. OE+00 3.2E+00
5.00E-01 7.9E+01 1. OE+00 3.2E+00
5.00E-01 2.5E+02 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
1.02E+03 95% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
1.05E+03 94% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
1.05E+03 93% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-193
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mo Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mo EaFA-L08-1313-T01-A 1 4.19E+03
Mo EaFA-L08-1313-T02-A 1 4.12E+03
Mo EaFA-L08-1313-T03-A 1 4.05E+03
Mo EaFA-L08-1313-T04-A 1 3.95E+03
Mo EaFA-L08-1313-T05-A 1 3.76E+03
Mo EaFA-L08-1313-T06-A 1 3.30E+03
Mo EaFA-L08-1313-T07-A 1 6.66E+02
Mo EaFA-L08-1313-T08-A 1 1.35E+02
Mo EaFA-L08-1313-T09-A 1 3.78E+02
Mo EaFA-L08-1313-T01-B 1 3.99E+03
Mo EaFA-L08-1313-T02-B 1 3.89E+03
Mo EaFA-L08-1313-T03-B 1 3.81 E+03
Mo EaFA-L08-1313-T04-B 1 3.96E+03
Mo EaFA-L08-1313-T05-B 1 3.49E+03
Mo EaFA-L08-1313-T06-B 1 3.27E+03
Mo EaFA-L08-1313-T07-B 1 9.70E+02
Mo EaFA-L08-1313-T08-B 1 1.34E+02
Mo EaFA-L08-1313-T09-B 1 2.52E+02
Mo EaFA-L08-1313-T01-C 1 4.19E+03
Mo EaFA-L08-1313-T02-C 1 3.92E+03
Mo EaFA-L08-1313-T03-C 1 3.97E+03
Mo EaFA-L08-1313-T04-C 1 1.04E+03
Mo EaFA-L08-1313-T05-C 1 3.83E+03
Mo EaFA-L08-1313-T06-C 1 3.34E+03
Mo EaFA-L08-1313-T07-C 1 1.02E+03
Mo EaFA-L08-1313-T08-C 1 1.32E+02
Mo EaFA-L08-1313-T09-C 1 1.11E+02
Mo EaFA-L08-1313-B01-A 1 9.91E+00
Mo EaFA-L08-1313-B02-A 1 8.75E+00
Mo EaFA-L08-1313-B03-A 1 3.98E+01
Mo EaFA-L08-1313-B01-B 1 9.23E+00
Mo EaFA-L08-1313-B02-B 1 7.33E+00
Mo EaFA-L08-1313-B03-B 1 1.36E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.19E+03 1.1E+00 1.2E+00 3.8E+00
4.12E+03 5.0E-01 1 .2E+00 3.8E+00
4.05E+03 3.9E-01 1 .2E+00 3.8E+00 10 325
3.95E+03 2.1E+00 1.2E+00 3.8E+00
3.76E+03 4.6E-01 1.2E+00 3.8E+00
3.30E+03 8.6E-01 1.2E+00 3.8E+00
6.66E+02 1.3E+01 1.2E+00 3.8E+00
1.35E+02 2.6E-01 1.2E+00 3.8E+00
3.78E+02 1.4E+01 1.2E+00 3.8E+00
3.99E+03 7.7E+00 1.2E+00 3.8E+00
3.89E+03 4.4E+00 1.2E+00 3.8E+00
3.81E+03 3.1E+00 1.2E+00 3.8E+00 10 325
3.96E+03 3.7E+00 1.2E+00 3.8E+00
3.49E+03 9.3E+00 1.2E+00 3.8E+00
3.27E+03 4.6E-01 1.2E+00 3.8E+00
9.70E+02 3.7E+00 1.2E+00 3.8E+00
1.34E+02 9.7E-01 1.2E+00 3.8E+00
2.52E+02 4.7E+01 1.2E+00 3.8E+00
4.19E+03 5.4E-01 1.2E+00 3.8E+00
3.92E+03 1.6E+00 1.2E+00 3.8E+00
3.97E+03 4.7E-01 1.2E+00 3.8E+00 10 325
1.04E+03 1.5E+02 1.2E+00 3.8E+00
3.83E+03 7.9E-01 1.2E+00 3.8E+00
3.34E+03 6.3E-01 1.2E+00 3.8E+00
1.02E+03 6.6E-01 1.2E+00 3.8E+00
1.32E+02 2.6E+00 1.2E+00 3.8E+00
1.11E+02 1.2E+02 1.2E+00 3.8E+00
9.91 E+00 4.9E+00 1.2E+00 3.8E+00
8.75E+00 2.7E+01 1.2E+00 3.8E+00
3.98E+01 9.5E+00 1.2E+00 3.8E+00
9.23E+00 7.1 E+00 1.2E+00 3.8E+00
7.33E+00 2.7E+01 1.2E+00 3.8E+00
1.36E+01 6.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
6.87E+03 87% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
6.74E+03 90% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
6.86E+03 89% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-194
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ni Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Ni EaFA-L08-1313-T01-A 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T02-A 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T03-A 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T04-A 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T05-A 1 1.83E+01
Ni EaFA-L08-1313-T06-A 1 1.47E+02
Ni EaFA-L08-1313-T07-A 1 5.20E+02
Ni EaFA-L08-1313-T08-A 1 4.99E+02
Ni EaFA-L08-1313-T09-A 1 7.07E+02
Ni EaFA-L08-1313-T01-B 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T02-B 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T03-B 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T04-B 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T05-B 1 1.80E+01
Ni EaFA-L08-1313-T06-B 1 1.50E+02
Ni EaFA-L08-1313-T07-B 1 5.50E+02
Ni EaFA-L08-1313-T08-B 1 5.09E+02
Ni EaFA-L08-1313-T09-B 1 5.96E+02
Ni EaFA-L08-1313-T01-C 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T02-C 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T03-C 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T04-C 1 9.00E-01 U1/2
Ni EaFA-L08-1313-T05-C 1 1.44E+01
Ni EaFA-L08-1313-T06-C 1 1.20E+02
Ni EaFA-L08-1313-T07-C 1 5.50E+02
Ni EaFA-L08-1313-T08-C 1 4.98E+02
Ni EaFA-L08-1313-T09-C 1 3.08E+02
Ni EaFA-L08-1313-B01-A 1 9.00E-01 U1/2
Ni EaFA-L08-1313-B02-A 1 9.00E-01 U1/2
Ni EaFA-L08-1313-B03-A 1 9.00E-01 U1/2
Ni EaFA-L08-1313-B01-B 1 9.00E-01 U1/2
Ni EaFA-L08-1313-B02-B 1 9.00E-01 U1/2
Ni EaFA-L08-1313-B03-B 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.6E+01 1.8E+00 5.7E+00
9.00E-01 5.2E+01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00 10 325
9.00E-01 8.6E+01 1.8E+00 5.7E+00
1.83E+01 1.8E+01 1.8E+00 5.7E+00
1.47E+02 2.9E+00 1.8E+00 5.7E+00
5.20E+02 1.3E+01 1.8E+00 5.7E+00
4.99E+02 4.1E-01 1.8E+00 5.7E+00
7.07E+02 1.1E+01 1.8E+00 5.7E+00
9.00E-01 3.5E+01 1.8E+00 5.7E+00
9.00E-01 6.7E+01 1.8E+00 5.7E+00
9.00E-01 8.1E+01 1.8E+00 5.7E+00 10 325
9.00E-01 9.4E+01 1.8E+00 5.7E+00
1.80E+01 5.5E+00 1.8E+00 5.7E+00
1.50E+02 3.6E+00 1.8E+00 5.7E+00
5.50E+02 2.3E+00 1.8E+00 5.7E+00
5.09E+02 7.0E-01 1.8E+00 5.7E+00
5.96E+02 3.9E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 6.5E+01 1.8E+00 5.7E+00
9.00E-01 3.5E+01 1.8E+00 5.7E+00 10 325
9.00E-01 6.5E+00 1.8E+00 5.7E+00
1.44E+01 9.7E+00 1.8E+00 5.7E+00
1.20E+02 5.2E+00 1.8E+00 5.7E+00
5.50E+02 1.9E+00 1.8E+00 5.7E+00
4.98E+02 3.3E+00 1.8E+00 5.7E+00
3.08E+02 1.3E+02 1.8E+00 5.7E+00
9.00E-01 2.5E+01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 2.2E+02 1.8E+00 5.7E+00
9.00E-01 3.0E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+01 1.8E+00 5.7E+00
9.00E-01 6.4E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
3.23E+03 99% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.16E+03 97% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.22E+03 99% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-195
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
P Sample Dilution Cone. Qualifier Review
ug/L
P EaFA-L08-1313-T01-A 1 1.16E+02
P EaFA-L08-1313-T02-A 1 1.88E+01
P EaFA-L08-1313-T03-A 1 1.23E+01
P EaFA-L08-1313-T04-A 1 1.29E+02
P EaFA-L08-1313-T05-A 1 6.10E+01
P EaFA-L08-1313-T06-A 1 1.36E+01
P EaFA-L08-1313-T07-A 1 1.38E+01
P EaFA-L08-1313-T08-A 1 1.40E+01
P EaFA-L08-1313-T09-A 1 3.02E+03
P EaFA-L08-1313-T01-B 1 8.07E+01
P EaFA-L08-1313-T02-B 1 2.80E+01
P EaFA-L08-1313-T03-B 1 1.67E+01
P EaFA-L08-1313-T04-B 1 1.05E+02
P EaFA-L08-1313-T05-B 1 5.17E+01
P EaFA-L08-1313-T06-B 1 2.73E+01
P EaFA-L08-1313-T07-B 1 1.64E+01
P EaFA-L08-1313-T08-B 1 1.61E+01
P EaFA-L08-1313-T09-B 1 1.92E+03
P EaFA-L08-1313-T01-C 1 7.71 E+01
P EaFA-L08-1313-T02-C 1 1.38E+01
P EaFA-L08-1313-T03-C 1 2.82E+01
P EaFA-L08-1313-T04-C 1 2.60E+01
P EaFA-L08-1313-T05-C 1 6.06E+01
P EaFA-L08-1313-T06-C 1 3.27E+01
P EaFA-L08-1313-T07-C 1 1.50E+01
P EaFA-L08-1313-T08-C 1 1.96E+01
P EaFA-L08-1313-T09-C 1 6.63E+02
P EaFA-L08-1313-B01-A 1 1.85E+OOU1/2
P EaFA-L08-1313-B02-A 1 1.85E+OOU1/2
P EaFA-L08-1313-B03-A 1 1.97E+01
P EaFA-L08-1313-B01-B 1 1.85E+OOU1/2
P EaFA-L08-1313-B02-B 1 1.85E+OOU1/2
P EaFA-L08-1313-B03-B 1 1.85E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.16E+02 1.6E+01 3.7E+00 1.2E+01
1.88E+01 1.7E+01 3.7E+00 1.2E+01
1.23E+01 7.7E+01 3.7E+00 1.2E+01 1000 100
1.29E+02 2.2E+00 3.7E+00 1.2E+01
6.10E+01 1.5E+01 3.7E+00 1.2E+01
1.36E+01 5.6E+01 3.7E+00 1.2E+01
1.38E+01 7.0E+01 3.7E+00 1.2E+01
1.40E+01 2.8E+01 3.7E+00 1.2E+01
3.02E+03 1.3E+01 3.7E+00 1.2E+01
8.07E+01 2.3E+01 3.7E+00 1.2E+01
2.80E+01 1.8E+01 3.7E+00 1.2E+01
1.67E+01 3.1E+01 3.7E+00 1.2E+01 1000 100
1.05E+02 4.1E+00 3.7E+00 1.2E+01
5.17E+01 1.7E+01 3.7E+00 1.2E+01
2.73E+01 2.6E+01 3.7E+00 1.2E+01
1.64E+01 3.3E+01 3.7E+00 1.2E+01
1.61 E+01 7.0E+01 3.7E+00 1.2E+01
1.92E+03 3.9E+01 3.7E+00 1.2E+01
7.71E+01 1.3E+01 3.7E+00 1.2E+01
1.38E+01 4.7E+01 3.7E+00 1.2E+01
2.82E+01 2.4E+01 3.7E+00 1.2E+01 1000 100
2.60E+01 2.2E+02 3.7E+00 1.2E+01
6.06E+01 2.0E+01 3.7E+00 1.2E+01
3.27E+01 3.1E+01 3.7E+00 1.2E+01
1.50E+01 4.5E+01 3.7E+00 1.2E+01
1.96E+01 2.7E+01 3.7E+00 1.2E+01
6.63E+02 1.3E+02 3.7E+00 1.2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01
1.85E+00 4.7E+02 3.7E+00 1.2E+01
1.97E+01 1.6E+00 3.7E+00 1.2E+01
1.85E+00 1.8E+03 3.7E+00 1.2E+01
1.85E+00 1.6E+02 3.7E+00 1.2E+01
1.85E+00 5.0E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
1.11E+03 110% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
1.09E+03 108% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
1.14E+03 112% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-196
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
ug/L
K EaFA-L08-1313-T01-A 1 5.16E+04
K EaFA-L08-1313-T02-A 1 3.37E+04
K EaFA-L08-1313-T03-A 1 2.68E+04
K EaFA-L08-1313-T04-A 1 2.54E+04
K EaFA-L08-1313-T05-A 1 2.47E+04
K EaFA-L08-1313-T06-A 1 2.42E+04
K EaFA-L08-1313-T07-A 1 2.24E+04
K EaFA-L08-1313-T08-A 1 1.94E+04
K EaFA-L08-1313-T09-A 1 1.99E+04
K EaFA-L08-1313-T01-B 1 4.89E+04
K EaFA-L08-1313-T02-B 1 3.05E+04
K EaFA-L08-1313-T03-B 1 2.47E+04
K EaFA-L08-1313-T04-B 1 2.48E+04
K EaFA-L08-1313-T05-B 1 2.26E+04
K EaFA-L08-1313-T06-B 1 2.41E+04
K EaFA-L08-1313-T07-B 1 2.50E+04
K EaFA-L08-1313-T08-B 1 1.94E+04
K EaFA-L08-1313-T09-B 1 1.66E+04
K EaFA-L08-1313-T01-C 1 5.15E+04
K EaFA-L08-1313-T02-C 1 3.16E+04
K EaFA-L08-1313-T03-C 1 2.59E+04
K EaFA-L08-1313-T04-C 1 6.02E+03
K EaFA-L08-1313-T05-C 1 2.48E+04
K EaFA-L08-1313-T06-C 1 2.38E+04
K EaFA-L08-1313-T07-C 1 2.52E+04
K EaFA-L08-1313-T08-C 1 1.88E+04
K EaFA-L08-1313-T09-C 1 8.45E+03
K EaFA-L08-1313-B01-A 1 3.98E+01
K EaFA-L08-1313-B02-A 1 3.81E+01
K EaFA-L08-1313-B03-A 1 1.83E+02
K EaFA-L08-1313-B01-B 1 3.86E+01
K EaFA-L08-1313-B02-B 1 3.89E+01
K EaFA-L08-1313-B03-B 1 5.91 E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.16E+04 9.3E-01 1 .6E+00 5.1E+00
3.37E+04 2.8E-01 1 .6E+00 5.1E+00
2.68E+04 1.2E+00 1 .6E+00 5.1E+00 1000 100
2.54E+04 1.0E+00 1 .6E+00 5.1E+00
2.47E+04 6.4E-01 1 .6E+00 5.1E+00
2.42E+04 1.2E+00 1 .6E+00 5.1E+00
2.24E+04 1.4E+01 1 .6E+00 5.1E+00
1.94E+04 2.2E-01 1 .6E+00 5.1E+00
1.99E+04 1.8E+01 1 .6E+00 5.1E+00
4.89E+04 9.0E+00 1 .6E+00 5.1E+00
3.05E+04 3.9E+00 1 .6E+00 5.1E+00
2.47E+04 5.5E+00 1 .6E+00 5.1E+00 1000 100
2.48E+04 1.4E+00 1 .6E+00 5.1E+00
2.26E+04 9.1E+00 1 .6E+00 5.1E+00
2.41E+04 9.5E-01 1 .6E+00 5.1E+00
2.50E+04 2.7E+00 1 .6E+00 5.1E+00
1.94E+04 6.0E-01 1 .6E+00 5.1E+00
1.66E+04 4.5E+01 1 .6E+00 5.1E+00
5.15E+04 3.6E-01 1 .6E+00 5.1E+00
3.16E+04 1.1E+00 1.6E+00 5.1E+00
2.59E+04 3.5E-01 1 .6E+00 5.1E+00 1000 100
6.02E+03 1.6E+02 1.6E+00 5.1E+00
2.48E+04 5.9E-01 1.6E+00 5.1E+00
2.38E+04 3.7E-01 1.6E+00 5.1E+00
2.52E+04 6.0E-01 1.6E+00 5.1E+00
1.88E+04 3.3E+00 1.6E+00 5.1E+00
8.45E+03 1.3E+02 1.6E+00 5.1E+00
3.98E+01 4.4E+00 1.6E+00 5.1E+00
3.81 E+01 8.1E+00 1.6E+00 5.1E+00
1.83E+02 1.2E+01 1.6E+00 5.1E+00
3.86E+01 1.0E+01 1.6E+00 5.1E+00
3.89E+01 8.1E+00 1.6E+00 5.1E+00
5.91 E+01 7.8E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
2.76E+04 85% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
2.55E+04 82% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
2.67E+04 82% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-197
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Se Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Se EaFA-L08-1313-T01-A 1 7.52E+03
Se EaFA-L08-1313-T02-A 1 6.06E+03
Se EaFA-L08-1313-T03-A 1 5.48E+03
Se EaFA-L08-1313-T04-A 1 4.05E+03
Se EaFA-L08-1313-T05-A 1 2.39E+03
Se EaFA-L08-1313-T06-A 1 1.49E+03
Se EaFA-L08-1313-T07-A 1 4.28E+02
Se EaFA-L08-1313-T08-A 1 2.21E+02
Se EaFA-L08-1313-T09-A 1 7.61 E+02
Se EaFA-L08-1313-T01-B 1 7.21E+03
Se EaFA-L08-1313-T02-B 1 5.69E+03
Se EaFA-L08-1313-T03-B 1 5.06E+03
Se EaFA-L08-1313-T04-B 1 3.94E+03
Se EaFA-L08-1313-T05-B 1 2.22E+03
Se EaFA-L08-1313-T06-B 1 1.42E+03
Se EaFA-L08-1313-T07-B 1 5.20E+02
Se EaFA-L08-1313-T08-B 1 1.94E+02
Se EaFA-L08-1313-T09-B 1 4.88E+02
Se EaFA-L08-1313-T01-C 1 7.59E+03
Se EaFA-L08-1313-T02-C 1 5.88E+03
Se EaFA-L08-1313-T03-C 1 5.33E+03
Se EaFA-L08-1313-T04-C 1 3.83E+03
Se EaFA-L08-1313-T05-C 1 2.47E+03
Se EaFA-L08-1313-T06-C 1 1.61E+03
Se EaFA-L08-1313-T07-C 1 5.34E+02
Se EaFA-L08-1313-T08-C 1 1.99E+02
Se EaFA-L08-1313-T09-C 1 4.02E+02
Se EaFA-L08-1313-B01-A 1 6.34E+01
Se EaFA-L08-1313-B02-A 1 4.31E+01 E
Se EaFA-L08-1313-B03-A 1 1.13E+02
Se EaFA-L08-1313-B01-B 1 7.95E+01
Se EaFA-L08-1313-B02-B 1 5.51 E+01
Se EaFA-L08-1313-B03-B 1 7.05E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.52E+03 1.7E+00 1 .5E+01 4.8E+01
6.06E+03 6.1E-01 1 .5E+01 4.8E+01
5.48E+03 1.2E+00 1 .5E+01 4.8E+01 10 325
4.05E+03 1.7E+00 1 .5E+01 4.8E+01
2.39E+03 2.5E+00 1.5E+01 4.8E+01
1.49E+03 2.6E+00 1.5E+01 4.8E+01
4.28E+02 1.4E+01 1.5E+01 4.8E+01
2.21 E+02 8.7E+00 1.5E+01 4.8E+01
7.61 E+02 1.1 E+01 1.5E+01 4.8E+01
7.21 E+03 8.4E+00 1.5E+01 4.8E+01
5.69E+03 4.3E+00 1.5E+01 4.8E+01
5.06E+03 3.7E+00 1.5E+01 4.8E+01 10 325
3.94E+03 1.2E+00 1.5E+01 4.8E+01
2.22E+03 8.3E+00 1.5E+01 4.8E+01
1.42E+03 1.1E+00 1.5E+01 4.8E+01
5.20E+02 1.6E+00 1.5E+01 4.8E+01
1.94E+02 1.1E+01 1.5E+01 4.8E+01
4.88E+02 4.0E+01 1.5E+01 4.8E+01
7.59E+03 5.0E-01 1.5E+01 4.8E+01
5.88E+03 2.0E+00 1.5E+01 4.8E+01
5.33E+03 4.0E-01 1.5E+01 4.8E+01 10 325
3.83E+03 1.5E+02 1.5E+01 4.8E+01
2.47E+03 5.7E-01 1.5E+01 4.8E+01
1.61 E+03 1.5E+00 1.5E+01 4.8E+01
5.34E+02 1.9E+00 1.5E+01 4.8E+01
1.99E+02 7.3E+00 1.5E+01 4.8E+01
4.02E+02 1.0E+02 1.5E+01 4.8E+01
6.34E+01 5.1 E+01 1.5E+01 4.8E+01
4.31E+01 2.7E+01 1.5E+01 4.8E+01
1.13E+02 2.7E+01 1.5E+01 4.8E+01
7.95E+01 4.7E+01 1.5E+01 4.8E+01
5.51 E+01 6.0E+01 1.5E+01 4.8E+01
7.05E+01 6.0E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:40AM EPA Interlab LOS 1313-1316 EaFA
8.28E+03 86% VUICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:43AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:46AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:48AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
7.97E+03 90% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1 :41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
8.26E+03 90% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1 :44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-198
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Si Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Si EaFA-L08-1313-T01-A 1 1.79E+04
Si EaFA-L08-1313-T02-A 1 6.02E+03
Si EaFA-L08-1313-T03-A 1 2.05E+03
Si EaFA-L08-1313-T04-A 1 5.18E+02
Si EaFA-L08-1313-T05-A 1 1.20E+03
Si EaFA-L08-1313-T06-A 1 3.29E+03
Si EaFA-L08-1313-T07-A 1 7.28E+03
Si EaFA-L08-1313-T08-A 1 1.52E+04
Si EaFA-L08-1313-T09-A 1 6.95E+04
Si EaFA-L08-1313-T01-B 1 1.74E+04
Si EaFA-L08-1313-T02-B 1 4.71E+03
Si EaFA-L08-1313-T03-B 1 1.30E+03
Si EaFA-L08-1313-T04-B 1 5.25E+02
Si EaFA-L08-1313-T05-B 1 1.19E+03
Si EaFA-L08-1313-T06-B 1 3.52E+03
Si EaFA-L08-1313-T07-B 1 7.90E+03
Si EaFA-L08-1313-T08-B 1 1.56E+04
Si EaFA-L08-1313-T09-B 1 6.27E+04
Si EaFA-L08-1313-T01-C 1 1.76E+04
Si EaFA-L08-1313-T02-C 1 5.27E+03
Si EaFA-L08-1313-T03-C 1 1.38E+03
Si EaFA-L08-1313-T04-C 1 1.27E+02
Si EaFA-L08-1313-T05-C 1 1.41E+03
Si EaFA-L08-1313-T06-C 1 3.41E+03
Si EaFA-L08-1313-T07-C 1 8.07E+03
Si EaFA-L08-1313-T08-C 1 1.53E+04
Si EaFA-L08-1313-T09-C 1 2.99E+04
Si EaFA-L08-1313-B01-A 1 5.50E-01 U1/2
Si EaFA-L08-1313-B02-A 1 3.20E+01
Si EaFA-L08-1313-B03-A 1 1.57E+02
Si EaFA-L08-1313-B01-B 1 5.50E-01 U1/2
Si EaFA-L08-1313-B02-B 1 2.47E+01
Si EaFA-L08-1313-B03-B 1 2.27E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.79E+04 8.5E-01 1.1E+00 3.5E+00
6.02E+03 1.6E-01 1.1E+00 3.5E+00
2.05E+03 1.3E+00 1.1E+00 3.5E+00 1000 100
5.18E+02 2.0E-01 1.1E+00 3.5E+00
1.20E+03 7.5E-01 1.1E+00 3.5E+00
3.29E+03 5.4E-01 1.1E+00 3.5E+00
7.28E+03 1.3E+01 1.1E+00 3.5E+00
1.52E+04 2.6E-01 1.1E+00 3.5E+00
6.95E+04 4.7E+00 1.1E+00 3.5E+00
1.74E+04 8.3E+00 1.1E+00 3.5E+00
4.71E+03 3.7E+00 1.1E+00 3.5E+00
1.30E+03 5.0E+00 1.1E+00 3.5E+00 1000 100
5.25E+02 1.0E+00 1.1E+00 3.5E+00
1.19E+03 9.8E+00 1.1E+00 3.5E+00
3.52E+03 7.2E-01 1.1E+00 3.5E+00
7.90E+03 2.9E+00 1.1E+00 3.5E+00
1.56E+04 1.6E-01 1.1E+00 3.5E+00
6.27E+04 1.8E+01 1.1E+00 3.5E+00
1.76E+04 2.1E-01 1.1E+00 3.5E+00
5.27E+03 1.3E+00 1.1E+00 3.5E+00
1.38E+03 4.5E-01 1.1E+00 3.5E+00 1000 100
1.27E+02 1.7E+02 1.1E+00 3.5E+00
1.41E+03 6.8E-01 1.1E+00 3.5E+00
3.41 E+03 7.6E-01 1.1E+00 3.5E+00
8.07E+03 7.9E-01 1.1E+00 3.5E+00
1.53E+04 2.9E+00 1.1E+00 3.5E+00
2.99E+04 1.1E+02 1.1E+00 3.5E+00
5.50E-01 1.7E+01 1.1E+00 3.5E+00
3.20E+01 1.3E+01 1.1E+00 3.5E+00
1.57E+02 1.6E+01 1.1E+00 3.5E+00
5.50E-01 4.3E+01 1.1E+00 3.5E+00
2.47E+01 1.9E+01 1.1E+00 3.5E+00
2.27E+03 1.2E+02 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
2.89E+03 84% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
2.25E+03 95% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:41 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
2.29E+03 91% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-199
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Na Sample Dilution Cone. Qualifier Review
ug/L
Na EaFA-L08-1313-T01-A 1 3.04E+05
Na EaFA-L08-1313-T02-A 1 1.33E+05
Na EaFA-L08-1313-T03-A 1 5.49E+04
Na EaFA-L08-1313-T04-A 1 2.98E+04
Na EaFA-L08-1313-T05-A 1 1.43E+04
Na EaFA-L08-1313-T06-A 1 4.94E+03
Na EaFA-L08-1313-T07-A 1 4.53E+03
Na EaFA-L08-1313-T08-A 1 3.77E+03
Na EaFA-L08-1313-T09-A 1 2.46E+03
Na EaFA-L08-1313-T01-B 1 2.82E+05
Na EaFA-L08-1313-T02-B 1 1.18E+05
Na EaFA-L08-1313-T03-B 1 4.79E+04
Na EaFA-L08-1313-T04-B 1 2.85E+04
Na EaFA-L08-1313-T05-B 1 1.30E+04
Na EaFA-L08-1313-T06-B 1 4.89E+03
Na EaFA-L08-1313-T07-B 1 4.92E+03
Na EaFA-L08-1313-T08-B 1 3.77E+03
Na EaFA-L08-1313-T09-B 1 2.04E+03
Na EaFA-L08-1313-T01-C 1 2.93E+05
Na EaFA-L08-1313-T02-C 1 1.17E+05
Na EaFA-L08-1313-T03-C 1 4.91 E+04
Na EaFA-L08-1313-T04-C 1 7.19E+03
Na EaFA-L08-1313-T05-C 1 1.42E+04
Na EaFA-L08-1313-T06-C 1 4.85E+03
Na EaFA-L08-1313-T07-C 1 5.00E+03
Na EaFA-L08-1313-T08-C 1 3.60E+03
Na EaFA-L08-1313-T09-C 1 1.04E+03
Na EaFA-L08-1313-B01-A 1 2.25E+01
Na EaFA-L08-1313-B02-A 1 1.95E+01
Na EaFA-L08-1313-B03-A 1 3.09E+05
Na EaFA-L08-1313-B01-B 1 1.97E+01
Na EaFA-L08-1313-B02-B 1 3.10E+01
Na EaFA-L08-1313-B03-B 1 1.17E+05
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.04E+05 1.4E+00 2.5E+00 8.0E+00
1.33E+05 3.7E-01 2.5E+00 8.0E+00
5.49E+04 1.3E+00 2.5E+00 8.0E+00 1000 100
2.98E+04 5.9E-01 2.5E+00 8.0E+00
1.43E+04 5.7E-01 2.5E+00 8.0E+00
4.94E+03 1.3E+00 2.5E+00 8.0E+00
4.53E+03 1.3E+01 2.5E+00 8.0E+00
3.77E+03 6.5E-01 2.5E+00 8.0E+00
2.46E+03 1.8E+01 2.5E+00 8.0E+00
2.82E+05 5.6E+00 2.5E+00 8.0E+00
1.18E+05 3.3E+00 2.5E+00 8.0E+00
4.79E+04 5.5E+00 2.5E+00 8.0E+00 1000 100
2.85E+04 1.7E+00 2.5E+00 8.0E+00
1.30E+04 9.6E+00 2.5E+00 8.0E+00
4.89E+03 1.1E+00 2.5E+00 8.0E+00
4.92E+03 2.6E+00 2.5E+00 8.0E+00
3.77E+03 3.1E-01 2.5E+00 8.0E+00
2.04E+03 4.8E+01 2.5E+00 8.0E+00
2.93E+05 6.9E-01 2.5E+00 8.0E+00
1.17E+05 9.1E-01 2.5E+00 8.0E+00
4.91E+04 3.7E-01 2.5E+00 8.0E+00 1000 100
7.19E+03 1.6E+02 2.5E+00 8.0E+00
1.42E+04 2.6E-01 2.5E+00 8.0E+00
4.85E+03 8.8E-01 2.5E+00 8.0E+00
5.00E+03 1.2E+00 2.5E+00 8.0E+00
3.60E+03 3.1E+00 2.5E+00 8.0E+00
1.04E+03 1.3E+02 2.5E+00 8.0E+00
2.25E+01 4.2E-01 2.5E+00 8.0E+00
1.95E+01 1.0E+01 2.5E+00 8.0E+00
3.09E+05 1.5E-01 2.5E+00 8.0E+00
1.97E+01 7.9E+00 2.5E+00 8.0E+00
3.10E+01 1.1E+01 2.5E+00 8.0E+00
1.17E+05 1.1E+02 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
5.58E+04 95% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
4.89E+04 96% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
5.00E+04 92% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-200
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-L08-1313-T01-A 1 1.45E+03
EaFA-L08-1313-T02-A 1 1.63E+03
EaFA-L08-1313-T03-A 1 1.88E+03
EaFA-L08-1313-T04-A 1 1.83E+03
EaFA-L08-1313-T05-A 1 1.97E+03
EaFA-L08-1313-T06-A 1 2.10E+03
EaFA-L08-1313-T07-A 1 2.27E+03
EaFA-L08-1313-T08-A 1 2.68E+03
EaFA-L08-1313-T09-A 1 5.13E+03
EaFA-L08-1313-T01-B 1 1.38E+03
EaFA-L08-1313-T02-B 1 1.58E+03
EaFA-L08-1313-T03-B 1 1.79E+03
EaFA-L08-1313-T04-B 1 1.81E+03
EaFA-L08-1313-T05-B 1 1.84E+03
EaFA-L08-1313-T06-B 1 2.17E+03
EaFA-L08-1313-T07-B 1 2.56E+03
EaFA-L08-1313-T08-B 1 2.72E+03
EaFA-L08-1313-T09-B 1 4.23E+03
EaFA-L08-1313-T01-C 1 1.50E+03
EaFA-L08-1313-T02-C 1 1.62E+03
EaFA-L08-1313-T03-C 1 1.88E+03
EaFA-L08-1313-T04-C 1 4.84E+02
EaFA-L08-1313-T05-C 1 2.02E+03
EaFA-L08-1313-T06-C 1 2.15E+03
EaFA-L08-1313-T07-C 1 2.69E+03
EaFA-L08-1313-T08-C 1 2.70E+03
EaFA-L08-1313-T09-C 1 2.66E+03
EaFA-L08-1313-B01-A 1 5.00E-01 U1/2
EaFA-L08-1313-B02-A 1 5.00E-01 U1/2
EaFA-L08-1313-B03-A 1 5.00E-01 U1/2
EaFA-L08-1313-B01-B 1 5.00E-01 U1/2
EaFA-L08-1313-B02-B 1 5.00E-01 U1/2
EaFA-L08-1313-B03-B 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.45E+03 7.8E-01 1 .OE+00 3.2E+00
1.63E+03 5.0E-01 1 .OE+00 3.2E+00
1.88E+03 5.1E-01 1 .OE+00 3.2E+00 1000 100
1.83E+03 2.4E+00 1 .OE+00 3.2E+00
1.97E+03 3.8E-01 1 .OE+00 3.2E+00
2.10E+03 5.9E-01 1 .OE+00 3.2E+00
2.27E+03 1.1E+01 1 .OE+00 3.2E+00
2.68E+03 1.4E+00 1 .OE+00 3.2E+00
5.13E+03 5.6E+00 1 .OE+00 3.2E+00
1.38E+03 7.5E+00 1 .OE+00 3.2E+00
1.58E+03 4.9E+00 1 .OE+00 3.2E+00
1.79E+03 3.1E+00 1 .OE+00 3.2E+00 1000 100
1.81E+03 8.9E-01 1 .OE+00 3.2E+00
1.84E+03 8.2E+00 1 .OE+00 3.2E+00
2.17E+03 6.0E-01 1 .OE+00 3.2E+00
2.56E+03 4.0E+00 1 .OE+00 3.2E+00
2.72E+03 2.1E-01 1 .OE+00 3.2E+00
4.23E+03 2.8E+01 1 .OE+00 3.2E+00
1.50E+03 9.7E-02 1 .OE+00 3.2E+00
1.62E+03 1.4E+00 1 .OE+00 3.2E+00
1.88E+03 3.7E-01 1 .OE+00 3.2E+00 1000 100
4.84E+02 1.5E+02 1. OE+00 3.2E+00
2.02E+03 8.2E-01 1. OE+00 3.2E+00
2.15E+03 7.9E-01 1. OE+00 3.2E+00
2.69E+03 3.4E-01 1. OE+00 3.2E+00
2.70E+03 3.5E-01 1. OE+00 3.2E+00
2.66E+03 8.3E+01 1. OE+00 3.2E+00
5.00E-01 1.2E+01 1. OE+00 3.2E+00
5.00E-01 6.4E+00 1. OE+00 3.2E+00
5.00E-01 4.8E+01 1. OE+00 3.2E+00
5.00E-01 3.4E+01 1. OE+00 3.2E+00
5.00E-01 1.9E+01 1. OE+00 3.2E+00
5.00E-01 4.3E+01 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
2.77E+03 89% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
2.66E+03 87% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
2.72E+03 84% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-201
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
S Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
S EaFA-L08-1313-T01-A 1 1.74E+05
S EaFA-L08-1313-T02-A 1 1.56E+05
S EaFA-L08-1313-T03-A 1 1.52E+05
S EaFA-L08-1313-T04-A 1 1.54E+05
S EaFA-L08-1313-T05-A 1 1.53E+05
S EaFA-L08-1313-T06-A 1 1.48E+05
S EaFA-L08-1313-T07-A 1 1.26E+05
S EaFA-L08-1313-T08-A 1 9.77E+04
S EaFA-L08-1313-T09-A 1 4.58E+04
S EaFA-L08-1313-T01-B 1 1.69E+05
S EaFA-L08-1313-T02-B 1 1.46E+05
S EaFA-L08-1313-T03-B 1 1.44E+05
S EaFA-L08-1313-T04-B 1 1.52E+05
S EaFA-L08-1313-T05-B 1 1.42E+05
S EaFA-L08-1313-T06-B 1 1.50E+05
S EaFA-L08-1313-T07-B 1 1.41E+05
S EaFA-L08-1313-T08-B 1 9.98E+04
S EaFA-L08-1313-T09-B 1 3.96E+04
S EaFA-L08-1313-T01-C 1 1.76E+05
S EaFA-L08-1313-T02-C 1 1.51E+05
S EaFA-L08-1313-T03-C 1 1.51E+05
S EaFA-L08-1313-T04-C 1 3.93E+04
S EaFA-L08-1313-T05-C 1 1.54E+05
S EaFA-L08-1313-T06-C 1 1.49E+05
S EaFA-L08-1313-T07-C 1 1.44E+05
S EaFA-L08-1313-T08-C 1 9.54E+04
S EaFA-L08-1313-T09-C 1 1.94E+04
S EaFA-L08-1313-B01-A 1 1.32E+01 E
S EaFA-L08-1313-B02-A 1 3.40E+00 U1/2
S EaFA-L08-1313-B03-A 1 1.33E+02
S EaFA-L08-1313-B01-B 1 1.38E+01 E
S EaFA-L08-1313-B02-B 1 1.68E+01 E
S EaFA-L08-1313-B03-B 1 1.15E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.74E+05 9.5E-01 6.8E+00 2.2E+01
1.56E+05 1.9E-01 6.8E+00 2.2E+01
1.52E+05 1.4E+00 6.8E+00 2.2E+01 1000 100
1.54E+05 6.5E-01 6.8E+00 2.2E+01
1.53E+05 2.7E-01 6.8E+00 2.2E+01
1.48E+05 5.8E-01 6.8E+00 2.2E+01
1.26E+05 1.4E+01 6.8E+00 2.2E+01
9.77E+04 4.9E-01 6.8E+00 2.2E+01
4.58E+04 1.0E+01 6.8E+00 2.2E+01
1.69E+05 8.5E+00 6.8E+00 2.2E+01
1.46E+05 3.4E+00 6.8E+00 2.2E+01
1.44E+05 4.4E+00 6.8E+00 2.2E+01 1000 100
1.52E+05 2.8E-01 6.8E+00 2.2E+01
1.42E+05 9.2E+00 6.8E+00 2.2E+01
1.50E+05 2.7E-01 6.8E+00 2.2E+01
1.41E+05 2.9E+00 6.8E+00 2.2E+01
9.98E+04 4.1E-01 6.8E+00 2.2E+01
3.96E+04 4.1E+01 6.8E+00 2.2E+01
1.76E+05 3.5E-01 6.8E+00 2.2E+01
1.51E+05 1.7E+00 6.8E+00 2.2E+01
1.51E+05 2.9E-01 6.8E+00 2.2E+01 1000 100
3.93E+04 1.5E+02 6.8E+00 2.2E+01
1.54E+05 3.9E-01 6.8E+00 2.2E+01
1.49E+05 3.9E-01 6.8E+00 2.2E+01
1.44E+05 8.4E-01 6.8E+00 2.2E+01
9.54E+04 2.2E+00 6.8E+00 2.2E+01
1.94E+04 1.3E+02 6.8E+00 2.2E+01
1.32E+01 3.8E+01 6.8E+00 2.2E+01
3.40E+00 2.0E+02 6.8E+00 2.2E+01
1.33E+02 1.6E+01 6.8E+00 2.2E+01
1.38E+01 7.6E+00 6.8E+00 2.2E+01
1.68E+01 5.4E+01 6.8E+00 2.2E+01
1.15E+01 5.0E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
1.53E+05 89%VUICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
1.45E+05 86% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
1.52E+05 87% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-202
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl EaFA-L08-1313-T01-A 1 9.00E+00 E
Tl EaFA-L08-1313-T02-A 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T03-A 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T04-A 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T05-A 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T06-A 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T07-A 1 3.19E+01
Tl EaFA-L08-1313-T08-A 1 6.44E+01
Tl EaFA-L08-1313-T09-A 1 8.17E+01
Tl EaFA-L08-1313-T01-B 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T02-B 1 6.57E+00 E
Tl EaFA-L08-1313-T03-B 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T04-B 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T05-B 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T06-B 1 7.97E+00 E
Tl EaFA-L08-1313-T07-B 1 3.68E+01
Tl EaFA-L08-1313-T08-B 1 5.80E+01
Tl EaFA-L08-1313-T09-B 1 5.56E+01
Tl EaFA-L08-1313-T01-C 1 1.11E+01 E
Tl EaFA-L08-1313-T02-C 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T03-C 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T04-C 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T05-C 1 2.30E+00 U1/2
Tl EaFA-L08-1313-T06-C 1 7.04E+00 E
Tl EaFA-L08-1313-T07-C 1 3.73E+01
Tl EaFA-L08-1313-T08-C 1 7.17E+01
Tl EaFA-L08-1313-T09-C 1 1.59E+01
Tl EaFA-L08-1313-B01-A 1 2.30E+00 U1/2
Tl EaFA-L08-1313-B02-A 1 2.30E+00 U1/2
Tl EaFA-L08-1313-B03-A 1 2.30E+00 U1/2
Tl EaFA-L08-1313-B01-B 1 2.30E+00 U1/2
Tl EaFA-L08-1313-B02-B 1 2.30E+00 U1/2
Tl EaFA-L08-1313-B03-B 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E+00 2.7E+01 4.6E+00 1.5E+01
2.30E+00 1.0E+02 4.6E+00 1.5E+01
2.30E+00 2.4E+03 4.6E+00 1.5E+01 10 325
2.30E+00 4.3E+02 4.6E+00 1.5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 9.8E+02 4.6E+00 1.5E+01
3.19E+01 5.1E+01 4.6E+00 1.5E+01
6.44E+01 1.3E+01 4.6E+00 1.5E+01
8.17E+01 2.0E+01 4.6E+00 1.5E+01
2.30E+00 3.2E+03 4.6E+00 1.5E+01
6.57E+00 1.0E+02 4.6E+00 1.5E+01
2.30E+00 6.6E+01 4.6E+00 1.5E+01 10 325
2.30E+00 1.3E+02 4.6E+00 1.5E+01
2.30E+00 2.2E+03 4.6E+00 1.5E+01
7.97E+00 1.7E+02 4.6E+00 1.5E+01
3.68E+01 2.2E+01 4.6E+00 1.5E+01
5.80E+01 6.5E+00 4.6E+00 1.5E+01
5.56E+01 6.5E+01 4.6E+00 1.5E+01
1.11E+01 7.8E+01 4.6E+00 1.5E+01
2.30E+00 1.3E+02 4.6E+00 1.5E+01
2.30E+00 2.6E+02 4.6E+00 1.5E+01 10 325
2.30E+00 9.6E+01 4.6E+00 1.5E+01
2.30E+00 1.4E+02 4.6E+00 1.5E+01
7.04E+00 2.4E+02 4.6E+00 1.5E+01
3.73E+01 5.2E+01 4.6E+00 1.5E+01
7.17E+01 1.1E+01 4.6E+00 1.5E+01
1.59E+01 3.2E+02 4.6E+00 1.5E+01
2.30E+00 3.9E+02 4.6E+00 1.5E+01
2.30E+00 7.5E+00 4.6E+00 1.5E+01
2.30E+00 4.5E+01 4.6E+00 1.5E+01
2.30E+00 8.4E+01 4.6E+00 1.5E+01
2.30E+00 4.3E+01 4.6E+00 1.5E+01
2.30E+00 2.0E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:40AM EPA Interlab LOS 1313-1316 EaFA
3.12E+03 96% VUICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:43AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:46AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.09E+03 95% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1 :41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.13E+03 96% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-203
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ti Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Ti EaFA-L08-1313-T01-A 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T02-A 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T03-A 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T04-A 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T05-A 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T06-A 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T07-A 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T08-A 1 8.47E+00
Ti EaFA-L08-1313-T09-A 1 5.17E+03
Ti EaFA-L08-1313-T01-B 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T02-B 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T03-B 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T04-B 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T05-B 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T06-B 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T07-B 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T08-B 1 8.08E+00
Ti EaFA-L08-1313-T09-B 1 2.65E+03
Ti EaFA-L08-1313-T01-C 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T02-C 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T03-C 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T04-C 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T05-C 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T06-C 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T07-C 1 1.00E+OOU1/2
Ti EaFA-L08-1313-T08-C 1 8.97E+00
Ti EaFA-L08-1313-T09-C 1 8.10E+02
Ti EaFA-L08-1313-B01-A 1 1.00E+OOU1/2
Ti EaFA-L08-1313-B02-A 1 1.00E+OOU1/2
Ti EaFA-L08-1313-B03-A 1 5.79E+00 E
Ti EaFA-L08-1313-B01-B 1 1.00E+OOU1/2
Ti EaFA-L08-1313-B02-B 1 1.00E+OOU1/2
Ti EaFA-L08-1313-B03-B 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.2E+01 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00
1.00E+00 9.0E+01 2.0E+00 6.4E+00 10 325
1.00E+00 9.2E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+03 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
8.47E+00 6.4E+00 2.0E+00 6.4E+00
5.17E+03 3.4E+00 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 8.3E+01 2.0E+00 6.4E+00
1.00E+00 3.7E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.1E+03 2.0E+00 6.4E+00
1.00E+00 1.1E+03 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00
8.08E+00 3.3E+00 2.0E+00 6.4E+00
2.65E+03 2.4E+01 2.0E+00 6.4E+00
1.00E+00 7.2E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 2.0E+03 2.0E+00 6.4E+00 10 325
1.00E+00 8.2E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+02 2.0E+00 6.4E+00
1.00E+00 6.6E+03 2.0E+00 6.4E+00
1.00E+00 1.4E+03 2.0E+00 6.4E+00
8.97E+00 9.1E+00 2.0E+00 6.4E+00
8.10E+02 1.1E+02 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
5.79E+00 5.0E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:40AM EPA Interlab LOS 1313-1316 EaFA
3.16E+03 97% VUICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:43AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:46AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:50AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.09E+03 95% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1 :41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.15E+03 97% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1 :44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-204
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
V Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
V EaFA-L08-1313-T01-A 1 5.51 E+03
V EaFA-L08-1313-T02-A 1 3.14E+03
V EaFA-L08-1313-T03-A 1 3.29E+03
V EaFA-L08-1313-T04-A 1 9.89E+02
V EaFA-L08-1313-T05-A 1 4.95E+02
V EaFA-L08-1313-T06-A 1 3.65E+02
V EaFA-L08-1313-T07-A 1 1.20E+02
V EaFA-L08-1313-T08-A 1 9.88E+01
V EaFA-L08-1313-T09-A 1 5.19E+03
V EaFA-L08-1313-T01-B 1 5.31 E+03
V EaFA-L08-1313-T02-B 1 2.67E+03
V EaFA-L08-1313-T03-B 1 2.78E+03
V EaFA-L08-1313-T04-B 1 1.06E+03
V EaFA-L08-1313-T05-B 1 4.76E+02
V EaFA-L08-1313-T06-B 1 3.55E+02
V EaFA-L08-1313-T07-B 1 1.54E+02
V EaFA-L08-1313-T08-B 1 9.41 E+01
V EaFA-L08-1313-T09-B 1 4.45E+03
V EaFA-L08-1313-T01-C 1 5.49E+03
V EaFA-L08-1313-T02-C 1 2.91E+03
V EaFA-L08-1313-T03-C 1 2.92E+03
V EaFA-L08-1313-T04-C 1 2.73E+02
V EaFA-L08-1313-T05-C 1 5.60E+02
V EaFA-L08-1313-T06-C 1 3.87E+02
V EaFA-L08-1313-T07-C 1 1.58E+02
V EaFA-L08-1313-T08-C 1 9.99E+01
V EaFA-L08-1313-T09-C 1 2.39E+03
V EaFA-L08-1313-B01-A 1 7.50E-01 U1/2
V EaFA-L08-1313-B02-A 1 7.50E-01 U1/2
V EaFA-L08-1313-B03-A 1 3.82E+00 E
V EaFA-L08-1313-B01-B 1 7.50E-01 U1/2
V EaFA-L08-1313-B02-B 1 7.50E-01 U1/2
V EaFA-L08-1313-B03-B 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.51 E+03 5.7E-01 1 .5E+00 4.8E+00
3.14E+03 8.8E-01 1 .5E+00 4.8E+00
3.29E+03 2.7E-01 1 .5E+00 4.8E+00 10 325
9.89E+02 2.3E+00 1 .5E+00 4.8E+00
4.95E+02 1.1E+00 1 .5E+00 4.8E+00
3.65E+02 1.6E+00 1 .5E+00 4.8E+00
1.20E+02 1.3E+01 1.5E+00 4.8E+00
9.88E+01 1.0E+00 1 .5E+00 4.8E+00
5.19E+03 1.2E+01 1 .5E+00 4.8E+00
5.31 E+03 6.9E+00 1 .5E+00 4.8E+00
2.67E+03 4.8E+00 1 .5E+00 4.8E+00
2.78E+03 2.9E+00 1 .5E+00 4.8E+00 10 325
1.06E+03 2.4E+00 1 .5E+00 4.8E+00
4.76E+02 8.0E+00 1 .5E+00 4.8E+00
3.55E+02 2.5E-01 1 .5E+00 4.8E+00
1.54E+02 3.3E+00 1 .5E+00 4.8E+00
9.41 E+01 1.5E+00 1.5E+00 4.8E+00
4.45E+03 3.9E+01 1 .5E+00 4.8E+00
5.49E+03 9.7E-01 1 .5E+00 4.8E+00
2. 91 E+03 1.5E+00 1 .5E+00 4.8E+00
2.92E+03 2.2E-01 1 .5E+00 4.8E+00 10 325
2.73E+02 1.6E+02 1.5E+00 4.8E+00
5.60E+02 2.3E+00 1.5E+00 4.8E+00
3.87E+02 6.2E-01 1.5E+00 4.8E+00
1.58E+02 8.4E-01 1.5E+00 4.8E+00
9.99E+01 1.3E+00 1.5E+00 4.8E+00
2.39E+03 1.0E+02 1.5E+00 4.8E+00
7.50E-01 1.1E+02 1.5E+00 4.8E+00
7.50E-01 6.2E+02 1.5E+00 4.8E+00
3.82E+00 3.0E+01 1.5E+00 4.8E+00
7.50E-01 1.7E+03 1.5E+00 4.8E+00
7.50E-01 2.4E+02 1.5E+00 4.8E+00
7.50E-01 1.8E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
6.20E+03 90% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
5.76E+03 92% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
5.90E+03 92% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-205
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Zn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Zn EaFA-L08-1313-T01-A 1 1.03E+02
Zn EaFA-L08-1313-T02-A 1 2.45E+01
Zn EaFA-L08-1313-T03-A 1 1.53E+01
Zn EaFA-L08-1313-T04-A 1 1.09E+01
Zn EaFA-L08-1313-T05-A 1 1.53E+01
Zn EaFA-L08-1313-T06-A 1 3.21E+01
Zn EaFA-L08-1313-T07-A 1 9.84E+02
Zn EaFA-L08-1313-T08-A 1 1.13E+03
Zn EaFA-L08-1313-T09-A 1 1.60E+03
Zn EaFA-L08-1313-T01-B 1 7.26E+01
Zn EaFA-L08-1313-T02-B 1 2.00E+01
Zn EaFA-L08-1313-T03-B 1 1.39E+01
Zn EaFA-L08-1313-T04-B 1 1.24E+01
Zn EaFA-L08-1313-T05-B 1 1.47E+01
Zn EaFA-L08-1313-T06-B 1 2.22E+01
Zn EaFA-L08-1313-T07-B 1 9.57E+02
Zn EaFA-L08-1313-T08-B 1 1.14E+03
Zn EaFA-L08-1313-T09-B 1 1.72E+03
Zn EaFA-L08-1313-T01-C 1 1.17E+02
Zn EaFA-L08-1313-T02-C 1 2.17E+01
Zn EaFA-L08-1313-T03-C 1 1.76E+01
Zn EaFA-L08-1313-T04-C 1 3.05E+00 E
Zn EaFA-L08-1313-T05-C 1 1.85E+01
Zn EaFA-L08-1313-T06-C 1 3.18E+01
Zn EaFA-L08-1313-T07-C 1 9.74E+02
Zn EaFA-L08-1313-T08-C 1 1.12E+03
Zn EaFA-L08-1313-T09-C 1 7.76E+02
Zn EaFA-L08-1313-B01-A 1 9.59E+00
Zn EaFA-L08-1313-B02-A 1 5.07E+00
Zn EaFA-L08-1313-B03-A 1 9.54E+00
Zn EaFA-L08-1313-B01-B 1 7.95E+00
Zn EaFA-L08-1313-B02-B 1 1.36E+01
Zn EaFA-L08-1313-B03-B 1 5.22E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.03E+02 6.2E-01 1 .OE+00 3.2E+00
2.45E+01 3.8E+00 1 .OE+00 3.2E+00
1.53E+01 4.0E+00 1 .OE+00 3.2E+00 10 325
1.09E+01 1.0E+01 1. OE+00 3.2E+00
1.53E+01 2.1E+00 1. OE+00 3.2E+00
3.21 E+01 6.6E+00 1 .OE+00 3.2E+00
9.84E+02 1.1 E+01 1 .OE+00 3.2E+00
1.13E+03 1.2E+00 1. OE+00 3.2E+00
1.60E+03 5.5E+00 1 .OE+00 3.2E+00
7.26E+01 1.1 E+01 1. OE+00 3.2E+00
2.00E+01 6.8E+00 1 .OE+00 3.2E+00
1.39E+01 5.8E+00 1 .OE+00 3.2E+00 10 325
1.24E+01 6.5E+00 1 .OE+00 3.2E+00
1.47E+01 1.2E+01 1. OE+00 3.2E+00
2.22E+01 1.1E+00 1.0E+00 3.2E+00
9.57E+02 3.5E+00 1 .OE+00 3.2E+00
1.14E+03 1. OE+00 1. OE+00 3.2E+00
1.72E+03 3.7E+00 1 .OE+00 3.2E+00
1.17E+02 8.1E-01 1. OE+00 3.2E+00
2.17E+01 5.2E+00 1 .OE+00 3.2E+00
1.76E+01 4.4E+00 1 .OE+00 3.2E+00 10 325
3.05E+00 2.0E+02 1. OE+00 3.2E+00
1.85E+01 3.2E+00 1. OE+00 3.2E+00
3.18E+01 1.4E+00 1. OE+00 3.2E+00
9.74E+02 9.2E-01 1. OE+00 3.2E+00
1.12E+03 9.9E-01 1. OE+00 3.2E+00
7.76E+02 9.4E+01 1. OE+00 3.2E+00
9.59E+00 6.6E+00 1. OE+00 3.2E+00
5.07E+00 2.4E+01 1. OE+00 3.2E+00
9.54E+00 1.1 E+01 1. OE+00 3.2E+00
7.95E+00 7.9E+00 1. OE+00 3.2E+00
1.36E+01 1.2E+01 1. OE+00 3.2E+00
5.22E+00 6.4E+01 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 11:38 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:40 AM EPA Interlab LOS 1313-1316 EaFA
3.37E+03 103% VU ICP-OES 6/7/10 1:34 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:43 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:46 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:48 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:50 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1011:51 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:03 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:39 PM EPA Interlab LOS 1313-1316 EaFA
3.29E+03 101% VU ICP-OES 6/7/10 12:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:08 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:09 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/1012:11 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:41 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:14 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:16 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:23 PM EPA Interlab LOS 1313-1316 EaFA
VUICP-OES 6/7/10 12:24 PM EPA Interlab LOS 1313-1316 EaFA
3.34E+03 102% VU ICP-OES 6/7/10 12:26 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:28 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:29 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:31 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:32 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:44 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:36 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:33 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:35 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:36 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:58 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 11:59 AM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:01 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                          1-206
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al EaFa-L09-1313-T01-A 1
Al EaFa-L09-1313-T02-A 1
Al EaFa-L09-1313-T03-A 1
Al EaFa-L09-1313-T04-A 1
Al EaFa-L09-1313-T05-A 1
Al EaFa-L09-1313-T06-A 1
Al EaFa-L09-1313-T07-A 1
Al EaFa-L09-1313-T08-A 1
Al EaFa-L09-1313-T09-A 1
Al EaFa-L09-1313-T01-B 1
Al EaFa-L09-1313-T02-B 1
Al EaFa-L09-1313-T03-B 1
Al EaFa-L09-1313-T04-B 1
Al EaFa-L09-1313-T05-B 1
Al EaFa-L09-1313-T06-B 1
Al EaFa-L09-1313-T07-B 1
Al EaFa-L09-1313-T08-B 1
Al EaFa-L09-1313-T09-B 1
Al EaFa-L09-1313-T01-C 1
Al EaFa-L09-1313-T02-C 1
Al EaFa-L09-1313-T03-C 1
Al EaFa-L09-1313-T04-C 1
Al EaFa-L09-1313-T05-C 1
Al EaFa-L09-1313-T06-C 1
Al EaFa-L09-1313-T07-C 1
Al EaFa-L09-1313-T08-C 1
Al EaFa-L09-1313-T09-C 1
Al EaFa-L09-1313-B01-A 1
Al EaFa-L09-1313-B02-A 1
Al EaFa-L09-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
3.79E+04
3.57E+04
2.69E+04
4.61 E+03
7.11E+02
1.39E+02
1.51 E+03
6.69E+04
1.23E+05
4.04E+04
3.89E+04
2.60E+04
4.40E+03
1.35E+03
1.88E+02
1.78E+03
6.79E+04
1.22E+05
4.00E+04
3.79E+04
2.51 E+04
4.87E+03
1.10E+03
2.18E+02
1.59E+03
6.62E+04
1.21E+05
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.79E+04 1.6E+00 1.00E+00 3.18E+00
3.57E+04 1.2E+00 1.00E+00 3.18E+00
2.69E+04 3.4E-01 1.00E+00 3.18E+00 1000 100
4.61E+03 8.3E-01 1.00E+00 3.18E+00
7.11E+02 1.2E+00 1.00E+00 3.18E+00
1.39E+02 5.6E-01 1.00E+00 3.18E+00
1.51E+03 4.0E-01 1.00E+00 3.18E+00
6.69E+04 4.1E-01 1.00E+00 3.18E+00
1.23E+05 5.3E-02 1.00E+00 3.18E+00
4.04E+04 2.2E+00 1.00E+00 3.18E+00
3.89E+04 6.4E-01 1.00E+00 3.18E+00
2.60E+04 2.2E+00 1.00E+00 3.18E+00 1000 100
4.40E+03 2.3E-01 1.00E+00 3.18E+00
1.35E+03 5.8E-01 1.00E+00 3.18E+00
1.88E+02 9.6E-01 1.00E+00 3.18E+00
1.78E+03 3.6E-01 1.00E+00 3.18E+00
6.79E+04 3.8E-01 1.00E+00 3.18E+00
1.22E+05 1.2E-01 1.00E+00 3.18E+00
4.00E+04 9.2E-01 1.00E+00 3.18E+00
3.79E+04 1.1E+00 1.00E+00 3.18E+00
2.51E+04 4.0E-01 1.00E+00 3.18E+00 1000 100
4.87E+03 6.2E-01 1.00E+00 3.18E+00
1.10E+03 4.9E-01 1.00E+00 3.18E+00
2.18E+02 2.3E+00 1.00E+00 3.18E+00
1.59E+03 4.2E-01 1.00E+00 3.18E+00
6.62E+04 2.9E-02 1.00E+00 3.18E+00
1.21E+05 9.7E-01 1.00E+00 3.18E+00
5.00E-01 1.5E+01 1.00E+00 3.18E+00
5.00E-01 1.2E+01 1.00E+00 3.18E+00
5.00E-01 1.2E+01 1.00E+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.78E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.69E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.60E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50 AM L09 1313-1316 EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 1 0:53 AM L09 131 3-1 31 6 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/10 11:01 AM L09 1313-1316 EaFA
6/11/10 11:03 AM L09 1313-1316 EaFA
6/11/10 11:15 AM L09 1313-1316 EaFA
6/11/10 11:16 AM L09 1313-1316 EaFA
6/11/10 11:18 AM L09 1313-1316 EaFA
6/11/10 11:20 AM L09 1313-1316 EaFA
6/11/10 11:21 AM L09 1313-1316 EaFA
6/11/10 11:23 AM L09 1313-1316 EaFA
6/11/10 11:24 AM L09 1313-1316 EaFA
6/11/10 11:26 AM L09 1313-1316 EaFA
6/11/10 11:28 AM L09 1313-1316 EaFA
6/11/10 11:34 AM L09 1313-1316 EaFA
6/11/10 11:36 AM L09 1313-1316 EaFA
6/11/10 11:38AML091313-1316EaFA
6/11/10 11:39 AM L09 1313-1316 EaFA
6/11/10 11:41 AM L09 1313-1316 EaFA
6/11/10 11:43 AM L09 1313-1316 EaFA
6/11/10 11:44 AM L09 1313-1316 EaFA
6/11/10 11:46 AM L09 1313-1316 EaFA
6/11/10 11:48 AM L09 1313-1316 EaFA
6/11/10 10:45 AM L09 1313-1316 EaFA
6/11/10 10:46 AM L09 1313-1316 EaFA
6/11/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                                   1-207
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qu
ug/L
Sb EaFa-L09-1313-T01-A 1 2.22E+02
Sb EaFa-L09-1313-T02-A 1 1.52E+02
Sb EaFa-L09-1313-T03-A 1 1.88E+02
Sb EaFa-L09-1313-T04-A 1 2.25E+02
Sb EaFa-L09-1313-T05-A 1 1.90E+02
Sb EaFa-L09-1313-T06-A 1 1.79E+02
Sb EaFa-L09-1313-T07-A 1 7.23E+01
Sb EaFa-L09-1313-T08-A 1 2.08E+01 E
Sb EaFa-L09-1313-T09-A 1 9.33E+00 E
Sb EaFa-L09-1313-T01-B 1 2.11E+02
Sb EaFa-L09-1313-T02-B 1 1.63E+02
Sb EaFa-L09-1313-T03-B 1 1.74E+02
Sb EaFa-L09-1313-T04-B 1 1.96E+02
Sb EaFa-L09-1313-T05-B 1 1.93E+02
Sb EaFa-L09-1313-T06-B 1 1.93E+02
Sb EaFa-L09-1313-T07-B 1 8.77E+01
Sb EaFa-L09-1313-T08-B 1 2.45E+01
Sb EaFa-L09-1313-T09-B 1 1 .22E+01 E
Sb EaFa-L09-1313-T01-C 1 2.17E+02
Sb EaFa-L09-1313-T02-C 1 1 .42E+02
Sb EaFa-L09-1313-T03-C 1 1 J7E+02
Sb EaFa-L09-1313-T04-C 1 1 .94E+02
Sb EaFa-L09-1313-T05-C 1 1.72E+02
Sb EaFa-L09-1313-T06-C 1 1.50E+02
Sb EaFa-L09-1313-T07-C 1 9.35E+01
Sb EaFa-L09-1313-T08-C 1 2.42E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.22E+02 8.6E+00 7.50E+00 2.39E+01
1.52E+02 8.9E+00 7.50E+00 2.39E+01
1.88E+02 1.1E+01 7.50E+00 2.39E+01 10 325
2.25E+02 8.4E+00 7.50E+00 2.39E+01
1.90E+02 4.6E+00 7.50E+00 2.39E+01
1.79E+02 3.3E+00 7.50E+00 2.39E+01
7.23E+01 3.8E+01 7.50E+00 2.39E+01
2.08E+01 2.0E+01 7.50E+00 2.39E+01
9.33E+00 8.8E+01 7.50E+00 2.39E+01
2.11E+02 1.1E+01 7.50E+00 2.39E+01
1.63E+02 1.1E+01 7.50E+00 2.39E+01
1.74E+02 4.3E+00 7.50E+00 2.39E+01 10 325
1.96E+02 1.4E+01 7.50E+00 2.39E+01
1.93E+02 1.3E+01 7.50E+00 2.39E+01
1.93E+02 5.1E+00 7.50E+00 2.39E+01
8.77E+01 1.3E+01 7.50E+00 2.39E+01
2.45E+01 4.6E+01 7.50E+00 2.39E+01
1.22E+01 8.6E+01 7.50E+00 2.39E+01
2.17E+02 5.3E+00 7.50E+00 2.39E+01
1.42E+02 1.0E+01 7.50E+00 2.39E+01
1.77E+02 1.2E+01 7.50E+00 2.39E+01 10 325
1.94E+02 3.3E+00 7.50E+00 2.39E+01
1.72E+02 1.0E+01 7.50E+00 2.39E+01
1.50E+02 6.0E+00 7.50E+00 2.39E+01
9.35E+01 1.9E+01 7.50E+00 2.39E+01
2.42E+01 3.0E+01 7.50E+00 2.39E+01
Sb EaFa-L09-1313-T09-C 1 3.75E+00 U1/2 3.75E+00 9.3E+00 7.50E+00 2.39E+01
Sb EaFa-L09-1313-B01-A 1 3.18E+01
Sb EaFa-L09-1313-B02-A 1 2.27E+01 E
Sb EaFa-L09-1313-B03-A 1 2.59E+01
3.18E+01 7.8E+01 7.50E+00 2.39E+01
2.27E+01 8.1E+01 7.50E+00 2.39E+01
2.59E+01 9.7E+01 7.50E+00 2.39E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.58E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.50E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.53E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/11/1011 :48 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-208
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qu
ug/L
As EaFa-L09-1313-T01-A 1 7.95E+03
As EaFa-L09-1313-T02-A 1 9.89E+02
As EaFa-L09-1313-T03-A 1 1.16E+03
As EaFa-L09-1313-T04-A 1 4.77E+02
As EaFa-L09-1313-T05-A 1 1.81E+02
As EaFa-L09-1313-T06-A 1 1.18E+02
As EaFa-L09-1313-T07-A 1 1.25E+02
As EaFa-L09-1313-T08-A 1 1.13E+02
As EaFa-L09-1313-T09-A 1 1.32E+03
As EaFa-L09-1313-T01-B 1 8.04E+03
As EaFa-L09-1313-T02-B 1 1.02E+03
As EaFa-L09-1313-T03-B 1 1.13E+03
As EaFa-L09-1313-T04-B 1 3.82E+02
As EaFa-L09-1313-T05-B 1 2.22E+02
As EaFa-L09-1313-T06-B 1 1.10E+02
As EaFa-L09-1313-T07-B 1 1.61E+02
As EaFa-L09-1313-T08-B 1 1.28E+02
As EaFa-L09-1313-T09-B 1 1 .38E+03
As EaFa-L09-1313-T01-C 1 7.95E+03
As EaFa-L09-1313-T02-C 1 1 .02E+03
As EaFa-L09-1313-T03-C 1 1.11E+03
As EaFa-L09-1313-T04-C 1 3.46E+02
As EaFa-L09-1313-T05-C 1 2.20E+02
As EaFa-L09-1313-T06-C 1 1.14E+02
As EaFa-L09-1313-T07-C 1 1.59E+02
As EaFa-L09-1313-T08-C 1 1.31E+02
As EaFa-L09-1313-T09-C 1 1.39E+03
As EaFa-L09-1313-B01-A 1 2.15E+01 E
As EaFa-L09-1313-B02-A 1 3.14E+01 E
As EaFa-L09-1313-B03-A 1 2.76E+01 E
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.95E+03 4.1E-01 1.10E+01 3.50E+01
9.89E+02 3.9E+00 1.10E+01 3.50E+01
1.16E+03 2.0E+00 1.10E+01 3.50E+01 10 325
4.77E+02 1.6E+00 1.10E+01 3.50E+01
1.81E+02 7.6E+00 1.10E+01 3.50E+01
1.18E+02 2.2E+01 1.10E+01 3.50E+01
1.25E+02 1.2E+01 1.10E+01 3.50E+01
1.13E+02 1.4E+00 1.10E+01 3.50E+01
1.32E+03 6.4E-01 1.10E+01 3.50E+01
8.04E+03 1.7E+00 1.10E+01 3.50E+01
1.02E+03 1.7E+00 1.10E+01 3.50E+01
1.13E+03 4.3E+00 1.10E+01 3.50E+01 10 325
3.82E+02 3.0E+00 1.10E+01 3.50E+01
2.22E+02 4.1E+00 1.10E+01 3.50E+01
1.10E+02 9.1E+00 1.10E+01 3.50E+01
1.61E+02 1.3E+01 1.10E+01 3.50E+01
1.28E+02 3.5E+00 1.10E+01 3.50E+01
1.38E+03 8.0E-01 1.10E+01 3.50E+01
7.95E+03 9.1E-01 1.10E+01 3.50E+01
1.02E+03 7.1E-01 1.10E+01 3.50E+01
1.11E+03 5.2E-01 1.10E+01 3.50E+01 10 325
3.46E+02 2.6E+00 1.10E+01 3.50E+01
2.20E+02 4.5E+00 1.10E+01 3.50E+01
1.14E+02 1.7E+01 1.10E+01 3.50E+01
1.59E+02 1.2E+01 1.10E+01 3.50E+01
1.31E+02 7.7E+00 1.10E+01 3.50E+01
1.39E+03 5.0E-01 1.10E+01 3.50E+01
2.15E+01 1.1E+01 1.10E+01 3.50E+01
3.14E+01 2.0E+01 1.10E+01 3.50E+01
2.76E+01 4.0E+01 1.10E+01 3.50E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.40E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.32E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.36E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-209
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone.
ug/L
B EaFa-L09-1313-T01-A 1 4.50E+03
B EaFa-L09-1313-T02-A 1 4.43E+03
B EaFa-L09-1313-T03-A 1 4.41 E+03
B EaFa-L09-1313-T04-A 1 4.17E+03
B EaFa-L09-1313-T05-A 1 4.41 E+03
B EaFa-L09-1313-T06-A 1 4.57E+03
B EaFa-L09-1313-T07-A 1 4.57E+03
B EaFa-L09-1313-T08-A 1 3.58E+03
B EaFa-L09-1313-T09-A 1 3.07E+03
B EaFa-L09-1313-T01-B 1 4.66E+03
B EaFa-L09-1313-T02-B 1 4.67E+03
B EaFa-L09-1313-T03-B 1 4.41 E+03
B EaFa-L09-1313-T04-B 1 4.32E+03
B EaFa-L09-1313-T05-B 1 4.49E+03
B EaFa-L09-1313-T06-B 1 4.68E+03
B EaFa-L09-1313-T07-B 1 4.50E+03
B EaFa-L09-1313-T08-B 1 3.62E+03
B EaFa-L09-1313-T09-B 1 3.10E+03
B EaFa-L09-1313-T01-C 1 4.70E+03
B EaFa-L09-1313-T02-C 1 4.50E+03
B EaFa-L09-1313-T03-C 1 4.20E+03
B EaFa-L09-1313-T04-C 1 4.33E+03
B EaFa-L09-1313-T05-C 1 4.30E+03
B EaFa-L09-1313-T06-C 1 4.62E+03
B EaFa-L09-1313-T07-C 1 4.50E+03
B EaFa-L09-1313-T08-C 1 3.62E+03
B EaFa-L09-1313-T09-C 1 3.09E+03
B EaFa-L09-1313-B01-A 1 3.67E+01
B EaFa-L09-1313-B02-A 1 3.06E+01
B EaFa-L09-1313-B03-A 1 3.31 E+01
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.50E+03 9.6E-01 1. OOE+00 3.18E+00
4.43E+03 2.9E+00 1. OOE+00 3.18E+00
4.41E+03 2.1E+00 1.00E+00 3.18E+00 1000 100
4.17E+03 1.5E+00 1.00E+00 3.18E+00
4.41 E+03 1.9E+00 1. OOE+00 3.18E+00
4.57E+03 8.3E-01 1. OOE+00 3.18E+00
4.57E+03 2.9E-01 1. OOE+00 3.18E+00
3.58E+03 3.5E-01 1. OOE+00 3.18E+00
3.07E+03 4.1E-01 1.00E+00 3.18E+00
4.66E+03 1.4E+00 1. OOE+00 3.18E+00
4.67E+03 1.2E+00 1. OOE+00 3.18E+00
4.41E+03 8.4E-01 1.00E+00 3.18E+00 1000 100
4.32E+03 1.7E+00 1. OOE+00 3.18E+00
4.49E+03 1.3E+00 1. OOE+00 3.18E+00
4.68E+03 5.7E-01 1. OOE+00 3.18E+00
4.50E+03 3.1E-01 1.00E+00 3.18E+00
3.62E+03 5.0E-01 1 .OOE+00 3.18E+00
3.10E+03 1.4E+00 1 .OOE+00 3.18E+00
4.70E+03 1.1E+00 1 .OOE+00 3.18E+00
4.50E+03 1.3E+00 1 .OOE+00 3.18E+00
4.20E+03 3.6E+00 1 .OOE+00 3.18E+00 1000 100
4.33E+03 1.3E+00 1 .OOE+00 3.18E+00
4.30E+03 1.7E+00 1. OOE+00 3.18E+00
4.62E+03 1.8E+00 1. OOE+00 3.18E+00
4.50E+03 5.8E-01 1. OOE+00 3.18E+00
3.62E+03 2.5E-01 1. OOE+00 3.18E+00
3.09E+03 4.3E-01 1. OOE+00 3.18E+00
3.67E+01 2.8E+00 1. OOE+00 3.18E+00
3.06E+01 1.9E+00 1. OOE+00 3.18E+00
3.31 E+01 3.6E+00 1. OOE+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.40E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.25E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.16E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 1 0:50 AM L09 131 3-1 31 6 EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-210
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone.
ug/L
Ba EaFa-L09-1313-T01-A 1 1.02E+03
Ba EaFa-L09-1313-T02-A 1 1.10E+03
Ba EaFa-L09-1313-T03-A 1 8.15E+02
Ba EaFa-L09-1313-T04-A 1 4.08E+02
Ba EaFa-L09-1313-T05-A 1 2.93E+02
Ba EaFa-L09-1313-T06-A 1 2.65E+02
Ba EaFa-L09-1313-T07-A 1 2.89E+02
Ba EaFa-L09-1313-T08-A 1 3.63E+02
Ba EaFa-L09-1313-T09-A 1 7.88E+02
Ba EaFa-L09-1313-T01-B 1 1.23E+03
Ba EaFa-L09-1313-T02-B 1 1.15E+03
Ba EaFa-L09-1313-T03-B 1 1.15E+03
Ba EaFa-L09-1313-T04-B 1 3.87E+02
Ba EaFa-L09-1313-T05-B 1 3.28E+02
Ba EaFa-L09-1313-T06-B 1 2.95E+02
Ba EaFa-L09-1313-T07-B 1 2.76E+02
Ba EaFa-L09-1313-T08-B 1 3.77E+02
Ba EaFa-L09-1313-T09-B 1 8.32E+02
Ba EaFa-L09-1313-T01-C 1 1 .34E+03
Ba EaFa-L09-1313-T02-C 1 1.15E+03
Ba EaFa-L09-1313-T03-C 1 1.10E+03
Ba EaFa-L09-1313-T04-C 1 3.85E+02
Ba EaFa-L09-1313-T05-C 1 3.11E+02
Ba EaFa-L09-1313-T06-C 1 2.89E+02
Ba EaFa-L09-1313-T07-C 1 2.80E+02
Ba EaFa-L09-1313-T08-C 1 3.76E+02
Ba EaFa-L09-1313-T09-C 1 8.38E+02
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.02E+03 7.6E-01 1. OOE+00 3.18E+00
1.10E+03 1.6E+00 1. OOE+00 3.18E+00
8.15E+02 5.3E-01 1.00E+00 3.18E+00 10 325
4.08E+02 9.3E-01 1. OOE+00 3.18E+00
2.93E+02 6.9E-01 1. OOE+00 3.18E+00
2.65E+02 3.5E-01 1. OOE+00 3.18E+00
2.89E+02 2.0E-01 1. OOE+00 3.18E+00
3.63E+02 4.6E-01 1. OOE+00 3.18E+00
7.88E+02 5.4E-01 1. OOE+00 3.18E+00
1.23E+03 1.5E+00 1. OOE+00 3.18E+00
1.15E+03 3.8E-01 1. OOE+00 3.18E+00
1.15E+03 2.1E+00 1.00E+00 3.18E+00 10 325
3.87E+02 4.8E-01 1. OOE+00 3.18E+00
3.28E+02 7.2E-01 1. OOE+00 3.18E+00
2.95E+02 5.7E-01 1. OOE+00 3.18E+00
2.76E+02 5.3E-01 1. OOE+00 3.18E+00
3.77E+02 6.9E-01 1 .OOE+00 3.18E+00
8.32E+02 2.6E-01 1 .OOE+00 3.18E+00
1.34E+03 8.7E-01 1 .OOE+00 3.18E+00
1.15E+03 1.5E-01 1. OOE+00 3.18E+00
1.10E+03 5.5E-01 1. OOE+00 3.18E+00 10 325
3.85E+02 9.0E-01 1 .OOE+00 3.18E+00
3.11E+02 2.2E-01 1 .OOE+00 3.18E+00
2.89E+02 3.1E-01 1 .OOE+00 3.18E+00
2.80E+02 5.7E-01 1 .OOE+00 3.18E+00
3.76E+02 1.4E-01 1 .OOE+00 3.18E+00
8.38E+02 2.7E-01 1 .OOE+00 3.18E+00
Ba EaFa-L09-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 4.9E+01 1 .OOE+00 3.18E+00
Ba EaFa-L09-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 6.8E+01 1 .OOE+00 3.18E+00
Ba EaFa-L09-1313-B03-A 1 1 .53E+00 E
1.53E+00 1.2E+01 1. OOE+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.80E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.02E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.02E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1/10 10:45 AM L09 1313-1316 EaFA
6/1 1/10 10:46 AM L09 1313-1316 EaFA
6/1 1/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-211
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Be Sample Dilution Cone. (
ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Be EaFa-L09-1313-T01-A 1 9.50E-01 U1/2 9.50E-01 1.1E+01 1.90E+00 6.00E+00
Be EaFa-L09-1313-T02-A 1 9.50E-01 U1/2 9.50E-01 1 .8E+01 1.90E+00 6.00E+00
Be EaFa-L09-1313-T03-A 1 9.50E-01 U1/2 9.50E-01 4.0E+01 1.90E+00 6.00E+00 10 325
Be EaFa-L09-1313-T04-A 1 9.50E-01 U1/2 9.50E-01 2.9E+01 1.90E+00 6.00E+00
Be EaFa-L09-1313-T05-A 1 9.50E-01 U1/2 9.50E-01 2.0E+02 1.90E+00 6.00E+00
Be EaFa-L09-1313-T06-A 1 9.50E-01 U1/2 9.50E-01 1.3E+02 1.90E+00 6.00E+00
Be EaFa-L09-1313-T07-A 1 1.27E+01
Be EaFa-L09-1313-T08-A 1 1.85E+02
Be EaFa-L09-1313-T09-A 1 2.53E+02
1.27E+01 7.4E-01 1.90E+00 6.00E+00
1.85E+02 7.1E-01 1.90E+00 6.00E+00
2.53E+02 1.7E+00 1.90E+00 6.00E+00
Be EaFa-L09-1313-T01-B 1 9.50E-01 U1/2 9.50E-01 8.7E+00 1.90E+00 6.00E+00
Be EaFa-L09-1313-T02-B 1 9.50E-01 U1/2 9.50E-01 6.1E+01 1.90E+00 6.00E+00
Be EaFa-L09-1313-T03-B 1 9.50E-01 U1/2 9.50E-01 4.7E+01 1.90E+00 6.00E+00 10 325
Be EaFa-L09-1313-T04-B 1 9.50E-01 U1/2 9.50E-01 2.7E+02 1.90E+00 6.00E+00
Be EaFa-L09-1313-T05-B 1 9.50E-01 U1/2 9.50E-01 3.4E+01 1.90E+00 6.00E+00
Be EaFa-L09-1313-T06-B 1 9.50E-01 U1/2 9.50E-01 8.4E+01 1.90E+00 6.00E+00
Be EaFa-L09-1313-T07-B 1 1.57E+01
Be EaFa-L09-1313-T08-B 1 1.88E+02
Be EaFa-L09-1313-T09-B 1 2.53E+02
1.57E+01 7.3E-01 1.90E+00 6.00E+00
1.88E+02 4.3E-01 1.90E+00 6.00E+00
2.53E+02 4.0E-01 1.90E+00 6.00E+00
Be EaFa-L09-1313-T01-C 1 9.50E-01 U1/2 9.50E-01 2.6E+01 1.90E+00 6.00E+00
Be EaFa-L09-1313-T02-C 1 9.50E-01 U1/2 9.50E-01 2.4E+02 1.90E+00 6.00E+00
Be EaFa-L09-1313-T03-C 1 9.50E-01 U1/2 9.50E-01 2.2E+02 1.90E+00 6.00E+00 10 325
Be EaFa-L09-1313-T04-C 1 9.50E-01 U1/2 9.50E-01 3.1E+02 1.90E+00 6.00E+00
Be EaFa-L09-1313-T05-C 1 9.50E-01 U1/2 9.50E-01 5.2E+01 1.90E+00 6.00E+00
Be EaFa-L09-1313-T06-C 1 9.50E-01 U1/2 9.50E-01 1.3E+03 1.90E+00 6.00E+00
Be EaFa-L09-1313-T07-C 1 1.44E+01
Be EaFa-L09-1313-T08-C 1 1.87E+02
Be EaFa-L09-1313-T09-C 1 2.52E+02
1.44E+01 2.2E+00 1.90E+00 6.00E+00
1.87E+02 4.3E-01 1.90E+00 6.00E+00
2.52E+02 5.0E-01 1.90E+00 6.00E+00
Be EaFa-L09-1313-B01-A 1 9.50E-01 U1/2 9.50E-01 1.5E+02 1.90E+00 6.00E+00
Be EaFa-L09-1313-B02-A 1 9.50E-01 U1/2 9.50E-01 3.4E+01 1.90E+00 6.00E+00
Be EaFa-L09-1313-B03-A 1 9.50E-01 U1/2 9.50E-01 1.2E+02 1.90E+00 6.00E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.50E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.41E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.44E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 1 0:50 AM L09 131 3-1 31 6 EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 1 0:53 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:57 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:58 AM L09 131 3-1 31 6 EaFA
6/11/10 11:OOAML091313-1316EaFA
6/11/10 11:01 AM L09 131 3-1 31 6 EaFA
6/11/10 11:03 AM L09 1313-1316 EaFA
6/11/10 11:15 AM L09 1313-1316 EaFA
6/11/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/11/10 11:20 AM L09 1313-1316 EaFA
6/11/10 11:21 AM L09 1313-1316 EaFA
6/11/10 11:23 AM L09 1313-1316 EaFA
6/11/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/11/10 10:45 AM L09 1313-1316 EaFA
6/11/10 10:46 AM L09 1313-1316 EaFA
6/11/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-212
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFa-L09-1313-T01-A 1
Cd EaFa-L09-1313-T02-A 1
Cd EaFa-L09-1313-T03-A 1
Cd EaFa-L09-1313-T04-A 1
Cd EaFa-L09-1313-T05-A 1
Cd EaFa-L09-1313-T06-A 1
Cd EaFa-L09-1313-T07-A 1
Cd EaFa-L09-1313-T08-A 1
Cd EaFa-L09-1313-T09-A 1
Cd EaFa-L09-1313-T01-B 1
Cd EaFa-L09-1313-T02-B 1
Cd EaFa-L09-1313-T03-B 1
Cd EaFa-L09-1313-T04-B 1
Cd EaFa-L09-1313-T05-B 1
Cd EaFa-L09-1313-T06-B 1
Cd EaFa-L09-1313-T07-B 1
Cd EaFa-L09-1313-T08-B 1
Cd EaFa-L09-1313-T09-B 1
Cd EaFa-L09-1313-T01-C 1
Cd EaFa-L09-1313-T02-C 1
Cd EaFa-L09-1313-T03-C 1
Cd EaFa-L09-1313-T04-C 1
Cd EaFa-L09-1313-T05-C 1
Cd EaFa-L09-1313-T06-C 1
Cd EaFa-L09-1313-T07-C 1
Cd EaFa-L09-1313-T08-C 1
Cd EaFa-L09-1313-T09-C 1
Cd EaFa-L09-1313-B01-A 1
Cd EaFa-L09-1313-B02-A 1
Cd EaFa-L09-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.11E+01
2.23E+01
2.72E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.07E+01
2.26E+01
2.71E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.11E+01
2.29E+01
2.68E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.1E+01 2.20E+00 7.00E+00
1.10E+00 4.0E+00 2.20E+00 7.00E+00
1.10E+00 4.8E+00 2.20E+00 7.00E+00 10 325
1.10E+00 1.0E+01 2.20E+00 7.00E+00
1.10E+00 8.9E+00 2.20E+00 7.00E+00
1.10E+00 7.6E+00 2.20E+00 7.00E+00
3.11E+01 4.2E+00 2.20E+00 7.00E+00
2.23E+01 3.5E+00 2.20E+00 7.00E+00
2.72E+01 4.4E-01 2.20E+00 7.00E+00
1.10E+00 8.1E+00 2.20E+00 7.00E+00
1.10E+00 8.1E+00 2.20E+00 7.00E+00
1.10E+00 7.6E+00 2.20E+00 7.00E+00 10 325
1.10E+00 8.4E+00 2.20E+00 7.00E+00
1.10E+00 7.2E+00 2.20E+00 7.00E+00
1.10E+00 1.3E+00 2.20E+00 7.00E+00
3.07E+01 8.8E-01 2.20E+00 7.00E+00
2.26E+01 8.6E-01 2.20E+00 7.00E+00
2.71E+01 1.9E+00 2.20E+00 7.00E+00
1.10E+00 1.5E+01 2.20E+00 7.00E+00
1.10E+00 1.2E+01 2.20E+00 7.00E+00
1.10E+00 7.8E+00 2.20E+00 7.00E+00 10 325
1.10E+00 8.2E+00 2.20E+00 7.00E+00
1.10E+00 4.6E+00 2.20E+00 7.00E+00
1.10E+00 7.4E+00 2.20E+00 7.00E+00
3.11E+01 6.9E-01 2.20E+00 7.00E+00
2.29E+01 8.8E-01 2.20E+00 7.00E+00
2.68E+01 2.0E+00 2.20E+00 7.00E+00
1.10E+00 7.6E+00 2.20E+00 7.00E+00
1.10E+00 1.0E+01 2.20E+00 7.00E+00
1.10E+00 1.0E+01 2.20E+00 7.00E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.50E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.42E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.45E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1/10 10:45 AM L09 1313-1316 EaFA
6/1 1/1 01 0:46 AM L09 1313-1316 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-213
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca EaFa-L09-1313-T01-A 1
Ca EaFa-L09-1313-T02-A 1
Ca EaFa-L09-1313-T03-A 1
Ca EaFa-L09-1313-T04-A 1
Ca EaFa-L09-1313-T05-A 1
Ca EaFa-L09-1313-T06-A 1
Ca EaFa-L09-1313-T07-A 1
Ca EaFa-L09-1313-T08-A 1
Ca EaFa-L09-1313-T09-A 1
Ca EaFa-L09-1313-T01-B 1
Ca EaFa-L09-1313-T02-B 1
Ca EaFa-L09-1313-T03-B 1
Ca EaFa-L09-1313-T04-B 1
Ca EaFa-L09-1313-T05-B 1
Ca EaFa-L09-1313-T06-B 1
Ca EaFa-L09-1313-T07-B 1
Ca EaFa-L09-1313-T08-B 1
Ca EaFa-L09-1313-T09-B 1
Ca EaFa-L09-1313-T01-C 1
Ca EaFa-L09-1313-T02-C 1
Ca EaFa-L09-1313-T03-C 1
Ca EaFa-L09-1313-T04-C 1
Ca EaFa-L09-1313-T05-C 1
Ca EaFa-L09-1313-T06-C 1
Ca EaFa-L09-1313-T07-C 1
Ca EaFa-L09-1313-T08-C 1
Ca EaFa-L09-1313-T09-C 1
Ca EaFa-L09-1313-B01-A 1
Ca EaFa-L09-1313-B02-A 1
Ca EaFa-L09-1313-B03-A 1
Sample I
Cone. Qualifier 1
ug/L 1
1.57E+04
5.19E+04
1.01E+05
1.32E+05
1.46E+05
1.62E+05
1.60E+05
1.49E+05
1.40E+05
1.68E+04
4.88E+04
9.87E+04
1.30E+05
1.44E+05
1.61E+05
1.58E+05
1.49E+05
1.41E+05
1.71E+04
4.73E+04
9.26E+04
1.27E+05
1.36E+05
1.57E+05
1.57E+05
1.45E+05
1.39E+05
1.30E+00 U1/2
1.30E+00 U1/2
9.17E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.57E+04 8.1E-01 2.60E+00 8.30E+00
5.19E+04 1.4E+00 2.60E+00 8.30E+00
1.01E+05 5.0E-01 2.60E+00 8.30E+00 1000 100
1.32E+05 1.5E+00 2.60E+00 8.30E+00
1.46E+05 8.5E-01 2.60E+00 8.30E+00
1.62E+05 4.7E-01 2.60E+00 8.30E+00
1.60E+05 7.3E-01 2.60E+00 8.30E+00
1.49E+05 4.1E-01 2.60E+00 8.30E+00
1.40E+05 4.6E-01 2.60E+00 8.30E+00
1.68E+04 1.3E+00 2.60E+00 8.30E+00
4.88E+04 4.9E-01 2.60E+00 8.30E+00
9.87E+04 2.2E+00 2.60E+00 8.30E+00 1000 100
1.30E+05 6.3E-01 2.60E+00 8.30E+00
1.44E+05 8.9E-01 2.60E+00 8.30E+00
1.61E+05 7.9E-01 2.60E+00 8.30E+00
1.58E+05 3.9E-01 2.60E+00 8.30E+00
1.49E+05 7.5E-01 2.60E+00 8.30E+00
1.41E+05 7.4E-01 2.60E+00 8.30E+00
1.71E+04 4.8E-01 2.60E+00 8.30E+00
4.73E+04 4.7E-01 2.60E+00 8.30E+00
9.26E+04 5.3E-01 2.60E+00 8.30E+00 1000 100
1.27E+05 6.9E-01 2.60E+00 8.30E+00
1.36E+05 4.4E-01 2.60E+00 8.30E+00
1.57E+05 6.7E-02 2.60E+00 8.30E+00
1.57E+05 1.1E-01 2.60E+00 8.30E+00
1.45E+05 7.3E-01 2.60E+00 8.30E+00
1.39E+05 6.2E-01 2.60E+00 8.30E+00
1.30E+00 9.4E+01 2.60E+00 8.30E+00
1.30E+00 5.6E+01 2.60E+00 8.30E+00
9.17E+00 2.2E+01 2.60E+00 8.30E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .02E+05 81 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.96E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:57 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:58 AM L09 131 3-1 31 6 EaFA
6/11/10 11:OOAML091313-1316EaFA
6/11/10 11:01 AM L09 131 3-1 31 6 EaFA
6/11/10 11:03AML091313-1316EaFA
6/11/10 11:15 AM L09 1313-1316 EaFA
6/11/10 11:16 AM L09 1313-1316 EaFA
6/11/10 11:18 AM L09 1313-1316 EaFA
6/11/10 11:20AML091313-1316EaFA
6/11/10 11:21 AM L09 131 3-1 31 6 EaFA
6/11/10 11:23AML091313-1316EaFA
6/11/10 11:24AML091313-1316EaFA
6/11/10 11:26AML091313-1316EaFA
6/11/10 11:28AML091313-1316EaFA
6/11/10 11:34AML091313-1316EaFA
6/11/10 11:36AML091313-1316EaFA
6/11/10 11:38 AM L09 1313-1316 EaFA
6/11/10 11:39AML091313-1316EaFA
6/11/10 11:41 AM L09 131 3-1 31 6 EaFA
6/11/10 11:43AML091313-1316EaFA
6/11/10 11:44AML091313-1316EaFA
6/11/10 11:46AML091313-1316EaFA
6/11/10 11:48AML091313-1316EaFA
6/11/10 10:45 AM L09 1313-1316 EaFA
6/11/10 10:46 AM L09 1313-1316 EaFA
6/11/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-214
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone.
ug/L
Cr EaFa-L09-1313-T01-A 1 4.26E+02
Cr EaFa-L09-1313-T02-A 1 3.17E+02
Cr EaFa-L09-1313-T03-A 1 2.59E+02
Cr EaFa-L09-1313-T04-A 1 1.81E+02
Cr EaFa-L09-1313-T05-A 1 7.84E+01
Cr EaFa-L09-1313-T06-A 1 1.81E+01
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.26E+02 6.9E-01 1.20E+00 3.82E+00
3.17E+02 8.3E-01 1.20E+00 3.82E+00
2.59E+02 8.9E-02 1.20E+00 3.82E+00 10 325
1.81E+02 1.9E+00 1.20E+00 3.82E+00
7.84E+01 1.4E+00 1.20E+00 3.82E+00
1.81E+01 4.2E+00 1.20E+00 3.82E+00
Cr EaFa-L09-1313-T07-A 1 1.69E+OOE 1.69E+00 6.4E+01 1.20E+00 3.82E+00
Cr EaFa-L09-1313-T08-A 1 9.29E+02
Cr EaFa-L09-1313-T09-A 1 1.83E+03
Cr EaFa-L09-1313-T01-B 1 4.13E+02
Cr EaFa-L09-1313-T02-B 1 3.14E+02
Cr EaFa-L09-1313-T03-B 1 2.21E+02
Cr EaFa-L09-1313-T04-B 1 1.66E+02
Cr EaFa-L09-1313-T05-B 1 1.20E+02
Cr EaFa-L09-1313-T06-B 1 2.51E+01
9.29E+02 1.0E+00 1.20E+00 3.82E+00
1.83E+03 3.4E-01 1.20E+00 3.82E+00
4.13E+02 2.5E+00 1.20E+00 3.82E+00
3.14E+02 2.1E-01 1.20E+00 3.82E+00
2.21E+02 1.6E+00 1.20E+00 3.82E+00 10 325
1.66E+02 1.1E+00 1.20E+00 3.82E+00
1.20E+02 1.0E+00 1.20E+00 3.82E+00
2.51 E+01 1.2E+00 1.20E+00 3.82E+00
Cr EaFa-L09-1313-T07-B 1 2.51E+00 E 2.51E+00 2.2E+01 1.20E+00 3.82E+00
Cr EaFa-L09-1313-T08-B 1 9.90E+02
Cr EaFa-L09-1313-T09-B 1 1.85E+03
Cr EaFa-L09-1313-T01-C 1 4.25E+02
Cr EaFa-L09-1313-T02-C 1 2.97E+02
Cr EaFa-L09-1313-T03-C 1 2.19E+02
Cr EaFa-L09-1313-T04-C 1 1.68E+02
Cr EaFa-L09-1313-T05-C 1 1.15E+02
Cr EaFa-L09-1313-T06-C 1 3.42E+01
9.90E+02 8.8E-01 1.20E+00 3.82E+00
1.85E+03 3.0E-01 1.20E+00 3.82E+00
4.25E+02 7.7E-01 1 .20E+00 3.82E+00
2.97E+02 5.5E-01 1 .20E+00 3.82E+00
2.19E+02 9.4E-01 1 .20E+00 3.82E+00 10 325
1.68E+02 1.3E+00 1.20E+00 3.82E+00
1.15E+02 4.0E-01 1.20E+00 3.82E+00
3.42E+01 5.7E-01 1 .20E+00 3.82E+00
Cr EaFa-L09-1313-T07-C 1 2.76E+00 E 2.76E+00 6.9E+00 1.20E+00 3.82E+00
Cr EaFa-L09-1313-T08-C 1 9.44E+02
Cr EaFa-L09-1313-T09-C 1 1.82E+03
9.44E+02 4.6E-01 1 .20E+00 3.82E+00
1.82E+03 2.1E-01 1 .20E+00 3.82E+00
Cr EaFa-L09-1313-B01-A 1 6.00E-01 U1/2 6.00E-01 7.9E+01 1 .20E+00 3.82E+00
Cr EaFa-L09-1313-B02-A 1 6.00E-01 U1/2 6.00E-01 2.5E+01 1 .20E+00 3.82E+00
Cr EaFa-L09-1313-B03-A 1 1.49E+OOE 1.49E+00 1.4E+02 1.20E+00 3.82E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.59E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.47E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.49E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/10 11:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1/10 10:45 AM L09 1313-1316 EaFA
6/1 1/10 10:46 AM L09 1313-1316 EaFA
6/1 1/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-215
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFa-L09-1313-T01-A 1
Co EaFa-L09-1313-T02-A 1
Co EaFa-L09-1313-T03-A 1
Co EaFa-L09-1313-T04-A 1
Co EaFa-L09-1313-T05-A 1
Co EaFa-L09-1313-T06-A 1
Co EaFa-L09-1313-T07-A 1
Co EaFa-L09-1313-T08-A 1
Co EaFa-L09-1313-T09-A 1
Co EaFa-L09-1313-T01-B 1
Co EaFa-L09-1313-T02-B 1
Co EaFa-L09-1313-T03-B 1
Co EaFa-L09-1313-T04-B 1
Co EaFa-L09-1313-T05-B 1
Co EaFa-L09-1313-T06-B 1
Co EaFa-L09-1313-T07-B 1
Co EaFa-L09-1313-T08-B 1
Co EaFa-L09-1313-T09-B 1
Co EaFa-L09-1313-T01-C 1
Co EaFa-L09-1313-T02-C 1
Co EaFa-L09-1313-T03-C 1
Co EaFa-L09-1313-T04-C 1
Co EaFa-L09-1313-T05-C 1
Co EaFa-L09-1313-T06-C 1
Co EaFa-L09-1313-T07-C 1
Co EaFa-L09-1313-T08-C 1
Co EaFa-L09-1313-T09-C 1
Co EaFa-L09-1313-B01-A 1
Co EaFa-L09-1313-B02-A 1
Co EaFa-L09-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
8.06E+00
6.17E+01
2.45E+02
2.46E+02
3.91 E+02
9.00E-01 U1/2
9.00E-01 U1/2
2.53E+00 E
2.55E+00 E
3.86E+00 E
4.63E+01
2.31 E+02
2.46E+02
3.91 E+02
9.00E-01 U1/2
9.00E-01 U1/2
1.92E+00 E
2.62E+00 E
6.25E+00
3.19E+01
2.35E+02
2.44E+02
3.86E+02
2.27E+00 E
9.00E-01 U1/2
3.46E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.6E+02 1.80E+00 5.72E+00
9.00E-01 1.9E+02 1.80E+00 5.72E+00
9.00E-01 5.9E+01 1.80E+00 5.72E+00 10 325
9.00E-01 1.0E+02 1.80E+00 5.72E+00
8.06E+00 3.6E+01 1.80E+00 5.72E+00
6.17E+01 3.1E+00 1.80E+00 5.72E+00
2.45E+02 5.7E-01 1.80E+00 5.72E+00
2.46E+02 1.3E+00 1.80E+00 5.72E+00
3.91 E+02 3.9E-01 1.80E+00 5.72E+00
9.00E-01 5.0E+01 1.80E+00 5.72E+00
9.00E-01 2.2E+02 1.80E+00 5.72E+00
2.53E+00 3.5E+01 1.80E+00 5.72E+00 10 325
2.55E+00 6.4E+01 1.80E+00 5.72E+00
3.86E+00 2.1E+01 1.80E+00 5.72E+00
4.63E+01 2.1E+00 1.80E+00 5.72E+00
2.31 E+02 1.0E+00 1.80E+00 5.72E+00
2.46E+02 6.1E-01 1.80E+00 5.72E+00
3.91 E+02 4.1E-01 1.80E+00 5.72E+00
9.00E-01 2.3E+02 1.80E+00 5.72E+00
9.00E-01 7.2E+01 1.80E+00 5.72E+00
1.92E+00 1.1 E+02 1.80E+00 5.72E+00 10 325
2.62E+00 7.2E+01 1.80E+00 5.72E+00
6.25E+00 2.1E+01 1.80E+00 5.72E+00
3.19E+01 7.6E+00 1.80E+00 5.72E+00
2.35E+02 1.6E+00 1.80E+00 5.72E+00
2.44E+02 3.4E-01 1.80E+00 5.72E+00
3.86E+02 2.6E-01 1.80E+00 5.72E+00
2.27E+00 2.6E+01 1.80E+00 5.72E+00
9.00E-01 2.4E+02 1.80E+00 5.72E+00
3.46E+00 9.1E+01 1.80E+00 5.72E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.38E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.28E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.30E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:57 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:58 AM L09 131 3-1 31 6 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/10 11:01 AML09 1313-1316 EaFA
6/11/10 11:03 AM L09 1313-1316 EaFA
6/11/10 11:15 AM L09 1313-1316 EaFA
6/11/10 11:16 AM L09 1313-1316 EaFA
6/11/10 11:18 AM L09 1313-1316 EaFA
6/11/10 11:20 AM L09 1313-1316 EaFA
6/11/10 11:21 AML09 1313-1316 EaFA
6/11/10 11:23 AM L09 1313-1316 EaFA
6/11/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/11/10 10:45 AM L09 1313-1316 EaFA
6/11/10 10:46 AM L09 1313-1316 EaFA
6/11/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-216
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFa-L09-1313-T01-A 1
Cu EaFa-L09-1313-T02-A 1
Cu EaFa-L09-1313-T03-A 1
Cu EaFa-L09-1313-T04-A 1
Cu EaFa-L09-1313-T05-A 1
Cu EaFa-L09-1313-T06-A 1
Cu EaFa-L09-1313-T07-A 1
Cu EaFa-L09-1313-T08-A 1
Cu EaFa-L09-1313-T09-A 1
Cu EaFa-L09-1313-T01-B 1
Cu EaFa-L09-1313-T02-B 1
Cu EaFa-L09-1313-T03-B 1
Cu EaFa-L09-1313-T04-B 1
Cu EaFa-L09-1313-T05-B 1
Cu EaFa-L09-1313-T06-B 1
Cu EaFa-L09-1313-T07-B 1
Cu EaFa-L09-1313-T08-B 1
Cu EaFa-L09-1313-T09-B 1
Cu EaFa-L09-1313-T01-C 1
Cu EaFa-L09-1313-T02-C 1
Cu EaFa-L09-1313-T03-C 1
Cu EaFa-L09-1313-T04-C 1
Cu EaFa-L09-1313-T05-C 1
Cu EaFa-L09-1313-T06-C 1
Cu EaFa-L09-1313-T07-C 1
Cu EaFa-L09-1313-T08-C 1
Cu EaFa-L09-1313-T09-C 1
Cu EaFa-L09-1313-B01-A 1
Cu EaFa-L09-1313-B02-A 1
Cu EaFa-L09-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L
4.41E+01
4.10E+00 E
6.47E+00 E
7.27E+00 E
1.07E+01 E
1.01E+01 E
3.42E+02
2.40E+03
3.06E+03
4.44E+01
7.86E+00 E
6.81 E+00 E
7.65E+00 E
9.09E+00 E
9.76E+00 E
4.25E+02
2.45E+03
3.06E+03
4.60E+01
7.99E+00 E
4.03E+00 E
7.54E+00 E
7.53E+00 E
1.11E+01 E
3.78E+02
2.38E+03
3.03E+03
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.41E+01 5.2E+00 3.70E+00 1.18E+01
4.10E+00 2.9E+01 3.70E+00 1.18E+01
6.47E+00 2.5E+01 3.70E+00 1.18E+01 10 325
7.27E+00 7.1E+01 3.70E+00 1.18E+01
1.07E+01 1.9E+01 3.70E+00 1.18E+01
1.01E+01 5.4E+01 3.70E+00 1.18E+01
3.42E+02 6.1E-01 3.70E+00 1.18E+01
2.40E+03 1.4E+00 3.70E+00 1.18E+01
3.06E+03 6.6E-01 3.70E+00 1.18E+01
4.44E+01 4.8E+00 3.70E+00 1.18E+01
7.86E+00 4.0E+01 3.70E+00 1.18E+01
6.81E+00 5.8E+01 3.70E+00 1.18E+01 10 325
7.65E+00 2.2E+01 3.70E+00 1.18E+01
9.09E+00 4.2E+01 3.70E+00 1.18E+01
9.76E+00 3.4E+01 3.70E+00 1.18E+01
4.25E+02 1.9E+00 3.70E+00 1.18E+01
2.45E+03 7.6E-01 3.70E+00 1.18E+01
3.06E+03 6.6E-01 3.70E+00 1.18E+01
4.60E+01 7.2E+00 3.70E+00 1.18E+01
7.99E+00 1.8E+01 3.70E+00 1.18E+01
4.03E+00 1.9E+01 3.70E+00 1.18E+01 10 325
7.54E+00 1.7E+01 3.70E+00 1.18E+01
7.53E+00 6.4E+01 3.70E+00 1.18E+01
1.11E+01 3.9E+01 3.70E+00 1.18E+01
3.78E+02 7.2E-01 3.70E+00 1.18E+01
2.38E+03 3.9E-01 3.70E+00 1.18E+01
3.03E+03 9.4E-01 3.70E+00 1.18E+01
1.85E+00 1.9E+02 3.70E+00 1.18E+01
1.85E+00 1.0E+02 3.70E+00 1.18E+01
1.85E+00 2.3E+02 3.70E+00 1.18E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.31E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.23E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.26E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:57 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:58 AM L09 131 3-1 31 6 EaFA
6/11/10 11:OOAML091313-1316EaFA
6/11/10 11:01 AM L09 131 3-1 31 6 EaFA
6/11/10 11:03 AM L09 1313-1316 EaFA
6/11/10 11:15 AM L09 1313-1316 EaFA
6/11/10 11:16 AM L09 1313-1316 EaFA
6/11/10 11:18 AM L09 1313-1316 EaFA
6/11/10 11:20 AM L09 1313-1316 EaFA
6/11/10 11:21 AML09 1313-1316 EaFA
6/11/10 11:23 AM L09 1313-1316 EaFA
6/11/10 11:24 AM L09 1313-1316 EaFA
6/11/10 11:26 AM L09 1313-1316 EaFA
6/11/10 11:28 AM L09 1313-1316 EaFA
6/11/10 11:34 AM L09 1313-1316 EaFA
6/11/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/11/10 11:39 AM L09 1313-1316 EaFA
6/11/10 11:41 AM L09 1313-1316 EaFA
6/11/10 11:43 AM L09 1313-1316 EaFA
6/11/10 11:44 AM L09 1313-1316 EaFA
6/11/10 11:46 AM L09 1313-1316 EaFA
6/11/10 11:48 AM L09 1313-1316 EaFA
6/11/10 10:45 AM L09 1313-1316 EaFA
6/11/10 10:46 AM L09 1313-1316 EaFA
6/11/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-217
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFa-L09-1313-T01-A 1
Fe EaFa-L09-1313-T02-A 1
Fe EaFa-L09-1313-T03-A 1
Fe EaFa-L09-1313-T04-A 1
Fe EaFa-L09-1313-T05-A 1
Fe EaFa-L09-1313-T06-A 1
Fe EaFa-L09-1313-T07-A 1
Fe EaFa-L09-1313-T08-A 1
Fe EaFa-L09-1313-T09-A 1
Fe EaFa-L09-1313-T01-B 1
Fe EaFa-L09-1313-T02-B 1
Fe EaFa-L09-1313-T03-B 1
Fe EaFa-L09-1313-T04-B 1
Fe EaFa-L09-1313-T05-B 1
Fe EaFa-L09-1313-T06-B 1
Fe EaFa-L09-1313-T07-B 1
Fe EaFa-L09-1313-T08-B 1
Fe EaFa-L09-1313-T09-B 1
Fe EaFa-L09-1313-T01-C 1
Fe EaFa-L09-1313-T02-C 1
Fe EaFa-L09-1313-T03-C 1
Fe EaFa-L09-1313-T04-C 1
Fe EaFa-L09-1313-T05-C 1
Fe EaFa-L09-1313-T06-C 1
Fe EaFa-L09-1313-T07-C 1
Fe EaFa-L09-1313-T08-C 1
Fe EaFa-L09-1313-T09-C 1
Fe EaFa-L09-1313-B01-A 1
Fe EaFa-L09-1313-B02-A 1
Fe EaFa-L09-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L
4.74E+01
2.96E+01
3.62E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.98E+03
3.11E+04
5.27E+01
3.35E+01
3.99E+00 E
4.81 E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
2.53E+00 E
3.21 E+03
3.10E+04
5.10E+01
3.20E+01
3.96E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.30E+00 E
3.03E+03
3.05E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.74E+01 1.9E+00 2.00E+00 6.40E+00
2.96E+01 1.2E+00 2.00E+00 6.40E+00
3.62E+00 5.4E+00 2.00E+00 6.40E+00 1000 100
1.00E+00 6.8E+02 2.00E+00 6.40E+00
1.00E+00 5.6E+03 2.00E+00 6.40E+00
1.00E+00 6.9E+01 2.00E+00 6.40E+00
1.00E+00 3.1E+01 2.00E+00 6.40E+00
2.98E+03 8.7E-01 2.00E+00 6.40E+00
3.11E+04 2.1E-01 2.00E+00 6.40E+00
5.27E+01 2.9E+00 2.00E+00 6.40E+00
3.35E+01 9.2E-01 2.00E+00 6.40E+00
3.99E+00 8.3E+00 2.00E+00 6.40E+00 1000 100
4.81 E+00 3.0E+00 2.00E+00 6.40E+00
1.00E+00 7.1E+01 2.00E+00 6.40E+00
1.00E+00 4.3E+01 2.00E+00 6.40E+00
2.53E+00 1.4E+01 2.00E+00 6.40E+00
3.21E+03 2.8E-01 2.00E+00 6.40E+00
3.10E+04 5.9E-01 2.00E+00 6.40E+00
5.10E+01 7.1E-01 2.00E+00 6.40E+00
3.20E+01 1.0E+00 2.00E+00 6.40E+00
3.96E+00 3.7E+00 2.00E+00 6.40E+00 1000 100
1.00E+00 2.5E+01 2.00E+00 6.40E+00
1.00E+00 7.9E+01 2.00E+00 6.40E+00
1.00E+00 1.2E+02 2.00E+00 6.40E+00
2.30E+00 1.4E+01 2.00E+00 6.40E+00
3.03E+03 7.4E-01 2.00E+00 6.40E+00
3.05E+04 4.0E-01 2.00E+00 6.40E+00
1.00E+00 5.1E+02 2.00E+00 6.40E+00
1.00E+00 6.5E+01 2.00E+00 6.40E+00
1.00E+00 1.9E+01 2.00E+00 6.40E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .04E+03 1 04% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-218
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFa-L09-1313-T01-A 1
Pb EaFa-L09-1313-T02-A 1
Pb EaFa-L09-1313-T03-A 1
Pb EaFa-L09-1313-T04-A 1
Pb EaFa-L09-1313-T05-A 1
Pb EaFa-L09-1313-T06-A 1
Pb EaFa-L09-1313-T07-A 1
Pb EaFa-L09-1313-T08-A 1
Pb EaFa-L09-1313-T09-A 1
Pb EaFa-L09-1313-T01-B 1
Pb EaFa-L09-1313-T02-B 1
Pb EaFa-L09-1313-T03-B 1
Pb EaFa-L09-1313-T04-B 1
Pb EaFa-L09-1313-T05-B 1
Pb EaFa-L09-1313-T06-B 1
Pb EaFa-L09-1313-T07-B 1
Pb EaFa-L09-1313-T08-B 1
Pb EaFa-L09-1313-T09-B 1
Pb EaFa-L09-1313-T01-C 1
Pb EaFa-L09-1313-T02-C 1
Pb EaFa-L09-1313-T03-C 1
Pb EaFa-L09-1313-T04-C 1
Pb EaFa-L09-1313-T05-C 1
Pb EaFa-L09-1313-T06-C 1
Pb EaFa-L09-1313-T07-C 1
Pb EaFa-L09-1313-T08-C 1
Pb EaFa-L09-1313-T09-C 1
Pb EaFa-L09-1313-B01-A 1
Pb EaFa-L09-1313-B02-A 1
Pb EaFa-L09-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L
7.72E+00 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
6.92E+01
1.62E+01 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
6.69E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
6.87E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.72E+00 2.1E+02 6.80E+00 2.16E+01
3.40E+00 8.2E+02 6.80E+00 2.16E+01
3.40E+00 6.6E+01 6.80E+00 2.16E+01 10 325
3.40E+00 3.4E+01 6.80E+00 2.16E+01
3.40E+00 3.7E+02 6.80E+00 2.16E+01
3.40E+00 5.7E+02 6.80E+00 2.16E+01
3.40E+00 6.8E+01 6.80E+00 2.16E+01
3.40E+00 4.3E+01 6.80E+00 2.16E+01
6.92E+01 6.3E+00 6.80E+00 2.16E+01
1.62E+01 3.7E+01 6.80E+00 2.16E+01
3.40E+00 6.2E+01 6.80E+00 2.16E+01
3.40E+00 2.4E+02 6.80E+00 2.16E+01 10 325
3.40E+00 6.4E+01 6.80E+00 2.16E+01
3.40E+00 5.0E+01 6.80E+00 2.16E+01
3.40E+00 8.6E+01 6.80E+00 2.16E+01
3.40E+00 1.6E+02 6.80E+00 2.16E+01
3.40E+00 2.4E+01 6.80E+00 2.16E+01
6.69E+01 9.1E+00 6.80E+00 2.16E+01
3.40E+00 1.3E+03 6.80E+00 2.16E+01
3.40E+00 4.6E+01 6.80E+00 2.16E+01
3.40E+00 2.9E+02 6.80E+00 2.16E+01 10 325
3.40E+00 8.2E+01 6.80E+00 2.16E+01
3.40E+00 2.2E+04 6.80E+00 2.16E+01
3.40E+00 9.6E+01 6.80E+00 2.16E+01
3.40E+00 1.6E+02 6.80E+00 2.16E+01
3.40E+00 8.0E+01 6.80E+00 2.16E+01
6.87E+01 8.3E+00 6.80E+00 2.16E+01
3.40E+00 2.0E+03 6.80E+00 2.16E+01
3.40E+00 6.5E+01 6.80E+00 2.16E+01
3.40E+00 3.6E+02 6.80E+00 2.16E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.35E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.23E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.27E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/11/1011 :43 AM L09 1 31 3-1 31 6 EaFA
6/11/1011 :44 AM L09 1 31 3-1 31 6 EaFA
6/11/1011 :46 AM L09 1 31 3-1 31 6 EaFA
6/11/1011 :48 AM L09 1 31 3-1 31 6 EaFA
6/11/10 10:45 AM L09 1313-1316 EaFA
6/11/10 10:46 AM L09 1313-1316 EaFA
6/11/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-219
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFa-L09-1313-T01-A 1
Li EaFa-L09-1313-T02-A 1
Li EaFa-L09-1313-T03-A 1
Li EaFa-L09-1313-T04-A 1
Li EaFa-L09-1313-T05-A 1
Li EaFa-L09-1313-T06-A 1
Li EaFa-L09-1313-T07-A 1
Li EaFa-L09-1313-T08-A 1
Li EaFa-L09-1313-T09-A 1
Li EaFa-L09-1313-T01-B 1
Li EaFa-L09-1313-T02-B 1
Li EaFa-L09-1313-T03-B 1
Li EaFa-L09-1313-T04-B 1
Li EaFa-L09-1313-T05-B 1
Li EaFa-L09-1313-T06-B 1
Li EaFa-L09-1313-T07-B 1
Li EaFa-L09-1313-T08-B 1
Li EaFa-L09-1313-T09-B 1
Li EaFa-L09-1313-T01-C 1
Li EaFa-L09-1313-T02-C 1
Li EaFa-L09-1313-T03-C 1
Li EaFa-L09-1313-T04-C 1
Li EaFa-L09-1313-T05-C 1
Li EaFa-L09-1313-T06-C 1
Li EaFa-L09-1313-T07-C 1
Li EaFa-L09-1313-T08-C 1
Li EaFa-L09-1313-T09-C 1
Li EaFa-L09-1313-B01-A 1
Li EaFa-L09-1313-B02-A 1
Li EaFa-L09-1313-B03-A 1
Sample I
Cone. Qualifier 1
ug/L 1
2.30E+03
3.03E+03
3.53E+03
3.71 E+03
3.99E+03
4.18E+03
3.85E+03
2.34E+03
1.86E+03
2.40E+03
3.09E+03
3.41 E+03
3.40E+03
3.84E+03
4.12E+03
3.78E+03
2.31 E+03
1.85E+03
2.40E+03
2.99E+03
3.23E+03
3.37E+03
3.68E+03
3.98E+03
3.75E+03
2.29E+03
1.82E+03
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+03 7.5E-01 1.90E+00 6.00E+00
3.03E+03 1.4E+00 1.90E+00 6.00E+00
3.53E+03 5.4E-01 1.90E+00 6.00E+00 10 325
3.71 E+03 7.6E-01 1.90E+00 6.00E+00
3.99E+03 7.0E-01 1.90E+00 6.00E+00
4.18E+03 2.7E-01 1.90E+00 6.00E+00
3.85E+03 4.7E-01 1.90E+00 6.00E+00
2.34E+03 5.3E-01 1.90E+00 6.00E+00
1.86E+03 9.0E-01 1.90E+00 6.00E+00
2.40E+03 1.1E+00 1.90E+00 6.00E+00
3.09E+03 4.6E-01 1.90E+00 6.00E+00
3.41 E+03 1.8E+00 1.90E+00 6.00E+00 10 325
3.40E+03 3.5E-01 1.90E+00 6.00E+00
3.84E+03 5.9E-01 1.90E+00 6.00E+00
4.12E+03 6.1E-01 1.90E+00 6.00E+00
3.78E+03 1.0E-01 1.90E+00 6.00E+00
2.31 E+03 9.7E-01 1.90E+00 6.00E+00
1.85E+03 5.1E-01 1.90E+00 6.00E+00
2.40E+03 8.2E-01 1.90E+00 6.00E+00
2.99E+03 2.1E-01 1.90E+00 6.00E+00
3.23E+03 5.8E-01 1.90E+00 6.00E+00 10 325
3.37E+03 7.8E-01 1.90E+00 6.00E+00
3.68E+03 3.1E-01 1.90E+00 6.00E+00
3.98E+03 3.4E-01 1.90E+00 6.00E+00
3.75E+03 8.3E-01 1.90E+00 6.00E+00
2.29E+03 2.5E-01 1.90E+00 6.00E+00
1.82E+03 8.0E-01 1.90E+00 6.00E+00
9.50E-01 1.1E+02 1.90E+00 6.00E+00
9.50E-01 2.4E+02 1.90E+00 6.00E+00
9.50E-01 7.4E+02 1.90E+00 6.00E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.60E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.41 E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.32E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 1 0:53 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:57 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:58 AM L09 131 3-1 31 6 EaFA
6/11/10 11:OOAML091313-1316EaFA
6/11/10 11:01 AM L09 131 3-1 31 6 EaFA
6/11/10 11:03AML091313-1316EaFA
6/11/10 11:15 AM L09 1313-1316 EaFA
6/11/10 11:16 AM L09 1313-1316 EaFA
6/11/10 11:18 AM L09 1313-1316 EaFA
6/11/10 11:20AML091313-1316EaFA
6/11/10 11:21 AM L09 131 3-1 31 6 EaFA
6/11/10 11:23AML091313-1316EaFA
6/11/10 11:24AML091313-1316EaFA
6/11/10 11:26AML091313-1316EaFA
6/11/10 11:28AML091313-1316EaFA
6/11/10 11:34AML091313-1316EaFA
6/11/10 11:36AML091313-1316EaFA
6/11/10 11:38AML091313-1316EaFA
6/11/10 11:39AML091313-1316EaFA
6/11/10 11:41 AM L09 131 3-1 31 6 EaFA
6/11/10 11:43AML091313-1316EaFA
6/11/10 11:44AML091313-1316EaFA
6/11/10 11:46AML091313-1316EaFA
6/11/10 11:48AML091313-1316EaFA
6/11/10 1 0:45 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:46 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:48 AM L09 131 3-1 31 6 EaFA
                                                                                                                                                                          1-220
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFa-L09-1313-T01-A 1
Mn EaFa-L09-1313-T02-A 1
Mn EaFa-L09-1313-T03-A 1
Mn EaFa-L09-1313-T04-A 1
Mn EaFa-L09-1313-T05-A 1
Mn EaFa-L09-1313-T06-A 1
Mn EaFa-L09-1313-T07-A 1
Mn EaFa-L09-1313-T08-A 1
Mn EaFa-L09-1313-T09-A 1
Mn EaFa-L09-1313-T01-B 1
Mn EaFa-L09-1313-T02-B 1
Mn EaFa-L09-1313-T03-B 1
Mn EaFa-L09-1313-T04-B 1
Mn EaFa-L09-1313-T05-B 1
Mn EaFa-L09-1313-T06-B 1
Mn EaFa-L09-1313-T07-B 1
Mn EaFa-L09-1313-T08-B 1
Mn EaFa-L09-1313-T09-B 1
Mn EaFa-L09-1313-T01-C 1
Mn EaFa-L09-1313-T02-C 1
Mn EaFa-L09-1313-T03-C 1
Mn EaFa-L09-1313-T04-C 1
Mn EaFa-L09-1313-T05-C 1
Mn EaFa-L09-1313-T06-C 1
Mn EaFa-L09-1313-T07-C 1
Mn EaFa-L09-1313-T08-C 1
Mn EaFa-L09-1313-T09-C 1
Mn EaFa-L09-1313-B01-A 1
Mn EaFa-L09-1313-B02-A 1
Mn EaFa-L09-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.35E+00 E
8.56E+01
4.51 E+02
9.80E+02
1.40E+03
1.74E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
5.03E+00 E
3.73E+01
3.57E+02
9.73E+02
1 .40E+03
1 J4E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.06E+00 E
4.28E+01
2.91 E+02
9.75E+02
1.38E+03
1.73E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.3E+00 2.00E+00 6.40E+00
1.00E+00 1.3E+02 2.00E+00 6.40E+00
1.00E+00 5.6E+01 2.00E+00 6.40E+00 10 325
4.35E+00 8.9E+00 2.00E+00 6.40E+00
8.56E+01 1.1E+00 2.00E+00 6.40E+00
4.51 E+02 4.1E-01 2.00E+00 6.40E+00
9.80E+02 1.2E+00 2.00E+00 6.40E+00
1.40E+03 3.9E-01 2.00E+00 6.40E+00
1.74E+03 7.2E-01 2.00E+00 6.40E+00
1.00E+00 1.0E+01 2.00E+00 6.40E+00
1.00E+00 2.0E+01 2.00E+00 6.40E+00
1.00E+00 7.9E+03 2.00E+00 6.40E+00 10 325
5.03E+00 4.6E+00 2.00E+00 6.40E+00
3.73E+01 1.2E+00 2.00E+00 6.40E+00
3.57E+02 1.1E+00 2.00E+00 6.40E+00
9.73E+02 8.4E-01 2.00E+00 6.40E+00
1.40E+03 4.9E-01 2.00E+00 6.40E+00
1.74E+03 2.0E-01 2.00E+00 6.40E+00
1.00E+00 1.9E+01 2.00E+00 6.40E+00
1.00E+00 1.6E+01 2.00E+00 6.40E+00
1.00E+00 5.2E+02 2.00E+00 6.40E+00 10 325
4.06E+00 4.0E+00 2.00E+00 6.40E+00
4.28E+01 5.0E-01 2.00E+00 6.40E+00
2.91 E+02 1.0E+00 2.00E+00 6.40E+00
9.75E+02 9.1E-01 2.00E+00 6.40E+00
1.38E+03 1.5E-01 2.00E+00 6.40E+00
1.73E+03 6.8E-01 2.00E+00 6.40E+00
1.00E+00 4.3E+01 2.00E+00 6.40E+00
1.00E+00 5.3E+01 2.00E+00 6.40E+00
1.00E+00 2.6E+02 2.00E+00 6.40E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.59E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.47E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.49E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-221
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFa-L09-1313-T01-A 1
Mg EaFa-L09-1313-T02-A 1
Mg EaFa-L09-1313-T03-A 1
Mg EaFa-L09-1313-T04-A 1
Mg EaFa-L09-1313-T05-A 1
Mg EaFa-L09-1313-T06-A 1
Mg EaFa-L09-1313-T07-A 1
Mg EaFa-L09-1313-T08-A 1
Mg EaFa-L09-1313-T09-A 1
Mg EaFa-L09-1313-T01-B 1
Mg EaFa-L09-1313-T02-B 1
Mg EaFa-L09-1313-T03-B 1
Mg EaFa-L09-1313-T04-B 1
Mg EaFa-L09-1313-T05-B 1
Mg EaFa-L09-1313-T06-B 1
Mg EaFa-L09-1313-T07-B 1
Mg EaFa-L09-1313-T08-B 1
Mg EaFa-L09-1313-T09-B 1
Mg EaFa-L09-1313-T01-C 1
Mg EaFa-L09-1313-T02-C 1
Mg EaFa-L09-1313-T03-C 1
Mg EaFa-L09-1313-T04-C 1
Mg EaFa-L09-1313-T05-C 1
Mg EaFa-L09-1313-T06-C 1
Mg EaFa-L09-1313-T07-C 1
Mg EaFa-L09-1313-T08-C 1
Mg EaFa-L09-1313-T09-C 1
Mg EaFa-L09-1313-B01-A 1
Mg EaFa-L09-1313-B02-A 1
Mg EaFa-L09-1313-B03-A 1
Sample I
Cone. Qualifier 1
ug/L 1
5.00E-01 U1/2
5.00E-01 U1/2
4.12E+02
3.72E+03
6.32E+03
8.03E+03
8.92E+03
1.01E+04
1.46E+04
5.00E-01 U1/2
5.00E-01 U1/2
3.57E+02
3.80E+03
5.69E+03
8.12E+03
8.57E+03
1.02E+04
1 .44E+04
5.00E-01 U1/2
5.00E-01 U1/2
3.19E+02
3.92E+03
5.52E+03
8.04E+03
8.57E+03
9.91 E+03
1 .43E+04
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 1.9E+01 1.00E+00 3.18E+00
5.00E-01 4.0E+01 1.00E+00 3.18E+00
4.12E+02 5.4E-01 1.00E+00 3.18E+00 1000 100
3.72E+03 1.0E+00 1.00E+00 3.18E+00
6.32E+03 1.9E+00 1.00E+00 3.18E+00
8.03E+03 1.7E-01 1.00E+00 3.18E+00
8.92E+03 6.5E-01 1.00E+00 3.18E+00
1.01E+04 1.2E+00 1.00E+00 3.18E+00
1.46E+04 9.8E-01 1.00E+00 3.18E+00
5.00E-01 1.4E+02 1.00E+00 3.18E+00
5.00E-01 2.1E+01 1.00E+00 3.18E+00
3.57E+02 4.3E+00 1.00E+00 3.18E+00 1000 100
3.80E+03 1.3E+00 1.00E+00 3.18E+00
5.69E+03 1.3E-01 1.00E+00 3.18E+00
8.12E+03 6.6E-01 1.00E+00 3.18E+00
8.57E+03 5.5E-01 1.00E+00 3.18E+00
1.02E+04 1.2E+00 1.00E+00 3.18E+00
1.44E+04 6.7E-01 1.00E+00 3.18E+00
5.00E-01 6.5E+01 1.00E+00 3.18E+00
5.00E-01 6.6E+01 1.00E+00 3.18E+00
3.19E+02 1.9E+00 1.00E+00 3.18E+00 1000 100
3.92E+03 9.0E-01 1.00E+00 3.18E+00
5.52E+03 5.5E-01 1.00E+00 3.18E+00
8.04E+03 6.8E-01 1.00E+00 3.18E+00
8.57E+03 1.1E+00 1.00E+00 3.18E+00
9.91E+03 5.7E-01 1 .OOE+00 3.18E+00
1.43E+04 6.9E-01 1 .OOE+00 3.18E+00
5.00E-01 5.2E+01 1 .OOE+00 3.18E+00
5.00E-01 5.4E+01 1 .OOE+00 3.18E+00
5.00E-01 3.8E+01 1 .OOE+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .49E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .40E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .40E+03 1 08% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:57 AM L09 131 3-1 31 6 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/10 11:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1/10 10:45 AM L09 1313-1316 EaFA
6/1 1/10 10:46 AM L09 1313-1316 EaFA
6/1 1/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-222
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo EaFa-L09-1313-T01-A 1
Mo EaFa-L09-1313-T02-A 1
Mo EaFa-L09-1313-T03-A 1
Mo EaFa-L09-1313-T04-A 1
Mo EaFa-L09-1313-T05-A 1
Mo EaFa-L09-1313-T06-A 1
Mo EaFa-L09-1313-T07-A 1
Mo EaFa-L09-1313-T08-A 1
Mo EaFa-L09-1313-T09-A 1
Mo EaFa-L09-1313-T01-B 1
Mo EaFa-L09-1313-T02-B 1
Mo EaFa-L09-1313-T03-B 1
Mo EaFa-L09-1313-T04-B 1
Mo EaFa-L09-1313-T05-B 1
Mo EaFa-L09-1313-T06-B 1
Mo EaFa-L09-1313-T07-B 1
Mo EaFa-L09-1313-T08-B 1
Mo EaFa-L09-1313-T09-B 1
Mo EaFa-L09-1313-T01-C 1
Mo EaFa-L09-1313-T02-C 1
Mo EaFa-L09-1313-T03-C 1
Mo EaFa-L09-1313-T04-C 1
Mo EaFa-L09-1313-T05-C 1
Mo EaFa-L09-1313-T06-C 1
Mo EaFa-L09-1313-T07-C 1
Mo EaFa-L09-1313-T08-C 1
Mo EaFa-L09-1313-T09-C 1
Mo EaFa-L09-1313-B01-A 1
Mo EaFa-L09-1313-B02-A 1
Mo EaFa-L09-1313-B03-A 1
Sample I
Cone. Qualifier 1
ug/L 1
4.32E+03
4.32E+03
4.17E+03
3.98E+03
3.78E+03
3.35E+03
2.57E+02
8.92E+01
3.14E+02
4.61 E+03
4.39E+03
4.07E+03
3.89E+03
3.81 E+03
3.48E+03
2.47E+02
9.21E+01
3.33E+02
4.48E+03
4.18E+03
3.83E+03
3.80E+03
3.63E+03
3.45E+03
2.68E+02
9.17E+01
3.27E+02
6.00E-01 U1/2
6.00E-01 U1/2
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.32E+03 1.8E+00 1.20E+00 3.82E+00
4.32E+03 5.6E-01 1.20E+00 3.82E+00
4.17E+03 9.9E-01 1.20E+00 3.82E+00 10 325
3.98E+03 1.7E+00 1.20E+00 3.82E+00
3.78E+03 5.6E-01 1.20E+00 3.82E+00
3.35E+03 5.7E-01 1.20E+00 3.82E+00
2.57E+02 1.5E+00 1.20E+00 3.82E+00
8.92E+01 2.9E+00 1.20E+00 3.82E+00
3.14E+02 5.1E-01 1.20E+00 3.82E+00
4.61 E+03 2.2E+00 1.20E+00 3.82E+00
4.39E+03 1.0E+00 1.20E+00 3.82E+00
4.07E+03 2.0E+00 1.20E+00 3.82E+00 10 325
3.89E+03 1.1E+00 1.20E+00 3.82E+00
3.81 E+03 1.4E+00 1.20E+00 3.82E+00
3.48E+03 5.9E-01 1.20E+00 3.82E+00
2.47E+02 9.7E-01 1 .20E+00 3.82E+00
9.21 E+01 2.1E+00 1.20E+00 3.82E+00
3.33E+02 1.8E-01 1 .20E+00 3.82E+00
4.48E+03 1.1E+00 1 .20E+00 3.82E+00
4.18E+03 1.4E+00 1 .20E+00 3.82E+00
3.83E+03 6.9E-01 1.20E+00 3.82E+00 10 325
3.80E+03 1.1E+00 1.20E+00 3.82E+00
3.63E+03 8.5E-01 1.20E+00 3.82E+00
3.45E+03 1.1E+00 1.20E+00 3.82E+00
2.68E+02 8.5E-01 1.20E+00 3.82E+00
9.17E+01 2.9E+00 1.20E+00 3.82E+00
3.27E+02 6.2E-01 1.20E+00 3.82E+00
6.00E-01 3.7E+01 1.20E+00 3.82E+00
6.00E-01 6.5E+01 1.20E+00 3.82E+00
6.00E-01 2.0E+02 1.20E+00 3.82E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.37E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.23E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.17E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1/10 10:45 AM L09 1313-1316 EaFA
6/1 1/10 10:46 AM L09 1313-1316 EaFA
6/1 1/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-223
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFa-L09-1313-T01-A 1
Ni EaFa-L09-1313-T02-A 1
Ni EaFa-L09-1313-T03-A 1
Ni EaFa-L09-1313-T04-A 1
Ni EaFa-L09-1313-T05-A 1
Ni EaFa-L09-1313-T06-A 1
Ni EaFa-L09-1313-T07-A 1
Ni EaFa-L09-1313-T08-A 1
Ni EaFa-L09-1313-T09-A 1
Ni EaFa-L09-1313-T01-B 1
Ni EaFa-L09-1313-T02-B 1
Ni EaFa-L09-1313-T03-B 1
Ni EaFa-L09-1313-T04-B 1
Ni EaFa-L09-1313-T05-B 1
Ni EaFa-L09-1313-T06-B 1
Ni EaFa-L09-1313-T07-B 1
Ni EaFa-L09-1313-T08-B 1
Ni EaFa-L09-1313-T09-B 1
Ni EaFa-L09-1313-T01-C
Ni EaFa-L09-1313-T02-C
Ni EaFa-L09-1313-T03-C
Ni EaFa-L09-1313-T04-C
Ni EaFa-L09-1313-T05-C
Ni EaFa-L09-1313-T06-C
Ni EaFa-L09-1313-T07-C
Ni EaFa-L09-1313-T08-C
Ni EaFa-L09-1313-T09-C
Ni EaFa-L09-1313-B01-A
Ni EaFa-L09-1313-B02-A
Ni EaFa-L09-1313-B03-A
Sample Internal
Cone. Qualifier Review
ug/L
9.00E-01 U1/2
9.00E-01 U1/2
5.26E+00 E
1.82E+00 E
2.63E+01
1.42E+02
6.14E+02
5.46E+02
7.17E+02
9.00E-01 U1/2
2.17E+00 E
9.00E-01 U1/2
5.32E+00 E
9.61 E+00
1.01E+02
6.02E+02
5.50E+02
7.16E+02
3.73E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
2.79E+00 E
1.64E+01
7.75E+01
6.04E+02
5.43E+02
7.09E+02
2.90E+00 E
2.41 E+00 E
2.36E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 7.4E+02 1.80E+00 5.70E+00
9.00E-01 1.5E+02 1.80E+00 5.70E+00
5.26E+00 1.1E+02 1.80E+00 5.70E+00 10 325
1.82E+00 2.8E+02 1.80E+00 5.70E+00
2.63E+01 2.1E+01 1.80E+00 5.70E+00
1.42E+02 1.3E+00 1.80E+00 5.70E+00
6.14E+02 3.9E-01 1.80E+00 5.70E+00
5.46E+02 7.4E-01 1.80E+00 5.70E+00
7.17E+02 6.2E-01 1.80E+00 5.70E+00
9.00E-01 4.9E+02 1.80E+00 5.70E+00
2.17E+00 1.3E+02 1.80E+00 5.70E+00
9.00E-01 6.8E+01 1.80E+00 5.70E+00 10 325
5.32E+00 5.6E+01 1.80E+00 5.70E+00
9.61 E+00 4.3E+01 1.80E+00 5.70E+00
1.01E+02 3.7E-01 1.80E+00 5.70E+00
6.02E+02 6.1E-01 1.80E+00 5.70E+00
5.50E+02 6.4E-01 1.80E+00 5.70E+00
7.16E+02 6.7E-01 1.80E+00 5.70E+00
3.73E+00 7.9E+01 1.80E+00 5.70E+00
9.00E-01 4.3E+01 1.80E+00 5.70E+00
9.00E-01 7.3E+01 1.80E+00 5.70E+00 10 325
2.79E+00 1.1E+02 1.80E+00 5.70E+00
1.64E+01 2.8E+01 1.80E+00 5.70E+00
7.75E+01 4.6E+00 1.80E+00 5.70E+00
6.04E+02 1.1 E+00 1.80E+00 5.70E+00
5.43E+02 1.0E+00 1.80E+00 5.70E+00
7.09E+02 6.8E-01 1.80E+00 5.70E+00
2.90E+00 2.7E+01 1.80E+00 5.70E+00
2.41 E+00 5.5E+01 1.80E+00 5.70E+00
2.36E+00 1.7E+02 1.80E+00 5.70E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.41E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.31E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.34E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 1 0:53 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:57 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:58 AM L09 131 3-1 31 6 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/10 11:01 AML09 1313-1316 EaFA
6/11/10 11:03 AM L09 1313-1316 EaFA
6/11/10 11:15 AM L09 1313-1316 EaFA
6/11/10 11:16 AM L09 1313-1316 EaFA
6/11/10 11:18 AM L09 1313-1316 EaFA
6/11/10 11:20 AM L09 1313-1316 EaFA
6/11/10 11:21 AML09 1313-1316 EaFA
6/11/10 11:23 AM L09 1313-1316 EaFA
6/11/10 11:24 AM L09 1313-1316 EaFA
6/11/10 11:26 AM L09 1313-1316 EaFA
6/11/10 11:28 AM L09 1313-1316 EaFA
6/11/10 11:34 AM L09 1313-1316 EaFA
6/11/10 11:36 AM L09 1313-1316 EaFA
6/11/10 11:38 AM L09 1313-1316 EaFA
6/11/10 11:39AML091313-1316EaFA
6/11/10 11:41 AM L09 131 3-1 31 6 EaFA
6/11/10 11:43AML091313-1316EaFA
6/11/10 11:44AML091313-1316EaFA
6/11/10 11:46AML091313-1316EaFA
6/11/10 11:48AML091313-1316EaFA
6/11/10 1 0:45 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:46 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:48 AM L09 131 3-1 31 6 EaFA
                                                                                                                                                                          1-224
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P EaFa-L09-1313-T01-A 1
P EaFa-L09-1313-T02-A 1
P EaFa-L09-1313-T03-A 1
P EaFa-L09-1313-T04-A 1
P EaFa-L09-1313-T05-A 1
P EaFa-L09-1313-T06-A 1
P EaFa-L09-1313-T07-A 1
P EaFa-L09-1313-T08-A 1
P EaFa-L09-1313-T09-A 1
P EaFa-L09-1313-T01-B 1
P EaFa-L09-1313-T02-B 1
P EaFa-L09-1313-T03-B 1
P EaFa-L09-1313-T04-B 1
P EaFa-L09-1313-T05-B 1
P EaFa-L09-1313-T06-B 1
P EaFa-L09-1313-T07-B 1
P EaFa-L09-1313-T08-B 1
P EaFa-L09-1313-T09-B 1
P EaFa-L09-1313-T01-C 1
P EaFa-L09-1313-T02-C 1
P EaFa-L09-1313-T03-C 1
P EaFa-L09-1313-T04-C 1
P EaFa-L09-1313-T05-C 1
P EaFa-L09-1313-T06-C 1
P EaFa-L09-1313-T07-C 1
P EaFa-L09-1313-T08-C 1
P EaFa-L09-1313-T09-C 1
P EaFa-L09-1313-B01-A 1
P EaFa-L09-1313-B02-A 1
P EaFa-L09-1313-B03-A 1
Sample I
Cone. Qualifier 1
ug/L 1
1.44E+02
4.63E+01
9.35E+01
6.76E+01
4.00E+01
1.28E+01
1.13E+01 E
3.83E+01
1.82E+03
1.48E+02
5.01 E+01
8.15E+01
6.79E+01
5.66E+01
2.71E+01
7.40E+00 E
3.48E+01
1 .89E+03
1.10E+02
5.68E+01
8.45E+01
6.76E+01
3.96E+01
2.24E+01
3.30E+01
4.16E+01
1.89E+03
4.65E+00 E
1.85E+00 U1/2
1.20E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.44E+02 1.2E+01 3.70E+00 1.18E+01
4.63E+01 3.7E+01 3.70E+00 1.18E+01
9.35E+01 7.7E+01 3.70E+00 1.18E+01 1000 100
6.76E+01 2.9E+01 3.70E+00 1.18E+01
4.00E+01 1.3E+01 3.70E+00 1.18E+01
1.28E+01 9.0E+00 3.70E+00 1.18E+01
1.13E+01 8.8E+00 3.70E+00 1.18E+01
3.83E+01 3.9E+00 3.70E+00 1.18E+01
1.82E+03 5.5E-01 3.70E+00 1.18E+01
1.48E+02 1.8E+01 3.70E+00 1.18E+01
5.01E+01 1.5E+01 3.70E+00 1.18E+01
8.15E+01 4.4E+01 3.70E+00 1.18E+01 1000 100
6.79E+01 3.2E+01 3.70E+00 1.18E+01
5.66E+01 9.4E+00 3.70E+00 1.18E+01
2.71E+01 5.6E+00 3.70E+00 1.18E+01
7.40E+00 9.2E+00 3.70E+00 1.18E+01
3.48E+01 5.0E+00 3.70E+00 1.18E+01
1.89E+03 4.6E-01 3.70E+00 1.18E+01
1.10E+02 1.7E+02 3.70E+00 1.18E+01
5.68E+01 1.0E+01 3.70E+00 1.18E+01
8.45E+01 5.4E+01 3.70E+00 1.18E+01 1000 100
6.76E+01 2.8E+01 3.70E+00 1.18E+01
3.96E+01 8.2E+00 3.70E+00 1.18E+01
2.24E+01 1.6E+00 3.70E+00 1.18E+01
3.30E+01 8.2E+00 3.70E+00 1.18E+01
4.16E+01 4.7E+00 3.70E+00 1.18E+01
1.89E+03 6.0E-01 3.70E+00 1.18E+01
4.65E+00 2.4E+00 3.70E+00 1.18E+01
1.85E+00 5.6E+00 3.70E+00 1.18E+01
1.20E+01 1.3E+01 3.70E+00 1.18E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/11/1011 :48 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-225
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
ug/L
K EaFa-L09-1313-T01-A 1 1.85E+06
K EaFa-L09-1313-T02-A 1 5.28E+05
K EaFa-L09-1313-T03-A 1 1.94E+05
K EaFa-L09-1313-T04-A 1 9.81 E+04
K EaFa-L09-1313-T05-A 1 5.94E+04
K EaFa-L09-1313-T06-A 1 2.54E+04
K EaFa-L09-1313-T07-A 1 2.48E+04
K EaFa-L09-1313-T08-A 1 1.83E+04
K EaFa-L09-1313-T09-A 1 2.14E+04
K EaFa-L09-1313-T01-B 1 1.88E+06
K EaFa-L09-1313-T02-B 1 5.19E+05
K EaFa-L09-1313-T03-B 1 1.85E+05
K EaFa-L09-1313-T04-B 1 9.53E+04
K EaFa-L09-1313-T05-B 1 6.13E+04
K EaFa-L09-1313-T06-B 1 2.56E+04
K EaFa-L09-1313-T07-B 1 2.38E+04
K EaFa-L09-1313-T08-B 1 1.81 E+04
K EaFa-L09-1313-T09-B 1 2.10E+04
K EaFa-L09-1313-T01-C 1 1 .83E+06
K EaFa-L09-1313-T02-C 1 5.03E+05
K EaFa-L09-1313-T03-C 1 1 J7E+05
K EaFa-L09-1313-T04-C 1 9.31E+04
K EaFa-L09-1313-T05-C 1 5.88E+04
K EaFa-L09-1313-T06-C 1 2.46E+04
K EaFa-L09-1313-T07-C 1 2.37E+04
K EaFa-L09-1313-T08-C 1 1.77E+04
K EaFa-L09-1313-T09-C 1 2.08E+04
K EaFa-L09-1313-B01-A 1 8.43E+01
K EaFa-L09-1313-B02-A 1 8.45E+01
K EaFa-L09-1313-B03-A 1 1.91E+06
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+06 6.3E-01 1.60E+00 5.09E+00
5.28E+05 1.2E+00 1.60E+00 5.09E+00
1.94E+05 3.3E-01 1.60E+00 5.09E+00 1000 100
9.81 E+04 8.4E-01 1.60E+00 5.09E+00
5.94E+04 5.2E-01 1.60E+00 5.09E+00
2.54E+04 5.8E-01 1.60E+00 5.09E+00
2.48E+04 1.1E+00 1.60E+00 5.09E+00
1.83E+04 1.6E-01 1.60E+00 5.09E+00
2.14E+04 1.6E-01 1.60E+00 5.09E+00
1.88E+06 1.4E+00 1.60E+00 5.09E+00
5.19E+05 6.9E-01 1.60E+00 5.09E+00
1.85E+05 2.2E+00 1.60E+00 5.09E+00 1000 100
9.53E+04 8.0E-01 1.60E+00 5.09E+00
6.13E+04 6.8E-01 1.60E+00 5.09E+00
2.56E+04 6.1E-01 1.60E+00 5.09E+00
2.38E+04 6.8E-01 1.60E+00 5.09E+00
1.81 E+04 1.6E-01 1.60E+00 5.09E+00
2.10E+04 2.2E-01 1 .60E+00 5.09E+00
1.83E+06 8.4E-01 1 .60E+00 5.09E+00
5.03E+05 2.8E-01 1 .60E+00 5.09E+00
1.77E+05 1.5E+00 1 .60E+00 5.09E+00 1000 100
9.31 E+04 4.3E-01 1.60E+00 5.09E+00
5.88E+04 7.5E-01 1.60E+00 5.09E+00
2.46E+04 1.5E-01 1.60E+00 5.09E+00
2.37E+04 1.3E+00 1.60E+00 5.09E+00
1.77E+04 8.7E-01 1.60E+00 5.09E+00
2.08E+04 1.1E-01 1.60E+00 5.09E+00
8.43E+01 4.0E+00 1.60E+00 5.09E+00
8.45E+01 5.5E+00 1.60E+00 5.09E+00
1.91E+06 9.2E-01 1.60E+00 5.09E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .94E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .86E+05 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 J8E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-226
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qu
ug/L
Se EaFa-L09-1313-T01-A 1 6.95E+03
Se EaFa-L09-1313-T02-A 1 5.79E+03
Se EaFa-L09-1313-T03-A 1 5.17E+03
Se EaFa-L09-1313-T04-A 1 3.14E+03
Se EaFa-L09-1313-T05-A 1 1.61E+03
Se EaFa-L09-1313-T06-A 1 9.55E+02
Se EaFa-L09-1313-T07-A 1 2.65E+02
Se EaFa-L09-1313-T08-A 1 1.20E+02
Se EaFa-L09-1313-T09-A 1 5.37E+02
Se EaFa-L09-1313-T01-B 1 7.37E+03
Se EaFa-L09-1313-T02-B 1 6.16E+03
Se EaFa-L09-1313-T03-B 1 5.04E+03
Se EaFa-L09-1313-T04-B 1 2.89E+03
Se EaFa-L09-1313-T05-B 1 1.86E+03
Se EaFa-L09-1313-T06-B 1 1.02E+03
Se EaFa-L09-1313-T07-B 1 2.94E+02
Se EaFa-L09-1313-T08-B 1 1.32E+02
Se EaFa-L09-1313-T09-B 1 5.71E+02
Se EaFa-L09-1313-T01-C 1 7.43E+03
Se EaFa-L09-1313-T02-C 1 5.99E+03
Se EaFa-L09-1313-T03-C 1 4.86E+03
Se EaFa-L09-1313-T04-C 1 2.87E+03
Se EaFa-L09-1313-T05-C 1 1 J7E+03
Se EaFa-L09-1313-T06-C 1 9.57E+02
Se EaFa-L09-1313-T07-C 1 2.75E+02
Se EaFa-L09-1313-T08-C 1 1.12E+02
Se EaFa-L09-1313-T09-C 1 5.53E+02
Se EaFa-L09-1313-B01-A 1 7.90E+01
Se EaFa-L09-1313-B02-A 1 8.96E+01
Se EaFa-L09-1313-B03-A 1 6.41E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.95E+03 1.3E+00 1.50E+01 4.77E+01
5.79E+03 1.9E+00 1.50E+01 4.77E+01
5.17E+03 7.9E-01 1.50E+01 4.77E+01 10 325
3.14E+03 2.5E+00 1.50E+01 4.77E+01
1.61E+03 1.8E+00 1.50E+01 4.77E+01
9.55E+02 1.0E+00 1.50E+01 4.77E+01
2.65E+02 1.7E+01 1.50E+01 4.77E+01
1.20E+02 1.0E+01 1.50E+01 4.77E+01
5.37E+02 1.4E+00 1.50E+01 4.77E+01
7.37E+03 1.5E+00 1.50E+01 4.77E+01
6.16E+03 6.6E-01 1.50E+01 4.77E+01
5.04E+03 2.6E+00 1.50E+01 4.77E+01 10 325
2.89E+03 1.1E+00 1.50E+01 4.77E+01
1.86E+03 1.3E+00 1.50E+01 4.77E+01
1.02E+03 2.2E+00 1.50E+01 4.77E+01
2.94E+02 3.2E+00 1.50E+01 4.77E+01
1.32E+02 1.4E+01 1.50E+01 4.77E+01
5.71 E+02 3.9E+00 1 .50E+01 4.77E+01
7.43E+03 1.0E+00 1 .50E+01 4.77E+01
5.99E+03 7.3E-01 1 .50E+01 4.77E+01
4.86E+03 1.0E+00 1 .50E+01 4.77E+01 10 325
2.87E+03 2.1E+00 1 .50E+01 4.77E+01
1.77E+03 9.8E-01 1.50E+01 4.77E+01
9.57E+02 1.4E+00 1 .50E+01 4.77E+01
2.75E+02 6.9E+00 1.50E+01 4.77E+01
1.12E+02 1.4E+01 1.50E+01 4.77E+01
5.53E+02 2.9E+00 1.50E+01 4.77E+01
7.90E+01 1.6E+01 1.50E+01 4.77E+01
8.96E+01 6.1E+00 1.50E+01 4.77E+01
6.41 E+01 2.9E+01 1.50E+01 4.77E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.04E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.96E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.97E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1/10 10:45 AM L09 1313-1316 EaFA
6/1 1/1 01 0:46 AM L09 1313-1316 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-227
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone.
ug/L
Si EaFa-L09-1313-T01-A 1 1.08E+04
Si EaFa-L09-1313-T02-A 1 3.30E+03
Si EaFa-L09-1313-T03-A 1 5.10E+02
Si EaFa-L09-1313-T04-A 1 3.91E+02
Si EaFa-L09-1313-T05-A 1 8.21E+02
Si EaFa-L09-1313-T06-A 1 2.26E+03
Si EaFa-L09-1313-T07-A 1 7.59E+03
Si EaFa-L09-1313-T08-A 1 3.88E+04
Si EaFa-L09-1313-T09-A 1 6.73E+04
Si EaFa-L09-1313-T01-B 1 1.11E+04
Si EaFa-L09-1313-T02-B 1 3.45E+03
Si EaFa-L09-1313-T03-B 1 5.85E+02
Si EaFa-L09-1313-T04-B 1 3.67E+02
Si EaFa-L09-1313-T05-B 1 6.04E+02
Si EaFa-L09-1313-T06-B 1 1.87E+03
Si EaFa-L09-1313-T07-B 1 8.43E+03
Si EaFa-L09-1313-T08-B 1 4.00E+04
Si EaFa-L09-1313-T09-B 1 6.81E+04
Si EaFa-L09-1313-T01-C 1 1.11E+04
Si EaFa-L09-1313-T02-C 1 3.32E+03
Si EaFa-L09-1313-T03-C 1 5.52E+02
Si EaFa-L09-1313-T04-C 1 3.36E+02
Si EaFa-L09-1313-T05-C 1 6.44E+02
Si EaFa-L09-1313-T06-C 1 1 .58E+03
Si EaFa-L09-1313-T07-C 1 8.43E+03
Si EaFa-L09-1313-T08-C 1 3.96E+04
Si EaFa-L09-1313-T09-C 1 6.76E+04
Si EaFa-L09-1313-B01-A 1 4.48E+00
Si EaFa-L09-1313-B02-A 1 4.51 E+00
Si EaFa-L09-1313-B03-A 1 1.20E+01
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+04 1.3E+00 1.10E+00 3.50E+00
3.30E+03 9.6E-01 1.10E+00 3.50E+00
5.10E+02 7.0E-01 1.10E+00 3.50E+00 1000 100
3.91E+02 1.4E+00 1.10E+00 3.50E+00
8.21E+02 1.4E+00 1.10E+00 3.50E+00
2.26E+03 1.2E+00 1.10E+00 3.50E+00
7.59E+03 3.6E-01 1.10E+00 3.50E+00
3.88E+04 6.1E-01 1.10E+00 3.50E+00
6.73E+04 4.6E-01 1.10E+00 3.50E+00
1.11E+04 2.3E+00 1.10E+00 3.50E+00
3.45E+03 8.8E-01 1.10E+00 3.50E+00
5.85E+02 2.4E+00 1.10E+00 3.50E+00 1000 100
3.67E+02 1.2E+00 1.10E+00 3.50E+00
6.04E+02 1.5E-01 1.10E+00 3.50E+00
1.87E+03 7.1E-02 1.10E+00 3.50E+00
8.43E+03 5.3E-01 1.10E+00 3.50E+00
4.00E+04 3.6E-01 1.10E+00 3.50E+00
6.81E+04 1.0E+00 1.10E+00 3.50E+00
1.11E+04 5.3E-01 1.10E+00 3.50E+00
3.32E+03 5.1E-01 1.10E+00 3.50E+00
5.52E+02 7.4E-01 1.10E+00 3.50E+00 1000 100
3.36E+02 5.5E-01 1.10E+00 3.50E+00
6.44E+02 1.2E+00 1.10E+00 3.50E+00
1.58E+03 6.5E-01 1.10E+00 3.50E+00
8.43E+03 1.1E+00 1.10E+00 3.50E+00
3.96E+04 6.1E-02 1.10E+00 3.50E+00
6.76E+04 7.5E-01 1.10E+00 3.50E+00
4.48E+00 3.5E+01 1.10E+00 3.50E+00
4.51E+00 3.3E+01 1.10E+00 3.50E+00
1.20E+01 2.2E+01 1.10E+00 3.50E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .56E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .60E+03 1 01 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .60E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1/10 10:45 AM L09 1313-1316 EaFA
6/1 1/10 10:46 AM L09 1313-1316 EaFA
6/1 1/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-228
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFa-L09-1313-T01-A 1
Na EaFa-L09-1313-T02-A 1
Na EaFa-L09-1313-T03-A 1
Na EaFa-L09-1313-T04-A 1
Na EaFa-L09-1313-T05-A 1
Na EaFa-L09-1313-T06-A 1
Na EaFa-L09-1313-T07-A 1
Na EaFa-L09-1313-T08-A 1
Na EaFa-L09-1313-T09-A 1
Na EaFa-L09-1313-T01-B 1
Na EaFa-L09-1313-T02-B 1
Na EaFa-L09-1313-T03-B 1
Na EaFa-L09-1313-T04-B 1
Na EaFa-L09-1313-T05-B 1
Na EaFa-L09-1313-T06-B 1
Na EaFa-L09-1313-T07-B 1
Na EaFa-L09-1313-T08-B 1
Na EaFa-L09-1313-T09-B 1
Na EaFa-L09-1313-T01-C 1
Na EaFa-L09-1313-T02-C 1
Na EaFa-L09-1313-T03-C 1
Na EaFa-L09-1313-T04-C 1
Na EaFa-L09-1313-T05-C 1
Na EaFa-L09-1313-T06-C 1
Na EaFa-L09-1313-T07-C 1
Na EaFa-L09-1313-T08-C 1
Na EaFa-L09-1313-T09-C 1
Na EaFa-L09-1313-B01-A 1
Na EaFa-L09-1313-B02-A 1
Na EaFa-L09-1313-B03-A 1
Sample I
Cone. Qualifier 1
ug/L 1
5.66E+03
5.74E+03
5.74E+03
5.60E+03
5.58E+03
5.62E+03
5.26E+03
3.52E+03
3.26E+03
6.05E+03
5.99E+03
5.73E+03
5.45E+03
5.50E+03
5.59E+03
5.15E+03
3.50E+03
3.28E+03
6.05E+03
5.68E+03
5.38E+03
5.30E+03
5.21 E+03
5.35E+03
5.10E+03
3.44E+03
3.21 E+03
2.11E+01
2.02E+01
4.02E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.66E+03 9.8E-01 2.50E+00 8.00E+00
5.74E+03 1.7E+00 2.50E+00 8.00E+00
5.74E+03 2.3E-01 2.50E+00 8.00E+00 1000 100
5.60E+03 1.3E+00 2.50E+00 8.00E+00
5.58E+03 7.6E-01 2.50E+00 8.00E+00
5.62E+03 3.4E-01 2.50E+00 8.00E+00
5.26E+03 7.2E-01 2.50E+00 8.00E+00
3.52E+03 5.7E-01 2.50E+00 8.00E+00
3.26E+03 1.9E-01 2.50E+00 8.00E+00
6.05E+03 1.4E+00 2.50E+00 8.00E+00
5.99E+03 1.9E-01 2.50E+00 8.00E+00
5.73E+03 1.8E+00 2.50E+00 8.00E+00 1000 100
5.45E+03 5.7E-01 2.50E+00 8.00E+00
5.50E+03 1.4E+00 2.50E+00 8.00E+00
5.59E+03 1.1E+00 2.50E+00 8.00E+00
5.15E+03 2.5E-01 2.50E+00 8.00E+00
3.50E+03 4.1E-01 2.50E+00 8.00E+00
3.28E+03 1.9E-01 2.50E+00 8.00E+00
6.05E+03 5.2E-01 2.50E+00 8.00E+00
5.68E+03 5.1E-01 2.50E+00 8.00E+00
5.38E+03 9.0E-01 2.50E+00 8.00E+00 1000 100
5.30E+03 4.8E-01 2.50E+00 8.00E+00
5.21 E+03 3.5E-01 2.50E+00 8.00E+00
5.35E+03 4.7E-01 2.50E+00 8.00E+00
5.10E+03 1.1E+00 2.50E+00 8.00E+00
3.44E+03 2.5E-01 2.50E+00 8.00E+00
3.21 E+03 4.6E-01 2.50E+00 8.00E+00
2.11E+01 1.8E+00 2.50E+00 8.00E+00
2.02E+01 3.0E+00 2.50E+00 8.00E+00
4.02E+02 1.4E+00 2.50E+00 8.00E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.58E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.60E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.27E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:57 AM L09 131 3-1 31 6 EaFA
6/11/10 1 0:58 AM L09 131 3-1 31 6 EaFA
6/11/10 11:OOAML091313-1316EaFA
6/11/10 11:01 AM L09 131 3-1 31 6 EaFA
6/11/10 11:03AML091313-1316EaFA
6/11/10 11:15 AM L09 1313-1316 EaFA
6/11/10 11:16 AM L09 1313-1316 EaFA
6/11/10 11:18 AM L09 1313-1316 EaFA
6/11/10 11:20AML091313-1316EaFA
6/11/10 11:21 AM L09 131 3-1 31 6 EaFA
6/11/10 11:23 AM L09 1313-1316 EaFA
6/11/10 11:24 AM L09 1313-1316 EaFA
6/11/10 11:26 AM L09 1313-1316 EaFA
6/11/10 11:28 AM L09 1313-1316 EaFA
6/11/10 11:34 AM L09 1313-1316 EaFA
6/11/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/11/10 11:39 AM L09 1313-1316 EaFA
6/11/10 11:41 AML09 1313-1316 EaFA
6/11/10 11:43 AM L09 1313-1316 EaFA
6/11/10 11:44 AM L09 1313-1316 EaFA
6/11/10 11:46 AM L09 1313-1316 EaFA
6/11/10 11:48 AM L09 1313-1316 EaFA
6/11/10 10:45 AM L09 1313-1316 EaFA
6/11/10 10:46 AM L09 1313-1316 EaFA
6/11/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-229
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
EaFa-L09-1313-T01-A 1
EaFa-L09-1313-T02-A 1
EaFa-L09-1313-T03-A 1
EaFa-L09-1313-T04-A 1
EaFa-L09-1313-T05-A 1
EaFa-L09-1313-T06-A 1
EaFa-L09-1313-T07-A 1
EaFa-L09-1313-T08-A 1
EaFa-L09-1313-T09-A 1
EaFa-L09-1313-T01-B 1
EaFa-L09-1313-T02-B 1
EaFa-L09-1313-T03-B 1
EaFa-L09-1313-T04-B 1
EaFa-L09-1313-T05-B 1
EaFa-L09-1313-T06-B 1
EaFa-L09-1313-T07-B 1
EaFa-L09-1313-T08-B 1
EaFa-L09-1313-T09-B 1
EaFa-L09-1313-T01-C 1
EaFa-L09-1313-T02-C 1
EaFa-L09-1313-T03-C 1
EaFa-L09-1313-T04-C 1
EaFa-L09-1313-T05-C 1
EaFa-L09-1313-T06-C 1
EaFa-L09-1313-T07-C 1
EaFa-L09-1313-T08-C 1
EaFa-L09-1313-T09-C 1
EaFa-L09-1313-B01-A 1
EaFa-L09-1313-B02-A 1
EaFa-L09-1313-B03-A 1
Sample I
Cone. Qualifier 1
ug/L 1
1.45E+03
1.79E+03
1.95E+03
2.04E+03
2.15E+03
2.28E+03
2.70E+03
3.99E+03
5.29E+03
1.52E+03
1.74E+03
1 .89E+03
2.06E+03
2.20E+03
2.33E+03
2.62E+03
3.99E+03
5.23E+03
1 .49E+03
1 .69E+03
1 .80E+03
2.03E+03
2.12E+03
2.32E+03
2.61 E+03
3.90E+03
5.17E+03
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.45E+03 1.6E+00 1.00E+00 3.18E+00
1.79E+03 1.0E+00 1.00E+00 3.18E+00
1.95E+03 6.7E-01 1.00E+00 3.18E+00 1000 100
2.04E+03 1.3E+00 1.00E+00 3.18E+00
2.15E+03 1.2E+00 1.00E+00 3.18E+00
2.28E+03 7.7E-01 1.00E+00 3.18E+00
2.70E+03 7.4E-01 1.00E+00 3.18E+00
3.99E+03 2.7E+00 1.00E+00 3.18E+00
5.29E+03 1.6E+00 1.00E+00 3.18E+00
1.52E+03 2.2E+00 1.00E+00 3.18E+00
1.74E+03 5.4E-01 1.00E+00 3.18E+00
1.89E+03 2.1E+00 1.00E+00 3.18E+00 1000 100
2.06E+03 1.1E+00 1.00E+00 3.18E+00
2.20E+03 1.0E+00 1.00E+00 3.18E+00
2.33E+03 1.2E+00 1.00E+00 3.18E+00
2.62E+03 6.1E-01 1.00E+00 3.18E+00
3.99E+03 6.7E-02 1 .OOE+00 3.18E+00
5.23E+03 6.1E-01 1 .OOE+00 3.18E+00
1.49E+03 1.3E+00 1 .OOE+00 3.18E+00
1.69E+03 1.2E+00 1 .OOE+00 3.18E+00
1.80E+03 1.2E+00 1 .OOE+00 3.18E+00 1000 100
2.03E+03 7.8E-01 1. OOE+00 3.18E+00
2.12E+03 9.4E-02 1. OOE+00 3.18E+00
2.32E+03 3.7E-01 1. OOE+00 3.18E+00
2.61E+03 4.0E-01 1.00E+00 3.18E+00
3.90E+03 1.2E+00 1. OOE+00 3.18E+00
5.17E+03 1.1E+00 1.00E+00 3.18E+00
5.00E-01 2.1E+02 1.00E+00 3.18E+00
5.00E-01 1.7E+02 1. OOE+00 3.18E+00
5.00E-01 1.3E+02 1. OOE+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.83E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.77E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.75E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-230
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
ug/L
S EaFa-L09-1313-T01-A 1 1.69E+05
S EaFa-L09-1313-T02-A 1 1.63E+05
S EaFa-L09-1313-T03-A 1 1.61E+05
S EaFa-L09-1313-T04-A 1 1.58E+05
S EaFa-L09-1313-T05-A 1 1.58E+05
S EaFa-L09-1313-T06-A 1 1.57E+05
S EaFa-L09-1313-T07-A 1 1.32E+05
S EaFa-L09-1313-T08-A 1 8.42E+04
S EaFa-L09-1313-T09-A 1 6.17E+04
S EaFa-L09-1313-T01-B 1 1.83E+05
S EaFa-L09-1313-T02-B 1 1.67E+05
S EaFa-L09-1313-T03-B 1 1.60E+05
S EaFa-L09-1313-T04-B 1 1.60E+05
S EaFa-L09-1313-T05-B 1 1.59E+05
S EaFa-L09-1313-T06-B 1 1.59E+05
S EaFa-L09-1313-T07-B 1 1.32E+05
S EaFa-L09-1313-T08-B 1 8.59E+04
S EaFa-L09-1313-T09-B 1 6.32E+04
S EaFa-L09-1313-T01-C 1 1.81E+05
S EaFa-L09-1313-T02-C 1 1 .64E+05
S EaFa-L09-1313-T03-C 1 1 .53E+05
S EaFa-L09-1313-T04-C 1 1 .58E+05
S EaFa-L09-1313-T05-C 1 1.53E+05
S EaFa-L09-1313-T06-C 1 1.58E+05
S EaFa-L09-1313-T07-C 1 1.34E+05
S EaFa-L09-1313-T08-C 1 8.61E+04
S EaFa-L09-1313-T09-C 1 6.27E+04
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.69E+05 9.4E-01 6.80E+00 2.16E+01
1.63E+05 1.1E+00 6.80E+00 2.16E+01
1.61E+05 1.4E-01 6.80E+00 2.16E+01 1000 100
1.58E+05 9.3E-01 6.80E+00 2.16E+01
1.58E+05 8.1E-01 6.80E+00 2.16E+01
1.57E+05 5.4E-01 6.80E+00 2.16E+01
1.32E+05 5.8E-01 6.80E+00 2.16E+01
8.42E+04 4.1E-01 6.80E+00 2.16E+01
6.17E+04 4.5E-01 6.80E+00 2.16E+01
1.83E+05 1.8E+00 6.80E+00 2.16E+01
1.67E+05 2.4E-01 6.80E+00 2.16E+01
1.60E+05 2.6E+00 6.80E+00 2.16E+01 1000 100
1.60E+05 4.5E-01 6.80E+00 2.16E+01
1.59E+05 4.5E-01 6.80E+00 2.16E+01
1.59E+05 4.1E-01 6.80E+00 2.16E+01
1.32E+05 4.4E-01 6.80E+00 2.16E+01
8.59E+04 3.9E-01 6.80E+00 2.16E+01
6.32E+04 6.6E-01 6.80E+00 2.16E+01
1.81E+05 6.7E-01 6.80E+00 2.16E+01
1.64E+05 5.2E-01 6.80E+00 2.16E+01
1.53E+05 7.1E-01 6.80E+00 2.16E+01 1000 100
1.58E+05 1.1E+00 6.80E+00 2.16E+01
1.53E+05 3.5E-01 6.80E+00 2.16E+01
1.58E+05 7.9E-01 6.80E+00 2.16E+01
1.34E+05 8.4E-01 6.80E+00 2.16E+01
8.61E+04 1.2E-01 6.80E+00 2.16E+01
6.27E+04 3.0E-01 6.80E+00 2.16E+01
S EaFa-L09-1313-B01-A 1 3.40E+00 U1/2 3.40E+00 2.3E+02 6.80E+00 2.16E+01
S EaFa-L09-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 1.3E+02 6.80E+00 2.16E+01
S EaFa-L09-1313-B03-A 1 6.99E+00 E
6.99E+00 8.4E+01 6.80E+00 2.16E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .62E+05 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .61 E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .54E+05 81 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/11/1011 :48 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-231
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFa-L09-1313-T01-A 1
Tl EaFa-L09-1313-T02-A 1
Tl EaFa-L09-1313-T03-A 1
Tl EaFa-L09-1313-T04-A 1
Tl EaFa-L09-1313-T05-A 1
Tl EaFa-L09-1313-T06-A 1
Tl EaFa-L09-1313-T07-A 1
Tl EaFa-L09-1313-T08-A 1
Tl EaFa-L09-1313-T09-A 1
Tl EaFa-L09-1313-T01-B 1
Tl EaFa-L09-1313-T02-B 1
Tl EaFa-L09-1313-T03-B 1
Tl EaFa-L09-1313-T04-B 1
Tl EaFa-L09-1313-T05-B 1
Tl EaFa-L09-1313-T06-B 1
Tl EaFa-L09-1313-T07-B 1
Tl EaFa-L09-1313-T08-B 1
Tl EaFa-L09-1313-T09-B 1
Tl EaFa-L09-1313-T01-C 1
Tl EaFa-L09-1313-T02-C 1
Tl EaFa-L09-1313-T03-C 1
Tl EaFa-L09-1313-T04-C 1
Tl EaFa-L09-1313-T05-C 1
Tl EaFa-L09-1313-T06-C 1
Tl EaFa-L09-1313-T07-C 1
Tl EaFa-L09-1313-T08-C 1
Tl EaFa-L09-1313-T09-C 1
Tl EaFa-L09-1313-B01-A 1
Tl EaFa-L09-1313-B02-A 1
Tl EaFa-L09-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
7.44E+00 E
2.30E+00 U1/2
1.28E+01 E
2.94E+01
5.77E+01
9.11E+01
6.40E+00 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
3.93E+01
5.47E+01
8.35E+01
6.08E+00 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
4.09E+01
5.17E+01
8.34E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 6.9E+01 4.60E+00 1.46E+01
2.30E+00 2.8E+02 4.60E+00 1.46E+01
2.30E+00 1.9E+02 4.60E+00 1.46E+01 10 325
7.44E+00 8.5E+01 4.60E+00 1.46E+01
2.30E+00 1.2E+02 4.60E+00 1.46E+01
1.28E+01 2.7E+01 4.60E+00 1.46E+01
2.94E+01 1.1E+01 4.60E+00 1.46E+01
5.77E+01 8.7E+00 4.60E+00 1.46E+01
9.11E+01 4.2E+00 4.60E+00 1.46E+01
6.40E+00 1.4E+02 4.60E+00 1.46E+01
2.30E+00 4.6E+02 4.60E+00 1.46E+01
2.30E+00 8.4E+01 4.60E+00 1.46E+01 10 325
2.30E+00 2.8E+01 4.60E+00 1.46E+01
2.30E+00 6.6E+01 4.60E+00 1.46E+01
2.30E+00 4.6E+02 4.60E+00 1.46E+01
3.93E+01 1.7E+01 4.60E+00 1.46E+01
5.47E+01 3.5E+00 4.60E+00 1.46E+01
8.35E+01 6.0E+00 4.60E+00 1.46E+01
6.08E+00 9.1E+01 4.60E+00 1.46E+01
2.30E+00 7.6E+02 4.60E+00 1.46E+01
2.30E+00 1.7E+02 4.60E+00 1.46E+01 10 325
2.30E+00 6.3E+01 4.60E+00 1.46E+01
2.30E+00 1.0E+03 4.60E+00 1.46E+01
2.30E+00 2.8E+02 4.60E+00 1.46E+01
4.09E+01 2.1E+01 4.60E+00 1.46E+01
5.17E+01 1.0E+01 4.60E+00 1.46E+01
8.34E+01 7.4E+00 4.60E+00 1.46E+01
2.30E+00 9.0E+01 4.60E+00 1.46E+01
2.30E+00 9.3E+01 4.60E+00 1.46E+01
2.30E+00 2.0E+02 4.60E+00 1.46E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.30E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.22E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/11/1011 :46 AM L09 1 31 3-1 31 6 EaFA
6/11/1011 :48 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1/10 10:46 AM L09 1313-1316 EaFA
6/11/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-232
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFa-L09-1313-T01-A 1
Ti EaFa-L09-1313-T02-A 1
Ti EaFa-L09-1313-T03-A 1
Ti EaFa-L09-1313-T04-A 1
Ti EaFa-L09-1313-T05-A 1
Ti EaFa-L09-1313-T06-A 1
Ti EaFa-L09-1313-T07-A 1
Ti EaFa-L09-1313-T08-A 1
Ti EaFa-L09-1313-T09-A 1
Ti EaFa-L09-1313-T01-B 1
Ti EaFa-L09-1313-T02-B 1
Ti EaFa-L09-1313-T03-B 1
Ti EaFa-L09-1313-T04-B 1
Ti EaFa-L09-1313-T05-B 1
Ti EaFa-L09-1313-T06-B 1
Ti EaFa-L09-1313-T07-B 1
Ti EaFa-L09-1313-T08-B 1
Ti EaFa-L09-1313-T09-B 1
Ti EaFa-L09-1313-T01-C 1
Ti EaFa-L09-1313-T02-C 1
Ti EaFa-L09-1313-T03-C 1
Ti EaFa-L09-1313-T04-C 1
Ti EaFa-L09-1313-T05-C 1
Ti EaFa-L09-1313-T06-C 1
Ti EaFa-L09-1313-T07-C 1
Ti EaFa-L09-1313-T08-C 1
Ti EaFa-L09-1313-T09-C 1
Ti EaFa-L09-1313-B01-A 1
Ti EaFa-L09-1313-B02-A 1
Ti EaFa-L09-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L
2.67E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.06E+01
2.07E+03
3.01 E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.35E+01
2.10E+03
2.30E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.26E+01
2.06E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.67E+00 4.7E+01 2.00E+00 6.40E+00
1.00E+00 2.3E+01 2.00E+00 6.40E+00
1.00E+00 8.2E+01 2.00E+00 6.40E+00 10 325
1.00E+00 1.1E+02 2.00E+00 6.40E+00
1.00E+00 1.1E+02 2.00E+00 6.40E+00
1.00E+00 5.6E+01 2.00E+00 6.40E+00
1.00E+00 4.8E+01 2.00E+00 6.40E+00
3.06E+01 8.6E-01 2.00E+00 6.40E+00
2.07E+03 4.9E-01 2.00E+00 6.40E+00
3.01 E+00 8.7E+00 2.00E+00 6.40E+00
1.00E+00 4.6E+01 2.00E+00 6.40E+00
1.00E+00 4.5E+01 2.00E+00 6.40E+00 10 325
1.00E+00 3.6E+01 2.00E+00 6.40E+00
1.00E+00 7.1E+01 2.00E+00 6.40E+00
1.00E+00 5.5E+01 2.00E+00 6.40E+00
1.00E+00 5.5E+01 2.00E+00 6.40E+00
3.35E+01 1.6E+00 2.00E+00 6.40E+00
2.10E+03 5.7E-01 2.00E+00 6.40E+00
2.30E+00 1.3E+01 2.00E+00 6.40E+00
1.00E+00 9.2E+01 2.00E+00 6.40E+00
1.00E+00 1.1E+02 2.00E+00 6.40E+00 10 325
1.00E+00 1.9E+01 2.00E+00 6.40E+00
1.00E+00 1.2E+02 2.00E+00 6.40E+00
1.00E+00 8.8E+01 2.00E+00 6.40E+00
1.00E+00 5.2E+01 2.00E+00 6.40E+00
3.26E+01 2.1 E+00 2.00E+00 6.40E+00
2.06E+03 7.7E-01 2.00E+00 6.40E+00
1.00E+00 1.2E+02 2.00E+00 6.40E+00
1.00E+00 4.4E+01 2.00E+00 6.40E+00
1.00E+00 4.3E+01 2.00E+00 6.40E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.46E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.31 E+03 1 02% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.30E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/11/1011 :44 AM L09 1 31 3-1 31 6 EaFA
6/11/1011 :46 AM L09 1 31 3-1 31 6 EaFA
6/11/1011 :48 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1/10 10:46 AM L09 1313-1316 EaFA
6/11/10 10:48 AM L09 1313-1316 EaFA
                                                                                                                                                                          1-233
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFa-L09-1313-T01-A 1
V EaFa-L09-1313-T02-A 1
V EaFa-L09-1313-T03-A 1
V EaFa-L09-1313-T04-A 1
V EaFa-L09-1313-T05-A 1
V EaFa-L09-1313-T06-A 1
V EaFa-L09-1313-T07-A 1
V EaFa-L09-1313-T08-A 1
V EaFa-L09-1313-T09-A 1
V EaFa-L09-1313-T01-B 1
V EaFa-L09-1313-T02-B 1
V EaFa-L09-1313-T03-B 1
V EaFa-L09-1313-T04-B 1
V EaFa-L09-1313-T05-B 1
V EaFa-L09-1313-T06-B 1
V EaFa-L09-1313-T07-B 1
V EaFa-L09-1313-T08-B 1
V EaFa-L09-1313-T09-B 1
V EaFa-L09-1313-T01-C 1
V EaFa-L09-1313-T02-C 1
V EaFa-L09-1313-T03-C 1
V EaFa-L09-1313-T04-C 1
V EaFa-L09-1313-T05-C 1
V EaFa-L09-1313-T06-C 1
V EaFa-L09-1313-T07-C 1
V EaFa-L09-1313-T08-C 1
V EaFa-L09-1313-T09-C 1
V EaFa-L09-1313-B01-A 1
V EaFa-L09-1313-B02-A 1
V EaFa-L09-1313-B03-A 1
Sample I
Cone. Qualifier 1
ug/L 1
4.87E+03
2.55E+03
1.95E+03
4.99E+02
2.31 E+02
1.86E+02
8.24E+01
1.34E+02
6.31 E+03
5.04E+03
2.73E+03
2.03E+03
4.28E+02
2.70E+02
1 .94E+02
9.04E+01
1 .50E+02
6.34E+03
4.88E+03
2. 61 E+03
1 .93E+03
4.19E+02
2.50E+02
1.80E+02
8.95E+01
1.48E+02
6.25E+03
2.51 E+00 E
7.50E-01 U1/2
4.56E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.87E+03 1.4E+00 1.50E+00 4.77E+00
2.55E+03 6.2E-01 1.50E+00 4.77E+00
1.95E+03 7.7E-01 1.50E+00 4.77E+00 10 325
4.99E+02 7.7E-01 1.50E+00 4.77E+00
2.31 E+02 2.3E+00 1.50E+00 4.77E+00
1.86E+02 4.2E-01 1.50E+00 4.77E+00
8.24E+01 1.6E+00 1.50E+00 4.77E+00
1.34E+02 1.2E+00 1.50E+00 4.77E+00
6.31 E+03 8.1E-01 1.50E+00 4.77E+00
5.04E+03 1.1 E+00 1.50E+00 4.77E+00
2.73E+03 4.9E-01 1.50E+00 4.77E+00
2.03E+03 1.9E+00 1.50E+00 4.77E+00 10 325
4.28E+02 1.4E+00 1.50E+00 4.77E+00
2.70E+02 1.1 E+00 1.50E+00 4.77E+00
1.94E+02 1.0E+00 1.50E+00 4.77E+00
9.04E+01 8.8E-01 1 .50E+00 4.77E+00
1.50E+02 7.6E-02 1 .50E+00 4.77E+00
6.34E+03 4.7E-01 1 .50E+00 4.77E+00
4.88E+03 1.3E+00 1 .50E+00 4.77E+00
2. 61 E+03 1.3E+00 1 .50E+00 4.77E+00
1.93E+03 8.1E-01 1.50E+00 4.77E+00 10 325
4.19E+02 1.6E+00 1.50E+00 4.77E+00
2.50E+02 1.2E+00 1.50E+00 4.77E+00
1.80E+02 2.6E-01 1.50E+00 4.77E+00
8.95E+01 1.5E+00 1.50E+00 4.77E+00
1.48E+02 1.0E+00 1.50E+00 4.77E+00
6.25E+03 1.0E-01 1.50E+00 4.77E+00
2.51 E+00 5.3E+01 1.50E+00 4.77E+00
7.50E-01 2.8E+01 1.50E+00 4.77E+00
4.56E+00 5.0E+01 1.50E+00 4.77E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.32E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.32E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.31E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 10:55 AM L09 1313-1316 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/1 1/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/11/1011 :48 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-234
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone.
ug/L
Zn EaFa-L09-1313-T01-A 1 1.02E+02
Zn EaFa-L09-1313-T02-A 1 1.18E+01
Zn EaFa-L09-1313-T03-A 1 8.45E+00
Zn EaFa-L09-1313-T04-A 1 6.64E+00
Zn EaFa-L09-1313-T05-A 1 1.27E+01
Zn EaFa-L09-1313-T06-A 1 2.15E+01
Zn EaFa-L09-1313-T07-A 1 1.36E+03
Zn EaFa-L09-1313-T08-A 1 1.25E+03
Zn EaFa-L09-1313-T09-A 1 1.59E+03
Zn EaFa-L09-1313-T01-B 1 1.01E+02
Zn EaFa-L09-1313-T02-B 1 1.95E+01
Zn EaFa-L09-1313-T03-B 1 8.46E+00
Zn EaFa-L09-1313-T04-B 1 7.00E+00
Zn EaFa-L09-1313-T05-B 1 2.02E+01
Zn EaFa-L09-1313-T06-B 1 1.94E+01
Zn EaFa-L09-1313-T07-B 1 1.33E+03
Zn EaFa-L09-1313-T08-B 1 1.26E+03
Zn EaFa-L09-1313-T09-B 1 1 .57E+03
Zn EaFa-L09-1313-T01-C 1 1 .09E+02
Zn EaFa-L09-1313-T02-C 1 1 .52E+01
Zn EaFa-L09-1313-T03-C 1 6.16E+00
Zn EaFa-L09-1313-T04-C 1 3.46E+00
Zn EaFa-L09-1313-T05-C 1 1 .87E+01
Zn EaFa-L09-1313-T06-C 1 2.52E+01
Zn EaFa-L09-1313-T07-C 1 1.32E+03
Zn EaFa-L09-1313-T08-C 1 1.24E+03
Zn EaFa-L09-1313-T09-C 1 1.56E+03
Zn EaFa-L09-1313-B01-A 1 7.48E+00
Zn EaFa-L09-1313-B02-A 1 1.04E+01
Zn EaFa-L09-1313-B03-A 1 1.34E+01
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.02E+02 1.6E+00 1.00E+00 3.18E+00
1.18E+01 4.1E+00 1.00E+00 3.18E+00
8.45E+00 9.4E+00 1.00E+00 3.18E+00 10 325
6.64E+00 4.7E+00 1.00E+00 3.18E+00
1.27E+01 8.4E+00 1.00E+00 3.18E+00
2.15E+01 1.4E+00 1.00E+00 3.18E+00
1.36E+03 9.2E-01 1.00E+00 3.18E+00
1.25E+03 1.2E+00 1.00E+00 3.18E+00
1.59E+03 1.3E+00 1.00E+00 3.18E+00
1.01E+02 2.3E+00 1.00E+00 3.18E+00
1.95E+01 4.9E+00 1.00E+00 3.18E+00
8.46E+00 6.3E+00 1.00E+00 3.18E+00 10 325
7.00E+00 2.1E+01 1.00E+00 3.18E+00
2.02E+01 1.6E+00 1.00E+00 3.18E+00
1.94E+01 5.1E+00 1.00E+00 3.18E+00
1.33E+03 6.1E-01 1.00E+00 3.18E+00
1.26E+03 1.1E+00 1.00E+00 3.18E+00
1.57E+03 7.5E-01 1 .OOE+00 3.18E+00
1.09E+02 1.1E+00 1.00E+00 3.18E+00
1.52E+01 1.3E+01 1. OOE+00 3.18E+00
6.16E+00 2.9E+00 1 .OOE+00 3.18E+00 10 325
3.46E+00 1.2E+01 1 .OOE+00 3.18E+00
1.87E+01 5.6E+00 1. OOE+00 3.18E+00
2.52E+01 8.8E+00 1. OOE+00 3.18E+00
1.32E+03 4.4E-01 1. OOE+00 3.18E+00
1.24E+03 8.1E-01 1. OOE+00 3.18E+00
1.56E+03 3.8E-01 1. OOE+00 3.18E+00
7.48E+00 1.1E+01 1.00E+00 3.18E+00
1.04E+01 2.9E+00 1. OOE+00 3.18E+00
1.34E+01 8.2E+00 1. OOE+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.63E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.52E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.55E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 10:50AML091313-1316EaFA
6/11/10 10:51 AM L09 1313-1316 EaFA
6/11/10 10:53 AM L09 1313-1316 EaFA
6/11/10 1 0:55 AM L09 131 3-1 31 6 EaFA
6/11/10 10:57 AM L09 1313-1316 EaFA
6/11/10 10:58 AM L09 1313-1316 EaFA
6/11/10 11:00 AM L09 1313-1316 EaFA
6/11/1011:01 AM L09 1313-1316 EaFA
6/1 1/10 11:03 AM L09 1313-1316 EaFA
6/1 1/10 11:15 AM L09 1313-1316 EaFA
6/1 1/10 11:16 AM L09 1313-1316 EaFA
6/1 1/10 11:18 AM L09 1313-1316 EaFA
6/1 1/10 11:20 AM L09 1313-1316 EaFA
6/11/1011:21 AM L09 1313-1316 EaFA
6/1 1/10 11:23 AM L09 1313-1316 EaFA
6/1 1/10 11:24 AM L09 1313-1316 EaFA
6/1 1/10 11:26 AM L09 1313-1316 EaFA
6/1 1/10 11:28 AM L09 1313-1316 EaFA
6/1 1/10 11:34 AM L09 1313-1316 EaFA
6/1 1/10 11:36 AM L09 1313-1316 EaFA
6/1 1/10 11:38 AM L09 1313-1316 EaFA
6/1 1/10 11:39 AM L09 1313-1316 EaFA
6/11/1011:41 AM L09 1313-1316 EaFA
6/1 1/10 11:43 AM L09 1313-1316 EaFA
6/1 1/10 11:44 AM L09 1313-1316 EaFA
6/1 1/10 11:46 AM L09 1313-1316 EaFA
6/1 1/10 11:48 AM L09 1313-1316 EaFA
6/1 1 /1 0 1 0:45 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:46 AM L09 1 31 3-1 31 6 EaFA
6/1 1 /1 0 1 0:48 AM L09 1 31 3-1 31 6 EaFA
                                                                                                                                                                          1-235
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Sample I
Al Sample Dilution Cone. Qualifier
I I ug/L
Al EaFA-L10-1313-T01-A 1 1.09E+05
Al EaFA-L10-1313-T02-A 1 3.27E+04
Al EaFA-L10-1313-T03-A 1 2.45E+04
Al EaFA-L10-1313-T04-A 1 1.11E+04
Al EaFA-L10-1313-T05-A 1 1.22E+02
Al EaFA-L10-1313-T06-A 1 4.93E+02
Al EaFA-L10-1313-T07-A 1 2.71E+02
Al EaFA-L10-1313-T08-A 1 7.33E+04
Al EaFA-L10-1313-T09-A 1 1.06E+05
Al EaFA-L10-1313-T01-B 1 1.11E+05
Al EaFA-L10-1313-T02-B 1 3.60E+04
Al EaFA-L10-1313-T03-B 1 2.27E+04
Al EaFA-L10-1313-T04-B 1 1.15E+04
Al EaFA-L10-1313-T05-B 1 1.56E+02
Al EaFA-L10-1313-T06-B 1 1.30E+02
Al EaFA-L10-1313-T07-B 1 5.65E+02
Al EaFA-L10-1313-T08-B 1 6.58E+04
Al EaFA-L10-1313-T09-B 1 1.07E+05
Al EaFA-L10-1313-T01-C 1 1.20E+05
Al EaFA-L10-1313-T02-C 1 3.59E+04
Al EaFA-L10-1313-T03-C 1 2.46E+04
Al EaFA-L10-1313-T04-C 1 1.06E+04
Al EaFA-L10-1313-T05-C 1 1.44E+02
Al EaFA-L10-1313-T06-C 1 1.09E+02
Al EaFA-L10-1313-T07-C 1 6.87E+02
Al EaFA-L10-1313-T08-C 1 7.58E+04
Al EaFA-L10-1313-T09-C 1 1.11E+05
Al EaFA-L10-1313-B01-A 1 8.48E+00
Al EaFA-L10-1313-B02-A 1 1.06E+01
Al EaFA-L10-1313-B03-A 1 2.78E+01
Al EaFA-L10-1313-B01-C 1 5.00E-01 U1/2
Al EaFA-L10-1313-B02-C 1 5.00E-01 U1/2
Al EaFA-L10-1313-B03-C 1 3.69E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.09E+05 3.6E-01 1.0E+00 3.2E+00
3.27E+04 1.2E+01 1.0E+00 3.2E+00
2.45E+04 9.8E-01 1.0E+00 3.2E+00 1000 100
1.11E+04 3.4E-01 1.0E+00 3.2E+00
1.22E+02 1.7E+00 1.0E+00 3.2E+00
4.93E+02 6.6E-02 1.0E+00 3.2E+00
2.71 E+02 1.5E+00 1.0E+00 3.2E+00
7.33E+04 3.1E-01 1.0E+00 3.2E+00
1.06E+05 3.0E-01 1.0E+00 3.2E+00
1.11E+05 1.3E-01 1.0E+00 3.2E+00
3.60E+04 1.1E+00 1.0E+00 3.2E+00
2.27E+04 8.9E-01 1.0E+00 3.2E+00 1000 100
1.15E+04 5.7E-01 1.0E+00 3.2E+00
1.56E+02 1.6E+00 1.0E+00 3.2E+00
1.30E+02 5.5E-01 1.0E+00 3.2E+00
5.65E+02 1.8E+00 1.0E+00 3.2E+00
6.58E+04 2.6E-01 1.0E+00 3.2E+00
1.07E+05 6.9E-01 1.0E+00 3.2E+00
1.20E+05 3.4E+00 1.0E+00 3.2E+00
3.59E+04 2.4E-01 1.0E+00 3.2E+00
2.46E+04 3.5E-01 1.0E+00 3.2E+00 1000 100
1.06E+04 2.0E-01 1.0E+00 3.2E+00
1.44E+02 3.5E+00 1.0E+00 3.2E+00
1.09E+02 5.0E+00 1.0E+00 3.2E+00
6.87E+02 6.5E-01 1.0E+00 3.2E+00
7.58E+04 4.8E-01 1.0E+00 3.2E+00
1.11E+05 2.5E-01 1.0E+00 3.2E+00
8.48E+00 3.7E+01 1.0E+00 3.2E+00
1.06E+01 1.3E+01 1.0E+00 3.2E+00
2.78E+01 9.8E+00 1.0E+00 3.2E+00
5.00E-01 6.4E+00 1.0E+00 3.2E+00
5.00E-01 6.3E+00 1.0E+00 3.2E+00
3.69E+01 5.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.54E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.36E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.55E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                                  1-236
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Sb Sample Dilution Cone. Qualifier Revi
1 1 1 ug/L |
Sb EaFA-L10-1313-T01-A 1 5.84E+02
Sb EaFA-L10-1313-T02-A 1 1.62E+02
Sb EaFA-L10-1313-T03-A 1 1.55E+02
Sb EaFA-L10-1313-T04-A 1 1.87E+02
Sb EaFA-L10-1313-T05-A 1 1.45E+02
Sb EaFA-L10-1313-T06-A 1 9.45E+01
Sb EaFA-L10-1313-T07-A 1 1.24E+02
Sb EaFA-L10-1313-T08-A 1 7.73E+00 E
Sb EaFA-L10-1313-T09-A 1 3.75E+00 U1/2
Sb EaFA-L10-1313-T01-B 1 5.51 E+02
Sb EaFA-L10-1313-T02-B 1 1.70E+02
Sb EaFA-L10-1313-T03-B 1 1.88E+02
Sb EaFA-L10-1313-T04-B 1 1.82E+02
Sb EaFA-L10-1313-T05-B 1 1.31 E+02
Sb EaFA-L10-1313-T06-B 1 1.22E+02
Sb EaFA-L10-1313-T07-B 1 1.33E+02
Sb EaFA-L10-1313-T08-B 1 2.26E+01 E
Sb EaFA-L10-1313-T09-B 1 8.95E+00 E
Sb EaFA-L10-1313-T01-C 1 6.08E+02
Sb EaFA-L10-1313-T02-C 1 2.21 E+02
Sb EaFA-L10-1313-T03-C 1 1.85E+02
Sb EaFA-L10-1313-T04-C 1 1.90E+02
Sb EaFA-L10-1313-T05-C 1 2.51 E+02
Sb EaFA-L10-1313-T06-C 1 1.30E+02
Sb EaFA-L10-1313-T07-C 1 1.17E+02
Sb EaFA-L10-1313-T08-C 1 3.75E+00 U1/2
Sb EaFA-L10-1313-T09-C 1 7.50E+00 E
Sb EaFA-L10-1313-B01-A 1 3.75E+00 U1/2
Sb EaFA-L10-1313-B02-A 1 3.75E+00 U1/2
Sb EaFA-L10-1313-B03-A 1 1.12E+01 E
Sb EaFA-L10-1313-B01-C 1 1.74E+01 E
Sb EaFA-L10-1313-B02-C 1 3.75E+00 U1/2
Sb EaFA-L10-1313-B03-C 1 1.42E+01 E
ial ICP-OES Spike Sol'n
sw Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.84E+02 2.8E+00 7.5E+00 2.4E+01
1.62E+02 1.6E+01 7.5E+00 2.4E+01
1.55E+02 1.0E+01 7.5E+00 2.4E+01 10 300
1.87E+02 1.6E+01 7.5E+00 2.4E+01
1.45E+02 2.1E+01 7.5E+00 2.4E+01
9.45E+01 1.5E+01 7.5E+00 2.4E+01
1.24E+02 7.9E+00 7.5E+00 2.4E+01
7.73E+00 2.1 E+02 7.5E+00 2.4E+01
3.75E+00 8.1E+01 7.5E+00 2.4E+01
5.51 E+02 7.2E+00 7.5E+00 2.4E+01
1.70E+02 9.7E+00 7.5E+00 2.4E+01
1.88E+02 8.8E+00 7.5E+00 2.4E+01 10 300
1.82E+02 1.7E+01 7.5E+00 2.4E+01
1.31 E+02 7.0E+00 7.5E+00 2.4E+01
1.22E+02 6.6E+00 7.5E+00 2.4E+01
1.33E+02 2.2E+01 7.5E+00 2.4E+01
2.26E+01 4.0E+01 7.5E+00 2.4E+01
8.95E+00 1.4E+02 7.5E+00 2.4E+01
6.08E+02 5.6E+00 7.5E+00 2.4E+01
2.21 E+02 1.4E+01 7.5E+00 2.4E+01
1.85E+02 1.6E+01 7.5E+00 2.4E+01 10 300
1.90E+02 9.3E+00 7.5E+00 2.4E+01
2.51 E+02 6.3E+00 7.5E+00 2.4E+01
1.30E+02 2.0E+01 7.5E+00 2.4E+01
1.17E+02 1.2E+01 7.5E+00 2.4E+01
3.75E+00 2.6E+02 7.5E+00 2.4E+01
7.50E+00 6.4E+01 7.5E+00 2.4E+01
3.75E+00 9.1E+01 7.5E+00 2.4E+01
3.75E+00 8.1E+01 7.5E+00 2.4E+01
1.12E+01 1.1 E+02 7.5E+00 2.4E+01
1.74E+01 6.2E+01 7.5E+00 2.4E+01
3.75E+00 1.2E+01 7.5E+00 2.4E+01
1.42E+01 4.2E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.93E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.07E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.25E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-237
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
1 1 ug/L
As EaFA-L10-1313-T01-A 1 1.83E+04
As EaFA-L10-1313-T02-A 1 2.67E+03
As EaFA-L10-1313-T03-A 1 1.58E+03
As EaFA-L10-1313-T04-A 1 8.80E+02
As EaFA-L10-1313-T05-A 1 8.87E+01
As EaFA-L10-1313-T06-A 1 1.29E+02
As EaFA-L10-1313-T07-A 1 1.11E+02
As EaFA-L10-1313-T08-A 1 1.12E+02
As EaFA-L10-1313-T09-A 1 1.09E+03
As EaFA-L10-1313-T01-B 1 1.86E+04
As EaFA-L10-1313-T02-B 1 3.30E+03
As EaFA-L10-1313-T03-B 1 1.59E+03
As EaFA-L10-1313-T04-B 1 8.63E+02
As EaFA-L10-1313-T05-B 1 1.03E+02
As EaFA-L10-1313-T06-B 1 8.62E+01
As EaFA-L10-1313-T07-B 1 1.26E+02
As EaFA-L10-1313-T08-B 1 1.25E+02
As EaFA-L10-1313-T09-B 1 1.03E+03
As EaFA-L10-1313-T01-C 1 1.99E+04
As EaFA-L10-1313-T02-C 1 3.23E+03
As EaFA-L10-1313-T03-C 1 1.85E+03
As EaFA-L10-1313-T04-C 1 8.54E+02
As EaFA-L10-1313-T05-C 1 9.98E+01
As EaFA-L10-1313-T06-C 1 8.06E+01
As EaFA-L10-1313-T07-C 1 1.40E+02
As EaFA-L10-1313-T08-C 1 1.16E+02
As EaFA-L10-1313-T09-C 1 1.06E+03
As EaFA-L10-1313-B01-A 1 3.44E+01 E
As EaFA-L10-1313-B02-A 1 3.90E+01
As EaFA-L10-1313-B03-A 1 3.08E+01 E
As EaFA-L10-1313-B01-C 1 3.94E+01
As EaFA-L10-1313-B02-C 1 3.53E+01
As EaFA-L10-1313-B03-C 1 3.71E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.83E+04 8.2E-01 1.1E+01 3.5E+01
2.67E+03 1.3E+01 1.1E+01 3.5E+01
1.58E+03 9.0E-01 1.1E+01 3.5E+01 10 300
8.80E+02 3.2E+00 1.1E+01 3.5E+01
8.87E+01 3.3E+01 1.1E+01 3.5E+01
1.29E+02 1.1E+01 1.1E+01 3.5E+01
1.11E+02 2.9E+01 1.1E+01 3.5E+01
1.12E+02 7.7E+00 1.1E+01 3.5E+01
1.09E+03 7.7E-01 1.1E+01 3.5E+01
1.86E+04 9.7E-01 1.1E+01 3.5E+01
3.30E+03 1.4E+00 1.1E+01 3.5E+01
1.59E+03 2.1E+00 1.1E+01 3.5E+01 10 300
8.63E+02 1.4E+00 1.1E+01 3.5E+01
1.03E+02 2.6E+01 1.1E+01 3.5E+01
8.62E+01 6.7E+00 1.1E+01 3.5E+01
1.26E+02 2.6E+00 1.1E+01 3.5E+01
1.25E+02 7.4E+00 1.1E+01 3.5E+01
1.03E+03 1.6E+00 1.1E+01 3.5E+01
1.99E+04 3.2E+00 1.1E+01 3.5E+01
3.23E+03 4.8E-01 1.1E+01 3.5E+01
1.85E+03 1.1E-01 1.1E+01 3.5E+01 10 300
8.54E+02 2.2E+00 1.1E+01 3.5E+01
9.98E+01 2.7E+01 1.1E+01 3.5E+01
8.06E+01 6.8E+00 1.1E+01 3.5E+01
1.40E+02 1.5E+01 1.1E+01 3.5E+01
1.16E+02 7.2E-01 1.1E+01 3.5E+01
1.06E+03 7.2E-01 1.1E+01 3.5E+01
3.44E+01 6.8E+01 1.1E+01 3.5E+01
3.90E+01 2.7E+01 1.1E+01 3.5E+01
3.08E+01 9.0E+00 1.1E+01 3.5E+01
3.94E+01 8.8E+00 1.1E+01 3.5E+01
3.53E+01 5.4E+01 1.1E+01 3.5E+01
3.71 E+01 3.8E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.28E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.53E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.85E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-238
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
1 1 ug/L
B EaFA-L10-1313-T01-A 1 4.96E+03
B EaFA-L10-1313-T02-A 1 3.06E+03
B EaFA-L10-1313-T03-A 1 3.50E+03
B EaFA-L10-1313-T04-A 1 4.24E+03
B EaFA-L10-1313-T05-A 1 3.95E+03
B EaFA-L10-1313-T06-A 1 4.15E+03
B EaFA-L10-1313-T07-A 1 4.95E+03
B EaFA-L10-1313-T08-A 1 2.97E+03
B EaFA-L10-1313-T09-A 1 2.71E+03
B EaFA-L10-1313-T01-B 1 5.08E+03
B EaFA-L10-1313-T02-B 1 3.28E+03
B EaFA-L10-1313-T03-B 1 3.58E+03
B EaFA-L10-1313-T04-B 1 4.21 E+03
B EaFA-L10-1313-T05-B 1 4.09E+03
B EaFA-L10-1313-T06-B 1 4.81 E+03
B EaFA-L10-1313-T07-B 1 4.83E+03
B EaFA-L10-1313-T08-B 1 3.12E+03
B EaFA-L10-1313-T09-B 1 2.69E+03
B EaFA-L10-1313-T01-C 1 5.42E+03
B EaFA-L10-1313-T02-C 1 3.47E+03
B EaFA-L10-1313-T03-C 1 3.70E+03
B EaFA-L10-1313-T04-C 1 4.10E+03
B EaFA-L10-1313-T05-C 1 8.30E+03
B EaFA-L10-1313-T06-C 1 4.64E+03
B EaFA-L10-1313-T07-C 1 4.85E+03
B EaFA-L10-1313-T08-C 1 3.14E+03
B EaFA-L10-1313-T09-C 1 2.80E+03
B EaFA-L10-1313-B01-A 1 1.28E+02
B EaFA-L10-1313-B02-A 1 1.19E+02
B EaFA-L10-1313-B03-A 1 1.54E+02
B EaFA-L10-1313-B01-C 1 1.17E+02
B EaFA-L10-1313-B02-C 1 9.93E+01
B EaFA-L10-1313-B03-C 1 2.00E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.96E+03 2.7E-01 1.0E+00 3.2E+00
3.06E+03 1.3E+01 1.0E+00 3.2E+00
3.50E+03 1.0E+00 1.0E+00 3.2E+00 1000 100
4.24E+03 2.0E+00 1.0E+00 3.2E+00
3.95E+03 1.3E+00 1.0E+00 3.2E+00
4.15E+03 1.2E+00 1.0E+00 3.2E+00
4.95E+03 7.4E-01 1.0E+00 3.2E+00
2.97E+03 5.3E-01 1.0E+00 3.2E+00
2.71 E+03 5.1E-01 1.0E+00 3.2E+00
5.08E+03 6.3E-01 1.0E+00 3.2E+00
3.28E+03 9.6E-01 1.0E+00 3.2E+00
3.58E+03 9.8E-01 1.0E+00 3.2E+00 1000 100
4.21 E+03 1.8E+00 1.0E+00 3.2E+00
4.09E+03 1.3E+00 1.0E+00 3.2E+00
4.81 E+03 1.8E+00 1.0E+00 3.2E+00
4.83E+03 4.8E-01 1.0E+00 3.2E+00
3.12E+03 3.3E-01 1.0E+00 3.2E+00
2.69E+03 1.1E-01 1.0E+00 3.2E+00
5.42E+03 3.1E+00 1.0E+00 3.2E+00
3.47E+03 1.7E-01 1.0E+00 3.2E+00
3.70E+03 4.1E-01 1.0E+00 3.2E+00 1000 100
4.10E+03 2.7E+00 1.0E+00 3.2E+00
8.30E+03 3.3E-01 1.0E+00 3.2E+00
4.64E+03 2.4E+00 1.0E+00 3.2E+00
4.85E+03 1.4E+00 1.0E+00 3.2E+00
3.14E+03 8.9E-01 1.0E+00 3.2E+00
2.80E+03 8.0E-01 1.0E+00 3.2E+00
1.28E+02 2.3E+00 1.0E+00 3.2E+00
1.19E+02 1.0E+00 1.0E+00 3.2E+00
1.54E+02 3.0E+00 1.0E+00 3.2E+00
1.17E+02 3.6E+00 1.0E+00 3.2E+00
9.93E+01 2.1E+00 1.0E+00 3.2E+00
2.00E+02 3.5E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.37E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.46E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.61 E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-239
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
1 1 ug/L
Ba EaFA-L10-1313-T01-A 1 6.70E+03
Ba EaFA-L10-1313-T02-A 1 1.52E+03
Ba EaFA-L10-1313-T03-A 1 9.19E+02
Ba EaFA-L10-1313-T04-A 1 5.35E+02
Ba EaFA-L10-1313-T05-A 1 2.59E+02
Ba EaFA-L10-1313-T06-A 1 2.91 E+02
Ba EaFA-L10-1313-T07-A 1 3.05E+02
Ba EaFA-L10-1313-T08-A 1 3.85E+02
Ba EaFA-L10-1313-T09-A 1 8.24E+02
Ba EaFA-L10-1313-T01-B 1 6.73E+03
Ba EaFA-L10-1313-T02-B 1 1.61E+03
Ba EaFA-L10-1313-T03-B 1 1.05E+03
Ba EaFA-L10-1313-T04-B 1 6.54E+02
Ba EaFA-L10-1313-T05-B 1 2.58E+02
Ba EaFA-L10-1313-T06-B 1 3.17E+02
Ba EaFA-L10-1313-T07-B 1 3.39E+02
Ba EaFA-L10-1313-T08-B 1 3.28E+02
Ba EaFA-L10-1313-T09-B 1 7.75E+02
Ba EaFA-L10-1313-T01-C 1 7.18E+03
Ba EaFA-L10-1313-T02-C 1 1.72E+03
Ba EaFA-L10-1313-T03-C 1 1.14E+03
Ba EaFA-L10-1313-T04-C 1 5.91 E+02
Ba EaFA-L10-1313-T05-C 1 2.47E+02
Ba EaFA-L10-1313-T06-C 1 3.29E+02
Ba EaFA-L10-1313-T07-C 1 3.71E+02
Ba EaFA-L10-1313-T08-C 1 3.60E+02
Ba EaFA-L10-1313-T09-C 1 7.73E+02
Ba EaFA-L10-1313-B01-A 1 5.00E-01 U1/2
Ba EaFA-L10-1313-B02-A 1 5.00E-01 U1/2
Ba EaFA-L10-1313-B03-A 1 1.47E+02
Ba EaFA-L10-1313-B01-C 1 5.00E-01 U1/2
Ba EaFA-L10-1313-B02-C 1 5.00E-01 U1/2
Ba EaFA-L10-1313-B03-C 1 1.67E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.70E+03 5.2E-01 1.0E+00 3.2E+00
1.52E+03 1.3E+01 1.0E+00 3.2E+00
9.19E+02 5.9E-01 1.0E+00 3.2E+00 10 300
5.35E+02 1.6E-01 1.0E+00 3.2E+00
2.59E+02 4.6E-01 1.0E+00 3.2E+00
2.91 E+02 4.2E-01 1.0E+00 3.2E+00
3.05E+02 6.9E-01 1.0E+00 3.2E+00
3.85E+02 4.0E-01 1.0E+00 3.2E+00
8.24E+02 5.0E-01 1.0E+00 3.2E+00
6.73E+03 4.9E-01 1.0E+00 3.2E+00
1.61E+03 8.5E-01 1.0E+00 3.2E+00
1.05E+03 8.5E-01 1.0E+00 3.2E+00 10 300
6.54E+02 5.0E-01 1.0E+00 3.2E+00
2.58E+02 9.6E-01 1.0E+00 3.2E+00
3.17E+02 3.1E-01 1.0E+00 3.2E+00
3.39E+02 1.1E+00 1.0E+00 3.2E+00
3.28E+02 1.6E-01 1.0E+00 3.2E+00
7.75E+02 3.3E-01 1.0E+00 3.2E+00
7.18E+03 3.1E+00 1.0E+00 3.2E+00
1.72E+03 4.9E-01 1.0E+00 3.2E+00
1.14E+03 5.6E-01 1.0E+00 3.2E+00 10 300
5.91 E+02 3.6E-01 1.0E+00 3.2E+00
2.47E+02 4.6E-01 1.0E+00 3.2E+00
3.29E+02 6.9E+00 1.0E+00 3.2E+00
3.71 E+02 2.7E-01 1.0E+00 3.2E+00
3.60E+02 2.5E-01 1.0E+00 3.2E+00
7.73E+02 7.9E-02 1.0E+00 3.2E+00
5.00E-01 2.3E+02 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
1.47E+02 9.8E-01 1.0E+00 3.2E+00
5.00E-01 3.9E+02 1.0E+00 3.2E+00
5.00E-01 2.2E+01 1.0E+00 3.2E+00
1.67E+02 1.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.35E+03 81 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.65E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.86E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-240
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
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Be
Be
Be
Be
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Be
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Sample Inter
Sample Dilution Cone. Qualifier Revi
1 1 ug/L |
EaFA-L10-1313-T01-A 1 1.06E+02
EaFA-L10-1313-T02-A 1 9.50E-01 U1/2
EaFA-L10-1313-T03-A 1 9.50E-01 U1/2
EaFA-L10-1313-T04-A 1 9.50E-01 U1/2
EaFA-L10-1313-T05-A 1 9.50E-01 U1/2
EaFA-L10-1313-T06-A 1 5.22E+00 E
EaFA-L10-1313-T07-A 1 4.05E+00 E
EaFA-L10-1313-T08-A 1 1.91E+02
EaFA-L10-1313-T09-A 1 2.31 E+02
EaFA-L10-1313-T01-B 1 1.09E+02
EaFA-L10-1313-T02-B 1 9.50E-01 U1/2
EaFA-L10-1313-T03-B 1 9.50E-01 U1/2
EaFA-L10-1313-T04-B 1 9.50E-01 U1/2
EaFA-L10-1313-T05-B 1 9.50E-01 U1/2
EaFA-L10-1313-T06-B 1 9.50E-01 U1/2
EaFA-L10-1313-T07-B 1 6.60E+00
EaFA-L10-1313-T08-B 1 1.86E+02
EaFA-L10-1313-T09-B 1 2.32E+02
EaFA-L10-1313-T01-C 1 1.15E+02
EaFA-L10-1313-T02-C 1 9.50E-01 U1/2
EaFA-L10-1313-T03-C 1 9.50E-01 U1/2
EaFA-L10-1313-T04-C 1 9.50E-01 U1/2
EaFA-L10-1313-T05-C 1 9.50E-01 U1/2
EaFA-L10-1313-T06-C 1 9.50E-01 U1/2
EaFA-L10-1313-T07-C 1 7.83E+00
EaFA-L10-1313-T08-C 1 2.00E+02
EaFA-L10-1313-T09-C 1 2.43E+02
EaFA-L10-1313-B01-A 1 9.50E-01 U1/2
EaFA-L10-1313-B02-A 1 9.50E-01 U1/2
EaFA-L10-1313-B03-A 1 9.50E-01 U1/2
EaFA-L10-1313-B01-C 1 9.50E-01 U1/2
EaFA-L10-1313-B02-C 1 9.50E-01 U1/2
EaFA-L10-1313-B03-C 1 9.50E-01 U1/2
ial ICP-OES Spike Sol'n
S\N Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+02 6.1E-01 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 3.6E+01 1.9E+00 6.0E+00 10 300
9.50E-01 2.9E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
5.22E+00 2.1E+00 1.9E+00 6.0E+00
4.05E+00 9.1E+00 1.9E+00 6.0E+00
1.91 E+02 7.0E-02 1.9E+00 6.0E+00
2. 31 E+02 7.4E-02 1.9E+00 6.0E+00
1.09E+02 4.3E-01 1.9E+00 6.0E+00
9.50E-01 5.7E+02 1.9E+00 6.0E+00
9.50E-01 1.1 E+02 1.9E+00 6.0E+00 10 300
9.50E-01 3.2E+01 1.9E+00 6.0E+00
9.50E-01 4.1E+03 1.9E+00 6.0E+00
9.50E-01 3.4E+01 1.9E+00 6.0E+00
6.60E+00 2.6E+00 1.9E+00 6.0E+00
1.86E+02 2.6E-02 1.9E+00 6.0E+00
2.32E+02 8.2E-01 1.9E+00 6.0E+00
1.15E+02 2.9E+00 1.9E+00 6.0E+00
9.50E-01 4.0E+02 1.9E+00 6.0E+00
9.50E-01 2.2E+01 1.9E+00 6.0E+00 10 300
9.50E-01 8.2E+01 1.9E+00 6.0E+00
9.50E-01 8.8E+01 1.9E+00 6.0E+00
9.50E-01 2.8E+01 1.9E+00 6.0E+00
7.83E+00 2.4E+00 1.9E+00 6.0E+00
2.00E+02 1.4E-01 1.9E+00 6.0E+00
2.43E+02 1.1E+00 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 8.3E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 3.9E+01 1.9E+00 6.0E+00
9.50E-01 6.7E+01 1.9E+00 6.0E+00
9.50E-01 7.0E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.81 E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.17E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-241
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Sample Inte
Sample Dilution Cone. Qualifier Rev
1 1 ug/L
EaFA-L10-1313-T01-A 1 1.10E+OOU1/2
EaFA-L10-1313-T02-A 1 1.10E+OOU1/2
EaFA-L10-1313-T03-A 1 1.10E+OOU1/2
EaFA-L10-1313-T04-A 1 1.10E+OOU1/2
EaFA-L10-1313-T05-A 1 1.10E+OOU1/2
EaFA-L10-1313-T06-A 1 3.14E+01
EaFA-L10-1313-T07-A 1 2.96E+01
EaFA-L10-1313-T08-A 1 2.57E+01
EaFA-L10-1313-T09-A 1 3.04E+01
EaFA-L10-1313-T01-B 1 1.10E+OOU1/2
EaFA-L10-1313-T02-B 1 1.10E+OOU1/2
EaFA-L10-1313-T03-B 1 1.10E+OOU1/2
EaFA-L10-1313-T04-B 1 1.10E+OOU1/2
EaFA-L10-1313-T05-B 1 1.10E+OOU1/2
EaFA-L10-1313-T06-B 1 2.88E+00 E
EaFA-L10-1313-T07-B 1 3.58E+01
EaFA-L10-1313-T08-B 1 2.69E+01
EaFA-L10-1313-T09-B 1 3.09E+01
EaFA-L10-1313-T01-C 1 1.10E+OOU1/2
EaFA-L10-1313-T02-C 1 1.10E+OOU1/2
EaFA-L10-1313-T03-C 1 1.10E+OOU1/2
EaFA-L10-1313-T04-C 1 1.10E+OOU1/2
EaFA-L10-1313-T05-C 1 4.22E+00 E
EaFA-L10-1313-T06-C 1 2.96E+00 E
EaFA-L10-1313-T07-C 1 3.80E+01
EaFA-L10-1313-T08-C 1 2.66E+01
EaFA-L10-1313-T09-C 1 3.19E+01
EaFA-L10-1313-B01-A 1 1.10E+OOU1/2
EaFA-L10-1313-B02-A 1 1.10E+OOU1/2
EaFA-L10-1313-B03-A 1 1.10E+OOU1/2
EaFA-L10-1313-B01-C 1 1.10E+OOU1/2
EaFA-L10-1313-B02-C 1 1.10E+OOU1/2
EaFA-L10-1313-B03-C 1 1.10E+OOU1/2
rnal ICP-OES Spike Sol'n
lew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 4.6E+01 2.2E+00 7.0E+00
1.10E+00 7.9E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+01 2.2E+00 7.0E+00 10 300
1.10E+00 1.1E+02 2.2E+00 7.0E+00
1.10E+00 1.5E+02 2.2E+00 7.0E+00
3.14E+01 1.2E+00 2.2E+00 7.0E+00
2.96E+01 2.8E+00 2.2E+00 7.0E+00
2.57E+01 1.1E+00 2.2E+00 7.0E+00
3.04E+01 8.9E-01 2.2E+00 7.0E+00
1.10E+00 2.4E+01 2.2E+00 7.0E+00
1.10E+00 9.0E+01 2.2E+00 7.0E+00
1.10E+00 6.1E+01 2.2E+00 7.0E+00 10 300
1.10E+00 9.3E+01 2.2E+00 7.0E+00
1.10E+00 2.8E+02 2.2E+00 7.0E+00
2.88E+00 3.4E+01 2.2E+00 7.0E+00
3.58E+01 1.1E+00 2.2E+00 7.0E+00
2.69E+01 5.6E-01 2.2E+00 7.0E+00
3.09E+01 6.7E-01 2.2E+00 7.0E+00
1.10E+00 4.8E+01 2.2E+00 7.0E+00
1.10E+00 5.9E+01 2.2E+00 7.0E+00
1.10E+00 3.8E+01 2.2E+00 7.0E+00 10 300
1.10E+00 1.0E+03 2.2E+00 7.0E+00
4.22E+00 2.8E+00 2.2E+00 7.0E+00
2.96E+00 2.8E+01 2.2E+00 7.0E+00
3.80E+01 1.6E+00 2.2E+00 7.0E+00
2.66E+01 1.8E+00 2.2E+00 7.0E+00
3.19E+01 1.0E+00 2.2E+00 7.0E+00
1.10E+00 1.4E+02 2.2E+00 7.0E+00
1.10E+00 8.4E+01 2.2E+00 7.0E+00
1.10E+00 1.6E+02 2.2E+00 7.0E+00
1.10E+00 3.0E+01 2.2E+00 7.0E+00
1.10E+00 4.4E+01 2.2E+00 7.0E+00
1.10E+00 3.4E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.82E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.99E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-242
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
1 1 ug/L
Ca EaFA-L10-1313-T01-A 1 4.19E+03
Ca EaFA-L10-1313-T02-A 1 2.59E+04
Ca EaFA-L10-1313-T03-A 1 7.38E+04
Ca EaFA-L10-1313-T04-A 1 1.16E+05
Ca EaFA-L10-1313-T05-A 1 1.39E+05
Ca EaFA-L10-1313-T06-A 1 1.52E+05
Ca EaFA-L10-1313-T07-A 1 1.72E+05
Ca EaFA-L10-1313-T08-A 1 1.26E+05
Ca EaFA-L10-1313-T09-A 1 1.22E+05
Ca EaFA-L10-1313-T01-B 1 4.24E+03
Ca EaFA-L10-1313-T02-B 1 2.57E+04
Ca EaFA-L10-1313-T03-B 1 7.84E+04
Ca EaFA-L10-1313-T04-B 1 1.12E+05
Ca EaFA-L10-1313-T05-B 1 1.42E+05
Ca EaFA-L10-1313-T06-B 1 1.66E+05
Ca EaFA-L10-1313-T07-B 1 1.69E+05
Ca EaFA-L10-1313-T08-B 1 1.29E+05
Ca EaFA-L10-1313-T09-B 1 1.20E+05
Ca EaFA-L10-1313-T01-C 1 4.50E+03
Ca EaFA-L10-1313-T02-C 1 2.85E+04
Ca EaFA-L10-1313-T03-C 1 7.24E+04
Ca EaFA-L10-1313-T04-C 1 1.11E+05
Ca EaFA-L10-1313-T05-C 1 3.02E+05
Ca EaFA-L10-1313-T06-C 1 1.58E+05
Ca EaFA-L10-1313-T07-C 1 1.72E+05
Ca EaFA-L10-1313-T08-C 1 1.31E+05
Ca EaFA-L10-1313-T09-C 1 1.25E+05
Ca EaFA-L10-1313-B01-A 1 2.34E+01
Ca EaFA-L10-1313-B02-A 1 1.49E+01
Ca EaFA-L10-1313-B03-A 1 1.67E+01
Ca EaFA-L10-1313-B01-C 1 1.30E+OOU1/2
Ca EaFA-L10-1313-B02-C 1 5.33E+00 E
Ca EaFA-L10-1313-B03-C 1 1.44E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.19E+03 4.3E+00 2.6E+00 8.3E+00
2.59E+04 1.4E+01 2.6E+00 8.3E+00
7.38E+04 5.8E-01 2.6E+00 8.3E+00 1000 100
1.16E+05 5.9E-01 2.6E+00 8.3E+00
1.39E+05 2.9E-01 2.6E+00 8.3E+00
1.52E+05 3.5E-01 2.6E+00 8.3E+00
1.72E+05 8.6E-01 2.6E+00 8.3E+00
1.26E+05 2.9E-01 2.6E+00 8.3E+00
1.22E+05 1.5E-01 2.6E+00 8.3E+00
4.24E+03 6.4E-01 2.6E+00 8.3E+00
2.57E+04 8.8E-01 2.6E+00 8.3E+00
7.84E+04 7.6E-01 2.6E+00 8.3E+00 1000 100
1.12E+05 4.4E-01 2.6E+00 8.3E+00
1.42E+05 1.1E+00 2.6E+00 8.3E+00
1.66E+05 6.6E-01 2.6E+00 8.3E+00
1.69E+05 9.2E-01 2.6E+00 8.3E+00
1.29E+05 4.3E-01 2.6E+00 8.3E+00
1.20E+05 3.8E-01 2.6E+00 8.3E+00
4.50E+03 4.1E+00 2.6E+00 8.3E+00
2.85E+04 8.3E-01 2.6E+00 8.3E+00
7.24E+04 2.0E-01 2.6E+00 8.3E+00 1000 100
1.11E+05 4.4E-01 2.6E+00 8.3E+00
3.02E+05 5.7E-01 2.6E+00 8.3E+00
1.58E+05 6.9E+00 2.6E+00 8.3E+00
1.72E+05 6.0E-01 2.6E+00 8.3E+00
1.31E+05 7.9E-01 2.6E+00 8.3E+00
1.25E+05 1.5E-01 2.6E+00 8.3E+00
2.34E+01 8.6E+00 2.6E+00 8.3E+00
1.49E+01 4.2E+01 2.6E+00 8.3E+00
1.67E+01 2.8E+02 2.6E+00 8.3E+00
1.30E+00 9.0E+02 2.6E+00 8.3E+00
5.33E+00 2.6E+02 2.6E+00 8.3E+00
1.44E+02 2.2E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.47E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.92E+04 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.33E+04 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-243
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qualifier
1 1 ug/L
Cr EaFA-L10-1313-T01-A 1 6.84E+02
Cr EaFA-L10-1313-T02-A 1 3.46E+02
Cr EaFA-L10-1313-T03-A 1 3.20E+02
Cr EaFA-L10-1313-T04-A 1 2.65E+02
Cr EaFA-L10-1313-T05-A 1 1.72E+01
Cr EaFA-L10-1313-T06-A 1 6.00E-01 U1/2
Cr EaFA-L10-1313-T07-A 1 2.24E+00 E
Cr EaFA-L10-1313-T08-A 1 1.32E+03
Cr EaFA-L10-1313-T09-A 1 1.62E+03
Cr EaFA-L10-1313-T01-B 1 7.20E+02
Cr EaFA-L10-1313-T02-B 1 3.85E+02
Cr EaFA-L10-1313-T03-B 1 3.16E+02
Cr EaFA-L10-1313-T04-B 1 2.90E+02
Cr EaFA-L10-1313-T05-B 1 2.97E+01
Cr EaFA-L10-1313-T06-B 1 9.16E+01
Cr EaFA-L10-1313-T07-B 1 1.78E+OOE
Cr EaFA-L10-1313-T08-B 1 1.07E+03
Cr EaFA-L10-1313-T09-B 1 1.59E+03
Cr EaFA-L10-1313-T01-C 1 7.19E+02
Cr EaFA-L10-1313-T02-C 1 4.00E+02
Cr EaFA-L10-1313-T03-C 1 3.47E+02
Cr EaFA-L10-1313-T04-C 1 2.82E+02
Cr EaFA-L10-1313-T05-C 1 1.95E+01
Cr EaFA-L10-1313-T06-C 1 7.49E+01
Cr EaFA-L10-1313-T07-C 1 2.89E+00 E
Cr EaFA-L10-1313-T08-C 1 1.41E+03
Cr EaFA-L10-1313-T09-C 1 1.66E+03
Cr EaFA-L10-1313-B01-A 1 6.00E-01 U1/2
Cr EaFA-L10-1313-B02-A 1 6.00E-01 U1/2
Cr EaFA-L10-1313-B03-A 1 6.26E+00
Cr EaFA-L10-1313-B01-C 1 6.00E-01 U1/2
Cr EaFA-L10-1313-B02-C 1 6.00E-01 U1/2
Cr EaFA-L10-1313-B03-C 1 8.44E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.84E+02 1.4E+00 1.2E+00 3.8E+00
3.46E+02 1.3E+01 1.2E+00 3.8E+00
3.20E+02 9.1E-01 1.2E+00 3.8E+00 10 300
2.65E+02 1.0E+00 1.2E+00 3.8E+00
1.72E+01 2.9E+00 1.2E+00 3.8E+00
6.00E-01 2.2E+02 1.2E+00 3.8E+00
2.24E+00 7.6E+01 1.2E+00 3.8E+00
1.32E+03 7.5E-01 1.2E+00 3.8E+00
1.62E+03 2.6E-01 1.2E+00 3.8E+00
7.20E+02 1.0E+00 1.2E+00 3.8E+00
3.85E+02 6.1E-01 1.2E+00 3.8E+00
3.16E+02 1.2E+00 1.2E+00 3.8E+00 10 300
2.90E+02 2.4E-01 1.2E+00 3.8E+00
2.97E+01 3.2E+00 1.2E+00 3.8E+00
9.16E+01 1.3E+00 1.2E+00 3.8E+00
1.78E+00 8.6E+01 1.2E+00 3.8E+00
1.07E+03 1.9E-01 1.2E+00 3.8E+00
1.59E+03 3.6E-01 1.2E+00 3.8E+00
7.19E+02 3.2E+00 1.2E+00 3.8E+00
4.00E+02 5.9E-01 1.2E+00 3.8E+00
3.47E+02 3.9E-01 1.2E+00 3.8E+00 10 300
2.82E+02 2.7E-01 1.2E+00 3.8E+00
1.95E+01 1.2E+01 1.2E+00 3.8E+00
7.49E+01 5.4E+00 1.2E+00 3.8E+00
2.89E+00 6.3E+01 1.2E+00 3.8E+00
1.41E+03 6.6E-01 1.2E+00 3.8E+00
1.66E+03 5.9E-01 1.2E+00 3.8E+00
6.00E-01 5.1E+01 1.2E+00 3.8E+00
6.00E-01 1.2E+03 1.2E+00 3.8E+00
6.26E+00 2.3E+01 1.2E+00 3.8E+00
6.00E-01 1.2E+02 1.2E+00 3.8E+00
6.00E-01 7.8E+01 1.2E+00 3.8E+00
8.44E+00 1.4E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.00E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.15E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.32E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-244
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Co Sample Dilution Cone. Qualifier Revi
1 1 ug/L |
Co EaFA-L10-1313-T01-A 1 2.04E+01
Co EaFA-L10-1313-T02-A 1 9.00E-01 U1/2
Co EaFA-L10-1313-T03-A 1 9.00E-01 U1/2
Co EaFA-L10-1313-T04-A 1 9.00E-01 U1/2
Co EaFA-L10-1313-T05-A 1 5.76E+01
Co EaFA-L10-1313-T06-A 1 2.26E+02
Co EaFA-L10-1313-T07-A 1 2.50E+02
Co EaFA-L10-1313-T08-A 1 2.51 E+02
Co EaFA-L10-1313-T09-A 1 3.57E+02
Co EaFA-L10-1313-T01-B 1 2.14E+01
Co EaFA-L10-1313-T02-B 1 9.00E-01 U1/2
Co EaFA-L10-1313-T03-B 1 9.00E-01 U1/2
Co EaFA-L10-1313-T04-B 1 9.00E-01 U1/2
Co EaFA-L10-1313-T05-B 1 4.11E+01
Co EaFA-L10-1313-T06-B 1 4.13E+01
Co EaFA-L10-1313-T07-B 1 2.57E+02
Co EaFA-L10-1313-T08-B 1 2.37E+02
Co EaFA-L10-1313-T09-B 1 3.56E+02
Co EaFA-L10-1313-T01-C 1 2.03E+01
Co EaFA-L10-1313-T02-C 1 9.00E-01 U1/2
Co EaFA-L10-1313-T03-C 1 9.00E-01 U1/2
Co EaFA-L10-1313-T04-C 1 9.00E-01 U1/2
Co EaFA-L10-1313-T05-C 1 1.29E+02
Co EaFA-L10-1313-T06-C 1 5.02E+01
Co EaFA-L10-1313-T07-C 1 2.64E+02
Co EaFA-L10-1313-T08-C 1 2.59E+02
Co EaFA-L10-1313-T09-C 1 3.73E+02
Co EaFA-L10-1313-B01-A 1 9.00E-01 U1/2
Co EaFA-L10-1313-B02-A 1 9.00E-01 U1/2
Co EaFA-L10-1313-B03-A 1 9.00E-01 U1/2
Co EaFA-L10-1313-B01-C 1 9.00E-01 U1/2
Co EaFA-L10-1313-B02-C 1 9.00E-01 U1/2
Co EaFA-L10-1313-B03-C 1 9.00E-01 U1/2
ial ICP-OES Spike Sol'n
S\N Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.04E+01 1.1E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 6.0E+01 1.8E+00 5.7E+00 10 300
9.00E-01 1.8E+02 1.8E+00 5.7E+00
5.76E+01 5.4E+00 1.8E+00 5.7E+00
2.26E+02 9.1E-01 1.8E+00 5.7E+00
2.50E+02 8.9E-01 1.8E+00 5.7E+00
2.51 E+02 6.1E-01 1.8E+00 5.7E+00
3.57E+02 3.7E-01 1.8E+00 5.7E+00
2.14E+01 1.7E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 6.0E+01 1.8E+00 5.7E+00 10 300
9.00E-01 4.6E+01 1.8E+00 5.7E+00
4.11E+01 4.9E+00 1.8E+00 5.7E+00
4.13E+01 6.4E+00 1.8E+00 5.7E+00
2.57E+02 2.8E+00 1.8E+00 5.7E+00
2.37E+02 8.3E-01 1.8E+00 5.7E+00
3.56E+02 5.3E-01 1.8E+00 5.7E+00
2.03E+01 4.0E+00 1.8E+00 5.7E+00
9.00E-01 3.0E+01 1.8E+00 5.7E+00
9.00E-01 4.6E+01 1.8E+00 5.7E+00 10 300
9.00E-01 7.2E+01 1.8E+00 5.7E+00
1.29E+02 1.7E+00 1.8E+00 5.7E+00
5.02E+01 4.4E+00 1.8E+00 5.7E+00
2.64E+02 9.1E-01 1.8E+00 5.7E+00
2.59E+02 1.0E+00 1.8E+00 5.7E+00
3.73E+02 4.0E-01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 5.3E+01 1.8E+00 5.7E+00
9.00E-01 4.4E+01 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 3.7E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.73E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.90E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-245
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cu Sample Dilution Cone. Qualifier Revi
1 1 ug/L |
Cu EaFA-L10-1313-T01-A 1 2.24E+03
Cu EaFA-L10-1313-T02-A 1 9.64E+00 E
Cu EaFA-L10-1313-T03-A 1 1.85E+OOU1/2
Cu EaFA-L10-1313-T04-A 1 8.42E+00 E
Cu EaFA-L10-1313-T05-A 1 9.72E+00 E
Cu EaFA-L10-1313-T06-A 1 1.19E+02
Cu EaFA-L10-1313-T07-A 1 7.18E+01
Cu EaFA-L10-1313-T08-A 1 2.47E+03
Cu EaFA-L10-1313-T09-A 1 2.82E+03
Cu EaFA-L10-1313-T01-B 1 2.30E+03
Cu EaFA-L10-1313-T02-B 1 9.24E+00 E
Cu EaFA-L10-1313-T03-B 1 4.13E+00 E
Cu EaFA-L10-1313-T04-B 1 5.93E+00 E
Cu EaFA-L10-1313-T05-B 1 1.19E+01
Cu EaFA-L10-1313-T06-B 1 1.27E+01
Cu EaFA-L10-1313-T07-B 1 1.39E+02
Cu EaFA-L10-1313-T08-B 1 2.40E+03
Cu EaFA-L10-1313-T09-B 1 2.77E+03
Cu EaFA-L10-1313-T01-C 1 2.39E+03
Cu EaFA-L10-1313-T02-C 1 1.12E+01 E
Cu EaFA-L10-1313-T03-C 1 4.02E+00 E
Cu EaFA-L10-1313-T04-C 1 7.74E+00 E
Cu EaFA-L10-1313-T05-C 1 1.04E+01 E
Cu EaFA-L10-1313-T06-C 1 1.24E+01
Cu EaFA-L10-1313-T07-C 1 1.59E+02
Cu EaFA-L10-1313-T08-C 1 2.57E+03
Cu EaFA-L10-1313-T09-C 1 2.90E+03
Cu EaFA-L10-1313-B01-A 1 1.85E+OOU1/2
Cu EaFA-L10-1313-B02-A 1 9.92E+00 E
Cu EaFA-L10-1313-B03-A 1 2.86E+01
Cu EaFA-L10-1313-B01-C 1 1.85E+OOU1/2
Cu EaFA-L10-1313-B02-C 1 1.18E+01 E
Cu EaFA-L10-1313-B03-C 1 1.42E+01
ial ICP-OES Spike Sol'n
S\N Cone. RSD MDL ML Cone. Volume
Mg/L % ug/L ug/L ug/L uL
2.24E+03 5.9E-01 3.7E+00 1.2E+01
9.64E+00 4.6E+01 3.7E+00 1.2E+01
1.85E+00 2.1E+02 3.7E+00 1.2E+01 10 300
8.42E+00 4.9E+01 3.7E+00 1.2E+01
9.72E+00 4.0E+01 3.7E+00 1.2E+01
1.19E+02 7.7E+00 3.7E+00 1.2E+01
7.18E+01 1.0E+00 3.7E+00 1.2E+01
2.47E+03 2.2E-01 3.7E+00 1.2E+01
2.82E+03 3.8E-01 3.7E+00 1.2E+01
2.30E+03 2.8E-01 3.7E+00 1.2E+01
9.24E+00 6.8E+01 3.7E+00 1.2E+01
4.13E+00 5.7E+01 3.7E+00 1.2E+01 10 300
5.93E+00 3.3E+01 3.7E+00 1.2E+01
1.19E+01 5.1E+01 3.7E+00 1.2E+01
1.27E+01 2.0E+01 3.7E+00 1.2E+01
1.39E+02 3.3E+00 3.7E+00 1.2E+01
2.40E+03 2.5E-01 3.7E+00 1.2E+01
2.77E+03 1.8E-01 3.7E+00 1.2E+01
2.39E+03 3.0E+00 3.7E+00 1.2E+01
1.12E+01 4.6E+01 3.7E+00 1.2E+01
4.02E+00 6.2E+01 3.7E+00 1.2E+01 10 300
7.74E+00 1.3E+01 3.7E+00 1.2E+01
1.04E+01 8.9E+01 3.7E+00 1.2E+01
1.24E+01 4.1E+01 3.7E+00 1.2E+01
1.59E+02 8.9E-01 3.7E+00 1.2E+01
2.57E+03 6.1E-01 3.7E+00 1.2E+01
2.90E+03 6.0E-01 3.7E+00 1.2E+01
1.85E+00 1.2E+03 3.7E+00 1.2E+01
9.92E+00 1.3E+01 3.7E+00 1.2E+01
2.86E+01 2.1E+01 3.7E+00 1.2E+01
1.85E+00 4.5E+00 3.7E+00 1.2E+01
1.18E+01 1.8E+00 3.7E+00 1.2E+01
1.42E+01 3.2E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.66E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.81 E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.96E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-246
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inte
Fe Sample Dilution Cone. Qualifier Rev
1 1 ug/L
Fe EaFA-L10-1313-T01-A 1 8.28E+02
Fe EaFA-L10-1313-T02-A 1 1.09E+01
Fe EaFA-L10-1313-T03-A 1 3.09E+00 E
Fe EaFA-L10-1313-T04-A 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T05-A 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T06-A 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T07-A 1 3.91E+00 E
Fe EaFA-L10-1313-T08-A 1 6.83E+03
Fe EaFA-L10-1313-T09-A 1 2.65E+04
Fe EaFA-L10-1313-T01-B 1 8.49E+02
Fe EaFA-L10-1313-T02-B 1 1.03E+01
Fe EaFA-L10-1313-T03-B 1 2.49E+00 E
Fe EaFA-L10-1313-T04-B 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T05-B 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T06-B 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T07-B 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T08-B 1 4.50E+03
Fe EaFA-L10-1313-T09-B 1 2.76E+04
Fe EaFA-L10-1313-T01-C 1 8.74E+02
Fe EaFA-L10-1313-T02-C 1 1.05E+01
Fe EaFA-L10-1313-T03-C 1 4.42E+00 E
Fe EaFA-L10-1313-T04-C 1 5.24E+00 E
Fe EaFA-L10-1313-T05-C 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T06-C 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T07-C 1 1.00E+OOU1/2
Fe EaFA-L10-1313-T08-C 1 7.25E+03
Fe EaFA-L10-1313-T09-C 1 2.88E+04
Fe EaFA-L10-1313-B01-A 1 1.00E+OOU1/2
Fe EaFA-L10-1313-B02-A 1 1.30E+01
Fe EaFA-L10-1313-B03-A 1 2.04E+01
Fe EaFA-L10-1313-B01-C 1 1.00E+OOU1/2
Fe EaFA-L10-1313-B02-C 1 3.41E+00 E
Fe EaFA-L10-1313-B03-C 1 1.24E+01
rnal ICP-OES Spike Sol'n
lew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.28E+02 1.6E+00 2.0E+00 6.4E+00
1.09E+01 2.1E+01 2.0E+00 6.4E+00
3.09E+00 6.5E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
3.91 E+00 8.0E+01 2.0E+00 6.4E+00
6.83E+03 1.9E-01 2.0E+00 6.4E+00
2.65E+04 9.7E-01 2.0E+00 6.4E+00
8.49E+02 1.4E+00 2.0E+00 6.4E+00
1.03E+01 6.1 E+00 2.0E+00 6.4E+00
2.49E+00 1.3E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
4.50E+03 1.3E-01 2.0E+00 6.4E+00
2.76E+04 2.6E-01 2.0E+00 6.4E+00
8.74E+02 3.3E+00 2.0E+00 6.4E+00
1.05E+01 4.5E+00 2.0E+00 6.4E+00
4.42E+00 8.4E+00 2.0E+00 6.4E+00 1000 100
5.24E+00 5.3E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 8.2E+01 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00
7.25E+03 8.3E-01 2.0E+00 6.4E+00
2.88E+04 6.1E-01 2.0E+00 6.4E+00
1.00E+00 7.0E+01 2.0E+00 6.4E+00
1.30E+01 1.3E+00 2.0E+00 6.4E+00
2.04E+01 1.4E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+02 2.0E+00 6.4E+00
3.41 E+00 1.1E+01 2.0E+00 6.4E+00
1.24E+01 7.9E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.54E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.51 E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-247
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Pb Sample Dilution Cone. Qualifier Revi
1 1 1 ug/L |
Pb EaFA-L10-1313-T01-A 1 5.03E+02
Pb EaFA-L10-1313-T02-A 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T03-A 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T04-A 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T05-A 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T06-A 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T07-A 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T08-A 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T09-A 1 8.66E+01
Pb EaFA-L10-1313-T01-B 1 4.75E+02
Pb EaFA-L10-1313-T02-B 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T03-B 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T04-B 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T05-B 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T06-B 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T07-B 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T08-B 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T09-B 1 6.88E+01
Pb EaFA-L10-1313-T01-C 1 4.80E+02
Pb EaFA-L10-1313-T02-C 1 1.64E+01 E
Pb EaFA-L10-1313-T03-C 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T04-C 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T05-C 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T06-C 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T07-C 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T08-C 1 3.40E+00 U1/2
Pb EaFA-L10-1313-T09-C 1 7.11E+01
Pb EaFA-L10-1313-B01-A 1 3.40E+00 U1/2
Pb EaFA-L10-1313-B02-A 1 2.52E+01
Pb EaFA-L10-1313-B03-A 1 3.40E+00 U1/2
Pb EaFA-L10-1313-B01-C 1 3.40E+00 U1/2
Pb EaFA-L10-1313-B02-C 1 1.80E+01 E
Pb EaFA-L10-1313-B03-C 1 2.17E+01
ial ICP-OES Spike Sol'n
S\N Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.03E+02 2.4E+00 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
3.40E+00 4.4E+01 6.8E+00 2.2E+01 10 300
3.40E+00 3.2E+02 6.8E+00 2.2E+01
3.40E+00 2.5E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 3.3E+01 6.8E+00 2.2E+01
3.40E+00 1.8E+02 6.8E+00 2.2E+01
8.66E+01 8.1E+00 6.8E+00 2.2E+01
4.75E+02 2.9E+00 6.8E+00 2.2E+01
3.40E+00 2.1E+03 6.8E+00 2.2E+01
3.40E+00 3.7E+01 6.8E+00 2.2E+01 10 300
3.40E+00 2.5E+01 6.8E+00 2.2E+01
3.40E+00 3.1E+01 6.8E+00 2.2E+01
3.40E+00 4.9E+01 6.8E+00 2.2E+01
3.40E+00 4.2E+02 6.8E+00 2.2E+01
3.40E+00 1.5E+01 6.8E+00 2.2E+01
6.88E+01 4.5E+00 6.8E+00 2.2E+01
4.80E+02 7.8E+00 6.8E+00 2.2E+01
1.64E+01 5.7E+01 6.8E+00 2.2E+01
3.40E+00 7.2E+01 6.8E+00 2.2E+01 10 300
3.40E+00 8.9E+01 6.8E+00 2.2E+01
3.40E+00 3.5E+01 6.8E+00 2.2E+01
3.40E+00 3.3E+01 6.8E+00 2.2E+01
3.40E+00 5.5E+02 6.8E+00 2.2E+01
3.40E+00 5.4E+01 6.8E+00 2.2E+01
7.11E+01 1.4E+01 6.8E+00 2.2E+01
3.40E+00 3.3E+01 6.8E+00 2.2E+01
2.52E+01 4.1E+01 6.8E+00 2.2E+01
3.40E+00 3.4E+02 6.8E+00 2.2E+01
3.40E+00 3.1E+02 6.8E+00 2.2E+01
1.80E+01 1.6E+01 6.8E+00 2.2E+01
2.17E+01 5.9E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.68E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.85E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-248
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
1 1 ug/L
Li EaFA-L10-1313-T01-A 1 1.41E+03
Li EaFA-L10-1313-T02-A 1 2.23E+03
Li EaFA-L10-1313-T03-A 1 2.79E+03
Li EaFA-L10-1313-T04-A 1 3.15E+03
Li EaFA-L10-1313-T05-A 1 3.15E+03
Li EaFA-L10-1313-T06-A 1 3.16E+03
Li EaFA-L10-1313-T07-A 1 3.81 E+03
Li EaFA-L10-1313-T08-A 1 1.60E+03
Li EaFA-L10-1313-T09-A 1 1.40E+03
Li EaFA-L10-1313-T01-B 1 1.41 E+03
Li EaFA-L10-1313-T02-B 1 2.38E+03
Li EaFA-L10-1313-T03-B 1 2.84E+03
Li EaFA-L10-1313-T04-B 1 3.04E+03
Li EaFA-L10-1313-T05-B 1 3.18E+03
Li EaFA-L10-1313-T06-B 1 3.77E+03
Li EaFA-L10-1313-T07-B 1 3.82E+03
Li EaFA-L10-1313-T08-B 1 1.69E+03
Li EaFA-L10-1313-T09-B 1 1.38E+03
Li EaFA-L10-1313-T01-C 1 1.54E+03
Li EaFA-L10-1313-T02-C 1 2.57E+03
Li EaFA-L10-1313-T03-C 1 2.87E+03
Li EaFA-L10-1313-T04-C 1 3.08E+03
Li EaFA-L10-1313-T05-C 1 6.72E+03
Li EaFA-L10-1313-T06-C 1 3.58E+03
Li EaFA-L10-1313-T07-C 1 3.87E+03
Li EaFA-L10-1313-T08-C 1 1.66E+03
Li EaFA-L10-1313-T09-C 1 1.43E+03
Li EaFA-L10-1313-B01-A 1 9.50E-01 U1/2
Li EaFA-L10-1313-B02-A 1 9.50E-01 U1/2
Li EaFA-L10-1313-B03-A 1 9.50E-01 U1/2
Li EaFA-L10-1313-B01-C 1 5.62E+00 E
Li EaFA-L10-1313-B02-C 1 2.58E+00 E
Li EaFA-L10-1313-B03-C 1 9.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.41 E+03 6.1E-01 1.9E+00 6.0E+00
2.23E+03 1.4E+01 1.9E+00 6.0E+00
2.79E+03 7.3E-01 1.9E+00 6.0E+00 10 300
3.15E+03 1.3E-01 1.9E+00 6.0E+00
3.15E+03 3.5E-01 1.9E+00 6.0E+00
3.16E+03 1.4E-01 1.9E+00 6.0E+00
3.81 E+03 7.5E-01 1.9E+00 6.0E+00
1.60E+03 9.7E-01 1.9E+00 6.0E+00
1.40E+03 2.5E-01 1.9E+00 6.0E+00
1.41 E+03 1.1E+00 1.9E+00 6.0E+00
2.38E+03 4.9E-01 1.9E+00 6.0E+00
2.84E+03 8.3E-01 1.9E+00 6.0E+00 10 300
3.04E+03 8.4E-01 1.9E+00 6.0E+00
3.18E+03 1.2E+00 1.9E+00 6.0E+00
3.77E+03 4.7E-01 1.9E+00 6.0E+00
3.82E+03 6.0E-01 1.9E+00 6.0E+00
1.69E+03 3.6E-01 1.9E+00 6.0E+00
1.38E+03 4.1E-01 1.9E+00 6.0E+00
1.54E+03 2.9E+00 1.9E+00 6.0E+00
2.57E+03 8.3E-01 1.9E+00 6.0E+00
2.87E+03 3.1E-01 1.9E+00 6.0E+00 10 300
3.08E+03 6.5E-01 1.9E+00 6.0E+00
6.72E+03 3.5E-01 1.9E+00 6.0E+00
3.58E+03 7.1E+00 1.9E+00 6.0E+00
3.87E+03 9.5E-02 1.9E+00 6.0E+00
1.66E+03 4.8E-01 1.9E+00 6.0E+00
1.43E+03 5.3E-01 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
9.50E-01 8.2E+01 1.9E+00 6.0E+00
5.62E+00 9.0E-01 1.9E+00 6.0E+00
2.58E+00 1.8E+00 1.9E+00 6.0E+00
9.50E-01 1.8E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.29E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.30E+03 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.37E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-249
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Mn Sample Dilution Cone. Qualifier Revi
1 1 ug/L |
Mn EaFA-L10-1313-T01-A 1 3.41 E+01
Mn EaFA-L10-1313-T02-A 1 1.00E+OOU1/2
Mn EaFA-L10-1313-T03-A 1 1.00E+OOU1/2
Mn EaFA-L10-1313-T04-A 1 1.00E+OOU1/2
Mn EaFA-L10-1313-T05-A 1 3.83E+02
Mn EaFA-L10-1313-T06-A 1 8.91 E+02
Mn EaFA-L10-1313-T07-A 1 9.86E+02
Mn EaFA-L10-1313-T08-A 1 1.26E+03
Mn EaFA-L10-1313-T09-A 1 1.48E+03
Mn EaFA-L10-1313-T01-B 1 3.49E+01
Mn EaFA-L10-1313-T02-B 1 1.00E+OOU1/2
Mn EaFA-L10-1313-T03-B 1 1.00E+OOU1/2
Mn EaFA-L10-1313-T04-B 1 1.00E+OOU1/2
Mn EaFA-L10-1313-T05-B 1 3.15E+02
Mn EaFA-L10-1313-T06-B 1 3.19E+02
Mn EaFA-L10-1313-T07-B 1 9.32E+02
Mn EaFA-L10-1313-T08-B 1 1.25E+03
Mn EaFA-L10-1313-T09-B 1 1.49E+03
Mn EaFA-L10-1313-T01-C 1 3.50E+01
Mn EaFA-L10-1313-T02-C 1 1.00E+OOU1/2
Mn EaFA-L10-1313-T03-C 1 1.00E+OOU1/2
Mn EaFA-L10-1313-T04-C 1 1.00E+OOU1/2
Mn EaFA-L10-1313-T05-C 1 8.15E+02
Mn EaFA-L10-1313-T06-C 1 3.50E+02
Mn EaFA-L10-1313-T07-C 1 9.52E+02
Mn EaFA-L10-1313-T08-C 1 1.32E+03
Mn EaFA-L10-1313-T09-C 1 1.53E+03
Mn EaFA-L10-1313-B01-A 1 1.00E+OOU1/2
Mn EaFA-L10-1313-B02-A 1 1.00E+OOU1/2
Mn EaFA-L10-1313-B03-A 1 2.06E+00 E
Mn EaFA-L10-1313-B01-C 1 1.00E+OOU1/2
Mn EaFA-L10-1313-B02-C 1 1.00E+OOU1/2
Mn EaFA-L10-1313-B03-C 1 3.24E+00 E
ial ICP-OES Spike Sol'n
sw Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.41 E+01 1.3E+00 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+03 2.0E+00 6.4E+00 10 300
1.00E+00 1.5E+01 2.0E+00 6.4E+00
3.83E+02 2.3E-01 2.0E+00 6.4E+00
8.91 E+02 1.1E+00 2.0E+00 6.4E+00
9.86E+02 6.1E-01 2.0E+00 6.4E+00
1.26E+03 2.2E-01 2.0E+00 6.4E+00
1.48E+03 4.9E-01 2.0E+00 6.4E+00
3.49E+01 4.4E-01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00 10 300
1.00E+00 2.0E+00 2.0E+00 6.4E+00
3.15E+02 1.4E+00 2.0E+00 6.4E+00
3.19E+02 2.7E-01 2.0E+00 6.4E+00
9.32E+02 1.4E+00 2.0E+00 6.4E+00
1.25E+03 2.0E-01 2.0E+00 6.4E+00
1.49E+03 3.3E-01 2.0E+00 6.4E+00
3.50E+01 2.8E+00 2.0E+00 6.4E+00
1.00E+00 2.1 E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00 10 300
1.00E+00 7.1E+00 2.0E+00 6.4E+00
8.15E+02 4.1E-01 2.0E+00 6.4E+00
3.50E+02 3.7E+00 2.0E+00 6.4E+00
9.52E+02 8.7E-01 2.0E+00 6.4E+00
1.32E+03 4.1E-01 2.0E+00 6.4E+00
1.53E+03 2.6E-01 2.0E+00 6.4E+00
1.00E+00 4.9E+01 2.0E+00 6.4E+00
1.00E+00 8.8E+00 2.0E+00 6.4E+00
2.06E+00 5.2E+00 2.0E+00 6.4E+00
1.00E+00 8.2E+01 2.0E+00 6.4E+00
1.00E+00 8.2E+00 2.0E+00 6.4E+00
3.24E+00 1.1 E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.68E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.84E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.98E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-250
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-L10-1313-T01-A 1 1.38E+01
EaFA-L10-1313-T02-A 1 7.02E+00
EaFA-L10-1313-T03-A 1 7.73E+01
EaFA-L10-1313-T04-A 1 2.73E+03
EaFA-L10-1313-T05-A 1 6.89E+03
EaFA-L10-1313-T06-A 1 8.18E+03
EaFA-L10-1313-T07-A 1 9.37E+03
EaFA-L10-1313-T08-A 1 9.64E+03
EaFA-L10-1313-T09-A 1 1.24E+04
EaFA-L10-1313-T01-B 1 1.85E+01
EaFA-L10-1313-T02-B 1 4.13E+00
EaFA-L10-1313-T03-B 1 1.30E+02
EaFA-L10-1313-T04-B 1 2.93E+03
EaFA-L10-1313-T05-B 1 7.25E+03
EaFA-L10-1313-T06-B 1 9.05E+03
EaFA-L10-1313-T07-B 1 9.13E+03
EaFA-L10-1313-T08-B 1 9.18E+03
EaFA-L10-1313-T09-B 1 1.24E+04
EaFA-L10-1313-T01-C 1 1.81E+01
EaFA-L10-1313-T02-C 1 2.43E+00 E
EaFA-L10-1313-T03-C 1 5.70E+01
EaFA-L10-1313-T04-C 1 2.90E+03
EaFA-L10-1313-T05-C 1 1.49E+04
EaFA-L10-1313-T06-C 1 8.73E+03
EaFA-L10-1313-T07-C 1 9.29E+03
EaFA-L10-1313-T08-C 1 9.90E+03
EaFA-L10-1313-T09-C 1 1.27E+04
EaFA-L10-1313-B01-A 1 5.00E-01 U1/2
EaFA-L10-1313-B02-A 1 4.34E+00
EaFA-L10-1313-B03-A 1 2.29E+01
EaFA-L10-1313-B01-C 1 5.00E-01 U1/2
EaFA-L10-1313-B02-C 1 3.81 E+00
EaFA-L10-1313-B03-C 1 4.70E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.38E+01 2.5E+01 1.0E+00 3.2E+00
7.02E+00 3.2E+01 1.0E+00 3.2E+00
7.73E+01 1.7E+01 1.0E+00 3.2E+00 1000 100
2.73E+03 3.6E-01 1.0E+00 3.2E+00
6.89E+03 6.6E-01 1.0E+00 3.2E+00
8.18E+03 4.0E-01 1.0E+00 3.2E+00
9.37E+03 4.4E-01 1.0E+00 3.2E+00
9.64E+03 7.1E-01 1.0E+00 3.2E+00
1.24E+04 2.3E-01 1.0E+00 3.2E+00
1.85E+01 4.1E+01 1.0E+00 3.2E+00
4.13E+00 4.5E+01 1.0E+00 3.2E+00
1.30E+02 4.3E+00 1.0E+00 3.2E+00 1000 100
2.93E+03 5.4E-01 1.0E+00 3.2E+00
7.25E+03 9.6E-01 1.0E+00 3.2E+00
9.05E+03 7.3E-01 1.0E+00 3.2E+00
9.13E+03 1.0E+00 1.0E+00 3.2E+00
9.18E+03 6.0E-01 1.0E+00 3.2E+00
1.24E+04 4.0E-01 1.0E+00 3.2E+00
1.81E+01 9.4E+01 1.0E+00 3.2E+00
2.43E+00 1.2E+02 1.0E+00 3.2E+00
5.70E+01 1.9E+01 1.0E+00 3.2E+00 1000 100
2.90E+03 5.3E-01 1.0E+00 3.2E+00
1.49E+04 1.0E+00 1.0E+00 3.2E+00
8.73E+03 7.2E+00 1.0E+00 3.2E+00
9.29E+03 3.7E-01 1.0E+00 3.2E+00
9.90E+03 1.1 E+00 1.0E+00 3.2E+00
1.27E+04 1.2E+00 1.0E+00 3.2E+00
5.00E-01 9.2E+01 1.0E+00 3.2E+00
4.34E+00 1.8E+02 1.0E+00 3.2E+00
2.29E+01 3.8E+01 1.0E+00 3.2E+00
5.00E-01 4.7E+01 1.0E+00 3.2E+00
3.81 E+00 9.0E+01 1.0E+00 3.2E+00
4.70E+00 2.6E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.15E+02 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.72E+02 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-251
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
1 1 ug/L
Mo EaFA-L10-1313-T01-A 1 3.29E+03
Mo EaFA-L10-1313-T02-A 1 3.30E+03
Mo EaFA-L10-1313-T03-A 1 3.52E+03
Mo EaFA-L10-1313-T04-A 1 3.74E+03
Mo EaFA-L10-1313-T05-A 1 2.76E+03
Mo EaFA-L10-1313-T06-A 1 5.16E+02
Mo EaFA-L10-1313-T07-A 1 8.04E+02
Mo EaFA-L10-1313-T08-A 1 6.64E+01
Mo EaFA-L10-1313-T09-A 1 2.36E+02
Mo EaFA-L10-1313-T01-B 1 3.36E+03
Mo EaFA-L10-1313-T02-B 1 3.48E+03
Mo EaFA-L10-1313-T03-B 1 3.62E+03
Mo EaFA-L10-1313-T04-B 1 3.69E+03
Mo EaFA-L10-1313-T05-B 1 2.90E+03
Mo EaFA-L10-1313-T06-B 1 2.48E+03
Mo EaFA-L10-1313-T07-B 1 6.00E+02
Mo EaFA-L10-1313-T08-B 1 8.14E+01
Mo EaFA-L10-1313-T09-B 1 2.42E+02
Mo EaFA-L10-1313-T01-C 1 3.52E+03
Mo EaFA-L10-1313-T02-C 1 3.79E+03
Mo EaFA-L10-1313-T03-C 1 3.79E+03
Mo EaFA-L10-1313-T04-C 1 3.63E+03
Mo EaFA-L10-1313-T05-C 1 5.55E+03
Mo EaFA-L10-1313-T06-C 1 2.29E+03
Mo EaFA-L10-1313-T07-C 1 5.61 E+02
Mo EaFA-L10-1313-T08-C 1 6.85E+01
Mo EaFA-L10-1313-T09-C 1 2.52E+02
Mo EaFA-L10-1313-B01-A 1 4.77E+00
Mo EaFA-L10-1313-B02-A 1 6.00E-01 U1/2
Mo EaFA-L10-1313-B03-A 1 1.58E+02
Mo EaFA-L10-1313-B01-C 1 7.82E+00
Mo EaFA-L10-1313-B02-C 1 6.00E-01 U1/2
Mo EaFA-L10-1313-B03-C 1 2.08E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.29E+03 5.9E-01 1.2E+00 3.8E+00
3.30E+03 1.0E+01 1.2E+00 3.8E+00
3.52E+03 6.5E-01 1.2E+00 3.8E+00 10 300
3.74E+03 1.5E+00 1.2E+00 3.8E+00
2.76E+03 3.3E-01 1.2E+00 3.8E+00
5.16E+02 3.4E-01 1.2E+00 3.8E+00
8.04E+02 1.0E+00 1.2E+00 3.8E+00
6.64E+01 3.1E+00 1.2E+00 3.8E+00
2.36E+02 1.1E+00 1.2E+00 3.8E+00
3.36E+03 5.6E-01 1.2E+00 3.8E+00
3.48E+03 1.1E+00 1.2E+00 3.8E+00
3.62E+03 7.5E-01 1.2E+00 3.8E+00 10 300
3.69E+03 4.3E-01 1.2E+00 3.8E+00
2.90E+03 1.2E+00 1.2E+00 3.8E+00
2.48E+03 3.0E-01 1.2E+00 3.8E+00
6.00E+02 4.9E-01 1.2E+00 3.8E+00
8.14E+01 3.6E-01 1.2E+00 3.8E+00
2.42E+02 1.0E+00 1.2E+00 3.8E+00
3.52E+03 3.1E+00 1.2E+00 3.8E+00
3.79E+03 8.5E-01 1.2E+00 3.8E+00
3.79E+03 4.2E-01 1.2E+00 3.8E+00 10 300
3.63E+03 9.6E-01 1.2E+00 3.8E+00
5.55E+03 2.5E-01 1.2E+00 3.8E+00
2.29E+03 6.8E+00 1.2E+00 3.8E+00
5.61 E+02 1.1E+00 1.2E+00 3.8E+00
6.85E+01 1.4E+00 1.2E+00 3.8E+00
2.52E+02 1.9E-01 1.2E+00 3.8E+00
4.77E+00 1.1E+01 1.2E+00 3.8E+00
6.00E-01 8.9E+01 1.2E+00 3.8E+00
1.58E+02 2.0E+00 1.2E+00 3.8E+00
7.82E+00 4.4E+01 1.2E+00 3.8E+00
6.00E-01 5.6E+01 1.2E+00 3.8E+00
2.08E+02 2.9E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.03E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.27E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.54E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-252
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inte
Ni Sample Dilution Cone. Qualifier Rev
1 1 1 ug/L |
Ni EaFA-L10-1313-T01-A 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T02-A 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T03-A 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T04-A 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T05-A 1 1.23E+02
Ni EaFA-L10-1313-T06-A 1 5.56E+02
Ni EaFA-L10-1313-T07-A 1 5.96E+02
Ni EaFA-L10-1313-T08-A 1 5.20E+02
Ni EaFA-L10-1313-T09-A 1 6.55E+02
Ni EaFA-L10-1313-T01-B 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T02-B 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T03-B 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T04-B 1 3.88E+00 E
Ni EaFA-L10-1313-T05-B 1 8.85E+01
Ni EaFA-L10-1313-T06-B 1 1.18E+02
Ni EaFA-L10-1313-T07-B 1 6.33E+02
Ni EaFA-L10-1313-T08-B 1 5.25E+02
Ni EaFA-L10-1313-T09-B 1 6.55E+02
Ni EaFA-L10-1313-T01-C 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T02-C 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T03-C 1 9.00E-01 U1/2
Ni EaFA-L10-1313-T04-C 1 5.62E+00 E
Ni EaFA-L10-1313-T05-C 1 2.76E+02
Ni EaFA-L10-1313-T06-C 1 1.40E+02
Ni EaFA-L10-1313-T07-C 1 6.52E+02
Ni EaFA-L10-1313-T08-C 1 5.46E+02
Ni EaFA-L10-1313-T09-C 1 6.85E+02
Ni EaFA-L10-1313-B01-A 1 9.00E-01 U1/2
Ni EaFA-L10-1313-B02-A 1 9.00E-01 U1/2
Ni EaFA-L10-1313-B03-A 1 9.00E-01 U1/2
Ni EaFA-L10-1313-B01-C 1 1.15E+OOU1/2
Ni EaFA-L10-1313-B02-C 1 9.00E-01 U1/2
Ni EaFA-L10-1313-B03-C 1 9.00E-01 U1/2
rnal ICP-OES Spike Sol'n
lew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.9E+02 1.8E+00 5.7E+00
9.00E-01 2.6E+01 1.8E+00 5.7E+00
9.00E-01 3.1E+01 1.8E+00 5.7E+00 10 300
9.00E-01 1.9E+03 1.8E+00 5.7E+00
1.23E+02 1.7E+00 1.8E+00 5.7E+00
5.56E+02 3.6E-01 1.8E+00 5.7E+00
5.96E+02 5.1E-01 1.8E+00 5.7E+00
5.20E+02 8.5E-01 1.8E+00 5.7E+00
6.55E+02 2.5E-01 1.8E+00 5.7E+00
9.00E-01 2.3E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+00 1.8E+00 5.7E+00
9.00E-01 3.8E+01 1.8E+00 5.7E+00 10 300
3.88E+00 3.2E+01 1.8E+00 5.7E+00
8.85E+01 7.0E+00 1.8E+00 5.7E+00
1.18E+02 3.4E+00 1.8E+00 5.7E+00
6.33E+02 4.9E-01 1.8E+00 5.7E+00
5.25E+02 1.8E-01 1.8E+00 5.7E+00
6.55E+02 2.2E-01 1.8E+00 5.7E+00
9.00E-01 2.5E+01 1.8E+00 5.7E+00
9.00E-01 5.7E+01 1.8E+00 5.7E+00
9.00E-01 2.6E+01 1.8E+00 5.7E+00 10 300
5.62E+00 1.5E+02 1.8E+00 5.7E+00
2.76E+02 1.6E+00 1.8E+00 5.7E+00
1.40E+02 5.6E+00 1.8E+00 5.7E+00
6.52E+02 7.9E-01 1.8E+00 5.7E+00
5.46E+02 8.2E-01 1.8E+00 5.7E+00
6.85E+02 6.2E-01 1.8E+00 5.7E+00
9.00E-01 3.9E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+01 1.8E+00 5.7E+00
9.00E-01 3.4E+01 1.8E+00 5.7E+00
1.15E+00 3.0E+01 1.8E+00 5.7E+00
9.00E-01 5.2E+01 1.8E+00 5.7E+00
9.00E-01 5.3E+00 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.75E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.91 E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.08E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-253
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-L10-1313-T01-A 1 6.67E+03
EaFA-L10-1313-T02-A 1 6.29E+01
EaFA-L10-1313-T03-A 1 5.77E+01
EaFA-L10-1313-T04-A 1 1.02E+02
EaFA-L10-1313-T05-A 1 2.13E+01
EaFA-L10-1313-T06-A 1 1.85E+OOU1/2
EaFA-L10-1313-T07-A 1 1.32E+01
EaFA-L10-1313-T08-A 1 2.13E+01
EaFA-L10-1313-T09-A 1 1.57E+03
EaFA-L10-1313-T01-B 1 6.85E+03
EaFA-L10-1313-T02-B 1 6.46E+01
EaFA-L10-1313-T03-B 1 9.77E+01
EaFA-L10-1313-T04-B 1 9.90E+01
EaFA-L10-1313-T05-B 1 1.79E+01
EaFA-L10-1313-T06-B 1 1.02E+01 E
EaFA-L10-1313-T07-B 1 1.85E+OOU1/2
EaFA-L10-1313-T08-B 1 2.66E+01
EaFA-L10-1313-T09-B 1 1.36E+03
EaFA-L10-1313-T01-C 1 7.34E+03
EaFA-L10-1313-T02-C 1 7.08E+01
EaFA-L10-1313-T03-C 1 4.77E+01
EaFA-L10-1313-T04-C 1 9.70E+01
EaFA-L10-1313-T05-C 1 3.09E+01
EaFA-L10-1313-T06-C 1 7.90E+00 E
EaFA-L10-1313-T07-C 1 1.75E+01
EaFA-L10-1313-T08-C 1 1.47E+01
EaFA-L10-1313-T09-C 1 1.44E+03
EaFA-L10-1313-B01-A 1 1.85E+OOU1/2
EaFA-L10-1313-B02-A 1 1.85E+OOU1/2
EaFA-L10-1313-B03-A 1 1.43E+01
EaFA-L10-1313-B01-C 1 1.85E+OOU1/2
EaFA-L10-1313-B02-C 1 1.85E+OOU1/2
EaFA-L10-1313-B03-C 1 4.45E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.67E+03 1.5E+00 3.7E+00 1.2E+01
6.29E+01 2.5E+01 3.7E+00 1.2E+01
5.77E+01 1.7E+01 3.7E+00 1.2E+01 1000 100
1.02E+02 9.3E+00 3.7E+00 1.2E+01
2.13E+01 7.0E+00 3.7E+00 1.2E+01
1.85E+00 2.3E+02 3.7E+00 1.2E+01
1.32E+01 7.0E+01 3.7E+00 1.2E+01
2.13E+01 1.4E+01 3.7E+00 1.2E+01
1.57E+03 6.5E-01 3.7E+00 1.2E+01
6.85E+03 8.4E-01 3.7E+00 1.2E+01
6.46E+01 1.5E+01 3.7E+00 1.2E+01
9.77E+01 3.1E+00 3.7E+00 1.2E+01 1000 100
9.90E+01 1.3E+01 3.7E+00 1.2E+01
1.79E+01 3.9E+01 3.7E+00 1.2E+01
1.02E+01 1.1E+02 3.7E+00 1.2E+01
1.85E+00 3.9E+02 3.7E+00 1.2E+01
2.66E+01 4.4E+00 3.7E+00 1.2E+01
1.36E+03 8.1E-01 3.7E+00 1.2E+01
7.34E+03 3.1E+00 3.7E+00 1.2E+01
7.08E+01 1.1E+01 3.7E+00 1.2E+01
4.77E+01 1.5E+01 3.7E+00 1.2E+01 1000 100
9.70E+01 8.9E+00 3.7E+00 1.2E+01
3.09E+01 2.7E+01 3.7E+00 1.2E+01
7.90E+00 4.7E+01 3.7E+00 1.2E+01
1.75E+01 1.4E+02 3.7E+00 1.2E+01
1.47E+01 7.2E+01 3.7E+00 1.2E+01
1.44E+03 1.2E+00 3.7E+00 1.2E+01
1.85E+00 7.6E+02 3.7E+00 1.2E+01
1.85E+00 2.5E+02 3.7E+00 1.2E+01
1.43E+01 9.4E+01 3.7E+00 1.2E+01
1.85E+00 5.7E+01 3.7E+00 1.2E+01
1.85E+00 4.0E+01 3.7E+00 1.2E+01
4.45E+01 1.7E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.91 E+02 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.53E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.94E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-254
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone. Qualifier
1 1 ug/L
K EaFA-L10-1313-T01-A 1 9.61 E+04
K EaFA-L10-1313-T02-A 1 3.06E+04
K EaFA-L10-1313-T03-A 1 2.53E+04
K EaFA-L10-1313-T04-A 1 2.80E+04
K EaFA-L10-1313-T05-A 1 2.31 E+04
K EaFA-L10-1313-T06-A 1 2.42E+04
K EaFA-L10-1313-T07-A 1 2.65E+04
K EaFA-L10-1313-T08-A 1 1.64E+04
K EaFA-L10-1313-T09-A 1 1.91 E+04
K EaFA-L10-1313-T01-B 1 9.46E+04
K EaFA-L10-1313-T02-B 1 3.44E+04
K EaFA-L10-1313-T03-B 1 2.50E+04
K EaFA-L10-1313-T04-B 1 2.61 E+04
K EaFA-L10-1313-T05-B 1 2.33E+04
K EaFA-L10-1313-T06-B 1 1.94E+04
K EaFA-L10-1313-T07-B 1 2.65E+04
K EaFA-L10-1313-T08-B 1 1.65E+04
K EaFA-L10-1313-T09-B 1 1.89E+04
K EaFA-L10-1313-T01-C 1 1.00E+05
K EaFA-L10-1313-T02-C 1 3.61 E+04
K EaFA-L10-1313-T03-C 1 2.62E+04
K EaFA-L10-1313-T04-C 1 2.62E+04
K EaFA-L10-1313-T05-C 1 5.14E+04
K EaFA-L10-1313-T06-C 1 1.80E+04
K EaFA-L10-1313-T07-C 1 2.68E+04
K EaFA-L10-1313-T08-C 1 1.69E+04
K EaFA-L10-1313-T09-C 1 1.97E+04
K EaFA-L10-1313-B01-A 1 2.21 E+02
K EaFA-L10-1313-B02-A 1 6.51 E+01
K EaFA-L10-1313-B03-A 1 1.66E+03
K EaFA-L10-1313-B01-C 1 2.84E+02
K EaFA-L10-1313-B02-C 1 7.32E+01
K EaFA-L10-1313-B03-C 1 1.85E+03
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.61 E+04 6.3E-01 1.6E+00 5.1E+00
3.06E+04 1.4E+01 1.6E+00 5.1E+00
2.53E+04 7.5E-01 1.6E+00 5.1E+00 1000 100
2.80E+04 2.2E-01 1.6E+00 5.1E+00
2.31 E+04 4.0E-01 1.6E+00 5.1E+00
2.42E+04 3.9E-01 1.6E+00 5.1E+00
2.65E+04 6.2E-01 1.6E+00 5.1E+00
1.64E+04 3.2E-01 1.6E+00 5.1E+00
1.91 E+04 6.9E-01 1.6E+00 5.1E+00
9.46E+04 3.2E-01 1.6E+00 5.1E+00
3.44E+04 7.2E-01 1.6E+00 5.1E+00
2.50E+04 4.2E-01 1.6E+00 5.1E+00 1000 100
2.61 E+04 4.1E-01 1.6E+00 5.1E+00
2.33E+04 1.3E+00 1.6E+00 5.1E+00
1.94E+04 3.4E-01 1.6E+00 5.1E+00
2.65E+04 8.7E-01 1.6E+00 5.1E+00
1.65E+04 4.3E-01 1.6E+00 5.1E+00
1.89E+04 4.2E-01 1.6E+00 5.1E+00
1.00E+05 2.8E+00 1.6E+00 5.1E+00
3.61 E+04 4.7E-01 1.6E+00 5.1E+00
2.62E+04 5.1E-01 1.6E+00 5.1E+00 1000 100
2.62E+04 7.9E-02 1.6E+00 5.1E+00
5.14E+04 9.3E-01 1.6E+00 5.1E+00
1.80E+04 7.5E+00 1.6E+00 5.1E+00
2.68E+04 2.9E-01 1.6E+00 5.1E+00
1.69E+04 8.5E-01 1.6E+00 5.1E+00
1.97E+04 6.2E-01 1.6E+00 5.1E+00
2.21 E+02 6.3E+00 1.6E+00 5.1E+00
6.51E+01 3.1E+00 1.6E+00 5.1E+00
1.66E+03 1.2E+00 1.6E+00 5.1E+00
2.84E+02 2.3E+00 1.6E+00 5.1E+00
7.32E+01 3.3E+00 1.6E+00 5.1E+00
1.85E+03 3.5E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.61 E+04 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.58E+04 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.71 E+04 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-255
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
1 1 ug/L
Se EaFA-L10-1313-T01-A 1 6.80E+03
Se EaFA-L10-1313-T02-A 1 5.28E+03
Se EaFA-L10-1313-T03-A 1 4.83E+03
Se EaFA-L10-1313-T04-A 1 4.29E+03
Se EaFA-L10-1313-T05-A 1 7.87E+02
Se EaFA-L10-1313-T06-A 1 2.59E+02
Se EaFA-L10-1313-T07-A 1 4.23E+02
Se EaFA-L10-1313-T08-A 1 5.64E+01
Se EaFA-L10-1313-T09-A 1 4.26E+02
Se EaFA-L10-1313-T01-B 1 6.82E+03
Se EaFA-L10-1313-T02-B 1 5.87E+03
Se EaFA-L10-1313-T03-B 1 4.78E+03
Se EaFA-L10-1313-T04-B 1 4.23E+03
Se EaFA-L10-1313-T05-B 1 8.05E+02
Se EaFA-L10-1313-T06-B 1 6.01 E+02
Se EaFA-L10-1313-T07-B 1 3.61 E+02
Se EaFA-L10-1313-T08-B 1 4.19E+01 E
Se EaFA-L10-1313-T09-B 1 3.75E+02
Se EaFA-L10-1313-T01-C 1 7.47E+03
Se EaFA-L10-1313-T02-C 1 6.22E+03
Se EaFA-L10-1313-T03-C 1 5.17E+03
Se EaFA-L10-1313-T04-C 1 4.11E+03
Se EaFA-L10-1313-T05-C 1 1.02E+03
Se EaFA-L10-1313-T06-C 1 5.57E+02
Se EaFA-L10-1313-T07-C 1 3.94E+02
Se EaFA-L10-1313-T08-C 1 4.57E+01 E
Se EaFA-L10-1313-T09-C 1 3.80E+02
Se EaFA-L10-1313-B01-A 1 7.50E+00 U1/2
Se EaFA-L10-1313-B02-A 1 2.83E+01 E
Se EaFA-L10-1313-B03-A 1 8.87E+01
Se EaFA-L10-1313-B01-C 1 1.17E+02
Se EaFA-L10-1313-B02-C 1 6.37E+01
Se EaFA-L10-1313-B03-C 1 9.57E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.80E+03 6.8E-01 1.5E+01 4.8E+01
5.28E+03 1.4E+01 1.5E+01 4.8E+01
4.83E+03 1.7E+00 1.5E+01 4.8E+01 10 300
4.29E+03 5.5E-01 1.5E+01 4.8E+01
7.87E+02 2.0E+00 1.5E+01 4.8E+01
2.59E+02 1.6E+01 1.5E+01 4.8E+01
4.23E+02 4.2E+00 1.5E+01 4.8E+01
5.64E+01 2.4E+01 1.5E+01 4.8E+01
4.26E+02 5.7E+00 1.5E+01 4.8E+01
6.82E+03 1.5E+00 1.5E+01 4.8E+01
5.87E+03 4.3E-01 1.5E+01 4.8E+01
4.78E+03 1.0E+00 1.5E+01 4.8E+01 10 300
4.23E+03 4.0E-01 1.5E+01 4.8E+01
8.05E+02 5.3E+00 1.5E+01 4.8E+01
6.01 E+02 7.4E+00 1.5E+01 4.8E+01
3.61 E+02 1.9E+01 1.5E+01 4.8E+01
4.19E+01 5.5E+01 1.5E+01 4.8E+01
3.75E+02 3.3E+00 1.5E+01 4.8E+01
7.47E+03 3.7E+00 1.5E+01 4.8E+01
6.22E+03 1.1E+00 1.5E+01 4.8E+01
5.17E+03 1.1E+00 1.5E+01 4.8E+01 10 300
4.11E+03 1.7E+00 1.5E+01 4.8E+01
1.02E+03 2.1E+00 1.5E+01 4.8E+01
5.57E+02 1.1E+01 1.5E+01 4.8E+01
3.94E+02 4.3E+00 1.5E+01 4.8E+01
4.57E+01 6.1E+01 1.5E+01 4.8E+01
3.80E+02 6.7E+00 1.5E+01 4.8E+01
7.50E+00 1.8E+02 1.5E+01 4.8E+01
2.83E+01 4.8E+00 1.5E+01 4.8E+01
8.87E+01 3.9E+01 1.5E+01 4.8E+01
1.17E+02 2.0E+01 1.5E+01 4.8E+01
6.37E+01 1.8E+01 1.5E+01 4.8E+01
9.57E+01 1.1E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.32E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.41 E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.77E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-256
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
1 1 ug/L
Si EaFA-L10-1313-T01-A 1 1.58E+05
Si EaFA-L10-1313-T02-A 1 7.11E+03
Si EaFA-L10-1313-T03-A 1 1.01E+03
Si EaFA-L10-1313-T04-A 1 3.84E+02
Si EaFA-L10-1313-T05-A 1 2.05E+03
Si EaFA-L10-1313-T06-A 1 6.84E+03
Si EaFA-L10-1313-T07-A 1 7.55E+03
Si EaFA-L10-1313-T08-A 1 4.33E+04
Si EaFA-L10-1313-T09-A 1 6.13E+04
Si EaFA-L10-1313-T01-B 1 1.61E+05
Si EaFA-L10-1313-T02-B 1 7.76E+03
Si EaFA-L10-1313-T03-B 1 8.66E+02
Si EaFA-L10-1313-T04-B 1 3.72E+02
Si EaFA-L10-1313-T05-B 1 1.74E+03
Si EaFA-L10-1313-T06-B 1 2.26E+03
Si EaFA-L10-1313-T07-B 1 7.36E+03
Si EaFA-L10-1313-T08-B 1 4.09E+04
Si EaFA-L10-1313-T09-B 1 6.24E+04
Si EaFA-L10-1313-T01-C 1 1.72E+05
Si EaFA-L10-1313-T02-C 1 8.50E+03
Si EaFA-L10-1313-T03-C 1 1.57E+03
Si EaFA-L10-1313-T04-C 1 3.66E+02
Si EaFA-L10-1313-T05-C 1 2.70E+03
Si EaFA-L10-1313-T06-C 1 2.39E+03
Si EaFA-L10-1313-T07-C 1 7.88E+03
Si EaFA-L10-1313-T08-C 1 4.68E+04
Si EaFA-L10-1313-T09-C 1 6.45E+04
Si EaFA-L10-1313-B01-A 1 5.50E-01 U1/2
Si EaFA-L10-1313-B02-A 1 5.50E-01 U1/2
Si EaFA-L10-1313-B03-A 1 2.31 E+02
Si EaFA-L10-1313-B01-C 1 9.99E+00
Si EaFA-L10-1313-B02-C 1 7.52E+00
Si EaFA-L10-1313-B03-C 1 2. 11 E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.58E+05 1.1E+00 1.1E+00 3.5E+00
7.11E+03 1.1E+01 1.1E+00 3.5E+00
1.01E+03 5.2E-01 1.1E+00 3.5E+00 1000 100
3.84E+02 1.1E+00 1.1E+00 3.5E+00
2.05E+03 3.7E-01 1.1E+00 3.5E+00
6.84E+03 6.6E-01 1.1E+00 3.5E+00
7.55E+03 6.3E-01 1.1E+00 3.5E+00
4.33E+04 2.6E-01 1.1E+00 3.5E+00
6.13E+04 1.6E-01 1.1E+00 3.5E+00
1.61E+05 2.8E-01 1.1E+00 3.5E+00
7.76E+03 8.3E-01 1.1E+00 3.5E+00
8.66E+02 9.7E-01 1.1E+00 3.5E+00 1000 100
3.72E+02 6.1E-01 1.1E+00 3.5E+00
1.74E+03 6.2E-01 1.1E+00 3.5E+00
2.26E+03 1.3E-01 1.1E+00 3.5E+00
7.36E+03 9.8E-01 1.1E+00 3.5E+00
4.09E+04 2.1E-01 1.1E+00 3.5E+00
6.24E+04 1.3E+00 1.1E+00 3.5E+00
1.72E+05 2.8E+00 1.1E+00 3.5E+00
8.50E+03 3.0E-01 1.1E+00 3.5E+00
1.57E+03 4.4E-01 1.1E+00 3.5E+00 1000 100
3.66E+02 9.2E-01 1.1E+00 3.5E+00
2.70E+03 5.5E-01 1.1E+00 3.5E+00
2.39E+03 6.0E+00 1.1E+00 3.5E+00
7.88E+03 8.5E-01 1.1E+00 3.5E+00
4.68E+04 7.3E-01 1.1E+00 3.5E+00
6.45E+04 6.0E-01 1.1E+00 3.5E+00
5.50E-01 1.6E+02 1.1E+00 3.5E+00
5.50E-01 5.1E+01 1.1E+00 3.5E+00
2. 31 E+02 4.4E+00 1.1E+00 3.5E+00
9.99E+00 1.7E+01 1.1E+00 3.5E+00
7.52E+00 5.1E+01 1.1E+00 3.5E+00
2. 11 E+02 4.5E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .88E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.73E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.40E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-257
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
1 1 ug/L
Na EaFA-L10-1313-T01-A 1 3.78E+05
Na EaFA-L10-1313-T02-A 1 1.53E+05
Na EaFA-L10-1313-T03-A 1 5.48E+04
Na EaFA-L10-1313-T04-A 1 3.81 E+04
Na EaFA-L10-1313-T05-A 1 4.77E+03
Na EaFA-L10-1313-T06-A 1 4.86E+03
Na EaFA-L10-1313-T07-A 1 5.78E+03
Na EaFA-L10-1313-T08-A 1 3.34E+03
Na EaFA-L10-1313-T09-A 1 2.76E+03
Na EaFA-L10-1313-T01-B 1 3.77E+05
Na EaFA-L10-1313-T02-B 1 1.75E+05
Na EaFA-L10-1313-T03-B 1 5.16E+04
Na EaFA-L10-1313-T04-B 1 3.84E+04
Na EaFA-L10-1313-T05-B 1 4.80E+03
Na EaFA-L10-1313-T06-B 1 5.67E+03
Na EaFA-L10-1313-T07-B 1 5.74E+03
Na EaFA-L10-1313-T08-B 1 7.10E+03
Na EaFA-L10-1313-T09-B 1 2.71E+03
Na EaFA-L10-1313-T01-C 1 3.94E+05
Na EaFA-L10-1313-T02-C 1 1.72E+05
Na EaFA-L10-1313-T03-C 1 5.91 E+04
Na EaFA-L10-1313-T04-C 1 3.76E+04
Na EaFA-L10-1313-T05-C 1 1.05E+04
Na EaFA-L10-1313-T06-C 1 5.34E+03
Na EaFA-L10-1313-T07-C 1 5.78E+03
Na EaFA-L10-1313-T08-C 1 2.97E+03
Na EaFA-L10-1313-T09-C 1 2.77E+03
Na EaFA-L10-1313-B01-A 1 2.96E+01
Na EaFA-L10-1313-B02-A 1 5.54E+01
Na EaFA-L10-1313-B03-A 1 3.90E+05
Na EaFA-L10-1313-B01-C 1 3.10E+01
Na EaFA-L10-1313-B02-C 1 4.19E+01
Na EaFA-L10-1313-B03-C 1 4.63E+05
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.78E+05 1.6E+00 2.5E+00 8.0E+00
1.53E+05 1.1E+01 2.5E+00 8.0E+00
5.48E+04 1.3E+00 2.5E+00 8.0E+00 1000 100
3.81 E+04 1.5E+00 2.5E+00 8.0E+00
4.77E+03 8.6E-01 2.5E+00 8.0E+00
4.86E+03 5.9E-01 2.5E+00 8.0E+00
5.78E+03 9.4E-01 2.5E+00 8.0E+00
3.34E+03 5.7E-01 2.5E+00 8.0E+00
2.76E+03 2.7E-01 2.5E+00 8.0E+00
3.77E+05 2.5E+00 2.5E+00 8.0E+00
1.75E+05 5.9E-01 2.5E+00 8.0E+00
5.16E+04 6.7E-01 2.5E+00 8.0E+00 1000 100
3.84E+04 2.3E+00 2.5E+00 8.0E+00
4.80E+03 1.1E+00 2.5E+00 8.0E+00
5.67E+03 5.1E-01 2.5E+00 8.0E+00
5.74E+03 8.5E-01 2.5E+00 8.0E+00
7.10E+03 8.6E-01 2.5E+00 8.0E+00
2.71 E+03 8.6E-01 2.5E+00 8.0E+00
3.94E+05 2.8E+00 2.5E+00 8.0E+00
1.72E+05 6.2E-01 2.5E+00 8.0E+00
5.91 E+04 3.8E-01 2.5E+00 8.0E+00 1000 100
3.76E+04 6.1E-01 2.5E+00 8.0E+00
1.05E+04 5.2E-01 2.5E+00 8.0E+00
5.34E+03 8.0E+00 2.5E+00 8.0E+00
5.78E+03 2.8E-01 2.5E+00 8.0E+00
2.97E+03 7.4E-01 2.5E+00 8.0E+00
2.77E+03 5.8E-01 2.5E+00 8.0E+00
2.96E+01 3.9E+00 2.5E+00 8.0E+00
5.54E+01 5.6E-01 2.5E+00 8.0E+00
3.90E+05 7.4E-01 2.5E+00 8.0E+00
3.10E+01 2.2E+00 2.5E+00 8.0E+00
4.19E+01 8.4E-01 2.5E+00 8.0E+00
4.63E+05 1.2E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.57E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.25E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.00E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-258
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sr Sample Dilution Cone. Qualifier
1 1 ug/L
Sr EaFA-L10-1313-T01-A 1 1.70E+03
Sr EaFA-L10-1313-T02-A 1 1.20E+03
Sr EaFA-L10-1313-T03-A 1 1.67E+03
Sr EaFA-L10-1313-T04-A 1 1.97E+03
Sr EaFA-L10-1313-T05-A 1 2.02E+03
Sr EaFA-L10-1313-T06-A 1 2.54E+03
Sr EaFA-L10-1313-T07-A 1 2.96E+03
Sr EaFA-L10-1313-T08-A 1 3.84E+03
Sr EaFA-L10-1313-T09-A 1 4.67E+03
Sr EaFA-L10-1313-T01-B 1 1.74E+03
Sr EaFA-L10-1313-T02-B 1 1.26E+03
Sr EaFA-L10-1313-T03-B 1 1.65E+03
Sr EaFA-L10-1313-T04-B 1 1.94E+03
Sr EaFA-L10-1313-T05-B 1 2.23E+03
Sr EaFA-L10-1313-T06-B 1 2.42E+03
Sr EaFA-L10-1313-T07-B 1 2.80E+03
Sr EaFA-L10-1313-T08-B 1 3.75E+03
Sr EaFA-L10-1313-T09-B 1 4.67E+03
Sr EaFA-L10-1313-T01-C 1 1.82E+03
Sr EaFA-L10-1313-T02-C 1 1.29E+03
Sr EaFA-L10-1313-T03-C 1 1.69E+03
Sr EaFA-L10-1313-T04-C 1 1.91E+03
Sr EaFA-L10-1313-T05-C 1 3.89E+03
Sr EaFA-L10-1313-T06-C 1 2.36E+03
Sr EaFA-L10-1313-T07-C 1 2.86E+03
Sr EaFA-L10-1313-T08-C 1 4.00E+03
Sr EaFA-L10-1313-T09-C 1 4.83E+03
Sr EaFA-L10-1313-B01-A 1 5.00E-01 U1/2
Sr EaFA-L10-1313-B02-A 1 5.00E-01 U1/2
Sr EaFA-L10-1313-B03-A 1 4.50E+00
Sr EaFA-L10-1313-B01-C 1 5.00E-01 U1/2
Sr EaFA-L10-1313-B02-C 1 5.00E-01 U1/2
Sr EaFA-L10-1313-B03-C 1 2.79E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.70E+03 2.1E+00 1.0E+00 3.2E+00
1.20E+03 1.0E+01 1.0E+00 3.2E+00
1.67E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
1.97E+03 8.1E-01 1.0E+00 3.2E+00
2.02E+03 2.7E-01 1.0E+00 3.2E+00
2.54E+03 5.0E-01 1.0E+00 3.2E+00
2.96E+03 1.4E+00 1.0E+00 3.2E+00
3.84E+03 4.9E-01 1.0E+00 3.2E+00
4.67E+03 8.5E-01 1.0E+00 3.2E+00
1.74E+03 1.8E+00 1.0E+00 3.2E+00
1.26E+03 1.3E+00 1.0E+00 3.2E+00
1.65E+03 1.0E+00 1.0E+00 3.2E+00 1000 100
1.94E+03 8.9E-01 1.0E+00 3.2E+00
2.23E+03 1.7E+00 1.0E+00 3.2E+00
2.42E+03 5.4E-01 1.0E+00 3.2E+00
2.80E+03 7.8E-01 1.0E+00 3.2E+00
3.75E+03 8.6E-01 1.0E+00 3.2E+00
4.67E+03 1.0E+00 1.0E+00 3.2E+00
1.82E+03 3.0E+00 1.0E+00 3.2E+00
1.29E+03 3.2E-01 1.0E+00 3.2E+00
1.69E+03 3.7E-01 1.0E+00 3.2E+00 1000 100
1.91E+03 1.9E-01 1.0E+00 3.2E+00
3.89E+03 6.0E-01 1.0E+00 3.2E+00
2.36E+03 4.1E+00 1.0E+00 3.2E+00
2.86E+03 1.0E+00 1.0E+00 3.2E+00
4.00E+03 1.2E+00 1.0E+00 3.2E+00
4.83E+03 1.9E+00 1.0E+00 3.2E+00
5.00E-01 7.4E+01 1.0E+00 3.2E+00
5.00E-01 7.3E+01 1.0E+00 3.2E+00
4.50E+00 2.2E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
2.79E+00 2.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.55E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.49E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.55E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-259
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
1 1 ug/L
S EaFA-L10-1313-T01-A 1 1.54E+05
S EaFA-L10-1313-T02-A 1 1.36E+05
S EaFA-L10-1313-T03-A 1 1.41E+05
S EaFA-L10-1313-T04-A 1 1.58E+05
S EaFA-L10-1313-T05-A 1 1.39E+05
S EaFA-L10-1313-T06-A 1 1.29E+05
S EaFA-L10-1313-T07-A 1 1.47E+05
S EaFA-L10-1313-T08-A 1 6.79E+04
S EaFA-L10-1313-T09-A 1 5.54E+04
S EaFA-L10-1313-T01-B 1 1.57E+05
S EaFA-L10-1313-T02-B 1 1.47E+05
S EaFA-L10-1313-T03-B 1 1.44E+05
S EaFA-L10-1313-T04-B 1 1.53E+05
S EaFA-L10-1313-T05-B 1 1.42E+05
S EaFA-L10-1313-T06-B 1 1.42E+05
S EaFA-L10-1313-T07-B 1 1.44E+05
S EaFA-L10-1313-T08-B 1 7.81 E+04
S EaFA-L10-1313-T09-B 1 5.41 E+04
S EaFA-L10-1313-T01-C 1 1.67E+05
S EaFA-L10-1313-T02-C 1 1.60E+05
S EaFA-L10-1313-T03-C 1 1.52E+05
S EaFA-L10-1313-T04-C 1 1.52E+05
S EaFA-L10-1313-T05-C 1 3.08E+05
S EaFA-L10-1313-T06-C 1 1.37E+05
S EaFA-L10-1313-T07-C 1 1.47E+05
S EaFA-L10-1313-T08-C 1 7.22E+04
S EaFA-L10-1313-T09-C 1 5.73E+04
S EaFA-L10-1313-B01-A 1 2.06E+01 E
S EaFA-L10-1313-B02-A 1 1.93E+01 E
S EaFA-L10-1313-B03-A 1 1.64E+02
S EaFA-L10-1313-B01-C 1 2.02E+01 E
S EaFA-L10-1313-B02-C 1 2.57E+01
S EaFA-L10-1313-B03-C 1 1.45E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+05 2.6E-01 6.8E+00 2.2E+01
1.36E+05 1.3E+01 6.8E+00 2.2E+01
1.41E+05 6.0E-01 6.8E+00 2.2E+01 1000 100
1.58E+05 3.7E-01 6.8E+00 2.2E+01
1.39E+05 3.9E-01 6.8E+00 2.2E+01
1.29E+05 4.3E-01 6.8E+00 2.2E+01
1.47E+05 7.5E-01 6.8E+00 2.2E+01
6.79E+04 4.9E-01 6.8E+00 2.2E+01
5.54E+04 4.4E-01 6.8E+00 2.2E+01
1.57E+05 2.1E-01 6.8E+00 2.2E+01
1.47E+05 8.5E-01 6.8E+00 2.2E+01
1.44E+05 8.3E-01 6.8E+00 2.2E+01 1000 100
1.53E+05 5.0E-01 6.8E+00 2.2E+01
1.42E+05 9.3E-01 6.8E+00 2.2E+01
1.42E+05 2.5E-01 6.8E+00 2.2E+01
1.44E+05 1.0E+00 6.8E+00 2.2E+01
7.81 E+04 7.9E-02 6.8E+00 2.2E+01
5.41 E+04 1.3E-01 6.8E+00 2.2E+01
1.67E+05 3.0E+00 6.8E+00 2.2E+01
1.60E+05 8.0E-02 6.8E+00 2.2E+01
1.52E+05 1.4E-01 6.8E+00 2.2E+01 1000 100
1.52E+05 3.7E-01 6.8E+00 2.2E+01
3.08E+05 4.9E-01 6.8E+00 2.2E+01
1.37E+05 6.1E+00 6.8E+00 2.2E+01
1.47E+05 3.3E-01 6.8E+00 2.2E+01
7.22E+04 6.7E-01 6.8E+00 2.2E+01
5.73E+04 3.6E-01 6.8E+00 2.2E+01
2.06E+01 6.0E+01 6.8E+00 2.2E+01
1.93E+01 9.0E+01 6.8E+00 2.2E+01
1.64E+02 5.8E+00 6.8E+00 2.2E+01
2.02E+01 9.1E+01 6.8E+00 2.2E+01
2.57E+01 5.5E+01 6.8E+00 2.2E+01
1.45E+02 1.8E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.42E+05 80% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .45E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .53E+05 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-260
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Tl Sample Dilution Cone. Qualifier Revi
1 1 ug/L |
Tl EaFA-L10-1313-T01-A 1 9.66E+00 E
Tl EaFA-L10-1313-T02-A 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T03-A 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T04-A 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T05-A 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T06-A 1 2.60E+01
Tl EaFA-L10-1313-T07-A 1 3.83E+01
Tl EaFA-L10-1313-T08-A 1 4.28E+01
Tl EaFA-L10-1313-T09-A 1 5.68E+01
Tl EaFA-L10-1313-T01-B 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T02-B 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T03-B 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T04-B 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T05-B 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T06-B 1 7.87E+00 E
Tl EaFA-L10-1313-T07-B 1 5.39E+01
Tl EaFA-L10-1313-T08-B 1 3.86E+01
Tl EaFA-L10-1313-T09-B 1 5.66E+01
Tl EaFA-L10-1313-T01-C 1 1.10E+01 E
Tl EaFA-L10-1313-T02-C 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T03-C 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T04-C 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T05-C 1 2.30E+00 U1/2
Tl EaFA-L10-1313-T06-C 1 1.59E+01
Tl EaFA-L10-1313-T07-C 1 3.65E+01
Tl EaFA-L10-1313-T08-C 1 4.66E+01
Tl EaFA-L10-1313-T09-C 1 5.74E+01
Tl EaFA-L10-1313-B01-A 1 2.30E+00 U1/2
Tl EaFA-L10-1313-B02-A 1 2.30E+00 U1/2
Tl EaFA-L10-1313-B03-A 1 2.30E+00 U1/2
Tl EaFA-L10-1313-B01-C 1 2.30E+00 U1/2
Tl EaFA-L10-1313-B02-C 1 2.30E+00 U1/2
Tl EaFA-L10-1313-B03-C 1 2.30E+00 U1/2
ial ICP-OES Spike Sol'n
S\N Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.66E+00 5.0E+01 4.6E+00 1.5E+01
2.30E+00 1.1E+01 4.6E+00 1.5E+01
2.30E+00 3.7E+01 4.6E+00 1.5E+01 10 300
2.30E+00 3.4E+02 4.6E+00 1.5E+01
2.30E+00 8.2E+02 4.6E+00 1.5E+01
2.60E+01 3.5E+01 4.6E+00 1.5E+01
3.83E+01 1.6E+01 4.6E+00 1.5E+01
4.28E+01 1.7E+01 4.6E+00 1.5E+01
5.68E+01 1.2E+01 4.6E+00 1.5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 2.4E+02 4.6E+00 1.5E+01
2.30E+00 2.9E+01 4.6E+00 1.5E+01 10 300
2.30E+00 8.3E+01 4.6E+00 1.5E+01
2.30E+00 6.0E+01 4.6E+00 1.5E+01
7.87E+00 3.2E+01 4.6E+00 1.5E+01
5.39E+01 2.7E+01 4.6E+00 1.5E+01
3.86E+01 1.0E+01 4.6E+00 1.5E+01
5.66E+01 1.0E+01 4.6E+00 1.5E+01
1.10E+01 1.1E+02 4.6E+00 1.5E+01
2.30E+00 6.5E+01 4.6E+00 1.5E+01
2.30E+00 4.0E+01 4.6E+00 1.5E+01 10 300
2.30E+00 2.5E+02 4.6E+00 1.5E+01
2.30E+00 4.9E+02 4.6E+00 1.5E+01
1.59E+01 1.3E+02 4.6E+00 1.5E+01
3.65E+01 2.3E+01 4.6E+00 1.5E+01
4.66E+01 1.5E+01 4.6E+00 1.5E+01
5.74E+01 1.2E+01 4.6E+00 1.5E+01
2.30E+00 2.4E+01 4.6E+00 1.5E+01
2.30E+00 6.7E+01 4.6E+00 1.5E+01
2.30E+00 7.0E+01 4.6E+00 1.5E+01
2.30E+00 5.6E+01 4.6E+00 1.5E+01
2.30E+00 7.8E+01 4.6E+00 1.5E+01
2.30E+00 3.9E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.74E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.87E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.01 E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-261
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
1 1 ug/L |
Ti EaFA-L10-1313-T01-A 1 9.07E+01
Ti EaFA-L10-1313-T02-A 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T03-A 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T04-A 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T05-A 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T06-A 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T07-A 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T08-A 1 7.36E+01
Ti EaFA-L10-1313-T09-A 1 2.22E+03
Ti EaFA-L10-1313-T01-B 1 9.36E+01
Ti EaFA-L10-1313-T02-B 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T03-B 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T04-B 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T05-B 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T06-B 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T07-B 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T08-B 1 4.18E+01
Ti EaFA-L10-1313-T09-B 1 1.73E+03
Ti EaFA-L10-1313-T01-C 1 9.53E+01
Ti EaFA-L10-1313-T02-C 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T03-C 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T04-C 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T05-C 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T06-C 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T07-C 1 1.00E+OOU1/2
Ti EaFA-L10-1313-T08-C 1 7.67E+01
Ti EaFA-L10-1313-T09-C 1 1.77E+03
Ti EaFA-L10-1313-B01-A 1 1.00E+OOU1/2
Ti EaFA-L10-1313-B02-A 1 1.00E+OOU1/2
Ti EaFA-L10-1313-B03-A 1 1.00E+OOU1/2
Ti EaFA-L10-1313-B01-C 1 1.00E+OOU1/2
Ti EaFA-L10-1313-B02-C 1 1.00E+OOU1/2
Ti EaFA-L10-1313-B03-C 1 1.00E+OOU1/2
ial ICP-OES Spike Sol'n
sw Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.07E+01 5.3E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00 10 300
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+02 2.0E+00 6.4E+00
7.36E+01 3.3E-01 2.0E+00 6.4E+00
2.22E+03 2.1E-01 2.0E+00 6.4E+00
9.36E+01 2.4E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+01 2.0E+00 6.4E+00
1.00E+00 5.9E+01 2.0E+00 6.4E+00 10 300
1.00E+00 5.5E+01 2.0E+00 6.4E+00
1.00E+00 5.8E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 8.0E+01 2.0E+00 6.4E+00
4.18E+01 9.6E-01 2.0E+00 6.4E+00
1.73E+03 2.5E-01 2.0E+00 6.4E+00
9.53E+01 2.5E+00 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00 10 300
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+03 2.0E+00 6.4E+00
1.00E+00 1.9E+03 2.0E+00 6.4E+00
7.67E+01 8.0E-01 2.0E+00 6.4E+00
1.77E+03 2.1E-01 2.0E+00 6.4E+00
1.00E+00 8.9E+01 2.0E+00 6.4E+00
1.00E+00 8.5E+00 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+02 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.68E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.83E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.96E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-262
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
1 1 ug/L
V EaFA-L10-1313-T01-A 1 7.17E+03
V EaFA-L10-1313-T02-A 1 3.28E+03
V EaFA-L10-1313-T03-A 1 2.33E+03
V EaFA-L10-1313-T04-A 1 9.25E+02
V EaFA-L10-1313-T05-A 1 1.65E+02
V EaFA-L10-1313-T06-A 1 9.27E+01
V EaFA-L10-1313-T07-A 1 1.10E+02
V EaFA-L10-1313-T08-A 1 2.69E+02
V EaFA-L10-1313-T09-A 1 4.74E+03
V EaFA-L10-1313-T01-B 1 7.31 E+03
V EaFA-L10-1313-T02-B 1 3.45E+03
V EaFA-L10-1313-T03-B 1 2.27E+03
V EaFA-L10-1313-T04-B 1 9.01 E+02
V EaFA-L10-1313-T05-B 1 1.49E+02
V EaFA-L10-1313-T06-B 1 1.47E+02
V EaFA-L10-1313-T07-B 1 1.02E+02
V EaFA-L10-1313-T08-B 1 1.56E+02
V EaFA-L10-1313-T09-B 1 5.31 E+03
V EaFA-L10-1313-T01-C 1 7.69E+03
V EaFA-L10-1313-T02-C 1 3.79E+03
V EaFA-L10-1313-T03-C 1 2.84E+03
V EaFA-L10-1313-T04-C 1 8.59E+02
V EaFA-L10-1313-T05-C 1 2. 11 E+02
V EaFA-L10-1313-T06-C 1 1.32E+02
V EaFA-L10-1313-T07-C 1 1.08E+02
V EaFA-L10-1313-T08-C 1 2.87E+02
V EaFA-L10-1313-T09-C 1 5.51 E+03
V EaFA-L10-1313-B01-A 1 5.89E+00
V EaFA-L10-1313-B02-A 1 5.89E+00
V EaFA-L10-1313-B03-A 1 6.37E+00
V EaFA-L10-1313-B01-C 1 2.57E+00 E
V EaFA-L10-1313-B02-C 1 1.79E+OOE
V EaFA-L10-1313-B03-C 1 4.84E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.17E+03 1.7E+00 1.5E+00 4.8E+00
3.28E+03 1.0E+01 1.5E+00 4.8E+00
2.33E+03 1.3E+00 1.5E+00 4.8E+00 10 300
9.25E+02 8.6E-01 1.5E+00 4.8E+00
1.65E+02 8.0E-01 1.5E+00 4.8E+00
9.27E+01 1.3E+00 1.5E+00 4.8E+00
1.10E+02 1.4E+00 1.5E+00 4.8E+00
2.69E+02 7.4E-01 1.5E+00 4.8E+00
4.74E+03 1.5E-01 1.5E+00 4.8E+00
7.31 E+03 1.3E+00 1.5E+00 4.8E+00
3.45E+03 7.2E-01 1.5E+00 4.8E+00
2.27E+03 1.5E+00 1.5E+00 4.8E+00 10 300
9.01 E+02 2.1E-01 1.5E+00 4.8E+00
1.49E+02 1.0E+00 1.5E+00 4.8E+00
1.47E+02 1.1E+00 1.5E+00 4.8E+00
1.02E+02 1.4E+00 1.5E+00 4.8E+00
1.56E+02 1.6E+00 1.5E+00 4.8E+00
5.31 E+03 8.6E-02 1.5E+00 4.8E+00
7.69E+03 2.4E+00 1.5E+00 4.8E+00
3.79E+03 5.2E-01 1.5E+00 4.8E+00
2.84E+03 4.7E-01 1.5E+00 4.8E+00 10 300
8.59E+02 4.3E-01 1.5E+00 4.8E+00
2. 11 E+02 8.6E-01 1.5E+00 4.8E+00
1.32E+02 1.0E+01 1.5E+00 4.8E+00
1.08E+02 2.0E+00 1.5E+00 4.8E+00
2.87E+02 1.1E+00 1.5E+00 4.8E+00
5.51 E+03 7.0E-01 1.5E+00 4.8E+00
5.89E+00 8.7E+00 1.5E+00 4.8E+00
5.89E+00 1.9E+01 1.5E+00 4.8E+00
6.37E+00 2.4E+01 1.5E+00 4.8E+00
2.57E+00 7.5E+01 1.5E+00 4.8E+00
1.79E+00 7.0E+00 1.5E+00 4.8E+00
4.84E+00 8.4E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.80E+03 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.96E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.58E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-263
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
1 1 ug/L
Zn EaFA-L10-1313-T01-A 1 2.04E+03
Zn EaFA-L10-1313-T02-A 1 1.56E+01
Zn EaFA-L10-1313-T03-A 1 5.79E+00
Zn EaFA-L10-1313-T04-A 1 5.50E+00
Zn EaFA-L10-1313-T05-A 1 2.27E+01
Zn EaFA-L10-1313-T06-A 1 1.10E+03
Zn EaFA-L10-1313-T07-A 1 1.02E+03
Zn EaFA-L10-1313-T08-A 1 1.17E+03
Zn EaFA-L10-1313-T09-A 1 1.40E+03
Zn EaFA-L10-1313-T01-B 1 2.10E+03
Zn EaFA-L10-1313-T02-B 1 1.44E+01
Zn EaFA-L10-1313-T03-B 1 3.48E+00
Zn EaFA-L10-1313-T04-B 1 4.52E+00
Zn EaFA-L10-1313-T05-B 1 4.37E+01
Zn EaFA-L10-1313-T06-B 1 1.82E+01
Zn EaFA-L10-1313-T07-B 1 1.28E+03
Zn EaFA-L10-1313-T08-B 1 1.17E+03
Zn EaFA-L10-1313-T09-B 1 1.41E+03
Zn EaFA-L10-1313-T01-C 1 2.17E+03
Zn EaFA-L10-1313-T02-C 1 1.61E+01
Zn EaFA-L10-1313-T03-C 1 2.44E+00 E
Zn EaFA-L10-1313-T04-C 1 4.13E+00
Zn EaFA-L10-1313-T05-C 1 3.62E+01
Zn EaFA-L10-1313-T06-C 1 1.91E+01
Zn EaFA-L10-1313-T07-C 1 1.33E+03
Zn EaFA-L10-1313-T08-C 1 1.23E+03
Zn EaFA-L10-1313-T09-C 1 1.47E+03
Zn EaFA-L10-1313-B01-A 1 3.92E+00
Zn EaFA-L10-1313-B02-A 1 1.39E+01
Zn EaFA-L10-1313-B03-A 1 4.98E+01
Zn EaFA-L10-1313-B01-C 1 6.05E+00
Zn EaFA-L10-1313-B02-C 1 1.96E+01
Zn EaFA-L10-1313-B03-C 1 5.28E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.04E+03 1.8E+00 1.0E+00 3.2E+00
1.56E+01 1.9E+01 1.0E+00 3.2E+00
5.79E+00 3.2E+00 1.0E+00 3.2E+00 10 300
5.50E+00 1.7E+01 1.0E+00 3.2E+00
2.27E+01 6.1E-01 1.0E+00 3.2E+00
1.10E+03 4.8E-01 1.0E+00 3.2E+00
1.02E+03 1.2E+00 1.0E+00 3.2E+00
1.17E+03 2.8E-01 1.0E+00 3.2E+00
1.40E+03 6.4E-01 1.0E+00 3.2E+00
2.10E+03 1.4E+00 1.0E+00 3.2E+00
1.44E+01 7.2E+00 1.0E+00 3.2E+00
3.48E+00 1.9E+01 1.0E+00 3.2E+00 10 300
4.52E+00 1.6E+01 1.0E+00 3.2E+00
4.37E+01 2.1E+00 1.0E+00 3.2E+00
1.82E+01 5.6E+00 1.0E+00 3.2E+00
1.28E+03 8.6E-01 1.0E+00 3.2E+00
1.17E+03 5.7E-01 1.0E+00 3.2E+00
1.41E+03 3.7E-01 1.0E+00 3.2E+00
2.17E+03 2.9E+00 1.0E+00 3.2E+00
1.61E+01 7.8E-01 1.0E+00 3.2E+00
2.44E+00 4.2E+01 1.0E+00 3.2E+00 10 300
4.13E+00 1.7E+01 1.0E+00 3.2E+00
3.62E+01 4.6E-01 1.0E+00 3.2E+00
1.91E+01 6.2E+00 1.0E+00 3.2E+00
1.33E+03 1.2E+00 1.0E+00 3.2E+00
1.23E+03 6.5E-01 1.0E+00 3.2E+00
1.47E+03 8.5E-01 1.0E+00 3.2E+00
3.92E+00 3.8E+00 1.0E+00 3.2E+00
1.39E+01 3.0E+00 1.0E+00 3.2E+00
4.98E+01 2.5E+00 1.0E+00 3.2E+00
6.05E+00 6.6E-01 1.0E+00 3.2E+00
1.96E+01 3.7E+00 1.0E+00 3.2E+00
5.28E+01 7.8E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.86E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.03E+03 1 01 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.21E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
7/1/10 11:44 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:46 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:48 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:10 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:51 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:53 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:14 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:56 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:57 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:04 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:06 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:07 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:00 AM EPA Interlab L10 1313-1316 EaFA
7/1/1012:11 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:02 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:03 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 1:46 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:17 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:24 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:25 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:27 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:05 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:30 PM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:07 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 11:08 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:35 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 12:37 PM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:39 AM EPA Interlab L10 1313-1316 EaFA
7/1/1011:41 AM EPA Interlab L10 1313-1316 EaFA
7/1/10 11:43 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:50 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:52 AM EPA Interlab L10 1313-1316 EaFA
7/20/10 10:53 AM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                          1-264
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al EaFA-L11-1313-T01-A 1
Al EaFA-L11-1313-T02-A 1
Al EaFA-L11-1313-T03-A 1
Al EaFA-L11-1313-T04-A 1
Al EaFA-L11-1313-T05-A 1
Al EaFA-L11-1313-T06-A 1
Al EaFA-L11-1313-T07-A 1
Al EaFA-L11-1313-T08-A 1
Al EaFA-L11-1313-T09-A 1
Al EaFA-L11-1313-T01-B 1
Al EaFA-L11-1313-T02-B 1
Al EaFA-L11-1313-T03-B 1
Al EaFA-L11-1313-T04-B 1
Al EaFA-L11-1313-T05-B 1
Al EaFA-L11-1313-T06-B 1
Al EaFA-L11-1313-T07-B 1
Al EaFA-L11-1313-T08-B 1
Al EaFA-L11-1313-T09-B 1
Al EaFA-L11-1313-T01-C 1
Al EaFA-L11-1313-T02-C 1
Al EaFA-L11-1313-T03-C 1
Al EaFA-L11-1313-T04-C 1
Al EaFA-L11-1313-T05-C 1
Al EaFA-L11-1313-T06-C 1
Al EaFA-L11-1313-T07-C 1
Al EaFA-L11-1313-T08-C 1
Al EaFA-L11-1313-T09-C 1
Al EaFA-L11-1313-B01-A 1
Al EaFA-L11-1313-B02-A 1
Al EaFA-L11-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
3.55E+04
4.70E+04
1.70E+04
3.45E+03
6.65E+02
1.29E+02
8.19E+02
4.85E+04
1.19E+05
3.73E+04
3.57E+04
2.31 E+04
2.77E+03
5.16E+02
1.30E+02
1.80E+03
5.78E+04
1.18E+05
3.63E+04
3.60E+04
2.27E+04
2.88E+03
6.30E+02
1.31E+02
1.87E+03
5.81 E+04
1.18E+05
1.47E+00 E
5.73E+00
4.49E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.55E+04 8.6E-01 1.0E+00 3.2E+00
4.70E+04 1.3E+00 1.0E+00 3.2E+00 1000 100
1.70E+04 3.6E-01 1.0E+00 3.2E+00
3.45E+03 6.5E-01 1.0E+00 3.2E+00
6.65E+02 1.1E+00 1.0E+00 3.2E+00
1.29E+02 8.0E-01 1.0E+00 3.2E+00
8.19E+02 1.2E+00 1.0E+00 3.2E+00
4.85E+04 7.9E-01 1.0E+00 3.2E+00
1.19E+05 1.2E+00 1.0E+00 3.2E+00
3.73E+04 8.2E-01 1.0E+00 3.2E+00
3.57E+04 1.2E+00 1.0E+00 3.2E+00 1000 100
2.31 E+04 1.9E-01 1.0E+00 3.2E+00
2.77E+03 6.5E-01 1.0E+00 3.2E+00
5.16E+02 1.0E+00 1.0E+00 3.2E+00
1.30E+02 6.7E-01 1.0E+00 3.2E+00
1.80E+03 1.6E+00 1.0E+00 3.2E+00
5.78E+04 1.5E+00 1.0E+00 3.2E+00
1.18E+05 6.1E-01 1.0E+00 3.2E+00
3.63E+04 3.3E-01 1.0E+00 3.2E+00
3.60E+04 3.5E-01 1.0E+00 3.2E+00 1000 100
2.27E+04 4.2E-01 1.0E+00 3.2E+00
2.88E+03 5.7E-01 1.0E+00 3.2E+00
6.30E+02 8.2E-01 1.0E+00 3.2E+00
1.31E+02 1.7E+00 1.0E+00 3.2E+00
1.87E+03 9.8E-01 1.0E+00 3.2E+00
5.81 E+04 3.2E-01 1.0E+00 3.2E+00
1.18E+05 6.3E-01 1.0E+00 3.2E+00
1.47E+00 5.2E+00 1.0E+00 3.2E+00
5.73E+00 1.9E+00 1.0E+00 3.2E+00
4.49E+00 1.0E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.80E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.65E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.69E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/22/11 2:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:15 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                                   1-265
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L11-1313-T01-A 1
Sb EaFA-L11-1313-T02-A 1
Sb EaFA-L11-1313-T03-A 1
Sb EaFA-L11-1313-T04-A 1
Sb EaFA-L11-1313-T05-A 1
Sb EaFA-L11-1313-T06-A 1
Sb EaFA-L11-1313-T07-A 1
Sb EaFA-L11-1313-T08-A 1
Sb EaFA-L11-1313-T09-A 1
Sb EaFA-L11-1313-T01-B 1
Sb EaFA-L11-1313-T02-B 1
Sb EaFA-L11-1313-T03-B 1
Sb EaFA-L11-1313-T04-B 1
Sb EaFA-L11-1313-T05-B 1
Sb EaFA-L11-1313-T06-B 1
Sb EaFA-L11-1313-T07-B 1
Sb EaFA-L11-1313-T08-B 1
Sb EaFA-L11-1313-T09-B 1
Sb EaFA-L11-1313-T01-C 1
Sb EaFA-L11-1313-T02-C 1
Sb EaFA-L11-1313-T03-C 1
Sb EaFA-L11-1313-T04-C 1
Sb EaFA-L11-1313-T05-C 1
Sb EaFA-L11-1313-T06-C 1
Sb EaFA-L11-1313-T07-C 1
Sb EaFA-L11-1313-T08-C 1
Sb EaFA-L11-1313-T09-C 1
Sb EaFA-L11-1313-B01-A 1
Sb EaFA-L11-1313-B02-A 1
Sb EaFA-L11-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
1.89E+02
1.78E+02
1.12E+02
9.58E+01
1.06E+02
9.29E+01
9.77E+01
2.38E+01 E
3.75E+00 U1/2
1.80E+02
1.75E+02
1.36E+02
1.15E+02
1.26E+02
1.07E+02
1.06E+02
3.92E+01
3.75E+00 U1/2
1 .99E+02
1 .60E+02
1.21E+02
1.14E+02
1 .20E+02
1 .20E+02
8.27E+01
3.54E+01
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.89E+02 1.7E+01 7.5E+00 2.4E+01
1.78E+02 1.8E+01 7.5E+00 2.4E+01 10 325
1.12E+02 1.8E+01 7.5E+00 2.4E+01
9.58E+01 2.5E+01 7.5E+00 2.4E+01
1.06E+02 2.2E+01 7.5E+00 2.4E+01
9.29E+01 1.0E+01 7.5E+00 2.4E+01
9.77E+01 1.9E+01 7.5E+00 2.4E+01
2.38E+01 1.1E+02 7.5E+00 2.4E+01
3.75E+00 9.6E+01 7.5E+00 2.4E+01
1.80E+02 8.5E+00 7.5E+00 2.4E+01
1.75E+02 3.6E+00 7.5E+00 2.4E+01 10 325
1.36E+02 1.0E+01 7.5E+00 2.4E+01
1.15E+02 3.1E+01 7.5E+00 2.4E+01
1.26E+02 1.7E+01 7.5E+00 2.4E+01
1.07E+02 1.9E+01 7.5E+00 2.4E+01
1.06E+02 2.5E+01 7.5E+00 2.4E+01
3.92E+01 2.0E+01 7.5E+00 2.4E+01
3.75E+00 2.0E+02 7.5E+00 2.4E+01
1.99E+02 2.7E+01 7.5E+00 2.4E+01
1.60E+02 2.0E+01 7.5E+00 2.4E+01 10 325
1.21E+02 1.7E+01 7.5E+00 2.4E+01
1.14E+02 1.5E+01 7.5E+00 2.4E+01
1.20E+02 2.9E+01 7.5E+00 2.4E+01
1.20E+02 2.3E+01 7.5E+00 2.4E+01
8.27E+01 2.5E+01 7.5E+00 2.4E+01
3.54E+01 7.8E+00 7.5E+00 2.4E+01
3.75E+00 7.5E+00 7.5E+00 2.4E+01
3.75E+00 7.3E+01 7.5E+00 2.4E+01
3.75E+00 3.3E+01 7.5E+00 2.4E+01
3.75E+00 5.7E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.33E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.74E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.67E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/11 2:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-266
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone.
1 ug/L
As EaFA-L11-1313-T01-A 1 6.09E+03
As EaFA-L11-1313-T02-A 1 1.82E+03
As EaFA-L11-1313-T03-A 1 4.60E+02
As EaFA-L11-1313-T04-A 1 2.53E+02
As EaFA-L11-1313-T05-A 1 1.02E+02
As EaFA-L11-1313-T06-A 1 4.30E+01
As EaFA-L11-1313-T07-A 1 8.39E+01
As EaFA-L11-1313-T08-A 1 5.93E+01
As EaFA-L11-1313-T09-A 1 3.19E+03
As EaFA-L11-1313-T01-B 1 5.81E+03
As EaFA-L11-1313-T02-B 1 2.01E+03
As EaFA-L11-1313-T03-B 1 7.27E+02
As EaFA-L11-1313-T04-B 1 2.25E+02
As EaFA-L11-1313-T05-B 1 1.29E+02
As EaFA-L11-1313-T06-B 1 5.34E+01
As EaFA-L11-1313-T07-B 1 6.08E+01
As EaFA-L11-1313-T08-B 1 6.67E+01
As EaFA-L11-1313-T09-B 1 3.35E+03
As EaFA-L11-1313-T01-C 1 5.67E+03
As EaFA-L11-1313-T02-C 1 2.01E+03
As EaFA-L11-1313-T03-C 1 6.66E+02
As EaFA-L11-1313-T04-C 1 2.14E+02
As EaFA-L11-1313-T05-C 1 1.21E+02
As EaFA-L11-1313-T06-C 1 4.26E+01
As EaFA-L11-1313-T07-C 1 7.31E+01
As EaFA-L11-1313-T08-C 1 6.46E+01
As EaFA-L11-1313-T09-C 1 3.33E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.09E+03 6.7E-01 1.1E+01 3.5E+01
1.82E+03 1.6E+00 1.1E+01 3.5E+01 10 325
4.60E+02 5.7E+00 1.1E+01 3.5E+01
2.53E+02 9.7E+00 1.1E+01 3.5E+01
1.02E+02 1.4E+01 1.1E+01 3.5E+01
4.30E+01 5.6E+01 1.1E+01 3.5E+01
8.39E+01 2.5E+01 1.1E+01 3.5E+01
5.93E+01 5.5E+01 1.1E+01 3.5E+01
3.19E+03 6.7E-01 1.1E+01 3.5E+01
5.81 E+03 1.1E+00 1.1E+01 3.5E+01
2.01E+03 1.6E+00 1.1E+01 3.5E+01 10 325
7.27E+02 1.3E+00 1.1E+01 3.5E+01
2.25E+02 4.3E+00 1.1E+01 3.5E+01
1.29E+02 1.7E+01 1.1E+01 3.5E+01
5.34E+01 2.6E+01 1.1E+01 3.5E+01
6.08E+01 1.8E+01 1.1E+01 3.5E+01
6.67E+01 1.4E+01 1.1E+01 3.5E+01
3.35E+03 3.8E-01 1.1E+01 3.5E+01
5.67E+03 1.0E+00 1.1E+01 3.5E+01
2.01E+03 7.5E-01 1.1E+01 3.5E+01 10 325
6.66E+02 1.4E+00 1.1E+01 3.5E+01
2.14E+02 1.3E+01 1.1E+01 3.5E+01
1.21E+02 1.6E+01 1.1E+01 3.5E+01
4.26E+01 3.1E+01 1.1E+01 3.5E+01
7.31E+01 1.6E+01 1.1E+01 3.5E+01
6.46E+01 2.5E+01 1.1E+01 3.5E+01
3.33E+03 8.6E-01 1.1E+01 3.5E+01
As EaFA-L11-1313-B01-A 1 5.50E+00 U1/2 5.50E+00 1.7E+02 1.1E+01 3.5E+01
As EaFA-L11-1313-B02-A 1 5.50E+00 U1/2 5.50E+00 6.4E+01 1.1E+01 3.5E+01
As EaFA-L11-1313-B03-A 1 5.50E+00 U1/2 5.50E+00 3.1E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
5.03E+03 99% VU ICP-OES 2/22/1 1 2:14 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
5.52E+03 108% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
5.41E+03 104% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/112:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-267
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qu
1 1 ug/L
B EaFA-L11-1313-T01-A 1 2.76E+03
B EaFA-L11-1313-T02-A 1 3.24E+03
B EaFA-L11-1313-T03-A 1 3.96E+03
B EaFA-L11-1313-T04-A 1 3.95E+03
B EaFA-L11-1313-T05-A 1 4.05E+03
B EaFA-L11-1313-T06-A 1 4.30E+03
B EaFA-L11-1313-T07-A 1 4.36E+03
B EaFA-L11-1313-T08-A 1 3.46E+03
B EaFA-L11-1313-T09-A 1 2.95E+03
B EaFA-L11-1313-T01-B 1 2.68E+03
B EaFA-L11-1313-T02-B 1 3.31E+03
B EaFA-L11-1313-T03-B 1 4.03E+03
B EaFA-L11-1313-T04-B 1 4.01E+03
B EaFA-L11-1313-T05-B 1 4.15E+03
B EaFA-L11-1313-T06-B 1 4.31 E+03
B EaFA-L11-1313-T07-B 1 4.13E+03
B EaFA-L11-1313-T08-B 1 3.47E+03
B EaFA-L11-1313-T09-B 1 2.95E+03
B EaFA-L11-1313-T01-C 1 2.55E+03
B EaFA-L11-1313-T02-C 1 3.33E+03
B EaFA-L11-1313-T03-C 1 4.01E+03
B EaFA-L11-1313-T04-C 1 4.04E+03
B EaFA-L11-1313-T05-C 1 4.09E+03
B EaFA-L11-1313-T06-C 1 4.30E+03
B EaFA-L11-1313-T07-C 1 4.12E+03
B EaFA-L11-1313-T08-C 1 3.46E+03
B EaFA-L11-1313-T09-C 1 2.95E+03
B EaFA-L11-1313-B01-A 1 1 .24E+01
B EaFA-L11-1313-B02-A 1 1 .34E+01
B EaFA-L11-1313-B03-A 1 1 .48E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.76E+03 6.0E-01 1.0E+00 3.2E+00
3.24E+03 1.6E+00 1.0E+00 3.2E+00 1000 100
3.96E+03 4.2E-01 1.0E+00 3.2E+00
3.95E+03 1.4E+00 1.0E+00 3.2E+00
4.05E+03 1.5E+00 1.0E+00 3.2E+00
4.30E+03 2.7E+00 1.0E+00 3.2E+00
4.36E+03 7.8E-01 1.0E+00 3.2E+00
3.46E+03 8.1E-01 1.0E+00 3.2E+00
2.95E+03 5.4E-01 1.0E+00 3.2E+00
2.68E+03 7.7E-01 1.0E+00 3.2E+00
3.31E+03 7.9E-01 1.0E+00 3.2E+00 1000 100
4.03E+03 1.1E+00 1.0E+00 3.2E+00
4.01 E+03 7.5E-01 1.0E+00 3.2E+00
4.15E+03 5.6E-02 1.0E+00 3.2E+00
4.31 E+03 7.7E-01 1.0E+00 3.2E+00
4.13E+03 7.5E-01 1.0E+00 3.2E+00
3.47E+03 1.5E+00 1.0E+00 3.2E+00
2.95E+03 6.8E-01 1 .OE+00 3.2E+00
2.55E+03 3.4E-01 1 .OE+00 3.2E+00
3.33E+03 4.8E-01 1 .OE+00 3.2E+00 1000 100
4.01 E+03 1.8E+00 1 .OE+00 3.2E+00
4.04E+03 2.8E-01 1 .OE+00 3.2E+00
4.09E+03 4.7E-01 1 .OE+00 3.2E+00
4.30E+03 3.6E-01 1 .OE+00 3.2E+00
4.12E+03 5.6E-01 1 .OE+00 3.2E+00
3.46E+03 1.5E-01 1 .OE+00 3.2E+00
2.95E+03 7.4E-01 1 .OE+00 3.2E+00
1.24E+01 6.8E+00 1 .OE+00 3.2E+00
1.34E+01 1.1E+01 1. OE+00 3.2E+00
1.48E+02 2.5E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
4.13E+03 89% VU ICP-OES 2/22/1 1 2:14 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
4.26E+03 95% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
4.26E+03 94% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/112:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-268
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFA-L11-1313-T01-A 1
Ba EaFA-L11-1313-T02-A 1
Ba EaFA-L11-1313-T03-A 1
Ba EaFA-L11-1313-T04-A 1
Ba EaFA-L11-1313-T05-A 1
Ba EaFA-L11-1313-T06-A 1
Ba EaFA-L11-1313-T07-A 1
Ba EaFA-L11-1313-T08-A 1
Ba EaFA-L11-1313-T09-A 1
Ba EaFA-L11-1313-T01-B 1
Ba EaFA-L11-1313-T02-B 1
Ba EaFA-L11-1313-T03-B 1
Ba EaFA-L11-1313-T04-B 1
Ba EaFA-L11-1313-T05-B 1
Ba EaFA-L11-1313-T06-B 1
Ba EaFA-L11-1313-T07-B 1
Ba EaFA-L11-1313-T08-B 1
Ba EaFA-L11-1313-T09-B 1
Ba EaFA-L11-1313-T01-C 1
Ba EaFA-L11-1313-T02-C 1
Ba EaFA-L11-1313-T03-C 1
Ba EaFA-L11-1313-T04-C 1
Ba EaFA-L11-1313-T05-C 1
Ba EaFA-L11-1313-T06-C 1
Ba EaFA-L11-1313-T07-C 1
Ba EaFA-L11-1313-T08-C 1
Ba EaFA-L11-1313-T09-C 1
Ba EaFA-L11-1313-B01-A 1
Ba EaFA-L11-1313-B02-A 1
Ba EaFA-L11-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.54E+03
1.61E+03
4.74E+02
3.43E+02
3.10E+02
2.91 E+02
3.44E+02
4.21 E+02
8.12E+02
1.33E+03
1.16E+03
4.93E+02
3.46E+02
3.14E+02
2.95E+02
3.52E+02
2.96E+02
8.16E+02
1 .43E+03
1.01E+03
4.54E+02
3.60E+02
3.08E+02
2.92E+02
3.38E+02
2.76E+02
7.94E+02
1.31E+00 E
2.04E+00 E
2.08E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+03 9.2E-01 1.0E+00 3.2E+00
1.61E+03 1.8E+00 1.0E+00 3.2E+00 10 325
4.74E+02 3.5E-01 1.0E+00 3.2E+00
3.43E+02 4.6E-01 1.0E+00 3.2E+00
3.10E+02 1.3E+00 1.0E+00 3.2E+00
2.91 E+02 4.2E-01 1.0E+00 3.2E+00
3.44E+02 7.3E-02 1.0E+00 3.2E+00
4.21 E+02 1.1E+00 1.0E+00 3.2E+00
8.12E+02 3.5E-01 1.0E+00 3.2E+00
1.33E+03 1.1E+00 1.0E+00 3.2E+00
1.16E+03 1.1E+00 1.0E+00 3.2E+00 10 325
4.93E+02 1.1E-01 1.0E+00 3.2E+00
3.46E+02 7.7E-01 1.0E+00 3.2E+00
3.14E+02 3.4E-01 1.0E+00 3.2E+00
2.95E+02 1.2E-01 1.0E+00 3.2E+00
3.52E+02 1.3E+00 1 .OE+00 3.2E+00
2.96E+02 1.5E+00 1 .OE+00 3.2E+00
8.16E+02 2.4E-01 1 .OE+00 3.2E+00
1.43E+03 3.4E-01 1 .OE+00 3.2E+00
1.01E+03 8.1E-01 1. OE+00 3.2E+00 10 325
4.54E+02 2.7E-01 1 .OE+00 3.2E+00
3.60E+02 1.3E+00 1 .OE+00 3.2E+00
3.08E+02 7.6E-02 1 .OE+00 3.2E+00
2.92E+02 8.1E-01 1 .OE+00 3.2E+00
3.38E+02 1.3E+00 1 .OE+00 3.2E+00
2.76E+02 2.6E-01 1 .OE+00 3.2E+00
7.94E+02 5.5E-01 1 .OE+00 3.2E+00
1.31E+00 1.1E+01 1. OE+00 3.2E+00
2.04E+00 2.9E+00 1 .OE+00 3.2E+00
2.08E+00 1.7E+01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
4.34E+03 84% VU ICP-OES 2/22/1 1 2:14 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
4.23E+03 95% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
4.07E+03 94% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:1 0PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-269
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L11-1313-T01-A 1
Be EaFA-L11-1313-T02-A 1
Be EaFA-L11-1313-T03-A 1
Be EaFA-L11-1313-T04-A 1
Be EaFA-L11-1313-T05-A 1
Be EaFA-L11-1313-T06-A 1
Be EaFA-L11-1313-T07-A 1
Be EaFA-L11-1313-T08-A 1
Be EaFA-L11-1313-T09-A 1
Be EaFA-L11-1313-T01-B 1
Be EaFA-L11-1313-T02-B 1
Be EaFA-L11-1313-T03-B 1
Be EaFA-L11-1313-T04-B 1
Be EaFA-L11-1313-T05-B 1
Be EaFA-L11-1313-T06-B 1
Be EaFA-L11-1313-T07-B 1
Be EaFA-L11-1313-T08-B 1
Be EaFA-L11-1313-T09-B 1
Be EaFA-L11-1313-T01-C 1
Be EaFA-L11-1313-T02-C 1
Be EaFA-L11-1313-T03-C 1
Be EaFA-L11-1313-T04-C 1
Be EaFA-L11-1313-T05-C 1
Be EaFA-L11-1313-T06-C 1
Be EaFA-L11-1313-T07-C 1
Be EaFA-L11-1313-T08-C 1
Be EaFA-L11-1313-T09-C 1
Be EaFA-L11-1313-B01-A 1
Be EaFA-L11-1313-B02-A 1
Be EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
6.79E+00
1.42E+02
2.53E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.34E+01
1.72E+02
2.55E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.42E+01
1.73E+02
2.51 E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 3.7E+01 1.9E+00 6.0E+00
9.50E-01 6.0E+01 1.9E+00 6.0E+00 10 325
9.50E-01 2.5E+01 1.9E+00 6.0E+00
9.50E-01 1.1 E+02 1.9E+00 6.0E+00
9.50E-01 7.9E+01 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
6.79E+00 9.1E+00 1.9E+00 6.0E+00
1.42E+02 7.9E-01 1.9E+00 6.0E+00
2.53E+02 5.5E-01 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
9.50E-01 4.2E+02 1.9E+00 6.0E+00 10 325
9.50E-01 2.5E+02 1.9E+00 6.0E+00
9.50E-01 2.4E+01 1.9E+00 6.0E+00
9.50E-01 3.2E+02 1.9E+00 6.0E+00
9.50E-01 9.7E+01 1.9E+00 6.0E+00
1.34E+01 3.6E+00 1.9E+00 6.0E+00
1.72E+02 1.3E+00 1.9E+00 6.0E+00
2.55E+02 9.1E-01 1.9E+00 6.0E+00
9.50E-01 2.4E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+03 1.9E+00 6.0E+00 10 325
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+03 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 5.8E+01 1.9E+00 6.0E+00
1.42E+01 1.4E+00 1.9E+00 6.0E+00
1.73E+02 6.3E-01 1.9E+00 6.0E+00
2.51 E+02 5.3E-01 1.9E+00 6.0E+00
9.50E-01 1.0E+01 1.9E+00 6.0E+00
9.50E-01 3.7E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
3.26E+03 100% VU ICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:32 PM EPA Interlab L1 1 1313-1316 EaFA
3.65E+03 112% VUICP-OES 2/22/1 1 2:33 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:35 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:37 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
3.60E+03 111% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:53 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:55 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:56 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:58 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 3:00 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:07 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:09 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-270
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-L11-1313-T01-A 1
Cd EaFA-L11-1313-T02-A 1
Cd EaFA-L11-1313-T03-A 1
Cd EaFA-L11-1313-T04-A 1
Cd EaFA-L11-1313-T05-A 1
Cd EaFA-L11-1313-T06-A 1
Cd EaFA-L11-1313-T07-A 1
Cd EaFA-L11-1313-T08-A 1
Cd EaFA-L11-1313-T09-A 1
Cd EaFA-L11-1313-T01-B 1
Cd EaFA-L11-1313-T02-B 1
Cd EaFA-L11-1313-T03-B 1
Cd EaFA-L11-1313-T04-B 1
Cd EaFA-L11-1313-T05-B 1
Cd EaFA-L11-1313-T06-B 1
Cd EaFA-L11-1313-T07-B 1
Cd EaFA-L11-1313-T08-B 1
Cd EaFA-L11-1313-T09-B 1
Cd EaFA-L11-1313-T01-C 1
Cd EaFA-L11-1313-T02-C 1
Cd EaFA-L11-1313-T03-C 1
Cd EaFA-L11-1313-T04-C 1
Cd EaFA-L11-1313-T05-C 1
Cd EaFA-L11-1313-T06-C 1
Cd EaFA-L11-1313-T07-C 1
Cd EaFA-L11-1313-T08-C 1
Cd EaFA-L11-1313-T09-C 1
Cd EaFA-L11-1313-B01-A 1
Cd EaFA-L11-1313-B02-A 1
Cd EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.59E+01
2.76E+01
3.46E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.79E+01
2.91E+01
3.46E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.78E+01
2.92E+01
3.46E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 2.3E+02 2.2E+00 7.0E+00
1.10E+00 1.7E+02 2.2E+00 7.0E+00 10 325
1.10E+00 6.0E+01 2.2E+00 7.0E+00
1.10E+00 6.0E+01 2.2E+00 7.0E+00
1.10E+00 4.4E+02 2.2E+00 7.0E+00
1.10E+00 4.1E+01 2.2E+00 7.0E+00
3.59E+01 7.7E-01 2.2E+00 7.0E+00
2.76E+01 3.0E+00 2.2E+00 7.0E+00
3.46E+01 6.8E-01 2.2E+00 7.0E+00
1.10E+00 5.3E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+02 2.2E+00 7.0E+00 10 325
1.10E+00 7.8E+01 2.2E+00 7.0E+00
1.10E+00 2.4E+02 2.2E+00 7.0E+00
1.10E+00 3.4E+02 2.2E+00 7.0E+00
1.10E+00 1.0E+02 2.2E+00 7.0E+00
3.79E+01 1.0E+00 2.2E+00 7.0E+00
2.91E+01 3.1E+00 2.2E+00 7.0E+00
3.46E+01 1.7E+00 2.2E+00 7.0E+00
1.10E+00 2.2E+02 2.2E+00 7.0E+00
1.10E+00 1.6E+02 2.2E+00 7.0E+00 10 325
1.10E+00 1.4E+02 2.2E+00 7.0E+00
1.10E+00 7.2E+01 2.2E+00 7.0E+00
1.10E+00 2.7E+02 2.2E+00 7.0E+00
1.10E+00 3.3E+01 2.2E+00 7.0E+00
3.78E+01 2.8E+00 2.2E+00 7.0E+00
2.92E+01 2.1E+00 2.2E+00 7.0E+00
3.46E+01 1.1E+00 2.2E+00 7.0E+00
1.10E+00 7.9E+01 2.2E+00 7.0E+00
1.10E+00 3.4E+04 2.2E+00 7.0E+00
1.10E+00 2.1E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 2/22/11 2:12 PM EPA Interlab L11 1313-1316 EaFA
3.23E+03 99% VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:15 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
3.61E+03 111% VUICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
3.55E+03 109% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-271
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca EaFA-L11-1313-T01-A 1
Ca EaFA-L11-1313-T02-A 1
Ca EaFA-L11-1313-T03-A 1
Ca EaFA-L11-1313-T04-A 1
Ca EaFA-L11-1313-T05-A 1
Ca EaFA-L11-1313-T06-A 1
Ca EaFA-L11-1313-T07-A 1
Ca EaFA-L11-1313-T08-A 1
Ca EaFA-L11-1313-T09-A 1
Ca EaFA-L11-1313-T01-B 1
Ca EaFA-L11-1313-T02-B 1
Ca EaFA-L11-1313-T03-B 1
Ca EaFA-L11-1313-T04-B 1
Ca EaFA-L11-1313-T05-B 1
Ca EaFA-L11-1313-T06-B 1
Ca EaFA-L11-1313-T07-B 1
Ca EaFA-L11-1313-T08-B 1
Ca EaFA-L11-1313-T09-B 1
Ca EaFA-L11-1313-T01-C 1
Ca EaFA-L11-1313-T02-C 1
Ca EaFA-L11-1313-T03-C 1
Ca EaFA-L11-1313-T04-C 1
Ca EaFA-L11-1313-T05-C 1
Ca EaFA-L11-1313-T06-C 1
Ca EaFA-L11-1313-T07-C 1
Ca EaFA-L11-1313-T08-C 1
Ca EaFA-L11-1313-T09-C 1
Ca EaFA-L11-1313-B01-A 1
Ca EaFA-L11-1313-B02-A 1
Ca EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.59E+04
2.64E+04
9.85E+04
1.28E+05
1.42E+05
1.57E+05
1.64E+05
1.47E+05
1.39E+05
1.57E+04
4.37E+04
1.01E+05
1.30E+05
1.45E+05
1.56E+05
1.54E+05
1.47E+05
1.39E+05
1.56E+04
4.30E+04
1.00E+05
1.30E+05
1.43E+05
1.53E+05
1.53E+05
1.46E+05
1.39E+05
3.45E+00 E
4.70E+01
1.86E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+04 5.8E-01 2.6E+00 8.3E+00
2.64E+04 1.1E+00 2.6E+00 8.3E+00 1000 100
9.85E+04 3.6E-01 2.6E+00 8.3E+00
1.28E+05 6.4E-01 2.6E+00 8.3E+00
1.42E+05 3.9E-01 2.6E+00 8.3E+00
1.57E+05 1.2E+00 2.6E+00 8.3E+00
1.64E+05 4.7E-01 2.6E+00 8.3E+00
1.47E+05 1.1E+00 2.6E+00 8.3E+00
1.39E+05 7.0E-01 2.6E+00 8.3E+00
1.57E+04 1.2E+00 2.6E+00 8.3E+00
4.37E+04 6.9E-01 2.6E+00 8.3E+00 1000 100
1.01E+05 1.1E-01 2.6E+00 8.3E+00
1.30E+05 7.6E-01 2.6E+00 8.3E+00
1.45E+05 6.2E-01 2.6E+00 8.3E+00
1.56E+05 1.1E+00 2.6E+00 8.3E+00
1.54E+05 1.1E+00 2.6E+00 8.3E+00
1.47E+05 1.4E+00 2.6E+00 8.3E+00
1.39E+05 6.8E-01 2.6E+00 8.3E+00
1.56E+04 2.7E-01 2.6E+00 8.3E+00
4.30E+04 8.0E-01 2.6E+00 8.3E+00 1000 100
1.00E+05 3.4E-01 2.6E+00 8.3E+00
1.30E+05 4.5E-01 2.6E+00 8.3E+00
1.43E+05 6.0E-01 2.6E+00 8.3E+00
1.53E+05 1.1E+00 2.6E+00 8.3E+00
1.53E+05 6.1E-01 2.6E+00 8.3E+00
1.46E+05 5.4E-01 2.6E+00 8.3E+00
1.39E+05 2.0E-01 2.6E+00 8.3E+00
3.45E+00 6.6E+01 2.6E+00 8.3E+00
4.70E+01 2.5E+01 2.6E+00 8.3E+00
1.86E+01 2.6E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
2.73E+04 90%VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:32 PM EPA Interlab L1 1 1313-1316 EaFA
4.46E+04 88% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:35 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:37 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:42 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:43 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:45 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:47 PM EPA Interlab L1 1 1313-1316 EaFA
4.39E+04 86% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:50 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:51 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:53 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:55 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:56 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:58 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 3:00 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:07 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:09 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:10 PM EPA Interlab L1 1 1313-1316 EaFA
                                                                                                                                                                          1-272
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Sample
Sample Dilution Cone.
1 ug/L
EaFA-L11-1313-T01-A 1 5.19E+02
EaFA-L11-1313-T02-A 1 4.89E+02
EaFA-L11-1313-T03-A 1 4.54E+02
EaFA-L11-1313-T04-A 1 4.03E+02
EaFA-L11-1313-T05-A 1 3.32E+02
EaFA-L11-1313-T06-A 1 1.21E+02
EaFA-L11-1313-T07-A 1 4.13E+00
EaFA-L11-1313-T08-A 1 6.57E+02
EaFA-L11-1313-T09-A 1 1.81E+03
EaFA-L11-1313-T01-B 1 5.46E+02
EaFA-L11-1313-T02-B 1 4.67E+02
EaFA-L11-1313-T03-B 1 4.16E+02
EaFA-L11-1313-T04-B 1 3.76E+02
EaFA-L11-1313-T05-B 1 2.95E+02
EaFA-L11-1313-T06-B 1 1.20E+02
EaFA-L11-1313-T07-B 1 3.86E+00
EaFA-L11-1313-T08-B 1 8.29E+02
EaFA-L11-1313-T09-B 1 1.80E+03
EaFA-L11-1313-T01-C 1 5.18E+02
EaFA-L11-1313-T02-C 1 4.60E+02
EaFA-L11-1313-T03-C 1 4.28E+02
EaFA-L11-1313-T04-C 1 3.82E+02
EaFA-L11-1313-T05-C 1 2.95E+02
EaFA-L11-1313-T06-C 1 1.20E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.19E+02 9.1E-01 1.2E+00 3.8E+00
4.89E+02 1.2E+00 1.2E+00 3.8E+00 10 325
4.54E+02 7.7E-02 1.2E+00 3.8E+00
4.03E+02 3.5E-01 1.2E+00 3.8E+00
3.32E+02 5.7E-01 1.2E+00 3.8E+00
1.21E+02 6.1E-01 1.2E+00 3.8E+00
4.13E+00 5.7E+01 1.2E+00 3.8E+00
6.57E+02 1.2E+00 1.2E+00 3.8E+00
1.81E+03 8.1E-01 1.2E+00 3.8E+00
5.46E+02 1.3E+00 1.2E+00 3.8E+00
4.67E+02 2.6E-01 1.2E+00 3.8E+00 10 325
4.16E+02 3.0E-02 1.2E+00 3.8E+00
3.76E+02 1.1E+00 1.2E+00 3.8E+00
2.95E+02 1.3E+00 1.2E+00 3.8E+00
1.20E+02 2.3E-01 1.2E+00 3.8E+00
3.86E+00 2.7E+01 1.2E+00 3.8E+00
8.29E+02 1.4E+00 1.2E+00 3.8E+00
1.80E+03 5.4E-01 1.2E+00 3.8E+00
5.18E+02 5.4E-01 1.2E+00 3.8E+00
4.60E+02 1.1E+00 1.2E+00 3.8E+00 10 325
4.28E+02 9.3E-02 1.2E+00 3.8E+00
3.82E+02 2.9E-01 1.2E+00 3.8E+00
2.95E+02 3.6E-01 1.2E+00 3.8E+00
1.20E+02 1.3E+00 1.2E+00 3.8E+00
EaFA-L11-1313-T07-C 1 2.90E+00 E 2.90E+00 1 .8E+01 1.2E+00 3.8E+00
EaFA-L11-1313-T08-C 1 8.25E+02
EaFA-L11-1313-T09-C 1 1.81E+03
8.25E+02 1.1E+00 1.2E+00 3.8E+00
1.81E+03 5.2E-01 1.2E+00 3.8E+00
EaFA-L11-1313-B01-A 1 6.00E-01 U1/2 6.00E-01 1 .8E+02 1.2E+00 3.8E+00
EaFA-L11-1313-B02-A 1 6.00E-01 U1/2 6.00E-01 2.4E+02 1.2E+00 3.8E+00
EaFA-L11-1313-B03-A 1 2.83E+00 E 2.83E+00 4.5E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
3.59E+03 95% VU ICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:32 PM EPA Interlab L1 1 1313-1316 EaFA
3.93E+03 107% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:35 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:37 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:42 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:43 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:45 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:47 PM EPA Interlab L1 1 1313-1316 EaFA
3.84E+03 104% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:50 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:51 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:53 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:55 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:56 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:58 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 3:00 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-273
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-L11-1313-T01-A 1
Co EaFA-L11-1313-T02-A 1
Co EaFA-L11-1313-T03-A 1
Co EaFA-L11-1313-T04-A 1
Co EaFA-L11-1313-T05-A 1
Co EaFA-L11-1313-T06-A 1
Co EaFA-L11-1313-T07-A 1
Co EaFA-L11-1313-T08-A 1
Co EaFA-L11-1313-T09-A 1
Co EaFA-L11-1313-T01-B 1
Co EaFA-L11-1313-T02-B 1
Co EaFA-L11-1313-T03-B 1
Co EaFA-L11-1313-T04-B 1
Co EaFA-L11-1313-T05-B 1
Co EaFA-L11-1313-T06-B 1
Co EaFA-L11-1313-T07-B 1
Co EaFA-L11-1313-T08-B 1
Co EaFA-L11-1313-T09-B 1
Co EaFA-L11-1313-T01-C 1
Co EaFA-L11-1313-T02-C 1
Co EaFA-L11-1313-T03-C 1
Co EaFA-L11-1313-T04-C 1
Co EaFA-L11-1313-T05-C 1
Co EaFA-L11-1313-T06-C 1
Co EaFA-L11-1313-T07-C 1
Co EaFA-L11-1313-T08-C 1
Co EaFA-L11-1313-T09-C 1
Co EaFA-L11-1313-B01-A 1
Co EaFA-L11-1313-B02-A 1
Co EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
1.89E+00 E
2.46E+01
2.32E+02
2.06E+02
3.94E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
1.85E+00 E
2.94E+01
2.33E+02
2.28E+02
3.89E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.96E+00 E
3.00E+01
2.33E+02
2.24E+02
3.89E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 4.4E+01 1.8E+00 5.7E+00
9.00E-01 7.5E+00 1.8E+00 5.7E+00 10 325
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 3.3E+02 1.8E+00 5.7E+00
1.89E+00 2.3E+02 1.8E+00 5.7E+00
2.46E+01 7.4E+00 1.8E+00 5.7E+00
2.32E+02 1.7E+00 1.8E+00 5.7E+00
2.06E+02 4.4E-01 1.8E+00 5.7E+00
3.94E+02 6.0E-01 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 9.5E+00 1.8E+00 5.7E+00 10 325
9.00E-01 6.1E+01 1.8E+00 5.7E+00
9.00E-01 4.3E+01 1.8E+00 5.7E+00
1.85E+00 1.1E+02 1.8E+00 5.7E+00
2.94E+01 1.4E+01 1.8E+00 5.7E+00
2.33E+02 5.4E-01 1.8E+00 5.7E+00
2.28E+02 1.2E+00 1.8E+00 5.7E+00
3.89E+02 2.8E-01 1.8E+00 5.7E+00
9.00E-01 7.6E+02 1.8E+00 5.7E+00
9.00E-01 2.8E+02 1.8E+00 5.7E+00 10 325
9.00E-01 9.1E+01 1.8E+00 5.7E+00
9.00E-01 7.6E+01 1.8E+00 5.7E+00
2.96E+00 4.0E+01 1.8E+00 5.7E+00
3.00E+01 5.6E+00 1.8E+00 5.7E+00
2.33E+02 2.2E+00 1.8E+00 5.7E+00
2.24E+02 1.6E+00 1.8E+00 5.7E+00
3.89E+02 1.2E+00 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 3.2E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 2/22/11 2:12 PM EPA Interlab L11 1313-1316 EaFA
3.12E+03 96% VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:15 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
3.43E+03 106% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:42 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:43 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:45 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
3.41E+03 105% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-274
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFA-L11-1313-T01-A 1
Cu EaFA-L11-1313-T02-A 1
Cu EaFA-L11-1313-T03-A 1
Cu EaFA-L11-1313-T04-A 1
Cu EaFA-L11-1313-T05-A 1
Cu EaFA-L11-1313-T06-A 1
Cu EaFA-L11-1313-T07-A 1
Cu EaFA-L11-1313-T08-A 1
Cu EaFA-L11-1313-T09-A 1
Cu EaFA-L11-1313-T01-B 1
Cu EaFA-L11-1313-T02-B 1
Cu EaFA-L11-1313-T03-B 1
Cu EaFA-L11-1313-T04-B 1
Cu EaFA-L11-1313-T05-B 1
Cu EaFA-L11-1313-T06-B 1
Cu EaFA-L11-1313-T07-B 1
Cu EaFA-L11-1313-T08-B 1
Cu EaFA-L11-1313-T09-B 1
Cu EaFA-L11-1313-T01-C 1
Cu EaFA-L11-1313-T02-C 1
Cu EaFA-L11-1313-T03-C 1
Cu EaFA-L11-1313-T04-C 1
Cu EaFA-L11-1313-T05-C 1
Cu EaFA-L11-1313-T06-C 1
Cu EaFA-L11-1313-T07-C 1
Cu EaFA-L11-1313-T08-C 1
Cu EaFA-L11-1313-T09-C 1
Cu EaFA-L11-1313-B01-A 1
Cu EaFA-L11-1313-B02-A 1
Cu EaFA-L11-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.48E+01
1.16E+01 E
1.79E+01
1.43E+01
1.27E+01
1.70E+01
1.49E+02
1.22E+03
3.18E+03
1.40E+01
1.21E+01
1.32E+01
1.49E+01
1.63E+01
1.48E+01
3.57E+02
2.34E+03
3.15E+03
1.96E+01
1.68E+01
6.43E+00 E
1.30E+01
1.45E+01
1.82E+01
3.78E+02
2.34E+03
3.17E+03
1.85E+00 U1/2
1.85E+00 U1/2
6.91 E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.48E+01 3.8E+01 3.7E+00 1 .2E+01
1.16E+01 7.2E+02 3.7E+00 1 .2E+01 10 325
1.79E+01 5.0E+01 3.7E+00 1 .2E+01
1.43E+01 2.5E+01 3.7E+00 1 .2E+01
1.27E+01 7.0E+01 3.7E+00 1 .2E+01
1.70E+01 5.9E+01 3.7E+00 1 .2E+01
1.49E+02 1.0E+01 3.7E+00 1 .2E+01
1.22E+03 8.4E-01 3.7E+00 1 .2E+01
3.18E+03 7.8E-01 3.7E+00 1 .2E+01
1.40E+01 3.8E+01 3.7E+00 1 .2E+01
1.21E+01 3.4E+01 3.7E+00 1 .2E+01 10 325
1.32E+01 1.9E+01 3.7E+00 1 .2E+01
1.49E+01 3.2E+01 3.7E+00 1 .2E+01
1.63E+01 4.3E+01 3.7E+00 1 .2E+01
1.48E+01 3.7E+01 3.7E+00 1 .2E+01
3.57E+02 1.2E+00 3.7E+00 1 .2E+01
2.34E+03 1.2E+00 3.7E+00 1 .2E+01
3.15E+03 2.4E-01 3.7E+00 1 .2E+01
1.96E+01 4.3E+01 3.7E+00 1 .2E+01
1.68E+01 2.0E+01 3.7E+00 1 .2E+01 10 325
6.43E+00 7.6E+01 3.7E+00 1 .2E+01
1.30E+01 5.3E+01 3.7E+00 1 .2E+01
1.45E+01 4.2E+01 3.7E+00 1 .2E+01
1.82E+01 4.1 E+00 3.7E+00 1 .2E+01
3.78E+02 7.1E-01 3.7E+00 1 .2E+01
2.34E+03 1.2E+00 3.7E+00 1 .2E+01
3.17E+03 8.6E-01 3.7E+00 1 .2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01
1.85E+00 5.3E+01 3.7E+00 1.2E+01
6.91E+00 2.2E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
3.08E+03 94% VU ICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:32 PM EPA Interlab L1 1 1313-1316 EaFA
3.44E+03 105% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:35 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:37 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:42 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:43 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:45 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:47 PM EPA Interlab L1 1 1313-1316 EaFA
3.37E+03 103% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:50 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:51 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:53 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:55 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:56 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:58 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 3:00 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-275
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L11-1313-T01-A 1
Fe EaFA-L11-1313-T02-A 1
Fe EaFA-L11-1313-T03-A 1
Fe EaFA-L11-1313-T04-A 1
Fe EaFA-L11-1313-T05-A 1
Fe EaFA-L11-1313-T06-A 1
Fe EaFA-L11-1313-T07-A 1
Fe EaFA-L11-1313-T08-A 1
Fe EaFA-L11-1313-T09-A 1
Fe EaFA-L11-1313-T01-B 1
Fe EaFA-L11-1313-T02-B 1
Fe EaFA-L11-1313-T03-B 1
Fe EaFA-L11-1313-T04-B 1
Fe EaFA-L11-1313-T05-B 1
Fe EaFA-L11-1313-T06-B 1
Fe EaFA-L11-1313-T07-B 1
Fe EaFA-L11-1313-T08-B 1
Fe EaFA-L11-1313-T09-B 1
Fe EaFA-L11-1313-T01-C 1
Fe EaFA-L11-1313-T02-C 1
Fe EaFA-L11-1313-T03-C 1
Fe EaFA-L11-1313-T04-C 1
Fe EaFA-L11-1313-T05-C 1
Fe EaFA-L11-1313-T06-C 1
Fe EaFA-L11-1313-T07-C 1
Fe EaFA-L11-1313-T08-C 1
Fe EaFA-L11-1313-T09-C 1
Fe EaFA-L11-1313-B01-A 1
Fe EaFA-L11-1313-B02-A 1
Fe EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.26E+01
9.26E+02
3.69E+04
2.58E+01
8.58E+00
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.73E+00 E
1.81E+03
3.66E+04
3.00E+01
7.97E+00
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.79E+03
3.67E+04
1.00E+00 U1/2
4.61 E+00 E
5.58E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+01 3.2E+00 2.0E+00 6.4E+00
1.00E+00 5.3E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 7.5E+01 2.0E+00 6.4E+00
1.00E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.26E+01 1.1E+01 2.0E+00 6.4E+00
9.26E+02 9.7E-01 2.0E+00 6.4E+00
3.69E+04 9.8E-01 2.0E+00 6.4E+00
2.58E+01 2.8E+00 2.0E+00 6.4E+00
8.58E+00 2.6E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 8.7E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
2.73E+00 1.5E+01 2.0E+00 6.4E+00
1.81E+03 3.6E-01 2.0E+00 6.4E+00
3.66E+04 5.4E-01 2.0E+00 6.4E+00
3.00E+01 4.2E-01 2.0E+00 6.4E+00
7.97E+00 9.4E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 3.7E+01 2.0E+00 6.4E+00
1.00E+00 5.2E+00 2.0E+00 6.4E+00
1.00E+00 9.5E+00 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+02 2.0E+00 6.4E+00
1.79E+03 3.4E-01 2.0E+00 6.4E+00
3.67E+04 3.8E-01 2.0E+00 6.4E+00
1.00E+00 8.0E+00 2.0E+00 6.4E+00
4.61 E+00 1.3E+01 2.0E+00 6.4E+00
5.58E+00 1.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
1.02E+03 102% VU ICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
1.14E+03 113% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
1.12E+03 111% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:56 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:58 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 3:00 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:07 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:09 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:10 PM EPA Interlab L1 1 1313-1316 EaFA
                                                                                                                                                                          1-276
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L11-1313-T01-A 1
Pb EaFA-L11-1313-T02-A 1
Pb EaFA-L11-1313-T03-A 1
Pb EaFA-L11-1313-T04-A 1
Pb EaFA-L11-1313-T05-A 1
Pb EaFA-L11-1313-T06-A 1
Pb EaFA-L11-1313-T07-A 1
Pb EaFA-L11-1313-T08-A 1
Pb EaFA-L11-1313-T09-A 1
Pb EaFA-L11-1313-T01-B 1
Pb EaFA-L11-1313-T02-B 1
Pb EaFA-L11-1313-T03-B 1
Pb EaFA-L11-1313-T04-B 1
Pb EaFA-L11-1313-T05-B 1
Pb EaFA-L11-1313-T06-B 1
Pb EaFA-L11-1313-T07-B 1
Pb EaFA-L11-1313-T08-B 1
Pb EaFA-L11-1313-T09-B 1
Pb EaFA-L11-1313-T01-C 1
Pb EaFA-L11-1313-T02-C 1
Pb EaFA-L11-1313-T03-C 1
Pb EaFA-L11-1313-T04-C 1
Pb EaFA-L11-1313-T05-C 1
Pb EaFA-L11-1313-T06-C 1
Pb EaFA-L11-1313-T07-C 1
Pb EaFA-L11-1313-T08-C 1
Pb EaFA-L11-1313-T09-C 1
Pb EaFA-L11-1313-B01-A 1
Pb EaFA-L11-1313-B02-A 1
Pb EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
8.99E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
8.26E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
9.22E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 3.3E+01 6.8E+00 2.2E+01
3.40E+00 1.2E+02 6.8E+00 2.2E+01 10 325
3.40E+00 2.7E+01 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
3.40E+00 7.8E+01 6.8E+00 2.2E+01
3.40E+00 3.0E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
3.40E+00 4.9E+00 6.8E+00 2.2E+01
8.99E+01 1.9E+00 6.8E+00 2.2E+01
3.40E+00 3.0E+02 6.8E+00 2.2E+01
3.40E+00 1.9E+02 6.8E+00 2.2E+01 10 325
3.40E+00 1.6E+01 6.8E+00 2.2E+01
3.40E+00 7.6E+01 6.8E+00 2.2E+01
3.40E+00 1.2E+02 6.8E+00 2.2E+01
3.40E+00 1.6E+02 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.40E+00 4.8E+01 6.8E+00 2.2E+01
8.26E+01 1.3E+01 6.8E+00 2.2E+01
3.40E+00 2.3E+02 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01 10 325
3.40E+00 4.0E+01 6.8E+00 2.2E+01
3.40E+00 4.9E+01 6.8E+00 2.2E+01
3.40E+00 5.6E+01 6.8E+00 2.2E+01
3.40E+00 4.8E+01 6.8E+00 2.2E+01
3.40E+00 1.2E+01 6.8E+00 2.2E+01
3.40E+00 3.5E+01 6.8E+00 2.2E+01
9.22E+01 2.0E+00 6.8E+00 2.2E+01
3.40E+00 2.7E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 7.4E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 2/22/11 2:12 PM EPA Interlab L11 1313-1316 EaFA
3.08E+03 95% VU ICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:15 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:32 PM EPA Interlab L1 1 1313-1316 EaFA
3.42E+03 105% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:35 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:37 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:42 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:43 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:45 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:47 PM EPA Interlab L1 1 1313-1316 EaFA
3.39E+03 104% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-277
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFA-L11-1313-T01-A 1
Li EaFA-L11-1313-T02-A 1
Li EaFA-L11-1313-T03-A 1
Li EaFA-L11-1313-T04-A 1
Li EaFA-L11-1313-T05-A 1
Li EaFA-L11-1313-T06-A 1
Li EaFA-L11-1313-T07-A 1
Li EaFA-L11-1313-T08-A 1
Li EaFA-L11-1313-T09-A 1
Li EaFA-L11-1313-T01-B 1
Li EaFA-L11-1313-T02-B 1
Li EaFA-L11-1313-T03-B 1
Li EaFA-L11-1313-T04-B 1
Li EaFA-L11-1313-T05-B 1
Li EaFA-L11-1313-T06-B 1
Li EaFA-L11-1313-T07-B 1
Li EaFA-L11-1313-T08-B 1
Li EaFA-L11-1313-T09-B 1
Li EaFA-L11-1313-T01-C 1
Li EaFA-L11-1313-T02-C 1
Li EaFA-L11-1313-T03-C 1
Li EaFA-L11-1313-T04-C 1
Li EaFA-L11-1313-T05-C 1
Li EaFA-L11-1313-T06-C 1
Li EaFA-L11-1313-T07-C 1
Li EaFA-L11-1313-T08-C 1
Li EaFA-L11-1313-T09-C 1
Li EaFA-L11-1313-B01-A 1
Li EaFA-L11-1313-B02-A 1
Li EaFA-L11-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.72E+03
3.03E+03
2.47E+03
3.42E+03
3.49E+03
3.58E+03
3.75E+03
2.09E+03
1.72E+03
2.75E+03
3.02E+03
3.28E+03
3.45E+03
3.53E+03
3.56E+03
3.43E+03
2.20E+03
1.73E+03
2.69E+03
3.05E+03
3.30E+03
3.46E+03
3.51 E+03
3.53E+03
3.42E+03
2.21E+03
1.71 E+03
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.72E+03 6.7E-01 1.9E+00 6.0E+00
3.03E+03 1.2E+00 1.9E+00 6.0E+00 10 325
2.47E+03 6.9E-01 1.9E+00 6.0E+00
3.42E+03 4.2E-01 1.9E+00 6.0E+00
3.49E+03 1.2E+00 1.9E+00 6.0E+00
3.58E+03 4.2E-01 1.9E+00 6.0E+00
3.75E+03 3.1E-01 1.9E+00 6.0E+00
2.09E+03 1.6E+00 1.9E+00 6.0E+00
1.72E+03 9.0E-01 1.9E+00 6.0E+00
2.75E+03 8.6E-01 1.9E+00 6.0E+00
3.02E+03 6.9E-01 1.9E+00 6.0E+00 10 325
3.28E+03 8.1E-02 1.9E+00 6.0E+00
3.45E+03 4.5E-01 1.9E+00 6.0E+00
3.53E+03 7.9E-01 1.9E+00 6.0E+00
3.56E+03 4.3E-01 1.9E+00 6.0E+00
3.43E+03 1.2E+00 1.9E+00 6.0E+00
2.20E+03 1.6E+00 1.9E+00 6.0E+00
1.73E+03 3.1E-01 1.9E+00 6.0E+00
2.69E+03 5.8E-01 1.9E+00 6.0E+00
3.05E+03 9.5E-01 1.9E+00 6.0E+00 10 325
3.30E+03 4.3E-01 1.9E+00 6.0E+00
3.46E+03 5.1E-01 1.9E+00 6.0E+00
3.51 E+03 4.7E-01 1.9E+00 6.0E+00
3.53E+03 4.0E-01 1.9E+00 6.0E+00
3.42E+03 3.1E-01 1.9E+00 6.0E+00
2.21 E+03 7.7E-01 1.9E+00 6.0E+00
1.71 E+03 5.2E-01 1.9E+00 6.0E+00
9.50E-01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 8.5E+00 1.9E+00 6.0E+00
9.50E-01 4.7E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
5.69E+03 82%VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:32 PM EPA Interlab L1 1 1313-1316 EaFA
5.79E+03 85% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:35 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:37 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:42 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:43 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:45 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:47 PM EPA Interlab L1 1 1313-1316 EaFA
5.73E+03 83% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:50 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:51 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:53 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:55 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:56 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:58 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 3:00 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-278
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFA-L11-1313-T01-A 1
Mn EaFA-L11-1313-T02-A 1
Mn EaFA-L11-1313-T03-A 1
Mn EaFA-L11-1313-T04-A 1
Mn EaFA-L11-1313-T05-A 1
Mn EaFA-L11-1313-T06-A 1
Mn EaFA-L11-1313-T07-A 1
Mn EaFA-L11-1313-T08-A 1
Mn EaFA-L11-1313-T09-A 1
Mn EaFA-L11-1313-T01-B 1
Mn EaFA-L11-1313-T02-B 1
Mn EaFA-L11-1313-T03-B 1
Mn EaFA-L11-1313-T04-B 1
Mn EaFA-L11-1313-T05-B 1
Mn EaFA-L11-1313-T06-B 1
Mn EaFA-L11-1313-T07-B 1
Mn EaFA-L11-1313-T08-B 1
Mn EaFA-L11-1313-T09-B 1
Mn EaFA-L11-1313-T01-C 1
Mn EaFA-L11-1313-T02-C 1
Mn EaFA-L11-1313-T03-C 1
Mn EaFA-L11-1313-T04-C 1
Mn EaFA-L11-1313-T05-C 1
Mn EaFA-L11-1313-T06-C 1
Mn EaFA-L11-1313-T07-C 1
Mn EaFA-L11-1313-T08-C 1
Mn EaFA-L11-1313-T09-C 1
Mn EaFA-L11-1313-B01-A 1
Mn EaFA-L11-1313-B02-A 1
Mn EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.60E+00
2.69E+01
2.51 E+02
8.82E+02
1.27E+03
1.68E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.57E+00
4.33E+01
2.61 E+02
8.59E+02
1.29E+03
1.66E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
7.02E+00
4.13E+01
2.59E+02
8.52E+02
1.29E+03
1.67E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.8E+00 2.0E+00 6.4E+00
1.00E+00 4.5E+01 2.0E+00 6.4E+00 10 325
1.00E+00 3.0E+00 2.0E+00 6.4E+00
6.60E+00 2.0E+00 2.0E+00 6.4E+00
2.69E+01 8.7E-01 2.0E+00 6.4E+00
2.51 E+02 7.9E-01 2.0E+00 6.4E+00
8.82E+02 6.2E-01 2.0E+00 6.4E+00
1.27E+03 8.1E-01 2.0E+00 6.4E+00
1.68E+03 1.1E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00 10 325
1.00E+00 2.3E+00 2.0E+00 6.4E+00
6.57E+00 5.0E+00 2.0E+00 6.4E+00
4.33E+01 5.4E-01 2.0E+00 6.4E+00
2.61 E+02 7.7E-01 2.0E+00 6.4E+00
8.59E+02 8.1E-01 2.0E+00 6.4E+00
1.29E+03 1.1E+00 2.0E+00 6.4E+00
1.66E+03 3.0E-01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00 10 325
1.00E+00 2.9E+01 2.0E+00 6.4E+00
7.02E+00 2.9E+00 2.0E+00 6.4E+00
4.13E+01 1.1E+00 2.0E+00 6.4E+00
2.59E+02 7.6E-01 2.0E+00 6.4E+00
8.52E+02 7.2E-01 2.0E+00 6.4E+00
1.29E+03 3.0E-01 2.0E+00 6.4E+00
1.67E+03 4.8E-01 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 5.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 2/22/11 2:12 PM EPA Interlab L11 1313-1316 EaFA
3.15E+03 97% VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:15 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
3.50E+03 108% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
3.44E+03 106% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-279
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Sample Dilution
EaFA-L11-1313-T01-A 1
EaFA-L11-1313-T02-A 1
EaFA-L11-1313-T03-A 1
EaFA-L11-1313-T04-A 1
EaFA-L11-1313-T05-A 1
EaFA-L11-1313-T06-A 1
EaFA-L11-1313-T07-A 1
EaFA-L11-1313-T08-A 1
EaFA-L11-1313-T09-A 1
EaFA-L11-1313-T01-B 1
EaFA-L11-1313-T02-B 1
EaFA-L11-1313-T03-B 1
EaFA-L11-1313-T04-B 1
EaFA-L11-1313-T05-B 1
EaFA-L11-1313-T06-B 1
EaFA-L11-1313-T07-B 1
EaFA-L11-1313-T08-B 1
EaFA-L11-1313-T09-B 1
EaFA-L11-1313-T01-C 1
EaFA-L11-1313-T02-C 1
EaFA-L11-1313-T03-C 1
EaFA-L11-1313-T04-C 1
EaFA-L11-1313-T05-C 1
EaFA-L11-1313-T06-C 1
EaFA-L11-1313-T07-C 1
EaFA-L11-1313-T08-C 1
EaFA-L11-1313-T09-C 1
EaFA-L11-1313-B01-A 1
EaFA-L11-1313-B02-A 1
EaFA-L11-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
1.56E+03
4.61 E+03
5.84E+03
8.00E+03
8.28E+03
8.82E+03
1.35E+04
5.00E-01 U1/2
5.00E-01 U1/2
1.71 E+03
4.35E+03
6.39E+03
8.03E+03
7.96E+03
8.88E+03
1.35E+04
5.00E-01 U1/2
5.00E-01 U1/2
1.69E+03
4.62E+03
6.24E+03
7.94E+03
7.93E+03
8.85E+03
1.33E+04
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 5.2E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00 1000 100
1.56E+03 4.5E-01 1.0E+00 3.2E+00
4.61 E+03 3.7E-01 1.0E+00 3.2E+00
5.84E+03 1.4E+00 1.0E+00 3.2E+00
8.00E+03 1.9E-01 1.0E+00 3.2E+00
8.28E+03 7.6E-01 1.0E+00 3.2E+00
8.82E+03 1.0E+00 1.0E+00 3.2E+00
1.35E+04 1.4E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+02 1.0E+00 3.2E+00
5.00E-01 1.7E+01 1.0E+00 3.2E+00 1000 100
1.71 E+03 5.9E-01 1.0E+00 3.2E+00
4.35E+03 8.6E-01 1.0E+00 3.2E+00
6.39E+03 1.0E+00 1.0E+00 3.2E+00
8.03E+03 1.0E+00 1.0E+00 3.2E+00
7.96E+03 1.3E+00 1.0E+00 3.2E+00
8.88E+03 1.4E+00 1.0E+00 3.2E+00
1.35E+04 7.2E-01 1.0E+00 3.2E+00
5.00E-01 4.9E+01 1.0E+00 3.2E+00
5.00E-01 9.4E+00 1.0E+00 3.2E+00 1000 100
1.69E+03 1.2E+00 1.0E+00 3.2E+00
4.62E+03 7.9E-01 1.0E+00 3.2E+00
6.24E+03 5.3E-01 1.0E+00 3.2E+00
7.94E+03 7.5E-01 1.0E+00 3.2E+00
7.93E+03 5.8E-01 1.0E+00 3.2E+00
8.85E+03 1.1E+00 1.0E+00 3.2E+00
1.33E+04 6.0E-01 1.0E+00 3.2E+00
5.00E-01 8.8E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
5.00E-01 8.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 2/22/11 2:12 PM EPA Interlab L11 1313-1316 EaFA
9.37E+02 94% VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:15 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
1.04E+03 104% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
1.05E+03 105% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-280
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 ug/L
Mo EaFA-L11-1313-T01-A 1 3.87E+03
Mo EaFA-L11-1313-T02-A 1 3.59E+03
Mo EaFA-L11-1313-T03-A 1 3.08E+03
Mo EaFA-L11-1313-T04-A 1 2.86E+03
Mo EaFA-L11-1313-T05-A 1 2.68E+03
Mo EaFA-L11-1313-T06-A 1 2.32E+03
Mo EaFA-L11-1313-T07-A 1 4.93E+02
Mo EaFA-L11-1313-T08-A 1 7.69E+01
Mo EaFA-L11-1313-T09-A 1 4.54E+02
Mo EaFA-L11-1313-T01-B 1 3.83E+03
Mo EaFA-L11-1313-T02-B 1 3.67E+03
Mo EaFA-L11-1313-T03-B 1 3.19E+03
Mo EaFA-L11-1313-T04-B 1 2.93E+03
Mo EaFA-L11-1313-T05-B 1 2.74E+03
Mo EaFA-L11-1313-T06-B 1 2.31E+03
Mo EaFA-L11-1313-T07-B 1 2.23E+02
Mo EaFA-L11-1313-T08-B 1 8.56E+01
Mo EaFA-L11-1313-T09-B 1 4.52E+02
Mo EaFA-L11-1313-T01-C 1 3.74E+03
Mo EaFA-L11-1313-T02-C 1 3.74E+03
Mo EaFA-L11-1313-T03-C 1 3.19E+03
Mo EaFA-L11-1313-T04-C 1 2.95E+03
Mo EaFA-L11-1313-T05-C 1 2.72E+03
Mo EaFA-L11-1313-T06-C 1 2.28E+03
Mo EaFA-L11-1313-T07-C 1 2.09E+02
Mo EaFA-L11-1313-T08-C 1 8.25E+01
Mo EaFA-L11-1313-T09-C 1 4.55E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.87E+03 1.1E+00 1.2E+00 3.8E+00
3.59E+03 1.2E+00 1.2E+00 3.8E+00 10 325
3.08E+03 4.3E-01 1.2E+00 3.8E+00
2.86E+03 4.6E-01 1.2E+00 3.8E+00
2.68E+03 9.0E-01 1.2E+00 3.8E+00
2.32E+03 6.9E-01 1.2E+00 3.8E+00
4.93E+02 1.3E+00 1.2E+00 3.8E+00
7.69E+01 4.2E+00 1.2E+00 3.8E+00
4.54E+02 1.9E-01 1.2E+00 3.8E+00
3.83E+03 2.2E-01 1.2E+00 3.8E+00
3.67E+03 1.2E+00 1.2E+00 3.8E+00 10 325
3.19E+03 3.9E-01 1.2E+00 3.8E+00
2.93E+03 6.2E-01 1.2E+00 3.8E+00
2.74E+03 5.0E-01 1.2E+00 3.8E+00
2.31 E+03 4.2E-01 1.2E+00 3.8E+00
2.23E+02 3.4E+00 1.2E+00 3.8E+00
8.56E+01 2.6E+00 1.2E+00 3.8E+00
4.52E+02 9.5E-01 1.2E+00 3.8E+00
3.74E+03 7.4E-01 1.2E+00 3.8E+00
3.74E+03 2.2E-01 1.2E+00 3.8E+00 10 325
3.19E+03 1.1E+00 1.2E+00 3.8E+00
2.95E+03 1.0E+00 1.2E+00 3.8E+00
2.72E+03 2.8E-01 1.2E+00 3.8E+00
2.28E+03 5.9E-01 1.2E+00 3.8E+00
2.09E+02 1.6E+00 1.2E+00 3.8E+00
8.25E+01 4.5E+00 1.2E+00 3.8E+00
4.55E+02 1.4E+00 1.2E+00 3.8E+00
Mo EaFA-L11-1313-B01-A 1 1.71E+OOE 1.71E+00 1 .4E+02 1.2E+00 3.8E+00
Mo EaFA-L11-1313-B02-A 1 1.23E+OOE 1.23E+00 2.4E+02 1.2E+00 3.8E+00
Mo EaFA-L11-1313-B03-A 1 4.97E+00
4.97E+00 4.2E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 2/22/11 2:12 PM EPA Interlab L11 1313-1316 EaFA
6.41E+03 87% VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:15 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
6.85E+03 98% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
6.87E+03 96% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-281
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFA-L11-1313-T01-A 1
Ni EaFA-L11-1313-T02-A 1
Ni EaFA-L11-1313-T03-A 1
Ni EaFA-L11-1313-T04-A 1
Ni EaFA-L11-1313-T05-A 1
Ni EaFA-L11-1313-T06-A 1
Ni EaFA-L11-1313-T07-A 1
Ni EaFA-L11-1313-T08-A 1
Ni EaFA-L11-1313-T09-A 1
Ni EaFA-L11-1313-T01-B 1
Ni EaFA-L11-1313-T02-B 1
Ni EaFA-L11-1313-T03-B 1
Ni EaFA-L11-1313-T04-B 1
Ni EaFA-L11-1313-T05-B 1
Ni EaFA-L11-1313-T06-B 1
Ni EaFA-L11-1313-T07-B 1
Ni EaFA-L11-1313-T08-B 1
Ni EaFA-L11-1313-T09-B 1
Ni EaFA-L11-1313-T01-C 1
Ni EaFA-L11-1313-T02-C 1
Ni EaFA-L11-1313-T03-C 1
Ni EaFA-L11-1313-T04-C 1
Ni EaFA-L11-1313-T05-C 1
Ni EaFA-L11-1313-T06-C 1
Ni EaFA-L11-1313-T07-C 1
Ni EaFA-L11-1313-T08-C 1
Ni EaFA-L11-1313-T09-C 1
Ni EaFA-L11-1313-B01-A 1
Ni EaFA-L11-1313-B02-A 1
Ni EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
8.56E+00
8.40E+01
5.92E+02
5.04E+02
7.20E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.53E+00 E
1.56E+01
8.63E+01
6.04E+02
5.34E+02
7.17E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
1.09E+01
8.57E+01
6.01 E+02
5.36E+02
7.15E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 8.8E+01 1.8E+00 5.7E+00
9.00E-01 5.5E+01 1.8E+00 5.7E+00 10 325
9.00E-01 6.2E+01 1.8E+00 5.7E+00
9.00E-01 5.2E+02 1.8E+00 5.7E+00
8.56E+00 5.6E+01 1.8E+00 5.7E+00
8.40E+01 1.5E+00 1.8E+00 5.7E+00
5.92E+02 1.1E+00 1.8E+00 5.7E+00
5.04E+02 1.1E+00 1.8E+00 5.7E+00
7.20E+02 8.0E-01 1.8E+00 5.7E+00
9.00E-01 6.8E+01 1.8E+00 5.7E+00
9.00E-01 8.9E+01 1.8E+00 5.7E+00 10 325
9.00E-01 6.0E+01 1.8E+00 5.7E+00
2.53E+00 1.1 E+02 1.8E+00 5.7E+00
1.56E+01 3.4E+01 1.8E+00 5.7E+00
8.63E+01 6.2E+00 1.8E+00 5.7E+00
6.04E+02 1.4E+00 1.8E+00 5.7E+00
5.34E+02 1.8E+00 1.8E+00 5.7E+00
7.17E+02 9.8E-02 1.8E+00 5.7E+00
9.00E-01 4.3E+02 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00 10 325
9.00E-01 3.4E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+03 1.8E+00 5.7E+00
1.09E+01 6.0E+01 1.8E+00 5.7E+00
8.57E+01 2.1E+00 1.8E+00 5.7E+00
6.01 E+02 8.8E-02 1.8E+00 5.7E+00
5.36E+02 8.7E-01 1.8E+00 5.7E+00
7.15E+02 8.2E-01 1.8E+00 5.7E+00
9.00E-01 9.8E+01 1.8E+00 5.7E+00
9.00E-01 4.9E+01 1.8E+00 5.7E+00
9.00E-01 7.3E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 2/22/11 2:12 PM EPA Interlab L11 1313-1316 EaFA
3.16E+03 97% VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:15 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
3.53E+03 108% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:37 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:42 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:43 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:45 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
3.49E+03 107% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-282
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone.
1 ug/L
EaFA-L11-1313-T01-A 1 1.04E+02
EaFA-L11-1313-T02-A 1 9.21E+01
EaFA-L11-1313-T03-A 1 8.05E+01
EaFA-L11-1313-T04-A 1 7.25E+01
EaFA-L11-1313-T05-A 1 1.02E+02
EaFA-L11-1313-T06-A 1 7.09E+01
EaFA-L11-1313-T07-A 1 6.05E+01
EaFA-L11-1313-T08-A 1 4.87E+01
EaFA-L11-1313-T09-A 1 3.92E+03
EaFA-L11-1313-T01-B 1 7.58E+01
EaFA-L11-1313-T02-B 1 1.08E+02
EaFA-L11-1313-T03-B 1 1.03E+02
EaFA-L11-1313-T04-B 1 6.43E+01
EaFA-L11-1313-T05-B 1 6.55E+01
EaFA-L11-1313-T06-B 1 8.38E+01
EaFA-L11-1313-T07-B 1 3.96E+01
EaFA-L11-1313-T08-B 1 7.12E+01
EaFA-L11-1313-T09-B 1 4.17E+03
EaFA-L11-1313-T01-C 1 1 .29E+02
EaFA-L11-1313-T02-C 1 1 .53E+02
EaFA-L11-1313-T03-C 1 1.14E+02
EaFA-L11-1313-T04-C 1 1 .28E+02
EaFA-L11-1313-T05-C 1 1 .02E+02
EaFA-L11-1313-T06-C 1 5.76E+01
EaFA-L11-1313-T07-C 1 5.23E+01
EaFA-L11-1313-T08-C 1 5.89E+01
EaFA-L11-1313-T09-C 1 4.17E+03
EaFA-L11-1313-B01-A 1 1.19E+01
EaFA-L11-1313-B02-A 1 2.42E+01
EaFA-L11-1313-B03-A 1 7.17E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.04E+02 4.7E+00 3.7E+00 1 .2E+01
9.21E+01 8.5E+00 3.7E+00 1 .2E+01 1000 100
8.05E+01 2.2E+01 3.7E+00 1 .2E+01
7.25E+01 1.0E+01 3.7E+00 1 .2E+01
1.02E+02 6.9E+00 3.7E+00 1.2E+01
7.09E+01 9.5E+00 3.7E+00 1.2E+01
6.05E+01 2.9E+01 3.7E+00 1.2E+01
4.87E+01 9.1E+00 3.7E+00 1.2E+01
3.92E+03 2.9E-01 3.7E+00 1.2E+01
7.58E+01 9.6E+00 3.7E+00 1.2E+01
1.08E+02 4.8E+00 3.7E+00 1.2E+01 1000 100
1.03E+02 1.0E+01 3.7E+00 1.2E+01
6.43E+01 2.2E+01 3.7E+00 1.2E+01
6.55E+01 1.2E+01 3.7E+00 1.2E+01
8.38E+01 2.1E+01 3.7E+00 1.2E+01
3.96E+01 3.2E+01 3.7E+00 1.2E+01
7.12E+01 1.0E+01 3.7E+00 1.2E+01
4.17E+03 4.3E-01 3.7E+00 1.2E+01
1.29E+02 8.3E+00 3.7E+00 1.2E+01
1.53E+02 4.0E+00 3.7E+00 1.2E+01 1000 100
1.14E+02 1.0E+01 3.7E+00 1.2E+01
1.28E+02 1.4E+01 3.7E+00 1.2E+01
1.02E+02 4.2E+00 3.7E+00 1.2E+01
5.76E+01 1.3E+01 3.7E+00 1.2E+01
5.23E+01 1.4E+01 3.7E+00 1.2E+01
5.89E+01 9.7E+00 3.7E+00 1.2E+01
4.17E+03 1.1E+00 3.7E+00 1.2E+01
1.19E+01 5.0E+01 3.7E+00 1.2E+01
2.42E+01 3.6E+01 3.7E+00 1.2E+01
7.17E+01 3.1E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
1.14E+03 104% VU ICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
1.21E+03 111% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
1.20E+03 104% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/112:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-283
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
1 ug/L
K EaFA-L11-1313-T01-A 1 3.84E+04
K EaFA-L11-1313-T02-A 1 3.09E+04
K EaFA-L11-1313-T03-A 1 1.66E+04
K EaFA-L11-1313-T04-A 1 1.45E+04
K EaFA-L11-1313-T05-A 1 1.39E+04
K EaFA-L11-1313-T06-A 1 1.61E+04
K EaFA-L11-1313-T07-A 1 2.53E+04
K EaFA-L11-1313-T08-A 1 1.68E+04
K EaFA-L11-1313-T09-A 1 1.99E+04
K EaFA-L11-1313-T01-B 1 3.88E+04
K EaFA-L11-1313-T02-B 1 3.07E+04
K EaFA-L11-1313-T03-B 1 1.82E+04
K EaFA-L11-1313-T04-B 1 1.64E+04
K EaFA-L11-1313-T05-B 1 1.56E+04
K EaFA-L11-1313-T06-B 1 1.61E+04
K EaFA-L11-1313-T07-B 1 2.32E+04
K EaFA-L11-1313-T08-B 1 1 J3E+04
K EaFA-L11-1313-T09-B 1 2.00E+04
K EaFA-L11-1313-T01-C 1 3.77E+04
K EaFA-L11-1313-T02-C 1 3.06E+04
K EaFA-L11-1313-T03-C 1 1 .83E+04
K EaFA-L11-1313-T04-C 1 1 .63E+04
K EaFA-L11-1313-T05-C 1 1 .56E+04
K EaFA-L11-1313-T06-C 1 1 .59E+04
K EaFA-L11-1313-T07-C 1 2.32E+04
K EaFA-L11-1313-T08-C 1 1.71E+04
K EaFA-L11-1313-T09-C 1 1 .97E+04
K EaFA-L11-1313-B01-A 1 6.48E+01
K EaFA-L11-1313-B02-A 1 3.94E+01
K EaFA-L11-1313-B03-A 1 5.18E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.84E+04 1.1E+00 1.6E+00 5.1E+00
3.09E+04 1.5E+00 1.6E+00 5.1E+00 1000 100
1.66E+04 2.5E-01 1.6E+00 5.1E+00
1.45E+04 1.6E-01 1.6E+00 5.1E+00
1.39E+04 9.7E-01 1.6E+00 5.1E+00
1.61E+04 2.4E-01 1.6E+00 5.1E+00
2.53E+04 1.1E+00 1.6E+00 5.1E+00
1.68E+04 8.6E-01 1.6E+00 5.1E+00
1.99E+04 8.6E-01 1.6E+00 5.1E+00
3.88E+04 1.4E+00 1.6E+00 5.1E+00
3.07E+04 4.3E-01 1.6E+00 5.1E+00 1000 100
1.82E+04 1.2E-01 1.6E+00 5.1E+00
1.64E+04 3.4E-01 1.6E+00 5.1E+00
1.56E+04 4.7E-01 1.6E+00 5.1E+00
1.61E+04 3.7E-01 1.6E+00 5.1E+00
2.32E+04 1.8E+00 1.6E+00 5.1E+00
1.73E+04 1.2E+00 1.6E+00 5.1E+00
2.00E+04 2.0E-01 1 .6E+00 5.1E+00
3.77E+04 3.6E-01 1 .6E+00 5.1E+00
3.06E+04 1.5E+00 1 .6E+00 5.1E+00 1000 100
1.83E+04 3.1E-01 1 .6E+00 5.1E+00
1.63E+04 6.6E-01 1 .6E+00 5.1E+00
1.56E+04 3.9E-01 1 .6E+00 5.1E+00
1.59E+04 5.8E-01 1 .6E+00 5.1E+00
2.32E+04 1.5E-01 1 .6E+00 5.1E+00
1.71E+04 7.6E-01 1 .6E+00 5.1E+00
1.97E+04 3.1E-01 1 .6E+00 5.1E+00
6.48E+01 3.2E+00 1 .6E+00 5.1E+00
3.94E+01 6.0E+00 1 .6E+00 5.1E+00
5.18E+02 1.4E+00 1 .6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
3.18E+04 86% VU ICP-OES 2/22/1 1 2:14 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
3.16E+04 90% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
3.15E+04 91% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/112:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-284
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Sample
Sample Dilution Cone. Qu
1 1 ug/L
EaFA-L11-1313-T01-A 1 6.76E+03
EaFA-L11-1313-T02-A 1 6.24E+03
EaFA-L11-1313-T03-A 1 4.36E+03
EaFA-L11-1313-T04-A 1 1.84E+03
EaFA-L11-1313-T05-A 1 1.05E+03
EaFA-L11-1313-T06-A 1 5.35E+02
EaFA-L11-1313-T07-A 1 2.48E+02
EaFA-L11-1313-T08-A 1 6.46E+01
EaFA-L11-1313-T09-A 1 1.08E+03
EaFA-L11-1313-T01-B 1 7.04E+03
EaFA-L11-1313-T02-B 1 6.28E+03
EaFA-L11-1313-T03-B 1 4.64E+03
EaFA-L11-1313-T04-B 1 1.79E+03
EaFA-L11-1313-T05-B 1 9.89E+02
EaFA-L11-1313-T06-B 1 5.84E+02
EaFA-L11-1313-T07-B 1 2.21E+02
EaFA-L11-1313-T08-B 1 6.68E+01
EaFA-L11-1313-T09-B 1 1.15E+03
EaFA-L11-1313-T01-C 1 6.84E+03
EaFA-L11-1313-T02-C 1 6.32E+03
EaFA-L11-1313-T03-C 1 4.64E+03
EaFA-L11-1313-T04-C 1 1 .80E+03
EaFA-L11-1313-T05-C 1 9.98E+02
EaFA-L11-1313-T06-C 1 5.37E+02
EaFA-L11-1313-T07-C 1 2.08E+02
EaFA-L11-1313-T08-C 1 6.95E+01
EaFA-L11-1313-T09-C 1 1.18E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.76E+03 2.8E-01 1.5E+01 4.8E+01
6.24E+03 1.6E+00 1.5E+01 4.8E+01 10 325
4.36E+03 1.3E+00 1.5E+01 4.8E+01
1.84E+03 2.5E+00 1.5E+01 4.8E+01
1.05E+03 2.2E+00 1.5E+01 4.8E+01
5.35E+02 6.0E+00 1.5E+01 4.8E+01
2.48E+02 6.0E+00 1.5E+01 4.8E+01
6.46E+01 2.6E+01 1.5E+01 4.8E+01
1.08E+03 2.3E+00 1.5E+01 4.8E+01
7.04E+03 2.2E+00 1.5E+01 4.8E+01
6.28E+03 4.4E-01 1.5E+01 4.8E+01 10 325
4.64E+03 8.9E-01 1.5E+01 4.8E+01
1.79E+03 1.1E+00 1.5E+01 4.8E+01
9.89E+02 6.5E+00 1.5E+01 4.8E+01
5.84E+02 3.4E+00 1.5E+01 4.8E+01
2.21E+02 7.4E+00 1 .5E+01 4.8E+01
6.68E+01 7.5E+00 1 .5E+01 4.8E+01
1.15E+03 2.0E-01 1.5E+01 4.8E+01
6.84E+03 1.6E-01 1 .5E+01 4.8E+01
6.32E+03 1.3E+00 1 .5E+01 4.8E+01 10 325
4.64E+03 5.4E-01 1 .5E+01 4.8E+01
1.80E+03 2.0E+00 1 .5E+01 4.8E+01
9.98E+02 1.6E+00 1 .5E+01 4.8E+01
5.37E+02 4.8E+00 1 .5E+01 4.8E+01
2.08E+02 1.3E+01 1 .5E+01 4.8E+01
6.95E+01 3.6E+01 1 .5E+01 4.8E+01
1.18E+03 2.1E+00 1.5E+01 4.8E+01
EaFA-L11-1313-B01-A 1 7.50E+00 U1/2 7.50E+00 3.3E+02 1 .5E+01 4.8E+01
EaFA-L11-1313-B02-A 1 1 .67E+01 E
EaFA-L11-1313-B03-A 1 3.05E+01 E
1.67E+01 4.3E+01 1 .5E+01 4.8E+01
3.05E+01 3.1E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
8.91E+03 82%VUICP-OES 2/22/1 1 2:14 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
9.22E+03 91% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
9.22E+03 89% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-285
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qu
1 1 ug/L
Si EaFA-L11-1313-T01-A 1 1.10E+04
Si EaFA-L11-1313-T02-A 1 3.50E+03
Si EaFA-L11-1313-T03-A 1 2.39E+02
Si EaFA-L11-1313-T04-A 1 3.31E+02
Si EaFA-L11-1313-T05-A 1 5.86E+02
Si EaFA-L11-1313-T06-A 1 1.63E+03
Si EaFA-L11-1313-T07-A 1 6.41E+03
Si EaFA-L11-1313-T08-A 1 3.02E+04
Si EaFA-L11-1313-T09-A 1 6.84E+04
Si EaFA-L11-1313-T01-B 1 9.93E+03
Si EaFA-L11-1313-T02-B 1 4.93E+03
Si EaFA-L11-1313-T03-B 1 3.26E+02
Si EaFA-L11-1313-T04-B 1 3.79E+02
Si EaFA-L11-1313-T05-B 1 7.44E+02
Si EaFA-L11-1313-T06-B 1 1.68E+03
Si EaFA-L11-1313-T07-B 1 6.43E+03
Si EaFA-L11-1313-T08-B 1 3.32E+04
Si EaFA-L11-1313-T09-B 1 6.80E+04
Si EaFA-L11-1313-T01-C 1 9.56E+03
Si EaFA-L11-1313-T02-C 1 4.98E+03
Si EaFA-L11-1313-T03-C 1 3.05E+02
Si EaFA-L11-1313-T04-C 1 4.47E+02
Si EaFA-L11-1313-T05-C 1 7.17E+02
Si EaFA-L11-1313-T06-C 1 1.73E+03
Si EaFA-L11-1313-T07-C 1 6.37E+03
Si EaFA-L11-1313-T08-C 1 3.33E+04
Si EaFA-L11-1313-T09-C 1 6.80E+04
Si EaFA-L11-1313-B01-A 1 1.23E+01
Si EaFA-L11-1313-B02-A 1 1.88E+01
Si EaFA-L11-1313-B03-A 1 3.04E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.10E+04 6.3E-01 1.1E+00 3.5E+00
3.50E+03 1.6E+00 1.1E+00 3.5E+00 1000 100
2.39E+02 6.8E-01 1.1E+00 3.5E+00
3.31 E+02 1.3E+00 1.1E+00 3.5E+00
5.86E+02 1.1E+00 1.1E+00 3.5E+00
1.63E+03 2.9E-01 1.1E+00 3.5E+00
6.41 E+03 1.6E-01 1.1E+00 3.5E+00
3.02E+04 1.3E+00 1.1E+00 3.5E+00
6.84E+04 8.7E-01 1.1E+00 3.5E+00
9.93E+03 6.7E-01 1.1E+00 3.5E+00
4.93E+03 9.0E-01 1.1E+00 3.5E+00 1000 100
3.26E+02 2.1E+00 1.1E+00 3.5E+00
3.79E+02 1.4E+00 1.1E+00 3.5E+00
7.44E+02 8.9E-01 1.1E+00 3.5E+00
1.68E+03 1.1E+00 1.1E+00 3.5E+00
6.43E+03 1.0E+00 1.1E+00 3.5E+00
3.32E+04 7.3E-01 1.1E+00 3.5E+00
6.80E+04 4.9E-01 1.1E+00 3.5E+00
9.56E+03 1.6E-01 1.1E+00 3.5E+00
4.98E+03 7.7E-01 1.1E+00 3.5E+00 1000 100
3.05E+02 1.7E+00 1.1E+00 3.5E+00
4.47E+02 7.6E-01 1.1E+00 3.5E+00
7.17E+02 6.8E-01 1.1E+00 3.5E+00
1.73E+03 2.4E-01 1.1E+00 3.5E+00
6.37E+03 3.7E-01 1.1E+00 3.5E+00
3.33E+04 1.7E-01 1.1E+00 3.5E+00
6.80E+04 7.0E-01 1.1E+00 3.5E+00
1.23E+01 3.3E+01 1.1E+00 3.5E+00
1.88E+01 2.5E+01 1.1E+00 3.5E+00
3.04E+03 2.1E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 2/22/11 2:12 PM EPA Interlab L11 1313-1316 EaFA
4.39E+03 89% VU ICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:15 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
5.87E+03 93% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
5.87E+03 88% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-286
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFA-L11-1313-T01-A 1
Na EaFA-L11-1313-T02-A 1
Na EaFA-L11-1313-T03-A 1
Na EaFA-L11-1313-T04-A 1
Na EaFA-L11-1313-T05-A 1
Na EaFA-L11-1313-T06-A 1
Na EaFA-L11-1313-T07-A 1
Na EaFA-L11-1313-T08-A 1
Na EaFA-L11-1313-T09-A 1
Na EaFA-L11-1313-T01-B 1
Na EaFA-L11-1313-T02-B 1
Na EaFA-L11-1313-T03-B 1
Na EaFA-L11-1313-T04-B 1
Na EaFA-L11-1313-T05-B 1
Na EaFA-L11-1313-T06-B 1
Na EaFA-L11-1313-T07-B 1
Na EaFA-L11-1313-T08-B 1
Na EaFA-L11-1313-T09-B 1
Na EaFA-L11-1313-T01-C 1
Na EaFA-L11-1313-T02-C 1
Na EaFA-L11-1313-T03-C 1
Na EaFA-L11-1313-T04-C 1
Na EaFA-L11-1313-T05-C 1
Na EaFA-L11-1313-T06-C 1
Na EaFA-L11-1313-T07-C 1
Na EaFA-L11-1313-T08-C 1
Na EaFA-L11-1313-T09-C 1
Na EaFA-L11-1313-B01-A 1
Na EaFA-L11-1313-B02-A 1
Na EaFA-L11-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.25E+05
1.27E+05
3.45E+04
1.18E+04
4.06E+03
4.14E+03
4.47E+03
2.72E+03
2.53E+03
2.20E+05
1.25E+05
3.55E+04
1.21E+04
4.15E+03
4.13E+03
4.00E+03
2.80E+03
2.53E+03
2.16E+05
1.25E+05
3.58E+04
1.21E+04
4.10E+03
4.12E+03
4.01 E+03
2.79E+03
2.50E+03
3.75E+01
4.59E+01
2.25E+05
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.25E+05 1.8E-01 2.5E+00 8.0E+00
1.27E+05 8.5E-01 2.5E+00 8.0E+00 1000 100
3.45E+04 4.3E-01 2.5E+00 8.0E+00
1.18E+04 1.0E-01 2.5E+00 8.0E+00
4.06E+03 1.0E+00 2.5E+00 8.0E+00
4.14E+03 1.3E+00 2.5E+00 8.0E+00
4.47E+03 5.4E-01 2.5E+00 8.0E+00
2.72E+03 1.3E+00 2.5E+00 8.0E+00
2.53E+03 7.0E-01 2.5E+00 8.0E+00
2.20E+05 1.4E+00 2.5E+00 8.0E+00
1.25E+05 5.2E-01 2.5E+00 8.0E+00 1000 100
3.55E+04 2.4E-01 2.5E+00 8.0E+00
1.21E+04 1.0E+00 2.5E+00 8.0E+00
4.15E+03 3.7E-01 2.5E+00 8.0E+00
4.13E+03 2.3E+00 2.5E+00 8.0E+00
4.00E+03 1.6E+00 2.5E+00 8.0E+00
2.80E+03 1.3E+00 2.5E+00 8.0E+00
2.53E+03 2.1E-01 2.5E+00 8.0E+00
2.16E+05 2.4E-01 2.5E+00 8.0E+00
1.25E+05 4.4E-01 2.5E+00 8.0E+00 1000 100
3.58E+04 5.4E-01 2.5E+00 8.0E+00
1.21E+04 3.4E-01 2.5E+00 8.0E+00
4.10E+03 5.4E-01 2.5E+00 8.0E+00
4.12E+03 8.8E-01 2.5E+00 8.0E+00
4.01 E+03 4.6E-01 2.5E+00 8.0E+00
2.79E+03 2.0E-01 2.5E+00 8.0E+00
2.50E+03 9.1E-01 2.5E+00 8.0E+00
3.75E+01 1.8E+00 2.5E+00 8.0E+00
4.59E+01 1.9E+00 2.5E+00 8.0E+00
2.25E+05 3.5E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
1.28E+05 85%VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:32 PM EPA Interlab L1 1 1313-1316 EaFA
1.26E+05 90% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:35 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:37 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:42 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:43 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:45 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:47 PM EPA Interlab L1 1 1313-1316 EaFA
1.26E+05 91% VUICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:50 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:51 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:53 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:55 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:56 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:58 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 3:00 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:07 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:09 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:10 PM EPA Interlab L1 1 1313-1316 EaFA
                                                                                                                                                                          1-287
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone.
1 ug/L
EaFA-L11-1313-T01-A 1 1.09E+03
EaFA-L11-1313-T02-A 1 1.60E+03
EaFA-L11-1313-T03-A 1 1.45E+03
EaFA-L11-1313-T04-A 1 1.64E+03
EaFA-L11-1313-T05-A 1 1.78E+03
EaFA-L11-1313-T06-A 1 2.07E+03
EaFA-L11-1313-T07-A 1 2.54E+03
EaFA-L11-1313-T08-A 1 3.66E+03
EaFA-L11-1313-T09-A 1 5.27E+03
EaFA-L11-1313-T01-B 1 1.15E+03
EaFA-L11-1313-T02-B 1 1.45E+03
EaFA-L11-1313-T03-B 1 1.61E+03
EaFA-L11-1313-T04-B 1 1.76E+03
EaFA-L11-1313-T05-B 1 1.93E+03
EaFA-L11-1313-T06-B 1 2.10E+03
EaFA-L11-1313-T07-B 1 2.47E+03
EaFA-L11-1313-T08-B 1 3.72E+03
EaFA-L11-1313-T09-B 1 5.24E+03
EaFA-L11-1313-T01-C 1 1.13E+03
EaFA-L11-1313-T02-C 1 1 .45E+03
EaFA-L11-1313-T03-C 1 1 .58E+03
EaFA-L11-1313-T04-C 1 1 J9E+03
EaFA-L11-1313-T05-C 1 1 .90E+03
EaFA-L11-1313-T06-C 1 2.07E+03
EaFA-L11-1313-T07-C 1 2.44E+03
EaFA-L11-1313-T08-C 1 3.72E+03
EaFA-L11-1313-T09-C 1 5.31E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.09E+03 1.2E+00 1.0E+00 3.2E+00
1.60E+03 1.3E+00 1.0E+00 3.2E+00 1000 100
1.45E+03 2.5E-01 1.0E+00 3.2E+00
1.64E+03 1.2E+00 1.0E+00 3.2E+00
1.78E+03 1.5E+00 1.0E+00 3.2E+00
2.07E+03 1.3E+00 1.0E+00 3.2E+00
2.54E+03 4.7E-01 1.0E+00 3.2E+00
3.66E+03 1.5E+00 1.0E+00 3.2E+00
5.27E+03 1.2E+00 1.0E+00 3.2E+00
1.15E+03 4.6E-01 1.0E+00 3.2E+00
1.45E+03 1.3E+00 1.0E+00 3.2E+00 1000 100
1.61E+03 6.2E-01 1.0E+00 3.2E+00
1.76E+03 7.8E-01 1.0E+00 3.2E+00
1.93E+03 6.6E-01 1.0E+00 3.2E+00
2.10E+03 2.1E-01 1.0E+00 3.2E+00
2.47E+03 1.0E+00 1.0E+00 3.2E+00
3.72E+03 8.3E-01 1.0E+00 3.2E+00
5.24E+03 1.3E+00 1 .OE+00 3.2E+00
1.13E+03 2.4E-01 1 .OE+00 3.2E+00
1.45E+03 4.4E-01 1 .OE+00 3.2E+00 1000 100
1.58E+03 1.2E+00 1 .OE+00 3.2E+00
1.79E+03 5.7E-01 1 .OE+00 3.2E+00
1.90E+03 3.0E-01 1 .OE+00 3.2E+00
2.07E+03 1.2E+00 1 .OE+00 3.2E+00
2.44E+03 1.5E+00 1 .OE+00 3.2E+00
3.72E+03 9.2E-01 1 .OE+00 3.2E+00
5.31 E+03 1.4E+00 1 .OE+00 3.2E+00
EaFA-L11-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 1.0E+02 1.0E+00 3.2E+00
EaFA-L11-1313-B02-A 1 3.07E+00 E 3.07E+00 1.8E+01 1.0E+00 3.2E+00
EaFA-L11-1313-B03-A 1 2.20E+00 E 2.20E+00 6.0E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
2.41E+03 81%VUICP-OES 2/22/1 1 2:14 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
2.38E+03 93% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
2.37E+03 92% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/112:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-288
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone.
1 ug/L
EaFA-L11-1313-T01-A 1 1.70E+05
EaFA-L11-1313-T02-A 1 1.63E+05
EaFA-L11-1313-T03-A 1 1.44E+05
EaFA-L11-1313-T04-A 1 1.41E+05
EaFA-L11-1313-T05-A 1 1.40E+05
EaFA-L11-1313-T06-A 1 1.44E+05
EaFA-L11-1313-T07-A 1 1.53E+05
EaFA-L11-1313-T08-A 1 8.69E+04
EaFA-L11-1313-T09-A 1 6.66E+04
EaFA-L11-1313-T01-B 1 1.72E+05
EaFA-L11-1313-T02-B 1 1.68E+05
EaFA-L11-1313-T03-B 1 1.49E+05
EaFA-L11-1313-T04-B 1 1.46E+05
EaFA-L11-1313-T05-B 1 1.47E+05
EaFA-L11-1313-T06-B 1 1.44E+05
EaFA-L11-1313-T07-B 1 1.40E+05
EaFA-L11-1313-T08-B 1 9.49E+04
EaFA-L11-1313-T09-B 1 6.67E+04
EaFA-L11-1313-T01-C 1 1 .68E+05
EaFA-L11-1313-T02-C 1 1 .68E+05
EaFA-L11-1313-T03-C 1 1.51E+05
EaFA-L11-1313-T04-C 1 1 .48E+05
EaFA-L11-1313-T05-C 1 1 .45E+05
EaFA-L11-1313-T06-C 1 1 .43E+05
EaFA-L11-1313-T07-C 1 1 .39E+05
EaFA-L11-1313-T08-C 1 9.49E+04
EaFA-L11-1313-T09-C 1 6.72E+04
EaFA-L11-1313-B01-A 1 2.44E+01
EaFA-L11-1313-B02-A 1 2.60E+01
EaFA-L11-1313-B03-A 1 7.90E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.70E+05 8.6E-01 6.8E+00 2.2E+01
1.63E+05 1.3E+00 6.8E+00 2.2E+01 1000 100
1.44E+05 3.0E-01 6.8E+00 2.2E+01
1.41E+05 3.6E-01 6.8E+00 2.2E+01
1.40E+05 7.8E-01 6.8E+00 2.2E+01
1.44E+05 3.5E-01 6.8E+00 2.2E+01
1.53E+05 5.2E-01 6.8E+00 2.2E+01
8.69E+04 5.7E-01 6.8E+00 2.2E+01
6.66E+04 4.5E-01 6.8E+00 2.2E+01
1.72E+05 1.6E+00 6.8E+00 2.2E+01
1.68E+05 5.1E-01 6.8E+00 2.2E+01 1000 100
1.49E+05 2.8E-01 6.8E+00 2.2E+01
1.46E+05 1.1E+00 6.8E+00 2.2E+01
1.47E+05 5.6E-01 6.8E+00 2.2E+01
1.44E+05 4.2E-01 6.8E+00 2.2E+01
1.40E+05 1.3E+00 6.8E+00 2.2E+01
9.49E+04 1.2E+00 6.8E+00 2.2E+01
6.67E+04 1.3E-01 6.8E+00 2.2E+01
1.68E+05 4.6E-01 6.8E+00 2.2E+01
1.68E+05 7.5E-01 6.8E+00 2.2E+01 1000 100
1.51E+05 3.0E-01 6.8E+00 2.2E+01
1.48E+05 5.3E-01 6.8E+00 2.2E+01
1.45E+05 7.1E-01 6.8E+00 2.2E+01
1.43E+05 8.7E-01 6.8E+00 2.2E+01
1.39E+05 4.8E-01 6.8E+00 2.2E+01
9.49E+04 4.5E-01 6.8E+00 2.2E+01
6.72E+04 2.0E-01 6.8E+00 2.2E+01
2.44E+01 4.9E+01 6.8E+00 2.2E+01
2.60E+01 2.1E+01 6.8E+00 2.2E+01
7.90E+01 2.2E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
1.64E+05 84%VUICP-OES 2/22/1 1 2:14 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
1.69E+05 92% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
1.69E+05 88% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/112:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-289
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilution
EaFA-L11-1313-T01-A 1
EaFA-L11-1313-T02-A 1
EaFA-L11-1313-T03-A 1
EaFA-L11-1313-T04-A 1
EaFA-L11-1313-T05-A 1
EaFA-L11-1313-T06-A 1
EaFA-L11-1313-T07-A 1
EaFA-L11-1313-T08-A 1
EaFA-L11-1313-T09-A 1
EaFA-L11-1313-T01-B 1
EaFA-L11-1313-T02-B 1
EaFA-L11-1313-T03-B 1
EaFA-L11-1313-T04-B 1
EaFA-L11-1313-T05-B 1
EaFA-L11-1313-T06-B 1
EaFA-L11-1313-T07-B 1
EaFA-L11-1313-T08-B 1
EaFA-L11-1313-T09-B 1
EaFA-L11-1313-T01-C 1
EaFA-L11-1313-T02-C 1
EaFA-L11-1313-T03-C 1
EaFA-L11-1313-T04-C 1
EaFA-L11-1313-T05-C 1
EaFA-L11-1313-T06-C 1
EaFA-L11-1313-T07-C 1
EaFA-L11-1313-T08-C 1
EaFA-L11-1313-T09-C 1
EaFA-L11-1313-B01-A 1
EaFA-L11-1313-B02-A 1
EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
3.70E+01
2.60E+01
7.59E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.55E+01
4.58E+01
5.59E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
7.79E+00 E
4.04E+01
4.85E+01
7.13E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 3.9E+02 4.6E+00 1 .5E+01
2.30E+00 7.8E+02 4.6E+00 1 .5E+01 10 325
2.30E+00 8.7E+01 4.6E+00 1 .5E+01
2.30E+00 3.4E+02 4.6E+00 1 .5E+01
2.30E+00 7.5E+01 4.6E+00 1 .5E+01
2.30E+00 9.4E+01 4.6E+00 1 .5E+01
3.70E+01 3.8E+01 4.6E+00 1 .5E+01
2.60E+01 1.8E+01 4.6E+00 1 .5E+01
7.59E+01 4.7E+00 4.6E+00 1 .5E+01
2.30E+00 8.6E+01 4.6E+00 1 .5E+01
2.30E+00 9.5E+01 4.6E+00 1 .5E+01 10 325
2.30E+00 7.7E+01 4.6E+00 1 .5E+01
2.30E+00 5.3E+01 4.6E+00 1 .5E+01
2.30E+00 8.2E+01 4.6E+00 1 .5E+01
2.30E+00 1.7E+02 4.6E+00 1 .5E+01
2.55E+01 2.4E+01 4.6E+00 1.5E+01
4.58E+01 6.1E+00 4.6E+00 1.5E+01
5.59E+01 1.3E+01 4.6E+00 1.5E+01
2.30E+00 1.5E+02 4.6E+00 1.5E+01
2.30E+00 2.7E+02 4.6E+00 1.5E+01 10 325
2.30E+00 5.3E+01 4.6E+00 1 .5E+01
2.30E+00 1.0E+03 4.6E+00 1 .5E+01
2.30E+00 1.7E+02 4.6E+00 1 .5E+01
7.79E+00 7.0E+01 4.6E+00 1 .5E+01
4.04E+01 5.9E+01 4.6E+00 1 .5E+01
4.85E+01 7.5E-01 4.6E+00 1 .5E+01
7.13E+01 1.1E+00 4.6E+00 1 .5E+01
2.30E+00 4.3E+01 4.6E+00 1 .5E+01
2.30E+00 5.7E+01 4.6E+00 1.5E+01
2.30E+00 1.5E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
3.02E+03 93%VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:25 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:32 PM EPA Interlab L1 1 1313-1316 EaFA
3.34E+03 103% VU ICP-OES 2/22/1 1 2:33 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:35 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:37 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:38 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:40 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
3.28E+03 101% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:50 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:51 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:53 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:55 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:56 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:58 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 3:00 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:07 PM EPA Interlab L1 1 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-290
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L11-1313-T01-A 1
Ti EaFA-L11-1313-T02-A 1
Ti EaFA-L11-1313-T03-A 1
Ti EaFA-L11-1313-T04-A 1
Ti EaFA-L11-1313-T05-A 1
Ti EaFA-L11-1313-T06-A 1
Ti EaFA-L11-1313-T07-A 1
Ti EaFA-L11-1313-T08-A 1
Ti EaFA-L11-1313-T09-A 1
Ti EaFA-L11-1313-T01-B 1
Ti EaFA-L11-1313-T02-B 1
Ti EaFA-L11-1313-T03-B 1
Ti EaFA-L11-1313-T04-B 1
Ti EaFA-L11-1313-T05-B 1
Ti EaFA-L11-1313-T06-B 1
Ti EaFA-L11-1313-T07-B 1
Ti EaFA-L11-1313-T08-B 1
Ti EaFA-L11-1313-T09-B 1
Ti EaFA-L11-1313-T01-C 1
Ti EaFA-L11-1313-T02-C 1
Ti EaFA-L11-1313-T03-C 1
Ti EaFA-L11-1313-T04-C 1
Ti EaFA-L11-1313-T05-C 1
Ti EaFA-L11-1313-T06-C 1
Ti EaFA-L11-1313-T07-C 1
Ti EaFA-L11-1313-T08-C 1
Ti EaFA-L11-1313-T09-C 1
Ti EaFA-L11-1313-B01-A 1
Ti EaFA-L11-1313-B02-A 1
Ti EaFA-L11-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.35E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.41 E+00 E
1.56E+01
5.87E+03
2.12E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.38E+01
6.11E+03
4.20E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.24E+01
6.09E+03
1.00E+00 U1/2
2.12E+00 E
2.38E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.35E+00 9.7E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00 10 325
1.00E+00 6.7E+01 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00
1.00E+00 6.9E+02 2.0E+00 6.4E+00
1.00E+00 9.0E+01 2.0E+00 6.4E+00
2.41E+00 2.8E+01 2.0E+00 6.4E+00
1.56E+01 6.6E+00 2.0E+00 6.4E+00
5.87E+03 7.9E-01 2.0E+00 6.4E+00
2.12E+00 6.1E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00 10 325
1.00E+00 2.7E+02 2.0E+00 6.4E+00
1.00E+00 2.2E+03 2.0E+00 6.4E+00
1.00E+00 4.3E+02 2.0E+00 6.4E+00
1.00E+00 2.1E+02 2.0E+00 6.4E+00
1.00E+00 3.4E+02 2.0E+00 6.4E+00
2.38E+01 3.2E+00 2.0E+00 6.4E+00
6.11E+03 4.2E-01 2.0E+00 6.4E+00
4.20E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 8.6E+02 2.0E+00 6.4E+00 10 325
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+03 2.0E+00 6.4E+00
1.00E+00 3.8E+02 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00
2.24E+01 2.0E+00 2.0E+00 6.4E+00
6.09E+03 1.7E-01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
2.12E+00 2.7E+01 2.0E+00 6.4E+00
2.38E+00 3.1 E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
3.20E+03 98%VUICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:19 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:20 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:22 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:23 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
3.48E+03 107% VU ICP-OES 2/22/1 1 2:33 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
3.40E+03 104% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:53 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:55 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:56 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:58 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 3:00 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:07 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:09 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:10 PM EPA Interlab L1 1 1313-1316 EaFA
                                                                                                                                                                          1-291
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
Sample Dilution
EaFA-L11-1313-T01-A 1
EaFA-L11-1313-T02-A 1
EaFA-L11-1313-T03-A 1
EaFA-L11-1313-T04-A 1
EaFA-L11-1313-T05-A 1
EaFA-L11-1313-T06-A 1
EaFA-L11-1313-T07-A 1
EaFA-L11-1313-T08-A 1
EaFA-L11-1313-T09-A 1
EaFA-L11-1313-T01-B 1
EaFA-L11-1313-T02-B 1
EaFA-L11-1313-T03-B 1
EaFA-L11-1313-T04-B 1
EaFA-L11-1313-T05-B 1
EaFA-L11-1313-T06-B 1
EaFA-L11-1313-T07-B 1
EaFA-L11-1313-T08-B 1
EaFA-L11-1313-T09-B 1
EaFA-L11-1313-T01-C 1
EaFA-L11-1313-T02-C 1
EaFA-L11-1313-T03-C 1
EaFA-L11-1313-T04-C 1
EaFA-L11-1313-T05-C 1
EaFA-L11-1313-T06-C 1
EaFA-L11-1313-T07-C 1
EaFA-L11-1313-T08-C 1
EaFA-L11-1313-T09-C 1
EaFA-L11-1313-B01-A 1
EaFA-L11-1313-B02-A 1
EaFA-L11-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
4.18E+03
2.52E+03
5.52E+02
1.92E+02
1.36E+02
1.05E+02
9.00E+01
9.14E+01
6.15E+03
3.82E+03
2.77E+03
6.97E+02
1.90E+02
1.43E+02
1.03E+02
7.18E+01
1.15E+02
6.11E+03
3.77E+03
2.87E+03
6.71 E+02
1 .88E+02
1 .37E+02
1 .04E+02
7.23E+01
1.12E+02
6.11E+03
3.78E+00 E
5.39E+00
1 .48E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.18E+03 1.6E+00 1.5E+00 4.8E+00
2.52E+03 1.0E+00 1.5E+00 4.8E+00 10 325
5.52E+02 4.3E-01 1.5E+00 4.8E+00
1.92E+02 1.5E+00 1.5E+00 4.8E+00
1.36E+02 5.4E-01 1.5E+00 4.8E+00
1.05E+02 1.3E+00 1.5E+00 4.8E+00
9.00E+01 4.1E+00 1.5E+00 4.8E+00
9.14E+01 2.5E+00 1.5E+00 4.8E+00
6.15E+03 5.1E-01 1.5E+00 4.8E+00
3.82E+03 7.8E-01 1.5E+00 4.8E+00
2.77E+03 9.6E-01 1.5E+00 4.8E+00 10 325
6.97E+02 2.1E+00 1.5E+00 4.8E+00
1.90E+02 2.6E+00 1.5E+00 4.8E+00
1.43E+02 3.4E+00 1.5E+00 4.8E+00
1.03E+02 1.6E+00 1.5E+00 4.8E+00
7.18E+01 1.4E+00 1.5E+00 4.8E+00
1.15E+02 7.2E-01 1.5E+00 4.8E+00
6.11E+03 1.4E-01 1.5E+00 4.8E+00
3.77E+03 7.5E-01 1 .5E+00 4.8E+00
2.87E+03 4.8E-01 1 .5E+00 4.8E+00 10 325
6.71 E+02 4.1E-01 1 .5E+00 4.8E+00
1.88E+02 1.0E+00 1 .5E+00 4.8E+00
1.37E+02 1.0E+00 1 .5E+00 4.8E+00
1.04E+02 3.0E+00 1 .5E+00 4.8E+00
7.23E+01 3.9E+00 1 .5E+00 4.8E+00
1.12E+02 2.4E+00 1 .5E+00 4.8E+00
6.11E+03 1.1E+00 1.5E+00 4.8E+00
3.78E+00 2.2E+01 1 .5E+00 4.8E+00
5.39E+00 3.8E+01 1 .5E+00 4.8E+00
1.48E+01 4.0E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
5.43E+03 90% VU ICP-OES 2/22/1 1 2:14 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
6.05E+03 101% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
6.06E+03 98% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/112:51 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-292
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn EaFA-L11-1313-T01-A 1
Zn EaFA-L11-1313-T02-A 1
Zn EaFA-L11-1313-T03-A 1
Zn EaFA-L11-1313-T04-A 1
Zn EaFA-L11-1313-T05-A 1
Zn EaFA-L11-1313-T06-A 1
Zn EaFA-L11-1313-T07-A 1
Zn EaFA-L11-1313-T08-A 1
Zn EaFA-L11-1313-T09-A 1
Zn EaFA-L11-1313-T01-B 1
Zn EaFA-L11-1313-T02-B 1
Zn EaFA-L11-1313-T03-B 1
Zn EaFA-L11-1313-T04-B 1
Zn EaFA-L11-1313-T05-B 1
Zn EaFA-L11-1313-T06-B 1
Zn EaFA-L11-1313-T07-B 1
Zn EaFA-L11-1313-T08-B 1
Zn EaFA-L11-1313-T09-B 1
Zn EaFA-L11-1313-T01-C 1
Zn EaFA-L11-1313-T02-C 1
Zn EaFA-L11-1313-T03-C 1
Zn EaFA-L11-1313-T04-C 1
Zn EaFA-L11-1313-T05-C 1
Zn EaFA-L11-1313-T06-C 1
Zn EaFA-L11-1313-T07-C 1
Zn EaFA-L11-1313-T08-C 1
Zn EaFA-L11-1313-T09-C 1
Zn EaFA-L11-1313-B01-A 1
Zn EaFA-L11-1313-B02-A 1
Zn EaFA-L11-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.25E+01
8.15E+00
1.14E+01
1.58E+01
2.42E+00 E
5.27E+00
1.21E+03
8.80E+02
1.51E+03
2.43E+01
8.94E+00
1.67E+00 E
1.19E+01
5.00E-01 U1/2
7.86E+00
1.30E+03
1.17E+03
1 .50E+03
2.64E+01
4.57E+00
5.00E-01 U1/2
4.81 E+00
1.08E+00 E
6.77E+00
1.29E+03
1.17E+03
1.51E+03
3.31 E+00
5.22E+00
1.20E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.25E+01 6.2E+00 1.0E+00 3.2E+00
8.15E+00 1.7E+01 1.0E+00 3.2E+00 10 325
1.14E+01 3.3E+00 1.0E+00 3.2E+00
1.58E+01 3.1 E+00 1.0E+00 3.2E+00
2.42E+00 2.1E+01 1.0E+00 3.2E+00
5.27E+00 1.7E+01 1.0E+00 3.2E+00
1.21E+03 6.9E-01 1.0E+00 3.2E+00
8.80E+02 7.8E-01 1.0E+00 3.2E+00
1.51E+03 5.8E-01 1.0E+00 3.2E+00
2.43E+01 5.1 E+00 1.0E+00 3.2E+00
8.94E+00 1.1E+01 1.0E+00 3.2E+00 10 325
1.67E+00 3.7E+01 1.0E+00 3.2E+00
1.19E+01 1.0E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+02 1.0E+00 3.2E+00
7.86E+00 8.3E+00 1.0E+00 3.2E+00
1.30E+03 1.2E+00 1.0E+00 3.2E+00
1.17E+03 1.2E+00 1.0E+00 3.2E+00
1.50E+03 5.3E-01 1.0E+00 3.2E+00
2.64E+01 6.4E-01 1.0E+00 3.2E+00
4.57E+00 3.0E+01 1.0E+00 3.2E+00 10 325
5.00E-01 1.6E+02 1.0E+00 3.2E+00
4.81 E+00 2.9E+01 1.0E+00 3.2E+00
1.08E+00 2.1E+01 1.0E+00 3.2E+00
6.77E+00 1.6E+01 1.0E+00 3.2E+00
1.29E+03 1.3E+00 1.0E+00 3.2E+00
1.17E+03 1.1E+00 1.0E+00 3.2E+00
1.51E+03 3.2E-01 1.0E+00 3.2E+00
3.31 E+00 6.5E+00 1.0E+00 3.2E+00
5.22E+00 2.2E+01 1.0E+00 3.2E+00
1.20E+00 2.0E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/22/1 1 2:12 PM EPA Interlab L1 1 1313-1316 EaFA
3.25E+03 100% VU ICP-OES 2/22/11 2:14 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/1 1 2:15 PM EPA Interlab L1 1 1313-1316 EaFA
VU ICP-OES 2/22/11 2:17 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:19 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:20 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:22 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:23 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:25 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:32 PM EPA Interlab L11 1313-1316 EaFA
3.62E+03 111% VU ICP-OES 2/22/11 2:33 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:35 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:37 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:38 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:40 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:42 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:43 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:45 PM EPA Interlab L11 1313-1316 EaFA
VUICP-OES 2/22/11 2:47 PM EPA Interlab L11 1313-1316 EaFA
3.57E+03 110% VU ICP-OES 2/22/11 2:48 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:50 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:51 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:53 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:55 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:56 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:58 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 3:00 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:07 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:09 PM EPA Interlab L11 1313-1316 EaFA
VU ICP-OES 2/22/11 2:10 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                          1-293
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al EaFA-LRef-1313-T01-A 1
Al EaFA-LRef-1313-T02-A 1
Al EaFA-LRef-1313-T03-A 1
Al EaFA-LRef-1313-T04-A 1
Al EaFA-LRef-1313-T05-A 1
Al EaFA-LRef-1313-T06-A 1
Al EaFA-LRef-1313-T07-A 1
Al EaFA-LRef-1313-T08-A 1
Al EaFA-LRef-1313-T09-A 1
Al EaFA-LRef-1313-T01-B 1
Al EaFA-LRef-1313-T02-B 1
Al EaFA-LRef-1313-T03-B 1
Al EaFA-LRef-1313-T04-B 1
Al EaFA-LRef-1313-T05-B 1
Al EaFA-LRef-1313-T06-B 1
Al EaFA-LRef-1313-T07-B 1
Al EaFA-LRef-1313-T08-B 1
Al EaFA-LRef-1313-T09-B 1
Al EaFA-LRef-1313-T01-C 1
Al EaFA-LRef-1313-T02-C 1
Al EaFA-LRef-1313-T03-C 1
Al EaFA-LRef-1313-T04-C 1
Al EaFA-LRef-1313-T05-C 1
Al EaFA-LRef-1313-T06-C 1
Al EaFA-LRef-1313-T07-C 1
Al EaFA-LRef-1313-T08-C 1
Al EaFA-LRef-1313-T09-C 1
Al EaFA-LRef-1313-B01-A 1
Al EaFA-LRef-1313-B02-A 1
Al EaFA-LRef-1313-B03-A 1
Al EaFA-LRef-1313-B01-B 1
Al EaFA-LRef-1313-B02-B 1
Al EaFA-LRef-1313-B03-B 1
Al EaFA-LRef-1313-B01-C 1
Al EaFA-LRef-1313-B02-C 1
Al EaFA-LRef-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
3.70E+04
3.38E+04
2.71E+04
1.77E+04
1.21E+03
2.02E+02
3.35E+02
3.20E+04
1.28E+05
3.53E+04
3.24E+04
2.85E+04
1.54E+04
1.14E+03
2.24E+02
1.58E+02
3.14E+04
1 .25E+05
3.68E+04
3.51 E+04
2.63E+04
1.41 E+04
1 .08E+03
2.60E+02
2.95E+02
3.05E+04
1.27E+05
5.00E-01 U1/2
3.99E+01
1.62E+03
5.00E-01 U1/2
4.08E+01
1.53E+03
5.00E-01 U1/2
1.55E+01
4.88E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.70E+04 6.2E-01 1.0E+00 3.2E+00
3.38E+04 4.6E-01 1.0E+00 3.2E+00 1000 100
2.71 E+04 7.7E-01 1.0E+00 3.2E+00
1.77E+04 3.1E-01 1.0E+00 3.2E+00
1.21E+03 7.2E-01 1.0E+00 3.2E+00
2.02E+02 3.2E+00 1.0E+00 3.2E+00
3.35E+02 1.1E+00 1.0E+00 3.2E+00
3.20E+04 1.1E+00 1.0E+00 3.2E+00
1.28E+05 8.3E-01 1.0E+00 3.2E+00
3.53E+04 9.2E-01 1.0E+00 3.2E+00
3.24E+04 1.1E+00 1.0E+00 3.2E+00
2.85E+04 8.4E-01 1.0E+00 3.2E+00 1000 100
1.54E+04 8.6E-01 1.0E+00 3.2E+00
1.14E+03 3.1E-01 1.0E+00 3.2E+00
2.24E+02 1.0E+00 1.0E+00 3.2E+00
1.58E+02 2.7E+00 1.0E+00 3.2E+00
3.14E+04 4.7E-01 1.0E+00 3.2E+00
1.25E+05 7.3E-01 1.0E+00 3.2E+00
3.68E+04 4.6E-01 1.0E+00 3.2E+00
3.51 E+04 5.7E-01 1.0E+00 3.2E+00
2.63E+04 7.7E-01 1.0E+00 3.2E+00
1.41E+04 4.0E-01 1.0E+00 3.2E+00 1000 100
1.08E+03 6.5E-01 1.0E+00 3.2E+00
2.60E+02 1.7E+00 1.0E+00 3.2E+00
2.95E+02 2.0E+00 1.0E+00 3.2E+00
3.05E+04 1.1E+00 1.0E+00 3.2E+00
1.27E+05 7.5E-01 1.0E+00 3.2E+00
5.00E-01 1.3E+00 1.0E+00 3.2E+00
3.99E+01 3.7E+00 1.0E+00 3.2E+00
1.62E+03 4.3E-01 1.0E+00 3.2E+00
5.00E-01 5.9E+00 1.0E+00 3.2E+00
4.08E+01 8.5E+00 1.0E+00 3.2E+00
1.53E+03 6.6E-01 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
1.55E+01 4.4E+01 1.0E+00 3.2E+00
4.88E+02 5.5E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.49E+04 113% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
2.94E+04 93% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.50E+04 93% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                                   1-294
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-LRef-1313-T01-A 1
Sb EaFA-LRef-1313-T02-A 1
Sb EaFA-LRef-1313-T03-A 1
Sb EaFA-LRef-1313-T04-A 1
Sb EaFA-LRef-1313-T05-A 1
Sb EaFA-LRef-1313-T06-A 1
Sb EaFA-LRef-1313-T07-A 1
Sb EaFA-LRef-1313-T08-A 1
Sb EaFA-LRef-1313-T09-A 1
Sb EaFA-LRef-1313-T01-B 1
Sb EaFA-LRef-1313-T02-B 1
Sb EaFA-LRef-1313-T03-B 1
Sb EaFA-LRef-1313-T04-B 1
Sb EaFA-LRef-1313-T05-B 1
Sb EaFA-LRef-1313-T06-B 1
Sb EaFA-LRef-1313-T07-B 1
Sb EaFA-LRef-1313-T08-B 1
Sb EaFA-LRef-1313-T09-B 1
Sb EaFA-LRef-1313-T01-C 1
Sb EaFA-LRef-1313-T02-C 1
Sb EaFA-LRef-1313-T03-C 1
Sb EaFA-LRef-1313-T04-C 1
Sb EaFA-LRef-1313-T05-C 1
Sb EaFA-LRef-1313-T06-C 1
Sb EaFA-LRef-1313-T07-C 1
Sb EaFA-LRef-1313-T08-C 1
Sb EaFA-LRef-1313-T09-C 1
Sb EaFA-LRef-1313-B01-A 1
Sb EaFA-LRef-1313-B02-A 1
Sb EaFA-LRef-1313-B03-A 1
Sb EaFA-LRef-1313-B01-B 1
Sb EaFA-LRef-1313-B02-B 1
Sb EaFA-LRef-1313-B03-B 1
Sb EaFA-LRef-1313-B01-C 1
Sb EaFA-LRef-1313-B02-C 1
Sb EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.81E+02
1.47E+02
1.43E+02
1.26E+02
1.38E+02
1.48E+02
8.78E+01
3.71 E+01
3.75E+00 U1/2
1.65E+02
1.29E+02
1.30E+02
1.16E+02
1.35E+02
1.28E+02
7.61E+01
1.05E+01 E
3.75E+00 U1/2
1.93E+02
1.50E+02
1.47E+02
1.55E+02
1.35E+02
1.17E+02
5.60E+01
1.81E+01 E
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
1.31 E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.81E+02 9.0E+00 7.5E+00 2.4E+01
1.47E+02 1.1E+01 7.5E+00 2.4E+01 10 325
1.43E+02 9.4E+00 7.5E+00 2.4E+01
1.26E+02 1.5E+00 7.5E+00 2.4E+01
1.38E+02 1.2E+01 7.5E+00 2.4E+01
1.48E+02 2.0E+01 7.5E+00 2.4E+01
8.78E+01 4.5E+01 7.5E+00 2.4E+01
3.71 E+01 1.7E+01 7.5E+00 2.4E+01
3.75E+00 3.8E+01 7.5E+00 2.4E+01
1.65E+02 9.1E+00 7.5E+00 2.4E+01
1.29E+02 2.2E+01 7.5E+00 2.4E+01
1.30E+02 2.4E+00 7.5E+00 2.4E+01 10 325
1.16E+02 1.1E+01 7.5E+00 2.4E+01
1.35E+02 2.7E+01 7.5E+00 2.4E+01
1.28E+02 7.1E+00 7.5E+00 2.4E+01
7.61E+01 2.1E+01 7.5E+00 2.4E+01
1.05E+01 1.7E+02 7.5E+00 2.4E+01
3.75E+00 7.0E+01 7.5E+00 2.4E+01
1.93E+02 1.7E+01 7.5E+00 2.4E+01
1.50E+02 7.2E+00 7.5E+00 2.4E+01
1.47E+02 5.4E+00 7.5E+00 2.4E+01
1.55E+02 1.6E+01 7.5E+00 2.4E+01 10 325
1.35E+02 3.0E+01 7.5E+00 2.4E+01
1.17E+02 2.3E+01 7.5E+00 2.4E+01
5.60E+01 3.8E+01 7.5E+00 2.4E+01
1.81 E+01 4.0E+01 7.5E+00 2.4E+01
3.75E+00 2.4E+01 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
3.75E+00 1.4E+01 7.5E+00 2.4E+01
3.75E+00 1.1E+02 7.5E+00 2.4E+01
3.75E+00 1.8E+03 7.5E+00 2.4E+01
3.75E+00 1.8E+02 7.5E+00 2.4E+01
3.75E+00 3.3E+02 7.5E+00 2.4E+01
3.75E+00 3.7E+02 7.5E+00 2.4E+01
3.75E+00 4.9E+02 7.5E+00 2.4E+01
1.31 E+01 6.1E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.18E+03 93% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.12E+03 92% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.14E+03 92% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-295
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As EaFA-LRef-1313-T01-A 1
As EaFA-LRef-1313-T02-A 1
As EaFA-LRef-1313-T03-A 1
As EaFA-LRef-1313-T04-A 1
As EaFA-LRef-1313-T05-A 1
As EaFA-LRef-1313-T06-A 1
As EaFA-LRef-1313-T07-A 1
As EaFA-LRef-1313-T08-A 1
As EaFA-LRef-1313-T09-A 1
As EaFA-LRef-1313-T01-B 1
As EaFA-LRef-1313-T02-B 1
As EaFA-LRef-1313-T03-B 1
As EaFA-LRef-1313-T04-B 1
As EaFA-LRef-1313-T05-B 1
As EaFA-LRef-1313-T06-B 1
As EaFA-LRef-1313-T07-B 1
As EaFA-LRef-1313-T08-B 1
As EaFA-LRef-1313-T09-B 1
As EaFA-LRef-1313-T01-C 1
As EaFA-LRef-1313-T02-C 1
As EaFA-LRef-1313-T03-C 1
As EaFA-LRef-1313-T04-C 1
As EaFA-LRef-1313-T05-C 1
As EaFA-LRef-1313-T06-C 1
As EaFA-LRef-1313-T07-C 1
As EaFA-LRef-1313-T08-C 1
As EaFA-LRef-1313-T09-C 1
As EaFA-LRef-1313-B01-A 1
As EaFA-LRef-1313-B02-A 1
As EaFA-LRef-1313-B03-A 1
As EaFA-LRef-1313-B01-B 1
As EaFA-LRef-1313-B02-B 1
As EaFA-LRef-1313-B03-B 1
As EaFA-LRef-1313-B01-C 1
As EaFA-LRef-1313-B02-C 1
As EaFA-LRef-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
9.69E+03
1.01E+03
1.05E+03
5.60E+02
1.99E+02
7.84E+01
4.17E+01
9.00E+01
1.55E+03
9.88E+03
9.35E+02
6.78E+02
5.35E+02
1.63E+02
6.43E+01
3.93E+01
9.47E+01
1.67E+03
9.25E+03
8.14E+02
8.66E+02
4.82E+02
1.63E+02
7.23E+01
5.57E+01
9.75E+01
1.36E+03
5.50E+00 U1/2
5.50E+00 U1/2
1.28E+01 E
5.50E+00 U1/2
5.50E+00 U1/2
1.63E+01 E
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.69E+03 7.3E-01 1.1E+01 3.5E+01
1.01E+03 3.9E+00 1.1E+01 3.5E+01 10 325
1.05E+03 7.4E-01 1.1E+01 3.5E+01
5.60E+02 5.7E+00 1.1E+01 3.5E+01
1.99E+02 5.9E+00 1.1E+01 3.5E+01
7.84E+01 3.4E+01 1.1E+01 3.5E+01
4.17E+01 3.5E+01 1.1E+01 3.5E+01
9.00E+01 1.3E+01 1.1E+01 3.5E+01
1.55E+03 1.4E+00 1.1E+01 3.5E+01
9.88E+03 1.3E+00 1.1E+01 3.5E+01
9.35E+02 4.5E+00 1.1E+01 3.5E+01
6.78E+02 2.0E+00 1.1E+01 3.5E+01 10 325
5.35E+02 2.9E+00 1.1E+01 3.5E+01
1.63E+02 1.3E+01 1.1E+01 3.5E+01
6.43E+01 1.9E+01 1.1E+01 3.5E+01
3.93E+01 1.2E+01 1.1E+01 3.5E+01
9.47E+01 3.7E+00 1.1E+01 3.5E+01
1.67E+03 1.0E+00 1.1E+01 3.5E+01
9.25E+03 8.2E-01 1.1E+01 3.5E+01
8.14E+02 2.1E+00 1.1E+01 3.5E+01
8.66E+02 2.4E+00 1.1E+01 3.5E+01
4.82E+02 4.0E+00 1.1E+01 3.5E+01 10 325
1.63E+02 5.3E+00 1.1E+01 3.5E+01
7.23E+01 1.4E+01 1.1E+01 3.5E+01
5.57E+01 2.0E+01 1.1E+01 3.5E+01
9.75E+01 6.5E+00 1.1E+01 3.5E+01
1.36E+03 1.9E+00 1.1E+01 3.5E+01
5.50E+00 4.3E+02 1.1E+01 3.5E+01
5.50E+00 1.3E+02 1.1E+01 3.5E+01
1.28E+01 1.0E+02 1.1E+01 3.5E+01
5.50E+00 3.3E+01 1.1E+01 3.5E+01
5.50E+00 7.9E+01 1.1E+01 3.5E+01
1.63E+01 7.2E+01 1.1E+01 3.5E+01
5.50E+00 2.6E+02 1.1E+01 3.5E+01
5.50E+00 7.3E+01 1.1E+01 3.5E+01
5.50E+00 4.8E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.92E+03 89% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.61E+03 90% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.43E+03 91% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/109:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-296
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B EaFA-LRef-1313-T01-A 1
B EaFA-LRef-1313-T02-A 1
B EaFA-LRef-1313-T03-A 1
B EaFA-LRef-1313-T04-A 1
B EaFA-LRef-1313-T05-A 1
B EaFA-LRef-1313-T06-A 1
B EaFA-LRef-1313-T07-A 1
B EaFA-LRef-1313-T08-A 1
B EaFA-LRef-1313-T09-A 1
B EaFA-LRef-1313-T01-B 1
B EaFA-LRef-1313-T02-B 1
B EaFA-LRef-1313-T03-B 1
B EaFA-LRef-1313-T04-B 1
B EaFA-LRef-1313-T05-B 1
B EaFA-LRef-1313-T06-B 1
B EaFA-LRef-1313-T07-B 1
B EaFA-LRef-1313-T08-B 1
B EaFA-LRef-1313-T09-B 1
B EaFA-LRef-1313-T01-C 1
B EaFA-LRef-1313-T02-C 1
B EaFA-LRef-1313-T03-C 1
B EaFA-LRef-1313-T04-C 1
B EaFA-LRef-1313-T05-C 1
B EaFA-LRef-1313-T06-C 1
B EaFA-LRef-1313-T07-C 1
B EaFA-LRef-1313-T08-C 1
B EaFA-LRef-1313-T09-C 1
B EaFA-LRef-1313-B01-A 1
B EaFA-LRef-1313-B02-A 1
B EaFA-LRef-1313-B03-A 1
B EaFA-LRef-1313-B01-B 1
B EaFA-LRef-1313-B02-B 1
B EaFA-LRef-1313-B03-B 1
B EaFA-LRef-1313-B01-C 1
B EaFA-LRef-1313-B02-C 1
B EaFA-LRef-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
9.77E+03
4.99E+03
4.64E+03
4.50E+03
4.38E+03
4.62E+03
4.98E+03
3.82E+03
3.25E+03
9.62E+03
5.00E+03
4.49E+03
4.31 E+03
4.37E+03
4.47E+03
4.87E+03
3.82E+03
3.25E+03
9.22E+03
4.40E+03
4.30E+03
4.31 E+03
4.27E+03
4.43E+03
4.82E+03
3.75E+03
3.20E+03
2.67E+01
5.13E+01
5.73E+03
2.33E+01
4.38E+01
5.54E+03
2.11E+01
4.27E+01
4.73E+03
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.77E+03 1.0E+00 1.0E+00 3.2E+00
4.99E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
4.64E+03 9.7E-01 1.0E+00 3.2E+00
4.50E+03 4.1E-01 1.0E+00 3.2E+00
4.38E+03 1.3E+00 1.0E+00 3.2E+00
4.62E+03 2.2E+00 1.0E+00 3.2E+00
4.98E+03 4.8E-01 1.0E+00 3.2E+00
3.82E+03 6.9E-01 1.0E+00 3.2E+00
3.25E+03 7.5E-01 1.0E+00 3.2E+00
9.62E+03 1.4E+00 1.0E+00 3.2E+00
5.00E+03 1.3E+00 1.0E+00 3.2E+00
4.49E+03 1.5E+00 1.0E+00 3.2E+00 1000 100
4.31 E+03 1.3E+00 1.0E+00 3.2E+00
4.37E+03 5.6E-01 1.0E+00 3.2E+00
4.47E+03 7.8E-01 1.0E+00 3.2E+00
4.87E+03 1.2E+00 1.0E+00 3.2E+00
3.82E+03 6.6E-01 1.0E+00 3.2E+00
3.25E+03 3.8E-01 1.0E+00 3.2E+00
9.22E+03 6.1E-01 1.0E+00 3.2E+00
4.40E+03 2.5E+00 1.0E+00 3.2E+00
4.30E+03 8.6E-01 1.0E+00 3.2E+00
4.31E+03 1.6E+00 1.0E+00 3.2E+00 1000 100
4.27E+03 2.3E+00 1.0E+00 3.2E+00
4.43E+03 1.6E-01 1.0E+00 3.2E+00
4.82E+03 1.3E+00 1.0E+00 3.2E+00
3.75E+03 2.2E+00 1.0E+00 3.2E+00
3.20E+03 5.8E-01 1.0E+00 3.2E+00
2.67E+01 3.8E+00 1.0E+00 3.2E+00
5.13E+01 2.1E+00 1.0E+00 3.2E+00
5.73E+03 5.9E-01 1.0E+00 3.2E+00
2.33E+01 1.0E+01 1.0E+00 3.2E+00
4.38E+01 4.2E+00 1.0E+00 3.2E+00
5.54E+03 1.0E+00 1.0E+00 3.2E+00
2.11E+01 3.9E+00 1.0E+00 3.2E+00
4.27E+01 8.3E-01 1.0E+00 3.2E+00
4.73E+03 1.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
5.90E+03 91% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
5.43E+03 94% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
5.20E+03 88% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-297
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFA-LRef-1313-T01-A 1
Ba EaFA-LRef-1313-T02-A 1
Ba EaFA-LRef-1313-T03-A 1
Ba EaFA-LRef-1313-T04-A 1
Ba EaFA-LRef-1313-T05-A 1
Ba EaFA-LRef-1313-T06-A 1
Ba EaFA-LRef-1313-T07-A 1
Ba EaFA-LRef-1313-T08-A 1
Ba EaFA-LRef-1313-T09-A 1
Ba EaFA-LRef-1313-T01-B 1
Ba EaFA-LRef-1313-T02-B 1
Ba EaFA-LRef-1313-T03-B 1
Ba EaFA-LRef-1313-T04-B 1
Ba EaFA-LRef-1313-T05-B 1
Ba EaFA-LRef-1313-T06-B 1
Ba EaFA-LRef-1313-T07-B 1
Ba EaFA-LRef-1313-T08-B 1
Ba EaFA-LRef-1313-T09-B 1
Ba EaFA-LRef-1313-T01-C 1
Ba EaFA-LRef-1313-T02-C 1
Ba EaFA-LRef-1313-T03-C 1
Ba EaFA-LRef-1313-T04-C 1
Ba EaFA-LRef-1313-T05-C 1
Ba EaFA-LRef-1313-T06-C 1
Ba EaFA-LRef-1313-T07-C 1
Ba EaFA-LRef-1313-T08-C 1
Ba EaFA-LRef-1313-T09-C 1
Ba EaFA-LRef-1313-B01-A 1
Ba EaFA-LRef-1313-B02-A 1
Ba EaFA-LRef-1313-B03-A 1
Ba EaFA-LRef-1313-B01-B 1
Ba EaFA-LRef-1313-B02-B 1
Ba EaFA-LRef-1313-B03-B 1
Ba EaFA-LRef-1313-B01-C 1
Ba EaFA-LRef-1313-B02-C 1
Ba EaFA-LRef-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
6.59E+02
9.21 E+02
9.03E+02
5.62E+02
2.56E+02
2.60E+02
2.81 E+02
2.20E+02
8.76E+02
5.35E+02
7.53E+02
9.91 E+02
5.51 E+02
2.76E+02
2.46E+02
2.82E+02
2.20E+02
8.61 E+02
6.69E+02
9.25E+02
1 .05E+03
4.55E+02
2.62E+02
2.44E+02
2.66E+02
2.17E+02
8.72E+02
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.59E+02 5.2E-01 1.0E+00 3.2E+00
9.21 E+02 6.0E-01 1.0E+00 3.2E+00 10 325
9.03E+02 5.8E-01 1.0E+00 3.2E+00
5.62E+02 2.8E-01 1.0E+00 3.2E+00
2.56E+02 7.0E-01 1.0E+00 3.2E+00
2.60E+02 5.7E-01 1.0E+00 3.2E+00
2.81 E+02 1.3E+00 1.0E+00 3.2E+00
2.20E+02 9.3E-01 1.0E+00 3.2E+00
8.76E+02 4.6E-01 1.0E+00 3.2E+00
5.35E+02 1.4E+00 1.0E+00 3.2E+00
7.53E+02 3.2E+00 1.0E+00 3.2E+00
9.91E+02 8.5E-01 1.0E+00 3.2E+00 10 325
5.51 E+02 7.6E-01 1.0E+00 3.2E+00
2.76E+02 6.8E-01 1.0E+00 3.2E+00
2.46E+02 5.6E-01 1.0E+00 3.2E+00
2.82E+02 6.0E-01 1.0E+00 3.2E+00
2.20E+02 6.0E-01 1.0E+00 3.2E+00
8.61 E+02 4.7E-01 1.0E+00 3.2E+00
6.69E+02 5.6E-01 1.0E+00 3.2E+00
9.25E+02 7.1E-01 1.0E+00 3.2E+00
1.05E+03 2.6E-01 1.0E+00 3.2E+00
4.55E+02 3.7E-01 1.0E+00 3.2E+00 10 325
2.62E+02 7.4E-01 1.0E+00 3.2E+00
2.44E+02 8.6E-02 1.0E+00 3.2E+00
2.66E+02 1.8E+00 1.0E+00 3.2E+00
2.17E+02 2.4E+00 1.0E+00 3.2E+00
8.72E+02 7.9E-01 1.0E+00 3.2E+00
5.00E-01 9.2E-01 1.0E+00 3.2E+00
5.00E-01 2.6E-01 1.0E+00 3.2E+00
5.00E-01 2.1E-01 1.0E+00 3.2E+00
5.00E-01 4.6E-01 1.0E+00 3.2E+00
5.00E-01 1.2E+00 1.0E+00 3.2E+00
5.00E-01 2.3E-01 1.0E+00 3.2E+00
5.00E-01 7.8E-01 1.0E+00 3.2E+00
5.00E-01 6.4E-01 1.0E+00 3.2E+00
5.00E-01 1.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.73E+03 86% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.84E+03 88% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.16E+03 83% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-298
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-LRef-1313-T01-A 1
Be EaFA-LRef-1313-T02-A 1
Be EaFA-LRef-1313-T03-A 1
Be EaFA-LRef-1313-T04-A 1
Be EaFA-LRef-1313-T05-A 1
Be EaFA-LRef-1313-T06-A 1
Be EaFA-LRef-1313-T07-A 1
Be EaFA-LRef-1313-T08-A 1
Be EaFA-LRef-1313-T09-A 1
Be EaFA-LRef-1313-T01-B 1
Be EaFA-LRef-1313-T02-B 1
Be EaFA-LRef-1313-T03-B 1
Be EaFA-LRef-1313-T04-B 1
Be EaFA-LRef-1313-T05-B 1
Be EaFA-LRef-1313-T06-B 1
Be EaFA-LRef-1313-T07-B 1
Be EaFA-LRef-1313-T08-B 1
Be EaFA-LRef-1313-T09-B 1
Be EaFA-LRef-1313-T01-C 1
Be EaFA-LRef-1313-T02-C 1
Be EaFA-LRef-1313-T03-C 1
Be EaFA-LRef-1313-T04-C 1
Be EaFA-LRef-1313-T05-C 1
Be EaFA-LRef-1313-T06-C 1
Be EaFA-LRef-1313-T07-C 1
Be EaFA-LRef-1313-T08-C 1
Be EaFA-LRef-1313-T09-C 1
Be EaFA-LRef-1313-B01-A 1
Be EaFA-LRef-1313-B02-A 1
Be EaFA-LRef-1313-B03-A 1
Be EaFA-LRef-1313-B01-B 1
Be EaFA-LRef-1313-B02-B 1
Be EaFA-LRef-1313-B03-B 1
Be EaFA-LRef-1313-B01-C 1
Be EaFA-LRef-1313-B02-C 1
Be EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.23E+02
2.68E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.23E+02
2.63E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.20E+02
2.63E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 3.5E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00 10 325
9.50E-01 1.2E+01 1.9E+00 6.0E+00
9.50E-01 3.1E+00 1.9E+00 6.0E+00
9.50E-01 7.9E+00 1.9E+00 6.0E+00
9.50E-01 6.4E+00 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
1.23E+02 1.4E+00 1.9E+00 6.0E+00
2.68E+02 1.5E-01 1.9E+00 6.0E+00
9.50E-01 2.5E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+01 1.9E+00 6.0E+00 10 325
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 7.1E+00 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 2.2E+01 1.9E+00 6.0E+00
1.23E+02 1.2E+00 1.9E+00 6.0E+00
2.63E+02 3.2E-01 1.9E+00 6.0E+00
9.50E-01 3.3E+01 1.9E+00 6.0E+00
9.50E-01 6.0E+00 1.9E+00 6.0E+00
9.50E-01 2.5E+00 1.9E+00 6.0E+00
9.50E-01 3.7E+00 1.9E+00 6.0E+00 10 325
9.50E-01 9.0E+00 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 3.7E+01 1.9E+00 6.0E+00
1.20E+02 1.9E+00 1.9E+00 6.0E+00
2.63E+02 1.2E+00 1.9E+00 6.0E+00
9.50E-01 4.5E+00 1.9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
9.50E-01 9.0E+00 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 6.4E+00 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00
9.50E-01 3.2E+00 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.17E+03 98% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.20E+03 99% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.29E+03 101% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-299
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-LRef-1313-T01-A 1
Cd EaFA-LRef-1313-T02-A 1
Cd EaFA-LRef-1313-T03-A 1
Cd EaFA-LRef-1313-T04-A 1
Cd EaFA-LRef-1313-T05-A 1
Cd EaFA-LRef-1313-T06-A 1
Cd EaFA-LRef-1313-T07-A 1
Cd EaFA-LRef-1313-T08-A 1
Cd EaFA-LRef-1313-T09-A 1
Cd EaFA-LRef-1313-T01-B 1
Cd EaFA-LRef-1313-T02-B 1
Cd EaFA-LRef-1313-T03-B 1
Cd EaFA-LRef-1313-T04-B 1
Cd EaFA-LRef-1313-T05-B 1
Cd EaFA-LRef-1313-T06-B 1
Cd EaFA-LRef-1313-T07-B 1
Cd EaFA-LRef-1313-T08-B 1
Cd EaFA-LRef-1313-T09-B 1
Cd EaFA-LRef-1313-T01-C 1
Cd EaFA-LRef-1313-T02-C 1
Cd EaFA-LRef-1313-T03-C 1
Cd EaFA-LRef-1313-T04-C 1
Cd EaFA-LRef-1313-T05-C 1
Cd EaFA-LRef-1313-T06-C 1
Cd EaFA-LRef-1313-T07-C 1
Cd EaFA-LRef-1313-T08-C 1
Cd EaFA-LRef-1313-T09-C 1
Cd EaFA-LRef-1313-B01-A 1
Cd EaFA-LRef-1313-B02-A 1
Cd EaFA-LRef-1313-B03-A 1
Cd EaFA-LRef-1313-B01-B 1
Cd EaFA-LRef-1313-B02-B 1
Cd EaFA-LRef-1313-B03-B 1
Cd EaFA-LRef-1313-B01-C 1
Cd EaFA-LRef-1313-B02-C 1
Cd EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.20E+01
2.69E+01
2.93E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
2.57E+01
2.71E+01
2.94E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.04E+01
2.60E+01
2.94E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.2E+01 2.2E+00 7.0E+00
1.10E+00 2.5E+01 2.2E+00 7.0E+00 10 325
1.10E+00 1.3E+01 2.2E+00 7.0E+00
1.10E+00 2.3E+01 2.2E+00 7.0E+00
1.10E+00 1.3E+01 2.2E+00 7.0E+00
1.10E+00 3.5E+01 2.2E+00 7.0E+00
3.20E+01 3.9E+00 2.2E+00 7.0E+00
2.69E+01 1.1E+00 2.2E+00 7.0E+00
2.93E+01 2.1E+00 2.2E+00 7.0E+00
1.10E+00 5.3E+01 2.2E+00 7.0E+00
1.10E+00 4.9E+01 2.2E+00 7.0E+00
1.10E+00 1.4E+01 2.2E+00 7.0E+00 10 325
1.10E+00 9.5E+00 2.2E+00 7.0E+00
1.10E+00 3.8E+01 2.2E+00 7.0E+00
1.10E+00 5.5E+01 2.2E+00 7.0E+00
2.57E+01 3.8E+00 2.2E+00 7.0E+00
2.71 E+01 1.1E+00 2.2E+00 7.0E+00
2.94E+01 2.1E+00 2.2E+00 7.0E+00
1.10E+00 6.3E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
1.10E+00 4.1E+01 2.2E+00 7.0E+00
1.10E+00 3.3E+00 2.2E+00 7.0E+00 10 325
1.10E+00 2.4E+01 2.2E+00 7.0E+00
1.10E+00 1.4E+01 2.2E+00 7.0E+00
3.04E+01 1.2E+00 2.2E+00 7.0E+00
2.60E+01 4.2E+00 2.2E+00 7.0E+00
2.94E+01 2.3E+00 2.2E+00 7.0E+00
1.10E+00 5.2E+01 2.2E+00 7.0E+00
1.10E+00 7.7E+00 2.2E+00 7.0E+00
1.10E+00 2.9E+01 2.2E+00 7.0E+00
1.10E+00 2.3E+01 2.2E+00 7.0E+00
1.10E+00 4.6E+01 2.2E+00 7.0E+00
1.10E+00 2.3E+01 2.2E+00 7.0E+00
1.10E+00 2.4E+01 2.2E+00 7.0E+00
1.10E+00 6.8E+01 2.2E+00 7.0E+00
1.10E+00 7.1 E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.25E+03 1 00% VU ICP-OES 5/6/1 0 8:20 AM EPA Interlab LRef A-C 1 31 3-1 31 6 EaFA
VU ICP-OES 5/6/10 8:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.19E+03 98% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.20E+03 98% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-300
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca EaFA-LRef-1313-T01-A 1
Ca EaFA-LRef-1313-T02-A 1
Ca EaFA-LRef-1313-T03-A 1
Ca EaFA-LRef-1313-T04-A 1
Ca EaFA-LRef-1313-T05-A 1
Ca EaFA-LRef-1313-T06-A 1
Ca EaFA-LRef-1313-T07-A 1
Ca EaFA-LRef-1313-T08-A 1
Ca EaFA-LRef-1313-T09-A 1
Ca EaFA-LRef-1313-T01-B 1
Ca EaFA-LRef-1313-T02-B 1
Ca EaFA-LRef-1313-T03-B 1
Ca EaFA-LRef-1313-T04-B 1
Ca EaFA-LRef-1313-T05-B 1
Ca EaFA-LRef-1313-T06-B 1
Ca EaFA-LRef-1313-T07-B 1
Ca EaFA-LRef-1313-T08-B 1
Ca EaFA-LRef-1313-T09-B 1
Ca EaFA-LRef-1313-T01-C 1
Ca EaFA-LRef-1313-T02-C 1
Ca EaFA-LRef-1313-T03-C 1
Ca EaFA-LRef-1313-T04-C 1
Ca EaFA-LRef-1313-T05-C 1
Ca EaFA-LRef-1313-T06-C 1
Ca EaFA-LRef-1313-T07-C 1
Ca EaFA-LRef-1313-T08-C 1
Ca EaFA-LRef-1313-T09-C 1
Ca EaFA-LRef-1313-B01-A 1
Ca EaFA-LRef-1313-B02-A 1
Ca EaFA-LRef-1313-B03-A 1
Ca EaFA-LRef-1313-B01-B 1
Ca EaFA-LRef-1313-B02-B 1
Ca EaFA-LRef-1313-B03-B 1
Ca EaFA-LRef-1313-B01-C 1
Ca EaFA-LRef-1313-B02-C 1
Ca EaFA-LRef-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
9.20E+03
4.09E+04
8.73E+04
1.11E+05
1.35E+05
1.55E+05
1.67E+05
1.40E+05
1.41E+05
7.79E+03
4.47E+04
9.67E+04
1.08E+05
1.33E+05
1.47E+05
1.64E+05
1.40E+05
1.40E+05
9.44E+03
4.60E+04
9.22E+04
1.11E+05
1.34E+05
1.41E+05
1.56E+05
1.35E+05
1.38E+05
2.95E+01
3.14E+01
2.45E+01
3.30E+01
3.36E+01
2.33E+01
2.24E+01
3.12E+01
1.05E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.20E+03 4.5E-01 2.6E+00 8.3E+00
4.09E+04 2.4E-01 2.6E+00 8.3E+00 1000 100
8.73E+04 9.9E-01 2.6E+00 8.3E+00
1.11E+05 4.7E-01 2.6E+00 8.3E+00
1.35E+05 1.1E+00 2.6E+00 8.3E+00
1.55E+05 1.0E+00 2.6E+00 8.3E+00
1.67E+05 6.9E-01 2.6E+00 8.3E+00
1.40E+05 8.0E-01 2.6E+00 8.3E+00
1.41E+05 3.8E-01 2.6E+00 8.3E+00
7.79E+03 1.0E+00 2.6E+00 8.3E+00
4.47E+04 7.8E-01 2.6E+00 8.3E+00
9.67E+04 1.0E+00 2.6E+00 8.3E+00 1000 100
1.08E+05 1.4E+00 2.6E+00 8.3E+00
1.33E+05 3.9E-01 2.6E+00 8.3E+00
1.47E+05 6.3E-01 2.6E+00 8.3E+00
1.64E+05 1.1E-01 2.6E+00 8.3E+00
1.40E+05 2.4E-01 2.6E+00 8.3E+00
1.40E+05 6.6E-01 2.6E+00 8.3E+00
9.44E+03 4.9E-01 2.6E+00 8.3E+00
4.60E+04 4.9E-01 2.6E+00 8.3E+00
9.22E+04 4.6E-01 2.6E+00 8.3E+00
1.11E+05 9.7E-01 2.6E+00 8.3E+00 1000 100
1.34E+05 7.7E-01 2.6E+00 8.3E+00
1.41E+05 3.2E-01 2.6E+00 8.3E+00
1.56E+05 1.7E+00 2.6E+00 8.3E+00
1.35E+05 1.1E+00 2.6E+00 8.3E+00
1.38E+05 3.9E-01 2.6E+00 8.3E+00
2.95E+01 1.7E+01 2.6E+00 8.3E+00
3.14E+01 2.0E+01 2.6E+00 8.3E+00
2.45E+01 5.5E+01 2.6E+00 8.3E+00
3.30E+01 1.9E+01 2.6E+00 8.3E+00
3.36E+01 2.0E+01 2.6E+00 8.3E+00
2.33E+01 6.8E+01 2.6E+00 8.3E+00
2.24E+01 2.8E+01 2.6E+00 8.3E+00
3.12E+01 2.8E+01 2.6E+00 8.3E+00
1.05E+01 8.0E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
4.18E+04 91% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
9.75E+04 88% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.12E+05 87% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-301
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr EaFA-LRef-1313-T01-A 1
Cr EaFA-LRef-1313-T02-A 1
Cr EaFA-LRef-1313-T03-A 1
Cr EaFA-LRef-1313-T04-A 1
Cr EaFA-LRef-1313-T05-A 1
Cr EaFA-LRef-1313-T06-A 1
Cr EaFA-LRef-1313-T07-A 1
Cr EaFA-LRef-1313-T08-A 1
Cr EaFA-LRef-1313-T09-A 1
Cr EaFA-LRef-1313-T01-B 1
Cr EaFA-LRef-1313-T02-B 1
Cr EaFA-LRef-1313-T03-B 1
Cr EaFA-LRef-1313-T04-B 1
Cr EaFA-LRef-1313-T05-B 1
Cr EaFA-LRef-1313-T06-B 1
Cr EaFA-LRef-1313-T07-B 1
Cr EaFA-LRef-1313-T08-B 1
Cr EaFA-LRef-1313-T09-B 1
Cr EaFA-LRef-1313-T01-C 1
Cr EaFA-LRef-1313-T02-C 1
Cr EaFA-LRef-1313-T03-C 1
Cr EaFA-LRef-1313-T04-C 1
Cr EaFA-LRef-1313-T05-C 1
Cr EaFA-LRef-1313-T06-C 1
Cr EaFA-LRef-1313-T07-C 1
Cr EaFA-LRef-1313-T08-C 1
Cr EaFA-LRef-1313-T09-C 1
Cr EaFA-LRef-1313-B01-A 1
Cr EaFA-LRef-1313-B02-A 1
Cr EaFA-LRef-1313-B03-A 1
Cr EaFA-LRef-1313-B01-B 1
Cr EaFA-LRef-1313-B02-B 1
Cr EaFA-LRef-1313-B03-B 1
Cr EaFA-LRef-1313-B01-C 1
Cr EaFA-LRef-1313-B02-C 1
Cr EaFA-LRef-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
3.92E+02
3.06E+02
2.48E+02
2.23E+02
1.34E+02
4.22E+01
1.57E+00 E
1.75E+02
1.96E+03
3.69E+02
2.80E+02
2.89E+02
2.10E+02
1.33E+02
5.43E+01
6.00E-01 U1/2
1.71E+02
1.95E+03
4.14E+02
3.26E+02
2.64E+02
2.18E+02
1.37E+02
6.01E+01
1.27E+00 E
1.56E+02
1.92E+03
6.00E-01 U1/2
6.00E-01 U1/2
6.44E+00
6.00E-01 U1/2
6.00E-01 U1/2
9.49E+00
6.00E-01 U1/2
6.00E-01 U1/2
4.16E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.92E+02 6.9E-01 1.2E+00 3.8E+00
3.06E+02 7.8E-01 1.2E+00 3.8E+00 10 325
2.48E+02 1.4E+00 1.2E+00 3.8E+00
2.23E+02 1.0E+00 1.2E+00 3.8E+00
1.34E+02 1.4E+00 1.2E+00 3.8E+00
4.22E+01 2.7E+00 1.2E+00 3.8E+00
1.57E+00 1.0E+02 1.2E+00 3.8E+00
1.75E+02 1.4E+00 1.2E+00 3.8E+00
1.96E+03 3.7E-01 1.2E+00 3.8E+00
3.69E+02 8.7E-01 1.2E+00 3.8E+00
2.80E+02 6.3E-01 1.2E+00 3.8E+00
2.89E+02 1.1E+00 1.2E+00 3.8E+00 10 325
2.10E+02 1.1E+00 1.2E+00 3.8E+00
1.33E+02 9.2E-01 1.2E+00 3.8E+00
5.43E+01 3.1E+00 1.2E+00 3.8E+00
6.00E-01 9.6E+01 1.2E+00 3.8E+00
1.71E+02 7.9E-01 1.2E+00 3.8E+00
1.95E+03 4.2E-01 1.2E+00 3.8E+00
4.14E+02 6.4E-01 1.2E+00 3.8E+00
3.26E+02 1.0E+00 1.2E+00 3.8E+00
2.64E+02 2.0E-01 1.2E+00 3.8E+00
2.18E+02 4.6E-01 1.2E+00 3.8E+00 10 325
1.37E+02 5.8E-01 1.2E+00 3.8E+00
6.01 E+01 2.5E+00 1.2E+00 3.8E+00
1.27E+00 2.0E+02 1.2E+00 3.8E+00
1.56E+02 1.4E+00 1.2E+00 3.8E+00
1.92E+03 1.5E-01 1.2E+00 3.8E+00
6.00E-01 4.8E+02 1.2E+00 3.8E+00
6.00E-01 2.3E+04 1.2E+00 3.8E+00
6.44E+00 3.5E+01 1.2E+00 3.8E+00
6.00E-01 2.2E+02 1.2E+00 3.8E+00
6.00E-01 8.3E+01 1.2E+00 3.8E+00
9.49E+00 4.7E+00 1.2E+00 3.8E+00
6.00E-01 9.5E+02 1.2E+00 3.8E+00
6.00E-01 5.2E+01 1.2E+00 3.8E+00
4.16E+00 3.6E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.30E+03 92% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.25E+03 91% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.20E+03 92% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-302
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-LRef-1313-T01-A 1
Co EaFA-LRef-1313-T02-A 1
Co EaFA-LRef-1313-T03-A 1
Co EaFA-LRef-1313-T04-A 1
Co EaFA-LRef-1313-T05-A 1
Co EaFA-LRef-1313-T06-A 1
Co EaFA-LRef-1313-T07-A 1
Co EaFA-LRef-1313-T08-A 1
Co EaFA-LRef-1313-T09-A 1
Co EaFA-LRef-1313-T01-B 1
Co EaFA-LRef-1313-T02-B 1
Co EaFA-LRef-1313-T03-B 1
Co EaFA-LRef-1313-T04-B 1
Co EaFA-LRef-1313-T05-B 1
Co EaFA-LRef-1313-T06-B 1
Co EaFA-LRef-1313-T07-B 1
Co EaFA-LRef-1313-T08-B 1
Co EaFA-LRef-1313-T09-B 1
Co EaFA-LRef-1313-T01-C 1
Co EaFA-LRef-1313-T02-C 1
Co EaFA-LRef-1313-T03-C 1
Co EaFA-LRef-1313-T04-C 1
Co EaFA-LRef-1313-T05-C 1
Co EaFA-LRef-1313-T06-C 1
Co EaFA-LRef-1313-T07-C 1
Co EaFA-LRef-1313-T08-C 1
Co EaFA-LRef-1313-T09-C 1
Co EaFA-LRef-1313-B01-A 1
Co EaFA-LRef-1313-B02-A 1
Co EaFA-LRef-1313-B03-A 1
Co EaFA-LRef-1313-B01-B 1
Co EaFA-LRef-1313-B02-B 1
Co EaFA-LRef-1313-B03-B 1
Co EaFA-LRef-1313-B01-C 1
Co EaFA-LRef-1313-B02-C 1
Co EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.93E+01
2.52E+02
2.14E+02
4.19E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
3.00E+00 E
2.13E+01
2.38E+02
2.14E+02
4.15E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
4.09E+00 E
2.03E+01
2.39E+02
2.06E+02
4.20E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.59E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.7E+02 1.8E+00 5.7E+00
9.00E-01 4.0E+03 1.8E+00 5.7E+00 10 325
9.00E-01 2.9E+02 1.8E+00 5.7E+00
9.00E-01 7.8E+02 1.8E+00 5.7E+00
9.00E-01 8.1E+03 1.8E+00 5.7E+00
2.93E+01 3.4E+00 1.8E+00 5.7E+00
2.52E+02 2.2E+00 1.8E+00 5.7E+00
2.14E+02 2.1E+00 1.8E+00 5.7E+00
4.19E+02 8.6E-01 1.8E+00 5.7E+00
9.00E-01 9.2E+01 1.8E+00 5.7E+00
9.00E-01 2.1E+03 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00 10 325
9.00E-01 1.3E+02 1.8E+00 5.7E+00
3.00E+00 6.4E+01 1.8E+00 5.7E+00
2.13E+01 2.0E+01 1.8E+00 5.7E+00
2.38E+02 1.7E+00 1.8E+00 5.7E+00
2.14E+02 1.0E+00 1.8E+00 5.7E+00
4.15E+02 6.2E-01 1.8E+00 5.7E+00
9.00E-01 8.8E+01 1.8E+00 5.7E+00
9.00E-01 3.3E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00
9.00E-01 2.4E+01 1.8E+00 5.7E+00 10 325
4.09E+00 8.4E+01 1.8E+00 5.7E+00
2.03E+01 1.5E+01 1.8E+00 5.7E+00
2.39E+02 8.5E-01 1.8E+00 5.7E+00
2.06E+02 1.8E+00 1.8E+00 5.7E+00
4.20E+02 2.3E-01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 8.4E+01 1.8E+00 5.7E+00
9.00E-01 3.3E+03 1.8E+00 5.7E+00
9.00E-01 3.9E+01 1 .8E+00 5.7E+00
9.00E-01 1.9E+02 1 .8E+00 5.7E+00
9.00E-01 2.2E+02 1 .8E+00 5.7E+00
9.00E-01 1.0E+03 1.8E+00 5.7E+00
9.00E-01 3.7E+02 1.8E+00 5.7E+00
2.59E+00 2.0E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.28E+03 1 01 % VU ICP-OES 5/6/1 0 8:20 AM EPA Interlab LRef A-C 1 31 3-1 31 6 EaFA
VU ICP-OES 5/6/10 8:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.12E+03 96% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.25E+03 100% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-303
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFA-LRef-1313-T01-A 1
Cu EaFA-LRef-1313-T02-A 1
Cu EaFA-LRef-1313-T03-A 1
Cu EaFA-LRef-1313-T04-A 1
Cu EaFA-LRef-1313-T05-A 1
Cu EaFA-LRef-1313-T06-A 1
Cu EaFA-LRef-1313-T07-A 1
Cu EaFA-LRef-1313-T08-A 1
Cu EaFA-LRef-1313-T09-A 1
Cu EaFA-LRef-1313-T01-B 1
Cu EaFA-LRef-1313-T02-B 1
Cu EaFA-LRef-1313-T03-B 1
Cu EaFA-LRef-1313-T04-B 1
Cu EaFA-LRef-1313-T05-B 1
Cu EaFA-LRef-1313-T06-B 1
Cu EaFA-LRef-1313-T07-B 1
Cu EaFA-LRef-1313-T08-B 1
Cu EaFA-LRef-1313-T09-B 1
Cu EaFA-LRef-1313-T01-C 1
Cu EaFA-LRef-1313-T02-C 1
Cu EaFA-LRef-1313-T03-C 1
Cu EaFA-LRef-1313-T04-C 1
Cu EaFA-LRef-1313-T05-C 1
Cu EaFA-LRef-1313-T06-C 1
Cu EaFA-LRef-1313-T07-C 1
Cu EaFA-LRef-1313-T08-C 1
Cu EaFA-LRef-1313-T09-C 1
Cu EaFA-LRef-1313-B01-A 1
Cu EaFA-LRef-1313-B02-A 1
Cu EaFA-LRef-1313-B03-A 1
Cu EaFA-LRef-1313-B01-B 1
Cu EaFA-LRef-1313-B02-B 1
Cu EaFA-LRef-1313-B03-B 1
Cu EaFA-LRef-1313-B01-C 1
Cu EaFA-LRef-1313-B02-C 1
Cu EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.52E+01
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
8.94E+01
1.91E+03
3.16E+03
2.90E+01
1.85E+00 U1/2
6.06E+00 E
1.85E+00 U1/2
1.14E+01 E
3.85E+00 E
3.96E+01
1.89E+03
3.15E+03
1.52E+01
1.85E+00 U1/2
5.39E+00 E
1.85E+00 U1/2
4.71 E+00 E
5.17E+00 E
7.23E+01
1.86E+03
3.11E+03
1.85E+00 U1/2
1.85E+00 U1/2
8.49E+00 E
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.52E+01 2.4E+01 3.7E+00 1.2E+01
1.85E+00 4.1E+02 3.7E+00 1.2E+01 10 325
1.85E+00 4.8E+04 3.7E+00 1.2E+01
1.85E+00 3.6E+02 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.85E+00 1.6E+02 3.7E+00 1.2E+01
8.94E+01 3.9E+00 3.7E+00 1.2E+01
1.91E+03 8.4E-01 3.7E+00 1.2E+01
3.16E+03 1.1E-01 3.7E+00 1.2E+01
2.90E+01 2.3E+01 3.7E+00 1.2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01
6.06E+00 1.0E+02 3.7E+00 1.2E+01 10 325
1.85E+00 1.1E+02 3.7E+00 1.2E+01
1.14E+01 1.1E+01 3.7E+00 1.2E+01
3.85E+00 1.3E+02 3.7E+00 1.2E+01
3.96E+01 7.9E+00 3.7E+00 1.2E+01
1.89E+03 9.3E-01 3.7E+00 1.2E+01
3.15E+03 3.6E-01 3.7E+00 1.2E+01
1.52E+01 2.8E+01 3.7E+00 1.2E+01
1.85E+00 4.7E+02 3.7E+00 1.2E+01
5.39E+00 4.6E+01 3.7E+00 1.2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01 10 325
4.71 E+00 1.3E+02 3.7E+00 1.2E+01
5.17E+00 9.6E+01 3.7E+00 1.2E+01
7.23E+01 1.2E+01 3.7E+00 1.2E+01
1.86E+03 1.1 E+00 3.7E+00 1.2E+01
3.11E+03 1.1 E+00 3.7E+00 1.2E+01
1.85E+00 6.6E+01 3.7E+00 1.2E+01
1.85E+00 7.1E+01 3.7E+00 1.2E+01
8.49E+00 3.8E+01 3.7E+00 1.2E+01
1.85E+00 2.3E+01 3.7E+00 1.2E+01
1.85E+00 7.5E+01 3.7E+00 1.2E+01
1.85E+00 4.1E+02 3.7E+00 1.2E+01
1.85E+00 9.3E+00 3.7E+00 1.2E+01
1.85E+00 6.7E+01 3.7E+00 1.2E+01
1.85E+00 1.3E+03 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.09E+03 95% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.07E+03 94% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.15E+03 97% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-304
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-LRef-1313-T01-A 1
Fe EaFA-LRef-1313-T02-A 1
Fe EaFA-LRef-1313-T03-A 1
Fe EaFA-LRef-1313-T04-A 1
Fe EaFA-LRef-1313-T05-A 1
Fe EaFA-LRef-1313-T06-A 1
Fe EaFA-LRef-1313-T07-A 1
Fe EaFA-LRef-1313-T08-A 1
Fe EaFA-LRef-1313-T09-A 1
Fe EaFA-LRef-1313-T01-B 1
Fe EaFA-LRef-1313-T02-B 1
Fe EaFA-LRef-1313-T03-B 1
Fe EaFA-LRef-1313-T04-B 1
Fe EaFA-LRef-1313-T05-B 1
Fe EaFA-LRef-1313-T06-B 1
Fe EaFA-LRef-1313-T07-B 1
Fe EaFA-LRef-1313-T08-B 1
Fe EaFA-LRef-1313-T09-B 1
Fe EaFA-LRef-1313-T01-C 1
Fe EaFA-LRef-1313-T02-C 1
Fe EaFA-LRef-1313-T03-C 1
Fe EaFA-LRef-1313-T04-C 1
Fe EaFA-LRef-1313-T05-C 1
Fe EaFA-LRef-1313-T06-C 1
Fe EaFA-LRef-1313-T07-C 1
Fe EaFA-LRef-1313-T08-C 1
Fe EaFA-LRef-1313-T09-C 1
Fe EaFA-LRef-1313-B01-A 1
Fe EaFA-LRef-1313-B02-A 1
Fe EaFA-LRef-1313-B03-A 1
Fe EaFA-LRef-1313-B01-B 1
Fe EaFA-LRef-1313-B02-B 1
Fe EaFA-LRef-1313-B03-B 1
Fe EaFA-LRef-1313-B01-C 1
Fe EaFA-LRef-1313-B02-C 1
Fe EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.39E+01
2.02E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.19E+02
3.39E+04
4.31E+01
2.07E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.00E+02
3.38E+04
3.59E+01
2.08E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.45E+02
3.30E+04
1.00E+00 U1/2
1.13E+01
1.45E+01
1.00E+00 U1/2
1.15E+01
1.13E+01
1.00E+00 U1/2
5.44E+00 E
1.20E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.39E+01 1.1E+00 2.0E+00 6.4E+00
2.02E+01 2.1E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 5.8E+00 2.0E+00 6.4E+00
4.19E+02 1.1E+00 2.0E+00 6.4E+00
3.39E+04 3.1E-01 2.0E+00 6.4E+00
4.31 E+01 1.4E+00 2.0E+00 6.4E+00
2.07E+01 7.3E-01 2.0E+00 6.4E+00
1.00E+00 6.2E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 7.9E+00 2.0E+00 6.4E+00
1.00E+00 1.1 E+01 2.0E+00 6.4E+00
4.00E+02 1.6E+00 2.0E+00 6.4E+00
3.38E+04 3.7E-01 2.0E+00 6.4E+00
3.59E+01 1.1E-01 2.0E+00 6.4E+00
2.08E+01 1.9E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 6.0E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 5.2E+00 2.0E+00 6.4E+00
4.45E+02 1.1E+00 2.0E+00 6.4E+00
3.30E+04 3.3E-01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.13E+01 3.5E+00 2.0E+00 6.4E+00
1.45E+01 6.1E+00 2.0E+00 6.4E+00
1.00E+00 6.1E+00 2.0E+00 6.4E+00
1.15E+01 8.3E+00 2.0E+00 6.4E+00
1.13E+01 9.4E-01 2.0E+00 6.4E+00
1.00E+00 5.7E+01 2.0E+00 6.4E+00
5.44E+00 2.3E+01 2.0E+00 6.4E+00
1.20E+01 5.0E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.09E+03 107% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
1 .07E+03 107% VU ICP-OES 5/6/1 0 8:45 AM EPA Interlab LRef A-C 1 31 3-1 31 6 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.05E+03 105% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-305
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-LRef-1313-T01-A 1
Pb EaFA-LRef-1313-T02-A 1
Pb EaFA-LRef-1313-T03-A 1
Pb EaFA-LRef-1313-T04-A 1
Pb EaFA-LRef-1313-T05-A 1
Pb EaFA-LRef-1313-T06-A 1
Pb EaFA-LRef-1313-T07-A 1
Pb EaFA-LRef-1313-T08-A 1
Pb EaFA-LRef-1313-T09-A 1
Pb EaFA-LRef-1313-T01-B 1
Pb EaFA-LRef-1313-T02-B 1
Pb EaFA-LRef-1313-T03-B 1
Pb EaFA-LRef-1313-T04-B 1
Pb EaFA-LRef-1313-T05-B 1
Pb EaFA-LRef-1313-T06-B 1
Pb EaFA-LRef-1313-T07-B 1
Pb EaFA-LRef-1313-T08-B 1
Pb EaFA-LRef-1313-T09-B 1
Pb EaFA-LRef-1313-T01-C 1
Pb EaFA-LRef-1313-T02-C 1
Pb EaFA-LRef-1313-T03-C 1
Pb EaFA-LRef-1313-T04-C 1
Pb EaFA-LRef-1313-T05-C 1
Pb EaFA-LRef-1313-T06-C 1
Pb EaFA-LRef-1313-T07-C 1
Pb EaFA-LRef-1313-T08-C 1
Pb EaFA-LRef-1313-T09-C 1
Pb EaFA-LRef-1313-B01-A 1
Pb EaFA-LRef-1313-B02-A 1
Pb EaFA-LRef-1313-B03-A 1
Pb EaFA-LRef-1313-B01-B 1
Pb EaFA-LRef-1313-B02-B 1
Pb EaFA-LRef-1313-B03-B 1
Pb EaFA-LRef-1313-B01-C 1
Pb EaFA-LRef-1313-B02-C 1
Pb EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
7.26E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
5.83E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
6.85E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 1.4E+01 6.8E+00 2.2E+01 10 325
3.40E+00 1.9E+01 6.8E+00 2.2E+01
3.40E+00 6.6E+01 6.8E+00 2.2E+01
3.40E+00 2.1E+01 6.8E+00 2.2E+01
3.40E+00 5.4E+01 6.8E+00 2.2E+01
3.40E+00 7.7E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+01 6.8E+00 2.2E+01
7.26E+01 1.0E+01 6.8E+00 2.2E+01
3.40E+00 1.9E+02 6.8E+00 2.2E+01
3.40E+00 5.8E+01 6.8E+00 2.2E+01
3.40E+00 2.8E+01 6.8E+00 2.2E+01 10 325
3.40E+00 3.0E+01 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.40E+00 2.0E+01 6.8E+00 2.2E+01
3.40E+00 4.0E+01 6.8E+00 2.2E+01
3.40E+00 1.5E+01 6.8E+00 2.2E+01
5.83E+01 3.1E+00 6.8E+00 2.2E+01
3.40E+00 1.0E+02 6.8E+00 2.2E+01
3.40E+00 8.5E+00 6.8E+00 2.2E+01
3.40E+00 2.0E+01 6.8E+00 2.2E+01
3.40E+00 6.4E+00 6.8E+00 2.2E+01 10 325
3.40E+00 7.9E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+01 6.8E+00 2.2E+01
3.40E+00 1.0E+01 6.8E+00 2.2E+01
3.40E+00 1.7E+01 6.8E+00 2.2E+01
6.85E+01 4.0E+00 6.8E+00 2.2E+01
3.40E+00 8.7E+01 6.8E+00 2.2E+01
3.40E+00 2.6E+01 6.8E+00 2.2E+01
3.40E+00 3.3E+01 6.8E+00 2.2E+01
3.40E+00 2.1E+01 6.8E+00 2.2E+01
3.40E+00 2.4E+01 6.8E+00 2.2E+01
3.40E+00 7.5E+01 6.8E+00 2.2E+01
3.40E+00 3.4E+01 6.8E+00 2.2E+01
3.40E+00 8.5E+00 6.8E+00 2.2E+01
3.40E+00 1.2E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.24E+03 1 00% VU ICP-OES 5/6/1 0 8:20 AM EPA Interlab LRef A-C 1 31 3-1 31 6 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.14E+03 96% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.23E+03 99% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-306
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFA-LRef-1313-T01-A 1
Li EaFA-LRef-1313-T02-A 1
Li EaFA-LRef-1313-T03-A 1
Li EaFA-LRef-1313-T04-A 1
Li EaFA-LRef-1313-T05-A 1
Li EaFA-LRef-1313-T06-A 1
Li EaFA-LRef-1313-T07-A 1
Li EaFA-LRef-1313-T08-A 1
Li EaFA-LRef-1313-T09-A 1
Li EaFA-LRef-1313-T01-B 1
Li EaFA-LRef-1313-T02-B 1
Li EaFA-LRef-1313-T03-B 1
Li EaFA-LRef-1313-T04-B 1
Li EaFA-LRef-1313-T05-B 1
Li EaFA-LRef-1313-T06-B 1
Li EaFA-LRef-1313-T07-B 1
Li EaFA-LRef-1313-T08-B 1
Li EaFA-LRef-1313-T09-B 1
Li EaFA-LRef-1313-T01-C 1
Li EaFA-LRef-1313-T02-C 1
Li EaFA-LRef-1313-T03-C 1
Li EaFA-LRef-1313-T04-C 1
Li EaFA-LRef-1313-T05-C 1
Li EaFA-LRef-1313-T06-C 1
Li EaFA-LRef-1313-T07-C 1
Li EaFA-LRef-1313-T08-C 1
Li EaFA-LRef-1313-T09-C 1
Li EaFA-LRef-1313-B01-A 1
Li EaFA-LRef-1313-B02-A 1
Li EaFA-LRef-1313-B03-A 1
Li EaFA-LRef-1313-B01-B 1
Li EaFA-LRef-1313-B02-B 1
Li EaFA-LRef-1313-B03-B 1
Li EaFA-LRef-1313-B01-C 1
Li EaFA-LRef-1313-B02-C 1
Li EaFA-LRef-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
1.56E+03
2.23E+03
2.56E+03
2.70E+03
2.97E+03
3.24E+03
3.26E+03
2.12E+03
1.51E+03
1.53E+03
2.21E+03
2.63E+03
2.50E+03
2.94E+03
3.06E+03
3.13E+03
2.15E+03
1.50E+03
1.53E+03
2.20E+03
2.54E+03
2.36E+03
2.88E+03
2.98E+03
3.07E+03
2.07E+03
1.48E+03
2.75E+00 E
9.50E-01 U1/2
5.32E+00 E
2.66E+00 E
2.85E+00 E
3.94E+00 E
2.26E+00 E
3.00E+00 E
2.46E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.56E+03 3.3E-01 1.9E+00 6.0E+00
2.23E+03 2.6E-01 1.9E+00 6.0E+00 10 325
2.56E+03 7.9E-01 1.9E+00 6.0E+00
2.70E+03 3.3E-01 1.9E+00 6.0E+00
2.97E+03 4.3E-01 1.9E+00 6.0E+00
3.24E+03 3.5E-01 1.9E+00 6.0E+00
3.26E+03 1.1E+00 1.9E+00 6.0E+00
2.12E+03 2.4E-01 1.9E+00 6.0E+00
1.51E+03 4.1E-01 1.9E+00 6.0E+00
1.53E+03 1.4E+00 1.9E+00 6.0E+00
2.21 E+03 1.0E+00 1.9E+00 6.0E+00
2.63E+03 4.8E-01 1.9E+00 6.0E+00 10 325
2.50E+03 8.6E-01 1.9E+00 6.0E+00
2.94E+03 8.6E-01 1.9E+00 6.0E+00
3.06E+03 2.9E-01 1.9E+00 6.0E+00
3.13E+03 5.1E-01 1.9E+00 6.0E+00
2.15E+03 4.5E-01 1.9E+00 6.0E+00
1.50E+03 7.2E-01 1.9E+00 6.0E+00
1.53E+03 8.1E-01 1.9E+00 6.0E+00
2.20E+03 5.7E-01 1.9E+00 6.0E+00
2.54E+03 3.4E-01 1.9E+00 6.0E+00
2.36E+03 4.6E-01 1.9E+00 6.0E+00 10 325
2.88E+03 2.9E-01 1.9E+00 6.0E+00
2.98E+03 3.7E-01 1.9E+00 6.0E+00
3.07E+03 1.8E+00 1.9E+00 6.0E+00
2.07E+03 1.8E+00 1.9E+00 6.0E+00
1.48E+03 3.0E-01 1.9E+00 6.0E+00
2.75E+00 1.9E+01 1.9E+00 6.0E+00
9.50E-01 8.6E+01 1.9E+00 6.0E+00
5.32E+00 3.7E+01 1.9E+00 6.0E+00
2.66E+00 1.3E+01 1.9E+00 6.0E+00
2.85E+00 1.6E+01 1.9E+00 6.0E+00
3.94E+00 6.1E+01 1.9E+00 6.0E+00
2.26E+00 9.2E+01 1.9E+00 6.0E+00
3.00E+00 2.5E+01 1.9E+00 6.0E+00
2.46E+00 4.5E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
4.96E+03 84% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
5.38E+03 85% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
5.25E+03 89% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-307
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFA-LRef-1313-T01-A 1
Mn EaFA-LRef-1313-T02-A 1
Mn EaFA-LRef-1313-T03-A 1
Mn EaFA-LRef-1313-T04-A 1
Mn EaFA-LRef-1313-T05-A 1
Mn EaFA-LRef-1313-T06-A 1
Mn EaFA-LRef-1313-T07-A 1
Mn EaFA-LRef-1313-T08-A 1
Mn EaFA-LRef-1313-T09-A 1
Mn EaFA-LRef-1313-T01-B 1
Mn EaFA-LRef-1313-T02-B 1
Mn EaFA-LRef-1313-T03-B 1
Mn EaFA-LRef-1313-T04-B 1
Mn EaFA-LRef-1313-T05-B 1
Mn EaFA-LRef-1313-T06-B 1
Mn EaFA-LRef-1313-T07-B 1
Mn EaFA-LRef-1313-T08-B 1
Mn EaFA-LRef-1313-T09-B 1
Mn EaFA-LRef-1313-T01-C 1
Mn EaFA-LRef-1313-T02-C 1
Mn EaFA-LRef-1313-T03-C 1
Mn EaFA-LRef-1313-T04-C 1
Mn EaFA-LRef-1313-T05-C 1
Mn EaFA-LRef-1313-T06-C 1
Mn EaFA-LRef-1313-T07-C 1
Mn EaFA-LRef-1313-T08-C 1
Mn EaFA-LRef-1313-T09-C 1
Mn EaFA-LRef-1313-B01-A 1
Mn EaFA-LRef-1313-B02-A 1
Mn EaFA-LRef-1313-B03-A 1
Mn EaFA-LRef-1313-B01-B 1
Mn EaFA-LRef-1313-B02-B 1
Mn EaFA-LRef-1313-B03-B 1
Mn EaFA-LRef-1313-B01-C 1
Mn EaFA-LRef-1313-B02-C 1
Mn EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.24E+01
2.68E+02
9.82E+02
1.17E+03
1.84E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.58E+01
2.19E+02
9.39E+02
1.15E+03
1.80E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.63E+01
1.93E+02
9.11E+02
1.15E+03
1.81E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.8E+00 2.0E+00 6.4E+00
1.00E+00 5.1E+00 2.0E+00 6.4E+00 10 325
1.00E+00 2.0E+00 2.0E+00 6.4E+00
1.00E+00 4.2E+00 2.0E+00 6.4E+00
3.24E+01 6.7E-01 2.0E+00 6.4E+00
2.68E+02 5.8E-01 2.0E+00 6.4E+00
9.82E+02 8.0E-01 2.0E+00 6.4E+00
1.17E+03 1.2E+00 2.0E+00 6.4E+00
1.84E+03 5.1E-01 2.0E+00 6.4E+00
1.00E+00 8.8E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+00 2.0E+00 6.4E+00 10 325
1.00E+00 4.9E+00 2.0E+00 6.4E+00
3.58E+01 1.1E+00 2.0E+00 6.4E+00
2.19E+02 1.2E+00 2.0E+00 6.4E+00
9.39E+02 1.3E+00 2.0E+00 6.4E+00
1.15E+03 9.5E-01 2.0E+00 6.4E+00
1.80E+03 2.5E-01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+00 2.0E+00 6.4E+00
1.00E+00 3.8E+00 2.0E+00 6.4E+00
1.00E+00 6.9E+00 2.0E+00 6.4E+00 10 325
3.63E+01 1.0E+00 2.0E+00 6.4E+00
1.93E+02 1.4E+00 2.0E+00 6.4E+00
9.11E+02 1.7E+00 2.0E+00 6.4E+00
1.15E+03 1.0E+00 2.0E+00 6.4E+00
1.81E+03 2.3E-01 2.0E+00 6.4E+00
1.00E+00 5.2E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+00 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 6.5E+00 2.0E+00 6.4E+00
1.00E+00 8.5E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 2.3E+00 2.0E+00 6.4E+00
1.00E+00 9.7E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.07E+03 95% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.02E+03 93% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.06E+03 94% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/109:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-308
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFA-LRef-1313-T01-A 1
Mg EaFA-LRef-1313-T02-A 1
Mg EaFA-LRef-1313-T03-A 1
Mg EaFA-LRef-1313-T04-A 1
Mg EaFA-LRef-1313-T05-A 1
Mg EaFA-LRef-1313-T06-A 1
Mg EaFA-LRef-1313-T07-A 1
Mg EaFA-LRef-1313-T08-A 1
Mg EaFA-LRef-1313-T09-A 1
Mg EaFA-LRef-1313-T01-B 1
Mg EaFA-LRef-1313-T02-B 1
Mg EaFA-LRef-1313-T03-B 1
Mg EaFA-LRef-1313-T04-B 1
Mg EaFA-LRef-1313-T05-B 1
Mg EaFA-LRef-1313-T06-B 1
Mg EaFA-LRef-1313-T07-B 1
Mg EaFA-LRef-1313-T08-B 1
Mg EaFA-LRef-1313-T09-B 1
Mg EaFA-LRef-1313-T01-C 1
Mg EaFA-LRef-1313-T02-C 1
Mg EaFA-LRef-1313-T03-C 1
Mg EaFA-LRef-1313-T04-C 1
Mg EaFA-LRef-1313-T05-C 1
Mg EaFA-LRef-1313-T06-C 1
Mg EaFA-LRef-1313-T07-C 1
Mg EaFA-LRef-1313-T08-C 1
Mg EaFA-LRef-1313-T09-C 1
Mg EaFA-LRef-1313-B01-A 1
Mg EaFA-LRef-1313-B02-A 1
Mg EaFA-LRef-1313-B03-A 1
Mg EaFA-LRef-1313-B01-B 1
Mg EaFA-LRef-1313-B02-B 1
Mg EaFA-LRef-1313-B03-B 1
Mg EaFA-LRef-1313-B01-C 1
Mg EaFA-LRef-1313-B02-C 1
Mg EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
1.11E+02
2.86E+03
5.10E+03
7.49E+03
8.90E+03
7.69E+03
1.40E+04
5.00E-01 U1/2
5.00E-01 U1/2
3.55E+02
1.84E+03
5.27E+03
7.03E+03
8.88E+03
7.75E+03
1.41E+04
5.00E-01 U1/2
5.00E-01 U1/2
4.15E+02
2.74E+03
5.20E+03
7.04E+03
8.48E+03
7.51 E+03
1.41E+04
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 4.9E+01 1.0E+00 3.2E+00
5.00E-01 2.9E+01 1.0E+00 3.2E+00 1000 100
1.11E+02 7.6E+00 1.0E+00 3.2E+00
2.86E+03 3.4E-01 1.0E+00 3.2E+00
5.10E+03 9.8E-01 1.0E+00 3.2E+00
7.49E+03 7.3E-01 1.0E+00 3.2E+00
8.90E+03 1.0E+00 1.0E+00 3.2E+00
7.69E+03 8.9E-01 1.0E+00 3.2E+00
1.40E+04 5.8E-01 1.0E+00 3.2E+00
5.00E-01 3.8E+01 1.0E+00 3.2E+00
5.00E-01 3.7E+00 1.0E+00 3.2E+00
3.55E+02 1.5E+00 1.0E+00 3.2E+00 1000 100
1.84E+03 1.2E+00 1.0E+00 3.2E+00
5.27E+03 1.1E+00 1.0E+00 3.2E+00
7.03E+03 8.8E-01 1.0E+00 3.2E+00
8.88E+03 3.7E-01 1.0E+00 3.2E+00
7.75E+03 4.2E-01 1.0E+00 3.2E+00
1.41E+04 1.7E+00 1.0E+00 3.2E+00
5.00E-01 5.4E+00 1.0E+00 3.2E+00
5.00E-01 6.3E+00 1.0E+00 3.2E+00
4.15E+02 3.1E+00 1.0E+00 3.2E+00
2.74E+03 7.9E-01 1.0E+00 3.2E+00 1000 100
5.20E+03 5.6E-01 1.0E+00 3.2E+00
7.04E+03 4.9E-01 1.0E+00 3.2E+00
8.48E+03 3.5E-01 1.0E+00 3.2E+00
7.51 E+03 1.4E+00 1.0E+00 3.2E+00
1.41E+04 1.2E+00 1.0E+00 3.2E+00
5.00E-01 1.8E+01 1.0E+00 3.2E+00
5.00E-01 3.2E+01 1.0E+00 3.2E+00
5.00E-01 7.9E+00 1.0E+00 3.2E+00
5.00E-01 4.4E+01 1.0E+00 3.2E+00
5.00E-01 8.7E+00 1.0E+00 3.2E+00
5.00E-01 7.4E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
1 .09E+03 1 09% VU ICP-OES 5/6/1 0 8:20 AM EPA Interlab LRef A-C 1 31 3-1 31 6 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.22E+03 86% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.63E+03 89% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-309
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo EaFA-LRef-1313-T01-A 1
Mo EaFA-LRef-1313-T02-A 1
Mo EaFA-LRef-1313-T03-A 1
Mo EaFA-LRef-1313-T04-A 1
Mo EaFA-LRef-1313-T05-A 1
Mo EaFA-LRef-1313-T06-A 1
Mo EaFA-LRef-1313-T07-A 1
Mo EaFA-LRef-1313-T08-A 1
Mo EaFA-LRef-1313-T09-A 1
Mo EaFA-LRef-1313-T01-B 1
Mo EaFA-LRef-1313-T02-B 1
Mo EaFA-LRef-1313-T03-B 1
Mo EaFA-LRef-1313-T04-B 1
Mo EaFA-LRef-1313-T05-B 1
Mo EaFA-LRef-1313-T06-B 1
Mo EaFA-LRef-1313-T07-B 1
Mo EaFA-LRef-1313-T08-B 1
Mo EaFA-LRef-1313-T09-B 1
Mo EaFA-LRef-1313-T01-C 1
Mo EaFA-LRef-1313-T02-C 1
Mo EaFA-LRef-1313-T03-C 1
Mo EaFA-LRef-1313-T04-C 1
Mo EaFA-LRef-1313-T05-C 1
Mo EaFA-LRef-1313-T06-C 1
Mo EaFA-LRef-1313-T07-C 1
Mo EaFA-LRef-1313-T08-C 1
Mo EaFA-LRef-1313-T09-C 1
Mo EaFA-LRef-1313-B01-A 1
Mo EaFA-LRef-1313-B02-A 1
Mo EaFA-LRef-1313-B03-A 1
Mo EaFA-LRef-1313-B01-B 1
Mo EaFA-LRef-1313-B02-B 1
Mo EaFA-LRef-1313-B03-B 1
Mo EaFA-LRef-1313-B01-C 1
Mo EaFA-LRef-1313-B02-C 1
Mo EaFA-LRef-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
3.92E+03
3.77E+03
3.83E+03
3.70E+03
3.49E+03
3.32E+03
5.52E+02
1.08E+02
3.34E+02
3.98E+03
3.85E+03
3.81 E+03
3.53E+03
3.44E+03
3.20E+03
7.19E+02
1.10E+02
3.52E+02
3.84E+03
3.73E+03
3.72E+03
3.59E+03
3.41 E+03
3.17E+03
5.34E+02
1.01E+02
3.04E+02
6.00E-01 U1/2
6.00E-01 U1/2
1.80E+00 E
6.00E-01 U1/2
6.00E-01 U1/2
4.99E+00
6.00E-01 U1/2
6.00E-01 U1/2
6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.92E+03 7.7E-01 1.2E+00 3.8E+00
3.77E+03 4.0E-01 1.2E+00 3.8E+00 10 325
3.83E+03 8.7E-01 1.2E+00 3.8E+00
3.70E+03 5.2E-01 1.2E+00 3.8E+00
3.49E+03 1.5E+00 1.2E+00 3.8E+00
3.32E+03 4.1E-01 1.2E+00 3.8E+00
5.52E+02 7.3E-01 1.2E+00 3.8E+00
1.08E+02 6.8E-01 1.2E+00 3.8E+00
3.34E+02 1.3E+00 1.2E+00 3.8E+00
3.98E+03 3.7E-01 1.2E+00 3.8E+00
3.85E+03 3.4E-01 1.2E+00 3.8E+00
3.81E+03 1.5E+00 1.2E+00 3.8E+00 10 325
3.53E+03 1.1E+00 1.2E+00 3.8E+00
3.44E+03 5.2E-01 1.2E+00 3.8E+00
3.20E+03 6.8E-01 1.2E+00 3.8E+00
7.19E+02 9.1E-01 1.2E+00 3.8E+00
1.10E+02 2.3E+00 1.2E+00 3.8E+00
3.52E+02 1.4E-01 1.2E+00 3.8E+00
3.84E+03 3.4E-01 1.2E+00 3.8E+00
3.73E+03 1.3E+00 1.2E+00 3.8E+00
3.72E+03 1.1E+00 1.2E+00 3.8E+00
3.59E+03 8.1E-01 1.2E+00 3.8E+00 10 325
3.41 E+03 8.8E-02 1.2E+00 3.8E+00
3.17E+03 6.6E-01 1.2E+00 3.8E+00
5.34E+02 1.3E+00 1.2E+00 3.8E+00
1.01E+02 2.1E+00 1.2E+00 3.8E+00
3.04E+02 1.3E+00 1.2E+00 3.8E+00
6.00E-01 8.7E+01 1.2E+00 3.8E+00
6.00E-01 3.8E+02 1.2E+00 3.8E+00
1.80E+00 3.7E+02 1.2E+00 3.8E+00
6.00E-01 5.5E+01 1.2E+00 3.8E+00
6.00E-01 2.8E+01 1.2E+00 3.8E+00
4.99E+00 4.3E+01 1.2E+00 3.8E+00
6.00E-01 4.1 E+03 1.2E+00 3.8E+00
6.00E-01 1.2E+02 1.2E+00 3.8E+00
6.00E-01 6.4E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
6.66E+03 89% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
6.92E+03 96% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
6.73E+03 97% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-310
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFA-LRef-1313-T01-A 1
Ni EaFA-LRef-1313-T02-A 1
Ni EaFA-LRef-1313-T03-A 1
Ni EaFA-LRef-1313-T04-A 1
Ni EaFA-LRef-1313-T05-A 1
Ni EaFA-LRef-1313-T06-A 1
Ni EaFA-LRef-1313-T07-A 1
Ni EaFA-LRef-1313-T08-A 1
Ni EaFA-LRef-1313-T09-A 1
Ni EaFA-LRef-1313-T01-B 1
Ni EaFA-LRef-1313-T02-B 1
Ni EaFA-LRef-1313-T03-B 1
Ni EaFA-LRef-1313-T04-B 1
Ni EaFA-LRef-1313-T05-B 1
Ni EaFA-LRef-1313-T06-B 1
Ni EaFA-LRef-1313-T07-B 1
Ni EaFA-LRef-1313-T08-B 1
Ni EaFA-LRef-1313-T09-B 1
Ni EaFA-LRef-1313-T01-C 1
Ni EaFA-LRef-1313-T02-C 1
Ni EaFA-LRef-1313-T03-C 1
Ni EaFA-LRef-1313-T04-C 1
Ni EaFA-LRef-1313-T05-C 1
Ni EaFA-LRef-1313-T06-C 1
Ni EaFA-LRef-1313-T07-C 1
Ni EaFA-LRef-1313-T08-C 1
Ni EaFA-LRef-1313-T09-C 1
Ni EaFA-LRef-1313-B01-A 1
Ni EaFA-LRef-1313-B02-A 1
Ni EaFA-LRef-1313-B03-A 1
Ni EaFA-LRef-1313-B01-B 1
Ni EaFA-LRef-1313-B02-B 1
Ni EaFA-LRef-1313-B03-B 1
Ni EaFA-LRef-1313-B01-C 1
Ni EaFA-LRef-1313-B02-C 1
Ni EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
6.83E+00
6.46E+01
6.03E+02
5.19E+02
7.62E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
5.92E+00
5.05E+01
5.46E+02
5.16E+02
7.50E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
4.26E+00 E
4.37E+01
5.75E+02
5.07E+02
7.58E+02
9.00E-01 U1/2
9.00E-01 U1/2
2.06E+01
9.00E-01 U1/2
9.00E-01 U1/2
3.75E+01
9.00E-01 U1/2
9.00E-01 U1/2
2.20E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 7.3E+01 1.8E+00 5.7E+00 10 325
9.00E-01 3.2E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
6.83E+00 6.1E+01 1.8E+00 5.7E+00
6.46E+01 2.3E+00 1.8E+00 5.7E+00
6.03E+02 1.0E+00 1.8E+00 5.7E+00
5.19E+02 1.4E+00 1.8E+00 5.7E+00
7.62E+02 5.9E-01 1.8E+00 5.7E+00
9.00E-01 1.1E+03 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00 10 325
9.00E-01 1.5E+02 1.8E+00 5.7E+00
5.92E+00 1.6E+01 1.8E+00 5.7E+00
5.05E+01 3.3E+00 1.8E+00 5.7E+00
5.46E+02 1.2E+00 1.8E+00 5.7E+00
5.16E+02 1.0E-01 1.8E+00 5.7E+00
7.50E+02 2.2E-01 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 2.9E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00 10 325
4.26E+00 4.4E+01 1.8E+00 5.7E+00
4.37E+01 2.7E+00 1.8E+00 5.7E+00
5.75E+02 1.8E+00 1.8E+00 5.7E+00
5.07E+02 1.6E+00 1.8E+00 5.7E+00
7.58E+02 2.5E-01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
2.06E+01 2.5E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 3.2E+02 1.8E+00 5.7E+00
3.75E+01 3.6E+00 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1 .8E+00 5.7E+00
9.00E-01 3.7E+02 1 .8E+00 5.7E+00
2.20E+01 4.3E+01 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.20E+03 98% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.08E+03 95% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.05E+03 94% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-311
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P EaFA-LRef-1313-T01-A 1
P EaFA-LRef-1313-T02-A 1
P EaFA-LRef-1313-T03-A 1
P EaFA-LRef-1313-T04-A 1
P EaFA-LRef-1313-T05-A 1
P EaFA-LRef-1313-T06-A 1
P EaFA-LRef-1313-T07-A 1
P EaFA-LRef-1313-T08-A 1
P EaFA-LRef-1313-T09-A 1
P EaFA-LRef-1313-T01-B 1
P EaFA-LRef-1313-T02-B 1
P EaFA-LRef-1313-T03-B 1
P EaFA-LRef-1313-T04-B 1
P EaFA-LRef-1313-T05-B 1
P EaFA-LRef-1313-T06-B 1
P EaFA-LRef-1313-T07-B 1
P EaFA-LRef-1313-T08-B 1
P EaFA-LRef-1313-T09-B 1
P EaFA-LRef-1313-T01-C 1
P EaFA-LRef-1313-T02-C 1
P EaFA-LRef-1313-T03-C 1
P EaFA-LRef-1313-T04-C 1
P EaFA-LRef-1313-T05-C 1
P EaFA-LRef-1313-T06-C 1
P EaFA-LRef-1313-T07-C 1
P EaFA-LRef-1313-T08-C 1
P EaFA-LRef-1313-T09-C 1
P EaFA-LRef-1313-B01-A 1
P EaFA-LRef-1313-B02-A 1
P EaFA-LRef-1313-B03-A 1
P EaFA-LRef-1313-B01-B 1
P EaFA-LRef-1313-B02-B 1
P EaFA-LRef-1313-B03-B 1
P EaFA-LRef-1313-B01-C 1
P EaFA-LRef-1313-B02-C 1
P EaFA-LRef-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
2.09E+02
3.72E+01
4.30E+01
8.54E+01
3.96E+01
1.63E+01
1.85E+00 U1/2
6.29E+01
2.42E+03
3.03E+02
2.44E+01
8.64E+01
8.09E+01
4.03E+01
2.66E+01
3.45E+01
7.11E+01
2.73E+03
2.35E+02
3.97E+01
7.16E+01
8.01E+01
3.93E+01
1.93E+01
1.74E+01
6.81E+01
2.35E+03
1.37E+01
8.36E+00 E
1.56E+01
1.85E+00 U1/2
4.22E+00 E
8.72E+00 E
1.24E+01
8.77E+00 E
2.14E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.09E+02 3.5E+00 3.7E+00 1.2E+01
3.72E+01 2.7E+01 3.7E+00 1.2E+01 1000 100
4.30E+01 4.4E+00 3.7E+00 1.2E+01
8.54E+01 1.9E+01 3.7E+00 1.2E+01
3.96E+01 2.9E+01 3.7E+00 1.2E+01
1.63E+01 4.8E+01 3.7E+00 1.2E+01
1.85E+00 2.0E+02 3.7E+00 1.2E+01
6.29E+01 9.0E+00 3.7E+00 1.2E+01
2.42E+03 3.0E-01 3.7E+00 1.2E+01
3.03E+02 3.7E+00 3.7E+00 1.2E+01
2.44E+01 2.3E+01 3.7E+00 1.2E+01
8.64E+01 5.8E+00 3.7E+00 1.2E+01 1000 100
8.09E+01 1.2E+01 3.7E+00 1.2E+01
4.03E+01 3.7E+01 3.7E+00 1.2E+01
2.66E+01 8.0E+01 3.7E+00 1.2E+01
3.45E+01 1.3E+01 3.7E+00 1.2E+01
7.11E+01 1.3E+01 3.7E+00 1.2E+01
2.73E+03 6.2E-01 3.7E+00 1.2E+01
2.35E+02 5.8E+00 3.7E+00 1.2E+01
3.97E+01 2.6E+01 3.7E+00 1 .2E+01
7.16E+01 1.5E+01 3.7E+00 1 .2E+01
8.01E+01 1.8E+01 3.7E+00 1 .2E+01 1000 100
3.93E+01 2.7E+01 3.7E+00 1 .2E+01
1.93E+01 1.1E+01 3.7E+00 1 .2E+01
1.74E+01 4.3E+01 3.7E+00 1 .2E+01
6.81 E+01 9.5E+00 3.7E+00 1 .2E+01
2.35E+03 7.7E-01 3.7E+00 1 .2E+01
1.37E+01 3.1 E+01 3.7E+00 1 .2E+01
8.36E+00 9.8E+01 3.7E+00 1 .2E+01
1.56E+01 1.1E+02 3.7E+00 1 .2E+01
1.85E+00 4.0E+01 3.7E+00 1 .2E+01
4.22E+00 7.8E+01 3.7E+00 1 .2E+01
8.72E+00 8.9E+01 3.7E+00 1.2E+01
1.24E+01 6.6E+01 3.7E+00 1.2E+01
8.77E+00 1.9E+02 3.7E+00 1.2E+01
2.14E+01 6.0E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.05E+03 102% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.15E+03 106% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
1 .09E+03 101% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-312
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K EaFA-LRef-1313-T01-A 1
K EaFA-LRef-1313-T02-A 1
K EaFA-LRef-1313-T03-A 1
K EaFA-LRef-1313-T04-A 1
K EaFA-LRef-1313-T05-A 1
K EaFA-LRef-1313-T06-A 1
K EaFA-LRef-1313-T07-A 1
K EaFA-LRef-1313-T08-A 1
K EaFA-LRef-1313-T09-A 1
K EaFA-LRef-1313-T01-B 1
K EaFA-LRef-1313-T02-B 1
K EaFA-LRef-1313-T03-B 1
K EaFA-LRef-1313-T04-B 1
K EaFA-LRef-1313-T05-B 1
K EaFA-LRef-1313-T06-B 1
K EaFA-LRef-1313-T07-B 1
K EaFA-LRef-1313-T08-B 1
K EaFA-LRef-1313-T09-B 1
K EaFA-LRef-1313-T01-C 1
K EaFA-LRef-1313-T02-C 1
K EaFA-LRef-1313-T03-C 1
K EaFA-LRef-1313-T04-C 1
K EaFA-LRef-1313-T05-C 1
K EaFA-LRef-1313-T06-C 1
K EaFA-LRef-1313-T07-C 1
K EaFA-LRef-1313-T08-C 1
K EaFA-LRef-1313-T09-C 1
K EaFA-LRef-1313-B01-A 1
K EaFA-LRef-1313-B02-A 1
K EaFA-LRef-1313-B03-A 1
K EaFA-LRef-1313-B01-B 1
K EaFA-LRef-1313-B02-B 1
K EaFA-LRef-1313-B03-B 1
K EaFA-LRef-1313-B01-C 1
K EaFA-LRef-1313-B02-C 1
K EaFA-LRef-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
1.72E+06
4.41 E+05
1.90E+05
1.35E+05
5.53E+04
2.50E+04
2.61 E+04
1.86E+04
2.21E+04
1.74E+06
4.50E+05
1.79E+05
1.31 E+05
5.45E+04
2.33E+04
2.48E+04
1.87E+04
2.17E+04
1.68E+06
3.92E+05
1.71 E+05
1.18E+05
5.01 E+04
2.28E+04
2.51 E+04
1.81 E+04
2.17E+04
8.00E-01 U1/2
2.83E+00 E
1.81E+06
8.00E-01 U1/2
1.24E+01
1.70E+06
8.00E-01 U1/2
3.25E+00 E
1.73E+06
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.72E+06 1.1E+00 1.6E+00 5.1E+00
4.41 E+05 1.7E+00 1.6E+00 5.1E+00 1000 100
1.90E+05 2.5E-01 1.6E+00 5.1E+00
1.35E+05 1.9E-01 1.6E+00 5.1E+00
5.53E+04 4.4E-01 1.6E+00 5.1E+00
2.50E+04 6.4E-01 1.6E+00 5.1E+00
2.61E+04 3.2E-01 1.6E+00 5.1E+00
1.86E+04 8.1E-01 1.6E+00 5.1E+00
2.21E+04 2.6E-01 1.6E+00 5.1E+00
1.74E+06 8.9E-01 1.6E+00 5.1E+00
4.50E+05 2.3E+00 1.6E+00 5.1E+00
1.79E+05 6.4E-01 1.6E+00 5.1E+00 1000 100
1.31E+05 8.2E-02 1.6E+00 5.1E+00
5.45E+04 7.6E-01 1.6E+00 5.1E+00
2.33E+04 5.9E-01 1.6E+00 5.1E+00
2.48E+04 8.1E-01 1.6E+00 5.1E+00
1.87E+04 7.3E-01 1.6E+00 5.1E+00
2.17E+04 5.2E-01 1.6E+00 5.1E+00
1.68E+06 7.9E-01 1.6E+00 5.1E+00
3.92E+05 7.4E-01 1.6E+00 5.1E+00
1.71 E+05 9.0E-01 1.6E+00 5.1E+00
1.18E+05 4.9E-01 1.6E+00 5.1E+00 1000 100
5.01 E+04 1.2E+00 1.6E+00 5.1E+00
2.28E+04 8.5E-01 1.6E+00 5.1E+00
2.51 E+04 8.3E-01 1.6E+00 5.1E+00
1.81 E+04 1.3E+00 1.6E+00 5.1E+00
2.17E+04 7.3E-01 1.6E+00 5.1E+00
8.00E-01 2.9E+02 1.6E+00 5.1E+00
2.83E+00 1.6E+02 1.6E+00 5.1E+00
1.81E+06 4.6E-01 1.6E+00 5.1E+00
8.00E-01 1.4E+02 1.6E+00 5.1E+00
1.24E+01 2.5E+01 1.6E+00 5.1E+00
1.70E+06 7.9E-01 1.6E+00 5.1E+00
8.00E-01 3.2E+02 1.6E+00 5.1E+00
3.25E+00 1.1E+02 1.6E+00 5.1E+00
1.73E+06 2.5E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
4.42E+05 93% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.80E+05 91% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
1 .19E+05 95% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-313
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se EaFA-LRef-1313-T01-A 1
Se EaFA-LRef-1313-T02-A 1
Se EaFA-LRef-1313-T03-A 1
Se EaFA-LRef-1313-T04-A 1
Se EaFA-LRef-1313-T05-A 1
Se EaFA-LRef-1313-T06-A 1
Se EaFA-LRef-1313-T07-A 1
Se EaFA-LRef-1313-T08-A 1
Se EaFA-LRef-1313-T09-A 1
Se EaFA-LRef-1313-T01-B 1
Se EaFA-LRef-1313-T02-B 1
Se EaFA-LRef-1313-T03-B 1
Se EaFA-LRef-1313-T04-B 1
Se EaFA-LRef-1313-T05-B 1
Se EaFA-LRef-1313-T06-B 1
Se EaFA-LRef-1313-T07-B 1
Se EaFA-LRef-1313-T08-B 1
Se EaFA-LRef-1313-T09-B 1
Se EaFA-LRef-1313-T01-C 1
Se EaFA-LRef-1313-T02-C 1
Se EaFA-LRef-1313-T03-C 1
Se EaFA-LRef-1313-T04-C 1
Se EaFA-LRef-1313-T05-C 1
Se EaFA-LRef-1313-T06-C 1
Se EaFA-LRef-1313-T07-C 1
Se EaFA-LRef-1313-T08-C 1
Se EaFA-LRef-1313-T09-C 1
Se EaFA-LRef-1313-B01-A 1
Se EaFA-LRef-1313-B02-A 1
Se EaFA-LRef-1313-B03-A 1
Se EaFA-LRef-1313-B01-B 1
Se EaFA-LRef-1313-B02-B 1
Se EaFA-LRef-1313-B03-B 1
Se EaFA-LRef-1313-B01-C 1
Se EaFA-LRef-1313-B02-C 1
Se EaFA-LRef-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
6.88E+03
5.60E+03
4.92E+03
4.01 E+03
1.64E+03
9.22E+02
2.30E+02
8.41 E+01
5.46E+02
6.80E+03
5.41 E+03
4.82E+03
3.78E+03
1.58E+03
8.42E+02
2.60E+02
9.37E+01
5.77E+02
6.81 E+03
5.46E+03
4.74E+03
3.66E+03
1.54E+03
9.26E+02
1.82E+02
5.67E+01
4.77E+02
7.50E+00 U1/2
7.50E+00 U1/2
3.59E+01 E
7.50E+00 U1/2
7.50E+00 U1/2
2.08E+01 E
7.50E+00 U1/2
7.50E+00 U1/2
3.55E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.88E+03 1.4E+00 1.5E+01 4.8E+01
5.60E+03 6.2E-01 1.5E+01 4.8E+01 10 325
4.92E+03 6.4E-01 1.5E+01 4.8E+01
4.01E+03 2.5E+00 1.5E+01 4.8E+01
1.64E+03 1.5E+00 1.5E+01 4.8E+01
9.22E+02 5.3E+00 1.5E+01 4.8E+01
2.30E+02 3.1E+00 1.5E+01 4.8E+01
8.41 E+01 2.5E+01 1.5E+01 4.8E+01
5.46E+02 5.7E+00 1.5E+01 4.8E+01
6.80E+03 1.5E+00 1.5E+01 4.8E+01
5.41 E+03 2.0E+00 1.5E+01 4.8E+01
4.82E+03 3.8E-01 1.5E+01 4.8E+01 10 325
3.78E+03 1.7E+00 1.5E+01 4.8E+01
1.58E+03 3.5E-01 1.5E+01 4.8E+01
8.42E+02 1.4E+00 1.5E+01 4.8E+01
2.60E+02 7.5E+00 1.5E+01 4.8E+01
9.37E+01 1.9E+00 1.5E+01 4.8E+01
5.77E+02 1.3E+00 1.5E+01 4.8E+01
6.81 E+03 1.7E-01 1.5E+01 4.8E+01
5.46E+03 3.6E-01 1.5E+01 4.8E+01
4.74E+03 1.5E+00 1.5E+01 4.8E+01
3.66E+03 8.2E-01 1.5E+01 4.8E+01 10 325
1.54E+03 2.5E+00 1.5E+01 4.8E+01
9.26E+02 5.3E+00 1.5E+01 4.8E+01
1.82E+02 1.0E+01 1.5E+01 4.8E+01
5.67E+01 2.7E+01 1.5E+01 4.8E+01
4.77E+02 1.1E+00 1.5E+01 4.8E+01
7.50E+00 7.5E+01 1.5E+01 4.8E+01
7.50E+00 6.9E+01 1.5E+01 4.8E+01
3.59E+01 1.5E+02 1.5E+01 4.8E+01
7.50E+00 4.6E+01 1.5E+01 4.8E+01
7.50E+00 6.2E+02 1.5E+01 4.8E+01
2.08E+01 1.1E+02 1.5E+01 4.8E+01
7.50E+00 8.1 E+01 1.5E+01 4.8E+01
7.50E+00 6.1 E+01 1.5E+01 4.8E+01
3.55E+01 4.9E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
8.90E+03 102% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
8.24E+03 105% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
6.90E+03 100% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-314
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si EaFA-LRef-1313-T01-A 1
Si EaFA-LRef-1313-T02-A 1
Si EaFA-LRef-1313-T03-A 1
Si EaFA-LRef-1313-T04-A 1
Si EaFA-LRef-1313-T05-A 1
Si EaFA-LRef-1313-T06-A 1
Si EaFA-LRef-1313-T07-A 1
Si EaFA-LRef-1313-T08-A 1
Si EaFA-LRef-1313-T09-A 1
Si EaFA-LRef-1313-T01-B 1
Si EaFA-LRef-1313-T02-B 1
Si EaFA-LRef-1313-T03-B 1
Si EaFA-LRef-1313-T04-B 1
Si EaFA-LRef-1313-T05-B 1
Si EaFA-LRef-1313-T06-B 1
Si EaFA-LRef-1313-T07-B 1
Si EaFA-LRef-1313-T08-B 1
Si EaFA-LRef-1313-T09-B 1
Si EaFA-LRef-1313-T01-C 1
Si EaFA-LRef-1313-T02-C 1
Si EaFA-LRef-1313-T03-C 1
Si EaFA-LRef-1313-T04-C 1
Si EaFA-LRef-1313-T05-C 1
Si EaFA-LRef-1313-T06-C 1
Si EaFA-LRef-1313-T07-C 1
Si EaFA-LRef-1313-T08-C 1
Si EaFA-LRef-1313-T09-C 1
Si EaFA-LRef-1313-B01-A 1
Si EaFA-LRef-1313-B02-A 1
Si EaFA-LRef-1313-B03-A 1
Si EaFA-LRef-1313-B01-B 1
Si EaFA-LRef-1313-B02-B 1
Si EaFA-LRef-1313-B03-B 1
Si EaFA-LRef-1313-B01-C 1
Si EaFA-LRef-1313-B02-C 1
Si EaFA-LRef-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
3.06E+04
3.76E+03
7.20E+02
2.78E+02
5.35E+02
1.43E+03
6.17E+03
1.80E+04
7.22E+04
3.55E+04
3.71 E+03
4.44E+02
2.75E+02
5.36E+02
1.20E+03
5.67E+03
1.80E+04
7.09E+04
2.82E+04
2.95E+03
4.64E+02
2.57E+02
5.67E+02
1.24E+03
5.90E+03
1.75E+04
7.20E+04
4.01 E+00
2.87E+02
5.24E+04
2.14E+01
2.93E+02
5.07E+04
2.54E+01
2.86E+02
1.65E+04
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.06E+04 1.4E-01 1.1 E+00 3.5E+00
3.76E+03 4.9E-01 1.1E+00 3.5E+00 1000 100
7.20E+02 6.5E-01 1.1 E+00 3.5E+00
2.78E+02 2.2E+00 1.1E+00 3.5E+00
5.35E+02 1.2E+00 1.1 E+00 3.5E+00
1.43E+03 2.4E-01 1.1 E+00 3.5E+00
6.17E+03 8.1E-01 1.1 E+00 3.5E+00
1.80E+04 4.9E-01 1.1 E+00 3.5E+00
7.22E+04 6.4E-01 1.1 E+00 3.5E+00
3.55E+04 1.1 E+00 1.1 E+00 3.5E+00
3.71 E+03 3.4E-01 1.1 E+00 3.5E+00
4.44E+02 7.0E-01 1.1E+00 3.5E+00 1000 100
2.75E+02 1.6E+00 1.1 E+00 3.5E+00
5.36E+02 5.2E-01 1.1 E+00 3.5E+00
1.20E+03 1.4E-01 1.1 E+00 3.5E+00
5.67E+03 2.7E-01 1.1 E+00 3.5E+00
1.80E+04 1.8E-01 1.1 E+00 3.5E+00
7.09E+04 3.5E-01 1.1 E+00 3.5E+00
2.82E+04 1.6E-01 1.1 E+00 3.5E+00
2.95E+03 6.4E-01 1.1 E+00 3.5E+00
4.64E+02 7.7E-01 1.1 E+00 3.5E+00
2.57E+02 1.9E+00 1.1 E+00 3.5E+00 1000 100
5.67E+02 3.8E-01 1.1 E+00 3.5E+00
1.24E+03 4.5E-01 1.1 E+00 3.5E+00
5.90E+03 9.0E-01 1.1 E+00 3.5E+00
1.75E+04 1.2E+00 1.1 E+00 3.5E+00
7.20E+04 4.9E-01 1.1 E+00 3.5E+00
4.01 E+00 1.1E+02 1.1 E+00 3.5E+00
2.87E+02 5.7E+00 1.1 E+00 3.5E+00
5.24E+04 3.0E-01 1.1 E+00 3.5E+00
2.14E+01 2.2E+01 1.1E+00 3.5E+00
2.93E+02 3.9E+00 1.1 E+00 3.5E+00
5.07E+04 1.2E+00 1.1 E+00 3.5E+00
2.54E+01 2.3E+00 1.1 E+00 3.5E+00
2.86E+02 4.5E+00 1.1 E+00 3.5E+00
1.65E+04 6.3E-01 1.1 E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
4.60E+03 84% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.29E+03 85% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.24E+03 99% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-315
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFA-LRef-1313-T01-A 1
Na EaFA-LRef-1313-T02-A 1
Na EaFA-LRef-1313-T03-A 1
Na EaFA-LRef-1313-T04-A 1
Na EaFA-LRef-1313-T05-A 1
Na EaFA-LRef-1313-T06-A 1
Na EaFA-LRef-1313-T07-A 1
Na EaFA-LRef-1313-T08-A 1
Na EaFA-LRef-1313-T09-A 1
Na EaFA-LRef-1313-T01-B 1
Na EaFA-LRef-1313-T02-B 1
Na EaFA-LRef-1313-T03-B 1
Na EaFA-LRef-1313-T04-B 1
Na EaFA-LRef-1313-T05-B 1
Na EaFA-LRef-1313-T06-B 1
Na EaFA-LRef-1313-T07-B 1
Na EaFA-LRef-1313-T08-B 1
Na EaFA-LRef-1313-T09-B 1
Na EaFA-LRef-1313-T01-C 1
Na EaFA-LRef-1313-T02-C 1
Na EaFA-LRef-1313-T03-C 1
Na EaFA-LRef-1313-T04-C 1
Na EaFA-LRef-1313-T05-C 1
Na EaFA-LRef-1313-T06-C 1
Na EaFA-LRef-1313-T07-C 1
Na EaFA-LRef-1313-T08-C 1
Na EaFA-LRef-1313-T09-C 1
Na EaFA-LRef-1313-B01-A 1
Na EaFA-LRef-1313-B02-A 1
Na EaFA-LRef-1313-B03-A 1
Na EaFA-LRef-1313-B01-B 1
Na EaFA-LRef-1313-B02-B 1
Na EaFA-LRef-1313-B03-B 1
Na EaFA-LRef-1313-B01-C 1
Na EaFA-LRef-1313-B02-C 1
Na EaFA-LRef-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
8.92E+03
6.80E+03
6.50E+03
6.39E+03
6.27E+03
6.45E+03
6.63E+03
4.51 E+03
3.85E+03
8.86E+03
6.77E+03
6.62E+03
6.19E+03
6.12E+03
6.03E+03
6.22E+03
4.48E+03
3.79E+03
8.94E+03
6.73E+03
6.48E+03
6.08E+03
6.04E+03
5.95E+03
6.25E+03
4.34E+03
3.75E+03
1.25E+00 U1/2
1.25E+00 U1/2
3.01 E+03
1.25E+00 U1/2
1.25E+00 U1/2
2.88E+03
1.25E+00 U1/2
1.25E+00 U1/2
3.65E+03
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.92E+03 5.8E-01 2.5E+00 8.0E+00
6.80E+03 5.0E-01 2.5E+00 8.0E+00 1000 100
6.50E+03 5.9E-01 2.5E+00 8.0E+00
6.39E+03 2.3E-01 2.5E+00 8.0E+00
6.27E+03 1.2E+00 2.5E+00 8.0E+00
6.45E+03 3.4E-01 2.5E+00 8.0E+00
6.63E+03 6.5E-01 2.5E+00 8.0E+00
4.51 E+03 5.5E-01 2.5E+00 8.0E+00
3.85E+03 3.2E-01 2.5E+00 8.0E+00
8.86E+03 1.2E+00 2.5E+00 8.0E+00
6.77E+03 8.0E-01 2.5E+00 8.0E+00
6.62E+03 1.4E+00 2.5E+00 8.0E+00 1000 100
6.19E+03 7.0E-01 2.5E+00 8.0E+00
6.12E+03 4.0E-01 2.5E+00 8.0E+00
6.03E+03 4.8E-01 2.5E+00 8.0E+00
6.22E+03 3.5E-01 2.5E+00 8.0E+00
4.48E+03 1.1E+00 2.5E+00 8.0E+00
3.79E+03 5.3E-01 2.5E+00 8.0E+00
8.94E+03 3.5E-01 2.5E+00 8.0E+00
6.73E+03 4.4E-01 2.5E+00 8.0E+00
6.48E+03 6.2E-01 2.5E+00 8.0E+00
6.08E+03 9.5E-01 2.5E+00 8.0E+00 1000 100
6.04E+03 2.2E-01 2.5E+00 8.0E+00
5.95E+03 1.0E-01 2.5E+00 8.0E+00
6.25E+03 1.7E+00 2.5E+00 8.0E+00
4.34E+03 1.9E+00 2.5E+00 8.0E+00
3.75E+03 6.4E-01 2.5E+00 8.0E+00
1.25E+00 7.9E-01 2.5E+00 8.0E+00
1.25E+00 2.3E+00 2.5E+00 8.0E+00
3.01 E+03 2.4E-01 2.5E+00 8.0E+00
1.25E+00 1.6E+00 2.5E+00 8.0E+00
1.25E+00 1.0E+00 2.5E+00 8.0E+00
2.88E+03 7.4E-01 2.5E+00 8.0E+00
1.25E+00 1.6E+00 2.5E+00 8.0E+00
1.25E+00 2.6E+00 2.5E+00 8.0E+00
3.65E+03 9.5E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
7.79E+03 99% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
7.58E+03 97% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
7.02E+03 94% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-316
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
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Sr
Sr
Sr
Sr
Sr
Sr
Sr
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Sample Dilution
EaFA-LRef-1313-T01-A 1
EaFA-LRef-1313-T02-A 1
EaFA-LRef-1313-T03-A 1
EaFA-LRef-1313-T04-A 1
EaFA-LRef-1313-T05-A 1
EaFA-LRef-1313-T06-A 1
EaFA-LRef-1313-T07-A 1
EaFA-LRef-1313-T08-A 1
EaFA-LRef-1313-T09-A 1
EaFA-LRef-1313-T01-B 1
EaFA-LRef-1313-T02-B 1
EaFA-LRef-1313-T03-B 1
EaFA-LRef-1313-T04-B 1
EaFA-LRef-1313-T05-B 1
EaFA-LRef-1313-T06-B 1
EaFA-LRef-1313-T07-B 1
EaFA-LRef-1313-T08-B 1
EaFA-LRef-1313-T09-B 1
EaFA-LRef-1313-T01-C 1
EaFA-LRef-1313-T02-C 1
EaFA-LRef-1313-T03-C 1
EaFA-LRef-1313-T04-C 1
EaFA-LRef-1313-T05-C 1
EaFA-LRef-1313-T06-C 1
EaFA-LRef-1313-T07-C 1
EaFA-LRef-1313-T08-C 1
EaFA-LRef-1313-T09-C 1
EaFA-LRef-1313-B01-A 1
EaFA-LRef-1313-B02-A 1
EaFA-LRef-1313-B03-A 1
EaFA-LRef-1313-B01-B 1
EaFA-LRef-1313-B02-B 1
EaFA-LRef-1313-B03-B 1
EaFA-LRef-1313-B01-C 1
EaFA-LRef-1313-B02-C 1
EaFA-LRef-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
9.16E+02
1.64E+03
1.96E+03
2.10E+03
2.30E+03
2.54E+03
3.09E+03
3.07E+03
5.56E+03
8.38E+02
1.66E+03
2.19E+03
2.04E+03
2.29E+03
2.42E+03
3.09E+03
3.04E+03
5.44E+03
9.44E+02
1.71E+03
2.02E+03
2.10E+03
2.28E+03
2.38E+03
2.95E+03
3.02E+03
5.55E+03
5.00E-01 U1/2
5.00E-01 U1/2
2.01 E+00 E
5.00E-01 U1/2
5.00E-01 U1/2
2.48E+00 E
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.16E+02 3.4E-01 1.0E+00 3.2E+00
1.64E+03 3.5E-01 1.0E+00 3.2E+00 1000 100
1.96E+03 1.1 E+00 1.0E+00 3.2E+00
2.10E+03 7.6E-01 1.0E+00 3.2E+00
2.30E+03 9.6E-01 1.0E+00 3.2E+00
2.54E+03 1.1 E+00 1.0E+00 3.2E+00
3.09E+03 2.9E-01 1.0E+00 3.2E+00
3.07E+03 1.2E+00 1.0E+00 3.2E+00
5.56E+03 8.5E-01 1.0E+00 3.2E+00
8.38E+02 1.1 E+00 1.0E+00 3.2E+00
1.66E+03 6.4E-01 1.0E+00 3.2E+00
2.19E+03 9.3E-01 1.0E+00 3.2E+00 1000 100
2.04E+03 5.7E-01 1.0E+00 3.2E+00
2.29E+03 1.1 E+00 1.0E+00 3.2E+00
2.42E+03 8.8E-01 1.0E+00 3.2E+00
3.09E+03 3.3E-01 1.0E+00 3.2E+00
3.04E+03 1.3E+00 1.0E+00 3.2E+00
5.44E+03 1.7E+00 1.0E+00 3.2E+00
9.44E+02 6.2E-01 1.0E+00 3.2E+00
1.71E+03 1.4E+00 1.0E+00 3.2E+00
2.02E+03 1.4E+00 1.0E+00 3.2E+00
2.10E+03 2.9E-01 1.0E+00 3.2E+00 1000 100
2.28E+03 6.8E-01 1.0E+00 3.2E+00
2.38E+03 7.8E-01 1.0E+00 3.2E+00
2.95E+03 9.6E-01 1.0E+00 3.2E+00
3.02E+03 1.7E+00 1.0E+00 3.2E+00
5.55E+03 1.4E+00 1.0E+00 3.2E+00
5.00E-01 1.7E+01 1.0E+00 3.2E+00
5.00E-01 3.5E+01 1.0E+00 3.2E+00
2.01 E+00 4.6E+01 1.0E+00 3.2E+00
5.00E-01 3.2E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
2.48E+00 2.9E+01 1.0E+00 3.2E+00
5.00E-01 5.6E+01 1.0E+00 3.2E+00
5.00E-01 2.8E+01 1.0E+00 3.2E+00
5.00E-01 1.0E+03 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
2.52E+03 88% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.06E+03 87% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.01E+03 91% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-317
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
1 ug/L
S EaFA-LRef-1313-T01-A 1 1.85E+05
S EaFA-LRef-1313-T02-A 1 1.62E+05
S EaFA-LRef-1313-T03-A 1 1.60E+05
S EaFA-LRef-1313-T04-A 1 1.63E+05
S EaFA-LRef-1313-T05-A 1 1.60E+05
S EaFA-LRef-1313-T06-A 1 1.64E+05
S EaFA-LRef-1313-T07-A 1 1.52E+05
S EaFA-LRef-1313-T08-A 1 1.04E+05
S EaFA-LRef-1313-T09-A 1 6.90E+04
S EaFA-LRef-1313-T01-B 1 1.88E+05
S EaFA-LRef-1313-T02-B 1 1.66E+05
S EaFA-LRef-1313-T03-B 1 1.65E+05
S EaFA-LRef-1313-T04-B 1 1.59E+05
S EaFA-LRef-1313-T05-B 1 1.59E+05
S EaFA-LRef-1313-T06-B 1 1.58E+05
S EaFA-LRef-1313-T07-B 1 1.50E+05
S EaFA-LRef-1313-T08-B 1 1.03E+05
S EaFA-LRef-1313-T09-B 1 6.93E+04
S EaFA-LRef-1313-T01-C 1 1.90E+05
S EaFA-LRef-1313-T02-C 1 1.63E+05
S EaFA-LRef-1313-T03-C 1 1.64E+05
S EaFA-LRef-1313-T04-C 1 1.62E+05
S EaFA-LRef-1313-T05-C 1 1.62E+05
S EaFA-LRef-1313-T06-C 1 1.60E+05
S EaFA-LRef-1313-T07-C 1 1.51E+05
S EaFA-LRef-1313-T08-C 1 1.03E+05
S EaFA-LRef-1313-T09-C 1 6.92E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.85E+05 3.8E-01 6.8E+00 2.2E+01
1.62E+05 6.9E-02 6.8E+00 2.2E+01 1000 100
1.60E+05 8.8E-01 6.8E+00 2.2E+01
1.63E+05 1.5E-01 6.8E+00 2.2E+01
1.60E+05 3.6E-01 6.8E+00 2.2E+01
1.64E+05 8.6E-01 6.8E+00 2.2E+01
1.52E+05 4.4E-01 6.8E+00 2.2E+01
1.04E+05 4.3E-01 6.8E+00 2.2E+01
6.90E+04 5.4E-01 6.8E+00 2.2E+01
1.88E+05 7.2E-01 6.8E+00 2.2E+01
1.66E+05 8.1E-01 6.8E+00 2.2E+01
1.65E+05 9.4E-01 6.8E+00 2.2E+01 1000 100
1.59E+05 6.9E-01 6.8E+00 2.2E+01
1.59E+05 5.3E-01 6.8E+00 2.2E+01
1.58E+05 3.0E-01 6.8E+00 2.2E+01
1.50E+05 6.2E-01 6.8E+00 2.2E+01
1.03E+05 1.6E-01 6.8E+00 2.2E+01
6.93E+04 2.0E-01 6.8E+00 2.2E+01
1.90E+05 3.2E-01 6.8E+00 2.2E+01
1.63E+05 3.0E-01 6.8E+00 2.2E+01
1.64E+05 5.0E-01 6.8E+00 2.2E+01
1.62E+05 2.1E-01 6.8E+00 2.2E+01 1000 100
1.62E+05 4.4E-01 6.8E+00 2.2E+01
1.60E+05 2.8E-01 6.8E+00 2.2E+01
1.51E+05 8.5E-01 6.8E+00 2.2E+01
1.03E+05 1.4E+00 6.8E+00 2.2E+01
6.92E+04 2.7E-01 6.8E+00 2.2E+01
S EaFA-LRef-1313-B01-A 1 3.40E+00 U1/2 3.40E+00 4.3E+01 6.8E+00 2.2E+01
S EaFA-LRef-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 5.2E+02 6.8E+00 2.2E+01
S EaFA-LRef-1313-B03-A 1 3.55E+01
3.55E+01 1.3E+01 6.8E+00 2.2E+01
S EaFA-LRef-1313-B01-B 1 3.40E+00 U1/2 3.40E+00 3.2E+01 6.8E+00 2.2E+01
S EaFA-LRef-1313-B02-B 1 3.40E+00 U1/2 3.40E+00 4.4E+01 6.8E+00 2.2E+01
S EaFA-LRef-1313-B03-B 1 3.28E+01
3.28E+01 1.3E+01 6.8E+00 2.2E+01
S EaFA-LRef-1313-B01-C 1 3.40E+00 U1/2 3.40E+00 2.3E+02 6.8E+00 2.2E+01
S EaFA-LRef-1313-B02-C 1 3.40E+00 U1/2 3.40E+00 1 .6E+02 6.8E+00 2.2E+01
S EaFA-LRef-1313-B03-C 1 4.09E+01
4.09E+01 3.8E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.63E+05 84% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
1.66E+05 82% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
1 .62E+05 87% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-318
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-LRef-1313-T01-A 1
Tl EaFA-LRef-1313-T02-A 1
Tl EaFA-LRef-1313-T03-A 1
Tl EaFA-LRef-1313-T04-A 1
Tl EaFA-LRef-1313-T05-A 1
Tl EaFA-LRef-1313-T06-A 1
Tl EaFA-LRef-1313-T07-A 1
Tl EaFA-LRef-1313-T08-A 1
Tl EaFA-LRef-1313-T09-A 1
Tl EaFA-LRef-1313-T01-B 1
Tl EaFA-LRef-1313-T02-B 1
Tl EaFA-LRef-1313-T03-B 1
Tl EaFA-LRef-1313-T04-B 1
Tl EaFA-LRef-1313-T05-B 1
Tl EaFA-LRef-1313-T06-B 1
Tl EaFA-LRef-1313-T07-B 1
Tl EaFA-LRef-1313-T08-B 1
Tl EaFA-LRef-1313-T09-B 1
Tl EaFA-LRef-1313-T01-C 1
Tl EaFA-LRef-1313-T02-C 1
Tl EaFA-LRef-1313-T03-C 1
Tl EaFA-LRef-1313-T04-C 1
Tl EaFA-LRef-1313-T05-C 1
Tl EaFA-LRef-1313-T06-C 1
Tl EaFA-LRef-1313-T07-C 1
Tl EaFA-LRef-1313-T08-C 1
Tl EaFA-LRef-1313-T09-C 1
Tl EaFA-LRef-1313-B01-A 1
Tl EaFA-LRef-1313-B02-A 1
Tl EaFA-LRef-1313-B03-A 1
Tl EaFA-LRef-1313-B01-B 1
Tl EaFA-LRef-1313-B02-B 1
Tl EaFA-LRef-1313-B03-B 1
Tl EaFA-LRef-1313-B01-C 1
Tl EaFA-LRef-1313-B02-C 1
Tl EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.25E+01
4.09E+01
7.87E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
5.63E+00 E
4.21E+01
6.79E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
1.28E+01 E
4.06E+01
7.14E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 7.5E+01 4.6E+00 1.5E+01
2.30E+00 1.2E+02 4.6E+00 1.5E+01 10 325
2.30E+00 2.6E+02 4.6E+00 1.5E+01
2.30E+00 7.8E+01 4.6E+00 1.5E+01
2.30E+00 2.8E+01 4.6E+00 1.5E+01
2.30E+00 4.1E+01 4.6E+00 1.5E+01
2.25E+01 7.2E+00 4.6E+00 1 .5E+01
4.09E+01 2.6E+01 4.6E+00 1 .5E+01
7.87E+01 3.3E+00 4.6E+00 1 .5E+01
2.30E+00 1.2E+02 4.6E+00 1.5E+01
2.30E+00 5.7E+01 4.6E+00 1.5E+01
2.30E+00 6.9E+01 4.6E+00 1.5E+01 10 325
2.30E+00 7.7E+02 4.6E+00 1.5E+01
2.30E+00 8.6E+01 4.6E+00 1.5E+01
2.30E+00 6.0E+01 4.6E+00 1.5E+01
5.63E+00 2.9E+02 4.6E+00 1 .5E+01
4.21 E+01 4.5E+00 4.6E+00 1 .5E+01
6.79E+01 3.7E+00 4.6E+00 1 .5E+01
2.30E+00 1.9E+02 4.6E+00 1 .5E+01
2.30E+00 3.1E+02 4.6E+00 1 .5E+01
2.30E+00 6.5E+01 4.6E+00 1 .5E+01
2.30E+00 9.1 E+01 4.6E+00 1 .5E+01 10 325
2.30E+00 6.9E+01 4.6E+00 1 .5E+01
2.30E+00 1.7E+02 4.6E+00 1 .5E+01
1.28E+01 1.3E+02 4.6E+00 1 .5E+01
4.06E+01 6.8E+00 4.6E+00 1 .5E+01
7.14E+01 1.4E+01 4.6E+00 1 .5E+01
2.30E+00 2.0E+01 4.6E+00 1 .5E+01
2.30E+00 1.2E+01 4.6E+00 1 .5E+01
2.30E+00 3.3E+02 4.6E+00 1 .5E+01
2.30E+00 2.8E+01 4.6E+00 1 .5E+01
2.30E+00 2.6E+01 4.6E+00 1 .5E+01
2.30E+00 4.5E+01 4.6E+00 1 .5E+01
2.30E+00 2.7E+01 4.6E+00 1 .5E+01
2.30E+00 1.2E+02 4.6E+00 1.5E+01
2.30E+00 5.1 E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.23E+03 99% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.16E+03 97% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.24E+03 100% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-319
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-LRef-1313-T01-A 1
Ti EaFA-LRef-1313-T02-A 1
Ti EaFA-LRef-1313-T03-A 1
Ti EaFA-LRef-1313-T04-A 1
Ti EaFA-LRef-1313-T05-A 1
Ti EaFA-LRef-1313-T06-A 1
Ti EaFA-LRef-1313-T07-A 1
Ti EaFA-LRef-1313-T08-A 1
Ti EaFA-LRef-1313-T09-A 1
Ti EaFA-LRef-1313-T01-B 1
Ti EaFA-LRef-1313-T02-B 1
Ti EaFA-LRef-1313-T03-B 1
Ti EaFA-LRef-1313-T04-B 1
Ti EaFA-LRef-1313-T05-B 1
Ti EaFA-LRef-1313-T06-B 1
Ti EaFA-LRef-1313-T07-B 1
Ti EaFA-LRef-1313-T08-B 1
Ti EaFA-LRef-1313-T09-B 1
Ti EaFA-LRef-1313-T01-C 1
Ti EaFA-LRef-1313-T02-C 1
Ti EaFA-LRef-1313-T03-C 1
Ti EaFA-LRef-1313-T04-C 1
Ti EaFA-LRef-1313-T05-C 1
Ti EaFA-LRef-1313-T06-C 1
Ti EaFA-LRef-1313-T07-C 1
Ti EaFA-LRef-1313-T08-C 1
Ti EaFA-LRef-1313-T09-C 1
Ti EaFA-LRef-1313-B01-A 1
Ti EaFA-LRef-1313-B02-A 1
Ti EaFA-LRef-1313-B03-A 1
Ti EaFA-LRef-1313-B01-B 1
Ti EaFA-LRef-1313-B02-B 1
Ti EaFA-LRef-1313-B03-B 1
Ti EaFA-LRef-1313-B01-C 1
Ti EaFA-LRef-1313-B02-C 1
Ti EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.73E+00 E
1.50E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.46E+00 E
1.69E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.30E+00 E
1.34E+03
1.00E+00 U1/2
1.00E+00 U1/2
4.15E+01
1.00E+00 U1/2
1.00E+00 U1/2
3.88E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.18E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.7E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00 10 325
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 9.2E+00 2.0E+00 6.4E+00
3.73E+00 1.0E+01 2.0E+00 6.4E+00
1.50E+03 1.2E+00 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 9.3E+00 2.0E+00 6.4E+00 10 325
1.00E+00 5.8E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 6.5E+01 2.0E+00 6.4E+00
1.00E+00 8.7E+00 2.0E+00 6.4E+00
3.46E+00 1.7E+01 2.0E+00 6.4E+00
1.69E+03 6.6E-01 2.0E+00 6.4E+00
1.00E+00 7.8E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+01 2.0E+00 6.4E+00
1.00E+00 8.6E+00 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00 10 325
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+00 2.0E+00 6.4E+00
3.30E+00 5.5E+00 2.0E+00 6.4E+00
1.34E+03 3.3E-01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 7.5E+01 2.0E+00 6.4E+00
4.15E+01 2.0E+00 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
1.00E+00 5.8E+01 2.0E+00 6.4E+00
3.88E+01 5.5E-01 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.18E+01 6.2E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.15E+03 97% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.12E+03 96% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.08E+03 95% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-320
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFA-LRef-1313-T01-A 1
V EaFA-LRef-1313-T02-A 1
V EaFA-LRef-1313-T03-A 1
V EaFA-LRef-1313-T04-A 1
V EaFA-LRef-1313-T05-A 1
V EaFA-LRef-1313-T06-A 1
V EaFA-LRef-1313-T07-A 1
V EaFA-LRef-1313-T08-A 1
V EaFA-LRef-1313-T09-A 1
V EaFA-LRef-1313-T01-B 1
V EaFA-LRef-1313-T02-B 1
V EaFA-LRef-1313-T03-B 1
V EaFA-LRef-1313-T04-B 1
V EaFA-LRef-1313-T05-B 1
V EaFA-LRef-1313-T06-B 1
V EaFA-LRef-1313-T07-B 1
V EaFA-LRef-1313-T08-B 1
V EaFA-LRef-1313-T09-B 1
V EaFA-LRef-1313-T01-C 1
V EaFA-LRef-1313-T02-C 1
V EaFA-LRef-1313-T03-C 1
V EaFA-LRef-1313-T04-C 1
V EaFA-LRef-1313-T05-C 1
V EaFA-LRef-1313-T06-C 1
V EaFA-LRef-1313-T07-C 1
V EaFA-LRef-1313-T08-C 1
V EaFA-LRef-1313-T09-C 1
V EaFA-LRef-1313-B01-A 1
V EaFA-LRef-1313-B02-A 1
V EaFA-LRef-1313-B03-A 1
V EaFA-LRef-1313-B01-B 1
V EaFA-LRef-1313-B02-B 1
V EaFA-LRef-1313-B03-B 1
V EaFA-LRef-1313-B01-C 1
V EaFA-LRef-1313-B02-C 1
V EaFA-LRef-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
5.21 E+03
2.74E+03
2.07E+03
8.32E+02
2.09E+02
1.58E+02
7.94E+01
8.18E+01
6.64E+03
5.24E+03
2.61 E+03
1.39E+03
7.86E+02
2.11E+02
1.50E+02
7.88E+01
8.33E+01
6.63E+03
4.92E+03
2.37E+03
1.51 E+03
6.84E+02
2.07E+02
1.57E+02
7.38E+01
7.99E+01
6.50E+03
4.59E+00 E
7.50E-01 U1/2
3.59E+00 E
2.12E+00 E
4.67E+00 E
3.97E+00 E
3.59E+00 E
2.28E+00 E
3.30E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.21 E+03 3.5E-01 1.5E+00 4.8E+00
2.74E+03 4.9E-01 1.5E+00 4.8E+00 10 325
2.07E+03 1.3E+00 1.5E+00 4.8E+00
8.32E+02 6.1E-01 1.5E+00 4.8E+00
2.09E+02 4.7E+00 1.5E+00 4.8E+00
1.58E+02 2.6E+00 1.5E+00 4.8E+00
7.94E+01 2.8E+00 1.5E+00 4.8E+00
8.18E+01 2.0E+00 1.5E+00 4.8E+00
6.64E+03 6.0E-01 1.5E+00 4.8E+00
5.24E+03 8.8E-01 1.5E+00 4.8E+00
2.61 E+03 1.4E+00 1.5E+00 4.8E+00
1.39E+03 1.4E+00 1.5E+00 4.8E+00 10 325
7.86E+02 1.8E+00 1.5E+00 4.8E+00
2.11E+02 2.0E+00 1.5E+00 4.8E+00
1.50E+02 4.2E+00 1.5E+00 4.8E+00
7.88E+01 3.7E+00 1.5E+00 4.8E+00
8.33E+01 8.3E-01 1.5E+00 4.8E+00
6.63E+03 4.0E-01 1.5E+00 4.8E+00
4.92E+03 7.2E-01 1.5E+00 4.8E+00
2.37E+03 1.4E+00 1.5E+00 4.8E+00
1.51 E+03 1.4E+00 1.5E+00 4.8E+00
6.84E+02 2.7E-01 1.5E+00 4.8E+00 10 325
2.07E+02 1.7E+00 1.5E+00 4.8E+00
1.57E+02 3.3E+00 1.5E+00 4.8E+00
7.38E+01 2.1E+00 1.5E+00 4.8E+00
7.99E+01 2.8E+00 1.5E+00 4.8E+00
6.50E+03 4.7E-01 1.5E+00 4.8E+00
4.59E+00 3.6E+01 1.5E+00 4.8E+00
7.50E-01 2.8E+02 1.5E+00 4.8E+00
3.59E+00 5.0E+01 1.5E+00 4.8E+00
2.12E+00 5.1E+01 1.5E+00 4.8E+00
4.67E+00 3.9E+01 1.5E+00 4.8E+00
3.97E+00 6.5E+01 1.5E+00 4.8E+00
3.59E+00 3.3E+01 1.5E+00 4.8E+00
2.28E+00 1.7E+01 1.5E+00 4.8E+00
3.30E+00 1.3E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
5.90E+03 97% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
5.21E+03 118% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.92E+03 100% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-321
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn EaFA-LRef-1313-T01-A 1
Zn EaFA-LRef-1313-T02-A 1
Zn EaFA-LRef-1313-T03-A 1
Zn EaFA-LRef-1313-T04-A 1
Zn EaFA-LRef-1313-T05-A 1
Zn EaFA-LRef-1313-T06-A 1
Zn EaFA-LRef-1313-T07-A 1
Zn EaFA-LRef-1313-T08-A 1
Zn EaFA-LRef-1313-T09-A 1
Zn EaFA-LRef-1313-T01-B 1
Zn EaFA-LRef-1313-T02-B 1
Zn EaFA-LRef-1313-T03-B 1
Zn EaFA-LRef-1313-T04-B 1
Zn EaFA-LRef-1313-T05-B 1
Zn EaFA-LRef-1313-T06-B 1
Zn EaFA-LRef-1313-T07-B 1
Zn EaFA-LRef-1313-T08-B 1
Zn EaFA-LRef-1313-T09-B 1
Zn EaFA-LRef-1313-T01-C 1
Zn EaFA-LRef-1313-T02-C 1
Zn EaFA-LRef-1313-T03-C 1
Zn EaFA-LRef-1313-T04-C 1
Zn EaFA-LRef-1313-T05-C 1
Zn EaFA-LRef-1313-T06-C 1
Zn EaFA-LRef-1313-T07-C 1
Zn EaFA-LRef-1313-T08-C 1
Zn EaFA-LRef-1313-T09-C 1
Zn EaFA-LRef-1313-B01-A 1
Zn EaFA-LRef-1313-B02-A 1
Zn EaFA-LRef-1313-B03-A 1
Zn EaFA-LRef-1313-B01-B 1
Zn EaFA-LRef-1313-B02-B 1
Zn EaFA-LRef-1313-B03-B 1
Zn EaFA-LRef-1313-B01-C 1
Zn EaFA-LRef-1313-B02-C 1
Zn EaFA-LRef-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
5.67E+01
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
1.14E+03
1.16E+03
1.63E+03
7.31E+01
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
8.63E+02
1.16E+03
1.63E+03
6.51E+01
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
1.06E+03
1.13E+03
1.62E+03
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.67E+01 1.6E+00 1.0E+00 3.2E+00
5.00E-01 9.7E+00 1.0E+00 3.2E+00 10 325
5.00E-01 3.0E+01 1.0E+00 3.2E+00
5.00E-01 1.6E+01 1.0E+00 3.2E+00
5.00E-01 5.4E+00 1.0E+00 3.2E+00
5.00E-01 2.0E+01 1.0E+00 3.2E+00
1.14E+03 9.5E-01 1.0E+00 3.2E+00
1.16E+03 1.0E+00 1.0E+00 3.2E+00
1.63E+03 6.2E-01 1.0E+00 3.2E+00
7.31 E+01 3.2E+00 1.0E+00 3.2E+00
5.00E-01 2.1E+02 1.0E+00 3.2E+00
5.00E-01 2.9E+00 1.0E+00 3.2E+00 10 325
5.00E-01 1.7E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
5.00E-01 3.6E+01 1.0E+00 3.2E+00
8.63E+02 3.4E-01 1.0E+00 3.2E+00
1.16E+03 1.1E+00 1.0E+00 3.2E+00
1.63E+03 5.0E-01 1.0E+00 3.2E+00
6.51 E+01 1.1E+00 1.0E+00 3.2E+00
5.00E-01 1.0E+02 1.0E+00 3.2E+00
5.00E-01 1.1 E+01 1.0E+00 3.2E+00
5.00E-01 7.5E+01 1.0E+00 3.2E+00 10 325
5.00E-01 1.0E+01 1.0E+00 3.2E+00
5.00E-01 9.5E+01 1.0E+00 3.2E+00
1.06E+03 6.3E-01 1.0E+00 3.2E+00
1.13E+03 1.7E+00 1.0E+00 3.2E+00
1.62E+03 7.0E-01 1.0E+00 3.2E+00
5.00E-01 4.6E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
5.00E-01 4.7E+01 1.0E+00 3.2E+00
5.00E-01 3.9E+00 1.0E+00 3.2E+00
5.00E-01 9.2E+00 1.0E+00 3.2E+00
5.00E-01 4.0E+04 1.0E+00 3.2E+00
5.00E-01 1.0E+01 1.0E+00 3.2E+00
5.00E-01 5.6E+00 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/10 8:18 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.80E+03 117% VU ICP-OES 5/6/10 8:20 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:22 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:23 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:25 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:26 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:28 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:30 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:31 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:41 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:43 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.25E+03 100% VU ICP-OES 5/6/10 8:45 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:46 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:48 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:49 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/108:51 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:53 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:54 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:04 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:06 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:08 AM EPA Interlab LRef A-C 1313-1316 EaFA
3.19E+03 98% VU ICP-OES 5/6/10 9:09 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:11 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:14 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:16 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:13 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:15 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:17 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:36 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:38 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:40 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 8:59 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:01 AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/6/10 9:03 AM EPA Interlab LRef A-C 1313-1316 EaFA
                                                                                                                                                                          1-322
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample
Sample Dilution Cone. Qualifier
ug/L
EaFA-LRef-1313-T01-D 1 4.02E+04
EaFA-LRef-1313-T02-D 1 3.49E+04
EaFA-LRef-1313-T03-D 1 2.55E+04
EaFA-LRef-1313-T04-D 1 1.24E+04
EaFA-LRef-1313-T05-D 1 1.14E+03
EaFA-LRef-1313-T06-D 1 2.26E+02
EaFA-LRef-1313-T07-D 1 2.73E+02
EaFA-LRef-1313-T08-D 1 3.09E+04
EaFA-LRef-1313-T09-D 1 1.27E+05
EaFA-LRef-1313-T01-E 1 3.86E+04
EaFA-LRef-1313-T02-E 1 3.52E+04
EaFA-LRef-1313-T03-E 1 2.67E+04
EaFA-LRef-1313-T04-E 1 1.44E+04
EaFA-LRef-1313-T05-E 1 1.14E+03
EaFA-LRef-1313-T06-E 1 2.74E+02
EaFA-LRef-1313-T07-E 1 1.96E+02
EaFA-LRef-1313-T08-E 1 3.07E+04
EaFA-LRef-1313-T09-E 1 1.24E+05
EaFA-LRef-1313-T01-F 1 3.99E+04
EaFA-LRef-1313-T02-F 1 3.45E+04
EaFA-LRef-1313-T03-F 1 2.62E+04
EaFA-LRef-1313-T04-F 1 1.40E+04
EaFA-LRef-1313-T05-F 1 1.30E+03
EaFA-LRef-1313-T06-F 1 2.14E+02
EaFA-LRef-1313-T07-F 1 2.77E+02
EaFA-LRef-1313-T08-F 1 3.12E+04
EaFA-LRef-1313-T09-F 1 1.25E+05
EaFA-LRef-1313-B01-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 2.50E+00 E
EaFA-LRef-1313-B03-D 1 1.27E+01
EaFA-LRef-1313-B01-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 1.62E+01
EaFA-LRef-1313-B03-E 1 2.77E+01
EaFA-LRef-1313-B01-F 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 2.24E+01
EaFA-LRef-1313-B03-F 1 4.07E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.02E+04 1.6E+00 1.0E+00 3.2E+00
3.49E+04 7.5E-01 1.0E+00 3.2E+00
2.55E+04 6.8E-01 1.0E+00 3.2E+00
1.24E+04 2.8E-01 1.0E+00 3.2E+00
1.14E+03 1.1E+00 1.0E+00 3.2E+00
2.26E+02 1.0E+00 1.0E+00 3.2E+00 1000 100
2.73E+02 9.3E-01 1.0E+00 3.2E+00
3.09E+04 6.2E-01 1.0E+00 3.2E+00
1.27E+05 1.6E+00 1.0E+00 3.2E+00
3.86E+04 3.9E-01 1.0E+00 3.2E+00
3.52E+04 7.1E-01 1.0E+00 3.2E+00
2.67E+04 3.0E-01 1.0E+00 3.2E+00
1.44E+04 5.0E-01 1.0E+00 3.2E+00
1.14E+03 1.3E-01 1.0E+00 3.2E+00
2.74E+02 1.2E+00 1.0E+00 3.2E+00
1.96E+02 3.0E+00 1.0E+00 3.2E+00 1000 100
3.07E+04 3.9E-01 1.0E+00 3.2E+00
1.24E+05 6.9E-01 1.0E+00 3.2E+00
3.99E+04 6.3E-01 1.0E+00 3.2E+00
3.45E+04 4.2E-01 1.0E+00 3.2E+00
2.62E+04 1.2E+00 1.0E+00 3.2E+00
1.40E+04 6.9E-01 1.0E+00 3.2E+00
1.30E+03 2.1E-01 1.0E+00 3.2E+00
2.14E+02 1.4E+00 1.0E+00 3.2E+00
2.77E+02 1.4E+00 1.0E+00 3.2E+00
3.12E+04 7.7E-01 1.0E+00 3.2E+00 1000 100
1.25E+05 8.8E-01 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
2.50E+00 1.1E+02 1.0E+00 3.2E+00
1.27E+01 1.3E+01 1.0E+00 3.2E+00
5.00E-01 7.4E+00 1.0E+00 3.2E+00
1.62E+01 2.4E+01 1.0E+00 3.2E+00
2.77E+01 4.2E+00 1.0E+00 3.2E+00
5.00E-01 1.6E+01 1.0E+00 3.2E+00
2.24E+01 2.4E+01 1.0E+00 3.2E+00
4.07E+01 1.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.28E+03 105% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.23E+03 103% VUICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.23E+04 105% VU ICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                                   1-323
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb
Sb
Sb
Sb
Sb
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Sb
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Sb
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Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
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Sb
Sb
Sb
Sb
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Sb
Sb
Sb
Sample Internal
Sample Dilution Cone. Qualifier Review
ug/L
EaFA-LRef-1313-T01-D 1 2.01E+02
EaFA-LRef-1313-T02-D 1 1.27E+02
EaFA-LRef-1313-T03-D 1 1.21E+02
EaFA-LRef-1313-T04-D 1 1.08E+02
EaFA-LRef-1313-T05-D 1 1.28E+02
EaFA-LRef-1313-T06-D 1 1.15E+02
EaFA-LRef-1313-T07-D 1 6.81 E+01
EaFA-LRef-1313-T08-D 1 2.59E+01
EaFA-LRef-1313-T09-D 1 3.75E+00 U1/2
EaFA-LRef-1313-T01-E 1 1.74E+02
EaFA-LRef-1313-T02-E 1 1.17E+02
EaFA-LRef-1313-T03-E 1 1.06E+02
EaFA-LRef-1313-T04-E 1 1.37E+02
EaFA-LRef-1313-T05-E 1 1.25E+02
EaFA-LRef-1313-T06-E 1 1.14E+02
EaFA-LRef-1313-T07-E 1 5.66E+01
EaFA-LRef-1313-T08-E 1 2.13E+01 E
EaFA-LRef-1313-T09-E 1 3.75E+00 U1/2
EaFA-LRef-1313-T01-F 1 1.88E+02
EaFA-LRef-1313-T02-F 1 1.03E+02
EaFA-LRef-1313-T03-F 1 1.29E+02
EaFA-LRef-1313-T04-F 1 1.46E+02
EaFA-LRef-1313-T05-F 1 1.30E+02
EaFA-LRef-1313-T06-F 1 1.34E+02
EaFA-LRef-1313-T07-F 1 6.09E+01
EaFA-LRef-1313-T08-F 1 1.90E+01 E
EaFA-LRef-1313-T09-F 1 3.75E+00 U1/2
EaFA-LRef-1313-B01-D 1 3.75E+00 U1/2
EaFA-LRef-1313-B02-D 1 3.75E+00 U1/2
EaFA-LRef-1313-B03-D 1 3.08E+01
EaFA-LRef-1313-B01-E 1 3.75E+00 U1/2
EaFA-LRef-1313-B02-E 1 3.75E+00 U1/2
EaFA-LRef-1313-B03-E 1 2.14E+01 E
EaFA-LRef-1313-B01-F 1 3.75E+00 U1/2
EaFA-LRef-1313-B02-F 1 3.75E+00 U1/2
EaFA-LRef-1313-B03-F 1 1.48E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01 E+02 2.5E+00 7.5E+00 2.4E+01
1.27E+02 1.7E+01 7.5E+00 2.4E+01
1.21 E+02 2.7E+01 7.5E+00 2.4E+01
1.08E+02 2.4E+01 7.5E+00 2.4E+01
1.28E+02 2.0E+01 7.5E+00 2.4E+01
1.15E+02 1.8E+01 7.5E+00 2.4E+01 10 325
6.81 E+01 6.7E+01 7.5E+00 2.4E+01
2.59E+01 4.9E+01 7.5E+00 2.4E+01
3.75E+00 1.1E+02 7.5E+00 2.4E+01
1.74E+02 2.0E+01 7.5E+00 2.4E+01
1.17E+02 1.3E+01 7.5E+00 2.4E+01
1.06E+02 1.2E+01 7.5E+00 2.4E+01
1.37E+02 3.3E+01 7.5E+00 2.4E+01
1.25E+02 3.2E+01 7.5E+00 2.4E+01
1.14E+02 2.8E+01 7.5E+00 2.4E+01
5.66E+01 4.5E+01 7.5E+00 2.4E+01 10 325
2.13E+01 9.0E+01 7.5E+00 2.4E+01
3.75E+00 1.1 E+02 7.5E+00 2.4E+01
1.88E+02 1.3E+01 7.5E+00 2.4E+01
1.03E+02 3.8E+01 7.5E+00 2.4E+01
1.29E+02 6.3E+00 7.5E+00 2.4E+01
1.46E+02 9.4E+00 7.5E+00 2.4E+01
1.30E+02 1.6E+01 7.5E+00 2.4E+01
1.34E+02 3.4E+00 7.5E+00 2.4E+01
6.09E+01 5.8E+01 7.5E+00 2.4E+01
1.90E+01 1.1E+01 7.5E+00 2.4E+01 10 325
3.75E+00 6.8E+01 7.5E+00 2.4E+01
3.75E+00 2.2E+02 7.5E+00 2.4E+01
3.75E+00 7.3E+02 7.5E+00 2.4E+01
3.08E+01 5.9E+01 7.5E+00 2.4E+01
3.75E+00 2.0E+02 7.5E+00 2.4E+01
3.75E+00 3.0E+02 7.5E+00 2.4E+01
2.14E+01 7.6E+01 7.5E+00 2.4E+01
3.75E+00 6.5E+02 7.5E+00 2.4E+01
3.75E+00 3.1 E+02 7.5E+00 2.4E+01
1.48E+01 2.1 E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.39E+03 101% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.37E+03 102% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.32E+03 102% VU ICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-324
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 9.35E+03
EaFA-LRef-1313-T02-D 1 8.30E+02
EaFA-LRef-1313-T03-D 1 8.57E+02
EaFA-LRef-1313-T04-D 1 4.69E+02
EaFA-LRef-1313-T05-D 1 1.41E+02
EaFA-LRef-1313-T06-D 1 7.20E+01
EaFA-LRef-1313-T07-D 1 3.74E+01
EaFA-LRef-1313-T08-D 1 8.52E+01
EaFA-LRef-1313-T09-D 1 1.40E+03
EaFA-LRef-1313-T01-E 1 8.64E+03
EaFA-LRef-1313-T02-E 1 7.66E+02
EaFA-LRef-1313-T03-E 1 8.89E+02
EaFA-LRef-1313-T04-E 1 4.60E+02
EaFA-LRef-1313-T05-E 1 1.58E+02
EaFA-LRef-1313-T06-E 1 8.41 E+01
EaFA-LRef-1313-T07-E 1 7.18E+01
EaFA-LRef-1313-T08-E 1 8.77E+01
EaFA-LRef-1313-T09-E 1 1.50E+03
EaFA-LRef-1313-T01-F 1 9.11E+03
EaFA-LRef-1313-T02-F 1 7.79E+02
EaFA-LRef-1313-T03-F 1 9.07E+02
EaFA-LRef-1313-T04-F 1 4.47E+02
EaFA-LRef-1313-T05-F 1 1.47E+02
EaFA-LRef-1313-T06-F 1 5.51 E+01
EaFA-LRef-1313-T07-F 1 4.73E+01
EaFA-LRef-1313-T08-F 1 9.08E+01
EaFA-LRef-1313-T09-F 1 1.47E+03
EaFA-LRef-1313-B01-D 1 5.50E+00 U1/2
EaFA-LRef-1313-B02-D 1 5.50E+00 U1/2
EaFA-LRef-1313-B03-D 1 2.35E+01 E
EaFA-LRef-1313-B01-E 1 5.50E+00 U1/2
EaFA-LRef-1313-B02-E 1 5.50E+00 U1/2
EaFA-LRef-1313-B03-E 1 2.17E+01 E
EaFA-LRef-1313-B01-F 1 5.50E+00 U1/2
EaFA-LRef-1313-B02-F 1 5.50E+00 U1/2
EaFA-LRef-1313-B03-F 1 4.31 E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.35E+03 1.6E+00 1.1 E+01 3.5E+01
8.30E+02 2.4E+00 1.1 E+01 3.5E+01
8.57E+02 2.9E+00 1.1 E+01 3.5E+01
4.69E+02 3.0E+00 1.1 E+01 3.5E+01
1.41E+02 2.7E+01 1.1 E+01 3.5E+01
7.20E+01 1.9E+01 1.1E+01 3.5E+01 10 325
3.74E+01 3.3E+01 1.1 E+01 3.5E+01
8.52E+01 5.4E+00 1.1 E+01 3.5E+01
1.40E+03 7.0E-01 1.1 E+01 3.5E+01
8.64E+03 7.3E-01 1.1 E+01 3.5E+01
7.66E+02 3.2E+00 1.1 E+01 3.5E+01
8.89E+02 3.9E+00 1.1 E+01 3.5E+01
4.60E+02 6.4E+00 1.1 E+01 3.5E+01
1.58E+02 9.6E+00 1.1 E+01 3.5E+01
8.41 E+01 2.1 E+01 1.1 E+01 3.5E+01
7.18E+01 2.3E+01 1.1E+01 3.5E+01 10 325
8.77E+01 2.0E+01 1.1 E+01 3.5E+01
1.50E+03 1.2E+00 1.1 E+01 3.5E+01
9.11E+03 1.1E+00 1.1 E+01 3.5E+01
7.79E+02 2.9E+00 1.1 E+01 3.5E+01
9.07E+02 2.4E+00 1.1 E+01 3.5E+01
4.47E+02 9.0E+00 1.1 E+01 3.5E+01
1.47E+02 1.7E+00 1.1 E+01 3.5E+01
5.51 E+01 3.0E+01 1.1 E+01 3.5E+01
4.73E+01 1.6E+01 1.1 E+01 3.5E+01
9.08E+01 1.3E+01 1.1E+01 3.5E+01 10 325
1.47E+03 1.2E-01 1.1 E+01 3.5E+01
5.50E+00 4.0E+02 1.1 E+01 3.5E+01
5.50E+00 2.5E+02 1.1 E+01 3.5E+01
2.35E+01 1.1E+02 1.1 E+01 3.5E+01
5.50E+00 1.4E+02 1.1 E+01 3.5E+01
5.50E+00 7.0E+01 1.1 E+01 3.5E+01
2.17E+01 2.8E+01 1.1 E+01 3.5E+01
5.50E+00 9.2E+01 1.1 E+01 3.5E+01
5.50E+00 5.9E+01 1.1 E+01 3.5E+01
4.31 E+01 4.5E+01 1.1 E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.26E+03 98% VU ICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.26E+03 98% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.38E+03 101% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-325
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B
B
B
B
B
B
B
B
B
B
B
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B
B
B
B
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B
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B
B
B
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B
B
B
B
B
Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 4.74E+03
EaFA-LRef-1313-T02-D 1 4.27E+03
EaFA-LRef-1313-T03-D 1 4.20E+03
EaFA-LRef-1313-T04-D 1 4.20E+03
EaFA-LRef-1313-T05-D 1 4.24E+03
EaFA-LRef-1313-T06-D 1 4.49E+03
EaFA-LRef-1313-T07-D 1 4.82E+03
EaFA-LRef-1313-T08-D 1 3.81E+03
EaFA-LRef-1313-T09-D 1 3.17E+03
EaFA-LRef-1313-T01-E 1 4.42E+03
EaFA-LRef-1313-T02-E 1 4.31 E+03
EaFA-LRef-1313-T03-E 1 4.34E+03
EaFA-LRef-1313-T04-E 1 4.35E+03
EaFA-LRef-1313-T05-E 1 4.36E+03
EaFA-LRef-1313-T06-E 1 4.49E+03
EaFA-LRef-1313-T07-E 1 4.91 E+03
EaFA-LRef-1313-T08-E 1 3.82E+03
EaFA-LRef-1313-T09-E 1 3.20E+03
EaFA-LRef-1313-T01-F 1 4.73E+03
EaFA-LRef-1313-T02-F 1 4.34E+03
EaFA-LRef-1313-T03-F 1 4.22E+03
EaFA-LRef-1313-T04-F 1 4.31 E+03
EaFA-LRef-1313-T05-F 1 4.44E+03
EaFA-LRef-1313-T06-F 1 4.45E+03
EaFA-LRef-1313-T07-F 1 4.89E+03
EaFA-LRef-1313-T08-F 1 3.84E+03
EaFA-LRef-1313-T09-F 1 3.21E+03
EaFA-LRef-1313-B01-D 1 1.56E+01
EaFA-LRef-1313-B02-D 1 4.07E+01
EaFA-LRef-1313-B03-D 1 1.32E+02
EaFA-LRef-1313-B01-E 1 1.87E+01
EaFA-LRef-1313-B02-E 1 4.19E+01
EaFA-LRef-1313-B03-E 1 1.66E+02
EaFA-LRef-1313-B01-F 1 1.98E+01
EaFA-LRef-1313-B02-F 1 4.26E+01
EaFA-LRef-1313-B03-F 1 1.93E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.74E+03 1.4E+00 1.0E+00 3.2E+00
4.27E+03 7.2E-01 1.0E+00 3.2E+00
4.20E+03 5.0E-01 1.0E+00 3.2E+00
4.20E+03 7.8E-01 1.0E+00 3.2E+00
4.24E+03 6.1E-01 1.0E+00 3.2E+00
4.49E+03 7.3E-01 1.0E+00 3.2E+00 1000 100
4.82E+03 9.9E-01 1.0E+00 3.2E+00
3.81 E+03 4.2E-01 1.0E+00 3.2E+00
3.17E+03 8.7E-02 1.0E+00 3.2E+00
4.42E+03 4.9E-01 1.0E+00 3.2E+00
4.31 E+03 3.9E-01 1.0E+00 3.2E+00
4.34E+03 1.2E+00 1.0E+00 3.2E+00
4.35E+03 6.0E-01 1.0E+00 3.2E+00
4.36E+03 8.5E-01 1.0E+00 3.2E+00
4.49E+03 5.1E-01 1.0E+00 3.2E+00
4.91E+03 8.6E-01 1.0E+00 3.2E+00 1000 100
3.82E+03 3.2E-01 1.0E+00 3.2E+00
3.20E+03 7.4E-01 1.0E+00 3.2E+00
4.73E+03 8.1E-01 1.0E+00 3.2E+00
4.34E+03 8.8E-01 1.0E+00 3.2E+00
4.22E+03 9.5E-01 1.0E+00 3.2E+00
4.31 E+03 4.7E-01 1.0E+00 3.2E+00
4.44E+03 1.2E+00 1.0E+00 3.2E+00
4.45E+03 1.3E+00 1.0E+00 3.2E+00
4.89E+03 1.3E-01 1.0E+00 3.2E+00
3.84E+03 3.8E-01 1.0E+00 3.2E+00 1000 100
3.21 E+03 3.7E-01 1.0E+00 3.2E+00
1.56E+01 7.4E+00 1.0E+00 3.2E+00
4.07E+01 3.6E+00 1.0E+00 3.2E+00
1.32E+02 7.3E-01 1.0E+00 3.2E+00
1.87E+01 5.3E+00 1.0E+00 3.2E+00
4.19E+01 3.0E+00 1.0E+00 3.2E+00
1.66E+02 8.9E-01 1.0E+00 3.2E+00
1.98E+01 8.2E+00 1.0E+00 3.2E+00
4.26E+01 2.8E+00 1.0E+00 3.2E+00
1.93E+02 7.4E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
5.30E+03 82% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
5.80E+03 90% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
4.88E+03 104% VU ICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-326
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Ba
Ba
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Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 1.02E+03
EaFA-LRef-1313-T02-D 1 9.34E+02
EaFA-LRef-1313-T03-D 1 7.96E+02
EaFA-LRef-1313-T04-D 1 4.02E+02
EaFA-LRef-1313-T05-D 1 2.56E+02
EaFA-LRef-1313-T06-D 1 2.45E+02
EaFA-LRef-1313-T07-D 1 2.62E+02
EaFA-LRef-1313-T08-D 1 2.33E+02
EaFA-LRef-1313-T09-D 1 8.94E+02
EaFA-LRef-1313-T01-E 1 1.01E+03
EaFA-LRef-1313-T02-E 1 9.06E+02
EaFA-LRef-1313-T03-E 1 8.30E+02
EaFA-LRef-1313-T04-E 1 5.18E+02
EaFA-LRef-1313-T05-E 1 2.77E+02
EaFA-LRef-1313-T06-E 1 2.46E+02
EaFA-LRef-1313-T07-E 1 2.67E+02
EaFA-LRef-1313-T08-E 1 2.29E+02
EaFA-LRef-1313-T09-E 1 8.75E+02
EaFA-LRef-1313-T01-F 1 1.03E+03
EaFA-LRef-1313-T02-F 1 9.02E+02
EaFA-LRef-1313-T03-F 1 7.42E+02
EaFA-LRef-1313-T04-F 1 4.94E+02
EaFA-LRef-1313-T05-F 1 2.81E+02
EaFA-LRef-1313-T06-F 1 2.29E+02
EaFA-LRef-1313-T07-F 1 2.57E+02
EaFA-LRef-1313-T08-F 1 2.05E+02
EaFA-LRef-1313-T09-F 1 8.70E+02
EaFA-LRef-1313-B01-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B01-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B01-F 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-F 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.02E+03 1.1E+00 1.0E+00 3.2E+00
9.34E+02 9.0E-01 1.0E+00 3.2E+00
7.96E+02 4.2E-01 1.0E+00 3.2E+00
4.02E+02 2.4E-01 1.0E+00 3.2E+00
2.56E+02 9.9E-01 1.0E+00 3.2E+00
2.45E+02 6.7E-01 1.0E+00 3.2E+00 10 325
2.62E+02 1.6E+00 1.0E+00 3.2E+00
2.33E+02 4.4E-01 1.0E+00 3.2E+00
8.94E+02 1.1E-01 1.0E+00 3.2E+00
1.01E+03 5.1E-01 1.0E+00 3.2E+00
9.06E+02 1.3E+00 1.0E+00 3.2E+00
8.30E+02 4.5E-01 1.0E+00 3.2E+00
5.18E+02 3.2E-01 1.0E+00 3.2E+00
2.77E+02 3.2E-01 1.0E+00 3.2E+00
2.46E+02 5.1E-01 1.0E+00 3.2E+00
2.67E+02 1.4E+00 1.0E+00 3.2E+00 10 325
2.29E+02 8.2E-01 1.0E+00 3.2E+00
8.75E+02 3.1E-01 1.0E+00 3.2E+00
1.03E+03 9.2E-01 1.0E+00 3.2E+00
9.02E+02 9.7E-02 1.0E+00 3.2E+00
7.42E+02 6.6E-01 1.0E+00 3.2E+00
4.94E+02 1.1E+00 1.0E+00 3.2E+00
2.81 E+02 7.5E-01 1.0E+00 3.2E+00
2.29E+02 1.1E+00 1.0E+00 3.2E+00
2.57E+02 5.7E-01 1.0E+00 3.2E+00
2.05E+02 1.1E+00 1.0E+00 3.2E+00 10 325
8.70E+02 3.7E-01 1.0E+00 3.2E+00
5.00E-01 1.8E-01 1.0E+00 3.2E+00
5.00E-01 2.7E-01 1.0E+00 3.2E+00
5.00E-01 4.9E-01 1.0E+00 3.2E+00
5.00E-01 6.5E-01 1.0E+00 3.2E+00
5.00E-01 2.4E-01 1.0E+00 3.2E+00
5.00E-01 6.5E-01 1.0E+00 3.2E+00
5.00E-01 9.1E-01 1.0E+00 3.2E+00
5.00E-01 1.2E+00 1.0E+00 3.2E+00
5.00E-01 5.8E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.05E+03 86% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.16E+03 89% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.20E+03 92% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-327
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-LRef-1313-T01-D 1 9.50E-01 U1/2
EaFA-LRef-1313-T02-D 1 9.50E-01 U1/2
EaFA-LRef-1313-T03-D 1 9.50E-01 U1/2
EaFA-LRef-1313-T04-D 1 9.50E-01 U1/2
EaFA-LRef-1313-T05-D 1 9.50E-01 U1/2
EaFA-LRef-1313-T06-D 1 9.50E-01 U1/2
EaFA-LRef-1313-T07-D 1 9.50E-01 U1/2
EaFA-LRef-1313-T08-D 1 1.21E+02
EaFA-LRef-1313-T09-D 1 2.64E+02
EaFA-LRef-1313-T01-E 1 9.50E-01 U1/2
EaFA-LRef-1313-T02-E 1 9.50E-01 U1/2
EaFA-LRef-1313-T03-E 1 9.50E-01 U1/2
EaFA-LRef-1313-T04-E 1 9.50E-01 U1/2
EaFA-LRef-1313-T05-E 1 9.50E-01 U1/2
EaFA-LRef-1313-T06-E 1 9.50E-01 U1/2
EaFA-LRef-1313-T07-E 1 9.50E-01 U1/2
EaFA-LRef-1313-T08-E 1 1.21E+02
EaFA-LRef-1313-T09-E 1 2.63E+02
EaFA-LRef-1313-T01-F 1 9.50E-01 U1/2
EaFA-LRef-1313-T02-F 1 9.50E-01 U1/2
EaFA-LRef-1313-T03-F 1 9.50E-01 U1/2
EaFA-LRef-1313-T04-F 1 9.50E-01 U1/2
EaFA-LRef-1313-T05-F 1 9.50E-01 U1/2
EaFA-LRef-1313-T06-F 1 9.50E-01 U1/2
EaFA-LRef-1313-T07-F 1 9.50E-01 U1/2
EaFA-LRef-1313-T08-F 1 1.22E+02
EaFA-LRef-1313-T09-F 1 2.63E+02
EaFA-LRef-1313-B01-D 1 9.50E-01 U1/2
EaFA-LRef-1313-B02-D 1 9.50E-01 U1/2
EaFA-LRef-1313-B03-D 1 9.50E-01 U1/2
EaFA-LRef-1313-B01-E 1 9.50E-01 U1/2
EaFA-LRef-1313-B02-E 1 9.50E-01 U1/2
EaFA-LRef-1313-B03-E 1 9.50E-01 U1/2
EaFA-LRef-1313-B01-F 1 9.50E-01 U1/2
EaFA-LRef-1313-B02-F 1 9.50E-01 U1/2
EaFA-LRef-1313-B03-F 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 7.4E+00 1.9E+00 6.0E+00
9.50E-01 2.9E+00 1.9E+00 6.0E+00
9.50E-01 8.1E+00 1.9E+00 6.0E+00
9.50E-01 1.0E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+01 1.9E+00 6.0E+00 10 325
9.50E-01 4.4E+01 1.9E+00 6.0E+00
1.21E+02 2.2E-01 1.9E+00 6.0E+00
2.64E+02 1.1E+00 1.9E+00 6.0E+00
9.50E-01 2.5E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 8.8E+00 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 4.2E+00 1.9E+00 6.0E+00
9.50E-01 8.2E+00 1.9E+00 6.0E+00
9.50E-01 5.9E+01 1.9E+00 6.0E+00 10 325
1.21E+02 3.1E-01 1.9E+00 6.0E+00
2.63E+02 5.8E-01 1.9E+00 6.0E+00
9.50E-01 4.1E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
9.50E-01 5.1E+00 1.9E+00 6.0E+00
9.50E-01 5.3E+00 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 8.8E+01 1.9E+00 6.0E+00
1.22E+02 7.8E-01 1.9E+00 6.0E+00 10 325
2.63E+02 1.4E-01 1.9E+00 6.0E+00
9.50E-01 5.0E+00 1.9E+00 6.0E+00
9.50E-01 5.0E+00 1.9E+00 6.0E+00
9.50E-01 4.5E+00 1.9E+00 6.0E+00
9.50E-01 7.2E+00 1.9E+00 6.0E+00
9.50E-01 9.9E+00 1.9E+00 6.0E+00
9.50E-01 3.8E+00 1.9E+00 6.0E+00
9.50E-01 6.4E+00 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00
9.50E-01 7.9E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.02E+03 93% VU ICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.10E+03 95% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.12E+03 92% VU ICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-328
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-LRef-1313-T01-D 1 1.10E+OOU1/2
EaFA-LRef-1313-T02-D 1 1.10E+OOU1/2
EaFA-LRef-1313-T03-D 1 1.10E+OOU1/2
EaFA-LRef-1313-T04-D 1 1.10E+OOU1/2
EaFA-LRef-1313-T05-D 1 1.10E+OOU1/2
EaFA-LRef-1313-T06-D 1 1.10E+OOU1/2
EaFA-LRef-1313-T07-D 1 2.97E+01
EaFA-LRef-1313-T08-D 1 2.73E+01
EaFA-LRef-1313-T09-D 1 2.92E+01
EaFA-LRef-1313-T01-E 1 1.10E+OOU1/2
EaFA-LRef-1313-T02-E 1 1.10E+OOU1/2
EaFA-LRef-1313-T03-E 1 1.10E+OOU1/2
EaFA-LRef-1313-T04-E 1 1.10E+00 U1/2
EaFA-LRef-1313-T05-E 1 1.10E+00 U1/2
EaFA-LRef-1313-T06-E 1 1.10E+00 U1/2
EaFA-LRef-1313-T07-E 1 2.69E+01
EaFA-LRef-1313-T08-E 1 2.65E+01
EaFA-LRef-1313-T09-E 1 2.83E+01
EaFA-LRef-1313-T01-F 1 1.10E+00 U1/2
EaFA-LRef-1313-T02-F 1 1.10E+00 U1/2
EaFA-LRef-1313-T03-F 1 1.10E+00 U1/2
EaFA-LRef-1313-T04-F 1 1.10E+00 U1/2
EaFA-LRef-1313-T05-F 1 1.10E+00 U1/2
EaFA-LRef-1313-T06-F 1 1.10E+00 U1/2
EaFA-LRef-1313-T07-F 1 2.85E+01
EaFA-LRef-1313-T08-F 1 2.71 E+01
EaFA-LRef-1313-T09-F 1 2.91 E+01
EaFA-LRef-1313-B01-D 1 1.10E+00 U1/2
EaFA-LRef-1313-B02-D 1 1.10E+00 U1/2
EaFA-LRef-1313-B03-D 1 1.10E+00 U1/2
EaFA-LRef-1313-B01-E 1 1.10E+00 U1/2
EaFA-LRef-1313-B02-E 1 1.10E+00 U1/2
EaFA-LRef-1313-B03-E 1 1.10E+00 U1/2
EaFA-LRef-1313-B01-F 1 1.10E+00 U1/2
EaFA-LRef-1313-B02-F 1 1.10E+00 U1/2
EaFA-LRef-1313-B03-F 1 1.10E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 5.6E+01 2.2E+00 7.0E+00
1.10E+00 2.3E+01 2.2E+00 7.0E+00
1.10E+00 4.9E+00 2.2E+00 7.0E+00
1.10E+00 2.6E+01 2.2E+00 7.0E+00
1.10E+00 5.2E+01 2.2E+00 7.0E+00
1.10E+00 5.2E+01 2.2E+00 7.0E+00 10 325
2.97E+01 8.8E-01 2.2E+00 7.0E+00
2.73E+01 1.7E+00 2.2E+00 7.0E+00
2.92E+01 1.6E+00 2.2E+00 7.0E+00
1.10E+00 1.8E+01 2.2E+00 7.0E+00
1.10E+00 6.3E+00 2.2E+00 7.0E+00
1.10E+00 9.4E+00 2.2E+00 7.0E+00
1.10E+00 2.2E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+01 2.2E+00 7.0E+00
1.10E+00 4.8E+01 2.2E+00 7.0E+00
2.69E+01 3.2E+00 2.2E+00 7.0E+00 10 325
2.65E+01 1.6E+00 2.2E+00 7.0E+00
2.83E+01 2.4E+00 2.2E+00 7.0E+00
1.10E+00 2.8E+01 2.2E+00 7.0E+00
1.10E+00 1.8E+01 2.2E+00 7.0E+00
1.10E+00 1.8E+01 2.2E+00 7.0E+00
1.10E+00 1.8E+01 2.2E+00 7.0E+00
1.10E+00 2.6E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+01 2.2E+00 7.0E+00
2.85E+01 7.7E-01 2.2E+00 7.0E+00
2.71 E+01 1.2E+00 2.2E+00 7.0E+00 10 325
2.91 E+01 1.1E+00 2.2E+00 7.0E+00
1.10E+00 1.4E+01 2.2E+00 7.0E+00
1.10E+00 3.3E+01 2.2E+00 7.0E+00
1.10E+00 3.5E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+01 2.2E+00 7.0E+00
1.10E+00 8.1E+00 2.2E+00 7.0E+00
1.10E+00 5.7E+01 2.2E+00 7.0E+00
1.10E+00 7.4E+00 2.2E+00 7.0E+00
1.10E+00 5.6E+01 2.2E+00 7.0E+00
1.10E+00 2.6E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.28E+03 101% VU ICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.26E+03 99% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.16E+03 96% VU ICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-329
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 1.15E+04
EaFA-LRef-1313-T02-D 1 4.57E+04
EaFA-LRef-1313-T03-D 1 8.77E+04
EaFA-LRef-1313-T04-D 1 1.09E+05
EaFA-LRef-1313-T05-D 1 1.29E+05
EaFA-LRef-1313-T06-D 1 1.43E+05
EaFA-LRef-1313-T07-D 1 1.58E+05
EaFA-LRef-1313-T08-D 1 1.36E+05
EaFA-LRef-1313-T09-D 1 1.37E+05
EaFA-LRef-1313-T01-E 1 1.11E+04
EaFA-LRef-1313-T02-E 1 4.68E+04
EaFA-LRef-1313-T03-E 1 9.11E+04
EaFA-LRef-1313-T04-E 1 1.10E+05
EaFA-LRef-1313-T05-E 1 1.33E+05
EaFA-LRef-1313-T06-E 1 1.43E+05
EaFA-LRef-1313-T07-E 1 1.59E+05
EaFA-LRef-1313-T08-E 1 1.34E+05
EaFA-LRef-1313-T09-E 1 1.35E+05
EaFA-LRef-1313-T01-F 1 1.15E+04
EaFA-LRef-1313-T02-F 1 4.74E+04
EaFA-LRef-1313-T03-F 1 8.93E+04
EaFA-LRef-1313-T04-F 1 1.09E+05
EaFA-LRef-1313-T05-F 1 1.36E+05
EaFA-LRef-1313-T06-F 1 1.41E+05
EaFA-LRef-1313-T07-F 1 1.56E+05
EaFA-LRef-1313-T08-F 1 1.37E+05
EaFA-LRef-1313-T09-F 1 1.36E+05
EaFA-LRef-1313-B01-D 1 3.36E+01
EaFA-LRef-1313-B02-D 1 2.62E+01
EaFA-LRef-1313-B03-D 1 2.32E+01
EaFA-LRef-1313-B01-E 1 2.44E+01
EaFA-LRef-1313-B02-E 1 4.14E+01
EaFA-LRef-1313-B03-E 1 1.45E+01
EaFA-LRef-1313-B01-F 1 2.30E+01
EaFA-LRef-1313-B02-F 1 2.73E+01
EaFA-LRef-1313-B03-F 1 1.01E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.15E+04 1.3E+00 2.6E+00 8.3E+00
4.57E+04 6.0E-01 2.6E+00 8.3E+00
8.77E+04 3.8E-01 2.6E+00 8.3E+00
1.09E+05 1.3E+00 2.6E+00 8.3E+00
1.29E+05 7.9E-01 2.6E+00 8.3E+00
1.43E+05 2.4E-01 2.6E+00 8.3E+00 1000 100
1.58E+05 7.3E-01 2.6E+00 8.3E+00
1.36E+05 7.1E-01 2.6E+00 8.3E+00
1.37E+05 5.0E-01 2.6E+00 8.3E+00
1.11E+04 2.4E-01 2.6E+00 8.3E+00
4.68E+04 5.9E-01 2.6E+00 8.3E+00
9.11E+04 9.5E-02 2.6E+00 8.3E+00
1.10E+05 5.5E-01 2.6E+00 8.3E+00
1.33E+05 9.2E-01 2.6E+00 8.3E+00
1.43E+05 8.4E-01 2.6E+00 8.3E+00
1.59E+05 9.8E-01 2.6E+00 8.3E+00 1000 100
1.34E+05 3.9E-01 2.6E+00 8.3E+00
1.35E+05 5.1E-01 2.6E+00 8.3E+00
1.15E+04 1.1E+00 2.6E+00 8.3E+00
4.74E+04 1.2E-01 2.6E+00 8.3E+00
8.93E+04 1.0E+00 2.6E+00 8.3E+00
1.09E+05 6.4E-01 2.6E+00 8.3E+00
1.36E+05 7.4E-01 2.6E+00 8.3E+00
1.41E+05 1.2E+00 2.6E+00 8.3E+00
1.56E+05 3.0E-01 2.6E+00 8.3E+00
1.37E+05 6.9E-01 2.6E+00 8.3E+00 1000 100
1.36E+05 2.9E-01 2.6E+00 8.3E+00
3.36E+01 2.6E+01 2.6E+00 8.3E+00
2.62E+01 8.1E+01 2.6E+00 8.3E+00
2.32E+01 3.9E+01 2.6E+00 8.3E+00
2.44E+01 5.3E+01 2.6E+00 8.3E+00
4.14E+01 6.4E+00 2.6E+00 8.3E+00
1.45E+01 4.3E+01 2.6E+00 8.3E+00
2.30E+01 2.0E+01 2.6E+00 8.3E+00
2.73E+01 2.1E+01 2.6E+00 8.3E+00
1.01E+01 1.1E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
1 .44E+05 89% VU ICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.60E+05 84% VUICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.38E+05 90% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-330
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 5.05E+02
EaFA-LRef-1313-T02-D 1 3.25E+02
EaFA-LRef-1313-T03-D 1 2.57E+02
EaFA-LRef-1313-T04-D 1 2.30E+02
EaFA-LRef-1313-T05-D 1 1.41E+02
EaFA-LRef-1313-T06-D 1 5.32E+01
EaFA-LRef-1313-T07-D 1 2.10E+00 E
EaFA-LRef-1313-T08-D 1 1.62E+02
EaFA-LRef-1313-T09-D 1 1.90E+03
EaFA-LRef-1313-T01-E 1 4.81E+02
EaFA-LRef-1313-T02-E 1 3.23E+02
EaFA-LRef-1313-T03-E 1 2.62E+02
EaFA-LRef-1313-T04-E 1 2.19E+02
EaFA-LRef-1313-T05-E 1 1.50E+02
EaFA-LRef-1313-T06-E 1 6.91E+01
EaFA-LRef-1313-T07-E 1 3.06E+00 E
EaFA-LRef-1313-T08-E 1 1.63E+02
EaFA-LRef-1313-T09-E 1 1.91E+03
EaFA-LRef-1313-T01-F 1 4.95E+02
EaFA-LRef-1313-T02-F 1 3.16E+02
EaFA-LRef-1313-T03-F 1 2.53E+02
EaFA-LRef-1313-T04-F 1 2.11E+02
EaFA-LRef-1313-T05-F 1 1.44E+02
EaFA-LRef-1313-T06-F 1 5.64E+01
EaFA-LRef-1313-T07-F 1 6.00E-01 U1/2
EaFA-LRef-1313-T08-F 1 1.64E+02
EaFA-LRef-1313-T09-F 1 1.92E+03
EaFA-LRef-1313-B01-D 1 6.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 6.00E-01 U1/2
EaFA-LRef-1313-B03-D 1 2.90E+00 E
EaFA-LRef-1313-B01-E 1 6.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 6.00E-01 U1/2
EaFA-LRef-1313-B03-E 1 2.30E+00 E
EaFA-LRef-1313-B01-F 1 6.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 6.00E-01 U1/2
EaFA-LRef-1313-B03-F 1 3.19E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.05E+02 2.2E+00 1.2E+00 3.8E+00
3.25E+02 6.5E-01 1.2E+00 3.8E+00
2.57E+02 4.7E-01 1.2E+00 3.8E+00
2.30E+02 1.3E+00 1.2E+00 3.8E+00
1.41E+02 4.4E-01 1.2E+00 3.8E+00
5.32E+01 4.1E+00 1.2E+00 3.8E+00 10 325
2.10E+00 5.8E+01 1.2E+00 3.8E+00
1.62E+02 7.9E-01 1.2E+00 3.8E+00
1.90E+03 8.0E-01 1.2E+00 3.8E+00
4.81 E+02 1.4E-01 1.2E+00 3.8E+00
3.23E+02 7.2E-01 1.2E+00 3.8E+00
2.62E+02 4.1E-01 1.2E+00 3.8E+00
2.19E+02 3.1E-01 1.2E+00 3.8E+00
1.50E+02 8.9E-01 1.2E+00 3.8E+00
6.91 E+01 2.1E+00 1.2E+00 3.8E+00
3.06E+00 4.3E+01 1.2E+00 3.8E+00 10 325
1.63E+02 4.1E-01 1.2E+00 3.8E+00
1.91E+03 2.7E-01 1.2E+00 3.8E+00
4.95E+02 9.1E-01 1.2E+00 3.8E+00
3.16E+02 3.2E-01 1.2E+00 3.8E+00
2.53E+02 1.7E+00 1.2E+00 3.8E+00
2.11 E+02 1.5E+00 1.2E+00 3.8E+00
1.44E+02 1.9E+00 1.2E+00 3.8E+00
5.64E+01 1.4E+00 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
1.64E+02 4.8E-01 1.2E+00 3.8E+00 10 325
1.92E+03 5.3E-01 1.2E+00 3.8E+00
6.00E-01 1.4E+01 1.2E+00 3.8E+00
6.00E-01 1.0E+02 1.2E+00 3.8E+00
2.90E+00 9.5E+01 1.2E+00 3.8E+00
6.00E-01 9.6E+01 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
2.30E+00 1.5E+01 1.2E+00 3.8E+00
6.00E-01 9.0E+01 1.2E+00 3.8E+00
6.00E-01 3.7E+00 1.2E+00 3.8E+00
3.19E+00 8.7E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.25E+03 98% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.21E+03 99% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.15E+03 92% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-331
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-LRef-1313-T01-D 1 9.00E-01 U1/2
EaFA-LRef-1313-T02-D 1 9.00E-01 U1/2
EaFA-LRef-1313-T03-D 1 9.00E-01 U1/2
EaFA-LRef-1313-T04-D 1 9.00E-01 U1/2
EaFA-LRef-1313-T05-D 1 3.39E+00 E
EaFA-LRef-1313-T06-D 1 2.20E+01
EaFA-LRef-1313-T07-D 1 2.43E+02
EaFA-LRef-1313-T08-D 1 2.09E+02
EaFA-LRef-1313-T09-D 1 4.17E+02
EaFA-LRef-1313-T01-E 1 9.00E-01 U1/2
EaFA-LRef-1313-T02-E 1 9.00E-01 U1/2
EaFA-LRef-1313-T03-E 1 9.00E-01 U1/2
EaFA-LRef-1313-T04-E 1 9.00E-01 U1/2
EaFA-LRef-1313-T05-E 1 2.84E+00 E
EaFA-LRef-1313-T06-E 1 1.64E+01
EaFA-LRef-1313-T07-E 1 2.34E+02
EaFA-LRef-1313-T08-E 1 2.11E+02
EaFA-LRef-1313-T09-E 1 4.11E+02
EaFA-LRef-1313-T01-F 1 9.00E-01 U1/2
EaFA-LRef-1313-T02-F 1 9.00E-01 U1/2
EaFA-LRef-1313-T03-F 1 9.00E-01 U1/2
EaFA-LRef-1313-T04-F 1 9.00E-01 U1/2
EaFA-LRef-1313-T05-F 1 1.91E+OOE
EaFA-LRef-1313-T06-F 1 2.73E+01
EaFA-LRef-1313-T07-F 1 2.37E+02
EaFA-LRef-1313-T08-F 1 2.12E+02
EaFA-LRef-1313-T09-F 1 4.15E+02
EaFA-LRef-1313-B01-D 1 9.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 9.00E-01 U1/2
EaFA-LRef-1313-B03-D 1 9.00E-01 U1/2
EaFA-LRef-1313-B01-E 1 9.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 9.00E-01 U1/2
EaFA-LRef-1313-B03-E 1 9.00E-01 U1/2
EaFA-LRef-1313-B01-F 1 9.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 9.00E-01 U1/2
EaFA-LRef-1313-B03-F 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.2E+02 1.8E+00 5.7E+00
9.00E-01 3.2E+02 1.8E+00 5.7E+00
9.00E-01 8.8E+01 1.8E+00 5.7E+00
9.00E-01 4.1E+01 1.8E+00 5.7E+00
3.39E+00 5.9E+01 1.8E+00 5.7E+00
2.20E+01 1.3E+01 1.8E+00 5.7E+00 10 325
2.43E+02 1.8E+00 1.8E+00 5.7E+00
2.09E+02 3.8E-01 1.8E+00 5.7E+00
4.17E+02 6.4E-01 1.8E+00 5.7E+00
9.00E-01 1.9E+04 1.8E+00 5.7E+00
9.00E-01 8.9E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
2.84E+00 1.1E+02 1.8E+00 5.7E+00
1.64E+01 1.7E+01 1.8E+00 5.7E+00
2.34E+02 2.0E+00 1.8E+00 5.7E+00 10 325
2.11E+02 1.8E+00 1.8E+00 5.7E+00
4.11E+02 6.6E-01 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 1.9E+03 1.8E+00 5.7E+00
1.91E+00 9.6E+01 1.8E+00 5.7E+00
2.73E+01 4.2E+00 1.8E+00 5.7E+00
2.37E+02 2.0E+00 1.8E+00 5.7E+00
2.12E+02 6.1E-01 1.8E+00 5.7E+00 10 325
4.15E+02 3.2E-01 1.8E+00 5.7E+00
9.00E-01 4.8E+01 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 6.7E+01 1.8E+00 5.7E+00
9.00E-01 2.3E+03 1.8E+00 5.7E+00
9.00E-01 4.7E+03 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 8.0E+03 1.8E+00 5.7E+00
9.00E-01 5.3E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.32E+03 102% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.21E+03 92% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.19E+03 92% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-332
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L
EaFA-LRef-1313-T01-D 1 2.05E+01
EaFA-LRef-1313-T02-D 1 1.85E+OOU1/2
EaFA-LRef-1313-T03-D 1 1.85E+OOU1/2
EaFA-LRef-1313-T04-D 1 1.85E+OOU1/2
EaFA-LRef-1313-T05-D 1 1.85E+OOU1/2
EaFA-LRef-1313-T06-D 1 1.85E+OOU1/2
EaFA-LRef-1313-T07-D 1 7.11E+01
EaFA-LRef-1313-T08-D 1 1.88E+03
EaFA-LRef-1313-T09-D 1 3.10E+03
EaFA-LRef-1313-T01-E 1 2.66E+01
EaFA-LRef-1313-T02-E 1 1.85E+OOU1/2
EaFA-LRef-1313-T03-E 1 1.85E+OOU1/2
EaFA-LRef-1313-T04-E 1 1.85E+OOU1/2
EaFA-LRef-1313-T05-E 1 1.85E+OOU1/2
EaFA-LRef-1313-T06-E 1 1.85E+00 U1/2
EaFA-LRef-1313-T07-E 1 4.91 E+01
EaFA-LRef-1313-T08-E 1 1.87E+03
EaFA-LRef-1313-T09-E 1 3.08E+03
EaFA-LRef-1313-T01-F 1 2.18E+01
EaFA-LRef-1313-T02-F 1 1.85E+OOU1/2
EaFA-LRef-1313-T03-F 1 1.85E+OOU1/2
EaFA-LRef-1313-T04-F 1 1.85E+OOU1/2
EaFA-LRef-1313-T05-F 1 1.85E+OOU1/2
EaFA-LRef-1313-T06-F 1 1.85E+OOU1/2
EaFA-LRef-1313-T07-F 1 7.05E+01
EaFA-LRef-1313-T08-F 1 1.89E+03
EaFA-LRef-1313-T09-F 1 3.11E+03
EaFA-LRef-1313-B01-D 1 1.85E+OOU1/2
EaFA-LRef-1313-B02-D 1 1.85E+OOU1/2
EaFA-LRef-1313-B03-D 1 1.85E+OOU1/2
EaFA-LRef-1313-B01-E 1 1.85E+OOU1/2
EaFA-LRef-1313-B02-E 1 1.85E+OOU1/2
EaFA-LRef-1313-B03-E 1 1.85E+OOU1/2
EaFA-LRef-1313-B01-F 1 1.85E+00 U1/2
EaFA-LRef-1313-B02-F 1 1.85E+00 U1/2
EaFA-LRef-1313-B03-F 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.05E+01 3.4E+01 3.7E+00 1.2E+01
1.85E+00 1.1E+02 3.7E+00 1.2E+01
1.85E+00 7.5E+02 3.7E+00 1.2E+01
1.85E+00 1.5E+02 3.7E+00 1.2E+01
1.85E+00 7.1E+01 3.7E+00 1.2E+01
1.85E+00 2.8E+02 3.7E+00 1.2E+01 10 325
7.11 E+01 3.5E+00 3.7E+00 1.2E+01
1.88E+03 7.2E-01 3.7E+00 1.2E+01
3.10E+03 4.4E-01 3.7E+00 1.2E+01
2.66E+01 1.6E+01 3.7E+00 1.2E+01
1.85E+00 3.9E+01 3.7E+00 1.2E+01
1.85E+00 4.2E+02 3.7E+00 1.2E+01
1.85E+00 5.0E+01 3.7E+00 1.2E+01
1.85E+00 7.2E+02 3.7E+00 1.2E+01
1.85E+00 2.1E+02 3.7E+00 1.2E+01
4.91 E+01 1.3E+01 3.7E+00 1.2E+01 10 325
1.87E+03 7.9E-01 3.7E+00 1.2E+01
3.08E+03 7.1E-01 3.7E+00 1.2E+01
2.18E+01 3.4E+01 3.7E+00 1.2E+01
1.85E+00 5.3E+02 3.7E+00 1.2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01
1.85E+00 2.0E+01 3.7E+00 1.2E+01
1.85E+00 1.7E+02 3.7E+00 1.2E+01
1.85E+00 1.0E+03 3.7E+00 1.2E+01
7.05E+01 6.9E+00 3.7E+00 1.2E+01
1.89E+03 3.7E-01 3.7E+00 1.2E+01 10 325
3.11E+03 4.3E-01 3.7E+00 1.2E+01
1.85E+00 4.5E+01 3.7E+00 1.2E+01
1.85E+00 6.4E+00 3.7E+00 1.2E+01
1.85E+00 8.2E+01 3.7E+00 1.2E+01
1.85E+00 1.9E+02 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.85E+00 6.9E+01 3.7E+00 1.2E+01
1.85E+00 1.8E+02 3.7E+00 1.2E+01
1.85E+00 8.3E+01 3.7E+00 1.2E+01
1.85E+00 8.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.01E+03 93% VU ICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.04E+03 92% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
5.43E+03 109% VU ICP-OES 5/6/1 0 1 0:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-333
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L
EaFA-LRef-1313-T01-D 1 5.26E+01
EaFA-LRef-1313-T02-D 1 2.05E+01
EaFA-LRef-1313-T03-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T04-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T05-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T06-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T07-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T08-D 1 4.12E+02
EaFA-LRef-1313-T09-D 1 3.31 E+04
EaFA-LRef-1313-T01-E 1 5.86E+01
EaFA-LRef-1313-T02-E 1 2.21E+01
EaFA-LRef-1313-T03-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T04-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T05-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T06-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T07-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T08-E 1 3.95E+02
EaFA-LRef-1313-T09-E 1 3.29E+04
EaFA-LRef-1313-T01-F 1 6.11E+01
EaFA-LRef-1313-T02-F 1 2.07E+01
EaFA-LRef-1313-T03-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T04-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T05-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T06-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T07-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T08-F 1 3.84E+02
EaFA-LRef-1313-T09-F 1 3.29E+04
EaFA-LRef-1313-B01-D 1 1.00E+OOU1/2
EaFA-LRef-1313-B02-D 1 2.64E+00 E
EaFA-LRef-1313-B03-D 1 4.36E+00 E
EaFA-LRef-1313-B01-E 1 1.00E+OOU1/2
EaFA-LRef-1313-B02-E 1 6.34E+00 E
EaFA-LRef-1313-B03-E 1 8.07E+00
EaFA-LRef-1313-B01-F 1 1.00E+OOU1/2
EaFA-LRef-1313-B02-F 1 7.98E+00
EaFA-LRef-1313-B03-F 1 4.07E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.26E+01 2.5E+00 2.0E+00 6.4E+00
2.05E+01 4.6E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 5.4E+00 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 4.3E+00 2.0E+00 6.4E+00
4.12E+02 5.8E-01 2.0E+00 6.4E+00
3.31 E+04 1.7E-01 2.0E+00 6.4E+00
5.86E+01 3.1E-01 2.0E+00 6.4E+00
2.21 E+01 2.1E+00 2.0E+00 6.4E+00
1.00E+00 9.9E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00 1000 100
3.95E+02 6.2E-01 2.0E+00 6.4E+00
3.29E+04 7.2E-01 2.0E+00 6.4E+00
6.11 E+01 1.8E+00 2.0E+00 6.4E+00
2.07E+01 2.3E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 7.8E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 5.5E+00 2.0E+00 6.4E+00
3.84E+02 4.4E-01 2.0E+00 6.4E+00 1000 100
3.29E+04 9.0E-01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
2.64E+00 1.7E+01 2.0E+00 6.4E+00
4.36E+00 7.1E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
6.34E+00 2.1 E+01 2.0E+00 6.4E+00
8.07E+00 5.2E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
7.98E+00 1.9E+01 2.0E+00 6.4E+00
4.07E+00 3.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.01E+03 101% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
9.56E+02 95% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.41E+03 102% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-334
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-LRef-1313-T01-D 1 3.40E+00 U1/2
EaFA-LRef-1313-T02-D 1 3.40E+00 U1/2
EaFA-LRef-1313-T03-D 1 3.40E+00 U1/2
EaFA-LRef-1313-T04-D 1 3.40E+00 U1/2
EaFA-LRef-1313-T05-D 1 3.40E+00 U1/2
EaFA-LRef-1313-T06-D 1 3.40E+00 U1/2
EaFA-LRef-1313-T07-D 1 3.40E+00 U1/2
EaFA-LRef-1313-T08-D 1 3.40E+00 U1/2
EaFA-LRef-1313-T09-D 1 5.66E+01
EaFA-LRef-1313-T01-E 1 3.40E+00 U1/2
EaFA-LRef-1313-T02-E 1 3.40E+00 U1/2
EaFA-LRef-1313-T03-E 1 3.40E+00 U1/2
EaFA-LRef-1313-T04-E 1 3.40E+00 U1/2
EaFA-LRef-1313-T05-E 1 3.40E+00 U1/2
EaFA-LRef-1313-T06-E 1 3.40E+00 U1/2
EaFA-LRef-1313-T07-E 1 3.40E+00 U1/2
EaFA-LRef-1313-T08-E 1 3.40E+00 U1/2
EaFA-LRef-1313-T09-E 1 6.26E+01
EaFA-LRef-1313-T01-F 1 3.40E+00 U1/2
EaFA-LRef-1313-T02-F 1 3.40E+00 U1/2
EaFA-LRef-1313-T03-F 1 3.40E+00 U1/2
EaFA-LRef-1313-T04-F 1 3.40E+00 U1/2
EaFA-LRef-1313-T05-F 1 3.40E+00 U1/2
EaFA-LRef-1313-T06-F 1 3.40E+00 U1/2
EaFA-LRef-1313-T07-F 1 3.40E+00 U1/2
EaFA-LRef-1313-T08-F 1 3.40E+00 U1/2
EaFA-LRef-1313-T09-F 1 6.15E+01
EaFA-LRef-1313-B01-D 1 3.40E+00 U1/2
EaFA-LRef-1313-B02-D 1 3.40E+00 U1/2
EaFA-LRef-1313-B03-D 1 3.40E+00 U1/2
EaFA-LRef-1313-B01-E 1 3.40E+00 U1/2
EaFA-LRef-1313-B02-E 1 3.40E+00 U1/2
EaFA-LRef-1313-B03-E 1 3.40E+00 U1/2
EaFA-LRef-1313-B01-F 1 3.40E+00 U1/2
EaFA-LRef-1313-B02-F 1 3.40E+00 U1/2
EaFA-LRef-1313-B03-F 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 4.3E+01 6.8E+00 2.2E+01
3.40E+00 1.6E+01 6.8E+00 2.2E+01
3.40E+00 8.5E+01 6.8E+00 2.2E+01
3.40E+00 4.9E+01 6.8E+00 2.2E+01
3.40E+00 2.3E+01 6.8E+00 2.2E+01
3.40E+00 4.6E+01 6.8E+00 2.2E+01 10 325
3.40E+00 3.7E+01 6.8E+00 2.2E+01
3.40E+00 1.6E+01 6.8E+00 2.2E+01
5.66E+01 1.4E+01 6.8E+00 2.2E+01
3.40E+00 6.2E+00 6.8E+00 2.2E+01
3.40E+00 2.2E+00 6.8E+00 2.2E+01
3.40E+00 5.3E+01 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.40E+00 7.9E+00 6.8E+00 2.2E+01
3.40E+00 2.5E+01 6.8E+00 2.2E+01
3.40E+00 3.2E+00 6.8E+00 2.2E+01 10 325
3.40E+00 1.6E+01 6.8E+00 2.2E+01
6.26E+01 1.4E+01 6.8E+00 2.2E+01
3.40E+00 2.6E+01 6.8E+00 2.2E+01
3.40E+00 3.0E+01 6.8E+00 2.2E+01
3.40E+00 1.5E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+01 6.8E+00 2.2E+01
3.40E+00 3.7E+01 6.8E+00 2.2E+01
3.40E+00 2.7E+01 6.8E+00 2.2E+01
3.40E+00 3.9E+01 6.8E+00 2.2E+01
3.40E+00 1.4E+01 6.8E+00 2.2E+01 10 325
6.15E+01 4.3E+00 6.8E+00 2.2E+01
3.40E+00 3.7E+01 6.8E+00 2.2E+01
3.40E+00 3.2E+00 6.8E+00 2.2E+01
3.40E+00 3.5E+01 6.8E+00 2.2E+01
3.40E+00 1.5E+01 6.8E+00 2.2E+01
3.40E+00 3.4E+01 6.8E+00 2.2E+01
3.40E+00 4.5E+01 6.8E+00 2.2E+01
3.40E+00 1.5E+01 6.8E+00 2.2E+01
3.40E+00 2.0E+01 6.8E+00 2.2E+01
3.40E+00 2.4E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.23E+03 99% VU ICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.13E+03 96% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.23E+03 99% VUICP-OES 5/6/1 0 1 0:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-335
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Sample 1
Sample Dilution Cone. Qualifier
1 1 ug/L 1
EaFA-LRef-1313-T01-D 1 1.59E+03
EaFA-LRef-1313-T02-D 1 2.16E+03
EaFA-LRef-1313-T03-D 1 2.41E+03
EaFA-LRef-1313-T04-D 1 2.01E+03
EaFA-LRef-1313-T05-D 1 2.82E+03
EaFA-LRef-1313-T06-D 1 3.01 E+03
EaFA-LRef-1313-T07-D 1 3.07E+03
EaFA-LRef-1313-T08-D 1 2.08E+03
EaFA-LRef-1313-T09-D 1 1.47E+03
EaFA-LRef-1313-T01-E 1 1.55E+03
EaFA-LRef-1313-T02-E 1 2.17E+03
EaFA-LRef-1313-T03-E 1 2.48E+03
EaFA-LRef-1313-T04-E 1 2.35E+03
EaFA-LRef-1313-T05-E 1 2.88E+03
EaFA-LRef-1313-T06-E 1 2.99E+03
EaFA-LRef-1313-T07-E 1 3.05E+03
EaFA-LRef-1313-T08-E 1 2.05E+03
EaFA-LRef-1313-T09-E 1 1.45E+03
EaFA-LRef-1313-T01-F 1 1.60E+03
EaFA-LRef-1313-T02-F 1 2.17E+03
EaFA-LRef-1313-T03-F 1 2.47E+03
EaFA-LRef-1313-T04-F 1 2.37E+03
EaFA-LRef-1313-T05-F 1 2.92E+03
EaFA-LRef-1313-T06-F 1 3.00E+03
EaFA-LRef-1313-T07-F 1 3.06E+03
EaFA-LRef-1313-T08-F 1 2.07E+03
EaFA-LRef-1313-T09-F 1 1.46E+03
EaFA-LRef-1313-B01-D 1 2.52E+00 E
EaFA-LRef-1313-B02-D 1 2.20E+00 E
EaFA-LRef-1313-B03-D 1 2.50E+00 E
EaFA-LRef-1313-B01-E 1 2.95E+00 E
EaFA-LRef-1313-B02-E 1 3.44E+00 E
EaFA-LRef-1313-B03-E 1 3.65E+00 E
EaFA-LRef-1313-B01-F 1 2.42E+00 E
EaFA-LRef-1313-B02-F 1 3.13E+00 E
EaFA-LRef-1313-B03-F 1 2.32E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+03 8.3E-01 1.9E+00 6.0E+00
2.16E+03 7.5E-01 1.9E+00 6.0E+00
2.41 E+03 4.6E-01 1.9E+00 6.0E+00
2.01 E+03 7.9E-01 1.9E+00 6.0E+00
2.82E+03 9.1E-01 1.9E+00 6.0E+00
3.01 E+03 4.7E-01 1.9E+00 6.0E+00 10 325
3.07E+03 9.3E-01 1.9E+00 6.0E+00
2.08E+03 1.7E-01 1.9E+00 6.0E+00
1.47E+03 8.4E-01 1.9E+00 6.0E+00
1.55E+03 3.9E-01 1.9E+00 6.0E+00
2.17E+03 4.7E-01 1.9E+00 6.0E+00
2.48E+03 2.9E-01 1.9E+00 6.0E+00
2.35E+03 7.6E-01 1.9E+00 6.0E+00
2.88E+03 2.4E-01 1.9E+00 6.0E+00
2.99E+03 3.0E-01 1.9E+00 6.0E+00
3.05E+03 7.1E-01 1.9E+00 6.0E+00 10 325
2.05E+03 4.3E-01 1.9E+00 6.0E+00
1.45E+03 8.4E-02 1.9E+00 6.0E+00
1.60E+03 1.0E+00 1.9E+00 6.0E+00
2.17E+03 9.9E-02 1.9E+00 6.0E+00
2.47E+03 6.7E-01 1.9E+00 6.0E+00
2.37E+03 6.0E-01 1.9E+00 6.0E+00
2.92E+03 5.2E-01 1.9E+00 6.0E+00
3.00E+03 6.0E-01 1.9E+00 6.0E+00
3.06E+03 8.5E-02 1.9E+00 6.0E+00
2.07E+03 4.9E-01 1.9E+00 6.0E+00 10 325
1.46E+03 2.1E-01 1.9E+00 6.0E+00
2.52E+00 4.5E+01 1.9E+00 6.0E+00
2.20E+00 4.5E+01 1.9E+00 6.0E+00
2.50E+00 6.9E+01 1.9E+00 6.0E+00
2.95E+00 4.5E+01 1.9E+00 6.0E+00
3.44E+00 1.2E+01 1.9E+00 6.0E+00
3.65E+00 7.6E+01 1.9E+00 6.0E+00
2.42E+00 8.5E+01 1.9E+00 6.0E+00
3.13E+00 1.6E+01 1.9E+00 6.0E+00
2.32E+00 7.4E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
6.17E+03 97% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
5.99E+03 91% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
4.98E+03 89% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-336
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-LRef-1313-T01-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T02-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T03-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T04-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T05-D 1 3.38E+01
EaFA-LRef-1313-T06-D 1 2.32E+02
EaFA-LRef-1313-T07-D 1 9.36E+02
EaFA-LRef-1313-T08-D 1 1.15E+03
EaFA-LRef-1313-T09-D 1 1.81E+03
EaFA-LRef-1313-T01-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T02-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T03-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T04-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T05-E 1 3.42E+01
EaFA-LRef-1313-T06-E 1 1.87E+02
EaFA-LRef-1313-T07-E 1 9.27E+02
EaFA-LRef-1313-T08-E 1 1.13E+03
EaFA-LRef-1313-T09-E 1 1.78E+03
EaFA-LRef-1313-T01-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T02-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T03-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T04-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T05-F 1 3.12E+01
EaFA-LRef-1313-T06-F 1 2.33E+02
EaFA-LRef-1313-T07-F 1 9.39E+02
EaFA-LRef-1313-T08-F 1 1.15E+03
EaFA-LRef-1313-T09-F 1 1.79E+03
EaFA-LRef-1313-B01-D 1 1.00E+OOU1/2
EaFA-LRef-1313-B02-D 1 1.00E+OOU1/2
EaFA-LRef-1313-B03-D 1 1.00E+OOU1/2
EaFA-LRef-1313-B01-E 1 1.00E+OOU1/2
EaFA-LRef-1313-B02-E 1 1.00E+OOU1/2
EaFA-LRef-1313-B03-E 1 1.00E+OOU1/2
EaFA-LRef-1313-B01-F 1 1.00E+OOU1/2
EaFA-LRef-1313-B02-F 1 1.00E+OOU1/2
EaFA-LRef-1313-B03-F 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.3E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+00 2.0E+00 6.4E+00
1.00E+00 6.1E+00 2.0E+00 6.4E+00
1.00E+00 4.3E+00 2.0E+00 6.4E+00
3.38E+01 1.7E+00 2.0E+00 6.4E+00
2.32E+02 1.2E+00 2.0E+00 6.4E+00 10 325
9.36E+02 2.7E-01 2.0E+00 6.4E+00
1.15E+03 2.8E-01 2.0E+00 6.4E+00
1.81E+03 5.3E-01 2.0E+00 6.4E+00
1.00E+00 6.6E+00 2.0E+00 6.4E+00
1.00E+00 5.6E+00 2.0E+00 6.4E+00
1.00E+00 7.0E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+00 2.0E+00 6.4E+00
3.42E+01 7.2E-01 2.0E+00 6.4E+00
1.87E+02 3.7E-01 2.0E+00 6.4E+00
9.27E+02 5.5E-01 2.0E+00 6.4E+00 10 325
1.13E+03 1.6E-01 2.0E+00 6.4E+00
1.78E+03 5.5E-01 2.0E+00 6.4E+00
1.00E+00 8.6E+00 2.0E+00 6.4E+00
1.00E+00 9.0E+00 2.0E+00 6.4E+00
1.00E+00 4.7E+00 2.0E+00 6.4E+00
1.00E+00 3.2E+00 2.0E+00 6.4E+00
3.12E+01 3.6E-01 2.0E+00 6.4E+00
2.33E+02 4.9E-01 2.0E+00 6.4E+00
9.39E+02 5.5E-01 2.0E+00 6.4E+00
1.15E+03 5.2E-01 2.0E+00 6.4E+00 10 325
1.79E+03 6.3E-01 2.0E+00 6.4E+00
1.00E+00 3.9E+00 2.0E+00 6.4E+00
1.00E+00 4.6E+00 2.0E+00 6.4E+00
1.00E+00 5.8E+00 2.0E+00 6.4E+00
1.00E+00 7.7E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+00 2.0E+00 6.4E+00
1.00E+00 5.1E+00 2.0E+00 6.4E+00
1.00E+00 6.7E+00 2.0E+00 6.4E+00
1.00E+00 3.8E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.21E+03 92% VU ICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.84E+03 90% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
4.05E+03 89% VU ICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-337
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-LRef-1313-T01-D 1 5.00E-01 U1/2
EaFA-LRef-1313-T02-D 1 5.00E-01 U1/2
EaFA-LRef-1313-T03-D 1 2.90E+02
EaFA-LRef-1313-T04-D 1 2.31E+03
EaFA-LRef-1313-T05-D 1 5.14E+03
EaFA-LRef-1313-T06-D 1 7.15E+03
EaFA-LRef-1313-T07-D 1 8.59E+03
EaFA-LRef-1313-T08-D 1 7.61 E+03
EaFA-LRef-1313-T09-D 1 1.39E+04
EaFA-LRef-1313-T01-E 1 5.00E-01 U1/2
EaFA-LRef-1313-T02-E 1 5.00E-01 U1/2
EaFA-LRef-1313-T03-E 1 2.19E+02
EaFA-LRef-1313-T04-E 1 2.81E+03
EaFA-LRef-1313-T05-E 1 5.37E+03
EaFA-LRef-1313-T06-E 1 7.05E+03
EaFA-LRef-1313-T07-E 1 8.64E+03
EaFA-LRef-1313-T08-E 1 7.60E+03
EaFA-LRef-1313-T09-E 1 1.40E+04
EaFA-LRef-1313-T01-F 1 5.00E-01 U1/2
EaFA-LRef-1313-T02-F 1 5.00E-01 U1/2
EaFA-LRef-1313-T03-F 1 2.65E+02
EaFA-LRef-1313-T04-F 1 2.92E+03
EaFA-LRef-1313-T05-F 1 5.46E+03
EaFA-LRef-1313-T06-F 1 7.11E+03
EaFA-LRef-1313-T07-F 1 8.59E+03
EaFA-LRef-1313-T08-F 1 7.71E+03
EaFA-LRef-1313-T09-F 1 1.40E+04
EaFA-LRef-1313-B01-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B01-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B01-F 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-F 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 4.6E+00 1.0E+00 3.2E+00
5.00E-01 2.0E+01 1.0E+00 3.2E+00
2.90E+02 2.3E+00 1.0E+00 3.2E+00
2.31 E+03 5.2E-01 1.0E+00 3.2E+00
5.14E+03 8.1E-01 1.0E+00 3.2E+00
7.15E+03 1.2E+00 1.0E+00 3.2E+00 1000 100
8.59E+03 1.5E+00 1.0E+00 3.2E+00
7.61 E+03 9.0E-02 1.0E+00 3.2E+00
1.39E+04 6.8E-01 1.0E+00 3.2E+00
5.00E-01 1.0E+01 1.0E+00 3.2E+00
5.00E-01 4.7E+02 1.0E+00 3.2E+00
2.19E+02 2.0E+00 1.0E+00 3.2E+00
2.81 E+03 8.4E-01 1.0E+00 3.2E+00
5.37E+03 1.0E+00 1.0E+00 3.2E+00
7.05E+03 2.0E-01 1.0E+00 3.2E+00
8.64E+03 8.4E-01 1.0E+00 3.2E+00 1000 100
7.60E+03 5.8E-01 1.0E+00 3.2E+00
1.40E+04 6.9E-01 1.0E+00 3.2E+00
5.00E-01 4.3E+01 1.0E+00 3.2E+00
5.00E-01 6.3E+00 1.0E+00 3.2E+00
2.65E+02 2.0E+00 1.0E+00 3.2E+00
2.92E+03 9.1E-01 1.0E+00 3.2E+00
5.46E+03 5.8E-01 1.0E+00 3.2E+00
7.11 E+03 3.9E-01 1.0E+00 3.2E+00
8.59E+03 4.9E-01 1.0E+00 3.2E+00
7.71 E+03 7.6E-01 1.0E+00 3.2E+00 1000 100
1.40E+04 1.7E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
5.00E-01 5.5E+01 1.0E+00 3.2E+00
5.00E-01 3.3E+01 1.0E+00 3.2E+00
5.00E-01 1.9E+01 1.0E+00 3.2E+00
5.00E-01 2.8E+01 1.0E+00 3.2E+00
5.00E-01 2.6E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
8.11E+03 96% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
9.74E+03 110% VUICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
8.63E+03 92% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-338
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 4.01E+03
EaFA-LRef-1313-T02-D 1 3.66E+03
EaFA-LRef-1313-T03-D 1 3.51 E+03
EaFA-LRef-1313-T04-D 1 3.48E+03
EaFA-LRef-1313-T05-D 1 3.29E+03
EaFA-LRef-1313-T06-D 1 3.11E+03
EaFA-LRef-1313-T07-D 1 5.51 E+02
EaFA-LRef-1313-T08-D 1 1.05E+02
EaFA-LRef-1313-T09-D 1 3.00E+02
EaFA-LRef-1313-T01-E 1 3.90E+03
EaFA-LRef-1313-T02-E 1 3.74E+03
EaFA-LRef-1313-T03-E 1 3.68E+03
EaFA-LRef-1313-T04-E 1 3.55E+03
EaFA-LRef-1313-T05-E 1 3.39E+03
EaFA-LRef-1313-T06-E 1 3.18E+03
EaFA-LRef-1313-T07-E 1 6.59E+02
EaFA-LRef-1313-T08-E 1 1.02E+02
EaFA-LRef-1313-T09-E 1 3.15E+02
EaFA-LRef-1313-T01-F 1 4.08E+03
EaFA-LRef-1313-T02-F 1 3.72E+03
EaFA-LRef-1313-T03-F 1 3.61 E+03
EaFA-LRef-1313-T04-F 1 3.52E+03
EaFA-LRef-1313-T05-F 1 3.50E+03
EaFA-LRef-1313-T06-F 1 3.11E+03
EaFA-LRef-1313-T07-F 1 5.74E+02
EaFA-LRef-1313-T08-F 1 9.94E+01
EaFA-LRef-1313-T09-F 1 3.09E+02
EaFA-LRef-1313-B01-D 1 6.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 6.00E-01 U1/2
EaFA-LRef-1313-B03-D 1 6.00E-01 U1/2
EaFA-LRef-1313-B01-E 1 6.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 6.00E-01 U1/2
EaFA-LRef-1313-B03-E 1 6.00E-01 U1/2
EaFA-LRef-1313-B01-F 1 6.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 6.00E-01 U1/2
EaFA-LRef-1313-B03-F 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.01 E+03 1.2E+00 1.2E+00 3.8E+00
3.66E+03 8.9E-01 1.2E+00 3.8E+00
3.51 E+03 7.9E-01 1.2E+00 3.8E+00
3.48E+03 5.8E-01 1.2E+00 3.8E+00
3.29E+03 9.1E-01 1.2E+00 3.8E+00
3.11E+03 4.0E-01 1.2E+00 3.8E+00 10 325
5.51 E+02 1.6E+00 1.2E+00 3.8E+00
1.05E+02 1.6E+00 1.2E+00 3.8E+00
3.00E+02 5.9E-01 1.2E+00 3.8E+00
3.90E+03 4.6E-01 1.2E+00 3.8E+00
3.74E+03 6.1E-01 1.2E+00 3.8E+00
3.68E+03 6.1E-01 1.2E+00 3.8E+00
3.55E+03 4.1E-01 1.2E+00 3.8E+00
3.39E+03 9.7E-01 1.2E+00 3.8E+00
3.18E+03 7.4E-01 1.2E+00 3.8E+00
6.59E+02 1.4E+00 1.2E+00 3.8E+00 10 325
1.02E+02 6.1E-01 1.2E+00 3.8E+00
3.15E+02 2.9E-01 1.2E+00 3.8E+00
4.08E+03 5.0E-01 1.2E+00 3.8E+00
3.72E+03 2.3E-01 1.2E+00 3.8E+00
3.61 E+03 8.5E-01 1.2E+00 3.8E+00
3.52E+03 1.2E+00 1.2E+00 3.8E+00
3.50E+03 3.7E-01 1.2E+00 3.8E+00
3.11 E+03 8.1E-01 1.2E+00 3.8E+00
5.74E+02 4.1E-01 1.2E+00 3.8E+00
9.94E+01 8.2E-01 1.2E+00 3.8E+00 10 325
3.09E+02 5.3E-01 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
6.00E-01 3.3E+01 1.2E+00 3.8E+00
6.00E-01 1.6E+03 1.2E+00 3.8E+00
6.00E-01 1.0E+02 1.2E+00 3.8E+00
6.00E-01 2.8E+01 1.2E+00 3.8E+00
6.00E-01 3.1 E+02 1.2E+00 3.8E+00
6.00E-01 7.9E+01 1.2E+00 3.8E+00
6.00E-01 2.2E+02 1.2E+00 3.8E+00
6.00E-01 3.0E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
6.07E+03 91% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.60E+03 91% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.59E+03 108% VU ICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-339
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-LRef-1313-T01-D 1 9.00E-01 U1/2
EaFA-LRef-1313-T02-D 1 9.00E-01 U1/2
EaFA-LRef-1313-T03-D 1 9.00E-01 U1/2
EaFA-LRef-1313-T04-D 1 9.00E-01 U1/2
EaFA-LRef-1313-T05-D 1 4.57E+00 E
EaFA-LRef-1313-T06-D 1 5.15E+01
EaFA-LRef-1313-T07-D 1 5.73E+02
EaFA-LRef-1313-T08-D 1 5.16E+02
EaFA-LRef-1313-T09-D 1 7.53E+02
EaFA-LRef-1313-T01-E 1 9.00E-01 U1/2
EaFA-LRef-1313-T02-E 1 9.00E-01 U1/2
EaFA-LRef-1313-T03-E 1 9.00E-01 U1/2
EaFA-LRef-1313-T04-E 1 9.00E-01 U1/2
EaFA-LRef-1313-T05-E 1 5.43E+00 E
EaFA-LRef-1313-T06-E 1 4.50E+01
EaFA-LRef-1313-T07-E 1 5.42E+02
EaFA-LRef-1313-T08-E 1 5.17E+02
EaFA-LRef-1313-T09-E 1 7.48E+02
EaFA-LRef-1313-T01-F 1 9.00E-01 U1/2
EaFA-LRef-1313-T02-F 1 9.00E-01 U1/2
EaFA-LRef-1313-T03-F 1 9.00E-01 U1/2
EaFA-LRef-1313-T04-F 1 9.00E-01 U1/2
EaFA-LRef-1313-T05-F 1 7.74E+00
EaFA-LRef-1313-T06-F 1 5.85E+01
EaFA-LRef-1313-T07-F 1 5.61 E+02
EaFA-LRef-1313-T08-F 1 5.16E+02
EaFA-LRef-1313-T09-F 1 7.50E+02
EaFA-LRef-1313-B01-D 1 9.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 9.00E-01 U1/2
EaFA-LRef-1313-B03-D 1 9.00E-01 U1/2
EaFA-LRef-1313-B01-E 1 9.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 9.00E-01 U1/2
EaFA-LRef-1313-B03-E 1 2.07E+00 E
EaFA-LRef-1313-B01-F 1 9.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 9.00E-01 U1/2
EaFA-LRef-1313-B03-F 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 7.1E+01 1.8E+00 5.7E+00
9.00E-01 2.7E+02 1.8E+00 5.7E+00
9.00E-01 4.3E+02 1.8E+00 5.7E+00
4.57E+00 7.6E+01 1.8E+00 5.7E+00
5.15E+01 1.0E+01 1.8E+00 5.7E+00 10 325
5.73E+02 2.3E+00 1.8E+00 5.7E+00
5.16E+02 6.7E-01 1.8E+00 5.7E+00
7.53E+02 6.9E-01 1.8E+00 5.7E+00
9.00E-01 9.3E+01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 4.5E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
5.43E+00 6.0E+01 1.8E+00 5.7E+00
4.50E+01 1.0E+00 1.8E+00 5.7E+00
5.42E+02 5.0E-01 1.8E+00 5.7E+00 10 325
5.17E+02 1.7E+00 1.8E+00 5.7E+00
7.48E+02 2.9E-01 1.8E+00 5.7E+00
9.00E-01 7.3E+02 1.8E+00 5.7E+00
9.00E-01 2.1 E+02 1.8E+00 5.7E+00
9.00E-01 4.9E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
7.74E+00 2.0E+01 1.8E+00 5.7E+00
5.85E+01 3.3E+00 1.8E+00 5.7E+00
5.61 E+02 1.4E+00 1.8E+00 5.7E+00
5.16E+02 6.9E-01 1.8E+00 5.7E+00 10 325
7.50E+02 8.1E-01 1.8E+00 5.7E+00
9.00E-01 6.0E+02 1.8E+00 5.7E+00
9.00E-01 8.6E+01 1.8E+00 5.7E+00
9.00E-01 1.1 E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
2.07E+00 3.9E+02 1.8E+00 5.7E+00
9.00E-01 7.1 E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 7.6E+03 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.14E+03 95% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.48E+03 90% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.47E+03 91% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-340
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample 1
Sample Dilution Cone. Qualifier
1 1 ug/L 1
EaFA-LRef-1313-T01-D 1 1.70E+02
EaFA-LRef-1313-T02-D 1 2.96E+01
EaFA-LRef-1313-T03-D 1 5.63E+01
EaFA-LRef-1313-T04-D 1 9.01 E+01
EaFA-LRef-1313-T05-D 1 2.67E+01
EaFA-LRef-1313-T06-D 1 1.32E+01
EaFA-LRef-1313-T07-D 1 1.12E+01 E
EaFA-LRef-1313-T08-D 1 6.93E+01
EaFA-LRef-1313-T09-D 1 2.52E+03
EaFA-LRef-1313-T01-E 1 1.55E+02
EaFA-LRef-1313-T02-E 1 3.72E+01
EaFA-LRef-1313-T03-E 1 7.46E+01
EaFA-LRef-1313-T04-E 1 7.39E+01
EaFA-LRef-1313-T05-E 1 3.93E+01
EaFA-LRef-1313-T06-E 1 2.23E+01
EaFA-LRef-1313-T07-E 1 2.13E+01
EaFA-LRef-1313-T08-E 1 7.81 E+01
EaFA-LRef-1313-T09-E 1 2.64E+03
EaFA-LRef-1313-T01-F 1 1.87E+02
EaFA-LRef-1313-T02-F 1 2.81E+01
EaFA-LRef-1313-T03-F 1 7.47E+01
EaFA-LRef-1313-T04-F 1 9.46E+01
EaFA-LRef-1313-T05-F 1 4.69E+01
EaFA-LRef-1313-T06-F 1 2.84E+01
EaFA-LRef-1313-T07-F 1 2.90E+01
EaFA-LRef-1313-T08-F 1 6.53E+01
EaFA-LRef-1313-T09-F 1 2.65E+03
EaFA-LRef-1313-B01-D 1 6.77E+00 E
EaFA-LRef-1313-B02-D 1 6.91 E+00 E
EaFA-LRef-1313-B03-D 1 3.11E+01
EaFA-LRef-1313-B01-E 1 9.02E+00 E
EaFA-LRef-1313-B02-E 1 1.85E+OOU1/2
EaFA-LRef-1313-B03-E 1 1.64E+01
EaFA-LRef-1313-B01-F 1 1.50E+01
EaFA-LRef-1313-B02-F 1 7.66E+00 E
EaFA-LRef-1313-B03-F 1 6.40E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.70E+02 1.1 E+01 3.7E+00 1.2E+01
2.96E+01 2.0E+01 3.7E+00 1.2E+01
5.63E+01 1.9E+01 3.7E+00 1.2E+01
9.01 E+01 1.1 E+01 3.7E+00 1.2E+01
2.67E+01 4.9E+01 3.7E+00 1.2E+01
1.32E+01 1.2E+01 3.7E+00 1.2E+01 1000 100
1.12E+01 1.6E+02 3.7E+00 1.2E+01
6.93E+01 9.2E+00 3.7E+00 1.2E+01
2.52E+03 4.4E-01 3.7E+00 1.2E+01
1.55E+02 3.9E+00 3.7E+00 1.2E+01
3.72E+01 3.7E+01 3.7E+00 1.2E+01
7.46E+01 1.9E+01 3.7E+00 1.2E+01
7.39E+01 1.6E+01 3.7E+00 1.2E+01
3.93E+01 1.8E+01 3.7E+00 1.2E+01
2.23E+01 3.6E+01 3.7E+00 1.2E+01
2.13E+01 4.5E+01 3.7E+00 1.2E+01 1000 100
7.81 E+01 6.9E+00 3.7E+00 1.2E+01
2.64E+03 2.0E-01 3.7E+00 1.2E+01
1.87E+02 5.8E+00 3.7E+00 1.2E+01
2.81 E+01 1.9E+01 3.7E+00 1.2E+01
7.47E+01 1.1 E+01 3.7E+00 1.2E+01
9.46E+01 2.1 E+00 3.7E+00 1.2E+01
4.69E+01 1.2E+01 3.7E+00 1.2E+01
2.84E+01 1.7E+01 3.7E+00 1.2E+01
2.90E+01 6.5E+00 3.7E+00 1.2E+01
6.53E+01 1.8E+00 3.7E+00 1.2E+01 1000 100
2.65E+03 6.8E-01 3.7E+00 1.2E+01
6.77E+00 1.2E+02 3.7E+00 1.2E+01
6.91 E+00 6.3E+01 3.7E+00 1.2E+01
3.11 E+01 2.1 E+01 3.7E+00 1.2E+01
9.02E+00 6.6E+01 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.64E+01 2.3E+01 3.7E+00 1.2E+01
1.50E+01 3.4E+01 3.7E+00 1.2E+01
7.66E+00 5.6E+01 3.7E+00 1.2E+01
6.40E+00 4.2E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.11E+03 109% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.04E+03 102% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.09E+03 103% VU ICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample 1
Sample Dilution Cone. Qualifier
1 1 ug/L 1
EaFA-LRef-1313-T01-D 1 1.62E+06
EaFA-LRef-1313-T02-D 1 3.77E+05
EaFA-LRef-1313-T03-D 1 1.63E+05
EaFA-LRef-1313-T04-D 1 1.15E+05
EaFA-LRef-1313-T05-D 1 4.90E+04
EaFA-LRef-1313-T06-D 1 2.30E+04
EaFA-LRef-1313-T07-D 1 2.45E+04
EaFA-LRef-1313-T08-D 1 1.83E+04
EaFA-LRef-1313-T09-D 1 2.18E+04
EaFA-LRef-1313-T01-E 1 1.58E+06
EaFA-LRef-1313-T02-E 1 3.77E+05
EaFA-LRef-1313-T03-E 1 1.68E+05
EaFA-LRef-1313-T04-E 1 1.16E+05
EaFA-LRef-1313-T05-E 1 4.97E+04
EaFA-LRef-1313-T06-E 1 2.28E+04
EaFA-LRef-1313-T07-E 1 2.44E+04
EaFA-LRef-1313-T08-E 1 1.82E+04
EaFA-LRef-1313-T09-E 1 2.17E+04
EaFA-LRef-1313-T01-F 1 1.59E+06
EaFA-LRef-1313-T02-F 1 3.88E+05
EaFA-LRef-1313-T03-F 1 1.68E+05
EaFA-LRef-1313-T04-F 1 1.15E+05
EaFA-LRef-1313-T05-F 1 5.02E+04
EaFA-LRef-1313-T06-F 1 2.27E+04
EaFA-LRef-1313-T07-F 1 2.43E+04
EaFA-LRef-1313-T08-F 1 1.83E+04
EaFA-LRef-1313-T09-F 1 2.19E+04
EaFA-LRef-1313-B01-D 1 8.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 6.97E+02
EaFA-LRef-1313-B03-D 1 1.61E+06
EaFA-LRef-1313-B01-E 1 8.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 7.00E+02
EaFA-LRef-1313-B03-E 1 1.60E+06
EaFA-LRef-1313-B01-F 1 8.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 7.01 E+02
EaFA-LRef-1313-B03-F 1 1.61E+06
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.62E+06 1.0E+00 1.6E+00 5.1E+00
3.77E+05 7.0E-01 1.6E+00 5.1E+00
1.63E+05 5.1E-01 1.6E+00 5.1E+00
1.15E+05 5.2E-01 1.6E+00 5.1E+00
4.90E+04 5.5E-01 1.6E+00 5.1E+00
2.30E+04 3.2E-01 1.6E+00 5.1E+00 1000 100
2.45E+04 7.0E-01 1.6E+00 5.1E+00
1.83E+04 3.0E-01 1.6E+00 5.1E+00
2.18E+04 1.0E-01 1.6E+00 5.1E+00
1.58E+06 3.7E-01 1.6E+00 5.1E+00
3.77E+05 7.1E-01 1.6E+00 5.1E+00
1.68E+05 2.4E-01 1.6E+00 5.1E+00
1.16E+05 1.3E-01 1.6E+00 5.1E+00
4.97E+04 5.7E-01 1.6E+00 5.1E+00
2.28E+04 9.1E-01 1.6E+00 5.1E+00
2.44E+04 4.0E-01 1.6E+00 5.1E+00 1000 100
1.82E+04 4.4E-01 1.6E+00 5.1E+00
2.17E+04 6.7E-01 1.6E+00 5.1E+00
1.59E+06 9.0E-01 1.6E+00 5.1E+00
3.88E+05 3.3E+00 1.6E+00 5.1E+00
1.68E+05 9.1E-01 1.6E+00 5.1E+00
1.15E+05 6.6E-01 1.6E+00 5.1E+00
5.02E+04 6.5E-01 1.6E+00 5.1E+00
2.27E+04 1.0E+00 1.6E+00 5.1E+00
2.43E+04 1.5E-01 1.6E+00 5.1E+00
1.83E+04 7.6E-02 1.6E+00 5.1E+00 1000 100
2.19E+04 4.1E-01 1.6E+00 5.1E+00
8.00E-01 1.7E+02 1.6E+00 5.1E+00
6.97E+02 3.7E-01 1.6E+00 5.1E+00
1.61E+06 8.4E-01 1.6E+00 5.1E+00
8.00E-01 3.6E+02 1.6E+00 5.1E+00
7.00E+02 6.0E-01 1.6E+00 5.1E+00
1.60E+06 6.9E-01 1.6E+00 5.1E+00
8.00E-01 2.4E+03 1.6E+00 5.1E+00
7.01 E+02 3.5E-01 1.6E+00 5.1E+00
1.61E+06 5.9E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
2.38E+04 83% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
2.53E+04 92% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.91E+04 82% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-342
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 7.16E+03
EaFA-LRef-1313-T02-D 1 5.37E+03
EaFA-LRef-1313-T03-D 1 4.64E+03
EaFA-LRef-1313-T04-D 1 3.65E+03
EaFA-LRef-1313-T05-D 1 1.51E+03
EaFA-LRef-1313-T06-D 1 8.20E+02
EaFA-LRef-1313-T07-D 1 2.38E+02
EaFA-LRef-1313-T08-D 1 6.63E+01
EaFA-LRef-1313-T09-D 1 5.19E+02
EaFA-LRef-1313-T01-E 1 7.02E+03
EaFA-LRef-1313-T02-E 1 5.47E+03
EaFA-LRef-1313-T03-E 1 4.85E+03
EaFA-LRef-1313-T04-E 1 3.75E+03
EaFA-LRef-1313-T05-E 1 1.60E+03
EaFA-LRef-1313-T06-E 1 9.11E+02
EaFA-LRef-1313-T07-E 1 2.40E+02
EaFA-LRef-1313-T08-E 1 7.71E+01
EaFA-LRef-1313-T09-E 1 5.49E+02
EaFA-LRef-1313-T01-F 1 7.29E+03
EaFA-LRef-1313-T02-F 1 5.48E+03
EaFA-LRef-1313-T03-F 1 4.71 E+03
EaFA-LRef-1313-T04-F 1 3.69E+03
EaFA-LRef-1313-T05-F 1 1.64E+03
EaFA-LRef-1313-T06-F 1 8.32E+02
EaFA-LRef-1313-T07-F 1 2.23E+02
EaFA-LRef-1313-T08-F 1 9.71 E+01
EaFA-LRef-1313-T09-F 1 5.67E+02
EaFA-LRef-1313-B01-D 1 7.50E+00 U1/2
EaFA-LRef-1313-B02-D 1 7.50E+00 U1/2
EaFA-LRef-1313-B03-D 1 7.50E+00 U1/2
EaFA-LRef-1313-B01-E 1 7.50E+00 U1/2
EaFA-LRef-1313-B02-E 1 7.50E+00 U1/2
EaFA-LRef-1313-B03-E 1 7.50E+00 U1/2
EaFA-LRef-1313-B01-F 1 7.50E+00 U1/2
EaFA-LRef-1313-B02-F 1 7.50E+00 U1/2
EaFA-LRef-1313-B03-F 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.16E+03 1.7E+00 1.5E+01 4.8E+01
5.37E+03 4.7E-01 1.5E+01 4.8E+01
4.64E+03 6.2E-01 1.5E+01 4.8E+01
3.65E+03 6.1E-01 1.5E+01 4.8E+01
1.51 E+03 2.0E+00 1.5E+01 4.8E+01
8.20E+02 6.0E+00 1.5E+01 4.8E+01 10 325
2.38E+02 1.9E+01 1.5E+01 4.8E+01
6.63E+01 2.4E+01 1.5E+01 4.8E+01
5.19E+02 4.3E+00 1.5E+01 4.8E+01
7.02E+03 9.2E-01 1.5E+01 4.8E+01
5.47E+03 4.6E-01 1.5E+01 4.8E+01
4.85E+03 3.8E-01 1.5E+01 4.8E+01
3.75E+03 6.6E-01 1.5E+01 4.8E+01
1.60E+03 2.1E+00 1.5E+01 4.8E+01
9.11E+02 2.6E+00 1.5E+01 4.8E+01
2.40E+02 9.4E+00 1.5E+01 4.8E+01 10 325
7.71 E+01 2.4E+01 1.5E+01 4.8E+01
5.49E+02 3.5E+00 1.5E+01 4.8E+01
7.29E+03 7.4E-01 1.5E+01 4.8E+01
5.48E+03 7.3E-01 1.5E+01 4.8E+01
4.71 E+03 9.6E-01 1.5E+01 4.8E+01
3.69E+03 1.8E+00 1.5E+01 4.8E+01
1.64E+03 1.9E+00 1.5E+01 4.8E+01
8.32E+02 1.2E+00 1.5E+01 4.8E+01
2.23E+02 1.2E+01 1.5E+01 4.8E+01
9.71E+01 3.1E+01 1.5E+01 4.8E+01 10 325
5.67E+02 1.1E+00 1.5E+01 4.8E+01
7.50E+00 3.0E+02 1.5E+01 4.8E+01
7.50E+00 9.4E+01 1.5E+01 4.8E+01
7.50E+00 1.5E+01 1.5E+01 4.8E+01
7.50E+00 3.0E+02 1.5E+01 4.8E+01
7.50E+00 3.7E+01 1.5E+01 4.8E+01
7.50E+00 3.9E+02 1.5E+01 4.8E+01
7.50E+00 8.0E+01 1.5E+01 4.8E+01
7.50E+00 4.7E+02 1.5E+01 4.8E+01
7.50E+00 3.3E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.80E+03 92% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.25E+03 93% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.49E+03 104% VU ICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-343
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 1.33E+04
EaFA-LRef-1313-T02-D 1 2.87E+03
EaFA-LRef-1313-T03-D 1 4.34E+02
EaFA-LRef-1313-T04-D 1 2.57E+02
EaFA-LRef-1313-T05-D 1 5.09E+02
EaFA-LRef-1313-T06-D 1 1.20E+03
EaFA-LRef-1313-T07-D 1 5.88E+03
EaFA-LRef-1313-T08-D 1 1.76E+04
EaFA-LRef-1313-T09-D 1 7.16E+04
EaFA-LRef-1313-T01-E 1 1.22E+04
EaFA-LRef-1313-T02-E 1 2.73E+03
EaFA-LRef-1313-T03-E 1 4.82E+02
EaFA-LRef-1313-T04-E 1 2.56E+02
EaFA-LRef-1313-T05-E 1 5.46E+02
EaFA-LRef-1313-T06-E 1 1.07E+03
EaFA-LRef-1313-T07-E 1 5.87E+03
EaFA-LRef-1313-T08-E 1 1.76E+04
EaFA-LRef-1313-T09-E 1 7.12E+04
EaFA-LRef-1313-T01-F 1 1.28E+04
EaFA-LRef-1313-T02-F 1 2.92E+03
EaFA-LRef-1313-T03-F 1 4.67E+02
EaFA-LRef-1313-T04-F 1 2.51E+02
EaFA-LRef-1313-T05-F 1 5.21E+02
EaFA-LRef-1313-T06-F 1 1.22E+03
EaFA-LRef-1313-T07-F 1 6.19E+03
EaFA-LRef-1313-T08-F 1 1.80E+04
EaFA-LRef-1313-T09-F 1 7.15E+04
EaFA-LRef-1313-B01-D 1 3.97E+01
EaFA-LRef-1313-B02-D 1 2.59E+02
EaFA-LRef-1313-B03-D 1 1.09E+03
EaFA-LRef-1313-B01-E 1 5.50E-01 U1/2
EaFA-LRef-1313-B02-E 1 2.57E+02
EaFA-LRef-1313-B03-E 1 1.43E+03
EaFA-LRef-1313-B01-F 1 2.00E+00 E
EaFA-LRef-1313-B02-F 1 2.63E+02
EaFA-LRef-1313-B03-F 1 1.66E+03
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+04 3.6E-01 1.1E+00 3.5E+00
2.87E+03 1.2E+00 1.1E+00 3.5E+00
4.34E+02 6.3E-01 1.1E+00 3.5E+00
2.57E+02 1.5E+00 1.1E+00 3.5E+00
5.09E+02 4.1E-01 1.1E+00 3.5E+00
1.20E+03 6.6E-01 1.1E+00 3.5E+00 1000 100
5.88E+03 3.2E-01 1.1E+00 3.5E+00
1.76E+04 3.7E-01 1.1E+00 3.5E+00
7.16E+04 9.1E-02 1.1E+00 3.5E+00
1.22E+04 3.5E-01 1.1E+00 3.5E+00
2.73E+03 8.1E-02 1.1E+00 3.5E+00
4.82E+02 1.1E+00 1.1E+00 3.5E+00
2.56E+02 1.9E+00 1.1E+00 3.5E+00
5.46E+02 6.6E-01 1.1E+00 3.5E+00
1.07E+03 5.2E-01 1.1E+00 3.5E+00
5.87E+03 5.9E-01 1.1E+00 3.5E+00 1000 100
1.76E+04 2.1E-01 1.1E+00 3.5E+00
7.12E+04 6.9E-01 1.1E+00 3.5E+00
1.28E+04 7.3E-01 1.1E+00 3.5E+00
2.92E+03 3.5E-01 1.1E+00 3.5E+00
4.67E+02 4.4E-01 1.1E+00 3.5E+00
2.51 E+02 1.1E+00 1.1E+00 3.5E+00
5.21 E+02 6.2E-01 1.1E+00 3.5E+00
1.22E+03 5.7E-01 1.1E+00 3.5E+00
6.19E+03 4.6E-01 1.1E+00 3.5E+00
1.80E+04 5.8E-01 1.1E+00 3.5E+00 1000 100
7.15E+04 4.4E-01 1.1E+00 3.5E+00
3.97E+01 1.3E+01 1.1E+00 3.5E+00
2.59E+02 1.1E+01 1.1E+00 3.5E+00
1.09E+03 9.7E-01 1.1E+00 3.5E+00
5.50E-01 3.3E+02 1.1E+00 3.5E+00
2.57E+02 6.1E+00 1.1E+00 3.5E+00
1.43E+03 6.2E-01 1.1E+00 3.5E+00
2.00E+00 3.8E+02 1.1E+00 3.5E+00
2.63E+02 3.3E+00 1.1E+00 3.5E+00
1.66E+03 5.0E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
2.27E+03 106% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
6.76E+03 89% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.90E+04 98% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-344
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 1.01E+04
EaFA-LRef-1313-T02-D 1 6.59E+03
EaFA-LRef-1313-T03-D 1 6.07E+03
EaFA-LRef-1313-T04-D 1 6.03E+03
EaFA-LRef-1313-T05-D 1 5.92E+03
EaFA-LRef-1313-T06-D 1 6.01 E+03
EaFA-LRef-1313-T07-D 1 6.24E+03
EaFA-LRef-1313-T08-D 1 4.38E+03
EaFA-LRef-1313-T09-D 1 3.72E+03
EaFA-LRef-1313-T01-E 1 1.01E+04
EaFA-LRef-1313-T02-E 1 6.58E+03
EaFA-LRef-1313-T03-E 1 6.40E+03
EaFA-LRef-1313-T04-E 1 6.12E+03
EaFA-LRef-1313-T05-E 1 6.09E+03
EaFA-LRef-1313-T06-E 1 5.99E+03
EaFA-LRef-1313-T07-E 1 6.23E+03
EaFA-LRef-1313-T08-E 1 4.36E+03
EaFA-LRef-1313-T09-E 1 3.70E+03
EaFA-LRef-1313-T01-F 1 1.02E+04
EaFA-LRef-1313-T02-F 1 6.68E+03
EaFA-LRef-1313-T03-F 1 6.25E+03
EaFA-LRef-1313-T04-F 1 6.04E+03
EaFA-LRef-1313-T05-F 1 6.14E+03
EaFA-LRef-1313-T06-F 1 6.00E+03
EaFA-LRef-1313-T07-F 1 6.16E+03
EaFA-LRef-1313-T08-F 1 4.36E+03
EaFA-LRef-1313-T09-F 1 3.72E+03
EaFA-LRef-1313-B01-D 1 1.25E+OOU1/2
EaFA-LRef-1313-B02-D 1 1.25E+OOU1/2
EaFA-LRef-1313-B03-D 1 3.49E+03
EaFA-LRef-1313-B01-E 1 1.25E+OOU1/2
EaFA-LRef-1313-B02-E 1 1.25E+OOU1/2
EaFA-LRef-1313-B03-E 1 3.96E+03
EaFA-LRef-1313-B01-F 1 1.25E+OOU1/2
EaFA-LRef-1313-B02-F 1 1.25E+OOU1/2
EaFA-LRef-1313-B03-F 1 4.07E+03
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.01E+04 1.2E+00 2.5E+00 8.0E+00
6.59E+03 5.0E-01 2.5E+00 8.0E+00
6.07E+03 2.9E-01 2.5E+00 8.0E+00
6.03E+03 7.7E-02 2.5E+00 8.0E+00
5.92E+03 8.4E-01 2.5E+00 8.0E+00
6.01E+03 7.2E-01 2.5E+00 8.0E+00 1000 100
6.24E+03 5.7E-01 2.5E+00 8.0E+00
4.38E+03 2.6E-01 2.5E+00 8.0E+00
3.72E+03 1.1E+00 2.5E+00 8.0E+00
1.01E+04 6.8E-01 2.5E+00 8.0E+00
6.58E+03 5.5E-01 2.5E+00 8.0E+00
6.40E+03 9.1E-01 2.5E+00 8.0E+00
6.12E+03 1.1E+00 2.5E+00 8.0E+00
6.09E+03 5.8E-01 2.5E+00 8.0E+00
5.99E+03 2.8E-01 2.5E+00 8.0E+00
6.23E+03 1.1E+00 2.5E+00 8.0E+00 1000 100
4.36E+03 7.3E-01 2.5E+00 8.0E+00
3.70E+03 9.0E-01 2.5E+00 8.0E+00
1.02E+04 7.4E-01 2.5E+00 8.0E+00
6.68E+03 3.1E-01 2.5E+00 8.0E+00
6.25E+03 5.1E-01 2.5E+00 8.0E+00
6.04E+03 9.9E-01 2.5E+00 8.0E+00
6.14E+03 9.1E-01 2.5E+00 8.0E+00
6.00E+03 1.2E+00 2.5E+00 8.0E+00
6.16E+03 7.2E-01 2.5E+00 8.0E+00
4.36E+03 7.2E-01 2.5E+00 8.0E+00 1000 100
3.72E+03 4.0E-01 2.5E+00 8.0E+00
1.25E+00 2.3E+00 2.5E+00 8.0E+00
1.25E+00 1.1E+00 2.5E+00 8.0E+00
3.49E+03 6.2E-01 2.5E+00 8.0E+00
1.25E+00 1.4E+00 2.5E+00 8.0E+00
1.25E+00 3.2E-01 2.5E+00 8.0E+00
3.96E+03 7.7E-01 2.5E+00 8.0E+00
1.25E+00 1.1E+00 2.5E+00 8.0E+00
1.25E+00 7.8E-01 2.5E+00 8.0E+00
4.07E+03 4.0E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
7.02E+03 101% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
7.29E+03 106% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
5.34E+03 98% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-345
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 1.35E+03
EaFA-LRef-1313-T02-D 1 1.71E+03
EaFA-LRef-1313-T03-D 1 1.90E+03
EaFA-LRef-1313-T04-D 1 2.08E+03
EaFA-LRef-1313-T05-D 1 2.26E+03
EaFA-LRef-1313-T06-D 1 2.40E+03
EaFA-LRef-1313-T07-D 1 2.97E+03
EaFA-LRef-1313-T08-D 1 3.03E+03
EaFA-LRef-1313-T09-D 1 5.47E+03
EaFA-LRef-1313-T01-E 1 1.30E+03
EaFA-LRef-1313-T02-E 1 1.72E+03
EaFA-LRef-1313-T03-E 1 1.95E+03
EaFA-LRef-1313-T04-E 1 2.10E+03
EaFA-LRef-1313-T05-E 1 2.33E+03
EaFA-LRef-1313-T06-E 1 2.44E+03
EaFA-LRef-1313-T07-E 1 2.97E+03
EaFA-LRef-1313-T08-E 1 3.03E+03
EaFA-LRef-1313-T09-E 1 5.47E+03
EaFA-LRef-1313-T01-F 1 1.32E+03
EaFA-LRef-1313-T02-F 1 1.75E+03
EaFA-LRef-1313-T03-F 1 1.94E+03
EaFA-LRef-1313-T04-F 1 2.06E+03
EaFA-LRef-1313-T05-F 1 2.37E+03
EaFA-LRef-1313-T06-F 1 2.39E+03
EaFA-LRef-1313-T07-F 1 2.92E+03
EaFA-LRef-1313-T08-F 1 3.06E+03
EaFA-LRef-1313-T09-F 1 5.49E+03
EaFA-LRef-1313-B01-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B01-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B01-F 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-F 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.35E+03 7.7E-01 1.0E+00 3.2E+00
1.71E+03 5.5E-01 1.0E+00 3.2E+00
1.90E+03 3.5E-01 1.0E+00 3.2E+00
2.08E+03 7.4E-01 1.0E+00 3.2E+00
2.26E+03 6.5E-01 1.0E+00 3.2E+00
2.40E+03 5.8E-01 1.0E+00 3.2E+00 1000 100
2.97E+03 1.0E+00 1.0E+00 3.2E+00
3.03E+03 9.5E-01 1.0E+00 3.2E+00
5.47E+03 1.3E+00 1.0E+00 3.2E+00
1.30E+03 7.3E-01 1.0E+00 3.2E+00
1.72E+03 9.8E-01 1.0E+00 3.2E+00
1.95E+03 9.1E-01 1.0E+00 3.2E+00
2.10E+03 5.5E-01 1.0E+00 3.2E+00
2.33E+03 8.9E-01 1.0E+00 3.2E+00
2.44E+03 1.7E-01 1.0E+00 3.2E+00
2.97E+03 1.3E+00 1.0E+00 3.2E+00 1000 100
3.03E+03 1.4E-01 1.0E+00 3.2E+00
5.47E+03 9.0E-01 1.0E+00 3.2E+00
1.32E+03 6.4E-01 1.0E+00 3.2E+00
1.75E+03 4.1E-01 1.0E+00 3.2E+00
1.94E+03 8.4E-01 1.0E+00 3.2E+00
2.06E+03 8.2E-01 1.0E+00 3.2E+00
2.37E+03 8.6E-01 1.0E+00 3.2E+00
2.39E+03 6.3E-01 1.0E+00 3.2E+00
2.92E+03 1.4E+00 1.0E+00 3.2E+00
3.06E+03 1.6E-01 1.0E+00 3.2E+00 1000 100
5.49E+03 9.1E-01 1.0E+00 3.2E+00
5.00E-01 5.5E+01 1.0E+00 3.2E+00
5.00E-01 3.9E+01 1.0E+00 3.2E+00
5.00E-01 9.0E+01 1.0E+00 3.2E+00
5.00E-01 7.1E+00 1.0E+00 3.2E+00
5.00E-01 2.2E+01 1.0E+00 3.2E+00
5.00E-01 2.2E+01 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
5.00E-01 6.7E+01 1.0E+00 3.2E+00
5.00E-01 2.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.30E+03 90% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.85E+03 88% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
4.03E+03 97% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-346
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 1.90E+05
EaFA-LRef-1313-T02-D 1 1.63E+05
EaFA-LRef-1313-T03-D 1 1.59E+05
EaFA-LRef-1313-T04-D 1 1.63E+05
EaFA-LRef-1313-T05-D 1 1.62E+05
EaFA-LRef-1313-T06-D 1 1.65E+05
EaFA-LRef-1313-T07-D 1 1.55E+05
EaFA-LRef-1313-T08-D 1 1.06E+05
EaFA-LRef-1313-T09-D 1 7.06E+04
EaFA-LRef-1313-T01-E 1 1.87E+05
EaFA-LRef-1313-T02-E 1 1.66E+05
EaFA-LRef-1313-T03-E 1 1.68E+05
EaFA-LRef-1313-T04-E 1 1.67E+05
EaFA-LRef-1313-T05-E 1 1.67E+05
EaFA-LRef-1313-T06-E 1 1.66E+05
EaFA-LRef-1313-T07-E 1 1.56E+05
EaFA-LRef-1313-T08-E 1 1.07E+05
EaFA-LRef-1313-T09-E 1 7.15E+04
EaFA-LRef-1313-T01-F 1 1.96E+05
EaFA-LRef-1313-T02-F 1 1.68E+05
EaFA-LRef-1313-T03-F 1 1.67E+05
EaFA-LRef-1313-T04-F 1 1.68E+05
EaFA-LRef-1313-T05-F 1 1.72E+05
EaFA-LRef-1313-T06-F 1 1.66E+05
EaFA-LRef-1313-T07-F 1 1.57E+05
EaFA-LRef-1313-T08-F 1 1.08E+05
EaFA-LRef-1313-T09-F 1 7.20E+04
EaFA-LRef-1313-B01-D 1 3.40E+00 U1/2
EaFA-LRef-1313-B02-D 1 3.40E+00 U1/2
EaFA-LRef-1313-B03-D 1 3.60E+01
EaFA-LRef-1313-B01-E 1 3.40E+00 U1/2
EaFA-LRef-1313-B02-E 1 3.40E+00 U1/2
EaFA-LRef-1313-B03-E 1 3.77E+01
EaFA-LRef-1313-B01-F 1 3.40E+00 U1/2
EaFA-LRef-1313-B02-F 1 3.40E+00 U1/2
EaFA-LRef-1313-B03-F 1 3.26E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.90E+05 1.1E+00 6.8E+00 2.2E+01
1.63E+05 7.0E-01 6.8E+00 2.2E+01
1.59E+05 1.0E-01 6.8E+00 2.2E+01
1.63E+05 6.8E-02 6.8E+00 2.2E+01
1.62E+05 6.8E-01 6.8E+00 2.2E+01
1.65E+05 6.1E-01 6.8E+00 2.2E+01 1000 100
1.55E+05 9.7E-01 6.8E+00 2.2E+01
1.06E+05 2.2E-01 6.8E+00 2.2E+01
7.06E+04 1.4E-01 6.8E+00 2.2E+01
1.87E+05 2.3E-01 6.8E+00 2.2E+01
1.66E+05 8.9E-01 6.8E+00 2.2E+01
1.68E+05 4.4E-01 6.8E+00 2.2E+01
1.67E+05 7.6E-01 6.8E+00 2.2E+01
1.67E+05 4.6E-01 6.8E+00 2.2E+01
1.66E+05 3.9E-01 6.8E+00 2.2E+01
1.56E+05 5.0E-01 6.8E+00 2.2E+01 1000 100
1.07E+05 5.3E-01 6.8E+00 2.2E+01
7.15E+04 6.7E-01 6.8E+00 2.2E+01
1.96E+05 5.2E-01 6.8E+00 2.2E+01
1.68E+05 2.9E-01 6.8E+00 2.2E+01
1.67E+05 7.6E-01 6.8E+00 2.2E+01
1.68E+05 5.4E-01 6.8E+00 2.2E+01
1.72E+05 5.1E-01 6.8E+00 2.2E+01
1.66E+05 8.0E-01 6.8E+00 2.2E+01
1.57E+05 9.6E-01 6.8E+00 2.2E+01
1.08E+05 6.3E-01 6.8E+00 2.2E+01 1000 100
7.20E+04 4.0E-01 6.8E+00 2.2E+01
3.40E+00 8.5E+01 6.8E+00 2.2E+01
3.40E+00 8.4E+01 6.8E+00 2.2E+01
3.60E+01 4.1E+01 6.8E+00 2.2E+01
3.40E+00 4.4E+01 6.8E+00 2.2E+01
3.40E+00 2.2E+02 6.8E+00 2.2E+01
3.77E+01 1.3E+01 6.8E+00 2.2E+01
3.40E+00 9.1E+01 6.8E+00 2.2E+01
3.40E+00 3.5E+02 6.8E+00 2.2E+01
3.26E+01 1.1E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.66E+05 83% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.57E+05 93% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.09E+05 91% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-347
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-LRef-1313-T01-D 1 2.30E+00 U1/2
EaFA-LRef-1313-T02-D 1 2.30E+00 U1/2
EaFA-LRef-1313-T03-D 1 2.30E+00 U1/2
EaFA-LRef-1313-T04-D 1 2.30E+00 U1/2
EaFA-LRef-1313-T05-D 1 2.30E+00 U1/2
EaFA-LRef-1313-T06-D 1 2.30E+00 U1/2
EaFA-LRef-1313-T07-D 1 2.30E+00 U1/2
EaFA-LRef-1313-T08-D 1 4.03E+01
EaFA-LRef-1313-T09-D 1 7.28E+01
EaFA-LRef-1313-T01-E 1 2.30E+00 U1/2
EaFA-LRef-1313-T02-E 1 2.30E+00 U1/2
EaFA-LRef-1313-T03-E 1 2.30E+00 U1/2
EaFA-LRef-1313-T04-E 1 2.30E+00 U1/2
EaFA-LRef-1313-T05-E 1 2.30E+00 U1/2
EaFA-LRef-1313-T06-E 1 2.30E+00 U1/2
EaFA-LRef-1313-T07-E 1 7.37E+00 E
EaFA-LRef-1313-T08-E 1 4.62E+01
EaFA-LRef-1313-T09-E 1 7.23E+01
EaFA-LRef-1313-T01-F 1 2.30E+00 U1/2
EaFA-LRef-1313-T02-F 1 2.30E+00 U1/2
EaFA-LRef-1313-T03-F 1 2.30E+00 U1/2
EaFA-LRef-1313-T04-F 1 2.30E+00 U1/2
EaFA-LRef-1313-T05-F 1 2.30E+00 U1/2
EaFA-LRef-1313-T06-F 1 2.30E+00 U1/2
EaFA-LRef-1313-T07-F 1 1.27E+01 E
EaFA-LRef-1313-T08-F 1 4.48E+01
EaFA-LRef-1313-T09-F 1 6.86E+01
EaFA-LRef-1313-B01-D 1 2.30E+00 U1/2
EaFA-LRef-1313-B02-D 1 2.30E+00 U1/2
EaFA-LRef-1313-B03-D 1 2.30E+00 U1/2
EaFA-LRef-1313-B01-E 1 2.30E+00 U1/2
EaFA-LRef-1313-B02-E 1 2.30E+00 U1/2
EaFA-LRef-1313-B03-E 1 2.30E+00 U1/2
EaFA-LRef-1313-B01-F 1 2.30E+00 U1/2
EaFA-LRef-1313-B02-F 1 2.30E+00 U1/2
EaFA-LRef-1313-B03-F 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 9.8E+01 4.6E+00 1.5E+01
2.30E+00 3.2E+01 4.6E+00 1.5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 9.3E+01 4.6E+00 1.5E+01
2.30E+00 3.1E+01 4.6E+00 1.5E+01
2.30E+00 7.5E+01 4.6E+00 1.5E+01 10 325
2.30E+00 1.1E+03 4.6E+00 1.5E+01
4.03E+01 1.7E+01 4.6E+00 1.5E+01
7.28E+01 9.3E+00 4.6E+00 1.5E+01
2.30E+00 2.2E+02 4.6E+00 1.5E+01
2.30E+00 7.4E+02 4.6E+00 1.5E+01
2.30E+00 8.8E+01 4.6E+00 1.5E+01
2.30E+00 4.7E+01 4.6E+00 1.5E+01
2.30E+00 1.0E+02 4.6E+00 1.5E+01
2.30E+00 7.9E+01 4.6E+00 1.5E+01
7.37E+00 2.6E+02 4.6E+00 1.5E+01 10 325
4.62E+01 2.3E+01 4.6E+00 1.5E+01
7.23E+01 6.6E+00 4.6E+00 1.5E+01
2.30E+00 3.5E+01 4.6E+00 1.5E+01
2.30E+00 1.6E+02 4.6E+00 1.5E+01
2.30E+00 3.4E+01 4.6E+00 1.5E+01
2.30E+00 3.0E+01 4.6E+00 1.5E+01
2.30E+00 5.4E+01 4.6E+00 1.5E+01
2.30E+00 2.9E+02 4.6E+00 1.5E+01
1.27E+01 1.2E+02 4.6E+00 1.5E+01
4.48E+01 1.4E+01 4.6E+00 1.5E+01 10 325
6.86E+01 2.6E+00 4.6E+00 1.5E+01
2.30E+00 3.1E+01 4.6E+00 1.5E+01
2.30E+00 1.2E+02 4.6E+00 1.5E+01
2.30E+00 3.1E+01 4.6E+00 1.5E+01
2.30E+00 3.3E+01 4.6E+00 1.5E+01
2.30E+00 1.9E+01 4.6E+00 1.5E+01
2.30E+00 5.4E+01 4.6E+00 1.5E+01
2.30E+00 2.9E+01 4.6E+00 1.5E+01
2.30E+00 7.5E+01 4.6E+00 1.5E+01
2.30E+00 3.6E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.22E+03 99% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.21E+03 99% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.14E+03 95% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-348
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
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Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
EaFA-LRef-1313-T01-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T02-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T03-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T04-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T05-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T06-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T07-D 1 1.00E+OOU1/2
EaFA-LRef-1313-T08-D 1 3.50E+00 E
EaFA-LRef-1313-T09-D 1 1.41E+03
EaFA-LRef-1313-T01-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T02-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T03-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T04-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T05-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T06-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T07-E 1 1.00E+OOU1/2
EaFA-LRef-1313-T08-E 1 3.61 E+00 E
EaFA-LRef-1313-T09-E 1 1.48E+03
EaFA-LRef-1313-T01-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T02-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T03-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T04-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T05-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T06-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T07-F 1 1.00E+OOU1/2
EaFA-LRef-1313-T08-F 1 3.22E+00 E
EaFA-LRef-1313-T09-F 1 1.46E+03
EaFA-LRef-1313-B01-D 1 1.00E+OOU1/2
EaFA-LRef-1313-B02-D 1 1.00E+OOU1/2
EaFA-LRef-1313-B03-D 1 1.00E+OOU1/2
EaFA-LRef-1313-B01-E 1 1.00E+OOU1/2
EaFA-LRef-1313-B02-E 1 1.00E+OOU1/2
EaFA-LRef-1313-B03-E 1 1.00E+OOU1/2
EaFA-LRef-1313-B01-F 1 1.00E+OOU1/2
EaFA-LRef-1313-B02-F 1 1.00E+OOU1/2
EaFA-LRef-1313-B03-F 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.7E+01 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00 10 325
1.00E+00 2.1E+01 2.0E+00 6.4E+00
3.50E+00 3.5E+00 2.0E+00 6.4E+00
1.41E+03 6.8E-02 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
1.00E+00 6.1 E+00 2.0E+00 6.4E+00
1.00E+00 8.2E+00 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00 10 325
3.61 E+00 1.1E+01 2.0E+00 6.4E+00
1.48E+03 2.6E-01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+00 2.0E+00 6.4E+00
1.00E+00 6.6E+00 2.0E+00 6.4E+00
3.22E+00 9.4E+00 2.0E+00 6.4E+00 10 325
1.46E+03 3.3E-01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 8.3E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 6.6E+03 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 5.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.10E+03 95% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/109:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.10E+03 95% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.00E+03 92% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-349
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone. Qualifier
1 1 ug/L
EaFA-LRef-1313-T01-D 1 4.79E+03
EaFA-LRef-1313-T02-D 1 2.32E+03
EaFA-LRef-1313-T03-D 1 1.50E+03
EaFA-LRef-1313-T04-D 1 6.39E+02
EaFA-LRef-1313-T05-D 1 1.90E+02
EaFA-LRef-1313-T06-D 1 1.38E+02
EaFA-LRef-1313-T07-D 1 7.50E+01
EaFA-LRef-1313-T08-D 1 8.19E+01
EaFA-LRef-1313-T09-D 1 6.45E+03
EaFA-LRef-1313-T01-E 1 4.57E+03
EaFA-LRef-1313-T02-E 1 2.26E+03
EaFA-LRef-1313-T03-E 1 1.59E+03
EaFA-LRef-1313-T04-E 1 6.75E+02
EaFA-LRef-1313-T05-E 1 2.04E+02
EaFA-LRef-1313-T06-E 1 1.45E+02
EaFA-LRef-1313-T07-E 1 7.98E+01
EaFA-LRef-1313-T08-E 1 8.47E+01
EaFA-LRef-1313-T09-E 1 6.44E+03
EaFA-LRef-1313-T01-F 1 4.84E+03
EaFA-LRef-1313-T02-F 1 2.30E+03
EaFA-LRef-1313-T03-F 1 1.58E+03
EaFA-LRef-1313-T04-F 1 6.65E+02
EaFA-LRef-1313-T05-F 1 2.12E+02
EaFA-LRef-1313-T06-F 1 1.39E+02
EaFA-LRef-1313-T07-F 1 7.81E+01
EaFA-LRef-1313-T08-F 1 7.94E+01
EaFA-LRef-1313-T09-F 1 6.46E+03
EaFA-LRef-1313-B01-D 1 1.80E+OOE
EaFA-LRef-1313-B02-D 1 7.50E-01 U1/2
EaFA-LRef-1313-B03-D 1 4.95E+00
EaFA-LRef-1313-B01-E 1 7.50E-01 U1/2
EaFA-LRef-1313-B02-E 1 7.50E-01 U1/2
EaFA-LRef-1313-B03-E 1 1.81E+OOE
EaFA-LRef-1313-B01-F 1 7.50E-01 U1/2
EaFA-LRef-1313-B02-F 1 2.97E+00 E
EaFA-LRef-1313-B03-F 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.79E+03 1.8E+00 1.5E+00 4.8E+00
2.32E+03 8.4E-01 1.5E+00 4.8E+00
1.50E+03 2.1E-01 1.5E+00 4.8E+00
6.39E+02 5.5E-01 1.5E+00 4.8E+00
1.90E+02 6.7E-01 1.5E+00 4.8E+00
1.38E+02 1.0E+00 1.5E+00 4.8E+00 10 325
7.50E+01 2.4E+00 1.5E+00 4.8E+00
8.19E+01 6.4E-01 1.5E+00 4.8E+00
6.45E+03 1.5E-01 1.5E+00 4.8E+00
4.57E+03 2.7E-01 1.5E+00 4.8E+00
2.26E+03 6.3E-01 1.5E+00 4.8E+00
1.59E+03 6.0E-01 1.5E+00 4.8E+00
6.75E+02 1.2E+00 1.5E+00 4.8E+00
2.04E+02 2.1E+00 1.5E+00 4.8E+00
1.45E+02 4.4E+00 1.5E+00 4.8E+00
7.98E+01 1.5E+00 1.5E+00 4.8E+00 10 325
8.47E+01 1.3E+00 1.5E+00 4.8E+00
6.44E+03 7.0E-01 1.5E+00 4.8E+00
4.84E+03 3.4E-01 1.5E+00 4.8E+00
2.30E+03 8.5E-01 1.5E+00 4.8E+00
1.58E+03 1.3E+00 1.5E+00 4.8E+00
6.65E+02 1.1E+00 1.5E+00 4.8E+00
2.12E+02 1.7E+00 1.5E+00 4.8E+00
1.39E+02 3.2E+00 1.5E+00 4.8E+00
7.81 E+01 5.3E+00 1.5E+00 4.8E+00
7.94E+01 1.1E+00 1.5E+00 4.8E+00 10 325
6.46E+03 6.9E-02 1.5E+00 4.8E+00
1.80E+00 1.2E+02 1.5E+00 4.8E+00
7.50E-01 1.7E+02 1.5E+00 4.8E+00
4.95E+00 4.9E+01 1.5E+00 4.8E+00
7.50E-01 9.7E+01 1.5E+00 4.8E+00
7.50E-01 1.6E+02 1.5E+00 4.8E+00
1.81E+00 6.0E+01 1.5E+00 4.8E+00
7.50E-01 2.1E+02 1.5E+00 4.8E+00
2.97E+00 5.9E+01 1.5E+00 4.8E+00
7.50E-01 7.8E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.13E+03 92% VUICP-OES 5/6/10 9:36 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.18E+03 95% VU ICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.07E+03 92% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-350
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Internal
Sample Dilution Cone. Qualifier Review
1 1 ug/L
EaFA-LRef-1313-T01-D 1 9.59E+01
EaFA-LRef-1313-T02-D 1 3.25E+00
EaFA-LRef-1313-T03-D 1 5.00E-01 U1/2
EaFA-LRef-1313-T04-D 1 5.00E-01 U1/2
EaFA-LRef-1313-T05-D 1 5.00E-01 U1/2
EaFA-LRef-1313-T06-D 1 2.58E+00 E
EaFA-LRef-1313-T07-D 1 1.04E+03
EaFA-LRef-1313-T08-D 1 1.15E+03
EaFA-LRef-1313-T09-D 1 1.61E+03
EaFA-LRef-1313-T01-E 1 1.12E+02
EaFA-LRef-1313-T02-E 1 9.24E+00
EaFA-LRef-1313-T03-E 1 1.57E+01
EaFA-LRef-1313-T04-E 1 3.26E+00
EaFA-LRef-1313-T05-E 1 1.64E+01
EaFA-LRef-1313-T06-E 1 1.31E+01
EaFA-LRef-1313-T07-E 1 1.01E+03
EaFA-LRef-1313-T08-E 1 1.15E+03
EaFA-LRef-1313-T09-E 1 1.62E+03
EaFA-LRef-1313-T01-F 1 1.07E+02
EaFA-LRef-1313-T02-F 1 1.72E+01
EaFA-LRef-1313-T03-F 1 5.00E-01 U1/2
EaFA-LRef-1313-T04-F 1 2.23E+00 E
EaFA-LRef-1313-T05-F 1 8.30E+00
EaFA-LRef-1313-T06-F 1 1.62E+01
EaFA-LRef-1313-T07-F 1 1.03E+03
EaFA-LRef-1313-T08-F 1 1.21E+03
EaFA-LRef-1313-T09-F 1 1.64E+03
EaFA-LRef-1313-B01-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-D 1 5.00E-01 U1/2
EaFA-LRef-1313-B01-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-E 1 5.00E-01 U1/2
EaFA-LRef-1313-B01-F 1 5.00E-01 U1/2
EaFA-LRef-1313-B02-F 1 5.00E-01 U1/2
EaFA-LRef-1313-B03-F 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.59E+01 2.1E+00 1.0E+00 3.2E+00
3.25E+00 2.2E+01 1.0E+00 3.2E+00
5.00E-01 3.3E+01 1.0E+00 3.2E+00
5.00E-01 2.2E+00 1.0E+00 3.2E+00
5.00E-01 6.2E+01 1.0E+00 3.2E+00
2.58E+00 2.7E+01 1.0E+00 3.2E+00 10 325
1.04E+03 6.1E-01 1.0E+00 3.2E+00
1.15E+03 1.0E+00 1.0E+00 3.2E+00
1.61E+03 9.7E-01 1.0E+00 3.2E+00
1.12E+02 1.6E+00 1.0E+00 3.2E+00
9.24E+00 1.6E+01 1.0E+00 3.2E+00
1.57E+01 3.2E+00 1.0E+00 3.2E+00
3.26E+00 2.0E+01 1.0E+00 3.2E+00
1.64E+01 3.2E+00 1.0E+00 3.2E+00
1.31E+01 8.2E+00 1.0E+00 3.2E+00
1.01E+03 1.2E+00 1.0E+00 3.2E+00 10 325
1.15E+03 6.5E-01 1.0E+00 3.2E+00
1.62E+03 3.0E-01 1.0E+00 3.2E+00
1.07E+02 1.3E+00 1.0E+00 3.2E+00
1.72E+01 3.7E+00 1.0E+00 3.2E+00
5.00E-01 5.8E+01 1.0E+00 3.2E+00
2.23E+00 5.0E+01 1.0E+00 3.2E+00
8.30E+00 1.2E+01 1.0E+00 3.2E+00
1.62E+01 1.6E+00 1.0E+00 3.2E+00
1.03E+03 1.1E+00 1.0E+00 3.2E+00
1.21E+03 2.5E-01 1.0E+00 3.2E+00 10 325
1.64E+03 2.3E-01 1.0E+00 3.2E+00
5.00E-01 9.7E+00 1.0E+00 3.2E+00
5.00E-01 8.9E+00 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
5.00E-01 8.0E+00 1.0E+00 3.2E+00
5.00E-01 5.9E+00 1.0E+00 3.2E+00
5.00E-01 8.8E+00 1.0E+00 3.2E+00
5.00E-01 1.8E+00 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/6/10 9:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:30 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:32 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:33 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 9:35 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.37E+03 104% VUICP-OES 5/6/109:36AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:38 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:40 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:41 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:51 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:53 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:55 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:56 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:58 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:00 AM EPA Interlab LRef D-F 1313-1316 EaFA
4.83E+03 118% VUICP-OES 5/6/10 10:01 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:03 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:05 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:14 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:16 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:18 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:19 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 10:21 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:24 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.98E+03 85% VUICP-OES 5/6/10 10:26 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:28 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:23 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:25 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:27 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:46 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:48 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 5/6/10 9:50 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:10 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/1010:11 AM EPA Interlab LRef D-F 1313-1316 EaFA
VUICP-OES 5/6/10 10:13 AM EPA Interlab LRef D-F 1313-1316 EaFA
                                                                                                                                                                          1-351
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al SWA-L01-1313-T01-A 1
Al SWA-L01-1313-T02-A 1
Al SWA-L01-1313-T03-A 1
Al SWA-L01-1313-T04-A 1
Al SWA-L01-1313-T05-A 1
Al SWA-L01-1313-T06-A 1
Al SWA-L01-1313-T07-A 1
Al SWA-L01-1313-T08-A 1
Al SWA-L01-1313-T09-A 1
Al SWA-L01-1313-T01-B 1
Al SWA-L01-1313-T02-B 1
Al SWA-L01-1313-T03-B 1
Al SWA-L01-1313-T04-B 1
Al SWA-L01-1313-T05-B 1
Al SWA-L01-1313-T06-B 1
Al SWA-L01-1313-T07-B 1
Al SWA-L01-1313-T08-B 1
Al SWA-L01-1313-T09-B 1
Al SWA-L01-1313-T01-C 1
Al SWA-L01-1313-T02-C 1
Al SWA-L01-1313-T03-C 1
Al SWA-L01-1313-T04-C 1
Al SWA-L01-1313-T05-C 1
Al SWA-L01-1313-T06-C 1
Al SWA-L01-1313-T07-C 1
Al SWA-L01-1313-T08-C 1
Al SWA-L01-1313-T09-C 1
Al SWA-L01-1313-B01-A 1
Al SWA-L01-1313-B02-A 1
Al SWA-L01-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
8.64E+04
3.50E+04
6.61 E+02
5.05E+01
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
2.30E+05
5.85E+05
8.17E+04
3.61 E+04
7.86E+02
1.76E+01
8.72E+00
5.00E-01 U1/2
5.00E-01 U1/2
2.38E+05
5.66E+05
7.95E+04
3.65E+04
5.08E+02
4.40E+01
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
2.24E+05
5.85E+05
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.64E+04 2.2E-01 1.0E+00 3.2E+00
3.50E+04 3.4E-01 1.0E+00 3.2E+00 1000 100
6.61 E+02 3.3E-01 1.0E+00 3.2E+00
5.05E+01 5.3E+00 1.0E+00 3.2E+00
5.00E-01 6.7E+00 1.0E+00 3.2E+00
5.00E-01 1.6E+01 1.0E+00 3.2E+00
5.00E-01 2.6E+01 1.0E+00 3.2E+00
2.30E+05 9.1E-01 1.0E+00 3.2E+00
5.85E+05 2.6E-01 1.0E+00 3.2E+00
8.17E+04 8.0E-01 1.0E+00 3.2E+00
3.61 E+04 1.1E+00 1.0E+00 3.2E+00
7.86E+02 9.7E-01 1.0E+00 3.2E+00
1.76E+01 1.6E+01 1.0E+00 3.2E+00
8.72E+00 9.9E+00 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
5.00E-01 2.0E+01 1.0E+00 3.2E+00
2.38E+05 9.6E-01 1.0E+00 3.2E+00
5.66E+05 3.3E-01 1.0E+00 3.2E+00
7.95E+04 2.1E+00 1.0E+00 3.2E+00
3.65E+04 5.3E-01 1.0E+00 3.2E+00 1000 100
5.08E+02 4.4E-01 1.0E+00 3.2E+00
4.40E+01 1.1E+01 1.0E+00 3.2E+00
5.00E-01 2.5E+01 1.0E+00 3.2E+00
5.00E-01 1.3E+00 1.0E+00 3.2E+00
5.00E-01 6.5E+00 1.0E+00 3.2E+00
2.24E+05 2.2E-01 1.0E+00 3.2E+00
5.85E+05 2.8E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+00 1.0E+00 3.2E+00
5.00E-01 3.6E+00 1.0E+00 3.2E+00
5.00E-01 2.0E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
3.62E+04 116% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:37 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55AM EPA Interlab L01 1313-1316SWA
3.76E+04 110% VUICP-OES 11/1/10 1 1:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                                   1-352
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L01-1313-T01-A 1
Sb SWA-L01-1313-T02-A 1
Sb SWA-L01-1313-T03-A 1
Sb SWA-L01-1313-T04-A 1
Sb SWA-L01-1313-T05-A 1
Sb SWA-L01-1313-T06-A 1
Sb SWA-L01-1313-T07-A 1
Sb SWA-L01-1313-T08-A 1
Sb SWA-L01-1313-T09-A 1
Sb SWA-L01-1313-T01-B 1
Sb SWA-L01-1313-T02-B 1
Sb SWA-L01-1313-T03-B 1
Sb SWA-L01-1313-T04-B 1
Sb SWA-L01-1313-T05-B 1
Sb SWA-L01-1313-T06-B 1
Sb SWA-L01-1313-T07-B 1
Sb SWA-L01-1313-T08-B 1
Sb SWA-L01-1313-T09-B 1
Sb SWA-L01-1313-T01-C 1
Sb SWA-L01-1313-T02-C 1
Sb SWA-L01-1313-T03-C 1
Sb SWA-L01-1313-T04-C 1
Sb SWA-L01-1313-T05-C 1
Sb SWA-L01-1313-T06-C 1
Sb SWA-L01-1313-T07-C 1
Sb SWA-L01-1313-T08-C 1
Sb SWA-L01-1313-T09-C 1
Sb SWA-L01-1313-B01-A 1
Sb SWA-L01-1313-B02-A 1
Sb SWA-L01-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
5.69E+03
3.12E+03
1.20E+03
1.20E+03
1.28E+03
1.37E+03
1.35E+03
6.89E+02
2.11E+02
6.11E+03
3.84E+03
1.29E+03
1.26E+03
1.21E+03
1.44E+03
1.29E+03
7.85E+02
2.38E+02
6.16E+03
2.35E+03
1 .22E+03
1.18E+03
9.85E+02
1.13E+03
1.14E+03
6.43E+02
2.28E+02
8.64E+00 E
8.75E+00 E
1.25E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.69E+03 3.8E-01 7.5E+00 2.4E+01
3.12E+03 5.5E-01 7.5E+00 2.4E+01 10 100
1.20E+03 1.0E+00 7.5E+00 2.4E+01
1.20E+03 1.3E+00 7.5E+00 2.4E+01
1.28E+03 4.6E-01 7.5E+00 2.4E+01
1.37E+03 1.1E+00 7.5E+00 2.4E+01
1.35E+03 2.3E+00 7.5E+00 2.4E+01
6.89E+02 7.6E-01 7.5E+00 2.4E+01
2.11E+02 8.0E+00 7.5E+00 2.4E+01
6.11E+03 5.3E-01 7.5E+00 2.4E+01
3.84E+03 1.2E+00 7.5E+00 2.4E+01
1.29E+03 6.4E-01 7.5E+00 2.4E+01
1.26E+03 1.0E+00 7.5E+00 2.4E+01
1.21E+03 6.9E-01 7.5E+00 2.4E+01
1.44E+03 2.6E-01 7.5E+00 2.4E+01
1.29E+03 3.7E+00 7.5E+00 2.4E+01
7.85E+02 5.6E+00 7.5E+00 2.4E+01
2.38E+02 4.6E+00 7.5E+00 2.4E+01
6.16E+03 1.2E+00 7.5E+00 2.4E+01
2.35E+03 8.3E-01 7.5E+00 2.4E+01 10 100
1.22E+03 3.4E+00 7.5E+00 2.4E+01
1.18E+03 1.4E+00 7.5E+00 2.4E+01
9.85E+02 5.6E-01 7.5E+00 2.4E+01
1.13E+03 7.9E-01 7.5E+00 2.4E+01
1.14E+03 9.9E-01 7.5E+00 2.4E+01
6.43E+02 8.8E+00 7.5E+00 2.4E+01
2.28E+02 1.7E+00 7.5E+00 2.4E+01
8.64E+00 3.5E+01 7.5E+00 2.4E+01
8.75E+00 2.8E+01 7.5E+00 2.4E+01
1.25E+01 2.0E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
4.28E+03 116% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:34 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316 SWA
3.38E+03 103% VU ICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-353
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone.
1 ug/L
As SWA-L01-1313-T01-A 1 1.64E+04
As SWA-L01-1313-T02-A 1 5.06E+03
As SWA-L01-1313-T03-A 1 1.53E+02
As SWA-L01-1313-T04-A 1 4.78E+02
As SWA-L01-1313-T05-A 1 3.06E+02
As SWA-L01-1313-T06-A 1 2.03E+02
As SWA-L01-1313-T07-A 1 1.97E+02
As SWA-L01-1313-T08-A 1 2.72E+03
As SWA-L01-1313-T09-A 1 5.75E+03
As SWA-L01-1313-T01-B 1 1.62E+04
As SWA-L01-1313-T02-B 1 5.50E+03
As SWA-L01-1313-T03-B 1 1.85E+02
As SWA-L01-1313-T04-B 1 4.04E+02
As SWA-L01-1313-T05-B 1 3.89E+02
As SWA-L01-1313-T06-B 1 2.02E+02
As SWA-L01-1313-T07-B 1 1.97E+02
As SWA-L01-1313-T08-B 1 2.47E+03
As SWA-L01-1313-T09-B 1 6.32E+03
As SWA-L01-1313-T01-C 1 1.58E+04
As SWA-L01-1313-T02-C 1 5.36E+03
As SWA-L01-1313-T03-C 1 1.82E+02
As SWA-L01-1313-T04-C 1 3.73E+02
As SWA-L01-1313-T05-C 1 1.91E+02
As SWA-L01-1313-T06-C 1 2.17E+02
As SWA-L01-1313-T07-C 1 1.92E+02
As SWA-L01-1313-T08-C 1 2.52E+03
As SWA-L01-1313-T09-C 1 6.55E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.64E+04 3.2E-01 1.1E+01 3.5E+01
5.06E+03 3.7E-01 1.1E+01 3.5E+01 10 100
1.53E+02 9.6E-01 1.1E+01 3.5E+01
4.78E+02 4.0E+00 1.1E+01 3.5E+01
3.06E+02 2.5E+00 1.1E+01 3.5E+01
2.03E+02 6.2E+00 1.1E+01 3.5E+01
1.97E+02 7.9E+00 1.1E+01 3.5E+01
2.72E+03 8.1E-01 1.1E+01 3.5E+01
5.75E+03 3.0E-01 1.1E+01 3.5E+01
1.62E+04 8.1E-01 1.1E+01 3.5E+01
5.50E+03 1.0E+00 1.1E+01 3.5E+01
1.85E+02 2.8E+00 1.1E+01 3.5E+01
4.04E+02 5.9E+00 1.1E+01 3.5E+01
3.89E+02 4.1E+00 1.1E+01 3.5E+01
2.02E+02 5.1E+00 1.1E+01 3.5E+01
1.97E+02 4.6E+00 1.1E+01 3.5E+01
2.47E+03 4.0E-01 1.1E+01 3.5E+01
6.32E+03 8.2E-01 1.1E+01 3.5E+01
1.58E+04 1.1E+00 1.1E+01 3.5E+01
5.36E+03 5.7E-02 1.1E+01 3.5E+01 10 100
1.82E+02 4.5E-02 1.1E+01 3.5E+01
3.73E+02 2.5E+00 1.1E+01 3.5E+01
1.91E+02 5.4E+00 1.1E+01 3.5E+01
2.17E+02 2.7E+00 1.1E+01 3.5E+01
1.92E+02 8.5E+00 1.1E+01 3.5E+01
2.52E+03 5.8E-01 1.1E+01 3.5E+01
6.55E+03 3.3E+00 1.1E+01 3.5E+01
As SWA-L01-1313-B01-A 1 5.50E+00 U1/2 5.50E+00 5.6E+01 1.1E+01 3.5E+01
As SWA-L01-1313-B02-A 1 5.50E+00 U1/2 5.50E+00 4.5E+01 1.1E+01 3.5E+01
As SWA-L01-1313-B03-A 1 5.50E+00 U1/2 5.50E+00 5.0E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
5.92E+03 85% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
6.32E+03 96% VUICP-OES 1 1/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-354
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-L01-1313-T01-A 1
B SWA-L01-1313-T02-A 1
B SWA-L01-1313-T03-A 1
B SWA-L01-1313-T04-A 1
B SWA-L01-1313-T05-A 1
B SWA-L01-1313-T06-A 1
B SWA-L01-1313-T07-A 1
B SWA-L01-1313-T08-A 1
B SWA-L01-1313-T09-A 1
B SWA-L01-1313-T01-B 1
B SWA-L01-1313-T02-B 1
B SWA-L01-1313-T03-B 1
B SWA-L01-1313-T04-B 1
B SWA-L01-1313-T05-B 1
B SWA-L01-1313-T06-B 1
B SWA-L01-1313-T07-B 1
B SWA-L01-1313-T08-B 1
B SWA-L01-1313-T09-B 1
B SWA-L01-1313-T01-C 1
B SWA-L01-1313-T02-C 1
B SWA-L01-1313-T03-C 1
B SWA-L01-1313-T04-C 1
B SWA-L01-1313-T05-C 1
B SWA-L01-1313-T06-C 1
B SWA-L01-1313-T07-C 1
B SWA-L01-1313-T08-C 1
B SWA-L01-1313-T09-C 1
B SWA-L01-1313-B01-A 1
B SWA-L01-1313-B02-A 1
B SWA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.18E+03
7.82E+02
1.04E+03
1.89E+03
2.73E+03
3.63E+03
5.83E+03
5.76E+03
5.79E+03
1.26E+03
9.37E+02
1.03E+03
1.48E+03
1.96E+03
2.91 E+03
5.88E+03
5.67E+03
5.79E+03
1.20E+03
9.96E+02
1.07E+03
1.55E+03
2.18E+03
2.28E+03
4.24E+03
5.86E+03
5.74E+03
1.19E+01
9.85E+00
1.15E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+03 1.2E+00 1.0E+00 3.2E+00
7.82E+02 4.5E-01 1.0E+00 3.2E+00 1000 100
1.04E+03 4.4E-01 1.0E+00 3.2E+00
1.89E+03 9.9E-01 1.0E+00 3.2E+00
2.73E+03 1.7E-01 1.0E+00 3.2E+00
3.63E+03 3.3E-01 1.0E+00 3.2E+00
5.83E+03 5.0E-01 1.0E+00 3.2E+00
5.76E+03 7.5E-01 1.0E+00 3.2E+00
5.79E+03 3.5E-01 1.0E+00 3.2E+00
1.26E+03 6.6E-01 1.0E+00 3.2E+00
9.37E+02 1.4E+00 1.0E+00 3.2E+00
1.03E+03 6.0E-01 1.0E+00 3.2E+00
1.48E+03 5.4E-01 1.0E+00 3.2E+00
1.96E+03 7.0E-01 1.0E+00 3.2E+00
2.91 E+03 8.1E-01 1.0E+00 3.2E+00
5.88E+03 1.4E+00 1.0E+00 3.2E+00
5.67E+03 3.6E-01 1.0E+00 3.2E+00
5.79E+03 4.0E-01 1.0E+00 3.2E+00
1.20E+03 1.1E+00 1.0E+00 3.2E+00
9.96E+02 3.4E-01 1.0E+00 3.2E+00 1000 100
1.07E+03 4.5E-02 1.0E+00 3.2E+00
1.55E+03 3.3E-01 1.0E+00 3.2E+00
2.18E+03 6.2E-01 1.0E+00 3.2E+00
2.28E+03 6.2E-01 1.0E+00 3.2E+00
4.24E+03 2.3E-01 1.0E+00 3.2E+00
5.86E+03 1.6E-01 1.0E+00 3.2E+00
5.74E+03 2.9E+00 1.0E+00 3.2E+00
1.19E+01 1.9E+00 1.0E+00 3.2E+00
9.85E+00 2.4E+00 1.0E+00 3.2E+00
1.15E+01 3.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.71E+03 93% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.95E+03 95% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-355
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qu
1 1 ug/L
Ba SWA-L01-1313-T01-A 1 2.09E+02
Ba SWA-L01-1313-T02-A 1 1.63E+02
Ba SWA-L01-1313-T03-A 1 1.11E+03
Ba SWA-L01-1313-T04-A 1 1.12E+03
Ba SWA-L01-1313-T05-A 1 1.08E+03
Ba SWA-L01-1313-T06-A 1 1.01E+03
Ba SWA-L01-1313-T07-A 1 1.50E+03
Ba SWA-L01-1313-T08-A 1 5.72E+02
Ba SWA-L01-1313-T09-A 1 6.52E+02
Ba SWA-L01-1313-T01-B 1 3.13E+02
Ba SWA-L01-1313-T02-B 1 1.71E+02
Ba SWA-L01-1313-T03-B 1 1.06E+03
Ba SWA-L01-1313-T04-B 1 1.17E+03
Ba SWA-L01-1313-T05-B 1 9.51E+02
Ba SWA-L01-1313-T06-B 1 9.93E+02
Ba SWA-L01-1313-T07-B 1 1.39E+03
Ba SWA-L01-1313-T08-B 1 5.54E+02
Ba SWA-L01-1313-T09-B 1 6.32E+02
Ba SWA-L01-1313-T01-C 1 2.59E+02
Ba SWA-L01-1313-T02-C 1 1 .54E+02
Ba SWA-L01-1313-T03-C 1 9.70E+02
Ba SWA-L01-1313-T04-C 1 1 .05E+03
Ba SWA-L01-1313-T05-C 1 8.57E+02
Ba SWA-L01-1313-T06-C 1 9.19E+02
Ba SWA-L01-1313-T07-C 1 1.13E+03
Ba SWA-L01-1313-T08-C 1 5.93E+02
Ba SWA-L01-1313-T09-C 1 6.87E+02
Ba SWA-L01-1313-B01-A 1 1.52E+OOE
Ba SWA-L01-1313-B02-A 1 1.46E+OOE
Ba SWA-L01-1313-B03-A 1 1.72E+OOE
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.09E+02 2.3E+01 1.0E+00 3.2E+00
1.63E+02 3.2E-01 1.0E+00 3.2E+00 10 100
1.11E+03 8.5E-01 1.0E+00 3.2E+00
1.12E+03 1.2E+00 1.0E+00 3.2E+00
1.08E+03 3.7E-01 1.0E+00 3.2E+00
1.01E+03 3.5E-01 1.0E+00 3.2E+00
1.50E+03 5.4E-01 1.0E+00 3.2E+00
5.72E+02 5.3E-01 1.0E+00 3.2E+00
6.52E+02 1.0E-01 1.0E+00 3.2E+00
3.13E+02 1.2E+00 1.0E+00 3.2E+00
1.71E+02 7.5E-01 1.0E+00 3.2E+00
1.06E+03 3.3E-01 1.0E+00 3.2E+00
1.17E+03 6.5E-01 1.0E+00 3.2E+00
9.51 E+02 4.1E-01 1.0E+00 3.2E+00
9.93E+02 9.3E-01 1.0E+00 3.2E+00
1.39E+03 1.1E+00 1.0E+00 3.2E+00
5.54E+02 1.5E-01 1.0E+00 3.2E+00
6.32E+02 1.5E-01 1 .OE+00 3.2E+00
2.59E+02 2.4E+00 1 .OE+00 3.2E+00
1.54E+02 2.6E-01 1 .OE+00 3.2E+00 10 100
9.70E+02 5.7E-01 1 .OE+00 3.2E+00
1.05E+03 9.0E-01 1 .OE+00 3.2E+00
8.57E+02 5.3E-01 1. OE+00 3.2E+00
9.19E+02 1.7E-01 1. OE+00 3.2E+00
1.13E+03 8.7E-01 1. OE+00 3.2E+00
5.93E+02 2.6E-01 1. OE+00 3.2E+00
6.87E+02 3.4E+00 1. OE+00 3.2E+00
1.52E+00 3.4E+00 1. OE+00 3.2E+00
1.46E+00 2.1E+00 1. OE+00 3.2E+00
1.72E+00 2.0E+00 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.03E+03 87% VUICP-OES 1 1/1/10 11:22 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:32 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316 SWA
1.03E+03 88% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-356
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L01-1313-T01-A 1
Be SWA-L01-1313-T02-A 1
Be SWA-L01-1313-T03-A 1
Be SWA-L01-1313-T04-A 1
Be SWA-L01-1313-T05-A 1
Be SWA-L01-1313-T06-A 1
Be SWA-L01-1313-T07-A 1
Be SWA-L01-1313-T08-A 1
Be SWA-L01-1313-T09-A 1
Be SWA-L01-1313-T01-B 1
Be SWA-L01-1313-T02-B 1
Be SWA-L01-1313-T03-B 1
Be SWA-L01-1313-T04-B 1
Be SWA-L01-1313-T05-B 1
Be SWA-L01-1313-T06-B 1
Be SWA-L01-1313-T07-B 1
Be SWA-L01-1313-T08-B 1
Be SWA-L01-1313-T09-B 1
Be SWA-L01-1313-T01-C 1
Be SWA-L01-1313-T02-C 1
Be SWA-L01-1313-T03-C 1
Be SWA-L01-1313-T04-C 1
Be SWA-L01-1313-T05-C 1
Be SWA-L01-1313-T06-C 1
Be SWA-L01-1313-T07-C 1
Be SWA-L01-1313-T08-C 1
Be SWA-L01-1313-T09-C 1
Be SWA-L01-1313-B01-A 1
Be SWA-L01-1313-B02-A 1
Be SWA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
2.79E+01
1.11E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
3.21E+01
1.11E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
3.00E+01
1.18E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 3.1E+02 1.9E+00 6.0E+00
9.50E-01 7.5E+02 1.9E+00 6.0E+00 10 100
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 3.1E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 8.7E+00 1.9E+00 6.0E+00
9.50E-01 5.9E+02 1.9E+00 6.0E+00
2.79E+01 5.9E+00 1.9E+00 6.0E+00
1.11E+02 1.1E+00 1.9E+00 6.0E+00
9.50E-01 3.0E+01 1.9E+00 6.0E+00
9.50E-01 5.9E+02 1.9E+00 6.0E+00
9.50E-01 6.7E+02 1.9E+00 6.0E+00
9.50E-01 3.5E+01 1.9E+00 6.0E+00
9.50E-01 2.6E+02 1.9E+00 6.0E+00
9.50E-01 2.4E+02 1.9E+00 6.0E+00
9.50E-01 4.0E+01 1.9E+00 6.0E+00
3.21E+01 2.5E+00 1.9E+00 6.0E+00
1.11E+02 1.4E+00 1.9E+00 6.0E+00
9.50E-01 4.5E+02 1.9E+00 6.0E+00
9.50E-01 4.8E+02 1.9E+00 6.0E+00 10 100
9.50E-01 3.3E+02 1.9E+00 6.0E+00
9.50E-01 8.8E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+03 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
3.00E+01 3.1E+00 1.9E+00 6.0E+00
1.18E+02 5.7E+00 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
9.50E-01 8.0E+02 1.9E+00 6.0E+00
9.50E-01 4.1E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.07E+03 107% VU ICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.07E+03 107% VU ICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                          1-357
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L01-1313-T01-A 1 1.10E+OOU1/2 1.10E+00 2.9E+02 2.2E+00 7.0E+00
Cd SWA-L01-1313-T02-A 1 1.10E+OOU1/2 1.10E+00 2.3E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L01-1313-T03-A 1 1.10E+OOU1/2 1.10E+00 9.1E+01 2.2E+00 7.0E+00
Cd SWA-L01-1313-T04-A 1 1.10E+OOU1/2 1.10E+00 5.3E+01 2.2E+00 7.0E+00
Cd SWA-L01-1313-T05-A 1 1.10E+OOU1/2 1.10E+00 1.5E+02 2.2E+00 7.0E+00
Cd SWA-L01-1313-T06-A 1 1.10E+OOU1/2 1.10E+00 7.1E+01 2.2E+00 7.0E+00
Cd SWA-L01-1313-T07-A 1 3.30E+00 E
Cd SWA-L01-1313-T08-A 1 1.69E+01
Cd SWA-L01-1313-T09-A 1 2.87E+01
3.30E+00 1.6E+01 2.2E+00 7.0E+00
1.69E+01 1.4E+00 2.2E+00 7.0E+00
2.87E+01 1.1E+00 2.2E+00 7.0E+00
Cd SWA-L01-1313-T01-B 1 1.10E+OOU1/2 1.10E+00 8.8E+01 2.2E+00 7.0E+00
Cd SWA-L01-1313-T02-B 1 1.10E+OOU1/2 1.10E+00 1.3E+02 2.2E+00 7.0E+00
Cd SWA-L01-1313-T03-B 1 1.10E+OOU1/2 1.10E+00 1.3E+02 2.2E+00 7.0E+00
Cd SWA-L01-1313-T04-B 1 1.10E+OOU1/2 1.10E+00 3.7E+02 2.2E+00 7.0E+00
Cd SWA-L01-1313-T05-B 1 1.10E+OOU1/2 1.10E+00 3.5E+01 2.2E+00 7.0E+00
Cd SWA-L01-1313-T06-B 1 1.10E+OOU1/2 1.10E+00 7.8E+01 2.2E+00 7.0E+00
Cd SWA-L01-1313-T07-B 1 3.75E+00 E
Cd SWA-L01-1313-T08-B 1 1.63E+01
Cd SWA-L01-1313-T09-B 1 2.85E+01
3.75E+00 9.5E+00 2.2E+00 7.0E+00
1.63E+01 1.7E+00 2.2E+00 7.0E+00
2.85E+01 1.2E+00 2.2E+00 7.0E+00
Cd SWA-L01-1313-T01-C 1 1.10E+OOU1/2 1.10E+00 4.7E+02 2.2E+00 7.0E+00
Cd SWA-L01-1313-T02-C 1 1.10E+OOU1/2 1.10E+00 2.4E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L01-1313-T03-C 1 1.10E+OOU1/2 1.10E+00 6.7E+02 2.2E+00 7.0E+00
Cd SWA-L01-1313-T04-C 1 1.10E+OOU1/2 1.10E+00 1.1E+02 2.2E+00 7.0E+00
Cd SWA-L01-1313-T05-C 1 1.10E+OOU1/2 1.10E+00 5.3E+01 2.2E+00 7.0E+00
Cd SWA-L01-1313-T06-C 1 1.10E+OOU1/2 1.10E+00 9.7E+02 2.2E+00 7.0E+00
Cd SWA-L01-1313-T07-C 1 1.10E+OOU1/2 1.10E+00 7.8E+00 2.2E+00 7.0E+00
Cd SWA-L01-1313-T08-C 1 1 .69E+01
Cd SWA-L01-1313-T09-C 1 2.94E+01
1.69E+01 1.9E-01 2.2E+00 7.0E+00
2.94E+01 9.1E+00 2.2E+00 7.0E+00
Cd SWA-L01-1313-B01-A 1 1.10E+OOU1/2 1.10E+00 5.8E+01 2.2E+00 7.0E+00
Cd SWA-L01-1313-B02-A 1 1.10E+OOU1/2 1.10E+00 6.1E+01 2.2E+00 7.0E+00
Cd SWA-L01-1313-B03-A 1 1.10E+OOU1/2
1.10E+00 2.2E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316 SWA
1.02E+03 102% VU ICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:27 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:29 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 11/1/10 11:31 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:32 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:34 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:36 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:37 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:39 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 11/1/10 11:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.03E+03 102% VU ICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:16 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:18 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:19 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                          1-358
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qu
1 1 ug/L
Ca SWA-L01-1313-T01-A 1 4.34E+03
Ca SWA-L01-1313-T02-A 1 1.38E+04
Ca SWA-L01-1313-T03-A 1 2.04E+06
Ca SWA-L01-1313-T04-A 1 5.80E+06
Ca SWA-L01-1313-T05-A 1 6.78E+06
Ca SWA-L01-1313-T06-A 1 7.07E+06
Ca SWA-L01-1313-T07-A 1 8.52E+06
Ca SWA-L01-1313-T08-A 1 3.48E+06
Ca SWA-L01-1313-T09-A 1 2.74E+06
Ca SWA-L01-1313-T01-B 1 5.14E+03
Ca SWA-L01-1313-T02-B 1 1.42E+04
Ca SWA-L01-1313-T03-B 1 1.93E+06
Ca SWA-L01-1313-T04-B 1 4.58E+06
Ca SWA-L01-1313-T05-B 1 5.60E+06
Ca SWA-L01-1313-T06-B 1 6.67E+06
Ca SWA-L01-1313-T07-B 1 8.11E+06
Ca SWA-L01-1313-T08-B 1 3.33E+06
Ca SWA-L01-1313-T09-B 1 2.63E+06
Ca SWA-L01-1313-T01-C 1 4.98E+03
Ca SWA-L01-1313-T02-C 1 1.39E+04
Ca SWA-L01-1313-T03-C 1 2.02E+06
Ca SWA-L01-1313-T04-C 1 4.54E+06
Ca SWA-L01-1313-T05-C 1 5.90E+06
Ca SWA-L01-1313-T06-C 1 5.85E+06
Ca SWA-L01-1313-T07-C 1 7.58E+06
Ca SWA-L01-1313-T08-C 1 3.32E+06
Ca SWA-L01-1313-T09-C 1 2.58E+06
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.34E+03 2.9E+00 2.6E+00 8.3E+00
1.38E+04 2.0E-01 2.6E+00 8.3E+00 1000 100
2.04E+06 4.6E-01 2.6E+00 8.3E+00
5.80E+06 7.2E-01 2.6E+00 8.3E+00
6.78E+06 4.0E-01 2.6E+00 8.3E+00
7.07E+06 1.0E+00 2.6E+00 8.3E+00
8.52E+06 2.5E-01 2.6E+00 8.3E+00
3.48E+06 7.6E-01 2.6E+00 8.3E+00
2.74E+06 6.3E-01 2.6E+00 8.3E+00
5.14E+03 1.2E+00 2.6E+00 8.3E+00
1.42E+04 1.4E+00 2.6E+00 8.3E+00
1.93E+06 2.9E-01 2.6E+00 8.3E+00
4.58E+06 6.0E-01 2.6E+00 8.3E+00
5.60E+06 5.3E-01 2.6E+00 8.3E+00
6.67E+06 8.1E-01 2.6E+00 8.3E+00
8.11E+06 4.6E-01 2.6E+00 8.3E+00
3.33E+06 4.0E-01 2.6E+00 8.3E+00
2.63E+06 2.9E-01 2.6E+00 8.3E+00
4.98E+03 9.6E-01 2.6E+00 8.3E+00
1.39E+04 4.6E-01 2.6E+00 8.3E+00 1000 100
2.02E+06 5.3E-01 2.6E+00 8.3E+00
4.54E+06 5.0E-01 2.6E+00 8.3E+00
5.90E+06 7.9E-01 2.6E+00 8.3E+00
5.85E+06 7.2E-01 2.6E+00 8.3E+00
7.58E+06 3.4E-01 2.6E+00 8.3E+00
3.32E+06 4.7E-01 2.6E+00 8.3E+00
2.58E+06 2.8E+00 2.6E+00 8.3E+00
Ca SWA-L01-1313-B01-A 1 1.30E+OOU1/2 1.30E+00 2.4E+01 2.6E+00 8.3E+00
Ca SWA-L01-1313-B02-A 1 1.30E+OOU1/2 1.30E+00 5.7E+02 2.6E+00 8.3E+00
Ca SWA-L01-1313-B03-A 1 3.61 E+01
3.61 E+01 2.7E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.47E+04 91% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.48E+04 90% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-359
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone.
1 ug/L
Cr SWA-L01-1313-T01-A 1 1.75E+03
Cr SWA-L01-1313-T02-A 1 1.17E+03
Cr SWA-L01-1313-T03-A 1 1.03E+01
Cr SWA-L01-1313-T04-A 1 9.05E+00
Cr SWA-L01-1313-T05-A 1 1.18E+01
Cr SWA-L01-1313-T06-A 1 1.71E+01
Cr SWA-L01-1313-T07-A 1 6.40E+00
Cr SWA-L01-1313-T08-A 1 3.65E+03
Cr SWA-L01-1313-T09-A 1 1.44E+04
Cr SWA-L01-1313-T01-B 1 1.79E+03
Cr SWA-L01-1313-T02-B 1 1.11E+03
Cr SWA-L01-1313-T03-B 1 8.13E+00
Cr SWA-L01-1313-T04-B 1 4.30E+00
Cr SWA-L01-1313-T05-B 1 6.39E+00
Cr SWA-L01-1313-T06-B 1 1.11E+01
Cr SWA-L01-1313-T07-B 1 5.03E+00
Cr SWA-L01-1313-T08-B 1 3.85E+03
Cr SWA-L01-1313-T09-B 1 1 .45E+04
Cr SWA-L01-1313-T01-C 1 1.18E+03
Cr SWA-L01-1313-T02-C 1 1 .38E+03
Cr SWA-L01-1313-T03-C 1 9.19E+00
Cr SWA-L01-1313-T04-C 1 3.85E+00
Cr SWA-L01-1313-T05-C 1 1 .06E+01
Cr SWA-L01-1313-T06-C 1 1.18E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.75E+03 3.2E+00 1.2E+00 3.8E+00
1.17E+03 3.7E-01 1.2E+00 3.8E+00 10 100
1.03E+01 5.7E+00 1.2E+00 3.8E+00
9.05E+00 1.0E+01 1.2E+00 3.8E+00
1.18E+01 3.1E+01 1.2E+00 3.8E+00
1.71E+01 5.9E+00 1.2E+00 3.8E+00
6.40E+00 2.9E+01 1.2E+00 3.8E+00
3.65E+03 8.0E-02 1.2E+00 3.8E+00
1.44E+04 3.3E-01 1.2E+00 3.8E+00
1.79E+03 2.0E+00 1.2E+00 3.8E+00
1.11E+03 7.6E-01 1.2E+00 3.8E+00
8.13E+00 7.0E+00 1.2E+00 3.8E+00
4.30E+00 2.0E+01 1.2E+00 3.8E+00
6.39E+00 1.0E+01 1.2E+00 3.8E+00
1.11E+01 8.4E+00 1.2E+00 3.8E+00
5.03E+00 3.2E+01 1.2E+00 3.8E+00
3.85E+03 3.5E-01 1.2E+00 3.8E+00
1.45E+04 3.5E-01 1 .2E+00 3.8E+00
1.18E+03 1.8E+00 1.2E+00 3.8E+00
1.38E+03 2.1E-01 1 .2E+00 3.8E+00 10 100
9.19E+00 2.8E+00 1 .2E+00 3.8E+00
3.85E+00 1.1E+01 1.2E+00 3.8E+00
1.06E+01 1.6E+01 1.2E+00 3.8E+00
1.18E+01 6.4E+00 1.2E+00 3.8E+00
Cr SWA-L01-1313-T07-C 1 3.60E+00 E 3.60E+00 3.1E+01 1 .2E+00 3.8E+00
Cr SWA-L01-1313-T08-C 1 3.45E+03
Cr SWA-L01-1313-T09-C 1 1 .40E+04
3.45E+03 1.7E-01 1 .2E+00 3.8E+00
1.40E+04 2.8E+00 1 .2E+00 3.8E+00
Cr SWA-L01-1313-B01-A 1 6.00E-01 U1/2 6.00E-01 6.1E+01 1.2E+00 3.8E+00
Cr SWA-L01-1313-B02-A 1 6.00E-01 U1/2 6.00E-01 5.4E+01 1.2E+00 3.8E+00
Cr SWA-L01-1313-B03-A 1 1.28E+OOE 1.28E+00 8.0E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
2.07E+03 90% VUICP-OES 1 1/1/10 11:22 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:32 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316 SWA
2.29E+03 92% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:16 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:18 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:19 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                          1-360
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. (
1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Co SWA-L01-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 2.0E+02 1.8E+00 5.7E+00
Co SWA-L01-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 3.2E+01 1.8E+00 5.7E+00 10 100
Co SWA-L01-1313-T03-A 1 2.38E+00 E
Co SWA-L01-1313-T04-A 1 4.73E+00 E
Co SWA-L01-1313-T05-A 1 1.31E+01
Co SWA-L01-1313-T06-A 1 3.74E+01
Co SWA-L01-1313-T07-A 1 1.53E+02
Co SWA-L01-1313-T08-A 1 1.52E+02
Co SWA-L01-1313-T09-A 1 1.81E+02
2.38E+00 4.1E+01 1.8E+00 5.7E+00
4.73E+00 3.6E+01 1.8E+00 5.7E+00
1.31E+01 3.2E-01 1.8E+00 5.7E+00
3.74E+01 9.0E+00 1.8E+00 5.7E+00
1.53E+02 2.2E+00 1.8E+00 5.7E+00
1.52E+02 1.2E+00 1.8E+00 5.7E+00
1.81E+02 1.2E-01 1.8E+00 5.7E+00
Co SWA-L01-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 1.9E+01 1.8E+00 5.7E+00
Co SWA-L01-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 3.0E+02 1.8E+00 5.7E+00
Co SWA-L01-1313-T03-B 1 1.86E+OOE
Co SWA-L01-1313-T04-B 1 3.75E+00 E
Co SWA-L01-1313-T05-B 1 5.43E+00 E
Co SWA-L01-1313-T06-B 1 1.37E+01
Co SWA-L01-1313-T07-B 1 1.61E+02
Co SWA-L01-1313-T08-B 1 1.48E+02
Co SWA-L01-1313-T09-B 1 1.78E+02
1.86E+00 2.9E+01 1.8E+00 5.7E+00
3.75E+00 3.9E+01 1.8E+00 5.7E+00
5.43E+00 1.9E+01 1.8E+00 5.7E+00
1.37E+01 1.7E+01 1.8E+00 5.7E+00
1.61E+02 6.6E-01 1.8E+00 5.7E+00
1.48E+02 5.2E-01 1.8E+00 5.7E+00
1.78E+02 3.9E-01 1.8E+00 5.7E+00
Co SWA-L01-1313-T01-C 1 9.00E-01 U1/2 9.00E-01 8.8E+01 1.8E+00 5.7E+00
Co SWA-L01-1313-T02-C 1 9.00E-01 U1/2 9.00E-01 2.2E+03 1.8E+00 5.7E+00 10 100
Co SWA-L01-1313-T03-C 1 1.94E+OOE
Co SWA-L01-1313-T04-C 1 3.04E+00 E
Co SWA-L01-1313-T05-C 1 9.43E+00
Co SWA-L01-1313-T06-C 1 1.09E+01
Co SWA-L01-1313-T07-C 1 1.09E+02
Co SWA-L01-1313-T08-C 1 1.51E+02
Co SWA-L01-1313-T09-C 1 1.85E+02
1.94E+00 7.8E+01 1.8E+00 5.7E+00
3.04E+00 1.7E+01 1.8E+00 5.7E+00
9.43E+00 3.3E+00 1.8E+00 5.7E+00
1.09E+01 4.9E+00 1.8E+00 5.7E+00
1.09E+02 2.7E+00 1.8E+00 5.7E+00
1.51E+02 3.9E-01 1.8E+00 5.7E+00
1.85E+02 3.6E+00 1.8E+00 5.7E+00
Co SWA-L01-1313-B01-A 1 9.00E-01 U1/2 9.00E-01 2.1E+02 1.8E+00 5.7E+00
Co SWA-L01-1313-B02-A 1 9.00E-01 U1/2 9.00E-01 3.7E+02 1.8E+00 5.7E+00
Co SWA-L01-1313-B03-A 1 9.00E-01 U1/2 9.00E-01 4.9E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316 SWA
9.81E+02 98% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:37 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316 SWA
9.88E+02 99% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1012:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                          1-361
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu SWA-L01-1313-T01-A 1
Cu SWA-L01-1313-T02-A 1
Cu SWA-L01-1313-T03-A 1
Cu SWA-L01-1313-T04-A 1
Cu SWA-L01-1313-T05-A 1
Cu SWA-L01-1313-T06-A 1
Cu SWA-L01-1313-T07-A 1
Cu SWA-L01-1313-T08-A 1
Cu SWA-L01-1313-T09-A 1
Cu SWA-L01-1313-T01-B 1
Cu SWA-L01-1313-T02-B 1
Cu SWA-L01-1313-T03-B 1
Cu SWA-L01-1313-T04-B 1
Cu SWA-L01-1313-T05-B 1
Cu SWA-L01-1313-T06-B 1
Cu SWA-L01-1313-T07-B 1
Cu SWA-L01-1313-T08-B 1
Cu SWA-L01-1313-T09-B 1
Cu SWA-L01-1313-T01-C 1
Cu SWA-L01-1313-T02-C 1
Cu SWA-L01-1313-T03-C 1
Cu SWA-L01-1313-T04-C 1
Cu SWA-L01-1313-T05-C 1
Cu SWA-L01-1313-T06-C 1
Cu SWA-L01-1313-T07-C 1
Cu SWA-L01-1313-T08-C 1
Cu SWA-L01-1313-T09-C 1
Cu SWA-L01-1313-B01-A 1
Cu SWA-L01-1313-B02-A 1
Cu SWA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
4.07E+00 E
1.85E+00 U1/2
5.88E+00 E
1.04E+01 E
1.04E+01 E
1.35E+01
1.65E+01
3.05E+01
9.26E+02
4.74E+00 E
1.85E+00 U1/2
5.58E+00 E
9.12E+00 E
8.96E+00 E
1.14E+01 E
1.53E+01
3.33E+01
9.43E+02
4.37E+00 E
1.85E+00 U1/2
5.33E+00 E
7.62E+00 E
1.26E+01
9.03E+00 E
1.27E+01
3.30E+01
9.39E+02
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.07E+00 5.8E+01 3.7E+00 1.2E+01
1.85E+00 1.5E+02 3.7E+00 1.2E+01 10 100
5.88E+00 3.3E+01 3.7E+00 1.2E+01
1.04E+01 9.4E+00 3.7E+00 1.2E+01
1.04E+01 1.8E+01 3.7E+00 1.2E+01
1.35E+01 2.2E+01 3.7E+00 1.2E+01
1.65E+01 1.5E+01 3.7E+00 1.2E+01
3.05E+01 9.3E-01 3.7E+00 1.2E+01
9.26E+02 4.6E-01 3.7E+00 1.2E+01
4.74E+00 6.4E+00 3.7E+00 1.2E+01
1.85E+00 9.7E+01 3.7E+00 1.2E+01
5.58E+00 4.4E+01 3.7E+00 1.2E+01
9.12E+00 1.0E+01 3.7E+00 1.2E+01
8.96E+00 3.7E+01 3.7E+00 1.2E+01
1.14E+01 5.1E+00 3.7E+00 1.2E+01
1.53E+01 1.8E+01 3.7E+00 1.2E+01
3.33E+01 1.9E+00 3.7E+00 1.2E+01
9.43E+02 1.1E+00 3.7E+00 1.2E+01
4.37E+00 1.8E+01 3.7E+00 1.2E+01
1.85E+00 1.4E+02 3.7E+00 1.2E+01 10 100
5.33E+00 6.8E+00 3.7E+00 1.2E+01
7.62E+00 1.9E+01 3.7E+00 1.2E+01
1.26E+01 1.2E+01 3.7E+00 1.2E+01
9.03E+00 4.3E+01 3.7E+00 1.2E+01
1.27E+01 2.4E+01 3.7E+00 1.2E+01
3.30E+01 1.3E+00 3.7E+00 1.2E+01
9.39E+02 2.9E+00 3.7E+00 1.2E+01
1.85E+00 7.2E+01 3.7E+00 1.2E+01
1.85E+00 2.8E+02 3.7E+00 1.2E+01
1.85E+00 3.0E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316 SWA
9.90E+02 99% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:24 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:26 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:27 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:29 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:32 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:34 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:36 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
9.98E+02 100% VU ICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                          1-362
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe SWA-L01-1313-T01-A 1
Fe SWA-L01-1313-T02-A 1
Fe SWA-L01-1313-T03-A 1
Fe SWA-L01-1313-T04-A 1
Fe SWA-L01-1313-T05-A 1
Fe SWA-L01-1313-T06-A 1
Fe SWA-L01-1313-T07-A 1
Fe SWA-L01-1313-T08-A 1
Fe SWA-L01-1313-T09-A 1
Fe SWA-L01-1313-T01-B 1
Fe SWA-L01-1313-T02-B 1
Fe SWA-L01-1313-T03-B 1
Fe SWA-L01-1313-T04-B 1
Fe SWA-L01-1313-T05-B 1
Fe SWA-L01-1313-T06-B 1
Fe SWA-L01-1313-T07-B 1
Fe SWA-L01-1313-T08-B 1
Fe SWA-L01-1313-T09-B 1
Fe SWA-L01-1313-T01-C 1
Fe SWA-L01-1313-T02-C 1
Fe SWA-L01-1313-T03-C 1
Fe SWA-L01-1313-T04-C 1
Fe SWA-L01-1313-T05-C 1
Fe SWA-L01-1313-T06-C 1
Fe SWA-L01-1313-T07-C 1
Fe SWA-L01-1313-T08-C 1
Fe SWA-L01-1313-T09-C 1
Fe SWA-L01-1313-B01-A 1
Fe SWA-L01-1313-B02-A 1
Fe SWA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.40E+02
1.00E+02
2.69E+01
3.93E+01
1.97E+01
2.91E+01
2.76E+04
9.94E+04
1.32E+05
1.49E+02
1.01E+02
1.89E+01
1.61E+01
2.34E+01
1.42E+01
3.26E+04
9.93E+04
1.29E+05
9.73E+01
9.97E+01
1.67E+01
1.77E+01
1.55E+01
4.96E+01
8.57E+03
1.01E+05
1.31E+05
1.00E+00 U1/2
1.00E+00 U1/2
3.40E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.40E+02 6.4E+00 2.0E+00 6.4E+00
1.00E+02 6.1E-01 2.0E+00 6.4E+00 1000 100
2.69E+01 1.8E+00 2.0E+00 6.4E+00
3.93E+01 1.9E+00 2.0E+00 6.4E+00
1.97E+01 1.4E+01 2.0E+00 6.4E+00
2.91 E+01 1.1E+01 2.0E+00 6.4E+00
2.76E+04 1.2E+00 2.0E+00 6.4E+00
9.94E+04 7.2E-01 2.0E+00 6.4E+00
1.32E+05 4.8E+00 2.0E+00 6.4E+00
1.49E+02 1.4E+00 2.0E+00 6.4E+00
1.01E+02 5.2E-01 2.0E+00 6.4E+00
1.89E+01 2.4E+00 2.0E+00 6.4E+00
1.61 E+01 6.5E+00 2.0E+00 6.4E+00
2.34E+01 5.1E+00 2.0E+00 6.4E+00
1.42E+01 4.6E+00 2.0E+00 6.4E+00
3.26E+04 9.5E-01 2.0E+00 6.4E+00
9.93E+04 1.1E+00 2.0E+00 6.4E+00
1.29E+05 4.9E+00 2.0E+00 6.4E+00
9.73E+01 1.2E+00 2.0E+00 6.4E+00
9.97E+01 3.3E-01 2.0E+00 6.4E+00 1000 100
1.67E+01 6.1E-01 2.0E+00 6.4E+00
1.77E+01 1.4E+00 2.0E+00 6.4E+00
1.55E+01 3.7E+00 2.0E+00 6.4E+00
4.96E+01 2.5E+00 2.0E+00 6.4E+00
8.57E+03 6.5E-01 2.0E+00 6.4E+00
1.01E+05 3.7E-01 2.0E+00 6.4E+00
1.31E+05 2.8E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+02 2.0E+00 6.4E+00
1.00E+00 2.2E+00 2.0E+00 6.4E+00
3.40E+00 5.5E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.16E+03 106% VU ICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.16E+03 106% VU ICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-363
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb SWA-L01-1313-T01-A 1
Pb SWA-L01-1313-T02-A 1
Pb SWA-L01-1313-T03-A 1
Pb SWA-L01-1313-T04-A 1
Pb SWA-L01-1313-T05-A 1
Pb SWA-L01-1313-T06-A 1
Pb SWA-L01-1313-T07-A 1
Pb SWA-L01-1313-T08-A 1
Pb SWA-L01-1313-T09-A 1
Pb SWA-L01-1313-T01-B 1
Pb SWA-L01-1313-T02-B 1
Pb SWA-L01-1313-T03-B 1
Pb SWA-L01-1313-T04-B 1
Pb SWA-L01-1313-T05-B 1
Pb SWA-L01-1313-T06-B 1
Pb SWA-L01-1313-T07-B 1
Pb SWA-L01-1313-T08-B 1
Pb SWA-L01-1313-T09-B 1
Pb SWA-L01-1313-T01-C 1
Pb SWA-L01-1313-T02-C 1
Pb SWA-L01-1313-T03-C 1
Pb SWA-L01-1313-T04-C 1
Pb SWA-L01-1313-T05-C 1
Pb SWA-L01-1313-T06-C 1
Pb SWA-L01-1313-T07-C 1
Pb SWA-L01-1313-T08-C 1
Pb SWA-L01-1313-T09-C 1
Pb SWA-L01-1313-B01-A 1
Pb SWA-L01-1313-B02-A 1
Pb SWA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
8.88E+01
1.67E+01 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.46E+02
2.22E+03
1.40E+02
1.96E+01 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
6.82E+00 E
1.73E+02
2.17E+03
1.09E+02
1.20E+01 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.12E+01 E
1.53E+02
2.49E+03
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.88E+01 5.4E+00 6.8E+00 2.2E+01
1.67E+01 1.1E+01 6.8E+00 2.2E+01 10 100
3.40E+00 2.8E+02 6.8E+00 2.2E+01
3.40E+00 4.5E+01 6.8E+00 2.2E+01
3.40E+00 1.6E+02 6.8E+00 2.2E+01
3.40E+00 5.7E+01 6.8E+00 2.2E+01
3.40E+00 4.9E+01 6.8E+00 2.2E+01
1.46E+02 6.5E-01 6.8E+00 2.2E+01
2.22E+03 5.7E-01 6.8E+00 2.2E+01
1.40E+02 3.3E-01 6.8E+00 2.2E+01
1.96E+01 5.6E+00 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
3.40E+00 8.2E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
6.82E+00 4.8E+01 6.8E+00 2.2E+01
1.73E+02 3.8E+00 6.8E+00 2.2E+01
2.17E+03 5.6E-01 6.8E+00 2.2E+01
1.09E+02 2.9E+00 6.8E+00 2.2E+01
1.20E+01 2.4E+01 6.8E+00 2.2E+01 10 100
3.40E+00 2.2E+02 6.8E+00 2.2E+01
3.40E+00 1.1E+04 6.8E+00 2.2E+01
3.40E+00 8.5E+01 6.8E+00 2.2E+01
3.40E+00 3.2E+02 6.8E+00 2.2E+01
1.12E+01 4.3E+01 6.8E+00 2.2E+01
1.53E+02 1.3E+00 6.8E+00 2.2E+01
2.49E+03 2.3E+00 6.8E+00 2.2E+01
3.40E+00 7.5E+01 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.40E+00 6.9E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
9.74E+02 96% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
9.70E+02 96% VUICP-OES 11/1/10 11 :57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-364
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
1 1 ug/L
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Li SWA-L01-1313-T01-A 1 5.16E+00 E 5.16E+00 1 .9E+01 1.9E+00 6.0E+00
Li SWA-L01-1313-T02-A 1 5.78E+00 E 5.78E+00 9.7E+00 1.9E+00 6.0E+00 10 100
Li SWA-L01-1313-T03-A 1 1.21E+02
Li SWA-L01-1313-T04-A 1 6.69E+02
Li SWA-L01-1313-T05-A 1 8.13E+02
Li SWA-L01-1313-T06-A 1 8.41 E+02
Li SWA-L01-1313-T07-A 1 1.15E+03
Li SWA-L01-1313-T08-A 1 6.00E+02
Li SWA-L01-1313-T09-A 1 6.06E+02
1.21 E+02 1.0E+01 1.9E+00 6.0E+00
6.69E+02 1.6E+00 1.9E+00 6.0E+00
8.13E+02 4.0E+00 1.9E+00 6.0E+00
8.41 E+02 3.4E+00 1.9E+00 6.0E+00
1.15E+03 3.4E+00 1.9E+00 6.0E+00
6.00E+02 5.5E+00 1.9E+00 6.0E+00
6.06E+02 2.3E+00 1.9E+00 6.0E+00
Li SWA-L01-1313-T01-B 1 5.40E+00 E 5.40E+00 3.3E+01 1.9E+00 6.0E+00
Li SWA-L01-1313-T02-B 1 5.26E+00 E 5.26E+00 1.3E+01 1.9E+00 6.0E+00
Li SWA-L01-1313-T03-B 1 1.08E+02
Li SWA-L01-1313-T04-B 1 4.75E+02
Li SWA-L01-1313-T05-B 1 6.50E+02
Li SWA-L01-1313-T06-B 1 8.13E+02
Li SWA-L01-1313-T07-B 1 1.18E+03
Li SWA-L01-1313-T08-B 1 6.03E+02
Li SWA-L01-1313-T09-B 1 6.12E+02
Li SWA-L01-1313-T01-C 1 6.90E+00
1.08E+02 6.8E+00 1.9E+00 6.0E+00
4.75E+02 1.6E+00 1.9E+00 6.0E+00
6.50E+02 2.0E+00 1.9E+00 6.0E+00
8.13E+02 8.0E+00 1.9E+00 6.0E+00
1.18E+03 1.1E+00 1.9E+00 6.0E+00
6.03E+02 6.3E+00 1 .9E+00 6.0E+00
6.12E+02 2.8E+00 1 .9E+00 6.0E+00
6.90E+00 1.8E+01 1 .9E+00 6.0E+00
Li SWA-L01-1313-T02-C 1 5.70E+00 E 5.70E+00 4.0E+00 1 .9E+00 6.0E+00 10 100
Li SWA-L01-1313-T03-C 1 1.31 E+02
Li SWA-L01-1313-T04-C 1 4.82E+02
Li SWA-L01-1313-T05-C 1 6.92E+02
Li SWA-L01-1313-T06-C 1 6.60E+02
Li SWA-L01-1313-T07-C 1 1.01E+03
Li SWA-L01-1313-T08-C 1 6.27E+02
Li SWA-L01-1313-T09-C 1 6.20E+02
1.31 E+02 4.9E+00 1 .9E+00 6.0E+00
4.82E+02 7.9E-01 1 .9E+00 6.0E+00
6.92E+02 4.2E+00 1 .9E+00 6.0E+00
6.60E+02 2.0E+00 1 .9E+00 6.0E+00
1.01E+03 2.2E+00 1 .9E+00 6.0E+00
6.27E+02 5.6E+00 1 .9E+00 6.0E+00
6.20E+02 1.5E+01 1 .9E+00 6.0E+00
Li SWA-L01-1313-B01-A 1 4.06E+00 E 4.06E+00 9.0E+00 1 .9E+00 6.0E+00
Li SWA-L01-1313-B02-A 1 4.14E+00 E 4.14E+00 1.3E+01 1 .9E+00 6.0E+00
Li SWA-L01-1313-B03-A 1 4.33E+00 E 4.33E+00 1.1E+01 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
8.22E+02 82% VUICP-OES 1 1/1/10 11:22 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:54AMEPAInterlabL01 1313-1316SWA
VUICP-OES 11/1/1011:55AMEPAInterlabL01 1313-1316SWA
8.17E+02 81% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:59AMEPAInterlabL01 1313-1316SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:16AMEPAInterlabL01 1313-1316SWA
VUICP-OES 11/1/1011:18AMEPAInterlabL01 1313-1316SWA
VUICP-OES 11/1/1011:19AMEPAInterlabL01 1313-1316SWA
                                                                                                                                                                          1-365
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Mn SWA-L01-1313-T01-A 1 1.00E+OOU1/2 1.00E+00 1 .OE+01 2.0E+00 6.4E+00
Mn SWA-L01-1313-T02-A 1 1.00E+OOU1/2 1.00E+00 1 JE+01 2.0E+00 6.4E+00 10 100
Mn SWA-L01-1313-T03-A 1 1.00E+OOU1/2 1.00E+00 6.1E+01 2.0E+00 6.4E+00
Mn SWA-L01-1313-T04-A 1 1.59E+02
Mn SWA-L01-1313-T05-A 1 3.36E+03
Mn SWA-L01-1313-T06-A 1 9.15E+03
Mn SWA-L01-1313-T07-A 1 2.34E+04
Mn SWA-L01-1313-T08-A 1 1.51E+04
Mn SWA-L01-1313-T09-A 1 1.55E+04
1.59E+02 1.1E+00 2.0E+00 6.4E+00
3.36E+03 4.5E-01 2.0E+00 6.4E+00
9.15E+03 3.3E-01 2.0E+00 6.4E+00
2.34E+04 4.4E-01 2.0E+00 6.4E+00
1.51E+04 1.7E+00 2.0E+00 6.4E+00
1.55E+04 6.6E-02 2.0E+00 6.4E+00
Mn SWA-L01-1313-T01-B 1 1.00E+OOU1/2 1.00E+00 1.7E+01 2.0E+00 6.4E+00
Mn SWA-L01-1313-T02-B 1 1.00E+OOU1/2 1.00E+00 2.6E+00 2.0E+00 6.4E+00
Mn SWA-L01-1313-T03-B 1 1.00E+OOU1/2 1.00E+00 7.6E+00 2.0E+00 6.4E+00
Mn SWA-L01-1313-T04-B 1 2.59E+00 E
Mn SWA-L01-1313-T05-B 1 3.81 E+02
Mn SWA-L01-1313-T06-B 1 4.68E+03
Mn SWA-L01-1313-T07-B 1 2.33E+04
Mn SWA-L01-1313-T08-B 1 1.45E+04
Mn SWA-L01-1313-T09-B 1 1.52E+04
2.59E+00 7.6E+00 2.0E+00 6.4E+00
3.81 E+02 5.2E-01 2.0E+00 6.4E+00
4.68E+03 9.3E-01 2.0E+00 6.4E+00
2.33E+04 9.4E-01 2.0E+00 6.4E+00
1.45E+04 5.5E-01 2.0E+00 6.4E+00
1.52E+04 6.6E-01 2.0E+00 6.4E+00
Mn SWA-L01-1313-T01-C 1 1.00E+OOU1/2 1.00E+00 3.2E+01 2.0E+00 6.4E+00
Mn SWA-L01-1313-T02-C 1 1.00E+OOU1/2 1.00E+00 1.2E+01 2.0E+00 6.4E+00 10 100
Mn SWA-L01-1313-T03-C 1 1.00E+OOU1/2 1.00E+00 2.3E+01 2.0E+00 6.4E+00
Mn SWA-L01-1313-T04-C 1 5.26E+00 E
Mn SWA-L01-1313-T05-C 1 3.30E+03
Mn SWA-L01-1313-T06-C 1 3.95E+03
Mn SWA-L01-1313-T07-C 1 1.76E+04
Mn SWA-L01-1313-T08-C 1 1.47E+04
Mn SWA-L01-1313-T09-C 1 1.55E+04
5.26E+00 7.3E-01 2.0E+00 6.4E+00
3.30E+03 7.8E-01 2.0E+00 6.4E+00
3.95E+03 3.7E-01 2.0E+00 6.4E+00
1.76E+04 2.2E-01 2.0E+00 6.4E+00
1.47E+04 8.6E-01 2.0E+00 6.4E+00
1.55E+04 2.3E+00 2.0E+00 6.4E+00
Mn SWA-L01-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 2.8E+01 2.0E+00 6.4E+00
Mn SWA-L01-1313-B02-A 1 1.00E+OOU1/2 1.00E+00 3.4E+01 2.0E+00 6.4E+00
Mn SWA-L01-1313-B03-A 1 1.00E+OOU1/2 1.00E+00 1 .OE+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316 SWA
1.02E+03 102% VU ICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.01E+03 101% VUICP-OES 11/1/10 11 :57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-366
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone.
1 ug/L
Mg SWA-L01-1313-T01-A 1 6.02E+00
Mg SWA-L01-1313-T02-A 1 4.19E+00
Mg SWA-L01-1313-T03-A 1 1.57E+03
Mg SWA-L01-1313-T04-A 1 7.31 E+05
Mg SWA-L01-1313-T05-A 1 1.09E+06
Mg SWA-L01-1313-T06-A 1 1.20E+06
Mg SWA-L01-1313-T07-A 1 1.60E+06
Mg SWA-L01-1313-T08-A 1 7.70E+05
Mg SWA-L01-1313-T09-A 1 6.62E+05
Mg SWA-L01-1313-T01-B 1 4.54E+01
Mg SWA-L01-1313-T02-B 1 8.29E+00
Mg SWA-L01-1313-T03-B 1 1.45E+03
Mg SWA-L01-1313-T04-B 1 3.66E+05
Mg SWA-L01-1313-T05-B 1 7.66E+05
Mg SWA-L01-1313-T06-B 1 1.10E+06
Mg SWA-L01-1313-T07-B 1 1.56E+06
Mg SWA-L01-1313-T08-B 1 7.47E+05
Mg SWA-L01-1313-T09-B 1 6.50E+05
Mg SWA-L01-1313-T01-C 1 2.32E+01
Mg SWA-L01-1313-T02-C 1 6.44E+00
Mg SWA-L01-1313-T03-C 1 2.64E+03
Mg SWA-L01-1313-T04-C 1 4.20E+05
Mg SWA-L01-1313-T05-C 1 9. 11 E+05
Mg SWA-L01-1313-T06-C 1 9.26E+05
Mg SWA-L01-1313-T07-C 1 1.37E+06
Mg SWA-L01-1313-T08-C 1 7.54E+05
Mg SWA-L01-1313-T09-C 1 6.59E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.02E+00 1.1E+02 1.0E+00 3.2E+00
4.19E+00 1.9E+02 1.0E+00 3.2E+00 1000 100
1.57E+03 6.1E-01 1.0E+00 3.2E+00
7.31E+05 2.0E+00 1.0E+00 3.2E+00
1.09E+06 4.8E-01 1.0E+00 3.2E+00
1.20E+06 8.6E-01 1.0E+00 3.2E+00
1.60E+06 4.7E-01 1.0E+00 3.2E+00
7.70E+05 1.4E+00 1.0E+00 3.2E+00
6.62E+05 5.7E-01 1.0E+00 3.2E+00
4.54E+01 3.9E+01 1.0E+00 3.2E+00
8.29E+00 7.5E+01 1.0E+00 3.2E+00
1.45E+03 2.9E-01 1.0E+00 3.2E+00
3.66E+05 1.3E+00 1.0E+00 3.2E+00
7.66E+05 9.7E-01 1.0E+00 3.2E+00
1.10E+06 1.0E+00 1.0E+00 3.2E+00
1.56E+06 9.9E-01 1.0E+00 3.2E+00
7.47E+05 8.1E-01 1.0E+00 3.2E+00
6.50E+05 3.2E-01 1.0E+00 3.2E+00
2.32E+01 4.5E+01 1.0E+00 3.2E+00
6.44E+00 1.8E+02 1.0E+00 3.2E+00 1000 100
2.64E+03 1.3E+00 1.0E+00 3.2E+00
4.20E+05 3.1E-01 1.0E+00 3.2E+00
9.11E+05 7.0E-01 1.0E+00 3.2E+00
9.26E+05 3.6E-01 1.0E+00 3.2E+00
1.37E+06 1.1E+00 1.0E+00 3.2E+00
7.54E+05 6.4E-01 1.0E+00 3.2E+00
6.59E+05 2.4E+00 1.0E+00 3.2E+00
Mg SWA-L01-1313-B01-A 1 1.87E+OOE 1.87E+00 1.2E+02 1.0E+00 3.2E+00
Mg SWA-L01-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 5.9E+01 1.0E+00 3.2E+00
Mg SWA-L01-1313-B03-A 1 1.12E+OOE 1.12E+00 3.6E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.00E+03 100% VU ICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:34 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316 SWA
9.88E+02 98% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-367
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 1 ug/L
Mo SWA-L01-1313-T01-A 1 1.35E+02
Mo SWA-L01-1313-T02-A 1 1.40E+02
Mo SWA-L01-1313-T03-A 1 1.50E+02
Mo SWA-L01-1313-T04-A 1 1.49E+02
Mo SWA-L01-1313-T05-A 1 1.28E+02
Mo SWA-L01-1313-T06-A 1 1.03E+02
Mo SWA-L01-1313-T07-A 1 2.65E+01
Mo SWA-L01-1313-T08-A 1 1.35E+01
Mo SWA-L01-1313-T09-A 1 6.75E+00
Mo SWA-L01-1313-T01-B 1 1.42E+02
Mo SWA-L01-1313-T02-B 1 1.49E+02
Mo SWA-L01-1313-T03-B 1 1.52E+02
Mo SWA-L01-1313-T04-B 1 1.51E+02
Mo SWA-L01-1313-T05-B 1 1.40E+02
Mo SWA-L01-1313-T06-B 1 1.20E+02
Mo SWA-L01-1313-T07-B 1 2.98E+01
Mo SWA-L01-1313-T08-B 1 1.27E+01
Mo SWA-L01-1313-T09-B 1 6.74E+00
Mo SWA-L01-1313-T01-C 1 1 .44E+02
Mo SWA-L01-1313-T02-C 1 1.41E+02
Mo SWA-L01-1313-T03-C 1 1 .38E+02
Mo SWA-L01-1313-T04-C 1 1 .49E+02
Mo SWA-L01-1313-T05-C 1 1.19E+02
Mo SWA-L01-1313-T06-C 1 1.15E+02
Mo SWA-L01-1313-T07-C 1 2.95E+01
Mo SWA-L01-1313-T08-C 1 1.17E+01
Mo SWA-L01-1313-T09-C 1 5.54E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.35E+02 6.2E-01 1.2E+00 3.8E+00
1.40E+02 1.5E+00 1.2E+00 3.8E+00 10 100
1.50E+02 1.8E+00 1.2E+00 3.8E+00
1.49E+02 9.7E-01 1.2E+00 3.8E+00
1.28E+02 1.4E+00 1.2E+00 3.8E+00
1.03E+02 2.4E+00 1.2E+00 3.8E+00
2.65E+01 1.1E+01 1.2E+00 3.8E+00
1.35E+01 8.4E+00 1.2E+00 3.8E+00
6.75E+00 3.1E+01 1.2E+00 3.8E+00
1.42E+02 1.2E+00 1.2E+00 3.8E+00
1.49E+02 1.1E+00 1.2E+00 3.8E+00
1.52E+02 1.0E+00 1.2E+00 3.8E+00
1.51E+02 6.6E-01 1.2E+00 3.8E+00
1.40E+02 1.2E+00 1.2E+00 3.8E+00
1.20E+02 7.2E-01 1.2E+00 3.8E+00
2.98E+01 1.3E+01 1.2E+00 3.8E+00
1.27E+01 8.1E+00 1.2E+00 3.8E+00
6.74E+00 3.7E+01 1.2E+00 3.8E+00
1.44E+02 1.2E+00 1.2E+00 3.8E+00
1.41E+02 5.3E-01 1.2E+00 3.8E+00 10 100
1.38E+02 8.1E-01 1.2E+00 3.8E+00
1.49E+02 1.3E+00 1.2E+00 3.8E+00
1.19E+02 2.8E+00 1.2E+00 3.8E+00
1.15E+02 3.0E+00 1.2E+00 3.8E+00
2.95E+01 1.1E+01 1.2E+00 3.8E+00
1.17E+01 1.2E+01 1.2E+00 3.8E+00
5.54E+00 3.4E+01 1.2E+00 3.8E+00
Mo SWA-L01-1313-B01-A 1 1.60E+OOE 1.60E+00 4.1E+01 1.2E+00 3.8E+00
Mo SWA-L01-1313-B02-A 1 1.98E+OOE 1.98E+00 9.2E+00 1.2E+00 3.8E+00
Mo SWA-L01-1313-B03-A 1 3.95E+00
3.95E+00 1.5E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.17E+03 103% VU ICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:34 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316 SWA
1.17E+03 103% VU ICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-368
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L01-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 1.4E+02 1.8E+00 5.7E+00
Ni SWA-L01-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 6.2E+01 1.8E+00 5.7E+00 10 100
Ni SWA-L01-1313-T03-A 1 3.29E+00 E
Ni SWA-L01-1313-T04-A 1 1.12E+01
Ni SWA-L01-1313-T05-A 1 3.29E+01
Ni SWA-L01-1313-T06-A 1 1.08E+02
Ni SWA-L01-1313-T07-A 1 3.99E+02
Ni SWA-L01-1313-T08-A 1 3.23E+02
Ni SWA-L01-1313-T09-A 1 3.38E+02
3.29E+00 3.1E+01 1.8E+00 5.7E+00
1.12E+01 1.5E+01 1.8E+00 5.7E+00
3.29E+01 1.1E+01 1.8E+00 5.7E+00
1.08E+02 3.7E+00 1.8E+00 5.7E+00
3.99E+02 6.1E-01 1.8E+00 5.7E+00
3.23E+02 2.0E-01 1.8E+00 5.7E+00
3.38E+02 3.6E-01 1.8E+00 5.7E+00
Ni SWA-L01-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 1.9E+01 1.8E+00 5.7E+00
Ni SWA-L01-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 7.4E+01 1.8E+00 5.7E+00
Ni SWA-L01-1313-T03-B 1 4.53E+00 E
Ni SWA-L01-1313-T04-B 1 7.23E+00
Ni SWA-L01-1313-T05-B 1 1.48E+01
Ni SWA-L01-1313-T06-B 1 4.62E+01
Ni SWA-L01-1313-T07-B 1 4.24E+02
Ni SWA-L01-1313-T08-B 1 3.16E+02
Ni SWA-L01-1313-T09-B 1 3.32E+02
4.53E+00 3.3E+01 1.8E+00 5.7E+00
7.23E+00 4.6E+01 1.8E+00 5.7E+00
1.48E+01 1.9E+01 1.8E+00 5.7E+00
4.62E+01 1.9E+00 1.8E+00 5.7E+00
4.24E+02 1.2E+00 1.8E+00 5.7E+00
3.16E+02 5.7E-01 1.8E+00 5.7E+00
3.32E+02 3.7E-01 1.8E+00 5.7E+00
Ni SWA-L01-1313-T01-C 1 9.00E-01 U1/2 9.00E-01 5.8E+01 1.8E+00 5.7E+00
Ni SWA-L01-1313-T02-C 1 9.00E-01 U1/2 9.00E-01 6.1E+02 1.8E+00 5.7E+00 10 100
Ni SWA-L01-1313-T03-C 1 2.93E+00 E
Ni SWA-L01-1313-T04-C 1 7.54E+00
Ni SWA-L01-1313-T05-C 1 2.60E+01
Ni SWA-L01-1313-T06-C 1 3.16E+01
Ni SWA-L01-1313-T07-C 1 3.08E+02
Ni SWA-L01-1313-T08-C 1 3.19E+02
Ni SWA-L01-1313-T09-C 1 3.36E+02
2.93E+00 3.9E+01 1.8E+00 5.7E+00
7.54E+00 1.6E+01 1.8E+00 5.7E+00
2.60E+01 3.7E+00 1.8E+00 5.7E+00
3.16E+01 2.9E+00 1.8E+00 5.7E+00
3.08E+02 3.0E-01 1.8E+00 5.7E+00
3.19E+02 4.3E-01 1.8E+00 5.7E+00
3.36E+02 2.3E+00 1.8E+00 5.7E+00
Ni SWA-L01-1313-B01-A 1 9.00E-01 U1/2 9.00E-01 4.0E+01 1.8E+00 5.7E+00
Ni SWA-L01-1313-B02-A 1 9.00E-01 U1/2 9.00E-01 1.6E+02 1.8E+00 5.7E+00
Ni SWA-L01-1313-B03-A 1 9.00E-01 U1/2 9.00E-01 9.7E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316 SWA
9.87E+02 99% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:37 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1011:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316 SWA
9.86E+02 98% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/1012:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                          1-369
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
P SWA-L01-1313-T01-A 1 U1/2 O.OOE+00 2.2E+00 3.7E+00 1.2E+01
P SWA-L01-1313-T02-A 1 U1/2 O.OOE+00 3.8E+01 3.7E+00 1.2E+01 1000 100
P SWA-L01-1313-T03-A 1 U1/2 O.OOE+00 1 .OE+01 3.7E+00 1.2E+01
P SWA-L01-1313-T04-A 1 U1/2 O.OOE+00 6.6E+00 3.7E+00 1.2E+01
P SWA-L01-1313-T05-A 1 U1/2 O.OOE+00 2.0E+01 3.7E+00 1.2E+01
P SWA-L01-1313-T06-A 1 U1/2 O.OOE+00 2.1E+01 3.7E+00 1.2E+01
P SWA-L01-1313-T07-A 1 U1/2 O.OOE+00 8.3E+01 3.7E+00 1.2E+01
P SWA-L01-1313-T08-A 1 U1/2 O.OOE+00 1 .4E+00 3.7E+00 1.2E+01
P SWA-L01-1313-T09-A 1 U1/2 O.OOE+00 1 .OE+00 3.7E+00 1.2E+01
P SWA-L01-1313-T01-B 1 U1/2 O.OOE+00 2.8E+00 3.7E+00 1.2E+01
P SWA-L01-1313-T02-B 1 U1/2 O.OOE+00 2.6E+01 3.7E+00 1.2E+01
P SWA-L01-1313-T03-B 1 U1/2 O.OOE+00 1 .2E+02 3.7E+00 1.2E+01
P SWA-L01-1313-T04-B 1 U1/2 O.OOE+00 1 .8E+01 3.7E+00 1.2E+01
P SWA-L01-1313-T05-B 1 U1/2 O.OOE+00 1 .9E+01 3.7E+00 1.2E+01
P SWA-L01-1313-T06-B 1 U1/2 O.OOE+00 1 JE+01 3.7E+00 1.2E+01
P SWA-L01-1313-T07-B 1 U1/2 O.OOE+00 2.2E+01 3.7E+00 1.2E+01
P SWA-L01-1313-T08-B 1 U1/2 O.OOE+00 1 .5E+00 3.7E+00 1.2E+01
P SWA-L01-1313-T09-B 1 U1/2 O.OOE+00 4.7E-01 3.7E+00 1.2E+01
P SWA-L01-1313-T01-C 1 U1/2 O.OOE+00 3.6E+00 3.7E+00 1.2E+01
P SWA-L01-1313-T02-C 1 U1/2 O.OOE+00 3.0E+01 3.7E+00 1 .2E+01 1000 100
P SWA-L01-1313-T03-C 1 U1/2 O.OOE+00 5.6E+01 3.7E+00 1 .2E+01
P SWA-L01-1313-T04-C 1 U1/2 O.OOE+00 2.7E+01 3.7E+00 1 .2E+01
P SWA-L01-1313-T05-C 1 U1/2 O.OOE+00 1 .9E+01 3.7E+00 1 .2E+01
P SWA-L01-1313-T06-C 1 U1/2 O.OOE+00 4.5E+01 3.7E+00 1 .2E+01
P SWA-L01-1313-T07-C 1 U1/2 O.OOE+00 4.0E+01 3.7E+00 1 .2E+01
P SWA-L01-1313-T08-C 1 U1/2 O.OOE+00 2.5E+00 3.7E+00 1 .2E+01
P SWA-L01-1313-T09-C 1 U1/2 O.OOE+00 2.5E+00 3.7E+00 1 .2E+01
P SWA-L01-1313-B01-A 1 U1/2 O.OOE+00 6.8E+01 3.7E+00 1 .2E+01
P SWA-L01-1313-B02-A 1 U1/2 O.OOE+00 2.6E+01 3.7E+00 1 .2E+01
P SWA-L01-1313-B03-A 1 U1/2 O.OOE+00 2.2E+01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.18E+03 118% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.19E+03 119% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-370
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone. Qu
K SWA-L01-1313-T01-A 1 3.77E+05
K SWA-L01-1313-T02-A 1 2.76E+05
K SWA-L01-1313-T03-A 1 3.82E+05
K SWA-L01-1313-T04-A 1 4.12E+05
K SWA-L01-1313-T05-A 1 4.23E+05
K SWA-L01-1313-T06-A 1 4.29E+05
K SWA-L01-1313-T07-A 1 4.64E+05
K SWA-L01-1313-T08-A 1 2.20E+05
K SWA-L01-1313-T09-A 1 2.43E+05
K SWA-L01-1313-T01-B 1 1.80E+06
K SWA-L01-1313-T02-B 1 2.83E+05
K SWA-L01-1313-T03-B 1 3.79E+05
K SWA-L01-1313-T04-B 1 4.16E+05
K SWA-L01-1313-T05-B 1 3.95E+05
K SWA-L01-1313-T06-B 1 4.05E+05
K SWA-L01-1313-T07-B 1 4.64E+05
K SWA-L01-1313-T08-B 1 2.39E+05
K SWA-L01-1313-T09-B 1 2.60E+05
K SWA-L01-1313-T01-C 1 1.72E+06
K SWA-L01-1313-T02-C 1 2.73E+05
K SWA-L01-1313-T03-C 1 3.63E+05
K SWA-L01-1313-T04-C 1 3.96E+05
K SWA-L01-1313-T05-C 1 3.85E+05
K SWA-L01-1313-T06-C 1 3.85E+05
K SWA-L01-1313-T07-C 1 4.26E+05
K SWA-L01-1313-T08-C 1 2.43E+05
K SWA-L01-1313-T09-C 1 2.49E+05
K SWA-L01-1313-B01-A 1 1.78E+01
K SWA-L01-1313-B02-A 1 9.14E+00
K SWA-L01-1313-B03-A 1 4.31 E+04
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.77E+05 2.5E-01 1.6E+00 5.1E+00
2.76E+05 4.1E-01 1.6E+00 5.1E+00 1000 100
3.82E+05 8.1E-01 1.6E+00 5.1E+00
4.12E+05 1.3E+00 1.6E+00 5.1E+00
4.23E+05 2.1E+00 1.6E+00 5.1E+00
4.29E+05 2.9E+00 1.6E+00 5.1E+00
4.64E+05 3.4E+00 1.6E+00 5.1E+00
2.20E+05 9.5E-01 1.6E+00 5.1E+00
2.43E+05 1.2E+01 1.6E+00 5.1E+00
1.80E+06 5.0E-01 1.6E+00 5.1E+00
2.83E+05 1.1E+00 1.6E+00 5.1E+00
3.79E+05 4.3E-01 1.6E+00 5.1E+00
4.16E+05 3.9E+00 1.6E+00 5.1E+00
3.95E+05 3.4E-01 1.6E+00 5.1E+00
4.05E+05 9.4E-01 1.6E+00 5.1E+00
4.64E+05 8.4E+00 1.6E+00 5.1E+00
2.39E+05 7.1E+00 1.6E+00 5.1E+00
2.60E+05 1.0E+01 1.6E+00 5.1E+00
1.72E+06 8.7E-01 1.6E+00 5.1E+00
2.73E+05 1.5E+00 1.6E+00 5.1E+00 1000 100
3.63E+05 1.1E-01 1.6E+00 5.1E+00
3.96E+05 1.8E+00 1.6E+00 5.1E+00
3.85E+05 5.9E-01 1.6E+00 5.1E+00
3.85E+05 1.1E+00 1.6E+00 5.1E+00
4.26E+05 3.3E+00 1.6E+00 5.1E+00
2.43E+05 4.9E+00 1.6E+00 5.1E+00
2.49E+05 2.7E+00 1.6E+00 5.1E+00
1.78E+01 9.5E+00 1.6E+00 5.1E+00
9.14E+00 2.2E+01 1.6E+00 5.1E+00
4.31 E+04 6.5E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
2.77E+05 85% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
2.74E+05 88% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-371
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
1 ug/L
Se SWA-L01-1313-T01-A 1 9.58E+04
Se SWA-L01-1313-T02-A 1 9.81 E+04
Se SWA-L01-1313-T03-A 1 1.02E+05
Se SWA-L01-1313-T04-A 1 1.25E+05
Se SWA-L01-1313-T05-A 1 1.28E+05
Se SWA-L01-1313-T06-A 1 1.27E+05
Se SWA-L01-1313-T07-A 1 1.30E+05
Se SWA-L01-1313-T08-A 1 4.90E+04
Se SWA-L01-1313-T09-A 1 3.46E+04
Se SWA-L01-1313-T01-B 1 9.89E+04
Se SWA-L01-1313-T02-B 1 1.02E+05
Se SWA-L01-1313-T03-B 1 1.03E+05
Se SWA-L01-1313-T04-B 1 1.16E+05
Se SWA-L01-1313-T05-B 1 1.19E+05
Se SWA-L01-1313-T06-B 1 1.24E+05
Se SWA-L01-1313-T07-B 1 1.27E+05
Se SWA-L01-1313-T08-B 1 4.83E+04
Se SWA-L01-1313-T09-B 1 3.45E+04
Se SWA-L01-1313-T01-C 1 1 .03E+05
Se SWA-L01-1313-T02-C 1 9.79E+04
Se SWA-L01-1313-T03-C 1 9.79E+04
Se SWA-L01-1313-T04-C 1 1.14E+05
Se SWA-L01-1313-T05-C 1 1.13E+05
Se SWA-L01-1313-T06-C 1 1.12E+05
Se SWA-L01-1313-T07-C 1 1.21E+05
Se SWA-L01-1313-T08-C 1 4.88E+04
Se SWA-L01-1313-T09-C 1 3.64E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.58E+04 3.6E-01 1.5E+01 4.8E+01
9.81E+04 4.1E-01 1.5E+01 4.8E+01 10 100
1.02E+05 4.0E-01 1.5E+01 4.8E+01
1.25E+05 1.2E+00 1.5E+01 4.8E+01
1.28E+05 2.3E-01 1.5E+01 4.8E+01
1.27E+05 3.7E-01 1.5E+01 4.8E+01
1.30E+05 8.1E-01 1.5E+01 4.8E+01
4.90E+04 1.0E+00 1.5E+01 4.8E+01
3.46E+04 2.9E-01 1.5E+01 4.8E+01
9.89E+04 5.0E-01 1.5E+01 4.8E+01
1.02E+05 8.8E-01 1.5E+01 4.8E+01
1.03E+05 1.5E-01 1.5E+01 4.8E+01
1.16E+05 1.7E-01 1.5E+01 4.8E+01
1.19E+05 2.7E-01 1.5E+01 4.8E+01
1.24E+05 8.5E-01 1.5E+01 4.8E+01
1.27E+05 7.5E-01 1.5E+01 4.8E+01
4.83E+04 6.5E-01 1.5E+01 4.8E+01
3.45E+04 5.7E-01 1.5E+01 4.8E+01
1.03E+05 1.3E+00 1.5E+01 4.8E+01
9.79E+04 3.1E-01 1.5E+01 4.8E+01 10 100
9.79E+04 2.3E-01 1.5E+01 4.8E+01
1.14E+05 5.1E-01 1.5E+01 4.8E+01
1.13E+05 7.9E-01 1.5E+01 4.8E+01
1.12E+05 4.5E-01 1.5E+01 4.8E+01
1.21E+05 4.3E-01 1.5E+01 4.8E+01
4.88E+04 2.5E-01 1.5E+01 4.8E+01
3.64E+04 3.1E+00 1.5E+01 4.8E+01
Se SWA-L01-1313-B01-A 1 7.50E+00 U1/2 7.50E+00 3.3E+02 1.5E+01 4.8E+01
Se SWA-L01-1313-B02-A 1 7.50E+00 U1/2 7.50E+00 4.4E+02 1.5E+01 4.8E+01
Se SWA-L01-1313-B03-A 1 7.50E+00 U1/2 7.50E+00 3.3E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
9.90E+04 93% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:34 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316 SWA
9.87E+04 85% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                          1-372
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-L01-1313-T01-A 1
Si SWA-L01-1313-T02-A 1
Si SWA-L01-1313-T03-A 1
Si SWA-L01-1313-T04-A 1
Si SWA-L01-1313-T05-A 1
Si SWA-L01-1313-T06-A 1
Si SWA-L01-1313-T07-A 1
Si SWA-L01-1313-T08-A 1
Si SWA-L01-1313-T09-A 1
Si SWA-L01-1313-T01-B 1
Si SWA-L01-1313-T02-B 1
Si SWA-L01-1313-T03-B 1
Si SWA-L01-1313-T04-B 1
Si SWA-L01-1313-T05-B 1
Si SWA-L01-1313-T06-B 1
Si SWA-L01-1313-T07-B 1
Si SWA-L01-1313-T08-B 1
Si SWA-L01-1313-T09-B 1
Si SWA-L01-1313-T01-C 1
Si SWA-L01-1313-T02-C 1
Si SWA-L01-1313-T03-C 1
Si SWA-L01-1313-T04-C 1
Si SWA-L01-1313-T05-C 1
Si SWA-L01-1313-T06-C 1
Si SWA-L01-1313-T07-C 1
Si SWA-L01-1313-T08-C 1
Si SWA-L01-1313-T09-C 1
Si SWA-L01-1313-B01-A 1
Si SWA-L01-1313-B02-A 1
Si SWA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
9.27E+03
5.51 E+03
1.55E+03
1.27E+03
9.28E+02
1.61 E+03
2.90E+03
1.27E+04
3.81 E+03
1.02E+04
5.85E+03
1.53E+03
1.17E+03
7.89E+02
1.23E+03
2.49E+03
1.25E+04
3.81 E+03
9.66E+03
5.88E+03
1 .60E+03
9.80E+02
6.98E+02
8.55E+02
1.90E+03
1.22E+04
2.36E+03
5.50E-01 U1/2
3.64E+00
1.94E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.27E+03 1.4E+00 1.1E+00 3.5E+00
5.51E+03 7.0E-01 1.1E+00 3.5E+00 1000 100
1.55E+03 3.9E-01 1.1E+00 3.5E+00
1.27E+03 1.3E+00 1.1E+00 3.5E+00
9.28E+02 1.2E+01 1.1E+00 3.5E+00
1.61 E+03 1.6E+01 1.1E+00 3.5E+00
2.90E+03 3.1E+00 1.1E+00 3.5E+00
1.27E+04 7.4E-01 1.1E+00 3.5E+00
3.81 E+03 7.4E-01 1.1E+00 3.5E+00
1.02E+04 5.9E+00 1.1E+00 3.5E+00
5.85E+03 7.5E-01 1.1E+00 3.5E+00
1.53E+03 7.7E-01 1.1E+00 3.5E+00
1.17E+03 2.1E+00 1.1E+00 3.5E+00
7.89E+02 2.2E+00 1.1E+00 3.5E+00
1.23E+03 8.5E-01 1.1E+00 3.5E+00
2.49E+03 4.2E+00 1.1E+00 3.5E+00
1.25E+04 3.8E-01 1.1E+00 3.5E+00
3.81E+03 3.2E-01 1.1E+00 3.5E+00
9.66E+03 1.1E+00 1.1E+00 3.5E+00
5.88E+03 6.7E-01 1.1E+00 3.5E+00 1000 100
1.60E+03 3.2E-01 1.1E+00 3.5E+00
9.80E+02 6.8E-01 1.1E+00 3.5E+00
6.98E+02 8.3E+00 1.1E+00 3.5E+00
8.55E+02 8.1E-01 1.1E+00 3.5E+00
1.90E+03 5.9E+00 1.1E+00 3.5E+00
1.22E+04 1.8E-01 1.1E+00 3.5E+00
2.36E+03 2.6E+00 1.1E+00 3.5E+00
5.50E-01 8.9E+01 1.1E+00 3.5E+00
3.64E+00 5.8E+00 1.1E+00 3.5E+00
1.94E+02 2.1E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
6.39E+03 88% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:34 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:41 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316 SWA
6.72E+03 85% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-373
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qu
Na SWA-L01-1313-T01-A 1 4.13E+05
Na SWA-L01-1313-T02-A 1 3.43E+05
Na SWA-L01-1313-T03-A 1 3.60E+05
Na SWA-L01-1313-T04-A 1 3.50E+05
Na SWA-L01-1313-T05-A 1 3.41 E+05
Na SWA-L01-1313-T06-A 1 3.41 E+05
Na SWA-L01-1313-T07-A 1 3.34E+05
Na SWA-L01-1313-T08-A 1 3.38E+05
Na SWA-L01-1313-T09-A 1 3.33E+05
Na SWA-L01-1313-T01-B 1 3.15E+05
Na SWA-L01-1313-T02-B 1 3.46E+05
Na SWA-L01-1313-T03-B 1 3.63E+05
Na SWA-L01-1313-T04-B 1 3.50E+05
Na SWA-L01-1313-T05-B 1 3.47E+05
Na SWA-L01-1313-T06-B 1 3.41 E+05
Na SWA-L01-1313-T07-B 1 3.37E+05
Na SWA-L01-1313-T08-B 1 3.36E+05
Na SWA-L01-1313-T09-B 1 3.37E+05
Na SWA-L01-1313-T01-C 1 3.27E+05
Na SWA-L01-1313-T02-C 1 3.43E+05
Na SWA-L01-1313-T03-C 1 3.56E+05
Na SWA-L01-1313-T04-C 1 3.51 E+05
Na SWA-L01-1313-T05-C 1 3.43E+05
Na SWA-L01-1313-T06-C 1 3.41 E+05
Na SWA-L01-1313-T07-C 1 3.40E+05
Na SWA-L01-1313-T08-C 1 3.37E+05
Na SWA-L01-1313-T09-C 1 3.38E+05
Na SWA-L01-1313-B01-A 1 2.78E+01
Na SWA-L01-1313-B02-A 1 3.04E+00 E
Na SWA-L01-1313-B03-A 1 4.04E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.13E+05 3.1E-01 2.5E+00 8.0E+00
3.43E+05 5.1E-01 2.5E+00 8.0E+00 1000 100
3.60E+05 8.3E-01 2.5E+00 8.0E+00
3.50E+05 1.5E+00 2.5E+00 8.0E+00
3.41 E+05 5.8E-01 2.5E+00 8.0E+00
3.41 E+05 1.3E-01 2.5E+00 8.0E+00
3.34E+05 7.8E-01 2.5E+00 8.0E+00
3.38E+05 4.9E-01 2.5E+00 8.0E+00
3.33E+05 4.7E-01 2.5E+00 8.0E+00
3.15E+05 3.6E-01 2.5E+00 8.0E+00
3.46E+05 7.3E-01 2.5E+00 8.0E+00
3.63E+05 5.2E-01 2.5E+00 8.0E+00
3.50E+05 1.2E+00 2.5E+00 8.0E+00
3.47E+05 6.6E-01 2.5E+00 8.0E+00
3.41 E+05 1.2E+00 2.5E+00 8.0E+00
3.37E+05 9.3E-01 2.5E+00 8.0E+00
3.36E+05 6.8E-02 2.5E+00 8.0E+00
3.37E+05 5.0E-01 2.5E+00 8.0E+00
3.27E+05 8.7E-01 2.5E+00 8.0E+00
3.43E+05 4.7E-01 2.5E+00 8.0E+00 1000 100
3.56E+05 3.9E-01 2.5E+00 8.0E+00
3.51 E+05 1.4E+00 2.5E+00 8.0E+00
3.43E+05 7.1E-01 2.5E+00 8.0E+00
3.41 E+05 2.2E-01 2.5E+00 8.0E+00
3.40E+05 1.9E-01 2.5E+00 8.0E+00
3.37E+05 9.2E-01 2.5E+00 8.0E+00
3.38E+05 3.3E-01 2.5E+00 8.0E+00
2.78E+01 1.2E+01 2.5E+00 8.0E+00
3.04E+00 6.6E+01 2.5E+00 8.0E+00
4.04E+01 2.1E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
3.44E+05 90% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
3.44E+05 89% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-374
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-L01-1313-T01-A 1
SWA-L01-1313-T02-A 1
SWA-L01-1313-T03-A 1
SWA-L01-1313-T04-A 1
SWA-L01-1313-T05-A 1
SWA-L01-1313-T06-A 1
SWA-L01-1313-T07-A 1
SWA-L01-1313-T08-A 1
SWA-L01-1313-T09-A 1
SWA-L01-1313-T01-B 1
SWA-L01-1313-T02-B 1
SWA-L01-1313-T03-B 1
SWA-L01-1313-T04-B 1
SWA-L01-1313-T05-B 1
SWA-L01-1313-T06-B 1
SWA-L01-1313-T07-B 1
SWA-L01-1313-T08-B 1
SWA-L01-1313-T09-B 1
SWA-L01-1313-T01-C 1
SWA-L01-1313-T02-C 1
SWA-L01-1313-T03-C 1
SWA-L01-1313-T04-C 1
SWA-L01-1313-T05-C 1
SWA-L01-1313-T06-C 1
SWA-L01-1313-T07-C 1
SWA-L01-1313-T08-C 1
SWA-L01-1313-T09-C 1
SWA-L01-1313-B01-A 1
SWA-L01-1313-B02-A 1
SWA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
3.79E+02
4.02E+02
1.69E+04
3.62E+04
4.17E+04
4.35E+04
5.47E+04
2.66E+04
2.26E+04
4.18E+02
4.09E+02
1.64E+04
3.03E+04
3.58E+04
4.11E+04
5.24E+04
2.56E+04
2.20E+04
4.11E+02
3.79E+02
1.64E+04
2.96E+04
3.69E+04
3.73E+04
4.82E+04
2.59E+04
2.33E+04
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.79E+02 5.8E-01 1.0E+00 3.2E+00
4.02E+02 5.0E-01 1.0E+00 3.2E+00 1000 100
1.69E+04 4.8E-01 1.0E+00 3.2E+00
3.62E+04 1.2E+00 1.0E+00 3.2E+00
4.17E+04 2.5E-01 1.0E+00 3.2E+00
4.35E+04 1.7E+00 1.0E+00 3.2E+00
5.47E+04 8.1E-01 1.0E+00 3.2E+00
2.66E+04 1.1E+00 1.0E+00 3.2E+00
2.26E+04 8.5E-01 1.0E+00 3.2E+00
4.18E+02 1.0E+00 1.0E+00 3.2E+00
4.09E+02 1.3E+00 1.0E+00 3.2E+00
1.64E+04 3.8E-01 1.0E+00 3.2E+00
3.03E+04 1.1E+00 1.0E+00 3.2E+00
3.58E+04 1.3E+00 1.0E+00 3.2E+00
4.11E+04 4.6E-01 1.0E+00 3.2E+00
5.24E+04 1.2E+00 1.0E+00 3.2E+00
2.56E+04 5.2E-01 1.0E+00 3.2E+00
2.20E+04 1.1E+00 1.0E+00 3.2E+00
4.11E+02 2.6E+00 1.0E+00 3.2E+00
3.79E+02 6.8E-01 1.0E+00 3.2E+00 1000 100
1.64E+04 1.7E+00 1.0E+00 3.2E+00
2.96E+04 1.2E+00 1.0E+00 3.2E+00
3.69E+04 5.1E-01 1.0E+00 3.2E+00
3.73E+04 7.4E-01 1.0E+00 3.2E+00
4.82E+04 6.0E-01 1.0E+00 3.2E+00
2.59E+04 4.4E-01 1.0E+00 3.2E+00
2.33E+04 3.0E+00 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
5.00E-01 7.7E+01 1.0E+00 3.2E+00
5.00E-01 4.9E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.43E+03 103% VU ICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.43E+03 105% VU ICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-375
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qu
1 1 ug/L
S SWA-L01-1313-T01-A 1 4.75E+05
S SWA-L01-1313-T02-A 1 8.37E+05
S SWA-L01-1313-T03-A 1 5.15E+05
S SWA-L01-1313-T04-A 1 4.88E+05
S SWA-L01-1313-T05-A 1 4.88E+05
S SWA-L01-1313-T06-A 1 5.12E+05
S SWA-L01-1313-T07-A 1 5.34E+05
S SWA-L01-1313-T08-A 1 2.21E+05
S SWA-L01-1313-T09-A 1 1.67E+05
S SWA-L01-1313-T01-B 1 3.64E+05
S SWA-L01-1313-T02-B 1 7.61 E+05
S SWA-L01-1313-T03-B 1 5.21E+05
S SWA-L01-1313-T04-B 1 5.19E+05
S SWA-L01-1313-T05-B 1 4.55E+05
S SWA-L01-1313-T06-B 1 4.79E+05
S SWA-L01-1313-T07-B 1 5.24E+05
S SWA-L01-1313-T08-B 1 2.16E+05
S SWA-L01-1313-T09-B 1 1.65E+05
S SWA-L01-1313-T01-C 1 4.89E+05
S SWA-L01-1313-T02-C 1 7.35E+05
S SWA-L01-1313-T03-C 1 4.91 E+05
S SWA-L01-1313-T04-C 1 4.97E+05
S SWA-L01-1313-T05-C 1 4.38E+05
S SWA-L01-1313-T06-C 1 4.27E+05
S SWA-L01-1313-T07-C 1 4.88E+05
S SWA-L01-1313-T08-C 1 2.17E+05
S SWA-L01-1313-T09-C 1 1.65E+05
S SWA-L01-1313-B01-A 1 3.36E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.75E+05 2.1E-01 6.8E+00 2.2E+01
8.37E+05 5.9E-01 6.8E+00 2.2E+01 1000 100
5.15E+05 3.2E-01 6.8E+00 2.2E+01
4.88E+05 1.3E+00 6.8E+00 2.2E+01
4.88E+05 2.7E-02 6.8E+00 2.2E+01
5.12E+05 1.1E-01 6.8E+00 2.2E+01
5.34E+05 7.5E-01 6.8E+00 2.2E+01
2.21 E+05 7.7E-01 6.8E+00 2.2E+01
1.67E+05 3.7E-01 6.8E+00 2.2E+01
3.64E+05 6.9E-01 6.8E+00 2.2E+01
7.61 E+05 7.5E-01 6.8E+00 2.2E+01
5.21 E+05 6.0E-01 6.8E+00 2.2E+01
5.19E+05 6.0E-01 6.8E+00 2.2E+01
4.55E+05 4.2E-01 6.8E+00 2.2E+01
4.79E+05 7.9E-01 6.8E+00 2.2E+01
5.24E+05 7.1E-01 6.8E+00 2.2E+01
2.16E+05 3.0E-01 6.8E+00 2.2E+01
1.65E+05 2.8E-01 6.8E+00 2.2E+01
4.89E+05 9.2E-01 6.8E+00 2.2E+01
7.35E+05 2.6E-01 6.8E+00 2.2E+01 1000 100
4.91E+05 2.0E-01 6.8E+00 2.2E+01
4.97E+05 4.0E-01 6.8E+00 2.2E+01
4.38E+05 5.3E-01 6.8E+00 2.2E+01
4.27E+05 5.8E-01 6.8E+00 2.2E+01
4.88E+05 4.0E-01 6.8E+00 2.2E+01
2.17E+05 1.9E-01 6.8E+00 2.2E+01
1.65E+05 2.7E+00 6.8E+00 2.2E+01
3.36E+01 2.8E+01 6.8E+00 2.2E+01
S SWA-L01-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 2.8E+01 6.8E+00 2.2E+01
S SWA-L01-1313-B03-A 1 1.34E+02
1.34E+02 4.5E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
8.38E+05 86% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
7.36E+05 89% VUICP-OES 1 1/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-376
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L01-1313-T01-A 1 2.30E+00 U1/2 2.30E+00 3.6E+01 4.6E+00 1.5E+01
Tl SWA-L01-1313-T02-A 1 2.30E+00 U1/2 2.30E+00 8.2E+02 4.6E+00 1.5E+01 10 100
Tl SWA-L01-1313-T03-A 1 2.30E+00 U1/2 2.30E+00 9.2E+01 4.6E+00 1.5E+01
Tl SWA-L01-1313-T04-A 1 2.30E+00 U1/2 2.30E+00 1.1E+02 4.6E+00 1.5E+01
Tl SWA-L01-1313-T05-A 1 2.30E+00 U1/2 2.30E+00 4.6E+02 4.6E+00 1.5E+01
Tl SWA-L01-1313-T06-A 1 1.18E+01 E
Tl SWA-L01-1313-T07-A 1 2.87E+01
Tl SWA-L01-1313-T08-A 1 1.05E+01 E
Tl SWA-L01-1313-T09-A 1 1.43E+01 E
1.18E+01 6.2E+01 4.6E+00 1 .5E+01
2.87E+01 2.9E+01 4.6E+00 1 .5E+01
1.05E+01 2.8E+01 4.6E+00 1 .5E+01
1.43E+01 6.2E+01 4.6E+00 1 .5E+01
Tl SWA-L01-1313-T01-B 1 2.30E+00 U1/2 2.30E+00 4.0E+01 4.6E+00 1 .5E+01
Tl SWA-L01-1313-T02-B 1 2.30E+00 U1/2 2.30E+00 1 .2E+02 4.6E+00 1 .5E+01
Tl SWA-L01-1313-T03-B 1 2.30E+00 U1/2 2.30E+00 2.0E+02 4.6E+00 1 .5E+01
Tl SWA-L01-1313-T04-B 1 2.30E+00 U1/2 2.30E+00 2.0E+03 4.6E+00 1 .5E+01
Tl SWA-L01-1313-T05-B 1 2.30E+00 U1/2 2.30E+00 1.1E+02 4.6E+00 1 .5E+01
Tl SWA-L01-1313-T06-B 1 8.40E+00 E
Tl SWA-L01-1313-T07-B 1 2.49E+01
Tl SWA-L01-1313-T08-B 1 9.02E+00 E
Tl SWA-L01-1313-T09-B 1 1.59E+01
8.40E+00 1.1E+02 4.6E+00 1 .5E+01
2.49E+01 3.7E+01 4.6E+00 1.5E+01
9.02E+00 1.9E+01 4.6E+00 1.5E+01
1.59E+01 2.4E+00 4.6E+00 1.5E+01
Tl SWA-L01-1313-T01-C 1 2.30E+00 U1/2 2.30E+00 2.8E+03 4.6E+00 1.5E+01
Tl SWA-L01-1313-T02-C 1 2.30E+00 U1/2 2.30E+00 6.3E+02 4.6E+00 1.5E+01 10 100
Tl SWA-L01-1313-T03-C 1 2.30E+00 U1/2 2.30E+00 2.4E+01 4.6E+00 1.5E+01
Tl SWA-L01-1313-T04-C 1 2.30E+00 U1/2 2.30E+00 5.7E+02 4.6E+00 1.5E+01
Tl SWA-L01-1313-T05-C 1 2.30E+00 U1/2 2.30E+00 7.6E+01 4.6E+00 1.5E+01
Tl SWA-L01-1313-T06-C 1 5.94E+00 E
Tl SWA-L01-1313-T07-C 1 2.36E+01
Tl SWA-L01-1313-T08-C 1 9.90E+00 E
Tl SWA-L01-1313-T09-C 1 1.57E+01
5.94E+00 5.7E+01 4.6E+00 1.5E+01
2.36E+01 2.2E+01 4.6E+00 1.5E+01
9.90E+00 1.5E+01 4.6E+00 1.5E+01
1.57E+01 2.7E+01 4.6E+00 1.5E+01
Tl SWA-L01-1313-B01-A 1 2.30E+00 U1/2 2.30E+00 8.4E+01 4.6E+00 1.5E+01
Tl SWA-L01-1313-B02-A 1 2.30E+00 U1/2 2.30E+00 1.1E+02 4.6E+00 1.5E+01
Tl SWA-L01-1313-B03-A 1 2.30E+00 U1/2 2.30E+00 1.5E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
9.23E+02 92% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
9.11E+02 91% VUICP-OES 1 1/1/10 11 :57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                          1-377
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti SWA-L01-1313-T01-A 1
Ti SWA-L01-1313-T02-A 1
Ti SWA-L01-1313-T03-A 1
Ti SWA-L01-1313-T04-A 1
Ti SWA-L01-1313-T05-A 1
Ti SWA-L01-1313-T06-A 1
Ti SWA-L01-1313-T07-A 1
Ti SWA-L01-1313-T08-A 1
Ti SWA-L01-1313-T09-A 1
Ti SWA-L01-1313-T01-B 1
Ti SWA-L01-1313-T02-B 1
Ti SWA-L01-1313-T03-B 1
Ti SWA-L01-1313-T04-B 1
Ti SWA-L01-1313-T05-B 1
Ti SWA-L01-1313-T06-B 1
Ti SWA-L01-1313-T07-B 1
Ti SWA-L01-1313-T08-B 1
Ti SWA-L01-1313-T09-B 1
Ti SWA-L01-1313-T01-C 1
Ti SWA-L01-1313-T02-C 1
Ti SWA-L01-1313-T03-C 1
Ti SWA-L01-1313-T04-C 1
Ti SWA-L01-1313-T05-C 1
Ti SWA-L01-1313-T06-C 1
Ti SWA-L01-1313-T07-C 1
Ti SWA-L01-1313-T08-C 1
Ti SWA-L01-1313-T09-C 1
Ti SWA-L01-1313-B01-A 1
Ti SWA-L01-1313-B02-A 1
Ti SWA-L01-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.96E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.75E+01
5.81E+01
4.95E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.96E+01
6.26E+01
2.05E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.40E+01
5.86E+01
1.00E+00 U1/2
1.00E+00 U1/2
4.01 E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.96E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00 10 100
1.00E+00 4.9E+01 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+02 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
3.75E+01 5.9E-01 2.0E+00 6.4E+00
5.81 E+01 1.7E+00 2.0E+00 6.4E+00
4.95E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 3.1 E+01 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
3.96E+01 5.5E-01 2.0E+00 6.4E+00
6.26E+01 3.8E-01 2.0E+00 6.4E+00
2.05E+00 4.9E+01 2.0E+00 6.4E+00
1.00E+00 6.5E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 7.1E+02 2.0E+00 6.4E+00
1.00E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 8.3E+01 2.0E+00 6.4E+00
3.40E+01 9.6E-01 2.0E+00 6.4E+00
5.86E+01 2.5E+00 2.0E+00 6.4E+00
1.00E+00 5.0E+00 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
4.01 E+00 7.9E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.01E+03 101% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
9.96E+02 100% VUICP-OES 1 1/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-378
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V SWA-L01-1313-T01-A 1
V SWA-L01-1313-T02-A 1
V SWA-L01-1313-T03-A 1
V SWA-L01-1313-T04-A 1
V SWA-L01-1313-T05-A 1
V SWA-L01-1313-T06-A 1
V SWA-L01-1313-T07-A 1
V SWA-L01-1313-T08-A 1
V SWA-L01-1313-T09-A 1
V SWA-L01-1313-T01-B 1
V SWA-L01-1313-T02-B 1
V SWA-L01-1313-T03-B 1
V SWA-L01-1313-T04-B 1
V SWA-L01-1313-T05-B 1
V SWA-L01-1313-T06-B 1
V SWA-L01-1313-T07-B 1
V SWA-L01-1313-T08-B 1
V SWA-L01-1313-T09-B 1
V SWA-L01-1313-T01-C 1
V SWA-L01-1313-T02-C 1
V SWA-L01-1313-T03-C 1
V SWA-L01-1313-T04-C 1
V SWA-L01-1313-T05-C 1
V SWA-L01-1313-T06-C 1
V SWA-L01-1313-T07-C 1
V SWA-L01-1313-T08-C 1
V SWA-L01-1313-T09-C 1
V SWA-L01-1313-B01-A 1
V SWA-L01-1313-B02-A 1
V SWA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
4.68E+02
3.44E+02
1.33E+02
2.51 E+02
2.29E+02
2.09E+02
2.16E+02
9.66E+01
1.99E+02
4.66E+02
3.60E+02
1.31 E+02
1.94E+02
2.25E+02
2.09E+02
2.02E+02
9.22E+01
2.36E+02
4.64E+02
3.61 E+02
1.29E+02
1.99E+02
1.85E+02
1.80E+02
1.99E+02
9.24E+01
2.59E+02
7.50E-01 U1/2
7.50E-01 U1/2
7.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.68E+02 3.3E-01 1.5E+00 4.8E+00
3.44E+02 2.2E-01 1.5E+00 4.8E+00 10 100
1.33E+02 1.5E+00 1.5E+00 4.8E+00
2.51 E+02 6.3E-01 1.5E+00 4.8E+00
2.29E+02 1.3E+00 1.5E+00 4.8E+00
2.09E+02 5.6E-01 1.5E+00 4.8E+00
2.16E+02 1.6E+00 1.5E+00 4.8E+00
9.66E+01 1.8E+00 1.5E+00 4.8E+00
1.99E+02 6.8E-01 1.5E+00 4.8E+00
4.66E+02 1.2E+00 1.5E+00 4.8E+00
3.60E+02 1.3E+00 1.5E+00 4.8E+00
1.31 E+02 1.3E+00 1.5E+00 4.8E+00
1.94E+02 6.9E-01 1.5E+00 4.8E+00
2.25E+02 4.6E-02 1.5E+00 4.8E+00
2.09E+02 1.3E+00 1.5E+00 4.8E+00
2.02E+02 1.3E+00 1.5E+00 4.8E+00
9.22E+01 1.7E+00 1.5E+00 4.8E+00
2.36E+02 2.8E-01 1.5E+00 4.8E+00
4.64E+02 1.9E+00 1.5E+00 4.8E+00
3.61E+02 9.0E-01 1.5E+00 4.8E+00 10 100
1.29E+02 3.4E+00 1.5E+00 4.8E+00
1.99E+02 2.3E-01 1.5E+00 4.8E+00
1.85E+02 1.5E+00 1.5E+00 4.8E+00
1.80E+02 3.8E-01 1.5E+00 4.8E+00
1.99E+02 1.5E+00 1.5E+00 4.8E+00
9.24E+01 7.3E-01 1.5E+00 4.8E+00
2.59E+02 3.2E+00 1.5E+00 4.8E+00
7.50E-01 6.6E+01 1.5E+00 4.8E+00
7.50E-01 4.5E+01 1.5E+00 4.8E+00
7.50E-01 3.1E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.33E+03 99% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.36E+03 100% VU ICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-379
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-L01-1313-T01-A 1
Zn SWA-L01-1313-T02-A 1
Zn SWA-L01-1313-T03-A 1
Zn SWA-L01-1313-T04-A 1
Zn SWA-L01-1313-T05-A 1
Zn SWA-L01-1313-T06-A 1
Zn SWA-L01-1313-T07-A 1
Zn SWA-L01-1313-T08-A 1
Zn SWA-L01-1313-T09-A 1
Zn SWA-L01-1313-T01-B 1
Zn SWA-L01-1313-T02-B 1
Zn SWA-L01-1313-T03-B 1
Zn SWA-L01-1313-T04-B 1
Zn SWA-L01-1313-T05-B 1
Zn SWA-L01-1313-T06-B 1
Zn SWA-L01-1313-T07-B 1
Zn SWA-L01-1313-T08-B 1
Zn SWA-L01-1313-T09-B 1
Zn SWA-L01-1313-T01-C 1
Zn SWA-L01-1313-T02-C 1
Zn SWA-L01-1313-T03-C 1
Zn SWA-L01-1313-T04-C 1
Zn SWA-L01-1313-T05-C 1
Zn SWA-L01-1313-T06-C 1
Zn SWA-L01-1313-T07-C 1
Zn SWA-L01-1313-T08-C 1
Zn SWA-L01-1313-T09-C 1
Zn SWA-L01-1313-B01-A 1
Zn SWA-L01-1313-B02-A 1
Zn SWA-L01-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.01E+01
1.74E+01
1.74E+01
2.05E+01
1.95E+01
1.75E+01
2.75E+02
1.33E+03
1.89E+03
2.00E+01
1.78E+01
1.75E+01
1.77E+01
1.72E+01
1.83E+01
3.17E+02
1.32E+03
1.90E+03
1.46E+01
1.58E+01
1.66E+01
1.79E+01
1.63E+01
1.85E+01
1.56E+02
1.33E+03
1.94E+03
5.00E-01 U1/2
5.00E-01 U1/2
3.40E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01 E+01 5.3E+00 1.0E+00 3.2E+00
1.74E+01 1.7E+00 1.0E+00 3.2E+00 10 100
1.74E+01 2.2E+00 1.0E+00 3.2E+00
2.05E+01 1.5E+00 1.0E+00 3.2E+00
1.95E+01 4.5E+00 1.0E+00 3.2E+00
1.75E+01 2.1E+00 1.0E+00 3.2E+00
2.75E+02 5.6E-01 1.0E+00 3.2E+00
1.33E+03 4.5E-01 1.0E+00 3.2E+00
1.89E+03 7.2E-01 1.0E+00 3.2E+00
2.00E+01 1.8E+00 1.0E+00 3.2E+00
1.78E+01 2.2E+00 1.0E+00 3.2E+00
1.75E+01 1.0E+00 1.0E+00 3.2E+00
1.77E+01 1.1E+00 1.0E+00 3.2E+00
1.72E+01 1.2E+00 1.0E+00 3.2E+00
1.83E+01 2.2E+00 1.0E+00 3.2E+00
3.17E+02 1.2E+00 1.0E+00 3.2E+00
1.32E+03 9.8E-01 1.0E+00 3.2E+00
1.90E+03 4.3E-01 1.0E+00 3.2E+00
1.46E+01 1.6E+00 1.0E+00 3.2E+00
1.58E+01 2.4E+00 1.0E+00 3.2E+00 10 100
1.66E+01 2.9E+00 1.0E+00 3.2E+00
1.79E+01 1.8E+00 1.0E+00 3.2E+00
1.63E+01 8.2E+00 1.0E+00 3.2E+00
1.85E+01 4.2E+00 1.0E+00 3.2E+00
1.56E+02 2.8E-01 1.0E+00 3.2E+00
1.33E+03 6.2E-01 1.0E+00 3.2E+00
1.94E+03 3.4E+00 1.0E+00 3.2E+00
5.00E-01 7.3E-01 1.0E+00 3.2E+00
5.00E-01 5.3E+00 1.0E+00 3.2E+00
3.40E+00 1.7E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/1/1011:21 AM EPA Interlab L01 1313-1316SWA
1.12E+03 110% VUICP-OES 11/1/10 11:22 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 11/1/10 11:24 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:26 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:27 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:29 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:31 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:32 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:34 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:36 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:37 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:39 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/1011:41 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:42 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:49 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:50 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:52 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:54 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:55 AM EPA Interlab L01 1313-1316SWA
1.13E+03 111% VUICP-OES 11/1/10 11:57 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 11/1/10 11:59 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 12:00 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:02 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:04 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:05 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:07 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 12:09 PM EPA Interlab L01 1313-1316 SWA
VUICP-OES 1 1/1/10 11:16 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:18 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 1 1/1/10 11:19 AM EPA Interlab L01 1313-1316SWA
                                                                                                                                                                          1-380
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al SWA-L02-1313-T01-A 1
Al SWA-L02-1313-T02-A 1
Al SWA-L02-1313-T03-A 1
Al SWA-L02-1313-T04-A 1
Al SWA-L02-1313-T05-A 1
Al SWA-L02-1313-T06-A 1
Al SWA-L02-1313-T07-A 1
Al SWA-L02-1313-T08-A 1
Al SWA-L02-1313-T09-A 1
Al SWA-L02-1313-T01-B 1
Al SWA-L02-1313-T02-B 1
Al SWA-L02-1313-T03-B 1
Al SWA-L02-1313-T04-B 1
Al SWA-L02-1313-T05-B 1
Al SWA-L02-1313-T06-B 1
Al SWA-L02-1313-T07-B 1
Al SWA-L02-1313-T08-B 1
Al SWA-L02-1313-T09-B 1
Al SWA-L02-1313-T01-C 1
Al SWA-L02-1313-T02-C 1
Al SWA-L02-1313-T03-C 1
Al SWA-L02-1313-T04-C 1
Al SWA-L02-1313-T05-C 1
Al SWA-L02-1313-T06-C 1
Al SWA-L02-1313-T07-C 1
Al SWA-L02-1313-T08-C 1
Al SWA-L02-1313-T09-C 1
Al SWA-L02-1313-B01-A 1
Al SWA-L02-1313-B02-A 1
Al SWA-L02-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
3.53E+04
1.57E+04
3.46E+04
3.14E+03
2.52E+02
5.00E-01 U1/2
2.86E+02
3.27E+05
1.20E+06
3.87E+04
1.61E+04
2.89E+04
2.67E+03
3.11E+02
1.35E+02
3.26E+02
4.13E+05
1.11E+06
3.69E+04
1.64E+04
2.81 E+04
3.75E+02
2.26E+02
2.48E+02
3.08E+02
4.39E+05
1.16E+06
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.53E+04 6.9E-01 1.0E+00 3.2E+00
1.57E+04 7.4E-01 1.0E+00 3.2E+00
3.46E+04 5.4E-01 1.0E+00 3.2E+00 1000 125
3.14E+03 1.6E+00 1.0E+00 3.2E+00
2.52E+02 2.6E+00 1.0E+00 3.2E+00
5.00E-01 7.4E+01 1.0E+00 3.2E+00
2.86E+02 6.5E+00 1.0E+00 3.2E+00
3.27E+05 4.3E-01 1.0E+00 3.2E+00
1.20E+06 2.6E-01 1.0E+00 3.2E+00
3.87E+04 9.6E-01 1.0E+00 3.2E+00
1.61 E+04 2.5E+00 1.0E+00 3.2E+00
2.89E+04 2.4E+00 1.0E+00 3.2E+00 1000 125
2.67E+03 9.6E-01 1.0E+00 3.2E+00
3.11E+02 6.3E+00 1.0E+00 3.2E+00
1.35E+02 1.4E+01 1.0E+00 3.2E+00
3.26E+02 6.0E+00 1.0E+00 3.2E+00
4.13E+05 6.7E-01 1.0E+00 3.2E+00
1.11E+06 9.9E-01 1.0E+00 3.2E+00
3.69E+04 9.1E-01 1.0E+00 3.2E+00
1.64E+04 4.7E-01 1.0E+00 3.2E+00
2.81E+04 3.7E+00 1.0E+00 3.2E+00 1000 125
3.75E+02 5.0E+00 1.0E+00 3.2E+00
2.26E+02 2.3E+00 1.0E+00 3.2E+00
2.48E+02 2.9E+00 1.0E+00 3.2E+00
3.08E+02 4.1E+00 1.0E+00 3.2E+00
4.39E+05 1.1E+00 1.0E+00 3.2E+00
1.16E+06 5.3E-01 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
3.58E+04 97% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
3.01E+04 91% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
2.94E+04 98% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                                   1-381
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L02-1313-T01-A 1
Sb SWA-L02-1313-T02-A 1
Sb SWA-L02-1313-T03-A 1
Sb SWA-L02-1313-T04-A 1
Sb SWA-L02-1313-T05-A 1
Sb SWA-L02-1313-T06-A 1
Sb SWA-L02-1313-T07-A 1
Sb SWA-L02-1313-T08-A 1
Sb SWA-L02-1313-T09-A 1
Sb SWA-L02-1313-T01-B 1
Sb SWA-L02-1313-T02-B 1
Sb SWA-L02-1313-T03-B 1
Sb SWA-L02-1313-T04-B 1
Sb SWA-L02-1313-T05-B 1
Sb SWA-L02-1313-T06-B 1
Sb SWA-L02-1313-T07-B 1
Sb SWA-L02-1313-T08-B 1
Sb SWA-L02-1313-T09-B 1
Sb SWA-L02-1313-T01-C 1
Sb SWA-L02-1313-T02-C 1
Sb SWA-L02-1313-T03-C 1
Sb SWA-L02-1313-T04-C 1
Sb SWA-L02-1313-T05-C 1
Sb SWA-L02-1313-T06-C 1
Sb SWA-L02-1313-T07-C 1
Sb SWA-L02-1313-T08-C 1
Sb SWA-L02-1313-T09-C 1
Sb SWA-L02-1313-B01-A 1
Sb SWA-L02-1313-B02-A 1
Sb SWA-L02-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
4.40E+03
3.37E+03
5.00E+03
2.33E+03
2.06E+03
1.87E+03
1.52E+03
1.69E+03
5.90E+02
4.59E+03
3.25E+03
4.20E+03
2.32E+03
2.10E+03
1.96E+03
1.63E+03
1.01E+03
5.45E+02
4.06E+03
3.25E+03
4.09E+03
2.05E+03
2.08E+03
1.85E+03
1.53E+03
1.02E+03
5.68E+02
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.40E+03 9.4E-01 7.5E+00 2.4E+01
3.37E+03 3.5E-01 7.5E+00 2.4E+01
5.00E+03 9.9E-01 7.5E+00 2.4E+01 10 125
2.33E+03 2.5E+00 7.5E+00 2.4E+01
2.06E+03 1.0E+00 7.5E+00 2.4E+01
1.87E+03 1.5E+00 7.5E+00 2.4E+01
1.52E+03 2.6E+00 7.5E+00 2.4E+01
1.69E+03 6.7E+00 7.5E+00 2.4E+01
5.90E+02 9.5E+00 7.5E+00 2.4E+01
4.59E+03 1.8E+00 7.5E+00 2.4E+01
3.25E+03 2.1E+00 7.5E+00 2.4E+01
4.20E+03 2.5E+00 7.5E+00 2.4E+01 10 125
2.32E+03 4.3E-01 7.5E+00 2.4E+01
2.10E+03 5.6E-01 7.5E+00 2.4E+01
1.96E+03 1.8E-01 7.5E+00 2.4E+01
1.63E+03 2.2E+00 7.5E+00 2.4E+01
1.01E+03 1.7E+00 7.5E+00 2.4E+01
5.45E+02 1.3E+01 7.5E+00 2.4E+01
4.06E+03 9.1E-01 7.5E+00 2.4E+01
3.25E+03 1.9E-01 7.5E+00 2.4E+01
4.09E+03 2.7E+00 7.5E+00 2.4E+01 10 125
2.05E+03 1.5E+00 7.5E+00 2.4E+01
2.08E+03 1.2E+00 7.5E+00 2.4E+01
1.85E+03 1.8E+00 7.5E+00 2.4E+01
1.53E+03 1.5E+00 7.5E+00 2.4E+01
1.02E+03 1.8E+00 7.5E+00 2.4E+01
5.68E+02 7.8E+00 7.5E+00 2.4E+01
3.75E+00 1.1E+02 7.5E+00 2.4E+01
3.75E+00 8.0E+01 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
6.24E+03 99% VU ICP-OES 1 1/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
5.45E+03 100% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
5.30E+03 96% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-382
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qu
1 1 ug/L
As SWA-L02-1313-T01-A 1 4.68E+03
As SWA-L02-1313-T02-A 1 1.49E+03
As SWA-L02-1313-T03-A 1 4.68E+03
As SWA-L02-1313-T04-A 1 9.15E+02
As SWA-L02-1313-T05-A 1 3.34E+02
As SWA-L02-1313-T06-A 1 2.67E+02
As SWA-L02-1313-T07-A 1 4.18E+02
As SWA-L02-1313-T08-A 1 5.05E+03
As SWA-L02-1313-T09-A 1 1.16E+04
As SWA-L02-1313-T01-B 1 5.18E+03
As SWA-L02-1313-T02-B 1 1.56E+03
As SWA-L02-1313-T03-B 1 3.89E+03
As SWA-L02-1313-T04-B 1 8.88E+02
As SWA-L02-1313-T05-B 1 3.68E+02
As SWA-L02-1313-T06-B 1 2.82E+02
As SWA-L02-1313-T07-B 1 4.22E+02
As SWA-L02-1313-T08-B 1 4.13E+03
As SWA-L02-1313-T09-B 1 1.05E+04
As SWA-L02-1313-T01-C 1 4.75E+03
As SWA-L02-1313-T02-C 1 1.61E+03
As SWA-L02-1313-T03-C 1 3.84E+03
As SWA-L02-1313-T04-C 1 5.95E+02
As SWA-L02-1313-T05-C 1 2.99E+02
As SWA-L02-1313-T06-C 1 2.57E+02
As SWA-L02-1313-T07-C 1 3.86E+02
As SWA-L02-1313-T08-C 1 4.43E+03
As SWA-L02-1313-T09-C 1 1.11E+04
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.68E+03 9.4E-01 1.1E+01 3.5E+01
1.49E+03 1.1E+00 1.1E+01 3.5E+01
4.68E+03 8.6E-01 1.1E+01 3.5E+01 10 125
9.15E+02 3.4E+00 1.1E+01 3.5E+01
3.34E+02 2.8E+00 1.1E+01 3.5E+01
2.67E+02 6.0E+00 1.1E+01 3.5E+01
4.18E+02 8.4E+00 1.1E+01 3.5E+01
5.05E+03 8.2E-01 1.1E+01 3.5E+01
1.16E+04 1.0E-01 1.1E+01 3.5E+01
5.18E+03 6.4E-01 1.1E+01 3.5E+01
1.56E+03 3.1E+00 1.1E+01 3.5E+01
3.89E+03 1.9E+00 1.1E+01 3.5E+01 10 125
8.88E+02 2.4E+00 1.1E+01 3.5E+01
3.68E+02 1.1E+01 1.1E+01 3.5E+01
2.82E+02 4.9E+00 1.1E+01 3.5E+01
4.22E+02 6.6E+00 1.1E+01 3.5E+01
4.13E+03 1.2E+00 1.1E+01 3.5E+01
1.05E+04 2.3E+00 1.1E+01 3.5E+01
4.75E+03 1.6E+00 1.1E+01 3.5E+01
1.61E+03 1.6E+00 1.1E+01 3.5E+01
3.84E+03 2.8E+00 1.1E+01 3.5E+01 10 125
5.95E+02 3.4E+00 1.1E+01 3.5E+01
2.99E+02 6.9E+00 1.1E+01 3.5E+01
2.57E+02 7.7E-01 1.1E+01 3.5E+01
3.86E+02 7.6E+00 1.1E+01 3.5E+01
4.43E+03 1.1E+00 1.1E+01 3.5E+01
1.11E+04 9.2E-01 1.1E+01 3.5E+01
As SWA-L02-1313-B01-A 1 5.50E+00 U1/2 5.50E+00 3.8E+02 1.1E+01 3.5E+01
As SWA-L02-1313-B02-A 1 5.50E+00 U1/2 5.50E+00 4.3E+02 1.1E+01 3.5E+01
As SWA-L02-1313-B03-A 1 5.50E+00 U1/2 5.50E+00 1 .5E+02 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
5.92E+03 99% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
5.21E+03 105% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
5.23E+03 112% VU ICP-OES 1 1/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-383
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-L02-1313-T01-A 1
B SWA-L02-1313-T02-A 1
B SWA-L02-1313-T03-A 1
B SWA-L02-1313-T04-A 1
B SWA-L02-1313-T05-A 1
B SWA-L02-1313-T06-A 1
B SWA-L02-1313-T07-A 1
B SWA-L02-1313-T08-A 1
B SWA-L02-1313-T09-A 1
B SWA-L02-1313-T01-B 1
B SWA-L02-1313-T02-B 1
B SWA-L02-1313-T03-B 1
B SWA-L02-1313-T04-B 1
B SWA-L02-1313-T05-B 1
B SWA-L02-1313-T06-B 1
B SWA-L02-1313-T07-B 1
B SWA-L02-1313-T08-B 1
B SWA-L02-1313-T09-B 1
B SWA-L02-1313-T01-C 1
B SWA-L02-1313-T02-C 1
B SWA-L02-1313-T03-C 1
B SWA-L02-1313-T04-C 1
B SWA-L02-1313-T05-C 1
B SWA-L02-1313-T06-C 1
B SWA-L02-1313-T07-C 1
B SWA-L02-1313-T08-C 1
B SWA-L02-1313-T09-C 1
B SWA-L02-1313-B01-A 1
B SWA-L02-1313-B02-A 1
B SWA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
8.05E+02
6.16E+02
8.63E+02
1.58E+03
2.52E+03
4.33E+03
5.51 E+03
7.49E+03
9.85E+03
8.87E+02
6.51 E+02
7.41 E+02
1.64E+03
2.77E+03
4.30E+03
5.70E+03
7.04E+03
8.89E+03
8.07E+02
7.32E+02
7.27E+02
1.63E+03
2.92E+03
3.78E+03
5.12E+03
7.45E+03
9.49E+03
1.11E+01
1.20E+01
9.16E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.05E+02 1.0E+00 1.0E+00 3.2E+00
6.16E+02 6.2E-01 1.0E+00 3.2E+00
8.63E+02 1.3E+00 1.0E+00 3.2E+00 1000 125
1.58E+03 1.7E+00 1.0E+00 3.2E+00
2.52E+03 4.6E-01 1.0E+00 3.2E+00
4.33E+03 4.3E-01 1.0E+00 3.2E+00
5.51 E+03 5.8E-01 1.0E+00 3.2E+00
7.49E+03 9.5E-01 1.0E+00 3.2E+00
9.85E+03 2.7E-01 1.0E+00 3.2E+00
8.87E+02 7.5E-01 1.0E+00 3.2E+00
6.51 E+02 3.1E+00 1.0E+00 3.2E+00
7.41E+02 2.1E+00 1.0E+00 3.2E+00 1000 125
1.64E+03 7.0E-01 1.0E+00 3.2E+00
2.77E+03 2.7E-01 1.0E+00 3.2E+00
4.30E+03 1.2E+00 1.0E+00 3.2E+00
5.70E+03 8.7E-01 1.0E+00 3.2E+00
7.04E+03 7.3E-01 1.0E+00 3.2E+00
8.89E+03 1.3E+00 1.0E+00 3.2E+00
8.07E+02 1.2E+00 1.0E+00 3.2E+00
7.32E+02 7.7E-01 1.0E+00 3.2E+00
7.27E+02 2.5E+00 1.0E+00 3.2E+00 1000 125
1.63E+03 2.9E+00 1.0E+00 3.2E+00
2.92E+03 8.4E-01 1.0E+00 3.2E+00
3.78E+03 1.8E+00 1.0E+00 3.2E+00
5.12E+03 1.4E+00 1.0E+00 3.2E+00
7.45E+03 7.8E-01 1.0E+00 3.2E+00
9.49E+03 5.5E-01 1.0E+00 3.2E+00
1.11E+01 2.6E+01 1.0E+00 3.2E+00
1.20E+01 7.5E+00 1.0E+00 3.2E+00
9.16E+00 1.5E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
2.15E+03 103% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
2.05E+03 105% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:1 7PM EPA Interlab L02 1313-1316SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
2.02E+03 103% VUICP-OES 1 1/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :43 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :45 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :46 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :48 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3 :42 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3 :44 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3 :45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-384
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone.
1 1 ug/L
Ba SWA-L02-1313-T01-A 1 1.66E+02
Ba SWA-L02-1313-T02-A 1 3.16E+02
Ba SWA-L02-1313-T03-A 1 2.10E+02
Ba SWA-L02-1313-T04-A 1 9.95E+02
Ba SWA-L02-1313-T05-A 1 9.08E+02
Ba SWA-L02-1313-T06-A 1 1.18E+03
Ba SWA-L02-1313-T07-A 1 1.45E+03
Ba SWA-L02-1313-T08-A 1 9.92E+02
Ba SWA-L02-1313-T09-A 1 1.10E+03
Ba SWA-L02-1313-T01-B 1 1.80E+02
Ba SWA-L02-1313-T02-B 1 2.83E+02
Ba SWA-L02-1313-T03-B 1 1.79E+02
Ba SWA-L02-1313-T04-B 1 9.67E+02
Ba SWA-L02-1313-T05-B 1 9.52E+02
Ba SWA-L02-1313-T06-B 1 1.18E+03
Ba SWA-L02-1313-T07-B 1 1.51E+03
Ba SWA-L02-1313-T08-B 1 9.05E+02
Ba SWA-L02-1313-T09-B 1 1.01E+03
Ba SWA-L02-1313-T01-C 1 1.81E+02
Ba SWA-L02-1313-T02-C 1 2.91E+02
Ba SWA-L02-1313-T03-C 1 1 .69E+02
Ba SWA-L02-1313-T04-C 1 9.20E+02
Ba SWA-L02-1313-T05-C 1 9.60E+02
Ba SWA-L02-1313-T06-C 1 1.05E+03
Ba SWA-L02-1313-T07-C 1 1.38E+03
Ba SWA-L02-1313-T08-C 1 9.42E+02
Ba SWA-L02-1313-T09-C 1 1.05E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.66E+02 4.5E+01 1.0E+00 3.2E+00
3.16E+02 8.6E+01 1.0E+00 3.2E+00
2.10E+02 7.3E+01 1.0E+00 3.2E+00 10 125
9.95E+02 8.9E-01 1.0E+00 3.2E+00
9.08E+02 6.1E-02 1.0E+00 3.2E+00
1.18E+03 6.9E-01 1.0E+00 3.2E+00
1.45E+03 1.1E+00 1.0E+00 3.2E+00
9.92E+02 6.2E-01 1.0E+00 3.2E+00
1.10E+03 1.0E-01 1.0E+00 3.2E+00
1.80E+02 7.2E-01 1.0E+00 3.2E+00
2.83E+02 9.6E-01 1.0E+00 3.2E+00
1.79E+02 7.4E-01 1.0E+00 3.2E+00 10 125
9.67E+02 7.2E-01 1.0E+00 3.2E+00
9.52E+02 4.1E+00 1.0E+00 3.2E+00
1.18E+03 2.2E+00 1.0E+00 3.2E+00
1.51E+03 5.9E-01 1.0E+00 3.2E+00
9.05E+02 4.4E-01 1.0E+00 3.2E+00
1.01E+03 8.3E-01 1.0E+00 3.2E+00
1.81E+02 1.2E+00 1.0E+00 3.2E+00
2.91E+02 6.8E-01 1.0E+00 3.2E+00
1.69E+02 1.5E+00 1.0E+00 3.2E+00 10 125
9.20E+02 9.5E-01 1.0E+00 3.2E+00
9.60E+02 5.6E-01 1.0E+00 3.2E+00
1.05E+03 3.5E+00 1.0E+00 3.2E+00
1.38E+03 4.6E+00 1.0E+00 3.2E+00
9.42E+02 9.4E-01 1.0E+00 3.2E+00
1.05E+03 1.8E+00 1.0E+00 3.2E+00
Ba SWA-L02-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 1.1E+00 1.0E+00 3.2E+00
Ba SWA-L02-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 1.1E+00 1.0E+00 3.2E+00
Ba SWA-L02-1313-B03-A 1 5.00E-01 U1/2 5.00E-01 1.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.35E+03 91% VU ICP-OES 1 1/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.38E+03 96% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.34E+03 93% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-385
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L02-1313-T01-A 1
Be SWA-L02-1313-T02-A 1
Be SWA-L02-1313-T03-A 1
Be SWA-L02-1313-T04-A 1
Be SWA-L02-1313-T05-A 1
Be SWA-L02-1313-T06-A 1
Be SWA-L02-1313-T07-A 1
Be SWA-L02-1313-T08-A 1
Be SWA-L02-1313-T09-A 1
Be SWA-L02-1313-T01-B 1
Be SWA-L02-1313-T02-B 1
Be SWA-L02-1313-T03-B 1
Be SWA-L02-1313-T04-B 1
Be SWA-L02-1313-T05-B 1
Be SWA-L02-1313-T06-B 1
Be SWA-L02-1313-T07-B 1
Be SWA-L02-1313-T08-B 1
Be SWA-L02-1313-T09-B 1
Be SWA-L02-1313-T01-C 1
Be SWA-L02-1313-T02-C 1
Be SWA-L02-1313-T03-C 1
Be SWA-L02-1313-T04-C 1
Be SWA-L02-1313-T05-C 1
Be SWA-L02-1313-T06-C 1
Be SWA-L02-1313-T07-C 1
Be SWA-L02-1313-T08-C 1
Be SWA-L02-1313-T09-C 1
Be SWA-L02-1313-B01-A 1
Be SWA-L02-1313-B02-A 1
Be SWA-L02-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
4.48E-01 U1/2
4.73E+01
1.99E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
7.19E+01
1.73E+02
3.72E+00 E
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
7.72E+01
1.91E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 3.6E+01 1.9E+00 6.0E+00
9.50E-01 3.0E+01 1.9E+00 6.0E+00
9.50E-01 5.8E+01 1.9E+00 6.0E+00 10 125
9.50E-01 7.2E+01 1.9E+00 6.0E+00
9.50E-01 9.4E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00
4.48E-01 1.1E+02 1.9E+00 6.0E+00
4.73E+01 1.2E+00 1.9E+00 6.0E+00
1.99E+02 1.6E+00 1.9E+00 6.0E+00
9.50E-01 8.1E+01 1.9E+00 6.0E+00
9.50E-01 7.6E+01 1.9E+00 6.0E+00
9.50E-01 2.2E+01 1.9E+00 6.0E+00 10 125
9.50E-01 5.8E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
7.19E+01 2.8E+00 1.9E+00 6.0E+00
1.73E+02 1.1E+00 1.9E+00 6.0E+00
3.72E+00 1.8E+00 1.9E+00 6.0E+00
9.50E-01 2.1E+01 1.9E+00 6.0E+00
9.50E-01 4.5E+01 1.9E+00 6.0E+00 10 125
9.50E-01 2.6E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 2.9E+01 1.9E+00 6.0E+00
7.72E+01 1.4E+00 1.9E+00 6.0E+00
1.91E+02 7.9E-01 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
9.50E-01 2.9E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.29E+03 103% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.32E+03 106% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.29E+03 103% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-386
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L02-1313-T01-A 1 1.10E+OOU1/2 1.10E+00 9.2E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T02-A 1 1.10E+OOU1/2 1.10E+00 1.4E+02 2.2E+00 7.0E+00
Cd SWA-L02-1313-T03-A 1 1.10E+OOU1/2 1.10E+00 5.2E+01 2.2E+00 7.0E+00 10 125
Cd SWA-L02-1313-T04-A 1 1.10E+OOU1/2 1.10E+00 1.3E+02 2.2E+00 7.0E+00
Cd SWA-L02-1313-T05-A 1 1.10E+OOU1/2 1.10E+00 4.5E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T06-A 1 1.10E+OOU1/2 1.10E+00 2.3E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T07-A 1 8.20E+00
Cd SWA-L02-1313-T08-A 1 2.38E+01
Cd SWA-L02-1313-T09-A 1 4.61E+01
8.20E+00 4.3E+00 2.2E+00 7.0E+00
2.38E+01 2.9E+00 2.2E+00 7.0E+00
4.61 E+01 3.1E-01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T01-B 1 1.10E+OOU1/2 1.10E+00 5.2E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T02-B 1 1.10E+OOU1/2 1.10E+00 7.6E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T03-B 1 1.10E+OOU1/2 1.10E+00 7.6E+01 2.2E+00 7.0E+00 10 125
Cd SWA-L02-1313-T04-B 1 1.10E+OOU1/2 1.10E+00 2.3E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T05-B 1 1.10E+OOU1/2 1.10E+00 9.1E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T06-B 1 1.10E+OOU1/2 1.10E+00 1.1E+02 2.2E+00 7.0E+00
Cd SWA-L02-1313-T07-B 1 6.74E+00 E
Cd SWA-L02-1313-T08-B 1 2.35E+01
Cd SWA-L02-1313-T09-B 1 4.14E+01
Cd SWA-L02-1313-T01-C 1 3.64E+00 E
6.74E+00 2.7E+00 2.2E+00 7.0E+00
2.35E+01 1.2E+00 2.2E+00 7.0E+00
4.14E+01 1.8E+00 2.2E+00 7.0E+00
3.64E+00 5.1E+00 2.2E+00 7.0E+00
Cd SWA-L02-1313-T02-C 1 1.10E+OOU1/2 1.10E+00 1.3E+02 2.2E+00 7.0E+00
Cd SWA-L02-1313-T03-C 1 1.10E+OOU1/2 1.10E+00 1.5E+02 2.2E+00 7.0E+00 10 125
Cd SWA-L02-1313-T04-C 1 1.10E+OOU1/2 1.10E+00 1.9E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T05-C 1 1.10E+OOU1/2 1.10E+00 2.7E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T06-C 1 1.10E+OOU1/2 1.10E+00 3.6E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-T07-C 1 6.72E+00 E
Cd SWA-L02-1313-T08-C 1 2.45E+01
Cd SWA-L02-1313-T09-C 1 4.41E+01
6.72E+00 3.6E+00 2.2E+00 7.0E+00
2.45E+01 9.4E-01 2.2E+00 7.0E+00
4.41E+01 5.9E-01 2.2E+00 7.0E+00
Cd SWA-L02-1313-B01-A 1 1.10E+OOU1/2 1.10E+00 1.7E+02 2.2E+00 7.0E+00
Cd SWA-L02-1313-B02-A 1 1.10E+OOU1/2 1.10E+00 1.8E+01 2.2E+00 7.0E+00
Cd SWA-L02-1313-B03-A 1 1.10E+OOU1/2 1.10E+00 1.5E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.22E+03 98% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/103:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.24E+03 99% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.22E+03 97% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-387
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
1 1 ug/L
Ca SWA-L02-1313-T01-A 1 1.39E+04
Ca SWA-L02-1313-T02-A 1 6.03E+04
Ca SWA-L02-1313-T03-A 1 2.54E+04
Ca SWA-L02-1313-T04-A 1 5.11E+06
Ca SWA-L02-1313-T05-A 1 7.16E+06
Ca SWA-L02-1313-T06-A 1 9.49E+06
Ca SWA-L02-1313-T07-A 1 1.06E+07
Ca SWA-L02-1313-T08-A 1 8.25E+06
Ca SWA-L02-1313-T09-A 1 5.58E+06
Ca SWA-L02-1313-T01-B 1 1.68E+04
Ca SWA-L02-1313-T02-B 1 5.63E+04
Ca SWA-L02-1313-T03-B 1 2.41E+04
Ca SWA-L02-1313-T04-B 1 5.36E+06
Ca SWA-L02-1313-T05-B 1 7.67E+06
Ca SWA-L02-1313-T06-B 1 9.57E+06
Ca SWA-L02-1313-T07-B 1 1.10E+07
Ca SWA-L02-1313-T08-B 1 7.12E+06
Ca SWA-L02-1313-T09-B 1 5.68E+06
Ca SWA-L02-1313-T01-C 1 1.77E+04
Ca SWA-L02-1313-T02-C 1 6.00E+04
Ca SWA-L02-1313-T03-C 1 2.33E+04
Ca SWA-L02-1313-T04-C 1 5.45E+06
Ca SWA-L02-1313-T05-C 1 7.78E+06
Ca SWA-L02-1313-T06-C 1 8.65E+06
Ca SWA-L02-1313-T07-C 1 1.01E+07
Ca SWA-L02-1313-T08-C 1 7.31 E+06
Ca SWA-L02-1313-T09-C 1 5.56E+06
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.39E+04 6.2E-01 2.6E+00 8.3E+00
6.03E+04 5.4E-01 2.6E+00 8.3E+00
2.54E+04 6.9E-01 2.6E+00 8.3E+00 1000 125
5.11E+06 2.0E+00 2.6E+00 8.3E+00
7.16E+06 5.5E-01 2.6E+00 8.3E+00
9.49E+06 7.8E-01 2.6E+00 8.3E+00
1.06E+07 4.5E-01 2.6E+00 8.3E+00
8.25E+06 4.0E-01 2.6E+00 8.3E+00
5.58E+06 5.2E-01 2.6E+00 8.3E+00
1.68E+04 1.0E+00 2.6E+00 8.3E+00
5.63E+04 3.4E+00 2.6E+00 8.3E+00
2.41E+04 2.1E+00 2.6E+00 8.3E+00 1000 125
5.36E+06 7.5E-01 2.6E+00 8.3E+00
7.67E+06 6.8E-01 2.6E+00 8.3E+00
9.57E+06 6.9E-01 2.6E+00 8.3E+00
1.10E+07 6.0E-01 2.6E+00 8.3E+00
7.12E+06 1.1E+00 2.6E+00 8.3E+00
5.68E+06 5.6E-01 2.6E+00 8.3E+00
1.77E+04 6.2E-01 2.6E+00 8.3E+00
6.00E+04 3.2E-01 2.6E+00 8.3E+00
2.33E+04 3.3E+00 2.6E+00 8.3E+00 1000 125
5.45E+06 4.4E+00 2.6E+00 8.3E+00
7.78E+06 1.1E-01 2.6E+00 8.3E+00
8.65E+06 2.0E+00 2.6E+00 8.3E+00
1.01E+07 1.3E+00 2.6E+00 8.3E+00
7.31 E+06 1.4E-01 2.6E+00 8.3E+00
5.56E+06 7.1E-01 2.6E+00 8.3E+00
Ca SWA-L02-1313-B01-A 1 1.30E+OOU1/2 1.30E+00 8.3E+00 2.6E+00 8.3E+00
Ca SWA-L02-1313-B02-A 1 1.30E+OOU1/2 1.30E+00 5.7E-01 2.6E+00 8.3E+00
Ca SWA-L02-1313-B03-A 1 1.30E+OOU1/2 1.30E+00 5.1E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
2.65E+04 92% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
2.53E+04 99% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:1 7PM EPA Interlab L02 1313-1316SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
2.45E+04 97% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-388
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone.
1 ug/L
Cr SWA-L02-1313-T01-A 1 1.09E+03
Cr SWA-L02-1313-T02-A 1 1.84E+02
Cr SWA-L02-1313-T03-A 1 1.12E+03
Cr SWA-L02-1313-T04-A 1 9.35E+01
Cr SWA-L02-1313-T05-A 1 6.24E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.09E+03 4.7E-01 1.2E+00 3.8E+00
1.84E+02 7.4E-01 1.2E+00 3.8E+00
1.12E+03 1.9E+00 1.2E+00 3.8E+00 10 125
9.35E+01 1.1E+00 1.2E+00 3.8E+00
6.24E+00 1.9E+01 1.2E+00 3.8E+00
Cr SWA-L02-1313-T06-A 1 6.00E-01 U1/2 6.00E-01 1.2E+03 1.2E+00 3.8E+00
Cr SWA-L02-1313-T07-A 1 4.06E+00
Cr SWA-L02-1313-T08-A 1 4.77E+03
Cr SWA-L02-1313-T09-A 1 2.69E+04
Cr SWA-L02-1313-T01-B 1 1.19E+03
Cr SWA-L02-1313-T02-B 1 2.11E+02
Cr SWA-L02-1313-T03-B 1 9.28E+02
Cr SWA-L02-1313-T04-B 1 7.63E+01
Cr SWA-L02-1313-T05-B 1 7.32E+00
4.06E+00 4.3E+01 1.2E+00 3.8E+00
4.77E+03 4.0E-01 1.2E+00 3.8E+00
2.69E+04 3.9E-01 1.2E+00 3.8E+00
1.19E+03 1.5E+00 1.2E+00 3.8E+00
2.11E+02 2.7E+00 1.2E+00 3.8E+00
9.28E+02 2.6E+00 1.2E+00 3.8E+00 10 125
7.63E+01 9.0E-01 1.2E+00 3.8E+00
7.32E+00 2.3E+01 1.2E+00 3.8E+00
Cr SWA-L02-1313-T06-B 1 1.39E+OOE 1.39E+00 1.3E+02 1.2E+00 3.8E+00
Cr SWA-L02-1313-T07-B 1 4.29E+00
Cr SWA-L02-1313-T08-B 1 6.94E+03
Cr SWA-L02-1313-T09-B 1 2.45E+04
Cr SWA-L02-1313-T01-C 1 1.13E+03
Cr SWA-L02-1313-T02-C 1 1.86E+02
Cr SWA-L02-1313-T03-C 1 9.16E+02
Cr SWA-L02-1313-T04-C 1 6.35E+00
4.29E+00 1.5E+01 1.2E+00 3.8E+00
6.94E+03 6.1E-01 1.2E+00 3.8E+00
2.45E+04 1.7E+00 1.2E+00 3.8E+00
1.13E+03 1.7E+00 1.2E+00 3.8E+00
1.86E+02 7.9E-01 1.2E+00 3.8E+00
9.16E+02 3.6E+00 1.2E+00 3.8E+00 10 125
6.35E+00 4.9E+00 1.2E+00 3.8E+00
Cr SWA-L02-1313-T05-C 1 3.80E+00 E 3.80E+00 2.8E+01 1.2E+00 3.8E+00
Cr SWA-L02-1313-T06-C 1 3.77E+00 E 3.77E+00 2.2E+01 1.2E+00 3.8E+00
Cr SWA-L02-1313-T07-C 1 4.64E+00
Cr SWA-L02-1313-T08-C 1 7.38E+03
Cr SWA-L02-1313-T09-C 1 2.58E+04
4.64E+00 1.4E+01 1.2E+00 3.8E+00
7.38E+03 2.6E-01 1.2E+00 3.8E+00
2.58E+04 5.3E-01 1.2E+00 3.8E+00
Cr SWA-L02-1313-B01-A 1 6.00E-01 U1/2 6.00E-01 3.1E+02 1.2E+00 3.8E+00
Cr SWA-L02-1313-B02-A 1 6.00E-01 U1/2 6.00E-01 1.9E+02 1.2E+00 3.8E+00
Cr SWA-L02-1313-B03-A 1 6.00E-01 U1/2 6.00E-01 9.4E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
2.36E+03 99% VU ICP-OES 1 1/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
2.21E+03 103% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
2.15E+03 99% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-389
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Co SWA-L02-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 1.0E+02 1.8E+00 5.7E+00
Co SWA-L02-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 2.6E+02 1.8E+00 5.7E+00
Co SWA-L02-1313-T03-A 1 9.00E-01 U1/2 9.00E-01 3.3E+02 1.8E+00 5.7E+00 10 125
Co SWA-L02-1313-T04-A 1 2.62E+00 E
Co SWA-L02-1313-T05-A 1 1.26E+01
Co SWA-L02-1313-T06-A 1 8.60E+01
Co SWA-L02-1313-T07-A 1 2.01E+02
Co SWA-L02-1313-T08-A 1 2.40E+02
Co SWA-L02-1313-T09-A 1 3.49E+02
2.62E+00 6.8E+01 1.8E+00 5.7E+00
1.26E+01 2.8E+01 1.8E+00 5.7E+00
8.60E+01 3.2E+00 1.8E+00 5.7E+00
2.01 E+02 5.7E-01 1.8E+00 5.7E+00
2.40E+02 1.4E+00 1.8E+00 5.7E+00
3.49E+02 1.3E-01 1.8E+00 5.7E+00
Co SWA-L02-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 1.7E+02 1.8E+00 5.7E+00
Co SWA-L02-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 5.5E+01 1.8E+00 5.7E+00
Co SWA-L02-1313-T03-B 1 9.00E-01 U1/2 9.00E-01 4.1 E+02 1.8E+00 5.7E+00 10 125
Co SWA-L02-1313-T04-B 1 1.91E+OOE
Co SWA-L02-1313-T05-B 1 1.69E+01
Co SWA-L02-1313-T06-B 1 7.27E+01
Co SWA-L02-1313-T07-B 1 2.03E+02
Co SWA-L02-1313-T08-B 1 2.35E+02
Co SWA-L02-1313-T09-B 1 3.27E+02
Co SWA-L02-1313-T01-C 1 2.89E+00 E
1.91E+00 8.1E+01 1.8E+00 5.7E+00
1.69E+01 5.3E+00 1.8E+00 5.7E+00
7.27E+01 2.6E+00 1.8E+00 5.7E+00
2.03E+02 5.9E-01 1.8E+00 5.7E+00
2.35E+02 1.7E+00 1.8E+00 5.7E+00
3.27E+02 8.2E-01 1.8E+00 5.7E+00
2.89E+00 6.4E+01 1.8E+00 5.7E+00
Co SWA-L02-1313-T02-C 1 9.00E-01 U1/2 9.00E-01 2.2E+02 1.8E+00 5.7E+00
Co SWA-L02-1313-T03-C 1 9.00E-01 U1/2 9.00E-01 3.6E+02 1.8E+00 5.7E+00 10 125
Co SWA-L02-1313-T04-C 1 9.00E-01 U1/2 9.00E-01 5.0E+01 1.8E+00 5.7E+00
Co SWA-L02-1313-T05-C 1 1.99E+01
Co SWA-L02-1313-T06-C 1 5.35E+01
Co SWA-L02-1313-T07-C 1 1.75E+02
Co SWA-L02-1313-T08-C 1 2.46E+02
Co SWA-L02-1313-T09-C 1 3.40E+02
1.99E+01 1.5E+00 1.8E+00 5.7E+00
5.35E+01 8.3E+00 1.8E+00 5.7E+00
1.75E+02 1.6E+00 1.8E+00 5.7E+00
2.46E+02 4.9E-01 1.8E+00 5.7E+00
3.40E+02 7.8E-01 1.8E+00 5.7E+00
Co SWA-L02-1313-B01-A 1 9.00E-01 U1/2 9.00E-01 2.1E+01 1.8E+00 5.7E+00
Co SWA-L02-1313-B02-A 1 9.00E-01 U1/2 9.00E-01 2.2E+01 1.8E+00 5.7E+00
Co SWA-L02-1313-B03-A 1 9.00E-01 U1/2 9.00E-01 1.9E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.23E+03 98% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.25E+03 100% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.22E+03 97% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-390
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cu SWA-L02-1313-T01-A 1 1.85E+OOU1/2 1.85E+00 1.2E+01 3.7E+00 1.2E+01
Cu SWA-L02-1313-T02-A 1 6.55E+00 E
Cu SWA-L02-1313-T03-A 1 5.45E+00 E
Cu SWA-L02-1313-T04-A 1 2.24E+01
Cu SWA-L02-1313-T05-A 1 2.92E+01
Cu SWA-L02-1313-T06-A 1 5.26E+01
Cu SWA-L02-1313-T07-A 1 6.74E+01
Cu SWA-L02-1313-T08-A 1 1.32E+02
Cu SWA-L02-1313-T09-A 1 2.02E+03
6.55E+00 3.8E+01 3.7E+00 1.2E+01
5.45E+00 3.4E+01 3.7E+00 1.2E+01 10 125
2.24E+01 2.4E+01 3.7E+00 1.2E+01
2.92E+01 8.9E+00 3.7E+00 1.2E+01
5.26E+01 1.4E+01 3.7E+00 1.2E+01
6.74E+01 1.8E+00 3.7E+00 1.2E+01
1.32E+02 2.5E+00 3.7E+00 1.2E+01
2.02E+03 1.2E+00 3.7E+00 1.2E+01
Cu SWA-L02-1313-T01-B 1 1.85E+OOU1/2 1.85E+00 1.3E+02 3.7E+00 1.2E+01
Cu SWA-L02-1313-T02-B 1 4.88E+00 E
Cu SWA-L02-1313-T03-B 1 4.00E+00 E
Cu SWA-L02-1313-T04-B 1 1.94E+01
Cu SWA-L02-1313-T05-B 1 3.04E+01
Cu SWA-L02-1313-T06-B 1 4.56E+01
Cu SWA-L02-1313-T07-B 1 6.63E+01
Cu SWA-L02-1313-T08-B 1 1.45E+02
Cu SWA-L02-1313-T09-B 1 1.77E+03
Cu SWA-L02-1313-T01-C 1 4.45E+00 E
Cu SWA-L02-1313-T02-C 1 6.89E+00 E
Cu SWA-L02-1313-T03-C 1 4.92E+00 E
Cu SWA-L02-1313-T04-C 1 2.08E+01
Cu SWA-L02-1313-T05-C 1 3.52E+01
Cu SWA-L02-1313-T06-C 1 3.71 E+01
Cu SWA-L02-1313-T07-C 1 6.05E+01
Cu SWA-L02-1313-T08-C 1 1.54E+02
Cu SWA-L02-1313-T09-C 1 1.93E+03
4.88E+00 6.4E+01 3.7E+00 1.2E+01
4.00E+00 6.3E+01 3.7E+00 1.2E+01 10 125
1.94E+01 3.5E+00 3.7E+00 1.2E+01
3.04E+01 3.8E+00 3.7E+00 1.2E+01
4.56E+01 1.8E+00 3.7E+00 1.2E+01
6.63E+01 2.6E+00 3.7E+00 1.2E+01
1.45E+02 6.3E-01 3.7E+00 1.2E+01
1.77E+03 1.3E+00 3.7E+00 1.2E+01
4.45E+00 2.1E+01 3.7E+00 1.2E+01
6.89E+00 9.0E+01 3.7E+00 1.2E+01
4.92E+00 3.7E+01 3.7E+00 1.2E+01 10 125
2.08E+01 6.6E+00 3.7E+00 1.2E+01
3.52E+01 2.0E+01 3.7E+00 1.2E+01
3.71 E+01 9.8E+00 3.7E+00 1.2E+01
6.05E+01 1.1E+01 3.7E+00 1.2E+01
1.54E+02 8.2E-01 3.7E+00 1.2E+01
1.93E+03 1.9E-01 3.7E+00 1.2E+01
Cu SWA-L02-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 1.6E+02 3.7E+00 1.2E+01
Cu SWA-L02-1313-B02-A 1 1.85E+OOU1/2 1.85E+00 3.7E+02 3.7E+00 1.2E+01
Cu SWA-L02-1313-B03-A 1 1.85E+OOU1/2 1.85E+00 1.3E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.27E+03 101% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.30E+03 104% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.26E+03 100% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-391
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone.
1 ug/L
Fe SWA-L02-1313-T01-A 1 6.39E+01
Fe SWA-L02-1313-T02-A 1 4.92E+01
Fe SWA-L02-1313-T03-A 1 2.49E+02
Fe SWA-L02-1313-T04-A 1 2.41E+02
Fe SWA-L02-1313-T05-A 1 2.26E+01
Fe SWA-L02-1313-T06-A 1 1.72E+02
Fe SWA-L02-1313-T07-A 1 7.34E+04
Fe SWA-L02-1313-T08-A 1 1.69E+05
Fe SWA-L02-1313-T09-A 1 2.22E+05
Fe SWA-L02-1313-T01-B 1 1.09E+02
Fe SWA-L02-1313-T02-B 1 1.06E+02
Fe SWA-L02-1313-T03-B 1 2.39E+02
Fe SWA-L02-1313-T04-B 1 1.34E+02
Fe SWA-L02-1313-T05-B 1 4.54E+01
Fe SWA-L02-1313-T06-B 1 1.44E+02
Fe SWA-L02-1313-T07-B 1 6.62E+04
Fe SWA-L02-1313-T08-B 1 1.71E+05
Fe SWA-L02-1313-T09-B 1 2.13E+05
Fe SWA-L02-1313-T01-C 1 1.35E+02
Fe SWA-L02-1313-T02-C 1 1.31E+02
Fe SWA-L02-1313-T03-C 1 2.63E+02
Fe SWA-L02-1313-T04-C 1 6.71 E+01
Fe SWA-L02-1313-T05-C 1 5.99E+01
Fe SWA-L02-1313-T06-C 1 9.10E+01
Fe SWA-L02-1313-T07-C 1 5.30E+04
Fe SWA-L02-1313-T08-C 1 1.77E+05
Fe SWA-L02-1313-T09-C 1 2.18E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.39E+01 9.8E-01 2.0E+00 6.4E+00
4.92E+01 1.5E+00 2.0E+00 6.4E+00
2.49E+02 1.2E+00 2.0E+00 6.4E+00 1000 125
2.41 E+02 1.8E+00 2.0E+00 6.4E+00
2.26E+01 2.5E+00 2.0E+00 6.4E+00
1.72E+02 5.5E-01 2.0E+00 6.4E+00
7.34E+04 1.9E-01 2.0E+00 6.4E+00
1.69E+05 1.3E+00 2.0E+00 6.4E+00
2.22E+05 9.4E-01 2.0E+00 6.4E+00
1.09E+02 1.2E+00 2.0E+00 6.4E+00
1.06E+02 3.0E+00 2.0E+00 6.4E+00
2.39E+02 2.9E+00 2.0E+00 6.4E+00 1000 125
1.34E+02 1.2E+00 2.0E+00 6.4E+00
4.54E+01 2.5E+00 2.0E+00 6.4E+00
1.44E+02 1.4E+00 2.0E+00 6.4E+00
6.62E+04 8.4E-01 2.0E+00 6.4E+00
1.71E+05 5.5E-01 2.0E+00 6.4E+00
2.13E+05 2.0E+00 2.0E+00 6.4E+00
1.35E+02 8.1E-01 2.0E+00 6.4E+00
1.31 E+02 6.4E-01 2.0E+00 6.4E+00
2.63E+02 3.6E+00 2.0E+00 6.4E+00 1000 125
6.71 E+01 1.8E+00 2.0E+00 6.4E+00
5.99E+01 2.5E+00 2.0E+00 6.4E+00
9.10E+01 8.8E-01 2.0E+00 6.4E+00
5.30E+04 1.2E+00 2.0E+00 6.4E+00
1.77E+05 1.2E+00 2.0E+00 6.4E+00
2.18E+05 1.9E+00 2.0E+00 6.4E+00
Fe SWA-L02-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 8.3E+00 2.0E+00 6.4E+00
Fe SWA-L02-1313-B02-A 1 1.00E+OOU1/2 1.00E+00 3.2E+00 2.0E+00 6.4E+00
Fe SWA-L02-1313-B03-A 1 1.00E+OOU1/2 1.00E+00 2.0E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.56E+03 105% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.64E+03 112% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:1 7PM EPA Interlab L02 1313-1316SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.70E+03 115% VUICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-392
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qu<
1 1 ug/L |
Pb SWA-L02-1313-T01-A 1 1.59E+01 E
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.59E+01 1.2E+01 6.8E+00 2.2E+01
Pb SWA-L02-1313-T02-A 1 3.40E+00 U1/2 3.40E+00 2.2E+01 6.8E+00 2.2E+01
Pb SWA-L02-1313-T03-A 1 2.92E+01
Pb SWA-L02-1313-T04-A 1 1.45E+01 E
Pb SWA-L02-1313-T05-A 1 1.42E+01 E
Pb SWA-L02-1313-T06-A 1 1.71E+01 E
Pb SWA-L02-1313-T07-A 1 2.66E+01
Pb SWA-L02-1313-T08-A 1 4.62E+02
Pb SWA-L02-1313-T09-A 1 4.94E+03
Pb SWA-L02-1313-T01-B 1 1.85E+01 E
Pb SWA-L02-1313-T02-B 1 9.52E+00 E
Pb SWA-L02-1313-T03-B 1 1.24E+01 E
2.92E+01 2.7E+01 6.8E+00 2.2E+01 10 125
1.45E+01 4.2E+01 6.8E+00 2.2E+01
1.42E+01 5.3E+01 6.8E+00 2.2E+01
1.71E+01 7.0E+01 6.8E+00 2.2E+01
2.66E+01 3.5E+00 6.8E+00 2.2E+01
4.62E+02 7.5E-01 6.8E+00 2.2E+01
4.94E+03 3.6E-01 6.8E+00 2.2E+01
1.85E+01 1.3E+01 6.8E+00 2.2E+01
9.52E+00 7.5E+01 6.8E+00 2.2E+01
1.24E+01 5.0E+01 6.8E+00 2.2E+01 10 125
Pb SWA-L02-1313-T04-B 1 3.40E+00 U1/2 3.40E+00 3.9E+02 6.8E+00 2.2E+01
Pb SWA-L02-1313-T05-B 1 1.23E+01 E
Pb SWA-L02-1313-T06-B 1 1.57E+01 E
Pb SWA-L02-1313-T07-B 1 1.84E+01 E
Pb SWA-L02-1313-T08-B 1 5.22E+02
Pb SWA-L02-1313-T09-B 1 4.47E+03
Pb SWA-L02-1313-T01-C 1 2.31E+01
1.23E+01 3.2E+01 6.8E+00 2.2E+01
1.57E+01 9.5E+01 6.8E+00 2.2E+01
1.84E+01 7.0E+01 6.8E+00 2.2E+01
5.22E+02 1.9E+00 6.8E+00 2.2E+01
4.47E+03 1.9E+00 6.8E+00 2.2E+01
2.31E+01 2.7E+01 6.8E+00 2.2E+01
Pb SWA-L02-1313-T02-C 1 3.40E+00 U1/2 3.40E+00 3.3E+02 6.8E+00 2.2E+01
Pb SWA-L02-1313-T03-C 1 1.78E+01 E
Pb SWA-L02-1313-T04-C 1 1.09E+01 E
Pb SWA-L02-1313-T05-C 1 1.60E+01 E
Pb SWA-L02-1313-T06-C 1 1.44E+01 E
Pb SWA-L02-1313-T07-C 1 1.74E+01 E
Pb SWA-L02-1313-T08-C 1 5.49E+02
Pb SWA-L02-1313-T09-C 1 4.70E+03
1.78E+01 1.5E+01 6.8E+00 2.2E+01 10 125
1.09E+01 1.5E+01 6.8E+00 2.2E+01
1.60E+01 1.0E+02 6.8E+00 2.2E+01
1.44E+01 6.2E+01 6.8E+00 2.2E+01
1.74E+01 2.5E+01 6.8E+00 2.2E+01
5.49E+02 1.8E+00 6.8E+00 2.2E+01
4.70E+03 3.4E-01 6.8E+00 2.2E+01
Pb SWA-L02-1313-B01-A 1 3.40E+00 U1/2 3.40E+00 2.6E+01 6.8E+00 2.2E+01
Pb SWA-L02-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 6.0E+01 6.8E+00 2.2E+01
Pb SWA-L02-1313-B03-A 1 3.40E+00 U1/2 3.40E+00 7.4E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.32E+03 103% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.35E+03 107% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.30E+03 103% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-393
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li SWA-L02-1313-T01-A 1
Li SWA-L02-1313-T02-A 1
Li SWA-L02-1313-T03-A 1
Li SWA-L02-1313-T04-A 1
Li SWA-L02-1313-T05-A 1
Li SWA-L02-1313-T06-A 1
Li SWA-L02-1313-T07-A 1
Li SWA-L02-1313-T08-A 1
Li SWA-L02-1313-T09-A 1
Li SWA-L02-1313-T01-B 1
Li SWA-L02-1313-T02-B 1
Li SWA-L02-1313-T03-B 1
Li SWA-L02-1313-T04-B 1
Li SWA-L02-1313-T05-B 1
Li SWA-L02-1313-T06-B 1
Li SWA-L02-1313-T07-B 1
Li SWA-L02-1313-T08-B 1
Li SWA-L02-1313-T09-B 1
Li SWA-L02-1313-T01-C 1
Li SWA-L02-1313-T02-C 1
Li SWA-L02-1313-T03-C 1
Li SWA-L02-1313-T04-C 1
Li SWA-L02-1313-T05-C 1
Li SWA-L02-1313-T06-C 1
Li SWA-L02-1313-T07-C 1
Li SWA-L02-1313-T08-C 1
Li SWA-L02-1313-T09-C 1
Li SWA-L02-1313-B01-A 1
Li SWA-L02-1313-B02-A 1
Li SWA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.49E+00 E
9.24E+00
2.38E+00 E
4.76E+02
8.27E+02
1.27E+03
1.50E+03
1.24E+03
1.28E+03
9.50E-01 U1/2
4.71 E+00 E
9.50E-01 U1/2
5.14E+02
9.45E+02
1.30E+03
1.61E+03
1.11E+03
1.15E+03
9.50E-01 U1/2
6.99E+00
9.50E-01 U1/2
5.20E+02
9.85E+02
1 .20E+03
1 .42E+03
1.14E+03
1 .22E+03
3.22E+00 E
9.50E-01 U1/2
9.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.49E+00 1.1E+01 1.9E+00 6.0E+00
9.24E+00 2.4E+01 1.9E+00 6.0E+00
2.38E+00 6.2E+01 1.9E+00 6.0E+00 10 125
4.76E+02 5.9E+00 1.9E+00 6.0E+00
8.27E+02 1.5E+00 1.9E+00 6.0E+00
1.27E+03 4.4E+00 1.9E+00 6.0E+00
1.50E+03 4.6E+00 1.9E+00 6.0E+00
1.24E+03 3.3E+00 1.9E+00 6.0E+00
1.28E+03 5.4E+00 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
4.71 E+00 7.2E+00 1.9E+00 6.0E+00
9.50E-01 5.1E+01 1.9E+00 6.0E+00 10 125
5.14E+02 2.8E+00 1.9E+00 6.0E+00
9.45E+02 2.8E+00 1.9E+00 6.0E+00
1.30E+03 2.6E+00 1.9E+00 6.0E+00
1.61E+03 2.3E+00 1.9E+00 6.0E+00
1.11E+03 4.8E+00 1.9E+00 6.0E+00
1.15E+03 4.4E+00 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00
6.99E+00 2.3E+01 1.9E+00 6.0E+00
9.50E-01 9.9E+01 1.9E+00 6.0E+00 10 125
5.20E+02 1.3E+01 1.9E+00 6.0E+00
9.85E+02 1.4E+00 1.9E+00 6.0E+00
1.20E+03 2.7E+00 1.9E+00 6.0E+00
1.42E+03 4.4E+00 1.9E+00 6.0E+00
1.14E+03 6.3E+00 1.9E+00 6.0E+00
1.22E+03 2.3E+00 1.9E+00 6.0E+00
3.22E+00 4.5E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 5.9E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.17E+03 93% VU ICP-OES 1 1/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.18E+03 94% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.08E+03 86% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-394
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn SWA-L02-1313-T01-A 1
Mn SWA-L02-1313-T02-A 1
Mn SWA-L02-1313-T03-A 1
Mn SWA-L02-1313-T04-A 1
Mn SWA-L02-1313-T05-A 1
Mn SWA-L02-1313-T06-A 1
Mn SWA-L02-1313-T07-A 1
Mn SWA-L02-1313-T08-A 1
Mn SWA-L02-1313-T09-A 1
Mn SWA-L02-1313-T01-B 1
Mn SWA-L02-1313-T02-B 1
Mn SWA-L02-1313-T03-B 1
Mn SWA-L02-1313-T04-B 1
Mn SWA-L02-1313-T05-B 1
Mn SWA-L02-1313-T06-B 1
Mn SWA-L02-1313-T07-B 1
Mn SWA-L02-1313-T08-B 1
Mn SWA-L02-1313-T09-B 1
Mn SWA-L02-1313-T01-C 1
Mn SWA-L02-1313-T02-C 1
Mn SWA-L02-1313-T03-C 1
Mn SWA-L02-1313-T04-C 1
Mn SWA-L02-1313-T05-C 1
Mn SWA-L02-1313-T06-C 1
Mn SWA-L02-1313-T07-C 1
Mn SWA-L02-1313-T08-C 1
Mn SWA-L02-1313-T09-C 1
Mn SWA-L02-1313-B01-A 1
Mn SWA-L02-1313-B02-A 1
Mn SWA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
2.52E+01
4.68E+01
3.61 E+03
1.42E+04
2.55E+04
2.46E+04
2.87E+04
4.45E+00 E
6.47E+00
2.60E+01
4.41 E+01
4.42E+03
1.33E+04
2.58E+04
2.34E+04
2.66E+04
1.15E+01
9.80E+00
2.91E+01
4.49E+01
5.19E+03
1.07E+04
2.28E+04
2.42E+04
2.78E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 6.0E+00 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
2.52E+01 5.5E-01 2.0E+00 6.4E+00 10 125
4.68E+01 1.6E+00 2.0E+00 6.4E+00
3.61 E+03 2.6E-01 2.0E+00 6.4E+00
1.42E+04 5.1E-01 2.0E+00 6.4E+00
2.55E+04 2.8E-01 2.0E+00 6.4E+00
2.46E+04 4.7E-01 2.0E+00 6.4E+00
2.87E+04 5.5E-01 2.0E+00 6.4E+00
4.45E+00 1.2E+00 2.0E+00 6.4E+00
6.47E+00 2.8E+00 2.0E+00 6.4E+00
2.60E+01 2.4E+00 2.0E+00 6.4E+00 10 125
4.41 E+01 7.4E-02 2.0E+00 6.4E+00
4.42E+03 9.0E-02 2.0E+00 6.4E+00
1.33E+04 7.7E-01 2.0E+00 6.4E+00
2.58E+04 8.2E-01 2.0E+00 6.4E+00
2.34E+04 1.5E-01 2.0E+00 6.4E+00
2.66E+04 8.8E-01 2.0E+00 6.4E+00
1.15E+01 6.0E-01 2.0E+00 6.4E+00
9.80E+00 1.6E+00 2.0E+00 6.4E+00
2.91E+01 3.2E+00 2.0E+00 6.4E+00 10 125
4.49E+01 2.2E+00 2.0E+00 6.4E+00
5.19E+03 9.2E-01 2.0E+00 6.4E+00
1.07E+04 1.8E+00 2.0E+00 6.4E+00
2.28E+04 1.4E+00 2.0E+00 6.4E+00
2.42E+04 1.0E+00 2.0E+00 6.4E+00
2.78E+04 1.2E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 5.8E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.31E+03 103% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.26E+03 98% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.35E+03 105% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3 :45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-395
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg SWA-L02-1313-T01-A 1
Mg SWA-L02-1313-T02-A 1
Mg SWA-L02-1313-T03-A 1
Mg SWA-L02-1313-T04-A 1
Mg SWA-L02-1313-T05-A 1
Mg SWA-L02-1313-T06-A 1
Mg SWA-L02-1313-T07-A 1
Mg SWA-L02-1313-T08-A 1
Mg SWA-L02-1313-T09-A 1
Mg SWA-L02-1313-T01-B 1
Mg SWA-L02-1313-T02-B 1
Mg SWA-L02-1313-T03-B 1
Mg SWA-L02-1313-T04-B 1
Mg SWA-L02-1313-T05-B 1
Mg SWA-L02-1313-T06-B 1
Mg SWA-L02-1313-T07-B 1
Mg SWA-L02-1313-T08-B 1
Mg SWA-L02-1313-T09-B 1
Mg SWA-L02-1313-T01-C 1
Mg SWA-L02-1313-T02-C 1
Mg SWA-L02-1313-T03-C 1
Mg SWA-L02-1313-T04-C 1
Mg SWA-L02-1313-T05-C 1
Mg SWA-L02-1313-T06-C 1
Mg SWA-L02-1313-T07-C 1
Mg SWA-L02-1313-T08-C 1
Mg SWA-L02-1313-T09-C 1
Mg SWA-L02-1313-B01-A 1
Mg SWA-L02-1313-B02-A 1
Mg SWA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
6.51 E+02
4.18E+05
9.00E+05
1.39E+06
1.67E+06
1.37E+06
1.22E+06
2.07E+02
3.03E+02
7.96E+02
4.48E+05
9.69E+05
1.38E+06
1.74E+06
1.19E+06
1.15E+06
4.19E+02
4.67E+02
9.54E+02
4.72E+05
9.84E+05
1.24E+06
1.55E+06
1.23E+06
1.18E+06
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 6.8E+00 1.0E+00 3.2E+00
5.00E-01 1.9E+01 1.0E+00 3.2E+00
6.51E+02 1.3E+00 1.0E+00 3.2E+00 1000 125
4.18E+05 1.4E+00 1.0E+00 3.2E+00
9.00E+05 5.8E-01 1.0E+00 3.2E+00
1.39E+06 1.1E+00 1.0E+00 3.2E+00
1.67E+06 4.5E-01 1.0E+00 3.2E+00
1.37E+06 1.0E+00 1.0E+00 3.2E+00
1.22E+06 3.0E-01 1.0E+00 3.2E+00
2.07E+02 1.8E+00 1.0E+00 3.2E+00
3.03E+02 2.6E+00 1.0E+00 3.2E+00
7.96E+02 1.2E+00 1.0E+00 3.2E+00 1000 125
4.48E+05 7.7E-01 1.0E+00 3.2E+00
9.69E+05 3.5E-01 1.0E+00 3.2E+00
1.38E+06 7.7E-01 1.0E+00 3.2E+00
1.74E+06 1.5E+00 1.0E+00 3.2E+00
1.19E+06 1.1E+00 1.0E+00 3.2E+00
1.15E+06 1.4E+00 1.0E+00 3.2E+00
4.19E+02 3.4E+00 1.0E+00 3.2E+00
4.67E+02 1.0E+00 1.0E+00 3.2E+00
9.54E+02 4.2E+00 1.0E+00 3.2E+00 1000 125
4.72E+05 5.6E+00 1.0E+00 3.2E+00
9.84E+05 1.0E+00 1.0E+00 3.2E+00
1.24E+06 2.0E+00 1.0E+00 3.2E+00
1.55E+06 8.7E-01 1.0E+00 3.2E+00
1.23E+06 1.9E-01 1.0E+00 3.2E+00
1.18E+06 1.0E+00 1.0E+00 3.2E+00
5.00E-01 8.1E+00 1.0E+00 3.2E+00
5.00E-01 1.0E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.86E+03 97% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.93E+03 91% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
2.14E+03 95% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3 :45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-396
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 1 ug/L
Mo SWA-L02-1313-T01-A 1 1.60E+02
Mo SWA-L02-1313-T02-A 1 1.97E+02
Mo SWA-L02-1313-T03-A 1 1.77E+02
Mo SWA-L02-1313-T04-A 1 1.75E+02
Mo SWA-L02-1313-T05-A 1 1.61E+02
Mo SWA-L02-1313-T06-A 1 7.06E+01
Mo SWA-L02-1313-T07-A 1 1.98E+01
Mo SWA-L02-1313-T08-A 1 1.95E+01
Mo SWA-L02-1313-T09-A 1 1.07E+01
Mo SWA-L02-1313-T01-B 1 1.75E+02
Mo SWA-L02-1313-T02-B 1 1.88E+02
Mo SWA-L02-1313-T03-B 1 1.51E+02
Mo SWA-L02-1313-T04-B 1 1.81E+02
Mo SWA-L02-1313-T05-B 1 1.66E+02
Mo SWA-L02-1313-T06-B 1 8.21E+01
Mo SWA-L02-1313-T07-B 1 1.78E+01
Mo SWA-L02-1313-T08-B 1 1.28E+01
Mo SWA-L02-1313-T09-B 1 6.19E+00
Mo SWA-L02-1313-T01-C 1 1.80E+02
Mo SWA-L02-1313-T02-C 1 2.15E+02
Mo SWA-L02-1313-T03-C 1 1.44E+02
Mo SWA-L02-1313-T04-C 1 1.76E+02
Mo SWA-L02-1313-T05-C 1 1.61E+02
Mo SWA-L02-1313-T06-C 1 9.31E+01
Mo SWA-L02-1313-T07-C 1 2.28E+01
Mo SWA-L02-1313-T08-C 1 1.36E+01
Mo SWA-L02-1313-T09-C 1 4.96E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.60E+02 1.7E+00 1.2E+00 3.8E+00
1.97E+02 9.8E-01 1.2E+00 3.8E+00
1.77E+02 2.5E+00 1.2E+00 3.8E+00 10 125
1.75E+02 2.1E+00 1.2E+00 3.8E+00
1.61E+02 1.2E+00 1.2E+00 3.8E+00
7.06E+01 3.6E+00 1.2E+00 3.8E+00
1.98E+01 2.0E+01 1.2E+00 3.8E+00
1.95E+01 2.4E+01 1.2E+00 3.8E+00
1.07E+01 5.4E+01 1.2E+00 3.8E+00
1.75E+02 2.1E+00 1.2E+00 3.8E+00
1.88E+02 5.5E-01 1.2E+00 3.8E+00
1.51E+02 3.3E+00 1.2E+00 3.8E+00 10 125
1.81E+02 1.4E+00 1.2E+00 3.8E+00
1.66E+02 1.7E+00 1.2E+00 3.8E+00
8.21E+01 2.3E+00 1.2E+00 3.8E+00
1.78E+01 1.4E+01 1.2E+00 3.8E+00
1.28E+01 8.3E+00 1.2E+00 3.8E+00
6.19E+00 8.9E+00 1.2E+00 3.8E+00
1.80E+02 6.8E-01 1.2E+00 3.8E+00
2.15E+02 2.4E+00 1.2E+00 3.8E+00
1.44E+02 5.9E+00 1.2E+00 3.8E+00 10 125
1.76E+02 5.5E+00 1.2E+00 3.8E+00
1.61E+02 9.4E-01 1.2E+00 3.8E+00
9.31 E+01 5.1E+00 1.2E+00 3.8E+00
2.28E+01 7.5E+00 1.2E+00 3.8E+00
1.36E+01 2.8E+01 1.2E+00 3.8E+00
4.96E+00 1.6E+02 1.2E+00 3.8E+00
Mo SWA-L02-1313-B01-A 1 6.00E-01 U1/2 6.00E-01 5.5E+02 1.2E+00 3.8E+00
Mo SWA-L02-1313-B02-A 1 6.00E-01 U1/2 6.00E-01 1.6E+02 1.2E+00 3.8E+00
Mo SWA-L02-1313-B03-A 1 6.00E-01 U1/2 6.00E-01 1.8E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.48E+03 104% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.52E+03 109% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.46E+03 106% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-397
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L02-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 2.5E+02 1.8E+00 5.7E+00
Ni SWA-L02-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 3.2E+02 1.8E+00 5.7E+00
Ni SWA-L02-1313-T03-A 1 9.93E+00
Ni SWA-L02-1313-T04-A 1 2.21E+01
Ni SWA-L02-1313-T05-A 1 3.62E+01
Ni SWA-L02-1313-T06-A 1 2.43E+02
Ni SWA-L02-1313-T07-A 1 4.76E+02
Ni SWA-L02-1313-T08-A 1 5.04E+02
Ni SWA-L02-1313-T09-A 1 6.26E+02
Ni SWA-L02-1313-T01-B 1 2.61 E+00 E
9.93E+00 2.5E+01 1.8E+00 5.7E+00 10 125
2.21 E+01 8.4E+00 1.8E+00 5.7E+00
3.62E+01 5.3E+00 1.8E+00 5.7E+00
2.43E+02 1.2E+00 1.8E+00 5.7E+00
4.76E+02 7.1E-01 1.8E+00 5.7E+00
5.04E+02 1.3E+00 1.8E+00 5.7E+00
6.26E+02 2.4E-01 1.8E+00 5.7E+00
2.61 E+00 8.3E+00 1.8E+00 5.7E+00
Ni SWA-L02-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 4.0E+01 1.8E+00 5.7E+00
Ni SWA-L02-1313-T03-B 1 7.30E+00
Ni SWA-L02-1313-T04-B 1 1.38E+01
Ni SWA-L02-1313-T05-B 1 4.87E+01
Ni SWA-L02-1313-T06-B 1 2.19E+02
Ni SWA-L02-1313-T07-B 1 4.78E+02
Ni SWA-L02-1313-T08-B 1 4.68E+02
Ni SWA-L02-1313-T09-B 1 5.82E+02
7.30E+00 4.0E+01 1.8E+00 5.7E+00 10 125
1.38E+01 1.3E+01 1.8E+00 5.7E+00
4.87E+01 9.2E+00 1.8E+00 5.7E+00
2.19E+02 6.1E-01 1.8E+00 5.7E+00
4.78E+02 5.4E-01 1.8E+00 5.7E+00
4.68E+02 4.8E-01 1.8E+00 5.7E+00
5.82E+02 7.9E-01 1.8E+00 5.7E+00
Ni SWA-L02-1313-T01-C 4.89E+00 U1/2 O.OOE+00 4.5E+00 1.8E+00 5.7E+00
Ni SWA-L02-1313-T02-C 9.00E-01 U1/2 O.OOE+00 2.0E+02 1.8E+00 5.7E+00
Ni SWA-L02-1313-T03-C 9.15E+00 U1/2 O.OOE+00 1.6E+01 1.8E+00 5.7E+00 10 125
Ni SWA-L02-1313-T04-C 7.82E+00 U1/2 O.OOE+00 2.0E+01 1.8E+00 5.7E+00
Ni SWA-L02-1313-T05-C 6.17E+01 U1/2 O.OOE+00 3.7E+00 1.8E+00 5.7E+00
Ni SWA-L02-1313-T06-C 1.58E+02U1/2 O.OOE+00 5.6E+00 1.8E+00 5.7E+00
Ni SWA-L02-1313-T07-C 4.14E+02 U1/2 O.OOE+00 3.8E-01 1.8E+00 5.7E+00
Ni SWA-L02-1313-T08-C 4.88E+02 U1/2 O.OOE+00 1.5E+00 1.8E+00 5.7E+00
Ni SWA-L02-1313-T09-C 6.05E+02 U1/2 O.OOE+00 8.6E-01 1.8E+00 5.7E+00
Ni SWA-L02-1313-B01-A 9.00E-01 U1/2 O.OOE+00 1.1E+02 1.8E+00 5.7E+00
Ni SWA-L02-1313-B02-A 9.00E-01 U1/2 O.OOE+00 1.0E+02 1.8E+00 5.7E+00
Ni SWA-L02-1313-B03-A 9.00E-01 U1/2 O.OOE+00 3.7E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.21E+03 96% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.23E+03 98% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.20E+03 95% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-398
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qu
1 1 ug/L
P SWA-L02-1313-T01-A 1 1.20E+02
P SWA-L02-1313-T02-A 1 4.08E+01
P SWA-L02-1313-T03-A 1 7.45E+01
P SWA-L02-1313-T04-A 1 1.12E+02
P SWA-L02-1313-T05-A 1 6.71 E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.20E+02 1.5E+01 3.7E+00 1.2E+01
4.08E+01 1.5E+01 3.7E+00 1.2E+01
7.45E+01 2.8E+01 3.7E+00 1.2E+01 1000 125
1.12E+02 1.5E+01 3.7E+00 1.2E+01
6.71E+01 4.9E+01 3.7E+00 1.2E+01
P SWA-L02-1313-T06-A 1 1.85E+OOU1/2 1.85E+00 1 .4E+03 3.7E+00 1.2E+01
P SWA-L02-1313-T07-A 1 9.94E+00 E
P SWA-L02-1313-T08-A 1 2.97E+03
P SWA-L02-1313-T09-A 1 2.32E+03
P SWA-L02-1313-T01-B 1 1.18E+02
P SWA-L02-1313-T02-B 1 2.78E+01
P SWA-L02-1313-T03-B 1 6.07E+01
P SWA-L02-1313-T04-B 1 5.96E+01
P SWA-L02-1313-T05-B 1 7.61 E+01
P SWA-L02-1313-T06-B 1 3.60E+01
P SWA-L02-1313-T07-B 1 2.92E+01
P SWA-L02-1313-T08-B 1 1.54E+03
P SWA-L02-1313-T09-B 1 2.06E+03
P SWA-L02-1313-T01-C 1 1.50E+02
P SWA-L02-1313-T02-C 1 8.65E+00 E
P SWA-L02-1313-T03-C 1 5.74E+01
P SWA-L02-1313-T04-C 1 5.19E+01
P SWA-L02-1313-T05-C 1 1.06E+02
P SWA-L02-1313-T06-C 1 7.95E+01
P SWA-L02-1313-T07-C 1 4.88E+01
P SWA-L02-1313-T08-C 1 1.59E+03
P SWA-L02-1313-T09-C 1 2.20E+03
9.94E+00 2.6E+02 3.7E+00 1.2E+01
2.97E+03 2.0E+00 3.7E+00 1 .2E+01
2.32E+03 8.2E-01 3.7E+00 1 .2E+01
1.18E+02 8.7E+00 3.7E+00 1 .2E+01
2.78E+01 3.7E+01 3.7E+00 1 .2E+01
6.07E+01 3.6E+01 3.7E+00 1 .2E+01 1000 125
5.96E+01 4.1 E+01 3.7E+00 1 .2E+01
7.61E+01 2.0E+01 3.7E+00 1 .2E+01
3.60E+01 1.7E+01 3.7E+00 1 .2E+01
2.92E+01 4.1E+01 3.7E+00 1 .2E+01
1.54E+03 2.2E+00 3.7E+00 1 .2E+01
2.06E+03 2.0E+00 3.7E+00 1 .2E+01
1.50E+02 1.2E+01 3.7E+00 1 .2E+01
8.65E+00 1.6E+02 3.7E+00 1 .2E+01
5.74E+01 1.9E+01 3.7E+00 1 .2E+01 1000 125
5.19E+01 3.1E+01 3.7E+00 1 .2E+01
1.06E+02 1.8E+01 3.7E+00 1 .2E+01
7.95E+01 2.9E+01 3.7E+00 1 .2E+01
4.88E+01 8.8E+01 3.7E+00 1 .2E+01
1.59E+03 2.2E-01 3.7E+00 1 .2E+01
2.20E+03 5.5E-01 3.7E+00 1 .2E+01
P SWA-L02-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 1 .9E+04 3.7E+00 1 .2E+01
P SWA-L02-1313-B02-A 1 1.85E+OOU1/2 1.85E+00 5.5E+01 3.7E+00 1 .2E+01
P SWA-L02-1313-B03-A 1 1.85E+OOU1/2 1.85E+00 8.1E+02 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.28E+03 96% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.32E+03 101% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.27E+03 97% VU ICP-OES 1 1/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-399
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
K SWA-L02-1313-T01-A 1 3.59E+05
K SWA-L02-1313-T02-A 1 4.10E+05
K SWA-L02-1313-T03-A 1 3.80E+05
K SWA-L02-1313-T04-A 1 5.08E+05
K SWA-L02-1313-T05-A 1 5.06E+05
K SWA-L02-1313-T06-A 1 5.67E+05
K SWA-L02-1313-T07-A 1 5.55E+05
K SWA-L02-1313-T08-A 1 4.89E+05
K SWA-L02-1313-T09-A 1 5.29E+05
K SWA-L02-1313-T01-B 1 5.10E+05
K SWA-L02-1313-T02-B 1 3.98E+05
K SWA-L02-1313-T03-B 1 3.32E+05
K SWA-L02-1313-T04-B 1 5.27E+05
K SWA-L02-1313-T05-B 1 5.32E+05
K SWA-L02-1313-T06-B 1 5.74E+05
K SWA-L02-1313-T07-B 1 5.76E+05
K SWA-L02-1313-T08-B 1 3.65E+05
K SWA-L02-1313-T09-B 1 3.69E+05
K SWA-L02-1313-T01-C 1 3.78E+05
K SWA-L02-1313-T02-C 1 4.22E+05
K SWA-L02-1313-T03-C 1 3.20E+05
K SWA-L02-1313-T04-C 1 5.12E+05
K SWA-L02-1313-T05-C 1 5.35E+05
K SWA-L02-1313-T06-C 1 5.18E+05
K SWA-L02-1313-T07-C 1 5.29E+05
K SWA-L02-1313-T08-C 1 4.50E+05
K SWA-L02-1313-T09-C 1 4.19E+05
K SWA-L02-1313-B01-A 1 1.03E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.59E+05 3.0E-01 1.6E+00 5.1E+00
4.10E+05 2.0E-01 1.6E+00 5.1E+00
3.80E+05 2.0E+00 1.6E+00 5.1E+00 1000 125
5.08E+05 1.6E+00 1.6E+00 5.1E+00
5.06E+05 3.9E-01 1.6E+00 5.1E+00
5.67E+05 6.5E-01 1.6E+00 5.1E+00
5.55E+05 3.5E-01 1.6E+00 5.1E+00
4.89E+05 1.8E+01 1.6E+00 5.1E+00
5.29E+05 2.3E+01 1.6E+00 5.1E+00
5.10E+05 2.6E+00 1.6E+00 5.1E+00
3.98E+05 5.1E+00 1.6E+00 5.1E+00
3.32E+05 1.5E+00 1.6E+00 5.1E+00 1000 125
5.27E+05 1.1E+00 1.6E+00 5.1E+00
5.32E+05 3.8E-01 1.6E+00 5.1E+00
5.74E+05 5.8E-01 1.6E+00 5.1E+00
5.76E+05 1.9E+00 1.6E+00 5.1E+00
3.65E+05 8.1E+00 1.6E+00 5.1E+00
3.69E+05 8.8E+00 1.6E+00 5.1E+00
3.78E+05 9.9E-01 1.6E+00 5.1E+00
4.22E+05 6.9E-01 1.6E+00 5.1E+00
3.20E+05 2.4E+00 1.6E+00 5.1E+00 1000 125
5.12E+05 2.0E+00 1.6E+00 5.1E+00
5.35E+05 2.4E+00 1.6E+00 5.1E+00
5.18E+05 1.4E+00 1.6E+00 5.1E+00
5.29E+05 9.5E-01 1.6E+00 5.1E+00
4.50E+05 1.8E+01 1.6E+00 5.1E+00
4.19E+05 1.2E+01 1.6E+00 5.1E+00
1.03E+01 2.7E+01 1.6E+00 5.1E+00
K SWA-L02-1313-B02-A 1 8.00E-01 U1/2 8.00E-01 8.4E+01 1.6E+00 5.1E+00
K SWA-L02-1313-B03-A 1 8.00E-01 U1/2 8.00E-01 1 .8E+02 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
3.82E+05 91% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
3.33E+05 101% VUICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:1 7PM EPA Interlab L02 1313-1316SWA
VUICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
3.21E+05 105% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-400
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
1 ug/L
Se SWA-L02-1313-T01-A 1 1.05E+05
Se SWA-L02-1313-T02-A 1 1.22E+05
Se SWA-L02-1313-T03-A 1 1.13E+05
Se SWA-L02-1313-T04-A 1 1.27E+05
Se SWA-L02-1313-T05-A 1 1.33E+05
Se SWA-L02-1313-T06-A 1 1.52E+05
Se SWA-L02-1313-T07-A 1 1.44E+05
Se SWA-L02-1313-T08-A 1 9.96E+04
Se SWA-L02-1313-T09-A 1 6.34E+04
Se SWA-L02-1313-T01-B 1 1.16E+05
Se SWA-L02-1313-T02-B 1 1.15E+05
Se SWA-L02-1313-T03-B 1 9.60E+04
Se SWA-L02-1313-T04-B 1 1.31E+05
Se SWA-L02-1313-T05-B 1 1.40E+05
Se SWA-L02-1313-T06-B 1 1.54E+05
Se SWA-L02-1313-T07-B 1 1.50E+05
Se SWA-L02-1313-T08-B 1 8.22E+04
Se SWA-L02-1313-T09-B 1 5.88E+04
Se SWA-L02-1313-T01-C 1 1.12E+05
Se SWA-L02-1313-T02-C 1 1.31E+05
Se SWA-L02-1313-T03-C 1 9.27E+04
Se SWA-L02-1313-T04-C 1 1.26E+05
Se SWA-L02-1313-T05-C 1 1.41E+05
Se SWA-L02-1313-T06-C 1 1.40E+05
Se SWA-L02-1313-T07-C 1 1.38E+05
Se SWA-L02-1313-T08-C 1 8.61E+04
Se SWA-L02-1313-T09-C 1 6.13E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.05E+05 8.0E-01 1.5E+01 4.8E+01
1.22E+05 9.5E-02 1.5E+01 4.8E+01
1.13E+05 1.1E+00 1.5E+01 4.8E+01 10 125
1.27E+05 1.6E+00 1.5E+01 4.8E+01
1.33E+05 7.0E-01 1.5E+01 4.8E+01
1.52E+05 2.6E-01 1.5E+01 4.8E+01
1.44E+05 4.6E-01 1.5E+01 4.8E+01
9.96E+04 1.1E+00 1.5E+01 4.8E+01
6.34E+04 3.5E-01 1.5E+01 4.8E+01
1.16E+05 8.8E-01 1.5E+01 4.8E+01
1.15E+05 2.8E+00 1.5E+01 4.8E+01
9.60E+04 2.1E+00 1.5E+01 4.8E+01 10 125
1.31E+05 3.9E-01 1.5E+01 4.8E+01
1.40E+05 4.2E-01 1.5E+01 4.8E+01
1.54E+05 7.8E-01 1.5E+01 4.8E+01
1.50E+05 1.0E+00 1.5E+01 4.8E+01
8.22E+04 9.2E-01 1.5E+01 4.8E+01
5.88E+04 1.7E+00 1.5E+01 4.8E+01
1.12E+05 1.2E+00 1.5E+01 4.8E+01
1.31E+05 5.7E-01 1.5E+01 4.8E+01
9.27E+04 3.2E+00 1.5E+01 4.8E+01 10 125
1.26E+05 3.2E+00 1.5E+01 4.8E+01
1.41E+05 9.5E-01 1.5E+01 4.8E+01
1.40E+05 1.6E+00 1.5E+01 4.8E+01
1.38E+05 1.3E+00 1.5E+01 4.8E+01
8.61 E+04 7.4E-01 1.5E+01 4.8E+01
6.13E+04 7.9E-01 1.5E+01 4.8E+01
Se SWA-L02-1313-B01-A 1 7.50E+00 U1/2 7.50E+00 7.0E+01 1.5E+01 4.8E+01
Se SWA-L02-1313-B02-A 1 7.50E+00 U1/2 7.50E+00 9.7E+01 1.5E+01 4.8E+01
Se SWA-L02-1313-B03-A 1 7.50E+00 U1/2 7.50E+00 3.7E+03 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.14E+05 83% VU ICP-OES 1 1/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
9.70E+04 85% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
9.38E+04 88% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-401
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qu
1 1 ug/L
Si SWA-L02-1313-T01-A 1 4.93E+03
Si SWA-L02-1313-T02-A 1 3.61E+03
Si SWA-L02-1313-T03-A 1 5.56E+03
Si SWA-L02-1313-T04-A 1 1.30E+03
Si SWA-L02-1313-T05-A 1 1.09E+03
Si SWA-L02-1313-T06-A 1 2.41E+03
Si SWA-L02-1313-T07-A 1 3.35E+03
Si SWA-L02-1313-T08-A 1 2.46E+04
Si SWA-L02-1313-T09-A 1 7.00E+03
Si SWA-L02-1313-T01-B 1 5.36E+03
Si SWA-L02-1313-T02-B 1 3.31E+03
Si SWA-L02-1313-T03-B 1 4.64E+03
Si SWA-L02-1313-T04-B 1 1.18E+03
Si SWA-L02-1313-T05-B 1 1.22E+03
Si SWA-L02-1313-T06-B 1 2.27E+03
Si SWA-L02-1313-T07-B 1 3.35E+03
Si SWA-L02-1313-T08-B 1 1.49E+04
Si SWA-L02-1313-T09-B 1 6.60E+03
Si SWA-L02-1313-T01-C 1 5.07E+03
Si SWA-L02-1313-T02-C 1 3.63E+03
Si SWA-L02-1313-T03-C 1 4.51 E+03
Si SWA-L02-1313-T04-C 1 7.74E+02
Si SWA-L02-1313-T05-C 1 1.30E+03
Si SWA-L02-1313-T06-C 1 1.85E+03
Si SWA-L02-1313-T07-C 1 2.92E+03
Si SWA-L02-1313-T08-C 1 1.59E+04
Si SWA-L02-1313-T09-C 1 6.73E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.93E+03 1.1E+00 1.1E+00 3.5E+00
3.61 E+03 6.2E-01 1.1E+00 3.5E+00
5.56E+03 1.9E+00 1.1E+00 3.5E+00 1000 125
1.30E+03 1.4E+00 1.1E+00 3.5E+00
1.09E+03 4.5E-01 1.1E+00 3.5E+00
2.41 E+03 3.2E-01 1.1E+00 3.5E+00
3.35E+03 6.8E-01 1.1E+00 3.5E+00
2.46E+04 1.2E+00 1.1E+00 3.5E+00
7.00E+03 1.7E-01 1.1E+00 3.5E+00
5.36E+03 1.0E+00 1.1E+00 3.5E+00
3.31 E+03 1.1E+01 1.1E+00 3.5E+00
4.64E+03 2.7E+00 1.1E+00 3.5E+00 1000 125
1.18E+03 3.7E-01 1.1E+00 3.5E+00
1.22E+03 3.9E-01 1.1E+00 3.5E+00
2.27E+03 6.7E-01 1.1E+00 3.5E+00
3.35E+03 4.5E-01 1.1E+00 3.5E+00
1.49E+04 8.3E-01 1.1E+00 3.5E+00
6.60E+03 1.4E+00 1.1E+00 3.5E+00
5.07E+03 1.7E+00 1.1E+00 3.5E+00
3.63E+03 1.2E+00 1.1E+00 3.5E+00
4.51E+03 3.4E+00 1.1E+00 3.5E+00 1000 125
7.74E+02 1.1E+00 1.1E+00 3.5E+00
1.30E+03 6.5E-01 1.1E+00 3.5E+00
1.85E+03 1.8E+00 1.1E+00 3.5E+00
2.92E+03 1.4E+00 1.1E+00 3.5E+00
1.59E+04 4.6E-01 1.1E+00 3.5E+00
6.73E+03 5.2E-01 1.1E+00 3.5E+00
Si SWA-L02-1313-B01-A 1 5.50E-01 U1/2 5.50E-01 5.6E+01 1.1E+00 3.5E+00
Si SWA-L02-1313-B02-A 1 5.50E-01 U1/2 5.50E-01 1.1E+02 1.1E+00 3.5E+00
Si SWA-L02-1313-B03-A 1 5.50E-01 U1/2 5.50E-01 7.1E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
6.68E+03 90% VU ICP-OES 1 1/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
6.02E+03 110% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
5.70E+03 96% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-402
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone.
1 1 ug/L
Na SWA-L02-1313-T01-A 1 5.56E+05
Na SWA-L02-1313-T02-A 1 6.23E+05
Na SWA-L02-1313-T03-A 1 5.94E+05
Na SWA-L02-1313-T04-A 1 7.18E+05
Na SWA-L02-1313-T05-A 1 7.05E+05
Na SWA-L02-1313-T06-A 1 7.61 E+05
Na SWA-L02-1313-T07-A 1 7.13E+05
Na SWA-L02-1313-T08-A 1 4.62E+05
Na SWA-L02-1313-T09-A 1 2.86E+05
Na SWA-L02-1313-T01-B 1 5.90E+05
Na SWA-L02-1313-T02-B 1 6.00E+05
Na SWA-L02-1313-T03-B 1 5.30E+05
Na SWA-L02-1313-T04-B 1 7.22E+05
Na SWA-L02-1313-T05-B 1 7.25E+05
Na SWA-L02-1313-T06-B 1 7.62E+05
Na SWA-L02-1313-T07-B 1 7.40E+05
Na SWA-L02-1313-T08-B 1 4.08E+05
Na SWA-L02-1313-T09-B 1 2.86E+05
Na SWA-L02-1313-T01-C 1 5.70E+05
Na SWA-L02-1313-T02-C 1 6.32E+05
Na SWA-L02-1313-T03-C 1 5.12E+05
Na SWA-L02-1313-T04-C 1 7.04E+05
Na SWA-L02-1313-T05-C 1 7.21E+05
Na SWA-L02-1313-T06-C 1 7.04E+05
Na SWA-L02-1313-T07-C 1 6.92E+05
Na SWA-L02-1313-T08-C 1 4.10E+05
Na SWA-L02-1313-T09-C 1 2.84E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.56E+05 7.1E-01 2.5E+00 8.0E+00
6.23E+05 5.3E-01 2.5E+00 8.0E+00
5.94E+05 6.7E-01 2.5E+00 8.0E+00 1000 125
7.18E+05 1.3E+00 2.5E+00 8.0E+00
7.05E+05 2.4E-01 2.5E+00 8.0E+00
7.61 E+05 3.2E-01 2.5E+00 8.0E+00
7.13E+05 7.1E-01 2.5E+00 8.0E+00
4.62E+05 7.3E-01 2.5E+00 8.0E+00
2.86E+05 5.6E-01 2.5E+00 8.0E+00
5.90E+05 1.1E+00 2.5E+00 8.0E+00
6.00E+05 1.8E+00 2.5E+00 8.0E+00
5.30E+05 1.0E+00 2.5E+00 8.0E+00 1000 125
7.22E+05 6.5E-01 2.5E+00 8.0E+00
7.25E+05 1.6E-01 2.5E+00 8.0E+00
7.62E+05 6.5E-01 2.5E+00 8.0E+00
7.40E+05 9.2E-01 2.5E+00 8.0E+00
4.08E+05 1.9E-01 2.5E+00 8.0E+00
2.86E+05 1.0E+00 2.5E+00 8.0E+00
5.70E+05 5.1E-01 2.5E+00 8.0E+00
6.32E+05 4.9E-01 2.5E+00 8.0E+00
5.12E+05 2.0E+00 2.5E+00 8.0E+00 1000 125
7.04E+05 2.0E+00 2.5E+00 8.0E+00
7.21 E+05 5.1E-01 2.5E+00 8.0E+00
7.04E+05 1.9E+00 2.5E+00 8.0E+00
6.92E+05 1.1E+00 2.5E+00 8.0E+00
4.10E+05 7.8E-01 2.5E+00 8.0E+00
2.84E+05 1.5E-01 2.5E+00 8.0E+00
Na SWA-L02-1313-B01-A 1 1.25E+OOU1/2 1.25E+00 5.1E+00 2.5E+00 8.0E+00
Na SWA-L02-1313-B02-A 1 1.25E+OOU1/2 1.25E+00 3.8E+00 2.5E+00 8.0E+00
Na SWA-L02-1313-B03-A 1 1.25E+OOU1/2 1.25E+00 5.3E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
5.95E+05 88% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
5.31E+05 83% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:1 7PM EPA Interlab L02 1313-1316SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
5.13E+05 85% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-403
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-L02-1313-T01-A 1
SWA-L02-1313-T02-A 1
SWA-L02-1313-T03-A 1
SWA-L02-1313-T04-A 1
SWA-L02-1313-T05-A 1
SWA-L02-1313-T06-A 1
SWA-L02-1313-T07-A 1
SWA-L02-1313-T08-A 1
SWA-L02-1313-T09-A 1
SWA-L02-1313-T01-B 1
SWA-L02-1313-T02-B 1
SWA-L02-1313-T03-B 1
SWA-L02-1313-T04-B 1
SWA-L02-1313-T05-B 1
SWA-L02-1313-T06-B 1
SWA-L02-1313-T07-B 1
SWA-L02-1313-T08-B 1
SWA-L02-1313-T09-B 1
SWA-L02-1313-T01-C 1
SWA-L02-1313-T02-C 1
SWA-L02-1313-T03-C 1
SWA-L02-1313-T04-C 1
SWA-L02-1313-T05-C 1
SWA-L02-1313-T06-C 1
SWA-L02-1313-T07-C 1
SWA-L02-1313-T08-C 1
SWA-L02-1313-T09-C 1
SWA-L02-1313-B01-A 1
SWA-L02-1313-B02-A 1
SWA-L02-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
3.68E+02
1.38E+03
6.25E+02
3.03E+04
4.00E+04
5.39E+04
6.23E+04
4.98E+04
4.03E+04
4.09E+02
1.19E+03
5.53E+02
3.15E+04
4.25E+04
5.46E+04
6.40E+04
4.15E+04
3.74E+04
4.14E+02
1.32E+03
5.16E+02
3.19E+04
4.31 E+04
4.87E+04
5.85E+04
4.28E+04
3.89E+04
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.68E+02 1.0E+00 1.0E+00 3.2E+00
1.38E+03 6.5E-01 1.0E+00 3.2E+00
6.25E+02 1.3E+00 1.0E+00 3.2E+00 1000 125
3.03E+04 6.4E-01 1.0E+00 3.2E+00
4.00E+04 1.2E+00 1.0E+00 3.2E+00
5.39E+04 5.6E-01 1.0E+00 3.2E+00
6.23E+04 9.7E-01 1.0E+00 3.2E+00
4.98E+04 1.2E+00 1.0E+00 3.2E+00
4.03E+04 2.0E-01 1.0E+00 3.2E+00
4.09E+02 1.4E+00 1.0E+00 3.2E+00
1.19E+03 1.0E+01 1.0E+00 3.2E+00
5.53E+02 2.6E+00 1.0E+00 3.2E+00 1000 125
3.15E+04 8.7E-01 1.0E+00 3.2E+00
4.25E+04 6.5E-01 1.0E+00 3.2E+00
5.46E+04 9.4E-01 1.0E+00 3.2E+00
6.40E+04 1.1E+00 1.0E+00 3.2E+00
4.15E+04 9.5E-02 1.0E+00 3.2E+00
3.74E+04 1.4E+00 1.0E+00 3.2E+00
4.14E+02 1.5E+00 1.0E+00 3.2E+00
1.32E+03 3.9E-01 1.0E+00 3.2E+00
5.16E+02 3.8E+00 1.0E+00 3.2E+00 1000 125
3.19E+04 5.1E+00 1.0E+00 3.2E+00
4.31 E+04 6.4E-01 1.0E+00 3.2E+00
4.87E+04 3.6E+00 1.0E+00 3.2E+00
5.85E+04 1.9E+00 1.0E+00 3.2E+00
4.28E+04 6.8E-01 1.0E+00 3.2E+00
3.89E+04 1.1E+00 1.0E+00 3.2E+00
5.00E-01 1.8E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.88E+03 101% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.84E+03 103% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:1 7PM EPA Interlab L02 1313-1316SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.83E+03 105% VUICP-OES 1 1/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :43 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :45 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :46 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :48 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4 :50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-404
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
S SWA-L02-1313-T01-A 1 6.08E+05
S SWA-L02-1313-T02-A 1 7.31 E+05
S SWA-L02-1313-T03-A 1 6.19E+05
S SWA-L02-1313-T04-A 1 5.28E+05
S SWA-L02-1313-T05-A 1 4.58E+05
S SWA-L02-1313-T06-A 1 5.17E+05
S SWA-L02-1313-T07-A 1 5.17E+05
S SWA-L02-1313-T08-A 1 3.72E+05
S SWA-L02-1313-T09-A 1 2.73E+05
S SWA-L02-1313-T01-B 1 7.28E+05
S SWA-L02-1313-T02-B 1 6.38E+05
S SWA-L02-1313-T03-B 1 4.63E+05
S SWA-L02-1313-T04-B 1 5.64E+05
S SWA-L02-1313-T05-B 1 4.72E+05
S SWA-L02-1313-T06-B 1 5.16E+05
S SWA-L02-1313-T07-B 1 5.42E+05
S SWA-L02-1313-T08-B 1 3.17E+05
S SWA-L02-1313-T09-B 1 2.58E+05
S SWA-L02-1313-T01-C 1 6.83E+05
S SWA-L02-1313-T02-C 1 7.05E+05
S SWA-L02-1313-T03-C 1 4.26E+05
S SWA-L02-1313-T04-C 1 5.52E+05
S SWA-L02-1313-T05-C 1 4.60E+05
S SWA-L02-1313-T06-C 1 4.68E+05
S SWA-L02-1313-T07-C 1 4.94E+05
S SWA-L02-1313-T08-C 1 3.30E+05
S SWA-L02-1313-T09-C 1 2.67E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.08E+05 8.6E-01 6.8E+00 2.2E+01
7.31 E+05 7.7E-01 6.8E+00 2.2E+01
6.19E+05 1.2E+00 6.8E+00 2.2E+01 1000 125
5.28E+05 1.5E+00 6.8E+00 2.2E+01
4.58E+05 6.7E-01 6.8E+00 2.2E+01
5.17E+05 9.3E-02 6.8E+00 2.2E+01
5.17E+05 2.9E-01 6.8E+00 2.2E+01
3.72E+05 8.8E-01 6.8E+00 2.2E+01
2.73E+05 2.3E-01 6.8E+00 2.2E+01
7.28E+05 1.3E+00 6.8E+00 2.2E+01
6.38E+05 3.9E+00 6.8E+00 2.2E+01
4.63E+05 4.3E+00 6.8E+00 2.2E+01 1000 125
5.64E+05 7.2E-01 6.8E+00 2.2E+01
4.72E+05 3.1E-01 6.8E+00 2.2E+01
5.16E+05 9.0E-01 6.8E+00 2.2E+01
5.42E+05 8.9E-01 6.8E+00 2.2E+01
3.17E+05 6.2E-01 6.8E+00 2.2E+01
2.58E+05 1.4E+00 6.8E+00 2.2E+01
6.83E+05 1.2E+00 6.8E+00 2.2E+01
7.05E+05 8.6E-01 6.8E+00 2.2E+01
4.26E+05 5.1E+00 6.8E+00 2.2E+01 1000 125
5.52E+05 3.4E+00 6.8E+00 2.2E+01
4.60E+05 6.6E-01 6.8E+00 2.2E+01
4.68E+05 1.8E+00 6.8E+00 2.2E+01
4.94E+05 1.1E+00 6.8E+00 2.2E+01
3.30E+05 4.9E-01 6.8E+00 2.2E+01
2.67E+05 5.9E-01 6.8E+00 2.2E+01
S SWA-L02-1313-B01-A 1 3.40E+00 U1/2 3.40E+00 2.6E+00 6.8E+00 2.2E+01
S SWA-L02-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 6.5E+00 6.8E+00 2.2E+01
S SWA-L02-1313-B03-A 1 3.40E+00 U1/2 3.40E+00 6.1E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
6.20E+05 87% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
4.65E+05 87% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:1 7PM EPA Interlab L02 1313-1316SWA
VUICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
4.27E+05 82% VUICP-OES 1 1/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-405
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L02-1313-T01-A 1 2.30E+00 U1/2 2.30E+00 3.0E+02 4.6E+00 1.5E+01
Tl SWA-L02-1313-T02-A 1 2.30E+00 U1/2 2.30E+00 6.8E+01 4.6E+00 1.5E+01
Tl SWA-L02-1313-T03-A 1 2.30E+00 U1/2 2.30E+00 3.1E+02 4.6E+00 1.5E+01 10 125
Tl SWA-L02-1313-T04-A 1 2.30E+00 U1/2 2.30E+00 1 .5E+03 4.6E+00 1.5E+01
Tl SWA-L02-1313-T05-A 1 4.77E+00 E
Tl SWA-L02-1313-T06-A 1 2.61E+01
Tl SWA-L02-1313-T07-A 1 2.93E+01
Tl SWA-L02-1313-T08-A 1 3.19E+01
Tl SWA-L02-1313-T09-A 1 3.65E+01
4.77E+00 2.3E+02 4.6E+00 1 .5E+01
2.61 E+01 3.6E+01 4.6E+00 1 .5E+01
2.93E+01 3.6E+01 4.6E+00 1 .5E+01
3.19E+01 2.2E+01 4.6E+00 1 .5E+01
3.65E+01 3.0E+01 4.6E+00 1 .5E+01
Tl SWA-L02-1313-T01-B 1 2.30E+00 U1/2 2.30E+00 2.8E+02 4.6E+00 1 .5E+01
Tl SWA-L02-1313-T02-B 1 2.30E+00 U1/2 2.30E+00 4.6E+01 4.6E+00 1 .5E+01
Tl SWA-L02-1313-T03-B 1 2.30E+00 U1/2 2.30E+00 1 .6E+03 4.6E+00 1 .5E+01 10 125
Tl SWA-L02-1313-T04-B 1 1.53E+01
Tl SWA-L02-1313-T05-B 1 1.40E+01 E
Tl SWA-L02-1313-T06-B 1 2.83E+01
Tl SWA-L02-1313-T07-B 1 3.37E+01
Tl SWA-L02-1313-T08-B 1 2.19E+01
Tl SWA-L02-1313-T09-B 1 4.65E+01
1.53E+01 4.7E+01 4.6E+00 1 .5E+01
1.40E+01 9.5E+01 4.6E+00 1 .5E+01
2.83E+01 3.6E+01 4.6E+00 1 .5E+01
3.37E+01 3.6E+01 4.6E+00 1 .5E+01
2.19E+01 9.3E+00 4.6E+00 1 .5E+01
4.65E+01 9.9E+00 4.6E+00 1 .5E+01
Tl SWA-L02-1313-T01-C 1 2.30E+00 U1/2 2.30E+00 7.3E+01 4.6E+00 1 .5E+01
Tl SWA-L02-1313-T02-C 1 2.30E+00 U1/2 2.30E+00 1 .3E+04 4.6E+00 1 .5E+01
Tl SWA-L02-1313-T03-C 1 2.30E+00 U1/2 2.30E+00 1 JE+02 4.6E+00 1 .5E+01 10 125
Tl SWA-L02-1313-T04-C 1 6.29E+00 E
6.29E+00 1.1E+02 4.6E+00 1 .5E+01
Tl SWA-L02-1313-T05-C 1 -4.79E+00 U1/2 -4.79E+00 2.1E+02 4.6E+00 1 .5E+01
Tl SWA-L02-1313-T06-C 1 1.52E+01
Tl SWA-L02-1313-T07-C 1 3.33E+01
Tl SWA-L02-1313-T08-C 1 2.53E+01
Tl SWA-L02-1313-T09-C 1 3.95E+01
1.52E+01 1.3E+01 4.6E+00 1.5E+01
3.33E+01 7.8E+00 4.6E+00 1.5E+01
2.53E+01 9.2E+00 4.6E+00 1.5E+01
3.95E+01 2.3E+01 4.6E+00 1.5E+01
Tl SWA-L02-1313-B01-A 1 2.30E+00 U1/2 2.30E+00 8.1E+01 4.6E+00 1 .5E+01
Tl SWA-L02-1313-B02-A 1 2.30E+00 U1/2 2.30E+00 5.9E+01 4.6E+00 1 .5E+01
Tl SWA-L02-1313-B03-A 1 2.30E+00 U1/2 2.30E+00 1.7E+02 4.6E+00 1 .5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.08E+03 86% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.11E+03 88% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1 .08E+03 86% VU ICP-OES 1 1/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4 :45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3 :42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3 :44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3 :45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-406
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L02-1313-T01-A 1 1.00E+OOU1/2 1.00E+00 3.2E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T02-A 1 1.00E+OOU1/2 1.00E+00 6.3E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T03-A 1 1.00E+OOU1/2 1.00E+00 5.5E+01 2.0E+00 6.4E+00 10 125
Ti SWA-L02-1313-T04-A 1 1.00E+OOU1/2 1.00E+00 9.3E+01 2.0E+00 6.4E+00
Ti SWA-L02-1313-T05-A 1 1.00E+OOU1/2 1.00E+00 5.7E+01 2.0E+00 6.4E+00
Ti SWA-L02-1313-T06-A 1 1.00E+OOU1/2 1.00E+00 1 .2E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T07-A 1 1.00E+OOU1/2 1.00E+00 2.0E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T08-A 1 1.21E+02
Ti SWA-L02-1313-T09-A 1 1.92E+02
1.21E+02 3.1E+00 2.0E+00 6.4E+00
1.92E+02 5.4E-01 2.0E+00 6.4E+00
Ti SWA-L02-1313-T01-B 1 1.00E+OOU1/2 1.00E+00 1 JE+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T02-B 1 1.00E+OOU1/2 1.00E+00 4.1E+01 2.0E+00 6.4E+00
Ti SWA-L02-1313-T03-B 1 1.00E+OOU1/2 1.00E+00 8.1E+01 2.0E+00 6.4E+00 10 125
Ti SWA-L02-1313-T04-B 1 1.00E+OOU1/2 1.00E+00 6.7E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T05-B 1 1.00E+OOU1/2 1.00E+00 1.1E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T06-B 1 1.00E+OOU1/2 1.00E+00 1 .5E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T07-B 1 1.00E+OOU1/2 1.00E+00 2.3E+03 2.0E+00 6.4E+00
Ti SWA-L02-1313-T08-B 1 4.27E+01
Ti SWA-L02-1313-T09-B 1 1.73E+02
Ti SWA-L02-1313-T01-C 1 3.98E+00 E
4.27E+01 3.7E+00 2.0E+00 6.4E+00
1.73E+02 1.1E+00 2.0E+00 6.4E+00
3.98E+00 3.0E+00 2.0E+00 6.4E+00
Ti SWA-L02-1313-T02-C 1 1.00E+OOU1/2 1.00E+00 8.1E+01 2.0E+00 6.4E+00
Ti SWA-L02-1313-T03-C 1 1.00E+OOU1/2 1.00E+00 1.1E+02 2.0E+00 6.4E+00 10 125
Ti SWA-L02-1313-T04-C 1 1.00E+OOU1/2 1.00E+00 1.1E+03 2.0E+00 6.4E+00
Ti SWA-L02-1313-T05-C 1 1.00E+OOU1/2 1.00E+00 1 .3E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T06-C 1 1.00E+OOU1/2 1.00E+00 2.9E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T07-C 1 1.00E+OOU1/2 1.00E+00 2.8E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-T08-C 1 4.58E+01
Ti SWA-L02-1313-T09-C 1 1.82E+02
4.58E+01 1.6E+00 2.0E+00 6.4E+00
1.82E+02 1.1E+00 2.0E+00 6.4E+00
Ti SWA-L02-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 1 .7E+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-B02-A 1 1.00E+OOU1/2 1.00E+00 1 .OE+02 2.0E+00 6.4E+00
Ti SWA-L02-1313-B03-A 1 1.00E+OOU1/2 1.00E+00 3.4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.24E+03 99% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.28E+03 103% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:1 7PM EPA Interlab L02 1313-1316SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.24E+03 99% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-407
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
V SWA-L02-1313-T01-A 1 3.51 E+02
V SWA-L02-1313-T02-A 1 2.06E+02
V SWA-L02-1313-T03-A 1 3.63E+02
V SWA-L02-1313-T04-A 1 2.65E+02
V SWA-L02-1313-T05-A 1 2.39E+02
V SWA-L02-1313-T06-A 1 2.63E+02
V SWA-L02-1313-T07-A 1 2.45E+02
V SWA-L02-1313-T08-A 1 2.00E+02
V SWA-L02-1313-T09-A 1 5.13E+02
V SWA-L02-1313-T01-B 1 3.84E+02
V SWA-L02-1313-T02-B 1 2.06E+02
V SWA-L02-1313-T03-B 1 3.04E+02
V SWA-L02-1313-T04-B 1 2.71E+02
V SWA-L02-1313-T05-B 1 2.40E+02
V SWA-L02-1313-T06-B 1 2.65E+02
V SWA-L02-1313-T07-B 1 2.52E+02
V SWA-L02-1313-T08-B 1 1.62E+02
V SWA-L02-1313-T09-B 1 4.68E+02
V SWA-L02-1313-T01-C 1 3.61 E+02
V SWA-L02-1313-T02-C 1 2.17E+02
V SWA-L02-1313-T03-C 1 2.95E+02
V SWA-L02-1313-T04-C 1 2.51E+02
V SWA-L02-1313-T05-C 1 2.35E+02
V SWA-L02-1313-T06-C 1 2.45E+02
V SWA-L02-1313-T07-C 1 2.38E+02
V SWA-L02-1313-T08-C 1 1.68E+02
V SWA-L02-1313-T09-C 1 4.92E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.51 E+02 1.1E+00 1.5E+00 4.8E+00
2.06E+02 2.5E-01 1.5E+00 4.8E+00
3.63E+02 1.6E+00 1.5E+00 4.8E+00 10 125
2.65E+02 1.7E-01 1.5E+00 4.8E+00
2.39E+02 1.8E+00 1.5E+00 4.8E+00
2.63E+02 9.2E-01 1.5E+00 4.8E+00
2.45E+02 2.2E+00 1.5E+00 4.8E+00
2.00E+02 2.7E+00 1.5E+00 4.8E+00
5.13E+02 9.3E-01 1.5E+00 4.8E+00
3.84E+02 1.7E-01 1.5E+00 4.8E+00
2.06E+02 2.6E+00 1.5E+00 4.8E+00
3.04E+02 3.3E+00 1.5E+00 4.8E+00 10 125
2.71 E+02 1.7E+00 1.5E+00 4.8E+00
2.40E+02 3.4E+00 1.5E+00 4.8E+00
2.65E+02 1.9E+00 1.5E+00 4.8E+00
2.52E+02 1.2E+00 1.5E+00 4.8E+00
1.62E+02 2.7E+00 1.5E+00 4.8E+00
4.68E+02 1.1E+00 1.5E+00 4.8E+00
3.61E+02 2.7E+00 1.5E+00 4.8E+00
2.17E+02 5.9E-01 1.5E+00 4.8E+00
2.95E+02 4.2E+00 1.5E+00 4.8E+00 10 125
2.51 E+02 3.7E+00 1.5E+00 4.8E+00
2.35E+02 1.1E+00 1.5E+00 4.8E+00
2.45E+02 2.7E+00 1.5E+00 4.8E+00
2.38E+02 5.5E-01 1.5E+00 4.8E+00
1.68E+02 1.6E+00 1.5E+00 4.8E+00
4.92E+02 1.5E+00 1.5E+00 4.8E+00
V SWA-L02-1313-B01-A 1 7.50E-01 U1/2 7.50E-01 1.1E+02 1.5E+00 4.8E+00
V SWA-L02-1313-B02-A 1 7.50E-01 U1/2 7.50E-01 9.9E+00 1.5E+00 4.8E+00
V SWA-L02-1313-B03-A 1 7.50E-01 U1/2 7.50E-01 2.7E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.66E+03 103% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.72E+03 113% VUICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:1 7PM EPA Interlab L02 1313-1316SWA
VUICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.64E+03 108% VU ICP-OES 11/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:42 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:44 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 3:45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-408
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone.
1 1 ug/L
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Zn SWA-L02-1313-T01-A 1 1.01E+OOE 1.01E+00 4.2E+01 1.0E+00 3.2E+00
Zn SWA-L02-1313-T02-A 1 6.80E+00
Zn SWA-L02-1313-T03-A 1 1.47E+02
Zn SWA-L02-1313-T04-A 1 2.06E+02
Zn SWA-L02-1313-T05-A 1 1.77E+01
Zn SWA-L02-1313-T06-A 1 1.01E+02
Zn SWA-L02-1313-T07-A 1 6.99E+02
Zn SWA-L02-1313-T08-A 1 2.95E+03
Zn SWA-L02-1313-T09-A 1 3.35E+03
Zn SWA-L02-1313-T01-B 1 4.76E+00
6.80E+00 4.8E+00 1.0E+00 3.2E+00
1.47E+02 1.8E+00 1.0E+00 3.2E+00 10 125
2.06E+02 1.8E+00 1.0E+00 3.2E+00
1.77E+01 2.6E+00 1.0E+00 3.2E+00
1.01E+02 8.0E-01 1.0E+00 3.2E+00
6.99E+02 7.7E-01 1.0E+00 3.2E+00
2.95E+03 1.1E+00 1.0E+00 3.2E+00
3.35E+03 6.7E-01 1.0E+00 3.2E+00
4.76E+00 8.0E+00 1.0E+00 3.2E+00
Zn SWA-L02-1313-T02-B 1 5.00E-01 U1/2 5.00E-01 6.5E+01 1.0E+00 3.2E+00
Zn SWA-L02-1313-T03-B 1 1.17E+02
Zn SWA-L02-1313-T04-B 1 7.68E+01
Zn SWA-L02-1313-T05-B 1 8.64E+00
Zn SWA-L02-1313-T06-B 1 7.81 E+01
Zn SWA-L02-1313-T07-B 1 6.49E+02
Zn SWA-L02-1313-T08-B 1 1.76E+03
Zn SWA-L02-1313-T09-B 1 2.98E+03
Zn SWA-L02-1313-T01-C 1 5.98E+00
1.17E+02 1.5E+00 1.0E+00 3.2E+00 10 125
7.68E+01 2.4E+00 1.0E+00 3.2E+00
8.64E+00 8.6E+00 1.0E+00 3.2E+00
7.81 E+01 1.5E+00 1.0E+00 3.2E+00
6.49E+02 2.7E-01 1.0E+00 3.2E+00
1.76E+03 1.0E+00 1.0E+00 3.2E+00
2.98E+03 7.3E-01 1.0E+00 3.2E+00
5.98E+00 9.7E+00 1.0E+00 3.2E+00
Zn SWA-L02-1313-T02-C 1 1.04E+OOE 1.04E+00 3.5E+01 1.0E+00 3.2E+00
Zn SWA-L02-1313-T03-C 1 1.19E+02
Zn SWA-L02-1313-T04-C 1 3.86E+00
Zn SWA-L02-1313-T05-C 1 3.30E+00
Zn SWA-L02-1313-T06-C 1 4.00E+01
Zn SWA-L02-1313-T07-C 1 5.27E+02
Zn SWA-L02-1313-T08-C 1 1.85E+03
Zn SWA-L02-1313-T09-C 1 3.17E+03
1.19E+02 3.3E+00 1.0E+00 3.2E+00 10 125
3.86E+00 6.8E+00 1.0E+00 3.2E+00
3.30E+00 2.6E+01 1.0E+00 3.2E+00
4.00E+01 3.5E+00 1.0E+00 3.2E+00
5.27E+02 1.3E+00 1.0E+00 3.2E+00
1.85E+03 7.7E-01 1.0E+00 3.2E+00
3.17E+03 1.4E+00 1.0E+00 3.2E+00
Zn SWA-L02-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 1.3E+02 1.0E+00 3.2E+00
Zn SWA-L02-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 1.6E+02 1.0E+00 3.2E+00
Zn SWA-L02-1313-B03-A 1 5.00E-01 U1/2 5.00E-01 5.4E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 3:47 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:49 PM EPA Interlab L02 1313-1316 SWA
1.49E+03 107% VU ICP-OES 11/29/10 3:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:52 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:54 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:55 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:57 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3:59 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:00 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:12 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:13 PM EPA Interlab L02 1313-1316 SWA
1.52E+03 113% VU ICP-OES 11/29/10 4:15 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:17 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:18 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:20 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:22 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:23 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:25 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:37 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 4:38 PM EPA Interlab L02 1313-1316 SWA
1.48E+03 109% VU ICP-OES 1 1/29/10 4:40 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:43 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:45 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:46 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:48 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 4:50 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/104:51 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3 :42 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3 :44 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 3 :45 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                          1-409
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample
SWA-L04-1313-T01-A
SWA-L04-1313-T02-A
SWA-L04-1313-T03-A
SWA-L04-1313-T04-A
SWA-L04-1313-T05-A
SWA-L04-1313-T06-A
SWA-L04-1313-T07-A
SWA-L04-1313-T08-A
SWA-L04-1313-T09-A
SWA-L04-1313-T10-A
SWA-L04-1313-T01-B
SWA-L04-1313-T02-B
SWA-L04-1313-T03-B
SWA-L04-1313-T04-B
SWA-L04-1313-T05-B
SWA-L04-1313-T06-B
SWA-L04-1313-T07-B
SWA-L04-1313-T08-B
SWA-L04-1313-T09-B
SWA-L04-1313-T10-B
SWA-L04-1313-T01-C
SWA-L04-1313-T02-C
SWA-L04-1313-T03-C
SWA-L04-1313-T04-C
SWA-L04-1313-T05-C
SWA-L04-1313-T06-C
SWA-L04-1313-T07-C
SWA-L04-1313-T08-C
SWA-L04-1313-T09-C
SWA-L04-1313-T10-C
SWA-L04-1313-B01-A
SWA-L04-1313-B02-A
SWA-L04-1313-B03-A
SWA-L04-1313-B01-B
SWA-L04-1313-B02-B
SWA-L04-1313-B03-B
SWA-L04-1313-B01-C
SWA-L04-1313-B02-C
SWA-L04-1313-B03-C
Sample
Dilution Cone.
I I ug/L
1 6.23E+04
1 1.51E+04
1 1.77E+02
1 4.55E+01
1 5.00E-01
1 5.00E-01
1 8.72E+00
1 3.29E+05

1 3.55E+04
1 5.82E+04
1 1.53E+04
1 1.42E+02
1 3.13E+01
1 5.00E-01
1 5.00E-01
1 1.89E+01
1 3.01 E+05
1 1.28E+06
1 3.72E+04
1 5.92E+04
1 1.74E+04
1 2.98E+02
1 5.10E+01
1 5.00E-01
1 5.00E-01
1 5.00E-01
1 1.45E+05

1 3.80E+04
1 5.00E-01
1 5.00E-01
1 5.00E-01
1 5.00E-01
1 5.00E-01
1 5.00E-01
1 5.00E-01
1 5.00E-01
1 5.00E-01
Internal
Qualifier Review




U1/2
U1/2








U1/2
U1/2








U1/2
U1/2
U1/2



U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
ICP-OES
Cone. RSD
ug/L %
6.23E+04 2.0E-01
1.51E+04 4.8E-01
1.77E+02 3.9E+00
4.55E+01 2.7E+01
5.00E-01 1.8E+03
5.00E-01 4.6E+02
8.72E+00 4.7E-01
3.29E+05 1.3E+00

3.55E+04 8.3E-01
5.82E+04 1.4E+00
1.53E+04 6.0E-01
1.42E+02 6.2E+00
3.13E+01 2.5E+01
5.00E-01 2.7E+01
5.00E-01 1.2E+02
1.89E+01 5.2E+01
3.01 E+05 4.6E-01
1.28E+06 5.5E-01
3.72E+04 5.9E-01
5.92E+04 7.1E-01
1.74E+04 6.9E-01
2.98E+02 3.3E+00
5.10E+01 1.1E+01
5.00E-01 1.5E+02
5.00E-01 5.2E+02
5.00E-01 5.7E+02
1.45E+05 1.1E+00

3.80E+04 1.3E+00
5.00E-01 1.3E+01
5.00E-01 3.2E+01
5.00E-01 3.1E+01
5.00E-01 1.3E+01
5.00E-01 3.5E+01
5.00E-01 2.0E+01
5.00E-01 3.8E+00
5.00E-01 9.9E+01
5.00E-01 1.3E+01
MDL
ug/L
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00

1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00

1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00

3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00

3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
vu
1.59E+04 89% VU
VU
VU
VU
VU
VU
VU

VU
VU
1.62E+04 90% VU
VU
VU
VU
VU
VU
VU
VU
VU
VU
1.84E+04 92% VU
VU
VU
VU
VU
VU
VU

VU
VU
VU
VU
VU
VU
VU
VU
VU
VU
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES

ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES

ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
Date/Time
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11

3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11

3/21/11

1:21 PM
1:23 PM
1:25 PM
1:26 PM
1:28 PM
1:30 PM
1:31 PM
1:33 PM

3:04 PM
2:03 PM
2:05 PM
2:06 PM
2:08 PM
2:10 PM
2:11 PM
2:13 PM
2:15 PM
2:16 PM
3:06 PM
2:18 PM
2:19 PM
2:21 PM
2:23 PM
2:24 PM
2:26 PM
2:28 PM
2:29 PM

3:07 PM
3/21/11 12:58 PM
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
3/21/11
1:00 PM
1:02 PM
1:11 PM
1:13PM
1:15PM
1:16PM
1:18PM
1:20 PM
Filename
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA

EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA

EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                                     1-410
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb SWA-L04-1313-T01-A
Sb SWA-L04-1313-T02-A
Sb SWA-L04-1313-T03-A
Sb SWA-L04-1313-T04-A
Sb SWA-L04-1313-T05-A
Sb SWA-L04-1313-T06-A
Sb SWA-L04-1313-T07-A
Sb SWA-L04-1313-T08-A
Sb SWA-L04-1313-T09-A
Sb SWA-L04-1313-T10-A
Sb SWA-L04-1313-T01-B
Sb SWA-L04-1313-T02-B
Sb SWA-L04-1313-T03-B
Sb SWA-L04-1313-T04-B
Sb SWA-L04-1313-T05-B
Sb SWA-L04-1313-T06-B
Sb SWA-L04-1313-T07-B
Sb SWA-L04-1313-T08-B
Sb SWA-L04-1313-T09-B
Sb SWA-L04-1313-T10-B
Sb SWA-L04-1313-T01-C
Sb SWA-L04-1313-T02-C
Sb SWA-L04-1313-T03-C
Sb SWA-L04-1313-T04-C
Sb SWA-L04-1313-T05-C
Sb SWA-L04-1313-T06-C
Sb SWA-L04-1313-T07-C
Sb SWA-L04-1313-T08-C
Sb SWA-L04-1313-T09-C
Sb SWA-L04-1313-T10-C
Sb SWA-L04-1313-B01-A
Sb SWA-L04-1313-B02-A
Sb SWA-L04-1313-B03-A
Sb SWA-L04-1313-B01-B
Sb SWA-L04-1313-B02-B
Sb SWA-L04-1313-B03-B
Sb SWA-L04-1313-B01-C
Sb SWA-L04-1313-B02-C
Sb SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.21 E+03
1 2.33E+03
1 1.30E+03
1 1.36E+03
1 1.20E+03
1 1.15E+03
1 9.77E+02
1 3.03E+02

1 4.28E+03
1 5.79E+03
1 2.33E+03
1 1.31 E+03
1 1.21 E+03
1 1.37E+03
1 1.25E+03
1 1.15E+03
1 4.33E+02
1 1.14E+03
1 4.27E+03
1 5.94E+03
1 2.32E+03
1 1.31 E+03
1 1.32E+03
1 1.19E+03
1 1.20E+03
1 1.01 E+03
1 5.49E+02

1 4.09E+03
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 1.15E+01 E
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 8.89E+00 E
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 8.72E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.21 E+03 2.0E+00 7.5E+00 2.4E+01
2.33E+03 4.4E-01 7.5E+00 2.4E+01 10 100
1.30E+03 1.8E+00 7.5E+00 2.4E+01
1.36E+03 1.0E+00 7.5E+00 2.4E+01
1.20E+03 9.7E-01 7.5E+00 2.4E+01
1.15E+03 2.0E+00 7.5E+00 2.4E+01
9.77E+02 8.5E+00 7.5E+00 2.4E+01
3.03E+02 4.9E+00 7.5E+00 2.4E+01

4.28E+03 7.4E-01 7.5E+00 2.4E+01
5.79E+03 1.2E+00 7.5E+00 2.4E+01
2.33E+03 3.4E-01 7.5E+00 2.4E+01 10 100
1.31 E+03 6.5E-01 7.5E+00 2.4E+01
1.21 E+03 2.0E+00 7.5E+00 2.4E+01
1.37E+03 1.3E+00 7.5E+00 2.4E+01
1.25E+03 8.6E-02 7.5E+00 2.4E+01
1.15E+03 2.4E+00 7.5E+00 2.4E+01
4.33E+02 6.4E+00 7.5E+00 2.4E+01
1.14E+03 9.1E+00 7.5E+00 2.4E+01
4.27E+03 8.5E-02 7.5E+00 2.4E+01
5.94E+03 3.3E-01 7.5E+00 2.4E+01
2.32E+03 5.2E-01 7.5E+00 2.4E+01 10 100
1.31 E+03 7.2E-01 7.5E+00 2.4E+01
1.32E+03 8.3E-01 7.5E+00 2.4E+01
1.19E+03 5.1E-01 7.5E+00 2.4E+01
1.20E+03 4.7E-01 7.5E+00 2.4E+01
1.01 E+03 3.0E+00 7.5E+00 2.4E+01
5.49E+02 8.5E+00 7.5E+00 2.4E+01

4.09E+03 6.9E-01 7.5E+00 2.4E+01
3.75E+00 4.3E+01 7.5E+00 2.4E+01
3.75E+00 7.2E+01 7.5E+00 2.4E+01
1.15E+01 1.3E+01 7.5E+00 2.4E+01
3.75E+00 4.9E+01 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
8.89E+00 1.4E+01 7.5E+00 2.4E+01
3.75E+00 7.5E+01 7.5E+00 2.4E+01
3.75E+00 6.0E+01 7.5E+00 2.4E+01
8.72E+00 8.1E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.25E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
3.28E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.31 E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-411
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As SWA-L04-1313-T01-A
As SWA-L04-1313-T02-A
As SWA-L04-1313-T03-A
As SWA-L04-1313-T04-A
As SWA-L04-1313-T05-A
As SWA-L04-1313-T06-A
As SWA-L04-1313-T07-A
As SWA-L04-1313-T08-A
As SWA-L04-1313-T09-A
As SWA-L04-1313-T10-A
As SWA-L04-1313-T01-B
As SWA-L04-1313-T02-B
As SWA-L04-1313-T03-B
As SWA-L04-1313-T04-B
As SWA-L04-1313-T05-B
As SWA-L04-1313-T06-B
As SWA-L04-1313-T07-B
As SWA-L04-1313-T08-B
As SWA-L04-1313-T09-B
As SWA-L04-1313-T10-B
As SWA-L04-1313-T01-C
As SWA-L04-1313-T02-C
As SWA-L04-1313-T03-C
As SWA-L04-1313-T04-C
As SWA-L04-1313-T05-C
As SWA-L04-1313-T06-C
As SWA-L04-1313-T07-C
As SWA-L04-1313-T08-C
As SWA-L04-1313-T09-C
As SWA-L04-1313-T10-C
As SWA-L04-1313-B01-A
As SWA-L04-1313-B02-A
As SWA-L04-1313-B03-A
As SWA-L04-1313-B01-B
As SWA-L04-1313-B02-B
As SWA-L04-1313-B03-B
As SWA-L04-1313-B01-C
As SWA-L04-1313-B02-C
As SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.09E+04
1 1.17E+03
1 1.24E+02
1 4.78E+02
1 1.83E+02
1 2.23E+02
1 1.05E+03
1 2.08E+03

1 4.28E+03
1 9.30E+03
1 1.27E+03
1 9.99E+01
1 2.75E+02
1 1.81E+02
1 1.79E+02
1 3.12E+02
1 2.07E+03
1 1.35E+04
1 5.28E+03
1 9.34E+03
1 2.01 E+03
1 1.31E+02
1 3.57E+02
1 2.06E+02
1 2.15E+02
1 2.87E+02
1 2.32E+03

1 5.29E+03
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.09E+04 7.8E-01 1.1E+01 3.5E+01
1.17E+03 2.0E-01 1.1E+01 3.5E+01 10 100
1.24E+02 5.6E+00 1.1E+01 3.5E+01
4.78E+02 3.5E+00 1.1E+01 3.5E+01
1.83E+02 9.2E+00 1.1E+01 3.5E+01
2.23E+02 4.7E+00 1.1E+01 3.5E+01
1.05E+03 9.9E-01 1.1E+01 3.5E+01
2.08E+03 8.0E-01 1.1E+01 3.5E+01

4.28E+03 2.6E-01 1.1E+01 3.5E+01
9.30E+03 1.8E+00 1.1E+01 3.5E+01
1.27E+03 9.7E-01 1.1E+01 3.5E+01 10 100
9.99E+01 1.4E+01 1.1E+01 3.5E+01
2.75E+02 3.2E+00 1.1E+01 3.5E+01
1.81E+02 1.5E+01 1.1E+01 3.5E+01
1.79E+02 1.0E+01 1.1E+01 3.5E+01
3.12E+02 2.3E+00 1.1E+01 3.5E+01
2.07E+03 1.6E+00 1.1E+01 3.5E+01
1.35E+04 1.6E+00 1.1E+01 3.5E+01
5.28E+03 7.5E-01 1.1E+01 3.5E+01
9.34E+03 1.0E+00 1.1E+01 3.5E+01
2.01E+03 7.4E-01 1.1E+01 3.5E+01 10 100
1.31E+02 1.4E+01 1.1E+01 3.5E+01
3.57E+02 4.9E+00 1.1E+01 3.5E+01
2.06E+02 7.0E+00 1.1E+01 3.5E+01
2.15E+02 3.2E+00 1.1E+01 3.5E+01
2.87E+02 3.7E+00 1.1E+01 3.5E+01
2.32E+03 6.9E-01 1.1E+01 3.5E+01

5.29E+03 1.1E+00 1.1E+01 3.5E+01
5.50E+00 3.8E+01 1.1E+01 3.5E+01
5.50E+00 3.8E+01 1.1E+01 3.5E+01
5.50E+00 5.0E+01 1.1E+01 3.5E+01
5.50E+00 6.7E+03 1.1E+01 3.5E+01
5.50E+00 1.4E+02 1.1E+01 3.5E+01
5.50E+00 1.1E+02 1.1E+01 3.5E+01
5.50E+00 3.6E+01 1.1E+01 3.5E+01
5.50E+00 6.0E+01 1.1E+01 3.5E+01
5.50E+00 1.2E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.26E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
2.38E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-412
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B SWA-L04-1313-T01-A
B SWA-L04-1313-T02-A
B SWA-L04-1313-T03-A
B SWA-L04-1313-T04-A
B SWA-L04-1313-T05-A
B SWA-L04-1313-T06-A
B SWA-L04-1313-T07-A
B SWA-L04-1313-T08-A
B SWA-L04-1313-T09-A
B SWA-L04-1313-T10-A
B SWA-L04-1313-T01-B
B SWA-L04-1313-T02-B
B SWA-L04-1313-T03-B
B SWA-L04-1313-T04-B
B SWA-L04-1313-T05-B
B SWA-L04-1313-T06-B
B SWA-L04-1313-T07-B
B SWA-L04-1313-T08-B
B SWA-L04-1313-T09-B
B SWA-L04-1313-T10-B
B SWA-L04-1313-T01-C
B SWA-L04-1313-T02-C
B SWA-L04-1313-T03-C
B SWA-L04-1313-T04-C
B SWA-L04-1313-T05-C
B SWA-L04-1313-T06-C
B SWA-L04-1313-T07-C
B SWA-L04-1313-T08-C
B SWA-L04-1313-T09-C
B SWA-L04-1313-T10-C
B SWA-L04-1313-B01-A
B SWA-L04-1313-B02-A
B SWA-L04-1313-B03-A
B SWA-L04-1313-B01-B
B SWA-L04-1313-B02-B
B SWA-L04-1313-B03-B
B SWA-L04-1313-B01-C
B SWA-L04-1313-B02-C
B SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.34E+03
1 7.89E+02
1 1.14E+03
1 1.95E+03
1 3.14E+03
1 4.70E+03
1 6.70E+03
1 5.71 E+03

1 9.88E+02
1 1.16E+03
1 8.27E+02
1 1.11E+03
1 2. 11 E+03
1 2.60E+03
1 3.44E+03
1 5.43E+03
1 5.78E+03
1 1.14E+04
1 1.16E+03
1 1.33E+03
1 1.05E+03
1 1.14E+03
1 1.76E+03
1 3.15E+03
1 3.82E+03
1 5.45E+03
1 5.59E+03

1 1.19E+03
1 1.33E+01
1 1.87E+01
1 1.45E+01
1 9.62E+00
1 1.18E+01
1 1.26E+01
1 9.01 E+00
1 1.22E+01
1 9.34E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.34E+03 7.1E-02 1.0E+00 3.2E+00
7.89E+02 6.8E-01 1.0E+00 3.2E+00 1000 100
1.14E+03 7.5E-01 1.0E+00 3.2E+00
1.95E+03 5.0E-01 1.0E+00 3.2E+00
3.14E+03 5.7E-01 1.0E+00 3.2E+00
4.70E+03 2.2E-01 1.0E+00 3.2E+00
6.70E+03 9.1E-01 1.0E+00 3.2E+00
5.71 E+03 1.4E-01 1.0E+00 3.2E+00

9.88E+02 4.9E-01 1.0E+00 3.2E+00
1.16E+03 1.2E+00 1.0E+00 3.2E+00
8.27E+02 9.5E-01 1.0E+00 3.2E+00 1000 100
1.11E+03 8.5E-01 1.0E+00 3.2E+00
2.11E+03 6.2E-01 1.0E+00 3.2E+00
2.60E+03 6.8E-01 1.0E+00 3.2E+00
3.44E+03 8.3E-01 1.0E+00 3.2E+00
5.43E+03 2.0E-01 1.0E+00 3.2E+00
5.78E+03 5.7E-01 1.0E+00 3.2E+00
1.14E+04 4.9E-01 1.0E+00 3.2E+00
1.16E+03 1.4E+00 1.0E+00 3.2E+00
1.33E+03 1.1 E+00 1.0E+00 3.2E+00
1.05E+03 1.6E+00 1.0E+00 3.2E+00 1000 100
1.14E+03 1.0E+00 1.0E+00 3.2E+00
1.76E+03 5.1E-01 1.0E+00 3.2E+00
3.15E+03 5.4E-01 1.0E+00 3.2E+00
3.82E+03 5.8E-01 1.0E+00 3.2E+00
5.45E+03 1.9E+00 1.0E+00 3.2E+00
5.59E+03 3.8E-01 1.0E+00 3.2E+00

1.19E+03 9.6E-01 1.0E+00 3.2E+00
1.33E+01 6.1 E+00 1.0E+00 3.2E+00
1.87E+01 6.4E+00 1.0E+00 3.2E+00
1.45E+01 7.3E+00 1.0E+00 3.2E+00
9.62E+00 4.0E+00 1.0E+00 3.2E+00
1.18E+01 2.2E+01 1.0E+00 3.2E+00
1.26E+01 1.5E+01 1.0E+00 3.2E+00
9.01 E+00 2.2E+01 1.0E+00 3.2E+00
1.22E+01 1.3E+01 1.0E+00 3.2E+00
9.34E+00 1.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.92E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
2.01E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.18E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-413
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba SWA-L04-1313-T01-A
Ba SWA-L04-1313-T02-A
Ba SWA-L04-1313-T03-A
Ba SWA-L04-1313-T04-A
Ba SWA-L04-1313-T05-A
Ba SWA-L04-1313-T06-A
Ba SWA-L04-1313-T07-A
Ba SWA-L04-1313-T08-A
Ba SWA-L04-1313-T09-A
Ba SWA-L04-1313-T10-A
Ba SWA-L04-1313-T01-B
Ba SWA-L04-1313-T02-B
Ba SWA-L04-1313-T03-B
Ba SWA-L04-1313-T04-B
Ba SWA-L04-1313-T05-B
Ba SWA-L04-1313-T06-B
Ba SWA-L04-1313-T07-B
Ba SWA-L04-1313-T08-B
Ba SWA-L04-1313-T09-B
Ba SWA-L04-1313-T10-B
Ba SWA-L04-1313-T01-C
Ba SWA-L04-1313-T02-C
Ba SWA-L04-1313-T03-C
Ba SWA-L04-1313-T04-C
Ba SWA-L04-1313-T05-C
Ba SWA-L04-1313-T06-C
Ba SWA-L04-1313-T07-C
Ba SWA-L04-1313-T08-C
Ba SWA-L04-1313-T09-C
Ba SWA-L04-1313-T10-C
Ba SWA-L04-1313-B01-A
Ba SWA-L04-1313-B02-A
Ba SWA-L04-1313-B03-A
Ba SWA-L04-1313-B01-B
Ba SWA-L04-1313-B02-B
Ba SWA-L04-1313-B03-B
Ba SWA-L04-1313-B01-C
Ba SWA-L04-1313-B02-C
Ba SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.36E+02
1 2.75E+02
1 1.08E+03
1 1.11E+03
1 1.24E+03
1 1.55E+03
1 1.16E+03
1 6.39E+02

1 1.97E+02
1 2.45E+02
1 2.64E+02
1 1.05E+03
1 1.15E+03
1 1.22E+03
1 1.36E+03
1 1.67E+03
1 6.81 E+02
1 1.51E+03
1 1.76E+02
1 2.60E+02
1 2.49E+02
1 1.02E+03
1 1.24E+03
1 1.27E+03
1 1.44E+03
1 1.67E+03
1 7.32E+02

1 1.76E+02
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.08E+00 E
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.33E+00 E
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.36E+02 1.9E-01 1.0E+00 3.2E+00
2.75E+02 2.3E-01 1.0E+00 3.2E+00 10 100
1.08E+03 1.4E+00 1.0E+00 3.2E+00
1.11E+03 2.5E-01 1.0E+00 3.2E+00
1.24E+03 3.0E-01 1.0E+00 3.2E+00
1.55E+03 1.4E-01 1.0E+00 3.2E+00
1.16E+03 4.4E-01 1.0E+00 3.2E+00
6.39E+02 1.1E+00 1.0E+00 3.2E+00

1.97E+02 6.2E-01 1.0E+00 3.2E+00
2.45E+02 1.0E+00 1.0E+00 3.2E+00
2.64E+02 2.1E-01 1.0E+00 3.2E+00 10 100
1.05E+03 1.0E+00 1.0E+00 3.2E+00
1.15E+03 6.7E-01 1.0E+00 3.2E+00
1.22E+03 2.4E-01 1.0E+00 3.2E+00
1.36E+03 6.2E-01 1.0E+00 3.2E+00
1.67E+03 6.9E-01 1.0E+00 3.2E+00
6.81 E+02 6.7E-01 1.0E+00 3.2E+00
1.51E+03 4.7E-01 1.0E+00 3.2E+00
1.76E+02 4.2E-01 1.0E+00 3.2E+00
2.60E+02 3.7E-01 1.0E+00 3.2E+00
2.49E+02 7.3E-01 1.0E+00 3.2E+00 10 100
1.02E+03 5.2E-01 1.0E+00 3.2E+00
1.24E+03 7.0E-01 1.0E+00 3.2E+00
1.27E+03 1.1E+00 1.0E+00 3.2E+00
1.44E+03 6.1E-01 1.0E+00 3.2E+00
1.67E+03 1.6E+00 1.0E+00 3.2E+00
7.32E+02 5.1E-01 1.0E+00 3.2E+00

1.76E+02 9.0E-01 1.0E+00 3.2E+00
5.00E-01 3.5E+00 1.0E+00 3.2E+00
5.00E-01 7.8E-01 1.0E+00 3.2E+00
1.08E+00 5.8E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
5.00E-01 3.5E+00 1.0E+00 3.2E+00
1.33E+00 3.1E+00 1.0E+00 3.2E+00
5.00E-01 1.7E+01 1.0E+00 3.2E+00
5.00E-01 4.1E+00 1.0E+00 3.2E+00
5.00E-01 2.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.26E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.30E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-414
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be SWA-L04-1313-T01-A
Be SWA-L04-1313-T02-A
Be SWA-L04-1313-T03-A
Be SWA-L04-1313-T04-A
Be SWA-L04-1313-T05-A
Be SWA-L04-1313-T06-A
Be SWA-L04-1313-T07-A
Be SWA-L04-1313-T08-A
Be SWA-L04-1313-T09-A
Be SWA-L04-1313-T10-A
Be SWA-L04-1313-T01-B
Be SWA-L04-1313-T02-B
Be SWA-L04-1313-T03-B
Be SWA-L04-1313-T04-B
Be SWA-L04-1313-T05-B
Be SWA-L04-1313-T06-B
Be SWA-L04-1313-T07-B
Be SWA-L04-1313-T08-B
Be SWA-L04-1313-T09-B
Be SWA-L04-1313-T10-B
Be SWA-L04-1313-T01-C
Be SWA-L04-1313-T02-C
Be SWA-L04-1313-T03-C
Be SWA-L04-1313-T04-C
Be SWA-L04-1313-T05-C
Be SWA-L04-1313-T06-C
Be SWA-L04-1313-T07-C
Be SWA-L04-1313-T08-C
Be SWA-L04-1313-T09-C
Be SWA-L04-1313-T10-C
Be SWA-L04-1313-B01-A
Be SWA-L04-1313-B02-A
Be SWA-L04-1313-B03-A
Be SWA-L04-1313-B01-B
Be SWA-L04-1313-B02-B
Be SWA-L04-1313-B03-B
Be SWA-L04-1313-B01-C
Be SWA-L04-1313-B02-C
Be SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 5.63E+01

1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.93E+01
1 2.32E+02
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 1.23E+01

1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 7.3E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00 10 100
9.50E-01 2.2E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 6.7E+01 1.9E+00 6.0E+00
9.50E-01 3.6E+01 1.9E+00 6.0E+00
5.63E+01 3.7E+00 1.9E+00 6.0E+00

9.50E-01 9.9E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00 10 100
9.50E-01 4.6E+01 1.9E+00 6.0E+00
9.50E-01 4.0E+01 1.9E+00 6.0E+00
9.50E-01 3.0E+01 1.9E+00 6.0E+00
9.50E-01 7.8E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00
4.93E+01 8.4E-01 1.9E+00 6.0E+00
2.32E+02 3.6E-01 1.9E+00 6.0E+00
9.50E-01 3.3E+01 1.9E+00 6.0E+00
9.50E-01 3.2E+02 1.9E+00 6.0E+00
9.50E-01 2.2E+02 1.9E+00 6.0E+00 10 100
9.50E-01 2.9E+01 1.9E+00 6.0E+00
9.50E-01 4.1E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 3.9E+01 1.9E+00 6.0E+00
1.23E+01 7.4E+00 1.9E+00 6.0E+00

9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 9.3E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 2.2E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 6.4E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.18E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:13 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:15 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:16 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:18 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-415
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd SWA-L04-1313-T01-A
Cd SWA-L04-1313-T02-A
Cd SWA-L04-1313-T03-A
Cd SWA-L04-1313-T04-A
Cd SWA-L04-1313-T05-A
Cd SWA-L04-1313-T06-A
Cd SWA-L04-1313-T07-A
Cd SWA-L04-1313-T08-A
Cd SWA-L04-1313-T09-A
Cd SWA-L04-1313-T10-A
Cd SWA-L04-1313-T01-B
Cd SWA-L04-1313-T02-B
Cd SWA-L04-1313-T03-B
Cd SWA-L04-1313-T04-B
Cd SWA-L04-1313-T05-B
Cd SWA-L04-1313-T06-B
Cd SWA-L04-1313-T07-B
Cd SWA-L04-1313-T08-B
Cd SWA-L04-1313-T09-B
Cd SWA-L04-1313-T10-B
Cd SWA-L04-1313-T01-C
Cd SWA-L04-1313-T02-C
Cd SWA-L04-1313-T03-C
Cd SWA-L04-1313-T04-C
Cd SWA-L04-1313-T05-C
Cd SWA-L04-1313-T06-C
Cd SWA-L04-1313-T07-C
Cd SWA-L04-1313-T08-C
Cd SWA-L04-1313-T09-C
Cd SWA-L04-1313-T10-C
Cd SWA-L04-1313-B01-A
Cd SWA-L04-1313-B02-A
Cd SWA-L04-1313-B03-A
Cd SWA-L04-1313-B01-B
Cd SWA-L04-1313-B02-B
Cd SWA-L04-1313-B03-B
Cd SWA-L04-1313-B01-C
Cd SWA-L04-1313-B02-C
Cd SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.12E+01
1 2.06E+01

1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 7.19E+00
1 2.00E+01
1 5.75E+01
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 5.83E+00 E
1 1.33E+01

1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.6E+02 2.2E+00 7.0E+00
1.10E+00 1.8E+03 2.2E+00 7.0E+00 10 100
1.10E+00 1.3E+02 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
1.10E+00 5.0E+01 2.2E+00 7.0E+00
1.10E+00 2.3E+01 2.2E+00 7.0E+00
1.12E+01 4.3E+00 2.2E+00 7.0E+00
2.06E+01 2.1E+00 2.2E+00 7.0E+00

1.10E+00 6.9E+02 2.2E+00 7.0E+00
1.10E+00 8.3E+02 2.2E+00 7.0E+00
1.10E+00 5.3E+02 2.2E+00 7.0E+00 10 100
1.10E+00 1.5E+02 2.2E+00 7.0E+00
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 1.9E+02 2.2E+00 7.0E+00
1.10E+00 8.2E+01 2.2E+00 7.0E+00
7.19E+00 1.3E+01 2.2E+00 7.0E+00
2.00E+01 1.7E+00 2.2E+00 7.0E+00
5.75E+01 1.5E+00 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00
1.10E+00 2.5E+01 2.2E+00 7.0E+00
1.10E+00 5.6E+01 2.2E+00 7.0E+00 10 100
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 2.8E+02 2.2E+00 7.0E+00
1.10E+00 5.5E+01 2.2E+00 7.0E+00
1.10E+00 7.7E+01 2.2E+00 7.0E+00
5.83E+00 9.3E+00 2.2E+00 7.0E+00
1.33E+01 1.7E+00 2.2E+00 7.0E+00

1.10E+00 3.8E+01 2.2E+00 7.0E+00
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 4.6E+01 2.2E+00 7.0E+00
1.10E+00 1.7E+02 2.2E+00 7.0E+00
1.10E+00 7.1E+02 2.2E+00 7.0E+00
1.10E+00 2.3E+02 2.2E+00 7.0E+00
1.10E+00 2.6E+02 2.2E+00 7.0E+00
1.10E+00 2.5E+02 2.2E+00 7.0E+00
1.10E+00 1.5E+02 2.2E+00 7.0E+00
1.10E+00 2.4E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.15E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.20E+03 120% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:13 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:15 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:16 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:18 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-416
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
SWA-L04-1313-T01-A
SWA-L04-1313-T02-A
SWA-L04-1313-T03-A
SWA-L04-1313-T04-A
SWA-L04-1313-T05-A
SWA-L04-1313-T06-A
SWA-L04-1313-T07-A
SWA-L04-1313-T08-A
SWA-L04-1313-T09-A
SWA-L04-1313-T10-A
SWA-L04-1313-T01-B
SWA-L04-1313-T02-B
SWA-L04-1313-T03-B
SWA-L04-1313-T04-B
SWA-L04-1313-T05-B
SWA-L04-1313-T06-B
SWA-L04-1313-T07-B
SWA-L04-1313-T08-B
SWA-L04-1313-T09-B
SWA-L04-1313-T10-B
SWA-L04-1313-T01-C
SWA-L04-1313-T02-C
SWA-L04-1313-T03-C
SWA-L04-1313-T04-C
SWA-L04-1313-T05-C
SWA-L04-1313-T06-C
SWA-L04-1313-T07-C
SWA-L04-1313-T08-C
SWA-L04-1313-T09-C
SWA-L04-1313-T10-C
SWA-L04-1313-B01-A
SWA-L04-1313-B02-A
SWA-L04-1313-B03-A
SWA-L04-1313-B01-B
SWA-L04-1313-B02-B
SWA-L04-1313-B03-B
SWA-L04-1313-B01-C
SWA-L04-1313-B02-C
SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 7.09E+03
1 3.87E+04
1 3.15E+06
1 5.84E+06
1 7.20E+06
1 8.59E+06
1 6.29E+06
1 3.48E+06

1 1.43E+04
1 7.59E+03
1 3.71 E+04
1 3.23E+06
1 5.80E+06
1 6.67E+06
1 7.66E+06
1 8.52E+06
1 3.59E+06
1 5.62E+06
1 1.26E+04
1 7.84E+03
1 3.09E+04
1 2.89E+06
1 5.52E+06
1 7.14E+06
1 7.75E+06
1 8.71 E+06
1 4.19E+06

1 1.28E+04
1 3.34E+01
1 4.57E+01
1 4.49E+01
1 2.75E+01
1 5.04E+01
1 3.49E+01
1 3.46E+01
1 6.39E+01
1 4.53E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.09E+03 7.0E-01 2.6E+00 8.3E+00
3.87E+04 5.6E-01 2.6E+00 8.3E+00 1000 100
3.15E+06 2.2E-01 2.6E+00 8.3E+00
5.84E+06 7.0E-01 2.6E+00 8.3E+00
7.20E+06 6.9E-01 2.6E+00 8.3E+00
8.59E+06 5.3E-01 2.6E+00 8.3E+00
6.29E+06 3.1E-01 2.6E+00 8.3E+00
3.48E+06 6.3E-01 2.6E+00 8.3E+00

1.43E+04 1.0E+00 2.6E+00 8.3E+00
7.59E+03 1.6E+00 2.6E+00 8.3E+00
3.71E+04 4.0E-01 2.6E+00 8.3E+00 1000 100
3.23E+06 1.2E+00 2.6E+00 8.3E+00
5.80E+06 4.1E-01 2.6E+00 8.3E+00
6.67E+06 3.8E-01 2.6E+00 8.3E+00
7.66E+06 8.2E-01 2.6E+00 8.3E+00
8.52E+06 2.0E+00 2.6E+00 8.3E+00
3.59E+06 8.6E-01 2.6E+00 8.3E+00
5.62E+06 5.4E-01 2.6E+00 8.3E+00
1.26E+04 7.2E-01 2.6E+00 8.3E+00
7.84E+03 3.4E-01 2.6E+00 8.3E+00
3.09E+04 6.7E-01 2.6E+00 8.3E+00 1000 100
2.89E+06 9.6E-01 2.6E+00 8.3E+00
5.52E+06 8.4E-01 2.6E+00 8.3E+00
7.14E+06 7.3E-01 2.6E+00 8.3E+00
7.75E+06 4.4E-01 2.6E+00 8.3E+00
8.71 E+06 1.6E+00 2.6E+00 8.3E+00
4.19E+06 1.1E+00 2.6E+00 8.3E+00

1.28E+04 8.2E-01 2.6E+00 8.3E+00
3.34E+01 1.3E+01 2.6E+00 8.3E+00
4.57E+01 7.8E+00 2.6E+00 8.3E+00
4.49E+01 1.2E+01 2.6E+00 8.3E+00
2.75E+01 9.8E-01 2.6E+00 8.3E+00
5.04E+01 7.1E+00 2.6E+00 8.3E+00
3.49E+01 9.4E-01 2.6E+00 8.3E+00
3.46E+01 2.2E+01 2.6E+00 8.3E+00
6.39E+01 2.3E+01 2.6E+00 8.3E+00
4.53E+01 1.3E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.96E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
3.81 E+04 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-417
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr SWA-L04-1313-T01-A
Cr SWA-L04-1313-T02-A
Cr SWA-L04-1313-T03-A
Cr SWA-L04-1313-T04-A
Cr SWA-L04-1313-T05-A
Cr SWA-L04-1313-T06-A
Cr SWA-L04-1313-T07-A
Cr SWA-L04-1313-T08-A
Cr SWA-L04-1313-T09-A
Cr SWA-L04-1313-T10-A
Cr SWA-L04-1313-T01-B
Cr SWA-L04-1313-T02-B
Cr SWA-L04-1313-T03-B
Cr SWA-L04-1313-T04-B
Cr SWA-L04-1313-T05-B
Cr SWA-L04-1313-T06-B
Cr SWA-L04-1313-T07-B
Cr SWA-L04-1313-T08-B
Cr SWA-L04-1313-T09-B
Cr SWA-L04-1313-T10-B
Cr SWA-L04-1313-T01-C
Cr SWA-L04-1313-T02-C
Cr SWA-L04-1313-T03-C
Cr SWA-L04-1313-T04-C
Cr SWA-L04-1313-T05-C
Cr SWA-L04-1313-T06-C
Cr SWA-L04-1313-T07-C
Cr SWA-L04-1313-T08-C
Cr SWA-L04-1313-T09-C
Cr SWA-L04-1313-T10-C
Cr SWA-L04-1313-B01-A
Cr SWA-L04-1313-B02-A
Cr SWA-L04-1313-B03-A
Cr SWA-L04-1313-B01-B
Cr SWA-L04-1313-B02-B
Cr SWA-L04-1313-B03-B
Cr SWA-L04-1313-B01-C
Cr SWA-L04-1313-B02-C
Cr SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.47E+03
1 2.95E+02
1 9.59E+00
1 1.05E+01
1 9.32E+00
1 5.30E+00
1 6.21E+01
1 5.33E+03

1 1.03E+03
1 1.43E+03
1 3.28E+02
1 1.12E+01
1 9.82E+00
1 1.85E+01
1 5.92E+00
1 7.28E+00
1 4.88E+03
1 3.22E+04
1 1.21E+03
1 1.45E+03
1 4.99E+02
1 1.17E+01
1 1.38E+01
1 1.65E+01
1 5.49E+00
1 5.57E+00
1 1.67E+03

1 1.20E+03
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.47E+03 7.1E-01 1.2E+00 3.8E+00
2.95E+02 7.8E-01 1.2E+00 3.8E+00 10 100
9.59E+00 1.2E+00 1.2E+00 3.8E+00
1.05E+01 7.1E+00 1.2E+00 3.8E+00
9.32E+00 1.1E+01 1.2E+00 3.8E+00
5.30E+00 1.5E+02 1.2E+00 3.8E+00
6.21 E+01 5.2E-01 1.2E+00 3.8E+00
5.33E+03 6.2E-01 1.2E+00 3.8E+00

1.03E+03 1.0E+00 1.2E+00 3.8E+00
1.43E+03 2.0E+00 1.2E+00 3.8E+00
3.28E+02 3.7E-01 1.2E+00 3.8E+00 10 100
1.12E+01 7.4E+00 1.2E+00 3.8E+00
9.82E+00 7.6E+00 1.2E+00 3.8E+00
1.85E+01 6.0E+00 1.2E+00 3.8E+00
5.92E+00 9.1E+00 1.2E+00 3.8E+00
7.28E+00 1.4E+01 1.2E+00 3.8E+00
4.88E+03 5.8E-01 1.2E+00 3.8E+00
3.22E+04 2.9E-01 1.2E+00 3.8E+00
1.21E+03 4.7E-01 1.2E+00 3.8E+00
1.45E+03 1.3E+00 1.2E+00 3.8E+00
4.99E+02 2.1E+00 1.2E+00 3.8E+00 10 100
1.17E+01 3.7E+00 1.2E+00 3.8E+00
1.38E+01 1.5E+00 1.2E+00 3.8E+00
1.65E+01 1.1E+00 1.2E+00 3.8E+00
5.49E+00 2.4E+01 1.2E+00 3.8E+00
5.57E+00 7.2E+00 1.2E+00 3.8E+00
1.67E+03 3.9E-01 1.2E+00 3.8E+00

1.20E+03 1.8E+00 1.2E+00 3.8E+00
6.00E-01 2.7E+02 1.2E+00 3.8E+00
6.00E-01 1.1E+02 1.2E+00 3.8E+00
6.00E-01 9.7E+01 1.2E+00 3.8E+00
6.00E-01 4.0E+02 1.2E+00 3.8E+00
6.00E-01 7.8E+01 1.2E+00 3.8E+00
6.00E-01 8.5E+01 1.2E+00 3.8E+00
6.00E-01 4.2E+01 1.2E+00 3.8E+00
6.00E-01 2.4E+02 1.2E+00 3.8E+00
6.00E-01 5.5E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.40E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.48E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.65E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-418
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
SWA-L04-1313-T01-A
SWA-L04-1313-T02-A
SWA-L04-1313-T03-A
SWA-L04-1313-T04-A
SWA-L04-1313-T05-A
SWA-L04-1313-T06-A
SWA-L04-1313-T07-A
SWA-L04-1313-T08-A
SWA-L04-1313-T09-A
SWA-L04-1313-T10-A
SWA-L04-1313-T01-B
SWA-L04-1313-T02-B
SWA-L04-1313-T03-B
SWA-L04-1313-T04-B
SWA-L04-1313-T05-B
SWA-L04-1313-T06-B
SWA-L04-1313-T07-B
SWA-L04-1313-T08-B
SWA-L04-1313-T09-B
SWA-L04-1313-T10-B
SWA-L04-1313-T01-C
SWA-L04-1313-T02-C
SWA-L04-1313-T03-C
SWA-L04-1313-T04-C
SWA-L04-1313-T05-C
SWA-L04-1313-T06-C
SWA-L04-1313-T07-C
SWA-L04-1313-T08-C
SWA-L04-1313-T09-C
SWA-L04-1313-T10-C
SWA-L04-1313-B01-A
SWA-L04-1313-B02-A
SWA-L04-1313-B03-A
SWA-L04-1313-B01-B
SWA-L04-1313-B02-B
SWA-L04-1313-B03-B
SWA-L04-1313-B01-C
SWA-L04-1313-B02-C
SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 4.67E+00 E
1 2.30E+01
1 1.01E+02
1 2.04E+02
1 1.59E+02

1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 4.13E+00 E
1 9.74E+00
1 2.80E+01
1 1.66E+02
1 1.61E+02
1 3.70E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 3.10E+00 E
1 1.70E+01
1 4.66E+01
1 1.62E+02
1 1.46E+02

1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.8E+02 1.8E+00 5.7E+00
9.00E-01 3.0E+02 1.8E+00 5.7E+00 10 100
9.00E-01 2.1E+01 1.8E+00 5.7E+00
4.67E+00 2.7E+01 1.8E+00 5.7E+00
2.30E+01 7.0E+00 1.8E+00 5.7E+00
1.01E+02 2.6E+00 1.8E+00 5.7E+00
2.04E+02 8.7E-01 1.8E+00 5.7E+00
1.59E+02 3.7E-01 1.8E+00 5.7E+00

9.00E-01 2.2E+02 1.8E+00 5.7E+00
9.00E-01 2.3E+03 1.8E+00 5.7E+00
9.00E-01 2.3E+02 1.8E+00 5.7E+00 10 100
9.00E-01 2.5E+02 1.8E+00 5.7E+00
4.13E+00 1.7E+01 1.8E+00 5.7E+00
9.74E+00 1.3E+01 1.8E+00 5.7E+00
2.80E+01 6.5E+00 1.8E+00 5.7E+00
1.66E+02 1.6E+00 1.8E+00 5.7E+00
1.61E+02 1.4E+00 1.8E+00 5.7E+00
3.70E+02 3.0E-01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 3.2E+02 1.8E+00 5.7E+00
9.00E-01 5.2E+02 1.8E+00 5.7E+00 10 100
9.00E-01 3.4E+02 1.8E+00 5.7E+00
3.10E+00 4.4E+01 1.8E+00 5.7E+00
1.70E+01 1.5E+01 1.8E+00 5.7E+00
4.66E+01 1.4E+00 1.8E+00 5.7E+00
1.62E+02 8.8E-01 1.8E+00 5.7E+00
1.46E+02 7.9E-01 1.8E+00 5.7E+00

9.00E-01 2.2E+03 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 4.9E+01 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00
9.00E-01 3.1E+01 1.8E+00 5.7E+00
9.00E-01 5.3E+01 1.8E+00 5.7E+00
9.00E-01 5.4E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 2.7E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.11E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.14E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:13 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:15 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:16 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:18 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-419
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu SWA-L04-1313-T01-A
Cu SWA-L04-1313-T02-A
Cu SWA-L04-1313-T03-A
Cu SWA-L04-1313-T04-A
Cu SWA-L04-1313-T05-A
Cu SWA-L04-1313-T06-A
Cu SWA-L04-1313-T07-A
Cu SWA-L04-1313-T08-A
Cu SWA-L04-1313-T09-A
Cu SWA-L04-1313-T10-A
Cu SWA-L04-1313-T01-B
Cu SWA-L04-1313-T02-B
Cu SWA-L04-1313-T03-B
Cu SWA-L04-1313-T04-B
Cu SWA-L04-1313-T05-B
Cu SWA-L04-1313-T06-B
Cu SWA-L04-1313-T07-B
Cu SWA-L04-1313-T08-B
Cu SWA-L04-1313-T09-B
Cu SWA-L04-1313-T10-B
Cu SWA-L04-1313-T01-C
Cu SWA-L04-1313-T02-C
Cu SWA-L04-1313-T03-C
Cu SWA-L04-1313-T04-C
Cu SWA-L04-1313-T05-C
Cu SWA-L04-1313-T06-C
Cu SWA-L04-1313-T07-C
Cu SWA-L04-1313-T08-C
Cu SWA-L04-1313-T09-C
Cu SWA-L04-1313-T10-C
Cu SWA-L04-1313-B01-A
Cu SWA-L04-1313-B02-A
Cu SWA-L04-1313-B03-A
Cu SWA-L04-1313-B01-B
Cu SWA-L04-1313-B02-B
Cu SWA-L04-1313-B03-B
Cu SWA-L04-1313-B01-C
Cu SWA-L04-1313-B02-C
Cu SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.03E+01 E
1 1.03E+01 E
1 1.36E+01
1 2.11E+01
1 2.28E+01
1 1.55E+02

1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.01E+01 E
1 1.20E+01
1 1.16E+01 E
1 1.23E+01
1 3.27E+01
1 1.26E+02
1 2.33E+03
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 6.00E+00 E
1 1.09E+01 E
1 1.13E+01 E
1 1.69E+01
1 3.23E+01
1 2.37E+01

1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 1.1E+02 3.7E+00 1.2E+01
1.85E+00 1.0E+02 3.7E+00 1.2E+01 10 100
1.03E+01 2.2E+01 3.7E+00 1.2E+01
1.03E+01 2.3E+01 3.7E+00 1.2E+01
1.36E+01 1.8E+01 3.7E+00 1.2E+01
2.11E+01 7.3E+00 3.7E+00 1.2E+01
2.28E+01 5.3E+00 3.7E+00 1.2E+01
1.55E+02 5.7E-01 3.7E+00 1.2E+01

1.85E+00 5.0E+01 3.7E+00 1.2E+01
1.85E+00 8.7E+01 3.7E+00 1.2E+01
1.85E+00 9.5E+01 3.7E+00 1.2E+01 10 100
1.01E+01 5.9E+00 3.7E+00 1.2E+01
1.20E+01 9.1E+00 3.7E+00 1.2E+01
1.16E+01 2.4E+01 3.7E+00 1.2E+01
1.23E+01 1.4E+01 3.7E+00 1.2E+01
3.27E+01 8.5E+00 3.7E+00 1.2E+01
1.26E+02 2.8E-01 3.7E+00 1.2E+01
2.33E+03 3.9E-01 3.7E+00 1.2E+01
1.85E+00 6.3E+01 3.7E+00 1.2E+01
1.85E+00 5.7E+01 3.7E+00 1.2E+01
1.85E+00 8.2E+01 3.7E+00 1.2E+01 10 100
6.00E+00 3.1E+01 3.7E+00 1.2E+01
1.09E+01 3.6E+01 3.7E+00 1.2E+01
1.13E+01 3.7E+00 3.7E+00 1.2E+01
1.69E+01 9.9E+00 3.7E+00 1.2E+01
3.23E+01 4.6E+00 3.7E+00 1.2E+01
2.37E+01 3.0E+00 3.7E+00 1.2E+01

1.85E+00 1.6E+02 3.7E+00 1.2E+01
1.85E+00 3.9E+01 3.7E+00 1.2E+01
1.85E+00 2.4E+01 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.85E+00 9.9E+01 3.7E+00 1.2E+01
1.85E+00 4.3E+01 3.7E+00 1.2E+01
1.85E+00 5.2E+01 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.85E+00 8.5E+01 3.7E+00 1.2E+01
1.85E+00 7.4E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.10E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.14E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:13 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:15 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:16 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:18 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-420
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe SWA-L04-1313-T01-A
Fe SWA-L04-1313-T02-A
Fe SWA-L04-1313-T03-A
Fe SWA-L04-1313-T04-A
Fe SWA-L04-1313-T05-A
Fe SWA-L04-1313-T06-A
Fe SWA-L04-1313-T07-A
Fe SWA-L04-1313-T08-A
Fe SWA-L04-1313-T09-A
Fe SWA-L04-1313-T10-A
Fe SWA-L04-1313-T01-B
Fe SWA-L04-1313-T02-B
Fe SWA-L04-1313-T03-B
Fe SWA-L04-1313-T04-B
Fe SWA-L04-1313-T05-B
Fe SWA-L04-1313-T06-B
Fe SWA-L04-1313-T07-B
Fe SWA-L04-1313-T08-B
Fe SWA-L04-1313-T09-B
Fe SWA-L04-1313-T10-B
Fe SWA-L04-1313-T01-C
Fe SWA-L04-1313-T02-C
Fe SWA-L04-1313-T03-C
Fe SWA-L04-1313-T04-C
Fe SWA-L04-1313-T05-C
Fe SWA-L04-1313-T06-C
Fe SWA-L04-1313-T07-C
Fe SWA-L04-1313-T08-C
Fe SWA-L04-1313-T09-C
Fe SWA-L04-1313-T10-C
Fe SWA-L04-1313-B01-A
Fe SWA-L04-1313-B02-A
Fe SWA-L04-1313-B03-A
Fe SWA-L04-1313-B01-B
Fe SWA-L04-1313-B02-B
Fe SWA-L04-1313-B03-B
Fe SWA-L04-1313-B01-C
Fe SWA-L04-1313-B02-C
Fe SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.09E+02
1 4.69E+01
1 9.29E+00
1 1.86E+01
1 1.09E+01
1 3.70E+03
1 1.13E+05
1 1.04E+05

1 6.94E+01
1 8.99E+01
1 4.62E+01
1 1.01E+01
1 1.68E+01
1 1.42E+01
1 1.17E+01
1 5.72E+04
1 1.03E+05
1 2.50E+05
1 8.48E+01
1 1.05E+02
1 6.63E+01
1 1.21E+01
1 1.91E+01
1 1.26E+01
1 1.28E+01
1 5.17E+04
1 9.15E+04

1 8.39E+01
1 1.00E+00 U1/2
1 3.30E+00 E
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 4.39E+00 E
1 3.95E+00 E
1 1.00E+00 U1/2
1 5.41 E+00 E
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.09E+02 5.7E-01 2.0E+00 6.4E+00
4.69E+01 1.7E+00 2.0E+00 6.4E+00 1000 100
9.29E+00 5.5E+00 2.0E+00 6.4E+00
1.86E+01 1.4E+00 2.0E+00 6.4E+00
1.09E+01 3.8E+00 2.0E+00 6.4E+00
3.70E+03 4.1E-01 2.0E+00 6.4E+00
1.13E+05 2.4E-01 2.0E+00 6.4E+00
1.04E+05 8.1E-01 2.0E+00 6.4E+00

6.94E+01 3.3E-01 2.0E+00 6.4E+00
8.99E+01 5.4E-01 2.0E+00 6.4E+00
4.62E+01 3.4E-01 2.0E+00 6.4E+00 1000 100
1.01E+01 6.3E+00 2.0E+00 6.4E+00
1.68E+01 1.7E+00 2.0E+00 6.4E+00
1.42E+01 7.6E+00 2.0E+00 6.4E+00
1.17E+01 7.6E+00 2.0E+00 6.4E+00
5.72E+04 3.9E-01 2.0E+00 6.4E+00
1.03E+05 1.2E+00 2.0E+00 6.4E+00
2.50E+05 4.5E+00 2.0E+00 6.4E+00
8.48E+01 6.4E-01 2.0E+00 6.4E+00
1.05E+02 9.6E-01 2.0E+00 6.4E+00
6.63E+01 8.4E-01 2.0E+00 6.4E+00 1000 100
1.21E+01 5.8E-01 2.0E+00 6.4E+00
1.91E+01 1.5E+00 2.0E+00 6.4E+00
1.26E+01 2.8E+00 2.0E+00 6.4E+00
1.28E+01 5.4E+00 2.0E+00 6.4E+00
5.17E+04 1.1 E+00 2.0E+00 6.4E+00
9.15E+04 8.5E-01 2.0E+00 6.4E+00

8.39E+01 9.1E-01 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
3.30E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 8.2E+01 2.0E+00 6.4E+00
4.39E+00 7.8E+00 2.0E+00 6.4E+00
3.95E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 5.5E+01 2.0E+00 6.4E+00
5.41 E+00 9.5E-01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.21E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.23E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+03 120% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-421
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb SWA-L04-1313-T01-A
Pb SWA-L04-1313-T02-A
Pb SWA-L04-1313-T03-A
Pb SWA-L04-1313-T04-A
Pb SWA-L04-1313-T05-A
Pb SWA-L04-1313-T06-A
Pb SWA-L04-1313-T07-A
Pb SWA-L04-1313-T08-A
Pb SWA-L04-1313-T09-A
Pb SWA-L04-1313-T10-A
Pb SWA-L04-1313-T01-B
Pb SWA-L04-1313-T02-B
Pb SWA-L04-1313-T03-B
Pb SWA-L04-1313-T04-B
Pb SWA-L04-1313-T05-B
Pb SWA-L04-1313-T06-B
Pb SWA-L04-1313-T07-B
Pb SWA-L04-1313-T08-B
Pb SWA-L04-1313-T09-B
Pb SWA-L04-1313-T10-B
Pb SWA-L04-1313-T01-C
Pb SWA-L04-1313-T02-C
Pb SWA-L04-1313-T03-C
Pb SWA-L04-1313-T04-C
Pb SWA-L04-1313-T05-C
Pb SWA-L04-1313-T06-C
Pb SWA-L04-1313-T07-C
Pb SWA-L04-1313-T08-C
Pb SWA-L04-1313-T09-C
Pb SWA-L04-1313-T10-C
Pb SWA-L04-1313-B01-A
Pb SWA-L04-1313-B02-A
Pb SWA-L04-1313-B03-A
Pb SWA-L04-1313-B01-B
Pb SWA-L04-1313-B02-B
Pb SWA-L04-1313-B03-B
Pb SWA-L04-1313-B01-C
Pb SWA-L04-1313-B02-C
Pb SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.23E+01
1 9.09E+00 E
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 9.98E+00 E
1 1.10E+01 E
1 2.32E+01
1 5.21E+02

1 1.13E+01 E
1 5.26E+01
1 1.03E+01 E
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 1.56E+01 E
1 1.73E+01 E
1 4.55E+02
1 5.89E+03
1 1.36E+01 E
1 5.23E+01
1 7.14E+00 E
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 1.02E+01 E
1 1.44E+01 E
1 1.14E+01 E
1 7.08E+01

1 1.74E+01 E
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.23E+01 1.2E+01 6.8E+00 2.2E+01
9.09E+00 1.3E+02 6.8E+00 2.2E+01 10 100
3.40E+00 1.0E+02 6.8E+00 2.2E+01
3.40E+00 2.8E+02 6.8E+00 2.2E+01
9.98E+00 8.3E+01 6.8E+00 2.2E+01
1.10E+01 4.4E+01 6.8E+00 2.2E+01
2.32E+01 5.5E+01 6.8E+00 2.2E+01
5.21 E+02 1.5E-01 6.8E+00 2.2E+01

1.13E+01 2.2E+01 6.8E+00 2.2E+01
5.26E+01 8.9E+00 6.8E+00 2.2E+01
1.03E+01 6.1E+01 6.8E+00 2.2E+01 10 100
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 5.5E+02 6.8E+00 2.2E+01
3.40E+00 1.9E+02 6.8E+00 2.2E+01
1.56E+01 3.3E+01 6.8E+00 2.2E+01
1.73E+01 3.3E+01 6.8E+00 2.2E+01
4.55E+02 1.0E+00 6.8E+00 2.2E+01
5.89E+03 5.2E-01 6.8E+00 2.2E+01
1.36E+01 1.2E+01 6.8E+00 2.2E+01
5.23E+01 1.4E+00 6.8E+00 2.2E+01
7.14E+00 5.7E+01 6.8E+00 2.2E+01 10 100
3.40E+00 2.9E+02 6.8E+00 2.2E+01
3.40E+00 4.4E+01 6.8E+00 2.2E+01
1.02E+01 5.2E+01 6.8E+00 2.2E+01
1.44E+01 3.5E+01 6.8E+00 2.2E+01
1.14E+01 1.1 E+02 6.8E+00 2.2E+01
7.08E+01 7.8E+00 6.8E+00 2.2E+01

1.74E+01 1.6E+01 6.8E+00 2.2E+01
3.40E+00 6.4E+01 6.8E+00 2.2E+01
3.40E+00 3.9E+02 6.8E+00 2.2E+01
3.40E+00 1.6E+03 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.40E+00 2.7E+02 6.8E+00 2.2E+01
3.40E+00 1.2E+03 6.8E+00 2.2E+01
3.40E+00 1.0E+02 6.8E+00 2.2E+01
3.40E+00 2.5E+02 6.8E+00 2.2E+01
3.40E+00 2.3E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.11E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.15E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:15 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:16 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:18 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-422
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li SWA-L04-1313-T01-A
Li SWA-L04-1313-T02-A
Li SWA-L04-1313-T03-A
Li SWA-L04-1313-T04-A
Li SWA-L04-1313-T05-A
Li SWA-L04-1313-T06-A
Li SWA-L04-1313-T07-A
Li SWA-L04-1313-T08-A
Li SWA-L04-1313-T09-A
Li SWA-L04-1313-T10-A
Li SWA-L04-1313-T01-B
Li SWA-L04-1313-T02-B
Li SWA-L04-1313-T03-B
Li SWA-L04-1313-T04-B
Li SWA-L04-1313-T05-B
Li SWA-L04-1313-T06-B
Li SWA-L04-1313-T07-B
Li SWA-L04-1313-T08-B
Li SWA-L04-1313-T09-B
Li SWA-L04-1313-T10-B
Li SWA-L04-1313-T01-C
Li SWA-L04-1313-T02-C
Li SWA-L04-1313-T03-C
Li SWA-L04-1313-T04-C
Li SWA-L04-1313-T05-C
Li SWA-L04-1313-T06-C
Li SWA-L04-1313-T07-C
Li SWA-L04-1313-T08-C
Li SWA-L04-1313-T09-C
Li SWA-L04-1313-T10-C
Li SWA-L04-1313-B01-A
Li SWA-L04-1313-B02-A
Li SWA-L04-1313-B03-A
Li SWA-L04-1313-B01-B
Li SWA-L04-1313-B02-B
Li SWA-L04-1313-B03-B
Li SWA-L04-1313-B01-C
Li SWA-L04-1313-B02-C
Li SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.50E-01 U1/2
1 2.87E+00 E
1 1.95E+02
1 5.84E+02
1 8.26E+02
1 1.03E+03
1 8.50E+02
1 5.26E+02

1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.24E+00 E
1 1.89E+02
1 6.07E+02
1 7.40E+02
1 8.78E+02
1 9.91 E+02
1 5.57E+02
1 1.15E+03
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 3.90E+00 E
1 1.68E+02
1 5.29E+02
1 8.27E+02
1 9.06E+02
1 1.04E+03
1 5.75E+02

1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.8E+01 1.9E+00 6.0E+00
2.87E+00 6.1E+00 1.9E+00 6.0E+00 10 100
1.95E+02 4.8E+00 1.9E+00 6.0E+00
5.84E+02 3.5E+00 1.9E+00 6.0E+00
8.26E+02 2.8E+00 1.9E+00 6.0E+00
1.03E+03 3.5E+00 1.9E+00 6.0E+00
8.50E+02 6.4E+00 1.9E+00 6.0E+00
5.26E+02 5.3E-01 1.9E+00 6.0E+00

9.50E-01 3.0E+00 1.9E+00 6.0E+00
9.50E-01 3.2E+01 1.9E+00 6.0E+00
2.24E+00 6.1E+00 1.9E+00 6.0E+00 10 100
1.89E+02 6.6E+00 1.9E+00 6.0E+00
6.07E+02 3.6E+00 1.9E+00 6.0E+00
7.40E+02 4.7E+00 1.9E+00 6.0E+00
8.78E+02 9.2E-01 1.9E+00 6.0E+00
9.91 E+02 5.0E+00 1.9E+00 6.0E+00
5.57E+02 1.7E+00 1.9E+00 6.0E+00
1.15E+03 3.7E+00 1.9E+00 6.0E+00
9.50E-01 1.0E+01 1.9E+00 6.0E+00
9.50E-01 7.4E+00 1.9E+00 6.0E+00
3.90E+00 3.2E+01 1.9E+00 6.0E+00 10 100
1.68E+02 7.1E+00 1.9E+00 6.0E+00
5.29E+02 1.0E+00 1.9E+00 6.0E+00
8.27E+02 3.0E+00 1.9E+00 6.0E+00
9.06E+02 4.3E+00 1.9E+00 6.0E+00
1.04E+03 4.7E+00 1.9E+00 6.0E+00
5.75E+02 1.9E+00 1.9E+00 6.0E+00

9.50E-01 2.5E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 3.9E+00 1.9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 7.2E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.49E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
8.91 E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.02E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-423
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn SWA-L04-1313-T01-A
Mn SWA-L04-1313-T02-A
Mn SWA-L04-1313-T03-A
Mn SWA-L04-1313-T04-A
Mn SWA-L04-1313-T05-A
Mn SWA-L04-1313-T06-A
Mn SWA-L04-1313-T07-A
Mn SWA-L04-1313-T08-A
Mn SWA-L04-1313-T09-A
Mn SWA-L04-1313-T10-A
Mn SWA-L04-1313-T01-B
Mn SWA-L04-1313-T02-B
Mn SWA-L04-1313-T03-B
Mn SWA-L04-1313-T04-B
Mn SWA-L04-1313-T05-B
Mn SWA-L04-1313-T06-B
Mn SWA-L04-1313-T07-B
Mn SWA-L04-1313-T08-B
Mn SWA-L04-1313-T09-B
Mn SWA-L04-1313-T10-B
Mn SWA-L04-1313-T01-C
Mn SWA-L04-1313-T02-C
Mn SWA-L04-1313-T03-C
Mn SWA-L04-1313-T04-C
Mn SWA-L04-1313-T05-C
Mn SWA-L04-1313-T06-C
Mn SWA-L04-1313-T07-C
Mn SWA-L04-1313-T08-C
Mn SWA-L04-1313-T09-C
Mn SWA-L04-1313-T10-C
Mn SWA-L04-1313-B01-A
Mn SWA-L04-1313-B02-A
Mn SWA-L04-1313-B03-A
Mn SWA-L04-1313-B01-B
Mn SWA-L04-1313-B02-B
Mn SWA-L04-1313-B03-B
Mn SWA-L04-1313-B01-C
Mn SWA-L04-1313-B02-C
Mn SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 4.08E+02
1 7.49E+03
1 1.76E+04
1 2.18E+04
1 1.47E+04

1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.02E+03
1 2.95E+03
1 8.60E+03
1 2.22E+04
1 1.48E+04
1 2.98E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 6.60E+01
1 6.00E+03
1 1.08E+04
1 2.21 E+04
1 1.46E+04

1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 4.1E+01 2.0E+00 6.4E+00 10 100
1.00E+00 4.5E+01 2.0E+00 6.4E+00
4.08E+02 6.5E-01 2.0E+00 6.4E+00
7.49E+03 3.1E-01 2.0E+00 6.4E+00
1.76E+04 1.8E-01 2.0E+00 6.4E+00
2.18E+04 2.3E-01 2.0E+00 6.4E+00
1.47E+04 1.8E-01 2.0E+00 6.4E+00

1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00 10 100
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.02E+03 1.5E-01 2.0E+00 6.4E+00
2.95E+03 9.1E-01 2.0E+00 6.4E+00
8.60E+03 2.5E-01 2.0E+00 6.4E+00
2.22E+04 7.2E-01 2.0E+00 6.4E+00
1.48E+04 1.3E+00 2.0E+00 6.4E+00
2.98E+04 7.2E-01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00
1.00E+00 6.1E+00 2.0E+00 6.4E+00 10 100
1.00E+00 3.2E+01 2.0E+00 6.4E+00
6.60E+01 2.8E-01 2.0E+00 6.4E+00
6.00E+03 6.7E-01 2.0E+00 6.4E+00
1.08E+04 5.9E-01 2.0E+00 6.4E+00
2.21E+04 1.1E+00 2.0E+00 6.4E+00
1.46E+04 4.4E-01 2.0E+00 6.4E+00

1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 2.0E+02 2.0E+00 6.4E+00
1.00E+00 4.5E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 4.6E+01 2.0E+00 6.4E+00
1.00E+00 3.6E+00 2.0E+00 6.4E+00
1.00E+00 5.7E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 8.3E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.16E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:13 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:15 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:16 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:18 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-424
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg SWA-L04-1313-T01-A
Mg SWA-L04-1313-T02-A
Mg SWA-L04-1313-T03-A
Mg SWA-L04-1313-T04-A
Mg SWA-L04-1313-T05-A
Mg SWA-L04-1313-T06-A
Mg SWA-L04-1313-T07-A
Mg SWA-L04-1313-T08-A
Mg SWA-L04-1313-T09-A
Mg SWA-L04-1313-T10-A
Mg SWA-L04-1313-T01-B
Mg SWA-L04-1313-T02-B
Mg SWA-L04-1313-T03-B
Mg SWA-L04-1313-T04-B
Mg SWA-L04-1313-T05-B
Mg SWA-L04-1313-T06-B
Mg SWA-L04-1313-T07-B
Mg SWA-L04-1313-T08-B
Mg SWA-L04-1313-T09-B
Mg SWA-L04-1313-T10-B
Mg SWA-L04-1313-T01-C
Mg SWA-L04-1313-T02-C
Mg SWA-L04-1313-T03-C
Mg SWA-L04-1313-T04-C
Mg SWA-L04-1313-T05-C
Mg SWA-L04-1313-T06-C
Mg SWA-L04-1313-T07-C
Mg SWA-L04-1313-T08-C
Mg SWA-L04-1313-T09-C
Mg SWA-L04-1313-T10-C
Mg SWA-L04-1313-B01-A
Mg SWA-L04-1313-B02-A
Mg SWA-L04-1313-B03-A
Mg SWA-L04-1313-B01-B
Mg SWA-L04-1313-B02-B
Mg SWA-L04-1313-B03-B
Mg SWA-L04-1313-B01-C
Mg SWA-L04-1313-B02-C
Mg SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.65E+00
1 9.18E+00
1 3.48E+04
1 7.77E+05
1 1.17E+06
1 1.51E+06
1 1.21E+06
1 7.20E+05

1 1.25E+01
1 1.22E+01
1 2.65E+01
1 5.49E+04
1 7.99E+05
1 1.01E+06
1 1.23E+06
1 1.50E+06
1 7.32E+05
1 1.28E+06
1 1.03E+01
1 1.36E+01
1 1.37E+01
1 1.12E+04
1 6.30E+05
1 1.14E+06
1 1.29E+06
1 1.53E+06
1 7.93E+05

1 8.14E+00
1 1.08E+00 E
1 8.53E+00
1 2.57E+00 E
1 1.63E+00 E
1 1.76E+00 E
1 2.25E+00 E
1 5.00E-01 U1/2
1 1.48E+00 E
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.65E+00 1.2E+02 1.0E+00 3.2E+00
9.18E+00 1.2E+02 1.0E+00 3.2E+00 1000 100
3.48E+04 2.2E-01 1.0E+00 3.2E+00
7.77E+05 9.6E-01 1.0E+00 3.2E+00
1.17E+06 9.6E-02 1.0E+00 3.2E+00
1.51E+06 6.4E-01 1.0E+00 3.2E+00
1.21E+06 7.5E-01 1.0E+00 3.2E+00
7.20E+05 5.0E-01 1.0E+00 3.2E+00

1.25E+01 1.6E+01 1.0E+00 3.2E+00
1.22E+01 3.5E+01 1.0E+00 3.2E+00
2.65E+01 2.8E+01 1.0E+00 3.2E+00 1000 100
5.49E+04 1.3E+00 1.0E+00 3.2E+00
7.99E+05 1.3E+00 1.0E+00 3.2E+00
1.01E+06 2.0E-01 1.0E+00 3.2E+00
1.23E+06 4.9E-01 1.0E+00 3.2E+00
1.50E+06 6.1E-01 1.0E+00 3.2E+00
7.32E+05 6.7E-01 1.0E+00 3.2E+00
1.28E+06 6.2E-01 1.0E+00 3.2E+00
1.03E+01 1.6E+02 1.0E+00 3.2E+00
1.36E+01 2.2E+01 1.0E+00 3.2E+00
1.37E+01 5.4E+01 1.0E+00 3.2E+00 1000 100
1.12E+04 1.2E+00 1.0E+00 3.2E+00
6.30E+05 7.0E-01 1.0E+00 3.2E+00
1.14E+06 7.6E-01 1.0E+00 3.2E+00
1.29E+06 2.6E-01 1.0E+00 3.2E+00
1.53E+06 9.7E-01 1.0E+00 3.2E+00
7.93E+05 3.8E-01 1.0E+00 3.2E+00

8.14E+00 9.5E+01 1.0E+00 3.2E+00
1.08E+00 8.5E+02 1.0E+00 3.2E+00
8.53E+00 2.5E+01 1.0E+00 3.2E+00
2.57E+00 1.6E+02 1.0E+00 3.2E+00
1.63E+00 5.6E+00 1.0E+00 3.2E+00
1.76E+00 1.6E+02 1.0E+00 3.2E+00
2.25E+00 2.6E+00 1.0E+00 3.2E+00
5.00E-01 3.6E+01 1.0E+00 3.2E+00
1.48E+00 1.1E+02 1.0E+00 3.2E+00
5.00E-01 5.6E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.16E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.19E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-425
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo SWA-L04-1313-T01-A
Mo SWA-L04-1313-T02-A
Mo SWA-L04-1313-T03-A
Mo SWA-L04-1313-T04-A
Mo SWA-L04-1313-T05-A
Mo SWA-L04-1313-T06-A
Mo SWA-L04-1313-T07-A
Mo SWA-L04-1313-T08-A
Mo SWA-L04-1313-T09-A
Mo SWA-L04-1313-T10-A
Mo SWA-L04-1313-T01-B
Mo SWA-L04-1313-T02-B
Mo SWA-L04-1313-T03-B
Mo SWA-L04-1313-T04-B
Mo SWA-L04-1313-T05-B
Mo SWA-L04-1313-T06-B
Mo SWA-L04-1313-T07-B
Mo SWA-L04-1313-T08-B
Mo SWA-L04-1313-T09-B
Mo SWA-L04-1313-T10-B
Mo SWA-L04-1313-T01-C
Mo SWA-L04-1313-T02-C
Mo SWA-L04-1313-T03-C
Mo SWA-L04-1313-T04-C
Mo SWA-L04-1313-T05-C
Mo SWA-L04-1313-T06-C
Mo SWA-L04-1313-T07-C
Mo SWA-L04-1313-T08-C
Mo SWA-L04-1313-T09-C
Mo SWA-L04-1313-T10-C
Mo SWA-L04-1313-B01-A
Mo SWA-L04-1313-B02-A
Mo SWA-L04-1313-B03-A
Mo SWA-L04-1313-B01-B
Mo SWA-L04-1313-B02-B
Mo SWA-L04-1313-B03-B
Mo SWA-L04-1313-B01-C
Mo SWA-L04-1313-B02-C
Mo SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.27E+02
1 1.31E+02
1 1.32E+02
1 1.34E+02
1 1.01E+02
1 3.69E+01
1 1.40E+01
1 5.84E+00

1 1.21E+02
1 1.14E+02
1 1.24E+02
1 1.27E+02
1 1.38E+02
1 1.20E+02
1 8.88E+01
1 1.65E+01
1 5.70E+00
1 8.97E+00
1 1.32E+02
1 1.12E+02
1 1.34E+02
1 1.40E+02
1 1.43E+02
1 1.10E+02
1 6.68E+01
1 2.12E+01
1 8.94E+00

1 1.34E+02
1 6.00E-01 U1/2
1 3.64E+00 E
1 6.00E-01 U1/2
1 1.28E+00 E
1 2.54E+00 E
1 1.36E+00 E
1 6.00E-01 U1/2
1 1.87E+00 E
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+02 1.5E+00 1.2E+00 3.8E+00
1.31E+02 3.8E-01 1.2E+00 3.8E+00 10 100
1.32E+02 2.2E-01 1.2E+00 3.8E+00
1.34E+02 2.1E+00 1.2E+00 3.8E+00
1.01E+02 1.1E+00 1.2E+00 3.8E+00
3.69E+01 6.9E-01 1.2E+00 3.8E+00
1.40E+01 2.5E+01 1.2E+00 3.8E+00
5.84E+00 9.5E+00 1.2E+00 3.8E+00

1.21E+02 1.6E-01 1.2E+00 3.8E+00
1.14E+02 7.4E-01 1.2E+00 3.8E+00
1.24E+02 5.9E-01 1.2E+00 3.8E+00 10 100
1.27E+02 1.2E+00 1.2E+00 3.8E+00
1.38E+02 9.8E-01 1.2E+00 3.8E+00
1.20E+02 2.1E+00 1.2E+00 3.8E+00
8.88E+01 1.4E+00 1.2E+00 3.8E+00
1.65E+01 9.5E+00 1.2E+00 3.8E+00
5.70E+00 2.9E+01 1.2E+00 3.8E+00
8.97E+00 2.3E+01 1.2E+00 3.8E+00
1.32E+02 7.5E-01 1.2E+00 3.8E+00
1.12E+02 1.2E+00 1.2E+00 3.8E+00
1.34E+02 2.2E+00 1.2E+00 3.8E+00 10 100
1.40E+02 1.2E+00 1.2E+00 3.8E+00
1.43E+02 9.4E-01 1.2E+00 3.8E+00
1.10E+02 1.7E-01 1.2E+00 3.8E+00
6.68E+01 5.9E-01 1.2E+00 3.8E+00
2.12E+01 8.0E+00 1.2E+00 3.8E+00
8.94E+00 2.6E+01 1.2E+00 3.8E+00

1.34E+02 1.3E+00 1.2E+00 3.8E+00
6.00E-01 3.2E+02 1.2E+00 3.8E+00
3.64E+00 3.5E+01 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
1.28E+00 2.3E+01 1.2E+00 3.8E+00
2.54E+00 5.6E+01 1.2E+00 3.8E+00
1.36E+00 3.3E+01 1.2E+00 3.8E+00
6.00E-01 1.7E+02 1.2E+00 3.8E+00
1.87E+00 5.0E+01 1.2E+00 3.8E+00
6.00E-01 1.0E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.25E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.28E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-426
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni SWA-L04-1313-T01-A
Ni SWA-L04-1313-T02-A
Ni SWA-L04-1313-T03-A
Ni SWA-L04-1313-T04-A
Ni SWA-L04-1313-T05-A
Ni SWA-L04-1313-T06-A
Ni SWA-L04-1313-T07-A
Ni SWA-L04-1313-T08-A
Ni SWA-L04-1313-T09-A
Ni SWA-L04-1313-T10-A
Ni SWA-L04-1313-T01-B
Ni SWA-L04-1313-T02-B
Ni SWA-L04-1313-T03-B
Ni SWA-L04-1313-T04-B
Ni SWA-L04-1313-T05-B
Ni SWA-L04-1313-T06-B
Ni SWA-L04-1313-T07-B
Ni SWA-L04-1313-T08-B
Ni SWA-L04-1313-T09-B
Ni SWA-L04-1313-T10-B
Ni SWA-L04-1313-T01-C
Ni SWA-L04-1313-T02-C
Ni SWA-L04-1313-T03-C
Ni SWA-L04-1313-T04-C
Ni SWA-L04-1313-T05-C
Ni SWA-L04-1313-T06-C
Ni SWA-L04-1313-T07-C
Ni SWA-L04-1313-T08-C
Ni SWA-L04-1313-T09-C
Ni SWA-L04-1313-T10-C
Ni SWA-L04-1313-B01-A
Ni SWA-L04-1313-B02-A
Ni SWA-L04-1313-B03-A
Ni SWA-L04-1313-B01-B
Ni SWA-L04-1313-B02-B
Ni SWA-L04-1313-B03-B
Ni SWA-L04-1313-B01-C
Ni SWA-L04-1313-B02-C
Ni SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 4.17E+00 E
1 1.30E+01
1 7.07E+01
1 2.80E+02
1 4.44E+02
1 3.20E+02

1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 7.57E+00
1 1.09E+01
1 2.64E+01
1 9.14E+01
1 4.10E+02
1 3.23E+02
1 6.70E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 2.95E+00 E
1 1.27E+01
1 5.24E+01
1 1.39E+02
1 3.99E+02
1 3.17E+02

1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.1E+03 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00 10 100
4.17E+00 3.5E+01 1.8E+00 5.7E+00
1.30E+01 1.8E+01 1.8E+00 5.7E+00
7.07E+01 2.3E+00 1.8E+00 5.7E+00
2.80E+02 1.0E+00 1.8E+00 5.7E+00
4.44E+02 9.5E-01 1.8E+00 5.7E+00
3.20E+02 3.1E-01 1.8E+00 5.7E+00

9.00E-01 5.5E+01 1.8E+00 5.7E+00
9.00E-01 6.5E+02 1.8E+00 5.7E+00
9.00E-01 2.7E+02 1.8E+00 5.7E+00 10 100
7.57E+00 2.3E+01 1.8E+00 5.7E+00
1.09E+01 1.6E+01 1.8E+00 5.7E+00
2.64E+01 1.5E+00 1.8E+00 5.7E+00
9.14E+01 3.4E+00 1.8E+00 5.7E+00
4.10E+02 8.1E-01 1.8E+00 5.7E+00
3.23E+02 1.3E+00 1.8E+00 5.7E+00
6.70E+02 5.8E-01 1.8E+00 5.7E+00
9.00E-01 2.4E+02 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00 10 100
2.95E+00 1.1E+02 1.8E+00 5.7E+00
1.27E+01 1.8E+01 1.8E+00 5.7E+00
5.24E+01 3.0E+00 1.8E+00 5.7E+00
1.39E+02 3.3E+00 1.8E+00 5.7E+00
3.99E+02 9.1E-01 1.8E+00 5.7E+00
3.17E+02 8.1E-02 1.8E+00 5.7E+00

9.00E-01 7.1E+01 1.8E+00 5.7E+00
9.00E-01 7.2E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 1.1E+01 1.8E+00 5.7E+00
9.00E-01 2.4E+02 1.8E+00 5.7E+00
9.00E-01 5.1E+01 1.8E+00 5.7E+00
9.00E-01 6.0E+02 1.8E+00 5.7E+00
9.00E-01 4.6E+02 1.8E+00 5.7E+00
9.00E-01 3.9E+02 1.8E+00 5.7E+00
9.00E-01 7.4E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.12E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.16E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:13 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:15 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:16 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:18 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-427
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P SWA-L04-1313-T01-A
P SWA-L04-1313-T02-A
P SWA-L04-1313-T03-A
P SWA-L04-1313-T04-A
P SWA-L04-1313-T05-A
P SWA-L04-1313-T06-A
P SWA-L04-1313-T07-A
P SWA-L04-1313-T08-A
P SWA-L04-1313-T09-A
P SWA-L04-1313-T10-A
P SWA-L04-1313-T01-B
P SWA-L04-1313-T02-B
P SWA-L04-1313-T03-B
P SWA-L04-1313-T04-B
P SWA-L04-1313-T05-B
P SWA-L04-1313-T06-B
P SWA-L04-1313-T07-B
P SWA-L04-1313-T08-B
P SWA-L04-1313-T09-B
P SWA-L04-1313-T10-B
P SWA-L04-1313-T01-C
P SWA-L04-1313-T02-C
P SWA-L04-1313-T03-C
P SWA-L04-1313-T04-C
P SWA-L04-1313-T05-C
P SWA-L04-1313-T06-C
P SWA-L04-1313-T07-C
P SWA-L04-1313-T08-C
P SWA-L04-1313-T09-C
P SWA-L04-1313-T10-C
P SWA-L04-1313-B01-A
P SWA-L04-1313-B02-A
P SWA-L04-1313-B03-A
P SWA-L04-1313-B01-B
P SWA-L04-1313-B02-B
P SWA-L04-1313-B03-B
P SWA-L04-1313-B01-C
P SWA-L04-1313-B02-C
P SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.24E+02
1 9.24E+01
1 1.85E+00 U1/2
1 6.23E+01
1 4.56E+01
1 2.83E+01
1 1.09E+02
1 3.66E+02

1 3.49E+01
1 1.16E+02
1 7.22E+01
1 1.85E+00 U1/2
1 8.40E+01
1 5.01 E+01
1 6.65E+01
1 2.15E+01
1 5.34E+02
1 2.68E+03
1 4.37E+01
1 1.17E+02
1 6.14E+01
1 1.85E+00 U1/2
1 6.82E+01
1 4.26E+01
1 1.88E+01
1 2. 11 E+01
1 5.74E+02

1 3.39E+01
1 1.85E+00 U1/2
1 5.02E+00 E
1 4.15E+00 E
1 6.10E+00 E
1 7.21 E+00 E
1 1.85E+00 U1/2
1 1.10E+01 E
1 5.25E+00 E
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.24E+02 6.0E+00 3.7E+00 1.2E+01
9.24E+01 2.6E+02 3.7E+00 1.2E+01 1000 100
1.85E+00 1.5E+02 3.7E+00 1.2E+01
6.23E+01 3.5E+01 3.7E+00 1.2E+01
4.56E+01 4.5E+01 3.7E+00 1.2E+01
2.83E+01 5.7E+01 3.7E+00 1.2E+01
1.09E+02 7.7E+00 3.7E+00 1.2E+01
3.66E+02 2.5E+00 3.7E+00 1.2E+01

3.49E+01 4.6E+01 3.7E+00 1.2E+01
1.16E+02 1.4E+01 3.7E+00 1.2E+01
7.22E+01 1.0E+02 3.7E+00 1.2E+01 1000 100
1.85E+00 1.2E+02 3.7E+00 1.2E+01
8.40E+01 1.7E+01 3.7E+00 1.2E+01
5.01 E+01 9.8E+01 3.7E+00 1.2E+01
6.65E+01 5.0E+01 3.7E+00 1.2E+01
2.15E+01 2.3E+01 3.7E+00 1.2E+01
5.34E+02 3.7E+00 3.7E+00 1.2E+01
2.68E+03 2.4E-02 3.7E+00 1.2E+01
4.37E+01 1.1 E+01 3.7E+00 1.2E+01
1.17E+02 5.5E+00 3.7E+00 1.2E+01
6.14E+01 5.9E+01 3.7E+00 1.2E+01 1000 100
1.85E+00 5.7E+02 3.7E+00 1.2E+01
6.82E+01 1.2E+01 3.7E+00 1.2E+01
4.26E+01 4.2E+01 3.7E+00 1.2E+01
1.88E+01 1.4E+02 3.7E+00 1.2E+01
2.11E+01 1.3E+02 3.7E+00 1.2E+01
5.74E+02 3.8E+00 3.7E+00 1.2E+01

3.39E+01 2.1 E+01 3.7E+00 1.2E+01
1.85E+00 1.7E+02 3.7E+00 1.2E+01
5.02E+00 2.1E+02 3.7E+00 1.2E+01
4.15E+00 8.8E+01 3.7E+00 1.2E+01
6.10E+00 5.6E+01 3.7E+00 1.2E+01
7.21E+00 4.2E+01 3.7E+00 1.2E+01
1.85E+00 8.4E+01 3.7E+00 1.2E+01
1.10E+01 9.3E+01 3.7E+00 1.2E+01
5.25E+00 4.3E+01 3.7E+00 1.2E+01
1.85E+00 2.6E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.14E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/1 1 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-428
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
SWA-L04-1313-T01-A
SWA-L04-1313-T02-A
SWA-L04-1313-T03-A
SWA-L04-1313-T04-A
SWA-L04-1313-T05-A
SWA-L04-1313-T06-A
SWA-L04-1313-T07-A
SWA-L04-1313-T08-A
SWA-L04-1313-T09-A
SWA-L04-1313-T10-A
SWA-L04-1313-T01-B
SWA-L04-1313-T02-B
SWA-L04-1313-T03-B
SWA-L04-1313-T04-B
SWA-L04-1313-T05-B
SWA-L04-1313-T06-B
SWA-L04-1313-T07-B
SWA-L04-1313-T08-B
SWA-L04-1313-T09-B
SWA-L04-1313-T10-B
SWA-L04-1313-T01-C
SWA-L04-1313-T02-C
SWA-L04-1313-T03-C
SWA-L04-1313-T04-C
SWA-L04-1313-T05-C
SWA-L04-1313-T06-C
SWA-L04-1313-T07-C
SWA-L04-1313-T08-C
SWA-L04-1313-T09-C
SWA-L04-1313-T10-C
SWA-L04-1313-B01-A
SWA-L04-1313-B02-A
SWA-L04-1313-B03-A
SWA-L04-1313-B01-B
SWA-L04-1313-B02-B
SWA-L04-1313-B03-B
SWA-L04-1313-B01-C
SWA-L04-1313-B02-C
SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.15E+06
1 3.16E+05
1 4.09E+05
1 4.23E+05
1 4.32E+05
1 4.70E+05
1 3.45E+05
1 2.07E+05

1 2.80E+05
1 2.17E+06
1 3.03E+05
1 4.02E+05
1 4.14E+05
1 4.24E+05
1 4.47E+05
1 4.65E+05
1 2.15E+05
1 6.23E+05
1 2.85E+05
1 2.14E+06
1 3.13E+05
1 4.10E+05
1 4.20E+05
1 4.25E+05
1 4.39E+05
1 4.81 E+05
1 2.35E+05

1 2.88E+05
1 2.91E+01
1 5.36E+01
1 2.03E+06
1 6.73E+01
1 2.93E+01
1 2.03E+06
1 5.39E+01
1 3.83E+01
1 2.02E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.15E+06 6.1E-01 1.6E+00 5.1E+00
3.16E+05 2.2E-01 1.6E+00 5.1E+00 1000 100
4.09E+05 7.8E-01 1.6E+00 5.1E+00
4.23E+05 2.2E+00 1.6E+00 5.1E+00
4.32E+05 4.4E-02 1.6E+00 5.1E+00
4.70E+05 2.5E+00 1.6E+00 5.1E+00
3.45E+05 6.5E+00 1.6E+00 5.1E+00
2.07E+05 2.9E+00 1.6E+00 5.1E+00

2.80E+05 6.4E-01 1.6E+00 5.1E+00
2.17E+06 1.0E+00 1.6E+00 5.1E+00
3.03E+05 4.7E-01 1.6E+00 5.1E+00 1000 100
4.02E+05 9.9E-01 1.6E+00 5.1E+00
4.14E+05 6.3E-01 1.6E+00 5.1E+00
4.24E+05 2.2E-01 1.6E+00 5.1E+00
4.47E+05 2.6E+00 1.6E+00 5.1E+00
4.65E+05 6.4E-01 1.6E+00 5.1E+00
2.15E+05 4.5E+00 1.6E+00 5.1E+00
6.23E+05 1.4E+01 1.6E+00 5.1E+00
2.85E+05 7.0E-01 1.6E+00 5.1E+00
2.14E+06 6.2E-01 1.6E+00 5.1E+00
3.13E+05 5.8E-01 1.6E+00 5.1E+00 1000 100
4.10E+05 1.8E+00 1.6E+00 5.1E+00
4.20E+05 2.8E+00 1.6E+00 5.1E+00
4.25E+05 9.1E-01 1.6E+00 5.1E+00
4.39E+05 1.4E-01 1.6E+00 5.1E+00
4.81 E+05 3.7E+00 1.6E+00 5.1E+00
2.35E+05 4.7E+00 1.6E+00 5.1E+00

2.88E+05 9.8E-01 1.6E+00 5.1E+00
2.91 E+01 7.0E+00 1.6E+00 5.1E+00
5.36E+01 4.7E+00 1.6E+00 5.1E+00
2.03E+06 9.7E-02 1.6E+00 5.1E+00
6.73E+01 7.2E-01 1.6E+00 5.1E+00
2.93E+01 8.0E+00 1.6E+00 5.1E+00
2.03E+06 5.5E-01 1.6E+00 5.1E+00
5.39E+01 1.1 E+01 1.6E+00 5.1E+00
3.83E+01 3.1E+00 1.6E+00 5.1E+00
2.02E+06 6.5E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.17E+05 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
3.04E+05 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.14E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-429
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
SWA-L04-1313-T01-A
SWA-L04-1313-T02-A
SWA-L04-1313-T03-A
SWA-L04-1313-T04-A
SWA-L04-1313-T05-A
SWA-L04-1313-T06-A
SWA-L04-1313-T07-A
SWA-L04-1313-T08-A
SWA-L04-1313-T09-A
SWA-L04-1313-T10-A
SWA-L04-1313-T01-B
SWA-L04-1313-T02-B
SWA-L04-1313-T03-B
SWA-L04-1313-T04-B
SWA-L04-1313-T05-B
SWA-L04-1313-T06-B
SWA-L04-1313-T07-B
SWA-L04-1313-T08-B
SWA-L04-1313-T09-B
SWA-L04-1313-T10-B
SWA-L04-1313-T01-C
SWA-L04-1313-T02-C
SWA-L04-1313-T03-C
SWA-L04-1313-T04-C
SWA-L04-1313-T05-C
SWA-L04-1313-T06-C
SWA-L04-1313-T07-C
SWA-L04-1313-T08-C
SWA-L04-1313-T09-C
SWA-L04-1313-T10-C
SWA-L04-1313-B01-A
SWA-L04-1313-B02-A
SWA-L04-1313-B03-A
SWA-L04-1313-B01-B
SWA-L04-1313-B02-B
SWA-L04-1313-B03-B
SWA-L04-1313-B01-C
SWA-L04-1313-B02-C
SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 8.84E+04
1 8.67E+04
1 9.65E+04
1 1.13E+05
1 1.16E+05
1 1.22E+05
1 7.60E+04
1 4.03E+04

1 8.22E+04
1 7.56E+04
1 8.60E+04
1 9.70E+04
1 1.10E+05
1 1.16E+05
1 1.20E+05
1 1.14E+05
1 4.16E+04
1 6.28E+04
1 9.21 E+04
1 7.75E+04
1 9.81 E+04
1 9.98E+04
1 1.15E+05
1 1.18E+05
1 1.21E+05
1 1.19E+05
1 4.91 E+04

1 9.25E+04
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.84E+04 2.6E-01 1.5E+01 4.8E+01
8.67E+04 4.4E-01 1.5E+01 4.8E+01 10 100
9.65E+04 5.7E-01 1.5E+01 4.8E+01
1.13E+05 8.0E-01 1.5E+01 4.8E+01
1.16E+05 3.1E-02 1.5E+01 4.8E+01
1.22E+05 1.7E-01 1.5E+01 4.8E+01
7.60E+04 4.8E-01 1.5E+01 4.8E+01
4.03E+04 3.6E-02 1.5E+01 4.8E+01

8.22E+04 8.4E-01 1.5E+01 4.8E+01
7.56E+04 9.9E-01 1.5E+01 4.8E+01
8.60E+04 1.1E-01 1.5E+01 4.8E+01 10 100
9.70E+04 9.3E-01 1.5E+01 4.8E+01
1.10E+05 5.8E-01 1.5E+01 4.8E+01
1.16E+05 6.3E-01 1.5E+01 4.8E+01
1.20E+05 7.0E-02 1.5E+01 4.8E+01
1.14E+05 1.1E+00 1.5E+01 4.8E+01
4.16E+04 6.3E-01 1.5E+01 4.8E+01
6.28E+04 6.4E-01 1.5E+01 4.8E+01
9.21 E+04 3.0E-01 1.5E+01 4.8E+01
7.75E+04 1.1E+00 1.5E+01 4.8E+01
9.81E+04 9.0E-01 1.5E+01 4.8E+01 10 100
9.98E+04 6.7E-01 1.5E+01 4.8E+01
1.15E+05 6.6E-01 1.5E+01 4.8E+01
1.18E+05 7.8E-01 1.5E+01 4.8E+01
1.21E+05 7.4E-01 1.5E+01 4.8E+01
1.19E+05 1.5E+00 1.5E+01 4.8E+01
4.91 E+04 4.7E-01 1.5E+01 4.8E+01

9.25E+04 9.3E-01 1.5E+01 4.8E+01
7.50E+00 8.3E+02 1.5E+01 4.8E+01
7.50E+00 1.2E+02 1.5E+01 4.8E+01
7.50E+00 1.7E+02 1.5E+01 4.8E+01
7.50E+00 3.5E+01 1.5E+01 4.8E+01
7.50E+00 6.5E+01 1.5E+01 4.8E+01
7.50E+00 3.8E+01 1.5E+01 4.8E+01
7.50E+00 3.4E+03 1.5E+01 4.8E+01
7.50E+00 1.1E+02 1.5E+01 4.8E+01
7.50E+00 2.9E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.76E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
8.69E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.90E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-430
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si SWA-L04-1313-T01-A
Si SWA-L04-1313-T02-A
Si SWA-L04-1313-T03-A
Si SWA-L04-1313-T04-A
Si SWA-L04-1313-T05-A
Si SWA-L04-1313-T06-A
Si SWA-L04-1313-T07-A
Si SWA-L04-1313-T08-A
Si SWA-L04-1313-T09-A
Si SWA-L04-1313-T10-A
Si SWA-L04-1313-T01-B
Si SWA-L04-1313-T02-B
Si SWA-L04-1313-T03-B
Si SWA-L04-1313-T04-B
Si SWA-L04-1313-T05-B
Si SWA-L04-1313-T06-B
Si SWA-L04-1313-T07-B
Si SWA-L04-1313-T08-B
Si SWA-L04-1313-T09-B
Si SWA-L04-1313-T10-B
Si SWA-L04-1313-T01-C
Si SWA-L04-1313-T02-C
Si SWA-L04-1313-T03-C
Si SWA-L04-1313-T04-C
Si SWA-L04-1313-T05-C
Si SWA-L04-1313-T06-C
Si SWA-L04-1313-T07-C
Si SWA-L04-1313-T08-C
Si SWA-L04-1313-T09-C
Si SWA-L04-1313-T10-C
Si SWA-L04-1313-B01-A
Si SWA-L04-1313-B02-A
Si SWA-L04-1313-B03-A
Si SWA-L04-1313-B01-B
Si SWA-L04-1313-B02-B
Si SWA-L04-1313-B03-B
Si SWA-L04-1313-B01-C
Si SWA-L04-1313-B02-C
Si SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.97E+04
1 1.87E+04
1 5.29E+03
1 4.48E+03
1 5.28E+03
1 8.00E+03
1 8.63E+03
1 1.74E+04

1 2.49E+04
1 3.65E+04
1 1.97E+04
1 5.07E+03
1 4.89E+03
1 4.49E+03
1 5.66E+03
1 8.54E+03
1 2.55E+04
1 4.95E+04
1 2.75E+04
1 3.71 E+04
1 2.22E+04
1 6.18E+03
1 4.97E+03
1 5.05E+03
1 6.72E+03
1 7.78E+03
1 2.44E+04

1 2.78E+04
1 3.21 E+00 E
1 1.61E+01
1 3.15E+01
1 1.98E+01
1 1.36E+01
1 4.50E+01
1 3.94E+01
1 1.11E+01
1 2.33E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.97E+04 8.4E-01 1.1E+00 3.5E+00
1.87E+04 8.0E-01 1.1 E+00 3.5E+00 1000 100
5.29E+03 5.2E-01 1.1 E+00 3.5E+00
4.48E+03 9.5E-01 1.1 E+00 3.5E+00
5.28E+03 7.5E-01 1.1 E+00 3.5E+00
8.00E+03 2.7E-01 1.1 E+00 3.5E+00
8.63E+03 2.4E-01 1.1 E+00 3.5E+00
1.74E+04 3.2E-01 1.1 E+00 3.5E+00

2.49E+04 6.0E-01 1.1 E+00 3.5E+00
3.65E+04 1.9E+00 1.1 E+00 3.5E+00
1.97E+04 4.6E-01 1.1 E+00 3.5E+00 1000 100
5.07E+03 8.1E-01 1.1 E+00 3.5E+00
4.89E+03 3.6E-01 1.1 E+00 3.5E+00
4.49E+03 7.3E-01 1.1 E+00 3.5E+00
5.66E+03 3.1E-01 1.1 E+00 3.5E+00
8.54E+03 9.1E-01 1.1 E+00 3.5E+00
2.55E+04 5.8E-01 1.1 E+00 3.5E+00
4.95E+04 5.5E-01 1.1 E+00 3.5E+00
2.75E+04 1.1 E+00 1.1 E+00 3.5E+00
3.71E+04 2.9E-01 1.1 E+00 3.5E+00
2.22E+04 5.7E-01 1.1 E+00 3.5E+00 1000 100
6.18E+03 5.5E-01 1.1 E+00 3.5E+00
4.97E+03 3.5E-01 1.1 E+00 3.5E+00
5.05E+03 6.3E-01 1.1 E+00 3.5E+00
6.72E+03 7.2E-01 1.1 E+00 3.5E+00
7.78E+03 5.8E-01 1.1 E+00 3.5E+00
2.44E+04 4.3E-01 1.1 E+00 3.5E+00

2.78E+04 1.2E+00 1.1 E+00 3.5E+00
3.21E+00 9.0E+01 1.1 E+00 3.5E+00
1.61E+01 4.3E+00 1.1 E+00 3.5E+00
3.15E+01 5.4E+00 1.1 E+00 3.5E+00
1.98E+01 2.2E+01 1.1 E+00 3.5E+00
1.36E+01 4.7E+01 1.1 E+00 3.5E+00
4.50E+01 2.5E+00 1.1 E+00 3.5E+00
3.94E+01 6.0E+00 1.1 E+00 3.5E+00
1.11E+01 5.3E+00 1.1 E+00 3.5E+00
2.33E+01 2.7E+00 1.1 E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.97E+04 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
2.06E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.31 E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-431
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na SWA-L04-1313-T01-A
Na SWA-L04-1313-T02-A
Na SWA-L04-1313-T03-A
Na SWA-L04-1313-T04-A
Na SWA-L04-1313-T05-A
Na SWA-L04-1313-T06-A
Na SWA-L04-1313-T07-A
Na SWA-L04-1313-T08-A
Na SWA-L04-1313-T09-A
Na SWA-L04-1313-T10-A
Na SWA-L04-1313-T01-B
Na SWA-L04-1313-T02-B
Na SWA-L04-1313-T03-B
Na SWA-L04-1313-T04-B
Na SWA-L04-1313-T05-B
Na SWA-L04-1313-T06-B
Na SWA-L04-1313-T07-B
Na SWA-L04-1313-T08-B
Na SWA-L04-1313-T09-B
Na SWA-L04-1313-T10-B
Na SWA-L04-1313-T01-C
Na SWA-L04-1313-T02-C
Na SWA-L04-1313-T03-C
Na SWA-L04-1313-T04-C
Na SWA-L04-1313-T05-C
Na SWA-L04-1313-T06-C
Na SWA-L04-1313-T07-C
Na SWA-L04-1313-T08-C
Na SWA-L04-1313-T09-C
Na SWA-L04-1313-T10-C
Na SWA-L04-1313-B01-A
Na SWA-L04-1313-B02-A
Na SWA-L04-1313-B03-A
Na SWA-L04-1313-B01-B
Na SWA-L04-1313-B02-B
Na SWA-L04-1313-B03-B
Na SWA-L04-1313-B01-C
Na SWA-L04-1313-B02-C
Na SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.02E+05
1 4.21 E+05
1 4.30E+05
1 4.13E+05
1 4.07E+05
1 4.02E+05
1 4.02E+05
1 4.02E+05

1 3.95E+05
1 3.94E+05
1 4.14E+05
1 4.23E+05
1 4. 11 E+05
1 4.09E+05
1 4.06E+05
1 3.98E+05
1 3.97E+05
1 7.88E+05
1 3.97E+05
1 3.95E+05
1 4.23E+05
1 4.28E+05
1 4.15E+05
1 4.03E+05
1 4.01 E+05
1 3.99E+05
1 3.97E+05

1 4.00E+05
1 5.79E+00 E
1 7.61 E+00 E
1 5.61 E+02
1 3.96E+00 E
1 6.57E+00 E
1 5.59E+02
1 6.36E+00 E
1 2.96E+00 E
1 5.77E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.02E+05 1.2E-01 2.5E+00 8.0E+00
4.21E+05 5.4E-01 2.5E+00 8.0E+00 1000 100
4.30E+05 1.5E-01 2.5E+00 8.0E+00
4.13E+05 2.0E-01 2.5E+00 8.0E+00
4.07E+05 8.4E-02 2.5E+00 8.0E+00
4.02E+05 5.3E-01 2.5E+00 8.0E+00
4.02E+05 3.9E-01 2.5E+00 8.0E+00
4.02E+05 5.7E-01 2.5E+00 8.0E+00

3.95E+05 1.3E-01 2.5E+00 8.0E+00
3.94E+05 3.1E-01 2.5E+00 8.0E+00
4.14E+05 2.7E-01 2.5E+00 8.0E+00 1000 100
4.23E+05 1.6E-01 2.5E+00 8.0E+00
4.11E+05 5.7E-01 2.5E+00 8.0E+00
4.09E+05 5.2E-01 2.5E+00 8.0E+00
4.06E+05 1.5E-01 2.5E+00 8.0E+00
3.98E+05 2.8E-01 2.5E+00 8.0E+00
3.97E+05 6.6E-01 2.5E+00 8.0E+00
7.88E+05 1.8E-01 2.5E+00 8.0E+00
3.97E+05 9.1E-02 2.5E+00 8.0E+00
3.95E+05 3.2E-01 2.5E+00 8.0E+00
4.23E+05 1.0E-01 2.5E+00 8.0E+00 1000 100
4.28E+05 6.3E-01 2.5E+00 8.0E+00
4.15E+05 8.8E-01 2.5E+00 8.0E+00
4.03E+05 2.4E-01 2.5E+00 8.0E+00
4.01 E+05 2.0E-01 2.5E+00 8.0E+00
3.99E+05 3.7E-01 2.5E+00 8.0E+00
3.97E+05 9.6E-01 2.5E+00 8.0E+00

4.00E+05 3.9E-01 2.5E+00 8.0E+00
5.79E+00 3.9E+01 2.5E+00 8.0E+00
7.61 E+00 2.7E+01 2.5E+00 8.0E+00
5.61 E+02 2.4E-01 2.5E+00 8.0E+00
3.96E+00 1.4E+00 2.5E+00 8.0E+00
6.57E+00 4.9E+01 2.5E+00 8.0E+00
5.59E+02 6.6E-01 2.5E+00 8.0E+00
6.36E+00 1.8E+01 2.5E+00 8.0E+00
2.96E+00 9.1E+01 2.5E+00 8.0E+00
5.77E+02 4.1E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.22E+05 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
4.15E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.24E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-432
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr SWA-L04-1313-T01-A
Sr SWA-L04-1313-T02-A
Sr SWA-L04-1313-T03-A
Sr SWA-L04-1313-T04-A
Sr SWA-L04-1313-T05-A
Sr SWA-L04-1313-T06-A
Sr SWA-L04-1313-T07-A
Sr SWA-L04-1313-T08-A
Sr SWA-L04-1313-T09-A
Sr SWA-L04-1313-T10-A
Sr SWA-L04-1313-T01-B
Sr SWA-L04-1313-T02-B
Sr SWA-L04-1313-T03-B
Sr SWA-L04-1313-T04-B
Sr SWA-L04-1313-T05-B
Sr SWA-L04-1313-T06-B
Sr SWA-L04-1313-T07-B
Sr SWA-L04-1313-T08-B
Sr SWA-L04-1313-T09-B
Sr SWA-L04-1313-T10-B
Sr SWA-L04-1313-T01-C
Sr SWA-L04-1313-T02-C
Sr SWA-L04-1313-T03-C
Sr SWA-L04-1313-T04-C
Sr SWA-L04-1313-T05-C
Sr SWA-L04-1313-T06-C
Sr SWA-L04-1313-T07-C
Sr SWA-L04-1313-T08-C
Sr SWA-L04-1313-T09-C
Sr SWA-L04-1313-T10-C
Sr SWA-L04-1313-B01-A
Sr SWA-L04-1313-B02-A
Sr SWA-L04-1313-B03-A
Sr SWA-L04-1313-B01-B
Sr SWA-L04-1313-B02-B
Sr SWA-L04-1313-B03-B
Sr SWA-L04-1313-B01-C
Sr SWA-L04-1313-B02-C
Sr SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.01 E+02
1 8.07E+02
1 2.05E+04
1 3.33E+04
1 4.11E+04
1 4.99E+04
1 3.86E+04
1 2.30E+04

1 3.28E+02
1 3.06E+02
1 7.57E+02
1 2.00E+04
1 3.43E+04
1 3.69E+04
1 4.35E+04
1 5.13E+04
1 2.36E+04
1 4.09E+04
1 2.99E+02
1 3.09E+02
1 6.58E+02
1 1.90E+04
1 3.14E+04
1 4.14E+04
1 4.47E+04
1 5.15E+04
1 2.61E+04

1 3.03E+02
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.33E+00 E
1 5.00E-01 U1/2
1 3.63E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.01 E+02 3.2E-01 1.0E+00 3.2E+00
8.07E+02 1.2E+00 1.0E+00 3.2E+00 1000 100
2.05E+04 3.5E-01 1.0E+00 3.2E+00
3.33E+04 1.1E+00 1.0E+00 3.2E+00
4.11E+04 1.1E+00 1.0E+00 3.2E+00
4.99E+04 6.6E-01 1.0E+00 3.2E+00
3.86E+04 1.7E-01 1.0E+00 3.2E+00
2.30E+04 1.1E+00 1.0E+00 3.2E+00

3.28E+02 1.4E+00 1.0E+00 3.2E+00
3.06E+02 8.4E-01 1.0E+00 3.2E+00
7.57E+02 2.8E-01 1.0E+00 3.2E+00 1000 100
2.00E+04 6.8E-01 1.0E+00 3.2E+00
3.43E+04 5.7E-01 1.0E+00 3.2E+00
3.69E+04 9.5E-01 1.0E+00 3.2E+00
4.35E+04 1.2E+00 1.0E+00 3.2E+00
5.13E+04 1.3E+00 1.0E+00 3.2E+00
2.36E+04 1.0E+00 1.0E+00 3.2E+00
4.09E+04 5.9E-01 1.0E+00 3.2E+00
2.99E+02 5.2E-01 1.0E+00 3.2E+00
3.09E+02 9.1E-01 1.0E+00 3.2E+00
6.58E+02 1.2E+00 1.0E+00 3.2E+00 1000 100
1.90E+04 1.3E+00 1.0E+00 3.2E+00
3.14E+04 9.9E-01 1.0E+00 3.2E+00
4.14E+04 9.9E-01 1.0E+00 3.2E+00
4.47E+04 1.6E-01 1.0E+00 3.2E+00
5.15E+04 6.9E-01 1.0E+00 3.2E+00
2.61 E+04 6.6E-01 1.0E+00 3.2E+00

3.03E+02 1.6E+00 1.0E+00 3.2E+00
5.00E-01 3.0E+01 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
5.00E-01 5.9E+01 1.0E+00 3.2E+00
1.33E+00 1.7E+01 1.0E+00 3.2E+00
5.00E-01 8.5E+01 1.0E+00 3.2E+00
3.63E+00 1.3E+01 1.0E+00 3.2E+00
5.00E-01 2.3E+01 1.0E+00 3.2E+00
5.00E-01 4.3E+01 1.0E+00 3.2E+00
5.00E-01 2.0E+03 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.88E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.86E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.79E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-433
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S SWA-L04-1313-T01-A
S SWA-L04-1313-T02-A
S SWA-L04-1313-T03-A
S SWA-L04-1313-T04-A
S SWA-L04-1313-T05-A
S SWA-L04-1313-T06-A
S SWA-L04-1313-T07-A
S SWA-L04-1313-T08-A
S SWA-L04-1313-T09-A
S SWA-L04-1313-T10-A
S SWA-L04-1313-T01-B
S SWA-L04-1313-T02-B
S SWA-L04-1313-T03-B
S SWA-L04-1313-T04-B
S SWA-L04-1313-T05-B
S SWA-L04-1313-T06-B
S SWA-L04-1313-T07-B
S SWA-L04-1313-T08-B
S SWA-L04-1313-T09-B
S SWA-L04-1313-T10-B
S SWA-L04-1313-T01-C
S SWA-L04-1313-T02-C
S SWA-L04-1313-T03-C
S SWA-L04-1313-T04-C
S SWA-L04-1313-T05-C
S SWA-L04-1313-T06-C
S SWA-L04-1313-T07-C
S SWA-L04-1313-T08-C
S SWA-L04-1313-T09-C
S SWA-L04-1313-T10-C
S SWA-L04-1313-B01-A
S SWA-L04-1313-B02-A
S SWA-L04-1313-B03-A
S SWA-L04-1313-B01-B
S SWA-L04-1313-B02-B
S SWA-L04-1313-B03-B
S SWA-L04-1313-B01-C
S SWA-L04-1313-B02-C
S SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.54E+05
1 2.98E+05
1 3.31 E+05
1 4.24E+05
1 4.65E+05
1 5.14E+05
1 3.48E+05
1 1.94E+05

1 3.62E+05
1 3.30E+05
1 3.16E+05
1 3.44E+05
1 4. 17 E+05
1 4.61 E+05
1 4.84E+05
1 4.91 E+05
1 2.01 E+05
1 3.18E+05
1 3.46E+05
1 3.81 E+05
1 3.71 E+05
1 3.62E+05
1 4.35E+05
1 4.75E+05
1 4.94E+05
1 5.06E+05
1 2.28E+05

1 3.51 E+05
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 2.32E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 2.44E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.54E+05 4.5E-01 6.8E+00 2.2E+01
2.98E+05 6.4E-02 6.8E+00 2.2E+01 1000 100
3.31 E+05 3.0E-01 6.8E+00 2.2E+01
4.24E+05 7.7E-01 6.8E+00 2.2E+01
4.65E+05 4.2E-01 6.8E+00 2.2E+01
5.14E+05 3.3E-01 6.8E+00 2.2E+01
3.48E+05 6.7E-01 6.8E+00 2.2E+01
1.94E+05 6.1E-01 6.8E+00 2.2E+01

3.62E+05 9.2E-01 6.8E+00 2.2E+01
3.30E+05 1.1E+00 6.8E+00 2.2E+01
3.16E+05 5.1E-01 6.8E+00 2.2E+01 1000 100
3.44E+05 4.6E-01 6.8E+00 2.2E+01
4.17E+05 5.7E-01 6.8E+00 2.2E+01
4.61 E+05 3.7E-01 6.8E+00 2.2E+01
4.84E+05 4.1E-01 6.8E+00 2.2E+01
4.91 E+05 1.1E+00 6.8E+00 2.2E+01
2.01 E+05 5.8E-01 6.8E+00 2.2E+01
3.18E+05 4.9E-01 6.8E+00 2.2E+01
3.46E+05 7.4E-01 6.8E+00 2.2E+01
3.81 E+05 5.4E-01 6.8E+00 2.2E+01
3.71E+05 7.4E-01 6.8E+00 2.2E+01 1000 100
3.62E+05 5.9E-01 6.8E+00 2.2E+01
4.35E+05 3.8E-01 6.8E+00 2.2E+01
4.75E+05 8.5E-01 6.8E+00 2.2E+01
4.94E+05 5.7E-01 6.8E+00 2.2E+01
5.06E+05 1.3E+00 6.8E+00 2.2E+01
2.28E+05 4.3E-01 6.8E+00 2.2E+01

3.51 E+05 2.0E-01 6.8E+00 2.2E+01
3.40E+00 3.9E+00 6.8E+00 2.2E+01
3.40E+00 3.2E+00 6.8E+00 2.2E+01
2.32E+02 5.3E-01 6.8E+00 2.2E+01
3.40E+00 1.2E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+01 6.8E+00 2.2E+01
2.44E+02 4.3E+00 6.8E+00 2.2E+01
3.40E+00 3.3E-01 6.8E+00 2.2E+01
3.40E+00 1.9E+00 6.8E+00 2.2E+01
3.40E+00 7.4E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.99E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
3.17E+05 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.72E+05 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-434
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample Dilutic
SWA-L04-1313-T01-A
SWA-L04-1313-T02-A
SWA-L04-1313-T03-A
SWA-L04-1313-T04-A
SWA-L04-1313-T05-A
SWA-L04-1313-T06-A
SWA-L04-1313-T07-A
SWA-L04-1313-T08-A
SWA-L04-1313-T09-A
SWA-L04-1313-T10-A
SWA-L04-1313-T01-B
SWA-L04-1313-T02-B
SWA-L04-1313-T03-B
SWA-L04-1313-T04-B
SWA-L04-1313-T05-B
SWA-L04-1313-T06-B
SWA-L04-1313-T07-B
SWA-L04-1313-T08-B
SWA-L04-1313-T09-B
SWA-L04-1313-T10-B
SWA-L04-1313-T01-C
SWA-L04-1313-T02-C
SWA-L04-1313-T03-C
SWA-L04-1313-T04-C
SWA-L04-1313-T05-C
SWA-L04-1313-T06-C
SWA-L04-1313-T07-C
SWA-L04-1313-T08-C
SWA-L04-1313-T09-C
SWA-L04-1313-T10-C
SWA-L04-1313-B01-A
SWA-L04-1313-B02-A
SWA-L04-1313-B03-A
SWA-L04-1313-B01-B
SWA-L04-1313-B02-B
SWA-L04-1313-B03-B
SWA-L04-1313-B01-C
SWA-L04-1313-B02-C
SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 8.45E+00 E
1 1.53E+01
1 2.09E+01
1 1.14E+01 E

1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 8.16E+00 E
1 6.83E+00 E
1 3.01 E+01
1 7.99E+00 E
1 2.68E+01
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 8.41 E+00 E
1 1.23E+01 E
1 2.56E+01
1 1.27E+01 E

1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 4.4E+01 4.6E+00 1.5E+01
2.30E+00 1.9E+02 4.6E+00 1.5E+01 10 100
2.30E+00 3.3E+02 4.6E+00 1.5E+01
2.30E+00 1.6E+02 4.6E+00 1.5E+01
8.45E+00 5.8E+01 4.6E+00 1.5E+01
1.53E+01 4.4E+01 4.6E+00 1.5E+01
2.09E+01 7.1 E+01 4.6E+00 1.5E+01
1.14E+01 4.3E+01 4.6E+00 1.5E+01

2.30E+00 9.8E+01 4.6E+00 1.5E+01
2.30E+00 6.1E+02 4.6E+00 1.5E+01
2.30E+00 1.7E+03 4.6E+00 1.5E+01 10 100
2.30E+00 8.1 E+01 4.6E+00 1.5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
8.16E+00 9.2E+01 4.6E+00 1.5E+01
6.83E+00 9.7E+01 4.6E+00 1.5E+01
3.01 E+01 1.5E+01 4.6E+00 1.5E+01
7.99E+00 5.0E+01 4.6E+00 1.5E+01
2.68E+01 2.3E+01 4.6E+00 1.5E+01
2.30E+00 2.4E+02 4.6E+00 1.5E+01
2.30E+00 1.7E+02 4.6E+00 1.5E+01
2.30E+00 2.8E+01 4.6E+00 1.5E+01 10 100
2.30E+00 7.8E+02 4.6E+00 1.5E+01
2.30E+00 6.4E+02 4.6E+00 1.5E+01
8.41 E+00 1.0E+02 4.6E+00 1.5E+01
1.23E+01 5.4E+01 4.6E+00 1.5E+01
2.56E+01 3.9E+01 4.6E+00 1.5E+01
1.27E+01 6.3E+01 4.6E+00 1.5E+01

2.30E+00 3.8E+03 4.6E+00 1.5E+01
2.30E+00 3.5E+01 4.6E+00 1.5E+01
2.30E+00 7.2E+01 4.6E+00 1.5E+01
2.30E+00 4.1E+01 4.6E+00 1.5E+01
2.30E+00 3.0E+01 4.6E+00 1.5E+01
2.30E+00 2.8E+01 4.6E+00 1.5E+01
2.30E+00 3.3E+01 4.6E+00 1.5E+01
2.30E+00 5.3E+02 4.6E+00 1.5E+01
2.30E+00 6.6E+01 4.6E+00 1.5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/1 1 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-435
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutic
SWA-L04-1313-T01-A
SWA-L04-1313-T02-A
SWA-L04-1313-T03-A
SWA-L04-1313-T04-A
SWA-L04-1313-T05-A
SWA-L04-1313-T06-A
SWA-L04-1313-T07-A
SWA-L04-1313-T08-A
SWA-L04-1313-T09-A
SWA-L04-1313-T10-A
SWA-L04-1313-T01-B
SWA-L04-1313-T02-B
SWA-L04-1313-T03-B
SWA-L04-1313-T04-B
SWA-L04-1313-T05-B
SWA-L04-1313-T06-B
SWA-L04-1313-T07-B
SWA-L04-1313-T08-B
SWA-L04-1313-T09-B
SWA-L04-1313-T10-B
SWA-L04-1313-T01-C
SWA-L04-1313-T02-C
SWA-L04-1313-T03-C
SWA-L04-1313-T04-C
SWA-L04-1313-T05-C
SWA-L04-1313-T06-C
SWA-L04-1313-T07-C
SWA-L04-1313-T08-C
SWA-L04-1313-T09-C
SWA-L04-1313-T10-C
SWA-L04-1313-B01-A
SWA-L04-1313-B02-A
SWA-L04-1313-B03-A
SWA-L04-1313-B01-B
SWA-L04-1313-B02-B
SWA-L04-1313-B03-B
SWA-L04-1313-B01-C
SWA-L04-1313-B02-C
SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.93E+00 E
1 1.02E+01

1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.96E+01
1 4.67E+02
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.41E+01

1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.7E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00 10 100
1.00E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 7.5E+01 2.0E+00 6.4E+00
2.93E+00 6.2E+00 2.0E+00 6.4E+00
1.02E+01 2.2E+00 2.0E+00 6.4E+00

1.00E+00 6.5E+01 2.0E+00 6.4E+00
1.00E+00 6.8E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00 10 100
1.00E+00 4.3E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.96E+01 4.2E+00 2.0E+00 6.4E+00
4.67E+02 4.7E-01 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00
1.00E+00 5.4E+01 2.0E+00 6.4E+00 10 100
1.00E+00 8.0E+02 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 5.9E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
2.41E+01 1.1E+00 2.0E+00 6.4E+00

1.00E+00 4.7E+01 2.0E+00 6.4E+00
1.00E+00 6.2E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 6.3E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 9.5E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
1.00E+00 8.0E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.14E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.16E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/1 1 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:13 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:15 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:16 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:18 PM EPA Interlab L04 131 3-1 31 6 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-436
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V SWA-L04-1313-T01-A
V SWA-L04-1313-T02-A
V SWA-L04-1313-T03-A
V SWA-L04-1313-T04-A
V SWA-L04-1313-T05-A
V SWA-L04-1313-T06-A
V SWA-L04-1313-T07-A
V SWA-L04-1313-T08-A
V SWA-L04-1313-T09-A
V SWA-L04-1313-T10-A
V SWA-L04-1313-T01-B
V SWA-L04-1313-T02-B
V SWA-L04-1313-T03-B
V SWA-L04-1313-T04-B
V SWA-L04-1313-T05-B
V SWA-L04-1313-T06-B
V SWA-L04-1313-T07-B
V SWA-L04-1313-T08-B
V SWA-L04-1313-T09-B
V SWA-L04-1313-T10-B
V SWA-L04-1313-T01-C
V SWA-L04-1313-T02-C
V SWA-L04-1313-T03-C
V SWA-L04-1313-T04-C
V SWA-L04-1313-T05-C
V SWA-L04-1313-T06-C
V SWA-L04-1313-T07-C
V SWA-L04-1313-T08-C
V SWA-L04-1313-T09-C
V SWA-L04-1313-T10-C
V SWA-L04-1313-B01-A
V SWA-L04-1313-B02-A
V SWA-L04-1313-B03-A
V SWA-L04-1313-B01-B
V SWA-L04-1313-B02-B
V SWA-L04-1313-B03-B
V SWA-L04-1313-B01-C
V SWA-L04-1313-B02-C
V SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.69E+02
1 1.81E+02
1 1.54E+02
1 2.39E+02
1 2.13E+02
1 2.36E+02
1 1.35E+02
1 8.33E+01

1 3.12E+02
1 4.00E+02
1 1.89E+02
1 1.53E+02
1 2.17E+02
1 2.14E+02
1 2.21 E+02
1 2. 11 E+02
1 8.46E+01
1 1.08E+03
1 3.75E+02
1 4.05E+02
1 2.47E+02
1 1.51 E+02
1 2.30E+02
1 2.15E+02
1 2.19E+02
1 2.14E+02
1 8.66E+01

1 3.77E+02
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.69E+02 9.4E-01 1.5E+00 4.8E+00
1.81 E+02 8.4E-01 1.5E+00 4.8E+00 10 100
1.54E+02 1.5E+00 1.5E+00 4.8E+00
2.39E+02 1.5E+00 1.5E+00 4.8E+00
2.13E+02 7.1E-01 1.5E+00 4.8E+00
2.36E+02 1.2E+00 1.5E+00 4.8E+00
1.35E+02 5.2E-01 1.5E+00 4.8E+00
8.33E+01 2.6E-01 1.5E+00 4.8E+00

3.12E+02 5.9E-01 1.5E+00 4.8E+00
4.00E+02 1.7E+00 1.5E+00 4.8E+00
1.89E+02 1.3E-01 1.5E+00 4.8E+00 10 100
1.53E+02 4.5E-01 1.5E+00 4.8E+00
2.17E+02 7.5E-01 1.5E+00 4.8E+00
2.14E+02 2.1E+00 1.5E+00 4.8E+00
2.21 E+02 4.4E-01 1.5E+00 4.8E+00
2.11E+02 2.7E+00 1.5E+00 4.8E+00
8.46E+01 1.7E+00 1.5E+00 4.8E+00
1.08E+03 4.7E-01 1.5E+00 4.8E+00
3.75E+02 9.5E-01 1.5E+00 4.8E+00
4.05E+02 2.9E-01 1.5E+00 4.8E+00
2.47E+02 1.9E+00 1.5E+00 4.8E+00 10 100
1.51 E+02 2.1E+00 1.5E+00 4.8E+00
2.30E+02 9.1E-01 1.5E+00 4.8E+00
2.15E+02 9.7E-01 1.5E+00 4.8E+00
2.19E+02 3.3E-01 1.5E+00 4.8E+00
2.14E+02 1.7E+00 1.5E+00 4.8E+00
8.66E+01 1.6E+00 1.5E+00 4.8E+00

3.77E+02 8.3E-01 1.5E+00 4.8E+00
7.50E-01 1.8E+01 1.5E+00 4.8E+00
7.50E-01 1.7E+03 1.5E+00 4.8E+00
7.50E-01 2.8E+02 1.5E+00 4.8E+00
7.50E-01 4.7E+01 1.5E+00 4.8E+00
7.50E-01 3.2E+02 1.5E+00 4.8E+00
7.50E-01 1.5E+02 1.5E+00 4.8E+00
7.50E-01 1.7E+01 1.5E+00 4.8E+00
7.50E-01 1.5E+02 1.5E+00 4.8E+00
7.50E-01 5.2E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.31E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.35E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.43E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-437
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn SWA-L04-1313-T01-A
Zn SWA-L04-1313-T02-A
Zn SWA-L04-1313-T03-A
Zn SWA-L04-1313-T04-A
Zn SWA-L04-1313-T05-A
Zn SWA-L04-1313-T06-A
Zn SWA-L04-1313-T07-A
Zn SWA-L04-1313-T08-A
Zn SWA-L04-1313-T09-A
Zn SWA-L04-1313-T10-A
Zn SWA-L04-1313-T01-B
Zn SWA-L04-1313-T02-B
Zn SWA-L04-1313-T03-B
Zn SWA-L04-1313-T04-B
Zn SWA-L04-1313-T05-B
Zn SWA-L04-1313-T06-B
Zn SWA-L04-1313-T07-B
Zn SWA-L04-1313-T08-B
Zn SWA-L04-1313-T09-B
Zn SWA-L04-1313-T10-B
Zn SWA-L04-1313-T01-C
Zn SWA-L04-1313-T02-C
Zn SWA-L04-1313-T03-C
Zn SWA-L04-1313-T04-C
Zn SWA-L04-1313-T05-C
Zn SWA-L04-1313-T06-C
Zn SWA-L04-1313-T07-C
Zn SWA-L04-1313-T08-C
Zn SWA-L04-1313-T09-C
Zn SWA-L04-1313-T10-C
Zn SWA-L04-1313-B01-A
Zn SWA-L04-1313-B02-A
Zn SWA-L04-1313-B03-A
Zn SWA-L04-1313-B01-B
Zn SWA-L04-1313-B02-B
Zn SWA-L04-1313-B03-B
Zn SWA-L04-1313-B01-C
Zn SWA-L04-1313-B02-C
Zn SWA-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.25E+00
1 3.53E+00
1 2.63E+00 E
1 3.15E+00 E
1 6.43E+00
1 9.22E+01
1 6.70E+02
1 1.41E+03

1 2.25E+00 E
1 3.30E+00
1 2.27E+00 E
1 2.74E+00 E
1 3.16E+00 E
1 3.82E+00
1 7.23E+00
1 4.75E+02
1 1.37E+03
1 3.72E+03
1 2.50E+00 E
1 3.98E+00
1 2.50E+00 E
1 2.76E+00 E
1 3.07E+00 E
1 4.22E+00
1 1.43E+01
1 3.64E+02
1 1.08E+03

1 2.80E+00 E
1 2.81 E+00 E
1 2.84E+00 E
1 3.19E+00
1 1.18E+00 E
1 2.24E+00 E
1 3.08E+00 E
1 2.49E+00 E
1 2.73E+00 E
1 2.81 E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.25E+00 1.3E+01 1.0E+00 3.2E+00
3.53E+00 6.0E+00 1.0E+00 3.2E+00 10 100
2.63E+00 2.0E+01 1.0E+00 3.2E+00
3.15E+00 1.6E+01 1.0E+00 3.2E+00
6.43E+00 9.3E+00 1.0E+00 3.2E+00
9.22E+01 1.0E+00 1.0E+00 3.2E+00
6.70E+02 1.7E+00 1.0E+00 3.2E+00
1.41E+03 1.9E+00 1.0E+00 3.2E+00

2.25E+00 1.2E+01 1.0E+00 3.2E+00
3.30E+00 1.2E+01 1.0E+00 3.2E+00
2.27E+00 1.4E+01 1.0E+00 3.2E+00 10 100
2.74E+00 2.4E+00 1.0E+00 3.2E+00
3.16E+00 1.2E+01 1.0E+00 3.2E+00
3.82E+00 1.7E+00 1.0E+00 3.2E+00
7.23E+00 7.5E+00 1.0E+00 3.2E+00
4.75E+02 1.0E+00 1.0E+00 3.2E+00
1.37E+03 8.9E-01 1.0E+00 3.2E+00
3.72E+03 1.1 E+00 1.0E+00 3.2E+00
2.50E+00 6.6E+00 1.0E+00 3.2E+00
3.98E+00 9.6E+00 1.0E+00 3.2E+00
2.50E+00 1.8E+01 1.0E+00 3.2E+00 10 100
2.76E+00 6.6E+00 1.0E+00 3.2E+00
3.07E+00 6.0E+00 1.0E+00 3.2E+00
4.22E+00 7.3E+00 1.0E+00 3.2E+00
1.43E+01 2.4E+00 1.0E+00 3.2E+00
3.64E+02 2.6E+00 1.0E+00 3.2E+00
1.08E+03 9.2E-01 1.0E+00 3.2E+00

2.80E+00 2.4E+00 1.0E+00 3.2E+00
2.81 E+00 3.2E+00 1.0E+00 3.2E+00
2.84E+00 1.4E+00 1.0E+00 3.2E+00
3.19E+00 8.4E+00 1.0E+00 3.2E+00
1.18E+00 6.1E-01 1.0E+00 3.2E+00
2.24E+00 4.6E-01 1.0E+00 3.2E+00
3.08E+00 1.2E+01 1.0E+00 3.2E+00
2.49E+00 1.6E+00 1.0E+00 3.2E+00
2.73E+00 8.4E-01 1.0E+00 3.2E+00
2.81 E+00 9.5E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/21/11 1:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:25 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:30 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:31 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:33 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:04 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:03 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:05 PM EPA Interlab L04 1313-1316SWA
3/21/11 2:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:08 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:10 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 3:06 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:19 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:21 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:23 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:24 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:26 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:28 PM EPA Interlab L04 1313-1316 SWA
3/21/11 2:29 PM EPA Interlab L04 1313-1316 SWA

3/21/11 3:07 PM EPA Interlab L04 1313-1316 SWA
3/21/11 12:58 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:00 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:02 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:11 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:13 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:15 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:16 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:18 PM EPA Interlab L04 1313-1316 SWA
3/21/11 1:20 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                          1-438
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample
SWA-L05-1313-T01-A
SWA-L05-1313-T02-A
SWA-L05-1313-T03-A
SWA-L05-1313-T04-A
SWA-L05-1313-T05-A
SWA-L05-1313-T06-A
SWA-L05-1313-T07-A
SWA-L05-1313-T08-A
SWA-L05-1313-T09-A
SWA-L05-1313-T01-B
SWA-L05-1313-T02-B
SWA-L05-1313-T03-B
SWA-L05-1313-T04-B
SWA-L05-1313-T05-B
SWA-L05-1313-T06-B
SWA-L05-1313-T07-B
SWA-L05-1313-T08-B
SWA-L05-1313-T09-B
SWA-L05-1313-T01-C
SWA-L05-1313-T02-C
SWA-L05-1313-T03-C
SWA-L05-1313-T04-C
SWA-L05-1313-T05-C
SWA-L05-1313-T06-C
SWA-L05-1313-T07-C
SWA-L05-1313-T08-C
SWA-L05-1313-T09-C
SWA-L05-1313-B01-A
SWA-L05-1313-B02-A
SWA-L05-1313-B03-A
SWA-L05-1313-B01-B
SWA-L05-1313-B02-B
SWA-L05-1313-B03-B
SWA-L05-1313-B01-C
SWA-L05-1313-B02-C
SWA-L05-1313-B03-C
Sample Internal
Dilution Cone. Qualifier Review
ug/L
1 5.66E+04
1 2.84E+04
1 1.88E+02
1 1.98E+01
1 3.33E+04
1 2.87E+04
1 9.15E+00
1 8.47E+03
1 1.00E+06
1 5.89E+04
1 2.87E+04
1 1.40E+02
1 2.04E+01
1 3.39E+04
1 2.80E+04
1 5.00E-01 U1/2
1 4.45E+05
1 7.97E+05
1 5.59E+04
1 2.83E+04
1 1.78E+02
1 2.14E+01
1 3.30E+04
1 2.85E+04
1 5.00E-01 U1/2
1 4.38E+05
1 6.70E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES
Cone. RSD
ug/L %
5.66E+04 4.5E-01
2.84E+04 9.3E-01
1.88E+02 7.2E-01
1.98E+01 4.0E+00
3.33E+04 9.6E-01
2.87E+04 2.2E-01
9.15E+00 6.0E+01
8.47E+03 1.0E+01
1.00E+06 1.4E+00
5.89E+04 1.5E-01
2.87E+04 9.8E-01
1.40E+02 2.4E+00
2.04E+01 4.0E+01
3.39E+04 6.7E+01
2.80E+04 7.3E-01
5.00E-01 7.8E+01
4.45E+05 9.9E-01
7.97E+05 2.6E+00
5.59E+04 5.7E-01
2.83E+04 2.2E+00
1.78E+02 1.3E+00
2.14E+01 5.6E+00
3.30E+04 5.3E-01
2.85E+04 2.9E-01
5.00E-01 7.2E+01
4.38E+05 2.0E+00
6.70E+05 6.3E+00
5.00E-01 3.6E+00
5.00E-01 2.5E+01
5.00E-01 4.2E+00
5.00E-01 7.3E-01
5.00E-01 1.6E+01
5.00E-01 1.4E+01
5.00E-01 3.4E+00
5.00E-01 4.9E+00
5.00E-01 9.4E+00
MDL
ug/L
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.94E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.97E+04 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.92E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab L05 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316SWA
                                                                                                                                                                                     1-439
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb SWA-L05-1313-T01-A
Sb SWA-L05-1313-T02-A
Sb SWA-L05-1313-T03-A
Sb SWA-L05-1313-T04-A
Sb SWA-L05-1313-T05-A
Sb SWA-L05-1313-T06-A
Sb SWA-L05-1313-T07-A
Sb SWA-L05-1313-T08-A
Sb SWA-L05-1313-T09-A
Sb SWA-L05-1313-T01-B
Sb SWA-L05-1313-T02-B
Sb SWA-L05-1313-T03-B
Sb SWA-L05-1313-T04-B
Sb SWA-L05-1313-T05-B
Sb SWA-L05-1313-T06-B
Sb SWA-L05-1313-T07-B
Sb SWA-L05-1313-T08-B
Sb SWA-L05-1313-T09-B
Sb SWA-L05-1313-T01-C
Sb SWA-L05-1313-T02-C
Sb SWA-L05-1313-T03-C
Sb SWA-L05-1313-T04-C
Sb SWA-L05-1313-T05-C
Sb SWA-L05-1313-T06-C
Sb SWA-L05-1313-T07-C
Sb SWA-L05-1313-T08-C
Sb SWA-L05-1313-T09-C
Sb SWA-L05-1313-B01-A
Sb SWA-L05-1313-B02-A
Sb SWA-L05-1313-B03-A
Sb SWA-L05-1313-B01-B
Sb SWA-L05-1313-B02-B
Sb SWA-L05-1313-B03-B
Sb SWA-L05-1313-B01-C
Sb SWA-L05-1313-B02-C
Sb SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 6.34E+03
1 5.70E+03
1 1.42E+03
1 1.12E+03
1 6.17E+03
1 5.77E+03
1 1.16E+03
1 4.12E+02
1 4.67E+04
1 6.33E+03
1 5.70E+03
1 1.28E+03
1 1.14E+03
1 6.16E+03
1 5.49E+03
1 9.00E+02
1 5.42E+02
1 9.31 E+03
1 6.06E+03
1 5.56E+03
1 1.18E+03
1 9.88E+02
1 6.20E+03
1 5.61 E+03
1 8.05E+02
1 8.95E+02
1 5.96E+03
1 1.28E+01 E
1 1.41E+01 E
1 1.07E+02
1 1.63E+01 E
1 1.46E+01 E
1 5.57E+01
1 2.17E+01 E
1 2.24E+01 E
1 2.95E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.34E+03 6.2E-01 7.5E+00 2.4E+01
5.70E+03 5.5E-01 7.5E+00 2.4E+01 10 100
1.42E+03 1.4E+00 7.5E+00 2.4E+01
1.12E+03 6.3E-01 7.5E+00 2.4E+01
6.17E+03 1.2E+00 7.5E+00 2.4E+01
5.77E+03 3.6E-01 7.5E+00 2.4E+01
1.16E+03 2.5E+00 7.5E+00 2.4E+01
4.12E+02 4.8E+00 7.5E+00 2.4E+01
4.67E+04 5.7E+00 7.5E+00 2.4E+01
6.33E+03 2.6E-01 7.5E+00 2.4E+01
5.70E+03 3.4E-01 7.5E+00 2.4E+01 10 100
1.28E+03 1.3E+00 7.5E+00 2.4E+01
1.14E+03 8.4E-01 7.5E+00 2.4E+01
6.16E+03 5.0E+01 7.5E+00 2.4E+01
5.49E+03 2.3E-01 7.5E+00 2.4E+01
9.00E+02 2.2E+00 7.5E+00 2.4E+01
5.42E+02 1.2E+00 7.5E+00 2.4E+01
9.31 E+03 4.7E+01 7.5E+00 2.4E+01
6.06E+03 2.0E-01 7.5E+00 2.4E+01
5.56E+03 2.2E+00 7.5E+00 2.4E+01 10 100
1.18E+03 9.5E-01 7.5E+00 2.4E+01
9.88E+02 7.5E-01 7.5E+00 2.4E+01
6.20E+03 4.1E-01 7.5E+00 2.4E+01
5.61 E+03 4.7E-01 7.5E+00 2.4E+01
8.05E+02 5.4E-01 7.5E+00 2.4E+01
8.95E+02 2.6E-01 7.5E+00 2.4E+01
5.96E+03 5.8E+01 7.5E+00 2.4E+01
1.28E+01 2.2E+01 7.5E+00 2.4E+01
1.41E+01 2.6E+01 7.5E+00 2.4E+01
1.07E+02 8.7E+00 7.5E+00 2.4E+01
1.63E+01 2.1E+01 7.5E+00 2.4E+01
1.46E+01 4.7E+01 7.5E+00 2.4E+01
5.57E+01 1.0E+01 7.5E+00 2.4E+01
2.17E+01 1.2E+01 7.5E+00 2.4E+01
2.24E+01 3.8E+01 7.5E+00 2.4E+01
2.95E+01 2.9E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
6.71E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.75E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.62E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-440
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As SWA-L05-1313-T01-A
As SWA-L05-1313-T02-A
As SWA-L05-1313-T03-A
As SWA-L05-1313-T04-A
As SWA-L05-1313-T05-A
As SWA-L05-1313-T06-A
As SWA-L05-1313-T07-A
As SWA-L05-1313-T08-A
As SWA-L05-1313-T09-A
As SWA-L05-1313-T01-B
As SWA-L05-1313-T02-B
As SWA-L05-1313-T03-B
As SWA-L05-1313-T04-B
As SWA-L05-1313-T05-B
As SWA-L05-1313-T06-B
As SWA-L05-1313-T07-B
As SWA-L05-1313-T08-B
As SWA-L05-1313-T09-B
As SWA-L05-1313-T01-C
As SWA-L05-1313-T02-C
As SWA-L05-1313-T03-C
As SWA-L05-1313-T04-C
As SWA-L05-1313-T05-C
As SWA-L05-1313-T06-C
As SWA-L05-1313-T07-C
As SWA-L05-1313-T08-C
As SWA-L05-1313-T09-C
As SWA-L05-1313-B01-A
As SWA-L05-1313-B02-A
As SWA-L05-1313-B03-A
As SWA-L05-1313-B01-B
As SWA-L05-1313-B02-B
As SWA-L05-1313-B03-B
As SWA-L05-1313-B01-C
As SWA-L05-1313-B02-C
As SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.11E+04
1 4.10E+03
1 1.54E+02
1 1.62E+02
1 4.80E+03
1 4.03E+03
1 2.74E+02
1 6.01 E+02
1 2.49E+04
1 1.12E+04
1 3.95E+03
1 1.40E+02
1 1.75E+02
1 4.81 E+03
1 3.90E+03
1 2.39E+02
1 2.17E+03
1 7.83E+03
1 1.05E+04
1 4.03E+03
1 1.66E+02
1 1.21 E+02
1 4.84E+03
1 4.22E+03
1 2.43E+02
1 2.30E+03
1 6.97E+03
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 2.61E+01 E
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 1.15E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.11E+04 1.5E+00 1.1E+01 3.5E+01
4.10E+03 2.3E-01 1.1E+01 3.5E+01 10 100
1.54E+02 3.2E+00 1.1E+01 3.5E+01
1.62E+02 1.7E+00 1.1E+01 3.5E+01
4.80E+03 6.8E-01 1.1E+01 3.5E+01
4.03E+03 1.2E+00 1.1E+01 3.5E+01
2.74E+02 6.4E+00 1.1E+01 3.5E+01
6.01E+02 7.2E+00 1.1E+01 3.5E+01
2.49E+04 4.9E+00 1.1E+01 3.5E+01
1.12E+04 2.1E+00 1.1E+01 3.5E+01
3.95E+03 5.0E-01 1.1E+01 3.5E+01 10 100
1.40E+02 3.5E+00 1.1E+01 3.5E+01
1.75E+02 4.8E+00 1.1E+01 3.5E+01
4.81E+03 5.7E+01 1.1E+01 3.5E+01
3.90E+03 4.9E-01 1.1E+01 3.5E+01
2.39E+02 2.4E+00 1.1E+01 3.5E+01
2.17E+03 6.6E-01 1.1E+01 3.5E+01
7.83E+03 2.4E+01 1.1E+01 3.5E+01
1.05E+04 9.0E-01 1.1E+01 3.5E+01
4.03E+03 3.2E+00 1.1E+01 3.5E+01 10 100
1.66E+02 3.4E+00 1.1E+01 3.5E+01
1.21E+02 7.6E+00 1.1E+01 3.5E+01
4.84E+03 7.1E-01 1.1E+01 3.5E+01
4.22E+03 4.0E-01 1.1E+01 3.5E+01
2.43E+02 9.9E+00 1.1E+01 3.5E+01
2.30E+03 2.2E-01 1.1E+01 3.5E+01
6.97E+03 3.0E+01 1.1E+01 3.5E+01
5.50E+00 2.0E+01 1.1E+01 3.5E+01
5.50E+00 9.7E+01 1.1E+01 3.5E+01
2.61E+01 2.9E+01 1.1E+01 3.5E+01
5.50E+00 6.1E+01 1.1E+01 3.5E+01
5.50E+00 4.6E+01 1.1E+01 3.5E+01
5.50E+00 4.0E+01 1.1E+01 3.5E+01
5.50E+00 1.1 E+02 1.1E+01 3.5E+01
5.50E+00 8.1E+01 1.1E+01 3.5E+01
1.15E+01 5.6E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.03E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.90E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.92E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab L05 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab L05 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab L05 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab L05 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-441
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B SWA-L05-1313-T01-A
B SWA-L05-1313-T02-A
B SWA-L05-1313-T03-A
B SWA-L05-1313-T04-A
B SWA-L05-1313-T05-A
B SWA-L05-1313-T06-A
B SWA-L05-1313-T07-A
B SWA-L05-1313-T08-A
B SWA-L05-1313-T09-A
B SWA-L05-1313-T01-B
B SWA-L05-1313-T02-B
B SWA-L05-1313-T03-B
B SWA-L05-1313-T04-B
B SWA-L05-1313-T05-B
B SWA-L05-1313-T06-B
B SWA-L05-1313-T07-B
B SWA-L05-1313-T08-B
B SWA-L05-1313-T09-B
B SWA-L05-1313-T01-C
B SWA-L05-1313-T02-C
B SWA-L05-1313-T03-C
B SWA-L05-1313-T04-C
B SWA-L05-1313-T05-C
B SWA-L05-1313-T06-C
B SWA-L05-1313-T07-C
B SWA-L05-1313-T08-C
B SWA-L05-1313-T09-C
B SWA-L05-1313-B01-A
B SWA-L05-1313-B02-A
B SWA-L05-1313-B03-A
B SWA-L05-1313-B01-B
B SWA-L05-1313-B02-B
B SWA-L05-1313-B03-B
B SWA-L05-1313-B01-C
B SWA-L05-1313-B02-C
B SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.05E+03
1 7.30E+02
1 8.27E+02
1 1.07E+03
1 8.40E+02
1 7.44E+02
1 1.59E+03
1 4.20E+03
1 6.43E+03
1 1.13E+03
1 7.36E+02
1 8.73E+02
1 1.11E+03
1 8.29E+02
1 7.27E+02
1 3.14E+03
1 4.54E+03
1 5.29E+03
1 1.06E+03
1 7.27E+02
1 8.49E+02
1 1.12E+03
1 8.31 E+02
1 7.38E+02
1 3.45E+03
1 4.52E+03
1 4.27E+03
1 5.00E-01 U1/2
1 2.09E+00 E
1 6.36E+00
1 5.00E-01 U1/2
1 1.49E+00 E
1 4.81 E+00
1 1.25E+00 E
1 2.53E+00 E
1 4.57E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.05E+03 6.3E-01 1.0E+00 3.2E+00
7.30E+02 8.5E-01 1.0E+00 3.2E+00 1000 100
8.27E+02 9.0E-01 1.0E+00 3.2E+00
1.07E+03 5.9E-01 1.0E+00 3.2E+00
8.40E+02 1.3E+00 1.0E+00 3.2E+00
7.44E+02 3.2E-01 1.0E+00 3.2E+00
1.59E+03 2.0E+00 1.0E+00 3.2E+00
4.20E+03 5.6E-01 1.0E+00 3.2E+00
6.43E+03 1.6E+00 1.0E+00 3.2E+00
1.13E+03 8.3E-01 1.0E+00 3.2E+00
7.36E+02 4.8E-01 1.0E+00 3.2E+00 1000 100
8.73E+02 7.3E-01 1.0E+00 3.2E+00
1.11E+03 2.4E-01 1.0E+00 3.2E+00
8.29E+02 4.2E+01 1.0E+00 3.2E+00
7.27E+02 8.1E-01 1.0E+00 3.2E+00
3.14E+03 7.0E-01 1.0E+00 3.2E+00
4.54E+03 2.3E-01 1.0E+00 3.2E+00
5.29E+03 7.3E+00 1.0E+00 3.2E+00
1.06E+03 2.8E-01 1.0E+00 3.2E+00
7.27E+02 2.0E+00 1.0E+00 3.2E+00 1000 100
8.49E+02 6.9E-01 1.0E+00 3.2E+00
1.12E+03 5.0E-01 1.0E+00 3.2E+00
8.31 E+02 5.0E-01 1.0E+00 3.2E+00
7.38E+02 6.6E-01 1.0E+00 3.2E+00
3.45E+03 2.3E-01 1.0E+00 3.2E+00
4.52E+03 5.6E-01 1.0E+00 3.2E+00
4.27E+03 4.6E+00 1.0E+00 3.2E+00
5.00E-01 4.8E+02 1.0E+00 3.2E+00
2.09E+00 1.6E+02 1.0E+00 3.2E+00
6.36E+00 2.4E+01 1.0E+00 3.2E+00
5.00E-01 2.6E+02 1.0E+00 3.2E+00
1.49E+00 1.4E+02 1.0E+00 3.2E+00
4.81 E+00 4.6E+01 1.0E+00 3.2E+00
1.25E+00 1.3E+02 1.0E+00 3.2E+00
2.53E+00 5.1E+01 1.0E+00 3.2E+00
4.57E+00 4.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.64E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.65E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.68E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-442
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba SWA-L05-1313-T01-A
Ba SWA-L05-1313-T02-A
Ba SWA-L05-1313-T03-A
Ba SWA-L05-1313-T04-A
Ba SWA-L05-1313-T05-A
Ba SWA-L05-1313-T06-A
Ba SWA-L05-1313-T07-A
Ba SWA-L05-1313-T08-A
Ba SWA-L05-1313-T09-A
Ba SWA-L05-1313-T01-B
Ba SWA-L05-1313-T02-B
Ba SWA-L05-1313-T03-B
Ba SWA-L05-1313-T04-B
Ba SWA-L05-1313-T05-B
Ba SWA-L05-1313-T06-B
Ba SWA-L05-1313-T07-B
Ba SWA-L05-1313-T08-B
Ba SWA-L05-1313-T09-B
Ba SWA-L05-1313-T01-C
Ba SWA-L05-1313-T02-C
Ba SWA-L05-1313-T03-C
Ba SWA-L05-1313-T04-C
Ba SWA-L05-1313-T05-C
Ba SWA-L05-1313-T06-C
Ba SWA-L05-1313-T07-C
Ba SWA-L05-1313-T08-C
Ba SWA-L05-1313-T09-C
Ba SWA-L05-1313-B01-A
Ba SWA-L05-1313-B02-A
Ba SWA-L05-1313-B03-A
Ba SWA-L05-1313-B01-B
Ba SWA-L05-1313-B02-B
Ba SWA-L05-1313-B03-B
Ba SWA-L05-1313-B01-C
Ba SWA-L05-1313-B02-C
Ba SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.18E+02
1 8.98E+01
1 5.16E+02
1 4.57E+02
1 1.21E+02
1 8.85E+01
1 7.08E+02
1 1.06E+03
1 8.98E+02
1 3.14E+02
1 9.47E+01
1 6.18E+02
1 4.83E+02
1 1.23E+02
1 1.20E+02
1 8.81 E+02
1 6.32E+02
1 7. 11 E+02
1 3.25E+02
1 9.41 E+01
1 6.27E+02
1 5.34E+02
1 1.21 E+02
1 8.38E+01
1 9.94E+02
1 6.52E+02
1 5.73E+02
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.17E+00 E
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.18E+02 3.5E-01 1.0E+00 3.2E+00
8.98E+01 5.7E-01 1.0E+00 3.2E+00 10 100
5.16E+02 6.7E-01 1.0E+00 3.2E+00
4.57E+02 6.6E-01 1.0E+00 3.2E+00
1.21 E+02 4.7E-01 1.0E+00 3.2E+00
8.85E+01 7.9E-01 1.0E+00 3.2E+00
7.08E+02 2.2E+00 1.0E+00 3.2E+00
1.06E+03 2.5E-01 1.0E+00 3.2E+00
8.98E+02 3.2E+00 1.0E+00 3.2E+00
3.14E+02 4.1E-01 1.0E+00 3.2E+00
9.47E+01 5.4E-01 1.0E+00 3.2E+00 10 100
6.18E+02 1.2E+00 1.0E+00 3.2E+00
4.83E+02 1.9E-01 1.0E+00 3.2E+00
1.23E+02 4.7E+01 1.0E+00 3.2E+00
1.20E+02 1.7E-01 1.0E+00 3.2E+00
8.81 E+02 4.4E-01 1.0E+00 3.2E+00
6.32E+02 3.3E-01 1.0E+00 3.2E+00
7.11E+02 4.9E+00 1.0E+00 3.2E+00
3.25E+02 1.0E-01 1.0E+00 3.2E+00
9.41E+01 1.7E+00 1.0E+00 3.2E+00 10 100
6.27E+02 4.5E-01 1.0E+00 3.2E+00
5.34E+02 1.0E+00 1.0E+00 3.2E+00
1.21 E+02 5.8E-01 1.0E+00 3.2E+00
8.38E+01 2.3E-01 1.0E+00 3.2E+00
9.94E+02 2.5E-01 1.0E+00 3.2E+00
6.52E+02 4.8E-01 1.0E+00 3.2E+00
5.73E+02 7.4E+00 1.0E+00 3.2E+00
5.00E-01 2.0E+02 1.0E+00 3.2E+00
5.00E-01 9.2E+01 1.0E+00 3.2E+00
5.00E-01 1.1 E+01 1.0E+00 3.2E+00
5.00E-01 8.8E+01 1.0E+00 3.2E+00
5.00E-01 9.1E+00 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
5.00E-01 1.6E+02 1.0E+00 3.2E+00
1.17E+00 2.6E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.93E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.78E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-443
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be SWA-L05-1313-T01-A
Be SWA-L05-1313-T02-A
Be SWA-L05-1313-T03-A
Be SWA-L05-1313-T04-A
Be SWA-L05-1313-T05-A
Be SWA-L05-1313-T06-A
Be SWA-L05-1313-T07-A
Be SWA-L05-1313-T08-A
Be SWA-L05-1313-T09-A
Be SWA-L05-1313-T01-B
Be SWA-L05-1313-T02-B
Be SWA-L05-1313-T03-B
Be SWA-L05-1313-T04-B
Be SWA-L05-1313-T05-B
Be SWA-L05-1313-T06-B
Be SWA-L05-1313-T07-B
Be SWA-L05-1313-T08-B
Be SWA-L05-1313-T09-B
Be SWA-L05-1313-T01-C
Be SWA-L05-1313-T02-C
Be SWA-L05-1313-T03-C
Be SWA-L05-1313-T04-C
Be SWA-L05-1313-T05-C
Be SWA-L05-1313-T06-C
Be SWA-L05-1313-T07-C
Be SWA-L05-1313-T08-C
Be SWA-L05-1313-T09-C
Be SWA-L05-1313-B01-A
Be SWA-L05-1313-B02-A
Be SWA-L05-1313-B03-A
Be SWA-L05-1313-B01-B
Be SWA-L05-1313-B02-B
Be SWA-L05-1313-B03-B
Be SWA-L05-1313-B01-C
Be SWA-L05-1313-B02-C
Be SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 1.28E+02
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 7.73E+01
1 9.69E+01
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 7.60E+01
1 7.92E+01
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 7.7E+01 1.9E+00 6.0E+00
9.50E-01 8.7E+01 1.9E+00 6.0E+00 10 100
9.50E-01 9.2E+01 1.9E+00 6.0E+00
9.50E-01 4.8E+02 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00
9.50E-01 7.4E+01 1.9E+00 6.0E+00
9.50E-01 5.1E+02 1.9E+00 6.0E+00
9.50E-01 4.0E+01 1.9E+00 6.0E+00
1.28E+02 6.4E+00 1.9E+00 6.0E+00
9.50E-01 8.2E+01 1.9E+00 6.0E+00
9.50E-01 9.6E+01 1.9E+00 6.0E+00 10 100
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 8.2E+01 1.9E+00 6.0E+00
9.50E-01 3.8E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 3.1E+02 1.9E+00 6.0E+00
7.73E+01 1.9E+00 1.9E+00 6.0E+00
9.69E+01 3.8E+00 1.9E+00 6.0E+00
9.50E-01 6.1E+01 1.9E+00 6.0E+00
9.50E-01 5.1E+02 1.9E+00 6.0E+00 10 100
9.50E-01 2.7E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+03 1.9E+00 6.0E+00
9.50E-01 4.4E+02 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
7.60E+01 4.3E-02 1.9E+00 6.0E+00
7.92E+01 7.0E+00 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 3.2E+02 1.9E+00 6.0E+00
9.50E-01 5.0E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 7.3E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.90E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.65E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.85E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:18 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-444
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd SWA-L05-1313-T01-A
Cd SWA-L05-1313-T02-A
Cd SWA-L05-1313-T03-A
Cd SWA-L05-1313-T04-A
Cd SWA-L05-1313-T05-A
Cd SWA-L05-1313-T06-A
Cd SWA-L05-1313-T07-A
Cd SWA-L05-1313-T08-A
Cd SWA-L05-1313-T09-A
Cd SWA-L05-1313-T01-B
Cd SWA-L05-1313-T02-B
Cd SWA-L05-1313-T03-B
Cd SWA-L05-1313-T04-B
Cd SWA-L05-1313-T05-B
Cd SWA-L05-1313-T06-B
Cd SWA-L05-1313-T07-B
Cd SWA-L05-1313-T08-B
Cd SWA-L05-1313-T09-B
Cd SWA-L05-1313-T01-C
Cd SWA-L05-1313-T02-C
Cd SWA-L05-1313-T03-C
Cd SWA-L05-1313-T04-C
Cd SWA-L05-1313-T05-C
Cd SWA-L05-1313-T06-C
Cd SWA-L05-1313-T07-C
Cd SWA-L05-1313-T08-C
Cd SWA-L05-1313-T09-C
Cd SWA-L05-1313-B01-A
Cd SWA-L05-1313-B02-A
Cd SWA-L05-1313-B03-A
Cd SWA-L05-1313-B01-B
Cd SWA-L05-1313-B02-B
Cd SWA-L05-1313-B03-B
Cd SWA-L05-1313-B01-C
Cd SWA-L05-1313-B02-C
Cd SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 5.55E+00 E
1 4.38E+01
1 1.10E+00 U1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.47E+01
1 2.86E+01
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.33E+01
1 2.43E+01
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 6.1E+02 2.2E+00 7.0E+00
1.10E+00 8.5E+01 2.2E+00 7.0E+00 10 100
1.10E+00 2.2E+02 2.2E+00 7.0E+00
1.10E+00 6.5E+01 2.2E+00 7.0E+00
1.10E+00 1.2E+03 2.2E+00 7.0E+00
1.10E+00 7.0E+01 2.2E+00 7.0E+00
1.10E+00 1.8E+02 2.2E+00 7.0E+00
5.55E+00 2.0E+00 2.2E+00 7.0E+00
4.38E+01 3.6E+00 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00
1.10E+00 4.1E+01 2.2E+00 7.0E+00 10 100
1.10E+00 5.1E+01 2.2E+00 7.0E+00
1.10E+00 3.7E+02 2.2E+00 7.0E+00
1.10E+00 2.6E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
1.10E+00 1.7E+01 2.2E+00 7.0E+00
1.47E+01 1.8E+00 2.2E+00 7.0E+00
2.86E+01 7.3E+00 2.2E+00 7.0E+00
1.10E+00 2.9E+02 2.2E+00 7.0E+00
1.10E+00 3.1E+03 2.2E+00 7.0E+00 10 100
1.10E+00 2.8E+02 2.2E+00 7.0E+00
1.10E+00 2.4E+02 2.2E+00 7.0E+00
1.10E+00 2.3E+02 2.2E+00 7.0E+00
1.10E+00 7.9E+01 2.2E+00 7.0E+00
1.10E+00 7.4E+01 2.2E+00 7.0E+00
1.33E+01 1.4E+00 2.2E+00 7.0E+00
2.43E+01 1.2E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+02 2.2E+00 7.0E+00
1.10E+00 2.5E+02 2.2E+00 7.0E+00
1.10E+00 4.9E+02 2.2E+00 7.0E+00
1.10E+00 1.7E+02 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00
1.10E+00 2.7E+02 2.2E+00 7.0E+00
1.10E+00 1.6E+02 2.2E+00 7.0E+00
1.10E+00 8.2E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.70E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.36E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:15 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:16 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:18 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-445
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
SWA-L05-1313-T01-A
SWA-L05-1313-T02-A
SWA-L05-1313-T03-A
SWA-L05-1313-T04-A
SWA-L05-1313-T05-A
SWA-L05-1313-T06-A
SWA-L05-1313-T07-A
SWA-L05-1313-T08-A
SWA-L05-1313-T09-A
SWA-L05-1313-T01-B
SWA-L05-1313-T02-B
SWA-L05-1313-T03-B
SWA-L05-1313-T04-B
SWA-L05-1313-T05-B
SWA-L05-1313-T06-B
SWA-L05-1313-T07-B
SWA-L05-1313-T08-B
SWA-L05-1313-T09-B
SWA-L05-1313-T01-C
SWA-L05-1313-T02-C
SWA-L05-1313-T03-C
SWA-L05-1313-T04-C
SWA-L05-1313-T05-C
SWA-L05-1313-T06-C
SWA-L05-1313-T07-C
SWA-L05-1313-T08-C
SWA-L05-1313-T09-C
SWA-L05-1313-B01-A
SWA-L05-1313-B02-A
SWA-L05-1313-B03-A
SWA-L05-1313-B01-B
SWA-L05-1313-B02-B
SWA-L05-1313-B03-B
SWA-L05-1313-B01-C
SWA-L05-1313-B02-C
SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.56E+03
1 8.37E+03
1 7.99E+05
1 1.73E+06
1 8.53E+03
1 8.58E+03
1 3.89E+06
1 4.65E+06
1 4.72E+06
1 5.31 E+03
1 8.44E+03
1 8.13E+05
1 1.77E+06
1 8.67E+03
1 9.25E+03
1 4.60E+06
1 3.21 E+06
1 3.92E+06
1 5.47E+03
1 8.67E+03
1 7.95E+05
1 1.80E+06
1 8.65E+03
1 9.03E+03
1 4.57E+06
1 3.29E+06
1 3.45E+06
1 3.71 E+00 E
1 1.30E+00 U1/2
1 1.30E+00 U1/2
1 7.48E+00 E
1 1.30E+00 U1/2
1 6.22E+00 E
1 1.08E+01
1 4.13E+03
1 5.24E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.56E+03 8.5E-01 2.6E+00 8.3E+00
8.37E+03 3.4E-01 2.6E+00 8.3E+00 1000 100
7.99E+05 6.7E-01 2.6E+00 8.3E+00
1.73E+06 8.7E-01 2.6E+00 8.3E+00
8.53E+03 4.6E-01 2.6E+00 8.3E+00
8.58E+03 5.6E-01 2.6E+00 8.3E+00
3.89E+06 2.5E+00 2.6E+00 8.3E+00
4.65E+06 4.5E-01 2.6E+00 8.3E+00
4.72E+06 3.3E+00 2.6E+00 8.3E+00
5.31 E+03 4.0E-01 2.6E+00 8.3E+00
8.44E+03 2.6E-01 2.6E+00 8.3E+00 1000 100
8.13E+05 1.1 E+00 2.6E+00 8.3E+00
1.77E+06 8.7E-02 2.6E+00 8.3E+00
8.67E+03 6.7E+01 2.6E+00 8.3E+00
9.25E+03 2.3E-01 2.6E+00 8.3E+00
4.60E+06 9.2E-01 2.6E+00 8.3E+00
3.21 E+06 1.1 E+00 2.6E+00 8.3E+00
3.92E+06 2.9E+00 2.6E+00 8.3E+00
5.47E+03 1.3E+00 2.6E+00 8.3E+00
8.67E+03 2.1E+00 2.6E+00 8.3E+00 1000 100
7.95E+05 2.6E-01 2.6E+00 8.3E+00
1.80E+06 6.1E-01 2.6E+00 8.3E+00
8.65E+03 6.9E-01 2.6E+00 8.3E+00
9.03E+03 4.7E-01 2.6E+00 8.3E+00
4.57E+06 3.4E-01 2.6E+00 8.3E+00
3.29E+06 9.0E-01 2.6E+00 8.3E+00
3.45E+06 6.0E+00 2.6E+00 8.3E+00
3.71 E+00 2.2E+01 2.6E+00 8.3E+00
1.30E+00 7.4E+01 2.6E+00 8.3E+00
1.30E+00 3.5E+02 2.6E+00 8.3E+00
7.48E+00 1.3E+02 2.6E+00 8.3E+00
1.30E+00 6.1E+02 2.6E+00 8.3E+00
6.22E+00 2.7E+02 2.6E+00 8.3E+00
1.08E+01 4.2E+01 2.6E+00 8.3E+00
4.13E+03 6.7E-01 2.6E+00 8.3E+00
5.24E+00 1.1E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.25E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.35E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.55E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-446
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr SWA-L05-1313-T01-A
Cr SWA-L05-1313-T02-A
Cr SWA-L05-1313-T03-A
Cr SWA-L05-1313-T04-A
Cr SWA-L05-1313-T05-A
Cr SWA-L05-1313-T06-A
Cr SWA-L05-1313-T07-A
Cr SWA-L05-1313-T08-A
Cr SWA-L05-1313-T09-A
Cr SWA-L05-1313-T01-B
Cr SWA-L05-1313-T02-B
Cr SWA-L05-1313-T03-B
Cr SWA-L05-1313-T04-B
Cr SWA-L05-1313-T05-B
Cr SWA-L05-1313-T06-B
Cr SWA-L05-1313-T07-B
Cr SWA-L05-1313-T08-B
Cr SWA-L05-1313-T09-B
Cr SWA-L05-1313-T01-C
Cr SWA-L05-1313-T02-C
Cr SWA-L05-1313-T03-C
Cr SWA-L05-1313-T04-C
Cr SWA-L05-1313-T05-C
Cr SWA-L05-1313-T06-C
Cr SWA-L05-1313-T07-C
Cr SWA-L05-1313-T08-C
Cr SWA-L05-1313-T09-C
Cr SWA-L05-1313-B01-A
Cr SWA-L05-1313-B02-A
Cr SWA-L05-1313-B03-A
Cr SWA-L05-1313-B01-B
Cr SWA-L05-1313-B02-B
Cr SWA-L05-1313-B03-B
Cr SWA-L05-1313-B01-C
Cr SWA-L05-1313-B02-C
Cr SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.13E+03
1 9.20E+02
1 5.99E+01
1 2.43E+01
1 9.14E+02
1 9.16E+02
1 2.04E+01
1 1.27E+02
1 2.66E+04
1 1.23E+03
1 8.60E+02
1 4.32E+01
1 2.14E+01
1 9.25E+02
1 8.40E+02
1 1.59E+00 E
1 8.53E+03
1 2.05E+04
1 1.08E+03
1 9.15E+02
1 4.50E+01
1 2.31E+01
1 8.94E+02
1 9.54E+02
1 6.00E-01 U1/2
1 8.69E+03
1 1.67E+04
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.13E+03 7.6E-01 1.2E+00 3.8E+00
9.20E+02 7.8E-02 1.2E+00 3.8E+00 10 100
5.99E+01 1.6E+00 1.2E+00 3.8E+00
2.43E+01 2.8E+00 1.2E+00 3.8E+00
9.14E+02 1.1E+00 1.2E+00 3.8E+00
9.16E+02 6.0E-01 1.2E+00 3.8E+00
2.04E+01 5.1E+00 1.2E+00 3.8E+00
1.27E+02 1.0E+01 1.2E+00 3.8E+00
2.66E+04 3.3E+00 1.2E+00 3.8E+00
1.23E+03 1.4E+00 1.2E+00 3.8E+00
8.60E+02 1.6E+00 1.2E+00 3.8E+00 10 100
4.32E+01 1.1E+00 1.2E+00 3.8E+00
2.14E+01 3.6E+00 1.2E+00 3.8E+00
9.25E+02 5.2E+01 1.2E+00 3.8E+00
8.40E+02 5.5E-01 1.2E+00 3.8E+00
1.59E+00 2.8E+01 1.2E+00 3.8E+00
8.53E+03 2.1E-01 1.2E+00 3.8E+00
2.05E+04 3.1E+00 1.2E+00 3.8E+00
1.08E+03 5.1E-01 1.2E+00 3.8E+00
9.15E+02 2.5E+00 1.2E+00 3.8E+00 10 100
4.50E+01 6.6E-01 1.2E+00 3.8E+00
2.31 E+01 2.4E+00 1.2E+00 3.8E+00
8.94E+02 3.0E-01 1.2E+00 3.8E+00
9.54E+02 6.3E-01 1.2E+00 3.8E+00
6.00E-01 4.5E+02 1.2E+00 3.8E+00
8.69E+03 4.2E-01 1.2E+00 3.8E+00
1.67E+04 7.7E+00 1.2E+00 3.8E+00
6.00E-01 8.3E+01 1.2E+00 3.8E+00
6.00E-01 3.2E+02 1.2E+00 3.8E+00
6.00E-01 4.8E+01 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.00E-01 2.3E+02 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.00E-01 2.0E+02 1.2E+00 3.8E+00
6.00E-01 9.1 E+01 1.2E+00 3.8E+00
6.00E-01 3.6E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.84E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.83E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.89E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-447
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
SWA-L05-1313-T01-A
SWA-L05-1313-T02-A
SWA-L05-1313-T03-A
SWA-L05-1313-T04-A
SWA-L05-1313-T05-A
SWA-L05-1313-T06-A
SWA-L05-1313-T07-A
SWA-L05-1313-T08-A
SWA-L05-1313-T09-A
SWA-L05-1313-T01-B
SWA-L05-1313-T02-B
SWA-L05-1313-T03-B
SWA-L05-1313-T04-B
SWA-L05-1313-T05-B
SWA-L05-1313-T06-B
SWA-L05-1313-T07-B
SWA-L05-1313-T08-B
SWA-L05-1313-T09-B
SWA-L05-1313-T01-C
SWA-L05-1313-T02-C
SWA-L05-1313-T03-C
SWA-L05-1313-T04-C
SWA-L05-1313-T05-C
SWA-L05-1313-T06-C
SWA-L05-1313-T07-C
SWA-L05-1313-T08-C
SWA-L05-1313-T09-C
SWA-L05-1313-B01-A
SWA-L05-1313-B02-A
SWA-L05-1313-B03-A
SWA-L05-1313-B01-B
SWA-L05-1313-B02-B
SWA-L05-1313-B03-B
SWA-L05-1313-B01-C
SWA-L05-1313-B02-C
SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.17E+02
1 3.38E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 2.70E+01
1 1.36E+02
1 2.23E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 5.31E+01
1 1.33E+02
1 1.88E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 8.4E+02 1.8E+00 5.7E+00
9.00E-01 1.2E+03 1.8E+00 5.7E+00 10 100
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 2.4E+02 1.8E+00 5.7E+00
9.00E-01 4.8E+02 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00
9.00E-01 2.5E+02 1.8E+00 5.7E+00
1.17E+02 1.1E+00 1.8E+00 5.7E+00
3.38E+02 3.8E+00 1.8E+00 5.7E+00
9.00E-01 6.7E+01 1.8E+00 5.7E+00
9.00E-01 4.2E+01 1.8E+00 5.7E+00 10 100
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 5.0E+01 1.8E+00 5.7E+00
9.00E-01 5.3E+01 1.8E+00 5.7E+00
9.00E-01 5.9E+01 1.8E+00 5.7E+00
2.70E+01 6.2E+00 1.8E+00 5.7E+00
1.36E+02 4.0E-01 1.8E+00 5.7E+00
2.23E+02 6.6E+00 1.8E+00 5.7E+00
9.00E-01 2.9E+02 1.8E+00 5.7E+00
9.00E-01 5.7E+01 1.8E+00 5.7E+00 10 100
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00
9.00E-01 2.5E+02 1.8E+00 5.7E+00
9.00E-01 5.3E+02 1.8E+00 5.7E+00
5.31 E+01 2.2E+00 1.8E+00 5.7E+00
1.33E+02 1.1E+00 1.8E+00 5.7E+00
1.88E+02 1.1E+01 1.8E+00 5.7E+00
9.00E-01 7.1E+01 1.8E+00 5.7E+00
9.00E-01 3.0E+01 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 2.2E+01 1.8E+00 5.7E+00
9.00E-01 2.2E+01 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+01 1.8E+00 5.7E+00
9.00E-01 2.4E+01 1.8E+00 5.7E+00
9.00E-01 2.5E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.18E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.35E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:18 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-448
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu SWA-L05-1313-T01-A
Cu SWA-L05-1313-T02-A
Cu SWA-L05-1313-T03-A
Cu SWA-L05-1313-T04-A
Cu SWA-L05-1313-T05-A
Cu SWA-L05-1313-T06-A
Cu SWA-L05-1313-T07-A
Cu SWA-L05-1313-T08-A
Cu SWA-L05-1313-T09-A
Cu SWA-L05-1313-T01-B
Cu SWA-L05-1313-T02-B
Cu SWA-L05-1313-T03-B
Cu SWA-L05-1313-T04-B
Cu SWA-L05-1313-T05-B
Cu SWA-L05-1313-T06-B
Cu SWA-L05-1313-T07-B
Cu SWA-L05-1313-T08-B
Cu SWA-L05-1313-T09-B
Cu SWA-L05-1313-T01-C
Cu SWA-L05-1313-T02-C
Cu SWA-L05-1313-T03-C
Cu SWA-L05-1313-T04-C
Cu SWA-L05-1313-T05-C
Cu SWA-L05-1313-T06-C
Cu SWA-L05-1313-T07-C
Cu SWA-L05-1313-T08-C
Cu SWA-L05-1313-T09-C
Cu SWA-L05-1313-B01-A
Cu SWA-L05-1313-B02-A
Cu SWA-L05-1313-B03-A
Cu SWA-L05-1313-B01-B
Cu SWA-L05-1313-B02-B
Cu SWA-L05-1313-B03-B
Cu SWA-L05-1313-B01-C
Cu SWA-L05-1313-B02-C
Cu SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 6.64E+00 E
1 5.03E+00 E
1 5.23E+00 E
1 7.85E+00 E
1 5.34E+00 E
1 4.03E+00 E
1 1.41E+01
1 1.66E+01
1 1.15E+03
1 6.61E+OOE
1 1.85E+00 U1/2
1 5.84E+00 E
1 1.00E+01 E
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 2.00E+01
1 2.65E+02
1 9.37E+02
1 6.21 E+00 E
1 1.85E+00 U1/2
1 6.09E+00 E
1 6.77E+00 E
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 2.42E+01
1 2.41 E+02
1 7.28E+02
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 8.19E+00 E
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.64E+00 3.8E+01 3.7E+00 1.2E+01
5.03E+00 2.0E+01 3.7E+00 1.2E+01 10 100
5.23E+00 3.3E+01 3.7E+00 1.2E+01
7.85E+00 2.5E+01 3.7E+00 1.2E+01
5.34E+00 3.6E+01 3.7E+00 1.2E+01
4.03E+00 8.0E+01 3.7E+00 1.2E+01
1.41E+01 5.2E+00 3.7E+00 1.2E+01
1.66E+01 8.9E+00 3.7E+00 1.2E+01
1.15E+03 3.7E+00 3.7E+00 1.2E+01
6.61 E+00 1.6E+01 3.7E+00 1.2E+01
1.85E+00 4.7E+02 3.7E+00 1.2E+01 10 100
5.84E+00 2.6E+01 3.7E+00 1.2E+01
1.00E+01 2.5E+01 3.7E+00 1.2E+01
1.85E+00 8.2E+01 3.7E+00 1.2E+01
1.85E+00 1.1 E+02 3.7E+00 1.2E+01
2.00E+01 1.5E+01 3.7E+00 1.2E+01
2.65E+02 6.2E-01 3.7E+00 1.2E+01
9.37E+02 2.4E+00 3.7E+00 1.2E+01
6.21 E+00 1.2E+01 3.7E+00 1.2E+01
1.85E+00 9.9E+01 3.7E+00 1.2E+01 10 100
6.09E+00 2.8E+01 3.7E+00 1.2E+01
6.77E+00 3.5E+01 3.7E+00 1.2E+01
1.85E+00 4.4E+01 3.7E+00 1.2E+01
1.85E+00 1.8E+01 3.7E+00 1.2E+01
2.42E+01 4.5E+00 3.7E+00 1.2E+01
2.41 E+02 8.1E-01 3.7E+00 1.2E+01
7.28E+02 6.9E+00 3.7E+00 1.2E+01
1.85E+00 9.0E+02 3.7E+00 1.2E+01
1.85E+00 3.1 E+02 3.7E+00 1.2E+01
1.85E+00 1.4E+02 3.7E+00 1.2E+01
1.85E+00 2.2E+02 3.7E+00 1.2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01
1.85E+00 7.6E+01 3.7E+00 1.2E+01
1.85E+00 9.4E+01 3.7E+00 1.2E+01
8.19E+00 9.1E+00 3.7E+00 1.2E+01
1.85E+00 5.8E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.95E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.84E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.02E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-449
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe SWA-L05-1313-T01-A
Fe SWA-L05-1313-T02-A
Fe SWA-L05-1313-T03-A
Fe SWA-L05-1313-T04-A
Fe SWA-L05-1313-T05-A
Fe SWA-L05-1313-T06-A
Fe SWA-L05-1313-T07-A
Fe SWA-L05-1313-T08-A
Fe SWA-L05-1313-T09-A
Fe SWA-L05-1313-T01-B
Fe SWA-L05-1313-T02-B
Fe SWA-L05-1313-T03-B
Fe SWA-L05-1313-T04-B
Fe SWA-L05-1313-T05-B
Fe SWA-L05-1313-T06-B
Fe SWA-L05-1313-T07-B
Fe SWA-L05-1313-T08-B
Fe SWA-L05-1313-T09-B
Fe SWA-L05-1313-T01-C
Fe SWA-L05-1313-T02-C
Fe SWA-L05-1313-T03-C
Fe SWA-L05-1313-T04-C
Fe SWA-L05-1313-T05-C
Fe SWA-L05-1313-T06-C
Fe SWA-L05-1313-T07-C
Fe SWA-L05-1313-T08-C
Fe SWA-L05-1313-T09-C
Fe SWA-L05-1313-B01-A
Fe SWA-L05-1313-B02-A
Fe SWA-L05-1313-B03-A
Fe SWA-L05-1313-B01-B
Fe SWA-L05-1313-B02-B
Fe SWA-L05-1313-B03-B
Fe SWA-L05-1313-B01-C
Fe SWA-L05-1313-B02-C
Fe SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 8.91 E+01
1 6.75E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 7.12E+01
1 6.49E+01
1 1.00E+00 U1/2
1 5.54E+04
1 2.99E+05
1 8.36E+01
1 6.12E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 7.03E+01
1 5.90E+01
1 1.00E+00 U1/2
1 9.03E+04
1 2.23E+05
1 1.07E+02
1 7.01 E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 7.18E+01
1 6.40E+01
1 6.16E+02
1 8.83E+04
1 1.89E+05
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.91 E+01 5.9E-01 2.0E+00 6.4E+00
6.75E+01 1.0E-01 2.0E+00 6.4E+00 1000 100
1.00E+00 2.5E+00 2.0E+00 6.4E+00
1.00E+00 3.1E+00 2.0E+00 6.4E+00
7.12E+01 7.1E-01 2.0E+00 6.4E+00
6.49E+01 1.5E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+03 2.0E+00 6.4E+00
5.54E+04 1.2E+00 2.0E+00 6.4E+00
2.99E+05 5.6E+00 2.0E+00 6.4E+00
8.36E+01 1.6E+00 2.0E+00 6.4E+00
6.12E+01 1.9E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 1.5E+00 2.0E+00 6.4E+00
1.00E+00 6.2E+00 2.0E+00 6.4E+00
7.03E+01 6.0E+00 2.0E+00 6.4E+00
5.90E+01 1.9E+00 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00
9.03E+04 8.6E-01 2.0E+00 6.4E+00
2.23E+05 6.3E+00 2.0E+00 6.4E+00
1.07E+02 1.3E+00 2.0E+00 6.4E+00
7.01E+01 5.8E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 3.0E+00 2.0E+00 6.4E+00
1.00E+00 9.7E+00 2.0E+00 6.4E+00
7.18E+01 1.3E+00 2.0E+00 6.4E+00
6.40E+01 8.8E-01 2.0E+00 6.4E+00
6.16E+02 5.8E+00 2.0E+00 6.4E+00
8.83E+04 7.0E-01 2.0E+00 6.4E+00
1.89E+05 1.1 E+01 2.0E+00 6.4E+00
1.00E+00 8.1E-01 2.0E+00 6.4E+00
1.00E+00 5.1 E+01 2.0E+00 6.4E+00
1.00E+00 9.7E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+00 2.0E+00 6.4E+00
1.00E+00 7.7E+00 2.0E+00 6.4E+00
1.00E+00 5.9E+00 2.0E+00 6.4E+00
1.00E+00 1.0E+00 2.0E+00 6.4E+00
1.00E+00 7.3E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.59E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.79E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-450
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb SWA-L05-1313-T01-A
Pb SWA-L05-1313-T02-A
Pb SWA-L05-1313-T03-A
Pb SWA-L05-1313-T04-A
Pb SWA-L05-1313-T05-A
Pb SWA-L05-1313-T06-A
Pb SWA-L05-1313-T07-A
Pb SWA-L05-1313-T08-A
Pb SWA-L05-1313-T09-A
Pb SWA-L05-1313-T01-B
Pb SWA-L05-1313-T02-B
Pb SWA-L05-1313-T03-B
Pb SWA-L05-1313-T04-B
Pb SWA-L05-1313-T05-B
Pb SWA-L05-1313-T06-B
Pb SWA-L05-1313-T07-B
Pb SWA-L05-1313-T08-B
Pb SWA-L05-1313-T09-B
Pb SWA-L05-1313-T01-C
Pb SWA-L05-1313-T02-C
Pb SWA-L05-1313-T03-C
Pb SWA-L05-1313-T04-C
Pb SWA-L05-1313-T05-C
Pb SWA-L05-1313-T06-C
Pb SWA-L05-1313-T07-C
Pb SWA-L05-1313-T08-C
Pb SWA-L05-1313-T09-C
Pb SWA-L05-1313-B01-A
Pb SWA-L05-1313-B02-A
Pb SWA-L05-1313-B03-A
Pb SWA-L05-1313-B01-B
Pb SWA-L05-1313-B02-B
Pb SWA-L05-1313-B03-B
Pb SWA-L05-1313-B01-C
Pb SWA-L05-1313-B02-C
Pb SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.33E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.27E+03
1 1.48E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 7.62E+00 E
1 7.36E+02
1 2.62E+03
1 1.40E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 6.29E+02
1 2.15E+03
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+02 7.1E+00 6.8E+00 2.2E+01
3.40E+00 1.6E+02 6.8E+00 2.2E+01 10 100
3.40E+00 3.9E+02 6.8E+00 2.2E+01
3.40E+00 8.3E+01 6.8E+00 2.2E+01
3.40E+00 5.1E+01 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01
3.40E+00 8.4E+01 6.8E+00 2.2E+01
3.40E+00 9.9E+00 6.8E+00 2.2E+01
3.27E+03 3.0E+00 6.8E+00 2.2E+01
1.48E+02 2.5E+00 6.8E+00 2.2E+01
3.40E+00 3.3E+00 6.8E+00 2.2E+01 10 100
3.40E+00 7.5E+01 6.8E+00 2.2E+01
3.40E+00 6.9E+01 6.8E+00 2.2E+01
3.40E+00 7.9E+01 6.8E+00 2.2E+01
3.40E+00 3.3E+02 6.8E+00 2.2E+01
7.62E+00 9.3E+01 6.8E+00 2.2E+01
7.36E+02 6.3E-01 6.8E+00 2.2E+01
2.62E+03 2.6E+00 6.8E+00 2.2E+01
1.40E+02 3.7E+00 6.8E+00 2.2E+01
3.40E+00 1.2E+02 6.8E+00 2.2E+01 10 100
3.40E+00 1.1E+02 6.8E+00 2.2E+01
3.40E+00 2.5E+01 6.8E+00 2.2E+01
3.40E+00 7.8E+01 6.8E+00 2.2E+01
3.40E+00 9.3E+01 6.8E+00 2.2E+01
3.40E+00 2.9E+02 6.8E+00 2.2E+01
6.29E+02 1.0E+00 6.8E+00 2.2E+01
2.15E+03 9.6E+00 6.8E+00 2.2E+01
3.40E+00 6.3E+02 6.8E+00 2.2E+01
3.40E+00 8.6E+02 6.8E+00 2.2E+01
3.40E+00 3.2E+03 6.8E+00 2.2E+01
3.40E+00 8.4E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 1.0E+02 6.8E+00 2.2E+01
3.40E+00 5.8E+01 6.8E+00 2.2E+01
3.40E+00 6.3E+01 6.8E+00 2.2E+01
3.40E+00 7.8E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.65E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.75E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.47E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:18 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-451
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li SWA-L05-1313-T01-A
Li SWA-L05-1313-T02-A
Li SWA-L05-1313-T03-A
Li SWA-L05-1313-T04-A
Li SWA-L05-1313-T05-A
Li SWA-L05-1313-T06-A
Li SWA-L05-1313-T07-A
Li SWA-L05-1313-T08-A
Li SWA-L05-1313-T09-A
Li SWA-L05-1313-T01-B
Li SWA-L05-1313-T02-B
Li SWA-L05-1313-T03-B
Li SWA-L05-1313-T04-B
Li SWA-L05-1313-T05-B
Li SWA-L05-1313-T06-B
Li SWA-L05-1313-T07-B
Li SWA-L05-1313-T08-B
Li SWA-L05-1313-T09-B
Li SWA-L05-1313-T01-C
Li SWA-L05-1313-T02-C
Li SWA-L05-1313-T03-C
Li SWA-L05-1313-T04-C
Li SWA-L05-1313-T05-C
Li SWA-L05-1313-T06-C
Li SWA-L05-1313-T07-C
Li SWA-L05-1313-T08-C
Li SWA-L05-1313-T09-C
Li SWA-L05-1313-B01-A
Li SWA-L05-1313-B02-A
Li SWA-L05-1313-B03-A
Li SWA-L05-1313-B01-B
Li SWA-L05-1313-B02-B
Li SWA-L05-1313-B03-B
Li SWA-L05-1313-B01-C
Li SWA-L05-1313-B02-C
Li SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 1.84E+01
1 5.29E+01
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 3.66E+02
1 6.47E+02
1 7.01 E+02
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 1.91E+01
1 6.42E+01
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 5.09E+02
1 4.82E+02
1 4.92E+02
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 1.28E+01
1 6.38E+01
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 5.07E+02
1 5. 11 E+02
1 3.63E+02
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 7.4E+00 1.9E+00 6.0E+00
9.50E-01 2.9E+00 1.9E+00 6.0E+00 10 100
1.84E+01 1.0E+01 1.9E+00 6.0E+00
5.29E+01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 3.6E-01 1.9E+00 6.0E+00
9.50E-01 6.1E+00 1.9E+00 6.0E+00
3.66E+02 1.5E+00 1.9E+00 6.0E+00
6.47E+02 1.8E+00 1.9E+00 6.0E+00
7.01 E+02 7.9E+00 1.9E+00 6.0E+00
9.50E-01 2.5E+00 1.9E+00 6.0E+00
9.50E-01 7.7E+00 1.9E+00 6.0E+00 10 100
1.91E+01 7.5E+00 1.9E+00 6.0E+00
6.42E+01 9.5E+00 1.9E+00 6.0E+00
9.50E-01 1.0E+01 1.9E+00 6.0E+00
9.50E-01 2.8E-01 1.9E+00 6.0E+00
5.09E+02 2.3E+00 1.9E+00 6.0E+00
4.82E+02 1.4E+00 1.9E+00 6.0E+00
4.92E+02 1.2E+01 1.9E+00 6.0E+00
9.50E-01 3.2E+01 1.9E+00 6.0E+00
9.50E-01 4.0E+00 1.9E+00 6.0E+00 10 100
1.28E+01 9.3E+00 1.9E+00 6.0E+00
6.38E+01 1.9E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+00 1.9E+00 6.0E+00
9.50E-01 2.8E+00 1.9E+00 6.0E+00
5.07E+02 3.7E+00 1.9E+00 6.0E+00
5.11E+02 2.7E+00 1.9E+00 6.0E+00
3.63E+02 1.0E+01 1.9E+00 6.0E+00
9.50E-01 4.2E+00 1.9E+00 6.0E+00
9.50E-01 1.0E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00
9.50E-01 4.0E+00 1.9E+00 6.0E+00
9.50E-01 2.8E+00 1.9E+00 6.0E+00
9.50E-01 1.8E+00 1.9E+00 6.0E+00
9.50E-01 4.5E+00 1.9E+00 6.0E+00
9.50E-01 9.6E+00 1.9E+00 6.0E+00
9.50E-01 3.4E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.49E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.70E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.70E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316SWA
                                                                                                                                                                          1-452
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn SWA-L05-1313-T01-A
Mn SWA-L05-1313-T02-A
Mn SWA-L05-1313-T03-A
Mn SWA-L05-1313-T04-A
Mn SWA-L05-1313-T05-A
Mn SWA-L05-1313-T06-A
Mn SWA-L05-1313-T07-A
Mn SWA-L05-1313-T08-A
Mn SWA-L05-1313-T09-A
Mn SWA-L05-1313-T01-B
Mn SWA-L05-1313-T02-B
Mn SWA-L05-1313-T03-B
Mn SWA-L05-1313-T04-B
Mn SWA-L05-1313-T05-B
Mn SWA-L05-1313-T06-B
Mn SWA-L05-1313-T07-B
Mn SWA-L05-1313-T08-B
Mn SWA-L05-1313-T09-B
Mn SWA-L05-1313-T01-C
Mn SWA-L05-1313-T02-C
Mn SWA-L05-1313-T03-C
Mn SWA-L05-1313-T04-C
Mn SWA-L05-1313-T05-C
Mn SWA-L05-1313-T06-C
Mn SWA-L05-1313-T07-C
Mn SWA-L05-1313-T08-C
Mn SWA-L05-1313-T09-C
Mn SWA-L05-1313-B01-A
Mn SWA-L05-1313-B02-A
Mn SWA-L05-1313-B03-A
Mn SWA-L05-1313-B01-B
Mn SWA-L05-1313-B02-B
Mn SWA-L05-1313-B03-B
Mn SWA-L05-1313-B01-C
Mn SWA-L05-1313-B02-C
Mn SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.64E+02
1 1.42E+04
1 2.25E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 6.16E+03
1 1.38E+04
1 1.81E+04
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 8.25E+03
1 1.37E+04
1 1.55E+04
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.8E+00 2.0E+00 6.4E+00
1.00E+00 6.3E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 8.7E+00 2.0E+00 6.4E+00
1.00E+00 7.7E+00 2.0E+00 6.4E+00
1.64E+02 2.4E+00 2.0E+00 6.4E+00
1.42E+04 3.3E-01 2.0E+00 6.4E+00
2.25E+04 2.1E+00 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00 10 100
1.00E+00 8.5E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 3.7E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
6.16E+03 5.2E-01 2.0E+00 6.4E+00
1.38E+04 1.8E-01 2.0E+00 6.4E+00
1.81E+04 5.0E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+00 2.0E+00 6.4E+00
1.00E+00 5.3E+00 2.0E+00 6.4E+00 10 100
1.00E+00 4.2E+01 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
8.25E+03 3.0E-01 2.0E+00 6.4E+00
1.37E+04 4.9E-01 2.0E+00 6.4E+00
1.55E+04 8.7E+00 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.00E+00 9.0E+04 2.0E+00 6.4E+00
1.00E+00 5.4E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+03 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 4.7E+01 2.0E+00 6.4E+00
1.00E+00 9.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.36E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.48E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:18 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-453
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg SWA-L05-1313-T01-A
Mg SWA-L05-1313-T02-A
Mg SWA-L05-1313-T03-A
Mg SWA-L05-1313-T04-A
Mg SWA-L05-1313-T05-A
Mg SWA-L05-1313-T06-A
Mg SWA-L05-1313-T07-A
Mg SWA-L05-1313-T08-A
Mg SWA-L05-1313-T09-A
Mg SWA-L05-1313-T01-B
Mg SWA-L05-1313-T02-B
Mg SWA-L05-1313-T03-B
Mg SWA-L05-1313-T04-B
Mg SWA-L05-1313-T05-B
Mg SWA-L05-1313-T06-B
Mg SWA-L05-1313-T07-B
Mg SWA-L05-1313-T08-B
Mg SWA-L05-1313-T09-B
Mg SWA-L05-1313-T01-C
Mg SWA-L05-1313-T02-C
Mg SWA-L05-1313-T03-C
Mg SWA-L05-1313-T04-C
Mg SWA-L05-1313-T05-C
Mg SWA-L05-1313-T06-C
Mg SWA-L05-1313-T07-C
Mg SWA-L05-1313-T08-C
Mg SWA-L05-1313-T09-C
Mg SWA-L05-1313-B01-A
Mg SWA-L05-1313-B02-A
Mg SWA-L05-1313-B03-A
Mg SWA-L05-1313-B01-B
Mg SWA-L05-1313-B02-B
Mg SWA-L05-1313-B03-B
Mg SWA-L05-1313-B01-C
Mg SWA-L05-1313-B02-C
Mg SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.36E+03
1 1.49E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 4.13E+05
1 8.17E+05
1 8.92E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.15E+03
1 1.52E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 7.34E+05
1 5.99E+05
1 7.31 E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.03E+03
1 1.35E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 7.12E+05
1 6.19E+05
1 6.13E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 3.94E+02
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 2.7E+01 1.0E+00 3.2E+00
5.00E-01 2.5E+01 1.0E+00 3.2E+00 1000 100
1.36E+03 1.2E+00 1.0E+00 3.2E+00
1.49E+05 1.1E+00 1.0E+00 3.2E+00
5.00E-01 1.0E+02 1.0E+00 3.2E+00
5.00E-01 2.9E+01 1.0E+00 3.2E+00
4.13E+05 9.7E-01 1.0E+00 3.2E+00
8.17E+05 5.2E-01 1.0E+00 3.2E+00
8.92E+05 3.1E+00 1.0E+00 3.2E+00
5.00E-01 6.7E+03 1.0E+00 3.2E+00
5.00E-01 3.2E+01 1.0E+00 3.2E+00 1000 100
1.15E+03 1.5E+00 1.0E+00 3.2E+00
1.52E+05 8.2E-01 1.0E+00 3.2E+00
5.00E-01 1.1E+01 1.0E+00 3.2E+00
5.00E-01 4.6E+01 1.0E+00 3.2E+00
7.34E+05 1.4E+00 1.0E+00 3.2E+00
5.99E+05 3.5E-01 1.0E+00 3.2E+00
7.31 E+05 5.7E+00 1.0E+00 3.2E+00
5.00E-01 1.9E+02 1.0E+00 3.2E+00
5.00E-01 4.2E+02 1.0E+00 3.2E+00 1000 100
1.03E+03 1.8E+00 1.0E+00 3.2E+00
1.35E+05 3.7E-01 1.0E+00 3.2E+00
5.00E-01 1.6E+02 1.0E+00 3.2E+00
5.00E-01 7.0E+01 1.0E+00 3.2E+00
7.12E+05 5.7E-01 1.0E+00 3.2E+00
6.19E+05 9.4E-01 1.0E+00 3.2E+00
6.13E+05 1.0E+01 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
5.00E-01 6.1E+01 1.0E+00 3.2E+00
5.00E-01 8.4E+01 1.0E+00 3.2E+00
5.00E-01 1.8E+01 1.0E+00 3.2E+00
5.00E-01 3.4E+01 1.0E+00 3.2E+00
5.00E-01 9.5E+00 1.0E+00 3.2E+00
5.00E-01 6.3E+00 1.0E+00 3.2E+00
3.94E+02 1.3E+00 1.0E+00 3.2E+00
5.00E-01 1.1E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.01 E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.25E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.25E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:18 PM EPA Interlab LOS 131 3-1 31 6 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-454
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo SWA-L05-1313-T01-A
Mo SWA-L05-1313-T02-A
Mo SWA-L05-1313-T03-A
Mo SWA-L05-1313-T04-A
Mo SWA-L05-1313-T05-A
Mo SWA-L05-1313-T06-A
Mo SWA-L05-1313-T07-A
Mo SWA-L05-1313-T08-A
Mo SWA-L05-1313-T09-A
Mo SWA-L05-1313-T01-B
Mo SWA-L05-1313-T02-B
Mo SWA-L05-1313-T03-B
Mo SWA-L05-1313-T04-B
Mo SWA-L05-1313-T05-B
Mo SWA-L05-1313-T06-B
Mo SWA-L05-1313-T07-B
Mo SWA-L05-1313-T08-B
Mo SWA-L05-1313-T09-B
Mo SWA-L05-1313-T01-C
Mo SWA-L05-1313-T02-C
Mo SWA-L05-1313-T03-C
Mo SWA-L05-1313-T04-C
Mo SWA-L05-1313-T05-C
Mo SWA-L05-1313-T06-C
Mo SWA-L05-1313-T07-C
Mo SWA-L05-1313-T08-C
Mo SWA-L05-1313-T09-C
Mo SWA-L05-1313-B01-A
Mo SWA-L05-1313-B02-A
Mo SWA-L05-1313-B03-A
Mo SWA-L05-1313-B01-B
Mo SWA-L05-1313-B02-B
Mo SWA-L05-1313-B03-B
Mo SWA-L05-1313-B01-C
Mo SWA-L05-1313-B02-C
Mo SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.60E+01
1 1.00E+02
1 9.27E+01
1 8.21 E+01
1 1.05E+02
1 9.81 E+01
1 1.42E+02
1 4.35E+00
1 4.29E+01
1 9.50E+01
1 9.73E+01
1 9.16E+01
1 8.68E+01
1 1.02E+02
1 9.49E+01
1 7.32E+01
1 2.71E+OOE
1 1.40E+01
1 8.77E+01
1 9.81 E+01
1 9.18E+01
1 9.07E+01
1 1.07E+02
1 9.70E+01
1 5.94E+01
1 2.21 E+00 E
1 1.57E+01
1 6.00E-01 U1/2
1 2.75E+00 E
1 9.82E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 3.98E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.60E+01 2.1 E+00 1.2E+00 3.8E+00
1.00E+02 2.4E+00 1.2E+00 3.8E+00 10 100
9.27E+01 1.0E+00 1.2E+00 3.8E+00
8.21 E+01 1.1 E+00 1.2E+00 3.8E+00
1.05E+02 8.4E-01 1.2E+00 3.8E+00
9.81 E+01 7.0E-01 1.2E+00 3.8E+00
1.42E+02 4.4E+00 1.2E+00 3.8E+00
4.35E+00 3.9E+01 1.2E+00 3.8E+00
4.29E+01 1.1 E+01 1.2E+00 3.8E+00
9.50E+01 1.3E+00 1.2E+00 3.8E+00
9.73E+01 2.9E+00 1.2E+00 3.8E+00 10 100
9.16E+01 2.7E+00 1.2E+00 3.8E+00
8.68E+01 3.6E+00 1.2E+00 3.8E+00
1.02E+02 5.6E+01 1.2E+00 3.8E+00
9.49E+01 2.7E+00 1.2E+00 3.8E+00
7.32E+01 1.4E+00 1.2E+00 3.8E+00
2.71 E+00 2.1 E+01 1.2E+00 3.8E+00
1.40E+01 3.9E+01 1.2E+00 3.8E+00
8.77E+01 2.3E+00 1.2E+00 3.8E+00
9.81E+01 1.5E+00 1.2E+00 3.8E+00 10 100
9.18E+01 1.7E+00 1.2E+00 3.8E+00
9.07E+01 1.6E+00 1.2E+00 3.8E+00
1.07E+02 2.5E+00 1.2E+00 3.8E+00
9.70E+01 1.0E+00 1.2E+00 3.8E+00
5.94E+01 2.7E+00 1.2E+00 3.8E+00
2.21 E+00 4.4E+01 1.2E+00 3.8E+00
1.57E+01 1.6E+01 1.2E+00 3.8E+00
6.00E-01 8.4E+01 1.2E+00 3.8E+00
2.75E+00 9.7E+01 1.2E+00 3.8E+00
9.82E+00 4.7E+00 1.2E+00 3.8E+00
6.00E-01 7.1 E+01 1.2E+00 3.8E+00
6.00E-01 7.7E+01 1.2E+00 3.8E+00
3.98E+00 5.6E+01 1.2E+00 3.8E+00
6.00E-01 1.7E+02 1.2E+00 3.8E+00
6.00E-01 8.0E+03 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.08E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-455
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni SWA-L05-1313-T01-A
Ni SWA-L05-1313-T02-A
Ni SWA-L05-1313-T03-A
Ni SWA-L05-1313-T04-A
Ni SWA-L05-1313-T05-A
Ni SWA-L05-1313-T06-A
Ni SWA-L05-1313-T07-A
Ni SWA-L05-1313-T08-A
Ni SWA-L05-1313-T09-A
Ni SWA-L05-1313-T01-B
Ni SWA-L05-1313-T02-B
Ni SWA-L05-1313-T03-B
Ni SWA-L05-1313-T04-B
Ni SWA-L05-1313-T05-B
Ni SWA-L05-1313-T06-B
Ni SWA-L05-1313-T07-B
Ni SWA-L05-1313-T08-B
Ni SWA-L05-1313-T09-B
Ni SWA-L05-1313-T01-C
Ni SWA-L05-1313-T02-C
Ni SWA-L05-1313-T03-C
Ni SWA-L05-1313-T04-C
Ni SWA-L05-1313-T05-C
Ni SWA-L05-1313-T06-C
Ni SWA-L05-1313-T07-C
Ni SWA-L05-1313-T08-C
Ni SWA-L05-1313-T09-C
Ni SWA-L05-1313-B01-A
Ni SWA-L05-1313-B02-A
Ni SWA-L05-1313-B03-A
Ni SWA-L05-1313-B01-B
Ni SWA-L05-1313-B02-B
Ni SWA-L05-1313-B03-B
Ni SWA-L05-1313-B01-C
Ni SWA-L05-1313-B02-C
Ni SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 4.26E+00 E
1 9.39E+00
1 9.00E-01 U1/2
1 1.01E+01
1 2.78E+02
1 4.66E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 5.06E+00
1 1.05E+01
1 9.00E-01 U1/2
1 7.63E+01
1 2.69E+02
1 3.68E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 3.77E+00 E
1 1.44E+01
1 9.00E-01 U1/2
1 1.48E+02
1 2.69E+02
1 3.17E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 7.8E+01 1.8E+00 5.7E+00 10 100
9.00E-01 2.1E+01 1.8E+00 5.7E+00
4.26E+00 3.5E+01 1.8E+00 5.7E+00
9.39E+00 8.1E+03 1.8E+00 5.7E+00
9.00E-01 2.8E+01 1.8E+00 5.7E+00
1.01E+01 3.4E+00 1.8E+00 5.7E+00
2.78E+02 3.1E-01 1.8E+00 5.7E+00
4.66E+02 2.2E+00 1.2E+00 3.8E+00
9.00E-01 1.0E+02 1.2E+00 3.8E+00
9.00E-01 1.2E+02 1.2E+00 3.8E+00 10 100
9.00E-01 1.8E+02 1.2E+00 3.8E+00
5.06E+00 3.3E+01 1.2E+00 3.8E+00
1.05E+01 1.3E+03 1.2E+00 3.8E+00
9.00E-01 1.4E+02 1.2E+00 3.8E+00
7.63E+01 5.1E+00 1.2E+00 3.8E+00
2.69E+02 1.1E+00 1.2E+00 3.8E+00
3.68E+02 5.5E+00 1.2E+00 3.8E+00
9.00E-01 4.3E+01 1.2E+00 3.8E+00
9.00E-01 3.7E+02 1.2E+00 3.8E+00 10 100
9.00E-01 1.5E+02 1.2E+00 3.8E+00
3.77E+00 1.0E+01 1.2E+00 3.8E+00
1.44E+01 2.9E+01 1.2E+00 3.8E+00
9.00E-01 3.6E+01 1.2E+00 3.8E+00
1.48E+02 1.3E+00 1.2E+00 3.8E+00
2.69E+02 9.0E-01 1.2E+00 3.8E+00
3.17E+02 8.8E+00 1.2E+00 3.8E+00
9.00E-01 3.7E+02 1.8E+00 5.7E+00
9.00E-01 4.8E+02 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 3.2E+02 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 5.1E+02 1.8E+00 5.7E+00
9.00E-01 5.8E+01 1.8E+00 5.7E+00
9.00E-01 6.5E+03 1.8E+00 5.7E+00
9.00E-01 8.0E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.83E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-456
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P SWA-L05-1313-T01-A
P SWA-L05-1313-T02-A
P SWA-L05-1313-T03-A
P SWA-L05-1313-T04-A
P SWA-L05-1313-T05-A
P SWA-L05-1313-T06-A
P SWA-L05-1313-T07-A
P SWA-L05-1313-T08-A
P SWA-L05-1313-T09-A
P SWA-L05-1313-T01-B
P SWA-L05-1313-T02-B
P SWA-L05-1313-T03-B
P SWA-L05-1313-T04-B
P SWA-L05-1313-T05-B
P SWA-L05-1313-T06-B
P SWA-L05-1313-T07-B
P SWA-L05-1313-T08-B
P SWA-L05-1313-T09-B
P SWA-L05-1313-T01-C
P SWA-L05-1313-T02-C
P SWA-L05-1313-T03-C
P SWA-L05-1313-T04-C
P SWA-L05-1313-T05-C
P SWA-L05-1313-T06-C
P SWA-L05-1313-T07-C
P SWA-L05-1313-T08-C
P SWA-L05-1313-T09-C
P SWA-L05-1313-B01-A
P SWA-L05-1313-B02-A
P SWA-L05-1313-B03-A
P SWA-L05-1313-B01-B
P SWA-L05-1313-B02-B
P SWA-L05-1313-B03-B
P SWA-L05-1313-B01-C
P SWA-L05-1313-B02-C
P SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.26E+02
1 4.01 E+01
1 2.30E+01
1 1.58E+01
1 5.97E+01
1 4.43E+01
1 8.02E+01
1 3.25E+01
1 4.27E+04
1 2.40E+02
1 5.76E+01
1 2.31 E+01
1 1.36E+01
1 6.14E+01
1 4.57E+01
1 2.98E+01
1 9.80E+01
1 1.13E+04
1 2.11E+02
1 4.63E+01
1 1.70E+01
1 1.41 E+01
1 6.36E+01
1 5.75E+01
1 4.17E+01
1 1.08E+02
1 1.06E+04
1 1.85E+00 U1/2
1 1.54E+01
1 5.84E+01
1 8.63E+00 E
1 4.00E+00 E
1 2.18E+01
1 1.14E+01 E
1 8.46E+00 E
1 2.30E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.26E+02 4.2E+00 3.7E+00 1.2E+01
4.01E+01 3.8E+01 3.7E+00 1.2E+01 1000 100
2.30E+01 3.4E+01 3.7E+00 1.2E+01
1.58E+01 9.0E+01 3.7E+00 1.2E+01
5.97E+01 9.6E+00 3.7E+00 1.2E+01
4.43E+01 3.5E+01 3.7E+00 1.2E+01
8.02E+01 2.5E+01 3.7E+00 1.2E+01
3.25E+01 2.5E+01 3.7E+00 1.2E+01
4.27E+04 6.1E+00 3.7E+00 1.2E+01
2.40E+02 3.3E+00 3.7E+00 1.2E+01
5.76E+01 1.4E+01 3.7E+00 1.2E+01 1000 100
2.31E+01 3.8E+01 3.7E+00 1.2E+01
1.36E+01 1.8E+02 3.7E+00 1.2E+01
6.14E+01 1.7E+02 3.7E+00 1.2E+01
4.57E+01 1.1 E+01 3.7E+00 1.2E+01
2.98E+01 8.4E+01 3.7E+00 1.2E+01
9.80E+01 9.7E-01 3.7E+00 1.2E+01
1.13E+04 3.2E+01 3.7E+00 1.2E+01
2.11E+02 6.3E+00 3.7E+00 1.2E+01
4.63E+01 2.6E+01 3.7E+00 1.2E+01 1000 100
1.70E+01 8.7E+01 3.7E+00 1.2E+01
1.41 E+01 3.4E+02 3.7E+00 1.2E+01
6.36E+01 1.8E+01 3.7E+00 1.2E+01
5.75E+01 3.4E+01 3.7E+00 1.2E+01
4.17E+01 4.4E+01 3.7E+00 1.2E+01
1.08E+02 5.9E+00 3.7E+00 1.2E+01
1.06E+04 3.6E+01 3.7E+00 1.2E+01
1.85E+00 1.5E+02 3.7E+00 1.2E+01
1.54E+01 8.0E+01 3.7E+00 1.2E+01
5.84E+01 1.4E+01 3.7E+00 1.2E+01
8.63E+00 9.7E+01 3.7E+00 1.2E+01
4.00E+00 2.0E+02 3.7E+00 1.2E+01
2.18E+01 4.9E+01 3.7E+00 1.2E+01
1.14E+01 8.3E+01 3.7E+00 1.2E+01
8.46E+00 1.1E+02 3.7E+00 1.2E+01
2.30E+01 7.9E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.92E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.96E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.51 E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-457
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
SWA-L05-1313-T01-A
SWA-L05-1313-T02-A
SWA-L05-1313-T03-A
SWA-L05-1313-T04-A
SWA-L05-1313-T05-A
SWA-L05-1313-T06-A
SWA-L05-1313-T07-A
SWA-L05-1313-T08-A
SWA-L05-1313-T09-A
SWA-L05-1313-T01-B
SWA-L05-1313-T02-B
SWA-L05-1313-T03-B
SWA-L05-1313-T04-B
SWA-L05-1313-T05-B
SWA-L05-1313-T06-B
SWA-L05-1313-T07-B
SWA-L05-1313-T08-B
SWA-L05-1313-T09-B
SWA-L05-1313-T01-C
SWA-L05-1313-T02-C
SWA-L05-1313-T03-C
SWA-L05-1313-T04-C
SWA-L05-1313-T05-C
SWA-L05-1313-T06-C
SWA-L05-1313-T07-C
SWA-L05-1313-T08-C
SWA-L05-1313-T09-C
SWA-L05-1313-B01-A
SWA-L05-1313-B02-A
SWA-L05-1313-B03-A
SWA-L05-1313-B01-B
SWA-L05-1313-B02-B
SWA-L05-1313-B03-B
SWA-L05-1313-B01-C
SWA-L05-1313-B02-C
SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.28E+06
1 2.39E+05
1 3.00E+05
1 3.10E+05
1 3.99E+05
1 2.38E+05
1 5.24E+05
1 2.99E+05
1 2.43E+05
1 2.25E+06
1 2.41 E+05
1 2.94E+05
1 3.14E+05
1 4.06E+05
1 2.36E+05
1 3.54E+05
1 2.00E+05
1 2.14E+05
1 2.23E+06
1 2.37E+05
1 2.96E+05
1 3.17E+05
1 4.06E+05
1 2.37E+05
1 3.51 E+05
1 2.04E+05
1 1.79E+05
1 1.24E+01
1 1.42E+02
1 2.26E+06
1 2.06E+02
1 9.92E+01
1 2.25E+06
1 2.56E+02
1 4.73E+02
1 2.24E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.28E+06 4.0E-01 1.6E+00 5.1E+00
2.39E+05 9.7E-01 1.6E+00 5.1E+00 1000 100
3.00E+05 4.0E-01 1.6E+00 5.1E+00
3.10E+05 1.1E+00 1.6E+00 5.1E+00
3.99E+05 1.8E-01 1.6E+00 5.1E+00
2.38E+05 1.1E-01 1.6E+00 5.1E+00
5.24E+05 5.1E+00 1.6E+00 5.1E+00
2.99E+05 1.2E+00 1.6E+00 5.1E+00
2.43E+05 2.5E+00 1.6E+00 5.1E+00
2.25E+06 5.8E-01 1.6E+00 5.1E+00
2.41E+05 5.8E-01 1.6E+00 5.1E+00 1000 100
2.94E+05 1.1E+00 1.6E+00 5.1E+00
3.14E+05 9.7E-01 1.6E+00 5.1E+00
4.06E+05 4.8E+01 1.6E+00 5.1E+00
2.36E+05 5.6E-01 1.6E+00 5.1E+00
3.54E+05 5.6E-01 1.6E+00 5.1E+00
2.00E+05 4.6E+00 1.6E+00 5.1E+00
2.14E+05 4.2E+00 1.6E+00 5.1E+00
2.23E+06 7.8E-01 1.6E+00 5.1E+00
2.37E+05 1.2E+00 1.6E+00 5.1E+00 1000 100
2.96E+05 8.5E-01 1.6E+00 5.1E+00
3.17E+05 7.3E-01 1.6E+00 5.1E+00
4.06E+05 5.4E-01 1.6E+00 5.1E+00
2.37E+05 5.1E-01 1.6E+00 5.1E+00
3.51 E+05 3.6E-01 1.6E+00 5.1E+00
2.04E+05 5.9E+00 1.6E+00 5.1E+00
1.79E+05 6.9E+00 1.6E+00 5.1E+00
1.24E+01 1.3E+01 1.6E+00 5.1E+00
1.42E+02 8.5E+01 1.6E+00 5.1E+00
2.26E+06 1.0E+00 1.6E+00 5.1E+00
2.06E+02 6.4E+00 1.6E+00 5.1E+00
9.92E+01 8.3E+00 1.6E+00 5.1E+00
2.25E+06 3.7E-01 1.6E+00 5.1E+00
2.56E+02 7.9E+00 1.6E+00 5.1E+00
4.73E+02 5.6E+00 1.6E+00 5.1E+00
2.24E+06 4.1E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.40E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.42E+05 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.38E+05 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-458
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Sample Dilutic
SWA-L05-1313-T01-A
SWA-L05-1313-T02-A
SWA-L05-1313-T03-A
SWA-L05-1313-T04-A
SWA-L05-1313-T05-A
SWA-L05-1313-T06-A
SWA-L05-1313-T07-A
SWA-L05-1313-T08-A
SWA-L05-1313-T09-A
SWA-L05-1313-T01-B
SWA-L05-1313-T02-B
SWA-L05-1313-T03-B
SWA-L05-1313-T04-B
SWA-L05-1313-T05-B
SWA-L05-1313-T06-B
SWA-L05-1313-T07-B
SWA-L05-1313-T08-B
SWA-L05-1313-T09-B
SWA-L05-1313-T01-C
SWA-L05-1313-T02-C
SWA-L05-1313-T03-C
SWA-L05-1313-T04-C
SWA-L05-1313-T05-C
SWA-L05-1313-T06-C
SWA-L05-1313-T07-C
SWA-L05-1313-T08-C
SWA-L05-1313-T09-C
SWA-L05-1313-B01-A
SWA-L05-1313-B02-A
SWA-L05-1313-B03-A
SWA-L05-1313-B01-B
SWA-L05-1313-B02-B
SWA-L05-1313-B03-B
SWA-L05-1313-B01-C
SWA-L05-1313-B02-C
SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 6.45E+04
1 6.44E+04
1 6.36E+04
1 6.54E+04
1 6.95E+04
1 6.38E+04
1 1.24E+05
1 6.41 E+04
1 3.93E+04
1 6.29E+04
1 6.40E+04
1 6.32E+04
1 6.75E+04
1 7.14E+04
1 6.24E+04
1 8.20E+04
1 3.76E+04
1 2.76E+04
1 6.04E+04
1 6.36E+04
1 6.39E+04
1 6.95E+04
1 7.04E+04
1 6.47E+04
1 8.22E+04
1 3.91 E+04
1 2.34E+04
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 1.02E+02
1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.45E+04 4.9E-01 1.5E+01 4.8E+01
6.44E+04 6.3E-01 1.5E+01 4.8E+01 10 100
6.36E+04 4.1E-01 1.5E+01 4.8E+01
6.54E+04 4.4E-01 1.5E+01 4.8E+01
6.95E+04 4.6E-01 1.5E+01 4.8E+01
6.38E+04 4.4E-01 1.5E+01 4.8E+01
1.24E+05 2.3E+00 1.5E+01 4.8E+01
6.41 E+04 4.9E-01 1.5E+01 4.8E+01
3.93E+04 4.3E+00 1.5E+01 4.8E+01
6.29E+04 9.5E-02 1.5E+01 4.8E+01
6.40E+04 3.3E-01 1.5E+01 4.8E+01 10 100
6.32E+04 7.3E-01 1.5E+01 4.8E+01
6.75E+04 1.9E-01 1.5E+01 4.8E+01
7.14E+04 5.7E+01 1.5E+01 4.8E+01
6.24E+04 2.3E-01 1.5E+01 4.8E+01
8.20E+04 5.0E-01 1.5E+01 4.8E+01
3.76E+04 6.1E-01 1.5E+01 4.8E+01
2.76E+04 4.9E+00 1.5E+01 4.8E+01
6.04E+04 2.8E-01 1.5E+01 4.8E+01
6.36E+04 2.5E+00 1.5E+01 4.8E+01 10 100
6.39E+04 2.7E-01 1.5E+01 4.8E+01
6.95E+04 3.7E-01 1.5E+01 4.8E+01
7.04E+04 2.4E-01 1.5E+01 4.8E+01
6.47E+04 1.4E-01 1.5E+01 4.8E+01
8.22E+04 1.7E-01 1.5E+01 4.8E+01
3.91 E+04 2.3E-01 1.5E+01 4.8E+01
2.34E+04 1.1E+01 1.5E+01 4.8E+01
7.50E+00 4.1E+02 1.5E+01 4.8E+01
7.50E+00 1.4E+02 1.5E+01 4.8E+01
7.50E+00 6.1E+01 1.5E+01 4.8E+01
7.50E+00 8.7E+01 1.5E+01 4.8E+01
7.50E+00 1.6E+02 1.5E+01 4.8E+01
7.50E+00 1.9E+02 1.5E+01 4.8E+01
7.50E+00 2.6E+01 1.5E+01 4.8E+01
1.02E+02 1.4E+01 1.5E+01 4.8E+01
7.50E+00 1.5E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
6.54E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.49E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.46E+04 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-459
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si SWA-L05-1313-T01-A
Si SWA-L05-1313-T02-A
Si SWA-L05-1313-T03-A
Si SWA-L05-1313-T04-A
Si SWA-L05-1313-T05-A
Si SWA-L05-1313-T06-A
Si SWA-L05-1313-T07-A
Si SWA-L05-1313-T08-A
Si SWA-L05-1313-T09-A
Si SWA-L05-1313-T01-B
Si SWA-L05-1313-T02-B
Si SWA-L05-1313-T03-B
Si SWA-L05-1313-T04-B
Si SWA-L05-1313-T05-B
Si SWA-L05-1313-T06-B
Si SWA-L05-1313-T07-B
Si SWA-L05-1313-T08-B
Si SWA-L05-1313-T09-B
Si SWA-L05-1313-T01-C
Si SWA-L05-1313-T02-C
Si SWA-L05-1313-T03-C
Si SWA-L05-1313-T04-C
Si SWA-L05-1313-T05-C
Si SWA-L05-1313-T06-C
Si SWA-L05-1313-T07-C
Si SWA-L05-1313-T08-C
Si SWA-L05-1313-T09-C
Si SWA-L05-1313-B01-A
Si SWA-L05-1313-B02-A
Si SWA-L05-1313-B03-A
Si SWA-L05-1313-B01-B
Si SWA-L05-1313-B02-B
Si SWA-L05-1313-B03-B
Si SWA-L05-1313-B01-C
Si SWA-L05-1313-B02-C
Si SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.24E+04
1 2.24E+04
1 8.15E+03
1 9.90E+03
1 2.44E+04
1 2.23E+04
1 6.08E+03
1 2.87E+04
1 1.76E+06
1 4.40E+04
1 2.24E+04
1 5.50E+03
1 1.13E+04
1 2.36E+04
1 2.17E+04
1 8.85E+03
1 5.60E+04
1 4.24E+05
1 4.25E+04
1 2.23E+04
1 8.13E+03
1 8.03E+03
1 2.38E+04
1 2.21 E+04
1 1.70E+04
1 6.14E+04
1 2.44E+05
1 8.91 E+00
1 8.38E+00
1 6.35E+03
1 7.07E+01
1 2.17E+01
1 3.59E+03
1 2.59E+01
1 2.28E+01
1 1.64E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.24E+04 3.5E-01 1.1 E+00 3.5E+00
2.24E+04 6.8E-01 1.1 E+00 3.5E+00 1000 100
8.15E+03 8.5E-01 1.1 E+00 3.5E+00
9.90E+03 6.8E-01 1.1 E+00 3.5E+00
2.44E+04 1.9E-01 1.1 E+00 3.5E+00
2.23E+04 1.0E+00 1.1 E+00 3.5E+00
6.08E+03 2.4E+00 1.1 E+00 3.5E+00
2.87E+04 2.6E+00 1.1 E+00 3.5E+00
1.76E+06 4.4E+00 1.1 E+00 3.5E+00
4.40E+04 1.7E+00 1.1 E+00 3.5E+00
2.24E+04 1.1 E+00 1.1 E+00 3.5E+00 1000 100
5.50E+03 1.1 E+00 1.1 E+00 3.5E+00
1.13E+04 1.6E-01 1.1 E+00 3.5E+00
2.36E+04 5.4E+01 1.1 E+00 3.5E+00
2.17E+04 6.9E-01 1.1 E+00 3.5E+00
8.85E+03 4.7E-01 1.1 E+00 3.5E+00
5.60E+04 1.1 E+00 1.1 E+00 3.5E+00
4.24E+05 4.7E+01 1.1 E+00 3.5E+00
4.25E+04 1.3E+00 1.1 E+00 3.5E+00
2.23E+04 1.8E+00 1.1 E+00 3.5E+00 1000 100
8.13E+03 3.1E-01 1.1 E+00 3.5E+00
8.03E+03 4.1E-01 1.1 E+00 3.5E+00
2.38E+04 9.0E-02 1.1 E+00 3.5E+00
2.21E+04 1.1 E+00 1.1 E+00 3.5E+00
1.70E+04 3.7E-01 1.1 E+00 3.5E+00
6.14E+04 4.8E-01 1.1 E+00 3.5E+00
2.44E+05 4.6E+01 1.1 E+00 3.5E+00
8.91E+00 2.7E+01 1.1 E+00 3.5E+00
8.38E+00 2.2E+02 1.1 E+00 3.5E+00
6.35E+03 5.7E+00 1.1 E+00 3.5E+00
7.07E+01 1.6E+01 1.1 E+00 3.5E+00
2.17E+01 1.4E+01 1.1 E+00 3.5E+00
3.59E+03 1.1E+01 1.1 E+00 3.5E+00
2.59E+01 9.2E+00 1.1 E+00 3.5E+00
2.28E+01 1.3E+01 1.1 E+00 3.5E+00
1.64E+03 6.9E+00 1.1 E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.33E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.33E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.33E+04 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-460
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na SWA-L05-1313-T01-A
Na SWA-L05-1313-T02-A
Na SWA-L05-1313-T03-A
Na SWA-L05-1313-T04-A
Na SWA-L05-1313-T05-A
Na SWA-L05-1313-T06-A
Na SWA-L05-1313-T07-A
Na SWA-L05-1313-T08-A
Na SWA-L05-1313-T09-A
Na SWA-L05-1313-T01-B
Na SWA-L05-1313-T02-B
Na SWA-L05-1313-T03-B
Na SWA-L05-1313-T04-B
Na SWA-L05-1313-T05-B
Na SWA-L05-1313-T06-B
Na SWA-L05-1313-T07-B
Na SWA-L05-1313-T08-B
Na SWA-L05-1313-T09-B
Na SWA-L05-1313-T01-C
Na SWA-L05-1313-T02-C
Na SWA-L05-1313-T03-C
Na SWA-L05-1313-T04-C
Na SWA-L05-1313-T05-C
Na SWA-L05-1313-T06-C
Na SWA-L05-1313-T07-C
Na SWA-L05-1313-T08-C
Na SWA-L05-1313-T09-C
Na SWA-L05-1313-B01-A
Na SWA-L05-1313-B02-A
Na SWA-L05-1313-B03-A
Na SWA-L05-1313-B01-B
Na SWA-L05-1313-B02-B
Na SWA-L05-1313-B03-B
Na SWA-L05-1313-B01-C
Na SWA-L05-1313-B02-C
Na SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.69E+05
1 3.91 E+05
1 4.12E+05
1 4. 11 E+05
1 3.98E+05
1 3.89E+05
1 4.98E+05
1 4.00E+05
1 5.46E+05
1 3.64E+05
1 3.87E+05
1 4.06E+05
1 4. 11 E+05
1 3.97E+05
1 3.85E+05
1 4.00E+05
1 3.92E+05
1 4.63E+05
1 3.59E+05
1 3.83E+05
1 4.07E+05
1 4.09E+05
1 3.93E+05
1 3.83E+05
1 3.98E+05
1 3.90E+05
1 4.15E+05
1 1.25E+00 U1/2
1 1.25E+00 U1/2
1 1.71E+04
1 1.25E+00 U1/2
1 1.25E+00 U1/2
1 1.72E+04
1 1.25E+00 U1/2
1 2.49E+03
1 1.68E+04
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.69E+05 1.6E-01 2.5E+00 8.0E+00
3.91E+05 4.1E-02 2.5E+00 8.0E+00 1000 100
4.12E+05 2.6E-01 2.5E+00 8.0E+00
4.11E+05 3.8E-01 2.5E+00 8.0E+00
3.98E+05 1.7E-01 2.5E+00 8.0E+00
3.89E+05 1.1E-01 2.5E+00 8.0E+00
4.98E+05 2.6E-01 2.5E+00 8.0E+00
4.00E+05 5.0E-01 2.5E+00 8.0E+00
5.46E+05 2.4E+00 2.5E+00 8.0E+00
3.64E+05 2.8E-01 2.5E+00 8.0E+00
3.87E+05 1.7E-01 2.5E+00 8.0E+00 1000 100
4.06E+05 1.2E-01 2.5E+00 8.0E+00
4.11E+05 6.7E-02 2.5E+00 8.0E+00
3.97E+05 5.9E+01 2.5E+00 8.0E+00
3.85E+05 2.5E-01 2.5E+00 8.0E+00
4.00E+05 1.4E-01 2.5E+00 8.0E+00
3.92E+05 1.5E-01 2.5E+00 8.0E+00
4.63E+05 9.6E-01 2.5E+00 8.0E+00
3.59E+05 7.2E-01 2.5E+00 8.0E+00
3.83E+05 4.1E-01 2.5E+00 8.0E+00 1000 100
4.07E+05 3.9E-01 2.5E+00 8.0E+00
4.09E+05 1.7E-01 2.5E+00 8.0E+00
3.93E+05 5.3E-01 2.5E+00 8.0E+00
3.83E+05 4.4E-01 2.5E+00 8.0E+00
3.98E+05 1.8E-01 2.5E+00 8.0E+00
3.90E+05 2.5E-01 2.5E+00 8.0E+00
4.15E+05 5.7E+00 2.5E+00 8.0E+00
1.25E+00 1.5E+01 2.5E+00 8.0E+00
1.25E+00 9.7E+01 2.5E+00 8.0E+00
1.71E+04 8.0E-01 2.5E+00 8.0E+00
1.25E+00 1.1E+01 2.5E+00 8.0E+00
1.25E+00 1.1E+01 2.5E+00 8.0E+00
1.72E+04 4.5E-01 2.5E+00 8.0E+00
1.25E+00 1.3E+01 2.5E+00 8.0E+00
2.49E+03 3.5E-01 2.5E+00 8.0E+00
1.68E+04 1.0E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.92E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.88E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.84E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-461
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr SWA-L05-1313-T01-A
Sr SWA-L05-1313-T02-A
Sr SWA-L05-1313-T03-A
Sr SWA-L05-1313-T04-A
Sr SWA-L05-1313-T05-A
Sr SWA-L05-1313-T06-A
Sr SWA-L05-1313-T07-A
Sr SWA-L05-1313-T08-A
Sr SWA-L05-1313-T09-A
Sr SWA-L05-1313-T01-B
Sr SWA-L05-1313-T02-B
Sr SWA-L05-1313-T03-B
Sr SWA-L05-1313-T04-B
Sr SWA-L05-1313-T05-B
Sr SWA-L05-1313-T06-B
Sr SWA-L05-1313-T07-B
Sr SWA-L05-1313-T08-B
Sr SWA-L05-1313-T09-B
Sr SWA-L05-1313-T01-C
Sr SWA-L05-1313-T02-C
Sr SWA-L05-1313-T03-C
Sr SWA-L05-1313-T04-C
Sr SWA-L05-1313-T05-C
Sr SWA-L05-1313-T06-C
Sr SWA-L05-1313-T07-C
Sr SWA-L05-1313-T08-C
Sr SWA-L05-1313-T09-C
Sr SWA-L05-1313-B01-A
Sr SWA-L05-1313-B02-A
Sr SWA-L05-1313-B03-A
Sr SWA-L05-1313-B01-B
Sr SWA-L05-1313-B02-B
Sr SWA-L05-1313-B03-B
Sr SWA-L05-1313-B01-C
Sr SWA-L05-1313-B02-C
Sr SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.14E+02
1 2.09E+02
1 5.82E+03
1 1.11E+04
1 2.42E+02
1 2.10E+02
1 2.52E+04
1 2.77E+04
1 2.95E+04
1 3.13E+02
1 2.14E+02
1 5.85E+03
1 1.12E+04
1 2.45E+02
1 2.20E+02
1 2.64E+04
1 1.99E+04
1 2.35E+04
1 3.18E+02
1 2.15E+02
1 5.87E+03
1 1.15E+04
1 2.48E+02
1 2.18E+02
1 2.68E+04
1 2.05E+04
1 1.84E+04
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 2.34E+01
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.14E+02 1.1E+00 1.0E+00 3.2E+00
2.09E+02 9.1E-02 1.0E+00 3.2E+00 1000 100
5.82E+03 5.4E-01 1.0E+00 3.2E+00
1.11E+04 5.5E-01 1.0E+00 3.2E+00
2.42E+02 7.8E-01 1.0E+00 3.2E+00
2.10E+02 1.2E+00 1.0E+00 3.2E+00
2.52E+04 2.2E+00 1.0E+00 3.2E+00
2.77E+04 1.9E+00 1.0E+00 3.2E+00
2.95E+04 2.7E+00 1.0E+00 3.2E+00
3.13E+02 7.3E-01 1.0E+00 3.2E+00
2.14E+02 1.4E+00 1.0E+00 3.2E+00 1000 100
5.85E+03 5.5E-01 1.0E+00 3.2E+00
1.12E+04 1.1E+00 1.0E+00 3.2E+00
2.45E+02 8.8E+01 1.0E+00 3.2E+00
2.20E+02 5.5E-01 1.0E+00 3.2E+00
2.64E+04 5.6E-01 1.0E+00 3.2E+00
1.99E+04 8.5E-01 1.0E+00 3.2E+00
2.35E+04 2.8E+00 1.0E+00 3.2E+00
3.18E+02 3.0E-01 1.0E+00 3.2E+00
2.15E+02 2.7E+00 1.0E+00 3.2E+00 1000 100
5.87E+03 1.5E+00 1.0E+00 3.2E+00
1.15E+04 8.6E-01 1.0E+00 3.2E+00
2.48E+02 2.5E-01 1.0E+00 3.2E+00
2.18E+02 1.6E+00 1.0E+00 3.2E+00
2.68E+04 7.9E-01 1.0E+00 3.2E+00
2.05E+04 2.0E+00 1.0E+00 3.2E+00
1.84E+04 4.2E+00 1.0E+00 3.2E+00
5.00E-01 5.0E+01 1.0E+00 3.2E+00
5.00E-01 2.2E+01 1.0E+00 3.2E+00
5.00E-01 1.6E+02 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
5.00E-01 5.2E+01 1.0E+00 3.2E+00
5.00E-01 9.2E+01 1.0E+00 3.2E+00
5.00E-01 6.6E+01 1.0E+00 3.2E+00
2.34E+01 2.2E+00 1.0E+00 3.2E+00
5.00E-01 7.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.21E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-462
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S SWA-L05-1313-T01-A
S SWA-L05-1313-T02-A
S SWA-L05-1313-T03-A
S SWA-L05-1313-T04-A
S SWA-L05-1313-T05-A
S SWA-L05-1313-T06-A
S SWA-L05-1313-T07-A
S SWA-L05-1313-T08-A
S SWA-L05-1313-T09-A
S SWA-L05-1313-T01-B
S SWA-L05-1313-T02-B
S SWA-L05-1313-T03-B
S SWA-L05-1313-T04-B
S SWA-L05-1313-T05-B
S SWA-L05-1313-T06-B
S SWA-L05-1313-T07-B
S SWA-L05-1313-T08-B
S SWA-L05-1313-T09-B
S SWA-L05-1313-T01-C
S SWA-L05-1313-T02-C
S SWA-L05-1313-T03-C
S SWA-L05-1313-T04-C
S SWA-L05-1313-T05-C
S SWA-L05-1313-T06-C
S SWA-L05-1313-T07-C
S SWA-L05-1313-T08-C
S SWA-L05-1313-T09-C
S SWA-L05-1313-B01-A
S SWA-L05-1313-B02-A
S SWA-L05-1313-B03-A
S SWA-L05-1313-B01-B
S SWA-L05-1313-B02-B
S SWA-L05-1313-B03-B
S SWA-L05-1313-B01-C
S SWA-L05-1313-B02-C
S SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.50E+05
1 2.80E+05
1 2.32E+05
1 2.39E+05
1 2.85E+05
1 2.77E+05
1 4.35E+05
1 2.81 E+05
1 2.05E+05
1 2.45E+05
1 2.74E+05
1 2.32E+05
1 2.45E+05
1 2.88E+05
1 2.68E+05
1 3.29E+05
1 1.77E+05
1 1.55E+05
1 2.34E+05
1 2.76E+05
1 2.35E+05
1 2.51 E+05
1 2.89E+05
1 2.79E+05
1 3.26E+05
1 1.86E+05
1 1.31 E+05
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 2.43E+02
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.50E+05 3.1E-01 6.8E+00 2.2E+01
2.80E+05 3.3E-01 6.8E+00 2.2E+01 1000 100
2.32E+05 4.9E-01 6.8E+00 2.2E+01
2.39E+05 3.9E-01 6.8E+00 2.2E+01
2.85E+05 4.1E-01 6.8E+00 2.2E+01
2.77E+05 4.3E-01 6.8E+00 2.2E+01
4.35E+05 2.6E+00 6.8E+00 2.2E+01
2.81 E+05 2.4E-01 6.8E+00 2.2E+01
2.05E+05 3.4E+00 6.8E+00 2.2E+01
2.45E+05 1.1E-01 6.8E+00 2.2E+01
2.74E+05 2.8E-01 6.8E+00 2.2E+01 1000 100
2.32E+05 7.3E-01 6.8E+00 2.2E+01
2.45E+05 3.2E-01 6.8E+00 2.2E+01
2.88E+05 5.4E+01 6.8E+00 2.2E+01
2.68E+05 5.5E-02 6.8E+00 2.2E+01
3.29E+05 4.5E-01 6.8E+00 2.2E+01
1.77E+05 2.8E-01 6.8E+00 2.2E+01
1.55E+05 4.4E+00 6.8E+00 2.2E+01
2.34E+05 6.1E-01 6.8E+00 2.2E+01
2.76E+05 2.3E+00 6.8E+00 2.2E+01 1000 100
2.35E+05 3.2E-01 6.8E+00 2.2E+01
2.51 E+05 3.4E-01 6.8E+00 2.2E+01
2.89E+05 4.9E-01 6.8E+00 2.2E+01
2.79E+05 4.9E-01 6.8E+00 2.2E+01
3.26E+05 6.6E-01 6.8E+00 2.2E+01
1.86E+05 3.7E-01 6.8E+00 2.2E+01
1.31 E+05 1.0E+01 6.8E+00 2.2E+01
3.40E+00 9.1E+00 6.8E+00 2.2E+01
3.40E+00 4.3E+01 6.8E+00 2.2E+01
3.40E+00 3.7E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+01 6.8E+00 2.2E+01
3.40E+00 4.6E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+01 6.8E+00 2.2E+01
2.43E+02 1.0E+01 6.8E+00 2.2E+01
3.40E+00 3.2E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.81 E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.75E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.77E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-463
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Tl
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Tl
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Tl
Tl
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Tl
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Tl
Tl
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Tl
Sample Dilutic
SWA-L05-1313-T01-A
SWA-L05-1313-T02-A
SWA-L05-1313-T03-A
SWA-L05-1313-T04-A
SWA-L05-1313-T05-A
SWA-L05-1313-T06-A
SWA-L05-1313-T07-A
SWA-L05-1313-T08-A
SWA-L05-1313-T09-A
SWA-L05-1313-T01-B
SWA-L05-1313-T02-B
SWA-L05-1313-T03-B
SWA-L05-1313-T04-B
SWA-L05-1313-T05-B
SWA-L05-1313-T06-B
SWA-L05-1313-T07-B
SWA-L05-1313-T08-B
SWA-L05-1313-T09-B
SWA-L05-1313-T01-C
SWA-L05-1313-T02-C
SWA-L05-1313-T03-C
SWA-L05-1313-T04-C
SWA-L05-1313-T05-C
SWA-L05-1313-T06-C
SWA-L05-1313-T07-C
SWA-L05-1313-T08-C
SWA-L05-1313-T09-C
SWA-L05-1313-B01-A
SWA-L05-1313-B02-A
SWA-L05-1313-B03-A
SWA-L05-1313-B01-B
SWA-L05-1313-B02-B
SWA-L05-1313-B03-B
SWA-L05-1313-B01-C
SWA-L05-1313-B02-C
SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 8.10E+00 E
1 1.63E+01
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 9.06E+00 E
1 1.21E+01 E
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 8.31 E+00 E
1 1.49E+01
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 6.47E+00 E
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 4.8E+02 4.6E+00 1.5E+01
2.30E+00 2.9E+02 4.6E+00 1.5E+01 10 100
2.30E+00 1.2E+02 4.6E+00 1.5E+01
2.30E+00 6.0E+02 4.6E+00 1.5E+01
2.30E+00 2.6E+01 4.6E+00 1.5E+01
2.30E+00 7.6E+01 4.6E+00 1.5E+01
8.10E+00 9.3E+01 4.6E+00 1.5E+01
1.63E+01 9.5E+00 4.6E+00 1.5E+01
2.30E+00 5.2E+01 4.6E+00 1.5E+01
2.30E+00 1.7E+01 4.6E+00 1.5E+01
2.30E+00 3.2E+02 4.6E+00 1.5E+01 10 100
2.30E+00 4.5E+02 4.6E+00 1.5E+01
2.30E+00 2.5E+02 4.6E+00 1.5E+01
2.30E+00 2.7E+01 4.6E+00 1.5E+01
2.30E+00 3.8E+01 4.6E+00 1.5E+01
9.06E+00 4.3E+01 4.6E+00 1.5E+01
1.21E+01 4.4E+01 4.6E+00 1.5E+01
2.30E+00 1.7E+01 4.6E+00 1.5E+01
2.30E+00 1.3E+03 4.6E+00 1.5E+01
2.30E+00 1.6E+02 4.6E+00 1.5E+01 10 100
2.30E+00 6.8E+01 4.6E+00 1.5E+01
2.30E+00 2.9E+02 4.6E+00 1.5E+01
2.30E+00 3.3E+01 4.6E+00 1.5E+01
2.30E+00 1.7E+02 4.6E+00 1.5E+01
8.31 E+00 2.4E+01 4.6E+00 1.5E+01
1.49E+01 1.9E+01 4.6E+00 1.5E+01
2.30E+00 1.2E+01 4.6E+00 1.5E+01
2.30E+00 7.1E+01 4.6E+00 1.5E+01
2.30E+00 2.5E+01 4.6E+00 1.5E+01
2.30E+00 7.0E+01 4.6E+00 1.5E+01
2.30E+00 1.9E+01 4.6E+00 1.5E+01
2.30E+00 6.4E+02 4.6E+00 1.5E+01
6.47E+00 2.6E+01 4.6E+00 1.5E+01
2.30E+00 5.4E+01 4.6E+00 1.5E+01
2.30E+00 1.3E+01 4.6E+00 1.5E+01
2.30E+00 8.4E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.82E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.53E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.74E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-464
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
SWA-L05-1313-T01-A
SWA-L05-1313-T02-A
SWA-L05-1313-T03-A
SWA-L05-1313-T04-A
SWA-L05-1313-T05-A
SWA-L05-1313-T06-A
SWA-L05-1313-T07-A
SWA-L05-1313-T08-A
SWA-L05-1313-T09-A
SWA-L05-1313-T01-B
SWA-L05-1313-T02-B
SWA-L05-1313-T03-B
SWA-L05-1313-T04-B
SWA-L05-1313-T05-B
SWA-L05-1313-T06-B
SWA-L05-1313-T07-B
SWA-L05-1313-T08-B
SWA-L05-1313-T09-B
SWA-L05-1313-T01-C
SWA-L05-1313-T02-C
SWA-L05-1313-T03-C
SWA-L05-1313-T04-C
SWA-L05-1313-T05-C
SWA-L05-1313-T06-C
SWA-L05-1313-T07-C
SWA-L05-1313-T08-C
SWA-L05-1313-T09-C
SWA-L05-1313-B01-A
SWA-L05-1313-B02-A
SWA-L05-1313-B03-A
SWA-L05-1313-B01-B
SWA-L05-1313-B02-B
SWA-L05-1313-B03-B
SWA-L05-1313-B01-C
SWA-L05-1313-B02-C
SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 5.36E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.10E+01
1 1.58E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 4.84E+01
1 1.07E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.05E+01
1 1.00E+00 U1/2
1 2.29E+00 E
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00 10 100
1.00E+00 2.3E+02 2.0E+00 6.4E+00
1.00E+00 5.4E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 8.2E+01 2.0E+00 6.4E+00
5.36E+04 6.3E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00 10 100
1.00E+00 9.5E+02 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.10E+01 5.2E+00 2.0E+00 6.4E+00
1.58E+04 4.1E+01 2.0E+00 6.4E+00
1.00E+00 4.8E+00 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00 10 100
1.00E+00 3.2E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
4.84E+01 1.2E+00 2.0E+00 6.4E+00
1.07E+04 3.4E+01 2.0E+00 6.4E+00
1.00E+00 8.7E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.05E+01 8.7E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
2.29E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.27E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.35E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-465
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V SWA-L05-1313-T01-A
V SWA-L05-1313-T02-A
V SWA-L05-1313-T03-A
V SWA-L05-1313-T04-A
V SWA-L05-1313-T05-A
V SWA-L05-1313-T06-A
V SWA-L05-1313-T07-A
V SWA-L05-1313-T08-A
V SWA-L05-1313-T09-A
V SWA-L05-1313-T01-B
V SWA-L05-1313-T02-B
V SWA-L05-1313-T03-B
V SWA-L05-1313-T04-B
V SWA-L05-1313-T05-B
V SWA-L05-1313-T06-B
V SWA-L05-1313-T07-B
V SWA-L05-1313-T08-B
V SWA-L05-1313-T09-B
V SWA-L05-1313-T01-C
V SWA-L05-1313-T02-C
V SWA-L05-1313-T03-C
V SWA-L05-1313-T04-C
V SWA-L05-1313-T05-C
V SWA-L05-1313-T06-C
V SWA-L05-1313-T07-C
V SWA-L05-1313-T08-C
V SWA-L05-1313-T09-C
V SWA-L05-1313-B01-A
V SWA-L05-1313-B02-A
V SWA-L05-1313-B03-A
V SWA-L05-1313-B01-B
V SWA-L05-1313-B02-B
V SWA-L05-1313-B03-B
V SWA-L05-1313-B01-C
V SWA-L05-1313-B02-C
V SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.62E+02
1 2.93E+02
1 9.05E+01
1 1.16E+02
1 3.14E+02
1 2.87E+02
1 1.80E+02
1 1.32E+02
1 2.09E+03
1 3.61 E+02
1 2.83E+02
1 8.67E+01
1 1.19E+02
1 3.10E+02
1 2.76E+02
1 1.61 E+02
1 7.84E+01
1 1.59E+03
1 3.38E+02
1 2.83E+02
1 8.96E+01
1 1.12E+02
1 3.19E+02
1 2.87E+02
1 1.51 E+02
1 8.67E+01
1 1.19E+03
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 2.82E+00 E
1 7.50E-01 U1/2
1 2.50E+00 E
1 2.31E+OOE
1 7.50E-01 U1/2
1 2.02E+00 E
1 2.23E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.62E+02 1.3E+00 1.5E+00 4.8E+00
2.93E+02 4.5E-01 1.5E+00 4.8E+00 10 100
9.05E+01 1.4E+00 1.5E+00 4.8E+00
1.16E+02 5.5E+00 1.5E+00 4.8E+00
3.14E+02 1.3E+00 1.5E+00 4.8E+00
2.87E+02 8.1E-01 1.5E+00 4.8E+00
1.80E+02 1.7E+00 1.5E+00 4.8E+00
1.32E+02 3.4E+00 1.5E+00 4.8E+00
2.09E+03 1.9E+00 1.5E+00 4.8E+00
3.61 E+02 1.0E+00 1.5E+00 4.8E+00
2.83E+02 1.4E+00 1.5E+00 4.8E+00 10 100
8.67E+01 9.7E-01 1.5E+00 4.8E+00
1.19E+02 3.2E+00 1.5E+00 4.8E+00
3.10E+02 4.5E+01 1.5E+00 4.8E+00
2.76E+02 5.7E-01 1.5E+00 4.8E+00
1.61 E+02 1.1E+00 1.5E+00 4.8E+00
7.84E+01 1.4E+00 1.5E+00 4.8E+00
1.59E+03 5.2E+00 1.5E+00 4.8E+00
3.38E+02 7.9E-01 1.5E+00 4.8E+00
2.83E+02 2.6E+00 1.5E+00 4.8E+00 10 100
8.96E+01 1.7E+00 1.5E+00 4.8E+00
1.12E+02 7.4E-01 1.5E+00 4.8E+00
3.19E+02 1.7E+00 1.5E+00 4.8E+00
2.87E+02 9.0E-01 1.5E+00 4.8E+00
1.51 E+02 2.9E-01 1.5E+00 4.8E+00
8.67E+01 1.3E+00 1.5E+00 4.8E+00
1.19E+03 9.4E+00 1.5E+00 4.8E+00
7.50E-01 3.3E+01 1.5E+00 4.8E+00
7.50E-01 2.3E+01 1.5E+00 4.8E+00
2.82E+00 1.9E+01 1.5E+00 4.8E+00
7.50E-01 2.5E+01 1.5E+00 4.8E+00
2.50E+00 5.1E+01 1.5E+00 4.8E+00
2.31 E+00 2.0E+01 1.5E+00 4.8E+00
7.50E-01 6.0E+01 1.5E+00 4.8E+00
2.02E+00 3.6E+01 1.5E+00 4.8E+00
2.23E+00 6.8E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.17E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-466
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn SWA-L05-1313-T01-A
Zn SWA-L05-1313-T02-A
Zn SWA-L05-1313-T03-A
Zn SWA-L05-1313-T04-A
Zn SWA-L05-1313-T05-A
Zn SWA-L05-1313-T06-A
Zn SWA-L05-1313-T07-A
Zn SWA-L05-1313-T08-A
Zn SWA-L05-1313-T09-A
Zn SWA-L05-1313-T01-B
Zn SWA-L05-1313-T02-B
Zn SWA-L05-1313-T03-B
Zn SWA-L05-1313-T04-B
Zn SWA-L05-1313-T05-B
Zn SWA-L05-1313-T06-B
Zn SWA-L05-1313-T07-B
Zn SWA-L05-1313-T08-B
Zn SWA-L05-1313-T09-B
Zn SWA-L05-1313-T01-C
Zn SWA-L05-1313-T02-C
Zn SWA-L05-1313-T03-C
Zn SWA-L05-1313-T04-C
Zn SWA-L05-1313-T05-C
Zn SWA-L05-1313-T06-C
Zn SWA-L05-1313-T07-C
Zn SWA-L05-1313-T08-C
Zn SWA-L05-1313-T09-C
Zn SWA-L05-1313-B01-A
Zn SWA-L05-1313-B02-A
Zn SWA-L05-1313-B03-A
Zn SWA-L05-1313-B01-B
Zn SWA-L05-1313-B02-B
Zn SWA-L05-1313-B03-B
Zn SWA-L05-1313-B01-C
Zn SWA-L05-1313-B02-C
Zn SWA-L05-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.05E+01
1 2.39E+00 E
1 5.00E-01 U1/2
1 1.13E+00 E
1 2.11E+OOE
1 2.93E+00 E
1 3.15E+00 E
1 5.86E+02
1 2.10E+03
1 8.34E+00
1 1.80E+00 E
1 5.00E-01 U1/2
1 1.44E+00 E
1 1.91E+00 E
1 2.06E+00 E
1 2.88E+00 E
1 1.22E+03
1 1.69E+03
1 7.16E+00
1 2.24E+00 E
1 5.00E-01 U1/2
1 1.09E+00 E
1 1.61E+OOE
1 2.12E+00 E
1 2.49E+00 E
1 1.18E+03
1 1.38E+03
1 5.00E-01 U1/2
1 2.12E+00 E
1 1.98E+00 E
1 5.00E-01 U1/2
1 2.97E+00 E
1 2.63E+00 E
1 5.00E-01 U1/2
1 3.66E+00
1 3.69E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.05E+01 1.3E+00 1.0E+00 3.2E+00
2.39E+00 1.1E+01 1.0E+00 3.2E+00 10 100
5.00E-01 5.3E+01 1.0E+00 3.2E+00
1.13E+00 1.4E+01 1.0E+00 3.2E+00
2.11E+00 9.5E+00 1.0E+00 3.2E+00
2.93E+00 5.5E+00 1.0E+00 3.2E+00
3.15E+00 1.5E+01 1.0E+00 3.2E+00
5.86E+02 3.6E-01 1.0E+00 3.2E+00
2.10E+03 1.6E+00 1.0E+00 3.2E+00
8.34E+00 1.2E+00 1.0E+00 3.2E+00
1.80E+00 5.1E+00 1.0E+00 3.2E+00 10 100
5.00E-01 1.9E+01 1.0E+00 3.2E+00
1.44E+00 2.9E+01 1.0E+00 3.2E+00
1.91E+00 1.3E+02 1.0E+00 3.2E+00
2.06E+00 7.6E+00 1.0E+00 3.2E+00
2.88E+00 1.4E+01 1.0E+00 3.2E+00
1.22E+03 2.1E+00 1.0E+00 3.2E+00
1.69E+03 4.6E+00 1.0E+00 3.2E+00
7.16E+00 2.3E+00 1.0E+00 3.2E+00
2.24E+00 5.5E+00 1.0E+00 3.2E+00 10 100
5.00E-01 7.6E+01 1.0E+00 3.2E+00
1.09E+00 1.3E+01 1.0E+00 3.2E+00
1.61E+00 3.3E+01 1.0E+00 3.2E+00
2.12E+00 1.0E+01 1.0E+00 3.2E+00
2.49E+00 2.9E-01 1.0E+00 3.2E+00
1.18E+03 8.7E-01 1.0E+00 3.2E+00
1.38E+03 1.1E+01 1.0E+00 3.2E+00
5.00E-01 8.9E+01 1.0E+00 3.2E+00
2.12E+00 1.2E+02 1.0E+00 3.2E+00
1.98E+00 4.7E+01 1.0E+00 3.2E+00
5.00E-01 1.7E+03 1.0E+00 3.2E+00
2.97E+00 5.2E+00 1.0E+00 3.2E+00
2.63E+00 1.6E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00
3.66E+00 5.3E-01 1.0E+00 3.2E+00
3.69E+00 1.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.96E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.41 E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.63E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/11 12:48 PM EPA Interlab 105 1313-1316 SWA
3/7/11 12:50 PM EPA Interlab LOS 1313-1316SWA
3/7/11 12:52 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:53 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:55 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:57 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:58 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:00 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:02 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:13 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:15 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:16 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:18 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:20 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:21 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:23 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:25 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:26 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:28 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:30 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:31 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:33 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:36 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:38 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 1:41 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:34 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:35 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:37 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:39 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:40 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:42 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:43 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:45 PM EPA Interlab LOS 1313-1316 SWA
3/7/11 12:47 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                          1-467
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample
Sample Dilution Cone. Qualifier
ug/L
SWA-L06-1313-T01-A 1 1.64E+05
SWA-L06-1313-T02-A 1 1.19E+04
SWA-L06-1313-T03-A 1 4.26E+02
SWA-L06-1313-T04-A 1 9.73E+01
SWA-L06-1313-T05-A 1 4.18E+01
SWA-L06-1313-T06-A 1 8.28E+00
SWA-L06-1313-T07-A 1 3.73E+02
SWA-L06-1313-T08-A 1 2.69E+05
SWA-L06-1313-T09-A 1 4.80E+05
SWA-L06-1313-T10-A 1 3.86E+04
SWA-L06-1313-T01-B 1 1.66E+05
SWA-L06-1313-T02-B 1 1.27E+04
SWA-L06-1313-T03-B 1 4.93E+02
SWA-L06-1313-T04-B 1 1.09E+02
SWA-L06-1313-T05-B 1 5.07E+01
SWA-L06-1313-T06-B 1 8.17E+00
SWA-L06-1313-T07-B 1 4.63E+02
SWA-L06-1313-T08-B 1 2.89E+05
SWA-L06-1313-T09-B 1 7.71E+05
SWA-L06-1313-T10-B 1 3.98E+04
SWA-L06-1313-T01-C 1 1.58E+05
SWA-L06-1313-T02-C 1 1.33E+04
SWA-L06-1313-T03-C 1 5.12E+02
SWA-L06-1313-T04-C 1 1.10E+02
SWA-L06-1313-T05-C 1 5.14E+01
SWA-L06-1313-T06-C 1 9.59E+00
SWA-L06-1313-T07-C 1 3.01 E+02
SWA-L06-1313-T08-C 1 2.89E+05
SWA-L06-1313-T09-C 1 7.59E+05
SWA-L06-1313-T10-C 1 3.91E+04
SWA-L06-1313-B01-A 1 3.84E+04
SWA-L06-1313-B02-A 1 2.57E+00 E
SWA-L06-1313-B03-A 1 8.98E+00
SWA-L06-1313-B01-B 1 1.83E+00 E
SWA-L06-1313-B02-B 1 7.85E+00
SWA-L06-1313-B03-B 1 9.23E+00
SWA-L06-1313-B01-C 1 2.86E+00 E
SWA-L06-1313-B02-C 1 3.37E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.64E+05 2.8E-01 1.0E+00 3.2E+00
1.19E+04 7.6E+00 1.0E+00 3.2E+00 1000 100
4.26E+02 1.5E+00 1.0E+00 3.2E+00
9.73E+01 3.7E+00 1.0E+00 3.2E+00
4.18E+01 2.1E+01 1.0E+00 3.2E+00
8.28E+00 4.6E+01 1.0E+00 3.2E+00
3.73E+02 4.2E+00 1.0E+00 3.2E+00
2.69E+05 1.6E+00 1.0E+00 3.2E+00
4.80E+05 7.7E+01 1.0E+00 3.2E+00
3.86E+04 4.7E+01 1.0E+00 3.2E+00
1.66E+05 5.8E-01 1.0E+00 3.2E+00
1.27E+04 7.1E-01 1.0E+00 3.2E+00 1000 100
4.93E+02 3.3E+00 1.0E+00 3.2E+00
1.09E+02 5.7E+00 1.0E+00 3.2E+00
5.07E+01 9.8E+00 1.0E+00 3.2E+00
8.17E+00 1.6E+01 1.0E+00 3.2E+00
4.63E+02 3.2E+00 1.0E+00 3.2E+00
2.89E+05 2.6E+00 1.0E+00 3.2E+00
7.71 E+05 8.9E-01 1.0E+00 3.2E+00
3.98E+04 1.6E-01 1.0E+00 3.2E+00
1.58E+05 3.0E-01 1.0E+00 3.2E+00
1.33E+04 1.4E+00 1.0E+00 3.2E+00 1000 100
5.12E+02 8.8E-01 1.0E+00 3.2E+00
1.10E+02 1.5E+00 1.0E+00 3.2E+00
5.14E+01 2.1E+01 1.0E+00 3.2E+00
9.59E+00 1.7E+00 1.0E+00 3.2E+00
3.01 E+02 5.5E+01 1.0E+00 3.2E+00
2.89E+05 3.1E-01 1.0E+00 3.2E+00
7.59E+05 1.2E+00 1.0E+00 3.2E+00
3.91 E+04 1.9E-01 1.0E+00 3.2E+00
3.84E+04 5.2E-01 1.0E+00 3.2E+00
2.57E+00 8.5E+01 1.0E+00 3.2E+00
8.98E+00 6.0E+01 1.0E+00 3.2E+00
1.83E+00 9.3E+01 1.0E+00 3.2E+00
7.85E+00 2.9E+01 1.0E+00 3.2E+00
9.23E+00 3.7E+01 1.0E+00 3.2E+00
2.86E+00 1.0E+02 1.0E+00 3.2E+00
3.37E+00 6.0E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.29E+04 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.38E+04 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.42E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316SWA
                                                                                                                                                                                     1-468
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb SWA-L06-1313-T01-A
Sb SWA-L06-1313-T02-A
Sb SWA-L06-1313-T03-A
Sb SWA-L06-1313-T04-A
Sb SWA-L06-1313-T05-A
Sb SWA-L06-1313-T06-A
Sb SWA-L06-1313-T07-A
Sb SWA-L06-1313-T08-A
Sb SWA-L06-1313-T09-A
Sb SWA-L06-1313-T10-A
Sb SWA-L06-1313-T01-B
Sb SWA-L06-1313-T02-B
Sb SWA-L06-1313-T03-B
Sb SWA-L06-1313-T04-B
Sb SWA-L06-1313-T05-B
Sb SWA-L06-1313-T06-B
Sb SWA-L06-1313-T07-B
Sb SWA-L06-1313-T08-B
Sb SWA-L06-1313-T09-B
Sb SWA-L06-1313-T10-B
Sb SWA-L06-1313-T01-C
Sb SWA-L06-1313-T02-C
Sb SWA-L06-1313-T03-C
Sb SWA-L06-1313-T04-C
Sb SWA-L06-1313-T05-C
Sb SWA-L06-1313-T06-C
Sb SWA-L06-1313-T07-C
Sb SWA-L06-1313-T08-C
Sb SWA-L06-1313-T09-C
Sb SWA-L06-1313-T10-C
Sb SWA-L06-1313-B01-A
Sb SWA-L06-1313-B02-A
Sb SWA-L06-1313-B03-A
Sb SWA-L06-1313-B01-B
Sb SWA-L06-1313-B02-B
Sb SWA-L06-1313-B03-B
Sb SWA-L06-1313-B01-C
Sb SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.34E+03
1 2.81 E+03
1 1.27E+03
1 1.33E+03
1 1.26E+03
1 1.03E+03
1 7.68E+02
1 2.69E+02
1 2.41E+04
1 4.07E+03
1 1.31 E+03
1 3. 11 E+03
1 1.09E+03
1 1.39E+03
1 1.15E+03
1 9.57E+02
1 7.56E+02
1 2.45E+02
1 3.77E+04
1 4.42E+03
1 1.72E+03
1 3.36E+03
1 1.25E+03
1 1.45E+03
1 9.85E+02
1 9.13E+02
1 7.25E+02
1 2.46E+02
1 2.65E+04
1 4.08E+03
1 3.96E+03
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.34E+03 1.4E+00 7.5E+00 2.4E+01
2.81E+03 7.3E+00 7.5E+00 2.4E+01 10 100
1.27E+03 6.3E-01 7.5E+00 2.4E+01
1.33E+03 4.4E+00 7.5E+00 2.4E+01
1.26E+03 1.2E+00 7.5E+00 2.4E+01
1.03E+03 1.3E+00 7.5E+00 2.4E+01
7.68E+02 2.4E+00 7.5E+00 2.4E+01
2.69E+02 2.7E+00 7.5E+00 2.4E+01
2.41 E+04 6.7E+01 7.5E+00 2.4E+01
4.07E+03 4.8E+01 7.5E+00 2.4E+01
1.31 E+03 1.9E-01 7.5E+00 2.4E+01
3.11E+03 3.4E-01 7.5E+00 2.4E+01 10 100
1.09E+03 4.1E+00 7.5E+00 2.4E+01
1.39E+03 1.4E+00 7.5E+00 2.4E+01
1.15E+03 1.2E+00 7.5E+00 2.4E+01
9.57E+02 9.4E+01 7.5E+00 2.4E+01
7.56E+02 3.3E+00 7.5E+00 2.4E+01
2.45E+02 3.0E+00 7.5E+00 2.4E+01
3.77E+04 1.3E+00 7.5E+00 2.4E+01
4.42E+03 2.3E-01 7.5E+00 2.4E+01
1.72E+03 5.1E-01 7.5E+00 2.4E+01
3.36E+03 1.3E+00 7.5E+00 2.4E+01 10 100
1.25E+03 1.0E+00 7.5E+00 2.4E+01
1.45E+03 1.4E+00 7.5E+00 2.4E+01
9.85E+02 5.4E+00 7.5E+00 2.4E+01
9.13E+02 1.8E+00 7.5E+00 2.4E+01
7.25E+02 7.3E+01 7.5E+00 2.4E+01
2.46E+02 6.2E+00 7.5E+00 2.4E+01
2.65E+04 2.5E+00 7.5E+00 2.4E+01
4.08E+03 7.7E-01 7.5E+00 2.4E+01
3.96E+03 1.3E+00 7.5E+00 2.4E+01
3.75E+00 1.9E+02 7.5E+00 2.4E+01
3.75E+00 4.3E+01 7.5E+00 2.4E+01
3.75E+00 6.3E+01 7.5E+00 2.4E+01
3.75E+00 6.4E+01 7.5E+00 2.4E+01
3.75E+00 8.9E+01 7.5E+00 2.4E+01
3.75E+00 6.8E+01 7.5E+00 2.4E+01
3.75E+00 1.9E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.88E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.01 E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.25E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-469
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As SWA-L06-1313-T01-A
As SWA-L06-1313-T02-A
As SWA-L06-1313-T03-A
As SWA-L06-1313-T04-A
As SWA-L06-1313-T05-A
As SWA-L06-1313-T06-A
As SWA-L06-1313-T07-A
As SWA-L06-1313-T08-A
As SWA-L06-1313-T09-A
As SWA-L06-1313-T10-A
As SWA-L06-1313-T01-B
As SWA-L06-1313-T02-B
As SWA-L06-1313-T03-B
As SWA-L06-1313-T04-B
As SWA-L06-1313-T05-B
As SWA-L06-1313-T06-B
As SWA-L06-1313-T07-B
As SWA-L06-1313-T08-B
As SWA-L06-1313-T09-B
As SWA-L06-1313-T10-B
As SWA-L06-1313-T01-C
As SWA-L06-1313-T02-C
As SWA-L06-1313-T03-C
As SWA-L06-1313-T04-C
As SWA-L06-1313-T05-C
As SWA-L06-1313-T06-C
As SWA-L06-1313-T07-C
As SWA-L06-1313-T08-C
As SWA-L06-1313-T09-C
As SWA-L06-1313-T10-C
As SWA-L06-1313-B01-A
As SWA-L06-1313-B02-A
As SWA-L06-1313-B03-A
As SWA-L06-1313-B01-B
As SWA-L06-1313-B02-B
As SWA-L06-1313-B03-B
As SWA-L06-1313-B01-C
As SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.26E+04
1 8.94E+02
1 1.34E+02
1 3.41 E+02
1 2.05E+02
1 2.45E+02
1 2.78E+02
1 1.87E+03
1 1.43E+04
1 5.18E+03
1 2.28E+04
1 9.71 E+02
1 1.25E+02
1 3.20E+02
1 1.89E+02
1 2.63E+02
1 3.75E+02
1 1.87E+03
1 2.25E+04
1 5.16E+03
1 2.16E+04
1 1.01E+03
1 1.43E+02
1 3.61 E+02
1 1.78E+02
1 2.28E+02
1 2.54E+02
1 1.85E+03
1 1.65E+04
1 5.17E+03
1 5.25E+03
1 1.14E+01 E
1 1.18E+01 E
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.26E+04 2.5E-01 1.1E+01 3.5E+01
8.94E+02 6.1E+00 1.1E+01 3.5E+01 10 100
1.34E+02 1.4E+01 1.1E+01 3.5E+01
3.41E+02 7.0E+00 1.1E+01 3.5E+01
2.05E+02 1.0E+01 1.1E+01 3.5E+01
2.45E+02 1.3E+00 1.1E+01 3.5E+01
2.78E+02 2.2E+00 1.1E+01 3.5E+01
1.87E+03 6.3E-01 1.1E+01 3.5E+01
1.43E+04 7.1E+01 1.1E+01 3.5E+01
5.18E+03 5.5E+01 1.1E+01 3.5E+01
2.28E+04 7.9E-01 1.1E+01 3.5E+01
9.71E+02 2.0E+00 1.1E+01 3.5E+01 10 100
1.25E+02 1.2E+01 1.1E+01 3.5E+01
3.20E+02 1.5E+00 1.1E+01 3.5E+01
1.89E+02 1.6E+01 1.1E+01 3.5E+01
2.63E+02 9.0E+01 1.1E+01 3.5E+01
3.75E+02 4.5E+00 1.1E+01 3.5E+01
1.87E+03 9.9E-01 1.1E+01 3.5E+01
2.25E+04 2.0E-01 1.1E+01 3.5E+01
5.16E+03 1.3E-01 1.1E+01 3.5E+01
2.16E+04 6.8E-01 1.1E+01 3.5E+01
1.01E+03 2.7E+00 1.1E+01 3.5E+01 10 100
1.43E+02 1.3E+01 1.1E+01 3.5E+01
3.61E+02 6.9E+00 1.1E+01 3.5E+01
1.78E+02 7.6E+00 1.1E+01 3.5E+01
2.28E+02 1.0E+01 1.1E+01 3.5E+01
2.54E+02 6.1E+01 1.1E+01 3.5E+01
1.85E+03 6.6E-01 1.1E+01 3.5E+01
1.65E+04 1.4E+00 1.1E+01 3.5E+01
5.17E+03 2.1E-01 1.1E+01 3.5E+01
5.25E+03 6.0E-01 1.1E+01 3.5E+01
1.14E+01 2.7E+01 1.1E+01 3.5E+01
1.18E+01 4.0E+01 1.1E+01 3.5E+01
5.50E+00 5.5E+01 1.1E+01 3.5E+01
5.50E+00 5.2E+01 1.1E+01 3.5E+01
5.50E+00 1.9E+01 1.1E+01 3.5E+01
5.50E+00 2.0E+01 1.1E+01 3.5E+01
5.50E+00 4.0E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.07E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.17E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.20E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-470
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B SWA-L06-1313-T01-A
B SWA-L06-1313-T02-A
B SWA-L06-1313-T03-A
B SWA-L06-1313-T04-A
B SWA-L06-1313-T05-A
B SWA-L06-1313-T06-A
B SWA-L06-1313-T07-A
B SWA-L06-1313-T08-A
B SWA-L06-1313-T09-A
B SWA-L06-1313-T10-A
B SWA-L06-1313-T01-B
B SWA-L06-1313-T02-B
B SWA-L06-1313-T03-B
B SWA-L06-1313-T04-B
B SWA-L06-1313-T05-B
B SWA-L06-1313-T06-B
B SWA-L06-1313-T07-B
B SWA-L06-1313-T08-B
B SWA-L06-1313-T09-B
B SWA-L06-1313-T10-B
B SWA-L06-1313-T01-C
B SWA-L06-1313-T02-C
B SWA-L06-1313-T03-C
B SWA-L06-1313-T04-C
B SWA-L06-1313-T05-C
B SWA-L06-1313-T06-C
B SWA-L06-1313-T07-C
B SWA-L06-1313-T08-C
B SWA-L06-1313-T09-C
B SWA-L06-1313-T10-C
B SWA-L06-1313-B01-A
B SWA-L06-1313-B02-A
B SWA-L06-1313-B03-A
B SWA-L06-1313-B01-B
B SWA-L06-1313-B02-B
B SWA-L06-1313-B03-B
B SWA-L06-1313-B01-C
B SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.71E+03
1 6.13E+02
1 1.04E+03
1 1.67E+03
1 2.26E+03
1 3.52E+03
1 4.90E+03
1 4.88E+03
1 3.67E+03
1 1.15E+03
1 1.73E+03
1 7.12E+02
1 9.65E+02
1 1.76E+03
1 2.25E+03
1 3.15E+03
1 4.94E+03
1 4.75E+03
1 5.02E+03
1 1.15E+03
1 1.70E+03
1 7.14E+02
1 1.05E+03
1 1.74E+03
1 2.12E+03
1 3.20E+03
1 4.38E+03
1 4.79E+03
1 4.91 E+03
1 1.10E+03
1 1.11E+03
1 1.89E+01
1 2.45E+01
1 9.80E+00
1 1.25E+01
1 1.17E+01
1 8.54E+00
1 9.53E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.71 E+03 4.4E-01 1.0E+00 3.2E+00
6.13E+02 7.5E+00 1.0E+00 3.2E+00 1000 100
1.04E+03 2.6E-01 1.0E+00 3.2E+00
1.67E+03 4.0E+00 1.0E+00 3.2E+00
2.26E+03 5.7E-01 1.0E+00 3.2E+00
3.52E+03 1.1E+00 1.0E+00 3.2E+00
4.90E+03 4.5E-01 1.0E+00 3.2E+00
4.88E+03 5.0E-01 1.0E+00 3.2E+00
3.67E+03 6.8E+01 1.0E+00 3.2E+00
1.15E+03 2.3E+01 1.0E+00 3.2E+00
1.73E+03 6.2E-01 1.0E+00 3.2E+00
7.12E+02 8.2E-01 1.0E+00 3.2E+00 1000 100
9.65E+02 3.7E+00 1.0E+00 3.2E+00
1.76E+03 7.5E-01 1.0E+00 3.2E+00
2.25E+03 2.4E-01 1.0E+00 3.2E+00
3.15E+03 9.0E+01 1.0E+00 3.2E+00
4.94E+03 9.9E-01 1.0E+00 3.2E+00
4.75E+03 5.2E-01 1.0E+00 3.2E+00
5.02E+03 1.6E+00 1.0E+00 3.2E+00
1.15E+03 3.3E-01 1.0E+00 3.2E+00
1.70E+03 1.5E-01 1.0E+00 3.2E+00
7.14E+02 6.9E-01 1.0E+00 3.2E+00 1000 100
1.05E+03 4.7E-01 1.0E+00 3.2E+00
1.74E+03 7.6E-01 1.0E+00 3.2E+00
2.12E+03 5.4E+00 1.0E+00 3.2E+00
3.20E+03 2.4E+00 1.0E+00 3.2E+00
4.38E+03 1.8E+01 1.0E+00 3.2E+00
4.79E+03 7.4E-01 1.0E+00 3.2E+00
4.91 E+03 2.5E+00 1.0E+00 3.2E+00
1.10E+03 5.8E-01 1.0E+00 3.2E+00
1.11E+03 1.5E+00 1.0E+00 3.2E+00
1.89E+01 2.2E+00 1.0E+00 3.2E+00
2.45E+01 1.5E+00 1.0E+00 3.2E+00
9.80E+00 3.1E+00 1.0E+00 3.2E+00
1.25E+01 1.3E+01 1.0E+00 3.2E+00
1.17E+01 1.5E+01 1.0E+00 3.2E+00
8.54E+00 6.0E+00 1.0E+00 3.2E+00
9.53E+00 1.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.76E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.89E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.85E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-471
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba SWA-L06-1313-T01-A
Ba SWA-L06-1313-T02-A
Ba SWA-L06-1313-T03-A
Ba SWA-L06-1313-T04-A
Ba SWA-L06-1313-T05-A
Ba SWA-L06-1313-T06-A
Ba SWA-L06-1313-T07-A
Ba SWA-L06-1313-T08-A
Ba SWA-L06-1313-T09-A
Ba SWA-L06-1313-T10-A
Ba SWA-L06-1313-T01-B
Ba SWA-L06-1313-T02-B
Ba SWA-L06-1313-T03-B
Ba SWA-L06-1313-T04-B
Ba SWA-L06-1313-T05-B
Ba SWA-L06-1313-T06-B
Ba SWA-L06-1313-T07-B
Ba SWA-L06-1313-T08-B
Ba SWA-L06-1313-T09-B
Ba SWA-L06-1313-T10-B
Ba SWA-L06-1313-T01-C
Ba SWA-L06-1313-T02-C
Ba SWA-L06-1313-T03-C
Ba SWA-L06-1313-T04-C
Ba SWA-L06-1313-T05-C
Ba SWA-L06-1313-T06-C
Ba SWA-L06-1313-T07-C
Ba SWA-L06-1313-T08-C
Ba SWA-L06-1313-T09-C
Ba SWA-L06-1313-T10-C
Ba SWA-L06-1313-B01-A
Ba SWA-L06-1313-B02-A
Ba SWA-L06-1313-B03-A
Ba SWA-L06-1313-B01-B
Ba SWA-L06-1313-B02-B
Ba SWA-L06-1313-B03-B
Ba SWA-L06-1313-B01-C
Ba SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 6.17E+02
1 2.74E+02
1 9.74E+02
1 9.93E+02
1 1.09E+03
1 1.26E+03
1 1.55E+03
1 6.18E+02
1 6.93E+02
1 1.63E+02
1 6.15E+02
1 2.90E+02
1 8.34E+02
1 1.00E+03
1 1.06E+03
1 1.25E+03
1 1.48E+03
1 6.13E+02
1 7.02E+02
1 1.79E+02
1 5.60E+02
1 3.33E+02
1 8.77E+02
1 1.11E+03
1 9.68E+02
1 1.32E+03
1 1.28E+03
1 5.95E+02
1 7.87E+02
1 1.59E+02
1 1.61E+02
1 1.29E+00 E
1 3.84E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.17E+02 7.8E-01 1.0E+00 3.2E+00
2.74E+02 6.8E+00 1.0E+00 3.2E+00 10 100
9.74E+02 6.7E-01 1.0E+00 3.2E+00
9.93E+02 3.8E+00 1.0E+00 3.2E+00
1.09E+03 4.9E-01 1.0E+00 3.2E+00
1.26E+03 1.2E+00 1.0E+00 3.2E+00
1.55E+03 6.3E-01 1.0E+00 3.2E+00
6.18E+02 6.7E-01 1.0E+00 3.2E+00
6.93E+02 6.0E+01 1.0E+00 3.2E+00
1.63E+02 5.3E+01 1.0E+00 3.2E+00
6.15E+02 3.1E-01 1.0E+00 3.2E+00
2.90E+02 9.7E-02 1.0E+00 3.2E+00 10 100
8.34E+02 4.2E+00 1.0E+00 3.2E+00
1.00E+03 9.5E-01 1.0E+00 3.2E+00
1.06E+03 2.2E-01 1.0E+00 3.2E+00
1.25E+03 8.6E+01 1.0E+00 3.2E+00
1.48E+03 9.3E-01 1.0E+00 3.2E+00
6.13E+02 2.8E-01 1.0E+00 3.2E+00
7.02E+02 1.0E+00 1.0E+00 3.2E+00
1.79E+02 6.6E-01 1.0E+00 3.2E+00
5.60E+02 3.4E-01 1.0E+00 3.2E+00
3.33E+02 9.6E-01 1.0E+00 3.2E+00 10 100
8.77E+02 1.1E+00 1.0E+00 3.2E+00
1.11E+03 6.6E-01 1.0E+00 3.2E+00
9.68E+02 5.0E+00 1.0E+00 3.2E+00
1.32E+03 2.9E+00 1.0E+00 3.2E+00
1.28E+03 5.2E+01 1.0E+00 3.2E+00
5.95E+02 2.1E-01 1.0E+00 3.2E+00
7.87E+02 9.4E-01 1.0E+00 3.2E+00
1.59E+02 1.0E+00 1.0E+00 3.2E+00
1.61E+02 1.0E+00 1.0E+00 3.2E+00
1.29E+00 5.5E+00 1.0E+00 3.2E+00
3.84E+00 6.6E+00 1.0E+00 3.2E+00
5.00E-01 4.7E+00 1.0E+00 3.2E+00
5.00E-01 8.5E+00 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00
5.00E-01 1.0E+01 1.0E+00 3.2E+00
5.00E-01 8.7E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.23E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.31E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-472
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be SWA-L06-1313-T01-A
Be SWA-L06-1313-T02-A
Be SWA-L06-1313-T03-A
Be SWA-L06-1313-T04-A
Be SWA-L06-1313-T05-A
Be SWA-L06-1313-T06-A
Be SWA-L06-1313-T07-A
Be SWA-L06-1313-T08-A
Be SWA-L06-1313-T09-A
Be SWA-L06-1313-T10-A
Be SWA-L06-1313-T01-B
Be SWA-L06-1313-T02-B
Be SWA-L06-1313-T03-B
Be SWA-L06-1313-T04-B
Be SWA-L06-1313-T05-B
Be SWA-L06-1313-T06-B
Be SWA-L06-1313-T07-B
Be SWA-L06-1313-T08-B
Be SWA-L06-1313-T09-B
Be SWA-L06-1313-T10-B
Be SWA-L06-1313-T01-C
Be SWA-L06-1313-T02-C
Be SWA-L06-1313-T03-C
Be SWA-L06-1313-T04-C
Be SWA-L06-1313-T05-C
Be SWA-L06-1313-T06-C
Be SWA-L06-1313-T07-C
Be SWA-L06-1313-T08-C
Be SWA-L06-1313-T09-C
Be SWA-L06-1313-T10-C
Be SWA-L06-1313-B01-A
Be SWA-L06-1313-B02-A
Be SWA-L06-1313-B03-A
Be SWA-L06-1313-B01-B
Be SWA-L06-1313-B02-B
Be SWA-L06-1313-B03-B
Be SWA-L06-1313-B01-C
Be SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.15E+01
1 7.86E+01
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.51E+01
1 1.12E+02
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.64E+01
1 1.14E+02
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.6E+01 1.9E+00 6.0E+00
9.50E-01 7.9E+02 1.9E+00 6.0E+00 10 100
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 2.9E+03 1.9E+00 6.0E+00
9.50E-01 5.1E+01 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
4.15E+01 1.0E+00 1.9E+00 6.0E+00
7.86E+01 6.5E+01 1.9E+00 6.0E+00
9.50E-01 9.1E+02 1.9E+00 6.0E+00
9.50E-01 2.3E+01 1.9E+00 6.0E+00
9.50E-01 6.3E+02 1.9E+00 6.0E+00 10 100
9.50E-01 3.3E+02 1.9E+00 6.0E+00
9.50E-01 2.4E+02 1.9E+00 6.0E+00
9.50E-01 4.0E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 7.2E+01 1.9E+00 6.0E+00
4.51 E+01 7.0E-01 1.9E+00 6.0E+00
1.12E+02 1.6E+00 1.9E+00 6.0E+00
9.50E-01 6.9E+01 1.9E+00 6.0E+00
9.50E-01 3.3E+01 1.9E+00 6.0E+00
9.50E-01 7.7E+01 1.9E+00 6.0E+00 10 100
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 8.2E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 3.5E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
4.64E+01 1.8E+00 1.9E+00 6.0E+00
1.14E+02 1.6E+00 1.9E+00 6.0E+00
9.50E-01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 3.8E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+04 1.9E+00 6.0E+00
9.50E-01 2.7E+02 1.9E+00 6.0E+00
9.50E-01 6.9E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.14E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/11 3:12 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-473
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd SWA-L06-1313-T01-A
Cd SWA-L06-1313-T02-A
Cd SWA-L06-1313-T03-A
Cd SWA-L06-1313-T04-A
Cd SWA-L06-1313-T05-A
Cd SWA-L06-1313-T06-A
Cd SWA-L06-1313-T07-A
Cd SWA-L06-1313-T08-A
Cd SWA-L06-1313-T09-A
Cd SWA-L06-1313-T10-A
Cd SWA-L06-1313-T01-B
Cd SWA-L06-1313-T02-B
Cd SWA-L06-1313-T03-B
Cd SWA-L06-1313-T04-B
Cd SWA-L06-1313-T05-B
Cd SWA-L06-1313-T06-B
Cd SWA-L06-1313-T07-B
Cd SWA-L06-1313-T08-B
Cd SWA-L06-1313-T09-B
Cd SWA-L06-1313-T10-B
Cd SWA-L06-1313-T01-C
Cd SWA-L06-1313-T02-C
Cd SWA-L06-1313-T03-C
Cd SWA-L06-1313-T04-C
Cd SWA-L06-1313-T05-C
Cd SWA-L06-1313-T06-C
Cd SWA-L06-1313-T07-C
Cd SWA-L06-1313-T08-C
Cd SWA-L06-1313-T09-C
Cd SWA-L06-1313-T10-C
Cd SWA-L06-1313-B01-A
Cd SWA-L06-1313-B02-A
Cd SWA-L06-1313-B03-A
Cd SWA-L06-1313-B01-B
Cd SWA-L06-1313-B02-B
Cd SWA-L06-1313-B03-B
Cd SWA-L06-1313-B01-C
Cd SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 7.49E+00
1 1.61E+01
1 3.33E+01
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 9.68E+00
1 1.60E+01
1 3.80E+01
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.04E+01
1 1.58E+01
1 3.40E+01
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 7.7E+01 2.2E+00 7.0E+00
1.10E+00 5.3E+01 2.2E+00 7.0E+00 10 100
1.10E+00 3.2E+01 2.2E+00 7.0E+00
1.10E+00 7.8E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+02 2.2E+00 7.0E+00
1.10E+00 4.6E+01 2.2E+00 7.0E+00
7.49E+00 2.6E+00 2.2E+00 7.0E+00
1.61E+01 2.1E+00 2.2E+00 7.0E+00
3.33E+01 7.0E+01 2.2E+00 7.0E+00
1.10E+00 1.6E+02 2.2E+00 7.0E+00
1.10E+00 7.5E+01 2.2E+00 7.0E+00
1.10E+00 7.1E+01 2.2E+00 7.0E+00 10 100
1.10E+00 8.7E+01 2.2E+00 7.0E+00
1.10E+00 4.5E+01 2.2E+00 7.0E+00
1.10E+00 6.5E+01 2.2E+00 7.0E+00
1.10E+00 9.8E+01 2.2E+00 7.0E+00
9.68E+00 2.1E+00 2.2E+00 7.0E+00
1.60E+01 1.7E+00 2.2E+00 7.0E+00
3.80E+01 7.7E-01 2.2E+00 7.0E+00
1.10E+00 1.0E+02 2.2E+00 7.0E+00
1.10E+00 7.4E+01 2.2E+00 7.0E+00
1.10E+00 1.5E+02 2.2E+00 7.0E+00 10 100
1.10E+00 2.3E+01 2.2E+00 7.0E+00
1.10E+00 3.2E+01 2.2E+00 7.0E+00
1.10E+00 2.4E+01 2.2E+00 7.0E+00
1.10E+00 5.5E+01 2.2E+00 7.0E+00
1.04E+01 6.7E+01 2.2E+00 7.0E+00
1.58E+01 1.8E+00 2.2E+00 7.0E+00
3.40E+01 9.0E-01 2.2E+00 7.0E+00
1.10E+00 3.3E+01 2.2E+00 7.0E+00
1.10E+00 4.1E+01 2.2E+00 7.0E+00
1.10E+00 7.2E+01 2.2E+00 7.0E+00
1.10E+00 3.9E+01 2.2E+00 7.0E+00
1.10E+00 6.0E+00 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00
1.10E+00 3.7E+02 2.2E+00 7.0E+00
1.10E+00 4.5E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/11 3:12 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-474
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
SWA-L06-1313-T01-A
SWA-L06-1313-T02-A
SWA-L06-1313-T03-A
SWA-L06-1313-T04-A
SWA-L06-1313-T05-A
SWA-L06-1313-T06-A
SWA-L06-1313-T07-A
SWA-L06-1313-T08-A
SWA-L06-1313-T09-A
SWA-L06-1313-T10-A
SWA-L06-1313-T01-B
SWA-L06-1313-T02-B
SWA-L06-1313-T03-B
SWA-L06-1313-T04-B
SWA-L06-1313-T05-B
SWA-L06-1313-T06-B
SWA-L06-1313-T07-B
SWA-L06-1313-T08-B
SWA-L06-1313-T09-B
SWA-L06-1313-T10-B
SWA-L06-1313-T01-C
SWA-L06-1313-T02-C
SWA-L06-1313-T03-C
SWA-L06-1313-T04-C
SWA-L06-1313-T05-C
SWA-L06-1313-T06-C
SWA-L06-1313-T07-C
SWA-L06-1313-T08-C
SWA-L06-1313-T09-C
SWA-L06-1313-T10-C
SWA-L06-1313-B01-A
SWA-L06-1313-B02-A
SWA-L06-1313-B03-A
SWA-L06-1313-B01-B
SWA-L06-1313-B02-B
SWA-L06-1313-B03-B
SWA-L06-1313-B01-C
SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.59E+03
1 4.90E+04
1 2.93E+06
1 5.78E+06
1 7.26E+06
1 8.93E+06
1 9.65E+06
1 4.01 E+06
1 2.07E+06
1 1.26E+04
1 3.48E+03
1 5.37E+04
1 2.70E+06
1 6.01 E+06
1 7.25E+06
1 8.72E+06
1 9.12E+06
1 4.01 E+06
1 3.15E+06
1 1.38E+04
1 3.37E+03
1 5.43E+04
1 2.85E+06
1 6.13E+06
1 6.85E+06
1 8.63E+06
1 6.07E+06
1 3.98E+06
1 3.17E+06
1 1.30E+04
1 1.28E+04
1 8.38E+00
1 7.30E+00 E
1 5.79E+00 E
1 3.07E+00 E
1 1.30E+00 U1/2
1 1.30E+00 U1/2
1 3.29E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.59E+03 4.5E-01 2.6E+00 8.3E+00
4.90E+04 7.7E+00 2.6E+00 8.3E+00 1000 100
2.93E+06 1.4E-01 2.6E+00 8.3E+00
5.78E+06 3.9E+00 2.6E+00 8.3E+00
7.26E+06 3.7E-01 2.6E+00 8.3E+00
8.93E+06 2.0E+00 2.6E+00 8.3E+00
9.65E+06 4.4E-01 2.6E+00 8.3E+00
4.01 E+06 4.3E-02 2.6E+00 8.3E+00
2.07E+06 7.7E+01 2.6E+00 8.3E+00
1.26E+04 6.8E+01 2.6E+00 8.3E+00
3.48E+03 1.4E+00 2.6E+00 8.3E+00
5.37E+04 8.3E-01 2.6E+00 8.3E+00 1000 100
2.70E+06 4.5E+00 2.6E+00 8.3E+00
6.01 E+06 5.4E-01 2.6E+00 8.3E+00
7.25E+06 8.2E-01 2.6E+00 8.3E+00
8.72E+06 1.4E+02 2.6E+00 8.3E+00
9.12E+06 7.0E-01 2.6E+00 8.3E+00
4.01 E+06 8.6E-01 2.6E+00 8.3E+00
3.15E+06 5.9E-01 2.6E+00 8.3E+00
1.38E+04 1.6E-01 2.6E+00 8.3E+00
3.37E+03 3.9E+00 2.6E+00 8.3E+00
5.43E+04 1.3E+00 2.6E+00 8.3E+00 1000 100
2.85E+06 4.3E-01 2.6E+00 8.3E+00
6.13E+06 2.1E-01 2.6E+00 8.3E+00
6.85E+06 5.0E+00 2.6E+00 8.3E+00
8.63E+06 2.9E+00 2.6E+00 8.3E+00
6.07E+06 7.8E+01 2.6E+00 8.3E+00
3.98E+06 4.7E-01 2.6E+00 8.3E+00
3.17E+06 6.4E-01 2.6E+00 8.3E+00
1.30E+04 6.0E-01 2.6E+00 8.3E+00
1.28E+04 4.9E-01 2.6E+00 8.3E+00
8.38E+00 5.2E+00 2.6E+00 8.3E+00
7.30E+00 1.2E+01 2.6E+00 8.3E+00
5.79E+00 1.1E+02 2.6E+00 8.3E+00
3.07E+00 1.5E+02 2.6E+00 8.3E+00
1.30E+00 2.6E+02 2.6E+00 8.3E+00
1.30E+00 1.4E+02 2.6E+00 8.3E+00
3.29E+00 8.1E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.99E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.46E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.52E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-475
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr SWA-L06-1313-T01-A
Cr SWA-L06-1313-T02-A
Cr SWA-L06-1313-T03-A
Cr SWA-L06-1313-T04-A
Cr SWA-L06-1313-T05-A
Cr SWA-L06-1313-T06-A
Cr SWA-L06-1313-T07-A
Cr SWA-L06-1313-T08-A
Cr SWA-L06-1313-T09-A
Cr SWA-L06-1313-T10-A
Cr SWA-L06-1313-T01-B
Cr SWA-L06-1313-T02-B
Cr SWA-L06-1313-T03-B
Cr SWA-L06-1313-T04-B
Cr SWA-L06-1313-T05-B
Cr SWA-L06-1313-T06-B
Cr SWA-L06-1313-T07-B
Cr SWA-L06-1313-T08-B
Cr SWA-L06-1313-T09-B
Cr SWA-L06-1313-T10-B
Cr SWA-L06-1313-T01-C
Cr SWA-L06-1313-T02-C
Cr SWA-L06-1313-T03-C
Cr SWA-L06-1313-T04-C
Cr SWA-L06-1313-T05-C
Cr SWA-L06-1313-T06-C
Cr SWA-L06-1313-T07-C
Cr SWA-L06-1313-T08-C
Cr SWA-L06-1313-T09-C
Cr SWA-L06-1313-T10-C
Cr SWA-L06-1313-B01-A
Cr SWA-L06-1313-B02-A
Cr SWA-L06-1313-B03-A
Cr SWA-L06-1313-B01-B
Cr SWA-L06-1313-B02-B
Cr SWA-L06-1313-B03-B
Cr SWA-L06-1313-B01-C
Cr SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.81E+03
1 1.57E+02
1 1.30E+01
1 1.68E+01
1 1.45E+01
1 6.00E-01 U1/2
1 1.02E+01
1 3.81 E+03
1 1.70E+04
1 1.12E+03
1 1.87E+03
1 1.37E+02
1 1.35E+01
1 1.24E+01
1 1.50E+01
1 6.00E-01 U1/2
1 1.32E+01
1 4.04E+03
1 1.82E+04
1 1.12E+03
1 1.87E+03
1 1.88E+02
1 1.13E+01
1 1.45E+01
1 1.70E+01
1 6.00E-01 U1/2
1 1.03E+01
1 4.04E+03
1 1.75E+04
1 1.15E+03
1 1.18E+03
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.81 E+03 6.6E-01 1.2E+00 3.8E+00
1.57E+02 7.1E+00 1.2E+00 3.8E+00 10 100
1.30E+01 2.1E+00 1.2E+00 3.8E+00
1.68E+01 9.5E-01 1.2E+00 3.8E+00
1.45E+01 3.8E+00 1.2E+00 3.8E+00
6.00E-01 5.9E+01 1.2E+00 3.8E+00
1.02E+01 1.2E+01 1.2E+00 3.8E+00
3.81 E+03 6.3E-01 1.2E+00 3.8E+00
1.70E+04 6.0E+01 1.2E+00 3.8E+00
1.12E+03 5.5E+01 1.2E+00 3.8E+00
1.87E+03 1.2E+00 1.2E+00 3.8E+00
1.37E+02 6.8E-01 1.2E+00 3.8E+00 10 100
1.35E+01 4.7E+00 1.2E+00 3.8E+00
1.24E+01 7.3E+00 1.2E+00 3.8E+00
1.50E+01 1.0E+01 1.2E+00 3.8E+00
6.00E-01 6.1E+01 1.2E+00 3.8E+00
1.32E+01 8.2E+00 1.2E+00 3.8E+00
4.04E+03 5.3E-01 1.2E+00 3.8E+00
1.82E+04 8.5E-01 1.2E+00 3.8E+00
1.12E+03 6.9E-01 1.2E+00 3.8E+00
1.87E+03 7.2E-02 1.2E+00 3.8E+00
1.88E+02 1.2E+00 1.2E+00 3.8E+00 10 100
1.13E+01 7.1E-01 1.2E+00 3.8E+00
1.45E+01 6.4E+00 1.2E+00 3.8E+00
1.70E+01 1.2E+01 1.2E+00 3.8E+00
6.00E-01 4.4E+00 1.2E+00 3.8E+00
1.03E+01 5.8E+01 1.2E+00 3.8E+00
4.04E+03 5.7E-01 1.2E+00 3.8E+00
1.75E+04 2.9E-01 1.2E+00 3.8E+00
1.15E+03 6.1E-01 1.2E+00 3.8E+00
1.18E+03 8.0E-01 1.2E+00 3.8E+00
6.00E-01 8.9E+01 1.2E+00 3.8E+00
6.00E-01 1.4E+01 1.2E+00 3.8E+00
6.00E-01 3.2E+01 1.2E+00 3.8E+00
6.00E-01 8.2E+01 1.2E+00 3.8E+00
6.00E-01 2.9E+01 1.2E+00 3.8E+00
6.00E-01 3.0E+01 1.2E+00 3.8E+00
6.00E-01 6.6E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.25E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.30E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316SWA
                                                                                                                                                                          1-476
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
SWA-L06-1313-T01-A
SWA-L06-1313-T02-A
SWA-L06-1313-T03-A
SWA-L06-1313-T04-A
SWA-L06-1313-T05-A
SWA-L06-1313-T06-A
SWA-L06-1313-T07-A
SWA-L06-1313-T08-A
SWA-L06-1313-T09-A
SWA-L06-1313-T10-A
SWA-L06-1313-T01-B
SWA-L06-1313-T02-B
SWA-L06-1313-T03-B
SWA-L06-1313-T04-B
SWA-L06-1313-T05-B
SWA-L06-1313-T06-B
SWA-L06-1313-T07-B
SWA-L06-1313-T08-B
SWA-L06-1313-T09-B
SWA-L06-1313-T10-B
SWA-L06-1313-T01-C
SWA-L06-1313-T02-C
SWA-L06-1313-T03-C
SWA-L06-1313-T04-C
SWA-L06-1313-T05-C
SWA-L06-1313-T06-C
SWA-L06-1313-T07-C
SWA-L06-1313-T08-C
SWA-L06-1313-T09-C
SWA-L06-1313-T10-C
SWA-L06-1313-B01-A
SWA-L06-1313-B02-A
SWA-L06-1313-B03-A
SWA-L06-1313-B01-B
SWA-L06-1313-B02-B
SWA-L06-1313-B03-B
SWA-L06-1313-B01-C
SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 3.28E+00 E
1 5.21 E+00 E
1 7.30E+00
1 5.55E+01
1 1.74E+02
1 1.47E+02
1 2.25E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 4.01 E+00 E
1 6.02E+00
1 8.88E+00
1 6.15E+01
1 1.90E+02
1 1.46E+02
1 2.39E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 2.95E+00 E
1 4.34E+00 E
1 8.95E+00
1 6.59E+01
1 1.24E+02
1 1.43E+02
1 2.20E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 8.7E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+01 1.8E+00 5.7E+00 10 100
3.28E+00 4.4E+01 1.8E+00 5.7E+00
5.21E+00 8.5E+00 1.8E+00 5.7E+00
7.30E+00 1.7E+01 1.8E+00 5.7E+00
5.55E+01 2.7E+00 1.8E+00 5.7E+00
1.74E+02 1.2E+00 1.8E+00 5.7E+00
1.47E+02 1.4E+00 1.8E+00 5.7E+00
2.25E+02 6.6E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+03 1.8E+00 5.7E+00
9.00E-01 5.6E+01 1.8E+00 5.7E+00
9.00E-01 3.6E+01 1.8E+00 5.7E+00 10 100
4.01 E+00 2.4E+01 1.8E+00 5.7E+00
6.02E+00 1.6E+01 1.8E+00 5.7E+00
8.88E+00 2.1E+00 1.8E+00 5.7E+00
6.15E+01 9.2E+01 1.8E+00 5.7E+00
1.90E+02 8.6E-01 1.8E+00 5.7E+00
1.46E+02 2.9E-01 1.8E+00 5.7E+00
2.39E+02 1.1 E+00 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 3.5E+01 1.8E+00 5.7E+00
9.00E-01 2.5E+01 1.8E+00 5.7E+00 10 100
2.95E+00 1.5E+01 1.8E+00 5.7E+00
4.34E+00 4.4E+00 1.8E+00 5.7E+00
8.95E+00 1.1E+01 1.8E+00 5.7E+00
6.59E+01 2.5E+00 1.8E+00 5.7E+00
1.24E+02 5.8E+01 1.8E+00 5.7E+00
1.43E+02 9.1E-01 1.8E+00 5.7E+00
2.20E+02 1.8E-01 1.8E+00 5.7E+00
9.00E-01 1.4E+01 1.8E+00 5.7E+00
9.00E-01 6.5E+01 1.8E+00 5.7E+00
9.00E-01 6.6E+01 1.8E+00 5.7E+00
9.00E-01 6.8E+01 1.8E+00 5.7E+00
9.00E-01 4.9E+01 1.8E+00 5.7E+00
9.00E-01 7.3E+01 1.8E+00 5.7E+00
9.00E-01 7.6E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+01 1.8E+00 5.7E+00
9.00E-01 4.1E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-477
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu SWA-L06-1313-T01-A
Cu SWA-L06-1313-T02-A
Cu SWA-L06-1313-T03-A
Cu SWA-L06-1313-T04-A
Cu SWA-L06-1313-T05-A
Cu SWA-L06-1313-T06-A
Cu SWA-L06-1313-T07-A
Cu SWA-L06-1313-T08-A
Cu SWA-L06-1313-T09-A
Cu SWA-L06-1313-T10-A
Cu SWA-L06-1313-T01-B
Cu SWA-L06-1313-T02-B
Cu SWA-L06-1313-T03-B
Cu SWA-L06-1313-T04-B
Cu SWA-L06-1313-T05-B
Cu SWA-L06-1313-T06-B
Cu SWA-L06-1313-T07-B
Cu SWA-L06-1313-T08-B
Cu SWA-L06-1313-T09-B
Cu SWA-L06-1313-T10-B
Cu SWA-L06-1313-T01-C
Cu SWA-L06-1313-T02-C
Cu SWA-L06-1313-T03-C
Cu SWA-L06-1313-T04-C
Cu SWA-L06-1313-T05-C
Cu SWA-L06-1313-T06-C
Cu SWA-L06-1313-T07-C
Cu SWA-L06-1313-T08-C
Cu SWA-L06-1313-T09-C
Cu SWA-L06-1313-T10-C
Cu SWA-L06-1313-B01-A
Cu SWA-L06-1313-B02-A
Cu SWA-L06-1313-B03-A
Cu SWA-L06-1313-B01-B
Cu SWA-L06-1313-B02-B
Cu SWA-L06-1313-B03-B
Cu SWA-L06-1313-B01-C
Cu SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.04E+01 E
1 1.85E+00 U1/2
1 9.06E+00 E
1 1.52E+01
1 1.74E+01
1 2.78E+01
1 3.52E+01
1 7.09E+01
1 8.57E+02
1 1.85E+00 U1/2
1 1.14E+01 E
1 1.85E+00 U1/2
1 8.98E+00 E
1 1.47E+01
1 1.81E+01
1 2.46E+01
1 2.97E+01
1 8.04E+01
1 1.45E+03
1 1.85E+00 U1/2
1 1.21E+01
1 1.85E+00 U1/2
1 1.07E+01 E
1 1.21E+01
1 1.59E+01
1 2.94E+01
1 2.69E+01
1 9.00E+01
1 1.25E+03
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.04E+01 6.2E+00 3.7E+00 1.2E+01
1.85E+00 1.2E+01 3.7E+00 1.2E+01 10 100
9.06E+00 8.7E+00 3.7E+00 1.2E+01
1.52E+01 1.3E+01 3.7E+00 1.2E+01
1.74E+01 1.2E+01 3.7E+00 1.2E+01
2.78E+01 2.0E+01 3.7E+00 1.2E+01
3.52E+01 5.9E+00 3.7E+00 1.2E+01
7.09E+01 4.5E-01 3.7E+00 1.2E+01
8.57E+02 5.2E+01 3.7E+00 1.2E+01
1.85E+00 6.4E+01 3.7E+00 1.2E+01
1.14E+01 3.1E+00 3.7E+00 1.2E+01
1.85E+00 3.0E+01 3.7E+00 1.2E+01 10 100
8.98E+00 2.7E+00 3.7E+00 1.2E+01
1.47E+01 1.4E+01 3.7E+00 1.2E+01
1.81E+01 3.4E+00 3.7E+00 1.2E+01
2.46E+01 7.5E+01 3.7E+00 1.2E+01
2.97E+01 2.4E+00 3.7E+00 1.2E+01
8.04E+01 2.5E+00 3.7E+00 1.2E+01
1.45E+03 8.8E-01 3.7E+00 1.2E+01
1.85E+00 2.0E+01 3.7E+00 1.2E+01
1.21E+01 1.2E+01 3.7E+00 1.2E+01
1.85E+00 2.8E+01 3.7E+00 1.2E+01 10 100
1.07E+01 1.7E+01 3.7E+00 1.2E+01
1.21E+01 4.9E+00 3.7E+00 1.2E+01
1.59E+01 8.2E+00 3.7E+00 1.2E+01
2.94E+01 5.8E+00 3.7E+00 1.2E+01
2.69E+01 3.1E+01 3.7E+00 1.2E+01
9.00E+01 1.3E+00 3.7E+00 1.2E+01
1.25E+03 8.0E-01 3.7E+00 1.2E+01
1.85E+00 4.5E+01 3.7E+00 1.2E+01
1.85E+00 9.3E+00 3.7E+00 1.2E+01
1.85E+00 2.6E+01 3.7E+00 1.2E+01
1.85E+00 1.4E+01 3.7E+00 1.2E+01
1.85E+00 2.5E+01 3.7E+00 1.2E+01
1.85E+00 3.0E+01 3.7E+00 1.2E+01
1.85E+00 1.3E+01 3.7E+00 1.2E+01
1.85E+00 6.4E+01 3.7E+00 1.2E+01
1.85E+00 2.9E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-478
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe SWA-L06-1313-T01-A
Fe SWA-L06-1313-T02-A
Fe SWA-L06-1313-T03-A
Fe SWA-L06-1313-T04-A
Fe SWA-L06-1313-T05-A
Fe SWA-L06-1313-T06-A
Fe SWA-L06-1313-T07-A
Fe SWA-L06-1313-T08-A
Fe SWA-L06-1313-T09-A
Fe SWA-L06-1313-T10-A
Fe SWA-L06-1313-T01-B
Fe SWA-L06-1313-T02-B
Fe SWA-L06-1313-T03-B
Fe SWA-L06-1313-T04-B
Fe SWA-L06-1313-T05-B
Fe SWA-L06-1313-T06-B
Fe SWA-L06-1313-T07-B
Fe SWA-L06-1313-T08-B
Fe SWA-L06-1313-T09-B
Fe SWA-L06-1313-T10-B
Fe SWA-L06-1313-T01-C
Fe SWA-L06-1313-T02-C
Fe SWA-L06-1313-T03-C
Fe SWA-L06-1313-T04-C
Fe SWA-L06-1313-T05-C
Fe SWA-L06-1313-T06-C
Fe SWA-L06-1313-T07-C
Fe SWA-L06-1313-T08-C
Fe SWA-L06-1313-T09-C
Fe SWA-L06-1313-T10-C
Fe SWA-L06-1313-B01-A
Fe SWA-L06-1313-B02-A
Fe SWA-L06-1313-B03-A
Fe SWA-L06-1313-B01-B
Fe SWA-L06-1313-B02-B
Fe SWA-L06-1313-B03-B
Fe SWA-L06-1313-B01-C
Fe SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.77E+02
1 4.61 E+01
1 1.28E+01
1 2.02E+01
1 1.74E+01
1 1.01 E+01
1 6.57E+04
1 9.30E+04
1 1.49E+05
1 9.38E+01
1 2.26E+02
1 4.94E+01
1 1.09E+01
1 2.40E+01
1 1.64E+01
1 8.59E+00
1 8.62E+04
1 9.06E+04
1 1.44E+05
1 9.05E+01
1 2.17E+02
1 5.54E+01
1 1.22E+01
1 2.43E+01
1 1.46E+01
1 1.20E+01
1 5.29E+04
1 8.90E+04
1 1.40E+05
1 8.89E+01
1 8.70E+01
1 2.92E+00 E
1 2.61E+OOE
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+02 4.8E-02 2.0E+00 6.4E+00
4.61E+01 7.8E+00 2.0E+00 6.4E+00 1000 100
1.28E+01 2.7E+00 2.0E+00 6.4E+00
2.02E+01 4.7E+00 2.0E+00 6.4E+00
1.74E+01 3.2E+00 2.0E+00 6.4E+00
1.01 E+01 4.8E+00 2.0E+00 6.4E+00
6.57E+04 4.6E-01 2.0E+00 6.4E+00
9.30E+04 1.3E+00 2.0E+00 6.4E+00
1.49E+05 5.0E+01 2.0E+00 6.4E+00
9.38E+01 4.6E+01 2.0E+00 6.4E+00
2.26E+02 7.9E-01 2.0E+00 6.4E+00
4.94E+01 8.0E-01 2.0E+00 6.4E+00 1000 100
1.09E+01 3.9E+00 2.0E+00 6.4E+00
2.40E+01 2.8E+00 2.0E+00 6.4E+00
1.64E+01 6.7E+00 2.0E+00 6.4E+00
8.59E+00 8.7E+01 2.0E+00 6.4E+00
8.62E+04 1.2E+00 2.0E+00 6.4E+00
9.06E+04 1.5E+00 2.0E+00 6.4E+00
1.44E+05 5.0E+00 2.0E+00 6.4E+00
9.05E+01 7.3E-01 2.0E+00 6.4E+00
2.17E+02 1.9E+00 2.0E+00 6.4E+00
5.54E+01 2.0E+00 2.0E+00 6.4E+00 1000 100
1.22E+01 2.5E+00 2.0E+00 6.4E+00
2.43E+01 2.9E+00 2.0E+00 6.4E+00
1.46E+01 2.3E+00 2.0E+00 6.4E+00
1.20E+01 2.5E+00 2.0E+00 6.4E+00
5.29E+04 4.6E+01 2.0E+00 6.4E+00
8.90E+04 5.2E-01 2.0E+00 6.4E+00
1.40E+05 1.8E+00 2.0E+00 6.4E+00
8.89E+01 9.3E-02 2.0E+00 6.4E+00
8.70E+01 1.1E+00 2.0E+00 6.4E+00
2.92E+00 1.3E+01 2.0E+00 6.4E+00
2.61 E+00 2.5E+00 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+00 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-479
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb SWA-L06-1313-T01-A
Pb SWA-L06-1313-T02-A
Pb SWA-L06-1313-T03-A
Pb SWA-L06-1313-T04-A
Pb SWA-L06-1313-T05-A
Pb SWA-L06-1313-T06-A
Pb SWA-L06-1313-T07-A
Pb SWA-L06-1313-T08-A
Pb SWA-L06-1313-T09-A
Pb SWA-L06-1313-T10-A
Pb SWA-L06-1313-T01-B
Pb SWA-L06-1313-T02-B
Pb SWA-L06-1313-T03-B
Pb SWA-L06-1313-T04-B
Pb SWA-L06-1313-T05-B
Pb SWA-L06-1313-T06-B
Pb SWA-L06-1313-T07-B
Pb SWA-L06-1313-T08-B
Pb SWA-L06-1313-T09-B
Pb SWA-L06-1313-T10-B
Pb SWA-L06-1313-T01-C
Pb SWA-L06-1313-T02-C
Pb SWA-L06-1313-T03-C
Pb SWA-L06-1313-T04-C
Pb SWA-L06-1313-T05-C
Pb SWA-L06-1313-T06-C
Pb SWA-L06-1313-T07-C
Pb SWA-L06-1313-T08-C
Pb SWA-L06-1313-T09-C
Pb SWA-L06-1313-T10-C
Pb SWA-L06-1313-B01-A
Pb SWA-L06-1313-B02-A
Pb SWA-L06-1313-B03-A
Pb SWA-L06-1313-B01-B
Pb SWA-L06-1313-B02-B
Pb SWA-L06-1313-B03-B
Pb SWA-L06-1313-B01-C
Pb SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.61 E+02
1 9.57E+00 E
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 1.39E+01 E
1 3.20E+02
1 1.86E+03
1 1.97E+01 E
1 3.96E+02
1 1.04E+01 E
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 1.32E+01 E
1 3.71 E+02
1 2.87E+03
1 1.88E+01 E
1 3.74E+02
1 1.06E+01 E
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 9.12E+00 E
1 3.56E+02
1 3.05E+03
1 2.17E+01
1 2.06E+01 E
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.61 E+02 1.4E+00 6.8E+00 2.2E+01
9.57E+00 6.0E+01 6.8E+00 2.2E+01 10 100
3.40E+00 2.4E+01 6.8E+00 2.2E+01
3.40E+00 6.8E+01 6.8E+00 2.2E+01
3.40E+00 5.2E+01 6.8E+00 2.2E+01
3.40E+00 2.0E+01 6.8E+00 2.2E+01
1.39E+01 2.3E+01 6.8E+00 2.2E+01
3.20E+02 1.6E+00 6.8E+00 2.2E+01
1.86E+03 6.7E+01 6.8E+00 2.2E+01
1.97E+01 7.1E+01 6.8E+00 2.2E+01
3.96E+02 1.4E+00 6.8E+00 2.2E+01
1.04E+01 2.0E+01 6.8E+00 2.2E+01 10 100
3.40E+00 1.4E+02 6.8E+00 2.2E+01
3.40E+00 1.1E+01 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01
3.40E+00 9.5E+01 6.8E+00 2.2E+01
1.32E+01 5.7E+01 6.8E+00 2.2E+01
3.71 E+02 7.3E-01 6.8E+00 2.2E+01
2.87E+03 4.4E-01 6.8E+00 2.2E+01
1.88E+01 2.8E+01 6.8E+00 2.2E+01
3.74E+02 1.7E+00 6.8E+00 2.2E+01
1.06E+01 8.5E+01 6.8E+00 2.2E+01 10 100
3.40E+00 2.8E+01 6.8E+00 2.2E+01
3.40E+00 6.0E+01 6.8E+00 2.2E+01
3.40E+00 5.7E+01 6.8E+00 2.2E+01
3.40E+00 7.0E+01 6.8E+00 2.2E+01
9.12E+00 3.7E+01 6.8E+00 2.2E+01
3.56E+02 7.7E-01 6.8E+00 2.2E+01
3.05E+03 6.2E-01 6.8E+00 2.2E+01
2.17E+01 4.7E+00 6.8E+00 2.2E+01
2.06E+01 1.3E+00 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 1.0E+01 6.8E+00 2.2E+01
3.40E+00 6.5E+01 6.8E+00 2.2E+01
3.40E+00 9.5E+01 6.8E+00 2.2E+01
3.40E+00 1.8E+02 6.8E+00 2.2E+01
3.40E+00 1.7E+02 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/11 3:12 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/1 1 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-480
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li SWA-L06-1313-T01-A
Li SWA-L06-1313-T02-A
Li SWA-L06-1313-T03-A
Li SWA-L06-1313-T04-A
Li SWA-L06-1313-T05-A
Li SWA-L06-1313-T06-A
Li SWA-L06-1313-T07-A
Li SWA-L06-1313-T08-A
Li SWA-L06-1313-T09-A
Li SWA-L06-1313-T10-A
Li SWA-L06-1313-T01-B
Li SWA-L06-1313-T02-B
Li SWA-L06-1313-T03-B
Li SWA-L06-1313-T04-B
Li SWA-L06-1313-T05-B
Li SWA-L06-1313-T06-B
Li SWA-L06-1313-T07-B
Li SWA-L06-1313-T08-B
Li SWA-L06-1313-T09-B
Li SWA-L06-1313-T10-B
Li SWA-L06-1313-T01-C
Li SWA-L06-1313-T02-C
Li SWA-L06-1313-T03-C
Li SWA-L06-1313-T04-C
Li SWA-L06-1313-T05-C
Li SWA-L06-1313-T06-C
Li SWA-L06-1313-T07-C
Li SWA-L06-1313-T08-C
Li SWA-L06-1313-T09-C
Li SWA-L06-1313-T10-C
Li SWA-L06-1313-B01-A
Li SWA-L06-1313-B02-A
Li SWA-L06-1313-B03-A
Li SWA-L06-1313-B01-B
Li SWA-L06-1313-B02-B
Li SWA-L06-1313-B03-B
Li SWA-L06-1313-B01-C
Li SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.48E+01
1 1.37E+01
1 2.28E+02
1 7.15E+02
1 9.66E+02
1 1.21E+03
1 1.41E+03
1 7.06E+02
1 4.77E+02
1 9.50E-01 U1/2
1 1.30E+01
1 1.54E+01
1 1.88E+02
1 7.45E+02
1 9.81 E+02
1 9.97E+02
1 1.31E+03
1 7.07E+02
1 7.27E+02
1 9.50E-01 U1/2
1 1.08E+01
1 1.62E+01
1 2.23E+02
1 7.26E+02
1 9.28E+02
1 1.18E+03
1 9.10E+02
1 7.07E+02
1 7.22E+02
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.48E+01 5.6E+00 1.9E+00 6.0E+00
1.37E+01 6.1E+00 1.9E+00 6.0E+00 10 100
2.28E+02 3.0E+00 1.9E+00 6.0E+00
7.15E+02 8.0E+00 1.9E+00 6.0E+00
9.66E+02 2.1E+00 1.9E+00 6.0E+00
1.21E+03 4.1E+00 1.9E+00 6.0E+00
1.41E+03 3.0E+00 1.9E+00 6.0E+00
7.06E+02 3.4E+00 1.9E+00 6.0E+00
4.77E+02 8.3E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+01 1.9E+00 6.0E+00
1.30E+01 5.4E+00 1.9E+00 6.0E+00
1.54E+01 2.0E+01 1.9E+00 6.0E+00 10 100
1.88E+02 7.0E+00 1.9E+00 6.0E+00
7.45E+02 3.6E+00 1.9E+00 6.0E+00
9.81 E+02 1.9E+00 1.9E+00 6.0E+00
9.97E+02 1.2E+02 1.9E+00 6.0E+00
1.31E+03 6.2E+00 1.9E+00 6.0E+00
7.07E+02 5.0E+00 1.9E+00 6.0E+00
7.27E+02 3.0E+00 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
1.08E+01 1.4E+01 1.9E+00 6.0E+00
1.62E+01 1.2E+01 1.9E+00 6.0E+00 10 100
2.23E+02 2.2E+00 1.9E+00 6.0E+00
7.26E+02 3.5E+00 1.9E+00 6.0E+00
9.28E+02 4.9E+00 1.9E+00 6.0E+00
1.18E+03 4.2E+00 1.9E+00 6.0E+00
9.10E+02 8.2E+01 1.9E+00 6.0E+00
7.07E+02 6.2E-01 1.9E+00 6.0E+00
7.22E+02 3.5E+00 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 4.0E+01 1.9E+00 6.0E+00
9.50E-01 2.9E+01 1.9E+00 6.0E+00
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.50E-01 3.2E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+01 1.9E+00 6.0E+00
9.50E-01 6.7E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.23E+02 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.88E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-481
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn SWA-L06-1313-T01-A
Mn SWA-L06-1313-T02-A
Mn SWA-L06-1313-T03-A
Mn SWA-L06-1313-T04-A
Mn SWA-L06-1313-T05-A
Mn SWA-L06-1313-T06-A
Mn SWA-L06-1313-T07-A
Mn SWA-L06-1313-T08-A
Mn SWA-L06-1313-T09-A
Mn SWA-L06-1313-T10-A
Mn SWA-L06-1313-T01-B
Mn SWA-L06-1313-T02-B
Mn SWA-L06-1313-T03-B
Mn SWA-L06-1313-T04-B
Mn SWA-L06-1313-T05-B
Mn SWA-L06-1313-T06-B
Mn SWA-L06-1313-T07-B
Mn SWA-L06-1313-T08-B
Mn SWA-L06-1313-T09-B
Mn SWA-L06-1313-T10-B
Mn SWA-L06-1313-T01-C
Mn SWA-L06-1313-T02-C
Mn SWA-L06-1313-T03-C
Mn SWA-L06-1313-T04-C
Mn SWA-L06-1313-T05-C
Mn SWA-L06-1313-T06-C
Mn SWA-L06-1313-T07-C
Mn SWA-L06-1313-T08-C
Mn SWA-L06-1313-T09-C
Mn SWA-L06-1313-T10-C
Mn SWA-L06-1313-B01-A
Mn SWA-L06-1313-B02-A
Mn SWA-L06-1313-B03-A
Mn SWA-L06-1313-B01-B
Mn SWA-L06-1313-B02-B
Mn SWA-L06-1313-B03-B
Mn SWA-L06-1313-B01-C
Mn SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.84E+00 E
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.99E+02
1 2.09E+03
1 1.20E+04
1 2.21 E+04
1 1.32E+04
1 9.59E+03
1 1.00E+00 U1/2
1 4.27E+00 E
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.76E+02
1 2.29E+03
1 9.39E+03
1 2.25E+04
1 1.31 E+04
1 1.35E+04
1 1.00E+00 U1/2
1 5.96E+00 E
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.88E+02
1 2.74E+03
1 1.24E+04
1 1.52E+04
1 1.29E+04
1 1.38E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.84E+00 5.9E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.99E+02 3.9E+00 2.0E+00 6.4E+00
2.09E+03 3.8E-01 2.0E+00 6.4E+00
1.20E+04 1.0E+00 2.0E+00 6.4E+00
2.21E+04 5.4E-01 2.0E+00 6.4E+00
1.32E+04 2.5E-01 2.0E+00 6.4E+00
9.59E+03 6.7E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
4.27E+00 6.7E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00 10 100
1.00E+00 8.4E+00 2.0E+00 6.4E+00
1.76E+02 5.7E-01 2.0E+00 6.4E+00
2.29E+03 3.4E-01 2.0E+00 6.4E+00
9.39E+03 8.4E+01 2.0E+00 6.4E+00
2.25E+04 1.2E+00 2.0E+00 6.4E+00
1.31 E+04 6.6E-01 2.0E+00 6.4E+00
1.35E+04 1.4E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+00 2.0E+00 6.4E+00
5.96E+00 8.2E-01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00 10 100
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.88E+02 7.3E-01 2.0E+00 6.4E+00
2.74E+03 5.5E+00 2.0E+00 6.4E+00
1.24E+04 2.3E+00 2.0E+00 6.4E+00
1.52E+04 6.3E+01 2.0E+00 6.4E+00
1.29E+04 1.0E+00 2.0E+00 6.4E+00
1.38E+04 4.1E-01 2.0E+00 6.4E+00
1.00E+00 5.5E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 9.5E+00 2.0E+00 6.4E+00
1.00E+00 6.7E+02 2.0E+00 6.4E+00
1.00E+00 6.8E+01 2.0E+00 6.4E+00
1.00E+00 6.8E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-482
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg SWA-L06-1313-T01-A
Mg SWA-L06-1313-T02-A
Mg SWA-L06-1313-T03-A
Mg SWA-L06-1313-T04-A
Mg SWA-L06-1313-T05-A
Mg SWA-L06-1313-T06-A
Mg SWA-L06-1313-T07-A
Mg SWA-L06-1313-T08-A
Mg SWA-L06-1313-T09-A
Mg SWA-L06-1313-T10-A
Mg SWA-L06-1313-T01-B
Mg SWA-L06-1313-T02-B
Mg SWA-L06-1313-T03-B
Mg SWA-L06-1313-T04-B
Mg SWA-L06-1313-T05-B
Mg SWA-L06-1313-T06-B
Mg SWA-L06-1313-T07-B
Mg SWA-L06-1313-T08-B
Mg SWA-L06-1313-T09-B
Mg SWA-L06-1313-T10-B
Mg SWA-L06-1313-T01-C
Mg SWA-L06-1313-T02-C
Mg SWA-L06-1313-T03-C
Mg SWA-L06-1313-T04-C
Mg SWA-L06-1313-T05-C
Mg SWA-L06-1313-T06-C
Mg SWA-L06-1313-T07-C
Mg SWA-L06-1313-T08-C
Mg SWA-L06-1313-T09-C
Mg SWA-L06-1313-T10-C
Mg SWA-L06-1313-B01-A
Mg SWA-L06-1313-B02-A
Mg SWA-L06-1313-B03-A
Mg SWA-L06-1313-B01-B
Mg SWA-L06-1313-B02-B
Mg SWA-L06-1313-B03-B
Mg SWA-L06-1313-B01-C
Mg SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.86E+01
1 1.72E+01
1 4.08E+03
1 6.91 E+05
1 1.00E+06
1 1.37E+06
1 1.52E+06
1 7.32E+05
1 4.54E+05
1 1.86E+01
1 2.17E+01
1 2.80E+01
1 3.81 E+03
1 7.00E+05
1 9.97E+05
1 1.28E+06
1 1.45E+06
1 7.09E+05
1 5.97E+05
1 1.85E+01
1 2.29E+01
1 2.45E+01
1 4.02E+03
1 6.66E+05
1 9.54E+05
1 1.29E+06
1 1.08E+06
1 7.01 E+05
1 6. 11 E+05
1 1.84E+01
1 1.39E+01
1 2.42E+00 E
1 1.86E+00 E
1 2.62E+00 E
1 1.71E+00 E
1 5.75E+00
1 9.50E+00
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.86E+01 2.6E+01 1.0E+00 3.2E+00
1.72E+01 3.5E+01 1.0E+00 3.2E+00 1000 100
4.08E+03 1.0E+00 1.0E+00 3.2E+00
6.91 E+05 3.1E+00 1.0E+00 3.2E+00
1.00E+06 8.3E-01 1.0E+00 3.2E+00
1.37E+06 8.3E-01 1.0E+00 3.2E+00
1.52E+06 1.2E+00 1.0E+00 3.2E+00
7.32E+05 1.0E+00 1.0E+00 3.2E+00
4.54E+05 5.8E+01 1.0E+00 3.2E+00
1.86E+01 3.8E+02 1.0E+00 3.2E+00
2.17E+01 2.6E+01 1.0E+00 3.2E+00
2.80E+01 4.5E+01 1.0E+00 3.2E+00 1000 100
3.81 E+03 4.3E+00 1.0E+00 3.2E+00
7.00E+05 1.5E+00 1.0E+00 3.2E+00
9.97E+05 4.9E-01 1.0E+00 3.2E+00
1.28E+06 8.6E+01 1.0E+00 3.2E+00
1.45E+06 1.4E+00 1.0E+00 3.2E+00
7.09E+05 5.0E-01 1.0E+00 3.2E+00
5.97E+05 1.3E+00 1.0E+00 3.2E+00
1.85E+01 3.8E+01 1.0E+00 3.2E+00
2.29E+01 3.4E+01 1.0E+00 3.2E+00
2.45E+01 4.6E+01 1.0E+00 3.2E+00 1000 100
4.02E+03 1.7E+00 1.0E+00 3.2E+00
6.66E+05 1.1E+00 1.0E+00 3.2E+00
9.54E+05 4.8E+00 1.0E+00 3.2E+00
1.29E+06 1.7E+00 1.0E+00 3.2E+00
1.08E+06 5.1E+01 1.0E+00 3.2E+00
7.01 E+05 4.8E-01 1.0E+00 3.2E+00
6.11E+05 2.1E+00 1.0E+00 3.2E+00
1.84E+01 2.0E+01 1.0E+00 3.2E+00
1.39E+01 4.1E+01 1.0E+00 3.2E+00
2.42E+00 7.7E+01 1.0E+00 3.2E+00
1.86E+00 2.1E+01 1.0E+00 3.2E+00
2.62E+00 3.3E+02 1.0E+00 3.2E+00
1.71E+00 1.3E+02 1.0E+00 3.2E+00
5.75E+00 5.4E+01 1.0E+00 3.2E+00
9.50E+00 5.6E+01 1.0E+00 3.2E+00
5.00E-01 2.3E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.16E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-483
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo SWA-L06-1313-T01-A
Mo SWA-L06-1313-T02-A
Mo SWA-L06-1313-T03-A
Mo SWA-L06-1313-T04-A
Mo SWA-L06-1313-T05-A
Mo SWA-L06-1313-T06-A
Mo SWA-L06-1313-T07-A
Mo SWA-L06-1313-T08-A
Mo SWA-L06-1313-T09-A
Mo SWA-L06-1313-T10-A
Mo SWA-L06-1313-T01-B
Mo SWA-L06-1313-T02-B
Mo SWA-L06-1313-T03-B
Mo SWA-L06-1313-T04-B
Mo SWA-L06-1313-T05-B
Mo SWA-L06-1313-T06-B
Mo SWA-L06-1313-T07-B
Mo SWA-L06-1313-T08-B
Mo SWA-L06-1313-T09-B
Mo SWA-L06-1313-T10-B
Mo SWA-L06-1313-T01-C
Mo SWA-L06-1313-T02-C
Mo SWA-L06-1313-T03-C
Mo SWA-L06-1313-T04-C
Mo SWA-L06-1313-T05-C
Mo SWA-L06-1313-T06-C
Mo SWA-L06-1313-T07-C
Mo SWA-L06-1313-T08-C
Mo SWA-L06-1313-T09-C
Mo SWA-L06-1313-T10-C
Mo SWA-L06-1313-B01-A
Mo SWA-L06-1313-B02-A
Mo SWA-L06-1313-B03-A
Mo SWA-L06-1313-B01-B
Mo SWA-L06-1313-B02-B
Mo SWA-L06-1313-B03-B
Mo SWA-L06-1313-B01-C
Mo SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.21E+02
1 1.31E+02
1 1.38E+02
1 1.33E+02
1 1.26E+02
1 5.69E+01
1 1.41E+01
1 4.65E+00
1 3.80E+00 E
1 1.33E+02
1 1.25E+02
1 1.44E+02
1 1.25E+02
1 1.31E+02
1 1.29E+02
1 3.84E+01
1 1.03E+01
1 7.04E+00
1 5.36E+00
1 1.38E+02
1 1.14E+02
1 1.46E+02
1 1.37E+02
1 1.40E+02
1 1.21E+02
1 4.86E+01
1 1.32E+01
1 6.88E+00
1 3.58E+00 E
1 1.35E+02
1 1.34E+02
1 2.64E+00 E
1 3.39E+00 E
1 2.66E+00 E
1 2.47E+00 E
1 2.02E+00 E
1 1.74E+00 E
1 1.77E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.21E+02 8.4E-01 1.2E+00 3.8E+00
1.31E+02 7.5E+00 1.2E+00 3.8E+00 10 100
1.38E+02 3.0E-01 1.2E+00 3.8E+00
1.33E+02 3.5E+00 1.2E+00 3.8E+00
1.26E+02 3.7E-01 1.2E+00 3.8E+00
5.69E+01 2.6E+00 1.2E+00 3.8E+00
1.41E+01 2.7E+01 1.2E+00 3.8E+00
4.65E+00 2.0E+01 1.2E+00 3.8E+00
3.80E+00 6.8E+01 1.2E+00 3.8E+00
1.33E+02 2.9E+01 1.2E+00 3.8E+00
1.25E+02 1.4E+00 1.2E+00 3.8E+00
1.44E+02 1.5E+00 1.2E+00 3.8E+00 10 100
1.25E+02 4.2E+00 1.2E+00 3.8E+00
1.31E+02 3.1E-01 1.2E+00 3.8E+00
1.29E+02 2.8E+00 1.2E+00 3.8E+00
3.84E+01 8.6E+01 1.2E+00 3.8E+00
1.03E+01 4.6E+01 1.2E+00 3.8E+00
7.04E+00 2.0E+01 1.2E+00 3.8E+00
5.36E+00 1.7E+00 1.2E+00 3.8E+00
1.38E+02 6.4E-01 1.2E+00 3.8E+00
1.14E+02 2.8E+00 1.2E+00 3.8E+00
1.46E+02 1.5E+00 1.2E+00 3.8E+00 10 100
1.37E+02 9.3E-01 1.2E+00 3.8E+00
1.40E+02 1.0E+00 1.2E+00 3.8E+00
1.21E+02 3.4E+00 1.2E+00 3.8E+00
4.86E+01 3.5E+00 1.2E+00 3.8E+00
1.32E+01 4.0E+01 1.2E+00 3.8E+00
6.88E+00 1.8E+01 1.2E+00 3.8E+00
3.58E+00 9.7E+00 1.2E+00 3.8E+00
1.35E+02 1.4E-01 1.2E+00 3.8E+00
1.34E+02 9.6E-01 1.2E+00 3.8E+00
2.64E+00 5.7E+00 1.2E+00 3.8E+00
3.39E+00 1.5E+01 1.2E+00 3.8E+00
2.66E+00 4.2E+01 1.2E+00 3.8E+00
2.47E+00 2.7E+01 1.2E+00 3.8E+00
2.02E+00 3.0E+01 1.2E+00 3.8E+00
1.74E+00 2.8E+01 1.2E+00 3.8E+00
1.77E+00 4.6E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.25E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-484
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni SWA-L06-1313-T01-A
Ni SWA-L06-1313-T02-A
Ni SWA-L06-1313-T03-A
Ni SWA-L06-1313-T04-A
Ni SWA-L06-1313-T05-A
Ni SWA-L06-1313-T06-A
Ni SWA-L06-1313-T07-A
Ni SWA-L06-1313-T08-A
Ni SWA-L06-1313-T09-A
Ni SWA-L06-1313-T10-A
Ni SWA-L06-1313-T01-B
Ni SWA-L06-1313-T02-B
Ni SWA-L06-1313-T03-B
Ni SWA-L06-1313-T04-B
Ni SWA-L06-1313-T05-B
Ni SWA-L06-1313-T06-B
Ni SWA-L06-1313-T07-B
Ni SWA-L06-1313-T08-B
Ni SWA-L06-1313-T09-B
Ni SWA-L06-1313-T10-B
Ni SWA-L06-1313-T01-C
Ni SWA-L06-1313-T02-C
Ni SWA-L06-1313-T03-C
Ni SWA-L06-1313-T04-C
Ni SWA-L06-1313-T05-C
Ni SWA-L06-1313-T06-C
Ni SWA-L06-1313-T07-C
Ni SWA-L06-1313-T08-C
Ni SWA-L06-1313-T09-C
Ni SWA-L06-1313-T10-C
Ni SWA-L06-1313-B01-A
Ni SWA-L06-1313-B02-A
Ni SWA-L06-1313-B03-A
Ni SWA-L06-1313-B01-B
Ni SWA-L06-1313-B02-B
Ni SWA-L06-1313-B03-B
Ni SWA-L06-1313-B01-C
Ni SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.38E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.20E+01
1 2.42E+01
1 1.62E+02
1 4.09E+02
1 2.96E+02
1 2.48E+02
1 9.00E-01 U1/2
1 3.08E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.69E+00
1 2.35E+01
1 1.58E+02
1 4.29E+02
1 2.90E+02
1 3.10E+02
1 9.00E-01 U1/2
1 2.85E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.09E+01
1 2.36E+01
1 1.78E+02
1 2.88E+02
1 2.90E+02
1 3.13E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.38E+00 4.8E+01 1.8E+00 5.7E+00
9.00E-01 4.9E+01 1.8E+00 5.7E+00 10 100
9.00E-01 1.8E+01 1.8E+00 5.7E+00
1.20E+01 3.9E+00 1.8E+00 5.7E+00
2.42E+01 5.8E+00 1.8E+00 5.7E+00
1.62E+02 5.3E-01 1.8E+00 5.7E+00
4.09E+02 1.2E+00 1.8E+00 5.7E+00
2.96E+02 1.0E+00 1.8E+00 5.7E+00
2.48E+02 3.9E+01 1.8E+00 5.7E+00
9.00E-01 8.7E+00 1.8E+00 5.7E+00
3.08E+00 3.8E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00 10 100
9.00E-01 8.5E+01 1.8E+00 5.7E+00
9.69E+00 2.3E+01 1.8E+00 5.7E+00
2.35E+01 7.3E+00 1.8E+00 5.7E+00
1.58E+02 9.2E+01 1.8E+00 5.7E+00
4.29E+02 1.2E+00 1.8E+00 5.7E+00
2.90E+02 4.6E-01 1.8E+00 5.7E+00
3.10E+02 1.5E+00 1.8E+00 5.7E+00
9.00E-01 4.6E+01 1.8E+00 5.7E+00
2.85E+00 4.8E+01 1.8E+00 5.7E+00
9.00E-01 6.4E+01 1.8E+00 5.7E+00 10 100
9.00E-01 2.9E+01 1.8E+00 5.7E+00
1.09E+01 1.8E+01 1.8E+00 5.7E+00
2.36E+01 7.4E+00 1.8E+00 5.7E+00
1.78E+02 1.8E+00 1.8E+00 5.7E+00
2.88E+02 5.8E+01 1.8E+00 5.7E+00
2.90E+02 2.1E-01 1.8E+00 5.7E+00
3.13E+02 8.8E-01 1.8E+00 5.7E+00
9.00E-01 4.6E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 7.0E+01 1.8E+00 5.7E+00
9.00E-01 7.7E+01 1.8E+00 5.7E+00
9.00E-01 3.6E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 4.8E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 131 3-1 31 6 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-485
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P SWA-L06-1313-T01-A
P SWA-L06-1313-T02-A
P SWA-L06-1313-T03-A
P SWA-L06-1313-T04-A
P SWA-L06-1313-T05-A
P SWA-L06-1313-T06-A
P SWA-L06-1313-T07-A
P SWA-L06-1313-T08-A
P SWA-L06-1313-T09-A
P SWA-L06-1313-T10-A
P SWA-L06-1313-T01-B
P SWA-L06-1313-T02-B
P SWA-L06-1313-T03-B
P SWA-L06-1313-T04-B
P SWA-L06-1313-T05-B
P SWA-L06-1313-T06-B
P SWA-L06-1313-T07-B
P SWA-L06-1313-T08-B
P SWA-L06-1313-T09-B
P SWA-L06-1313-T10-B
P SWA-L06-1313-T01-C
P SWA-L06-1313-T02-C
P SWA-L06-1313-T03-C
P SWA-L06-1313-T04-C
P SWA-L06-1313-T05-C
P SWA-L06-1313-T06-C
P SWA-L06-1313-T07-C
P SWA-L06-1313-T08-C
P SWA-L06-1313-T09-C
P SWA-L06-1313-T10-C
P SWA-L06-1313-B01-A
P SWA-L06-1313-B02-A
P SWA-L06-1313-B03-A
P SWA-L06-1313-B01-B
P SWA-L06-1313-B02-B
P SWA-L06-1313-B03-B
P SWA-L06-1313-B01-C
P SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.09E+03
1 2.87E+01
1 2.41 E+01
1 8.51 E+01
1 5.90E+01
1 3.49E+01
1 2.67E+01
1 3.73E+02
1 9.49E+03
1 4.93E+01
1 1.11E+03
1 2.84E+01
1 2.62E+01
1 8.61 E+01
1 7.42E+01
1 4.39E+01
1 4.03E+01
1 3.41 E+02
1 3.65E+04
1 5.44E+01
1 1.06E+03
1 3.91 E+01
1 3.07E+01
1 8.86E+01
1 9.34E+01
1 4.51 E+01
1 2.89E+01
1 2.81 E+02
1 2.36E+04
1 5.74E+01
1 5.38E+01
1 8.88E+00 E
1 1.54E+01
1 2.18E+01
1 1.65E+01
1 1.59E+01
1 1.85E+00 U1/2
1 1.66E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.09E+03 1.4E+00 3.7E+00 1.2E+01
2.87E+01 5.2E+00 3.7E+00 1.2E+01 1000 100
2.41 E+01 4.1 E+01 3.7E+00 1.2E+01
8.51E+01 2.8E+01 3.7E+00 1.2E+01
5.90E+01 7.7E+01 3.7E+00 1.2E+01
3.49E+01 4.0E+01 3.7E+00 1.2E+01
2.67E+01 4.7E+01 3.7E+00 1.2E+01
3.73E+02 1.9E+00 3.7E+00 1.2E+01
9.49E+03 7.1 E+01 3.7E+00 1.2E+01
4.93E+01 5.9E+01 3.7E+00 1.2E+01
1.11E+03 1.5E+00 3.7E+00 1.2E+01
2.84E+01 1.7E+01 3.7E+00 1.2E+01 1000 100
2.62E+01 6.5E+01 3.7E+00 1.2E+01
8.61E+01 1.7E+01 3.7E+00 1.2E+01
7.42E+01 1.1 E+01 3.7E+00 1.2E+01
4.39E+01 7.9E+01 3.7E+00 1.2E+01
4.03E+01 1.9E+01 3.7E+00 1.2E+01
3.41 E+02 2.0E-01 3.7E+00 1.2E+01
3.65E+04 7.4E-01 3.7E+00 1.2E+01
5.44E+01 2.4E+01 3.7E+00 1.2E+01
1.06E+03 1.4E+00 3.7E+00 1.2E+01
3.91E+01 2.3E+01 3.7E+00 1.2E+01 1000 100
3.07E+01 6.7E+01 3.7E+00 1.2E+01
8.86E+01 1.5E+01 3.7E+00 1.2E+01
9.34E+01 1.3E+01 3.7E+00 1.2E+01
4.51E+01 2.5E+01 3.7E+00 1.2E+01
2.89E+01 2.9E+01 3.7E+00 1.2E+01
2.81 E+02 4.4E+00 3.7E+00 1.2E+01
2.36E+04 3.8E-01 3.7E+00 1.2E+01
5.74E+01 5.6E+00 3.7E+00 1.2E+01
5.38E+01 1.7E+01 3.7E+00 1.2E+01
8.88E+00 1.1 E+02 3.7E+00 1.2E+01
1.54E+01 6.5E+00 3.7E+00 1.2E+01
2.18E+01 3.0E+01 3.7E+00 1.2E+01
1.65E+01 1.6E+01 3.7E+00 1.2E+01
1.59E+01 1.3E+01 3.7E+00 1.2E+01
1.85E+00 1.1 E+02 3.7E+00 1.2E+01
1.66E+01 4.5E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.20E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-486
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
SWA-L06-1313-T01-A
SWA-L06-1313-T02-A
SWA-L06-1313-T03-A
SWA-L06-1313-T04-A
SWA-L06-1313-T05-A
SWA-L06-1313-T06-A
SWA-L06-1313-T07-A
SWA-L06-1313-T08-A
SWA-L06-1313-T09-A
SWA-L06-1313-T10-A
SWA-L06-1313-T01-B
SWA-L06-1313-T02-B
SWA-L06-1313-T03-B
SWA-L06-1313-T04-B
SWA-L06-1313-T05-B
SWA-L06-1313-T06-B
SWA-L06-1313-T07-B
SWA-L06-1313-T08-B
SWA-L06-1313-T09-B
SWA-L06-1313-T10-B
SWA-L06-1313-T01-C
SWA-L06-1313-T02-C
SWA-L06-1313-T03-C
SWA-L06-1313-T04-C
SWA-L06-1313-T05-C
SWA-L06-1313-T06-C
SWA-L06-1313-T07-C
SWA-L06-1313-T08-C
SWA-L06-1313-T09-C
SWA-L06-1313-T10-C
SWA-L06-1313-B01-A
SWA-L06-1313-B02-A
SWA-L06-1313-B03-A
SWA-L06-1313-B01-B
SWA-L06-1313-B02-B
SWA-L06-1313-B03-B
SWA-L06-1313-B01-C
SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.30E+05
1 3.17E+05
1 4.39E+05
1 4.42E+05
1 4.67E+05
1 5.02E+05
1 5.03E+05
1 2.55E+05
1 2.69E+05
1 3.15E+05
1 5.36E+05
1 3.45E+05
1 4.09E+05
1 4.52E+05
1 4.65E+05
1 4.92E+05
1 4.66E+05
1 2.31 E+05
1 3.28E+05
1 3.18E+05
1 5.27E+05
1 3.47E+05
1 4.40E+05
1 4.60E+05
1 4.60E+05
1 4.83E+05
1 4.26E+05
1 2.63E+05
1 2.97E+05
1 3.12E+05
1 3. 11 E+05
1 3.28E+01
1 3.36E+01
1 3.65E+01
1 3.51 E+01
1 3.90E+01
1 3.48E+01
1 3.15E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.30E+05 2.0E-01 1.6E+00 5.1E+00
3.17E+05 7.0E+00 1.6E+00 5.1E+00 1000 100
4.39E+05 4.6E-01 1.6E+00 5.1E+00
4.42E+05 6.0E+00 1.6E+00 5.1E+00
4.67E+05 5.0E-01 1.6E+00 5.1E+00
5.02E+05 1.1E+00 1.6E+00 5.1E+00
5.03E+05 1.1E+00 1.6E+00 5.1E+00
2.55E+05 5.9E+00 1.6E+00 5.1E+00
2.69E+05 7.6E+01 1.6E+00 5.1E+00
3.15E+05 7.0E+01 1.6E+00 5.1E+00
5.36E+05 1.2E+00 1.6E+00 5.1E+00
3.45E+05 6.6E-01 1.6E+00 5.1E+00 1000 100
4.09E+05 4.1E+00 1.6E+00 5.1E+00
4.52E+05 9.4E-01 1.6E+00 5.1E+00
4.65E+05 3.6E-01 1.6E+00 5.1E+00
4.92E+05 1.2E+02 1.6E+00 5.1E+00
4.66E+05 5.2E-01 1.6E+00 5.1E+00
2.31 E+05 1.0E+01 1.6E+00 5.1E+00
3.28E+05 5.6E+00 1.6E+00 5.1E+00
3.18E+05 3.2E-01 1.6E+00 5.1E+00
5.27E+05 1.3E+00 1.6E+00 5.1E+00
3.47E+05 1.9E+00 1.6E+00 5.1E+00 1000 100
4.40E+05 2.8E+00 1.6E+00 5.1E+00
4.60E+05 3.6E-01 1.6E+00 5.1E+00
4.60E+05 6.0E+00 1.6E+00 5.1E+00
4.83E+05 2.0E+00 1.6E+00 5.1E+00
4.26E+05 7.2E+01 1.6E+00 5.1E+00
2.63E+05 7.7E+00 1.6E+00 5.1E+00
2.97E+05 2.0E+01 1.6E+00 5.1E+00
3.12E+05 5.5E-01 1.6E+00 5.1E+00
3.11E+05 8.6E-01 1.6E+00 5.1E+00
3.28E+01 1.5E+00 1.6E+00 5.1E+00
3.36E+01 7.0E-01 1.6E+00 5.1E+00
3.65E+01 4.7E+00 1.6E+00 5.1E+00
3.51 E+01 1.3E+01 1.6E+00 5.1E+00
3.90E+01 1.9E+01 1.6E+00 5.1E+00
3.48E+01 4.6E+00 1.6E+00 5.1E+00
3.15E+01 7.8E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.18E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.45E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.48E+05 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-487
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
SWA-L06-1313-T01-A
SWA-L06-1313-T02-A
SWA-L06-1313-T03-A
SWA-L06-1313-T04-A
SWA-L06-1313-T05-A
SWA-L06-1313-T06-A
SWA-L06-1313-T07-A
SWA-L06-1313-T08-A
SWA-L06-1313-T09-A
SWA-L06-1313-T10-A
SWA-L06-1313-T01-B
SWA-L06-1313-T02-B
SWA-L06-1313-T03-B
SWA-L06-1313-T04-B
SWA-L06-1313-T05-B
SWA-L06-1313-T06-B
SWA-L06-1313-T07-B
SWA-L06-1313-T08-B
SWA-L06-1313-T09-B
SWA-L06-1313-T10-B
SWA-L06-1313-T01-C
SWA-L06-1313-T02-C
SWA-L06-1313-T03-C
SWA-L06-1313-T04-C
SWA-L06-1313-T05-C
SWA-L06-1313-T06-C
SWA-L06-1313-T07-C
SWA-L06-1313-T08-C
SWA-L06-1313-T09-C
SWA-L06-1313-T10-C
SWA-L06-1313-B01-A
SWA-L06-1313-B02-A
SWA-L06-1313-B03-A
SWA-L06-1313-B01-B
SWA-L06-1313-B02-B
SWA-L06-1313-B03-B
SWA-L06-1313-B01-C
SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 7.66E+04
1 8.38E+04
1 9.87E+04
1 1.07E+05
1 1.14E+05
1 1.20E+05
1 1.12E+05
1 4.07E+04
1 2.08E+04
1 9.15E+04
1 7.82E+04
1 9.19E+04
1 9.06E+04
1 1.09E+05
1 1.13E+05
1 1.16E+05
1 1.03E+05
1 4.03E+04
1 2.90E+04
1 9.37E+04
1 7.34E+04
1 9.31 E+04
1 9.73E+04
1 1.13E+05
1 1.07E+05
1 1.14E+05
1 7.34E+04
1 4.05E+04
1 2.93E+04
1 9.27E+04
1 9.18E+04
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.66E+04 1.9E-01 1.5E+01 4.8E+01
8.38E+04 7.3E+00 1.5E+01 4.8E+01 10 100
9.87E+04 4.4E-01 1.5E+01 4.8E+01
1.07E+05 4.1E+00 1.5E+01 4.8E+01
1.14E+05 4.2E-01 1.5E+01 4.8E+01
1.20E+05 8.3E-01 1.5E+01 4.8E+01
1.12E+05 9.3E-01 1.5E+01 4.8E+01
4.07E+04 7.4E-01 1.5E+01 4.8E+01
2.08E+04 7.1E+01 1.5E+01 4.8E+01
9.15E+04 5.3E+01 1.5E+01 4.8E+01
7.82E+04 4.0E-01 1.5E+01 4.8E+01
9.19E+04 6.5E-01 1.5E+01 4.8E+01 10 100
9.06E+04 4.1E+00 1.5E+01 4.8E+01
1.09E+05 8.2E-01 1.5E+01 4.8E+01
1.13E+05 1.4E-01 1.5E+01 4.8E+01
1.16E+05 9.4E+01 1.5E+01 4.8E+01
1.03E+05 8.7E-01 1.5E+01 4.8E+01
4.03E+04 5.5E-01 1.5E+01 4.8E+01
2.90E+04 8.5E-01 1.5E+01 4.8E+01
9.37E+04 3.4E-01 1.5E+01 4.8E+01
7.34E+04 4.1E-01 1.5E+01 4.8E+01
9.31E+04 1.3E+00 1.5E+01 4.8E+01 10 100
9.73E+04 5.4E-01 1.5E+01 4.8E+01
1.13E+05 3.7E-01 1.5E+01 4.8E+01
1.07E+05 5.1E+00 1.5E+01 4.8E+01
1.14E+05 2.4E+00 1.5E+01 4.8E+01
7.34E+04 6.4E+01 1.5E+01 4.8E+01
4.05E+04 6.5E-01 1.5E+01 4.8E+01
2.93E+04 1.0E+00 1.5E+01 4.8E+01
9.27E+04 4.3E-01 1.5E+01 4.8E+01
9.18E+04 6.9E-01 1.5E+01 4.8E+01
7.50E+00 9.0E+01 1.5E+01 4.8E+01
7.50E+00 1.8E+02 1.5E+01 4.8E+01
7.50E+00 2.5E+01 1.5E+01 4.8E+01
7.50E+00 1.3E+02 1.5E+01 4.8E+01
7.50E+00 6.3E+01 1.5E+01 4.8E+01
7.50E+00 4.3E+01 1.5E+01 4.8E+01
7.50E+00 1.4E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.49E+04 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.28E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-488
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si SWA-L06-1313-T01-A
Si SWA-L06-1313-T02-A
Si SWA-L06-1313-T03-A
Si SWA-L06-1313-T04-A
Si SWA-L06-1313-T05-A
Si SWA-L06-1313-T06-A
Si SWA-L06-1313-T07-A
Si SWA-L06-1313-T08-A
Si SWA-L06-1313-T09-A
Si SWA-L06-1313-T10-A
Si SWA-L06-1313-T01-B
Si SWA-L06-1313-T02-B
Si SWA-L06-1313-T03-B
Si SWA-L06-1313-T04-B
Si SWA-L06-1313-T05-B
Si SWA-L06-1313-T06-B
Si SWA-L06-1313-T07-B
Si SWA-L06-1313-T08-B
Si SWA-L06-1313-T09-B
Si SWA-L06-1313-T10-B
Si SWA-L06-1313-T01-C
Si SWA-L06-1313-T02-C
Si SWA-L06-1313-T03-C
Si SWA-L06-1313-T04-C
Si SWA-L06-1313-T05-C
Si SWA-L06-1313-T06-C
Si SWA-L06-1313-T07-C
Si SWA-L06-1313-T08-C
Si SWA-L06-1313-T09-C
Si SWA-L06-1313-T10-C
Si SWA-L06-1313-B01-A
Si SWA-L06-1313-B02-A
Si SWA-L06-1313-B03-A
Si SWA-L06-1313-B01-B
Si SWA-L06-1313-B02-B
Si SWA-L06-1313-B03-B
Si SWA-L06-1313-B01-C
Si SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.65E+04
1 1.41E+04
1 6.37E+03
1 3.73E+03
1 3.76E+03
1 5.50E+03
1 5.80E+03
1 1.91E+04
1 2.77E+05
1 2.77E+04
1 4.78E+04
1 1.58E+04
1 5.94E+03
1 4.11E+03
1 3.25E+03
1 6.55E+03
1 5.56E+03
1 1.68E+04
1 7.65E+05
1 2.64E+04
1 4.74E+04
1 1.62E+04
1 6.37E+03
1 4.67E+03
1 2.98E+03
1 7.30E+03
1 4.67E+03
1 1.58E+04
1 6.95E+05
1 2.68E+04
1 2.60E+04
1 1.12E+01
1 1.25E+01
1 4.54E+00
1 1.74E+01
1 1.84E+01
1 9.78E+00
1 1.58E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.65E+04 6.9E-01 1.1E+00 3.5E+00
1.41E+04 6.9E+00 1.1E+00 3.5E+00 1000 100
6.37E+03 3.3E-01 1.1E+00 3.5E+00
3.73E+03 4.1E+00 1.1E+00 3.5E+00
3.76E+03 3.5E-01 1.1E+00 3.5E+00
5.50E+03 1.2E+00 1.1E+00 3.5E+00
5.80E+03 8.1E-01 1.1E+00 3.5E+00
1.91E+04 7.3E-01 1.1E+00 3.5E+00
2.77E+05 6.1E+01 1.1E+00 3.5E+00
2.77E+04 5.8E+01 1.1E+00 3.5E+00
4.78E+04 1.3E+00 1.1E+00 3.5E+00
1.58E+04 3.4E-01 1.1E+00 3.5E+00 1000 100
5.94E+03 4.0E+00 1.1E+00 3.5E+00
4.11E+03 1.1E+00 1.1E+00 3.5E+00
3.25E+03 3.5E-01 1.1E+00 3.5E+00
6.55E+03 9.1E+01 1.1E+00 3.5E+00
5.56E+03 1.0E+00 1.1E+00 3.5E+00
1.68E+04 7.0E-01 1.1E+00 3.5E+00
7.65E+05 1.8E+00 1.1E+00 3.5E+00
2.64E+04 1.2E-01 1.1E+00 3.5E+00
4.74E+04 7.6E-01 1.1E+00 3.5E+00
1.62E+04 1.3E+00 1.1E+00 3.5E+00 1000 100
6.37E+03 4.9E-01 1.1E+00 3.5E+00
4.67E+03 4.4E-01 1.1E+00 3.5E+00
2.98E+03 5.8E+00 1.1E+00 3.5E+00
7.30E+03 2.1E+00 1.1E+00 3.5E+00
4.67E+03 6.7E+01 1.1E+00 3.5E+00
1.58E+04 8.9E-01 1.1E+00 3.5E+00
6.95E+05 2.0E+00 1.1E+00 3.5E+00
2.68E+04 8.4E-01 1.1E+00 3.5E+00
2.60E+04 4.3E-01 1.1E+00 3.5E+00
1.12E+01 1.8E+01 1.1E+00 3.5E+00
1.25E+01 4.3E+00 1.1E+00 3.5E+00
4.54E+00 6.9E+01 1.1E+00 3.5E+00
1.74E+01 2.6E+00 1.1E+00 3.5E+00
1.84E+01 9.5E+00 1.1E+00 3.5E+00
9.78E+00 1.7E+01 1.1E+00 3.5E+00
1.58E+01 2.0E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.51E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.67E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.71E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-489
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na SWA-L06-1313-T01-A
Na SWA-L06-1313-T02-A
Na SWA-L06-1313-T03-A
Na SWA-L06-1313-T04-A
Na SWA-L06-1313-T05-A
Na SWA-L06-1313-T06-A
Na SWA-L06-1313-T07-A
Na SWA-L06-1313-T08-A
Na SWA-L06-1313-T09-A
Na SWA-L06-1313-T10-A
Na SWA-L06-1313-T01-B
Na SWA-L06-1313-T02-B
Na SWA-L06-1313-T03-B
Na SWA-L06-1313-T04-B
Na SWA-L06-1313-T05-B
Na SWA-L06-1313-T06-B
Na SWA-L06-1313-T07-B
Na SWA-L06-1313-T08-B
Na SWA-L06-1313-T09-B
Na SWA-L06-1313-T10-B
Na SWA-L06-1313-T01-C
Na SWA-L06-1313-T02-C
Na SWA-L06-1313-T03-C
Na SWA-L06-1313-T04-C
Na SWA-L06-1313-T05-C
Na SWA-L06-1313-T06-C
Na SWA-L06-1313-T07-C
Na SWA-L06-1313-T08-C
Na SWA-L06-1313-T09-C
Na SWA-L06-1313-T10-C
Na SWA-L06-1313-B01-A
Na SWA-L06-1313-B02-A
Na SWA-L06-1313-B03-A
Na SWA-L06-1313-B01-B
Na SWA-L06-1313-B02-B
Na SWA-L06-1313-B03-B
Na SWA-L06-1313-B01-C
Na SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 7.06E+05
1 4.77E+05
1 5.04E+05
1 4.88E+05
1 4.87E+05
1 4.87E+05
1 4.83E+05
1 4.83E+05
1 4.39E+05
1 4.57E+05
1 7.15E+05
1 4.79E+05
1 4.93E+05
1 4.90E+05
1 4.83E+05
1 4.63E+05
1 4.76E+05
1 4.80E+05
1 4.58E+05
1 4.62E+05
1 7.04E+05
1 4.80E+05
1 5.01 E+05
1 4.89E+05
1 4.77E+05
1 4.76E+05
1 4.72E+05
1 4.80E+05
1 4.54E+05
1 4.62E+05
1 4.68E+05
1 2.21E+01
1 7.25E+05
1 1.51E+02
1 9.67E+01
1 7.90E+01
1 6.63E+01
1 2.59E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.06E+05 7.0E-01 2.5E+00 8.0E+00
4.77E+05 1.3E+00 2.5E+00 8.0E+00 1000 100
5.04E+05 3.2E-01 2.5E+00 8.0E+00
4.88E+05 6.9E-01 2.5E+00 8.0E+00
4.87E+05 4.1E-01 2.5E+00 8.0E+00
4.87E+05 3.4E-01 2.5E+00 8.0E+00
4.83E+05 3.5E-01 2.5E+00 8.0E+00
4.83E+05 8.2E-01 2.5E+00 8.0E+00
4.39E+05 6.9E+01 2.5E+00 8.0E+00
4.57E+05 5.1E+01 2.5E+00 8.0E+00
7.15E+05 2.2E-01 2.5E+00 8.0E+00
4.79E+05 3.2E-01 2.5E+00 8.0E+00 1000 100
4.93E+05 5.1E-01 2.5E+00 8.0E+00
4.90E+05 4.5E-01 2.5E+00 8.0E+00
4.83E+05 6.5E-01 2.5E+00 8.0E+00
4.63E+05 8.7E+01 2.5E+00 8.0E+00
4.76E+05 2.5E-01 2.5E+00 8.0E+00
4.80E+05 1.0E+00 2.5E+00 8.0E+00
4.58E+05 7.0E-01 2.5E+00 8.0E+00
4.62E+05 3.2E-01 2.5E+00 8.0E+00
7.04E+05 5.5E-01 2.5E+00 8.0E+00
4.80E+05 1.4E-01 2.5E+00 8.0E+00 1000 100
5.01 E+05 1.9E-01 2.5E+00 8.0E+00
4.89E+05 1.7E-01 2.5E+00 8.0E+00
4.77E+05 1.7E-01 2.5E+00 8.0E+00
4.76E+05 6.2E-01 2.5E+00 8.0E+00
4.72E+05 5.1E+01 2.5E+00 8.0E+00
4.80E+05 2.5E-01 2.5E+00 8.0E+00
4.54E+05 7.0E-01 2.5E+00 8.0E+00
4.62E+05 9.3E-02 2.5E+00 8.0E+00
4.68E+05 6.1E-01 2.5E+00 8.0E+00
2.21 E+01 1.3E+01 2.5E+00 8.0E+00
7.25E+05 6.3E-01 2.5E+00 8.0E+00
1.51E+02 4.9E+00 2.5E+00 8.0E+00
9.67E+01 9.1E+00 2.5E+00 8.0E+00
7.90E+01 3.2E+01 2.5E+00 8.0E+00
6.63E+01 2.1E+00 2.5E+00 8.0E+00
2.59E+01 1.8E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.78E+05 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.80E+05 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.81 E+05 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-490
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr SWA-L06-1313-T01-A
Sr SWA-L06-1313-T02-A
Sr SWA-L06-1313-T03-A
Sr SWA-L06-1313-T04-A
Sr SWA-L06-1313-T05-A
Sr SWA-L06-1313-T06-A
Sr SWA-L06-1313-T07-A
Sr SWA-L06-1313-T08-A
Sr SWA-L06-1313-T09-A
Sr SWA-L06-1313-T10-A
Sr SWA-L06-1313-T01-B
Sr SWA-L06-1313-T02-B
Sr SWA-L06-1313-T03-B
Sr SWA-L06-1313-T04-B
Sr SWA-L06-1313-T05-B
Sr SWA-L06-1313-T06-B
Sr SWA-L06-1313-T07-B
Sr SWA-L06-1313-T08-B
Sr SWA-L06-1313-T09-B
Sr SWA-L06-1313-T10-B
Sr SWA-L06-1313-T01-C
Sr SWA-L06-1313-T02-C
Sr SWA-L06-1313-T03-C
Sr SWA-L06-1313-T04-C
Sr SWA-L06-1313-T05-C
Sr SWA-L06-1313-T06-C
Sr SWA-L06-1313-T07-C
Sr SWA-L06-1313-T08-C
Sr SWA-L06-1313-T09-C
Sr SWA-L06-1313-T10-C
Sr SWA-L06-1313-B01-A
Sr SWA-L06-1313-B02-A
Sr SWA-L06-1313-B03-A
Sr SWA-L06-1313-B01-B
Sr SWA-L06-1313-B02-B
Sr SWA-L06-1313-B03-B
Sr SWA-L06-1313-B01-C
Sr SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.52E+02
1 9.50E+02
1 1.80E+04
1 2.95E+04
1 3.57E+04
1 4.74E+04
1 5.02E+04
1 2.28E+04
1 1.73E+04
1 3.05E+02
1 5.49E+02
1 1.05E+03
1 1.65E+04
1 3.02E+04
1 3.61 E+04
1 4.60E+04
1 4.71 E+04
1 2.26E+04
1 1.90E+04
1 3.17E+02
1 5.26E+02
1 1.04E+03
1 1.78E+04
1 3. 11 E+04
1 3.46E+04
1 4.49E+04
1 3.54E+04
1 2.25E+04
1 1.88E+04
1 3.01 E+02
1 2.94E+02
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.52E+02 4.2E-01 1.0E+00 3.2E+00
9.50E+02 6.4E+00 1.0E+00 3.2E+00 1000 100
1.80E+04 6.6E-01 1.0E+00 3.2E+00
2.95E+04 4.2E+00 1.0E+00 3.2E+00
3.57E+04 5.8E-01 1.0E+00 3.2E+00
4.74E+04 1.0E+00 1.0E+00 3.2E+00
5.02E+04 1.4E+00 1.0E+00 3.2E+00
2.28E+04 9.8E-01 1.0E+00 3.2E+00
1.73E+04 1.2E+01 1.0E+00 3.2E+00
3.05E+02 6.4E+01 1.0E+00 3.2E+00
5.49E+02 3.2E-01 1.0E+00 3.2E+00
1.05E+03 1.3E+00 1.0E+00 3.2E+00 1000 100
1.65E+04 4.3E+00 1.0E+00 3.2E+00
3.02E+04 5.2E-01 1.0E+00 3.2E+00
3.61 E+04 9.5E-01 1.0E+00 3.2E+00
4.60E+04 9.4E+01 1.0E+00 3.2E+00
4.71 E+04 8.0E-01 1.0E+00 3.2E+00
2.26E+04 7.6E-01 1.0E+00 3.2E+00
1.90E+04 2.2E+00 1.0E+00 3.2E+00
3.17E+02 9.4E-01 1.0E+00 3.2E+00
5.26E+02 8.8E-01 1.0E+00 3.2E+00
1.04E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
1.78E+04 9.5E-01 1.0E+00 3.2E+00
3.11E+04 1.2E+00 1.0E+00 3.2E+00
3.46E+04 5.2E+00 1.0E+00 3.2E+00
4.49E+04 3.4E+00 1.0E+00 3.2E+00
3.54E+04 4.8E+01 1.0E+00 3.2E+00
2.25E+04 8.3E-01 1.0E+00 3.2E+00
1.88E+04 7.3E-01 1.0E+00 3.2E+00
3.01 E+02 1.3E-01 1.0E+00 3.2E+00
2.94E+02 1.1E+00 1.0E+00 3.2E+00
5.00E-01 4.0E+02 1.0E+00 3.2E+00
5.00E-01 1.6E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00
5.00E-01 3.8E+02 1.0E+00 3.2E+00
5.00E-01 1.5E+02 1.0E+00 3.2E+00
5.00E-01 5.7E+01 1.0E+00 3.2E+00
5.00E-01 5.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.05E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.14E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.13E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-491
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S SWA-L06-1313-T01-A
S SWA-L06-1313-T02-A
S SWA-L06-1313-T03-A
S SWA-L06-1313-T04-A
S SWA-L06-1313-T05-A
S SWA-L06-1313-T06-A
S SWA-L06-1313-T07-A
S SWA-L06-1313-T08-A
S SWA-L06-1313-T09-A
S SWA-L06-1313-T10-A
S SWA-L06-1313-T01-B
S SWA-L06-1313-T02-B
S SWA-L06-1313-T03-B
S SWA-L06-1313-T04-B
S SWA-L06-1313-T05-B
S SWA-L06-1313-T06-B
S SWA-L06-1313-T07-B
S SWA-L06-1313-T08-B
S SWA-L06-1313-T09-B
S SWA-L06-1313-T10-B
S SWA-L06-1313-T01-C
S SWA-L06-1313-T02-C
S SWA-L06-1313-T03-C
S SWA-L06-1313-T04-C
S SWA-L06-1313-T05-C
S SWA-L06-1313-T06-C
S SWA-L06-1313-T07-C
S SWA-L06-1313-T08-C
S SWA-L06-1313-T09-C
S SWA-L06-1313-T10-C
S SWA-L06-1313-B01-A
S SWA-L06-1313-B02-A
S SWA-L06-1313-B03-A
S SWA-L06-1313-B01-B
S SWA-L06-1313-B02-B
S SWA-L06-1313-B03-B
S SWA-L06-1313-B01-C
S SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.22E+05
1 8.30E+05
1 9.63E+05
1 7.57E+05
1 5.09E+05
1 5.03E+05
1 4.78E+05
1 1.88E+05
1 1.04E+05
1 7.72E+05
1 3.25E+05
1 9.88E+05
1 7.74E+05
1 7.95E+05
1 5.16E+05
1 5.19E+05
1 4.44E+05
1 1.87E+05
1 1.39E+05
1 8.43E+05
1 3.06E+05
1 9.07E+05
1 9.25E+05
1 8.83E+05
1 5.02E+05
1 4.96E+05
1 4.23E+05
1 1.87E+05
1 1.36E+05
1 7.63E+05
1 1.00E+06
1 3.58E+03
1 1.90E+02
1 1.03E+02
1 3.40E+00 U1/2
1 5.11E+01
1 6.26E+01
1 1.41E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.22E+05 4.2E-01 6.8E+00 2.2E+01
8.30E+05 1.1E+01 6.8E+00 2.2E+01 1000 100
9.63E+05 6.9E-01 6.8E+00 2.2E+01
7.57E+05 5.0E+00 6.8E+00 2.2E+01
5.09E+05 2.0E-01 6.8E+00 2.2E+01
5.03E+05 6.8E-01 6.8E+00 2.2E+01
4.78E+05 9.5E-01 6.8E+00 2.2E+01
1.88E+05 7.0E-01 6.8E+00 2.2E+01
1.04E+05 7.0E+01 6.8E+00 2.2E+01
7.72E+05 3.2E+01 6.8E+00 2.2E+01
3.25E+05 1.8E-01 6.8E+00 2.2E+01
9.88E+05 6.7E-01 6.8E+00 2.2E+01 1000 100
7.74E+05 5.3E+00 6.8E+00 2.2E+01
7.95E+05 1.2E+00 6.8E+00 2.2E+01
5.16E+05 4.4E-01 6.8E+00 2.2E+01
5.19E+05 1.0E+02 6.8E+00 2.2E+01
4.44E+05 9.3E-01 6.8E+00 2.2E+01
1.87E+05 4.0E-01 6.8E+00 2.2E+01
1.39E+05 8.6E-01 6.8E+00 2.2E+01
8.43E+05 1.1E+00 6.8E+00 2.2E+01
3.06E+05 2.9E-01 6.8E+00 2.2E+01
9.07E+05 9.2E-01 6.8E+00 2.2E+01 1000 100
9.25E+05 1.4E+00 6.8E+00 2.2E+01
8.83E+05 3.1E-01 6.8E+00 2.2E+01
5.02E+05 7.5E+00 6.8E+00 2.2E+01
4.96E+05 2.7E+00 6.8E+00 2.2E+01
4.23E+05 5.6E+01 6.8E+00 2.2E+01
1.87E+05 7.8E-01 6.8E+00 2.2E+01
1.36E+05 1.2E+00 6.8E+00 2.2E+01
7.63E+05 8.5E-01 6.8E+00 2.2E+01
1.00E+06 7.8E-01 6.8E+00 2.2E+01
3.58E+03 4.8E+00 6.8E+00 2.2E+01
1.90E+02 1.9E+01 6.8E+00 2.2E+01
1.03E+02 7.5E+00 6.8E+00 2.2E+01
3.40E+00 4.1E+02 6.8E+00 2.2E+01
5.11E+01 1.2E+02 6.8E+00 2.2E+01
6.26E+01 4.8E+01 6.8E+00 2.2E+01
1.41E+02 3.2E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.30E+05 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+05 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.08E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-492
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
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Sample Dilutic
SWA-L06-1313-T01-A
SWA-L06-1313-T02-A
SWA-L06-1313-T03-A
SWA-L06-1313-T04-A
SWA-L06-1313-T05-A
SWA-L06-1313-T06-A
SWA-L06-1313-T07-A
SWA-L06-1313-T08-A
SWA-L06-1313-T09-A
SWA-L06-1313-T10-A
SWA-L06-1313-T01-B
SWA-L06-1313-T02-B
SWA-L06-1313-T03-B
SWA-L06-1313-T04-B
SWA-L06-1313-T05-B
SWA-L06-1313-T06-B
SWA-L06-1313-T07-B
SWA-L06-1313-T08-B
SWA-L06-1313-T09-B
SWA-L06-1313-T10-B
SWA-L06-1313-T01-C
SWA-L06-1313-T02-C
SWA-L06-1313-T03-C
SWA-L06-1313-T04-C
SWA-L06-1313-T05-C
SWA-L06-1313-T06-C
SWA-L06-1313-T07-C
SWA-L06-1313-T08-C
SWA-L06-1313-T09-C
SWA-L06-1313-T10-C
SWA-L06-1313-B01-A
SWA-L06-1313-B02-A
SWA-L06-1313-B03-A
SWA-L06-1313-B01-B
SWA-L06-1313-B02-B
SWA-L06-1313-B03-B
SWA-L06-1313-B01-C
SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 6.12E+00 E
1 2.62E+01
1 1.66E+01
1 1.16E+01 E
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 5.63E+00 E
1 2.32E+01
1 1.34E+01 E
1 9.39E+00 E
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 8.63E+00 E
1 2.13E+01
1 1.10E+01 E
1 1.01E+01 E
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 2.1E+01 4.6E+00 1.5E+01
2.30E+00 3.0E+02 4.6E+00 1.5E+01 10 100
2.30E+00 5.8E+01 4.6E+00 1.5E+01
2.30E+00 3.7E+02 4.6E+00 1.5E+01
2.30E+00 3.8E+01 4.6E+00 1.5E+01
6.12E+00 5.8E+01 4.6E+00 1.5E+01
2.62E+01 8.7E+00 4.6E+00 1.5E+01
1.66E+01 2.9E+01 4.6E+00 1.5E+01
1.16E+01 7.9E+01 4.6E+00 1.5E+01
2.30E+00 3.1E+02 4.6E+00 1.5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 5.8E+01 4.6E+00 1.5E+01 10 100
2.30E+00 1.0E+02 4.6E+00 1.5E+01
2.30E+00 6.1E+01 4.6E+00 1.5E+01
2.30E+00 6.8E+01 4.6E+00 1.5E+01
5.63E+00 1.1E+02 4.6E+00 1.5E+01
2.32E+01 2.7E+01 4.6E+00 1.5E+01
1.34E+01 3.3E+01 4.6E+00 1.5E+01
9.39E+00 8.4E+01 4.6E+00 1.5E+01
2.30E+00 6.9E+01 4.6E+00 1.5E+01
2.30E+00 2.8E+01 4.6E+00 1.5E+01
2.30E+00 4.7E+01 4.6E+00 1.5E+01 10 100
2.30E+00 7.3E+01 4.6E+00 1.5E+01
2.30E+00 6.4E+01 4.6E+00 1.5E+01
2.30E+00 5.4E+01 4.6E+00 1.5E+01
8.63E+00 8.6E+01 4.6E+00 1.5E+01
2.13E+01 7.7E+01 4.6E+00 1.5E+01
1.10E+01 1.5E+01 4.6E+00 1.5E+01
1.01E+01 1.1E+02 4.6E+00 1.5E+01
2.30E+00 4.5E+01 4.6E+00 1.5E+01
2.30E+00 1.7E+02 4.6E+00 1.5E+01
2.30E+00 7.3E+01 4.6E+00 1.5E+01
2.30E+00 9.2E+01 4.6E+00 1.5E+01
2.30E+00 3.9E+01 4.6E+00 1.5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 1.7E+02 4.6E+00 1.5E+01
2.30E+00 5.4E+01 4.6E+00 1.5E+01
2.30E+00 1.5E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.82E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-493
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutic
SWA-L06-1313-T01-A
SWA-L06-1313-T02-A
SWA-L06-1313-T03-A
SWA-L06-1313-T04-A
SWA-L06-1313-T05-A
SWA-L06-1313-T06-A
SWA-L06-1313-T07-A
SWA-L06-1313-T08-A
SWA-L06-1313-T09-A
SWA-L06-1313-T10-A
SWA-L06-1313-T01-B
SWA-L06-1313-T02-B
SWA-L06-1313-T03-B
SWA-L06-1313-T04-B
SWA-L06-1313-T05-B
SWA-L06-1313-T06-B
SWA-L06-1313-T07-B
SWA-L06-1313-T08-B
SWA-L06-1313-T09-B
SWA-L06-1313-T10-B
SWA-L06-1313-T01-C
SWA-L06-1313-T02-C
SWA-L06-1313-T03-C
SWA-L06-1313-T04-C
SWA-L06-1313-T05-C
SWA-L06-1313-T06-C
SWA-L06-1313-T07-C
SWA-L06-1313-T08-C
SWA-L06-1313-T09-C
SWA-L06-1313-T10-C
SWA-L06-1313-B01-A
SWA-L06-1313-B02-A
SWA-L06-1313-B03-A
SWA-L06-1313-B01-B
SWA-L06-1313-B02-B
SWA-L06-1313-B03-B
SWA-L06-1313-B01-C
SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.01E+01
1 3.85E+02
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.77E+01
1 4.18E+03
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.37E+01
1 3.00E+02
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.1E+00 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00 10 100
1.00E+00 2.2E+02 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00
1.00E+00 8.0E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
2.01 E+01 4.6E+00 2.0E+00 6.4E+00
3.85E+02 1.1 E+01 2.0E+00 6.4E+00
1.00E+00 6.3E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+00 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00 10 100
1.00E+00 9.2E+01 2.0E+00 6.4E+00
1.00E+00 5.5E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.5E+03 2.0E+00 6.4E+00
1.00E+00 7.8E+01 2.0E+00 6.4E+00
1.77E+01 5.3E+00 2.0E+00 6.4E+00
4.18E+03 1.9E+00 2.0E+00 6.4E+00
1.00E+00 2.0E+00 2.0E+00 6.4E+00
1.00E+00 2.8E+00 2.0E+00 6.4E+00
1.00E+00 4.4E+00 2.0E+00 6.4E+00 10 100
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
1.00E+00 8.9E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+00 2.0E+00 6.4E+00
1.00E+00 4.9E+01 2.0E+00 6.4E+00
1.37E+01 1.9E+00 2.0E+00 6.4E+00
3.00E+02 8.7E-01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 5.8E+00 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/1 1 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-494
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V SWA-L06-1313-T01-A
V SWA-L06-1313-T02-A
V SWA-L06-1313-T03-A
V SWA-L06-1313-T04-A
V SWA-L06-1313-T05-A
V SWA-L06-1313-T06-A
V SWA-L06-1313-T07-A
V SWA-L06-1313-T08-A
V SWA-L06-1313-T09-A
V SWA-L06-1313-T10-A
V SWA-L06-1313-T01-B
V SWA-L06-1313-T02-B
V SWA-L06-1313-T03-B
V SWA-L06-1313-T04-B
V SWA-L06-1313-T05-B
V SWA-L06-1313-T06-B
V SWA-L06-1313-T07-B
V SWA-L06-1313-T08-B
V SWA-L06-1313-T09-B
V SWA-L06-1313-T10-B
V SWA-L06-1313-T01-C
V SWA-L06-1313-T02-C
V SWA-L06-1313-T03-C
V SWA-L06-1313-T04-C
V SWA-L06-1313-T05-C
V SWA-L06-1313-T06-C
V SWA-L06-1313-T07-C
V SWA-L06-1313-T08-C
V SWA-L06-1313-T09-C
V SWA-L06-1313-T10-C
V SWA-L06-1313-B01-A
V SWA-L06-1313-B02-A
V SWA-L06-1313-B03-A
V SWA-L06-1313-B01-B
V SWA-L06-1313-B02-B
V SWA-L06-1313-B03-B
V SWA-L06-1313-B01-C
V SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.29E+02
1 1.47E+02
1 1.16E+02
1 1.77E+02
1 1.75E+02
1 1.71E+02
1 1.50E+02
1 5.87E+01
1 1.39E+03
1 3.78E+02
1 5.41 E+02
1 1.59E+02
1 1.12E+02
1 1.90E+02
1 1.64E+02
1 1.88E+02
1 1.41 E+02
1 5.85E+01
1 1.40E+03
1 3.71 E+02
1 5.18E+02
1 1.64E+02
1 1.17E+02
1 1.92E+02
1 1.57E+02
1 1.66E+02
1 9.68E+01
1 5.85E+01
1 1.25E+03
1 3.73E+02
1 3.65E+02
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.29E+02 7.3E-01 1.5E+00 4.8E+00
1.47E+02 6.8E+00 1.5E+00 4.8E+00 10 100
1.16E+02 1.9E+00 1.5E+00 4.8E+00
1.77E+02 3.9E+00 1.5E+00 4.8E+00
1.75E+02 1.4E+00 1.5E+00 4.8E+00
1.71 E+02 4.8E-01 1.5E+00 4.8E+00
1.50E+02 2.6E+00 1.5E+00 4.8E+00
5.87E+01 3.7E+00 1.5E+00 4.8E+00
1.39E+03 7.2E+01 1.5E+00 4.8E+00
3.78E+02 5.5E+01 1.5E+00 4.8E+00
5.41 E+02 5.8E-01 1.5E+00 4.8E+00
1.59E+02 3.4E-01 1.5E+00 4.8E+00 10 100
1.12E+02 3.1E+00 1.5E+00 4.8E+00
1.90E+02 1.0E+00 1.5E+00 4.8E+00
1.64E+02 5.2E-01 1.5E+00 4.8E+00
1.88E+02 8.7E+01 1.5E+00 4.8E+00
1.41 E+02 3.8E+00 1.5E+00 4.8E+00
5.85E+01 3.8E+00 1.5E+00 4.8E+00
1.40E+03 1.4E-01 1.5E+00 4.8E+00
3.71 E+02 3.9E-01 1.5E+00 4.8E+00
5.18E+02 1.0E+00 1.5E+00 4.8E+00
1.64E+02 1.2E+00 1.5E+00 4.8E+00 10 100
1.17E+02 1.6E+00 1.5E+00 4.8E+00
1.92E+02 6.2E-01 1.5E+00 4.8E+00
1.57E+02 4.6E+00 1.5E+00 4.8E+00
1.66E+02 3.2E+00 1.5E+00 4.8E+00
9.68E+01 6.1E+01 1.5E+00 4.8E+00
5.85E+01 3.1E+00 1.5E+00 4.8E+00
1.25E+03 1.7E+00 1.5E+00 4.8E+00
3.73E+02 6.1E-01 1.5E+00 4.8E+00
3.65E+02 5.9E-01 1.5E+00 4.8E+00
7.50E-01 1.4E+01 1.5E+00 4.8E+00
7.50E-01 2.3E+01 1.5E+00 4.8E+00
7.50E-01 2.7E+01 1.5E+00 4.8E+00
7.50E-01 4.3E+01 1.5E+00 4.8E+00
7.50E-01 2.9E+01 1.5E+00 4.8E+00
7.50E-01 2.4E+01 1.5E+00 4.8E+00
7.50E-01 4.2E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.26E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-495
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn SWA-L06-1313-T01-A
Zn SWA-L06-1313-T02-A
Zn SWA-L06-1313-T03-A
Zn SWA-L06-1313-T04-A
Zn SWA-L06-1313-T05-A
Zn SWA-L06-1313-T06-A
Zn SWA-L06-1313-T07-A
Zn SWA-L06-1313-T08-A
Zn SWA-L06-1313-T09-A
Zn SWA-L06-1313-T10-A
Zn SWA-L06-1313-T01-B
Zn SWA-L06-1313-T02-B
Zn SWA-L06-1313-T03-B
Zn SWA-L06-1313-T04-B
Zn SWA-L06-1313-T05-B
Zn SWA-L06-1313-T06-B
Zn SWA-L06-1313-T07-B
Zn SWA-L06-1313-T08-B
Zn SWA-L06-1313-T09-B
Zn SWA-L06-1313-T10-B
Zn SWA-L06-1313-T01-C
Zn SWA-L06-1313-T02-C
Zn SWA-L06-1313-T03-C
Zn SWA-L06-1313-T04-C
Zn SWA-L06-1313-T05-C
Zn SWA-L06-1313-T06-C
Zn SWA-L06-1313-T07-C
Zn SWA-L06-1313-T08-C
Zn SWA-L06-1313-T09-C
Zn SWA-L06-1313-T10-C
Zn SWA-L06-1313-B01-A
Zn SWA-L06-1313-B02-A
Zn SWA-L06-1313-B03-A
Zn SWA-L06-1313-B01-B
Zn SWA-L06-1313-B02-B
Zn SWA-L06-1313-B03-B
Zn SWA-L06-1313-B01-C
Zn SWA-L06-1313-B02-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.60E+01
1 2.89E+00 E
1 3.22E+00
1 3.66E+00
1 3.11E+OOE
1 2.76E+01
1 5.54E+02
1 1.17E+03
1 1.35E+03
1 2.07E+00 E
1 3.09E+01
1 2.86E+00 E
1 2.58E+00 E
1 2.80E+00 E
1 3.76E+00
1 2.60E+01
1 6.94E+02
1 1.18E+03
1 1.73E+03
1 2.94E+00 E
1 2.80E+01
1 2.67E+00 E
1 2.20E+00 E
1 2.70E+00 E
1 3.15E+00 E
1 3.09E+01
1 5.31 E+02
1 1.15E+03
1 1.72E+03
1 2.28E+00 E
1 3.52E+00
1 1.36E+00 E
1 1.25E+00 E
1 1.62E+00 E
1 3.92E+00
1 2.43E+00 E
1 2.01 E+00 E
1 2.14E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.60E+01 1.2E+00 1.0E+00 3.2E+00
2.89E+00 1.5E+01 1.0E+00 3.2E+00 10 100
3.22E+00 1.9E+01 1.0E+00 3.2E+00
3.66E+00 2.6E+01 1.0E+00 3.2E+00
3.11E+00 1.2E+01 1.0E+00 3.2E+00
2.76E+01 1.6E+00 1.0E+00 3.2E+00
5.54E+02 1.6E+00 1.0E+00 3.2E+00
1.17E+03 1.8E+00 1.0E+00 3.2E+00
1.35E+03 4.0E+01 1.0E+00 3.2E+00
2.07E+00 3.6E+03 1.0E+00 3.2E+00
3.09E+01 2.0E+00 1.0E+00 3.2E+00
2.86E+00 5.6E+00 1.0E+00 3.2E+00 10 100
2.58E+00 4.1 E+00 1.0E+00 3.2E+00
2.80E+00 1.7E+01 1.0E+00 3.2E+00
3.76E+00 3.1 E+00 1.0E+00 3.2E+00
2.60E+01 9.2E+01 1.0E+00 3.2E+00
6.94E+02 1.8E+00 1.0E+00 3.2E+00
1.18E+03 8.4E-01 1.0E+00 3.2E+00
1.73E+03 5.7E-01 1.0E+00 3.2E+00
2.94E+00 1.6E+01 1.0E+00 3.2E+00
2.80E+01 4.0E-01 1.0E+00 3.2E+00
2.67E+00 8.4E+00 1.0E+00 3.2E+00 10 100
2.20E+00 6.6E+00 1.0E+00 3.2E+00
2.70E+00 1.9E+01 1.0E+00 3.2E+00
3.15E+00 1.4E+01 1.0E+00 3.2E+00
3.09E+01 3.6E+00 1.0E+00 3.2E+00
5.31 E+02 3.0E+01 1.0E+00 3.2E+00
1.15E+03 5.7E-01 1.0E+00 3.2E+00
1.72E+03 3.1 E+00 1.0E+00 3.2E+00
2.28E+00 1.2E+01 1.0E+00 3.2E+00
3.52E+00 1.2E+01 1.0E+00 3.2E+00
1.36E+00 2.1E+01 1.0E+00 3.2E+00
1.25E+00 4.6E+00 1.0E+00 3.2E+00
1.62E+00 2.3E+01 1.0E+00 3.2E+00
3.92E+00 8.3E+00 1.0E+00 3.2E+00
2.43E+00 2.0E+01 1.0E+00 3.2E+00
2.01 E+00 7.4E+00 1.0E+00 3.2E+00
2.14E+00 1.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.16E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/1/11 2:59 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:00 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:02 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:04 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:05 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:07 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:09 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:10 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:12 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:51 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:18 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:20 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:22 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:23 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:25 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:27 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:28 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:30 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:32 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:53 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:33 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:35 PM EPA Interlab L06 1313-1316SWA
4/1/11 3:37 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:38 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:40 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:41 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:43 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:45 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 3:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:46 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:47 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:49 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:50 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:52 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:54 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:55 PM EPA Interlab L06 1313-1316 SWA
4/1/11 2:57 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                          1-496
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al SWA-L07-1313-T01-A 1
Al SWA-L07-1313-T02-A 1
Al SWA-L07-1313-T03-A 1
Al SWA-L07-1313-T04-A 1
Al SWA-L07-1313-T05-A 1
Al SWA-L07-1313-T06-A 1
Al SWA-L07-1313-T07-A 1
Al SWA-L07-1313-T08-A 1
Al SWA-L07-1313-T09-A 1
Al SWA-L07-1313-T01-B 1
Al SWA-L07-1313-T02-B 1
Al SWA-L07-1313-T03-B 1
Al SWA-L07-1313-T04-B 1
Al SWA-L07-1313-T05-B 1
Al SWA-L07-1313-T06-B 1
Al SWA-L07-1313-T07-B 1
Al SWA-L07-1313-T08-B 1
Al SWA-L07-1313-T09-B 1
Al SWA-L07-1313-T01-C 1
Al SWA-L07-1313-T02-C 1
Al SWA-L07-1313-T03-C 1
Al SWA-L07-1313-T04-C 1
Al SWA-L07-1313-T05-C 1
Al SWA-L07-1313-T06-C 1
Al SWA-L07-1313-T07-C 1
Al SWA-L07-1313-T08-C 1
Al SWA-L07-1313-T09-C 1
Al SWA-L07-1313-B01-A 1
Al SWA-L07-1313-B02-A 1
Sample
Cone. Qualifier
ug/L
3.56E+04
2.92E+03
1.56E+02
5.91E+01
1.91E+01
5.91E+01
3.20E+02
2.00E+05
3.12E+06
3.63E+04
2.89E+03
2.82E+02
4.08E+01
1.78E+01
8.45E+01
2.82E+02
2.43E+05
6.07E+05
3.85E+04
3.45E+03
2.55E+02
3.12E+01
2.80E+01
8.92E+01
2.78E+02
1.75E+05
6.36E+05
1.07E+01
2.31 E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.56E+04 7.6E-01 1.0E+00 3.2E+00
2.92E+03 5.4E-01 1.0E+00 3.2E+00
1.56E+02 1.1E+01 1.0E+00 3.2E+00 1000 100
5.91 E+01 1.6E+01 1.0E+00 3.2E+00
1.91 E+01 5.9E+01 1.0E+00 3.2E+00
5.91 E+01 3.6E+01 1.0E+00 3.2E+00
3.20E+02 3.1E-01 1.0E+00 3.2E+00
2.00E+05 1.1E+00 1.0E+00 3.2E+00
3.12E+06 2.2E-01 1.0E+00 3.2E+00
3.63E+04 1.4E+00 1.0E+00 3.2E+00
2.89E+03 6.9E-01 1.0E+00 3.2E+00
2.82E+02 1.3E+00 1.0E+00 3.2E+00 1000 100
4.08E+01 4.7E+00 1.0E+00 3.2E+00
1.78E+01 3.3E+01 1.0E+00 3.2E+00
8.45E+01 4.8E+00 1.0E+00 3.2E+00
2.82E+02 6.5E-02 1.0E+00 3.2E+00
2.43E+05 7.6E-01 1.0E+00 3.2E+00
6.07E+05 5.7E-01 1.0E+00 3.2E+00
3.85E+04 3.1E-01 1.0E+00 3.2E+00
3.45E+03 2.9E-01 1.0E+00 3.2E+00
2.55E+02 7.2E+01 1.0E+00 3.2E+00 1000 100
3.12E+01 3.4E+01 1.0E+00 3.2E+00
2.80E+01 2.5E+01 1.0E+00 3.2E+00
8.92E+01 2.5E+00 1.0E+00 3.2E+00
2.78E+02 7.2E-01 1.0E+00 3.2E+00
1.75E+05 1.0E+00 1.0E+00 3.2E+00
6.36E+05 8.4E-01 1.0E+00 3.2E+00
1.07E+01 6.6E+00 1.0E+00 3.2E+00
2.31 E+01 9.6E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.20E+03 104% VU ICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.40E+03 112% VUICP-OES 11/3/10 11 :54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:11 PM EPA Interlab L07 1313-1316 SWA
1.11E+03 86% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 4PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 6PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 7PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                                   1-497
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L07-1313-T01-A 1
Sb SWA-L07-1313-T02-A 1
Sb SWA-L07-1313-T03-A 1
Sb SWA-L07-1313-T04-A 1
Sb SWA-L07-1313-T05-A 1
Sb SWA-L07-1313-T06-A 1
Sb SWA-L07-1313-T07-A 1
Sb SWA-L07-1313-T08-A 1
Sb SWA-L07-1313-T09-A 1
Sb SWA-L07-1313-T01-B 1
Sb SWA-L07-1313-T02-B 1
Sb SWA-L07-1313-T03-B 1
Sb SWA-L07-1313-T04-B 1
Sb SWA-L07-1313-T05-B 1
Sb SWA-L07-1313-T06-B 1
Sb SWA-L07-1313-T07-B 1
Sb SWA-L07-1313-T08-B 1
Sb SWA-L07-1313-T09-B 1
Sb SWA-L07-1313-T01-C 1
Sb SWA-L07-1313-T02-C 1
Sb SWA-L07-1313-T03-C 1
Sb SWA-L07-1313-T04-C 1
Sb SWA-L07-1313-T05-C 1
Sb SWA-L07-1313-T06-C 1
Sb SWA-L07-1313-T07-C 1
Sb SWA-L07-1313-T08-C 1
Sb SWA-L07-1313-T09-C 1
Sb SWA-L07-1313-B01-A 1
Sb SWA-L07-1313-B02-A 1
Sample
Cone. Qualifier
ug/L
3.04E+03
4.91 E+02
1.46E+03
1.56E+03
1.51E+03
1.47E+03
1.25E+03
7.84E+02
2.61 E+04
3.66E+03
5.22E+02
1.42E+03
1.56E+03
1.48E+03
1.35E+03
1.07E+03
7.38E+02
1.48E+04
3.76E+03
6.90E+02
1.52E+03
1.60E+03
1.69E+03
1.38E+03
1.33E+03
1.06E+03
4.66E+03
7.74E+00 E
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.04E+03 1.2E+00 7.5E+00 2.4E+01
4.91E+02 3.7E-01 7.5E+00 2.4E+01
1.46E+03 2.1E+00 7.5E+00 2.4E+01 10 100
1.56E+03 9.1E-01 7.5E+00 2.4E+01
1.51E+03 1.7E+00 7.5E+00 2.4E+01
1.47E+03 1.1E+00 7.5E+00 2.4E+01
1.25E+03 1.0E+00 7.5E+00 2.4E+01
7.84E+02 1.4E+00 7.5E+00 2.4E+01
2.61 E+04 6.9E-01 7.5E+00 2.4E+01
3.66E+03 6.5E-01 7.5E+00 2.4E+01
5.22E+02 1.8E+00 7.5E+00 2.4E+01
1.42E+03 3.3E-01 7.5E+00 2.4E+01 10 100
1.56E+03 3.4E-01 7.5E+00 2.4E+01
1.48E+03 1.5E+00 7.5E+00 2.4E+01
1.35E+03 1.4E+00 7.5E+00 2.4E+01
1.07E+03 9.6E+00 7.5E+00 2.4E+01
7.38E+02 2.6E+00 7.5E+00 2.4E+01
1.48E+04 7.3E-01 7.5E+00 2.4E+01
3.76E+03 6.6E-01 7.5E+00 2.4E+01
6.90E+02 1.5E+00 7.5E+00 2.4E+01
1.52E+03 2.3E+00 7.5E+00 2.4E+01 10 100
1.60E+03 6.7E-01 7.5E+00 2.4E+01
1.69E+03 1.1E+00 7.5E+00 2.4E+01
1.38E+03 2.3E+00 7.5E+00 2.4E+01
1.33E+03 5.0E+00 7.5E+00 2.4E+01
1.06E+03 6.8E-01 7.5E+00 2.4E+01
4.66E+03 6.9E-01 7.5E+00 2.4E+01
7.74E+00 8.7E+01 7.5E+00 2.4E+01
3.75E+00 8.5E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
2.36E+03 91% VUICP-OES 1 1/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
2.45E+03 103% VU ICP-OES 11/3/10 1 1:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:11 PM EPA Interlab L07 1313-1316 SWA
2.50E+03 98% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 4PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 6PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 7PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-498
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone.
1 ug/L
As SWA-L07-1313-T01-A 1 4.55E+03
As SWA-L07-1313-T02-A 1 2.30E+02
As SWA-L07-1313-T03-A 1 1.39E+02
As SWA-L07-1313-T04-A 1 4.20E+02
As SWA-L07-1313-T05-A 1 1.97E+02
As SWA-L07-1313-T06-A 1 2.33E+02
As SWA-L07-1313-T07-A 1 2.75E+02
As SWA-L07-1313-T08-A 1 2.62E+03
As SWA-L07-1313-T09-A 1 6.64E+04
As SWA-L07-1313-T01-B 1 4.39E+03
As SWA-L07-1313-T02-B 1 2.12E+02
As SWA-L07-1313-T03-B 1 1.43E+02
As SWA-L07-1313-T04-B 1 3.78E+02
As SWA-L07-1313-T05-B 1 2.31E+02
As SWA-L07-1313-T06-B 1 1.92E+02
As SWA-L07-1313-T07-B 1 3.75E+02
As SWA-L07-1313-T08-B 1 2.85E+03
As SWA-L07-1313-T09-B 1 1.39E+04
As SWA-L07-1313-T01-C 1 4.62E+03
As SWA-L07-1313-T02-C 1 2.45E+02
As SWA-L07-1313-T03-C 1 2.01E+02
As SWA-L07-1313-T04-C 1 4.17E+02
As SWA-L07-1313-T05-C 1 3.69E+02
As SWA-L07-1313-T06-C 1 1.45E+02
As SWA-L07-1313-T07-C 1 2.91E+02
As SWA-L07-1313-T08-C 1 2.50E+03
As SWA-L07-1313-T09-C 1 9.32E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.55E+03 1.2E+00 1.1E+01 3.5E+01
2.30E+02 2.7E+00 1.1E+01 3.5E+01
1.39E+02 7.7E+00 1.1E+01 3.5E+01 10 100
4.20E+02 2.5E+00 1.1E+01 3.5E+01
1.97E+02 8.3E+00 1.1E+01 3.5E+01
2.33E+02 8.6E+00 1.1E+01 3.5E+01
2.75E+02 2.5E+00 1.1E+01 3.5E+01
2.62E+03 1.4E+00 1.1E+01 3.5E+01
6.64E+04 1.9E+00 1.1E+01 3.5E+01
4.39E+03 3.9E-01 1.1E+01 3.5E+01
2.12E+02 2.7E+00 1.1E+01 3.5E+01
1.43E+02 5.6E+00 1.1E+01 3.5E+01 10 100
3.78E+02 1.5E+00 1.1E+01 3.5E+01
2.31 E+02 3.9E+00 1.1E+01 3.5E+01
1.92E+02 7.6E+00 1.1E+01 3.5E+01
3.75E+02 2.9E+00 1.1E+01 3.5E+01
2.85E+03 4.2E-01 1.1E+01 3.5E+01
1.39E+04 1.4E+00 1.1E+01 3.5E+01
4.62E+03 8.9E-01 1.1E+01 3.5E+01
2.45E+02 2.3E+00 1.1E+01 3.5E+01
2.01E+02 4.7E+00 1.1E+01 3.5E+01 10 100
4.17E+02 2.3E+00 1.1E+01 3.5E+01
3.69E+02 2.9E+00 1.1E+01 3.5E+01
1.45E+02 3.9E+00 1.1E+01 3.5E+01
2.91E+02 2.3E+00 1.1E+01 3.5E+01
2.50E+03 3.8E-01 1.1E+01 3.5E+01
9.32E+03 5.8E-01 1.1E+01 3.5E+01
As SWA-L07-1313-B01-A 1 5.50E+00 U1/2 5.50E+00 6.4E+01 1.1E+01 3.5E+01
As SWA-L07-1313-B02-A 1 5.50E+00 U1/2 5.50E+00 5.7E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.23E+03 109% VU ICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.33E+03 119% VUICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
1.34E+03 114% VUICP-OES 1 1/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-499
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-L07-1313-T01-A 1
B SWA-L07-1313-T02-A 1
B SWA-L07-1313-T03-A 1
B SWA-L07-1313-T04-A 1
B SWA-L07-1313-T05-A 1
B SWA-L07-1313-T06-A 1
B SWA-L07-1313-T07-A 1
B SWA-L07-1313-T08-A 1
B SWA-L07-1313-T09-A 1
B SWA-L07-1313-T01-B 1
B SWA-L07-1313-T02-B 1
B SWA-L07-1313-T03-B 1
B SWA-L07-1313-T04-B 1
B SWA-L07-1313-T05-B 1
B SWA-L07-1313-T06-B 1
B SWA-L07-1313-T07-B 1
B SWA-L07-1313-T08-B 1
B SWA-L07-1313-T09-B 1
B SWA-L07-1313-T01-C 1
B SWA-L07-1313-T02-C 1
B SWA-L07-1313-T03-C 1
B SWA-L07-1313-T04-C 1
B SWA-L07-1313-T05-C 1
B SWA-L07-1313-T06-C 1
B SWA-L07-1313-T07-C 1
B SWA-L07-1313-T08-C 1
B SWA-L07-1313-T09-C 1
B SWA-L07-1313-B01-A 1
B SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
9.45E+02
9.62E+01
1.19E+03
1.88E+03
3.41 E+03
4.41 E+03
6.94E+03
6.15E+03
1.77E+04
9.47E+02
1.03E+02
1.20E+03
1.95E+03
2.93E+03
4.87E+03
6.32E+03
5.90E+03
6.15E+03
1.09E+03
1.61E+02
1.19E+03
2.13E+03
2.64E+03
4.77E+03
6.58E+03
6.79E+03
5.96E+03
1.28E+01
1.69E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.45E+02 1.1E+00 1.0E+00 3.2E+00
9.62E+01 1.5E+00 1.0E+00 3.2E+00
1.19E+03 4.5E-01 1.0E+00 3.2E+00 1000 100
1.88E+03 5.5E-01 1.0E+00 3.2E+00
3.41 E+03 3.9E-01 1.0E+00 3.2E+00
4.41 E+03 4.9E-01 1.0E+00 3.2E+00
6.94E+03 4.2E-01 1.0E+00 3.2E+00
6.15E+03 7.4E-01 1.0E+00 3.2E+00
1.77E+04 3.3E-01 1.0E+00 3.2E+00
9.47E+02 1.0E+00 1.0E+00 3.2E+00
1.03E+02 9.6E-01 1.0E+00 3.2E+00
1.20E+03 1.8E-01 1.0E+00 3.2E+00 1000 100
1.95E+03 2.7E-01 1.0E+00 3.2E+00
2.93E+03 4.4E-01 1.0E+00 3.2E+00
4.87E+03 1.9E-01 1.0E+00 3.2E+00
6.32E+03 2.8E-01 1.0E+00 3.2E+00
5.90E+03 2.8E-01 1.0E+00 3.2E+00
6.15E+03 7.0E-01 1.0E+00 3.2E+00
1.09E+03 3.7E-01 1.0E+00 3.2E+00
1.61E+02 2.1E+00 1.0E+00 3.2E+00
1.19E+03 2.9E+00 1.0E+00 3.2E+00 1000 100
2.13E+03 1.1E+00 1.0E+00 3.2E+00
2.64E+03 1.2E+00 1.0E+00 3.2E+00
4.77E+03 2.4E+00 1.0E+00 3.2E+00
6.58E+03 5.8E-01 1.0E+00 3.2E+00
6.79E+03 6.6E-01 1.0E+00 3.2E+00
5.96E+03 2.8E-01 1.0E+00 3.2E+00
1.28E+01 1.2E+01 1.0E+00 3.2E+00
1.69E+01 6.6E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
2.13E+03 94% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
2.29E+03 109% VU ICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
2.35E+03 116% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-500
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba SWA-L07-1313-T01-A 1
Ba SWA-L07-1313-T02-A 1
Ba SWA-L07-1313-T03-A 1
Ba SWA-L07-1313-T04-A 1
Ba SWA-L07-1313-T05-A 1
Ba SWA-L07-1313-T06-A 1
Ba SWA-L07-1313-T07-A 1
Ba SWA-L07-1313-T08-A 1
Ba SWA-L07-1313-T09-A 1
Ba SWA-L07-1313-T01-B 1
Ba SWA-L07-1313-T02-B 1
Ba SWA-L07-1313-T03-B 1
Ba SWA-L07-1313-T04-B 1
Ba SWA-L07-1313-T05-B 1
Ba SWA-L07-1313-T06-B 1
Ba SWA-L07-1313-T07-B 1
Ba SWA-L07-1313-T08-B 1
Ba SWA-L07-1313-T09-B 1
Ba SWA-L07-1313-T01-C 1
Ba SWA-L07-1313-T02-C 1
Ba SWA-L07-1313-T03-C 1
Ba SWA-L07-1313-T04-C 1
Ba SWA-L07-1313-T05-C 1
Ba SWA-L07-1313-T06-C 1
Ba SWA-L07-1313-T07-C 1
Ba SWA-L07-1313-T08-C 1
Ba SWA-L07-1313-T09-C 1
Ba SWA-L07-1313-B01-A 1
Ba SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
1.95E+02
6.89E+02
1.35E+03
1.12E+03
1.15E+03
1.53E+03
1.87E+03
8.53E+02
9.37E+03
2.02E+02
7.17E+02
1.29E+03
1.09E+03
1.16E+03
1.53E+03
1.62E+03
7.52E+02
9.18E+02
2.00E+02
6.96E+02
1.51E+03
1.16E+03
1.29E+03
1.39E+03
2.08E+03
1.08E+03
9.13E+02
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.95E+02 6.0E-01 1.0E+00 3.2E+00
6.89E+02 1.4E+00 1.0E+00 3.2E+00
1.35E+03 6.5E-01 1.0E+00 3.2E+00 10 100
1.12E+03 5.9E-01 1.0E+00 3.2E+00
1.15E+03 4.1E-01 1.0E+00 3.2E+00
1.53E+03 5.8E-01 1.0E+00 3.2E+00
1.87E+03 2.1E-01 1.0E+00 3.2E+00
8.53E+02 1.0E+00 1.0E+00 3.2E+00
9.37E+03 7.1E-01 1.0E+00 3.2E+00
2.02E+02 6.0E-01 1.0E+00 3.2E+00
7.17E+02 6.0E-01 1.0E+00 3.2E+00
1.29E+03 1.7E-01 1.0E+00 3.2E+00 10 100
1.09E+03 6.2E-01 1.0E+00 3.2E+00
1.16E+03 5.1E-01 1.0E+00 3.2E+00
1.53E+03 3.1E-01 1.0E+00 3.2E+00
1.62E+03 4.3E-01 1.0E+00 3.2E+00
7.52E+02 4.7E-01 1.0E+00 3.2E+00
9.18E+02 8.3E-01 1.0E+00 3.2E+00
2.00E+02 3.6E-01 1.0E+00 3.2E+00
6.96E+02 8.1E-01 1.0E+00 3.2E+00
1.51E+03 2.1E+00 1.0E+00 3.2E+00 10 100
1.16E+03 8.8E-01 1.0E+00 3.2E+00
1.29E+03 9.2E-01 1.0E+00 3.2E+00
1.39E+03 2.8E+00 1.0E+00 3.2E+00
2.08E+03 6.9E-01 1.0E+00 3.2E+00
1.08E+03 3.8E-01 1.0E+00 3.2E+00
9.13E+02 1.4E+00 1.0E+00 3.2E+00
5.00E-01 5.0E-01 1.0E+00 3.2E+00
5.00E-01 3.9E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
2.31E+03 95% VUICP-OES 1 1/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
2.32E+03 102% VU ICP-OES 11/3/10 1 1:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:11 PM EPA Interlab L07 1313-1316 SWA
2.37E+03 86% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 4PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 6PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 7PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 9PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-501
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L07-1313-T01-A 1
Be SWA-L07-1313-T02-A 1
Be SWA-L07-1313-T03-A 1
Be SWA-L07-1313-T04-A 1
Be SWA-L07-1313-T05-A 1
Be SWA-L07-1313-T06-A 1
Be SWA-L07-1313-T07-A 1
Be SWA-L07-1313-T08-A 1
Be SWA-L07-1313-T09-A 1
Be SWA-L07-1313-T01-B 1
Be SWA-L07-1313-T02-B 1
Be SWA-L07-1313-T03-B 1
Be SWA-L07-1313-T04-B 1
Be SWA-L07-1313-T05-B 1
Be SWA-L07-1313-T06-B 1
Be SWA-L07-1313-T07-B 1
Be SWA-L07-1313-T08-B 1
Be SWA-L07-1313-T09-B 1
Be SWA-L07-1313-T01-C 1
Be SWA-L07-1313-T02-C 1
Be SWA-L07-1313-T03-C 1
Be SWA-L07-1313-T04-C 1
Be SWA-L07-1313-T05-C 1
Be SWA-L07-1313-T06-C 1
Be SWA-L07-1313-T07-C 1
Be SWA-L07-1313-T08-C 1
Be SWA-L07-1313-T09-C 1
Be SWA-L07-1313-B01-A 1
Be SWA-L07-1313-B02-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.88E+01
3.25E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
3.68E+01
1.35E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
6.48E+00
1.24E+02
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 8.3E+01 1.9E+00 6.0E+00
9.50E-01 4.7E+03 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00 10 100
9.50E-01 2.6E+03 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 2.9E+02 1.9E+00 6.0E+00
9.50E-01 7.0E+01 1.9E+00 6.0E+00
1.88E+01 5.5E+00 1.9E+00 6.0E+00
3.25E+02 2.9E-01 1.9E+00 6.0E+00
9.50E-01 5.1E+01 1.9E+00 6.0E+00
9.50E-01 4.6E+02 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00 10 100
9.50E-01 4.0E+02 1.9E+00 6.0E+00
9.50E-01 8.3E+01 1.9E+00 6.0E+00
9.50E-01 4.4E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
3.68E+01 8.2E-01 1.9E+00 6.0E+00
1.35E+02 1.5E+00 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 3.7E+02 1.9E+00 6.0E+00
9.50E-01 5.0E+01 1.9E+00 6.0E+00 10 100
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 7.8E+01 1.9E+00 6.0E+00
6.48E+00 1.2E+01 1.9E+00 6.0E+00
1.24E+02 5.5E-01 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00
9.50E-01 2.7E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.07E+03 107% VU ICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.14E+03 114% VUICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
1.11E+03 111% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-502
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L07-1313-T01-A 1 1.10E+OOU1/2 1.10E+00 2.0E+02 2.2E+00 7.0E+00
Cd SWA-L07-1313-T02-A 1 1.10E+OOU1/2 1.10E+00 4.5E+02 2.2E+00 7.0E+00
Cd SWA-L07-1313-T03-A 1 1.10E+OOU1/2 1.10E+00 3.5E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L07-1313-T04-A 1 1.10E+OOU1/2 1.10E+00 4.8E+02 2.2E+00 7.0E+00
Cd SWA-L07-1313-T05-A 1 1.10E+OOU1/2 1.10E+00 1.3E+02 2.2E+00 7.0E+00
Cd SWA-L07-1313-T06-A 1 1.10E+OOU1/2 1.10E+00 1.7E+02 2.2E+00 7.0E+00
Cd SWA-L07-1313-T07-A 1 9.25E+00
Cd SWA-L07-1313-T08-A 1 1.36E+01
Cd SWA-L07-1313-T09-A 1 1.20E+02
9.25E+00 2.6E+00 2.2E+00 7.0E+00
1.36E+01 2.0E+00 2.2E+00 7.0E+00
1.20E+02 2.6E+00 2.2E+00 7.0E+00
Cd SWA-L07-1313-T01-B 1 1.10E+OOU1/2 1.10E+00 9.9E+01 2.2E+00 7.0E+00
Cd SWA-L07-1313-T02-B 1 1.10E+OOU1/2 1.10E+00 5.6E+02 2.2E+00 7.0E+00
Cd SWA-L07-1313-T03-B 1 1.10E+OOU1/2 1.10E+00 8.6E+01 2.2E+00 7.0E+00 10 100
Cd SWA-L07-1313-T04-B 1 1.10E+OOU1/2 1.10E+00 6.2E+01 2.2E+00 7.0E+00
Cd SWA-L07-1313-T05-B 1 1.10E+OOU1/2 1.10E+00 8.0E+01 2.2E+00 7.0E+00
Cd SWA-L07-1313-T06-B 1 1.10E+OOU1/2 1.10E+00 8.9E+01 2.2E+00 7.0E+00
Cd SWA-L07-1313-T07-B 1 1.27E+01
Cd SWA-L07-1313-T08-B 1 1.62E+01
Cd SWA-L07-1313-T09-B 1 3.37E+01
1.27E+01 1.7E+00 2.2E+00 7.0E+00
1.62E+01 1.4E+00 2.2E+00 7.0E+00
3.37E+01 7.7E-01 2.2E+00 7.0E+00
Cd SWA-L07-1313-T01-C 1 1.10E+OOU1/2 1.10E+00 1.5E+03 2.2E+00 7.0E+00
Cd SWA-L07-1313-T02-C 1 1.10E+OOU1/2 1.10E+00 1.1E+02 2.2E+00 7.0E+00
Cd SWA-L07-1313-T03-C 1 1.10E+OOU1/2 1.10E+00 1.9E+01 2.2E+00 7.0E+00 10 100
Cd SWA-L07-1313-T04-C 1 1.10E+OOU1/2 1.10E+00 1.5E+02 2.2E+00 7.0E+00
Cd SWA-L07-1313-T05-C 1 1.10E+OOU1/2 1.10E+00 6.9E+01 2.2E+00 7.0E+00
Cd SWA-L07-1313-T06-C 1 1.10E+OOU1/2 1.10E+00 3.1E+01 2.2E+00 7.0E+00
Cd SWA-L07-1313-T07-C 1 7.01E+00
Cd SWA-L07-1313-T08-C 1 1 .40E+01
Cd SWA-L07-1313-T09-C 1 3.19E+01
7.01E+00 1.1E+01 2.2E+00 7.0E+00
1.40E+01 2.3E+00 2.2E+00 7.0E+00
3.19E+01 1.0E+00 2.2E+00 7.0E+00
Cd SWA-L07-1313-B01-A 1 1.10E+OOU1/2 1.10E+00 1.4E+02 2.2E+00 7.0E+00
Cd SWA-L07-1313-B02-A 1 1.10E+OOU1/2 1.10E+00 2.6E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
9.42E+02 94% VU ICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.01E+03 101% VU ICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:59AMEPAInterlabL071313-1316SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
8.86E+02 88% VU ICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:30AMEPAInterlabL07 1313-1316 SWA
VUICP-OES 11/3/10 11:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-503
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qu
Ca SWA-L07-1313-T01-A 1 1.43E+04
Ca SWA-L07-1313-T02-A 1 2.18E+05
Ca SWA-L07-1313-T03-A 1 3.35E+06
Ca SWA-L07-1313-T04-A 1 5.58E+06
Ca SWA-L07-1313-T05-A 1 6.86E+06
Ca SWA-L07-1313-T06-A 1 7.89E+06
Ca SWA-L07-1313-T07-A 1 8.63E+06
Ca SWA-L07-1313-T08-A 1 3.87E+06
Ca SWA-L07-1313-T09-A 1 1.41E+07
Ca SWA-L07-1313-T01-B 1 1.49E+04
Ca SWA-L07-1313-T02-B 1 2.32E+05
Ca SWA-L07-1313-T03-B 1 2.91E+06
Ca SWA-L07-1313-T04-B 1 5.52E+06
Ca SWA-L07-1313-T05-B 1 6.52E+06
Ca SWA-L07-1313-T06-B 1 7.90E+06
Ca SWA-L07-1313-T07-B 1 7.41 E+06
Ca SWA-L07-1313-T08-B 1 3.68E+06
Ca SWA-L07-1313-T09-B 1 2.83E+06
Ca SWA-L07-1313-T01-C 1 1.82E+04
Ca SWA-L07-1313-T02-C 1 2.26E+05
Ca SWA-L07-1313-T03-C 1 3.08E+06
Ca SWA-L07-1313-T04-C 1 5.99E+06
Ca SWA-L07-1313-T05-C 1 6.62E+06
Ca SWA-L07-1313-T06-C 1 7.78E+06
Ca SWA-L07-1313-T07-C 1 8.95E+06
Ca SWA-L07-1313-T08-C 1 4.73E+06
Ca SWA-L07-1313-T09-C 1 2.96E+06
Ca SWA-L07-1313-B01-A 1 4.36E+01
Ca SWA-L07-1313-B02-A 1 8.26E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.43E+04 7.4E-01 2.6E+00 8.3E+00
2.18E+05 9.3E-01 2.6E+00 8.3E+00
3.35E+06 4.5E-01 2.6E+00 8.3E+00 1000 100
5.58E+06 8.3E-01 2.6E+00 8.3E+00
6.86E+06 6.0E-01 2.6E+00 8.3E+00
7.89E+06 9.7E-01 2.6E+00 8.3E+00
8.63E+06 1.3E-01 2.6E+00 8.3E+00
3.87E+06 5.2E-01 2.6E+00 8.3E+00
1.41E+07 9.2E-01 2.6E+00 8.3E+00
1.49E+04 2.0E-01 2.6E+00 8.3E+00
2.32E+05 7.0E-01 2.6E+00 8.3E+00
2.91E+06 1.1E+00 2.6E+00 8.3E+00 1000 100
5.52E+06 1.5E-01 2.6E+00 8.3E+00
6.52E+06 6.2E-01 2.6E+00 8.3E+00
7.90E+06 1.1E+00 2.6E+00 8.3E+00
7.41 E+06 2.8E-01 2.6E+00 8.3E+00
3.68E+06 9.2E-01 2.6E+00 8.3E+00
2.83E+06 3.9E-01 2.6E+00 8.3E+00
1.82E+04 6.0E-01 2.6E+00 8.3E+00
2.26E+05 5.1E-01 2.6E+00 8.3E+00
3.08E+06 2.8E+00 2.6E+00 8.3E+00 1000 100
5.99E+06 6.5E-01 2.6E+00 8.3E+00
6.62E+06 1.5E+00 2.6E+00 8.3E+00
7.78E+06 2.9E+00 2.6E+00 8.3E+00
8.95E+06 1.3E-01 2.6E+00 8.3E+00
4.73E+06 9.2E-01 2.6E+00 8.3E+00
2.96E+06 1.2E+00 2.6E+00 8.3E+00
4.36E+01 2.8E+01 2.6E+00 8.3E+00
8.26E+02 4.5E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
3.35E+06 84% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
2.91E+06 86% VUICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
3.08E+06 84% VU ICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-504
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr SWA-L07-1313-T01-A 1
Cr SWA-L07-1313-T02-A 1
Cr SWA-L07-1313-T03-A 1
Cr SWA-L07-1313-T04-A 1
Cr SWA-L07-1313-T05-A 1
Cr SWA-L07-1313-T06-A 1
Cr SWA-L07-1313-T07-A 1
Cr SWA-L07-1313-T08-A 1
Cr SWA-L07-1313-T09-A 1
Cr SWA-L07-1313-T01-B 1
Cr SWA-L07-1313-T02-B 1
Cr SWA-L07-1313-T03-B 1
Cr SWA-L07-1313-T04-B 1
Cr SWA-L07-1313-T05-B 1
Cr SWA-L07-1313-T06-B 1
Cr SWA-L07-1313-T07-B 1
Cr SWA-L07-1313-T08-B 1
Cr SWA-L07-1313-T09-B 1
Cr SWA-L07-1313-T01-C 1
Cr SWA-L07-1313-T02-C 1
Cr SWA-L07-1313-T03-C 1
Cr SWA-L07-1313-T04-C 1
Cr SWA-L07-1313-T05-C 1
Cr SWA-L07-1313-T06-C 1
Cr SWA-L07-1313-T07-C 1
Cr SWA-L07-1313-T08-C 1
Cr SWA-L07-1313-T09-C 1
Cr SWA-L07-1313-B01-A 1
Cr SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
1.10E+03
1.38E+01
7.92E+00
1.37E+01
1.86E+01
1.56E+00 E
1.16E+01
2.47E+03
7.55E+04
1.08E+03
1.52E+01
9.89E+00
8.93E+00
1.18E+01
6.00E-01 U1/2
7.72E+01
3.65E+03
1.98E+04
1.16E+03
1.60E+01
6.44E+00
7.32E+00
6.66E+00
1.86E+00 E
7.35E+00
1.28E+03
1.84E+04
6.00E-01 U1/2
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+03 2.9E-01 1.2E+00 3.8E+00
1.38E+01 1.0E+00 1.2E+00 3.8E+00
7.92E+00 2.9E+00 1.2E+00 3.8E+00 10 100
1.37E+01 1.1E+01 1.2E+00 3.8E+00
1.86E+01 6.3E+00 1.2E+00 3.8E+00
1.56E+00 6.5E+01 1.2E+00 3.8E+00
1.16E+01 7.4E+00 1.2E+00 3.8E+00
2.47E+03 5.0E-01 1.2E+00 3.8E+00
7.55E+04 7.2E-01 1.2E+00 3.8E+00
1.08E+03 1.4E+00 1.2E+00 3.8E+00
1.52E+01 4.9E+00 1.2E+00 3.8E+00
9.89E+00 1.7E+00 1.2E+00 3.8E+00 10 100
8.93E+00 1.2E+01 1.2E+00 3.8E+00
1.18E+01 1.1E+01 1.2E+00 3.8E+00
6.00E-01 3.6E+01 1.2E+00 3.8E+00
7.72E+01 1.7E-01 1.2E+00 3.8E+00
3.65E+03 5.7E-01 1.2E+00 3.8E+00
1.98E+04 1.7E-01 1.2E+00 3.8E+00
1.16E+03 3.9E-01 1.2E+00 3.8E+00
1.60E+01 7.9E-01 1.2E+00 3.8E+00
6.44E+00 6.3E+01 1.2E+00 3.8E+00 10 100
7.32E+00 2.2E+01 1.2E+00 3.8E+00
6.66E+00 3.1E+00 1.2E+00 3.8E+00
1.86E+00 7.1E+00 1.2E+00 3.8E+00
7.35E+00 7.5E+00 1.2E+00 3.8E+00
1.28E+03 8.2E-01 1.2E+00 3.8E+00
1.84E+04 8.4E-01 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
6.00E-01 3.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
9.66E+02 96% VUICP-OES 1 1/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.04E+03 103% VU ICP-OES 11/3/10 1 1:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:11 PM EPA Interlab L07 1313-1316 SWA
9.34E+02 93% VU ICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 4PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 6PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 7PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 9PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:22PMEPAInterlabL07 1313-1316 SWA
VUICP-OES 11/3/10 11:30AMEPAInterlabL07 1313-1316 SWA
VUICP-OES 11/3/10 11:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-505
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. (
1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Co SWA-L07-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 1.4E+02 1.8E+00 5.7E+00
Co SWA-L07-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 6.6E+01 1.8E+00 5.7E+00
Co SWA-L07-1313-T03-A 1 2.07E+00 E
Co SWA-L07-1313-T04-A 1 3.02E+00 E
Co SWA-L07-1313-T05-A 1 2.14E+01
Co SWA-L07-1313-T06-A 1 4.59E+01
Co SWA-L07-1313-T07-A 1 2.24E+02
Co SWA-L07-1313-T08-A 1 1.58E+02
Co SWA-L07-1313-T09-A 1 8.90E+02
2.07E+00 3.0E+01 1.8E+00 5.7E+00 10 100
3.02E+00 4.5E+01 1.8E+00 5.7E+00
2.14E+01 2.1E+00 1.8E+00 5.7E+00
4.59E+01 5.8E+00 1.8E+00 5.7E+00
2.24E+02 5.9E-01 1.8E+00 5.7E+00
1.58E+02 2.1E+00 1.8E+00 5.7E+00
8.90E+02 6.0E-01 1.8E+00 5.7E+00
Co SWA-L07-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 6.5E+01 1.8E+00 5.7E+00
Co SWA-L07-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 1.2E+02 1.8E+00 5.7E+00
Co SWA-L07-1313-T03-B 1 2.71E+00 E
Co SWA-L07-1313-T04-B 1 4.18E+00 E
Co SWA-L07-1313-T05-B 1 1.51E+01
Co SWA-L07-1313-T06-B 1 8.99E+01
Co SWA-L07-1313-T07-B 1 2.15E+02
Co SWA-L07-1313-T08-B 1 1.55E+02
Co SWA-L07-1313-T09-B 1 2.14E+02
2.71E+00 4.8E+01 1.8E+00 5.7E+00 10 100
4.18E+00 1.1E+00 1.8E+00 5.7E+00
1.51E+01 6.0E+00 1.8E+00 5.7E+00
8.99E+01 1.7E+00 1.8E+00 5.7E+00
2.15E+02 7.1E-02 1.8E+00 5.7E+00
1.55E+02 7.7E-01 1.8E+00 5.7E+00
2.14E+02 9.3E-02 1.8E+00 5.7E+00
Co SWA-L07-1313-T01-C 1 9.00E-01 U1/2 9.00E-01 2.5E+02 1.8E+00 5.7E+00
Co SWA-L07-1313-T02-C 1 9.00E-01 U1/2 9.00E-01 7.8E+01 1.8E+00 5.7E+00
Co SWA-L07-1313-T03-C 1 2.20E+00 E
Co SWA-L07-1313-T04-C 1 5.82E+00
Co SWA-L07-1313-T05-C 1 1.74E+01
Co SWA-L07-1313-T06-C 1 5.27E+01
Co SWA-L07-1313-T07-C 1 2.05E+02
Co SWA-L07-1313-T08-C 1 1.78E+02
Co SWA-L07-1313-T09-C 1 2.02E+02
2.20E+00 4.1E+00 1.8E+00 5.7E+00 10 100
5.82E+00 1.1E+01 1.8E+00 5.7E+00
1.74E+01 2.9E+01 1.8E+00 5.7E+00
5.27E+01 3.4E+01 1.8E+00 5.7E+00
2.05E+02 2.2E-01 1.8E+00 5.7E+00
1.78E+02 1.2E+00 1.8E+00 5.7E+00
2.02E+02 6.6E-01 1.8E+00 5.7E+00
Co SWA-L07-1313-B01-A 1 9.00E-01 U1/2 9.00E-01 4.4E+01 1.8E+00 5.7E+00
Co SWA-L07-1313-B02-A 1 9.00E-01 U1/2 9.00E-01 1.5E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
9.27E+02 93% VU ICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.01E+03 100% VU ICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
9.18E+02 92% VU ICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-506
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cu SWA-L07-1313-T01-A 1 1.85E+OOU1/2 1.85E+00 1.4E+02 3.7E+00 1.2E+01
Cu SWA-L07-1313-T02-A 1 5.16E+00 E
Cu SWA-L07-1313-T03-A 1 8.00E+00 E
Cu SWA-L07-1313-T04-A 1 1.17E+01 E
Cu SWA-L07-1313-T05-A 1 1.21E+01
Cu SWA-L07-1313-T06-A 1 1.26E+01
Cu SWA-L07-1313-T07-A 1 2.25E+01
Cu SWA-L07-1313-T08-A 1 2.45E+01
Cu SWA-L07-1313-T09-A 1 3.82E+03
5.16E+00 5.6E+01 3.7E+00 1.2E+01
8.00E+00 6.9E+00 3.7E+00 1.2E+01 10 100
1.17E+01 9.8E+00 3.7E+00 1.2E+01
1.21E+01 3.2E+01 3.7E+00 1.2E+01
1.26E+01 1.5E+01 3.7E+00 1.2E+01
2.25E+01 1.2E+01 3.7E+00 1.2E+01
2.45E+01 2.8E+00 3.7E+00 1.2E+01
3.82E+03 9.5E-01 3.7E+00 1.2E+01
Cu SWA-L07-1313-T01-B 1 1.85E+OOU1/2 1.85E+00 3.4E+01 3.7E+00 1.2E+01
Cu SWA-L07-1313-T02-B 1 4.81E+00 E
Cu SWA-L07-1313-T03-B 1 9.01E+00 E
Cu SWA-L07-1313-T04-B 1 1.39E+01
Cu SWA-L07-1313-T05-B 1 1.09E+01 E
Cu SWA-L07-1313-T06-B 1 1.65E+01
Cu SWA-L07-1313-T07-B 1 2.30E+01
Cu SWA-L07-1313-T08-B 1 5.29E+01
Cu SWA-L07-1313-T09-B 1 1.43E+03
4.81E+00 2.1E+01 3.7E+00 1.2E+01
9.01E+00 4.1E+01 3.7E+00 1.2E+01 10 100
1.39E+01 2.5E+01 3.7E+00 1.2E+01
1.09E+01 5.7E+00 3.7E+00 1.2E+01
1.65E+01 3.1E+01 3.7E+00 1.2E+01
2.30E+01 1.3E+01 3.7E+00 1.2E+01
5.29E+01 1.4E+00 3.7E+00 1.2E+01
1.43E+03 1.2E+00 3.7E+00 1.2E+01
Cu SWA-L07-1313-T01-C 1 1.85E+OOU1/2 1.85E+00 5.9E+01 3.7E+00 1.2E+01
Cu SWA-L07-1313-T02-C 1 5.29E+00 E
Cu SWA-L07-1313-T03-C 1 1.29E+01
Cu SWA-L07-1313-T04-C 1 1.34E+01
Cu SWA-L07-1313-T05-C 1 1.20E+01
Cu SWA-L07-1313-T06-C 1 8.50E+00 E
Cu SWA-L07-1313-T07-C 1 2.69E+01
Cu SWA-L07-1313-T08-C 1 1.60E+01
Cu SWA-L07-1313-T09-C 1 1.39E+03
5.29E+00 3.2E+01 3.7E+00 1.2E+01
1.29E+01 1.8E+01 3.7E+00 1.2E+01 10 100
1.34E+01 1.4E+01 3.7E+00 1.2E+01
1.20E+01 2.9E+01 3.7E+00 1.2E+01
8.50E+00 1.3E+01 3.7E+00 1.2E+01
2.69E+01 1.0E+01 3.7E+00 1.2E+01
1.60E+01 1.1E+01 3.7E+00 1.2E+01
1.39E+03 1.5E+00 3.7E+00 1.2E+01
Cu SWA-L07-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 5.3E+01 3.7E+00 1.2E+01
Cu SWA-L07-1313-B02-A 1 1.85E+OOU1/2 1.85E+00 5.2E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.01E+03 100% VU ICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.07E+03 106% VU ICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
1.04E+03 102% VU ICP-OES 11/3/1012:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 131 3-1 31 6 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-507
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe SWA-L07-1313-T01-A 1
Fe SWA-L07-1313-T02-A 1
Fe SWA-L07-1313-T03-A 1
Fe SWA-L07-1313-T04-A 1
Fe SWA-L07-1313-T05-A 1
Fe SWA-L07-1313-T06-A 1
Fe SWA-L07-1313-T07-A 1
Fe SWA-L07-1313-T08-A 1
Fe SWA-L07-1313-T09-A 1
Fe SWA-L07-1313-T01-B 1
Fe SWA-L07-1313-T02-B 1
Fe SWA-L07-1313-T03-B 1
Fe SWA-L07-1313-T04-B 1
Fe SWA-L07-1313-T05-B 1
Fe SWA-L07-1313-T06-B 1
Fe SWA-L07-1313-T07-B 1
Fe SWA-L07-1313-T08-B 1
Fe SWA-L07-1313-T09-B 1
Fe SWA-L07-1313-T01-C 1
Fe SWA-L07-1313-T02-C 1
Fe SWA-L07-1313-T03-C 1
Fe SWA-L07-1313-T04-C 1
Fe SWA-L07-1313-T05-C 1
Fe SWA-L07-1313-T06-C 1
Fe SWA-L07-1313-T07-C 1
Fe SWA-L07-1313-T08-C 1
Fe SWA-L07-1313-T09-C 1
Fe SWA-L07-1313-B01-A 1
Fe SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
8.38E+01
3.45E+01
1.27E+01
1.77E+01
1.48E+01
1.78E+01
8.83E+04
9.95E+04
9.70E+05
7.86E+01
3.51E+01
1.31E+01
1.89E+01
1.38E+01
2.17E+01
1.19E+05
1.06E+05
1.41E+05
2.03E+02
3.64E+01
1.51E+01
1.83E+01
1.60E+01
1.89E+01
6.75E+04
1.11E+05
1.37E+05
2.58E+00 E
1.14E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.38E+01 1.1E+00 2.0E+00 6.4E+00
3.45E+01 1.0E+00 2.0E+00 6.4E+00
1.27E+01 3.5E+00 2.0E+00 6.4E+00 1000 100
1.77E+01 1.6E+00 2.0E+00 6.4E+00
1.48E+01 8.3E+00 2.0E+00 6.4E+00
1.78E+01 3.9E+00 2.0E+00 6.4E+00
8.83E+04 7.5E-01 2.0E+00 6.4E+00
9.95E+04 1.7E+00 2.0E+00 6.4E+00
9.70E+05 7.0E-01 2.0E+00 6.4E+00
7.86E+01 1.5E-01 2.0E+00 6.4E+00
3.51 E+01 1.0E+00 2.0E+00 6.4E+00
1.31E+01 8.8E+00 2.0E+00 6.4E+00 1000 100
1.89E+01 1.3E+00 2.0E+00 6.4E+00
1.38E+01 3.1E+00 2.0E+00 6.4E+00
2.17E+01 8.3E-01 2.0E+00 6.4E+00
1.19E+05 8.0E-01 2.0E+00 6.4E+00
1.06E+05 3.5E-01 2.0E+00 6.4E+00
1.41E+05 5.5E-01 2.0E+00 6.4E+00
2.03E+02 6.7E-01 2.0E+00 6.4E+00
3.64E+01 8.5E-01 2.0E+00 6.4E+00
1.51E+01 2.9E+00 2.0E+00 6.4E+00 1000 100
1.83E+01 2.2E+00 2.0E+00 6.4E+00
1.60E+01 3.6E+00 2.0E+00 6.4E+00
1.89E+01 4.6E+00 2.0E+00 6.4E+00
6.75E+04 4.3E-02 2.0E+00 6.4E+00
1.11E+05 7.4E-01 2.0E+00 6.4E+00
1.37E+05 2.2E+00 2.0E+00 6.4E+00
2.58E+00 6.1E+00 2.0E+00 6.4E+00
1.14E+01 2.8E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
9.95E+02 98% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.08E+03 106% VU ICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
9.64E+02 95% VUICP-OES 1 1/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-508
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb SWA-L07-1313-T01-A 1
Pb SWA-L07-1313-T02-A 1
Pb SWA-L07-1313-T03-A 1
Pb SWA-L07-1313-T04-A 1
Pb SWA-L07-1313-T05-A 1
Pb SWA-L07-1313-T06-A 1
Pb SWA-L07-1313-T07-A 1
Pb SWA-L07-1313-T08-A 1
Pb SWA-L07-1313-T09-A 1
Pb SWA-L07-1313-T01-B 1
Pb SWA-L07-1313-T02-B 1
Pb SWA-L07-1313-T03-B 1
Pb SWA-L07-1313-T04-B 1
Pb SWA-L07-1313-T05-B 1
Pb SWA-L07-1313-T06-B 1
Pb SWA-L07-1313-T07-B 1
Pb SWA-L07-1313-T08-B 1
Pb SWA-L07-1313-T09-B 1
Pb SWA-L07-1313-T01-C 1
Pb SWA-L07-1313-T02-C 1
Pb SWA-L07-1313-T03-C 1
Pb SWA-L07-1313-T04-C 1
Pb SWA-L07-1313-T05-C 1
Pb SWA-L07-1313-T06-C 1
Pb SWA-L07-1313-T07-C 1
Pb SWA-L07-1313-T08-C 1
Pb SWA-L07-1313-T09-C 1
Pb SWA-L07-1313-B01-A 1
Pb SWA-L07-1313-B02-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.33E+01 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
9.32E+01
1.36E+04
1.35E+01 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
2.23E+02
3.68E+03
2.17E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
2.99E+01
3.39E+03
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+01 1.4E+01 6.8E+00 2.2E+01
3.40E+00 1.6E+02 6.8E+00 2.2E+01
3.40E+00 6.0E+02 6.8E+00 2.2E+01 10 100
3.40E+00 3.1E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 1.0E+02 6.8E+00 2.2E+01
3.40E+00 4.4E+02 6.8E+00 2.2E+01
9.32E+01 1.1E+01 6.8E+00 2.2E+01
1.36E+04 5.4E-01 6.8E+00 2.2E+01
1.35E+01 3.6E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
3.40E+00 2.3E+03 6.8E+00 2.2E+01 10 100
3.40E+00 1.2E+02 6.8E+00 2.2E+01
3.40E+00 7.3E+01 6.8E+00 2.2E+01
3.40E+00 6.3E+01 6.8E+00 2.2E+01
3.40E+00 2.6E+02 6.8E+00 2.2E+01
2.23E+02 3.3E+00 6.8E+00 2.2E+01
3.68E+03 4.3E-01 6.8E+00 2.2E+01
2.17E+01 1.5E+01 6.8E+00 2.2E+01
3.40E+00 1.9E+02 6.8E+00 2.2E+01
3.40E+00 1.2E+01 6.8E+00 2.2E+01 10 100
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 2.0E+01 6.8E+00 2.2E+01
3.40E+00 9.9E+01 6.8E+00 2.2E+01
3.40E+00 2.4E+02 6.8E+00 2.2E+01
2.99E+01 2.2E+01 6.8E+00 2.2E+01
3.39E+03 9.4E-01 6.8E+00 2.2E+01
3.40E+00 4.1E+01 6.8E+00 2.2E+01
3.40E+00 2.5E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
9.17E+02 91% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
9.91E+02 99% VUICP-OES 1 1/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
8.69E+02 87% VUICP-OES 1 1/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 131 3-1 31 6 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-509
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
1 1 ug/L
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Li SWA-L07-1313-T01-A 1 2.14E+00 E 2.14E+00 6.3E+01 1.9E+00 6.0E+00
Li SWA-L07-1313-T02-A 1 2.14E+01
Li SWA-L07-1313-T03-A 1 2.71E+02
Li SWA-L07-1313-T04-A 1 6.50E+02
Li SWA-L07-1313-T05-A 1 8.18E+02
Li SWA-L07-1313-T06-A 1 9.72E+02
Li SWA-L07-1313-T07-A 1 1.24E+03
Li SWA-L07-1313-T08-A 1 6.50E+02
Li SWA-L07-1313-T09-A 1 1.05E+03
2.14E+01 1.1E+01 1.9E+00 6.0E+00
2.71E+02 4.5E+00 1.9E+00 6.0E+00 10 100
6.50E+02 9.4E-01 1.9E+00 6.0E+00
8.18E+02 3.5E+00 1.9E+00 6.0E+00
9.72E+02 3.4E+00 1.9E+00 6.0E+00
1.24E+03 3.2E+00 1.9E+00 6.0E+00
6.50E+02 2.1E+00 1.9E+00 6.0E+00
1.05E+03 1.1E+01 1.9E+00 6.0E+00
Li SWA-L07-1313-T01-B 1 2.52E+00 E 2.52E+00 1.1E+01 1.9E+00 6.0E+00
Li SWA-L07-1313-T02-B 1 2.23E+01
Li SWA-L07-1313-T03-B 1 2.15E+02
Li SWA-L07-1313-T04-B 1 6.40E+02
Li SWA-L07-1313-T05-B 1 7.49E+02
Li SWA-L07-1313-T06-B 1 1.03E+03
Li SWA-L07-1313-T07-B 1 1.12E+03
Li SWA-L07-1313-T08-B 1 6.38E+02
Li SWA-L07-1313-T09-B 1 6.61E+02
2.23E+01 7.7E+00 1.9E+00 6.0E+00
2.15E+02 5.0E+00 1.9E+00 6.0E+00 10 100
6.40E+02 1.6E+00 1.9E+00 6.0E+00
7.49E+02 2.1E+00 1.9E+00 6.0E+00
1.03E+03 2.0E+00 1.9E+00 6.0E+00
1.12E+03 5.5E+00 1.9E+00 6.0E+00
6.38E+02 4.4E+00 1 .9E+00 6.0E+00
6.61 E+02 1.1E+00 1.9E+00 6.0E+00
Li SWA-L07-1313-T01-C 1 9.50E-01 U1/2 9.50E-01 9.7E+01 1 .9E+00 6.0E+00
Li SWA-L07-1313-T02-C 1 2.52E+01
Li SWA-L07-1313-T03-C 1 2.18E+02
Li SWA-L07-1313-T04-C 1 7.05E+02
Li SWA-L07-1313-T05-C 1 7.51E+02
Li SWA-L07-1313-T06-C 1 9.99E+02
Li SWA-L07-1313-T07-C 1 1.31E+03
Li SWA-L07-1313-T08-C 1 7.82E+02
Li SWA-L07-1313-T09-C 1 6.33E+02
2.52E+01 9.0E+00 1 .9E+00 6.0E+00
2.18E+02 4.7E+00 1 .9E+00 6.0E+00 10 100
7.05E+02 1.8E+00 1 .9E+00 6.0E+00
7.51 E+02 7.3E+00 1 .9E+00 6.0E+00
9.99E+02 9.0E+00 1 .9E+00 6.0E+00
1.31E+03 1.7E+00 1.9E+00 6.0E+00
7.82E+02 6.9E+00 1 .9E+00 6.0E+00
6.33E+02 1.1E+00 1 .9E+00 6.0E+00
Li SWA-L07-1313-B01-A 1 9.50E-01 U1/2 9.50E-01 1.1E+02 1 .9E+00 6.0E+00
Li SWA-L07-1313-B02-A 1 9.50E-01 U1/2 9.50E-01 2.3E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.15E+03 88% VUICP-OES 1 1/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53AM EPA Interlab L07 1313-1316 SWA
1.14E+03 92% VUICP-OES 11/3/10 1 1:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
1.11E+03 89% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:30AMEPAInterlabL07 1313-1316 SWA
VUICP-OES 11/3/10 11:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-510
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn SWA-L07-1313-T01-A 1
Mn SWA-L07-1313-T02-A 1
Mn SWA-L07-1313-T03-A 1
Mn SWA-L07-1313-T04-A 1
Mn SWA-L07-1313-T05-A 1
Mn SWA-L07-1313-T06-A 1
Mn SWA-L07-1313-T07-A 1
Mn SWA-L07-1313-T08-A 1
Mn SWA-L07-1313-T09-A 1
Mn SWA-L07-1313-T01-B 1
Mn SWA-L07-1313-T02-B 1
Mn SWA-L07-1313-T03-B 1
Mn SWA-L07-1313-T04-B 1
Mn SWA-L07-1313-T05-B 1
Mn SWA-L07-1313-T06-B 1
Mn SWA-L07-1313-T07-B 1
Mn SWA-L07-1313-T08-B 1
Mn SWA-L07-1313-T09-B 1
Mn SWA-L07-1313-T01-C 1
Mn SWA-L07-1313-T02-C 1
Mn SWA-L07-1313-T03-C 1
Mn SWA-L07-1313-T04-C 1
Mn SWA-L07-1313-T05-C 1
Mn SWA-L07-1313-T06-C 1
Mn SWA-L07-1313-T07-C 1
Mn SWA-L07-1313-T08-C 1
Mn SWA-L07-1313-T09-C 1
Mn SWA-L07-1313-B01-A 1
Mn SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.61 E+02
6.45E+03
1.13E+04
2.82E+04
1.55E+04
6.23E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.35E+02
4.85E+03
1.59E+04
2.50E+04
1.49E+04
1.57E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
8.08E+02
1.94E+03
1.48E+04
2.71 E+04
1.82E+04
1.57E+04
1.00E+00 U1/2
1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 6.1E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00 10 100
3.61 E+02 3.1E-01 2.0E+00 6.4E+00
6.45E+03 5.3E-01 2.0E+00 6.4E+00
1.13E+04 3.5E-01 2.0E+00 6.4E+00
2.82E+04 2.5E-01 2.0E+00 6.4E+00
1.55E+04 3.3E-01 2.0E+00 6.4E+00
6.23E+04 6.0E-01 2.0E+00 6.4E+00
1.00E+00 2.7E+00 2.0E+00 6.4E+00
1.00E+00 7.8E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00 10 100
6.35E+02 7.8E-01 2.0E+00 6.4E+00
4.85E+03 4.0E-01 2.0E+00 6.4E+00
1.59E+04 1.8E-01 2.0E+00 6.4E+00
2.50E+04 4.3E-01 2.0E+00 6.4E+00
1.49E+04 2.7E-01 2.0E+00 6.4E+00
1.57E+04 2.6E-01 2.0E+00 6.4E+00
1.00E+00 1.2E+00 2.0E+00 6.4E+00
1.00E+00 6.9E+00 2.0E+00 6.4E+00
1.00E+00 2.9E+00 2.0E+00 6.4E+00 10 100
8.08E+02 5.2E-01 2.0E+00 6.4E+00
1.94E+03 8.1E-01 2.0E+00 6.4E+00
1.48E+04 9.5E+00 2.0E+00 6.4E+00
2.71 E+04 7.0E-01 2.0E+00 6.4E+00
1.82E+04 1.5E+00 2.0E+00 6.4E+00
1.57E+04 1.7E+00 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 8.6E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
9.58E+02 96% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.01E+03 101% VUICP-OES 1 1/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
1.16E+03 116% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-511
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qu
1 1 ug/L
Mg SWA-L07-1313-T01-A 1 1.29E+01
Mg SWA-L07-1313-T02-A 1 7.97E+01
Mg SWA-L07-1313-T03-A 1 5.69E+04
Mg SWA-L07-1313-T04-A 1 7.57E+05
Mg SWA-L07-1313-T05-A 1 1.15E+06
Mg SWA-L07-1313-T06-A 1 1.32E+06
Mg SWA-L07-1313-T07-A 1 1.73E+06
Mg SWA-L07-1313-T08-A 1 8.32E+05
Mg SWA-L07-1313-T09-A 1 2.45E+06
Mg SWA-L07-1313-T01-B 1 5.26E+00
Mg SWA-L07-1313-T02-B 1 9.61E+01
Mg SWA-L07-1313-T03-B 1 1.43E+04
Mg SWA-L07-1313-T04-B 1 7.61E+05
Mg SWA-L07-1313-T05-B 1 1.04E+06
Mg SWA-L07-1313-T06-B 1 1.36E+06
Mg SWA-L07-1313-T07-B 1 1.46E+06
Mg SWA-L07-1313-T08-B 1 7.89E+05
Mg SWA-L07-1313-T09-B 1 6.71E+05
Mg SWA-L07-1313-T01-C 1 6.18E+00
Mg SWA-L07-1313-T02-C 1 9.48E+01
Mg SWA-L07-1313-T03-C 1 1.44E+04
Mg SWA-L07-1313-T04-C 1 8.67E+05
Mg SWA-L07-1313-T05-C 1 9.81 E+05
Mg SWA-L07-1313-T06-C 1 1.30E+06
Mg SWA-L07-1313-T07-C 1 1.74E+06
Mg SWA-L07-1313-T08-C 1 1.01E+06
Mg SWA-L07-1313-T09-C 1 6.82E+05
Mg SWA-L07-1313-B01-A 1 5.09E+00
Mg SWA-L07-1313-B02-A 1 1.23E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.29E+01 6.2E+01 1.0E+00 3.2E+00
7.97E+01 2.1E+01 1.0E+00 3.2E+00
5.69E+04 1.9E-01 1.0E+00 3.2E+00 1000 100
7.57E+05 7.0E-01 1.0E+00 3.2E+00
1.15E+06 3.4E-01 1.0E+00 3.2E+00
1.32E+06 3.6E-01 1.0E+00 3.2E+00
1.73E+06 1.4E-01 1.0E+00 3.2E+00
8.32E+05 3.1E-01 1.0E+00 3.2E+00
2.45E+06 1.4E+00 1.0E+00 3.2E+00
5.26E+00 9.9E+01 1.0E+00 3.2E+00
9.61 E+01 8.0E+00 1.0E+00 3.2E+00
1.43E+04 3.5E-01 1.0E+00 3.2E+00 1000 100
7.61 E+05 7.0E-01 1.0E+00 3.2E+00
1.04E+06 5.0E-01 1.0E+00 3.2E+00
1.36E+06 3.7E-01 1.0E+00 3.2E+00
1.46E+06 7.2E-01 1.0E+00 3.2E+00
7.89E+05 7.0E-01 1.0E+00 3.2E+00
6.71 E+05 1.0E-01 1.0E+00 3.2E+00
6.18E+00 9.9E-01 1.0E+00 3.2E+00
9.48E+01 8.5E+00 1.0E+00 3.2E+00
1.44E+04 3.2E+00 1.0E+00 3.2E+00 1000 100
8.67E+05 8.7E-01 1.0E+00 3.2E+00
9.81 E+05 1.1E+00 1.0E+00 3.2E+00
1.30E+06 2.8E+00 1.0E+00 3.2E+00
1.74E+06 3.0E-01 1.0E+00 3.2E+00
1.01E+06 4.1E-01 1.0E+00 3.2E+00
6.82E+05 3.3E-01 1.0E+00 3.2E+00
5.09E+00 8.9E+01 1.0E+00 3.2E+00
1.23E+02 4.7E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
5.79E+04 97% VUICP-OES 1 1/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.53E+04 99% VUICP-OES 11/3/10 1 1:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:11 PM EPA Interlab L07 1313-1316 SWA
1.53E+04 87% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 4PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 6PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 7PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-512
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo SWA-L07-1313-T01-A 1
Mo SWA-L07-1313-T02-A 1
Mo SWA-L07-1313-T03-A 1
Mo SWA-L07-1313-T04-A 1
Mo SWA-L07-1313-T05-A 1
Mo SWA-L07-1313-T06-A 1
Mo SWA-L07-1313-T07-A 1
Mo SWA-L07-1313-T08-A 1
Mo SWA-L07-1313-T09-A 1
Mo SWA-L07-1313-T01-B 1
Mo SWA-L07-1313-T02-B 1
Mo SWA-L07-1313-T03-B 1
Mo SWA-L07-1313-T04-B 1
Mo SWA-L07-1313-T05-B 1
Mo SWA-L07-1313-T06-B 1
Mo SWA-L07-1313-T07-B 1
Mo SWA-L07-1313-T08-B 1
Mo SWA-L07-1313-T09-B 1
Mo SWA-L07-1313-T01-C 1
Mo SWA-L07-1313-T02-C 1
Mo SWA-L07-1313-T03-C 1
Mo SWA-L07-1313-T04-C 1
Mo SWA-L07-1313-T05-C 1
Mo SWA-L07-1313-T06-C 1
Mo SWA-L07-1313-T07-C 1
Mo SWA-L07-1313-T08-C 1
Mo SWA-L07-1313-T09-C 1
Mo SWA-L07-1313-B01-A 1
Mo SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
9.69E+01
1.52E+02
1.39E+02
1.32E+02
1.04E+02
7.52E+01
1.30E+01
1.74E+01
1.85E+02
1.07E+02
1.47E+02
1.40E+02
1.26E+02
1.16E+02
4.23E+01
9.28E+00
1.38E+01
1.37E+01
1.09E+02
1.59E+02
1.32E+02
1.38E+02
1.31E+02
4.22E+01
1.53E+01
2.15E+01
8.96E+00
6.00E-01 U1/2
2.31 E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.69E+01 9.4E-01 1.2E+00 3.8E+00
1.52E+02 1.1 E+00 1.2E+00 3.8E+00
1.39E+02 7.1E-01 1.2E+00 3.8E+00 10 100
1.32E+02 2.7E+00 1.2E+00 3.8E+00
1.04E+02 9.5E-01 1.2E+00 3.8E+00
7.52E+01 1.2E+00 1.2E+00 3.8E+00
1.30E+01 2.5E+01 1.2E+00 3.8E+00
1.74E+01 9.2E+00 1.2E+00 3.8E+00
1.85E+02 1.1E+01 1.2E+00 3.8E+00
1.07E+02 7.3E-01 1.2E+00 3.8E+00
1.47E+02 3.2E-01 1.2E+00 3.8E+00
1.40E+02 1.9E+00 1.2E+00 3.8E+00 10 100
1.26E+02 8.3E-01 1.2E+00 3.8E+00
1.16E+02 1.6E+00 1.2E+00 3.8E+00
4.23E+01 4.7E-01 1.2E+00 3.8E+00
9.28E+00 3.2E+01 1.2E+00 3.8E+00
1.38E+01 5.0E+00 1.2E+00 3.8E+00
1.37E+01 2.1E+01 1.2E+00 3.8E+00
1.09E+02 1.3E+00 1.2E+00 3.8E+00
1.59E+02 1.1 E+00 1.2E+00 3.8E+00
1.32E+02 6.7E+00 1.2E+00 3.8E+00 10 100
1.38E+02 9.7E-01 1.2E+00 3.8E+00
1.31E+02 2.0E+00 1.2E+00 3.8E+00
4.22E+01 1.8E+00 1.2E+00 3.8E+00
1.53E+01 1.7E+01 1.2E+00 3.8E+00
2.15E+01 6.8E+00 1.2E+00 3.8E+00
8.96E+00 1.5E+01 1.2E+00 3.8E+00
6.00E-01 1.8E+02 1.2E+00 3.8E+00
2.31 E+00 6.5E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.14E+03 100% VU ICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.21E+03 107% VU ICP-OES 11/3/10 1 1:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:11 PM EPA Interlab L07 1313-1316 SWA
1.06E+03 92% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 4PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 6PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 7PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-513
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L07-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 2.7E+02 1.8E+00 5.7E+00
Ni SWA-L07-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 2.6E+02 1.8E+00 5.7E+00
Ni SWA-L07-1313-T03-A 1 4.91 E+00 E
Ni SWA-L07-1313-T04-A 1 1.10E+01
Ni SWA-L07-1313-T05-A 1 6.46E+01
Ni SWA-L07-1313-T06-A 1 1.38E+02
Ni SWA-L07-1313-T07-A 1 5.34E+02
Ni SWA-L07-1313-T08-A 1 3.40E+02
Ni SWA-L07-1313-T09-A 1 1.28E+03
4.91E+00 5.7E+01 1.8E+00 5.7E+00 10 100
1.10E+01 2.4E+01 1.8E+00 5.7E+00
6.46E+01 2.6E+00 1.8E+00 5.7E+00
1.38E+02 1.4E+00 1.8E+00 5.7E+00
5.34E+02 3.0E-01 1.8E+00 5.7E+00
3.40E+02 3.0E-01 1.8E+00 5.7E+00
1.28E+03 5.9E-01 1.8E+00 5.7E+00
Ni SWA-L07-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 2.3E+02 1.8E+00 5.7E+00
Ni SWA-L07-1313-T02-B 1 2.21E+00 E
Ni SWA-L07-1313-T03-B 1 3.80E+00 E
Ni SWA-L07-1313-T04-B 1 1.03E+01
Ni SWA-L07-1313-T05-B 1 4.24E+01
Ni SWA-L07-1313-T06-B 1 2.62E+02
Ni SWA-L07-1313-T07-B 1 4.91 E+02
Ni SWA-L07-1313-T08-B 1 3.20E+02
Ni SWA-L07-1313-T09-B 1 3.55E+02
2.21 E+00 4.6E+01 1.8E+00 5.7E+00
3.80E+00 5.6E+01 1.8E+00 5.7E+00 10 100
1.03E+01 1.1E+01 1.8E+00 5.7E+00
4.24E+01 7.6E+00 1.8E+00 5.7E+00
2.62E+02 4.1E-01 1.8E+00 5.7E+00
4.91 E+02 2.1E-01 1.8E+00 5.7E+00
3.20E+02 3.2E-01 1.8E+00 5.7E+00
3.55E+02 9.2E-01 1.8E+00 5.7E+00
Ni SWA-L07-1313-T01-C 9.00E-01 U1/2 O.OOE+00 6.5E+02 1.8E+00 5.7E+00
Ni SWA-L07-1313-T02-C 9.00E-01 U1/2 O.OOE+00 3.0E+02 1.8E+00 5.7E+00
Ni SWA-L07-1313-T03-C 5.50E+00 U1/2 O.OOE+00 1.6E+00 1.8E+00 5.7E+00 10 100
Ni SWA-L07-1313-T04-C 1.56E+01 U1/2 O.OOE+00 1.3E+01 1.8E+00 5.7E+00
Ni SWA-L07-1313-T05-C 2.26E+01 U1/2 O.OOE+00 3.0E+01 1.8E+00 5.7E+00
Ni SWA-L07-1313-T06-C 2.83E+02 U1/2 O.OOE+00 2.5E+01 1.8E+00 5.7E+00
Ni SWA-L07-1313-T07-C 4.84E+02 U1/2 O.OOE+00 6.3E-01 1.8E+00 5.7E+00
Ni SWA-L07-1313-T08-C 3.82E+02 U1/2 O.OOE+00 7.8E-01 1.8E+00 5.7E+00
Ni SWA-L07-1313-T09-C 3.52E+02 U1/2 O.OOE+00 6.6E-01 1.8E+00 5.7E+00
Ni SWA-L07-1313-B01-A 9.00E-01 U1/2 O.OOE+00 2.9E+02 1.8E+00 5.7E+00
Ni SWA-L07-1313-B02-A 9.00E-01 U1/2 O.OOE+00 1.1E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
9.21E+02 92% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
9.87E+02 98% VU ICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
1.00E+03 100% VU ICP-OES 11/3/1012:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-514
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P SWA-L07-1313-T01-A 1
P SWA-L07-1313-T02-A 1
P SWA-L07-1313-T03-A 1
P SWA-L07-1313-T04-A 1
P SWA-L07-1313-T05-A 1
P SWA-L07-1313-T06-A 1
P SWA-L07-1313-T07-A 1
P SWA-L07-1313-T08-A 1
P SWA-L07-1313-T09-A 1
P SWA-L07-1313-T01-B 1
P SWA-L07-1313-T02-B 1
P SWA-L07-1313-T03-B 1
P SWA-L07-1313-T04-B 1
P SWA-L07-1313-T05-B 1
P SWA-L07-1313-T06-B 1
P SWA-L07-1313-T07-B 1
P SWA-L07-1313-T08-B 1
P SWA-L07-1313-T09-B 1
P SWA-L07-1313-T01-C 1
P SWA-L07-1313-T02-C 1
P SWA-L07-1313-T03-C 1
P SWA-L07-1313-T04-C 1
P SWA-L07-1313-T05-C 1
P SWA-L07-1313-T06-C 1
P SWA-L07-1313-T07-C 1
P SWA-L07-1313-T08-C 1
P SWA-L07-1313-T09-C 1
P SWA-L07-1313-B01-A 1
P SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
6.69E+01
3.93E+01
3.25E+01
8.99E+01
7.94E+01
7.38E+01
7.80E+01
8.21 E+02
1.20E+05
6.42E+01
4.53E+01
3.24E+01
1.05E+02
9.19E+01
5.87E+01
8.12E+01
7.51 E+02
9.13E+03
7.50E+01
3.82E+01
3.44E+01
1.32E+02
1.29E+02
5.54E+01
7.35E+01
8.79E+02
4.22E+03
1.85E+00 U1/2
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.69E+01 1.4E+01 3.7E+00 1.2E+01
3.93E+01 1.5E+01 3.7E+00 1.2E+01
3.25E+01 8.3E+01 3.7E+00 1.2E+01 1000 100
8.99E+01 1.1E+01 3.7E+00 1.2E+01
7.94E+01 2.2E+01 3.7E+00 1.2E+01
7.38E+01 2.5E+01 3.7E+00 1.2E+01
7.80E+01 2.4E+01 3.7E+00 1.2E+01
8.21 E+02 2.7E-01 3.7E+00 1.2E+01
1.20E+05 2.8E-01 3.7E+00 1.2E+01
6.42E+01 1.8E+01 3.7E+00 1.2E+01
4.53E+01 8.5E+00 3.7E+00 1.2E+01
3.24E+01 3.7E+01 3.7E+00 1.2E+01 1000 100
1.05E+02 9.8E+00 3.7E+00 1.2E+01
9.19E+01 5.4E+01 3.7E+00 1.2E+01
5.87E+01 1.5E+01 3.7E+00 1.2E+01
8.12E+01 2.8E+01 3.7E+00 1.2E+01
7.51 E+02 1.1E+00 3.7E+00 1.2E+01
9.13E+03 3.9E-01 3.7E+00 1.2E+01
7.50E+01 7.2E+00 3.7E+00 1.2E+01
3.82E+01 1.8E+01 3.7E+00 1 .2E+01
3.44E+01 3.3E+01 3.7E+00 1 .2E+01 1000 100
1.32E+02 1.2E+01 3.7E+00 1 .2E+01
1.29E+02 1.5E+01 3.7E+00 1 .2E+01
5.54E+01 8.5E+00 3.7E+00 1 .2E+01
7.35E+01 3.3E+01 3.7E+00 1 .2E+01
8.79E+02 1.0E+00 3.7E+00 1 .2E+01
4.22E+03 9.7E-01 3.7E+00 1 .2E+01
1.85E+00 1.2E+01 3.7E+00 1 .2E+01
1.85E+00 9.0E+00 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.13E+03 110% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.22E+03 119% VUICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
1.21E+03 118% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-515
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
K SWA-L07-1313-T01-A 1 3.03E+05
K SWA-L07-1313-T02-A 1 3.61 E+05
K SWA-L07-1313-T03-A 1 4.36E+05
K SWA-L07-1313-T04-A 1 4.47E+05
K SWA-L07-1313-T05-A 1 4.50E+05
K SWA-L07-1313-T06-A 1 4.79E+05
K SWA-L07-1313-T07-A 1 5.08E+05
K SWA-L07-1313-T08-A 1 2.65E+05
K SWA-L07-1313-T09-A 1 6.09E+05
K SWA-L07-1313-T01-B 1 3.03E+05
K SWA-L07-1313-T02-B 1 3.62E+05
K SWA-L07-1313-T03-B 1 4.29E+05
K SWA-L07-1313-T04-B 1 4.35E+05
K SWA-L07-1313-T05-B 1 4.52E+05
K SWA-L07-1313-T06-B 1 4.74E+05
K SWA-L07-1313-T07-B 1 5.29E+05
K SWA-L07-1313-T08-B 1 2.56E+05
K SWA-L07-1313-T09-B 1 3.57E+05
K SWA-L07-1313-T01-C 1 3.13E+05
K SWA-L07-1313-T02-C 1 3.72E+05
K SWA-L07-1313-T03-C 1 4.80E+05
K SWA-L07-1313-T04-C 1 4.47E+05
K SWA-L07-1313-T05-C 1 4.50E+05
K SWA-L07-1313-T06-C 1 4.29E+05
K SWA-L07-1313-T07-C 1 5.14E+05
K SWA-L07-1313-T08-C 1 3.24E+05
K SWA-L07-1313-T09-C 1 3.65E+05
K SWA-L07-1313-B01-A 1 5.61 E+00
K SWA-L07-1313-B02-A 1 9.83E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.03E+05 7.5E-01 1.6E+00 5.1E+00
3.61E+05 1.1E+00 1.6E+00 5.1E+00
4.36E+05 2.3E+00 1.6E+00 5.1 E+00 1000 100
4.47E+05 1.6E+00 1.6E+00 5.1 E+00
4.50E+05 5.7E-01 1.6E+00 5.1E+00
4.79E+05 1.6E+00 1.6E+00 5.1 E+00
5.08E+05 3.7E+00 1.6E+00 5.1E+00
2.65E+05 5.4E+00 1.6E+00 5.1E+00
6.09E+05 7.7E-01 1.6E+00 5.1E+00
3.03E+05 5.5E-01 1.6E+00 5.1E+00
3.62E+05 1.2E+00 1.6E+00 5.1E+00
4.29E+05 7.3E-01 1.6E+00 5.1 E+00 1000 100
4.35E+05 1.4E+00 1.6E+00 5.1 E+00
4.52E+05 1.9E-01 1.6E+00 5.1E+00
4.74E+05 7.0E-01 1.6E+00 5.1E+00
5.29E+05 1.1E+01 1.6E+00 5.1E+00
2.56E+05 9.0E+00 1.6E+00 5.1E+00
3.57E+05 9.2E+00 1.6E+00 5.1E+00
3.13E+05 1.7E+00 1.6E+00 5.1E+00
3.72E+05 7.0E-01 1.6E+00 5.1 E+00
4.80E+05 3.2E+00 1.6E+00 5.1E+00 1000 100
4.47E+05 1.5E+00 1.6E+00 5.1 E+00
4.50E+05 2.3E+00 1.6E+00 5.1E+00
4.29E+05 3.2E+00 1.6E+00 5.1 E+00
5.14E+05 2.0E-01 1.6E+00 5.1E+00
3.24E+05 8.3E+00 1.6E+00 5.1 E+00
3.65E+05 1.2E+01 1.6E+00 5.1 E+00
5.61 E+00 1.3E+00 1.6E+00 5.1 E+00
9.83E+01 2.1E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
4.37E+05 88% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
4.30E+05 95% VUICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
4.81E+05 81% VUICP-OES 1 1/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-516
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
1 ug/L
Se SWA-L07-1313-T01-A 1 9.32E+04
Se SWA-L07-1313-T02-A 1 9.73E+04
Se SWA-L07-1313-T03-A 1 1.04E+05
Se SWA-L07-1313-T04-A 1 1.17E+05
Se SWA-L07-1313-T05-A 1 1.23E+05
Se SWA-L07-1313-T06-A 1 1.28E+05
Se SWA-L07-1313-T07-A 1 1.24E+05
Se SWA-L07-1313-T08-A 1 5.23E+04
Se SWA-L07-1313-T09-A 1 9.69E+04
Se SWA-L07-1313-T01-B 1 9.41 E+04
Se SWA-L07-1313-T02-B 1 9.30E+04
Se SWA-L07-1313-T03-B 1 1.01E+05
Se SWA-L07-1313-T04-B 1 1.15E+05
Se SWA-L07-1313-T05-B 1 1.20E+05
Se SWA-L07-1313-T06-B 1 1.24E+05
Se SWA-L07-1313-T07-B 1 1.03E+05
Se SWA-L07-1313-T08-B 1 4.96E+04
Se SWA-L07-1313-T09-B 1 3.64E+04
Se SWA-L07-1313-T01-C 1 1.02E+05
Se SWA-L07-1313-T02-C 1 1.01E+05
Se SWA-L07-1313-T03-C 1 1.28E+05
Se SWA-L07-1313-T04-C 1 1.19E+05
Se SWA-L07-1313-T05-C 1 1.24E+05
Se SWA-L07-1313-T06-C 1 9.85E+04
Se SWA-L07-1313-T07-C 1 1.28E+05
Se SWA-L07-1313-T08-C 1 6.46E+04
Se SWA-L07-1313-T09-C 1 3.59E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.32E+04 8.3E-01 1.5E+01 4.8E+01
9.73E+04 1.1E+00 1.5E+01 4.8E+01
1.04E+05 4.5E-01 1.5E+01 4.8E+01 10 100
1.17E+05 3.8E-01 1.5E+01 4.8E+01
1.23E+05 2.8E-01 1.5E+01 4.8E+01
1.28E+05 3.2E-01 1.5E+01 4.8E+01
1.24E+05 5.0E-01 1.5E+01 4.8E+01
5.23E+04 7.9E-01 1.5E+01 4.8E+01
9.69E+04 8.7E-02 1.5E+01 4.8E+01
9.41 E+04 5.3E-01 1.5E+01 4.8E+01
9.30E+04 8.5E-01 1.5E+01 4.8E+01
1.01E+05 1.5E-01 1.5E+01 4.8E+01 10 100
1.15E+05 1.6E-01 1.5E+01 4.8E+01
1.20E+05 4.7E-01 1.5E+01 4.8E+01
1.24E+05 2.0E-01 1.5E+01 4.8E+01
1.03E+05 5.5E-01 1.5E+01 4.8E+01
4.96E+04 5.5E-01 1.5E+01 4.8E+01
3.64E+04 7.4E-01 1.5E+01 4.8E+01
1.02E+05 5.0E-01 1.5E+01 4.8E+01
1.01E+05 6.2E-01 1.5E+01 4.8E+01
1.28E+05 2.4E+00 1.5E+01 4.8E+01 10 100
1.19E+05 9.4E-01 1.5E+01 4.8E+01
1.24E+05 9.7E-01 1.5E+01 4.8E+01
9.85E+04 3.1E+00 1.5E+01 4.8E+01
1.28E+05 3.7E-01 1.5E+01 4.8E+01
6.46E+04 8.6E-01 1.5E+01 4.8E+01
3.59E+04 8.4E-01 1.5E+01 4.8E+01
Se SWA-L07-1313-B01-A 1 7.50E+00 U1/2 7.50E+00 3.8E+01 1.5E+01 4.8E+01
Se SWA-L07-1313-B02-A 1 7.50E+00 U1/2 7.50E+00 1.7E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.05E+05 91% VUICP-OES 1 1/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.02E+05 99% VUICP-OES 11/3/10 1 1:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:11 PM EPA Interlab L07 1313-1316 SWA
1.29E+05 86% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 4PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 6PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 7PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-517
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone.
1 1 ug/L
Si SWA-L07-1313-T01-A 1 5.53E+03
Si SWA-L07-1313-T02-A 1 2.65E+03
Si SWA-L07-1313-T03-A 1 1.19E+03
Si SWA-L07-1313-T04-A 1 1.19E+03
Si SWA-L07-1313-T05-A 1 1.59E+03
Si SWA-L07-1313-T06-A 1 1.97E+03
Si SWA-L07-1313-T07-A 1 2.65E+03
Si SWA-L07-1313-T08-A 1 1.57E+04
Si SWA-L07-1313-T09-A 1 2.87E+05
Si SWA-L07-1313-T01-B 1 5.66E+03
Si SWA-L07-1313-T02-B 1 2.69E+03
Si SWA-L07-1313-T03-B 1 1.41E+03
Si SWA-L07-1313-T04-B 1 1.20E+03
Si SWA-L07-1313-T05-B 1 1.41E+03
Si SWA-L07-1313-T06-B 1 2.40E+03
Si SWA-L07-1313-T07-B 1 2.66E+03
Si SWA-L07-1313-T08-B 1 1.13E+04
Si SWA-L07-1313-T09-B 1 1.21E+05
Si SWA-L07-1313-T01-C 1 5.76E+03
Si SWA-L07-1313-T02-C 1 2.58E+03
Si SWA-L07-1313-T03-C 1 1.53E+03
Si SWA-L07-1313-T04-C 1 1.18E+03
Si SWA-L07-1313-T05-C 1 1.31E+03
Si SWA-L07-1313-T06-C 1 2.48E+03
Si SWA-L07-1313-T07-C 1 2.61E+03
Si SWA-L07-1313-T08-C 1 1.58E+04
Si SWA-L07-1313-T09-C 1 5.13E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.53E+03 8.8E-01 1.1 E+00 3.5E+00
2.65E+03 1.3E+00 1.1 E+00 3.5E+00
1.19E+03 3.2E-01 1.1E+00 3.5E+00 1000 100
1.19E+03 4.2E-01 1.1E+00 3.5E+00
1.59E+03 2.7E-01 1.1 E+00 3.5E+00
1.97E+03 7.4E-01 1.1 E+00 3.5E+00
2.65E+03 2.9E-01 1.1 E+00 3.5E+00
1.57E+04 5.6E-01 1.1 E+00 3.5E+00
2.87E+05 1.6E+00 1.1 E+00 3.5E+00
5.66E+03 6.9E-01 1.1 E+00 3.5E+00
2.69E+03 1.3E+00 1.1 E+00 3.5E+00
1.41E+03 1.8E-01 1.1E+00 3.5E+00 1000 100
1.20E+03 2.6E-01 1.1 E+00 3.5E+00
1.41E+03 3.9E-01 1.1 E+00 3.5E+00
2.40E+03 4.8E-02 1.1 E+00 3.5E+00
2.66E+03 6.2E-01 1.1 E+00 3.5E+00
1.13E+04 1.4E-01 1.1 E+00 3.5E+00
1.21E+05 4.8E-01 1.1E+00 3.5E+00
5.76E+03 8.2E-01 1.1E+00 3.5E+00
2.58E+03 6.5E-01 1.1E+00 3.5E+00
1.53E+03 2.2E+00 1.1E+00 3.5E+00 1000 100
1.18E+03 8.6E-01 1.1E+00 3.5E+00
1.31E+03 1.2E+00 1.1 E+00 3.5E+00
2.48E+03 2.8E+00 1.1 E+00 3.5E+00
2.61 E+03 4.1E-01 1.1 E+00 3.5E+00
1.58E+04 6.2E-01 1.1 E+00 3.5E+00
5.13E+04 7.9E-01 1.1 E+00 3.5E+00
Si SWA-L07-1313-B01-A 1 5.50E-01 U1/2 5.50E-01 3.6E+01 1.1E+00 3.5E+00
Si SWA-L07-1313-B02-A 1 4.01 E+00
4.01 E+00 2.2E+01 1.1 E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
2.16E+03 97% VUICP-OES 1 1/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
2.26E+03 85% VUICP-OES 11/3/10 1 1:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:11 PM EPA Interlab L07 1313-1316 SWA
2.33E+03 80% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 4PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 6PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:1 7PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-518
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na SWA-L07-1313-T01-A 1
Na SWA-L07-1313-T02-A 1
Na SWA-L07-1313-T03-A 1
Na SWA-L07-1313-T04-A 1
Na SWA-L07-1313-T05-A 1
Na SWA-L07-1313-T06-A 1
Na SWA-L07-1313-T07-A 1
Na SWA-L07-1313-T08-A 1
Na SWA-L07-1313-T09-A 1
Na SWA-L07-1313-T01-B 1
Na SWA-L07-1313-T02-B 1
Na SWA-L07-1313-T03-B 1
Na SWA-L07-1313-T04-B 1
Na SWA-L07-1313-T05-B 1
Na SWA-L07-1313-T06-B 1
Na SWA-L07-1313-T07-B 1
Na SWA-L07-1313-T08-B 1
Na SWA-L07-1313-T09-B 1
Na SWA-L07-1313-T01-C 1
Na SWA-L07-1313-T02-C 1
Na SWA-L07-1313-T03-C 1
Na SWA-L07-1313-T04-C 1
Na SWA-L07-1313-T05-C 1
Na SWA-L07-1313-T06-C 1
Na SWA-L07-1313-T07-C 1
Na SWA-L07-1313-T08-C 1
Na SWA-L07-1313-T09-C 1
Na SWA-L07-1313-B01-A 1
Na SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
3.61 E+05
3.88E+05
3.82E+05
3.71 E+05
3.64E+05
3.66E+05
3.58E+05
3.58E+05
1.29E+06
3.62E+05
3.78E+05
3.78E+05
3.67E+05
3.62E+05
3.58E+05
3.56E+05
3.61 E+05
3.64E+05
3.60E+05
3.85E+05
3.78E+05
3.62E+05
3.62E+05
3.61 E+05
3.56E+05
3.52E+05
3.52E+05
1.25E+00 U1/2
3.50E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.61 E+05 1.4E-01 2.5E+00 8.0E+00
3.88E+05 1.3E+00 2.5E+00 8.0E+00
3.82E+05 2.0E-01 2.5E+00 8.0E+00 1000 100
3.71 E+05 5.4E-01 2.5E+00 8.0E+00
3.64E+05 5.7E-01 2.5E+00 8.0E+00
3.66E+05 4.4E-01 2.5E+00 8.0E+00
3.58E+05 4.7E-01 2.5E+00 8.0E+00
3.58E+05 3.1E-01 2.5E+00 8.0E+00
1.29E+06 1.2E+00 2.5E+00 8.0E+00
3.62E+05 5.0E-01 2.5E+00 8.0E+00
3.78E+05 4.5E-01 2.5E+00 8.0E+00
3.78E+05 7.8E-01 2.5E+00 8.0E+00 1000 100
3.67E+05 6.6E-02 2.5E+00 8.0E+00
3.62E+05 3.7E-01 2.5E+00 8.0E+00
3.58E+05 2.2E-01 2.5E+00 8.0E+00
3.56E+05 3.0E-01 2.5E+00 8.0E+00
3.61 E+05 5.6E-01 2.5E+00 8.0E+00
3.64E+05 6.5E-01 2.5E+00 8.0E+00
3.60E+05 9.6E-01 2.5E+00 8.0E+00
3.85E+05 6.7E-01 2.5E+00 8.0E+00
3.78E+05 1.2E+00 2.5E+00 8.0E+00 1000 100
3.62E+05 5.0E-01 2.5E+00 8.0E+00
3.62E+05 1.5E+00 2.5E+00 8.0E+00
3.61E+05 2.2E+00 2.5E+00 8.0E+00
3.56E+05 5.1E-01 2.5E+00 8.0E+00
3.52E+05 5.2E-01 2.5E+00 8.0E+00
3.52E+05 1.4E+00 2.5E+00 8.0E+00
1.25E+00 3.3E+01 2.5E+00 8.0E+00
3.50E+02 1.9E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
3.83E+05 86% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
3.79E+05 92% VUICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
3.78E+05 82% VUICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-519
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-L07-1313-T01-A 1
SWA-L07-1313-T02-A 1
SWA-L07-1313-T03-A 1
SWA-L07-1313-T04-A 1
SWA-L07-1313-T05-A 1
SWA-L07-1313-T06-A 1
SWA-L07-1313-T07-A 1
SWA-L07-1313-T08-A 1
SWA-L07-1313-T09-A 1
SWA-L07-1313-T01-B 1
SWA-L07-1313-T02-B 1
SWA-L07-1313-T03-B 1
SWA-L07-1313-T04-B 1
SWA-L07-1313-T05-B 1
SWA-L07-1313-T06-B 1
SWA-L07-1313-T07-B 1
SWA-L07-1313-T08-B 1
SWA-L07-1313-T09-B 1
SWA-L07-1313-T01-C 1
SWA-L07-1313-T02-C 1
SWA-L07-1313-T03-C 1
SWA-L07-1313-T04-C 1
SWA-L07-1313-T05-C 1
SWA-L07-1313-T06-C 1
SWA-L07-1313-T07-C 1
SWA-L07-1313-T08-C 1
SWA-L07-1313-T09-C 1
SWA-L07-1313-B01-A 1
SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
3.75E+02
4.03E+03
2.20E+04
3.21 E+04
3.91 E+04
4.57E+04
5.44E+04
2.70E+04
7.99E+04
3.85E+02
4.23E+03
1.99E+04
3.18E+04
3.75E+04
4.56E+04
4.85E+04
2.59E+04
2.19E+04
4.10E+02
4.25E+03
2.03E+04
3.46E+04
3.77E+04
4.92E+04
5.71 E+04
3.28E+04
2.21E+04
5.00E-01 U1/2
3.76E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+02 6.7E-01 1.0E+00 3.2E+00
4.03E+03 1.6E+00 1.0E+00 3.2E+00
2.20E+04 1.6E-01 1.0E+00 3.2E+00 1000 100
3.21 E+04 2.6E-01 1.0E+00 3.2E+00
3.91 E+04 1.3E+00 1.0E+00 3.2E+00
4.57E+04 4.9E-01 1.0E+00 3.2E+00
5.44E+04 2.8E-01 1.0E+00 3.2E+00
2.70E+04 1.3E+00 1.0E+00 3.2E+00
7.99E+04 1.9E+00 1.0E+00 3.2E+00
3.85E+02 1.0E+00 1.0E+00 3.2E+00
4.23E+03 1.6E+00 1.0E+00 3.2E+00
1.99E+04 1.6E+00 1.0E+00 3.2E+00 1000 100
3.18E+04 1.1E+00 1.0E+00 3.2E+00
3.75E+04 7.7E-01 1.0E+00 3.2E+00
4.56E+04 4.4E-01 1.0E+00 3.2E+00
4.85E+04 4.7E-01 1.0E+00 3.2E+00
2.59E+04 6.1E-01 1.0E+00 3.2E+00
2.19E+04 2.9E-01 1.0E+00 3.2E+00
4.10E+02 1.5E+00 1.0E+00 3.2E+00
4.25E+03 6.1E-01 1.0E+00 3.2E+00
2.03E+04 2.3E+00 1.0E+00 3.2E+00 1000 100
3.46E+04 1.4E+00 1.0E+00 3.2E+00
3.77E+04 1.1E+00 1.0E+00 3.2E+00
4.92E+04 4.2E+00 1.0E+00 3.2E+00
5.71 E+04 5.4E-01 1.0E+00 3.2E+00
3.28E+04 3.3E-01 1.0E+00 3.2E+00
2.21 E+04 1.7E+00 1.0E+00 3.2E+00
5.00E-01 7.3E+01 1.0E+00 3.2E+00
3.76E+00 4.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
2.29E+04 86% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
2.08E+04 89% VUICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
2.11E+04 85% VUICP-OES 1 1/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-520
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S SWA-L07-1313-T01-A 1
S SWA-L07-1313-T02-A 1
S SWA-L07-1313-T03-A 1
S SWA-L07-1313-T04-A 1
S SWA-L07-1313-T05-A 1
S SWA-L07-1313-T06-A 1
S SWA-L07-1313-T07-A 1
S SWA-L07-1313-T08-A 1
S SWA-L07-1313-T09-A 1
S SWA-L07-1313-T01-B 1
S SWA-L07-1313-T02-B 1
S SWA-L07-1313-T03-B 1
S SWA-L07-1313-T04-B 1
S SWA-L07-1313-T05-B 1
S SWA-L07-1313-T06-B 1
S SWA-L07-1313-T07-B 1
S SWA-L07-1313-T08-B 1
S SWA-L07-1313-T09-B 1
S SWA-L07-1313-T01-C 1
S SWA-L07-1313-T02-C 1
S SWA-L07-1313-T03-C 1
S SWA-L07-1313-T04-C 1
S SWA-L07-1313-T05-C 1
S SWA-L07-1313-T06-C 1
S SWA-L07-1313-T07-C 1
S SWA-L07-1313-T08-C 1
S SWA-L07-1313-T09-C 1
S SWA-L07-1313-B01-A 1
S SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
9.64E+05
1.04E+06
1.03E+06
9.50E+05
7.20E+05
9.05E+05
5.30E+05
2.26E+05
5.17E+05
9.38E+05
1.04E+06
1.10E+06
1.04E+06
9.29E+05
8.22E+05
4.54E+05
2.10E+05
1.55E+05
1.03E+06
1.11E+06
9.97E+05
1.00E+06
1.06E+06
8.80E+05
6.87E+05
2.82E+05
1.59E+05
1.28E+01 E
8.64E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.64E+05 4.0E-01 6.8E+00 2.2E+01
1.04E+06 1.9E+00 6.8E+00 2.2E+01
1.03E+06 9.8E-01 6.8E+00 2.2E+01 1000 100
9.50E+05 7.0E-01 6.8E+00 2.2E+01
7.20E+05 3.6E-01 6.8E+00 2.2E+01
9.05E+05 4.2E-01 6.8E+00 2.2E+01
5.30E+05 6.0E-01 6.8E+00 2.2E+01
2.26E+05 9.5E-01 6.8E+00 2.2E+01
5.17E+05 3.2E-01 6.8E+00 2.2E+01
9.38E+05 6.0E-01 6.8E+00 2.2E+01
1.04E+06 7.3E-01 6.8E+00 2.2E+01
1.10E+06 1.0E+00 6.8E+00 2.2E+01 1000 100
1.04E+06 1.4E-01 6.8E+00 2.2E+01
9.29E+05 2.1E-01 6.8E+00 2.2E+01
8.22E+05 6.8E-01 6.8E+00 2.2E+01
4.54E+05 4.9E-01 6.8E+00 2.2E+01
2.10E+05 1.6E-01 6.8E+00 2.2E+01
1.55E+05 4.5E-01 6.8E+00 2.2E+01
1.03E+06 1.1E+00 6.8E+00 2.2E+01
1.11E+06 9.9E-02 6.8E+00 2.2E+01
9.97E+05 2.1E+00 6.8E+00 2.2E+01 1000 100
1.00E+06 6.2E-01 6.8E+00 2.2E+01
1.06E+06 8.4E-01 6.8E+00 2.2E+01
8.80E+05 1.9E+00 6.8E+00 2.2E+01
6.87E+05 1.3E-01 6.8E+00 2.2E+01
2.82E+05 7.0E-01 6.8E+00 2.2E+01
1.59E+05 5.3E-01 6.8E+00 2.2E+01
1.28E+01 6.0E+01 6.8E+00 2.2E+01
8.64E+01 2.4E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.03E+06 88% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.10E+06 95% VUICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
9.98E+05 92% VUICP-OES 1 1/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-521
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L07-1313-T01-A 1 2.30E+00 U1/2 2.30E+00 3.2E+01 4.6E+00 1.5E+01
Tl SWA-L07-1313-T02-A 1 2.30E+00 U1/2 2.30E+00 3.9E+01 4.6E+00 1.5E+01
Tl SWA-L07-1313-T03-A 1 2.30E+00 U1/2 2.30E+00 1 .4E+02 4.6E+00 1.5E+01 10 100
Tl SWA-L07-1313-T04-A 1 2.30E+00 U1/2 2.30E+00 8.2E+01 4.6E+00 1.5E+01
Tl SWA-L07-1313-T05-A 1 2.30E+00 U1/2 2.30E+00 1 .4E+02 4.6E+00 1.5E+01
Tl SWA-L07-1313-T06-A 1 1.29E+01 E
Tl SWA-L07-1313-T07-A 1 3.26E+01
Tl SWA-L07-1313-T08-A 1 9.15E+00 E
1.29E+01 3.7E+01 4.6E+00 1 .5E+01
3.26E+01 1.7E+01 4.6E+00 1 .5E+01
9.15E+00 3.3E+01 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T09-A 1 2.30E+00 U1/2 2.30E+00 8.7E+00 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T01-B 1 2.30E+00 U1/2 2.30E+00 4.1E+01 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T02-B 1 2.30E+00 U1/2 2.30E+00 6.9E+01 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T03-B 1 2.30E+00 U1/2 2.30E+00 5.6E+01 4.6E+00 1 .5E+01 10 100
Tl SWA-L07-1313-T04-B 1 2.30E+00 U1/2 2.30E+00 2.7E+02 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T05-B 1 2.30E+00 U1/2 2.30E+00 4.7E+01 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T06-B 1 1.09E+01 E
Tl SWA-L07-1313-T07-B 1 2.30E+01
Tl SWA-L07-1313-T08-B 1 7.93E+00 E
1.09E+01 3.4E+01 4.6E+00 1 .5E+01
2.30E+01 1.2E+01 4.6E+00 1 .5E+01
7.93E+00 2.7E+01 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T09-B 1 2.30E+00 U1/2 2.30E+00 1.2E+02 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T01-C 1 2.30E+00 U1/2 2.30E+00 6.0E+01 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T02-C 1 2.30E+00 U1/2 2.30E+00 8.6E+01 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T03-C 1 2.30E+00 U1/2 2.30E+00 5.9E+02 4.6E+00 1 .5E+01 10 100
Tl SWA-L07-1313-T04-C 1 2.30E+00 U1/2 2.30E+00 2.0E+02 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T05-C 1 2.30E+00 U1/2 2.30E+00 5.6E+02 4.6E+00 1 .5E+01
Tl SWA-L07-1313-T06-C 1 1.15E+01 E
Tl SWA-L07-1313-T07-C 1 3.09E+01
Tl SWA-L07-1313-T08-C 1 8.89E+00 E
1.15E+01 6.7E+01 4.6E+00 1.5E+01
3.09E+01 2.7E+01 4.6E+00 1.5E+01
8.89E+00 8.9E+01 4.6E+00 1.5E+01
Tl SWA-L07-1313-T09-C 1 2.30E+00 U1/2 2.30E+00 1.1E+02 4.6E+00 1.5E+01
Tl SWA-L07-1313-B01-A 1 2.30E+00 U1/2 2.30E+00 7.6E+01 4.6E+00 1.5E+01
Tl SWA-L07-1313-B02-A 1 2.30E+00 U1/2 2.30E+00 3.8E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
8.48E+02 85% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
9.13E+02 91% VUICP-OES 1 1/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
8.19E+02 82% VUICP-OES 1 1/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-522
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L07-1313-T01-A 1 1.00E+OOU1/2 1.00E+00 2.4E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T02-A 1 1.00E+OOU1/2 1.00E+00 3.4E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T03-A 1 1.00E+OOU1/2 1.00E+00 8.2E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L07-1313-T04-A 1 1.00E+OOU1/2 1.00E+00 8.7E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T05-A 1 1.00E+OOU1/2 1.00E+00 5.7E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T06-A 1 1.00E+OOU1/2 1.00E+00 4.4E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T07-A 1 1.00E+OOU1/2 1.00E+00 5.2E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T08-A 1 5.97E+01
Ti SWA-L07-1313-T09-A 1 1.52E+05
5.97E+01 1.8E+00 2.0E+00 6.4E+00
1.52E+05 1.0E+00 2.0E+00 6.4E+00
Ti SWA-L07-1313-T01-B 1 1.00E+OOU1/2 1.00E+00 1 .3E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T02-B 1 1.00E+OOU1/2 1.00E+00 8.3E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T03-B 1 1.00E+OOU1/2 1.00E+00 1 .6E+02 2.0E+00 6.4E+00 10 100
Ti SWA-L07-1313-T04-B 1 1.00E+OOU1/2 1.00E+00 4.2E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T05-B 1 1.00E+OOU1/2 1.00E+00 3.6E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T06-B 1 1.00E+OOU1/2 1.00E+00 7.8E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T07-B 1 1.00E+OOU1/2 1.00E+00 1 .8E+02 2.0E+00 6.4E+00
Ti SWA-L07-1313-T08-B 1 5.69E+01
Ti SWA-L07-1313-T09-B 1 1.58E+04
5.69E+01 1.3E+00 2.0E+00 6.4E+00
1.58E+04 1.2E+00 2.0E+00 6.4E+00
Ti SWA-L07-1313-T01-C 1 1.00E+OOU1/2 1.00E+00 1 .OE+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T02-C 1 1.00E+OOU1/2 1.00E+00 3.6E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T03-C 1 1.00E+OOU1/2 1.00E+00 5.4E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L07-1313-T04-C 1 1.00E+OOU1/2 1.00E+00 1 .OE+02 2.0E+00 6.4E+00
Ti SWA-L07-1313-T05-C 1 1.00E+OOU1/2 1.00E+00 3.5E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T06-C 1 1.00E+OOU1/2 1.00E+00 7.5E+02 2.0E+00 6.4E+00
Ti SWA-L07-1313-T07-C 1 1.00E+OOU1/2 1.00E+00 2.8E+01 2.0E+00 6.4E+00
Ti SWA-L07-1313-T08-C 1 8.26E+01
Ti SWA-L07-1313-T09-C 1 1.56E+04
8.26E+01 1.1E+00 2.0E+00 6.4E+00
1.56E+04 7.9E-01 2.0E+00 6.4E+00
Ti SWA-L07-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 9.9E+00 2.0E+00 6.4E+00
Ti SWA-L07-1313-B02-A 1 2.73E+00 E
2.73E+00 9.5E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.01E+03 101% VUICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.11E+03 111% VUICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
9.85E+02 98% VU ICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-523
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V SWA-L07-1313-T01-A 1
V SWA-L07-1313-T02-A 1
V SWA-L07-1313-T03-A 1
V SWA-L07-1313-T04-A 1
V SWA-L07-1313-T05-A 1
V SWA-L07-1313-T06-A 1
V SWA-L07-1313-T07-A 1
V SWA-L07-1313-T08-A 1
V SWA-L07-1313-T09-A 1
V SWA-L07-1313-T01-B 1
V SWA-L07-1313-T02-B 1
V SWA-L07-1313-T03-B 1
V SWA-L07-1313-T04-B 1
V SWA-L07-1313-T05-B 1
V SWA-L07-1313-T06-B 1
V SWA-L07-1313-T07-B 1
V SWA-L07-1313-T08-B 1
V SWA-L07-1313-T09-B 1
V SWA-L07-1313-T01-C 1
V SWA-L07-1313-T02-C 1
V SWA-L07-1313-T03-C 1
V SWA-L07-1313-T04-C 1
V SWA-L07-1313-T05-C 1
V SWA-L07-1313-T06-C 1
V SWA-L07-1313-T07-C 1
V SWA-L07-1313-T08-C 1
V SWA-L07-1313-T09-C 1
V SWA-L07-1313-B01-A 1
V SWA-L07-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
3.44E+02
8.56E+01
1.49E+02
2.25E+02
1.97E+02
2.08E+02
1.84E+02
9.46E+01
5.77E+03
3.39E+02
8.21E+01
1.45E+02
2.14E+02
1.95E+02
1.97E+02
1.50E+02
8.57E+01
1.41E+03
3.76E+02
8.63E+01
1.55E+02
2.22E+02
2.10E+02
2.04E+02
2.02E+02
1.13E+02
8.75E+02
7.50E-01 U1/2
7.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.44E+02 6.3E-01 1.5E+00 4.8E+00
8.56E+01 1.9E+00 1.5E+00 4.8E+00
1.49E+02 3.3E+00 1.5E+00 4.8E+00 10 100
2.25E+02 1.3E+00 1.5E+00 4.8E+00
1.97E+02 3.3E-01 1.5E+00 4.8E+00
2.08E+02 1.5E+00 1.5E+00 4.8E+00
1.84E+02 1.0E+00 1.5E+00 4.8E+00
9.46E+01 1.4E+00 1.5E+00 4.8E+00
5.77E+03 7.6E-01 1.5E+00 4.8E+00
3.39E+02 9.7E-01 1.5E+00 4.8E+00
8.21 E+01 3.0E-01 1.5E+00 4.8E+00
1.45E+02 1.2E+00 1.5E+00 4.8E+00 10 100
2.14E+02 7.5E-01 1.5E+00 4.8E+00
1.95E+02 8.0E-01 1.5E+00 4.8E+00
1.97E+02 6.5E-01 1.5E+00 4.8E+00
1.50E+02 3.3E+00 1.5E+00 4.8E+00
8.57E+01 1.3E+00 1.5E+00 4.8E+00
1.41E+03 1.1E+00 1.5E+00 4.8E+00
3.76E+02 2.1E-01 1.5E+00 4.8E+00
8.63E+01 6.3E-01 1.5E+00 4.8E+00
1.55E+02 2.0E+00 1.5E+00 4.8E+00 10 100
2.22E+02 1.9E+00 1.5E+00 4.8E+00
2.10E+02 1.6E+00 1.5E+00 4.8E+00
2.04E+02 2.3E+00 1.5E+00 4.8E+00
2.02E+02 1.2E+00 1.5E+00 4.8E+00
1.13E+02 2.6E+00 1.5E+00 4.8E+00
8.75E+02 7.9E-01 1.5E+00 4.8E+00
7.50E-01 3.9E+01 1.5E+00 4.8E+00
7.50E-01 7.2E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.15E+03 100% VU ICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.21E+03 106% VU ICP-OES 11/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
1.18E+03 103% VU ICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 1 1/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-524
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-L07-1313-T01-A 1
Zn SWA-L07-1313-T02-A 1
Zn SWA-L07-1313-T03-A 1
Zn SWA-L07-1313-T04-A 1
Zn SWA-L07-1313-T05-A 1
Zn SWA-L07-1313-T06-A 1
Zn SWA-L07-1313-T07-A 1
Zn SWA-L07-1313-T08-A 1
Zn SWA-L07-1313-T09-A 1
Zn SWA-L07-1313-T01-B 1
Zn SWA-L07-1313-T02-B 1
Zn SWA-L07-1313-T03-B 1
Zn SWA-L07-1313-T04-B 1
Zn SWA-L07-1313-T05-B 1
Zn SWA-L07-1313-T06-B 1
Zn SWA-L07-1313-T07-B 1
Zn SWA-L07-1313-T08-B 1
Zn SWA-L07-1313-T09-B 1
Zn SWA-L07-1313-T01-C 1
Zn SWA-L07-1313-T02-C 1
Zn SWA-L07-1313-T03-C 1
Zn SWA-L07-1313-T04-C 1
Zn SWA-L07-1313-T05-C 1
Zn SWA-L07-1313-T06-C 1
Zn SWA-L07-1313-T07-C 1
Zn SWA-L07-1313-T08-C 1
Zn SWA-L07-1313-T09-C 1
Zn SWA-L07-1313-B01-A 1
Zn SWA-L07-1313-B02-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.72E+00 E
5.00E-01 U1/2
1.97E+00 E
1.37E+00 E
2.65E+00 E
1.67E+01
6.78E+02
1.15E+03
5.65E+03
5.00E-01 U1/2
1.34E+00 E
1.74E+00 E
2.34E+00 E
2.90E+00 E
8.23E+01
9.74E+02
1.21E+03
2.01 E+03
1.93E+00 E
5.00E-01 U1/2
1.66E+00 E
1.31E+00 E
2.64E+00 E
2.11E+01
5.53E+02
1.14E+03
1.96E+03
5.00E-01 U1/2
1.22E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.72E+00 3.4E+01 1.0E+00 3.2E+00
5.00E-01 7.2E+00 1.0E+00 3.2E+00
1.97E+00 4.7E+01 1.0E+00 3.2E+00 10 100
1.37E+00 1.2E+01 1.0E+00 3.2E+00
2.65E+00 1.1E+01 1.0E+00 3.2E+00
1.67E+01 1.3E+00 1.0E+00 3.2E+00
6.78E+02 8.5E-01 1.0E+00 3.2E+00
1.15E+03 6.0E-01 1.0E+00 3.2E+00
5.65E+03 1.5E+00 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00
1.34E+00 2.9E+01 1.0E+00 3.2E+00
1.74E+00 4.7E+01 1.0E+00 3.2E+00 10 100
2.34E+00 2.7E+01 1.0E+00 3.2E+00
2.90E+00 1.4E+01 1.0E+00 3.2E+00
8.23E+01 9.4E-01 1.0E+00 3.2E+00
9.74E+02 3.2E-01 1.0E+00 3.2E+00
1.21 E+03 8.4E-01 1.0E+00 3.2E+00
2.01 E+03 4.6E-01 1.0E+00 3.2E+00
1.93E+00 1.5E+01 1.0E+00 3.2E+00
5.00E-01 2.4E+02 1.0E+00 3.2E+00
1.66E+00 5.6E+00 1.0E+00 3.2E+00 10 100
1.31E+00 4.3E+01 1.0E+00 3.2E+00
2.64E+00 1.7E+01 1.0E+00 3.2E+00
2.11E+01 6.3E+00 1.0E+00 3.2E+00
5.53E+02 2.2E-01 1.0E+00 3.2E+00
1.14E+03 8.2E-01 1.0E+00 3.2E+00
1.96E+03 3.0E-01 1.0E+00 3.2E+00
5.00E-01 2.8E+01 1.0E+00 3.2E+00
1.22E+00 2.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/3/10 11:33 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:34 AM EPA Interlab L07 1313-1316 SWA
1.05E+03 105% VU ICP-OES 11/3/10 11:36 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:38 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:39 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:41 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:43 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:44 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:46 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1011:51 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:53 AM EPA Interlab L07 1313-1316 SWA
1.13E+03 113% VUICP-OES 1 1/3/10 11:54 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:56 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:58 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 1 1/3/10 11:59 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:01 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:03 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:04 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:09 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:11 PM EPA Interlab L07 1313-1316 SWA
1.09E+03 109% VU ICP-OES 11/3/10 12:12 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:14 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 12:16 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:17 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:19 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/1012:21 PM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 12:22 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 11/3/10 11:30 AM EPA Interlab L07 1313-1316 SWA
VUICP-OES 11/3/10 11:31 AM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                          1-525
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al SWA-L09-1313-T01-A 1
Al SWA-L09-1313-T02-A 1
Al SWA-L09-1313-T03-A 1
Al SWA-L09-1313-T04-A 1
Al SWA-L09-1313-T05-A 1
Al SWA-L09-1313-T06-A 1
Al SWA-L09-1313-T07-A 1
Al SWA-L09-1313-T08-A 1
Al SWA-L09-1313-T09-A 1
Al SWA-L09-1313-T01-B 1
Al SWA-L09-1313-T02-B 1
Al SWA-L09-1313-T03-B 1
Al SWA-L09-1313-T04-B 1
Al SWA-L09-1313-T05-B 1
Al SWA-L09-1313-T06-B 1
Al SWA-L09-1313-T07-B 1
Al SWA-L09-1313-T08-B 1
Al SWA-L09-1313-T09-B 1
Al SWA-L09-1313-T01-C 1
Al SWA-L09-1313-T02-C 1
Al SWA-L09-1313-T03-C 1
Al SWA-L09-1313-T04-C 1
Al SWA-L09-1313-T05-C 1
Al SWA-L09-1313-T06-C 1
Al SWA-L09-1313-T07-C 1
Al SWA-L09-1313-T08-C 1
Al SWA-L09-1313-T09-C 1
Al SWA-L09-1313-B01-A 1
Al SWA-L09-1313-B02-A 1
Al SWA-L09-1313-B03-A 1
Al SWA-L09-1313-B01-B 1
Al SWA-L09-1313-B03-B 1
Al SWA-L09-1313-B01-C 1
Al SWA-L09-1313-B02-C 1
Al SWA-L09-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
5.64E+04
3.46E+04
8.69E+02
9.63E+01
3.35E+01
1.14E+01
8.95E+00
1.55E+05
6.77E+05
5.20E+04
3.41 E+04
6.54E+02
1.09E+02
3.31E+01
1.49E+01
8.56E+00
1.59E+05
6.15E+05
5.07E+04
3.77E+04
4.53E+02
1.02E+02
5.55E+01
1.56E+01
1.23E+01
3.54E+05
6.12E+05
5.00E-01 U1/2
5.00E-01 U1/2
6.24E+00
8.64E+00
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.64E+04 1.6E+00 1.0E+00 3.2E+00
3.46E+04 8.1E-01 1.0E+00 3.2E+00 1000 100
8.69E+02 5.4E-01 1.0E+00 3.2E+00
9.63E+01 7.9E+00 1.0E+00 3.2E+00
3.35E+01 3.4E+01 1.0E+00 3.2E+00
1.14E+01 2.6E+01 1.0E+00 3.2E+00
8.95E+00 1.0E+02 1.0E+00 3.2E+00
1.55E+05 1.4E+00 1.0E+00 3.2E+00
6.77E+05 2.8E+00 1.0E+00 3.2E+00
5.20E+04 7.8E-01 1.0E+00 3.2E+00
3.41E+04 7.5E-01 1.0E+00 3.2E+00 1000 100
6.54E+02 2.4E-01 1.0E+00 3.2E+00
1.09E+02 6.1E+00 1.0E+00 3.2E+00
3.31E+01 2.5E+01 1.0E+00 3.2E+00
1.49E+01 4.0E+01 1.0E+00 3.2E+00
8.56E+00 8.6E-01 1.0E+00 3.2E+00
1.59E+05 9.4E-01 1.0E+00 3.2E+00
6.15E+05 3.0E-01 1.0E+00 3.2E+00
5.07E+04 3.8E-01 1.0E+00 3.2E+00
3.77E+04 2.5E-01 1.0E+00 3.2E+00 1000 100
4.53E+02 1.3E+00 1.0E+00 3.2E+00
1.02E+02 9.9E+00 1.0E+00 3.2E+00
5.55E+01 2.0E+01 1.0E+00 3.2E+00
1.56E+01 6.9E+00 1.0E+00 3.2E+00
1.23E+01 5.6E+00 1.0E+00 3.2E+00
3.54E+05 6.0E-01 1.0E+00 3.2E+00
6.12E+05 4.3E-01 1.0E+00 3.2E+00
5.00E-01 3.9E+02 1.0E+00 3.2E+00
5.00E-01 1.4E+02 1.0E+00 3.2E+00
6.24E+00 5.1E+01 1.0E+00 3.2E+00
8.64E+00 1.1E+00 1.0E+00 3.2E+00
5.00E-01 4.1E+02 1.0E+00 3.2E+00
5.00E-01 1.1E+02 1.0E+00 3.2E+00
5.00E-01 1.9E+02 1.0E+00 3.2E+00
5.00E-01 6.9E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
3.55E+04 97% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:09 PM EPA Interlab L09 1313-1316 SWA
3.50E+04 86% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
3.87E+04 102% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                                   1-526
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L09-1313-T01-A 1
Sb SWA-L09-1313-T02-A 1
Sb SWA-L09-1313-T03-A 1
Sb SWA-L09-1313-T04-A 1
Sb SWA-L09-1313-T05-A 1
Sb SWA-L09-1313-T06-A 1
Sb SWA-L09-1313-T07-A 1
Sb SWA-L09-1313-T08-A 1
Sb SWA-L09-1313-T09-A 1
Sb SWA-L09-1313-T01-B 1
Sb SWA-L09-1313-T02-B 1
Sb SWA-L09-1313-T03-B 1
Sb SWA-L09-1313-T04-B 1
Sb SWA-L09-1313-T05-B 1
Sb SWA-L09-1313-T06-B 1
Sb SWA-L09-1313-T07-B 1
Sb SWA-L09-1313-T08-B 1
Sb SWA-L09-1313-T09-B 1
Sb SWA-L09-1313-T01-C 1
Sb SWA-L09-1313-T02-C 1
Sb SWA-L09-1313-T03-C 1
Sb SWA-L09-1313-T04-C 1
Sb SWA-L09-1313-T05-C 1
Sb SWA-L09-1313-T06-C 1
Sb SWA-L09-1313-T07-C 1
Sb SWA-L09-1313-T08-C 1
Sb SWA-L09-1313-T09-C 1
Sb SWA-L09-1313-B01-A 1
Sb SWA-L09-1313-B02-A 1
Sb SWA-L09-1313-B03-A 1
Sb SWA-L09-1313-B01-B 1
Sb SWA-L09-1313-B03-B 1
Sb SWA-L09-1313-B01-C 1
Sb SWA-L09-1313-B02-C 1
Sb SWA-L09-1313-B03-C 1
Sample
Cone. Qualifier
ug/L
5.11E+03
4.35E+03
8.12E+02
1.10E+03
1.00E+03
9.71 E+02
6.62E+02
4.33E+02
3.12E+04
5.11E+03
4.50E+03
9.37E+02
8.88E+02
9.27E+02
1.00E+03
6.31 E+02
5.75E+02
8.25E+02
5.20E+03
3.61 E+03
1.15E+03
1.15E+03
1.22E+03
7.99E+02
8.76E+02
6.06E+02
8.61 E+02
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.11 E+03 6.4E-01 7.5E+00 2.4E+01
4.35E+03 7.1E-01 7.5E+00 2.4E+01 10 100
8.12E+02 2.3E+00 7.5E+00 2.4E+01
1.10E+03 5.4E+00 7.5E+00 2.4E+01
1.00E+03 8.8E-01 7.5E+00 2.4E+01
9.71E+02 2.2E+00 7.5E+00 2.4E+01
6.62E+02 5.7E-01 7.5E+00 2.4E+01
4.33E+02 1.4E+00 7.5E+00 2.4E+01
3.12E+04 4.9E+00 7.5E+00 2.4E+01
5.11 E+03 4.8E-01 7.5E+00 2.4E+01
4.50E+03 8.9E-01 7.5E+00 2.4E+01 10 100
9.37E+02 9.4E-01 7.5E+00 2.4E+01
8.88E+02 1.8E-01 7.5E+00 2.4E+01
9.27E+02 1.5E+00 7.5E+00 2.4E+01
1.00E+03 8.5E-01 7.5E+00 2.4E+01
6.31 E+02 1.7E+00 7.5E+00 2.4E+01
5.75E+02 1.3E+00 7.5E+00 2.4E+01
8.25E+02 7.3E+00 7.5E+00 2.4E+01
5.20E+03 3.8E-01 7.5E+00 2.4E+01
3.61E+03 3.6E-01 7.5E+00 2.4E+01 10 100
1.15E+03 8.8E-01 7.5E+00 2.4E+01
1.15E+03 5.7E-01 7.5E+00 2.4E+01
1.22E+03 5.5E-01 7.5E+00 2.4E+01
7.99E+02 2.3E+00 7.5E+00 2.4E+01
8.76E+02 3.7E-01 7.5E+00 2.4E+01
6.06E+02 9.6E+00 7.5E+00 2.4E+01
8.61 E+02 1.1E+01 7.5E+00 2.4E+01
3.75E+00 1.1 E+02 7.5E+00 2.4E+01
3.75E+00 7.2E+01 7.5E+00 2.4E+01
3.75E+00 6.9E+01 7.5E+00 2.4E+01
3.75E+00 7.5E+01 7.5E+00 2.4E+01
3.75E+00 1.1 E+02 7.5E+00 2.4E+01
3.75E+00 2.3E+00 7.5E+00 2.4E+01
3.75E+00 5.0E+01 7.5E+00 2.4E+01
3.75E+00 6.5E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
5.42E+03 107% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
5.47E+03 97% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
4.56E+03 94% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-527
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-L09-1313-T01-A 1
As SWA-L09-1313-T02-A 1
As SWA-L09-1313-T03-A 1
As SWA-L09-1313-T04-A 1
As SWA-L09-1313-T05-A 1
As SWA-L09-1313-T06-A 1
As SWA-L09-1313-T07-A 1
As SWA-L09-1313-T08-A 1
As SWA-L09-1313-T09-A 1
As SWA-L09-1313-T01-B 1
As SWA-L09-1313-T02-B 1
As SWA-L09-1313-T03-B 1
As SWA-L09-1313-T04-B 1
As SWA-L09-1313-T05-B 1
As SWA-L09-1313-T06-B 1
As SWA-L09-1313-T07-B 1
As SWA-L09-1313-T08-B 1
As SWA-L09-1313-T09-B 1
As SWA-L09-1313-T01-C 1
As SWA-L09-1313-T02-C 1
As SWA-L09-1313-T03-C 1
As SWA-L09-1313-T04-C 1
As SWA-L09-1313-T05-C 1
As SWA-L09-1313-T06-C 1
As SWA-L09-1313-T07-C 1
As SWA-L09-1313-T08-C 1
As SWA-L09-1313-T09-C 1
As SWA-L09-1313-B01-A 1
As SWA-L09-1313-B02-A 1
As SWA-L09-1313-B03-A 1
As SWA-L09-1313-B01-B 1
As SWA-L09-1313-B03-B 1
As SWA-L09-1313-B01-C 1
As SWA-L09-1313-B02-C 1
As SWA-L09-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
7.81 E+03
4.08E+03
1.28E+02
1.29E+02
1.65E+02
1.68E+02
1.47E+02
1.71 E+03
1.67E+04
7.73E+03
3.89E+03
1.53E+02
3.21 E+02
1.63E+02
2.17E+02
8.17E+02
1.48E+03
5.07E+03
7.51 E+03
4.60E+03
1.18E+02
3.03E+02
3.29E+02
2.39E+02
2.65E+02
1.97E+03
4.53E+03
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.81 E+03 9.9E-01 1.1E+01 3.5E+01
4.08E+03 1.1E+00 1.1E+01 3.5E+01 10 100
1.28E+02 7.6E+00 1.1E+01 3.5E+01
1.29E+02 4.7E+00 1.1E+01 3.5E+01
1.65E+02 5.5E+00 1.1E+01 3.5E+01
1.68E+02 3.7E+00 1.1E+01 3.5E+01
1.47E+02 3.3E+00 1.1E+01 3.5E+01
1.71 E+03 6.3E-01 1.1E+01 3.5E+01
1.67E+04 5.3E+00 1.1E+01 3.5E+01
7.73E+03 5.3E-01 1.1E+01 3.5E+01
3.89E+03 6.6E-01 1.1E+01 3.5E+01 10 100
1.53E+02 1.4E+01 1.1E+01 3.5E+01
3.21 E+02 3.9E+00 1.1E+01 3.5E+01
1.63E+02 4.0E+00 1.1E+01 3.5E+01
2.17E+02 5.6E+00 1.1E+01 3.5E+01
8.17E+02 1.7E+00 1.1E+01 3.5E+01
1.48E+03 7.9E-01 1.1E+01 3.5E+01
5.07E+03 5.5E-01 1.1E+01 3.5E+01
7.51 E+03 6.9E-01 1.1E+01 3.5E+01
4.60E+03 2.0E-01 1.1E+01 3.5E+01 10 100
1.18E+02 6.4E+00 1.1E+01 3.5E+01
3.03E+02 2.5E+00 1.1E+01 3.5E+01
3.29E+02 4.8E+00 1.1E+01 3.5E+01
2.39E+02 9.3E-01 1.1E+01 3.5E+01
2.65E+02 5.7E+00 1.1E+01 3.5E+01
1.97E+03 4.8E-01 1.1E+01 3.5E+01
4.53E+03 4.6E-01 1.1E+01 3.5E+01
5.50E+00 5.1E+01 1.1E+01 3.5E+01
5.50E+00 5.6E+01 1.1E+01 3.5E+01
5.50E+00 4.6E+01 1.1E+01 3.5E+01
5.50E+00 2.4E+02 1.1E+01 3.5E+01
5.50E+00 1.1 E+02 1.1E+01 3.5E+01
5.50E+00 4.2E+01 1.1E+01 3.5E+01
5.50E+00 6.4E+01 1.1E+01 3.5E+01
5.50E+00 7.6E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
4.92E+03 84% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
4.78E+03 88% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
5.45E+03 85% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-528
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone.
1 ug/L
B SWA-L09-1313-T01-A 1 1.05E+03
B SWA-L09-1313-T02-A 1 8.38E+02
B SWA-L09-1313-T03-A 1 7.89E+02
B SWA-L09-1313-T04-A 1 1.17E+03
B SWA-L09-1313-T05-A 1 2.03E+03
B SWA-L09-1313-T06-A 1 2.43E+03
B SWA-L09-1313-T07-A 1 3.62E+03
B SWA-L09-1313-T08-A 1 3.58E+03
B SWA-L09-1313-T09-A 1 4.30E+03
B SWA-L09-1313-T01-B 1 9.89E+02
B SWA-L09-1313-T02-B 1 8.78E+02
B SWA-L09-1313-T03-B 1 8.87E+02
B SWA-L09-1313-T04-B 1 1.41E+03
B SWA-L09-1313-T05-B 1 2.09E+03
B SWA-L09-1313-T06-B 1 4.15E+03
B SWA-L09-1313-T07-B 1 4.39E+03
B SWA-L09-1313-T08-B 1 4.49E+03
B SWA-L09-1313-T09-B 1 4.68E+03
B SWA-L09-1313-T01-C 1 1.02E+03
B SWA-L09-1313-T02-C 1 9.87E+02
B SWA-L09-1313-T03-C 1 9.06E+02
B SWA-L09-1313-T04-C 1 1.48E+03
B SWA-L09-1313-T05-C 1 1.88E+03
B SWA-L09-1313-T06-C 1 3.98E+03
B SWA-L09-1313-T07-C 1 4.37E+03
B SWA-L09-1313-T08-C 1 4.68E+03
B SWA-L09-1313-T09-C 1 4.70E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.05E+03 1.3E+00 1.0E+00 3.2E+00
8.38E+02 1.4E+00 1.0E+00 3.2E+00 1000 100
7.89E+02 1.6E-01 1.0E+00 3.2E+00
1.17E+03 5.8E+00 1.0E+00 3.2E+00
2.03E+03 1.1E+00 1.0E+00 3.2E+00
2.43E+03 9.1E-01 1.0E+00 3.2E+00
3.62E+03 5.4E-01 1.0E+00 3.2E+00
3.58E+03 1.3E+00 1.0E+00 3.2E+00
4.30E+03 1.3E+00 1.0E+00 3.2E+00
9.89E+02 3.8E-01 1.0E+00 3.2E+00
8.78E+02 6.0E-01 1.0E+00 3.2E+00 1000 100
8.87E+02 1.4E-01 1.0E+00 3.2E+00
1.41E+03 7.3E-01 1.0E+00 3.2E+00
2.09E+03 4.2E-01 1.0E+00 3.2E+00
4.15E+03 4.0E-01 1.0E+00 3.2E+00
4.39E+03 5.4E-01 1.0E+00 3.2E+00
4.49E+03 8.8E-01 1.0E+00 3.2E+00
4.68E+03 6.1E-01 1.0E+00 3.2E+00
1.02E+03 6.2E-01 1.0E+00 3.2E+00
9.87E+02 3.5E-01 1.0E+00 3.2E+00 1000 100
9.06E+02 5.7E-01 1.0E+00 3.2E+00
1.48E+03 4.7E-01 1.0E+00 3.2E+00
1.88E+03 4.5E-01 1.0E+00 3.2E+00
3.98E+03 5.9E-01 1.0E+00 3.2E+00
4.37E+03 4.1E-01 1.0E+00 3.2E+00
4.68E+03 2.2E-01 1.0E+00 3.2E+00
4.70E+03 6.0E-01 1.0E+00 3.2E+00
B SWA-L09-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 7.4E+01 1.0E+00 3.2E+00
B SWA-L09-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 8.1E+01 1.0E+00 3.2E+00
B SWA-L09-1313-B03-A 1 5.00E-01 U1/2 5.00E-01 6.5E+01 1.0E+00 3.2E+00
B SWA-L09-1313-B01-B 1 5.00E-01 U1/2 5.00E-01 6.3E+01 1.0E+00 3.2E+00
B SWA-L09-1313-B03-B 1 5.00E-01 U1/2 5.00E-01 4.6E+01 1.0E+00 3.2E+00
B SWA-L09-1313-B01-C 1 5.00E-01 U1/2 5.00E-01 7.6E+02 1.0E+00 3.2E+00
B SWA-L09-1313-B02-C 1 5.00E-01 U1/2 5.00E-01 5.1E+01 1.0E+00 3.2E+00
B SWA-L09-1313-B03-C 1 5.00E-01 U1/2 5.00E-01 1 .4E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.86E+03 102% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.80E+03 92% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.97E+03 99% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-529
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone.
1 1 ug/L
Ba SWA-L09-1313-T01-A 1 2.64E+02
Ba SWA-L09-1313-T02-A 1 1.77E+02
Ba SWA-L09-1313-T03-A 1 9.20E+02
Ba SWA-L09-1313-T04-A 1 9.52E+02
Ba SWA-L09-1313-T05-A 1 1.07E+03
Ba SWA-L09-1313-T06-A 1 1.00E+03
Ba SWA-L09-1313-T07-A 1 1.64E+03
Ba SWA-L09-1313-T08-A 1 7.87E+02
Ba SWA-L09-1313-T09-A 1 8.18E+02
Ba SWA-L09-1313-T01-B 1 2.20E+02
Ba SWA-L09-1313-T02-B 1 1.70E+02
Ba SWA-L09-1313-T03-B 1 1.11E+03
Ba SWA-L09-1313-T04-B 1 9.99E+02
Ba SWA-L09-1313-T05-B 1 1.07E+03
Ba SWA-L09-1313-T06-B 1 1.54E+03
Ba SWA-L09-1313-T07-B 1 1.49E+03
Ba SWA-L09-1313-T08-B 1 7.64E+02
Ba SWA-L09-1313-T09-B 1 7.21E+02
Ba SWA-L09-1313-T01-C 1 2.57E+02
Ba SWA-L09-1313-T02-C 1 1.70E+02
Ba SWA-L09-1313-T03-C 1 1.05E+03
Ba SWA-L09-1313-T04-C 1 1.11E+03
Ba SWA-L09-1313-T05-C 1 1.27E+03
Ba SWA-L09-1313-T06-C 1 1.55E+03
Ba SWA-L09-1313-T07-C 1 1.73E+03
Ba SWA-L09-1313-T08-C 1 6.45E+02
Ba SWA-L09-1313-T09-C 1 7.10E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.64E+02 5.1E-01 1.0E+00 3.2E+00
1.77E+02 3.3E-01 1.0E+00 3.2E+00 10 100
9.20E+02 2.5E-01 1.0E+00 3.2E+00
9.52E+02 7.3E+00 1.0E+00 3.2E+00
1.07E+03 2.6E-01 1.0E+00 3.2E+00
1.00E+03 2.7E-01 1.0E+00 3.2E+00
1.64E+03 2.6E-01 1.0E+00 3.2E+00
7.87E+02 8.4E-01 1.0E+00 3.2E+00
8.18E+02 9.0E+00 1.0E+00 3.2E+00
2.20E+02 1.1E+00 1.0E+00 3.2E+00
1.70E+02 1.2E-01 1.0E+00 3.2E+00 10 100
1.11E+03 3.2E-01 1.0E+00 3.2E+00
9.99E+02 4.4E-01 1.0E+00 3.2E+00
1.07E+03 3.9E-01 1.0E+00 3.2E+00
1.54E+03 4.6E-01 1.0E+00 3.2E+00
1.49E+03 6.5E-01 1.0E+00 3.2E+00
7.64E+02 6.4E-01 1.0E+00 3.2E+00
7.21 E+02 3.3E-01 1.0E+00 3.2E+00
2.57E+02 1.6E+00 1.0E+00 3.2E+00
1.70E+02 2.6E-01 1.0E+00 3.2E+00 10 100
1.05E+03 3.6E-01 1.0E+00 3.2E+00
1.11E+03 6.6E-01 1.0E+00 3.2E+00
1.27E+03 1.7E-01 1.0E+00 3.2E+00
1.55E+03 1.2E+00 1.0E+00 3.2E+00
1.73E+03 3.0E-01 1.0E+00 3.2E+00
6.45E+02 6.6E-01 1.0E+00 3.2E+00
7.10E+02 5.1E-01 1.0E+00 3.2E+00
Ba SWA-L09-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 2.0E+02 1.0E+00 3.2E+00
Ba SWA-L09-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 7.5E+01 1.0E+00 3.2E+00
Ba SWA-L09-1313-B03-A 1 5.00E-01 U1/2 5.00E-01 3.3E+00 1.0E+00 3.2E+00
Ba SWA-L09-1313-B01-B 1 2.69E+00 E 2.69E+00 1.4E+00 1.0E+00 3.2E+00
Ba SWA-L09-1313-B03-B 1 5.00E-01 U1/2 5.00E-01 8.4E+01 1.0E+00 3.2E+00
Ba SWA-L09-1313-B01-C 1 5.00E-01 U1/2 5.00E-01 7.7E+01 1.0E+00 3.2E+00
Ba SWA-L09-1313-B02-C 1 5.00E-01 U1/2 5.00E-01 7.4E+00 1.0E+00 3.2E+00
Ba SWA-L09-1313-B03-C 1 5.00E-01 U1/2 5.00E-01 9.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.18E+03 100% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.15E+03 98% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.18E+03 101% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-530
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L09-1313-T01-A 1
Be SWA-L09-1313-T02-A 1
Be SWA-L09-1313-T03-A 1
Be SWA-L09-1313-T04-A 1
Be SWA-L09-1313-T05-A 1
Be SWA-L09-1313-T06-A 1
Be SWA-L09-1313-T07-A 1
Be SWA-L09-1313-T08-A 1
Be SWA-L09-1313-T09-A 1
Be SWA-L09-1313-T01-B 1
Be SWA-L09-1313-T02-B 1
Be SWA-L09-1313-T03-B 1
Be SWA-L09-1313-T04-B 1
Be SWA-L09-1313-T05-B 1
Be SWA-L09-1313-T06-B 1
Be SWA-L09-1313-T07-B 1
Be SWA-L09-1313-T08-B 1
Be SWA-L09-1313-T09-B 1
Be SWA-L09-1313-T01-C 1
Be SWA-L09-1313-T02-C 1
Be SWA-L09-1313-T03-C 1
Be SWA-L09-1313-T04-C 1
Be SWA-L09-1313-T05-C 1
Be SWA-L09-1313-T06-C 1
Be SWA-L09-1313-T07-C 1
Be SWA-L09-1313-T08-C 1
Be SWA-L09-1313-T09-C 1
Be SWA-L09-1313-B01-A 1
Be SWA-L09-1313-B02-A 1
Be SWA-L09-1313-B03-A 1
Be SWA-L09-1313-B01-B 1
Be SWA-L09-1313-B03-B 1
Be SWA-L09-1313-B01-C 1
Be SWA-L09-1313-B02-C 1
Be SWA-L09-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.76E+01
9.42E+01
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.69E+01
9.99E+01
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
5.55E+01
9.95E+01
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.2E+01 1.9E+00 6.0E+00
9.50E-01 3.5E+01 1.9E+00 6.0E+00 10 100
9.50E-01 8.9E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 9.1E+01 1.9E+00 6.0E+00
9.50E-01 3.4E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
1.76E+01 1.4E+00 1.9E+00 6.0E+00
9.42E+01 7.4E+00 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
9.50E-01 9.2E+01 1.9E+00 6.0E+00 10 100
9.50E-01 4.8E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 3.6E+01 1.9E+00 6.0E+00
9.50E-01 6.0E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
1.69E+01 5.3E+00 1.9E+00 6.0E+00
9.99E+01 8.3E-01 1.9E+00 6.0E+00
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.50E-01 6.3E+01 1.9E+00 6.0E+00 10 100
9.50E-01 7.2E+01 1.9E+00 6.0E+00
9.50E-01 7.5E+01 1.9E+00 6.0E+00
9.50E-01 6.3E+01 1.9E+00 6.0E+00
9.50E-01 3.1E+01 1.9E+00 6.0E+00
9.50E-01 6.8E+01 1.9E+00 6.0E+00
5.55E+01 9.9E-01 1.9E+00 6.0E+00
9.95E+01 9.0E-01 1.9E+00 6.0E+00
9.50E-01 4.4E+02 1.9E+00 6.0E+00
9.50E-01 3.1E+01 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 6.9E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 4.5E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
9.94E+02 99% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
9.62E+02 96% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
9.94E+02 99% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-531
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L09-1313-T01-A 1 1.10E+OOU1/2 1.10E+00 9.2E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T02-A 1 1.10E+OOU1/2 1.10E+00 1.7E+01 2.2E+00 7.0E+00 10 100
Cd SWA-L09-1313-T03-A 1 1.10E+OOU1/2 1.10E+00 4.7E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T04-A 1 1.10E+OOU1/2 1.10E+00 5.7E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T05-A 1 1.10E+OOU1/2 1.10E+00 1.8E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T06-A 1 1.10E+OOU1/2 1.10E+00 4.2E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T07-A 1 7.29E+00
Cd SWA-L09-1313-T08-A 1 9.86E+00
Cd SWA-L09-1313-T09-A 1 3.59E+01
7.29E+00 1.1E+01 2.2E+00 7.0E+00
9.86E+00 4.1E+00 2.2E+00 7.0E+00
3.59E+01 7.4E+00 2.2E+00 7.0E+00
Cd SWA-L09-1313-T01-B 1 1.10E+OOU1/2 1.10E+00 9.7E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T02-B 1 1.10E+OOU1/2 1.10E+00 7.0E+01 2.2E+00 7.0E+00 10 100
Cd SWA-L09-1313-T03-B 1 1.10E+OOU1/2 1.10E+00 6.1E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T04-B 1 1.10E+OOU1/2 1.10E+00 8.2E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T05-B 1 1.10E+OOU1/2 1.10E+00 4.3E+00 2.2E+00 7.0E+00
Cd SWA-L09-1313-T06-B 1 2.54E+00 E
Cd SWA-L09-1313-T07-B 1 7.98E+00
Cd SWA-L09-1313-T08-B 1 1.06E+01
Cd SWA-L09-1313-T09-B 1 2.54E+01
2.54E+00 1.9E+01 2.2E+00 7.0E+00
7.98E+00 8.8E-01 2.2E+00 7.0E+00
1.06E+01 3.8E-01 2.2E+00 7.0E+00
2.54E+01 3.9E-01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T01-C 1 1.10E+OOU1/2 1.10E+00 1.4E+02 2.2E+00 7.0E+00
Cd SWA-L09-1313-T02-C 1 1.10E+OOU1/2 1.10E+00 1.8E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L09-1313-T03-C 1 1.10E+OOU1/2 1.10E+00 5.9E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T04-C 1 1.10E+OOU1/2 1.10E+00 5.6E+00 2.2E+00 7.0E+00
Cd SWA-L09-1313-T05-C 1 1.10E+OOU1/2 1.10E+00 6.9E+01 2.2E+00 7.0E+00
Cd SWA-L09-1313-T06-C 1 2.77E+00 E
Cd SWA-L09-1313-T07-C 1 7.30E+00
Cd SWA-L09-1313-T08-C 1 1 J8E+01
Cd SWA-L09-1313-T09-C 1 2.44E+01
Cd SWA-L09-1313-B01-A 1 1.10E+OOU1/2
Cd SWA-L09-1313-B02-A 1 1.10E+OOU1/2
Cd SWA-L09-1313-B03-A 1 1.10E+OOU1/2
Cd SWA-L09-1313-B01-B 1 1.10E+OOU1/2
Cd SWA-L09-1313-B03-B 1 1.10E+OOU1/2
Cd SWA-L09-1313-B01-C 1 1.10E+OOU1/2
Cd SWA-L09-1313-B02-C 1 1.10E+OOU1/2
Cd SWA-L09-1313-B03-C 1 1.10E+OOU1/2
2.77E+00 8.8E+00 2.2E+00 7.0E+00
7.30E+00 5.5E+00 2.2E+00 7.0E+00
1.78E+01 5.1E-01 2.2E+00 7.0E+00
2.44E+01 6.7E-01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 7.0E+01 2.2E+00 7.0E+00
1.10E+00 7.4E+01 2.2E+00 7.0E+00
1.10E+00 9.8E+02 2.2E+00 7.0E+00
1.10E+00 2.7E+02 2.2E+00 7.0E+00
1.10E+00 9.1E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
8.95E+02 89% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
8.71E+02 87% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
8.88E+02 89% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-532
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca SWA-L09-1313-T01-A 1
Ca SWA-L09-1313-T02-A 1
Ca SWA-L09-1313-T03-A 1
Ca SWA-L09-1313-T04-A 1
Ca SWA-L09-1313-T05-A 1
Ca SWA-L09-1313-T06-A 1
Ca SWA-L09-1313-T07-A 1
Ca SWA-L09-1313-T08-A 1
Ca SWA-L09-1313-T09-A 1
Ca SWA-L09-1313-T01-B 1
Ca SWA-L09-1313-T02-B 1
Ca SWA-L09-1313-T03-B 1
Ca SWA-L09-1313-T04-B 1
Ca SWA-L09-1313-T05-B 1
Ca SWA-L09-1313-T06-B 1
Ca SWA-L09-1313-T07-B 1
Ca SWA-L09-1313-T08-B 1
Ca SWA-L09-1313-T09-B 1
Ca SWA-L09-1313-T01-C 1
Ca SWA-L09-1313-T02-C 1
Ca SWA-L09-1313-T03-C 1
Ca SWA-L09-1313-T04-C 1
Ca SWA-L09-1313-T05-C 1
Ca SWA-L09-1313-T06-C 1
Ca SWA-L09-1313-T07-C 1
Ca SWA-L09-1313-T08-C 1
Ca SWA-L09-1313-T09-C 1
Ca SWA-L09-1313-B01-A 1
Ca SWA-L09-1313-B02-A 1
Ca SWA-L09-1313-B03-A 1
Ca SWA-L09-1313-B01-B 1
Ca SWA-L09-1313-B03-B 1
Ca SWA-L09-1313-B01-C 1
Ca SWA-L09-1313-B02-C 1
Ca SWA-L09-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
7.97E+03
1.28E+04
1.66E+06
3.89E+06
6.05E+06
6.37E+06
8.39E+06
3.92E+06
3.04E+06
8.08E+03
1.31E+04
2.03E+06
4.69E+06
6.15E+06
7.92E+06
5.32E+06
4.34E+06
2.81 E+06
7.58E+03
1.26E+04
2.04E+06
4.90E+06
6.17E+06
7.43E+06
7.58E+06
3.38E+06
2.79E+06
2.65E+01
2.69E+01
2.99E+01
3.52E+01
2.75E+01
4.59E+01
2.99E+01
3.96E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.97E+03 9.3E-01 2.6E+00 8.3E+00
1.28E+04 7.3E-01 2.6E+00 8.3E+00 1000 100
1.66E+06 1.5E-01 2.6E+00 8.3E+00
3.89E+06 1.9E+00 2.6E+00 8.3E+00
6.05E+06 4.3E-01 2.6E+00 8.3E+00
6.37E+06 1.3E-01 2.6E+00 8.3E+00
8.39E+06 4.4E-01 2.6E+00 8.3E+00
3.92E+06 1.2E+00 2.6E+00 8.3E+00
3.04E+06 6.6E+00 2.6E+00 8.3E+00
8.08E+03 2.5E-01 2.6E+00 8.3E+00
1.31E+04 5.5E-01 2.6E+00 8.3E+00 1000 100
2.03E+06 3.3E-01 2.6E+00 8.3E+00
4.69E+06 5.5E-01 2.6E+00 8.3E+00
6.15E+06 5.3E-01 2.6E+00 8.3E+00
7.92E+06 8.0E-01 2.6E+00 8.3E+00
5.32E+06 1.0E+00 2.6E+00 8.3E+00
4.34E+06 7.8E-01 2.6E+00 8.3E+00
2.81 E+06 5.3E-01 2.6E+00 8.3E+00
7.58E+03 5.3E-01 2.6E+00 8.3E+00
1.26E+04 1.6E-01 2.6E+00 8.3E+00 1000 100
2.04E+06 7.4E-01 2.6E+00 8.3E+00
4.90E+06 8.8E-01 2.6E+00 8.3E+00
6.17E+06 9.1E-01 2.6E+00 8.3E+00
7.43E+06 3.4E-01 2.6E+00 8.3E+00
7.58E+06 7.4E-01 2.6E+00 8.3E+00
3.38E+06 6.4E-01 2.6E+00 8.3E+00
2.79E+06 5.4E-01 2.6E+00 8.3E+00
2.65E+01 1.7E+00 2.6E+00 8.3E+00
2.69E+01 1.6E+01 2.6E+00 8.3E+00
2.99E+01 9.6E+00 2.6E+00 8.3E+00
3.52E+01 1.7E+01 2.6E+00 8.3E+00
2.75E+01 1.2E+01 2.6E+00 8.3E+00
4.59E+01 1.3E+02 2.6E+00 8.3E+00
2.99E+01 1.6E+01 2.6E+00 8.3E+00
3.96E+01 8.6E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.40E+04 117% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.41E+04 95% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.35E+04 92% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-533
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone.
1 ug/L
Cr SWA-L09-1313-T01-A 1 1.35E+03
Cr SWA-L09-1313-T02-A 1 9.90E+02
Cr SWA-L09-1313-T03-A 1 1.07E+01
Cr SWA-L09-1313-T04-A 1 9.29E+00
Cr SWA-L09-1313-T05-A 1 7.08E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.35E+03 1.9E+00 1.2E+00 3.8E+00
9.90E+02 1.3E+00 1.2E+00 3.8E+00 10 100
1.07E+01 9.5E+00 1.2E+00 3.8E+00
9.29E+00 1.6E+01 1.2E+00 3.8E+00
7.08E+00 3.2E+00 1.2E+00 3.8E+00
Cr SWA-L09-1313-T06-A 1 1.69E+OOE 1.69E+00 7.3E+01 1.2E+00 3.8E+00
Cr SWA-L09-1313-T07-A 1 6.32E+00
Cr SWA-L09-1313-T08-A 1 1.74E+03
Cr SWA-L09-1313-T09-A 1 1.62E+04
Cr SWA-L09-1313-T01-B 1 1.34E+03
Cr SWA-L09-1313-T02-B 1 1.08E+03
Cr SWA-L09-1313-T03-B 1 1.08E+01
Cr SWA-L09-1313-T04-B 1 8.36E+00
Cr SWA-L09-1313-T05-B 1 6.04E+00
6.32E+00 2.8E+01 1.2E+00 3.8E+00
1.74E+03 1.1E+00 1.2E+00 3.8E+00
1.62E+04 8.1E+00 1.2E+00 3.8E+00
1.34E+03 2.1E+00 1.2E+00 3.8E+00
1.08E+03 1.5E+00 1.2E+00 3.8E+00 10 100
1.08E+01 2.0E+00 1.2E+00 3.8E+00
8.36E+00 1.7E+00 1.2E+00 3.8E+00
6.04E+00 5.4E+00 1.2E+00 3.8E+00
Cr SWA-L09-1313-T06-B 1 1.97E+OOE 1.97E+00 3.7E+00 1.2E+00 3.8E+00
Cr SWA-L09-1313-T07-B 1 8.21E+00
Cr SWA-L09-1313-T08-B 1 1.59E+03
Cr SWA-L09-1313-T09-B 1 1.36E+04
Cr SWA-L09-1313-T01-C 1 1.34E+03
Cr SWA-L09-1313-T02-C 1 1.16E+03
Cr SWA-L09-1313-T03-C 1 1.41E+01
Cr SWA-L09-1313-T04-C 1 9.92E+00
Cr SWA-L09-1313-T05-C 1 9.55E+00
8.21 E+00 4.1E-01 1.2E+00 3.8E+00
1.59E+03 7.3E-01 1.2E+00 3.8E+00
1.36E+04 4.4E-01 1.2E+00 3.8E+00
1.34E+03 8.4E-01 1.2E+00 3.8E+00
1.16E+03 7.2E-01 1.2E+00 3.8E+00 10 100
1.41E+01 3.0E+00 1.2E+00 3.8E+00
9.92E+00 2.0E+00 1.2E+00 3.8E+00
9.55E+00 2.7E+00 1.2E+00 3.8E+00
Cr SWA-L09-1313-T06-C 1 1.67E+OOE 1.67E+00 9.2E+00 1.2E+00 3.8E+00
Cr SWA-L09-1313-T07-C 1 8.38E+00
Cr SWA-L09-1313-T08-C 1 4.94E+03
Cr SWA-L09-1313-T09-C 1 1.32E+04
8.38E+00 1.1E+01 1.2E+00 3.8E+00
4.94E+03 1.5E-01 1.2E+00 3.8E+00
1.32E+04 5.0E-01 1.2E+00 3.8E+00
Cr SWA-L09-1313-B01-A 1 6.00E-01 U1/2 6.00E-01 1.2E+02 1.2E+00 3.8E+00
Cr SWA-L09-1313-B02-A 1 6.00E-01 U1/2 6.00E-01 1.5E+02 1.2E+00 3.8E+00
Cr SWA-L09-1313-B03-A 1 6.00E-01 U1/2 6.00E-01 2.7E+01 1.2E+00 3.8E+00
Cr SWA-L09-1313-B01-B 1 6.00E-01 U1/2 6.00E-01 7.2E+01 1.2E+00 3.8E+00
Cr SWA-L09-1313-B03-B 1 6.00E-01 U1/2 6.00E-01 2.9E+01 1.2E+00 3.8E+00
Cr SWA-L09-1313-B01-C 1 6.00E-01 U1/2 6.00E-01 1.6E+01 1.2E+00 3.8E+00
Cr SWA-L09-1313-B02-C 1 6.00E-01 U1/2 6.00E-01 5.3E+01 1.2E+00 3.8E+00
Cr SWA-L09-1313-B03-C 1 6.00E-01 U1/2 6.00E-01 1.4E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.89E+03 90% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:09 PM EPA Interlab L09 1313-1316 SWA
1.94E+03 86% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:31 PM EPA Interlab L09 1313-1316 SWA
2.04E+03 89% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-534
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co SWA-L09-1313-T01-A 1
Co SWA-L09-1313-T02-A 1
Co SWA-L09-1313-T03-A 1
Co SWA-L09-1313-T04-A 1
Co SWA-L09-1313-T05-A 1
Co SWA-L09-1313-T06-A 1
Co SWA-L09-1313-T07-A 1
Co SWA-L09-1313-T08-A 1
Co SWA-L09-1313-T09-A 1
Co SWA-L09-1313-T01-B 1
Co SWA-L09-1313-T02-B 1
Co SWA-L09-1313-T03-B 1
Co SWA-L09-1313-T04-B 1
Co SWA-L09-1313-T05-B 1
Co SWA-L09-1313-T06-B 1
Co SWA-L09-1313-T07-B 1
Co SWA-L09-1313-T08-B 1
Co SWA-L09-1313-T09-B 1
Co SWA-L09-1313-T01-C 1
Co SWA-L09-1313-T02-C 1
Co SWA-L09-1313-T03-C 1
Co SWA-L09-1313-T04-C 1
Co SWA-L09-1313-T05-C 1
Co SWA-L09-1313-T06-C 1
Co SWA-L09-1313-T07-C 1
Co SWA-L09-1313-T08-C 1
Co SWA-L09-1313-T09-C 1
Co SWA-L09-1313-B01-A 1
Co SWA-L09-1313-B02-A 1
Co SWA-L09-1313-B03-A 1
Co SWA-L09-1313-B01-B 1
Co SWA-L09-1313-B03-B 1
Co SWA-L09-1313-B01-C 1
Co SWA-L09-1313-B02-C 1
Co SWA-L09-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
2.94E+00 E
3.32E+00 E
5.47E+00 E
4.23E+00 E
9.72E+01
1.17E+02
2.04E+02
9.00E-01 U1/2
9.00E-01 U1/2
3.04E+00 E
3.22E+00 E
5.60E+00 E
1.17E+02
1.47E+02
1.28E+02
1.65E+02
9.00E-01 U1/2
9.00E-01 U1/2
3.54E+00 E
2.78E+00 E
4.72E+00 E
1.41E+02
1.47E+02
1.44E+02
1.64E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.7E+01 1.8E+00 5.7E+00
9.00E-01 2.6E+01 1.8E+00 5.7E+00 10 100
2.94E+00 7.9E+00 1.8E+00 5.7E+00
3.32E+00 5.2E+00 1.8E+00 5.7E+00
5.47E+00 8.5E+00 1.8E+00 5.7E+00
4.23E+00 3.8E+00 1.8E+00 5.7E+00
9.72E+01 2.2E+00 1.8E+00 5.7E+00
1.17E+02 1.4E+00 1.8E+00 5.7E+00
2.04E+02 1.5E+01 1.8E+00 5.7E+00
9.00E-01 5.8E+01 1.8E+00 5.7E+00
9.00E-01 3.9E+01 1.8E+00 5.7E+00 10 100
3.04E+00 5.1E+01 1.8E+00 5.7E+00
3.22E+00 4.8E+01 1.8E+00 5.7E+00
5.60E+00 4.8E+00 1.8E+00 5.7E+00
1.17E+02 2.4E+00 1.8E+00 5.7E+00
1.47E+02 1.3E+00 1.8E+00 5.7E+00
1.28E+02 2.6E-01 1.8E+00 5.7E+00
1.65E+02 7.3E-01 1.8E+00 5.7E+00
9.00E-01 2.1E+01 1.8E+00 5.7E+00
9.00E-01 2.5E+01 1.8E+00 5.7E+00 10 100
3.54E+00 4.8E+01 1.8E+00 5.7E+00
2.78E+00 3.4E+01 1.8E+00 5.7E+00
4.72E+00 4.7E+01 1.8E+00 5.7E+00
1.41E+02 1.2E+00 1.8E+00 5.7E+00
1.47E+02 2.7E-01 1.8E+00 5.7E+00
1.44E+02 5.4E-01 1.8E+00 5.7E+00
1.64E+02 4.6E-01 1.8E+00 5.7E+00
9.00E-01 3.7E+02 1.8E+00 5.7E+00
9.00E-01 9.4E+01 1.8E+00 5.7E+00
9.00E-01 7.5E+02 1.8E+00 5.7E+00
9.00E-01 4.4E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00
9.00E-01 2.9E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.01E+03 101% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
9.81E+02 98% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.01E+03 100% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-535
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cu SWA-L09-1313-T01-A 1 1.85E+OOU1/2 1.85E+00 9.8E+01 3.7E+00 1.2E+01
Cu SWA-L09-1313-T02-A 1 1.85E+OOU1/2 1.85E+00 2.0E+02 3.7E+00 1.2E+01 10 100
Cu SWA-L09-1313-T03-A 1 8.20E+00 E
Cu SWA-L09-1313-T04-A 1 9.22E+00 E
Cu SWA-L09-1313-T05-A 1 1.72E+01
Cu SWA-L09-1313-T06-A 1 1.69E+01
Cu SWA-L09-1313-T07-A 1 2.11E+01
Cu SWA-L09-1313-T08-A 1 3.04E+01
Cu SWA-L09-1313-T09-A 1 1.04E+03
8.20E+00 9.0E+00 3.7E+00 1.2E+01
9.22E+00 9.3E+00 3.7E+00 1.2E+01
1.72E+01 8.5E+00 3.7E+00 1.2E+01
1.69E+01 1.6E+01 3.7E+00 1.2E+01
2.11E+01 1.7E+01 3.7E+00 1.2E+01
3.04E+01 2.1E+00 3.7E+00 1.2E+01
1.04E+03 1.4E+01 3.7E+00 1.2E+01
Cu SWA-L09-1313-T01-B 1 1.85E+OOU1/2 1.85E+00 3.3E+01 3.7E+00 1.2E+01
Cu SWA-L09-1313-T02-B 1 1.85E+OOU1/2 1.85E+00 1.1E+01 3.7E+00 1.2E+01 10 100
Cu SWA-L09-1313-T03-B 1 7.51E+00 E
Cu SWA-L09-1313-T04-B 1 1.28E+01
Cu SWA-L09-1313-T05-B 1 1.37E+01
Cu SWA-L09-1313-T06-B 1 2.31E+01
Cu SWA-L09-1313-T07-B 1 2.24E+01
Cu SWA-L09-1313-T08-B 1 2.19E+01
Cu SWA-L09-1313-T09-B 1 1.06E+03
7.51 E+00 2.0E+00 3.7E+00 1.2E+01
1.28E+01 1.0E+01 3.7E+00 1.2E+01
1.37E+01 1.2E+01 3.7E+00 1.2E+01
2.31 E+01 6.1 E+00 3.7E+00 1.2E+01
2.24E+01 1.9E+00 3.7E+00 1.2E+01
2.19E+01 6.9E+00 3.7E+00 1.2E+01
1.06E+03 6.4E-01 3.7E+00 1.2E+01
Cu SWA-L09-1313-T01-C 1 1.85E+OOU1/2 1.85E+00 7.3E+01 3.7E+00 1.2E+01
Cu SWA-L09-1313-T02-C 1 1.85E+OOU1/2 1.85E+00 1.2E+02 3.7E+00 1.2E+01 10 100
Cu SWA-L09-1313-T03-C 1 7.74E+00 E
Cu SWA-L09-1313-T04-C 1 1.29E+01
Cu SWA-L09-1313-T05-C 1 1.27E+01
Cu SWA-L09-1313-T06-C 1 2.29E+01
Cu SWA-L09-1313-T07-C 1 3.27E+01
Cu SWA-L09-1313-T08-C 1 1.71E+02
Cu SWA-L09-1313-T09-C 1 1.08E+03
7.74E+00 2.9E+01 3.7E+00 1.2E+01
1.29E+01 6.8E+00 3.7E+00 1.2E+01
1.27E+01 2.1E+01 3.7E+00 1.2E+01
2.29E+01 3.9E+00 3.7E+00 1.2E+01
3.27E+01 8.0E+00 3.7E+00 1.2E+01
1.71E+02 6.5E-01 3.7E+00 1.2E+01
1.08E+03 7.0E-01 3.7E+00 1.2E+01
Cu SWA-L09-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 2.2E+02 3.7E+00 1.2E+01
Cu SWA-L09-1313-B02-A 1 1.85E+OOU1/2 1 .85E+00 1.0E+02 3.7E+00 1.2E+01
Cu SWA-L09-1313-B03-A 1 1.85E+OOU1/2 1 .85E+00 1.6E+01 3.7E+00 1.2E+01
Cu SWA-L09-1313-B01-B 1 1.85E+OOU1/2 1 .85E+00 3.0E+02 3.7E+00 1.2E+01
Cu SWA-L09-1313-B03-B 1 1.85E+OOU1/2 1 .85E+00 1.6E+02 3.7E+00 1.2E+01
Cu SWA-L09-1313-B01-C 1 1.85E+OOU1/2 1 .85E+00 5.8E+01 3.7E+00 1.2E+01
Cu SWA-L09-1313-B02-C 1 1.85E+OOU1/2 1 .85E+00 4.7E+01 3.7E+00 1.2E+01
Cu SWA-L09-1313-B03-C 1 1.85E+OOU1/2 1 .85E+00 4.4E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.04E+03 104% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.00E+03 100% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
9.84E+02 98% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-536
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone.
1 ug/L
Fe SWA-L09-1313-T01-A 1 9.01 E+01
Fe SWA-L09-1313-T02-A 1 7.81 E+01
Fe SWA-L09-1313-T03-A 1 1.13E+01
Fe SWA-L09-1313-T04-A 1 2.16E+01
Fe SWA-L09-1313-T05-A 1 3.35E+01
Fe SWA-L09-1313-T06-A 1 3.17E+01
Fe SWA-L09-1313-T07-A 1 5.47E+04
Fe SWA-L09-1313-T08-A 1 7.97E+04
Fe SWA-L09-1313-T09-A 1 1.59E+05
Fe SWA-L09-1313-T01-B 1 1.04E+02
Fe SWA-L09-1313-T02-B 1 8.24E+01
Fe SWA-L09-1313-T03-B 1 1.96E+01
Fe SWA-L09-1313-T04-B 1 2.65E+01
Fe SWA-L09-1313-T05-B 1 3.31 E+01
Fe SWA-L09-1313-T06-B 1 1.84E+04
Fe SWA-L09-1313-T07-B 1 6.48E+04
Fe SWA-L09-1313-T08-B 1 8.06E+04
Fe SWA-L09-1313-T09-B 1 1.12E+05
Fe SWA-L09-1313-T01-C 1 8.74E+01
Fe SWA-L09-1313-T02-C 1 9.42E+01
Fe SWA-L09-1313-T03-C 1 1.16E+01
Fe SWA-L09-1313-T04-C 1 2.28E+01
Fe SWA-L09-1313-T05-C 1 2.43E+01
Fe SWA-L09-1313-T06-C 1 1.70E+04
Fe SWA-L09-1313-T07-C 1 6.01 E+04
Fe SWA-L09-1313-T08-C 1 9.30E+04
Fe SWA-L09-1313-T09-C 1 1.07E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.01 E+01 1.5E+00 2.0E+00 6.4E+00
7.81E+01 1.9E+00 2.0E+00 6.4E+00 1000 100
1.13E+01 5.0E+00 2.0E+00 6.4E+00
2.16E+01 9.6E-01 2.0E+00 6.4E+00
3.35E+01 3.7E+00 2.0E+00 6.4E+00
3.17E+01 1.0E+01 2.0E+00 6.4E+00
5.47E+04 5.9E-01 2.0E+00 6.4E+00
7.97E+04 1.3E+00 2.0E+00 6.4E+00
1.59E+05 9.4E+00 2.0E+00 6.4E+00
1.04E+02 4.3E+00 2.0E+00 6.4E+00
8.24E+01 1.0E+00 2.0E+00 6.4E+00 1000 100
1.96E+01 2.9E+00 2.0E+00 6.4E+00
2.65E+01 7.1E-01 2.0E+00 6.4E+00
3.31E+01 2.7E+00 2.0E+00 6.4E+00
1.84E+04 7.0E-01 2.0E+00 6.4E+00
6.48E+04 5.6E-01 2.0E+00 6.4E+00
8.06E+04 6.9E-01 2.0E+00 6.4E+00
1.12E+05 4.2E+00 2.0E+00 6.4E+00
8.74E+01 1.4E+00 2.0E+00 6.4E+00
9.42E+01 5.4E-01 2.0E+00 6.4E+00 1000 100
1.16E+01 1.8E+00 2.0E+00 6.4E+00
2.28E+01 5.3E+00 2.0E+00 6.4E+00
2.43E+01 6.0E-01 2.0E+00 6.4E+00
1.70E+04 3.9E-01 2.0E+00 6.4E+00
6.01 E+04 4.5E-01 2.0E+00 6.4E+00
9.30E+04 3.0E-01 2.0E+00 6.4E+00
1.07E+05 2.3E+00 2.0E+00 6.4E+00
Fe SWA-L09-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 1 .4E+03 2.0E+00 6.4E+00
Fe SWA-L09-1313-B02-A 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00
Fe SWA-L09-1313-B03-A 1 1.00E+OOU1/2 1.00E+00 2.0E+01 2.0E+00 6.4E+00
Fe SWA-L09-1313-B01-B 1 4.34E+00 E 4.34E+00 3.2E-01 2.0E+00 6.4E+00
Fe SWA-L09-1313-B03-B 1 1.00E+OOU1/2 1.00E+00 8.9E+01 2.0E+00 6.4E+00
Fe SWA-L09-1313-B01-C 1 3.85E+00 E 3.85E+00 6.5E+01 2.0E+00 6.4E+00
Fe SWA-L09-1313-B02-C 1 2.83E+00 E 2.83E+00 5.6E+00 2.0E+00 6.4E+00
Fe SWA-L09-1313-B03-C 1 5.71E+00 E 5.71E+00 6.3E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.23E+03 116% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.14E+03 106% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.24E+03 114% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-537
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qu<
Pb SWA-L09-1313-T01-A 1 5.60E+01
Pb SWA-L09-1313-T02-A 1 1.61E+01 E
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.60E+01 7.8E+00 6.8E+00 2.2E+01
1.61E+01 1.9E+01 6.8E+00 2.2E+01 10 100
Pb SWA-L09-1313-T03-A 1 3.40E+00 U1/2 3.40E+00 8.0E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T04-A 1 3.40E+00 U1/2 3.40E+00 3.2E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T05-A 1 3.40E+00 U1/2 3.40E+00 6.2E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T06-A 1 3.40E+00 U1/2 3.40E+00 1 .4E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T07-A 1 3.40E+00 U1/2 3.40E+00 6.2E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T08-A 1 4.64E+01
Pb SWA-L09-1313-T09-A 1 2.86E+03
Pb SWA-L09-1313-T01-B 1 5.02E+01
Pb SWA-L09-1313-T02-B 1 1.68E+01 E
4.64E+01 1.1E+01 6.8E+00 2.2E+01
2.86E+03 4.9E+00 6.8E+00 2.2E+01
5.02E+01 1.0E+01 6.8E+00 2.2E+01
1.68E+01 3.2E+01 6.8E+00 2.2E+01 10 100
Pb SWA-L09-1313-T03-B 1 3.40E+00 U1/2 3.40E+00 8.4E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T04-B 1 3.40E+00 U1/2 3.40E+00 4.1E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T05-B 1 3.40E+00 U1/2 3.40E+00 7.5E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T06-B 1 3.40E+00 U1/2 3.40E+00 6.2E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T07-B 1 3.40E+00 U1/2 3.40E+00 4.1E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T08-B 1 3.24E+01
Pb SWA-L09-1313-T09-B 1 2.68E+03
Pb SWA-L09-1313-T01-C 1 5.20E+01
Pb SWA-L09-1313-T02-C 1 1.52E+01 E
3.24E+01 1.3E+01 6.8E+00 2.2E+01
2.68E+03 2.5E-01 6.8E+00 2.2E+01
5.20E+01 7.7E+02 6.8E+00 2.2E+01
1.52E+01 1.8E+01 6.8E+00 2.2E+01 10 100
Pb SWA-L09-1313-T03-C 1 3.40E+00 U1/2 3.40E+00 6.8E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T04-C 1 3.40E+00 U1/2 3.40E+00 5.0E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T05-C 1 3.40E+00 U1/2 3.40E+00 1.4E+02 6.8E+00 2.2E+01
Pb SWA-L09-1313-T06-C 1 3.40E+00 U1/2 3.40E+00 7.8E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T07-C 1 3.40E+00 U1/2 3.40E+00 9.2E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-T08-C 1 6.04E+02
Pb SWA-L09-1313-T09-C 1 2.57E+03
6.04E+02 3.2E-01 6.8E+00 2.2E+01
2.57E+03 8.1E-01 6.8E+00 2.2E+01
Pb SWA-L09-1313-B01-A 1 3.40E+00 U1/2 3.40E+00 7.4E+01 6.8E+00 2.2E+01
Pb SWA-L09-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 1.1E+02 6.8E+00 2.2E+01
Pb SWA-L09-1313-B03-A 1 3.40E+00 U1/2 3.40E+00 1.0E+02 6.8E+00 2.2E+01
Pb SWA-L09-1313-B01-B 1 3.40E+00 U1/2 3.40E+00 1.3E+02 6.8E+00 2.2E+01
Pb SWA-L09-1313-B03-B 1 3.40E+00 U1/2 3.40E+00 2.5E+02 6.8E+00 2.2E+01
Pb SWA-L09-1313-B01-C 1 3.40E+00 U1/2 3.40E+00 1.3E+02 6.8E+00 2.2E+01
Pb SWA-L09-1313-B02-C 1 3.40E+00 U1/2 3.40E+00 2.2E+02 6.8E+00 2.2E+01
Pb SWA-L09-1313-B03-C 1 3.40E+00 U1/2 3.40E+00 2.4E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.04E+03 102% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:09 PM EPA Interlab L09 1313-1316 SWA
1.01E+03 99% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:31 PM EPA Interlab L09 1313-1316 SWA
1.02E+03 101% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-538
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li SWA-L09-1313-T01-A 1
Li SWA-L09-1313-T02-A 1
Li SWA-L09-1313-T03-A 1
Li SWA-L09-1313-T04-A 1
Li SWA-L09-1313-T05-A 1
Li SWA-L09-1313-T06-A 1
Li SWA-L09-1313-T07-A 1
Li SWA-L09-1313-T08-A 1
Li SWA-L09-1313-T09-A 1
Li SWA-L09-1313-T01-B 1
Li SWA-L09-1313-T02-B 1
Li SWA-L09-1313-T03-B 1
Li SWA-L09-1313-T04-B 1
Li SWA-L09-1313-T05-B 1
Li SWA-L09-1313-T06-B 1
Li SWA-L09-1313-T07-B 1
Li SWA-L09-1313-T08-B 1
Li SWA-L09-1313-T09-B 1
Li SWA-L09-1313-T01-C 1
Li SWA-L09-1313-T02-C 1
Li SWA-L09-1313-T03-C 1
Li SWA-L09-1313-T04-C 1
Li SWA-L09-1313-T05-C 1
Li SWA-L09-1313-T06-C 1
Li SWA-L09-1313-T07-C 1
Li SWA-L09-1313-T08-C 1
Li SWA-L09-1313-T09-C 1
Li SWA-L09-1313-B01-A 1
Li SWA-L09-1313-B02-A 1
Li SWA-L09-1313-B03-A 1
Li SWA-L09-1313-B01-B 1
Li SWA-L09-1313-B03-B 1
Li SWA-L09-1313-B01-C 1
Li SWA-L09-1313-B02-C 1
Li SWA-L09-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.57E+01
3.95E+02
7.56E+02
8.13E+02
1.14E+03
5.82E+02
5.25E+02
9.50E-01 U1/2
9.50E-01 U1/2
1.31E+02
4.91 E+02
7.94E+02
1.09E+03
7.73E+02
6.22E+02
6.44E+02
9.50E-01 U1/2
9.50E-01 U1/2
1.15E+02
5.58E+02
7.87E+02
9.99E+02
1.01E+03
5.99E+02
6.27E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.92E+00 E
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.3E+01 1.9E+00 6.0E+00
9.50E-01 5.1E+01 1.9E+00 6.0E+00 10 100
9.57E+01 3.4E+00 1.9E+00 6.0E+00
3.95E+02 2.8E+00 1.9E+00 6.0E+00
7.56E+02 8.0E-01 1.9E+00 6.0E+00
8.13E+02 1.9E+00 1.9E+00 6.0E+00
1.14E+03 5.8E+00 1.9E+00 6.0E+00
5.82E+02 4.1E+00 1.9E+00 6.0E+00
5.25E+02 2.0E+01 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00
9.50E-01 3.7E+01 1.9E+00 6.0E+00 10 100
1.31 E+02 3.3E+00 1.9E+00 6.0E+00
4.91 E+02 6.0E+00 1.9E+00 6.0E+00
7.94E+02 1.4E+00 1.9E+00 6.0E+00
1.09E+03 1.7E+00 1.9E+00 6.0E+00
7.73E+02 7.0E+00 1.9E+00 6.0E+00
6.22E+02 3.5E+00 1.9E+00 6.0E+00
6.44E+02 4.7E+00 1.9E+00 6.0E+00
9.50E-01 6.7E+00 1.9E+00 6.0E+00
9.50E-01 4.2E+01 1.9E+00 6.0E+00 10 100
1.15E+02 3.2E+00 1.9E+00 6.0E+00
5.58E+02 2.3E+00 1.9E+00 6.0E+00
7.87E+02 8.5E-01 1.9E+00 6.0E+00
9.99E+02 4.1E+00 1.9E+00 6.0E+00
1.01E+03 2.7E+00 1.9E+00 6.0E+00
5.99E+02 1.7E+00 1.9E+00 6.0E+00
6.27E+02 2.3E+00 1.9E+00 6.0E+00
9.50E-01 4.5E+01 1.9E+00 6.0E+00
9.50E-01 5.3E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 7.0E+02 1.9E+00 6.0E+00
1.92E+00 3.5E+01 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 6.0E+01 1.9E+00 6.0E+00
9.50E-01 6.0E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
8.57E+02 86% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
8.41E+02 84% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
8.53E+02 85% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-539
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Mn SWA-L09-1313-T01-A 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-T02-A 1 1.00E+OOU1/2 1.00E+00 3.9E+00 2.0E+00 6.4E+00 10 100
Mn SWA-L09-1313-T03-A 1 1.00E+OOU1/2 1.00E+00 2.1E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-T04-A 1 2.85E+01
Mn SWA-L09-1313-T05-A 1 2.60E+03
Mn SWA-L09-1313-T06-A 1 6.23E+03
Mn SWA-L09-1313-T07-A 1 1.62E+04
Mn SWA-L09-1313-T08-A 1 1.18E+04
Mn SWA-L09-1313-T09-A 1 1.21E+04
2.85E+01 5.4E+00 2.0E+00 6.4E+00
2.60E+03 7.3E-01 2.0E+00 6.4E+00
6.23E+03 5.1E-01 2.0E+00 6.4E+00
1.62E+04 7.1E-01 2.0E+00 6.4E+00
1.18E+04 1.4E+00 2.0E+00 6.4E+00
1.21E+04 1.1E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-T01-B 1 1.00E+OOU1/2 1.00E+00 5.8E+00 2.0E+00 6.4E+00
Mn SWA-L09-1313-T02-B 1 1.00E+OOU1/2 1.00E+00 6.1E+00 2.0E+00 6.4E+00 10 100
Mn SWA-L09-1313-T03-B 1 1.00E+OOU1/2 1.00E+00 5.3E+00 2.0E+00 6.4E+00
Mn SWA-L09-1313-T04-B 1 3.05E+01
Mn SWA-L09-1313-T05-B 1 3.27E+03
Mn SWA-L09-1313-T06-B 1 1.67E+04
Mn SWA-L09-1313-T07-B 1 1.55E+04
Mn SWA-L09-1313-T08-B 1 1.33E+04
Mn SWA-L09-1313-T09-B 1 1.28E+04
3.05E+01 5.1E-01 2.0E+00 6.4E+00
3.27E+03 4.1E-01 2.0E+00 6.4E+00
1.67E+04 5.6E-01 2.0E+00 6.4E+00
1.55E+04 7.1E-01 2.0E+00 6.4E+00
1.33E+04 5.8E-01 2.0E+00 6.4E+00
1.28E+04 1.5E+00 2.0E+00 6.4E+00
Mn SWA-L09-1313-T01-C 1 1.00E+OOU1/2 1.00E+00 1.6E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-T02-C 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00 10 100
Mn SWA-L09-1313-T03-C 1 1.00E+OOU1/2 1.00E+00 1.6E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-T04-C 1 5.74E+01
Mn SWA-L09-1313-T05-C 1 5.42E+02
Mn SWA-L09-1313-T06-C 1 1.74E+04
Mn SWA-L09-1313-T07-C 1 1.79E+04
Mn SWA-L09-1313-T08-C 1 1.25E+04
Mn SWA-L09-1313-T09-C 1 1.28E+04
5.74E+01 5.6E-01 2.0E+00 6.4E+00
5.42E+02 8.2E-01 2.0E+00 6.4E+00
1.74E+04 3.7E-01 2.0E+00 6.4E+00
1.79E+04 4.1E-01 2.0E+00 6.4E+00
1.25E+04 8.0E-01 2.0E+00 6.4E+00
1.28E+04 1.0E+00 2.0E+00 6.4E+00
Mn SWA-L09-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 7.5E+02 2.0E+00 6.4E+00
Mn SWA-L09-1313-B02-A 1 1.00E+OOU1/2 1.00E+00 6.8E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-B03-A 1 1.00E+OOU1/2 1.00E+00 5.5E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-B01-B 1 1.00E+OOU1/2 1.00E+00 6.6E+00 2.0E+00 6.4E+00
Mn SWA-L09-1313-B03-B 1 1.00E+OOU1/2 1 .OOE+00 8.6E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-B01-C 1 1. OOE+00 U1/2 1 .OOE+00 9.8E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-B02-C 1 1.00E+OOU1/2 1 .OOE+00 1.4E+01 2.0E+00 6.4E+00
Mn SWA-L09-1313-B03-C 1 1.00E+OOU1/2 1 .OOE+00 1.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.00E+03 100% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
9.63E+02 96% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
9.93E+02 99% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-540
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qu
1 1 ug/L
Mg SWA-L09-1313-T01-A 1 1.26E+01
Mg SWA-L09-1313-T02-A 1 1.16E+01
Mg SWA-L09-1313-T03-A 1 9.79E+02
Mg SWA-L09-1313-T04-A 1 3.42E+05
Mg SWA-L09-1313-T05-A 1 9.15E+05
Mg SWA-L09-1313-T06-A 1 9.88E+05
Mg SWA-L09-1313-T07-A 1 1.42E+06
Mg SWA-L09-1313-T08-A 1 6.60E+05
Mg SWA-L09-1313-T09-A 1 5.53E+05
Mg SWA-L09-1313-T01-B 1 1.85E+01
Mg SWA-L09-1313-T02-B 1 2.01E+01
Mg SWA-L09-1313-T03-B 1 2.11E+03
Mg SWA-L09-1313-T04-B 1 5.18E+05
Mg SWA-L09-1313-T05-B 1 9.37E+05
Mg SWA-L09-1313-T06-B 1 1.38E+06
Mg SWA-L09-1313-T07-B 1 9.48E+05
Mg SWA-L09-1313-T08-B 1 7.80E+05
Mg SWA-L09-1313-T09-B 1 6.15E+05
Mg SWA-L09-1313-T01-C 1 1.37E+01
Mg SWA-L09-1313-T02-C 1 1.34E+01
Mg SWA-L09-1313-T03-C 1 4.24E+03
Mg SWA-L09-1313-T04-C 1 5.82E+05
Mg SWA-L09-1313-T05-C 1 8.50E+05
Mg SWA-L09-1313-T06-C 1 1.28E+06
Mg SWA-L09-1313-T07-C 1 1.31E+06
Mg SWA-L09-1313-T08-C 1 6.72E+05
Mg SWA-L09-1313-T09-C 1 6.12E+05
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.26E+01 6.4E+01 1.0E+00 3.2E+00
1.16E+01 1.2E+01 1.0E+00 3.2E+00 1000 100
9.79E+02 8.9E-01 1.0E+00 3.2E+00
3.42E+05 5.5E+00 1.0E+00 3.2E+00
9.15E+05 4.5E-01 1.0E+00 3.2E+00
9.88E+05 4.5E-01 1.0E+00 3.2E+00
1.42E+06 9.7E-01 1.0E+00 3.2E+00
6.60E+05 2.0E+00 1.0E+00 3.2E+00
5.53E+05 7.9E+00 1.0E+00 3.2E+00
1.85E+01 2.0E+01 1.0E+00 3.2E+00
2.01E+01 3.6E+01 1.0E+00 3.2E+00 1000 100
2.11E+03 9.7E-01 1.0E+00 3.2E+00
5.18E+05 5.6E-01 1.0E+00 3.2E+00
9.37E+05 1.8E-01 1.0E+00 3.2E+00
1.38E+06 7.4E-01 1.0E+00 3.2E+00
9.48E+05 6.9E-01 1.0E+00 3.2E+00
7.80E+05 1.4E+00 1.0E+00 3.2E+00
6.15E+05 3.4E-01 1.0E+00 3.2E+00
1.37E+01 4.6E+01 1.0E+00 3.2E+00
1.34E+01 4.9E+01 1.0E+00 3.2E+00 1000 100
4.24E+03 1.5E+00 1.0E+00 3.2E+00
5.82E+05 1.0E+00 1.0E+00 3.2E+00
8.50E+05 4.3E-01 1.0E+00 3.2E+00
1.28E+06 9.0E-01 1.0E+00 3.2E+00
1.31E+06 1.1E+00 1.0E+00 3.2E+00
6.72E+05 7.8E-02 1.0E+00 3.2E+00
6.12E+05 6.2E-01 1.0E+00 3.2E+00
Mg SWA-L09-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 6.1E+03 1.0E+00 3.2E+00
Mg SWA-L09-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 5.6E+01 1.0E+00 3.2E+00
Mg SWA-L09-1313-B03-A 1 5.00E-01 U1/2 5.00E-01 1.4E+02 1.0E+00 3.2E+00
Mg SWA-L09-1313-B01-B 1 1.37E+OOE
1.37E+00 7.1E+01 1.0E+00 3.2E+00
Mg SWA-L09-1313-B03-B 1 5.00E-01 U1/2 5.00E-01 3.2E+01 1.0E+00 3.2E+00
Mg SWA-L09-1313-B01-C 1 1.95E+OOE
1.95E+00 2.0E+02 1.0E+00 3.2E+00
Mg SWA-L09-1313-B02-C 1 5.00E-01 U1/2 5.00E-01 7.2E+01 1.0E+00 3.2E+00
Mg SWA-L09-1313-B03-C 1 1.43E+OOE
1.43E+00 5.8E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.09E+03 108% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.03E+03 101% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.10E+03 109% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-541
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qu
1 1 ug/L
Mo SWA-L09-1313-T01-A 1 1.11E+02
Mo SWA-L09-1313-T02-A 1 1.28E+02
Mo SWA-L09-1313-T03-A 1 1.27E+02
Mo SWA-L09-1313-T04-A 1 1.23E+02
Mo SWA-L09-1313-T05-A 1 1.13E+02
Mo SWA-L09-1313-T06-A 1 9.29E+01
Mo SWA-L09-1313-T07-A 1 2.70E+01
Mo SWA-L09-1313-T08-A 1 1.57E+01
Mo SWA-L09-1313-T09-A 1 4.18E+01
Mo SWA-L09-1313-T01-B 1 1.06E+02
Mo SWA-L09-1313-T02-B 1 1.22E+02
Mo SWA-L09-1313-T03-B 1 1.36E+02
Mo SWA-L09-1313-T04-B 1 1.27E+02
Mo SWA-L09-1313-T05-B 1 1.08E+02
Mo SWA-L09-1313-T06-B 1 2.44E+01
Mo SWA-L09-1313-T07-B 1 1.19E+01
Mo SWA-L09-1313-T08-B 1 1.30E+01
Mo SWA-L09-1313-T09-B 1 3.42E+00 E
Mo SWA-L09-1313-T01-C 1 1.25E+02
Mo SWA-L09-1313-T02-C 1 1.35E+02
Mo SWA-L09-1313-T03-C 1 1.12E+02
Mo SWA-L09-1313-T04-C 1 1.21E+02
Mo SWA-L09-1313-T05-C 1 1.23E+02
Mo SWA-L09-1313-T06-C 1 1.38E+01
Mo SWA-L09-1313-T07-C 1 1.10E+01
Mo SWA-L09-1313-T08-C 1 6.32E+00
Mo SWA-L09-1313-T09-C 1 5.04E+00
Mo SWA-L09-1313-B01-A 1 1.64E+OOE
Mo SWA-L09-1313-B02-A 1 1.24E+OOE
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.11E+02 1.6E+00 1.2E+00 3.8E+00
1.28E+02 9.5E-01 1.2E+00 3.8E+00 10 100
1.27E+02 1.4E+00 1.2E+00 3.8E+00
1.23E+02 6.7E+00 1.2E+00 3.8E+00
1.13E+02 1.0E+00 1.2E+00 3.8E+00
9.29E+01 1.5E+00 1.2E+00 3.8E+00
2.70E+01 8.9E+00 1.2E+00 3.8E+00
1.57E+01 5.8E+00 1.2E+00 3.8E+00
4.18E+01 1.4E+01 1.2E+00 3.8E+00
1.06E+02 1.0E+00 1.2E+00 3.8E+00
1.22E+02 2.0E+00 1.2E+00 3.8E+00 10 100
1.36E+02 1.6E+00 1.2E+00 3.8E+00
1.27E+02 1.5E+00 1.2E+00 3.8E+00
1.08E+02 2.4E+00 1.2E+00 3.8E+00
2.44E+01 2.7E+00 1.2E+00 3.8E+00
1.19E+01 4.0E+00 1.2E+00 3.8E+00
1.30E+01 3.9E+00 1.2E+00 3.8E+00
3.42E+00 5.2E+01 1.2E+00 3.8E+00
1.25E+02 7.5E-01 1.2E+00 3.8E+00
1.35E+02 4.5E-01 1.2E+00 3.8E+00 10 100
1.12E+02 2.0E+00 1.2E+00 3.8E+00
1.21E+02 9.2E-01 1.2E+00 3.8E+00
1.23E+02 4.7E-01 1.2E+00 3.8E+00
1.38E+01 5.1E+00 1.2E+00 3.8E+00
1.10E+01 9.1E+00 1.2E+00 3.8E+00
6.32E+00 6.2E+00 1.2E+00 3.8E+00
5.04E+00 8.8E+00 1.2E+00 3.8E+00
1.64E+00 6.5E+01 1.2E+00 3.8E+00
1.24E+00 9.5E+01 1.2E+00 3.8E+00
Mo SWA-L09-1313-B03-A 1 6.00E-01 U1/2 6.00E-01 6.1E+02 1.2E+00 3.8E+00
Mo SWA-L09-1313-B01-B 1 6.00E-01 U1/2 6.00E-01 1.4E+02 1.2E+00 3.8E+00
Mo SWA-L09-1313-B03-B 1 6.00E-01 U1/2 6.00E-01 3.4E+03 1.2E+00 3.8E+00
Mo SWA-L09-1313-B01-C 1 2.67E+00 E
Mo SWA-L09-1313-B02-C 1 1.74E+OOE
Mo SWA-L09-1313-B03-C 1 3.13E+00 E
2.67E+00 5.0E+01 1.2E+00 3.8E+00
1.74E+00 4.8E+01 1.2E+00 3.8E+00
3.13E+00 4.5E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.18E+03 105% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.15E+03 102% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.17E+03 104% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-542
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L09-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 9.3E+01 1.8E+00 5.7E+00
Ni SWA-L09-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 1.1 E+02 1.8E+00 5.7E+00 10 100
Ni SWA-L09-1313-T03-A 1 3.56E+00 E
Ni SWA-L09-1313-T04-A 1 6.74E+00
Ni SWA-L09-1313-T05-A 1 2.20E+01
Ni SWA-L09-1313-T06-A 1 5.97E+01
Ni SWA-L09-1313-T07-A 1 2.38E+02
Ni SWA-L09-1313-T08-A 1 2.21E+02
Ni SWA-L09-1313-T09-A 1 2.65E+02
3.56E+00 4.3E+01 1.8E+00 5.7E+00
6.74E+00 4.1E+01 1.8E+00 5.7E+00
2.20E+01 5.1E+00 1.8E+00 5.7E+00
5.97E+01 1.4E+00 1.8E+00 5.7E+00
2.38E+02 1.6E+00 1.8E+00 5.7E+00
2.21 E+02 2.4E+00 1.8E+00 5.7E+00
2.65E+02 3.7E+00 1.8E+00 5.7E+00
Ni SWA-L09-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 2.5E+01 1.8E+00 5.7E+00
Ni SWA-L09-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 3.8E+01 1.8E+00 5.7E+00 10 100
Ni SWA-L09-1313-T03-B 1 3.45E+00 E
Ni SWA-L09-1313-T04-B 1 9.12E+00
Ni SWA-L09-1313-T05-B 1 2.34E+01
Ni SWA-L09-1313-T06-B 1 2.89E+02
Ni SWA-L09-1313-T07-B 1 2.99E+02
Ni SWA-L09-1313-T08-B 1 2.59E+02
Ni SWA-L09-1313-T09-B 1 2.73E+02
3.45E+00 5.7E+01 1.8E+00 5.7E+00
9.12E+00 2.4E+01 1.8E+00 5.7E+00
2.34E+01 8.9E+00 1.8E+00 5.7E+00
2.89E+02 1.1E+00 1.8E+00 5.7E+00
2.99E+02 1.1E+00 1.8E+00 5.7E+00
2.59E+02 1.1E+00 1.8E+00 5.7E+00
2.73E+02 4.9E-01 1.8E+00 5.7E+00
Ni SWA-L09-1313-T01-C 1 9.00E-01 U1/2 9.00E-01 1.0E+02 1.8E+00 5.7E+00
Ni SWA-L09-1313-T02-C 1 9.00E-01 U1/2 9.00E-01 3.8E+01 1.8E+00 5.7E+00 10 100
Ni SWA-L09-1313-T03-C 1 3.16E+00 E
Ni SWA-L09-1313-T04-C 1 9.85E+00
Ni SWA-L09-1313-T05-C 1 1.68E+01
Ni SWA-L09-1313-T06-C 1 3.17E+02
Ni SWA-L09-1313-T07-C 1 3.28E+02
Ni SWA-L09-1313-T08-C 1 2.60E+02
Ni SWA-L09-1313-T09-C 1 2.72E+02
3.16E+00 3.3E+01 1.8E+00 5.7E+00
9.85E+00 6.4E+00 1.8E+00 5.7E+00
1.68E+01 3.4E+00 1.8E+00 5.7E+00
3.17E+02 2.6E-01 1.8E+00 5.7E+00
3.28E+02 3.2E-01 1.8E+00 5.7E+00
2.60E+02 4.2E-01 1.8E+00 5.7E+00
2.72E+02 3.7E-01 1.8E+00 5.7E+00
Ni SWA-L09-1313-B01-A 1 9.00E-01 U1/2 9.00E-01 1.1E+02 1.8E+00 5.7E+00
Ni SWA-L09-1313-B02-A 1 9.00E-01 U1/2 9.00E-01 7.9E+00 1.8E+00 5.7E+00
Ni SWA-L09-1313-B03-A 1 9.00E-01 U1/2 9.00E-01 6.2E+01 1.8E+00 5.7E+00
Ni SWA-L09-1313-B01-B 1 9.00E-01 U1/2 9.00E-01 6.5E+01 1.8E+00 5.7E+00
Ni SWA-L09-1313-B03-B 1 9.00E-01 U1/2 9.00E-01 6.2E+01 1.8E+00 5.7E+00
Ni SWA-L09-1313-B01-C 1 9.00E-01 U1/2 9.00E-01 1.4E+03 1.8E+00 5.7E+00
Ni SWA-L09-1313-B02-C 1 9.00E-01 U1/2 9.00E-01 2.1E+01 1.8E+00 5.7E+00
Ni SWA-L09-1313-B03-C 1 9.00E-01 U1/2 9.00E-01 6.9E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
9.34E+02 93% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
9.07E+02 91% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
9.25E+02 92% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-543
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone.
1 ug/L
P SWA-L09-1313-T01-A 1 9.09E+01
P SWA-L09-1313-T02-A 1 3.49E+01
P SWA-L09-1313-T03-A 1 1.83E+01
P SWA-L09-1313-T04-A 1 3.51 E+01
P SWA-L09-1313-T05-A 1 4.33E+01
P SWA-L09-1313-T06-A 1 3.63E+01
P SWA-L09-1313-T07-A 1 2.32E+01
P SWA-L09-1313-T08-A 1 4.58E+02
P SWA-L09-1313-T09-A 1 2.52E+04
P SWA-L09-1313-T01-B 1 1.09E+02
P SWA-L09-1313-T02-B 1 4.35E+01
P SWA-L09-1313-T03-B 1 1.45E+01
P SWA-L09-1313-T04-B 1 3.69E+01
P SWA-L09-1313-T05-B 1 3.70E+01
P SWA-L09-1313-T06-B 1 2.98E+01
P SWA-L09-1313-T07-B 1 2.39E+01
P SWA-L09-1313-T08-B 1 4.34E+02
P SWA-L09-1313-T09-B 1 8.67E+02
P SWA-L09-1313-T01-C 1 8.57E+01
P SWA-L09-1313-T02-C 1 3.94E+01
P SWA-L09-1313-T03-C 1 1.67E+01
P SWA-L09-1313-T04-C 1 4.47E+01
P SWA-L09-1313-T05-C 1 5.87E+01
P SWA-L09-1313-T06-C 1 2.81E+01
P SWA-L09-1313-T07-C 1 3.31 E+01
P SWA-L09-1313-T08-C 1 5.14E+02
P SWA-L09-1313-T09-C 1 8.52E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.09E+01 2.3E+00 3.7E+00 1.2E+01
3.49E+01 9.2E+00 3.7E+00 1.2E+01 1000 100
1.83E+01 6.5E+01 3.7E+00 1.2E+01
3.51E+01 7.0E+01 3.7E+00 1.2E+01
4.33E+01 1.9E+01 3.7E+00 1.2E+01
3.63E+01 4.4E+01 3.7E+00 1.2E+01
2.32E+01 7.9E+01 3.7E+00 1.2E+01
4.58E+02 1.4E+00 3.7E+00 1.2E+01
2.52E+04 2.4E+00 3.7E+00 1.2E+01
1.09E+02 3.9E+00 3.7E+00 1.2E+01
4.35E+01 2.0E+01 3.7E+00 1.2E+01 1000 100
1.45E+01 7.3E+01 3.7E+00 1.2E+01
3.69E+01 5.0E+01 3.7E+00 1.2E+01
3.70E+01 3.6E+01 3.7E+00 1.2E+01
2.98E+01 1.7E+01 3.7E+00 1.2E+01
2.39E+01 4.1E+00 3.7E+00 1.2E+01
4.34E+02 5.7E-01 3.7E+00 1.2E+01
8.67E+02 1.5E+00 3.7E+00 1.2E+01
8.57E+01 4.3E+00 3.7E+00 1.2E+01
3.94E+01 3.2E+01 3.7E+00 1.2E+01 1000 100
1.67E+01 4.8E+01 3.7E+00 1.2E+01
4.47E+01 2.3E+01 3.7E+00 1.2E+01
5.87E+01 1.1 E+01 3.7E+00 1.2E+01
2.81E+01 8.8E+01 3.7E+00 1.2E+01
3.31E+01 5.9E+01 3.7E+00 1.2E+01
5.14E+02 3.2E+00 3.7E+00 1.2E+01
8.52E+02 4.5E-01 3.7E+00 1.2E+01
P SWA-L09-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 3.5E+03 3.7E+00 1.2E+01
P SWA-L09-1313-B02-A 1 1.85E+OOU1/2 1.85E+00 9.1E+01 3.7E+00 1.2E+01
P SWA-L09-1313-B03-A 1 6.46E+00 E 6.46E+00 5.2E+01 3.7E+00 1.2E+01
P SWA-L09-1313-B01-B 1 6.95E+00 E 6.95E+00 3.0E+01 3.7E+00 1.2E+01
P SWA-L09-1313-B03-B 1 1.85E+OOU1/2 1.85E+00 9.8E+01 3.7E+00 1.2E+01
P SWA-L09-1313-B01-C 1 6.09E+00 E 6.09E+00 3.2E+01 3.7E+00 1.2E+01
P SWA-L09-1313-B02-C 1 9.49E+00 E 9.49E+00 7.3E+01 3.7E+00 1.2E+01
P SWA-L09-1313-B03-C 1 8.09E+00 E 8.09E+00 4.8E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
8.65E+02 83% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
9.04E+02 86% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
8.93E+02 85% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-544
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone. Qu
1 1 ug/L
K SWA-L09-1313-T01-A 1 2.07E+06
K SWA-L09-1313-T02-A 1 2.64E+05
K SWA-L09-1313-T03-A 1 3.39E+05
K SWA-L09-1313-T04-A 1 3.71 E+05
K SWA-L09-1313-T05-A 1 3.81 E+05
K SWA-L09-1313-T06-A 1 3.91 E+05
K SWA-L09-1313-T07-A 1 4.27E+05
K SWA-L09-1313-T08-A 1 1.94E+05
K SWA-L09-1313-T09-A 1 2.13E+05
K SWA-L09-1313-T01-B 1 2.07E+06
K SWA-L09-1313-T02-B 1 2.56E+05
K SWA-L09-1313-T03-B 1 3.69E+05
K SWA-L09-1313-T04-B 1 3.60E+05
K SWA-L09-1313-T05-B 1 3.90E+05
K SWA-L09-1313-T06-B 1 4.08E+05
K SWA-L09-1313-T07-B 1 3.00E+05
K SWA-L09-1313-T08-B 1 2.14E+05
K SWA-L09-1313-T09-B 1 2.33E+05
K SWA-L09-1313-T01-C 1 2.11E+06
K SWA-L09-1313-T02-C 1 2.73E+05
K SWA-L09-1313-T03-C 1 3.43E+05
K SWA-L09-1313-T04-C 1 3.72E+05
K SWA-L09-1313-T05-C 1 3.85E+05
K SWA-L09-1313-T06-C 1 3.91 E+05
K SWA-L09-1313-T07-C 1 4.00E+05
K SWA-L09-1313-T08-C 1 1.86E+05
K SWA-L09-1313-T09-C 1 2.22E+05
K SWA-L09-1313-B01-A 1 1.97E+01
K SWA-L09-1313-B02-A 1 2.45E+01
K SWA-L09-1313-B03-A 1 2.51E+01
K SWA-L09-1313-B01-B 1 1.81E+01
K SWA-L09-1313-B03-B 1 3.38E+01
K SWA-L09-1313-B01-C 1 2.01E+06
K SWA-L09-1313-B02-C 1 1.98E+06
K SWA-L09-1313-B03-C 1 2.06E+06
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.07E+06 8.4E-01 1.6E+00 5.1E+00
2.64E+05 1.0E+00 1.6E+00 5.1E+00 1000 100
3.39E+05 4.9E-01 1.6E+00 5.1E+00
3.71E+05 6.2E+00 1.6E+00 5.1E+00
3.81E+05 1.3E+00 1.6E+00 5.1E+00
3.91E+05 3.1E+00 1.6E+00 5.1E+00
4.27E+05 9.9E-01 1.6E+00 5.1E+00
1.94E+05 2.9E+00 1.6E+00 5.1E+00
2.13E+05 4.4E+01 1.6E+00 5.1E+00
2.07E+06 9.8E-01 1.6E+00 5.1E+00
2.56E+05 1.2E+00 1.6E+00 5.1E+00 1000 100
3.69E+05 2.2E+00 1.6E+00 5.1E+00
3.60E+05 2.5E-01 1.6E+00 5.1E+00
3.90E+05 2.8E+00 1.6E+00 5.1E+00
4.08E+05 1.5E-01 1.6E+00 5.1E+00
3.00E+05 1.3E+01 1.6E+00 5.1E+00
2.14E+05 1.8E+00 1.6E+00 5.1E+00
2.33E+05 1.4E+01 1.6E+00 5.1E+00
2.11E+06 2.0E-01 1.6E+00 5.1E+00
2.73E+05 6.3E-01 1.6E+00 5.1E+00 1000 100
3.43E+05 3.8E-01 1.6E+00 5.1E+00
3.72E+05 6.3E-01 1.6E+00 5.1E+00
3.85E+05 3.9E-01 1.6E+00 5.1E+00
3.91E+05 3.8E-01 1.6E+00 5.1E+00
4.00E+05 4.6E+00 1.6E+00 5.1E+00
1.86E+05 7.7E+00 1.6E+00 5.1E+00
2.22E+05 3.5E+00 1.6E+00 5.1E+00
1.97E+01 3.2E+01 1.6E+00 5.1E+00
2.45E+01 1.4E+01 1.6E+00 5.1E+00
2.51E+01 6.1E+00 1.6E+00 5.1E+00
1.81E+01 1.1E+00 1.6E+00 5.1E+00
3.38E+01 5.6E+01 1.6E+00 5.1E+00
2.01 E+06 1.8E+00 1.6E+00 5.1E+00
1.98E+06 2.0E-01 1.6E+00 5.1E+00
2.06E+06 1.1E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
2.65E+05 101% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
2.57E+05 89% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
2.74E+05 104% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-545
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se SWA-L09-1313-T01-A 1
Se SWA-L09-1313-T02-A 1
Se SWA-L09-1313-T03-A 1
Se SWA-L09-1313-T04-A 1
Se SWA-L09-1313-T05-A 1
Se SWA-L09-1313-T06-A 1
Se SWA-L09-1313-T07-A 1
Se SWA-L09-1313-T08-A 1
Se SWA-L09-1313-T09-A 1
Se SWA-L09-1313-T01-B 1
Se SWA-L09-1313-T02-B 1
Se SWA-L09-1313-T03-B 1
Se SWA-L09-1313-T04-B 1
Se SWA-L09-1313-T05-B 1
Se SWA-L09-1313-T06-B 1
Se SWA-L09-1313-T07-B 1
Se SWA-L09-1313-T08-B 1
Se SWA-L09-1313-T09-B 1
Se SWA-L09-1313-T01-C 1
Se SWA-L09-1313-T02-C 1
Se SWA-L09-1313-T03-C 1
Se SWA-L09-1313-T04-C 1
Se SWA-L09-1313-T05-C 1
Se SWA-L09-1313-T06-C 1
Se SWA-L09-1313-T07-C 1
Se SWA-L09-1313-T08-C 1
Se SWA-L09-1313-T09-C 1
Se SWA-L09-1313-B01-A 1
Se SWA-L09-1313-B02-A 1
Se SWA-L09-1313-B03-A 1
Se SWA-L09-1313-B01-B 1
Se SWA-L09-1313-B03-B 1
Se SWA-L09-1313-B01-C 1
Se SWA-L09-1313-B02-C 1
Se SWA-L09-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
6.77E+04
7.55E+04
7.96E+04
8.72E+04
9.36E+04
9.55E+04
1.04E+05
4.26E+04
2.36E+04
6.45E+04
7.21 E+04
8.56E+04
8.85E+04
9.33E+04
9.87E+04
9.72E+04
4.50E+04
2.67E+04
7.82E+04
8.24E+04
7.57E+04
9.19E+04
1.01E+05
9.00E+04
9.23E+04
3.34E+04
2.66E+04
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
2.01E+01 E
7.50E+00 U1/2
1.91E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.77E+04 6.9E-01 1.5E+01 4.8E+01
7.55E+04 1.1E+00 1.5E+01 4.8E+01 10 100
7.96E+04 1.1E-01 1.5E+01 4.8E+01
8.72E+04 5.8E+00 1.5E+01 4.8E+01
9.36E+04 5.2E-01 1.5E+01 4.8E+01
9.55E+04 2.8E-01 1.5E+01 4.8E+01
1.04E+05 4.4E-01 1.5E+01 4.8E+01
4.26E+04 1.4E+00 1.5E+01 4.8E+01
2.36E+04 7.8E+00 1.5E+01 4.8E+01
6.45E+04 5.6E-01 1.5E+01 4.8E+01
7.21E+04 6.5E-01 1.5E+01 4.8E+01 10 100
8.56E+04 1.8E-02 1.5E+01 4.8E+01
8.85E+04 4.1E-01 1.5E+01 4.8E+01
9.33E+04 5.8E-01 1.5E+01 4.8E+01
9.87E+04 5.4E-01 1.5E+01 4.8E+01
9.72E+04 5.9E-01 1.5E+01 4.8E+01
4.50E+04 1.1E+00 1.5E+01 4.8E+01
2.67E+04 4.0E-01 1.5E+01 4.8E+01
7.82E+04 6.0E-01 1.5E+01 4.8E+01
8.24E+04 2.6E-01 1.5E+01 4.8E+01 10 100
7.57E+04 5.0E-01 1.5E+01 4.8E+01
9.19E+04 2.6E-01 1.5E+01 4.8E+01
1.01E+05 9.4E-02 1.5E+01 4.8E+01
9.00E+04 2.4E-01 1.5E+01 4.8E+01
9.23E+04 1.3E-01 1.5E+01 4.8E+01
3.34E+04 5.7E-01 1.5E+01 4.8E+01
2.66E+04 3.3E-01 1.5E+01 4.8E+01
7.50E+00 4.9E+01 1.5E+01 4.8E+01
7.50E+00 1.5E+02 1.5E+01 4.8E+01
7.50E+00 4.6E+02 1.5E+01 4.8E+01
7.50E+00 8.3E+01 1.5E+01 4.8E+01
7.50E+00 2.1E+02 1.5E+01 4.8E+01
2.01 E+01 3.5E+01 1.5E+01 4.8E+01
7.50E+00 1.8E+02 1.5E+01 4.8E+01
1.91 E+01 3.9E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
7.66E+04 105% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
7.32E+04 109% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
8.35E+04 115% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-546
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-L09-1313-T01-A 1
Si SWA-L09-1313-T02-A 1
Si SWA-L09-1313-T03-A 1
Si SWA-L09-1313-T04-A 1
Si SWA-L09-1313-T05-A 1
Si SWA-L09-1313-T06-A 1
Si SWA-L09-1313-T07-A 1
Si SWA-L09-1313-T08-A 1
Si SWA-L09-1313-T09-A 1
Si SWA-L09-1313-T01-B 1
Si SWA-L09-1313-T02-B 1
Si SWA-L09-1313-T03-B 1
Si SWA-L09-1313-T04-B 1
Si SWA-L09-1313-T05-B 1
Si SWA-L09-1313-T06-B 1
Si SWA-L09-1313-T07-B 1
Si SWA-L09-1313-T08-B 1
Si SWA-L09-1313-T09-B 1
Si SWA-L09-1313-T01-C 1
Si SWA-L09-1313-T02-C 1
Si SWA-L09-1313-T03-C 1
Si SWA-L09-1313-T04-C 1
Si SWA-L09-1313-T05-C 1
Si SWA-L09-1313-T06-C 1
Si SWA-L09-1313-T07-C 1
Si SWA-L09-1313-T08-C 1
Si SWA-L09-1313-T09-C 1
Si SWA-L09-1313-B01-A 1
Si SWA-L09-1313-B02-A 1
Si SWA-L09-1313-B03-A 1
Si SWA-L09-1313-B01-B 1
Si SWA-L09-1313-B03-B 1
Si SWA-L09-1313-B01-C 1
Si SWA-L09-1313-B02-C 1
Si SWA-L09-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
3.47E+04
2.48E+04
6.19E+03
4.22E+03
3.76E+03
4.82E+03
8.27E+03
1.17E+04
7.82E+05
3.96E+04
2.32E+04
6.31 E+03
3.53E+03
3.97E+03
9.18E+03
1.59E+04
1.84E+04
2.27E+04
3.50E+04
2.61 E+04
6.48E+03
4.98E+03
4.91 E+03
8.75E+03
1.13E+04
1.48E+04
1.85E+04
5.50E-01 U1/2
5.50E-01 U1/2
2.45E+00 E
5.20E+00
5.50E-01 U1/2
1.26E+03
2.92E+01
1.76E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.47E+04 7.0E-01 1.1E+00 3.5E+00
2.48E+04 9.7E-01 1.1E+00 3.5E+00 1000 100
6.19E+03 3.9E-01 1.1E+00 3.5E+00
4.22E+03 6.0E+00 1.1E+00 3.5E+00
3.76E+03 6.6E-01 1.1E+00 3.5E+00
4.82E+03 3.1E-01 1.1E+00 3.5E+00
8.27E+03 4.2E-01 1.1E+00 3.5E+00
1.17E+04 9.2E-01 1.1E+00 3.5E+00
7.82E+05 7.6E+00 1.1E+00 3.5E+00
3.96E+04 6.1E-01 1.1E+00 3.5E+00
2.32E+04 8.8E-01 1.1E+00 3.5E+00 1000 100
6.31 E+03 2.7E-01 1.1E+00 3.5E+00
3.53E+03 3.0E-01 1.1E+00 3.5E+00
3.97E+03 7.2E-01 1.1E+00 3.5E+00
9.18E+03 5.4E-01 1.1E+00 3.5E+00
1.59E+04 6.4E-01 1.1E+00 3.5E+00
1.84E+04 1.7E-01 1.1E+00 3.5E+00
2.27E+04 5.6E-01 1.1E+00 3.5E+00
3.50E+04 4.9E-01 1.1E+00 3.5E+00
2.61E+04 2.6E-01 1.1E+00 3.5E+00 1000 100
6.48E+03 5.0E-01 1.1E+00 3.5E+00
4.98E+03 5.1E-01 1.1E+00 3.5E+00
4.91 E+03 2.8E-01 1.1E+00 3.5E+00
8.75E+03 4.9E-01 1.1E+00 3.5E+00
1.13E+04 7.5E-01 1.1E+00 3.5E+00
1.48E+04 1.6E-01 1.1E+00 3.5E+00
1.85E+04 7.1E-01 1.1E+00 3.5E+00
5.50E-01 6.1E+01 1.1E+00 3.5E+00
5.50E-01 2.0E+01 1.1E+00 3.5E+00
2.45E+00 1.0E+02 1.1E+00 3.5E+00
5.20E+00 3.1E+00 1.1E+00 3.5E+00
5.50E-01 5.9E+01 1.1E+00 3.5E+00
1.26E+03 7.9E+00 1.1E+00 3.5E+00
2.92E+01 1.4E+01 1.1E+00 3.5E+00
1.76E+02 1.3E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
2.57E+04 85% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
2.40E+04 82% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
2.70E+04 91% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-547
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qu
Na SWA-L09-1313-T01-A 1 4.73E+05
Na SWA-L09-1313-T02-A 1 4.80E+05
Na SWA-L09-1313-T03-A 1 5.10E+05
Na SWA-L09-1313-T04-A 1 5.00E+05
Na SWA-L09-1313-T05-A 1 4.88E+05
Na SWA-L09-1313-T06-A 1 4.89E+05
Na SWA-L09-1313-T07-A 1 4.82E+05
Na SWA-L09-1313-T08-A 1 4.83E+05
Na SWA-L09-1313-T09-A 1 4.36E+05
Na SWA-L09-1313-T01-B 1 4.63E+05
Na SWA-L09-1313-T02-B 1 4.69E+05
Na SWA-L09-1313-T03-B 1 5.15E+05
Na SWA-L09-1313-T04-B 1 4.83E+05
Na SWA-L09-1313-T05-B 1 4.84E+05
Na SWA-L09-1313-T06-B 1 4.82E+05
Na SWA-L09-1313-T07-B 1 4.73E+05
Na SWA-L09-1313-T08-B 1 4.77E+05
Na SWA-L09-1313-T09-B 1 4.81 E+05
Na SWA-L09-1313-T01-C 1 4.65E+05
Na SWA-L09-1313-T02-C 1 4.78E+05
Na SWA-L09-1313-T03-C 1 5.01 E+05
Na SWA-L09-1313-T04-C 1 4.93E+05
Na SWA-L09-1313-T05-C 1 4.93E+05
Na SWA-L09-1313-T06-C 1 4.79E+05
Na SWA-L09-1313-T07-C 1 4.78E+05
Na SWA-L09-1313-T08-C 1 4.78E+05
Na SWA-L09-1313-T09-C 1 4.83E+05
Na SWA-L09-1313-B01-A 1 7.34E+01
Na SWA-L09-1313-B02-A 1 8.09E+01
Na SWA-L09-1313-B03-A 1 1.28E+01
Na SWA-L09-1313-B01-B 1 7.09E+01
Na SWA-L09-1313-B03-B 1 5.71 E+01
Na SWA-L09-1313-B01-C 1 1.42E+03
Na SWA-L09-1313-B02-C 1 6.11E+02
Na SWA-L09-1313-B03-C 1 1.34E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.73E+05 5.5E-01 2.5E+00 8.0E+00
4.80E+05 3.7E-01 2.5E+00 8.0E+00 1000 100
5.10E+05 1.0E-01 2.5E+00 8.0E+00
5.00E+05 7.3E-01 2.5E+00 8.0E+00
4.88E+05 3.0E-01 2.5E+00 8.0E+00
4.89E+05 4.8E-01 2.5E+00 8.0E+00
4.82E+05 2.6E-01 2.5E+00 8.0E+00
4.83E+05 7.2E-01 2.5E+00 8.0E+00
4.36E+05 6.2E+00 2.5E+00 8.0E+00
4.63E+05 1.6E-01 2.5E+00 8.0E+00
4.69E+05 6.0E-01 2.5E+00 8.0E+00 1000 100
5.15E+05 7.4E-02 2.5E+00 8.0E+00
4.83E+05 4.1E-01 2.5E+00 8.0E+00
4.84E+05 4.9E-01 2.5E+00 8.0E+00
4.82E+05 5.7E-01 2.5E+00 8.0E+00
4.73E+05 7.8E-01 2.5E+00 8.0E+00
4.77E+05 4.3E-01 2.5E+00 8.0E+00
4.81 E+05 3.0E-01 2.5E+00 8.0E+00
4.65E+05 3.7E-02 2.5E+00 8.0E+00
4.78E+05 4.2E-01 2.5E+00 8.0E+00 1000 100
5.01 E+05 7.3E-01 2.5E+00 8.0E+00
4.93E+05 2.4E-01 2.5E+00 8.0E+00
4.93E+05 6.8E-01 2.5E+00 8.0E+00
4.79E+05 3.8E-01 2.5E+00 8.0E+00
4.78E+05 5.2E-01 2.5E+00 8.0E+00
4.78E+05 1.5E-01 2.5E+00 8.0E+00
4.83E+05 1.7E-01 2.5E+00 8.0E+00
7.34E+01 4.5E+01 2.5E+00 8.0E+00
8.09E+01 2.6E+00 2.5E+00 8.0E+00
1.28E+01 8.5E+00 2.5E+00 8.0E+00
7.09E+01 2.1E+00 2.5E+00 8.0E+00
5.71 E+01 4.5E+01 2.5E+00 8.0E+00
1.42E+03 8.8E-01 2.5E+00 8.0E+00
6.11E+02 3.2E-01 2.5E+00 8.0E+00
1.34E+03 1.2E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
4.81E+05 85% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
4.70E+05 88% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
4.79E+05 87% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-548
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone.
1 ug/L
SWA-L09-1313-T01-A 1 2.99E+02
SWA-L09-1313-T02-A 1 3.06E+02
SWA-L09-1313-T03-A 1 1.19E+04
SWA-L09-1313-T04-A 1 2.29E+04
SWA-L09-1313-T05-A 1 3.19E+04
SWA-L09-1313-T06-A 1 3.50E+04
SWA-L09-1313-T07-A 1 4.53E+04
SWA-L09-1313-T08-A 1 2.16E+04
SWA-L09-1313-T09-A 1 1.70E+04
SWA-L09-1313-T01-B 1 2.80E+02
SWA-L09-1313-T02-B 1 3.04E+02
SWA-L09-1313-T03-B 1 1.45E+04
SWA-L09-1313-T04-B 1 2.60E+04
SWA-L09-1313-T05-B 1 3.28E+04
SWA-L09-1313-T06-B 1 4.35E+04
SWA-L09-1313-T07-B 1 3.00E+04
SWA-L09-1313-T08-B 1 2.41E+04
SWA-L09-1313-T09-B 1 1.85E+04
SWA-L09-1313-T01-C 1 2.64E+02
SWA-L09-1313-T02-C 1 3.05E+02
SWA-L09-1313-T03-C 1 1.36E+04
SWA-L09-1313-T04-C 1 2.68E+04
SWA-L09-1313-T05-C 1 3.25E+04
SWA-L09-1313-T06-C 1 4.25E+04
SWA-L09-1313-T07-C 1 4.26E+04
SWA-L09-1313-T08-C 1 2.00E+04
SWA-L09-1313-T09-C 1 1.83E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.99E+02 9.5E-01 1.0E+00 3.2E+00
3.06E+02 7.4E-01 1.0E+00 3.2E+00 1000 100
1.19E+04 5.3E-01 1.0E+00 3.2E+00
2.29E+04 1.1E+01 1.0E+00 3.2E+00
3.19E+04 1.5E+00 1.0E+00 3.2E+00
3.50E+04 1.1E+00 1.0E+00 3.2E+00
4.53E+04 9.3E-01 1.0E+00 3.2E+00
2.16E+04 1.9E+00 1.0E+00 3.2E+00
1.70E+04 1.1E+01 1.0E+00 3.2E+00
2.80E+02 3.3E-01 1.0E+00 3.2E+00
3.04E+02 5.5E-01 1.0E+00 3.2E+00 1000 100
1.45E+04 7.6E-01 1.0E+00 3.2E+00
2.60E+04 4.6E-01 1.0E+00 3.2E+00
3.28E+04 7.3E-01 1.0E+00 3.2E+00
4.35E+04 2.1E-01 1.0E+00 3.2E+00
3.00E+04 8.8E-01 1.0E+00 3.2E+00
2.41 E+04 8.2E-01 1.0E+00 3.2E+00
1.85E+04 9.0E-01 1.0E+00 3.2E+00
2.64E+02 9.9E-01 1.0E+00 3.2E+00
3.05E+02 3.9E-01 1.0E+00 3.2E+00 1000 100
1.36E+04 1.2E+00 1.0E+00 3.2E+00
2.68E+04 9.2E-01 1.0E+00 3.2E+00
3.25E+04 1.4E+00 1.0E+00 3.2E+00
4.25E+04 1.7E+00 1.0E+00 3.2E+00
4.26E+04 1.7E+00 1.0E+00 3.2E+00
2.00E+04 4.5E-01 1.0E+00 3.2E+00
1.83E+04 7.3E-01 1.0E+00 3.2E+00
SWA-L09-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 6.2E+03 1.0E+00 3.2E+00
SWA-L09-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 6.1E+01 1.0E+00 3.2E+00
SWA-L09-1313-B03-A 1 5.00E-01 U1/2 5.00E-01 2.2E+01 1.0E+00 3.2E+00
SWA-L09-1313-B01-B 1 2.75E+00 E 2.75E+00 2.5E+01 1.0E+00 3.2E+00
SWA-L09-1313-B03-B 1 5.00E-01 U1/2 5.00E-01 1 .9E+02 1.0E+00 3.2E+00
SWA-L09-1313-B01-C 1 1.86E+OOE 1.86E+00 7.9E+01 1.0E+00 3.2E+00
SWA-L09-1313-B02-C 1 1.22E+OOE 1.22E+00 2.9E+01 1.0E+00 3.2E+00
SWA-L09-1313-B03-C 1 5.00E-01 U1/2 5.00E-01 6.0E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.34E+03 104% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.30E+03 99% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.34E+03 103% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-549
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
1 ug/L
S SWA-L09-1313-T01-A 1 2.80E+05
S SWA-L09-1313-T02-A 1 3.87E+05
S SWA-L09-1313-T03-A 1 2.99E+05
S SWA-L09-1313-T04-A 1 3.06E+05
S SWA-L09-1313-T05-A 1 3.53E+05
S SWA-L09-1313-T06-A 1 3.10E+05
S SWA-L09-1313-T07-A 1 3.69E+05
S SWA-L09-1313-T08-A 1 1.45E+05
S SWA-L09-1313-T09-A 1 8.18E+04
S SWA-L09-1313-T01-B 1 2.69E+05
S SWA-L09-1313-T02-B 1 3.39E+05
S SWA-L09-1313-T03-B 1 3.12E+05
S SWA-L09-1313-T04-B 1 2.68E+05
S SWA-L09-1313-T05-B 1 3.08E+05
S SWA-L09-1313-T06-B 1 3.18E+05
S SWA-L09-1313-T07-B 1 2.98E+05
S SWA-L09-1313-T08-B 1 1.57E+05
S SWA-L09-1313-T09-B 1 9.65E+04
S SWA-L09-1313-T01-C 1 3.16E+05
S SWA-L09-1313-T02-C 1 3.63E+05
S SWA-L09-1313-T03-C 1 3.18E+05
S SWA-L09-1313-T04-C 1 3.60E+05
S SWA-L09-1313-T05-C 1 3.40E+05
S SWA-L09-1313-T06-C 1 3.32E+05
S SWA-L09-1313-T07-C 1 3.11E+05
S SWA-L09-1313-T08-C 1 1.20E+05
S SWA-L09-1313-T09-C 1 1.01E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.80E+05 1.2E+00 6.8E+00 2.2E+01
3.87E+05 6.5E-01 6.8E+00 2.2E+01 1000 100
2.99E+05 2.7E-01 6.8E+00 2.2E+01
3.06E+05 4.8E+00 6.8E+00 2.2E+01
3.53E+05 2.8E-01 6.8E+00 2.2E+01
3.10E+05 6.6E-02 6.8E+00 2.2E+01
3.69E+05 6.9E-01 6.8E+00 2.2E+01
1.45E+05 1.6E+00 6.8E+00 2.2E+01
8.18E+04 5.0E+00 6.8E+00 2.2E+01
2.69E+05 2.8E-01 6.8E+00 2.2E+01
3.39E+05 3.9E-01 6.8E+00 2.2E+01 1000 100
3.12E+05 2.0E-01 6.8E+00 2.2E+01
2.68E+05 4.3E-01 6.8E+00 2.2E+01
3.08E+05 4.8E-01 6.8E+00 2.2E+01
3.18E+05 8.4E-02 6.8E+00 2.2E+01
2.98E+05 5.7E-01 6.8E+00 2.2E+01
1.57E+05 8.4E-01 6.8E+00 2.2E+01
9.65E+04 5.7E-01 6.8E+00 2.2E+01
3.16E+05 7.7E-01 6.8E+00 2.2E+01
3.63E+05 3.2E-01 6.8E+00 2.2E+01 1000 100
3.18E+05 5.3E-01 6.8E+00 2.2E+01
3.60E+05 1.4E-01 6.8E+00 2.2E+01
3.40E+05 2.1E-01 6.8E+00 2.2E+01
3.32E+05 9.3E-02 6.8E+00 2.2E+01
3.11E+05 4.2E-01 6.8E+00 2.2E+01
1.20E+05 6.1E-01 6.8E+00 2.2E+01
1.01E+05 5.4E-01 6.8E+00 2.2E+01
S SWA-L09-1313-B01-A 1 2.11E+01 E 2.11E+01 7.1E+00 6.8E+00 2.2E+01
S SWA-L09-1313-B02-A 1 3.48E+01
3.48E+01 7.0E+00 6.8E+00 2.2E+01
S SWA-L09-1313-B03-A 1 3.40E+00 U1/2 3.40E+00 2.7E+00 6.8E+00 2.2E+01
S SWA-L09-1313-B01-B 1 2.24E+01
S SWA-L09-1313-B03-B 1 2.24E+01
S SWA-L09-1313-B01-C 1 5.30E+01
S SWA-L09-1313-B02-C 1 7.32E+01
S SWA-L09-1313-B03-C 1 4.46E+01
2.24E+01 7.0E+00 6.8E+00 2.2E+01
2.24E+01 1.1E+01 6.8E+00 2.2E+01
5.30E+01 4.2E+01 6.8E+00 2.2E+01
7.32E+01 7.1E+00 6.8E+00 2.2E+01
4.46E+01 4.6E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
3.88E+05 84% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
3.40E+05 82% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
3.64E+05 90% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-550
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl SWA-L09-1313-T01-A 1
Tl SWA-L09-1313-T02-A 1
Tl SWA-L09-1313-T03-A 1
Tl SWA-L09-1313-T04-A 1
Tl SWA-L09-1313-T05-A 1
Tl SWA-L09-1313-T06-A 1
Tl SWA-L09-1313-T07-A 1
Tl SWA-L09-1313-T08-A 1
Tl SWA-L09-1313-T09-A 1
Tl SWA-L09-1313-T01-B 1
Tl SWA-L09-1313-T02-B 1
Tl SWA-L09-1313-T03-B 1
Tl SWA-L09-1313-T04-B 1
Tl SWA-L09-1313-T05-B 1
Tl SWA-L09-1313-T06-B 1
Tl SWA-L09-1313-T07-B 1
Tl SWA-L09-1313-T08-B 1
Tl SWA-L09-1313-T09-B 1
Tl SWA-L09-1313-T01-C 1
Tl SWA-L09-1313-T02-C 1
Tl SWA-L09-1313-T03-C 1
Tl SWA-L09-1313-T04-C 1
Tl SWA-L09-1313-T05-C 1
Tl SWA-L09-1313-T06-C 1
Tl SWA-L09-1313-T07-C 1
Tl SWA-L09-1313-T08-C 1
Tl SWA-L09-1313-T09-C 1
Tl SWA-L09-1313-B01-A 1
Tl SWA-L09-1313-B02-A 1
Tl SWA-L09-1313-B03-A 1
Tl SWA-L09-1313-B01-B 1
Tl SWA-L09-1313-B03-B 1
Tl SWA-L09-1313-B01-C 1
Tl SWA-L09-1313-B02-C 1
Tl SWA-L09-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
1.13E+01 E
9.81 E+00 E
1.26E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
1.72E+01
1.75E+01
1.14E+01 E
1.38E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
1.58E+01
2.17E+01
1.04E+01 E
1.28E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 3.7E+03 4.6E+00 1.5E+01
2.30E+00 6.2E+01 4.6E+00 1.5E+01 10 100
2.30E+00 9.0E+01 4.6E+00 1.5E+01
2.30E+00 3.9E+01 4.6E+00 1.5E+01
2.30E+00 9.0E+01 4.6E+00 1.5E+01
2.30E+00 1.2E+02 4.6E+00 1.5E+01
1.13E+01 3.4E+01 4.6E+00 1 .5E+01
9.81 E+00 3.4E+01 4.6E+00 1 .5E+01
1.26E+01 5.4E+01 4.6E+00 1 .5E+01
2.30E+00 5.9E+03 4.6E+00 1.5E+01
2.30E+00 8.7E+01 4.6E+00 1.5E+01 10 100
2.30E+00 5.8E+01 4.6E+00 1.5E+01
2.30E+00 1.4E+02 4.6E+00 1.5E+01
2.30E+00 2.0E+02 4.6E+00 1.5E+01
1.72E+01 1.9E+01 4.6E+00 1 .5E+01
1.75E+01 8.1E+01 4.6E+00 1 .5E+01
1.14E+01 2.0E+01 4.6E+00 1 .5E+01
1.38E+01 5.3E+01 4.6E+00 1 .5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 6.2E+02 4.6E+00 1.5E+01 10 100
2.30E+00 2.7E+02 4.6E+00 1.5E+01
2.30E+00 4.1E+02 4.6E+00 1.5E+01
2.30E+00 3.1E+01 4.6E+00 1.5E+01
1.58E+01 2.8E+01 4.6E+00 1 .5E+01
2.17E+01 4.1E+01 4.6E+00 1 .5E+01
1.04E+01 1.6E+02 4.6E+00 1 .5E+01
1.28E+01 1.2E+01 4.6E+00 1 .5E+01
2.30E+00 8.7E+01 4.6E+00 1.5E+01
2.30E+00 6.5E+01 4.6E+00 1.5E+01
2.30E+00 5.0E+01 4.6E+00 1.5E+01
2.30E+00 4.4E+01 4.6E+00 1.5E+01
2.30E+00 1.6E+01 4.6E+00 1.5E+01
2.30E+00 1.2E+02 4.6E+00 1.5E+01
2.30E+00 1.4E+04 4.6E+00 1.5E+01
2.30E+00 5.7E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
8.86E+02 88% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
8.59E+02 86% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
8.81E+02 88% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-551
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti SWA-L09-1313-T01-A 1
Ti SWA-L09-1313-T02-A 1
Ti SWA-L09-1313-T03-A 1
Ti SWA-L09-1313-T04-A 1
Ti SWA-L09-1313-T05-A 1
Ti SWA-L09-1313-T06-A 1
Ti SWA-L09-1313-T07-A 1
Ti SWA-L09-1313-T08-A 1
Ti SWA-L09-1313-T09-A 1
Ti SWA-L09-1313-T01-B 1
Ti SWA-L09-1313-T02-B 1
Ti SWA-L09-1313-T03-B 1
Ti SWA-L09-1313-T04-B 1
Ti SWA-L09-1313-T05-B 1
Ti SWA-L09-1313-T06-B 1
Ti SWA-L09-1313-T07-B 1
Ti SWA-L09-1313-T08-B 1
Ti SWA-L09-1313-T09-B 1
Ti SWA-L09-1313-T01-C 1
Ti SWA-L09-1313-T02-C 1
Ti SWA-L09-1313-T03-C 1
Ti SWA-L09-1313-T04-C 1
Ti SWA-L09-1313-T05-C 1
Ti SWA-L09-1313-T06-C 1
Ti SWA-L09-1313-T07-C 1
Ti SWA-L09-1313-T08-C 1
Ti SWA-L09-1313-T09-C 1
Ti SWA-L09-1313-B01-A 1
Ti SWA-L09-1313-B02-A 1
Ti SWA-L09-1313-B03-A 1
Ti SWA-L09-1313-B01-B 1
Ti SWA-L09-1313-B03-B 1
Ti SWA-L09-1313-B01-C 1
Ti SWA-L09-1313-B02-C 1
Ti SWA-L09-1313-B03-C 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.77E+01
4.25E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
5.87E+01
1.87E+02
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
8.59E+01
1.46E+02
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.6E+03 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
1.00E+00 9.8E+01 2.0E+00 6.4E+00
1.00E+00 3.8E+00 2.0E+00 6.4E+00
6.77E+01 1.3E+00 2.0E+00 6.4E+00
4.25E+04 4.4E+00 2.0E+00 6.4E+00
1.00E+00 9.8E+00 2.0E+00 6.4E+00
1.00E+00 7.0E+00 2.0E+00 6.4E+00 10 100
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+00 2.0E+00 6.4E+00
5.87E+01 1.8E-01 2.0E+00 6.4E+00
1.87E+02 4.1E-01 2.0E+00 6.4E+00
1.00E+00 2.1E+00 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00 10 100
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 6.6E+01 2.0E+00 6.4E+00
1.00E+00 6.5E+01 2.0E+00 6.4E+00
1.00E+00 5.4E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
8.59E+01 3.9E+00 2.0E+00 6.4E+00
1.46E+02 6.1E-01 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00
1.00E+00 8.3E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 4.2E-01 2.0E+00 6.4E+00
1.00E+00 6.5E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 5.2E+01 2.0E+00 6.4E+00
1.00E+00 3.7E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.06E+03 106% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.06E+03 106% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.06E+03 106% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/11 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-552
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V SWA-L09-1313-T01-A 1
V SWA-L09-1313-T02-A 1
V SWA-L09-1313-T03-A 1
V SWA-L09-1313-T04-A 1
V SWA-L09-1313-T05-A 1
V SWA-L09-1313-T06-A 1
V SWA-L09-1313-T07-A 1
V SWA-L09-1313-T08-A 1
V SWA-L09-1313-T09-A 1
V SWA-L09-1313-T01-B 1
V SWA-L09-1313-T02-B 1
V SWA-L09-1313-T03-B 1
V SWA-L09-1313-T04-B 1
V SWA-L09-1313-T05-B 1
V SWA-L09-1313-T06-B 1
V SWA-L09-1313-T07-B 1
V SWA-L09-1313-T08-B 1
V SWA-L09-1313-T09-B 1
V SWA-L09-1313-T01-C 1
V SWA-L09-1313-T02-C 1
V SWA-L09-1313-T03-C 1
V SWA-L09-1313-T04-C 1
V SWA-L09-1313-T05-C 1
V SWA-L09-1313-T06-C 1
V SWA-L09-1313-T07-C 1
V SWA-L09-1313-T08-C 1
V SWA-L09-1313-T09-C 1
V SWA-L09-1313-B01-A 1
V SWA-L09-1313-B02-A 1
V SWA-L09-1313-B03-A 1
V SWA-L09-1313-B01-B 1
V SWA-L09-1313-B03-B 1
V SWA-L09-1313-B01-C 1
V SWA-L09-1313-B02-C 1
V SWA-L09-1313-B03-C 1
Sample I
Cone. Qualifier
ug/L I
3.79E+02
3.10E+02
1.05E+02
1.66E+02
1.87E+02
1.80E+02
2.04E+02
9.70E+01
1.35E+03
3.68E+02
3.09E+02
1.19E+02
2.06E+02
1.89E+02
1.91E+02
1.60E+02
8.83E+01
1.41E+03
3.82E+02
3.72E+02
1.21E+02
2.14E+02
2.17E+02
1.75E+02
1.75E+02
7.40E+01
1.30E+03
7.50E-01 U1/2
7.50E-01 U1/2
7.50E-01 U1/2
1.59E+00 E
7.50E-01 U1/2
1.61E+00 E
7.50E-01 U1/2
2.16E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.79E+02 1.8E+00 1.5E+00 4.8E+00
3.10E+02 1.6E+00 1.5E+00 4.8E+00 10 100
1.05E+02 1.2E+00 1.5E+00 4.8E+00
1.66E+02 1.1E+01 1.5E+00 4.8E+00
1.87E+02 1.2E+00 1.5E+00 4.8E+00
1.80E+02 1.5E+00 1.5E+00 4.8E+00
2.04E+02 1.9E+00 1.5E+00 4.8E+00
9.70E+01 1.4E+00 1.5E+00 4.8E+00
1.35E+03 2.6E+01 1.5E+00 4.8E+00
3.68E+02 7.6E-01 1.5E+00 4.8E+00
3.09E+02 9.3E-01 1.5E+00 4.8E+00 10 100
1.19E+02 6.9E-01 1.5E+00 4.8E+00
2.06E+02 1.7E+00 1.5E+00 4.8E+00
1.89E+02 9.7E-01 1.5E+00 4.8E+00
1.91E+02 6.0E-01 1.5E+00 4.8E+00
1.60E+02 7.2E-01 1.5E+00 4.8E+00
8.83E+01 3.7E+00 1.5E+00 4.8E+00
1.41E+03 3.3E-01 1.5E+00 4.8E+00
3.82E+02 5.6E-01 1.5E+00 4.8E+00
3.72E+02 1.1E+00 1.5E+00 4.8E+00 10 100
1.21E+02 1.5E+00 1.5E+00 4.8E+00
2.14E+02 1.0E+00 1.5E+00 4.8E+00
2.17E+02 5.7E-01 1.5E+00 4.8E+00
1.75E+02 1.0E+00 1.5E+00 4.8E+00
1.75E+02 2.4E+00 1.5E+00 4.8E+00
7.40E+01 3.3E-01 1.5E+00 4.8E+00
1.30E+03 8.0E-01 1.5E+00 4.8E+00
7.50E-01 3.4E+01 1.5E+00 4.8E+00
7.50E-01 3.8E+01 1.5E+00 4.8E+00
7.50E-01 2.6E+01 1.5E+00 4.8E+00
1.59E+00 4.2E+01 1.5E+00 4.8E+00
7.50E-01 5.0E+01 1.5E+00 4.8E+00
1.61E+00 4.5E+01 1.5E+00 4.8E+00
7.50E-01 3.7E+01 1.5E+00 4.8E+00
2.16E+00 1.5E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 2:54 PM EPA Interlab L09 1313-1316 SWA
1.31E+03 100% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:09 PM EPA Interlab L09 1313-1316 SWA
1.28E+03 97% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.34E+03 97% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-553
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qu
Zn SWA-L09-1313-T01-A 1 4.43E+00
Zn SWA-L09-1313-T02-A 1 4.28E+00
Zn SWA-L09-1313-T03-A 1 3.45E+00
Zn SWA-L09-1313-T04-A 1 4.44E+00
Zn SWA-L09-1313-T05-A 1 4.76E+00
Zn SWA-L09-1313-T06-A 1 6.57E+00
Zn SWA-L09-1313-T07-A 1 1.99E+02
Zn SWA-L09-1313-T08-A 1 8.53E+02
Zn SWA-L09-1313-T09-A 1 1.44E+03
Zn SWA-L09-1313-T01-B 1 4.31 E+00
Zn SWA-L09-1313-T02-B 1 6.68E+00
Zn SWA-L09-1313-T03-B 1 3.99E+00
Zn SWA-L09-1313-T04-B 1 4.09E+00
Zn SWA-L09-1313-T05-B 1 5.03E+00
Zn SWA-L09-1313-T06-B 1 2.07E+02
Zn SWA-L09-1313-T07-B 1 8.62E+02
Zn SWA-L09-1313-T08-B 1 8.67E+02
Zn SWA-L09-1313-T09-B 1 1.62E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.43E+00 4.5E+00 1.0E+00 3.2E+00
4.28E+00 5.3E+00 1.0E+00 3.2E+00 10 100
3.45E+00 1.2E+01 1.0E+00 3.2E+00
4.44E+00 6.3E+00 1.0E+00 3.2E+00
4.76E+00 1.1E+01 1.0E+00 3.2E+00
6.57E+00 4.4E+00 1.0E+00 3.2E+00
1.99E+02 1.1 E+00 1.0E+00 3.2E+00
8.53E+02 1.5E+00 1.0E+00 3.2E+00
1.44E+03 1.5E+01 1.0E+00 3.2E+00
4.31 E+00 7.7E+00 1.0E+00 3.2E+00
6.68E+00 2.6E+00 1.0E+00 3.2E+00 10 100
3.99E+00 2.6E+00 1.0E+00 3.2E+00
4.09E+00 6.3E+00 1.0E+00 3.2E+00
5.03E+00 1.2E+01 1.0E+00 3.2E+00
2.07E+02 3.4E-02 1.0E+00 3.2E+00
8.62E+02 2.9E-01 1.0E+00 3.2E+00
8.67E+02 1.9E+00 1.0E+00 3.2E+00
1.62E+03 4.5E-01 1.0E+00 3.2E+00
Zn SWA-L09-1313-T01-C 1 5.00E-01 U1/2 5.00E-01 1 .9E+02 1.0E+00 3.2E+00
Zn SWA-L09-1313-T02-C 1 4.03E+00
Zn SWA-L09-1313-T03-C 1 3.36E+00
Zn SWA-L09-1313-T04-C 1 3.99E+00
Zn SWA-L09-1313-T05-C 1 4.00E+00
Zn SWA-L09-1313-T06-C 1 5.01 E+02
Zn SWA-L09-1313-T07-C 1 4.78E+02
Zn SWA-L09-1313-T08-C 1 1.25E+03
Zn SWA-L09-1313-T09-C 1 1.63E+03
Zn SWA-L09-1313-B01-A 1 1.57E+OOE
Zn SWA-L09-1313-B02-A 1 2.52E+00 E
4.03E+00 7.7E+00 1.0E+00 3.2E+00 10 100
3.36E+00 1.2E+01 1.0E+00 3.2E+00
3.99E+00 8.9E+00 1.0E+00 3.2E+00
4.00E+00 2.8E+01 1.0E+00 3.2E+00
5.01 E+02 7.3E-01 1.0E+00 3.2E+00
4.78E+02 2.4E-01 1.0E+00 3.2E+00
1.25E+03 1.3E+00 1.0E+00 3.2E+00
1.63E+03 4.3E-01 1.0E+00 3.2E+00
1.57E+00 8.6E+01 1.0E+00 3.2E+00
2.52E+00 6.1 E+00 1.0E+00 3.2E+00
Zn SWA-L09-1313-B03-A 1 5.00E-01 U1/2 5.00E-01 9.6E+01 1.0E+00 3.2E+00
Zn SWA-L09-1313-B01-B 1 3.44E+00
Zn SWA-L09-1313-B03-B 1 2.08E+00 E
Zn SWA-L09-1313-B01-C 1 2.44E+00 E
Zn SWA-L09-1313-B02-C 1 2.52E+00 E
Zn SWA-L09-1313-B03-C 1 2.34E+00 E
3.44E+00 1.3E+01 1.0E+00 3.2E+00
2.08E+00 8.3E+01 1.0E+00 3.2E+00
2.44E+00 7.2E+00 1.0E+00 3.2E+00
2.52E+00 7.3E+00 1.0E+00 3.2E+00
2.34E+00 1.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/1 1 2:54 PM EPA Interlab L09 1313-1316 SWA
1.06E+03 106% VU ICP-OES 4/20/11 2:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:58 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:03 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:06 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:08 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:09 PM EPA Interlab L09 1313-1316 SWA
1.03E+03 102% VU ICP-OES 4/20/11 3:11 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:13 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:16 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:18 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:40 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:21 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:23 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:31 PM EPA Interlab L09 1313-1316 SWA
1.06E+03 106% VU ICP-OES 4/20/11 3:33 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:34 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:36 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:38 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:39 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:42 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 3:44 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:41 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:43 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 2:44 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:46 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:48 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:49 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:51 PM EPA Interlab L09 1313-1316 SWA
4/20/1 1 2:53 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                          1-554
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al SWA-L10-1313-T01-A 1
Al SWA-L10-1313-T02-A 1
Al SWA-L10-1313-T03-A 1
Al SWA-L10-1313-T04-A 1
Al SWA-L10-1313-T05-A 1
Al SWA-L10-1313-T06-A 1
Al SWA-L10-1313-T07-A 1
Al SWA-L10-1313-T08-A 1
Al SWA-L10-1313-T09-A 1
Al SWA-L10-1313-T01-B 1
Al SWA-L10-1313-T02-B 1
Al SWA-L10-1313-T03-B 1
Al SWA-L10-1313-T04-B 1
Al SWA-L10-1313-T05-B 1
Al SWA-L10-1313-T06-B 1
Al SWA-L10-1313-T07-B 1
Al SWA-L10-1313-T08-B 1
Al SWA-L10-1313-T09-B 1
Al SWA-L10-1313-T01-C 1
Al SWA-L10-1313-T02-C 1
Al SWA-L10-1313-T03-C 1
Al SWA-L10-1313-T04-C 1
Al SWA-L10-1313-T05-C 1
Al SWA-L10-1313-T06-C 1
Al SWA-L10-1313-T07-C 1
Al SWA-L10-1313-T08-C 1
Al SWA-L10-1313-T09-C 1
Al SWA-L10-1313-B01-A 1
Al SWA-L10-1313-B02-A 1
Sample
Cone. Qualifier
ug/L
3.13E+04
4.74E+03
4.91 E+02
2.14E+02
8.52E+01
5.77E+01
4.67E+04
1.61E+05
3.03E+05
3.69E+04
5.80E+03
5.11 E+02
2.42E+02
9.95E+01
8.00E+01
4.48E+04
1.39E+05
3.27E+05
3.87E+04
5.54E+03
4.99E+02
2.01 E+02
9.77E+01
6.84E+01
4.25E+04
1.85E+05
3.29E+05
5.00E-01 U1/2
2.25E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.13E+04 1.8E+00 1.0E+00 3.2E+00
4.74E+03 1.3E+00 1.0E+00 3.2E+00
4.91E+02 1.9E+00 1.0E+00 3.2E+00 1000 125
2.14E+02 3.0E+00 1.0E+00 3.2E+00
8.52E+01 9.0E+00 1.0E+00 3.2E+00
5.77E+01 1.2E+01 1.0E+00 3.2E+00
4.67E+04 5.0E+00 1.0E+00 3.2E+00
1.61E+05 9.1E+01 1.0E+00 3.2E+00
3.03E+05 5.7E+00 1.0E+00 3.2E+00
3.69E+04 7.5E-01 1.0E+00 3.2E+00
5.80E+03 4.1E-01 1.0E+00 3.2E+00
5.11E+02 1.1E+00 1.0E+00 3.2E+00 1000 125
2.42E+02 1.6E+00 1.0E+00 3.2E+00
9.95E+01 2.7E+00 1.0E+00 3.2E+00
8.00E+01 7.0E+00 1.0E+00 3.2E+00
4.48E+04 1.0E+00 1.0E+00 3.2E+00
1.39E+05 1.4E+02 1.0E+00 3.2E+00
3.27E+05 1.0E+00 1.0E+00 3.2E+00
3.87E+04 9.2E-01 1.0E+00 3.2E+00
5.54E+03 1.5E+00 1.0E+00 3.2E+00
4.99E+02 2.6E-01 1.0E+00 3.2E+00 1000 125
2.01 E+02 2.5E+00 1.0E+00 3.2E+00
9.77E+01 4.1E+00 1.0E+00 3.2E+00
6.84E+01 3.5E+00 1.0E+00 3.2E+00
4.25E+04 1.5E+00 1.0E+00 3.2E+00
1.85E+05 6.6E-01 1.0E+00 3.2E+00
3.29E+05 5.6E-01 1.0E+00 3.2E+00
5.00E-01 3.4E+01 1.0E+00 3.2E+00
2.25E+00 2.9E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.59E+03 88% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.76E+03 100% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.76E+03 101% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                                   1-555
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L10-1313-T01-A 1
Sb SWA-L10-1313-T02-A 1
Sb SWA-L10-1313-T03-A 1
Sb SWA-L10-1313-T04-A 1
Sb SWA-L10-1313-T05-A 1
Sb SWA-L10-1313-T06-A 1
Sb SWA-L10-1313-T07-A 1
Sb SWA-L10-1313-T08-A 1
Sb SWA-L10-1313-T09-A 1
Sb SWA-L10-1313-T01-B 1
Sb SWA-L10-1313-T02-B 1
Sb SWA-L10-1313-T03-B 1
Sb SWA-L10-1313-T04-B 1
Sb SWA-L10-1313-T05-B 1
Sb SWA-L10-1313-T06-B 1
Sb SWA-L10-1313-T07-B 1
Sb SWA-L10-1313-T08-B 1
Sb SWA-L10-1313-T09-B 1
Sb SWA-L10-1313-T01-C 1
Sb SWA-L10-1313-T02-C 1
Sb SWA-L10-1313-T03-C 1
Sb SWA-L10-1313-T04-C 1
Sb SWA-L10-1313-T05-C 1
Sb SWA-L10-1313-T06-C 1
Sb SWA-L10-1313-T07-C 1
Sb SWA-L10-1313-T08-C 1
Sb SWA-L10-1313-T09-C 1
Sb SWA-L10-1313-B01-A 1
Sb SWA-L10-1313-B02-A 1
Sample
Cone. Qualifier
ug/L
5.06E+03
1.34E+03
7.99E+02
1.05E+03
9.54E+02
9.04E+02
7.49E+02
9.22E+02
4.39E+03
3.30E+03
1.30E+03
1.18E+03
1.06E+03
1.27E+03
1.10E+03
7.61 E+02
9.14E+02
1.12E+04
1.41E+03
1.09E+03
1.26E+03
9.97E+02
1.29E+03
1.16E+03
7.56E+02
9.00E+02
3.81 E+03
8.06E+00 E
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.06E+03 1.7E+00 7.5E+00 2.4E+01
1.34E+03 6.3E-01 7.5E+00 2.4E+01
7.99E+02 8.4E-01 7.5E+00 2.4E+01 10 100
1.05E+03 1.3E+00 7.5E+00 2.4E+01
9.54E+02 4.3E+00 7.5E+00 2.4E+01
9.04E+02 2.0E+00 7.5E+00 2.4E+01
7.49E+02 1.5E+00 7.5E+00 2.4E+01
9.22E+02 5.2E+01 7.5E+00 2.4E+01
4.39E+03 5.0E+00 7.5E+00 2.4E+01
3.30E+03 6.3E-01 7.5E+00 2.4E+01
1.30E+03 1.5E+00 7.5E+00 2.4E+01
1.18E+03 1.4E+00 7.5E+00 2.4E+01 10 100
1.06E+03 1.6E+00 7.5E+00 2.4E+01
1.27E+03 5.6E-01 7.5E+00 2.4E+01
1.10E+03 6.2E-01 7.5E+00 2.4E+01
7.61 E+02 2.5E+00 7.5E+00 2.4E+01
9.14E+02 1.4E+02 7.5E+00 2.4E+01
1.12E+04 4.7E-01 7.5E+00 2.4E+01
1.41 E+03 3.2E+00 7.5E+00 2.4E+01
1.09E+03 7.2E-01 7.5E+00 2.4E+01
1.26E+03 8.9E-01 7.5E+00 2.4E+01 10 100
9.97E+02 2.7E+00 7.5E+00 2.4E+01
1.29E+03 3.2E+00 7.5E+00 2.4E+01
1.16E+03 1.9E+00 7.5E+00 2.4E+01
7.56E+02 1.6E+00 7.5E+00 2.4E+01
9.00E+02 1.3E+00 7.5E+00 2.4E+01
3.81 E+03 1.0E+00 7.5E+00 2.4E+01
8.06E+00 6.2E+02 7.5E+00 2.4E+01
3.75E+00 5.2E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.86E+03 106% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
2.29E+03 111% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
2.37E+03 111% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-556
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone.
As SWA-L10-1313-T01-A 1 4.25E+03
As SWA-L10-1313-T02-A 1 3.03E+02
As SWA-L10-1313-T03-A 1 1.52E+02
As SWA-L10-1313-T04-A 1 3.79E+02
As SWA-L10-1313-T05-A 1 1.86E+02
As SWA-L10-1313-T06-A 1 1.25E+02
As SWA-L10-1313-T07-A 1 7.75E+02
As SWA-L10-1313-T08-A 1 2.48E+03
As SWA-L10-1313-T09-A 1 4.88E+03
As SWA-L10-1313-T01-B 1 4.81 E+03
As SWA-L10-1313-T02-B 1 4.04E+02
As SWA-L10-1313-T03-B 1 2.31E+02
As SWA-L10-1313-T04-B 1 3.92E+02
As SWA-L10-1313-T05-B 1 2.11E+02
As SWA-L10-1313-T06-B 1 1.75E+02
As SWA-L10-1313-T07-B 1 8.27E+02
As SWA-L10-1313-T08-B 1 2.39E+03
As SWA-L10-1313-T09-B 1 6.81 E+03
As SWA-L10-1313-T01-C 1 5.20E+03
As SWA-L10-1313-T02-C 1 3.71 E+02
As SWA-L10-1313-T03-C 1 2.37E+02
As SWA-L10-1313-T04-C 1 3.77E+02
As SWA-L10-1313-T05-C 1 2.42E+02
As SWA-L10-1313-T06-C 1 1.70E+02
As SWA-L10-1313-T07-C 1 6.47E+02
As SWA-L10-1313-T08-C 1 2.56E+03
As SWA-L10-1313-T09-C 1 5.20E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.25E+03 1.9E+00 1.1E+01 3.5E+01
3.03E+02 5.0E-01 1.1E+01 3.5E+01
1.52E+02 1.3E+01 1.1E+01 3.5E+01 10 100
3.79E+02 1.2E+00 1.1E+01 3.5E+01
1.86E+02 1.5E+01 1.1E+01 3.5E+01
1.25E+02 8.3E+00 1.1E+01 3.5E+01
7.75E+02 6.2E+00 1.1E+01 3.5E+01
2.48E+03 3.8E+01 1.1E+01 3.5E+01
4.88E+03 5.0E+00 1.1E+01 3.5E+01
4.81 E+03 1.5E+00 1.1E+01 3.5E+01
4.04E+02 2.6E+00 1.1E+01 3.5E+01
2.31E+02 4.7E+00 1.1E+01 3.5E+01 10 100
3.92E+02 4.5E+00 1.1E+01 3.5E+01
2.11E+02 5.5E+00 1.1E+01 3.5E+01
1.75E+02 3.3E+00 1.1E+01 3.5E+01
8.27E+02 3.1E+00 1.1E+01 3.5E+01
2.39E+03 1.4E+02 1.1E+01 3.5E+01
6.81 E+03 7.4E-01 1.1E+01 3.5E+01
5.20E+03 1.3E+00 1.1E+01 3.5E+01
3.71E+02 1.1E+00 1.1E+01 3.5E+01
2.37E+02 5.7E+00 1.1E+01 3.5E+01 10 100
3.77E+02 5.8E+00 1.1E+01 3.5E+01
2.42E+02 1.2E+01 1.1E+01 3.5E+01
1.70E+02 2.9E+00 1.1E+01 3.5E+01
6.47E+02 1.5E+00 1.1E+01 3.5E+01
2.56E+03 3.7E-01 1.1E+01 3.5E+01
5.20E+03 1.1E+00 1.1E+01 3.5E+01
As SWA-L10-1313-B01-A 1 5.50E+00 U1/2 5.50E+00 6.1E+01 1.1E+01 3.5E+01
As SWA-L10-1313-B02-A 1 5.50E+00 U1/2 5.50E+00 1 .3E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.14E+03 98% VUICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.29E+03 106% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.29E+03 105% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-557
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-L10-1313-T01-A 1
B SWA-L10-1313-T02-A 1
B SWA-L10-1313-T03-A 1
B SWA-L10-1313-T04-A 1
B SWA-L10-1313-T05-A 1
B SWA-L10-1313-T06-A 1
B SWA-L10-1313-T07-A 1
B SWA-L10-1313-T08-A 1
B SWA-L10-1313-T09-A 1
B SWA-L10-1313-T01-B 1
B SWA-L10-1313-T02-B 1
B SWA-L10-1313-T03-B 1
B SWA-L10-1313-T04-B 1
B SWA-L10-1313-T05-B 1
B SWA-L10-1313-T06-B 1
B SWA-L10-1313-T07-B 1
B SWA-L10-1313-T08-B 1
B SWA-L10-1313-T09-B 1
B SWA-L10-1313-T01-C 1
B SWA-L10-1313-T02-C 1
B SWA-L10-1313-T03-C 1
B SWA-L10-1313-T04-C 1
B SWA-L10-1313-T05-C 1
B SWA-L10-1313-T06-C 1
B SWA-L10-1313-T07-C 1
B SWA-L10-1313-T08-C 1
B SWA-L10-1313-T09-C 1
B SWA-L10-1313-B01-A 1
B SWA-L10-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
7.90E+02
6.14E+01
9.98E+02
1.61E+03
2.55E+03
3.96E+03
5.34E+03
5.22E+03
1.51E+03
9.32E+02
1.20E+02
1.05E+03
1.58E+03
2.54E+03
3.01 E+03
5.51 E+03
5.16E+03
1.70E+03
9.58E+02
9.49E+01
1.05E+03
1.57E+03
2.49E+03
3.07E+03
5.87E+03
5.34E+03
1.68E+03
1.89E+00 E
3.93E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.90E+02 2.1E+00 1.0E+00 3.2E+00
6.14E+01 2.4E+00 1.0E+00 3.2E+00
9.98E+02 1.1E+00 1.0E+00 3.2E+00 1000 100
1.61 E+03 1.0E+00 1.0E+00 3.2E+00
2.55E+03 3.4E-01 1.0E+00 3.2E+00
3.96E+03 3.5E-01 1.0E+00 3.2E+00
5.34E+03 1.1E+00 1.0E+00 3.2E+00
5.22E+03 2.3E+01 1.0E+00 3.2E+00
1.51 E+03 4.5E+00 1.0E+00 3.2E+00
9.32E+02 1.0E+00 1.0E+00 3.2E+00
1.20E+02 4.0E+00 1.0E+00 3.2E+00
1.05E+03 9.0E-01 1.0E+00 3.2E+00 1000 100
1.58E+03 2.1E-01 1.0E+00 3.2E+00
2.54E+03 1.0E+00 1.0E+00 3.2E+00
3.01 E+03 4.9E-01 1.0E+00 3.2E+00
5.51 E+03 6.8E-01 1.0E+00 3.2E+00
5.16E+03 1.3E+02 1.0E+00 3.2E+00
1.70E+03 1.1E+00 1.0E+00 3.2E+00
9.58E+02 1.6E+00 1.0E+00 3.2E+00
9.49E+01 2.2E+00 1.0E+00 3.2E+00
1.05E+03 5.4E-01 1.0E+00 3.2E+00 1000 100
1.57E+03 1.0E+00 1.0E+00 3.2E+00
2.49E+03 1.0E+00 1.0E+00 3.2E+00
3.07E+03 6.4E-01 1.0E+00 3.2E+00
5.87E+03 6.4E-01 1.0E+00 3.2E+00
5.34E+03 2.8E-01 1.0E+00 3.2E+00
1.68E+03 1.4E+00 1.0E+00 3.2E+00
1.89E+00 4.5E+01 1.0E+00 3.2E+00
3.93E+00 8.5E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.91E+03 91% VUICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
2.10E+03 105% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
2.11E+03 106% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 131 3-1 31 6 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-558
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba SWA-L10-1313-T01-A 1
Ba SWA-L10-1313-T02-A 1
Ba SWA-L10-1313-T03-A 1
Ba SWA-L10-1313-T04-A 1
Ba SWA-L10-1313-T05-A 1
Ba SWA-L10-1313-T06-A 1
Ba SWA-L10-1313-T07-A 1
Ba SWA-L10-1313-T08-A 1
Ba SWA-L10-1313-T09-A 1
Ba SWA-L10-1313-T01-B 1
Ba SWA-L10-1313-T02-B 1
Ba SWA-L10-1313-T03-B 1
Ba SWA-L10-1313-T04-B 1
Ba SWA-L10-1313-T05-B 1
Ba SWA-L10-1313-T06-B 1
Ba SWA-L10-1313-T07-B 1
Ba SWA-L10-1313-T08-B 1
Ba SWA-L10-1313-T09-B 1
Ba SWA-L10-1313-T01-C 1
Ba SWA-L10-1313-T02-C 1
Ba SWA-L10-1313-T03-C 1
Ba SWA-L10-1313-T04-C 1
Ba SWA-L10-1313-T05-C 1
Ba SWA-L10-1313-T06-C 1
Ba SWA-L10-1313-T07-C 1
Ba SWA-L10-1313-T08-C 1
Ba SWA-L10-1313-T09-C 1
Ba SWA-L10-1313-B01-A 1
Ba SWA-L10-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
8.66E+01
4.01 E+02
7.66E+02
9.02E+02
1.00E+03
1.23E+03
1.06E+03
6.24E+02
2.33E+02
1.51 E+02
3.66E+02
9.30E+02
8.57E+02
9.75E+02
1.07E+03
9.81 E+02
6.19E+02
2.57E+02
1 .49E+02
3.30E+02
9.41 E+02
9.32E+02
9.64E+02
1.06E+03
1.08E+03
6.35E+02
2.69E+02
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.66E+01 9.1E-01 1.0E+00 3.2E+00
4.01 E+02 1.3E+00 1.0E+00 3.2E+00
7.66E+02 1.4E-01 1.0E+00 3.2E+00 10 100
9.02E+02 7.4E-01 1.0E+00 3.2E+00
1.00E+03 3.1E-01 1.0E+00 3.2E+00
1.23E+03 4.5E-01 1.0E+00 3.2E+00
1.06E+03 4.2E-01 1.0E+00 3.2E+00
6.24E+02 6.0E+01 1.0E+00 3.2E+00
2.33E+02 5.3E+00 1.0E+00 3.2E+00
1.51 E+02 1.0E+00 1.0E+00 3.2E+00
3.66E+02 1.1E+00 1.0E+00 3.2E+00
9.30E+02 8.5E-02 1.0E+00 3.2E+00 10 100
8.57E+02 4.8E-01 1.0E+00 3.2E+00
9.75E+02 4.4E-01 1.0E+00 3.2E+00
1.07E+03 3.1E-01 1.0E+00 3.2E+00
9.81 E+02 9.0E-01 1.0E+00 3.2E+00
6.19E+02 1.4E+02 1.0E+00 3.2E+00
2.57E+02 1.2E-01 1.0E+00 3.2E+00
1.49E+02 6.9E-01 1.0E+00 3.2E+00
3.30E+02 4.1E-01 1.0E+00 3.2E+00
9.41E+02 3.2E-01 1.0E+00 3.2E+00 10 100
9.32E+02 4.1E-01 1.0E+00 3.2E+00
9.64E+02 8.6E-01 1.0E+00 3.2E+00
1.06E+03 9.0E-01 1.0E+00 3.2E+00
1.08E+03 7.8E-01 1.0E+00 3.2E+00
6.35E+02 4.2E-01 1.0E+00 3.2E+00
2.69E+02 1.3E+00 1.0E+00 3.2E+00
5.00E-01 6.2E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.65E+03 88% VUICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.91E+03 98% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.92E+03 98% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-559
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L10-1313-T01-A 1
Be SWA-L10-1313-T02-A 1
Be SWA-L10-1313-T03-A 1
Be SWA-L10-1313-T04-A 1
Be SWA-L10-1313-T05-A 1
Be SWA-L10-1313-T06-A 1
Be SWA-L10-1313-T07-A 1
Be SWA-L10-1313-T08-A 1
Be SWA-L10-1313-T09-A 1
Be SWA-L10-1313-T01-B 1
Be SWA-L10-1313-T02-B 1
Be SWA-L10-1313-T03-B 1
Be SWA-L10-1313-T04-B 1
Be SWA-L10-1313-T05-B 1
Be SWA-L10-1313-T06-B 1
Be SWA-L10-1313-T07-B 1
Be SWA-L10-1313-T08-B 1
Be SWA-L10-1313-T09-B 1
Be SWA-L10-1313-T01-C 1
Be SWA-L10-1313-T02-C 1
Be SWA-L10-1313-T03-C 1
Be SWA-L10-1313-T04-C 1
Be SWA-L10-1313-T05-C 1
Be SWA-L10-1313-T06-C 1
Be SWA-L10-1313-T07-C 1
Be SWA-L10-1313-T08-C 1
Be SWA-L10-1313-T09-C 1
Be SWA-L10-1313-B01-A 1
Be SWA-L10-1313-B02-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.46E+00
3.04E+01
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
8.07E+00
3.52E+01
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.46E+01
3.29E+01
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.8E+01 1.9E+00 6.0E+00
9.50E-01 6.3E+02 1.9E+00 6.0E+00
9.50E-01 1.9E+01 1.9E+00 6.0E+00 10 100
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 5.5E+01 1.9E+00 6.0E+00
9.46E+00 1.4E+02 1.9E+00 6.0E+00
3.04E+01 6.4E+00 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 6.3E+01 1.9E+00 6.0E+00
9.50E-01 6.8E+01 1.9E+00 6.0E+00 10 100
9.50E-01 2.2E+02 1.9E+00 6.0E+00
9.50E-01 8.9E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+03 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
8.07E+00 1.3E+02 1.9E+00 6.0E+00
3.52E+01 4.7E-01 1.9E+00 6.0E+00
9.50E-01 3.0E+02 1.9E+00 6.0E+00
9.50E-01 2.2E+02 1.9E+00 6.0E+00
9.50E-01 3.7E+02 1.9E+00 6.0E+00 10 100
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 9.8E+00 1.9E+00 6.0E+00
9.50E-01 3.8E+02 1.9E+00 6.0E+00
9.50E-01 7.1E+01 1.9E+00 6.0E+00
1.46E+01 1.5E+00 1.9E+00 6.0E+00
3.29E+01 2.0E+00 1.9E+00 6.0E+00
9.50E-01 4.1E+01 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.09E+03 109% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.12E+03 112% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.14E+03 114% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-560
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L10-1313-T01-A 1 1.10E+OOU1/2 1.10E+00 1.3E+02 2.2E+00 7.0E+00
Cd SWA-L10-1313-T02-A 1 1.10E+OOU1/2 1.10E+00 2.0E+04 2.2E+00 7.0E+00
Cd SWA-L10-1313-T03-A 1 1.10E+OOU1/2 1.10E+00 8.7E+01 2.2E+00 7.0E+00 10 100
Cd SWA-L10-1313-T04-A 1 1.10E+OOU1/2 1.10E+00 5.2E+01 2.2E+00 7.0E+00
Cd SWA-L10-1313-T05-A 1 1.10E+OOU1/2 1.10E+00 6.9E+01 2.2E+00 7.0E+00
Cd SWA-L10-1313-T06-A 1 1.10E+OOU1/2 1.10E+00 1.2E+01 2.2E+00 7.0E+00
Cd SWA-L10-1313-T07-A 1 1.84E+01
Cd SWA-L10-1313-T08-A 1 1.64E+01
Cd SWA-L10-1313-T09-A 1 1.50E+01
1.84E+01 5.2E+00 2.2E+00 7.0E+00
1.64E+01 9.7E+01 2.2E+00 7.0E+00
1.50E+01 6.3E+00 2.2E+00 7.0E+00
Cd SWA-L10-1313-T01-B 1 1.10E+OOU1/2 1.10E+00 1.8E+02 2.2E+00 7.0E+00
Cd SWA-L10-1313-T02-B 1 1.10E+OOU1/2 1.10E+00 5.7E+01 2.2E+00 7.0E+00
Cd SWA-L10-1313-T03-B 1 1.10E+OOU1/2 1.10E+00 8.2E+01 2.2E+00 7.0E+00 10 100
Cd SWA-L10-1313-T04-B 1 1.10E+OOU1/2 1.10E+00 3.8E+01 2.2E+00 7.0E+00
Cd SWA-L10-1313-T05-B 1 1.10E+OOU1/2 1.10E+00 5.1E+01 2.2E+00 7.0E+00
Cd SWA-L10-1313-T06-B 1 1.10E+OOU1/2 1.10E+00 2.1E+03 2.2E+00 7.0E+00
Cd SWA-L10-1313-T07-B 1 1.90E+01
Cd SWA-L10-1313-T08-B 1 1.70E+01
Cd SWA-L10-1313-T09-B 1 1.81E+01
1.90E+01 5.1E-01 2.2E+00 7.0E+00
1.70E+01 1.4E+02 2.2E+00 7.0E+00
1.81E+01 2.8E+00 2.2E+00 7.0E+00
Cd SWA-L10-1313-T01-C 1 1.10E+OOU1/2 1.10E+00 2.1E+02 2.2E+00 7.0E+00
Cd SWA-L10-1313-T02-C 1 1.10E+OOU1/2 1.10E+00 2.8E+04 2.2E+00 7.0E+00
Cd SWA-L10-1313-T03-C 1 1.10E+OOU1/2 1.10E+00 1.0E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L10-1313-T04-C 1 1.10E+OOU1/2 1.10E+00 1.5E+02 2.2E+00 7.0E+00
Cd SWA-L10-1313-T05-C 1 1.10E+OOU1/2 1.10E+00 8.4E+00 2.2E+00 7.0E+00
Cd SWA-L10-1313-T06-C 1 1.10E+OOU1/2 1.10E+00 2.9E+01 2.2E+00 7.0E+00
Cd SWA-L10-1313-T07-C 1 2.21E+01
Cd SWA-L10-1313-T08-C 1 1 .95E+01
Cd SWA-L10-1313-T09-C 1 1 .59E+01
2.21E+01 2.9E+00 2.2E+00 7.0E+00
1.95E+01 2.2E+00 2.2E+00 7.0E+00
1.59E+01 3.3E+00 2.2E+00 7.0E+00
Cd SWA-L10-1313-B01-A 1 1.10E+OOU1/2 1.10E+00 2.5E+02 2.2E+00 7.0E+00
Cd SWA-L10-1313-B02-A 1 1.10E+OOU1/2 1.10E+00 1.4E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % |
VU ICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
9.87E+02 99% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/1012:12 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.11E+03 110% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.12E+03 112% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-561
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qu
1 1 ug/L
Ca SWA-L10-1313-T01-A 1 1.40E+04
Ca SWA-L10-1313-T02-A 1 1.25E+05
Ca SWA-L10-1313-T03-A 1 2.62E+06
Ca SWA-L10-1313-T04-A 1 5.67E+06
Ca SWA-L10-1313-T05-A 1 8.47E+06
Ca SWA-L10-1313-T06-A 1 8.70E+06
Ca SWA-L10-1313-T07-A 1 8.93E+06
Ca SWA-L10-1313-T08-A 1 5.13E+06
Ca SWA-L10-1313-T09-A 1 1.39E+06
Ca SWA-L10-1313-T01-B 1 1.57E+04
Ca SWA-L10-1313-T02-B 1 1.42E+05
Ca SWA-L10-1313-T03-B 1 2.86E+06
Ca SWA-L10-1313-T04-B 1 5.55E+06
Ca SWA-L10-1313-T05-B 1 8.00E+06
Ca SWA-L10-1313-T06-B 1 8.58E+06
Ca SWA-L10-1313-T07-B 1 7.83E+06
Ca SWA-L10-1313-T08-B 1 5.18E+06
Ca SWA-L10-1313-T09-B 1 1.57E+06
Ca SWA-L10-1313-T01-C 1 1.58E+04
Ca SWA-L10-1313-T02-C 1 1.22E+05
Ca SWA-L10-1313-T03-C 1 2.84E+06
Ca SWA-L10-1313-T04-C 1 5.64E+06
Ca SWA-L10-1313-T05-C 1 8.00E+06
Ca SWA-L10-1313-T06-C 1 8.51 E+06
Ca SWA-L10-1313-T07-C 1 8.23E+06
Ca SWA-L10-1313-T08-C 1 5.33E+06
Ca SWA-L10-1313-T09-C 1 1.50E+06
Ca SWA-L10-1313-B01-A 1 4.47E+02
Ca SWA-L10-1313-B02-A 1 3.98E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.40E+04 1.7E+00 2.6E+00 8.3E+00
1.25E+05 8.3E-01 2.6E+00 8.3E+00
2.62E+06 7.4E-01 2.6E+00 8.3E+00 1000 100
5.67E+06 1.7E-01 2.6E+00 8.3E+00
8.47E+06 5.4E-01 2.6E+00 8.3E+00
8.70E+06 3.9E-01 2.6E+00 8.3E+00
8.93E+06 7.2E-01 2.6E+00 8.3E+00
5.13E+06 7.8E+01 2.6E+00 8.3E+00
1.39E+06 2.9E+00 2.6E+00 8.3E+00
1.57E+04 6.1E-01 2.6E+00 8.3E+00
1.42E+05 5.5E-01 2.6E+00 8.3E+00
2.86E+06 4.1E-01 2.6E+00 8.3E+00 1000 100
5.55E+06 3.9E-01 2.6E+00 8.3E+00
8.00E+06 2.1E-01 2.6E+00 8.3E+00
8.58E+06 1.3E-01 2.6E+00 8.3E+00
7.83E+06 8.7E-01 2.6E+00 8.3E+00
5.18E+06 1.4E+02 2.6E+00 8.3E+00
1.57E+06 9.5E-01 2.6E+00 8.3E+00
1.58E+04 1.0E+00 2.6E+00 8.3E+00
1.22E+05 9.2E-01 2.6E+00 8.3E+00
2.84E+06 3.7E-01 2.6E+00 8.3E+00 1000 100
5.64E+06 1.3E+00 2.6E+00 8.3E+00
8.00E+06 8.2E-01 2.6E+00 8.3E+00
8.51 E+06 4.8E-01 2.6E+00 8.3E+00
8.23E+06 7.5E-01 2.6E+00 8.3E+00
5.33E+06 8.3E-01 2.6E+00 8.3E+00
1.50E+06 1.6E+00 2.6E+00 8.3E+00
4.47E+02 1.1E+01 2.6E+00 8.3E+00
3.98E+02 2.4E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
2.62E+06 85% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
2.86E+06 93% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
2.84E+06 98% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-562
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr SWA-L10-1313-T01-A 1
Cr SWA-L10-1313-T02-A 1
Cr SWA-L10-1313-T03-A 1
Cr SWA-L10-1313-T04-A 1
Cr SWA-L10-1313-T05-A 1
Cr SWA-L10-1313-T06-A 1
Cr SWA-L10-1313-T07-A 1
Cr SWA-L10-1313-T08-A 1
Cr SWA-L10-1313-T09-A 1
Cr SWA-L10-1313-T01-B 1
Cr SWA-L10-1313-T02-B 1
Cr SWA-L10-1313-T03-B 1
Cr SWA-L10-1313-T04-B 1
Cr SWA-L10-1313-T05-B 1
Cr SWA-L10-1313-T06-B 1
Cr SWA-L10-1313-T07-B 1
Cr SWA-L10-1313-T08-B 1
Cr SWA-L10-1313-T09-B 1
Cr SWA-L10-1313-T01-C 1
Cr SWA-L10-1313-T02-C 1
Cr SWA-L10-1313-T03-C 1
Cr SWA-L10-1313-T04-C 1
Cr SWA-L10-1313-T05-C 1
Cr SWA-L10-1313-T06-C 1
Cr SWA-L10-1313-T07-C 1
Cr SWA-L10-1313-T08-C 1
Cr SWA-L10-1313-T09-C 1
Cr SWA-L10-1313-B01-A 1
Cr SWA-L10-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
6.97E+02
4.06E+01
1.06E+01
9.48E+00
1.03E+01
2.93E+00 E
3.22E+02
2.11E+03
6.68E+03
1.13E+03
2.27E+01
6.29E+00
8.00E+00
9.03E+00
4.45E+00
3.61 E+02
2.07E+03
7.53E+03
1.13E+03
6.14E+01
5.00E+00
1.24E+01
9.52E+00
3.54E+00 E
3.39E+02
2.05E+03
7.23E+03
6.00E-01 U1/2
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.97E+02 6.4E-01 1.2E+00 3.8E+00
4.06E+01 1.9E+00 1.2E+00 3.8E+00
1.06E+01 6.0E+00 1.2E+00 3.8E+00 10 100
9.48E+00 2.0E+01 1.2E+00 3.8E+00
1.03E+01 2.2E+01 1.2E+00 3.8E+00
2.93E+00 1.0E+02 1.2E+00 3.8E+00
3.22E+02 5.3E+00 1.2E+00 3.8E+00
2.11E+03 4.7E+01 1.2E+00 3.8E+00
6.68E+03 5.2E+00 1.2E+00 3.8E+00
1.13E+03 4.9E-01 1.2E+00 3.8E+00
2.27E+01 3.5E+00 1.2E+00 3.8E+00
6.29E+00 3.0E+00 1.2E+00 3.8E+00 10 100
8.00E+00 6.7E+00 1.2E+00 3.8E+00
9.03E+00 1.5E+01 1.2E+00 3.8E+00
4.45E+00 1.7E+01 1.2E+00 3.8E+00
3.61 E+02 7.4E-01 1.2E+00 3.8E+00
2.07E+03 1.3E+02 1.2E+00 3.8E+00
7.53E+03 9.7E-01 1.2E+00 3.8E+00
1.13E+03 9.0E-01 1.2E+00 3.8E+00
6.14E+01 1.8E+00 1.2E+00 3.8E+00
5.00E+00 1.4E+01 1.2E+00 3.8E+00 10 100
1.24E+01 3.8E+00 1.2E+00 3.8E+00
9.52E+00 1.1E+01 1.2E+00 3.8E+00
3.54E+00 2.2E+01 1.2E+00 3.8E+00
3.39E+02 9.3E-01 1.2E+00 3.8E+00
2.05E+03 4.5E-01 1.2E+00 3.8E+00
7.23E+03 1.3E+00 1.2E+00 3.8E+00
6.00E-01 7.1E+01 1.2E+00 3.8E+00
6.00E-01 6.9E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
9.94E+02 98% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.09E+03 108% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.11E+03 111% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-563
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. (
1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Co SWA-L10-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 1.5E+01 1.8E+00 5.7E+00
Co SWA-L10-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 7.8E+01 1.8E+00 5.7E+00
Co SWA-L10-1313-T03-A 1 2.10E+00 E
Co SWA-L10-1313-T04-A 1 4.41E+00 E
Co SWA-L10-1313-T05-A 1 2.35E+01
Co SWA-L10-1313-T06-A 1 3.81 E+01
Co SWA-L10-1313-T07-A 1 2.15E+02
Co SWA-L10-1313-T08-A 1 1.66E+02
Co SWA-L10-1313-T09-A 1 7.95E+01
2.10E+00 1.9E+01 1.8E+00 5.7E+00 10 100
4.41 E+00 3.7E+01 1.8E+00 5.7E+00
2.35E+01 9.3E+00 1.8E+00 5.7E+00
3.81 E+01 1.3E+00 1.8E+00 5.7E+00
2.15E+02 1.8E+00 1.8E+00 5.7E+00
1.66E+02 7.9E+01 1.8E+00 5.7E+00
7.95E+01 5.1E+00 1.8E+00 5.7E+00
Co SWA-L10-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 3.1E+03 1.8E+00 5.7E+00
Co SWA-L10-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 2.6E+01 1.8E+00 5.7E+00
Co SWA-L10-1313-T03-B 1 2.71E+00 E
Co SWA-L10-1313-T04-B 1 2.80E+00 E
Co SWA-L10-1313-T05-B 1 1.65E+01
Co SWA-L10-1313-T06-B 1 4.11E+01
Co SWA-L10-1313-T07-B 1 1.85E+02
Co SWA-L10-1313-T08-B 1 1.57E+02
Co SWA-L10-1313-T09-B 1 1.00E+02
2.71E+00 2.4E+01 1.8E+00 5.7E+00 10 100
2.80E+00 6.2E+01 1.8E+00 5.7E+00
1.65E+01 6.5E+00 1.8E+00 5.7E+00
4.11 E+01 3.3E+00 1.8E+00 5.7E+00
1.85E+02 1.5E+00 1.8E+00 5.7E+00
1.57E+02 1.3E+02 1.8E+00 5.7E+00
1.00E+02 1.4E+00 1.8E+00 5.7E+00
Co SWA-L10-1313-T01-C 1 9.00E-01 U1/2 9.00E-01 3.0E+02 1.8E+00 5.7E+00
Co SWA-L10-1313-T02-C 1 9.00E-01 U1/2 9.00E-01 2.3E+02 1.8E+00 5.7E+00
Co SWA-L10-1313-T03-C 1 3.33E+00 E
Co SWA-L10-1313-T04-C 1 3.17E+00 E
Co SWA-L10-1313-T05-C 1 1.20E+01
Co SWA-L10-1313-T06-C 1 4.38E+01
Co SWA-L10-1313-T07-C 1 2.02E+02
Co SWA-L10-1313-T08-C 1 1.44E+02
Co SWA-L10-1313-T09-C 1 8.50E+01
3.33E+00 2.8E+01 1.8E+00 5.7E+00 10 100
3.17E+00 2.6E+01 1.8E+00 5.7E+00
1.20E+01 2.7E+00 1.8E+00 5.7E+00
4.38E+01 3.4E+00 1.8E+00 5.7E+00
2.02E+02 1.4E+00 1.8E+00 5.7E+00
1.44E+02 9.9E-01 1.8E+00 5.7E+00
8.50E+01 5.0E-01 1.8E+00 5.7E+00
Co SWA-L10-1313-B01-A 1 9.00E-01 U1/2 9.00E-01 6.0E+01 1.8E+00 5.7E+00
Co SWA-L10-1313-B02-A 1 9.00E-01 U1/2 9.00E-01 1.3E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % |
VU ICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
9.78E+02 98% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.09E+03 109% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/1012:32 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.10E+03 110% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-564
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cu SWA-L10-1313-T01-A 1 1.85E+OOU1/2 1.85E+00 3.7E+01 3.7E+00 1.2E+01
Cu SWA-L10-1313-T02-A 1 1.85E+OOU1/2 1.85E+00 9.4E+01 3.7E+00 1.2E+01
Cu SWA-L10-1313-T03-A 1 5.76E+00 E
Cu SWA-L10-1313-T04-A 1 1.12E+01 E
Cu SWA-L10-1313-T05-A 1 1.25E+01
Cu SWA-L10-1313-T06-A 1 1.26E+01
Cu SWA-L10-1313-T07-A 1 1.50E+01
Cu SWA-L10-1313-T08-A 1 1.45E+01
Cu SWA-L10-1313-T09-A 1 3.34E+02
5.76E+00 1.8E+01 3.7E+00 1.2E+01 10 100
1.12E+01 1.7E+01 3.7E+00 1.2E+01
1.25E+01 1.2E+01 3.7E+00 1.2E+01
1.26E+01 6.2E-01 3.7E+00 1.2E+01
1.50E+01 1.1E+01 3.7E+00 1.2E+01
1.45E+01 1.9E+01 3.7E+00 1.2E+01
3.34E+02 5.8E+00 3.7E+00 1.2E+01
Cu SWA-L10-1313-T01-B 1 1.85E+OOU1/2 1.85E+00 1.7E+02 3.7E+00 1.2E+01
Cu SWA-L10-1313-T02-B 1 1.85E+OOU1/2 1.85E+00 1.7E+01 3.7E+00 1.2E+01
Cu SWA-L10-1313-T03-B 1 4.60E+00 E
Cu SWA-L10-1313-T04-B 1 1.27E+01
Cu SWA-L10-1313-T05-B 1 1.15E+01 E
Cu SWA-L10-1313-T06-B 1 1.07E+01 E
Cu SWA-L10-1313-T07-B 1 1.53E+01
Cu SWA-L10-1313-T08-B 1 1.70E+01
Cu SWA-L10-1313-T09-B 1 3.47E+02
4.60E+00 1.6E+01 3.7E+00 1.2E+01 10 100
1.27E+01 7.9E+00 3.7E+00 1.2E+01
1.15E+01 7.4E+00 3.7E+00 1.2E+01
1.07E+01 9.7E+00 3.7E+00 1.2E+01
1.53E+01 1.2E+01 3.7E+00 1.2E+01
1.70E+01 1.1E+02 3.7E+00 1.2E+01
3.47E+02 1.0E-01 3.7E+00 1.2E+01
Cu SWA-L10-1313-T01-C 1 1.85E+OOU1/2 1.85E+00 2.7E+02 3.7E+00 1.2E+01
Cu SWA-L10-1313-T02-C 1 1.85E+OOU1/2 1.85E+00 8.1E+01 3.7E+00 1.2E+01
Cu SWA-L10-1313-T03-C 1 6.78E+00 E
Cu SWA-L10-1313-T04-C 1 8.59E+00 E
Cu SWA-L10-1313-T05-C 1 1.17E+01 E
Cu SWA-L10-1313-T06-C 1 1.11E+01 E
Cu SWA-L10-1313-T07-C 1 1.06E+01 E
Cu SWA-L10-1313-T08-C 1 1.70E+01
Cu SWA-L10-1313-T09-C 1 3.40E+02
Cu SWA-L10-1313-B01-A 1 4.34E+00 E
Cu SWA-L10-1313-B02-A 1 3.81E+00 E
6.78E+00 9.5E+00 3.7E+00 1.2E+01 10 100
8.59E+00 2.3E+01 3.7E+00 1.2E+01
1.17E+01 1.7E+01 3.7E+00 1.2E+01
1.11E+01 1.8E+01 3.7E+00 1.2E+01
1.06E+01 1.4E+01 3.7E+00 1.2E+01
1.70E+01 8.0E+00 3.7E+00 1.2E+01
3.40E+02 9.5E-01 3.7E+00 1.2E+01
4.34E+00 2.8E+01 3.7E+00 1.2E+01
3.81 E+00 1.6E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % |
VU ICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.05E+03 104% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.17E+03 117% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/1012:32 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.19E+03 118% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 131 3-1 31 6 SWA
                                                                                                                                                                          1-565
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. Qu
1 1 ug/L
Fe SWA-L10-1313-T01-A 1 4.19E+01
Fe SWA-L10-1313-T02-A 1 3.70E+01
Fe SWA-L10-1313-T03-A 1 1.40E+01
Fe SWA-L10-1313-T04-A 1 2.40E+01
Fe SWA-L10-1313-T05-A 1 1.40E+01
Fe SWA-L10-1313-T06-A 1 1.70E+04
Fe SWA-L10-1313-T07-A 1 1.09E+05
Fe SWA-L10-1313-T08-A 1 9.48E+04
Fe SWA-L10-1313-T09-A 1 8.58E+04
Fe SWA-L10-1313-T01-B 1 7.87E+01
Fe SWA-L10-1313-T02-B 1 4.44E+01
Fe SWA-L10-1313-T03-B 1 1.44E+01
Fe SWA-L10-1313-T04-B 1 2.69E+01
Fe SWA-L10-1313-T05-B 1 1.25E+01
Fe SWA-L10-1313-T06-B 1 1.30E+01
Fe SWA-L10-1313-T07-B 1 1.03E+05
Fe SWA-L10-1313-T08-B 1 9.37E+05
Fe SWA-L10-1313-T09-B 1 9.59E+04
Fe SWA-L10-1313-T01-C 1 8.74E+01
Fe SWA-L10-1313-T02-C 1 3.75E+01
Fe SWA-L10-1313-T03-C 1 1.26E+01
Fe SWA-L10-1313-T04-C 1 2.62E+01
Fe SWA-L10-1313-T05-C 1 1.58E+01
Fe SWA-L10-1313-T06-C 1 1.34E+04
Fe SWA-L10-1313-T07-C 1 1.14E+05
Fe SWA-L10-1313-T08-C 1 9.28E+04
Fe SWA-L10-1313-T09-C 1 8.98E+04
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.19E+01 2.8E+00 2.0E+00 6.4E+00
3.70E+01 1.5E+00 2.0E+00 6.4E+00
1.40E+01 1.5E+00 2.0E+00 6.4E+00 1000 100
2.40E+01 7.4E-01 2.0E+00 6.4E+00
1.40E+01 8.3E-01 2.0E+00 6.4E+00
1.70E+04 1.1E+00 2.0E+00 6.4E+00
1.09E+05 5.1E-01 2.0E+00 6.4E+00
9.48E+04 1.4E+02 2.0E+00 6.4E+00
8.58E+04 5.6E+00 2.0E+00 6.4E+00
7.87E+01 7.4E-01 2.0E+00 6.4E+00
4.44E+01 1.7E+00 2.0E+00 6.4E+00
1.44E+01 7.9E+00 2.0E+00 6.4E+00 1000 100
2.69E+01 3.2E+00 2.0E+00 6.4E+00
1.25E+01 3.0E+00 2.0E+00 6.4E+00
1.30E+01 3.3E+00 2.0E+00 6.4E+00
1.03E+05 1.2E+00 2.0E+00 6.4E+00
9.37E+05 1.3E+02 2.0E+00 6.4E+00
9.59E+04 4.8E-01 2.0E+00 6.4E+00
8.74E+01 1.7E+00 2.0E+00 6.4E+00
3.75E+01 8.5E-01 2.0E+00 6.4E+00
1.26E+01 6.5E+00 2.0E+00 6.4E+00 1000 100
2.62E+01 1.2E+00 2.0E+00 6.4E+00
1.58E+01 6.9E+00 2.0E+00 6.4E+00
1.34E+04 7.9E+00 2.0E+00 6.4E+00
1.14E+05 4.4E-01 2.0E+00 6.4E+00
9.28E+04 4.9E-01 2.0E+00 6.4E+00
8.98E+04 9.9E-01 2.0E+00 6.4E+00
Fe SWA-L10-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 2.7E+01 2.0E+00 6.4E+00
Fe SWA-L10-1313-B02-A 1 6.30E+00 E
6.30E+00 5.3E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.01E+03 99% VUICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.12E+03 110% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.13E+03 112% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-566
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb SWA-L10-1313-T01-A 1
Pb SWA-L10-1313-T02-A 1
Pb SWA-L10-1313-T03-A 1
Pb SWA-L10-1313-T04-A 1
Pb SWA-L10-1313-T05-A 1
Pb SWA-L10-1313-T06-A 1
Pb SWA-L10-1313-T07-A 1
Pb SWA-L10-1313-T08-A 1
Pb SWA-L10-1313-T09-A 1
Pb SWA-L10-1313-T01-B 1
Pb SWA-L10-1313-T02-B 1
Pb SWA-L10-1313-T03-B 1
Pb SWA-L10-1313-T04-B 1
Pb SWA-L10-1313-T05-B 1
Pb SWA-L10-1313-T06-B 1
Pb SWA-L10-1313-T07-B 1
Pb SWA-L10-1313-T08-B 1
Pb SWA-L10-1313-T09-B 1
Pb SWA-L10-1313-T01-C 1
Pb SWA-L10-1313-T02-C 1
Pb SWA-L10-1313-T03-C 1
Pb SWA-L10-1313-T04-C 1
Pb SWA-L10-1313-T05-C 1
Pb SWA-L10-1313-T06-C 1
Pb SWA-L10-1313-T07-C 1
Pb SWA-L10-1313-T08-C 1
Pb SWA-L10-1313-T09-C 1
Pb SWA-L10-1313-B01-A 1
Pb SWA-L10-1313-B02-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.70E+01 E
1.33E+01 E
1.21E+01 E
1.39E+01 E
1.87E+01 E
1.57E+01 E
2.40E+01
5.83E+01
1.19E+03
1.96E+01 E
1.02E+01 E
1.05E+01 E
1.06E+01 E
2.70E+01
3.32E+01
2.07E+01 E
5.72E+01
1.18E+03
2.53E+01
1.11E+01 E
1.00E+01 E
1.07E+01 E
2.39E+01
1.98E+01 E
2.63E+01
6.57E+01
1.17E+03
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.70E+01 3.8E+01 6.8E+00 2.2E+01
1.33E+01 3.7E+01 6.8E+00 2.2E+01
1.21E+01 7.8E+01 6.8E+00 2.2E+01 10 100
1.39E+01 2.0E+01 6.8E+00 2.2E+01
1.87E+01 4.5E+01 6.8E+00 2.2E+01
1.57E+01 7.8E+01 6.8E+00 2.2E+01
2.40E+01 1.0E+02 6.8E+00 2.2E+01
5.83E+01 5.4E+01 6.8E+00 2.2E+01
1.19E+03 5.1E+00 6.8E+00 2.2E+01
1.96E+01 1.6E+01 6.8E+00 2.2E+01
1.02E+01 5.3E+01 6.8E+00 2.2E+01
1.05E+01 7.7E+01 6.8E+00 2.2E+01 10 100
1.06E+01 9.6E+01 6.8E+00 2.2E+01
2.70E+01 2.3E+01 6.8E+00 2.2E+01
3.32E+01 3.8E+01 6.8E+00 2.2E+01
2.07E+01 3.4E+01 6.8E+00 2.2E+01
5.72E+01 1.1E+02 6.8E+00 2.2E+01
1.18E+03 1.5E+00 6.8E+00 2.2E+01
2.53E+01 2.4E+01 6.8E+00 2.2E+01
1.11E+01 3.5E+01 6.8E+00 2.2E+01
1.00E+01 3.5E+01 6.8E+00 2.2E+01 10 100
1.07E+01 6.1E+01 6.8E+00 2.2E+01
2.39E+01 2.4E+01 6.8E+00 2.2E+01
1.98E+01 3.6E+01 6.8E+00 2.2E+01
2.63E+01 3.4E+01 6.8E+00 2.2E+01
6.57E+01 4.6E+00 6.8E+00 2.2E+01
1.17E+03 9.7E-01 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
3.40E+00 3.4E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
9.64E+02 95% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.09E+03 108% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.09E+03 108% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-567
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
1 1 ug/L
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Li SWA-L10-1313-T01-A 1 5.59E+00 E 5.59E+00 3.1E+01 1.9E+00 6.0E+00
Li SWA-L10-1313-T02-A 1 3.02E+01
Li SWA-L10-1313-T03-A 1 2.14E+02
Li SWA-L10-1313-T04-A 1 6.46E+02
Li SWA-L10-1313-T05-A 1 1.11E+03
Li SWA-L10-1313-T06-A 1 1.18E+03
Li SWA-L10-1313-T07-A 1 1.10E+03
Li SWA-L10-1313-T08-A 1 8.34E+02
Li SWA-L10-1313-T09-A 1 1.31E+02
3.02E+01 5.4E+00 1.9E+00 6.0E+00
2.14E+02 3.8E+00 1.9E+00 6.0E+00 10 100
6.46E+02 1.2E+00 1.9E+00 6.0E+00
1.11E+03 1.9E+00 1.9E+00 6.0E+00
1.18E+03 1.3E+00 1.9E+00 6.0E+00
1.10E+03 4.3E+00 1.9E+00 6.0E+00
8.34E+02 1.4E+01 1.9E+00 6.0E+00
1.31E+02 5.4E+00 1.9E+00 6.0E+00
Li SWA-L10-1313-T01-B 1 5.73E+00 E 5.73E+00 1.1E+01 1.9E+00 6.0E+00
Li SWA-L10-1313-T02-B 1 3.59E+01
Li SWA-L10-1313-T03-B 1 2.48E+02
Li SWA-L10-1313-T04-B 1 6.32E+02
Li SWA-L10-1313-T05-B 1 1.07E+03
Li SWA-L10-1313-T06-B 1 1.19E+03
Li SWA-L10-1313-T07-B 1 1 .08E+03
Li SWA-L10-1313-T08-B 1 7.95E+02
Li SWA-L10-1313-T09-B 1 1 .59E+02
Li SWA-L10-1313-T01-C 1 8.40E+00
Li SWA-L10-1313-T02-C 1 3.58E+01
Li SWA-L10-1313-T03-C 1 2.44E+02
Li SWA-L10-1313-T04-C 1 6.40E+02
Li SWA-L10-1313-T05-C 1 1 .07E+03
Li SWA-L10-1313-T06-C 1 1.17E+03
Li SWA-L10-1313-T07-C 1 1 .25E+03
Li SWA-L10-1313-T08-C 1 8.15E+02
Li SWA-L10-1313-T09-C 1 1 .59E+02
3.59E+01 2.2E+00 1.9E+00 6.0E+00
2.48E+02 7.2E+00 1.9E+00 6.0E+00 10 100
6.32E+02 4.7E+00 1.9E+00 6.0E+00
1.07E+03 2.2E+00 1.9E+00 6.0E+00
1.19E+03 1.2E+00 1.9E+00 6.0E+00
1.08E+03 6.9E+00 1.9E+00 6.0E+00
7.95E+02 1.6E+02 1 .9E+00 6.0E+00
1.59E+02 7.5E+00 1 .9E+00 6.0E+00
8.40E+00 2.0E+01 1 .9E+00 6.0E+00
3.58E+01 2.5E+00 1 .9E+00 6.0E+00
2.44E+02 5.7E+00 1 .9E+00 6.0E+00 10 100
6.40E+02 1.6E+00 1 .9E+00 6.0E+00
1.07E+03 1.9E+00 1 .9E+00 6.0E+00
1.17E+03 2.0E+00 1 .9E+00 6.0E+00
1.25E+03 3.9E+00 1 .9E+00 6.0E+00
8.15E+02 3.9E+00 1 .9E+00 6.0E+00
1.59E+02 3.5E+00 1 .9E+00 6.0E+00
Li SWA-L10-1313-B01-A 1 9.50E-01 U1/2 9.50E-01 1.8E+01 1 .9E+00 6.0E+00
Li SWA-L10-1313-B02-A 1 9.50E-01 U1/2 9.50E-01 1.6E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.10E+03 88% VUICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.12E+03 87% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.10E+03 86% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-568
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn SWA-L10-1313-T01-A 1
Mn SWA-L10-1313-T02-A 1
Mn SWA-L10-1313-T03-A 1
Mn SWA-L10-1313-T04-A 1
Mn SWA-L10-1313-T05-A 1
Mn SWA-L10-1313-T06-A 1
Mn SWA-L10-1313-T07-A 1
Mn SWA-L10-1313-T08-A 1
Mn SWA-L10-1313-T09-A 1
Mn SWA-L10-1313-T01-B 1
Mn SWA-L10-1313-T02-B 1
Mn SWA-L10-1313-T03-B 1
Mn SWA-L10-1313-T04-B 1
Mn SWA-L10-1313-T05-B 1
Mn SWA-L10-1313-T06-B 1
Mn SWA-L10-1313-T07-B 1
Mn SWA-L10-1313-T08-B 1
Mn SWA-L10-1313-T09-B 1
Mn SWA-L10-1313-T01-C 1
Mn SWA-L10-1313-T02-C 1
Mn SWA-L10-1313-T03-C 1
Mn SWA-L10-1313-T04-C 1
Mn SWA-L10-1313-T05-C 1
Mn SWA-L10-1313-T06-C 1
Mn SWA-L10-1313-T07-C 1
Mn SWA-L10-1313-T08-C 1
Mn SWA-L10-1313-T09-C 1
Mn SWA-L10-1313-B01-A 1
Mn SWA-L10-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.41E+01
6.99E+03
1.61E+04
2.60E+04
1.45E+04
5.42E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.67E+01
4.91 E+03
9.43E+03
2.02E+04
1.63E+04
6.18E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.76E+01
3.88E+03
9.81 E+03
2.19E+04
1.50E+04
5.98E+03
1.00E+00 U1/2
1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.8E+02 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+00 2.0E+00 6.4E+00 10 100
3.41 E+01 1.0E+00 2.0E+00 6.4E+00
6.99E+03 6.5E-01 2.0E+00 6.4E+00
1.61E+04 9.2E-01 2.0E+00 6.4E+00
2.60E+04 1.3E+00 2.0E+00 6.4E+00
1.45E+04 7.7E+01 2.0E+00 6.4E+00
5.42E+03 5.5E+00 2.0E+00 6.4E+00
1.00E+00 1.1 E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 6.8E+00 2.0E+00 6.4E+00 10 100
3.67E+01 3.9E-01 2.0E+00 6.4E+00
4.91 E+03 9.0E-01 2.0E+00 6.4E+00
9.43E+03 3.1E-01 2.0E+00 6.4E+00
2.02E+04 1.2E+00 2.0E+00 6.4E+00
1.63E+04 1.3E+02 2.0E+00 6.4E+00
6.18E+03 3.8E-01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 4.4E+01 2.0E+00 6.4E+00
1.00E+00 5.4E+01 2.0E+00 6.4E+00 10 100
2.76E+01 6.5E-01 2.0E+00 6.4E+00
3.88E+03 1.1E+00 2.0E+00 6.4E+00
9.81 E+03 8.8E-01 2.0E+00 6.4E+00
2.19E+04 1.1E+00 2.0E+00 6.4E+00
1.50E+04 7.3E-01 2.0E+00 6.4E+00
5.98E+03 1.3E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
9.68E+02 97% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.09E+03 109% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.10E+03 110% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-569
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone.
1 ug/L
Mg SWA-L10-1313-T01-A 1 1.88E+01
Mg SWA-L10-1313-T02-A 1 4.02E+01
Mg SWA-L10-1313-T03-A 1 4.25E+03
Mg SWA-L10-1313-T04-A 1 5.33E+05
Mg SWA-L10-1313-T05-A 1 1.11E+06
Mg SWA-L10-1313-T06-A 1 1.26E+06
Mg SWA-L10-1313-T07-A 1 1.63E+06
Mg SWA-L10-1313-T08-A 1 7.99E+05
Mg SWA-L10-1313-T09-A 1 2.13E+05
Mg SWA-L10-1313-T01-B 1 1.04E+01
Mg SWA-L10-1313-T02-B 1 3.29E+01
Mg SWA-L10-1313-T03-B 1 5.10E+03
Mg SWA-L10-1313-T04-B 1 5.24E+05
Mg SWA-L10-1313-T05-B 1 1.07E+06
Mg SWA-L10-1313-T06-B 1 1.18E+06
Mg SWA-L10-1313-T07-B 1 1.18E+06
Mg SWA-L10-1313-T08-B 1 8.15E+05
Mg SWA-L10-1313-T09-B 1 2.41E+05
Mg SWA-L10-1313-T01-C 1 1.11E+01
Mg SWA-L10-1313-T02-C 1 4.35E+01
Mg SWA-L10-1313-T03-C 1 5.27E+03
Mg SWA-L10-1313-T04-C 1 5.35E+05
Mg SWA-L10-1313-T05-C 1 1.04E+06
Mg SWA-L10-1313-T06-C 1 1.18E+06
Mg SWA-L10-1313-T07-C 1 1.26E+06
Mg SWA-L10-1313-T08-C 1 8.05E+05
Mg SWA-L10-1313-T09-C 1 2.32E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.88E+01 6.1E+01 1.0E+00 3.2E+00
4.02E+01 4.3E+01 1.0E+00 3.2E+00
4.25E+03 5.1E-01 1.0E+00 3.2E+00 1000 100
5.33E+05 1.0E+00 1.0E+00 3.2E+00
1.11E+06 2.3E-01 1.0E+00 3.2E+00
1.26E+06 4.1E-01 1.0E+00 3.2E+00
1.63E+06 1.1E+00 1.0E+00 3.2E+00
7.99E+05 8.2E+01 1.0E+00 3.2E+00
2.13E+05 4.6E+00 1.0E+00 3.2E+00
1.04E+01 1.2E+02 1.0E+00 3.2E+00
3.29E+01 4.5E+01 1.0E+00 3.2E+00
5.10E+03 1.0E-01 1.0E+00 3.2E+00 1000 100
5.24E+05 9.6E-01 1.0E+00 3.2E+00
1.07E+06 9.4E-01 1.0E+00 3.2E+00
1.18E+06 8.6E-01 1.0E+00 3.2E+00
1.18E+06 1.7E+00 1.0E+00 3.2E+00
8.15E+05 1.5E+02 1.0E+00 3.2E+00
2.41 E+05 5.7E-01 1.0E+00 3.2E+00
1.11E+01 5.6E+02 1.0E+00 3.2E+00
4.35E+01 3.2E+01 1.0E+00 3.2E+00
5.27E+03 8.0E-01 1.0E+00 3.2E+00 1000 100
5.35E+05 6.7E-01 1.0E+00 3.2E+00
1.04E+06 7.9E-01 1.0E+00 3.2E+00
1.18E+06 3.5E-01 1.0E+00 3.2E+00
1.26E+06 1.5E+00 1.0E+00 3.2E+00
8.05E+05 3.7E-01 1.0E+00 3.2E+00
2.32E+05 1.6E+00 1.0E+00 3.2E+00
Mg SWA-L10-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 3.0E+01 1.0E+00 3.2E+00
Mg SWA-L10-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 6.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
5.21E+03 96% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
6.12E+03 102% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
6.24E+03 97% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-570
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 1 ug/L
Mo SWA-L10-1313-T01-A 1 1.31E+02
Mo SWA-L10-1313-T02-A 1 1.32E+02
Mo SWA-L10-1313-T03-A 1 1.20E+02
Mo SWA-L10-1313-T04-A 1 1.42E+02
Mo SWA-L10-1313-T05-A 1 1.03E+02
Mo SWA-L10-1313-T06-A 1 3.00E+01
Mo SWA-L10-1313-T07-A 1 1.28E+01
Mo SWA-L10-1313-T08-A 1 1.49E+01
Mo SWA-L10-1313-T09-A 1 1.36E+01
Mo SWA-L10-1313-T01-B 1 1.31E+02
Mo SWA-L10-1313-T02-B 1 1.46E+02
Mo SWA-L10-1313-T03-B 1 1.40E+02
Mo SWA-L10-1313-T04-B 1 1.40E+02
Mo SWA-L10-1313-T05-B 1 1.13E+02
Mo SWA-L10-1313-T06-B 1 8.09E+01
Mo SWA-L10-1313-T07-B 1 8.15E+00
Mo SWA-L10-1313-T08-B 1 1.21E+01
Mo SWA-L10-1313-T09-B 1 1.45E+01
Mo SWA-L10-1313-T01-C 1 1.41E+02
Mo SWA-L10-1313-T02-C 1 1.49E+02
Mo SWA-L10-1313-T03-C 1 1.37E+02
Mo SWA-L10-1313-T04-C 1 1.42E+02
Mo SWA-L10-1313-T05-C 1 1.23E+02
Mo SWA-L10-1313-T06-C 1 7.58E+01
Mo SWA-L10-1313-T07-C 1 8.41E+00
Mo SWA-L10-1313-T08-C 1 1.49E+01
Mo SWA-L10-1313-T09-C 1 1.29E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.31E+02 3.4E+00 1.2E+00 3.8E+00
1.32E+02 3.1E+00 1.2E+00 3.8E+00
1.20E+02 2.2E+00 1.2E+00 3.8E+00 10 100
1.42E+02 2.5E+00 1.2E+00 3.8E+00
1.03E+02 3.5E+00 1.2E+00 3.8E+00
3.00E+01 1.1E+01 1.2E+00 3.8E+00
1.28E+01 9.7E+00 1.2E+00 3.8E+00
1.49E+01 8.8E+00 1.2E+00 3.8E+00
1.36E+01 2.1E+01 1.2E+00 3.8E+00
1.31E+02 1.0E+00 1.2E+00 3.8E+00
1.46E+02 1.1E+00 1.2E+00 3.8E+00
1.40E+02 7.0E-01 1.2E+00 3.8E+00 10 100
1.40E+02 1.5E+00 1.2E+00 3.8E+00
1.13E+02 9.5E-01 1.2E+00 3.8E+00
8.09E+01 3.1E+00 1.2E+00 3.8E+00
8.15E+00 8.4E+00 1.2E+00 3.8E+00
1.21E+01 9.0E+01 1.2E+00 3.8E+00
1.45E+01 7.0E+00 1.2E+00 3.8E+00
1.41E+02 2.6E+00 1.2E+00 3.8E+00
1.49E+02 1.1E+00 1.2E+00 3.8E+00
1.37E+02 2.0E+00 1.2E+00 3.8E+00 10 100
1.42E+02 1.1E+00 1.2E+00 3.8E+00
1.23E+02 1.4E+00 1.2E+00 3.8E+00
7.58E+01 1.6E+00 1.2E+00 3.8E+00
8.41 E+00 2.5E+01 1.2E+00 3.8E+00
1.49E+01 8.8E+00 1.2E+00 3.8E+00
1.29E+01 3.3E+00 1.2E+00 3.8E+00
Mo SWA-L10-1313-B01-A 1 3.06E+00 E 3.06E+00 1.1E+01 1.2E+00 3.8E+00
Mo SWA-L10-1313-B02-A 1 1.98E+OOE 1.98E+00 5.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.11E+03 99% VUICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.26E+03 112% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.26E+03 113% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-571
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L10-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 3.3E+02 1.8E+00 5.7E+00
Ni SWA-L10-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 7.4E+01 1.8E+00 5.7E+00
Ni SWA-L10-1313-T03-A 1 2.72E+00 E
Ni SWA-L10-1313-T04-A 1 1.09E+01
Ni SWA-L10-1313-T05-A 1 6.41 E+01
Ni SWA-L10-1313-T06-A 1 3.02E+02
Ni SWA-L10-1313-T07-A 1 5.03E+02
Ni SWA-L10-1313-T08-A 1 3.12E+02
Ni SWA-L10-1313-T09-A 1 1.15E+02
2.72E+00 2.5E+01 1.8E+00 5.7E+00 10 100
1.09E+01 3.3E+01 1.8E+00 5.7E+00
6.41 E+01 5.9E+00 1.8E+00 5.7E+00
3.02E+02 1.6E+00 1.8E+00 5.7E+00
5.03E+02 8.6E-01 1.8E+00 5.7E+00
3.12E+02 5.4E+01 1.8E+00 5.7E+00
1.15E+02 2.3E+00 1.8E+00 5.7E+00
Ni SWA-L10-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 2.6E+03 1.8E+00 5.7E+00
Ni SWA-L10-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 1.3E+02 1.8E+00 5.7E+00
Ni SWA-L10-1313-T03-B 1 3.77E+00 E
Ni SWA-L10-1313-T04-B 1 6.77E+00
Ni SWA-L10-1313-T05-B 1 4.17E+01
Ni SWA-L10-1313-T06-B 1 1.09E+02
Ni SWA-L10-1313-T07-B 1 4.09E+02
Ni SWA-L10-1313-T08-B 1 3.26E+02
Ni SWA-L10-1313-T09-B 1 1.33E+02
3.77E+00 3.1 E+01 1.8E+00 5.7E+00 10 100
6.77E+00 5.6E+01 1.8E+00 5.7E+00
4.17E+01 8.0E+00 1.8E+00 5.7E+00
1.09E+02 5.5E+00 1.8E+00 5.7E+00
4.09E+02 4.9E-01 1.8E+00 5.7E+00
3.26E+02 1.3E+02 1.8E+00 5.7E+00
1.33E+02 3.0E-01 1.8E+00 5.7E+00
Ni SWA-L10-1313-T01-C 9.00E-01 U1/2 O.OOE+00 9.1 E+01 1.8E+00 5.7E+00
Ni SWA-L10-1313-T02-C 9.00E-01 U1/2 O.OOE+00 3.4E+02 1.8E+00 5.7E+00
Ni SWA-L10-1313-T03-C 2.44E+00 U1/2 O.OOE+00 8.0E+01 1.8E+00 5.7E+00 10 100
Ni SWA-L10-1313-T04-C 1.05E+01 U1/2 O.OOE+00 2.6E+01 1.8E+00 5.7E+00
Ni SWA-L10-1313-T05-C 3.16E+01 U1/2 O.OOE+00 7.9E+00 1.8E+00 5.7E+00
Ni SWA-L10-1313-T06-C 1.20E+02U1/2 O.OOE+00 3.2E+00 1.8E+00 5.7E+00
Ni SWA-L10-1313-T07-C 4.50E+02 U1/2 O.OOE+00 5.9E-01 1.8E+00 5.7E+00
Ni SWA-L10-1313-T08-C 3.08E+02 U1/2 O.OOE+00 2.7E-01 1.8E+00 5.7E+00
Ni SWA-L10-1313-T09-C 1.26E+02U1/2 O.OOE+00 1.5E+00 1.8E+00 5.7E+00
Ni SWA-L10-1313-B01-A 9.00E-01 U1/2 O.OOE+00 3.4E+01 1.8E+00 5.7E+00
Ni SWA-L10-1313-B02-A 9.00E-01 U1/2 O.OOE+00 2.0E+03 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % |
VU ICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
9.42E+02 94% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.06E+03 106% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/1012:32 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.08E+03 108% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-572
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P SWA-L10-1313-T01-A 1
P SWA-L10-1313-T02-A 1
P SWA-L10-1313-T03-A 1
P SWA-L10-1313-T04-A 1
P SWA-L10-1313-T05-A 1
P SWA-L10-1313-T06-A 1
P SWA-L10-1313-T07-A 1
P SWA-L10-1313-T08-A 1
P SWA-L10-1313-T09-A 1
P SWA-L10-1313-T01-B 1
P SWA-L10-1313-T02-B 1
P SWA-L10-1313-T03-B 1
P SWA-L10-1313-T04-B 1
P SWA-L10-1313-T05-B 1
P SWA-L10-1313-T06-B 1
P SWA-L10-1313-T07-B 1
P SWA-L10-1313-T08-B 1
P SWA-L10-1313-T09-B 1
P SWA-L10-1313-T01-C 1
P SWA-L10-1313-T02-C 1
P SWA-L10-1313-T03-C 1
P SWA-L10-1313-T04-C 1
P SWA-L10-1313-T05-C 1
P SWA-L10-1313-T06-C 1
P SWA-L10-1313-T07-C 1
P SWA-L10-1313-T08-C 1
P SWA-L10-1313-T09-C 1
P SWA-L10-1313-B01-A 1
P SWA-L10-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
4.47E+01
1.70E+01
1.74E+01
3.37E+01
4.02E+01
4.30E+01
2.18E+02
7.28E+02
7.19E+03
5.80E+01
1.28E+01
1.28E+01
9.44E+01
3.72E+01
4.77E+01
2.09E+02
7.21 E+02
1.25E+04
5.38E+01
2.10E+01
3.78E+01
6.12E+01
1.04E+02
3.99E+01
2.06E+02
7.42E+02
7.00E+03
1.00E+01 E
7.00E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.47E+01 1.6E+01 3.7E+00 1.2E+01
1.70E+01 2.9E+00 3.7E+00 1.2E+01
1.74E+01 1.0E+02 3.7E+00 1.2E+01 1000 100
3.37E+01 7.5E+01 3.7E+00 1.2E+01
4.02E+01 2.1E+01 3.7E+00 1.2E+01
4.30E+01 2.1E+01 3.7E+00 1.2E+01
2.18E+02 3.1E+02 3.7E+00 1.2E+01
7.28E+02 5.5E+01 3.7E+00 1.2E+01
7.19E+03 5.9E+00 3.7E+00 1.2E+01
5.80E+01 5.0E+01 3.7E+00 1.2E+01
1.28E+01 1.6E+02 3.7E+00 1.2E+01
1.28E+01 3.6E+01 3.7E+00 1.2E+01 1000 100
9.44E+01 2.6E+01 3.7E+00 1.2E+01
3.72E+01 6.5E+01 3.7E+00 1.2E+01
4.77E+01 7.9E+01 3.7E+00 1.2E+01
2.09E+02 2.9E+01 3.7E+00 1.2E+01
7.21 E+02 1.3E+02 3.7E+00 1.2E+01
1.25E+04 9.2E-01 3.7E+00 1.2E+01
5.38E+01 2.4E+01 3.7E+00 1.2E+01
2.10E+01 6.6E+01 3.7E+00 1 .2E+01
3.78E+01 4.0E+01 3.7E+00 1 .2E+01 1000 100
6.12E+01 1.8E+01 3.7E+00 1 .2E+01
1.04E+02 2.7E+01 3.7E+00 1 .2E+01
3.99E+01 6.3E+01 3.7E+00 1 .2E+01
2.06E+02 6.1E+00 3.7E+00 1 .2E+01
7.42E+02 1.2E+00 3.7E+00 1 .2E+01
7.00E+03 7.5E-01 3.7E+00 1 .2E+01
1.00E+01 1.1 E+02 3.7E+00 1 .2E+01
7.00E+00 6.9E+01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.11E+03 109% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.19E+03 118% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.17E+03 113% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 131 3-1 31 6 SWA
                                                                                                                                                                          1-573
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K SWA-L10-1313-T01-A 1
K SWA-L10-1313-T02-A 1
K SWA-L10-1313-T03-A 1
K SWA-L10-1313-T04-A 1
K SWA-L10-1313-T05-A 1
K SWA-L10-1313-T06-A 1
K SWA-L10-1313-T07-A 1
K SWA-L10-1313-T08-A 1
K SWA-L10-1313-T09-A 1
K SWA-L10-1313-T01-B 1
K SWA-L10-1313-T02-B 1
K SWA-L10-1313-T03-B 1
K SWA-L10-1313-T04-B 1
K SWA-L10-1313-T05-B 1
K SWA-L10-1313-T06-B 1
K SWA-L10-1313-T07-B 1
K SWA-L10-1313-T08-B 1
K SWA-L10-1313-T09-B 1
K SWA-L10-1313-T01-C 1
K SWA-L10-1313-T02-C 1
K SWA-L10-1313-T03-C 1
K SWA-L10-1313-T04-C 1
K SWA-L10-1313-T05-C 1
K SWA-L10-1313-T06-C 1
K SWA-L10-1313-T07-C 1
K SWA-L10-1313-T08-C 1
K SWA-L10-1313-T09-C 1
K SWA-L10-1313-B01-A 1
K SWA-L10-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
3.45E+05
3.99E+05
4.73E+05
5.14E+05
5.48E+05
5.59E+05
3.82E+05
2.66E+05
5.40E+04
3.40E+05
4.14E+05
4.98E+05
5.05E+05
5.32E+05
5.43E+05
3.87E+05
2.57E+05
6.18E+04
3.54E+05
4.07E+05
4.86E+05
5.08E+05
5.31 E+05
5.32E+05
3.97E+05
2.64E+05
5.93E+04
1.62E+03
2.80E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.45E+05 1.7E+00 1.6E+00 5.1E+00
3.99E+05 1.5E+00 1.6E+00 5.1E+00
4.73E+05 4.9E-01 1.6E+00 5.1E+00 1000 100
5.14E+05 6.4E-01 1.6E+00 5.1E+00
5.48E+05 4.0E-01 1.6E+00 5.1E+00
5.59E+05 5.8E-01 1.6E+00 5.1E+00
3.82E+05 7.6E-01 1.6E+00 5.1E+00
2.66E+05 6.3E+01 1.6E+00 5.1E+00
5.40E+04 5.5E+00 1.6E+00 5.1E+00
3.40E+05 7.8E-01 1.6E+00 5.1E+00
4.14E+05 3.6E-01 1.6E+00 5.1E+00
4.98E+05 9.3E-01 1.6E+00 5.1E+00 1000 100
5.05E+05 2.3E-01 1.6E+00 5.1E+00
5.32E+05 3.3E-01 1.6E+00 5.1E+00
5.43E+05 1.1E-01 1.6E+00 5.1E+00
3.87E+05 3.9E-01 1.6E+00 5.1E+00
2.57E+05 1.4E+02 1.6E+00 5.1E+00
6.18E+04 1.0E+00 1.6E+00 5.1E+00
3.54E+05 9.1E-01 1.6E+00 5.1E+00
4.07E+05 9.7E-01 1.6E+00 5.1E+00
4.86E+05 7.4E-01 1.6E+00 5.1E+00 1000 100
5.08E+05 8.2E-01 1.6E+00 5.1E+00
5.31 E+05 5.5E-01 1.6E+00 5.1E+00
5.32E+05 8.6E-01 1.6E+00 5.1E+00
3.97E+05 1.6E+00 1.6E+00 5.1E+00
2.64E+05 1.1E+00 1.6E+00 5.1E+00
5.93E+04 1.0E+00 1.6E+00 5.1E+00
1.62E+03 2.6E+01 1.6E+00 5.1E+00
2.80E+01 2.2E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
4.74E+05 93% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
4.99E+05 96% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
4.87E+05 94% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 131 3-1 31 6 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 131 3-1 31 6 SWA
                                                                                                                                                                          1-574
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
1 ug/L
Se SWA-L10-1313-T01-A 1 8.81 E+04
Se SWA-L10-1313-T02-A 1 8.99E+04
Se SWA-L10-1313-T03-A 1 9.31 E+04
Se SWA-L10-1313-T04-A 1 1.12E+05
Se SWA-L10-1313-T05-A 1 1.20E+05
Se SWA-L10-1313-T06-A 1 1.16E+05
Se SWA-L10-1313-T07-A 1 9.55E+04
Se SWA-L10-1313-T08-A 1 5.16E+04
Se SWA-L10-1313-T09-A 1 8.29E+03
Se SWA-L10-1313-T01-B 1 8.78E+04
Se SWA-L10-1313-T02-B 1 9.91E+04
Se SWA-L10-1313-T03-B 1 1.01E+05
Se SWA-L10-1313-T04-B 1 1.10E+05
Se SWA-L10-1313-T05-B 1 1.17E+05
Se SWA-L10-1313-T06-B 1 1.18E+05
Se SWA-L10-1313-T07-B 1 8.04E+04
Se SWA-L10-1313-T08-B 1 5.14E+04
Se SWA-L10-1313-T09-B 1 9.64E+03
Se SWA-L10-1313-T01-C 1 9.49E+04
Se SWA-L10-1313-T02-C 1 9.92E+04
Se SWA-L10-1313-T03-C 1 9.71E+04
Se SWA-L10-1313-T04-C 1 1.12E+05
Se SWA-L10-1313-T05-C 1 1.18E+05
Se SWA-L10-1313-T06-C 1 1.15E+05
Se SWA-L10-1313-T07-C 1 8.34E+04
Se SWA-L10-1313-T08-C 1 5.25E+04
Se SWA-L10-1313-T09-C 1 9.19E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
8.81 E+04 1.6E+00 1.5E+01 4.8E+01
8.99E+04 9.6E-01 1.5E+01 4.8E+01
9.31E+04 4.7E-01 1.5E+01 4.8E+01 10 100
1.12E+05 7.4E-01 1.5E+01 4.8E+01
1.20E+05 1.7E-01 1.5E+01 4.8E+01
1.16E+05 1.0E-01 1.5E+01 4.8E+01
9.55E+04 4.8E-01 1.5E+01 4.8E+01
5.16E+04 4.0E+01 1.5E+01 4.8E+01
8.29E+03 5.9E+00 1.5E+01 4.8E+01
8.78E+04 9.1E-01 1.5E+01 4.8E+01
9.91 E+04 5.7E-01 1.5E+01 4.8E+01
1.01E+05 3.8E-01 1.5E+01 4.8E+01 10 100
1.10E+05 5.2E-01 1.5E+01 4.8E+01
1.17E+05 3.7E-01 1.5E+01 4.8E+01
1.18E+05 3.9E-01 1.5E+01 4.8E+01
8.04E+04 5.8E-01 1.5E+01 4.8E+01
5.14E+04 1.4E+02 1.5E+01 4.8E+01
9.64E+03 5.9E-01 1.5E+01 4.8E+01
9.49E+04 1.3E+00 1.5E+01 4.8E+01
9.92E+04 9.0E-01 1.5E+01 4.8E+01
9.71E+04 8.5E-01 1.5E+01 4.8E+01 10 100
1.12E+05 7.7E-01 1.5E+01 4.8E+01
1.18E+05 9.7E-01 1.5E+01 4.8E+01
1.15E+05 8.3E-01 1.5E+01 4.8E+01
8.34E+04 8.1E-01 1.5E+01 4.8E+01
5.25E+04 2.2E-01 1.5E+01 4.8E+01
9.19E+03 1.2E+00 1.5E+01 4.8E+01
Se SWA-L10-1313-B01-A 1 1.58E+01 E 1.58E+01 6.3E+01 1.5E+01 4.8E+01
Se SWA-L10-1313-B02-A 1 7.50E+00 U1/2 7.50E+00 7.5E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
9.40E+04 87% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.02E+05 99% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
9.80E+04 95% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-575
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-L10-1313-T01-A 1
Si SWA-L10-1313-T02-A 1
Si SWA-L10-1313-T03-A 1
Si SWA-L10-1313-T04-A 1
Si SWA-L10-1313-T05-A 1
Si SWA-L10-1313-T06-A 1
Si SWA-L10-1313-T07-A 1
Si SWA-L10-1313-T08-A 1
Si SWA-L10-1313-T09-A 1
Si SWA-L10-1313-T01-B 1
Si SWA-L10-1313-T02-B 1
Si SWA-L10-1313-T03-B 1
Si SWA-L10-1313-T04-B 1
Si SWA-L10-1313-T05-B 1
Si SWA-L10-1313-T06-B 1
Si SWA-L10-1313-T07-B 1
Si SWA-L10-1313-T08-B 1
Si SWA-L10-1313-T09-B 1
Si SWA-L10-1313-T01-C 1
Si SWA-L10-1313-T02-C 1
Si SWA-L10-1313-T03-C 1
Si SWA-L10-1313-T04-C 1
Si SWA-L10-1313-T05-C 1
Si SWA-L10-1313-T06-C 1
Si SWA-L10-1313-T07-C 1
Si SWA-L10-1313-T08-C 1
Si SWA-L10-1313-T09-C 1
Si SWA-L10-1313-B01-A 1
Si SWA-L10-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
4.60E+03
3.28E+03
1.55E+03
8.68E+02
1.08E+03
2.22E+03
4.76E+03
1.41E+04
5.13E+04
5.92E+03
2.92E+03
1.54E+03
7.64E+02
9.81 E+02
1.30E+03
5.03E+03
1.48E+04
1.25E+05
5.90E+03
3.34E+03
1.52E+03
9.48E+02
9.72E+02
1.33E+03
5.21E+03
1.41E+04
4.62E+04
1.83E+00 E
7.09E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.60E+03 2.9E-01 1.1E+00 3.5E+00
3.28E+03 1.0E+00 1.1E+00 3.5E+00
1.55E+03 9.3E-01 1.1E+00 3.5E+00 1000 100
8.68E+02 5.0E-01 1.1E+00 3.5E+00
1.08E+03 7.8E-01 1.1E+00 3.5E+00
2.22E+03 5.5E-01 1.1E+00 3.5E+00
4.76E+03 4.3E-01 1.1E+00 3.5E+00
1.41E+04 4.3E+01 1.1E+00 3.5E+00
5.13E+04 5.2E+00 1.1E+00 3.5E+00
5.92E+03 1.7E-02 1.1E+00 3.5E+00
2.92E+03 3.9E-01 1.1E+00 3.5E+00
1.54E+03 1.1E+00 1.1E+00 3.5E+00 1000 100
7.64E+02 7.1E-01 1.1E+00 3.5E+00
9.81 E+02 5.4E-01 1.1E+00 3.5E+00
1.30E+03 9.2E-02 1.1E+00 3.5E+00
5.03E+03 6.7E-01 1.1E+00 3.5E+00
1.48E+04 1.3E+02 1.1E+00 3.5E+00
1.25E+05 4.0E-01 1.1E+00 3.5E+00
5.90E+03 6.0E-01 1.1E+00 3.5E+00
3.34E+03 4.0E-01 1.1E+00 3.5E+00
1.52E+03 1.1E+00 1.1E+00 3.5E+00 1000 100
9.48E+02 1.2E+00 1.1E+00 3.5E+00
9.72E+02 7.2E-01 1.1E+00 3.5E+00
1.33E+03 4.4E-01 1.1E+00 3.5E+00
5.21E+03 6.1E-01 1.1E+00 3.5E+00
1.41E+04 5.0E-01 1.1E+00 3.5E+00
4.62E+04 1.1E+00 1.1E+00 3.5E+00
1.83E+00 1.2E+02 1.1E+00 3.5E+00
7.09E+00 7.6E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
2.48E+03 93% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
2.54E+03 100% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
2.48E+03 96% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-576
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone.
Na SWA-L10-1313-T01-A 1 5.13E+05
Na SWA-L10-1313-T02-A 1 5.51 E+05
Na SWA-L10-1313-T03-A 1 6.00E+05
Na SWA-L10-1313-T04-A 1 6.43E+05
Na SWA-L10-1313-T05-A 1 6.64E+05
Na SWA-L10-1313-T06-A 1 6.54E+05
Na SWA-L10-1313-T07-A 1 4.22E+05
Na SWA-L10-1313-T08-A 1 2.61E+05
Na SWA-L10-1313-T09-A 1 1.26E+05
Na SWA-L10-1313-T01-B 1 4.96E+05
Na SWA-L10-1313-T02-B 1 5.54E+05
Na SWA-L10-1313-T03-B 1 6.08E+05
Na SWA-L10-1313-T04-B 1 6.23E+05
Na SWA-L10-1313-T05-B 1 6.44E+05
Na SWA-L10-1313-T06-B 1 6.44E+05
Na SWA-L10-1313-T07-B 1 4.37E+05
Na SWA-L10-1313-T08-B 1 2.38E+05
Na SWA-L10-1313-T09-B 1 1.37E+05
Na SWA-L10-1313-T01-C 1 5.08E+05
Na SWA-L10-1313-T02-C 1 5.52E+05
Na SWA-L10-1313-T03-C 1 5.99E+05
Na SWA-L10-1313-T04-C 1 6.25E+05
Na SWA-L10-1313-T05-C 1 6.41 E+05
Na SWA-L10-1313-T06-C 1 6.32E+05
Na SWA-L10-1313-T07-C 1 4.36E+05
Na SWA-L10-1313-T08-C 1 2.84E+05
Na SWA-L10-1313-T09-C 1 1.32E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.13E+05 2.2E+00 2.5E+00 8.0E+00
5.51 E+05 8.5E-01 2.5E+00 8.0E+00
6.00E+05 4.2E-01 2.5E+00 8.0E+00 1000 100
6.43E+05 9.0E-01 2.5E+00 8.0E+00
6.64E+05 2.8E-01 2.5E+00 8.0E+00
6.54E+05 7.1E-01 2.5E+00 8.0E+00
4.22E+05 7.0E-01 2.5E+00 8.0E+00
2.61 E+05 6.7E+01 2.5E+00 8.0E+00
1.26E+05 3.6E+00 2.5E+00 8.0E+00
4.96E+05 1.5E+00 2.5E+00 8.0E+00
5.54E+05 5.7E-01 2.5E+00 8.0E+00
6.08E+05 3.6E-03 2.5E+00 8.0E+00 1000 100
6.23E+05 2.8E-01 2.5E+00 8.0E+00
6.44E+05 2.5E-01 2.5E+00 8.0E+00
6.44E+05 2.7E-01 2.5E+00 8.0E+00
4.37E+05 1.4E+00 2.5E+00 8.0E+00
2.38E+05 1.1E+02 2.5E+00 8.0E+00
1.37E+05 3.4E-01 2.5E+00 8.0E+00
5.08E+05 2.6E-01 2.5E+00 8.0E+00
5.52E+05 7.7E-01 2.5E+00 8.0E+00
5.99E+05 1.5E-01 2.5E+00 8.0E+00 1000 100
6.25E+05 1.1E+00 2.5E+00 8.0E+00
6.41 E+05 4.1E-01 2.5E+00 8.0E+00
6.32E+05 5.5E-01 2.5E+00 8.0E+00
4.36E+05 1.1E+00 2.5E+00 8.0E+00
2.84E+05 5.6E-01 2.5E+00 8.0E+00
1.32E+05 4.8E-01 2.5E+00 8.0E+00
Na SWA-L10-1313-B01-A 1 5.45E+00 E 5.45E+00 1 .4E+01 2.5E+00 8.0E+00
Na SWA-L10-1313-B02-A 1 1.25E+OOU1/2 1.25E+00 3.0E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
6.01E+05 94% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
6.09E+05 109% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
6.00E+05 108% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-577
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone.
SWA-L10-1313-T01-A 1 3.03E+02
SWA-L10-1313-T02-A 1 2.25E+03
SWA-L10-1313-T03-A 1 1.51 E+04
SWA-L10-1313-T04-A 1 2.82E+04
SWA-L10-1313-T05-A 1 4.12E+04
SWA-L10-1313-T06-A 1 4.35E+04
SWA-L10-1313-T07-A 1 4.26E+04
SWA-L10-1313-T08-A 1 2.59E+04
SWA-L10-1313-T09-A 1 7.21E+03
SWA-L10-1313-T01-B 1 3.30E+02
SWA-L10-1313-T02-B 1 2.47E+03
SWA-L10-1313-T03-B 1 1.73E+04
SWA-L10-1313-T04-B 1 2.80E+04
SWA-L10-1313-T05-B 1 3.83E+04
SWA-L10-1313-T06-B 1 4.23E+04
SWA-L10-1313-T07-B 1 3.93E+04
SWA-L10-1313-T08-B 1 2.25E+04
SWA-L10-1313-T09-B 1 8.06E+03
SWA-L10-1313-T01-C 1 3.43E+02
SWA-L10-1313-T02-C 1 2.11E+03
SWA-L10-1313-T03-C 1 1.71 E+04
SWA-L10-1313-T04-C 1 2.81E+04
SWA-L10-1313-T05-C 1 3.80E+04
SWA-L10-1313-T06-C 1 4.15E+04
SWA-L10-1313-T07-C 1 4.06E+04
SWA-L10-1313-T08-C 1 2.69E+04
SWA-L10-1313-T09-C 1 7.71 E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.03E+02 1.2E+00 1.0E+00 3.2E+00
2.25E+03 9.1E-01 1.0E+00 3.2E+00
1.51 E+04 2.0E+00 1.0E+00 3.2E+00 1000 100
2.82E+04 4.7E-01 1.0E+00 3.2E+00
4.12E+04 7.9E-01 1.0E+00 3.2E+00
4.35E+04 3.9E-01 1.0E+00 3.2E+00
4.26E+04 2.0E+00 1.0E+00 3.2E+00
2.59E+04 9.7E+01 1.0E+00 3.2E+00
7.21 E+03 6.5E+00 1.0E+00 3.2E+00
3.30E+02 9.6E-01 1.0E+00 3.2E+00
2.47E+03 5.3E-01 1.0E+00 3.2E+00
1.73E+04 3.7E-01 1.0E+00 3.2E+00 1000 100
2.80E+04 1.1E+00 1.0E+00 3.2E+00
3.83E+04 2.4E+00 1.0E+00 3.2E+00
4.23E+04 1.7E+00 1.0E+00 3.2E+00
3.93E+04 8.4E-01 1.0E+00 3.2E+00
2.25E+04 1.1E+02 1.0E+00 3.2E+00
8.06E+03 1.0E+00 1.0E+00 3.2E+00
3.43E+02 1.7E+00 1.0E+00 3.2E+00
2. 11 E+03 8.6E-01 1.0E+00 3.2E+00
1.71E+04 1.2E+00 1.0E+00 3.2E+00 1000 100
2.81 E+04 3.7E-01 1.0E+00 3.2E+00
3.80E+04 5.3E-01 1.0E+00 3.2E+00
4.15E+04 1.1E+00 1.0E+00 3.2E+00
4.06E+04 6.5E-01 1.0E+00 3.2E+00
2.69E+04 1.3E-01 1.0E+00 3.2E+00
7.71 E+03 1.3E+00 1.0E+00 3.2E+00
SWA-L10-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 2.1E+01 1.0E+00 3.2E+00
SWA-L10-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 3.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.61E+04 93% VUICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.83E+04 97% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.81E+04 94% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-578
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qu
1 1 ug/L
S SWA-L10-1313-T01-A 1 7.12E+05
S SWA-L10-1313-T02-A 1 8.41 E+05
S SWA-L10-1313-T03-A 1 8.71 E+05
S SWA-L10-1313-T04-A 1 8.19E+05
S SWA-L10-1313-T05-A 1 7.80E+05
S SWA-L10-1313-T06-A 1 3.84E+05
S SWA-L10-1313-T07-A 1 4.14E+05
S SWA-L10-1313-T08-A 1 1.87E+05
S SWA-L10-1313-T09-A 1 3.80E+04
S SWA-L10-1313-T01-B 1 7.30E+05
S SWA-L10-1313-T02-B 1 9.43E+05
S SWA-L10-1313-T03-B 1 9.69E+05
S SWA-L10-1313-T04-B 1 8.42E+05
S SWA-L10-1313-T05-B 1 8.24E+05
S SWA-L10-1313-T06-B 1 7.88E+05
S SWA-L10-1313-T07-B 1 2.93E+05
S SWA-L10-1313-T08-B 1 8.02E+04
S SWA-L10-1313-T09-B 1 4.34E+04
S SWA-L10-1313-T01-C 1 6.88E+05
S SWA-L10-1313-T02-C 1 9.71 E+05
S SWA-L10-1313-T03-C 1 8.32E+05
S SWA-L10-1313-T04-C 1 8.20E+05
S SWA-L10-1313-T05-C 1 8.23E+05
S SWA-L10-1313-T06-C 1 7.48E+05
S SWA-L10-1313-T07-C 1 3.73E+05
S SWA-L10-1313-T08-C 1 1.94E+05
S SWA-L10-1313-T09-C 1 4.19E+04
S SWA-L10-1313-B01-A 1 1.54E+01 E
S SWA-L10-1313-B02-A 1 3.02E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
7.12E+05 1.9E+00 6.8E+00 2.2E+01
8.41 E+05 1.2E+00 6.8E+00 2.2E+01
8.71E+05 4.1E-01 6.8E+00 2.2E+01 1000 100
8.19E+05 4.3E-01 6.8E+00 2.2E+01
7.80E+05 4.0E-01 6.8E+00 2.2E+01
3.84E+05 2.1E-01 6.8E+00 2.2E+01
4.14E+05 6.3E-01 6.8E+00 2.2E+01
1.87E+05 3.9E+01 6.8E+00 2.2E+01
3.80E+04 5.7E+00 6.8E+00 2.2E+01
7.30E+05 1.2E+00 6.8E+00 2.2E+01
9.43E+05 6.9E-01 6.8E+00 2.2E+01
9.69E+05 8.8E-01 6.8E+00 2.2E+01 1000 100
8.42E+05 3.9E-01 6.8E+00 2.2E+01
8.24E+05 6.9E-01 6.8E+00 2.2E+01
7.88E+05 1.2E-01 6.8E+00 2.2E+01
2.93E+05 1.0E+00 6.8E+00 2.2E+01
8.02E+04 1.4E+02 6.8E+00 2.2E+01
4.34E+04 4.6E-01 6.8E+00 2.2E+01
6.88E+05 7.5E-01 6.8E+00 2.2E+01
9.71E+05 3.0E-01 6.8E+00 2.2E+01
8.32E+05 4.1E-01 6.8E+00 2.2E+01 1000 100
8.20E+05 2.8E-01 6.8E+00 2.2E+01
8.23E+05 2.0E-01 6.8E+00 2.2E+01
7.48E+05 3.2E-01 6.8E+00 2.2E+01
3.73E+05 8.2E-01 6.8E+00 2.2E+01
1.94E+05 2.3E-01 6.8E+00 2.2E+01
4.19E+04 1.0E+00 6.8E+00 2.2E+01
1.54E+01 2.7E+01 6.8E+00 2.2E+01
3.02E+01 9.0E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
8.72E+05 96% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
9.70E+05 98% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
8.33E+05 93% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 131 3-1 31 6 SWA
                                                                                                                                                                          1-579
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L10-1313-T01-A 1 2.30E+00 U1/2 2.30E+00 4.3E+01 4.6E+00 1.5E+01
Tl SWA-L10-1313-T02-A 1 2.30E+00 U1/2 2.30E+00 1 .OE+02 4.6E+00 1.5E+01
Tl SWA-L10-1313-T03-A 1 2.30E+00 U1/2 2.30E+00 5.5E+01 4.6E+00 1.5E+01 10 100
Tl SWA-L10-1313-T04-A 1 2.30E+00 U1/2 2.30E+00 1 .2E+03 4.6E+00 1.5E+01
Tl SWA-L10-1313-T05-A 1 2.30E+00 U1/2 2.30E+00 1 JE+02 4.6E+00 1.5E+01
Tl SWA-L10-1313-T06-A 1 1.32E+01 E
Tl SWA-L10-1313-T07-A 1 1.65E+01
Tl SWA-L10-1313-T08-A 1 5.11E+OOE
1.32E+01 1.9E+01 4.6E+00 1 .5E+01
1.65E+01 2.4E+01 4.6E+00 1 .5E+01
5.11E+00 1.3E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T09-A 1 2.30E+00 U1/2 2.30E+00 3.6E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T01-B 1 2.30E+00 U1/2 2.30E+00 3.1E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T02-B 1 2.30E+00 U1/2 2.30E+00 2.2E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T03-B 1 2.30E+00 U1/2 2.30E+00 3.6E+01 4.6E+00 1 .5E+01 10 100
Tl SWA-L10-1313-T04-B 1 2.30E+00 U1/2 2.30E+00 2.4E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T05-B 1 1.81E+01
Tl SWA-L10-1313-T06-B 1 1.55E+01
Tl SWA-L10-1313-T07-B 1 1.02E+01 E
1.81E+01 1. OE+02 4.6E+00 1 .5E+01
1.55E+01 6.2E+01 4.6E+00 1 .5E+01
1.02E+01 8.8E+01 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T08-B 1 2.30E+00 U1/2 2.30E+00 9.9E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T09-B 1 2.30E+00 U1/2 2.30E+00 1 .5E+03 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T01-C 1 2.30E+00 U1/2 2.30E+00 1 .2E+03 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T02-C 1 2.30E+00 U1/2 2.30E+00 1 .6E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T03-C 1 2.30E+00 U1/2 2.30E+00 6.3E+00 4.6E+00 1 .5E+01 10 100
Tl SWA-L10-1313-T04-C 1 2.30E+00 U1/2 2.30E+00 2.4E+01 4.6E+00 1 .5E+01
Tl SWA-L10-1313-T05-C 1 4.82E+00 E
Tl SWA-L10-1313-T06-C 1 1.14E+01 E
Tl SWA-L10-1313-T07-C 1 1.43E+01 E
Tl SWA-L10-1313-T08-C 1 4.93E+00 E
4.82E+00 9.0E+01 4.6E+00 1 .5E+01
1.14E+01 8.7E+01 4.6E+00 1.5E+01
1.43E+01 2.0E+01 4.6E+00 1.5E+01
4.93E+00 8.9E+01 4.6E+00 1.5E+01
Tl SWA-L10-1313-T09-C 1 2.30E+00 U1/2 2.30E+00 2.3E+02 4.6E+00 1.5E+01
Tl SWA-L10-1313-B01-A 1 2.30E+00 U1/2 2.30E+00 4.5E+01 4.6E+00 1.5E+01
Tl SWA-L10-1313-B02-A 1 2.30E+00 U1/2 2.30E+00 3.3E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
8.85E+02 88% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
9.98E+02 100% VU ICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
9.84E+02 98% VU ICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-580
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L10-1313-T01-A 1 1.00E+OOU1/2 1.00E+00 4.3E+01 2.0E+00 6.4E+00
Ti SWA-L10-1313-T02-A 1 1.00E+OOU1/2 1.00E+00 9.4E+01 2.0E+00 6.4E+00
Ti SWA-L10-1313-T03-A 1 1.00E+OOU1/2 1.00E+00 6.3E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L10-1313-T04-A 1 1.00E+OOU1/2 1.00E+00 3.0E+02 2.0E+00 6.4E+00
Ti SWA-L10-1313-T05-A 1 1.00E+OOU1/2 1.00E+00 1 .OE+02 2.0E+00 6.4E+00
Ti SWA-L10-1313-T06-A 1 1.00E+OOU1/2 1.00E+00 3.1E+01 2.0E+00 6.4E+00
Ti SWA-L10-1313-T07-A 1 1.00E+OOU1/2 1.00E+00 2.2E+02 2.0E+00 6.4E+00
Ti SWA-L10-1313-T08-A 1 1.16E+02
Ti SWA-L10-1313-T09-A 1 1.01E+04
1.16E+02 5.0E+01 2.0E+00 6.4E+00
1.01E+04 4.9E+00 2.0E+00 6.4E+00
Ti SWA-L10-1313-T01-B 1 1.00E+OOU1/2 1.00E+00 5.6E+01 2.0E+00 6.4E+00
Ti SWA-L10-1313-T02-B 1 1.00E+OOU1/2 1.00E+00 7.1E+01 2.0E+00 6.4E+00
Ti SWA-L10-1313-T03-B 1 1.00E+OOU1/2 1.00E+00 3.1E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L10-1313-T04-B 1 1.00E+OOU1/2 1.00E+00 1 .9E+03 2.0E+00 6.4E+00
Ti SWA-L10-1313-T05-B 1 1.00E+OOU1/2 1.00E+00 1.1E+02 2.0E+00 6.4E+00
Ti SWA-L10-1313-T06-B 1 1.00E+OOU1/2 1.00E+00 7.1E+02 2.0E+00 6.4E+00
Ti SWA-L10-1313-T07-B 1 2.95E+01
Ti SWA-L10-1313-T08-B 1 1.04E+02
Ti SWA-L10-1313-T09-B 1 1.83E+04
2.95E+01 2.9E+00 2.0E+00 6.4E+00
1.04E+02 1.2E+02 2.0E+00 6.4E+00
1.83E+04 3.5E-01 2.0E+00 6.4E+00
Ti SWA-L10-1313-T01-C 1 1.00E+OOU1/2 1.00E+00 4.3E+01 2.0E+00 6.4E+00
Ti SWA-L10-1313-T02-C 1 1.00E+OOU1/2 1.00E+00 2.0E+02 2.0E+00 6.4E+00
Ti SWA-L10-1313-T03-C 1 1.00E+OOU1/2 1.00E+00 2.6E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L10-1313-T04-C 1 1.00E+OOU1/2 1.00E+00 1 .9E+02 2.0E+00 6.4E+00
Ti SWA-L10-1313-T05-C 1 1.00E+OOU1/2 1.00E+00 3.9E+01 2.0E+00 6.4E+00
Ti SWA-L10-1313-T06-C 1 1.00E+OOU1/2 1.00E+00 3.0E+01 2.0E+00 6.4E+00
Ti SWA-L10-1313-T07-C 1 1.95E+01
Ti SWA-L10-1313-T08-C 1 1.43E+02
Ti SWA-L10-1313-T09-C 1 9.69E+03
1.95E+01 1.1E+01 2.0E+00 6.4E+00
1.43E+02 1.6E+00 2.0E+00 6.4E+00
9.69E+03 1.8E+00 2.0E+00 6.4E+00
Ti SWA-L10-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00
Ti SWA-L10-1313-B02-A 1 1.00E+OOU1/2 1.00E+00 1 .4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.01E+03 101% VUICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.13E+03 113% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.13E+03 113% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-581
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
V SWA-L10-1313-T01-A 1 2.98E+02
V SWA-L10-1313-T02-A 1 9.18E+01
V SWA-L10-1313-T03-A 1 8.75E+01
V SWA-L10-1313-T04-A 1 1.42E+02
V SWA-L10-1313-T05-A 1 1.20E+02
V SWA-L10-1313-T06-A 1 1.11E+02
V SWA-L10-1313-T07-A 1 1.07E+02
V SWA-L10-1313-T08-A 1 5.60E+01
V SWA-L10-1313-T09-A 1 5.63E+02
V SWA-L10-1313-T01-B 1 3.26E+02
V SWA-L10-1313-T02-B 1 9.74E+01
V SWA-L10-1313-T03-B 1 9.88E+01
V SWA-L10-1313-T04-B 1 1.45E+02
V SWA-L10-1313-T05-B 1 1.19E+02
V SWA-L10-1313-T06-B 1 1.21E+02
V SWA-L10-1313-T07-B 1 7.94E+01
V SWA-L10-1313-T08-B 1 4.68E+01
V SWA-L10-1313-T09-B 1 6.03E+02
V SWA-L10-1313-T01-C 1 3.47E+02
V SWA-L10-1313-T02-C 1 9.76E+01
V SWA-L10-1313-T03-C 1 9.87E+01
V SWA-L10-1313-T04-C 1 1.45E+02
V SWA-L10-1313-T05-C 1 1.36E+02
V SWA-L10-1313-T06-C 1 1.17E+02
V SWA-L10-1313-T07-C 1 8.64E+01
V SWA-L10-1313-T08-C 1 5.57E+01
V SWA-L10-1313-T09-C 1 6.17E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.98E+02 1.4E+00 1.5E+00 4.8E+00
9.18E+01 9.9E-01 1.5E+00 4.8E+00
8.75E+01 8.5E-01 1.5E+00 4.8E+00 10 100
1.42E+02 9.7E-02 1.5E+00 4.8E+00
1.20E+02 1.4E+00 1.5E+00 4.8E+00
1.11E+02 3.6E+00 1.5E+00 4.8E+00
1.07E+02 2.1E+00 1.5E+00 4.8E+00
5.60E+01 4.4E+01 1.5E+00 4.8E+00
5.63E+02 4.7E+00 1.5E+00 4.8E+00
3.26E+02 1.2E+00 1.5E+00 4.8E+00
9.74E+01 3.6E-01 1.5E+00 4.8E+00
9.88E+01 1.3E+00 1.5E+00 4.8E+00 10 100
1.45E+02 2.9E+00 1.5E+00 4.8E+00
1.19E+02 6.6E-01 1.5E+00 4.8E+00
1.21E+02 9.8E-01 1.5E+00 4.8E+00
7.94E+01 5.1E+00 1.5E+00 4.8E+00
4.68E+01 1.0E+02 1.5E+00 4.8E+00
6.03E+02 4.8E-01 1.5E+00 4.8E+00
3.47E+02 1.0E+00 1.5E+00 4.8E+00
9.76E+01 9.9E-01 1.5E+00 4.8E+00
9.87E+01 1.5E+00 1.5E+00 4.8E+00 10 100
1.45E+02 2.2E+00 1.5E+00 4.8E+00
1.36E+02 8.4E-02 1.5E+00 4.8E+00
1.17E+02 7.0E-01 1.5E+00 4.8E+00
8.64E+01 4.9E+00 1.5E+00 4.8E+00
5.57E+01 4.8E+00 1.5E+00 4.8E+00
6.17E+02 1.3E+00 1.5E+00 4.8E+00
V SWA-L10-1313-B01-A 1 7.50E-01 U1/2 7.50E-01 4.6E+01 1.5E+00 4.8E+00
V SWA-L10-1313-B02-A 1 1.66E+OOE 1.66E+00 3.4E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.09E+03 100% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.22E+03 112% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.24E+03 114% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 11:57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-582
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone.
1 1 ug/L
Zn SWA-L10-1313-T01-A 1 3.22E+00
Zn SWA-L10-1313-T02-A 1 4.83E+00
Zn SWA-L10-1313-T03-A 1 6.98E+00
Zn SWA-L10-1313-T04-A 1 5.39E+00
Zn SWA-L10-1313-T05-A 1 9.44E+00
Zn SWA-L10-1313-T06-A 1 2.23E+02
Zn SWA-L10-1313-T07-A 1 9.30E+02
Zn SWA-L10-1313-T08-A 1 1.07E+03
Zn SWA-L10-1313-T09-A 1 5.07E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.22E+00 8.4E+01 1.0E+00 3.2E+00
4.83E+00 7.5E+00 1.0E+00 3.2E+00
6.98E+00 4.2E+00 1.0E+00 3.2E+00 10 100
5.39E+00 1.7E+01 1.0E+00 3.2E+00
9.44E+00 2.5E+00 1.0E+00 3.2E+00
2.23E+02 2.2E-01 1.0E+00 3.2E+00
9.30E+02 1.5E+00 1.0E+00 3.2E+00
1.07E+03 4.4E+01 1.0E+00 3.2E+00
5.07E+02 5.9E+00 1.0E+00 3.2E+00
Zn SWA-L10-1313-T01-B 1 2.90E+00 E 2.90E+00 5.4E+00 1.0E+00 3.2E+00
Zn SWA-L10-1313-T02-B 1 2.68E+00 E 2.68E+00 8.6E+00 1.0E+00 3.2E+00
Zn SWA-L10-1313-T03-B 1 3.47E+00
Zn SWA-L10-1313-T04-B 1 5.64E+00
Zn SWA-L10-1313-T05-B 1 7.74E+00
Zn SWA-L10-1313-T06-B 1 1.24E+01
Zn SWA-L10-1313-T07-B 1 1.02E+03
Zn SWA-L10-1313-T08-B 1 9.94E+02
Zn SWA-L10-1313-T09-B 1 5.68E+02
3.47E+00 1.6E+01 1.0E+00 3.2E+00 10 100
5.64E+00 2.3E+01 1.0E+00 3.2E+00
7.74E+00 8.0E+00 1.0E+00 3.2E+00
1.24E+01 6.7E+00 1.0E+00 3.2E+00
1.02E+03 5.6E-01 1.0E+00 3.2E+00
9.94E+02 1.4E+02 1.0E+00 3.2E+00
5.68E+02 4.6E-01 1.0E+00 3.2E+00
Zn SWA-L10-1313-T01-C 1 2.49E+00 E 2.49E+00 1 .6E+01 1.0E+00 3.2E+00
Zn SWA-L10-1313-T02-C 1 2.98E+00 E 2.98E+00 1.4E+01 1.0E+00 3.2E+00
Zn SWA-L10-1313-T03-C 1 3.25E+00
Zn SWA-L10-1313-T04-C 1 6.29E+00
Zn SWA-L10-1313-T05-C 1 1.12E+01
Zn SWA-L10-1313-T06-C 1 1.44E+01
Zn SWA-L10-1313-T07-C 1 1.06E+03
Zn SWA-L10-1313-T08-C 1 1.04E+03
Zn SWA-L10-1313-T09-C 1 5.46E+02
Zn SWA-L10-1313-B01-A 1 3.56E+00
Zn SWA-L10-1313-B02-A 1 5.29E+00
3.25E+00 8.4E+00 1.0E+00 3.2E+00 10 100
6.29E+00 8.5E+00 1.0E+00 3.2E+00
1.12E+01 5.7E+00 1.0E+00 3.2E+00
1.44E+01 7.0E+00 1.0E+00 3.2E+00
1.06E+03 1.5E+00 1.0E+00 3.2E+00
1.04E+03 4.0E-01 1.0E+00 3.2E+00
5.46E+02 1.6E+00 1.0E+00 3.2E+00
3.56E+00 2.2E+01 1.0E+00 3.2E+00
5.29E+00 8.5E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 11:59 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:01 PM EPA Interlab L10 1313-1316 SWA
1.09E+03 108% VU ICP-OES 12/8/10 12:02 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:04 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:06 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:07 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:09 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:12 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:24 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:25 PM EPA Interlab L10 1313-1316 SWA
1.11E+03 111% VUICP-OES 12/8/10 12:27 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:29 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:30 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:32 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:33 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:35 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:37 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:43 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 12:45 PM EPA Interlab L10 1313-1316 SWA
1.13E+03 113% VUICP-OES 12/8/10 12:47 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:48 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:50 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:52 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:53 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:55 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 12:57 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :56 AM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 1 :57 AM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                          1-583
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al SWA-L11-1313-T01-A 1
Al SWA-L11-1313-T02-A 1
Al SWA-L11-1313-T03-A 1
Al SWA-L11-1313-T04-A 1
Al SWA-L11-1313-T05-A 1
Al SWA-L11-1313-T06-A 1
Al SWA-L11-1313-T07-A 1
Al SWA-L11-1313-T08-A 1
Al SWA-L11-1313-T09-A 1
Al SWA-L11-1313-T01-B 1
Al SWA-L11-1313-T02-B 1
Al SWA-L11-1313-T03-B 1
Al SWA-L11-1313-T04-B 1
Al SWA-L11-1313-T05-B 1
Al SWA-L11-1313-T06-B 1
Al SWA-L11-1313-T07-B 1
Al SWA-L11-1313-T08-B 1
Al SWA-L11-1313-T09-B 1
Al SWA-L11-1313-T01-C 1
Al SWA-L11-1313-T02-C 1
Al SWA-L11-1313-T03-C 1
Al SWA-L11-1313-T04-C 1
Al SWA-L11-1313-T05-C 1
Al SWA-L11-1313-T06-C 1
Al SWA-L11-1313-T07-C 1
Al SWA-L11-1313-T08-C 1
Al SWA-L11-1313-T09-C 1
Al SWA-L11-1313-B01-A 1
Al SWA-L11-1313-B02-A 1
Sample
Cone. Qualifier
ug/L
3.41 E+04
1.21E+03
2.96E+02
1.16E+02
1.93E+01
9.08E+00
8.79E+03
2.41 E+05
7.19E+05
3.36E+04
9.87E+02
5.83E+02
9.35E+01
1.81E+01
1.27E+01
8.92E+03
2.31 E+05
7.20E+05
3.42E+04
8.92E+03
2.79E+02
1.05E+02
2.57E+01
4.07E+01
7.66E+03
2.25E+05
6.96E+05
5.59E+00
6.77E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.41 E+04 1.7E+00 1.0E+00 3.2E+00
1.21E+03 3.3E-01 1.0E+00 3.2E+00
2.96E+02 3.6E+01 1.0E+00 3.2E+00 1000 100
1.16E+02 8.4E+00 1.0E+00 3.2E+00
1.93E+01 4.2E+01 1.0E+00 3.2E+00
9.08E+00 1.5E+02 1.0E+00 3.2E+00
8.79E+03 4.0E-01 1.0E+00 3.2E+00
2.41 E+05 6.6E-01 1.0E+00 3.2E+00
7.19E+05 7.4E-01 1.0E+00 3.2E+00
3.36E+04 6.6E-01 1.0E+00 3.2E+00
9.87E+02 4.0E-01 1.0E+00 3.2E+00
5.83E+02 9.6E-01 1.0E+00 3.2E+00 1000 100
9.35E+01 2.8E+00 1.0E+00 3.2E+00
1.81E+01 1.7E+01 1.0E+00 3.2E+00
1.27E+01 9.4E+01 1.0E+00 3.2E+00
8.92E+03 1.9E+00 1.0E+00 3.2E+00
2.31 E+05 1.1E+02 1.0E+00 3.2E+00
7.20E+05 1.7E+00 1.0E+00 3.2E+00
3.42E+04 3.6E-01 1.0E+00 3.2E+00
8.92E+03 8.1E-01 1.0E+00 3.2E+00
2.79E+02 2.2E+00 1.0E+00 3.2E+00 1000 100
1.05E+02 4.9E+00 1.0E+00 3.2E+00
2.57E+01 1.9E+01 1.0E+00 3.2E+00
4.07E+01 6.2E+00 1.0E+00 3.2E+00
7.66E+03 2.0E-01 1.0E+00 3.2E+00
2.25E+05 7.4E+00 1.0E+00 3.2E+00
6.96E+05 3.3E-01 1.0E+00 3.2E+00
5.59E+00 2.8E+02 1.0E+00 3.2E+00
6.77E+00 3.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .26E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .51 E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .1 7E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                                   1-584
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L11-1313-T01-A 1
Sb SWA-L11-1313-T02-A 1
Sb SWA-L11-1313-T03-A 1
Sb SWA-L11-1313-T04-A 1
Sb SWA-L11-1313-T05-A 1
Sb SWA-L11-1313-T06-A 1
Sb SWA-L11-1313-T07-A 1
Sb SWA-L11-1313-T08-A 1
Sb SWA-L11-1313-T09-A 1
Sb SWA-L11-1313-T01-B 1
Sb SWA-L11-1313-T02-B 1
Sb SWA-L11-1313-T03-B 1
Sb SWA-L11-1313-T04-B 1
Sb SWA-L11-1313-T05-B 1
Sb SWA-L11-1313-T06-B 1
Sb SWA-L11-1313-T07-B 1
Sb SWA-L11-1313-T08-B 1
Sb SWA-L11-1313-T09-B 1
Sb SWA-L11-1313-T01-C 1
Sb SWA-L11-1313-T02-C 1
Sb SWA-L11-1313-T03-C 1
Sb SWA-L11-1313-T04-C 1
Sb SWA-L11-1313-T05-C 1
Sb SWA-L11-1313-T06-C 1
Sb SWA-L11-1313-T07-C 1
Sb SWA-L11-1313-T08-C 1
Sb SWA-L11-1313-T09-C 1
Sb SWA-L11-1313-B01-A 1
Sb SWA-L11-1313-B02-A 1
Sample
Cone. Qualifier
ug/L
3.73E+03
9.88E+02
9.22E+02
8.01 E+02
6.05E+02
5.89E+02
4.33E+02
2.48E+02
1.87E+03
3.19E+03
1.01E+03
1.12E+03
8.68E+02
5.49E+02
5.30E+02
5.52E+02
2.44E+02
2.12E+03
2.99E+03
1 .56E+03
1 .38E+03
8.57E+02
5.18E+02
7.10E+02
4.34E+02
2.53E+02
2.33E+03
3.75E+00 U1/2
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.73E+03 4.5E-01 7.5E+00 2.4E+01
9.88E+02 9.1E+00 7.5E+00 2.4E+01
9.22E+02 3.8E+01 7.5E+00 2.4E+01 10 100
8.01E+02 8.1E+00 7.5E+00 2.4E+01
6.05E+02 1.3E+00 7.5E+00 2.4E+01
5.89E+02 8.4E+01 7.5E+00 2.4E+01
4.33E+02 1.6E+00 7.5E+00 2.4E+01
2.48E+02 4.6E+00 7.5E+00 2.4E+01
1.87E+03 2.8E+00 7.5E+00 2.4E+01
3.19E+03 4.2E-01 7.5E+00 2.4E+01
1.01E+03 8.0E+00 7.5E+00 2.4E+01
1.12E+03 1.8E+00 7.5E+00 2.4E+01 10 100
8.68E+02 7.2E-01 7.5E+00 2.4E+01
5.49E+02 3.0E+00 7.5E+00 2.4E+01
5.30E+02 3.2E+00 7.5E+00 2.4E+01
5.52E+02 3.4E+00 7.5E+00 2.4E+01
2.44E+02 1.1 E+02 7.5E+00 2.4E+01
2.12E+03 7.2E-01 7.5E+00 2.4E+01
2.99E+03 3.2E-01 7.5E+00 2.4E+01
1.56E+03 1.5E+00 7.5E+00 2.4E+01
1.38E+03 3.6E-01 7.5E+00 2.4E+01 10 100
8.57E+02 1.2E+00 7.5E+00 2.4E+01
5.18E+02 5.0E+00 7.5E+00 2.4E+01
7.10E+02 2.6E+00 7.5E+00 2.4E+01
4.34E+02 2.6E+00 7.5E+00 2.4E+01
2.53E+02 8.5E+00 7.5E+00 2.4E+01
2.33E+03 2.9E+00 7.5E+00 2.4E+01
3.75E+00 3.0E+01 7.5E+00 2.4E+01
3.75E+00 4.8E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .92E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.18E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.42E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
4/7/11 4:11 PM EPAInterlabLH 1313-1316 SWA
4/7/11 4:13 PM EPA InterlabLH 1313-1316 SWA
4/7/11 4:14 PM EPA InterlabLH 1313-1316 SWA
4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-585
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-L11-1313-T01-A 1
As SWA-L11-1313-T02-A 1
As SWA-L11-1313-T03-A 1
As SWA-L11-1313-T04-A 1
As SWA-L11-1313-T05-A 1
As SWA-L11-1313-T06-A 1
As SWA-L11-1313-T07-A 1
As SWA-L11-1313-T08-A 1
As SWA-L11-1313-T09-A 1
As SWA-L11-1313-T01-B 1
As SWA-L11-1313-T02-B 1
As SWA-L11-1313-T03-B 1
As SWA-L11-1313-T04-B 1
As SWA-L11-1313-T05-B 1
As SWA-L11-1313-T06-B 1
As SWA-L11-1313-T07-B 1
As SWA-L11-1313-T08-B 1
As SWA-L11-1313-T09-B 1
As SWA-L11-1313-T01-C 1
As SWA-L11-1313-T02-C 1
As SWA-L11-1313-T03-C 1
As SWA-L11-1313-T04-C 1
As SWA-L11-1313-T05-C 1
As SWA-L11-1313-T06-C 1
As SWA-L11-1313-T07-C 1
As SWA-L11-1313-T08-C 1
As SWA-L11-1313-T09-C 1
As SWA-L11-1313-B01-A 1
As SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
4.67E+03
2.89E+02
1.27E+02
1.39E+02
8.83E+01
7.53E+01
3.05E+02
1.66E+03
7.30E+03
4.30E+03
2.95E+02
2.03E+02
1.47E+02
9.52E+01
9.41E+01
1.18E+03
1.71E+03
8.35E+03
4.45E+03
7.28E+02
1 .98E+02
1 .46E+02
9.59E+01
7.02E+01
4.22E+02
1 .56E+03
7.27E+03
5.50E+00 U1/2
5.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.67E+03 9.5E-01 1.1E+01 3.5E+01
2.89E+02 5.1E+00 1.1E+01 3.5E+01
1.27E+02 4.6E+01 1.1E+01 3.5E+01 10 100
1.39E+02 1.1E+01 1.1E+01 3.5E+01
8.83E+01 3.2E+01 1.1E+01 3.5E+01
7.53E+01 4.4E+01 1.1E+01 3.5E+01
3.05E+02 1.0E+00 1.1E+01 3.5E+01
1.66E+03 8.1E-01 1.1E+01 3.5E+01
7.30E+03 1.2E+00 1.1E+01 3.5E+01
4.30E+03 7.1E-01 1.1E+01 3.5E+01
2.95E+02 8.7E+00 1.1E+01 3.5E+01
2.03E+02 5.6E+00 1.1E+01 3.5E+01 10 100
1.47E+02 1.2E+01 1.1E+01 3.5E+01
9.52E+01 2.5E+00 1.1E+01 3.5E+01
9.41E+01 1.1E+01 1.1E+01 3.5E+01
1.18E+03 1.1E+00 1.1E+01 3.5E+01
1.71E+03 1.4E+02 1.1E+01 3.5E+01
8.35E+03 7.6E-01 1.1E+01 3.5E+01
4.45E+03 7.4E-01 1.1E+01 3.5E+01
7.28E+02 2.4E+00 1.1E+01 3.5E+01
1.98E+02 6.9E+00 1.1E+01 3.5E+01 10 100
1.46E+02 9.2E+00 1.1E+01 3.5E+01
9.59E+01 1.4E+01 1.1E+01 3.5E+01
7.02E+01 2.3E+01 1.1E+01 3.5E+01
4.22E+02 1.4E+00 1.1E+01 3.5E+01
1.56E+03 2.6E+00 1.1E+01 3.5E+01
7.27E+03 8.0E-01 1.1E+01 3.5E+01
5.50E+00 2.5E+01 1.1E+01 3.5E+01
5.50E+00 2.4E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
1.13E+03 101% VUICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.18E+03 98% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.16E+03 96% VUICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-586
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-L11-1313-T01-A 1
B SWA-L11-1313-T02-A 1
B SWA-L11-1313-T03-A 1
B SWA-L11-1313-T04-A 1
B SWA-L11-1313-T05-A 1
B SWA-L11-1313-T06-A 1
B SWA-L11-1313-T07-A 1
B SWA-L11-1313-T08-A 1
B SWA-L11-1313-T09-A 1
B SWA-L11-1313-T01-B 1
B SWA-L11-1313-T02-B 1
B SWA-L11-1313-T03-B 1
B SWA-L11-1313-T04-B 1
B SWA-L11-1313-T05-B 1
B SWA-L11-1313-T06-B 1
B SWA-L11-1313-T07-B 1
B SWA-L11-1313-T08-B 1
B SWA-L11-1313-T09-B 1
B SWA-L11-1313-T01-C 1
B SWA-L11-1313-T02-C 1
B SWA-L11-1313-T03-C 1
B SWA-L11-1313-T04-C 1
B SWA-L11-1313-T05-C 1
B SWA-L11-1313-T06-C 1
B SWA-L11-1313-T07-C 1
B SWA-L11-1313-T08-C 1
B SWA-L11-1313-T09-C 1
B SWA-L11-1313-B01-A 1
B SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
6.68E+02
6.44E+02
8.33E+02
1.38E+03
3.80E+03
3.75E+03
3.22E+03
3.88E+03
4.83E+03
6.57E+02
6.50E+02
8.97E+02
1.45E+03
4.23E+03
3.73E+03
3.56E+03
4.17E+03
4.66E+03
7.33E+02
7.39E+02
9.45E+02
1 .46E+03
3.80E+03
3.92E+03
3.38E+03
4.03E+03
4.95E+03
3.56E+00
1.30E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.68E+02 5.6E-01 1.0E+00 3.2E+00
6.44E+02 5.2E+00 1.0E+00 3.2E+00
8.33E+02 3.8E+01 1.0E+00 3.2E+00 1000 100
1.38E+03 7.7E+00 1.0E+00 3.2E+00
3.80E+03 5.6E-01 1.0E+00 3.2E+00
3.75E+03 8.6E+01 1.0E+00 3.2E+00
3.22E+03 5.6E-01 1.0E+00 3.2E+00
3.88E+03 3.5E-01 1.0E+00 3.2E+00
4.83E+03 1.6E+00 1.0E+00 3.2E+00
6.57E+02 3.5E-01 1.0E+00 3.2E+00
6.50E+02 4.2E+00 1.0E+00 3.2E+00
8.97E+02 1.3E+00 1.0E+00 3.2E+00 1000 100
1.45E+03 5.5E-01 1.0E+00 3.2E+00
4.23E+03 7.0E-01 1.0E+00 3.2E+00
3.73E+03 3.6E+00 1.0E+00 3.2E+00
3.56E+03 2.0E+00 1.0E+00 3.2E+00
4.17E+03 9.1E+01 1.0E+00 3.2E+00
4.66E+03 1.2E+00 1 .OE+00 3.2E+00
7.33E+02 3.0E-01 1 .OE+00 3.2E+00
7.39E+02 3.3E+00 1 .OE+00 3.2E+00
9.45E+02 9.8E-01 1 .OE+00 3.2E+00 1000 100
1.46E+03 2.4E-01 1 .OE+00 3.2E+00
3.80E+03 3.8E+00 1 .OE+00 3.2E+00
3.92E+03 1.7E+00 1 .OE+00 3.2E+00
3.38E+03 2.3E-01 1 .OE+00 3.2E+00
4.03E+03 2.7E+00 1 .OE+00 3.2E+00
4.95E+03 6.3E-01 1 .OE+00 3.2E+00
3.56E+00 1.0E+02 1 .OE+00 3.2E+00
1.30E+01 3.5E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
1.82E+03 99% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.88E+03 98% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.87E+03 92% VUICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-587
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba SWA-L11-1313-T01-A 1
Ba SWA-L11-1313-T02-A 1
Ba SWA-L11-1313-T03-A 1
Ba SWA-L11-1313-T04-A 1
Ba SWA-L11-1313-T05-A 1
Ba SWA-L11-1313-T06-A 1
Ba SWA-L11-1313-T07-A 1
Ba SWA-L11-1313-T08-A 1
Ba SWA-L11-1313-T09-A 1
Ba SWA-L11-1313-T01-B 1
Ba SWA-L11-1313-T02-B 1
Ba SWA-L11-1313-T03-B 1
Ba SWA-L11-1313-T04-B 1
Ba SWA-L11-1313-T05-B 1
Ba SWA-L11-1313-T06-B 1
Ba SWA-L11-1313-T07-B 1
Ba SWA-L11-1313-T08-B 1
Ba SWA-L11-1313-T09-B 1
Ba SWA-L11-1313-T01-C 1
Ba SWA-L11-1313-T02-C 1
Ba SWA-L11-1313-T03-C 1
Ba SWA-L11-1313-T04-C 1
Ba SWA-L11-1313-T05-C 1
Ba SWA-L11-1313-T06-C 1
Ba SWA-L11-1313-T07-C 1
Ba SWA-L11-1313-T08-C 1
Ba SWA-L11-1313-T09-C 1
Ba SWA-L11-1313-B01-A 1
Ba SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
2.45E+02
5.40E+02
8.60E+02
6.46E+02
1.19E+03
1.31E+03
1.39E+03
7.89E+02
7.52E+02
2.34E+02
5.54E+02
9.51 E+02
6.90E+02
1.34E+03
1.33E+03
9.95E+02
7.26E+02
7.40E+02
2.46E+02
5.00E+02
9.75E+02
6.82E+02
1.31E+03
1.15E+03
1 .30E+03
7.16E+02
7.98E+02
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.45E+02 6.0E-01 1.0E+00 3.2E+00
5.40E+02 3.7E-01 1.0E+00 3.2E+00
8.60E+02 2.8E+01 1.0E+00 3.2E+00 10 100
6.46E+02 6.1E+00 1.0E+00 3.2E+00
1.19E+03 1.9E-01 1.0E+00 3.2E+00
1.31E+03 1.1 E+02 1.0E+00 3.2E+00
1.39E+03 1.0E-01 1.0E+00 3.2E+00
7.89E+02 1.3E-01 1.0E+00 3.2E+00
7.52E+02 4.3E-01 1.0E+00 3.2E+00
2.34E+02 7.2E-01 1.0E+00 3.2E+00
5.54E+02 1.2E+00 1.0E+00 3.2E+00
9.51E+02 1.2E+00 1.0E+00 3.2E+00 10 100
6.90E+02 3.1E-01 1.0E+00 3.2E+00
1.34E+03 5.3E-01 1.0E+00 3.2E+00
1.33E+03 2.9E+00 1.0E+00 3.2E+00
9.95E+02 1.9E+00 1.0E+00 3.2E+00
7.26E+02 1.4E+02 1.0E+00 3.2E+00
7.40E+02 8.6E-01 1 .OE+00 3.2E+00
2.46E+02 1. OE+00 1 .OE+00 3.2E+00
5.00E+02 6.1E-01 1 .OE+00 3.2E+00
9.75E+02 8.1E-01 1 .OE+00 3.2E+00 10 100
6.82E+02 5.4E-01 1 .OE+00 3.2E+00
1.31E+03 3.1E+00 1. OE+00 3.2E+00
1.15E+03 2.0E+00 1 .OE+00 3.2E+00
1.30E+03 3.7E-01 1 .OE+00 3.2E+00
7.16E+02 1.9E+00 1 .OE+00 3.2E+00
7.98E+02 6.0E-01 1 .OE+00 3.2E+00
5.00E-01 1.8E+02 1. OE+00 3.2E+00
5.00E-01 1.7E+01 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
1.94E+03 108% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.93E+03 98% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.83E+03 85% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-588
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L11-1313-T01-A 1
Be SWA-L11-1313-T02-A 1
Be SWA-L11-1313-T03-A 1
Be SWA-L11-1313-T04-A 1
Be SWA-L11-1313-T05-A 1
Be SWA-L11-1313-T06-A 1
Be SWA-L11-1313-T07-A 1
Be SWA-L11-1313-T08-A 1
Be SWA-L11-1313-T09-A 1
Be SWA-L11-1313-T01-B 1
Be SWA-L11-1313-T02-B 1
Be SWA-L11-1313-T03-B 1
Be SWA-L11-1313-T04-B 1
Be SWA-L11-1313-T05-B 1
Be SWA-L11-1313-T06-B 1
Be SWA-L11-1313-T07-B 1
Be SWA-L11-1313-T08-B 1
Be SWA-L11-1313-T09-B 1
Be SWA-L11-1313-T01-C 1
Be SWA-L11-1313-T02-C 1
Be SWA-L11-1313-T03-C 1
Be SWA-L11-1313-T04-C 1
Be SWA-L11-1313-T05-C 1
Be SWA-L11-1313-T06-C 1
Be SWA-L11-1313-T07-C 1
Be SWA-L11-1313-T08-C 1
Be SWA-L11-1313-T09-C 1
Be SWA-L11-1313-B01-A 1
Be SWA-L11-1313-B02-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
3.55E+01
1.05E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
4.87E+00 E
3.21 E+01
1.02E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
3.08E+01
1.08E+02
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 3.5E+01 1.9E+00 6.0E+00
9.50E-01 5.6E+02 1.9E+00 6.0E+00
9.50E-01 9.8E+01 1.9E+00 6.0E+00 10 100
9.50E-01 6.1E+00 1.9E+00 6.0E+00
9.50E-01 5.1E+02 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
3.55E+01 1.1E+00 1.9E+00 6.0E+00
1.05E+02 1.5E+00 1.9E+00 6.0E+00
9.50E-01 6.5E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00 10 100
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
4.87E+00 1.1 E+01 1.9E+00 6.0E+00
3.21 E+01 9.0E+01 1.9E+00 6.0E+00
1.02E+02 2.4E+00 1.9E+00 6.0E+00
9.50E-01 4.2E+02 1.9E+00 6.0E+00
9.50E-01 4.3E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00 10 100
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 3.5E+02 1.9E+00 6.0E+00
9.50E-01 8.8E+01 1.9E+00 6.0E+00
3.08E+01 5.3E+00 1.9E+00 6.0E+00
1.08E+02 6.3E-01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
1.05E+03 105% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.03E+03 103% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.06E+03 106% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-589
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L11-1313-T01-A 1 1.10E+OOU1/2 1.10E+00 1 .4E+02 2.2E+00 7.0E+00
Cd SWA-L11-1313-T02-A 1 1.10E+OOU1/2 1.10E+00 2.2E+02 2.2E+00 7.0E+00
Cd SWA-L11-1313-T03-A 1 1.10E+OOU1/2 1.10E+00 1.2E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L11-1313-T04-A 1 1.10E+OOU1/2 1.10E+00 2.7E+02 2.2E+00 7.0E+00
Cd SWA-L11-1313-T05-A 1 1.10E+OOU1/2 1.10E+00 2.4E+02 2.2E+00 7.0E+00
Cd SWA-L11-1313-T06-A 1 1.10E+OOU1/2 1.10E+00 3.5E+01 2.2E+00 7.0E+00
Cd SWA-L11-1313-T07-A 1 8.23E+00
Cd SWA-L11-1313-T08-A 1 1.23E+01
Cd SWA-L11-1313-T09-A 1 2.65E+01
8.23E+00 6.1E+00 2.2E+00 7.0E+00
1.23E+01 1.8E+00 2.2E+00 7.0E+00
2.65E+01 5.7E-01 2.2E+00 7.0E+00
Cd SWA-L11-1313-T01-B 1 1.10E+OOU1/2 1.10E+00 4.1E+01 2.2E+00 7.0E+00
Cd SWA-L11-1313-T02-B 1 1.10E+OOU1/2 1.10E+00 7.8E+01 2.2E+00 7.0E+00
Cd SWA-L11-1313-T03-B 1 1.10E+OOU1/2 1.10E+00 4.1E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L11-1313-T04-B 1 1.10E+OOU1/2 1.10E+00 7.4E+01 2.2E+00 7.0E+00
Cd SWA-L11-1313-T05-B 1 1.10E+OOU1/2 1.10E+00 6.8E+00 2.2E+00 7.0E+00
Cd SWA-L11-1313-T06-B 1 1.10E+OOU1/2 1.10E+00 1.3E+02 2.2E+00 7.0E+00
Cd SWA-L11-1313-T07-B 1 1.02E+01
Cd SWA-L11-1313-T08-B 1 1.28E+01
Cd SWA-L11-1313-T09-B 1 2.68E+01
1.02E+01 2.1E+00 2.2E+00 7.0E+00
1.28E+01 2.5E+02 2.2E+00 7.0E+00
2.68E+01 7.2E-01 2.2E+00 7.0E+00
Cd SWA-L11-1313-T01-C 1 1.10E+OOU1/2 1.10E+00 4.1E+01 2.2E+00 7.0E+00
Cd SWA-L11-1313-T02-C 1 1.10E+OOU1/2 1.10E+00 1.6E+02 2.2E+00 7.0E+00
Cd SWA-L11-1313-T03-C 1 1.10E+OOU1/2 1.10E+00 4.8E+01 2.2E+00 7.0E+00 10 100
Cd SWA-L11-1313-T04-C 1 1.10E+OOU1/2 1.10E+00 7.6E+01 2.2E+00 7.0E+00
Cd SWA-L11-1313-T05-C 1 1.10E+OOU1/2 1.10E+00 5.1E+01 2.2E+00 7.0E+00
Cd SWA-L11-1313-T06-C 1 1.10E+OOU1/2 1.10E+00 1.5E+02 2.2E+00 7.0E+00
Cd SWA-L11-1313-T07-C 1 1.16E+01
Cd SWA-L11-1313-T08-C 1 1 .23E+01
Cd SWA-L11-1313-T09-C 1 2.84E+01
1.16E+01 2.1E+00 2.2E+00 7.0E+00
1.23E+01 3.6E+00 2.2E+00 7.0E+00
2.84E+01 7.9E-01 2.2E+00 7.0E+00
Cd SWA-L11-1313-B01-A 1 1.10E+OOU1/2 1.10E+00 4.1E+01 2.2E+00 7.0E+00
Cd SWA-L11-1313-B02-A 1 1.10E+OOU1/2 1.10E+00 8.4E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
9.18E+02 92%VUICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
9.73E+02 97% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.02E+03 102% VUICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-590
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca SWA-L11-1313-T01-A 1
Ca SWA-L11-1313-T02-A 1
Ca SWA-L11-1313-T03-A 1
Ca SWA-L11-1313-T04-A 1
Ca SWA-L11-1313-T05-A 1
Ca SWA-L11-1313-T06-A 1
Ca SWA-L11-1313-T07-A 1
Ca SWA-L11-1313-T08-A 1
Ca SWA-L11-1313-T09-A 1
Ca SWA-L11-1313-T01-B 1
Ca SWA-L11-1313-T02-B 1
Ca SWA-L11-1313-T03-B 1
Ca SWA-L11-1313-T04-B 1
Ca SWA-L11-1313-T05-B 1
Ca SWA-L11-1313-T06-B 1
Ca SWA-L11-1313-T07-B 1
Ca SWA-L11-1313-T08-B 1
Ca SWA-L11-1313-T09-B 1
Ca SWA-L11-1313-T01-C 1
Ca SWA-L11-1313-T02-C 1
Ca SWA-L11-1313-T03-C 1
Ca SWA-L11-1313-T04-C 1
Ca SWA-L11-1313-T05-C 1
Ca SWA-L11-1313-T06-C 1
Ca SWA-L11-1313-T07-C 1
Ca SWA-L11-1313-T08-C 1
Ca SWA-L11-1313-T09-C 1
Ca SWA-L11-1313-B01-A 1
Ca SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
1.53E+04
2.68E+05
1.65E+06
3.64E+06
7.07E+06
6.88E+06
6.32E+06
4.11E+06
3.08E+06
1.54E+04
3.07E+05
2.12E+06
3.88E+06
6.76E+06
7.08E+06
4.72E+06
4.16E+06
3.23E+06
1.56E+04
5.34E+04
2.46E+06
3.85E+06
6.99E+06
7.25E+06
6.05E+06
4.27E+06
3.04E+06
1.06E+02
8.93E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+04 4.0E-01 2.6E+00 8.3E+00
2.68E+05 5.3E-01 2.6E+00 8.3E+00
1.65E+06 4.4E+01 2.6E+00 8.3E+00 1000 100
3.64E+06 7.0E+00 2.6E+00 8.3E+00
7.07E+06 7.0E-01 2.6E+00 8.3E+00
6.88E+06 1.3E+02 2.6E+00 8.3E+00
6.32E+06 4.0E-01 2.6E+00 8.3E+00
4.11E+06 3.2E-01 2.6E+00 8.3E+00
3.08E+06 1.1E-01 2.6E+00 8.3E+00
1.54E+04 3.2E-01 2.6E+00 8.3E+00
3.07E+05 1.3E+00 2.6E+00 8.3E+00
2.12E+06 6.3E-01 2.6E+00 8.3E+00 1000 100
3.88E+06 9.7E-01 2.6E+00 8.3E+00
6.76E+06 8.8E-01 2.6E+00 8.3E+00
7.08E+06 3.3E+00 2.6E+00 8.3E+00
4.72E+06 1.8E+00 2.6E+00 8.3E+00
4.16E+06 1.2E+02 2.6E+00 8.3E+00
3.23E+06 3.9E-01 2.6E+00 8.3E+00
1.56E+04 9.0E-01 2.6E+00 8.3E+00
5.34E+04 4.4E-01 2.6E+00 8.3E+00
2.46E+06 8.0E-01 2.6E+00 8.3E+00 1000 100
3.85E+06 1.1E+00 2.6E+00 8.3E+00
6.99E+06 2.9E+00 2.6E+00 8.3E+00
7.25E+06 3.2E-01 2.6E+00 8.3E+00
6.05E+06 7.3E-01 2.6E+00 8.3E+00
4.27E+06 5.4E+00 2.6E+00 8.3E+00
3.04E+06 2.2E-01 2.6E+00 8.3E+00
1.06E+02 1.4E+02 2.6E+00 8.3E+00
8.93E+01 6.5E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
1.65E+06 85% VUICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
2.13E+06 82% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
2.46E+06 82% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:51 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-591
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Sample Dilution
SWA-L11-1313-T01-A 1
SWA-L11-1313-T02-A 1
SWA-L11-1313-T03-A 1
SWA-L11-1313-T04-A 1
SWA-L11-1313-T05-A 1
SWA-L11-1313-T06-A 1
SWA-L11-1313-T07-A 1
SWA-L11-1313-T08-A 1
SWA-L11-1313-T09-A 1
SWA-L11-1313-T01-B 1
SWA-L11-1313-T02-B 1
SWA-L11-1313-T03-B 1
SWA-L11-1313-T04-B 1
SWA-L11-1313-T05-B 1
SWA-L11-1313-T06-B 1
SWA-L11-1313-T07-B 1
SWA-L11-1313-T08-B 1
SWA-L11-1313-T09-B 1
SWA-L11-1313-T01-C 1
SWA-L11-1313-T02-C 1
SWA-L11-1313-T03-C 1
SWA-L11-1313-T04-C 1
SWA-L11-1313-T05-C 1
SWA-L11-1313-T06-C 1
SWA-L11-1313-T07-C 1
SWA-L11-1313-T08-C 1
SWA-L11-1313-T09-C 1
SWA-L11-1313-B01-A 1
SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
5.41 E+02
1.05E+01
2.30E+00 E
8.81 E+00
6.00E-01 U1/2
6.00E-01 U1/2
9.61 E+01
3.42E+03
1.58E+04
6.08E+02
1.04E+01
4.34E+00
9.53E+00
1.48E+00 E
6.00E-01 U1/2
7.66E+02
3.22E+03
1.57E+04
5.91 E+02
4.68E+01
3.28E+00 E
6.32E+00
6.00E-01 U1/2
6.00E-01 U1/2
9.75E+01
3.15E+03
1.57E+04
6.00E-01 U1/2
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.41 E+02 5.4E-01 1.2E+00 3.8E+00
1.05E+01 2.6E+00 1.2E+00 3.8E+00
2.30E+00 5.0E+01 1.2E+00 3.8E+00 10 100
8.81 E+00 7.7E+00 1.2E+00 3.8E+00
6.00E-01 5.7E+01 1.2E+00 3.8E+00
6.00E-01 5.1 E+01 1.2E+00 3.8E+00
9.61 E+01 5.1E-01 1.2E+00 3.8E+00
3.42E+03 6.0E-01 1.2E+00 3.8E+00
1.58E+04 7.1E-01 1.2E+00 3.8E+00
6.08E+02 4.6E-01 1.2E+00 3.8E+00
1.04E+01 6.5E+00 1.2E+00 3.8E+00
4.34E+00 3.6E+00 1.2E+00 3.8E+00 10 100
9.53E+00 1.0E+01 1.2E+00 3.8E+00
1.48E+00 1.3E+01 1.2E+00 3.8E+00
6.00E-01 3.6E+02 1.2E+00 3.8E+00
7.66E+02 1.7E+00 1.2E+00 3.8E+00
3.22E+03 8.8E+01 1.2E+00 3.8E+00
1.57E+04 7.8E-01 1.2E+00 3.8E+00
5.91 E+02 1.1 E+00 1.2E+00 3.8E+00
4.68E+01 2.0E+00 1.2E+00 3.8E+00
3.28E+00 1.3E+01 1.2E+00 3.8E+00 10 100
6.32E+00 1.1 E+01 1.2E+00 3.8E+00
6.00E-01 2.5E+03 1.2E+00 3.8E+00
6.00E-01 1.1 E+02 1.2E+00 3.8E+00
9.75E+01 7.1E-01 1.2E+00 3.8E+00
3.15E+03 2.6E+00 1.2E+00 3.8E+00
1.57E+04 5.4E-01 1.2E+00 3.8E+00
6.00E-01 2.6E+02 1.2E+00 3.8E+00
6.00E-01 1.2E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
1.02E+03 102% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VU ICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.04E+03 103% VU ICP-OES 4/7/1 1 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.14E+03 114% VUICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-592
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. (
1 1 ug/L |
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Co SWA-L11-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 1 JE+02 1.8E+00 5.7E+00
Co SWA-L11-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 1.1E+01 1.8E+00 5.7E+00
Co SWA-L11-1313-T03-A 1 2.31E+00 E
Co SWA-L11-1313-T04-A 1 2.63E+00 E
Co SWA-L11-1313-T05-A 1 8.83E+01
Co SWA-L11-1313-T06-A 1 1.09E+02
Co SWA-L11-1313-T07-A 1 1.29E+02
Co SWA-L11-1313-T08-A 1 1.21E+02
Co SWA-L11-1313-T09-A 1 1.64E+02
2.31E+00 7.4E+01 1.8E+00 5.7E+00 10 100
2.63E+00 2.5E+01 1.8E+00 5.7E+00
8.83E+01 9.5E-01 1.8E+00 5.7E+00
1.09E+02 1.9E+02 1.8E+00 5.7E+00
1.29E+02 1.4E+00 1.8E+00 5.7E+00
1.21E+02 3.9E-01 1.8E+00 5.7E+00
1.64E+02 4.9E-01 1.8E+00 5.7E+00
Co SWA-L11-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 5.5E+01 1.8E+00 5.7E+00
Co SWA-L11-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 4.4E+01 1.8E+00 5.7E+00
Co SWA-L11-1313-T03-B 1 2.13E+00 E
Co SWA-L11-1313-T04-B 1 1.92E+OOE
Co SWA-L11-1313-T05-B 1 1.62E+02
Co SWA-L11-1313-T06-B 1 1.22E+02
Co SWA-L11-1313-T07-B 1 1.30E+02
Co SWA-L11-1313-T08-B 1 1.15E+02
Co SWA-L11-1313-T09-B 1 1.68E+02
2.13E+00 6.8E+00 1.8E+00 5.7E+00 10 100
1.92E+00 2.6E+01 1.8E+00 5.7E+00
1.62E+02 1.3E+00 1.8E+00 5.7E+00
1.22E+02 1.9E+00 1.8E+00 5.7E+00
1.30E+02 2.2E+00 1.8E+00 5.7E+00
1.15E+02 1.3E+02 1.8E+00 5.7E+00
1.68E+02 1.6E+00 1.8E+00 5.7E+00
Co SWA-L11-1313-T01-C 1 9.00E-01 U1/2 9.00E-01 7.6E+00 1.8E+00 5.7E+00
Co SWA-L11-1313-T02-C 1 9.00E-01 U1/2 9.00E-01 4.5E+01 1.8E+00 5.7E+00
Co SWA-L11-1313-T03-C 1 2.31E+00 E
Co SWA-L11-1313-T04-C 1 2.14E+00 E
Co SWA-L11-1313-T05-C 1 1.26E+02
Co SWA-L11-1313-T06-C 1 7.09E+01
Co SWA-L11-1313-T07-C 1 1.56E+02
Co SWA-L11-1313-T08-C 1 1.16E+02
Co SWA-L11-1313-T09-C 1 1.66E+02
2.31E+00 3.1E+01 1.8E+00 5.7E+00 10 100
2.14E+00 3.8E+00 1.8E+00 5.7E+00
1.26E+02 5.3E+00 1.8E+00 5.7E+00
7.09E+01 5.3E-01 1.8E+00 5.7E+00
1.56E+02 1.8E-01 1.8E+00 5.7E+00
1.16E+02 2.8E+00 1.8E+00 5.7E+00
1.66E+02 5.9E-01 1.8E+00 5.7E+00
Co SWA-L11-1313-B01-A 1 9.00E-01 U1/2 9.00E-01 2.7E+02 1.8E+00 5.7E+00
Co SWA-L11-1313-B02-A 1 9.00E-01 U1/2 9.00E-01 1.3E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
1.05E+03 104% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.02E+03 102% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.07E+03 107% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-593
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. (
1 1 ug/L |
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cu SWA-L11-1313-T01-A 1 1.85E+OOU1/2 1.85E+00 1.1E+04 3.7E+00 1.2E+01
Cu SWA-L11-1313-T02-A 1 1.85E+OOU1/2 1.85E+00 6.3E+01 3.7E+00 1.2E+01
Cu SWA-L11-1313-T03-A 1 6.83E+00 E
Cu SWA-L11-1313-T04-A 1 1.12E+01 E
Cu SWA-L11-1313-T05-A 1 1.93E+01
Cu SWA-L11-1313-T06-A 1 1.62E+01
Cu SWA-L11-1313-T07-A 1 1.12E+01 E
Cu SWA-L11-1313-T08-A 1 3.38E+01
Cu SWA-L11-1313-T09-A 1 9.86E+02
6.83E+00 1.5E+01 3.7E+00 1.2E+01 10 100
1.12E+01 1.8E+01 3.7E+00 1.2E+01
1.93E+01 7.4E+00 3.7E+00 1.2E+01
1.62E+01 3.3E+02 3.7E+00 1.2E+01
1.12E+01 1.4E+01 3.7E+00 1.2E+01
3.38E+01 4.2E+00 3.7E+00 1.2E+01
9.86E+02 8.8E-01 3.7E+00 1.2E+01
Cu SWA-L11-1313-T01-B 1 1.85E+OOU1/2 1.85E+00 6.8E+02 3.7E+00 1.2E+01
Cu SWA-L11-1313-T02-B 1 1.85E+OOU1/2 1.85E+00 4.7E+01 3.7E+00 1.2E+01
Cu SWA-L11-1313-T03-B 1 7.32E+00 E
Cu SWA-L11-1313-T04-B 1 8.77E+00 E
Cu SWA-L11-1313-T05-B 1 1.76E+01
Cu SWA-L11-1313-T06-B 1 1.54E+01
Cu SWA-L11-1313-T07-B 1 1.14E+01 E
Cu SWA-L11-1313-T08-B 1 3.79E+01
Cu SWA-L11-1313-T09-B 1 9.15E+02
7.32E+00 4.0E+01 3.7E+00 1.2E+01 10 100
8.77E+00 2.1E+01 3.7E+00 1.2E+01
1.76E+01 7.8E+00 3.7E+00 1.2E+01
1.54E+01 9.3E+00 3.7E+00 1.2E+01
1.14E+01 8.3E+00 3.7E+00 1.2E+01
3.79E+01 2.7E+02 3.7E+00 1.2E+01
9.15E+02 1.1E+00 3.7E+00 1.2E+01
Cu SWA-L11-1313-T01-C 1 1.85E+OOU1/2 1.85E+00 6.8E+02 3.7E+00 1.2E+01
Cu SWA-L11-1313-T02-C 1 1.85E+OOU1/2 1.85E+00 3.8E+02 3.7E+00 1.2E+01
Cu SWA-L11-1313-T03-C 1 5.84E+00 E
Cu SWA-L11-1313-T04-C 1 7.09E+00 E
Cu SWA-L11-1313-T05-C 1 1.27E+01
Cu SWA-L11-1313-T06-C 1 1.19E+01
Cu SWA-L11-1313-T07-C 1 1.25E+01
Cu SWA-L11-1313-T08-C 1 4.05E+01
Cu SWA-L11-1313-T09-C 1 1.07E+03
5.84E+00 2.3E+01 3.7E+00 1.2E+01 10 100
7.09E+00 1.1E+01 3.7E+00 1.2E+01
1.27E+01 1.6E+01 3.7E+00 1.2E+01
1.19E+01 1.2E+01 3.7E+00 1.2E+01
1.25E+01 1.6E+01 3.7E+00 1.2E+01
4.05E+01 2.5E+00 3.7E+00 1.2E+01
1.07E+03 2.4E-01 3.7E+00 1.2E+01
Cu SWA-L11-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 1.0E+02 3.7E+00 1.2E+01
Cu SWA-L11-1313-B02-A 1 1.85E+OOU1/2 1.85E+00 1.8E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
1.04E+03 103% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.03E+03 102% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.03E+03 102% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-594
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe SWA-L11-1313-T01-A 1
Fe SWA-L11-1313-T02-A 1
Fe SWA-L11-1313-T03-A 1
Fe SWA-L11-1313-T04-A 1
Fe SWA-L11-1313-T05-A 1
Fe SWA-L11-1313-T06-A 1
Fe SWA-L11-1313-T07-A 1
Fe SWA-L11-1313-T08-A 1
Fe SWA-L11-1313-T09-A 1
Fe SWA-L11-1313-T01-B 1
Fe SWA-L11-1313-T02-B 1
Fe SWA-L11-1313-T03-B 1
Fe SWA-L11-1313-T04-B 1
Fe SWA-L11-1313-T05-B 1
Fe SWA-L11-1313-T06-B 1
Fe SWA-L11-1313-T07-B 1
Fe SWA-L11-1313-T08-B 1
Fe SWA-L11-1313-T09-B 1
Fe SWA-L11-1313-T01-C 1
Fe SWA-L11-1313-T02-C 1
Fe SWA-L11-1313-T03-C 1
Fe SWA-L11-1313-T04-C 1
Fe SWA-L11-1313-T05-C 1
Fe SWA-L11-1313-T06-C 1
Fe SWA-L11-1313-T07-C 1
Fe SWA-L11-1313-T08-C 1
Fe SWA-L11-1313-T09-C 1
Fe SWA-L11-1313-B01-A 1
Fe SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
7.30E+01
1.73E+01
6.61 E+00
1.86E+01
1.48E+01
1.26E+01
6.93E+04
8.08E+04
1.09E+05
6.65E+01
1.25E+01
1.07E+01
1.59E+01
3.33E+02
3.33E+03
8.57E+04
7.82E+04
1.15E+05
8.09E+01
4.11E+01
1.06E+01
1.81E+01
8.29E+03
3.67E+01
9.79E+04
7.89E+04
1.10E+05
1.00E+00 U1/2
1.11E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.30E+01 8.4E-01 2.0E+00 6.4E+00
1.73E+01 8.6E-01 2.0E+00 6.4E+00
6.61E+00 4.0E+01 2.0E+00 6.4E+00 1000 100
1.86E+01 8.2E+00 2.0E+00 6.4E+00
1.48E+01 3.5E+00 2.0E+00 6.4E+00
1.26E+01 6.2E+01 2.0E+00 6.4E+00
6.93E+04 4.8E-01 2.0E+00 6.4E+00
8.08E+04 7.3E-01 2.0E+00 6.4E+00
1.09E+05 2.2E+00 2.0E+00 6.4E+00
6.65E+01 1.0E+00 2.0E+00 6.4E+00
1.25E+01 3.1 E+00 2.0E+00 6.4E+00
1.07E+01 4.3E+00 2.0E+00 6.4E+00 1000 100
1.59E+01 1.2E+00 2.0E+00 6.4E+00
3.33E+02 8.1E-01 2.0E+00 6.4E+00
3.33E+03 2.3E+00 2.0E+00 6.4E+00
8.57E+04 1.5E+00 2.0E+00 6.4E+00
7.82E+04 9.4E+01 2.0E+00 6.4E+00
1.15E+05 8.5E-01 2.0E+00 6.4E+00
8.09E+01 4.4E+00 2.0E+00 6.4E+00
4.11E+01 1.2E+00 2.0E+00 6.4E+00
1.06E+01 5.0E+00 2.0E+00 6.4E+00 1000 100
1.81E+01 2.6E+00 2.0E+00 6.4E+00
8.29E+03 1.8E+00 2.0E+00 6.4E+00
3.67E+01 3.8E+00 2.0E+00 6.4E+00
9.79E+04 1.6E-01 2.0E+00 6.4E+00
7.89E+04 9.3E-01 2.0E+00 6.4E+00
1.10E+05 6.9E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+02 2.0E+00 6.4E+00
1.11E+01 2.3E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
9.77E+02 97% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
9.67E+02 96% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
9.90E+02 98% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-595
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qu<
Pb SWA-L11-1313-T01-A 1 1.57E+01 E
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.57E+01 3.5E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T02-A 1 3.40E+00 U1/2 3.40E+00 8.7E+02 6.8E+00 2.2E+01
Pb SWA-L11-1313-T03-A 1 3.40E+00 U1/2 3.40E+00 8.5E+01 6.8E+00 2.2E+01 10 100
Pb SWA-L11-1313-T04-A 1 3.40E+00 U1/2 3.40E+00 4.2E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T05-A 1 3.40E+00 U1/2 3.40E+00 1 .OE+02 6.8E+00 2.2E+01
Pb SWA-L11-1313-T06-A 1 3.40E+00 U1/2 3.40E+00 2.5E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T07-A 1 3.40E+00 U1/2 3.40E+00 7.5E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T08-A 1 1.47E+02
Pb SWA-L11-1313-T09-A 1 2.40E+03
Pb SWA-L11-1313-T01-B 1 1.14E+01 E
1.47E+02 4.9E+00 6.8E+00 2.2E+01
2.40E+03 1.8E-01 6.8E+00 2.2E+01
1.14E+01 3.4E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T02-B 1 3.40E+00 U1/2 3.40E+00 1.4E+02 6.8E+00 2.2E+01
Pb SWA-L11-1313-T03-B 1 3.40E+00 U1/2 3.40E+00 3.1E+02 6.8E+00 2.2E+01 10 100
Pb SWA-L11-1313-T04-B 1 3.40E+00 U1/2 3.40E+00 8.4E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T05-B 1 3.40E+00 U1/2 3.40E+00 1.1E+02 6.8E+00 2.2E+01
Pb SWA-L11-1313-T06-B 1 3.40E+00 U1/2 3.40E+00 4.6E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T07-B 1 8.05E+00 E
Pb SWA-L11-1313-T08-B 1 1.56E+02
Pb SWA-L11-1313-T09-B 1 2.30E+03
Pb SWA-L11-1313-T01-C 1 1.77E+01 E
Pb SWA-L11-1313-T02-C 1 6.99E+00 E
8.05E+00 1.7E+02 6.8E+00 2.2E+01
1.56E+02 2.7E+02 6.8E+00 2.2E+01
2.30E+03 3.4E-01 6.8E+00 2.2E+01
1.77E+01 1.1E+01 6.8E+00 2.2E+01
6.99E+00 6.1E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T03-C 1 3.40E+00 U1/2 3.40E+00 2.4E+02 6.8E+00 2.2E+01 10 100
Pb SWA-L11-1313-T04-C 1 3.40E+00 U1/2 3.40E+00 8.0E+02 6.8E+00 2.2E+01
Pb SWA-L11-1313-T05-C 1 3.40E+00 U1/2 3.40E+00 4.0E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T06-C 1 3.40E+00 U1/2 3.40E+00 3.8E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-T07-C 1 3.40E+00 U1/2 3.40E+00 4.4E+02 6.8E+00 2.2E+01
Pb SWA-L11-1313-T08-C 1 1.69E+02
Pb SWA-L11-1313-T09-C 1 2.56E+03
1.69E+02 2.1E+00 6.8E+00 2.2E+01
2.56E+03 8.3E-02 6.8E+00 2.2E+01
Pb SWA-L11-1313-B01-A 1 3.40E+00 U1/2 3.40E+00 3.0E+01 6.8E+00 2.2E+01
Pb SWA-L11-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 3.3E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
1.02E+03 102% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.02E+03 102% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.08E+03 108% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L1 1 1313-1316 SWA
VU ICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:51 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-596
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li SWA-L11-1313-T01-A 1
Li SWA-L11-1313-T02-A 1
Li SWA-L11-1313-T03-A 1
Li SWA-L11-1313-T04-A 1
Li SWA-L11-1313-T05-A 1
Li SWA-L11-1313-T06-A 1
Li SWA-L11-1313-T07-A 1
Li SWA-L11-1313-T08-A 1
Li SWA-L11-1313-T09-A 1
Li SWA-L11-1313-T01-B 1
Li SWA-L11-1313-T02-B 1
Li SWA-L11-1313-T03-B 1
Li SWA-L11-1313-T04-B 1
Li SWA-L11-1313-T05-B 1
Li SWA-L11-1313-T06-B 1
Li SWA-L11-1313-T07-B 1
Li SWA-L11-1313-T08-B 1
Li SWA-L11-1313-T09-B 1
Li SWA-L11-1313-T01-C 1
Li SWA-L11-1313-T02-C 1
Li SWA-L11-1313-T03-C 1
Li SWA-L11-1313-T04-C 1
Li SWA-L11-1313-T05-C 1
Li SWA-L11-1313-T06-C 1
Li SWA-L11-1313-T07-C 1
Li SWA-L11-1313-T08-C 1
Li SWA-L11-1313-T09-C 1
Li SWA-L11-1313-B01-A 1
Li SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
9.50E-01 U1/2
2.09E+01
9.25E+01
3.22E+02
8.32E+02
8.15E+02
8.13E+02
5.61 E+02
6.24E+02
9.50E-01 U1/2
2.40E+01
1.30E+02
3.34E+02
8.06E+02
8.55E+02
6.09E+02
5.75E+02
5.80E+02
9.50E-01 U1/2
5.60E+00 E
1 .53E+02
3.37E+02
8.25E+02
9.15E+02
7.64E+02
5.88E+02
6.50E+02
9.50E-01 U1/2
9.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 9.7E-01 1.9E+00 6.0E+00
2.09E+01 1.4E+00 1.9E+00 6.0E+00
9.25E+01 3.6E+01 1.9E+00 6.0E+00 10 100
3.22E+02 8.6E+00 1.9E+00 6.0E+00
8.32E+02 4.0E+00 1.9E+00 6.0E+00
8.15E+02 9.5E-01 1.9E+00 6.0E+00
8.13E+02 5.9E-01 1.9E+00 6.0E+00
5.61 E+02 3.6E+00 1.9E+00 6.0E+00
6.24E+02 4.1E+00 1.9E+00 6.0E+00
9.50E-01 9.9E-01 1.9E+00 6.0E+00
2.40E+01 3.9E+00 1.9E+00 6.0E+00
1.30E+02 5.6E+00 1.9E+00 6.0E+00 10 100
3.34E+02 8.1E+00 1.9E+00 6.0E+00
8.06E+02 1.4E+00 1.9E+00 6.0E+00
8.55E+02 2.7E+00 1.9E+00 6.0E+00
6.09E+02 3.6E+00 1.9E+00 6.0E+00
5.75E+02 2.5E+00 1.9E+00 6.0E+00
5.80E+02 4.4E+00 1 .9E+00 6.0E+00
9.50E-01 7.1E-01 1.9E+00 6.0E+00
5.60E+00 3.3E+00 1 .9E+00 6.0E+00
1.53E+02 4.0E+00 1 .9E+00 6.0E+00 10 100
3.37E+02 1.7E+00 1 .9E+00 6.0E+00
8.25E+02 7.0E+00 1 .9E+00 6.0E+00
9.15E+02 1.6E+00 1 .9E+00 6.0E+00
7.64E+02 7.7E-01 1 .9E+00 6.0E+00
5.88E+02 6.4E+00 1 .9E+00 6.0E+00
6.50E+02 2.3E+00 1 .9E+00 6.0E+00
9.50E-01 6.6E-01 1 .9E+00 6.0E+00
9.50E-01 4.0E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
9.46E+02 85% VUICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
9.80E+02 85% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
9.89E+02 84% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-597
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn SWA-L11-1313-T01-A 1
Mn SWA-L11-1313-T02-A 1
Mn SWA-L11-1313-T03-A 1
Mn SWA-L11-1313-T04-A 1
Mn SWA-L11-1313-T05-A 1
Mn SWA-L11-1313-T06-A 1
Mn SWA-L11-1313-T07-A 1
Mn SWA-L11-1313-T08-A 1
Mn SWA-L11-1313-T09-A 1
Mn SWA-L11-1313-T01-B 1
Mn SWA-L11-1313-T02-B 1
Mn SWA-L11-1313-T03-B 1
Mn SWA-L11-1313-T04-B 1
Mn SWA-L11-1313-T05-B 1
Mn SWA-L11-1313-T06-B 1
Mn SWA-L11-1313-T07-B 1
Mn SWA-L11-1313-T08-B 1
Mn SWA-L11-1313-T09-B 1
Mn SWA-L11-1313-T01-C 1
Mn SWA-L11-1313-T02-C 1
Mn SWA-L11-1313-T03-C 1
Mn SWA-L11-1313-T04-C 1
Mn SWA-L11-1313-T05-C 1
Mn SWA-L11-1313-T06-C 1
Mn SWA-L11-1313-T07-C 1
Mn SWA-L11-1313-T08-C 1
Mn SWA-L11-1313-T09-C 1
Mn SWA-L11-1313-B01-A 1
Mn SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
7.08E+01
1.46E+04
1.67E+04
1.56E+04
1.30E+04
1.36E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.11E+01
1.87E+04
1.66E+04
1.42E+04
1.26E+04
1.32E+04
2.41 E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
7.85E+00
1.67E+04
1.45E+04
1.71E+04
1.26E+04
1.35E+04
1.00E+00 U1/2
1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.6E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 8.0E+01 2.0E+00 6.4E+00 10 100
7.08E+01 7.5E+00 2.0E+00 6.4E+00
1.46E+04 5.0E-01 2.0E+00 6.4E+00
1.67E+04 9.3E+01 2.0E+00 6.4E+00
1.56E+04 3.9E-01 2.0E+00 6.4E+00
1.30E+04 5.6E-01 2.0E+00 6.4E+00
1.36E+04 1.6E+00 2.0E+00 6.4E+00
1.00E+00 9.3E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00 10 100
1.11E+01 5.7E-01 2.0E+00 6.4E+00
1.87E+04 6.9E-01 2.0E+00 6.4E+00
1.66E+04 2.8E+00 2.0E+00 6.4E+00
1.42E+04 2.2E+00 2.0E+00 6.4E+00
1.26E+04 1.0E+02 2.0E+00 6.4E+00
1.32E+04 1.6E+00 2.0E+00 6.4E+00
2.41 E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00 10 100
7.85E+00 2.9E+00 2.0E+00 6.4E+00
1.67E+04 3.3E+00 2.0E+00 6.4E+00
1.45E+04 2.7E+00 2.0E+00 6.4E+00
1.71E+04 6.8E-01 2.0E+00 6.4E+00
1.26E+04 2.8E+00 2.0E+00 6.4E+00
1.35E+04 4.4E-01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 5.2E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
1.04E+03 104% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.07E+03 107% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L1 1 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.05E+03 105% VU ICP-OES 4/7/1 1 4:46 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-598
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Sample Dilution
SWA-L11-1313-T01-A 1
SWA-L11-1313-T02-A 1
SWA-L11-1313-T03-A 1
SWA-L11-1313-T04-A 1
SWA-L11-1313-T05-A 1
SWA-L11-1313-T06-A 1
SWA-L11-1313-T07-A 1
SWA-L11-1313-T08-A 1
SWA-L11-1313-T09-A 1
SWA-L11-1313-T01-B 1
SWA-L11-1313-T02-B 1
SWA-L11-1313-T03-B 1
SWA-L11-1313-T04-B 1
SWA-L11-1313-T05-B 1
SWA-L11-1313-T06-B 1
SWA-L11-1313-T07-B 1
SWA-L11-1313-T08-B 1
SWA-L11-1313-T09-B 1
SWA-L11-1313-T01-C 1
SWA-L11-1313-T02-C 1
SWA-L11-1313-T03-C 1
SWA-L11-1313-T04-C 1
SWA-L11-1313-T05-C 1
SWA-L11-1313-T06-C 1
SWA-L11-1313-T07-C 1
SWA-L11-1313-T08-C 1
SWA-L11-1313-T09-C 1
SWA-L11-1313-B01-A 1
SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
8.37E+00
9.34E+01
3.12E+03
4.24E+05
1.05E+06
1.04E+06
9.51 E+05
6.51 E+05
5.81 E+05
1.93E+01
9.09E+01
2.16E+03
4.47E+05
1.01E+06
1.04E+06
7.23E+05
6.45E+05
5.71 E+05
3.56E+00
3.03E+01
7.30E+03
4.48E+05
1 .02E+06
1.11E+06
9.12E+05
6.48E+05
5.90E+05
3.54E+01
3.02E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.37E+00 1.4E+02 1.0E+00 3.2E+00
9.34E+01 1.0E+01 1.0E+00 3.2E+00
3.12E+03 4.8E+01 1.0E+00 3.2E+00 1000 100
4.24E+05 8.4E+00 1.0E+00 3.2E+00
1.05E+06 3.9E-01 1.0E+00 3.2E+00
1.04E+06 1.1E+02 1.0E+00 3.2E+00
9.51 E+05 9.6E-02 1.0E+00 3.2E+00
6.51 E+05 2.6E-01 1.0E+00 3.2E+00
5.81 E+05 2.2E-01 1.0E+00 3.2E+00
1.93E+01 5.2E+01 1.0E+00 3.2E+00
9.09E+01 8.4E+00 1.0E+00 3.2E+00
2.16E+03 1.8E+00 1.0E+00 3.2E+00 1000 100
4.47E+05 8.5E-01 1.0E+00 3.2E+00
1.01E+06 1.0E+00 1.0E+00 3.2E+00
1.04E+06 2.9E+00 1.0E+00 3.2E+00
7.23E+05 1.4E+00 1.0E+00 3.2E+00
6.45E+05 1.5E+02 1.0E+00 3.2E+00
5.71 E+05 4.7E-01 1.0E+00 3.2E+00
3.56E+00 6.5E+00 1.0E+00 3.2E+00
3.03E+01 2.9E+01 1.0E+00 3.2E+00
7.30E+03 3.8E-01 1.0E+00 3.2E+00 1000 100
4.48E+05 1.2E+00 1.0E+00 3.2E+00
1.02E+06 2.9E+00 1.0E+00 3.2E+00
1.11E+06 2.1E+00 1.0E+00 3.2E+00
9.12E+05 6.8E-01 1.0E+00 3.2E+00
6.48E+05 1.6E+00 1.0E+00 3.2E+00
5.90E+05 1.4E+00 1.0E+00 3.2E+00
3.54E+01 1.3E+02 1.0E+00 3.2E+00
3.02E+01 8.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
4.19E+03 107% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
3.11E+03 95% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
8.30E+03 100% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-599
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo SWA-L11-1313-T01-A 1
Mo SWA-L11-1313-T02-A 1
Mo SWA-L11-1313-T03-A 1
Mo SWA-L11-1313-T04-A 1
Mo SWA-L11-1313-T05-A 1
Mo SWA-L11-1313-T06-A 1
Mo SWA-L11-1313-T07-A 1
Mo SWA-L11-1313-T08-A 1
Mo SWA-L11-1313-T09-A 1
Mo SWA-L11-1313-T01-B 1
Mo SWA-L11-1313-T02-B 1
Mo SWA-L11-1313-T03-B 1
Mo SWA-L11-1313-T04-B 1
Mo SWA-L11-1313-T05-B 1
Mo SWA-L11-1313-T06-B 1
Mo SWA-L11-1313-T07-B 1
Mo SWA-L11-1313-T08-B 1
Mo SWA-L11-1313-T09-B 1
Mo SWA-L11-1313-T01-C 1
Mo SWA-L11-1313-T02-C 1
Mo SWA-L11-1313-T03-C 1
Mo SWA-L11-1313-T04-C 1
Mo SWA-L11-1313-T05-C 1
Mo SWA-L11-1313-T06-C 1
Mo SWA-L11-1313-T07-C 1
Mo SWA-L11-1313-T08-C 1
Mo SWA-L11-1313-T09-C 1
Mo SWA-L11-1313-B01-A 1
Mo SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
1.18E+02
1.29E+02
1.15E+02
8.14E+01
4.85E+01
3.15E+01
9.59E+00
4.50E+00
5.12E+00
1.12E+02
1.19E+02
1.22E+02
8.78E+01
1.99E+01
3.30E+01
9.29E+00
4.81 E+00
5.46E+00
1.12E+02
1 .26E+02
1.13E+02
8.86E+01
3.07E+01
5.43E+01
8.85E+00
5.70E+00
4.30E+00
6.00E-01 U1/2
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+02 5.2E-01 1.2E+00 3.8E+00
1.29E+02 1.1 E+00 1.2E+00 3.8E+00
1.15E+02 3.9E+01 1.2E+00 3.8E+00 10 100
8.14E+01 6.6E+00 1.2E+00 3.8E+00
4.85E+01 4.5E+00 1.2E+00 3.8E+00
3.15E+01 1.3E+02 1.2E+00 3.8E+00
9.59E+00 1.6E+01 1.2E+00 3.8E+00
4.50E+00 2.7E+01 1.2E+00 3.8E+00
5.12E+00 1.0E+02 1.2E+00 3.8E+00
1.12E+02 8.8E-01 1.2E+00 3.8E+00
1.19E+02 1.2E+00 1.2E+00 3.8E+00
1.22E+02 2.4E-01 1.2E+00 3.8E+00 10 100
8.78E+01 3.5E+00 1.2E+00 3.8E+00
1.99E+01 1.0E+01 1.2E+00 3.8E+00
3.30E+01 9.7E+00 1.2E+00 3.8E+00
9.29E+00 9.9E+00 1.2E+00 3.8E+00
4.81 E+00 2.5E+01 1.2E+00 3.8E+00
5.46E+00 2.9E+01 1.2E+00 3.8E+00
1.12E+02 1.8E+00 1.2E+00 3.8E+00
1.26E+02 1.6E-01 1.2E+00 3.8E+00
1.13E+02 3.3E-01 1.2E+00 3.8E+00 10 100
8.86E+01 1.7E+00 1.2E+00 3.8E+00
3.07E+01 1.0E+01 1.2E+00 3.8E+00
5.43E+01 4.5E+00 1.2E+00 3.8E+00
8.85E+00 2.3E+01 1.2E+00 3.8E+00
5.70E+00 1.9E+01 1.2E+00 3.8E+00
4.30E+00 2.8E+01 1.2E+00 3.8E+00
6.00E-01 5.9E+01 1.2E+00 3.8E+00
6.00E-01 7.6E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
1.16E+03 105% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.07E+03 94% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.15E+03 104% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-600
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L11-1313-T01-A 1 9.00E-01 U1/2 9.00E-01 1 .5E+02 1.8E+00 5.7E+00
Ni SWA-L11-1313-T02-A 1 9.00E-01 U1/2 9.00E-01 1 .OE+02 1.8E+00 5.7E+00
Ni SWA-L11-1313-T03-A 1 2.67E+00 E
Ni SWA-L11-1313-T04-A 1 3.91 E+00 E
Ni SWA-L11-1313-T05-A 1 2.05E+02
Ni SWA-L11-1313-T06-A 1 2.61E+02
Ni SWA-L11-1313-T07-A 1 3.01 E+02
Ni SWA-L11-1313-T08-A 1 2.56E+02
Ni SWA-L11-1313-T09-A 1 2.94E+02
2.67E+00 2.0E+02 1.8E+00 5.7E+00 10 100
3.91 E+00 5.1E+01 1.8E+00 5.7E+00
2.05E+02 1.8E+00 1.8E+00 5.7E+00
2.61 E+02 1.4E+03 1.8E+00 5.7E+00
3.01 E+02 2.8E-01 1.8E+00 5.7E+00
2.56E+02 7.2E-01 1.8E+00 5.7E+00
2.94E+02 8.3E-01 1.8E+00 5.7E+00
Ni SWA-L11-1313-T01-B 1 9.00E-01 U1/2 9.00E-01 9.5E+02 1.8E+00 5.7E+00
Ni SWA-L11-1313-T02-B 1 9.00E-01 U1/2 9.00E-01 1.5E+03 1.8E+00 5.7E+00
Ni SWA-L11-1313-T03-B 1 2.51 E+00 E
Ni SWA-L11-1313-T04-B 1 3.54E+00 E
Ni SWA-L11-1313-T05-B 1 3.54E+02
Ni SWA-L11-1313-T06-B 1 2.85E+02
Ni SWA-L11-1313-T07-B 1 2.75E+02
Ni SWA-L11-1313-T08-B 1 2.59E+02
Ni SWA-L11-1313-T09-B 1 2.91E+02
2.51E+00 1.3E+01 1.8E+00 5.7E+00 10 100
3.54E+00 3.7E+01 1.8E+00 5.7E+00
3.54E+02 4.8E-01 1.8E+00 5.7E+00
2.85E+02 3.1E+00 1.8E+00 5.7E+00
2.75E+02 1.8E+00 1.8E+00 5.7E+00
2.59E+02 1.5E+02 1.8E+00 5.7E+00
2.91 E+02 5.1E-01 1.8E+00 5.7E+00
Ni SWA-L11-1313-T01-C 1 9.00E-01 U1/2 9.00E-01 5.4E+01 1.8E+00 5.7E+00
Ni SWA-L11-1313-T02-C 1 9.00E-01 U1/2 9.00E-01 2.0E+02 1.8E+00 5.7E+00
Ni SWA-L11-1313-T03-C 1 2.01 E+00 E
Ni SWA-L11-1313-T04-C 1 6.40E+00
Ni SWA-L11-1313-T05-C 1 2.96E+02
Ni SWA-L11-1313-T06-C 1 1.68E+02
Ni SWA-L11-1313-T07-C 1 3.37E+02
Ni SWA-L11-1313-T08-C 1 2.58E+02
Ni SWA-L11-1313-T09-C 1 2.99E+02
2.01E+00 7.4E+01 1.8E+00 5.7E+00 10 100
6.40E+00 2.2E+01 1.8E+00 5.7E+00
2.96E+02 3.2E+00 1.8E+00 5.7E+00
1.68E+02 8.2E-01 1.8E+00 5.7E+00
3.37E+02 5.8E-01 1.8E+00 5.7E+00
2.58E+02 2.7E+00 1.8E+00 5.7E+00
2.99E+02 4.9E-01 1.8E+00 5.7E+00
Ni SWA-L11-1313-B01-A 1 9.00E-01 U1/2 9.00E-01 8.6E+00 1.8E+00 5.7E+00
Ni SWA-L11-1313-B02-A 1 9.00E-01 U1/2 9.00E-01 3.4E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
1.05E+03 105% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.07E+03 107% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.02E+03 102% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-601
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone.
1 ug/L
SWA-L11-1313-T01-A 1 2.96E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.96E+01 1.4E+01 3.7E+00 1 .2E+01
SWA-L11-1313-T02-A 1 6.38E+00 E 6.38E+00 1.1E+02 3.7E+00 1 .2E+01
SWA-L11-1313-T03-A 1 4.63E+00 E 4.63E+00 1.4E+03 3.7E+00 1 .2E+01 1000 100
SWA-L11-1313-T04-A 1 1.61E+01
SWA-L11-1313-T05-A 1 2.14E+01
SWA-L11-1313-T06-A 1 1.75E+01
SWA-L11-1313-T07-A 1 2.10E+01
SWA-L11-1313-T08-A 1 2.10E+02
SWA-L11-1313-T09-A 1 1.53E+03
SWA-L11-1313-T01-B 1 2.42E+01
SWA-L11-1313-T02-B 1 1.98E+01
1.61E+01 1.2E+02 3.7E+00 1 .2E+01
2.14E+01 1.4E+02 3.7E+00 1.2E+01
1.75E+01 1.4E+01 3.7E+00 1.2E+01
2.10E+01 3.6E+01 3.7E+00 1.2E+01
2.10E+02 5.2E+00 3.7E+00 1.2E+01
1.53E+03 4.0E-01 3.7E+00 1.2E+01
2.42E+01 7.2E+01 3.7E+00 1.2E+01
1.98E+01 2.2E+01 3.7E+00 1.2E+01
SWA-L11-1313-T03-B 1 4.13E+00 E 4.13E+00 3.4E+02 3.7E+00 1.2E+01 1000 100
SWA-L11-1313-T04-B 1 1.34E+01
SWA-L11-1313-T05-B 1 1.52E+01
SWA-L11-1313-T06-B 1 2.29E+01
SWA-L11-1313-T07-B 1 5.84E+01
SWA-L11-1313-T08-B 1 2.53E+02
SWA-L11-1313-T09-B 1 4.31E+03
SWA-L11-1313-T01-C 1 2.66E+01
SWA-L11-1313-T02-C 1 2.36E+01
1.34E+01 6.0E+01 3.7E+00 1.2E+01
1.52E+01 1.6E+02 3.7E+00 1.2E+01
2.29E+01 1.1E+02 3.7E+00 1.2E+01
5.84E+01 2.3E+00 3.7E+00 1.2E+01
2.53E+02 3.5E+01 3.7E+00 1.2E+01
4.31 E+03 1.3E+00 3.7E+00 1.2E+01
2.66E+01 1.5E+01 3.7E+00 1.2E+01
2.36E+01 1.4E+02 3.7E+00 1.2E+01
SWA-L11-1313-T03-C 1 5.04E+00 E 5.04E+00 4.0E+05 3.7E+00 1.2E+01 1000 100
SWA-L11-1313-T04-C 1 1.53E+01
SWA-L11-1313-T05-C 1 2.72E+01
SWA-L11-1313-T06-C 1 1.35E+01
SWA-L11-1313-T07-C 1 1.99E+01
SWA-L11-1313-T08-C 1 2.71E+02
SWA-L11-1313-T09-C 1 1.47E+03
1.53E+01 1.3E+04 3.7E+00 1.2E+01
2.72E+01 1.9E+02 3.7E+00 1.2E+01
1.35E+01 1.9E+02 3.7E+00 1.2E+01
1.99E+01 2.0E+01 3.7E+00 1.2E+01
2.71 E+02 5.1E+00 3.7E+00 1.2E+01
1.47E+03 5.7E-01 3.7E+00 1.2E+01
SWA-L11-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 6.1E+01 3.7E+00 1.2E+01
SWA-L11-1313-B02-A 1 1.85E+OOU1/2 1.85E+00 1.5E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
1.15E+03 114% VUICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.10E+03 110% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.07E+03 106% VUICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-602
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
1 ug/L
K SWA-L11-1313-T01-A 1 3.19E+05
K SWA-L11-1313-T02-A 1 3.71 E+05
K SWA-L11-1313-T03-A 1 4.05E+05
K SWA-L11-1313-T04-A 1 3.82E+05
K SWA-L11-1313-T05-A 1 4.55E+05
K SWA-L11-1313-T06-A 1 4.47E+05
K SWA-L11-1313-T07-A 1 3.68E+05
K SWA-L11-1313-T08-A 1 2.35E+05
K SWA-L11-1313-T09-A 1 2.94E+05
K SWA-L11-1313-T01-B 1 3.15E+05
K SWA-L11-1313-T02-B 1 3.61E+05
K SWA-L11-1313-T03-B 1 4.19E+05
K SWA-L11-1313-T04-B 1 4.10E+05
K SWA-L11-1313-T05-B 1 4.34E+05
K SWA-L11-1313-T06-B 1 4.50E+05
K SWA-L11-1313-T07-B 1 2.76E+05
K SWA-L11-1313-T08-B 1 2.46E+05
K SWA-L11-1313-T09-B 1 2.90E+05
K SWA-L11-1313-T01-C 1 3.16E+05
K SWA-L11-1313-T02-C 1 3.45E+05
K SWA-L11-1313-T03-C 1 4.12E+05
K SWA-L11-1313-T04-C 1 4.05E+05
K SWA-L11-1313-T05-C 1 4.47E+05
K SWA-L11-1313-T06-C 1 4.52E+05
K SWA-L11-1313-T07-C 1 3.51E+05
K SWA-L11-1313-T08-C 1 2.68E+05
K SWA-L11-1313-T09-C 1 3.24E+05
K SWA-L11-1313-B01-A 1 1.13E+02
K SWA-L11-1313-B02-A 1 6.32E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.19E+05 7.2E-01 1.6E+00 5.1E+00
3.71 E+05 3.1E+00 1.6E+00 5.1E+00
4.05E+05 3.9E+01 1.6E+00 5.1E+00 1000 100
3.82E+05 7.0E+00 1.6E+00 5.1E+00
4.55E+05 3.8E+00 1.6E+00 5.1E+00
4.47E+05 1.3E+02 1.6E+00 5.1E+00
3.68E+05 2.3E-01 1.6E+00 5.1E+00
2.35E+05 3.6E+00 1.6E+00 5.1E+00
2.94E+05 2.9E+01 1.6E+00 5.1E+00
3.15E+05 3.8E-01 1.6E+00 5.1E+00
3.61 E+05 6.7E-01 1.6E+00 5.1E+00
4.19E+05 2.7E+00 1.6E+00 5.1E+00 1000 100
4.10E+05 1.5E+00 1.6E+00 5.1E+00
4.34E+05 6.4E-01 1.6E+00 5.1E+00
4.50E+05 5.2E+00 1.6E+00 5.1E+00
2.76E+05 2.4E+00 1.6E+00 5.1E+00
2.46E+05 1.2E+02 1.6E+00 5.1E+00
2.90E+05 1.2E+01 1 .6E+00 5.1E+00
3.16E+05 1.7E+00 1 .6E+00 5.1E+00
3.45E+05 7.4E-01 1 .6E+00 5.1E+00
4.12E+05 1.2E+00 1 .6E+00 5.1E+00 1000 100
4.05E+05 8.8E-01 1 .6E+00 5.1E+00
4.47E+05 4.8E+00 1 .6E+00 5.1E+00
4.52E+05 1.6E+00 1 .6E+00 5.1E+00
3.51 E+05 1.5E+00 1 .6E+00 5.1E+00
2.68E+05 2.5E+01 1 .6E+00 5.1E+00
3.24E+05 2.4E+01 1 .6E+00 5.1E+00
1.13E+02 1.0E+02 1.6E+00 5.1E+00
6.32E+01 1.5E+00 1 .6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
4.05E+05 84% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
4.20E+05 92% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
4.13E+05 88% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-603
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone.
SWA-L11-1313-T01-A 1 8.45E+04
SWA-L11-1313-T02-A 1 8.48E+04
SWA-L11-1313-T03-A 1 8.38E+04
SWA-L11-1313-T04-A 1 7.33E+04
SWA-L11-1313-T05-A 1 9.66E+04
SWA-L11-1313-T06-A 1 8.70E+04
SWA-L11-1313-T07-A 1 7.48E+04
SWA-L11-1313-T08-A 1 4.19E+04
SWA-L11-1313-T09-A 1 2.77E+04
SWA-L11-1313-T01-B 1 8.08E+04
SWA-L11-1313-T02-B 1 7.93E+04
SWA-L11-1313-T03-B 1 8.88E+04
SWA-L11-1313-T04-B 1 7.86E+04
SWA-L11-1313-T05-B 1 8.63E+04
SWA-L11-1313-T06-B 1 9.20E+04
SWA-L11-1313-T07-B 1 5.47E+04
SWA-L11-1313-T08-B 1 4.13E+04
SWA-L11-1313-T09-B 1 2.57E+04
SWA-L11-1313-T01-C 1 8.13E+04
SWA-L11-1313-T02-C 1 8.27E+04
SWA-L11-1313-T03-C 1 8.52E+04
SWA-L11-1313-T04-C 1 7.75E+04
SWA-L11-1313-T05-C 1 9.30E+04
SWA-L11-1313-T06-C 1 9.97E+04
SWA-L11-1313-T07-C 1 6.94E+04
SWA-L11-1313-T08-C 1 4.09E+04
SWA-L11-1313-T09-C 1 2.84E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
8.45E+04 4.4E-01 1.5E+01 4.8E+01
8.48E+04 8.6E-01 1.5E+01 4.8E+01
8.38E+04 3.9E+01 1.5E+01 4.8E+01 10 100
7.33E+04 7.4E+00 1.5E+01 4.8E+01
9.66E+04 1.7E-01 1.5E+01 4.8E+01
8.70E+04 1.3E+02 1.5E+01 4.8E+01
7.48E+04 3.3E-01 1.5E+01 4.8E+01
4.19E+04 5.2E-01 1.5E+01 4.8E+01
2.77E+04 3.9E-01 1.5E+01 4.8E+01
8.08E+04 5.1E-01 1.5E+01 4.8E+01
7.93E+04 1.3E+00 1.5E+01 4.8E+01
8.88E+04 9.4E-01 1.5E+01 4.8E+01 10 100
7.86E+04 9.0E-01 1.5E+01 4.8E+01
8.63E+04 4.3E-01 1.5E+01 4.8E+01
9.20E+04 3.1E+00 1.5E+01 4.8E+01
5.47E+04 2.0E+00 1.5E+01 4.8E+01
4.13E+04 1.2E+02 1.5E+01 4.8E+01
2.57E+04 1.1E+00 1 .5E+01 4.8E+01
8.13E+04 4.7E-01 1 .5E+01 4.8E+01
8.27E+04 2.2E-01 1 .5E+01 4.8E+01
8.52E+04 8.5E-01 1 .5E+01 4.8E+01 10 100
7.75E+04 2.1E-01 1 .5E+01 4.8E+01
9.30E+04 4.3E+00 1 .5E+01 4.8E+01
9.97E+04 1.4E+00 1 .5E+01 4.8E+01
6.94E+04 8.6E-02 1 .5E+01 4.8E+01
4.09E+04 3.2E+00 1 .5E+01 4.8E+01
2.84E+04 2.2E-01 1 .5E+01 4.8E+01
SWA-L11-1313-B01-A 1 7.50E+00 U1/2 7.50E+00 1.7E+02 1.5E+01 4.8E+01
SWA-L11-1313-B02-A 1 7.50E+00 U1/2 7.50E+00 2.0E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
8.48E+04 92% VUICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
8.97E+04 90% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
8.60E+04 86% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-604
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-L11-1313-T01-A 1
Si SWA-L11-1313-T02-A 1
Si SWA-L11-1313-T03-A 1
Si SWA-L11-1313-T04-A 1
Si SWA-L11-1313-T05-A 1
Si SWA-L11-1313-T06-A 1
Si SWA-L11-1313-T07-A 1
Si SWA-L11-1313-T08-A 1
Si SWA-L11-1313-T09-A 1
Si SWA-L11-1313-T01-B 1
Si SWA-L11-1313-T02-B 1
Si SWA-L11-1313-T03-B 1
Si SWA-L11-1313-T04-B 1
Si SWA-L11-1313-T05-B 1
Si SWA-L11-1313-T06-B 1
Si SWA-L11-1313-T07-B 1
Si SWA-L11-1313-T08-B 1
Si SWA-L11-1313-T09-B 1
Si SWA-L11-1313-T01-C 1
Si SWA-L11-1313-T02-C 1
Si SWA-L11-1313-T03-C 1
Si SWA-L11-1313-T04-C 1
Si SWA-L11-1313-T05-C 1
Si SWA-L11-1313-T06-C 1
Si SWA-L11-1313-T07-C 1
Si SWA-L11-1313-T08-C 1
Si SWA-L11-1313-T09-C 1
Si SWA-L11-1313-B01-A 1
Si SWA-L11-1313-B02-A 1
Sample I
Cone. Qualifier
ug/L I
2.34E+04
1.50E+04
5.01 E+03
3.63E+03
7.21 E+03
8.56E+03
1.08E+04
2.53E+04
1.01E+05
2.26E+04
1.49E+04
6.70E+03
3.83E+03
8.03E+03
8.49E+03
1.58E+04
2.13E+04
2.88E+05
2.30E+04
1 .86E+04
5.96E+03
3.77E+03
9.36E+03
7.53E+03
1 .34E+04
2.01E+04
1.16E+05
1.61E+00 E
1.72E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.34E+04 1.2E+00 1.1E+00 3.5E+00
1.50E+04 7.3E-01 1.1E+00 3.5E+00
5.01E+03 2.3E+01 1.1E+00 3.5E+00 1000 100
3.63E+03 7.6E+00 1.1E+00 3.5E+00
7.21 E+03 3.3E-01 1.1E+00 3.5E+00
8.56E+03 1.4E+02 1.1E+00 3.5E+00
1.08E+04 5.0E-01 1.1E+00 3.5E+00
2.53E+04 8.9E-01 1.1E+00 3.5E+00
1.01E+05 2.6E-01 1.1E+00 3.5E+00
2.26E+04 6.6E-02 1.1E+00 3.5E+00
1.49E+04 1.7E+00 1.1E+00 3.5E+00
6.70E+03 1.2E+00 1.1E+00 3.5E+00 1000 100
3.83E+03 5.7E-01 1.1E+00 3.5E+00
8.03E+03 5.3E-01 1.1E+00 3.5E+00
8.49E+03 3.4E+00 1.1E+00 3.5E+00
1.58E+04 1.7E+00 1.1E+00 3.5E+00
2.13E+04 8.8E+01 1.1E+00 3.5E+00
2.88E+05 4.0E-01 1.1E+00 3.5E+00
2.30E+04 8.3E-01 1.1E+00 3.5E+00
1.86E+04 1.6E+00 1.1E+00 3.5E+00
5.96E+03 6.1E-01 1.1E+00 3.5E+00 1000 100
3.77E+03 3.7E-01 1.1E+00 3.5E+00
9.36E+03 4.5E+00 1.1E+00 3.5E+00
7.53E+03 2.3E+00 1.1E+00 3.5E+00
1.34E+04 3.1E-01 1.1E+00 3.5E+00
2.01E+04 2.8E+00 1.1E+00 3.5E+00
1.16E+05 5.1E-01 1.1E+00 3.5E+00
1.61E+00 2.0E+02 1.1E+00 3.5E+00
1.72E+01 2.3E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
6.10E+03 110% VUICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
7.82E+03 112% VUICP-OES 4/7/1 1 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
6.96E+03 100% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-605
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qu
1 ug/L
Na SWA-L11-1313-T01-A 1 4.81 E+05
Na SWA-L11-1313-T02-A 1 5.09E+05
Na SWA-L11-1313-T03-A 1 5.10E+05
Na SWA-L11-1313-T04-A 1 4.93E+05
Na SWA-L11-1313-T05-A 1 4.90E+05
Na SWA-L11-1313-T06-A 1 4.65E+05
Na SWA-L11-1313-T07-A 1 4.84E+05
Na SWA-L11-1313-T08-A 1 4.80E+05
Na SWA-L11-1313-T09-A 1 4.69E+05
Na SWA-L11-1313-T01-B 1 4.69E+05
Na SWA-L11-1313-T02-B 1 5.01 E+05
Na SWA-L11-1313-T03-B 1 5.05E+05
Na SWA-L11-1313-T04-B 1 4.89E+05
Na SWA-L11-1313-T05-B 1 4.79E+05
Na SWA-L11-1313-T06-B 1 4.78E+05
Na SWA-L11-1313-T07-B 1 4.77E+05
Na SWA-L11-1313-T08-B 1 4.80E+05
Na SWA-L11-1313-T09-B 1 4.38E+05
Na SWA-L11-1313-T01-C 1 4.66E+05
Na SWA-L11-1313-T02-C 1 4.82E+05
Na SWA-L11-1313-T03-C 1 5.04E+05
Na SWA-L11-1313-T04-C 1 4.88E+05
Na SWA-L11-1313-T05-C 1 4.85E+05
Na SWA-L11-1313-T06-C 1 4.82E+05
Na SWA-L11-1313-T07-C 1 4.82E+05
Na SWA-L11-1313-T08-C 1 4.77E+05
Na SWA-L11-1313-T09-C 1 4.75E+05
Na SWA-L11-1313-B01-A 1 1.24E+02
Na SWA-L11-1313-B02-A 1 2.23E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.81 E+05 8.1E-02 2.5E+00 8.0E+00
5.09E+05 2.6E-01 2.5E+00 8.0E+00
5.10E+05 1.5E+01 2.5E+00 8.0E+00 1000 100
4.93E+05 1.4E+00 2.5E+00 8.0E+00
4.90E+05 3.5E-01 2.5E+00 8.0E+00
4.65E+05 1.2E+02 2.5E+00 8.0E+00
4.84E+05 7.0E-01 2.5E+00 8.0E+00
4.80E+05 2.7E-01 2.5E+00 8.0E+00
4.69E+05 8.4E-01 2.5E+00 8.0E+00
4.69E+05 1.6E-01 2.5E+00 8.0E+00
5.01 E+05 6.4E-01 2.5E+00 8.0E+00
5.05E+05 3.6E-01 2.5E+00 8.0E+00 1000 100
4.89E+05 3.1E-01 2.5E+00 8.0E+00
4.79E+05 3.1E-01 2.5E+00 8.0E+00
4.78E+05 1.3E-01 2.5E+00 8.0E+00
4.77E+05 9.9E-01 2.5E+00 8.0E+00
4.80E+05 1.3E+02 2.5E+00 8.0E+00
4.38E+05 5.9E-01 2.5E+00 8.0E+00
4.66E+05 5.6E-01 2.5E+00 8.0E+00
4.82E+05 3.3E-01 2.5E+00 8.0E+00
5.04E+05 5.2E-01 2.5E+00 8.0E+00 1000 100
4.88E+05 5.5E-01 2.5E+00 8.0E+00
4.85E+05 7.9E-01 2.5E+00 8.0E+00
4.82E+05 7.2E-01 2.5E+00 8.0E+00
4.82E+05 3.5E-01 2.5E+00 8.0E+00
4.77E+05 6.3E-01 2.5E+00 8.0E+00
4.75E+05 3.6E-01 2.5E+00 8.0E+00
1.24E+02 1.2E+02 2.5E+00 8.0E+00
2.23E+02 2.4E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
5.11E+05 83% VUICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
5.06E+05 90% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
5.05E+05 84% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:51 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-606
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
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Sr
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Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone.
1 ug/L
SWA-L11-1313-T01-A 1 3.21E+02
SWA-L11-1313-T02-A 1 3.75E+03
SWA-L11-1313-T03-A 1 1.10E+04
SWA-L11-1313-T04-A 1 1.73E+04
SWA-L11-1313-T05-A 1 3.34E+04
SWA-L11-1313-T06-A 1 3.25E+04
SWA-L11-1313-T07-A 1 3.16E+04
SWA-L11-1313-T08-A 1 2.03E+04
SWA-L11-1313-T09-A 1 1.77E+04
SWA-L11-1313-T01-B 1 3.22E+02
SWA-L11-1313-T02-B 1 4.03E+03
SWA-L11-1313-T03-B 1 1.27E+04
SWA-L11-1313-T04-B 1 1.85E+04
SWA-L11-1313-T05-B 1 3.23E+04
SWA-L11-1313-T06-B 1 3.34E+04
SWA-L11-1313-T07-B 1 2.27E+04
SWA-L11-1313-T08-B 1 2.12E+04
SWA-L11-1313-T09-B 1 1 J2E+04
SWA-L11-1313-T01-C 1 3.16E+02
SWA-L11-1313-T02-C 1 1.01E+03
SWA-L11-1313-T03-C 1 1.37E+04
SWA-L11-1313-T04-C 1 1.83E+04
SWA-L11-1313-T05-C 1 3.25E+04
SWA-L11-1313-T06-C 1 3.34E+04
SWA-L11-1313-T07-C 1 2.96E+04
SWA-L11-1313-T08-C 1 2.05E+04
SWA-L11-1313-T09-C 1 1.76E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.21 E+02 8.9E-01 1. OE+00 3.2E+00
3.75E+03 2.5E-01 1. OE+00 3.2E+00
1.10E+04 1.9E+01 1.0E+00 3.2E+00 1000 100
1.73E+04 8.4E+00 1. OE+00 3.2E+00
3.34E+04 6.6E-01 1. OE+00 3.2E+00
3.25E+04 9.0E+01 1. OE+00 3.2E+00
3.16E+04 1. OE+00 1. OE+00 3.2E+00
2.03E+04 6.0E-01 1. OE+00 3.2E+00
1.77E+04 1.1E-01 1. OE+00 3.2E+00
3.22E+02 3.2E-01 1. OE+00 3.2E+00
4.03E+03 1.3E+00 1. OE+00 3.2E+00
1.27E+04 1.3E+00 1. OE+00 3.2E+00 1000 100
1.85E+04 1.1E+00 1. OE+00 3.2E+00
3.23E+04 5.1E-01 1. OE+00 3.2E+00
3.34E+04 1.5E+00 1. OE+00 3.2E+00
2.27E+04 1.9E+00 1. OE+00 3.2E+00
2.12E+04 8.7E+01 1. OE+00 3.2E+00
1.72E+04 9.7E-01 1 .OE+00 3.2E+00
3.16E+02 1.5E-01 1 .OE+00 3.2E+00
1.01E+03 1.2E+00 1. OE+00 3.2E+00
1.37E+04 2.0E+00 1 .OE+00 3.2E+00 1000 100
1.83E+04 1.3E+00 1 .OE+00 3.2E+00
3.25E+04 2.6E+00 1 .OE+00 3.2E+00
3.34E+04 1.1E-01 1 .OE+00 3.2E+00
2.96E+04 2.2E+00 1 .OE+00 3.2E+00
2.05E+04 1.4E+00 1 .OE+00 3.2E+00
1.76E+04 5.5E-01 1 .OE+00 3.2E+00
SWA-L11-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 1.6E+02 1 .OE+00 3.2E+00
SWA-L11-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 1.9E+02 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
1.19E+04 95% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.36E+04 96% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.47E+04 98% VUICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-607
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone.
1 ug/L
SWA-L11-1313-T01-A 1 8.11E+05
SWA-L11-1313-T02-A 1 9.15E+05
SWA-L11-1313-T03-A 1 9.08E+05
SWA-L11-1313-T04-A 1 7.53E+05
SWA-L11-1313-T05-A 1 6.42E+05
SWA-L11-1313-T06-A 1 6.40E+05
SWA-L11-1313-T07-A 1 3.19E+05
SWA-L11-1313-T08-A 1 1.86E+05
SWA-L11-1313-T09-A 1 1.32E+05
SWA-L11-1313-T01-B 1 7.71E+05
SWA-L11-1313-T02-B 1 8.98E+05
SWA-L11-1313-T03-B 1 9.02E+05
SWA-L11-1313-T04-B 1 7.82E+05
SWA-L11-1313-T05-B 1 5.46E+05
SWA-L11-1313-T06-B 1 5.14E+05
SWA-L11-1313-T07-B 1 2.32E+05
SWA-L11-1313-T08-B 1 1.81E+05
SWA-L11-1313-T09-B 1 1 .27E+05
SWA-L11-1313-T01-C 1 7.69E+05
SWA-L11-1313-T02-C 1 8.09E+05
SWA-L11-1313-T03-C 1 8.82E+05
SWA-L11-1313-T04-C 1 7.76E+05
SWA-L11-1313-T05-C 1 5.81E+05
SWA-L11-1313-T06-C 1 6.43E+05
SWA-L11-1313-T07-C 1 2.99E+05
SWA-L11-1313-T08-C 1 1.82E+05
SWA-L11-1313-T09-C 1 1.32E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
8.11E+05 8.8E-01 6.8E+00 2.2E+01
9.15E+05 1.4E+00 6.8E+00 2.2E+01
9.08E+05 3.0E+01 6.8E+00 2.2E+01 1000 100
7.53E+05 9.5E+00 6.8E+00 2.2E+01
6.42E+05 8.8E-01 6.8E+00 2.2E+01
6.40E+05 9.2E+01 6.8E+00 2.2E+01
3.19E+05 2.3E-01 6.8E+00 2.2E+01
1.86E+05 7.6E-01 6.8E+00 2.2E+01
1.32E+05 3.8E-01 6.8E+00 2.2E+01
7.71 E+05 1.7E+00 6.8E+00 2.2E+01
8.98E+05 1.7E-01 6.8E+00 2.2E+01
9.02E+05 1.5E+00 6.8E+00 2.2E+01 1000 100
7.82E+05 9.5E-01 6.8E+00 2.2E+01
5.46E+05 9.9E-02 6.8E+00 2.2E+01
5.14E+05 3.3E+00 6.8E+00 2.2E+01
2.32E+05 1.7E+00 6.8E+00 2.2E+01
1.81 E+05 1.3E+02 6.8E+00 2.2E+01
1.27E+05 4.5E-02 6.8E+00 2.2E+01
7.69E+05 1.3E+00 6.8E+00 2.2E+01
8.09E+05 1.9E+00 6.8E+00 2.2E+01
8.82E+05 1.5E+00 6.8E+00 2.2E+01 1000 100
7.76E+05 3.6E-01 6.8E+00 2.2E+01
5.81 E+05 3.3E+00 6.8E+00 2.2E+01
6.43E+05 1.4E+00 6.8E+00 2.2E+01
2.99E+05 3.3E-01 6.8E+00 2.2E+01
1.82E+05 3.1E+00 6.8E+00 2.2E+01
1.32E+05 5.9E-01 6.8E+00 2.2E+01
SWA-L11-1313-B01-A 1 3.40E+00 U1/2 3.40E+00 1.3E+02 6.8E+00 2.2E+01
SWA-L11-1313-B02-A 1 3.40E+00 U1/2 3.40E+00 5.9E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
9.09E+05 89% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
9.03E+05 87% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
8.83E+05 82% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-608
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
SWA-L11-1313-T01-A 1 2.30E+00 U1/2 2.30E+00 4.4E+01 4.6E+00 1 .5E+01
SWA-L11-1313-T02-A 1 2.30E+00 U1/2 2.30E+00 2.8E+01 4.6E+00 1 .5E+01
SWA-L11-1313-T03-A 1 2.30E+00 U1/2 2.30E+00 4.7E+01 4.6E+00 1 .5E+01 10 100
SWA-L11-1313-T04-A 1 2.30E+00 U1/2 2.30E+00 1 .6E+01 4.6E+00 1 .5E+01
SWA-L11-1313-T05-A 1 1.06E+01 E
SWA-L11-1313-T06-A 1 1.10E+01 E
SWA-L11-1313-T07-A 1 2.09E+01
SWA-L11-1313-T08-A 1 5.80E+00 E
1.06E+01 1.1E+02 4.6E+00 1 .5E+01
1.10E+01 5.9E+00 4.6E+00 1 .5E+01
2.09E+01 7.0E+01 4.6E+00 1 .5E+01
5.80E+00 1.7E+02 4.6E+00 1.5E+01
SWA-L11-1313-T09-A 1 2.30E+00 U1/2 2.30E+00 6.0E+01 4.6E+00 1.5E+01
SWA-L11-1313-T01-B 1 2.30E+00 U1/2 2.30E+00 4.9E+01 4.6E+00 1.5E+01
SWA-L11-1313-T02-B 1 2.30E+00 U1/2 2.30E+00 4.3E+01 4.6E+00 1.5E+01
SWA-L11-1313-T03-B 1 2.30E+00 U1/2 2.30E+00 3.0E+01 4.6E+00 1.5E+01 10 100
SWA-L11-1313-T04-B 1 2.30E+00 U1/2 2.30E+00 1.9E+01 4.6E+00 1.5E+01
SWA-L11-1313-T05-B 1 5.85E+00 E
SWA-L11-1313-T06-B 1 1.17E+01 E
SWA-L11-1313-T07-B 1 1.85E+01
SWA-L11-1313-T08-B 1 6.40E+00 E
5.85E+00 1.4E+01 4.6E+00 1.5E+01
1.17E+01 1.9E+01 4.6E+00 1.5E+01
1.85E+01 4.3E+01 4.6E+00 1.5E+01
6.40E+00 1.9E+00 4.6E+00 1.5E+01
SWA-L11-1313-T09-B 1 2.30E+00 U1/2 2.30E+00 1.4E+01 4.6E+00 1.5E+01
SWA-L11-1313-T01-C 1 2.30E+00 U1/2 2.30E+00 5.7E+01 4.6E+00 1.5E+01
SWA-L11-1313-T02-C 1 2.30E+00 U1/2 2.30E+00 1.1E+01 4.6E+00 1.5E+01
SWA-L11-1313-T03-C 1 2.30E+00 U1/2 2.30E+00 8.7E+01 4.6E+00 1.5E+01 10 100
SWA-L11-1313-T04-C 1 2.30E+00 U1/2 2.30E+00 3.0E+01 4.6E+00 1.5E+01
SWA-L11-1313-T05-C 1 1.29E+01 E
SWA-L11-1313-T06-C 1 1.06E+01 E
SWA-L11-1313-T07-C 1 2.21E+01
SWA-L11-1313-T08-C 1 5.25E+00 E
1.29E+01 4.8E+01 4.6E+00 1.5E+01
1.06E+01 2.6E+01 4.6E+00 1.5E+01
2.21E+01 8.6E+02 4.6E+00 1.5E+01
5.25E+00 8.7E+01 4.6E+00 1.5E+01
SWA-L11-1313-T09-C 1 2.30E+00 U1/2 2.30E+00 3.7E+02 4.6E+00 1.5E+01
SWA-L11-1313-B01-A 1 2.30E+00 U1/2 2.30E+00 3.9E+00 4.6E+00 1.5E+01
SWA-L11-1313-B02-A 1 2.30E+00 U1/2 2.30E+00 6.7E+00 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA Interlab L11 1313-1316 SWA
1.12E+03 112% VUICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.14E+03 114% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L1 1 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.15E+03 115% VUICP-OES 4/7/1 1 4:46 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-609
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L |
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L11-1313-T01-A 1 1.00E+OOU1/2 1.00E+00 5.0E+02 2.0E+00 6.4E+00
Ti SWA-L11-1313-T02-A 1 1.00E+OOU1/2 1.00E+00 8.2E+01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T03-A 1 1.00E+OOU1/2 1.00E+00 5.9E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L11-1313-T04-A 1 1.00E+OOU1/2 1.00E+00 2.9E+01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T05-A 1 1.00E+OOU1/2 1.00E+00 1 .2E+02 2.0E+00 6.4E+00
Ti SWA-L11-1313-T06-A 1 1.00E+OOU1/2 1.00E+00 8.6E+00 2.0E+00 6.4E+00
Ti SWA-L11-1313-T07-A 1 1.00E+OOU1/2 1.00E+00 1 .8E+01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T08-A 1 1.22E+01
Ti SWA-L11-1313-T09-A 1 1.11E+03
1.22E+01 5.3E+00 2.0E+00 6.4E+00
1.11E+03 1.5E-01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T01-B 1 1.00E+OOU1/2 1.00E+00 2.7E+00 2.0E+00 6.4E+00
Ti SWA-L11-1313-T02-B 1 1.00E+OOU1/2 1.00E+00 2.3E+01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T03-B 1 1.00E+OOU1/2 1.00E+00 3.6E+00 2.0E+00 6.4E+00 10 100
Ti SWA-L11-1313-T04-B 1 1.00E+OOU1/2 1.00E+00 2.4E+01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T05-B 1 1.00E+OOU1/2 1.00E+00 6.0E+02 2.0E+00 6.4E+00
Ti SWA-L11-1313-T06-B 1 1.00E+OOU1/2 1.00E+00 1 .5E+02 2.0E+00 6.4E+00
Ti SWA-L11-1313-T07-B 1 1.00E+OOU1/2 1.00E+00 1 .6E+00 2.0E+00 6.4E+00
Ti SWA-L11-1313-T08-B 1 1.83E+01
Ti SWA-L11-1313-T09-B 1 6.33E+03
1.83E+01 1.0E+02 2.0E+00 6.4E+00
6.33E+03 2.7E-01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T01-C 1 1.00E+OOU1/2 1.00E+00 3.6E+01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T02-C 1 1.00E+OOU1/2 1.00E+00 2.8E+01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T03-C 1 1.00E+OOU1/2 1.00E+00 1.7E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L11-1313-T04-C 1 1.00E+OOU1/2 1.00E+00 1.5E+01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T05-C 1 1.00E+OOU1/2 1.00E+00 5.7E+02 2.0E+00 6.4E+00
Ti SWA-L11-1313-T06-C 1 1.00E+OOU1/2 1.00E+00 6.5E+01 2.0E+00 6.4E+00
Ti SWA-L11-1313-T07-C 1 1.00E+OOU1/2 1.00E+00 3.6E+02 2.0E+00 6.4E+00
Ti SWA-L11-1313-T08-C 1 1.46E+01
Ti SWA-L11-1313-T09-C 1 1.15E+03
1.46E+01 6.8E+00 2.0E+00 6.4E+00
1.15E+03 6.9E-01 2.0E+00 6.4E+00
Ti SWA-L11-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 4.8E+00 2.0E+00 6.4E+00
Ti SWA-L11-1313-B02-A 1 1.00E+OOU1/2 1.00E+00 1.7E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
9.63E+02 96% VU ICP-OES 4/7/11 4:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
9.98E+02 100% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
9.67E+02 97% VU ICP-OES 4/7/11 4:46 PM EPA Interlab L1 1 1313-1316 SWA
VU ICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:51 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-610
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample
Sample Dilution Cone.
1 ug/L
SWA-L11-1313-T01-A 1 2.95E+02
SWA-L11-1313-T02-A 1 1.27E+02
SWA-L11-1313-T03-A 1 8.44E+01
SWA-L11-1313-T04-A 1 1.29E+02
SWA-L11-1313-T05-A 1 1.44E+02
SWA-L11-1313-T06-A 1 1.35E+02
SWA-L11-1313-T07-A 1 1.09E+02
SWA-L11-1313-T08-A 1 7.53E+01
SWA-L11-1313-T09-A 1 9.11E+02
SWA-L11-1313-T01-B 1 2.80E+02
SWA-L11-1313-T02-B 1 1.31E+02
SWA-L11-1313-T03-B 1 1.04E+02
SWA-L11-1313-T04-B 1 1.39E+02
SWA-L11-1313-T05-B 1 1.26E+02
SWA-L11-1313-T06-B 1 1.42E+02
SWA-L11-1313-T07-B 1 1.06E+02
SWA-L11-1313-T08-B 1 6.80E+01
SWA-L11-1313-T09-B 1 1 .02E+03
SWA-L11-1313-T01-C 1 2.82E+02
SWA-L11-1313-T02-C 1 1 .34E+02
SWA-L11-1313-T03-C 1 1.08E+02
SWA-L11-1313-T04-C 1 1.35E+02
SWA-L11-1313-T05-C 1 1.40E+02
SWA-L11-1313-T06-C 1 1.49E+02
SWA-L11-1313-T07-C 1 1.01E+02
SWA-L11-1313-T08-C 1 6.43E+01
SWA-L11-1313-T09-C 1 1.01E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.95E+02 9.4E-01 1.5E+00 4.8E+00
1.27E+02 8.6E-01 1.5E+00 4.8E+00
8.44E+01 1.9E+01 1.5E+00 4.8E+00 10 100
1.29E+02 5.7E+00 1.5E+00 4.8E+00
1.44E+02 5.3E-01 1.5E+00 4.8E+00
1.35E+02 9.4E+01 1.5E+00 4.8E+00
1.09E+02 2.0E+00 1.5E+00 4.8E+00
7.53E+01 1.8E+00 1.5E+00 4.8E+00
9.11E+02 1.3E-01 1.5E+00 4.8E+00
2.80E+02 8.6E-01 1.5E+00 4.8E+00
1.31E+02 8.8E-01 1.5E+00 4.8E+00
1.04E+02 5.5E-01 1.5E+00 4.8E+00 10 100
1.39E+02 3.0E+00 1.5E+00 4.8E+00
1.26E+02 2.8E+00 1.5E+00 4.8E+00
1.42E+02 1.5E+00 1.5E+00 4.8E+00
1.06E+02 1.0E+00 1.5E+00 4.8E+00
6.80E+01 1.2E+02 1.5E+00 4.8E+00
1.02E+03 7.0E-01 1 .5E+00 4.8E+00
2.82E+02 1.1E-01 1 .5E+00 4.8E+00
1.34E+02 3.5E-01 1 .5E+00 4.8E+00
1.08E+02 1.8E+00 1 .5E+00 4.8E+00 10 100
1.35E+02 2.3E+00 1 .5E+00 4.8E+00
1.40E+02 4.0E+00 1 .5E+00 4.8E+00
1.49E+02 5.4E-01 1 .5E+00 4.8E+00
1.01E+02 3.5E+00 1 .5E+00 4.8E+00
6.43E+01 5.8E+00 1 .5E+00 4.8E+00
1.01E+03 6.2E-01 1.5E+00 4.8E+00
SWA-L11-1313-B01-A 1 7.50E-01 U1/2 7.50E-01 3.3E+01 1 .5E+00 4.8E+00
SWA-L11-1313-B02-A 1 1.72E+OOE 1.72E+00 2.2E+01 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
9.61E+02 88% VUICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.05E+03 95% VUICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.12E+03 102% VUICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-611
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qu<
1 1 ug/L |
Zn SWA-L11-1313-T01-A 1 2.29E+00 E
Zn SWA-L11-1313-T02-A 1 1.45E+OOE
Zn SWA-L11-1313-T03-A 1 1.49E+OOE
Zn SWA-L11-1313-T04-A 1 2.29E+00 E
Zn SWA-L11-1313-T05-A 1 2.07E+01
Zn SWA-L11-1313-T06-A 1 1.82E+01
Zn SWA-L11-1313-T07-A 1 5.88E+02
Zn SWA-L11-1313-T08-A 1 9.46E+02
Zn SWA-L11-1313-T09-A 1 1.65E+03
Zn SWA-L11-1313-T01-B 1 1.04E+OOE
Zn SWA-L11-1313-T02-B 1 1.32E+OOE
Zn SWA-L11-1313-T03-B 1 2.07E+00 E
Zn SWA-L11-1313-T04-B 1 2.46E+00 E
Zn SWA-L11-1313-T05-B 1 1.20E+01
Zn SWA-L11-1313-T06-B 1 1.05E+02
Zn SWA-L11-1313-T07-B 1 8.77E+02
Zn SWA-L11-1313-T08-B 1 9.38E+02
Zn SWA-L11-1313-T09-B 1 1 .60E+03
Zn SWA-L11-1313-T01-C 1 1 .44E+00 E
Zn SWA-L11-1313-T02-C 1 1 .56E+00 E
Zn SWA-L11-1313-T03-C 1 1.29E+OOE
Zn SWA-L11-1313-T04-C 1 2.36E+00 E
Zn SWA-L11-1313-T05-C 1 1.62E+02
Zn SWA-L11-1313-T06-C 1 9.97E+00
Zn SWA-L11-1313-T07-C 1 9.00E+02
Zn SWA-L11-1313-T08-C 1 8.88E+02
Zn SWA-L11-1313-T09-C 1 1.71E+03
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.29E+00 7.4E+00 1. OE+00 3.2E+00
1.45E+00 1.2E+01 1. OE+00 3.2E+00
1.49E+00 4.4E+01 1.0E+00 3.2E+00 10 100
2.29E+00 3.6E+00 1. OE+00 3.2E+00
2.07E+01 3.3E+00 1. OE+00 3.2E+00
1.82E+01 7.2E+01 1. OE+00 3.2E+00
5.88E+02 6.2E-01 1. OE+00 3.2E+00
9.46E+02 5.3E-01 1. OE+00 3.2E+00
1.65E+03 5.2E-01 1. OE+00 3.2E+00
1.04E+00 1.6E+01 1. OE+00 3.2E+00
1.32E+00 3.5E+01 1. OE+00 3.2E+00
2.07E+00 2.5E+01 1. OE+00 3.2E+00 10 100
2.46E+00 2.4E+01 1. OE+00 3.2E+00
1.20E+01 7.0E-01 1. OE+00 3.2E+00
1.05E+02 3.3E+00 1. OE+00 3.2E+00
8.77E+02 1.6E+00 1. OE+00 3.2E+00
9.38E+02 1.2E+02 1. OE+00 3.2E+00
1.60E+03 5.0E-01 1 .OE+00 3.2E+00
1.44E+00 2.9E+01 1 .OE+00 3.2E+00
1.56E+00 1.1E+01 1. OE+00 3.2E+00
1.29E+00 1.2E+01 1.0E+00 3.2E+00 10 100
2.36E+00 1.7E+01 1 .OE+00 3.2E+00
1.62E+02 3.6E+00 1. OE+00 3.2E+00
9.97E+00 5.3E+00 1. OE+00 3.2E+00
9.00E+02 6.5E-01 1. OE+00 3.2E+00
8.88E+02 2.1E+00 1. OE+00 3.2E+00
1.71E+03 7.0E-01 1. OE+00 3.2E+00
Zn SWA-L11-1313-B01-A 1 5.00E-01 U1/2 5.00E-01 1.0E+02 1 .OE+00 3.2E+00
Zn SWA-L11-1313-B02-A 1 5.00E-01 U1/2 5.00E-01 1.5E+01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 4:08 PM EPA InterlabLH 1313-1316 SWA
VUICP-OES 4/7/11 4:10 PM EPA InterlabLH 1313-1316 SWA
9.91E+02 99% VUICP-OES 4/7/11 4:11 PM EPA Interlab L1 1 1313-1316 SWA
VUICP-OES 4/7/11 4:13 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:14 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:16 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:18 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:21 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:28 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:29 PM EPA Interlab L11 1313-1316 SWA
1.02E+03 102% VU ICP-OES 4/7/11 4:31 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:33 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:34 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:36 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:38 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:39 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:41 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 4:42 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:44 PM EPA Interlab L11 1313-1316 SWA
1.10E+03 110% VUICP-OES 4/7/11 4:46 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:47 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:49 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/114:51 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:52 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:54 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:56 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 3:58 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 4:00 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                          1-612
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al SWA-LRef-1313-T01-A 1
Al SWA-LRef-1313-T02-A 1
Al SWA-LRef-1313-T03-A 1
Al SWA-LRef-1313-T04-A 1
Al SWA-LRef-1313-T05-A 1
Al SWA-LRef-1313-T06-A 1
Al SWA-LRef-1313-T07-A 1
Al SWA-LRef-1313-T08-A 1
Al SWA-LRef-1313-T09-A 1
Al SWA-LRef-1313-T01-B 1
Al SWA-LRef-1313-T02-B 1
Al SWA-LRef-1313-T03-B 1
Al SWA-LRef-1313-T04-B 1
Al SWA-LRef-1313-T05-B 1
Al SWA-LRef-1313-T06-B 1
Al SWA-LRef-1313-T07-B 1
Al SWA-LRef-1313-T08-B 1
Al SWA-LRef-1313-T09-B 1
Al SWA-LRef-1313-T01-C 1
Al SWA-LRef-1313-T02-C 1
Al SWA-LRef-1313-T03-C 1
Al SWA-LRef-1313-T04-C 1
Al SWA-LRef-1313-T05-C 1
Al SWA-LRef-1313-T06-C 1
Al SWA-LRef-1313-T07-C 1
Al SWA-LRef-1313-T08-C 1
Al SWA-LRef-1313-T09-C 1
Al SWA-LRef-1313-B01-A 1
Al SWA-LRef-1313-B02-A 1
Al SWA-LRef-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
5.51 E+04
2.65E+04
2.04E+04
1.08E+02
4.83E+01
3.26E+00
4.62E+02
2.57E+05
3.76E+05
6.08E+04
3.47E+04
2.35E+04
1.28E+02
3.98E+01
5.68E+00
4.96E+02
2.70E+05
9.23E+05
6.27E+04
3.58E+04
2.06E+04
1.61E+02
3.44E+01
5.86E+00
4.78E+01
2.00E+05
9.46E+05
1.21E+00 E
9.15E+00
4.11E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.51 E+04 6.3E-01 1.0E+00 3.2E+00
2.65E+04 1.7E+00 1.0E+00 3.2E+00
2.04E+04 8.5E-01 1.0E+00 3.2E+00 1000 100
1.08E+02 1.3E+01 1.0E+00 3.2E+00
4.83E+01 7.0E+00 1.0E+00 3.2E+00
3.26E+00 2.7E+02 1.0E+00 3.2E+00
4.62E+02 2.0E+00 1.0E+00 3.2E+00
2.57E+05 8.7E-01 1.0E+00 3.2E+00
3.76E+05 5.1E-01 1.0E+00 3.2E+00
6.08E+04 3.6E+00 1.0E+00 3.2E+00
3.47E+04 2.8E-01 1.0E+00 3.2E+00
2.35E+04 4.1E-01 1.0E+00 3.2E+00 1000 100
1.28E+02 1.9E+00 1.0E+00 3.2E+00
3.98E+01 3.1E+01 1.0E+00 3.2E+00
5.68E+00 6.8E+01 1.0E+00 3.2E+00
4.96E+02 2.3E+00 1.0E+00 3.2E+00
2.70E+05 1.1E+00 1.0E+00 3.2E+00
9.23E+05 1.9E-01 1.0E+00 3.2E+00
6.27E+04 4.0E-01 1.0E+00 3.2E+00
3.58E+04 2.0E-01 1.0E+00 3.2E+00
2.06E+04 3.9E-01 1.0E+00 3.2E+00 1000 100
1.61E+02 8.5E+00 1.0E+00 3.2E+00
3.44E+01 2.6E+01 1.0E+00 3.2E+00
5.86E+00 8.2E+01 1.0E+00 3.2E+00
4.78E+01 1.6E+01 1.0E+00 3.2E+00
2.00E+05 8.1E-01 1.0E+00 3.2E+00
9.46E+05 1.8E+00 1.0E+00 3.2E+00
1.21E+00 2.5E+01 1.0E+00 3.2E+00
9.15E+00 3.4E+00 1.0E+00 3.2E+00
4.11E+00 1.0E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
2.12E+04 86% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:17 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:22PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:23PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:30PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:32PM EPA Interlab LRef 1313-1316SWA
2.44E+04 89% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:35PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:36PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:38PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:40PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:43PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:50PM EPA Interlab LRef 1313-1316SWA
VU ICP-OES 1 1/19/10 1 :51 PM EPA Interlab LRef 1313-1316 SWA
2.16E+04 105% VU ICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                                   1-613
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-LRef-1313-T01-A 1
Sb SWA-LRef-1313-T02-A 1
Sb SWA-LRef-1313-T03-A 1
Sb SWA-LRef-1313-T04-A 1
Sb SWA-LRef-1313-T05-A 1
Sb SWA-LRef-1313-T06-A 1
Sb SWA-LRef-1313-T07-A 1
Sb SWA-LRef-1313-T08-A 1
Sb SWA-LRef-1313-T09-A 1
Sb SWA-LRef-1313-T01-B 1
Sb SWA-LRef-1313-T02-B 1
Sb SWA-LRef-1313-T03-B 1
Sb SWA-LRef-1313-T04-B 1
Sb SWA-LRef-1313-T05-B 1
Sb SWA-LRef-1313-T06-B 1
Sb SWA-LRef-1313-T07-B 1
Sb SWA-LRef-1313-T08-B 1
Sb SWA-LRef-1313-T09-B 1
Sb SWA-LRef-1313-T01-C 1
Sb SWA-LRef-1313-T02-C 1
Sb SWA-LRef-1313-T03-C 1
Sb SWA-LRef-1313-T04-C 1
Sb SWA-LRef-1313-T05-C 1
Sb SWA-LRef-1313-T06-C 1
Sb SWA-LRef-1313-T07-C 1
Sb SWA-LRef-1313-T08-C 1
Sb SWA-LRef-1313-T09-C 1
Sb SWA-LRef-1313-B01-A 1
Sb SWA-LRef-1313-B02-A 1
Sb SWA-LRef-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
6.01 E+03
5.61 E+03
4.83E+03
1.36E+03
1.53E+03
1.08E+03
6.40E+02
1.18E+03
5.35E+02
6.63E+03
6.05E+03
5.09E+03
1.34E+03
1.34E+03
8.27E+02
5.20E+02
1.14E+03
8.37E+02
6.45E+03
5.73E+03
5.38E+03
1.44E+03
1.03E+03
1.21 E+03
5.74E+02
8.40E+02
7.39E+02
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.01 E+03 8.4E-01 7.5E+00 2.4E+01
5.61 E+03 7.4E-01 7.5E+00 2.4E+01
4.83E+03 1.0E+00 7.5E+00 2.4E+01 10 100
1.36E+03 3.6E-01 7.5E+00 2.4E+01
1.53E+03 6.9E-01 7.5E+00 2.4E+01
1.08E+03 1.7E+00 7.5E+00 2.4E+01
6.40E+02 9.7E+00 7.5E+00 2.4E+01
1.18E+03 1.9E+00 7.5E+00 2.4E+01
5.35E+02 3.4E+00 7.5E+00 2.4E+01
6.63E+03 9.8E-01 7.5E+00 2.4E+01
6.05E+03 8.0E-01 7.5E+00 2.4E+01
5.09E+03 4.5E-01 7.5E+00 2.4E+01 10 100
1.34E+03 1.3E+00 7.5E+00 2.4E+01
1.34E+03 5.2E-01 7.5E+00 2.4E+01
8.27E+02 2.3E+00 7.5E+00 2.4E+01
5.20E+02 1.3E+00 7.5E+00 2.4E+01
1.14E+03 2.8E+00 7.5E+00 2.4E+01
8.37E+02 9.6E-01 7.5E+00 2.4E+01
6.45E+03 3.4E-01 7.5E+00 2.4E+01
5.73E+03 6.5E-01 7.5E+00 2.4E+01
5.38E+03 3.2E-01 7.5E+00 2.4E+01 10 100
1.44E+03 1.4E+00 7.5E+00 2.4E+01
1.03E+03 2.5E+00 7.5E+00 2.4E+01
1.21E+03 1.4E+00 7.5E+00 2.4E+01
5.74E+02 2.1E+00 7.5E+00 2.4E+01
8.40E+02 2.7E+00 7.5E+00 2.4E+01
7.39E+02 7.6E+01 7.5E+00 2.4E+01
3.75E+00 1.1E+02 7.5E+00 2.4E+01
3.75E+00 1.5E+02 7.5E+00 2.4E+01
3.75E+00 8.5E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
5.82E+03 99% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:22PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:23PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:30PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:32PM EPA Interlab LRef 1313-1316SWA
6.13E+03 104% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:35PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:36PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:38PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:40PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:43PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:50PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
6.33E+03 95% VUICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-614
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone.
1 ug/L
As SWA-LRef-1313-T01-A 1 1.02E+04
As SWA-LRef-1313-T02-A 1 4.22E+03
As SWA-LRef-1313-T03-A 1 2.29E+03
As SWA-LRef-1313-T04-A 1 2.49E+02
As SWA-LRef-1313-T05-A 1 2.89E+02
As SWA-LRef-1313-T06-A 1 1.60E+02
As SWA-LRef-1313-T07-A 1 3.19E+02
As SWA-LRef-1313-T08-A 1 3.69E+03
As SWA-LRef-1313-T09-A 1 6.80E+03
As SWA-LRef-1313-T01-B 1 1.20E+04
As SWA-LRef-1313-T02-B 1 4.90E+03
As SWA-LRef-1313-T03-B 1 3.23E+03
As SWA-LRef-1313-T04-B 1 4.65E+02
As SWA-LRef-1313-T05-B 1 3.38E+02
As SWA-LRef-1313-T06-B 1 3.61 E+02
As SWA-LRef-1313-T07-B 1 2.01E+02
As SWA-LRef-1313-T08-B 1 3.95E+03
As SWA-LRef-1313-T09-B 1 1.05E+04
As SWA-LRef-1313-T01-C 1 1.03E+04
As SWA-LRef-1313-T02-C 1 4.37E+03
As SWA-LRef-1313-T03-C 1 2.54E+03
As SWA-LRef-1313-T04-C 1 4.06E+02
As SWA-LRef-1313-T05-C 1 3.72E+02
As SWA-LRef-1313-T06-C 1 2.43E+02
As SWA-LRef-1313-T07-C 1 1.86E+02
As SWA-LRef-1313-T08-C 1 3.19E+03
As SWA-LRef-1313-T09-C 1 1.40E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.02E+04 5.1E-01 1.1E+01 3.5E+01
4.22E+03 3.0E+00 1.1E+01 3.5E+01
2.29E+03 8.0E-01 1.1E+01 3.5E+01 10 100
2.49E+02 2.9E+00 1.1E+01 3.5E+01
2.89E+02 5.6E+00 1.1E+01 3.5E+01
1.60E+02 1.5E+01 1.1E+01 3.5E+01
3.19E+02 9.0E+00 1.1E+01 3.5E+01
3.69E+03 5.9E-01 1.1E+01 3.5E+01
6.80E+03 6.8E-01 1.1E+01 3.5E+01
1.20E+04 2.0E+00 1.1E+01 3.5E+01
4.90E+03 7.5E-01 1.1E+01 3.5E+01
3.23E+03 3.9E-01 1.1E+01 3.5E+01 10 100
4.65E+02 1.9E+00 1.1E+01 3.5E+01
3.38E+02 5.5E+00 1.1E+01 3.5E+01
3.61 E+02 4.4E+00 1.1E+01 3.5E+01
2.01 E+02 7.5E+00 1.1E+01 3.5E+01
3.95E+03 1.0E+00 1.1E+01 3.5E+01
1.05E+04 4.2E-01 1.1E+01 3.5E+01
1.03E+04 2.1E-01 1.1E+01 3.5E+01
4.37E+03 6.3E-01 1.1E+01 3.5E+01
2.54E+03 1.1E+00 1.1E+01 3.5E+01 10 100
4.06E+02 3.9E+00 1.1E+01 3.5E+01
3.72E+02 5.5E+00 1.1E+01 3.5E+01
2.43E+02 7.0E-01 1.1E+01 3.5E+01
1.86E+02 1.1E+01 1.1E+01 3.5E+01
3.19E+03 9.6E-01 1.1E+01 3.5E+01
1.40E+04 5.6E+00 1.1E+01 3.5E+01
As SWA-LRef-1313-B01-A 1 5.50E+00 U1/2 5.50E+00 2.3E+02 1.1E+01 3.5E+01
As SWA-LRef-1313-B02-A 1 5.50E+00 U1/2 5.50E+00 4.1E+01 1.1E+01 3.5E+01
As SWA-LRef-1313-B03-A 1 5.50E+00 U1/2 5.50E+00 5.2E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
3.23E+03 94% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:17 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:22PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:23PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:30PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:32PM EPA Interlab LRef 1313-1316SWA
4.08E+03 85% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:35PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:36PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:38PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:40PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:43PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:50PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
3.63E+03 109% VU ICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-615
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-LRef-1313-T01-A 1
B SWA-LRef-1313-T02-A 1
B SWA-LRef-1313-T03-A 1
B SWA-LRef-1313-T04-A 1
B SWA-LRef-1313-T05-A 1
B SWA-LRef-1313-T06-A 1
B SWA-LRef-1313-T07-A 1
B SWA-LRef-1313-T08-A 1
B SWA-LRef-1313-T09-A 1
B SWA-LRef-1313-T01-B 1
B SWA-LRef-1313-T02-B 1
B SWA-LRef-1313-T03-B 1
B SWA-LRef-1313-T04-B 1
B SWA-LRef-1313-T05-B 1
B SWA-LRef-1313-T06-B 1
B SWA-LRef-1313-T07-B 1
B SWA-LRef-1313-T08-B 1
B SWA-LRef-1313-T09-B 1
B SWA-LRef-1313-T01-C 1
B SWA-LRef-1313-T02-C 1
B SWA-LRef-1313-T03-C 1
B SWA-LRef-1313-T04-C 1
B SWA-LRef-1313-T05-C 1
B SWA-LRef-1313-T06-C 1
B SWA-LRef-1313-T07-C 1
B SWA-LRef-1313-T08-C 1
B SWA-LRef-1313-T09-C 1
B SWA-LRef-1313-B01-A 1
B SWA-LRef-1313-B02-A 1
B SWA-LRef-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.23E+03
1.00E+03
8.97E+02
1.42E+03
2.18E+03
3.76E+03
6.02E+03
6.84E+03
7.29E+03
1.32E+03
1.03E+03
1.01E+03
1.80E+03
2.65E+03
5.27E+03
5.04E+03
6.96E+03
7.31 E+03
1.27E+03
1.01 E+03
8.70E+02
1.65E+03
2.96E+03
3.41 E+03
5.99E+03
7.07E+03
7.42E+03
1.79E+01
1.25E+01
3.05E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.23E+03 7.8E+00 1.0E+00 3.2E+00
1.00E+03 9.8E-01 1.0E+00 3.2E+00
8.97E+02 1.9E+00 1.0E+00 3.2E+00 1000 100
1.42E+03 6.3E-01 1.0E+00 3.2E+00
2.18E+03 9.9E-01 1.0E+00 3.2E+00
3.76E+03 7.3E-01 1.0E+00 3.2E+00
6.02E+03 7.0E-01 1.0E+00 3.2E+00
6.84E+03 3.2E-01 1.0E+00 3.2E+00
7.29E+03 4.7E-01 1.0E+00 3.2E+00
1.32E+03 7.4E-01 1.0E+00 3.2E+00
1.03E+03 8.9E-01 1.0E+00 3.2E+00
1.01E+03 8.0E-01 1.0E+00 3.2E+00 1000 100
1.80E+03 8.5E-01 1.0E+00 3.2E+00
2.65E+03 4.3E-01 1.0E+00 3.2E+00
5.27E+03 1.1E+00 1.0E+00 3.2E+00
5.04E+03 1.3E-01 1.0E+00 3.2E+00
6.96E+03 9.6E-01 1.0E+00 3.2E+00
7.31 E+03 8.9E-01 1.0E+00 3.2E+00
1.27E+03 4.1E-01 1.0E+00 3.2E+00
1.01 E+03 9.2E-01 1.0E+00 3.2E+00
8.70E+02 2.5E-01 1.0E+00 3.2E+00 1000 100
1.65E+03 1.1E+00 1.0E+00 3.2E+00
2.96E+03 5.2E-01 1.0E+00 3.2E+00
3.41 E+03 3.7E-01 1.0E+00 3.2E+00
5.99E+03 3.8E-01 1.0E+00 3.2E+00
7.07E+03 7.9E-01 1.0E+00 3.2E+00
7.42E+03 2.6E+00 1.0E+00 3.2E+00
1.79E+01 1.2E+00 1.0E+00 3.2E+00
1.25E+01 3.3E+00 1.0E+00 3.2E+00
3.05E+01 4.4E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.87E+03 97% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:22PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:23PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:30PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:32PM EPA Interlab LRef 1313-1316SWA
2.07E+03 106% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:35PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:36PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:38PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:40PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:43PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:50PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.95E+03 108% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-616
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba SWA-LRef-1313-T01-A 1
Ba SWA-LRef-1313-T02-A 1
Ba SWA-LRef-1313-T03-A 1
Ba SWA-LRef-1313-T04-A 1
Ba SWA-LRef-1313-T05-A 1
Ba SWA-LRef-1313-T06-A 1
Ba SWA-LRef-1313-T07-A 1
Ba SWA-LRef-1313-T08-A 1
Ba SWA-LRef-1313-T09-A 1
Ba SWA-LRef-1313-T01-B 1
Ba SWA-LRef-1313-T02-B 1
Ba SWA-LRef-1313-T03-B 1
Ba SWA-LRef-1313-T04-B 1
Ba SWA-LRef-1313-T05-B 1
Ba SWA-LRef-1313-T06-B 1
Ba SWA-LRef-1313-T07-B 1
Ba SWA-LRef-1313-T08-B 1
Ba SWA-LRef-1313-T09-B 1
Ba SWA-LRef-1313-T01-C 1
Ba SWA-LRef-1313-T02-C 1
Ba SWA-LRef-1313-T03-C 1
Ba SWA-LRef-1313-T04-C 1
Ba SWA-LRef-1313-T05-C 1
Ba SWA-LRef-1313-T06-C 1
Ba SWA-LRef-1313-T07-C 1
Ba SWA-LRef-1313-T08-C 1
Ba SWA-LRef-1313-T09-C 1
Ba SWA-LRef-1313-B01-A 1
Ba SWA-LRef-1313-B02-A 1
Ba SWA-LRef-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
4.35E+01
1.43E+02
1.81E+02
1.12E+03
9.81 E+02
1.51E+03
1.84E+03
8.52E+02
9.29E+02
1.85E+02
1.59E+02
1.66E+02
1.05E+03
1.15E+03
1.55E+03
1.56E+03
8.45E+02
9.27E+02
2.33E+02
1.65E+02
1.89E+02
1.00E+03
1.24E+03
1.14E+03
1.75E+03
9.68E+02
9.54E+02
5.00E-01 U1/2
1.87E+00 E
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.35E+01 1.3E+00 1.0E+00 3.2E+00
1.43E+02 4.1E-01 1.0E+00 3.2E+00
1.81 E+02 7.9E-01 1.0E+00 3.2E+00 10 100
1.12E+03 1.2E+00 1.0E+00 3.2E+00
9.81 E+02 8.4E-01 1.0E+00 3.2E+00
1.51E+03 1.1E+00 1.0E+00 3.2E+00
1.84E+03 8.0E-01 1.0E+00 3.2E+00
8.52E+02 3.5E-01 1.0E+00 3.2E+00
9.29E+02 8.3E-01 1.0E+00 3.2E+00
1.85E+02 5.8E+00 1.0E+00 3.2E+00
1.59E+02 5.4E-01 1.0E+00 3.2E+00
1.66E+02 6.1E-01 1.0E+00 3.2E+00 10 100
1.05E+03 3.6E-01 1.0E+00 3.2E+00
1.15E+03 9.3E-01 1.0E+00 3.2E+00
1.55E+03 9.2E-01 1.0E+00 3.2E+00
1.56E+03 2.8E-01 1.0E+00 3.2E+00
8.45E+02 5.3E-01 1.0E+00 3.2E+00
9.27E+02 4.4E-01 1.0E+00 3.2E+00
2.33E+02 5.5E-01 1.0E+00 3.2E+00
1.65E+02 4.7E-01 1.0E+00 3.2E+00
1.89E+02 2.9E-01 1.0E+00 3.2E+00 10 100
1.00E+03 9.6E-01 1.0E+00 3.2E+00
1.24E+03 2.4E-01 1.0E+00 3.2E+00
1.14E+03 7.4E-01 1.0E+00 3.2E+00
1.75E+03 2.4E-01 1.0E+00 3.2E+00
9.68E+02 4.4E-01 1.0E+00 3.2E+00
9.54E+02 5.7E+00 1.0E+00 3.2E+00
5.00E-01 6.3E+00 1.0E+00 3.2E+00
1.87E+00 2.1E+00 1.0E+00 3.2E+00
5.00E-01 3.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.20E+03 102% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:17 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.19E+03 102% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.22E+03 103% VUICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-617
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-LRef-1313-T01-A 1
Be SWA-LRef-1313-T02-A 1
Be SWA-LRef-1313-T03-A 1
Be SWA-LRef-1313-T04-A 1
Be SWA-LRef-1313-T05-A 1
Be SWA-LRef-1313-T06-A 1
Be SWA-LRef-1313-T07-A 1
Be SWA-LRef-1313-T08-A 1
Be SWA-LRef-1313-T09-A 1
Be SWA-LRef-1313-T01-B 1
Be SWA-LRef-1313-T02-B 1
Be SWA-LRef-1313-T03-B 1
Be SWA-LRef-1313-T04-B 1
Be SWA-LRef-1313-T05-B 1
Be SWA-LRef-1313-T06-B 1
Be SWA-LRef-1313-T07-B 1
Be SWA-LRef-1313-T08-B 1
Be SWA-LRef-1313-T09-B 1
Be SWA-LRef-1313-T01-C 1
Be SWA-LRef-1313-T02-C 1
Be SWA-LRef-1313-T03-C 1
Be SWA-LRef-1313-T04-C 1
Be SWA-LRef-1313-T05-C 1
Be SWA-LRef-1313-T06-C 1
Be SWA-LRef-1313-T07-C 1
Be SWA-LRef-1313-T08-C 1
Be SWA-LRef-1313-T09-C 1
Be SWA-LRef-1313-B01-A 1
Be SWA-LRef-1313-B02-A 1
Be SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
2.42E+01
1.39E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
3.05E+01
1.49E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.01E+01
1.53E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 8.4E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+03 1.9E+00 6.0E+00
9.50E-01 5.2E+02 1.9E+00 6.0E+00 10 100
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
2.42E+01 1.9E+00 1.9E+00 6.0E+00
1.39E+02 1.6E+00 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 8.6E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+03 1.9E+00 6.0E+00 10 100
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 8.6E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
3.05E+01 5.1E-01 1.9E+00 6.0E+00
1.49E+02 7.5E-01 1.9E+00 6.0E+00
9.50E-01 8.5E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00
9.50E-01 1.6E+04 1.9E+00 6.0E+00 10 100
9.50E-01 3.5E+02 1.9E+00 6.0E+00
9.50E-01 3.6E+02 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 8.6E+01 1.9E+00 6.0E+00
1.01E+01 7.6E+00 1.9E+00 6.0E+00
1.53E+02 4.6E+00 1.9E+00 6.0E+00
9.50E-01 8.7E+02 1.9E+00 6.0E+00
9.50E-01 4.5E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.08E+03 108% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.08E+03 108% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.09E+03 109% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-618
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd SWA-LRef-1313-T01-A 1
Cd SWA-LRef-1313-T02-A 1
Cd SWA-LRef-1313-T03-A 1
Cd SWA-LRef-1313-T04-A 1
Cd SWA-LRef-1313-T05-A 1
Cd SWA-LRef-1313-T06-A 1
Cd SWA-LRef-1313-T07-A 1
Cd SWA-LRef-1313-T08-A 1
Cd SWA-LRef-1313-T09-A 1
Cd SWA-LRef-1313-T01-B 1
Cd SWA-LRef-1313-T02-B 1
Cd SWA-LRef-1313-T03-B 1
Cd SWA-LRef-1313-T04-B 1
Cd SWA-LRef-1313-T05-B 1
Cd SWA-LRef-1313-T06-B 1
Cd SWA-LRef-1313-T07-B 1
Cd SWA-LRef-1313-T08-B 1
Cd SWA-LRef-1313-T09-B 1
Cd SWA-LRef-1313-T01-C 1
Cd SWA-LRef-1313-T02-C 1
Cd SWA-LRef-1313-T03-C 1
Cd SWA-LRef-1313-T04-C 1
Cd SWA-LRef-1313-T05-C 1
Cd SWA-LRef-1313-T06-C 1
Cd SWA-LRef-1313-T07-C 1
Cd SWA-LRef-1313-T08-C 1
Cd SWA-LRef-1313-T09-C 1
Cd SWA-LRef-1313-B01-A 1
Cd SWA-LRef-1313-B02-A 1
Cd SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.41E+01
1.77E+01
3.83E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
3.28E+00 E
1.96E+01
3.89E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.03E+01
1.56E+01
4.25E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 4.3E+01 2.2E+00 7.0E+00
1.10E+00 1.6E+03 2.2E+00 7.0E+00
1.10E+00 1.8E+02 2.2E+00 7.0E+00 10 100
1.10E+00 1.0E+02 2.2E+00 7.0E+00
1.10E+00 1.0E+02 2.2E+00 7.0E+00
1.10E+00 1.5E+01 2.2E+00 7.0E+00
1.41E+01 3.2E+00 2.2E+00 7.0E+00
1.77E+01 1.4E+00 2.2E+00 7.0E+00
3.83E+01 1.1E+00 2.2E+00 7.0E+00
1.10E+00 1.6E+02 2.2E+00 7.0E+00
1.10E+00 1.4E+02 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00 10 100
1.10E+00 3.8E+01 2.2E+00 7.0E+00
1.10E+00 2.1E+02 2.2E+00 7.0E+00
1.10E+00 5.6E+00 2.2E+00 7.0E+00
3.28E+00 1.7E+00 2.2E+00 7.0E+00
1.96E+01 1.6E+00 2.2E+00 7.0E+00
3.89E+01 2.4E-01 2.2E+00 7.0E+00
1.10E+00 9.8E+01 2.2E+00 7.0E+00
1.10E+00 1.8E+02 2.2E+00 7.0E+00
1.10E+00 1.9E+02 2.2E+00 7.0E+00 10 100
1.10E+00 4.8E+01 2.2E+00 7.0E+00
1.10E+00 1.0E+02 2.2E+00 7.0E+00
1.10E+00 7.7E+01 2.2E+00 7.0E+00
1.03E+01 5.7E+00 2.2E+00 7.0E+00
1.56E+01 3.7E+00 2.2E+00 7.0E+00
4.25E+01 3.0E+00 2.2E+00 7.0E+00
1.10E+00 1.7E+01 2.2E+00 7.0E+00
1.10E+00 6.7E+02 2.2E+00 7.0E+00
1.10E+00 1.4E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316 SWA
1.04E+03 104% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:17 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.04E+03 104% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:40 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:43PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :51 PM EPA Interlab LRef 1313-1316 SWA
1.05E+03 105% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/101 :58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/101 :05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1 /1 9/1 0 1 :07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/101 :09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-619
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
1 1 ug/L
Ca SWA-LRef-1313-T01-A 1 5.39E+03
Ca SWA-LRef-1313-T02-A 1 1.34E+04
Ca SWA-LRef-1313-T03-A 1 2.34E+04
Ca SWA-LRef-1313-T04-A 1 4.20E+06
Ca SWA-LRef-1313-T05-A 1 5.79E+06
Ca SWA-LRef-1313-T06-A 1 8.99E+06
Ca SWA-LRef-1313-T07-A 1 1.02E+07
Ca SWA-LRef-1313-T08-A 1 5.28E+06
Ca SWA-LRef-1313-T09-A 1 3.60E+06
Ca SWA-LRef-1313-T01-B 1 6.81E+03
Ca SWA-LRef-1313-T02-B 1 1.34E+04
Ca SWA-LRef-1313-T03-B 1 2.13E+04
Ca SWA-LRef-1313-T04-B 1 5.23E+06
Ca SWA-LRef-1313-T05-B 1 7.12E+06
Ca SWA-LRef-1313-T06-B 1 9.20E+06
Ca SWA-LRef-1313-T07-B 1 8.54E+06
Ca SWA-LRef-1313-T08-B 1 5.16E+06
Ca SWA-LRef-1313-T09-B 1 3.82E+06
Ca SWA-LRef-1313-T01-C 1 7.65E+03
Ca SWA-LRef-1313-T02-C 1 1 .44E+04
Ca SWA-LRef-1313-T03-C 1 2.32E+04
Ca SWA-LRef-1313-T04-C 1 4.67E+06
Ca SWA-LRef-1313-T05-C 1 7.71E+06
Ca SWA-LRef-1313-T06-C 1 6.94E+06
Ca SWA-LRef-1313-T07-C 1 8.96E+06
Ca SWA-LRef-1313-T08-C 1 5.61E+06
Ca SWA-LRef-1313-T09-C 1 3.83E+06
Ca SWA-LRef-1313-B01-A 1 3.20E+01
Ca SWA-LRef-1313-B02-A 1 3.05E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.39E+03 5.7E-01 2.6E+00 8.3E+00
1.34E+04 5.8E-01 2.6E+00 8.3E+00
2.34E+04 8.1E-01 2.6E+00 8.3E+00 1000 100
4.20E+06 1.2E+00 2.6E+00 8.3E+00
5.79E+06 4.4E-01 2.6E+00 8.3E+00
8.99E+06 9.4E-01 2.6E+00 8.3E+00
1.02E+07 6.5E-01 2.6E+00 8.3E+00
5.28E+06 1.2E-01 2.6E+00 8.3E+00
3.60E+06 7.9E-01 2.6E+00 8.3E+00
6.81 E+03 5.4E+00 2.6E+00 8.3E+00
1.34E+04 3.9E-01 2.6E+00 8.3E+00
2.13E+04 5.6E-01 2.6E+00 8.3E+00 1000 100
5.23E+06 9.3E-01 2.6E+00 8.3E+00
7.12E+06 7.0E-01 2.6E+00 8.3E+00
9.20E+06 1.6E+00 2.6E+00 8.3E+00
8.54E+06 9.6E-01 2.6E+00 8.3E+00
5.16E+06 5.5E-01 2.6E+00 8.3E+00
3.82E+06 1.2E+00 2.6E+00 8.3E+00
7.65E+03 7.2E-01 2.6E+00 8.3E+00
1.44E+04 5.5E-01 2.6E+00 8.3E+00
2.32E+04 4.0E-01 2.6E+00 8.3E+00 1000 100
4.67E+06 9.6E-01 2.6E+00 8.3E+00
7.71 E+06 1.0E+00 2.6E+00 8.3E+00
6.94E+06 2.0E-01 2.6E+00 8.3E+00
8.96E+06 6.7E-01 2.6E+00 8.3E+00
5.61 E+06 1.4E+00 2.6E+00 8.3E+00
3.83E+06 6.3E-01 2.6E+00 8.3E+00
3.20E+01 4.7E+01 2.6E+00 8.3E+00
3.05E+01 2.2E+01 2.6E+00 8.3E+00
Ca SWA-LRef-1313-B03-A 1 1.30E+OOU1/2 1 .30E+00 4.9E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
2.43E+04 91% VUICP-OES 1 1/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:15 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:17 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316 SWA
2.23E+04 95% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
2.40E+04 83% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-620
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr SWA-LRef-1313-T01-A 1
Cr SWA-LRef-1313-T02-A 1
Cr SWA-LRef-1313-T03-A 1
Cr SWA-LRef-1313-T04-A 1
Cr SWA-LRef-1313-T05-A 1
Cr SWA-LRef-1313-T06-A 1
Cr SWA-LRef-1313-T07-A 1
Cr SWA-LRef-1313-T08-A 1
Cr SWA-LRef-1313-T09-A 1
Cr SWA-LRef-1313-T01-B 1
Cr SWA-LRef-1313-T02-B 1
Cr SWA-LRef-1313-T03-B 1
Cr SWA-LRef-1313-T04-B 1
Cr SWA-LRef-1313-T05-B 1
Cr SWA-LRef-1313-T06-B 1
Cr SWA-LRef-1313-T07-B 1
Cr SWA-LRef-1313-T08-B 1
Cr SWA-LRef-1313-T09-B 1
Cr SWA-LRef-1313-T01-C 1
Cr SWA-LRef-1313-T02-C 1
Cr SWA-LRef-1313-T03-C 1
Cr SWA-LRef-1313-T04-C 1
Cr SWA-LRef-1313-T05-C 1
Cr SWA-LRef-1313-T06-C 1
Cr SWA-LRef-1313-T07-C 1
Cr SWA-LRef-1313-T08-C 1
Cr SWA-LRef-1313-T09-C 1
Cr SWA-LRef-1313-B01-A 1
Cr SWA-LRef-1313-B02-A 1
Cr SWA-LRef-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.13E+03
9.85E+02
4.12E+02
3.92E+00
4.15E+00
1.23E+00 E
1.59E+01
2.80E+03
2.40E+04
1.53E+03
1.21E+03
6.01 E+02
2.32E+00 E
1.79E+00 E
6.00E-01 U1/2
4.91 E+00
3.59E+03
2.18E+04
1.51E+03
1.17E+03
3.55E+02
3.68E+00 E
1.24E+00 E
6.00E-01 U1/2
3.41 E+00 E
1.78E+03
2.40E+04
6.00E-01 U1/2
6.00E-01 U1/2
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.13E+03 7.5E-01 1.2E+00 3.8E+00
9.85E+02 1.1 E+00 1.2E+00 3.8E+00
4.12E+02 6.2E-01 1.2E+00 3.8E+00 10 100
3.92E+00 1.6E+01 1.2E+00 3.8E+00
4.15E+00 2.1E+01 1.2E+00 3.8E+00
1.23E+00 7.0E+01 1.2E+00 3.8E+00
1.59E+01 2.3E+00 1.2E+00 3.8E+00
2.80E+03 4.8E-01 1.2E+00 3.8E+00
2.40E+04 1.9E-01 1.2E+00 3.8E+00
1.53E+03 5.8E+00 1.2E+00 3.8E+00
1.21E+03 1.7E-02 1.2E+00 3.8E+00
6.01E+02 2.5E-01 1.2E+00 3.8E+00 10 100
2.32E+00 1.1E+01 1.2E+00 3.8E+00
1.79E+00 7.4E+01 1.2E+00 3.8E+00
6.00E-01 1.9E+02 1.2E+00 3.8E+00
4.91 E+00 1.4E+01 1.2E+00 3.8E+00
3.59E+03 9.1E-01 1.2E+00 3.8E+00
2.18E+04 6.8E-01 1.2E+00 3.8E+00
1.51E+03 8.0E-01 1.2E+00 3.8E+00
1.17E+03 2.1E-01 1.2E+00 3.8E+00
3.55E+02 4.9E-01 1.2E+00 3.8E+00 10 100
3.68E+00 4.6E+01 1.2E+00 3.8E+00
1.24E+00 6.0E+01 1.2E+00 3.8E+00
6.00E-01 4.8E+01 1.2E+00 3.8E+00
3.41 E+00 2.0E+01 1.2E+00 3.8E+00
1.78E+03 6.5E-01 1.2E+00 3.8E+00
2.40E+04 3.3E+00 1.2E+00 3.8E+00
6.00E-01 2.7E+01 1.2E+00 3.8E+00
6.00E-01 4.3E+02 1.2E+00 3.8E+00
6.00E-01 7.1E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.45E+03 103% VUICP-OES 1 1/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:15 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:17 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316 SWA
1.60E+03 100% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.40E+03 104% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-621
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co SWA-LRef-1313-T01-A 1
Co SWA-LRef-1313-T02-A 1
Co SWA-LRef-1313-T03-A 1
Co SWA-LRef-1313-T04-A 1
Co SWA-LRef-1313-T05-A 1
Co SWA-LRef-1313-T06-A 1
Co SWA-LRef-1313-T07-A 1
Co SWA-LRef-1313-T08-A 1
Co SWA-LRef-1313-T09-A 1
Co SWA-LRef-1313-T01-B 1
Co SWA-LRef-1313-T02-B 1
Co SWA-LRef-1313-T03-B 1
Co SWA-LRef-1313-T04-B 1
Co SWA-LRef-1313-T05-B 1
Co SWA-LRef-1313-T06-B 1
Co SWA-LRef-1313-T07-B 1
Co SWA-LRef-1313-T08-B 1
Co SWA-LRef-1313-T09-B 1
Co SWA-LRef-1313-T01-C 1
Co SWA-LRef-1313-T02-C 1
Co SWA-LRef-1313-T03-C 1
Co SWA-LRef-1313-T04-C 1
Co SWA-LRef-1313-T05-C 1
Co SWA-LRef-1313-T06-C 1
Co SWA-LRef-1313-T07-C 1
Co SWA-LRef-1313-T08-C 1
Co SWA-LRef-1313-T09-C 1
Co SWA-LRef-1313-B01-A 1
Co SWA-LRef-1313-B02-A 1
Co SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.36E+00 E
4.05E+00 E
1.49E+02
2.46E+02
1.81E+02
2.50E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.18E+00 E
7.06E+00
1.29E+02
1.54E+02
1.89E+02
2.50E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.31 E+00 E
1.01E+01
4.27E+01
2.06E+02
1.91E+02
2.61 E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 8.0E+01 1.8E+00 5.7E+00
9.00E-01 6.3E+01 1.8E+00 5.7E+00 10 100
2.36E+00 5.0E+01 1.8E+00 5.7E+00
4.05E+00 1.6E+01 1.8E+00 5.7E+00
1.49E+02 9.0E-01 1.8E+00 5.7E+00
2.46E+02 1.7E-01 1.8E+00 5.7E+00
1.81 E+02 8.0E-01 1.8E+00 5.7E+00
2.50E+02 8.3E-01 1.8E+00 5.7E+00
9.00E-01 8.1E+01 1.8E+00 5.7E+00
9.00E-01 3.4E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00 10 100
2.18E+00 6.9E+01 1.8E+00 5.7E+00
7.06E+00 1.2E+01 1.8E+00 5.7E+00
1.29E+02 2.1 E+00 1.8E+00 5.7E+00
1.54E+02 1.8E+00 1.8E+00 5.7E+00
1.89E+02 7.5E-01 1.8E+00 5.7E+00
2.50E+02 6.0E-01 1.8E+00 5.7E+00
9.00E-01 5.2E+01 1.8E+00 5.7E+00
9.00E-01 4.3E+01 1.8E+00 5.7E+00
9.00E-01 7.6E+01 1.8E+00 5.7E+00 10 100
2.31 E+00 6.9E+01 1.8E+00 5.7E+00
1.01E+01 1.1E+01 1.8E+00 5.7E+00
4.27E+01 5.2E+00 1.8E+00 5.7E+00
2.06E+02 7.4E-01 1.8E+00 5.7E+00
1.91 E+02 6.0E-01 1.8E+00 5.7E+00
2.61 E+02 2.2E+00 1.8E+00 5.7E+00
9.00E-01 5.8E+01 1.8E+00 5.7E+00
9.00E-01 3.5E+01 1.8E+00 5.7E+00
9.00E-01 3.3E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316 SWA
1.02E+03 102% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:17 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:22 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:23PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:30PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:32PM EPA Interlab LRef 1313-1316SWA
1.01E+03 101% VUICP-OES 1 1/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:35PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:51 PM EPA Interlab LRef 1313-1316 SWA
1.02E+03 102% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-622
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu SWA-LRef-1313-T01-A 1
Cu SWA-LRef-1313-T02-A 1
Cu SWA-LRef-1313-T03-A 1
Cu SWA-LRef-1313-T04-A 1
Cu SWA-LRef-1313-T05-A 1
Cu SWA-LRef-1313-T06-A 1
Cu SWA-LRef-1313-T07-A 1
Cu SWA-LRef-1313-T08-A 1
Cu SWA-LRef-1313-T09-A 1
Cu SWA-LRef-1313-T01-B 1
Cu SWA-LRef-1313-T02-B 1
Cu SWA-LRef-1313-T03-B 1
Cu SWA-LRef-1313-T04-B 1
Cu SWA-LRef-1313-T05-B 1
Cu SWA-LRef-1313-T06-B 1
Cu SWA-LRef-1313-T07-B 1
Cu SWA-LRef-1313-T08-B 1
Cu SWA-LRef-1313-T09-B 1
Cu SWA-LRef-1313-T01-C 1
Cu SWA-LRef-1313-T02-C 1
Cu SWA-LRef-1313-T03-C 1
Cu SWA-LRef-1313-T04-C 1
Cu SWA-LRef-1313-T05-C 1
Cu SWA-LRef-1313-T06-C 1
Cu SWA-LRef-1313-T07-C 1
Cu SWA-LRef-1313-T08-C 1
Cu SWA-LRef-1313-T09-C 1
Cu SWA-LRef-1313-B01-A 1
Cu SWA-LRef-1313-B02-A 1
Cu SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
6.06E+00 E
8.81 E+00 E
1.97E+01
1.54E+01
3.17E+01
1.50E+03
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
7.25E+00 E
1.04E+01 E
1.10E+01 E
1.26E+01
1.87E+01
1.51E+03
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
6.19E+00 E
8.30E+00 E
8.19E+00 E
1.54E+01
1.87E+01
1.57E+03
5.29E+00 E
1.85E+00 U1/2
1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 1.7E+02 3.7E+00 1.2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01
1.85E+00 1.4E+02 3.7E+00 1.2E+01 10 100
6.06E+00 2.0E+01 3.7E+00 1.2E+01
8.81 E+00 4.0E+01 3.7E+00 1 .2E+01
1.97E+01 2.9E+01 3.7E+00 1 .2E+01
1.54E+01 2.1E+01 3.7E+00 1 .2E+01
3.17E+01 7.0E+00 3.7E+00 1 .2E+01
1.50E+03 6.3E-01 3.7E+00 1.2E+01
1.85E+00 1.7E+02 3.7E+00 1.2E+01
1.85E+00 2.4E+02 3.7E+00 1.2E+01
1.85E+00 9.2E+01 3.7E+00 1.2E+01 10 100
7.25E+00 1.9E+01 3.7E+00 1.2E+01
1.04E+01 3.3E+01 3.7E+00 1.2E+01
1.10E+01 3.8E+01 3.7E+00 1.2E+01
1.26E+01 2.2E+01 3.7E+00 1.2E+01
1.87E+01 9.6E-01 3.7E+00 1.2E+01
1.51E+03 7.7E-01 3.7E+00 1.2E+01
1.85E+00 9.6E+02 3.7E+00 1.2E+01
1.85E+00 3.8E+02 3.7E+00 1.2E+01
1.85E+00 8.1E+02 3.7E+00 1.2E+01 10 100
6.19E+00 1.2E+01 3.7E+00 1.2E+01
8.30E+00 2.3E+01 3.7E+00 1.2E+01
8.19E+00 3.0E+01 3.7E+00 1.2E+01
1.54E+01 7.7E+00 3.7E+00 1.2E+01
1.87E+01 1.1E+01 3.7E+00 1.2E+01
1.57E+03 1.7E+00 3.7E+00 1.2E+01
5.29E+00 3.7E+01 3.7E+00 1.2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01
1.85E+00 3.4E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316 SWA
1.03E+03 103% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:17 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:22 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:23PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:30PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:32PM EPA Interlab LRef 1313-1316SWA
1.03E+03 102% VUICP-OES 1 1/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:35PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:51 PM EPA Interlab LRef 1313-1316 SWA
1.03E+03 102% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-623
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone.
1 ug/L
Fe SWA-LRef-1313-T01-A 1 5.87E+01
Fe SWA-LRef-1313-T02-A 1 7.31 E+01
Fe SWA-LRef-1313-T03-A 1 5.33E+01
Fe SWA-LRef-1313-T04-A 1 2.08E+01
Fe SWA-LRef-1313-T05-A 1 3.03E+01
Fe SWA-LRef-1313-T06-A 1 3.90E+04
Fe SWA-LRef-1313-T07-A 1 1.31E+05
Fe SWA-LRef-1313-T08-A 1 1.31E+05
Fe SWA-LRef-1313-T09-A 1 1.95E+05
Fe SWA-LRef-1313-T01-B 1 1.13E+02
Fe SWA-LRef-1313-T02-B 1 8.01 E+01
Fe SWA-LRef-1313-T03-B 1 8.13E+01
Fe SWA-LRef-1313-T04-B 1 2.63E+01
Fe SWA-LRef-1313-T05-B 1 2.59E+01
Fe SWA-LRef-1313-T06-B 1 6.12E+04
Fe SWA-LRef-1313-T07-B 1 5.18E+04
Fe SWA-LRef-1313-T08-B 1 1.35E+05
Fe SWA-LRef-1313-T09-B 1 1.78E+05
Fe SWA-LRef-1313-T01-C 1 9.26E+01
Fe SWA-LRef-1313-T02-C 1 7.18E+01
Fe SWA-LRef-1313-T03-C 1 6.28E+01
Fe SWA-LRef-1313-T04-C 1 2.69E+01
Fe SWA-LRef-1313-T05-C 1 2.70E+01
Fe SWA-LRef-1313-T06-C 1 3.09E+03
Fe SWA-LRef-1313-T07-C 1 1.01E+05
Fe SWA-LRef-1313-T08-C 1 1.24E+05
Fe SWA-LRef-1313-T09-C 1 1.91E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.87E+01 4.0E+01 2.0E+00 6.4E+00
7.31E+01 2.4E+01 2.0E+00 6.4E+00
5.33E+01 1.5E+00 2.0E+00 6.4E+00 1000 100
2.08E+01 3.7E+00 2.0E+00 6.4E+00
3.03E+01 1.1E+00 2.0E+00 6.4E+00
3.90E+04 1.6E-02 2.0E+00 6.4E+00
1.31E+05 4.3E-01 2.0E+00 6.4E+00
1.31E+05 7.4E-01 2.0E+00 6.4E+00
1.95E+05 6.2E-01 2.0E+00 6.4E+00
1.13E+02 5.2E+00 2.0E+00 6.4E+00
8.01 E+01 9.7E-01 2.0E+00 6.4E+00
8.13E+01 1.4E+00 2.0E+00 6.4E+00 1000 100
2.63E+01 3.7E+00 2.0E+00 6.4E+00
2.59E+01 4.9E+00 2.0E+00 6.4E+00
6.12E+04 1.3E+00 2.0E+00 6.4E+00
5.18E+04 8.2E-01 2.0E+00 6.4E+00
1.35E+05 4.9E-01 2.0E+00 6.4E+00
1.78E+05 1.3E+00 2.0E+00 6.4E+00
9.26E+01 4.2E-01 2.0E+00 6.4E+00
7.18E+01 2.0E+00 2.0E+00 6.4E+00
6.28E+01 1.2E+00 2.0E+00 6.4E+00 1000 100
2.69E+01 2.3E+00 2.0E+00 6.4E+00
2.70E+01 7.4E+00 2.0E+00 6.4E+00
3.09E+03 9.6E-01 2.0E+00 6.4E+00
1.01E+05 5.4E-01 2.0E+00 6.4E+00
1.24E+05 5.5E-01 2.0E+00 6.4E+00
1.91E+05 4.3E+00 2.0E+00 6.4E+00
Fe SWA-LRef-1313-B01-A 1 1.00E+OOU1/2 1.00E+00 5.8E+00 2.0E+00 6.4E+00
Fe SWA-LRef-1313-B02-A 1 4.90E+00 E 4.90E+00 3.7E+00 2.0E+00 6.4E+00
Fe SWA-LRef-1313-B03-A 1 2.47E+00 E 2.47E+00 6.1E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.11E+03 106% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.14E+03 105% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.13E+03 107% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-624
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb SWA-LRef-1313-T01-A 1
Pb SWA-LRef-1313-T02-A 1
Pb SWA-LRef-1313-T03-A 1
Pb SWA-LRef-1313-T04-A 1
Pb SWA-LRef-1313-T05-A 1
Pb SWA-LRef-1313-T06-A 1
Pb SWA-LRef-1313-T07-A 1
Pb SWA-LRef-1313-T08-A 1
Pb SWA-LRef-1313-T09-A 1
Pb SWA-LRef-1313-T01-B 1
Pb SWA-LRef-1313-T02-B 1
Pb SWA-LRef-1313-T03-B 1
Pb SWA-LRef-1313-T04-B 1
Pb SWA-LRef-1313-T05-B 1
Pb SWA-LRef-1313-T06-B 1
Pb SWA-LRef-1313-T07-B 1
Pb SWA-LRef-1313-T08-B 1
Pb SWA-LRef-1313-T09-B 1
Pb SWA-LRef-1313-T01-C 1
Pb SWA-LRef-1313-T02-C 1
Pb SWA-LRef-1313-T03-C 1
Pb SWA-LRef-1313-T04-C 1
Pb SWA-LRef-1313-T05-C 1
Pb SWA-LRef-1313-T06-C 1
Pb SWA-LRef-1313-T07-C 1
Pb SWA-LRef-1313-T08-C 1
Pb SWA-LRef-1313-T09-C 1
Pb SWA-LRef-1313-B01-A 1
Pb SWA-LRef-1313-B02-A 1
Pb SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.02E+01 E
7.28E+00 E
8.46E+00 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.34E+02
3.65E+03
5.69E+01
1.38E+01 E
8.83E+00 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.44E+02
3.70E+03
3.25E+01
2.12E+01 E
9.07E+00 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
4.79E+01
4.09E+03
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.02E+01 4.3E+00 6.8E+00 2.2E+01
7.28E+00 1.1E+01 6.8E+00 2.2E+01
8.46E+00 5.4E+01 6.8E+00 2.2E+01 10 100
3.40E+00 7.4E+01 6.8E+00 2.2E+01
3.40E+00 2.4E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
1.34E+02 2.7E+00 6.8E+00 2.2E+01
3.65E+03 4.4E-01 6.8E+00 2.2E+01
5.69E+01 1.3E+01 6.8E+00 2.2E+01
1.38E+01 2.6E+01 6.8E+00 2.2E+01
8.83E+00 2.0E+01 6.8E+00 2.2E+01 10 100
3.40E+00 8.9E+01 6.8E+00 2.2E+01
3.40E+00 7.3E+01 6.8E+00 2.2E+01
3.40E+00 3.3E+02 6.8E+00 2.2E+01
3.40E+00 5.8E+02 6.8E+00 2.2E+01
1.44E+02 1.0E-01 6.8E+00 2.2E+01
3.70E+03 4.8E-01 6.8E+00 2.2E+01
3.25E+01 1.3E+01 6.8E+00 2.2E+01
2.12E+01 2.3E+01 6.8E+00 2.2E+01
9.07E+00 7.5E+01 6.8E+00 2.2E+01 10 100
3.40E+00 1.0E+02 6.8E+00 2.2E+01
3.40E+00 3.7E+02 6.8E+00 2.2E+01
3.40E+00 7.2E+01 6.8E+00 2.2E+01
3.40E+00 8.2E+02 6.8E+00 2.2E+01
4.79E+01 6.1E+00 6.8E+00 2.2E+01
4.09E+03 2.6E+00 6.8E+00 2.2E+01
3.40E+00 1.4E+01 6.8E+00 2.2E+01
3.40E+00 1.7E+02 6.8E+00 2.2E+01
3.40E+00 2.9E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
9.86E+02 98% VUICP-OES 1 1/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:17 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
9.89E+02 98% VUICP-OES 1 1/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VU ICP-OES 1 1/19/10 1 :41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:43 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
9.95E+02 99% VU ICP-OES 1 1/19/10 1 :53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1 :55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1 :56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1 :58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1 :05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1 :07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1 :09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-625
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li SWA-LRef-1313-T01-A 1
Li SWA-LRef-1313-T02-A 1
Li SWA-LRef-1313-T03-A 1
Li SWA-LRef-1313-T04-A 1
Li SWA-LRef-1313-T05-A 1
Li SWA-LRef-1313-T06-A 1
Li SWA-LRef-1313-T07-A 1
Li SWA-LRef-1313-T08-A 1
Li SWA-LRef-1313-T09-A 1
Li SWA-LRef-1313-T01-B 1
Li SWA-LRef-1313-T02-B 1
Li SWA-LRef-1313-T03-B 1
Li SWA-LRef-1313-T04-B 1
Li SWA-LRef-1313-T05-B 1
Li SWA-LRef-1313-T06-B 1
Li SWA-LRef-1313-T07-B 1
Li SWA-LRef-1313-T08-B 1
Li SWA-LRef-1313-T09-B 1
Li SWA-LRef-1313-T01-C 1
Li SWA-LRef-1313-T02-C 1
Li SWA-LRef-1313-T03-C 1
Li SWA-LRef-1313-T04-C 1
Li SWA-LRef-1313-T05-C 1
Li SWA-LRef-1313-T06-C 1
Li SWA-LRef-1313-T07-C 1
Li SWA-LRef-1313-T08-C 1
Li SWA-LRef-1313-T09-C 1
Li SWA-LRef-1313-B01-A 1
Li SWA-LRef-1313-B02-A 1
Li SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
4.47E+02
7.98E+02
1.37E+03
1.67E+03
9.04E+02
9.61 E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
6.74E+02
1.08E+03
1.45E+03
1.26E+03
8.98E+02
9.74E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
5.36E+02
1.13E+03
1.01E+03
1.35E+03
9.93E+02
9.55E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 5.5E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+01 1.9E+00 6.0E+00
9.50E-01 4.5E+01 1.9E+00 6.0E+00 10 100
4.47E+02 1.6E+00 1.9E+00 6.0E+00
7.98E+02 2.5E+00 1.9E+00 6.0E+00
1.37E+03 2.6E+00 1.9E+00 6.0E+00
1.67E+03 1.8E+00 1.9E+00 6.0E+00
9.04E+02 6.3E+00 1.9E+00 6.0E+00
9.61 E+02 1.2E+01 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
9.50E-01 3.6E+01 1.9E+00 6.0E+00
9.50E-01 6.3E+01 1.9E+00 6.0E+00 10 100
6.74E+02 5.6E+00 1.9E+00 6.0E+00
1.08E+03 1.6E+00 1.9E+00 6.0E+00
1.45E+03 5.7E+00 1.9E+00 6.0E+00
1.26E+03 3.3E+00 1.9E+00 6.0E+00
8.98E+02 1.0E+01 1.9E+00 6.0E+00
9.74E+02 4.3E+00 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00 10 100
5.36E+02 3.5E+00 1.9E+00 6.0E+00
1.13E+03 1.7E+00 1.9E+00 6.0E+00
1.01E+03 2.1E+00 1.9E+00 6.0E+00
1.35E+03 5.6E-01 1.9E+00 6.0E+00
9.93E+02 5.3E+00 1.9E+00 6.0E+00
9.55E+02 6.2E+00 1.9E+00 6.0E+00
9.50E-01 8.2E+01 1.9E+00 6.0E+00
9.50E-01 6.8E+01 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
8.18E+02 82% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:17 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:20 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:22PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:23PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:30PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:32PM EPA Interlab LRef 1313-1316SWA
8.06E+02 81% VUICP-OES 1 1/19/10 1 :33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:51 PM EPA Interlab LRef 1313-1316 SWA
8.11E+02 81% VUICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-626
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn SWA-LRef-1313-T01-A 1
Mn SWA-LRef-1313-T02-A 1
Mn SWA-LRef-1313-T03-A 1
Mn SWA-LRef-1313-T04-A 1
Mn SWA-LRef-1313-T05-A 1
Mn SWA-LRef-1313-T06-A 1
Mn SWA-LRef-1313-T07-A 1
Mn SWA-LRef-1313-T08-A 1
Mn SWA-LRef-1313-T09-A 1
Mn SWA-LRef-1313-T01-B 1
Mn SWA-LRef-1313-T02-B 1
Mn SWA-LRef-1313-T03-B 1
Mn SWA-LRef-1313-T04-B 1
Mn SWA-LRef-1313-T05-B 1
Mn SWA-LRef-1313-T06-B 1
Mn SWA-LRef-1313-T07-B 1
Mn SWA-LRef-1313-T08-B 1
Mn SWA-LRef-1313-T09-B 1
Mn SWA-LRef-1313-T01-C 1
Mn SWA-LRef-1313-T02-C 1
Mn SWA-LRef-1313-T03-C 1
Mn SWA-LRef-1313-T04-C 1
Mn SWA-LRef-1313-T05-C 1
Mn SWA-LRef-1313-T06-C 1
Mn SWA-LRef-1313-T07-C 1
Mn SWA-LRef-1313-T08-C 1
Mn SWA-LRef-1313-T09-C 1
Mn SWA-LRef-1313-B01-A 1
Mn SWA-LRef-1313-B02-A 1
Mn SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.16E+01
1.95E+03
2.30E+04
3.14E+04
1.91E+04
2.04E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.39E+02
3.33E+03
2.16E+04
2.19E+04
1.88E+04
2.07E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.32E+01
3.36E+03
1.03E+04
2.63E+04
2.04E+04
2.06E+04
1.00E+00 U1/2
4.73E+00 E
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 9.5E+00 2.0E+00 6.4E+00 10 100
3.16E+01 1.0E+01 2.0E+00 6.4E+00
1.95E+03 5.5E-01 2.0E+00 6.4E+00
2.30E+04 4.3E-01 2.0E+00 6.4E+00
3.14E+04 5.3E-01 2.0E+00 6.4E+00
1.91E+04 5.8E-01 2.0E+00 6.4E+00
2.04E+04 5.2E-01 2.0E+00 6.4E+00
1.00E+00 7.5E+00 2.0E+00 6.4E+00
1.00E+00 3.7E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+00 2.0E+00 6.4E+00 10 100
1.39E+02 6.6E-01 2.0E+00 6.4E+00
3.33E+03 9.6E-01 2.0E+00 6.4E+00
2.16E+04 7.9E-01 2.0E+00 6.4E+00
2.19E+04 3.3E-01 2.0E+00 6.4E+00
1.88E+04 1.2E+00 2.0E+00 6.4E+00
2.07E+04 8.2E-01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 6.3E+00 2.0E+00 6.4E+00 10 100
3.32E+01 7.7E-01 2.0E+00 6.4E+00
3.36E+03 3.1E-01 2.0E+00 6.4E+00
1.03E+04 6.6E-01 2.0E+00 6.4E+00
2.63E+04 1.7E-01 2.0E+00 6.4E+00
2.04E+04 1.7E+00 2.0E+00 6.4E+00
2.06E+04 2.2E+00 2.0E+00 6.4E+00
1.00E+00 5.7E+00 2.0E+00 6.4E+00
4.73E+00 2.1E+00 2.0E+00 6.4E+00
1.00E+00 2.6E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316 SWA
1.04E+03 104% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316 SWA
1.03E+03 103% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.05E+03 105% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/101 :05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/101 :09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-627
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone.
1 ug/L
Mg SWA-LRef-1313-T01-A 1 1.78E+01
Mg SWA-LRef-1313-T02-A 1 1.97E+01
Mg SWA-LRef-1313-T03-A 1 6.24E+00
Mg SWA-LRef-1313-T04-A 1 2.78E+05
Mg SWA-LRef-1313-T05-A 1 8.36E+05
Mg SWA-LRef-1313-T06-A 1 1.54E+06
Mg SWA-LRef-1313-T07-A 1 1.79E+06
Mg SWA-LRef-1313-T08-A 1 9.62E+05
Mg SWA-LRef-1313-T09-A 1 8.31 E+05
Mg SWA-LRef-1313-T01-B 1 1.12E+01
Mg SWA-LRef-1313-T02-B 1 5.10E+00
Mg SWA-LRef-1313-T03-B 1 1.17E+01
Mg SWA-LRef-1313-T04-B 1 5.87E+05
Mg SWA-LRef-1313-T05-B 1 1.03E+06
Mg SWA-LRef-1313-T06-B 1 1.53E+06
Mg SWA-LRef-1313-T07-B 1 1.42E+06
Mg SWA-LRef-1313-T08-B 1 9.24E+05
Mg SWA-LRef-1313-T09-B 1 8.36E+05
Mg SWA-LRef-1313-T01-C 1 1.28E+01
Mg SWA-LRef-1313-T02-C 1 4.93E+00
Mg SWA-LRef-1313-T03-C 1 2.46E+01
Mg SWA-LRef-1313-T04-C 1 4.69E+05
Mg SWA-LRef-1313-T05-C 1 1.15E+06
Mg SWA-LRef-1313-T06-C 1 1.07E+06
Mg SWA-LRef-1313-T07-C 1 1.52E+06
Mg SWA-LRef-1313-T08-C 1 1.02E+06
Mg SWA-LRef-1313-T09-C 1 8.44E+05
Mg SWA-LRef-1313-B01-A 1 9.01 E+00
Mg SWA-LRef-1313-B02-A 1 3.08E+01
Mg SWA-LRef-1313-B03-A 1 3.55E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.78E+01 9.3E+01 1.0E+00 3.2E+00
1.97E+01 9.4E+01 1.0E+00 3.2E+00
6.24E+00 5.9E+01 1.0E+00 3.2E+00 1000 100
2.78E+05 5.9E-01 1.0E+00 3.2E+00
8.36E+05 7.9E-01 1.0E+00 3.2E+00
1.54E+06 8.1E-01 1.0E+00 3.2E+00
1.79E+06 2.0E-01 1.0E+00 3.2E+00
9.62E+05 9.4E-02 1.0E+00 3.2E+00
8.31 E+05 7.6E-01 1.0E+00 3.2E+00
1.12E+01 1.1E+02 1.0E+00 3.2E+00
5.10E+00 5.0E+00 1.0E+00 3.2E+00
1.17E+01 5.2E+01 1.0E+00 3.2E+00 1000 100
5.87E+05 6.3E-01 1.0E+00 3.2E+00
1.03E+06 7.6E-01 1.0E+00 3.2E+00
1.53E+06 8.0E-01 1.0E+00 3.2E+00
1.42E+06 2.7E-01 1.0E+00 3.2E+00
9.24E+05 7.1E-01 1.0E+00 3.2E+00
8.36E+05 3.9E-01 1.0E+00 3.2E+00
1.28E+01 6.5E+01 1.0E+00 3.2E+00
4.93E+00 2.2E+02 1.0E+00 3.2E+00
2.46E+01 2.2E+01 1.0E+00 3.2E+00 1000 100
4.69E+05 9.4E-01 1.0E+00 3.2E+00
1.15E+06 4.7E-01 1.0E+00 3.2E+00
1.07E+06 1.3E+00 1.0E+00 3.2E+00
1.52E+06 3.7E-01 1.0E+00 3.2E+00
1.02E+06 4.3E-01 1.0E+00 3.2E+00
8.44E+05 3.5E+00 1.0E+00 3.2E+00
9.01 E+00 3.5E+01 1.0E+00 3.2E+00
3.08E+01 2.5E+01 1.0E+00 3.2E+00
3.55E+00 1.6E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.01E+03 100% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.01E+03 99% VUICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.01E+03 99% VUICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-628
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo SWA-LRef-1313-T01-A 1
Mo SWA-LRef-1313-T02-A 1
Mo SWA-LRef-1313-T03-A 1
Mo SWA-LRef-1313-T04-A 1
Mo SWA-LRef-1313-T05-A 1
Mo SWA-LRef-1313-T06-A 1
Mo SWA-LRef-1313-T07-A 1
Mo SWA-LRef-1313-T08-A 1
Mo SWA-LRef-1313-T09-A 1
Mo SWA-LRef-1313-T01-B 1
Mo SWA-LRef-1313-T02-B 1
Mo SWA-LRef-1313-T03-B 1
Mo SWA-LRef-1313-T04-B 1
Mo SWA-LRef-1313-T05-B 1
Mo SWA-LRef-1313-T06-B 1
Mo SWA-LRef-1313-T07-B 1
Mo SWA-LRef-1313-T08-B 1
Mo SWA-LRef-1313-T09-B 1
Mo SWA-LRef-1313-T01-C 1
Mo SWA-LRef-1313-T02-C 1
Mo SWA-LRef-1313-T03-C 1
Mo SWA-LRef-1313-T04-C 1
Mo SWA-LRef-1313-T05-C 1
Mo SWA-LRef-1313-T06-C 1
Mo SWA-LRef-1313-T07-C 1
Mo SWA-LRef-1313-T08-C 1
Mo SWA-LRef-1313-T09-C 1
Mo SWA-LRef-1313-B01-A 1
Mo SWA-LRef-1313-B02-A 1
Mo SWA-LRef-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.42E+02
1.48E+02
1.39E+02
1.34E+02
1.15E+02
6.73E+01
1.63E+01
2.42E+01
1.73E+01
1.51E+02
1.50E+02
1.57E+02
1.34E+02
1.29E+02
3.35E+01
8.06E+00
1.78E+01
1.55E+01
1.43E+02
1.45E+02
1.44E+02
1.33E+02
1.28E+02
8.94E+01
1.07E+01
2.47E+01
2.04E+01
6.00E-01 U1/2
2.28E+00 E
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.42E+02 1.6E+00 1.2E+00 3.8E+00
1.48E+02 7.8E-01 1.2E+00 3.8E+00
1.39E+02 2.7E+00 1.2E+00 3.8E+00 10 100
1.34E+02 1.5E+00 1.2E+00 3.8E+00
1.15E+02 1.2E+00 1.2E+00 3.8E+00
6.73E+01 8.9E+00 1.2E+00 3.8E+00
1.63E+01 2.2E+01 1.2E+00 3.8E+00
2.42E+01 4.1E+00 1.2E+00 3.8E+00
1.73E+01 5.8E+00 1.2E+00 3.8E+00
1.51E+02 1.2E+00 1.2E+00 3.8E+00
1.50E+02 1.6E+00 1.2E+00 3.8E+00
1.57E+02 2.1E+00 1.2E+00 3.8E+00 10 100
1.34E+02 2.4E+00 1.2E+00 3.8E+00
1.29E+02 1.5E+00 1.2E+00 3.8E+00
3.35E+01 5.6E+00 1.2E+00 3.8E+00
8.06E+00 2.1E+01 1.2E+00 3.8E+00
1.78E+01 8.6E+00 1.2E+00 3.8E+00
1.55E+01 1.6E+01 1.2E+00 3.8E+00
1.43E+02 1.5E+00 1.2E+00 3.8E+00
1.45E+02 3.3E-01 1.2E+00 3.8E+00
1.44E+02 1.1E+00 1.2E+00 3.8E+00 10 100
1.33E+02 2.1E+00 1.2E+00 3.8E+00
1.28E+02 9.0E-01 1.2E+00 3.8E+00
8.94E+01 2.5E+00 1.2E+00 3.8E+00
1.07E+01 1.4E+01 1.2E+00 3.8E+00
2.47E+01 3.1E+01 1.2E+00 3.8E+00
2.04E+01 3.9E+01 1.2E+00 3.8E+00
6.00E-01 3.5E+01 1.2E+00 3.8E+00
2.28E+00 2.9E+01 1.2E+00 3.8E+00
6.00E-01 2.1E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.16E+03 103% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.17E+03 102% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.17E+03 103% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-629
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni SWA-LRef-1313-T01-A 1
Ni SWA-LRef-1313-T02-A 1
Ni SWA-LRef-1313-T03-A 1
Ni SWA-LRef-1313-T04-A 1
Ni SWA-LRef-1313-T05-A 1
Ni SWA-LRef-1313-T06-A 1
Ni SWA-LRef-1313-T07-A 1
Ni SWA-LRef-1313-T08-A 1
Ni SWA-LRef-1313-T09-A 1
Ni SWA-LRef-1313-T01-B 1
Ni SWA-LRef-1313-T02-B 1
Ni SWA-LRef-1313-T03-B 1
Ni SWA-LRef-1313-T04-B 1
Ni SWA-LRef-1313-T05-B 1
Ni SWA-LRef-1313-T06-B 1
Ni SWA-LRef-1313-T07-B 1
Ni SWA-LRef-1313-T08-B 1
Ni SWA-LRef-1313-T09-B 1
Ni SWA-LRef-1313-T01-C
Ni SWA-LRef-1313-T02-C
Ni SWA-LRef-1313-T03-C
Ni SWA-LRef-1313-T04-C
Ni SWA-LRef-1313-T05-C
Ni SWA-LRef-1313-T06-C
Ni SWA-LRef-1313-T07-C
Ni SWA-LRef-1313-T08-C
Ni SWA-LRef-1313-T09-C
Ni SWA-LRef-1313-B01-A
Ni SWA-LRef-1313-B02-A
Ni SWA-LRef-1313-B03-A
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
3.51 E+00 E
2.00E+01
1.24E+02
5.34E+02
3.70E+02
4.40E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
5.10E+00 E
2.66E+01
2.67E+02
3.52E+02
3.74E+02
4.36E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
6.22E+00 U1/2
3.06E+01 U1/2
1.17E+02 U1/2
4.58E+02 U1/2
4.00E+02 U1/2
4.39E+02 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 1.1E+01 1.8E+00 5.7E+00
9.00E-01 3.2E+01 1.8E+00 5.7E+00 10 100
3.51E+00 2.9E+01 1.8E+00 5.7E+00
2.00E+01 1.1E+01 1.8E+00 5.7E+00
1.24E+02 1.6E+00 1.8E+00 5.7E+00
5.34E+02 6.7E-01 1.8E+00 5.7E+00
3.70E+02 7.2E-01 1.8E+00 5.7E+00
4.40E+02 2.1 E+00 1.8E+00 5.7E+00
9.00E-01 9.5E+01 1.8E+00 5.7E+00
9.00E-01 3.2E+01 1.8E+00 5.7E+00
9.00E-01 7.1E+01 1.8E+00 5.7E+00 10 100
5.10E+00 7.4E+00 1.8E+00 5.7E+00
2.66E+01 6.8E-01 1.8E+00 5.7E+00
2.67E+02 7.5E-01 1.8E+00 5.7E+00
3.52E+02 1.5E+00 1.8E+00 5.7E+00
3.74E+02 7.7E-01 1.8E+00 5.7E+00
4.36E+02 2.5E-01 1.8E+00 5.7E+00
O.OOE+00 7.9E+01 1.8E+00 5.7E+00
O.OOE+00 7.3E+01 1.8E+00 5.7E+00
O.OOE+00 2.1E+01 1.8E+00 5.7E+00 10 100
O.OOE+00 4.1E+01 1.8E+00 5.7E+00
O.OOE+00 5.4E+00 1.8E+00 5.7E+00
O.OOE+00 3.7E+00 1.8E+00 5.7E+00
O.OOE+00 1.1 E+00 1.8E+00 5.7E+00
O.OOE+00 6.9E-01 1.8E+00 5.7E+00
O.OOE+00 2.8E+00 1.8E+00 5.7E+00
O.OOE+00 8.0E+00 1.8E+00 5.7E+00
O.OOE+00 7.4E+00 1.8E+00 5.7E+00
O.OOE+00 7.2E+00 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316 SWA
1.00E+03 100% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:17 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:22 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:23PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:30PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:32PM EPA Interlab LRef 1313-1316SWA
1.00E+03 100% VUICP-OES 1 1/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:35PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:51 PM EPA Interlab LRef 1313-1316 SWA
1.01E+03 101% VUICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-630
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qu
1 1 ug/L
P SWA-LRef-1313-T01-A 1 9.46E+01
P SWA-LRef-1313-T02-A 1 3.59E+01
P SWA-LRef-1313-T03-A 1 2.32E+01
P SWA-LRef-1313-T04-A 1 7.43E+01
P SWA-LRef-1313-T05-A 1 6.40E+01
P SWA-LRef-1313-T06-A 1 2.72E+01
P SWA-LRef-1313-T07-A 1 1.45E+01
P SWA-LRef-1313-T08-A 1 1.02E+03
P SWA-LRef-1313-T09-A 1 1.24E+04
P SWA-LRef-1313-T01-B 1 1.40E+02
P SWA-LRef-1313-T02-B 1 4.47E+01
P SWA-LRef-1313-T03-B 1 2.67E+01
P SWA-LRef-1313-T04-B 1 6.30E+01
P SWA-LRef-1313-T05-B 1 1.19E+02
P SWA-LRef-1313-T06-B 1 4.75E+01
P SWA-LRef-1313-T07-B 1 4.45E+01
P SWA-LRef-1313-T08-B 1 8.44E+02
P SWA-LRef-1313-T09-B 1 1.31E+04
P SWA-LRef-1313-T01-C 1 1.10E+02
P SWA-LRef-1313-T02-C 1 3.66E+01
P SWA-LRef-1313-T03-C 1 1.79E+01
P SWA-LRef-1313-T04-C 1 5.42E+01
P SWA-LRef-1313-T05-C 1 2.74E+01
P SWA-LRef-1313-T06-C 1 4.58E+01
P SWA-LRef-1313-T07-C 1 2.37E+01
P SWA-LRef-1313-T08-C 1 7.91 E+02
P SWA-LRef-1313-T09-C 1 1.25E+04
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.46E+01 1.9E+01 3.7E+00 1.2E+01
3.59E+01 5.7E+01 3.7E+00 1.2E+01
2.32E+01 9.4E+01 3.7E+00 1.2E+01 1000 100
7.43E+01 5.1E+01 3.7E+00 1.2E+01
6.40E+01 4.9E+01 3.7E+00 1.2E+01
2.72E+01 1.0E+02 3.7E+00 1.2E+01
1.45E+01 1.5E+02 3.7E+00 1.2E+01
1.02E+03 5.9E-01 3.7E+00 1.2E+01
1.24E+04 7.5E-01 3.7E+00 1.2E+01
1.40E+02 3.9E+00 3.7E+00 1.2E+01
4.47E+01 2.7E+01 3.7E+00 1.2E+01
2.67E+01 3.8E+01 3.7E+00 1.2E+01 1000 100
6.30E+01 1.7E+01 3.7E+00 1.2E+01
1.19E+02 1.3E+01 3.7E+00 1.2E+01
4.75E+01 2.8E+01 3.7E+00 1.2E+01
4.45E+01 8.4E+01 3.7E+00 1.2E+01
8.44E+02 1.0E+00 3.7E+00 1.2E+01
1.31E+04 1.3E+00 3.7E+00 1.2E+01
1.10E+02 1.5E+01 3.7E+00 1.2E+01
3.66E+01 3.6E+01 3.7E+00 1 .2E+01
1.79E+01 5.1E+01 3.7E+00 1 .2E+01 1000 100
5.42E+01 4.4E+01 3.7E+00 1 .2E+01
2.74E+01 9.0E+00 3.7E+00 1 .2E+01
4.58E+01 4.1E+01 3.7E+00 1 .2E+01
2.37E+01 2.9E+01 3.7E+00 1 .2E+01
7.91 E+02 4.0E-01 3.7E+00 1 .2E+01
1.25E+04 3.0E+00 3.7E+00 1 .2E+01
P SWA-LRef-1313-B01-A 1 1.85E+OOU1/2 1.85E+00 3.2E+01 3.7E+00 1 .2E+01
P SWA-LRef-1313-B02-A 1 1.54E+01
1.54E+01 2.0E+01 3.7E+00 1 .2E+01
P SWA-LRef-1313-B03-A 1 1.85E+OOU1/2 1.85E+00 3.5E+01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.19E+03 117% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.22E+03 119% VUICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.21E+03 119% VUICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-631
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K SWA-LRef-1313-T01-A 1
K SWA-LRef-1313-T02-A 1
K SWA-LRef-1313-T03-A 1
K SWA-LRef-1313-T04-A 1
K SWA-LRef-1313-T05-A 1
K SWA-LRef-1313-T06-A 1
K SWA-LRef-1313-T07-A 1
K SWA-LRef-1313-T08-A 1
K SWA-LRef-1313-T09-A 1
K SWA-LRef-1313-T01-B 1
K SWA-LRef-1313-T02-B 1
K SWA-LRef-1313-T03-B 1
K SWA-LRef-1313-T04-B 1
K SWA-LRef-1313-T05-B 1
K SWA-LRef-1313-T06-B 1
K SWA-LRef-1313-T07-B 1
K SWA-LRef-1313-T08-B 1
K SWA-LRef-1313-T09-B 1
K SWA-LRef-1313-T01-C 1
K SWA-LRef-1313-T02-C 1
K SWA-LRef-1313-T03-C 1
K SWA-LRef-1313-T04-C 1
K SWA-LRef-1313-T05-C 1
K SWA-LRef-1313-T06-C 1
K SWA-LRef-1313-T07-C 1
K SWA-LRef-1313-T08-C 1
K SWA-LRef-1313-T09-C 1
K SWA-LRef-1313-B01-A 1
K SWA-LRef-1313-B02-A 1
K SWA-LRef-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.21E+06
2.80E+05
2.81 E+05
4.14E+05
4.12E+05
4.65E+05
4.81 E+05
2.88E+05
3.23E+05
2.26E+06
2.81 E+05
2.84E+05
4.10E+05
4.33E+05
4.86E+05
4.64E+05
3.18E+05
3.18E+05
2.21E+06
2.80E+05
2.85E+05
4.16E+05
4.42E+05
4.40E+05
4.85E+05
3.92E+05
3.77E+05
7.04E+00
7.67E+00
2.11E+06
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.21E+06 3.3E-01 1.6E+00 5.1E+00
2.80E+05 2.6E-01 1.6E+00 5.1E+00
2.81E+05 8.1E-01 1.6E+00 5.1E+00 1000 100
4.14E+05 8.3E-01 1.6E+00 5.1E+00
4.12E+05 1.0E+00 1.6E+00 5.1E+00
4.65E+05 9.4E-01 1.6E+00 5.1E+00
4.81E+05 3.4E+00 1.6E+00 5.1E+00
2.88E+05 2.9E+00 1.6E+00 5.1E+00
3.23E+05 8.7E-01 1.6E+00 5.1E+00
2.26E+06 8.5E-01 1.6E+00 5.1E+00
2.81E+05 3.4E-01 1.6E+00 5.1E+00
2.84E+05 2.6E-01 1.6E+00 5.1E+00 1000 100
4.10E+05 9.2E-01 1.6E+00 5.1E+00
4.33E+05 4.9E-01 1.6E+00 5.1E+00
4.86E+05 5.2E+00 1.6E+00 5.1E+00
4.64E+05 7.1E-01 1.6E+00 5.1E+00
3.18E+05 7.9E+00 1.6E+00 5.1E+00
3.18E+05 1.2E+01 1.6E+00 5.1E+00
2.21E+06 4.5E-01 1.6E+00 5.1E+00
2.80E+05 5.5E-01 1.6E+00 5.1E+00
2.85E+05 1.2E+00 1.6E+00 5.1E+00 1000 100
4.16E+05 7.0E-01 1.6E+00 5.1E+00
4.42E+05 3.6E-01 1.6E+00 5.1E+00
4.40E+05 4.7E-01 1.6E+00 5.1E+00
4.85E+05 6.3E+00 1.6E+00 5.1E+00
3.92E+05 1.6E+01 1.6E+00 5.1E+00
3.77E+05 9.9E+00 1.6E+00 5.1E+00
7.04E+00 6.8E+00 1.6E+00 5.1E+00
7.67E+00 1.2E+01 1.6E+00 5.1E+00
2.11E+06 2.3E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
2.82E+05 95% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
2.85E+05 100% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
2.86E+05 85% VUICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-632
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se SWA-LRef-1313-T01-A 1
Se SWA-LRef-1313-T02-A 1
Se SWA-LRef-1313-T03-A 1
Se SWA-LRef-1313-T04-A 1
Se SWA-LRef-1313-T05-A 1
Se SWA-LRef-1313-T06-A 1
Se SWA-LRef-1313-T07-A 1
Se SWA-LRef-1313-T08-A 1
Se SWA-LRef-1313-T09-A 1
Se SWA-LRef-1313-T01-B 1
Se SWA-LRef-1313-T02-B 1
Se SWA-LRef-1313-T03-B 1
Se SWA-LRef-1313-T04-B 1
Se SWA-LRef-1313-T05-B 1
Se SWA-LRef-1313-T06-B 1
Se SWA-LRef-1313-T07-B 1
Se SWA-LRef-1313-T08-B 1
Se SWA-LRef-1313-T09-B 1
Se SWA-LRef-1313-T01-C 1
Se SWA-LRef-1313-T02-C 1
Se SWA-LRef-1313-T03-C 1
Se SWA-LRef-1313-T04-C 1
Se SWA-LRef-1313-T05-C 1
Se SWA-LRef-1313-T06-C 1
Se SWA-LRef-1313-T07-C 1
Se SWA-LRef-1313-T08-C 1
Se SWA-LRef-1313-T09-C 1
Se SWA-LRef-1313-B01-A 1
Se SWA-LRef-1313-B02-A 1
Se SWA-LRef-1313-B03-A 1
Sample I
Cone. Qualifier
ug/L I
9.17E+04
1.04E+05
9.91 E+04
1.09E+05
1.16E+05
1.28E+05
1.26E+05
6.64E+04
4.54E+04
1.02E+05
1.04E+05
1.08E+05
1.14E+05
1.24E+05
1.28E+05
1.21E+05
6.05E+04
4.40E+04
9.53E+04
1.00E+05
1.03E+05
1.08E+05
1.32E+05
1.17E+05
1.22E+05
6.71 E+04
4.40E+04
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.17E+04 3.9E-01 1.5E+01 4.8E+01
1.04E+05 6.1E-01 1.5E+01 4.8E+01
9.91E+04 1.0E+00 1.5E+01 4.8E+01 10 100
1.09E+05 4.8E-01 1.5E+01 4.8E+01
1.16E+05 1.0E+00 1.5E+01 4.8E+01
1.28E+05 6.8E-01 1.5E+01 4.8E+01
1.26E+05 8.0E-01 1.5E+01 4.8E+01
6.64E+04 2.2E-01 1.5E+01 4.8E+01
4.54E+04 1.7E-01 1.5E+01 4.8E+01
1.02E+05 9.4E-01 1.5E+01 4.8E+01
1.04E+05 4.7E-01 1.5E+01 4.8E+01
1.08E+05 7.9E-01 1.5E+01 4.8E+01 10 100
1.14E+05 7.1E-01 1.5E+01 4.8E+01
1.24E+05 8.4E-01 1.5E+01 4.8E+01
1.28E+05 1.0E+00 1.5E+01 4.8E+01
1.21E+05 1.1E-01 1.5E+01 4.8E+01
6.05E+04 7.8E-01 1.5E+01 4.8E+01
4.40E+04 4.5E-01 1.5E+01 4.8E+01
9.53E+04 5.7E-01 1.5E+01 4.8E+01
1.00E+05 5.7E-01 1.5E+01 4.8E+01
1.03E+05 1.8E-01 1.5E+01 4.8E+01 10 100
1.08E+05 7.5E-01 1.5E+01 4.8E+01
1.32E+05 5.1E-01 1.5E+01 4.8E+01
1.17E+05 1.8E-01 1.5E+01 4.8E+01
1.22E+05 3.7E-01 1.5E+01 4.8E+01
6.71 E+04 7.1E-01 1.5E+01 4.8E+01
4.40E+04 3.2E+00 1.5E+01 4.8E+01
7.50E+00 7.5E+01 1.5E+01 4.8E+01
7.50E+00 4.1E+02 1.5E+01 4.8E+01
7.50E+00 1.8E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.00E+05 104% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.09E+05 105% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.04E+05 92% VUICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-633
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone.
1 1 ug/L
Si SWA-LRef-1313-T01-A 1 5.80E+03
Si SWA-LRef-1313-T02-A 1 5.00E+03
Si SWA-LRef-1313-T03-A 1 4.84E+03
Si SWA-LRef-1313-T04-A 1 9.77E+02
Si SWA-LRef-1313-T05-A 1 1.26E+03
Si SWA-LRef-1313-T06-A 1 2.32E+03
Si SWA-LRef-1313-T07-A 1 2.39E+03
Si SWA-LRef-1313-T08-A 1 1.90E+04
Si SWA-LRef-1313-T09-A 1 1.44E+04
Si SWA-LRef-1313-T01-B 1 7.62E+03
Si SWA-LRef-1313-T02-B 1 5.65E+03
Si SWA-LRef-1313-T03-B 1 5.22E+03
Si SWA-LRef-1313-T04-B 1 9.80E+02
Si SWA-LRef-1313-T05-B 1 1.05E+03
Si SWA-LRef-1313-T06-B 1 2.08E+03
Si SWA-LRef-1313-T07-B 1 2.51E+03
Si SWA-LRef-1313-T08-B 1 1.57E+04
Si SWA-LRef-1313-T09-B 1 1.54E+04
Si SWA-LRef-1313-T01-C 1 7.97E+03
Si SWA-LRef-1313-T02-C 1 5.56E+03
Si SWA-LRef-1313-T03-C 1 4.64E+03
Si SWA-LRef-1313-T04-C 1 1.03E+03
Si SWA-LRef-1313-T05-C 1 1.12E+03
Si SWA-LRef-1313-T06-C 1 1.68E+03
Si SWA-LRef-1313-T07-C 1 2.54E+03
Si SWA-LRef-1313-T08-C 1 1.58E+04
Si SWA-LRef-1313-T09-C 1 1.58E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.80E+03 8.7E-01 1.1E+00 3.5E+00
5.00E+03 1.1E+00 1.1E+00 3.5E+00
4.84E+03 9.7E-01 1.1E+00 3.5E+00 1000 100
9.77E+02 8.0E-01 1.1E+00 3.5E+00
1.26E+03 8.9E-01 1.1E+00 3.5E+00
2.32E+03 7.6E-01 1.1E+00 3.5E+00
2.39E+03 6.0E-01 1.1E+00 3.5E+00
1.90E+04 6.3E-01 1.1E+00 3.5E+00
1.44E+04 2.8E+00 1.1E+00 3.5E+00
7.62E+03 5.4E+00 1.1E+00 3.5E+00
5.65E+03 2.2E-01 1.1E+00 3.5E+00
5.22E+03 4.1E-01 1.1E+00 3.5E+00 1000 100
9.80E+02 7.6E-01 1.1E+00 3.5E+00
1.05E+03 6.9E-01 1.1E+00 3.5E+00
2.08E+03 4.6E-01 1.1E+00 3.5E+00
2.51 E+03 2.5E-01 1.1E+00 3.5E+00
1.57E+04 8.0E-01 1.1E+00 3.5E+00
1.54E+04 5.2E-01 1.1E+00 3.5E+00
7.97E+03 7.5E-01 1.1E+00 3.5E+00
5.56E+03 6.1E-01 1.1E+00 3.5E+00
4.64E+03 6.6E-01 1.1E+00 3.5E+00 1000 100
1.03E+03 1.1E+00 1.1E+00 3.5E+00
1.12E+03 7.7E-01 1.1E+00 3.5E+00
1.68E+03 6.6E-01 1.1E+00 3.5E+00
2.54E+03 4.9E-01 1.1E+00 3.5E+00
1.58E+04 2.4E-01 1.1E+00 3.5E+00
1.58E+04 1.6E+01 1.1E+00 3.5E+00
Si SWA-LRef-1313-B01-A 1 1.58E+OOE 1.58E+00 2.3E+01 1.1E+00 3.5E+00
Si SWA-LRef-1313-B02-A 1 2.17E+00 E 2.17E+00 5.7E+00 1.1E+00 3.5E+00
Si SWA-LRef-1313-B03-A 1 1.93E+01
1.93E+01 2.4E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
5.71E+03 88% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
6.16E+03 94% VUICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
5.60E+03 96% VUICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-634
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qu
1 1 ug/L
Na SWA-LRef-1313-T01-A 1 4.76E+05
Na SWA-LRef-1313-T02-A 1 4.40E+05
Na SWA-LRef-1313-T03-A 1 4.41 E+05
Na SWA-LRef-1313-T04-A 1 5.53E+05
Na SWA-LRef-1313-T05-A 1 5.48E+05
Na SWA-LRef-1313-T06-A 1 5.80E+05
Na SWA-LRef-1313-T07-A 1 5.68E+05
Na SWA-LRef-1313-T08-A 1 2.92E+05
Na SWA-LRef-1313-T09-A 1 1.84E+05
Na SWA-LRef-1313-T01-B 1 4.78E+05
Na SWA-LRef-1313-T02-B 1 4.39E+05
Na SWA-LRef-1313-T03-B 1 4.41E+05
Na SWA-LRef-1313-T04-B 1 5.45E+05
Na SWA-LRef-1313-T05-B 1 5.61E+05
Na SWA-LRef-1313-T06-B 1 5.79E+05
Na SWA-LRef-1313-T07-B 1 5.71E+05
Na SWA-LRef-1313-T08-B 1 2.78E+05
Na SWA-LRef-1313-T09-B 1 1 .83E+05
Na SWA-LRef-1313-T01-C 1 4.63E+05
Na SWA-LRef-1313-T02-C 1 4.35E+05
Na SWA-LRef-1313-T03-C 1 4.47E+05
Na SWA-LRef-1313-T04-C 1 5.50E+05
Na SWA-LRef-1313-T05-C 1 5.72E+05
Na SWA-LRef-1313-T06-C 1 5.64E+05
Na SWA-LRef-1313-T07-C 1 5.69E+05
Na SWA-LRef-1313-T08-C 1 3.02E+05
Na SWA-LRef-1313-T09-C 1 1 .85E+05
Na SWA-LRef-1313-B01-A 1 3.45E+00 E
Na SWA-LRef-1313-B02-A 1 3.00E+00 E
Na SWA-LRef-1313-B03-A 1 9.88E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.76E+05 6.0E-01 2.5E+00 8.0E+00
4.40E+05 2.7E-01 2.5E+00 8.0E+00
4.41E+05 2.4E-01 2.5E+00 8.0E+00 1000 100
5.53E+05 1.5E+00 2.5E+00 8.0E+00
5.48E+05 6.5E-01 2.5E+00 8.0E+00
5.80E+05 1.2E+00 2.5E+00 8.0E+00
5.68E+05 2.0E-01 2.5E+00 8.0E+00
2.92E+05 5.1E-01 2.5E+00 8.0E+00
1.84E+05 6.1E-01 2.5E+00 8.0E+00
4.78E+05 7.6E-01 2.5E+00 8.0E+00
4.39E+05 1.9E-01 2.5E+00 8.0E+00
4.41E+05 5.4E-01 2.5E+00 8.0E+00 1000 100
5.45E+05 4.3E-01 2.5E+00 8.0E+00
5.61 E+05 7.5E-01 2.5E+00 8.0E+00
5.79E+05 1.1E+00 2.5E+00 8.0E+00
5.71 E+05 2.6E-01 2.5E+00 8.0E+00
2.78E+05 8.8E-01 2.5E+00 8.0E+00
1.83E+05 3.6E-01 2.5E+00 8.0E+00
4.63E+05 3.8E-01 2.5E+00 8.0E+00
4.35E+05 4.5E-01 2.5E+00 8.0E+00
4.47E+05 5.2E-01 2.5E+00 8.0E+00 1000 100
5.50E+05 1.5E+00 2.5E+00 8.0E+00
5.72E+05 3.4E-01 2.5E+00 8.0E+00
5.64E+05 4.4E-01 2.5E+00 8.0E+00
5.69E+05 3.1E-01 2.5E+00 8.0E+00
3.02E+05 7.8E-01 2.5E+00 8.0E+00
1.85E+05 1.7E+00 2.5E+00 8.0E+00
3.45E+00 1.9E+01 2.5E+00 8.0E+00
3.00E+00 4.0E+01 2.5E+00 8.0E+00
9.88E+02 2.9E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
4.42E+05 90% VUICP-OES 1 1/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:15 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:17 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:20PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316 SWA
4.42E+05 103% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
4.48E+05 89% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-635
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-LRef-1313-T01-A 1
SWA-LRef-1313-T02-A 1
SWA-LRef-1313-T03-A 1
SWA-LRef-1313-T04-A 1
SWA-LRef-1313-T05-A 1
SWA-LRef-1313-T06-A 1
SWA-LRef-1313-T07-A 1
SWA-LRef-1313-T08-A 1
SWA-LRef-1313-T09-A 1
SWA-LRef-1313-T01-B 1
SWA-LRef-1313-T02-B 1
SWA-LRef-1313-T03-B 1
SWA-LRef-1313-T04-B 1
SWA-LRef-1313-T05-B 1
SWA-LRef-1313-T06-B 1
SWA-LRef-1313-T07-B 1
SWA-LRef-1313-T08-B 1
SWA-LRef-1313-T09-B 1
SWA-LRef-1313-T01-C 1
SWA-LRef-1313-T02-C 1
SWA-LRef-1313-T03-C 1
SWA-LRef-1313-T04-C 1
SWA-LRef-1313-T05-C 1
SWA-LRef-1313-T06-C 1
SWA-LRef-1313-T07-C 1
SWA-LRef-1313-T08-C 1
SWA-LRef-1313-T09-C 1
SWA-LRef-1313-B01-A 1
SWA-LRef-1313-B02-A 1
SWA-LRef-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
2.32E+02
3.41 E+02
5.57E+02
2.53E+04
3.20E+04
5.16E+04
5.92E+04
3.30E+04
2.41 E+04
2.92E+02
3.42E+02
5.04E+02
3.00E+04
3.99E+04
5.26E+04
5.01 E+04
3.16E+04
2.78E+04
3.42E+02
3.53E+02
5.56E+02
2.69E+04
4.26E+04
3.99E+04
5.23E+04
3.48E+04
2.78E+04
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.32E+02 1.5E-01 1.0E+00 3.2E+00
3.41 E+02 4.2E-01 1.0E+00 3.2E+00
5.57E+02 4.6E-01 1.0E+00 3.2E+00 1000 100
2.53E+04 4.8E-01 1.0E+00 3.2E+00
3.20E+04 1.3E+00 1.0E+00 3.2E+00
5.16E+04 1.3E+00 1.0E+00 3.2E+00
5.92E+04 6.2E-01 1.0E+00 3.2E+00
3.30E+04 8.4E-01 1.0E+00 3.2E+00
2.41 E+04 5.2E-01 1.0E+00 3.2E+00
2.92E+02 5.9E+00 1.0E+00 3.2E+00
3.42E+02 3.5E-01 1.0E+00 3.2E+00
5.04E+02 1.3E-01 1.0E+00 3.2E+00 1000 100
3.00E+04 8.6E-01 1.0E+00 3.2E+00
3.99E+04 2.4E-01 1.0E+00 3.2E+00
5.26E+04 7.8E-01 1.0E+00 3.2E+00
5.01 E+04 1.7E-01 1.0E+00 3.2E+00
3.16E+04 5.8E-01 1.0E+00 3.2E+00
2.78E+04 8.4E-01 1.0E+00 3.2E+00
3.42E+02 1.4E-01 1.0E+00 3.2E+00
3.53E+02 4.7E-01 1.0E+00 3.2E+00
5.56E+02 6.6E-01 1.0E+00 3.2E+00 1000 100
2.69E+04 1.0E+00 1.0E+00 3.2E+00
4.26E+04 6.8E-01 1.0E+00 3.2E+00
3.99E+04 8.9E-01 1.0E+00 3.2E+00
5.23E+04 4.2E-01 1.0E+00 3.2E+00
3.48E+04 1.9E-01 1.0E+00 3.2E+00
2.78E+04 4.4E+00 1.0E+00 3.2E+00
5.00E-01 3.1 E+02 1.0E+00 3.2E+00
5.00E-01 3.7E+02 1.0E+00 3.2E+00
5.00E-01 4.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.58E+03 103% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.53E+03 102% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.58E+03 102% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-636
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S SWA-LRef-1313-T01-A 1
S SWA-LRef-1313-T02-A 1
S SWA-LRef-1313-T03-A 1
S SWA-LRef-1313-T04-A 1
S SWA-LRef-1313-T05-A 1
S SWA-LRef-1313-T06-A 1
S SWA-LRef-1313-T07-A 1
S SWA-LRef-1313-T08-A 1
S SWA-LRef-1313-T09-A 1
S SWA-LRef-1313-T01-B 1
S SWA-LRef-1313-T02-B 1
S SWA-LRef-1313-T03-B 1
S SWA-LRef-1313-T04-B 1
S SWA-LRef-1313-T05-B 1
S SWA-LRef-1313-T06-B 1
S SWA-LRef-1313-T07-B 1
S SWA-LRef-1313-T08-B 1
S SWA-LRef-1313-T09-B 1
S SWA-LRef-1313-T01-C 1
S SWA-LRef-1313-T02-C 1
S SWA-LRef-1313-T03-C 1
S SWA-LRef-1313-T04-C 1
S SWA-LRef-1313-T05-C 1
S SWA-LRef-1313-T06-C 1
S SWA-LRef-1313-T07-C 1
S SWA-LRef-1313-T08-C 1
S SWA-LRef-1313-T09-C 1
S SWA-LRef-1313-B01-A 1
S SWA-LRef-1313-B02-A 1
S SWA-LRef-1313-B03-A 1
Sample
Cone. Qualifier
ug/L
3.95E+05
4.06E+05
5.26E+05
8.19E+05
7.49E+05
5.53E+05
5.20E+05
2.54E+05
1.80E+05
3.77E+05
4.72E+05
5.83E+05
7.97E+05
9.01 E+05
5.32E+05
5.84E+05
2.42E+05
1.90E+05
4.08E+05
4.34E+05
5.19E+05
8.51 E+05
8.97E+05
7.66E+05
5.49E+05
2.76E+05
1.93E+05
2.29E+01
2.80E+01
1.22E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.95E+05 3.4E-01 6.8E+00 2.2E+01
4.06E+05 5.1E-01 6.8E+00 2.2E+01
5.26E+05 4.1E-01 6.8E+00 2.2E+01 1000 100
8.19E+05 2.8E-01 6.8E+00 2.2E+01
7.49E+05 5.6E-01 6.8E+00 2.2E+01
5.53E+05 5.3E-01 6.8E+00 2.2E+01
5.20E+05 5.7E-01 6.8E+00 2.2E+01
2.54E+05 4.2E-01 6.8E+00 2.2E+01
1.80E+05 2.9E-01 6.8E+00 2.2E+01
3.77E+05 6.1E-01 6.8E+00 2.2E+01
4.72E+05 1.5E-01 6.8E+00 2.2E+01
5.83E+05 1.9E-01 6.8E+00 2.2E+01 1000 100
7.97E+05 4.5E-01 6.8E+00 2.2E+01
9.01 E+05 4.7E-01 6.8E+00 2.2E+01
5.32E+05 1.1E+00 6.8E+00 2.2E+01
5.84E+05 2.3E-01 6.8E+00 2.2E+01
2.42E+05 6.2E-01 6.8E+00 2.2E+01
1.90E+05 4.7E-01 6.8E+00 2.2E+01
4.08E+05 5.1E-01 6.8E+00 2.2E+01
4.34E+05 6.0E-01 6.8E+00 2.2E+01
5.19E+05 3.0E-01 6.8E+00 2.2E+01 1000 100
8.51E+05 9.6E-01 6.8E+00 2.2E+01
8.97E+05 5.4E-01 6.8E+00 2.2E+01
7.66E+05 2.4E-01 6.8E+00 2.2E+01
5.49E+05 6.7E-02 6.8E+00 2.2E+01
2.76E+05 6.1E-01 6.8E+00 2.2E+01
1.93E+05 2.4E+00 6.8E+00 2.2E+01
2.29E+01 1.2E+01 6.8E+00 2.2E+01
2.80E+01 2.4E+01 6.8E+00 2.2E+01
1.22E+02 4.1E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
5.26E+05 91% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
5.84E+05 101% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
5.20E+05 86% VUICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-637
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl SWA-LRef-1313-T01-A 1
Tl SWA-LRef-1313-T02-A 1
Tl SWA-LRef-1313-T03-A 1
Tl SWA-LRef-1313-T04-A 1
Tl SWA-LRef-1313-T05-A 1
Tl SWA-LRef-1313-T06-A 1
Tl SWA-LRef-1313-T07-A 1
Tl SWA-LRef-1313-T08-A 1
Tl SWA-LRef-1313-T09-A 1
Tl SWA-LRef-1313-T01-B 1
Tl SWA-LRef-1313-T02-B 1
Tl SWA-LRef-1313-T03-B 1
Tl SWA-LRef-1313-T04-B 1
Tl SWA-LRef-1313-T05-B 1
Tl SWA-LRef-1313-T06-B 1
Tl SWA-LRef-1313-T07-B 1
Tl SWA-LRef-1313-T08-B 1
Tl SWA-LRef-1313-T09-B 1
Tl SWA-LRef-1313-T01-C 1
Tl SWA-LRef-1313-T02-C 1
Tl SWA-LRef-1313-T03-C 1
Tl SWA-LRef-1313-T04-C 1
Tl SWA-LRef-1313-T05-C 1
Tl SWA-LRef-1313-T06-C 1
Tl SWA-LRef-1313-T07-C 1
Tl SWA-LRef-1313-T08-C 1
Tl SWA-LRef-1313-T09-C 1
Tl SWA-LRef-1313-B01-A 1
Tl SWA-LRef-1313-B02-A 1
Tl SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
1.75E+01
3.01E+01
1.32E+01 E
1.40E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
1.76E+01
1.93E+01
1.16E+01 E
1.25E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
6.29E+00 E
2.18E+01
1.58E+01
1.54E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 5.3E+01 4.6E+00 1.5E+01
2.30E+00 8.7E+01 4.6E+00 1.5E+01 10 100
2.30E+00 1.5E+02 4.6E+00 1.5E+01
2.30E+00 4.1E+02 4.6E+00 1.5E+01
1.75E+01 4.2E+00 4.6E+00 1 .5E+01
3.01 E+01 8.2E+00 4.6E+00 1 .5E+01
1.32E+01 2.6E+01 4.6E+00 1 .5E+01
1.40E+01 8.4E+01 4.6E+00 1 .5E+01
2.30E+00 1.4E+01 4.6E+00 1 .5E+01
2.30E+00 6.0E+01 4.6E+00 1 .5E+01
2.30E+00 7.3E+01 4.6E+00 1 .5E+01 10 100
2.30E+00 7.0E+02 4.6E+00 1 .5E+01
2.30E+00 6.3E+02 4.6E+00 1 .5E+01
1.76E+01 4.1 E+01 4.6E+00 1 .5E+01
1.93E+01 2.2E+01 4.6E+00 1 .5E+01
1.16E+01 3.0E+01 4.6E+00 1 .5E+01
1.25E+01 1.5E+01 4.6E+00 1 .5E+01
2.30E+00 2.2E+01 4.6E+00 1 .5E+01
2.30E+00 9.8E+00 4.6E+00 1 .5E+01
2.30E+00 1.5E+01 4.6E+00 1 .5E+01 10 100
2.30E+00 5.4E+01 4.6E+00 1 .5E+01
2.30E+00 1.1E+02 4.6E+00 1 .5E+01
6.29E+00 3.3E+02 4.6E+00 1.5E+01
2.18E+01 6.5E+01 4.6E+00 1.5E+01
1.58E+01 5.5E+01 4.6E+00 1.5E+01
1.54E+01 1.4E+02 4.6E+00 1.5E+01
2.30E+00 6.0E+01 4.6E+00 1 .5E+01
2.30E+00 6.3E+00 4.6E+00 1 .5E+01
2.30E+00 2.4E+01 4.6E+00 1 .5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
9.51E+02 95% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
9.54E+02 95% VUICP-OES 1 1/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 1 1/19/10 1:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:40 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:43 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 1:50 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
9.57E+02 95% VUICP-OES 1 1/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 1 :58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1 :09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-638
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti SWA-LRef-1313-T01-A 1
Ti SWA-LRef-1313-T02-A 1
Ti SWA-LRef-1313-T03-A 1
Ti SWA-LRef-1313-T04-A 1
Ti SWA-LRef-1313-T05-A 1
Ti SWA-LRef-1313-T06-A 1
Ti SWA-LRef-1313-T07-A 1
Ti SWA-LRef-1313-T08-A 1
Ti SWA-LRef-1313-T09-A 1
Ti SWA-LRef-1313-T01-B 1
Ti SWA-LRef-1313-T02-B 1
Ti SWA-LRef-1313-T03-B 1
Ti SWA-LRef-1313-T04-B 1
Ti SWA-LRef-1313-T05-B 1
Ti SWA-LRef-1313-T06-B 1
Ti SWA-LRef-1313-T07-B 1
Ti SWA-LRef-1313-T08-B 1
Ti SWA-LRef-1313-T09-B 1
Ti SWA-LRef-1313-T01-C 1
Ti SWA-LRef-1313-T02-C 1
Ti SWA-LRef-1313-T03-C 1
Ti SWA-LRef-1313-T04-C 1
Ti SWA-LRef-1313-T05-C 1
Ti SWA-LRef-1313-T06-C 1
Ti SWA-LRef-1313-T07-C 1
Ti SWA-LRef-1313-T08-C 1
Ti SWA-LRef-1313-T09-C 1
Ti SWA-LRef-1313-B01-A 1
Ti SWA-LRef-1313-B02-A 1
Ti SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
5.13E+01
7.94E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.13E+01
7.15E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.50E+01
7.49E+03
1.00E+00 U1/2
2.31 E+00 E
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.7E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00 10 100
1.00E+00 7.4E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+03 2.0E+00 6.4E+00
1.00E+00 2.3E+04 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
5.13E+01 2.4E+00 2.0E+00 6.4E+00
7.94E+03 1.3E-01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
1.00E+00 6.6E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00 10 100
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 2.6E+02 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
4.13E+01 3.2E+00 2.0E+00 6.4E+00
7.15E+03 7.0E-01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 5.4E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 9.3E+01 2.0E+00 6.4E+00
4.50E+01 3.6E+00 2.0E+00 6.4E+00
7.49E+03 3.5E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
2.31 E+00 4.7E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.03E+03 103% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.03E+03 103% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.04E+03 104% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-639
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
V SWA-LRef-1313-T01-A 1 4.20E+02
V SWA-LRef-1313-T02-A 1 2.93E+02
V SWA-LRef-1313-T03-A 1 2.32E+02
V SWA-LRef-1313-T04-A 1 1.89E+02
V SWA-LRef-1313-T05-A 1 2.15E+02
V SWA-LRef-1313-T06-A 1 2.27E+02
V SWA-LRef-1313-T07-A 1 2.20E+02
V SWA-LRef-1313-T08-A 1 1.41E+02
V SWA-LRef-1313-T09-A 1 1.22E+03
V SWA-LRef-1313-T01-B 1 4.86E+02
V SWA-LRef-1313-T02-B 1 3.49E+02
V SWA-LRef-1313-T03-B 1 2.99E+02
V SWA-LRef-1313-T04-B 1 2.36E+02
V SWA-LRef-1313-T05-B 1 2.26E+02
V SWA-LRef-1313-T06-B 1 2.25E+02
V SWA-LRef-1313-T07-B 1 2.14E+02
V SWA-LRef-1313-T08-B 1 1.14E+02
V SWA-LRef-1313-T09-B 1 9.13E+02
V SWA-LRef-1313-T01-C 1 4.30E+02
V SWA-LRef-1313-T02-C 1 3.18E+02
V SWA-LRef-1313-T03-C 1 2.47E+02
V SWA-LRef-1313-T04-C 1 2.24E+02
V SWA-LRef-1313-T05-C 1 2.35E+02
V SWA-LRef-1313-T06-C 1 2.08E+02
V SWA-LRef-1313-T07-C 1 2.06E+02
V SWA-LRef-1313-T08-C 1 1.26E+02
V SWA-LRef-1313-T09-C 1 1.42E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.20E+02 1.4E+00 1.5E+00 4.8E+00
2.93E+02 1.2E+00 1.5E+00 4.8E+00
2.32E+02 5.7E-02 1.5E+00 4.8E+00 10 100
1.89E+02 7.5E-01 1.5E+00 4.8E+00
2.15E+02 1.4E+00 1.5E+00 4.8E+00
2.27E+02 2.9E+00 1.5E+00 4.8E+00
2.20E+02 8.1E-01 1.5E+00 4.8E+00
1.41E+02 1.7E+00 1.5E+00 4.8E+00
1.22E+03 4.2E-01 1.5E+00 4.8E+00
4.86E+02 3.8E+00 1.5E+00 4.8E+00
3.49E+02 1.2E+00 1.5E+00 4.8E+00
2.99E+02 6.2E-01 1.5E+00 4.8E+00 10 100
2.36E+02 1.4E+00 1.5E+00 4.8E+00
2.26E+02 1.4E+00 1.5E+00 4.8E+00
2.25E+02 2.0E+00 1.5E+00 4.8E+00
2.14E+02 6.8E-01 1.5E+00 4.8E+00
1.14E+02 3.3E+00 1.5E+00 4.8E+00
9.13E+02 1.7E-01 1.5E+00 4.8E+00
4.30E+02 3.5E-01 1.5E+00 4.8E+00
3.18E+02 9.7E-01 1.5E+00 4.8E+00
2.47E+02 3.8E-01 1.5E+00 4.8E+00 10 100
2.24E+02 1.1E+00 1.5E+00 4.8E+00
2.35E+02 5.4E-01 1.5E+00 4.8E+00
2.08E+02 6.2E-01 1.5E+00 4.8E+00
2.06E+02 1.7E+00 1.5E+00 4.8E+00
1.26E+02 2.8E-01 1.5E+00 4.8E+00
1.42E+03 1.4E+00 1.5E+00 4.8E+00
V SWA-LRef-1313-B01-A 1 7.50E-01 U1/2 7.50E-01 5.5E+01 1.5E+00 4.8E+00
V SWA-LRef-1313-B02-A 1 1.67E+OOE 1.67E+00 1.1E+01 1.5E+00 4.8E+00
V SWA-LRef-1313-B03-A 1 1.62E+OOE 1.62E+00 3.9E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.28E+03 105% VU ICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.34E+03 104% VU ICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.31E+03 107% VU ICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-640
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-LRef-1313-T01-A 1
Zn SWA-LRef-1313-T02-A 1
Zn SWA-LRef-1313-T03-A 1
Zn SWA-LRef-1313-T04-A 1
Zn SWA-LRef-1313-T05-A 1
Zn SWA-LRef-1313-T06-A 1
Zn SWA-LRef-1313-T07-A 1
Zn SWA-LRef-1313-T08-A 1
Zn SWA-LRef-1313-T09-A 1
Zn SWA-LRef-1313-T01-B 1
Zn SWA-LRef-1313-T02-B 1
Zn SWA-LRef-1313-T03-B 1
Zn SWA-LRef-1313-T04-B 1
Zn SWA-LRef-1313-T05-B 1
Zn SWA-LRef-1313-T06-B 1
Zn SWA-LRef-1313-T07-B 1
Zn SWA-LRef-1313-T08-B 1
Zn SWA-LRef-1313-T09-B 1
Zn SWA-LRef-1313-T01-C 1
Zn SWA-LRef-1313-T02-C 1
Zn SWA-LRef-1313-T03-C 1
Zn SWA-LRef-1313-T04-C 1
Zn SWA-LRef-1313-T05-C 1
Zn SWA-LRef-1313-T06-C 1
Zn SWA-LRef-1313-T07-C 1
Zn SWA-LRef-1313-T08-C 1
Zn SWA-LRef-1313-T09-C 1
Zn SWA-LRef-1313-B01-A 1
Zn SWA-LRef-1313-B02-A 1
Zn SWA-LRef-1313-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.12E+01
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
1.12E+01
6.72E+02
1.35E+03
2.24E+03
1.48E+02
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
1.35E+01
2.77E+02
1.41E+03
2.54E+03
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.16E+00
6.46E+02
1.33E+03
2.53E+03
5.00E-01 U1/2
2.37E+00 E
3.48E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.12E+01 2.3E+02 1.0E+00 3.2E+00
5.00E-01 1.1E+01 1.0E+00 3.2E+00
5.00E-01 8.3E+00 1.0E+00 3.2E+00 10 100
5.00E-01 3.1E+01 1.0E+00 3.2E+00
5.00E-01 8.4E+01 1.0E+00 3.2E+00
1.12E+01 6.4E-01 1.0E+00 3.2E+00
6.72E+02 7.0E-01 1.0E+00 3.2E+00
1.35E+03 9.9E-01 1.0E+00 3.2E+00
2.24E+03 9.7E-01 1.0E+00 3.2E+00
1.48E+02 6.0E+00 1.0E+00 3.2E+00
5.00E-01 6.0E+00 1.0E+00 3.2E+00
5.00E-01 1.0E+02 1.0E+00 3.2E+00 10 100
5.00E-01 6.9E+00 1.0E+00 3.2E+00
5.00E-01 3.9E+01 1.0E+00 3.2E+00
1.35E+01 1.2E+00 1.0E+00 3.2E+00
2.77E+02 1.9E-01 1.0E+00 3.2E+00
1.41E+03 1.2E+00 1.0E+00 3.2E+00
2.54E+03 4.7E-01 1.0E+00 3.2E+00
5.00E-01 1.6E+00 1.0E+00 3.2E+00
5.00E-01 7.6E+00 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00 10 100
5.00E-01 2.3E+00 1.0E+00 3.2E+00
5.00E-01 3.6E+01 1.0E+00 3.2E+00
5.16E+00 9.7E+00 1.0E+00 3.2E+00
6.46E+02 4.0E-01 1.0E+00 3.2E+00
1.33E+03 7.6E-01 1.0E+00 3.2E+00
2.53E+03 4.2E+00 1.0E+00 3.2E+00
5.00E-01 6.8E+01 1.0E+00 3.2E+00
2.37E+00 8.3E+00 1.0E+00 3.2E+00
3.48E+00 9.4E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 11/19/10 1:10 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:12 PM EPA Interlab LRef 1313-1316SWA
1.14E+03 114% VUICP-OES 11/19/10 1:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:15 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:1 7PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:18 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:20 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:22 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:23 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:30 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:32 PM EPA Interlab LRef 1313-1316SWA
1.13E+03 113% VUICP-OES 11/19/10 1:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:35 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:36 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:38 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:40 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 1:43 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/10 1:50 PM EPA Interlab LRef 1313-1316SWA
VUICP-OES 11/19/101:51 PM EPA Interlab LRef 1313-1316 SWA
1.13E+03 113% VUICP-OES 11/19/10 1:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:00 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:01 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:03 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 1:09 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-641
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al Sample Dilution
Al SWA-LRef-1313-T01-D 1
Al SWA-LRef-1313-T02-D 1
Al SWA-LRef-1313-T03-D 1
Al SWA-LRef-1313-T04-D 1
Al SWA-LRef-1313-T05-D 1
Al SWA-LRef-1313-T06-D 1
Al SWA-LRef-1313-T07-D 1
Al SWA-LRef-1313-T08-D 1
Al SWA-LRef-1313-T09-D 1
Al SWA-LRef-1313-T01-E 1
Al SWA-LRef-1313-T02-E 1
Al SWA-LRef-1313-T03-E 1
Al SWA-LRef-1313-T04-E 1
Al SWA-LRef-1313-T05-E 1
Al SWA-LRef-1313-T06-E 1
Al SWA-LRef-1313-T07-E 1
Al SWA-LRef-1313-T08-E 1
Al SWA-LRef-1313-T09-E 1
Al SWA-LRef-1313-T01-F 1
Al SWA-LRef-1313-T02-F 1
Al SWA-LRef-1313-T03-F 1
Al SWA-LRef-1313-T04-F 1
Al SWA-LRef-1313-T05-F 1
Al SWA-LRef-1313-T06-F 1
Al SWA-LRef-1313-T07-F 1
Al SWA-LRef-1313-T08-F 1
Al SWA-LRef-1313-T09-F 1
Sample
Cone. Qualifier
ug/L
6.16E+04
3.89E+04
2.16E+04
1.30E+02
6.84E+01
2.36E+01
8.07E+03
2.65E+05
3.38E+05
6.07E+04
3.55E+04
2.40E+04
9.41 E+01
6.62E+01
2.98E+01
8.12E+01
2.18E+05
3.43E+05
5.80E+04
3.47E+04
2.24E+04
9.56E+01
7.83E+01
4.06E+01
2.41 E+01
1.97E+05
3.56E+05
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.16E+04 3.0E-01 1.0E+00 3.2E+00
3.89E+04 6.8E-01 1.0E+00 3.2E+00
2.16E+04 1.3E-01 1.0E+00 3.2E+00 1000 100
1.30E+02 1.2E+01 1.0E+00 3.2E+00
6.84E+01 1.4E+01 1.0E+00 3.2E+00
2.36E+01 1.1E+02 1.0E+00 3.2E+00
8.07E+03 6.7E-01 1.0E+00 3.2E+00
2.65E+05 1.4E+00 1.0E+00 3.2E+00
3.38E+05 9.8E-01 1.0E+00 3.2E+00
6.07E+04 1.1E+00 1.0E+00 3.2E+00
3.55E+04 1.4E+00 1.0E+00 3.2E+00
2.40E+04 6.1E-01 1.0E+00 3.2E+00 1000 100
9.41 E+01 9.1E+00 1.0E+00 3.2E+00
6.62E+01 9.3E+00 1.0E+00 3.2E+00
2.98E+01 5.5E+01 1.0E+00 3.2E+00
8.12E+01 1.6E+01 1.0E+00 3.2E+00
2.18E+05 3.9E-01 1.0E+00 3.2E+00
3.43E+05 1.8E+00 1.0E+00 3.2E+00
5.80E+04 8.6E-01 1.0E+00 3.2E+00
3.47E+04 2.8E-01 1.0E+00 3.2E+00
2.24E+04 4.3E-02 1.0E+00 3.2E+00 1000 100
9.56E+01 5.3E-01 1.0E+00 3.2E+00
7.83E+01 7.3E+00 1.0E+00 3.2E+00
4.06E+01 8.2E+00 1.0E+00 3.2E+00
2.41 E+01 6.4E+02 1.0E+00 3.2E+00
1.97E+05 3.6E-01 1.0E+00 3.2E+00
3.56E+05 1.4E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
2.26E+04 104% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
2.51E+04 111% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
2.34E+04 101% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                                   1-642
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-LRef-1313-T01-D 1
Sb SWA-LRef-1313-T02-D 1
Sb SWA-LRef-1313-T03-D 1
Sb SWA-LRef-1313-T04-D 1
Sb SWA-LRef-1313-T05-D 1
Sb SWA-LRef-1313-T06-D 1
Sb SWA-LRef-1313-T07-D 1
Sb SWA-LRef-1313-T08-D 1
Sb SWA-LRef-1313-T09-D 1
Sb SWA-LRef-1313-T01-E 1
Sb SWA-LRef-1313-T02-E 1
Sb SWA-LRef-1313-T03-E 1
Sb SWA-LRef-1313-T04-E 1
Sb SWA-LRef-1313-T05-E 1
Sb SWA-LRef-1313-T06-E 1
Sb SWA-LRef-1313-T07-E 1
Sb SWA-LRef-1313-T08-E 1
Sb SWA-LRef-1313-T09-E 1
Sb SWA-LRef-1313-T01-F 1
Sb SWA-LRef-1313-T02-F 1
Sb SWA-LRef-1313-T03-F 1
Sb SWA-LRef-1313-T04-F 1
Sb SWA-LRef-1313-T05-F 1
Sb SWA-LRef-1313-T06-F 1
Sb SWA-LRef-1313-T07-F 1
Sb SWA-LRef-1313-T08-F 1
Sb SWA-LRef-1313-T09-F 1
Sample
Cone. Qualifier
ug/L
5.60E+03
5.74E+03
5.15E+03
1.29E+03
1.03E+03
1.35E+03
7.83E+02
9.00E+02
4.96E+02
6.33E+03
5.74E+03
5.44E+03
1.29E+03
9.10E+02
7.43E+02
5.79E+02
1.04E+03
3.93E+02
6.02E+03
5.66E+03
1.38E+03
1.00E+03
1.11E+03
8.75E+02
6.62E+02
1.03E+03
3.84E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.60E+03 9.2E-01 7.5E+00 2.4E+01
5.74E+03 2.5E-01 7.5E+00 2.4E+01
5.15E+03 3.0E-01 7.5E+00 2.4E+01 10 100
1.29E+03 2.4E+00 7.5E+00 2.4E+01
1.03E+03 1.1E+00 7.5E+00 2.4E+01
1.35E+03 1.2E+00 7.5E+00 2.4E+01
7.83E+02 1.6E+00 7.5E+00 2.4E+01
9.00E+02 6.3E+00 7.5E+00 2.4E+01
4.96E+02 1.9E+00 7.5E+00 2.4E+01
6.33E+03 6.4E-01 7.5E+00 2.4E+01
5.74E+03 2.1E+00 7.5E+00 2.4E+01
5.44E+03 3.2E-01 7.5E+00 2.4E+01 10 100
1.29E+03 1.7E+00 7.5E+00 2.4E+01
9.10E+02 3.3E+00 7.5E+00 2.4E+01
7.43E+02 1.6E+00 7.5E+00 2.4E+01
5.79E+02 2.9E+00 7.5E+00 2.4E+01
1.04E+03 2.6E+00 7.5E+00 2.4E+01
3.93E+02 1.8E+00 7.5E+00 2.4E+01
6.02E+03 7.4E-01 7.5E+00 2.4E+01
5.66E+03 4.7E-01 7.5E+00 2.4E+01
1.38E+03 5.0E-01 7.5E+00 2.4E+01 10 100
1.00E+03 2.7E+00 7.5E+00 2.4E+01
1.11E+03 2.4E+00 7.5E+00 2.4E+01
8.75E+02 5.3E-01 7.5E+00 2.4E+01
6.62E+02 3.6E+00 7.5E+00 2.4E+01
1.03E+03 2.4E+00 7.5E+00 2.4E+01
3.84E+02 6.0E-01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
6.29E+03 114% VUICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
6.61E+03 117% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
2.32E+03 95% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-643
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone.
1 ug/L
As SWA-LRef-1313-T01-D 1 8.80E+03
As SWA-LRef-1313-T02-D 1 4.79E+03
As SWA-LRef-1313-T03-D 1 2.41E+03
As SWA-LRef-1313-T04-D 1 4.53E+02
As SWA-LRef-1313-T05-D 1 3.15E+02
As SWA-LRef-1313-T06-D 1 2.48E+02
As SWA-LRef-1313-T07-D 1 4.42E+02
As SWA-LRef-1313-T08-D 1 3.37E+03
As SWA-LRef-1313-T09-D 1 5.21 E+03
As SWA-LRef-1313-T01-E 1 1.08E+04
As SWA-LRef-1313-T02-E 1 4.95E+03
As SWA-LRef-1313-T03-E 1 3.17E+03
As SWA-LRef-1313-T04-E 1 2.39E+02
As SWA-LRef-1313-T05-E 1 3.33E+02
As SWA-LRef-1313-T06-E 1 2.41E+02
As SWA-LRef-1313-T07-E 1 1.67E+02
As SWA-LRef-1313-T08-E 1 3.11E+03
As SWA-LRef-1313-T09-E 1 6.90E+03
As SWA-LRef-1313-T01-F 1 1.01E+04
As SWA-LRef-1313-T02-F 1 4.37E+03
As SWA-LRef-1313-T03-F 1 2.51E+03
As SWA-LRef-1313-T04-F 1 5.27E+02
As SWA-LRef-1313-T05-F 1 3.80E+02
As SWA-LRef-1313-T06-F 1 2.77E+02
As SWA-LRef-1313-T07-F 1 1.80E+02
As SWA-LRef-1313-T08-F 1 3.06E+03
As SWA-LRef-1313-T09-F 1 7.04E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
8.80E+03 7.0E-01 1.1E+01 3.5E+01
4.79E+03 6.1E-01 1.1E+01 3.5E+01
2.41E+03 7.5E-01 1.1E+01 3.5E+01 10 100
4.53E+02 1.3E+00 1.1E+01 3.5E+01
3.15E+02 4.8E+00 1.1E+01 3.5E+01
2.48E+02 1.2E+01 1.1E+01 3.5E+01
4.42E+02 6.6E+00 1.1E+01 3.5E+01
3.37E+03 3.2E-01 1.1E+01 3.5E+01
5.21 E+03 4.6E-01 1.1E+01 3.5E+01
1.08E+04 8.2E-01 1.1E+01 3.5E+01
4.95E+03 1.3E+00 1.1E+01 3.5E+01
3.17E+03 9.9E-01 1.1E+01 3.5E+01 10 100
2.39E+02 1.0E+01 1.1E+01 3.5E+01
3.33E+02 2.3E+00 1.1E+01 3.5E+01
2.41 E+02 5.9E+00 1.1E+01 3.5E+01
1.67E+02 3.4E+00 1.1E+01 3.5E+01
3.11E+03 2.2E-01 1.1E+01 3.5E+01
6.90E+03 1.2E+00 1.1E+01 3.5E+01
1.01E+04 8.1E-01 1.1E+01 3.5E+01
4.37E+03 4.6E-01 1.1E+01 3.5E+01
2.51E+03 4.7E-01 1.1E+01 3.5E+01 10 100
5.27E+02 3.9E+00 1.1E+01 3.5E+01
3.80E+02 3.2E+00 1.1E+01 3.5E+01
2.77E+02 6.7E+00 1.1E+01 3.5E+01
1.80E+02 4.3E+00 1.1E+01 3.5E+01
3.06E+03 3.9E-01 1.1E+01 3.5E+01
7.04E+03 1.9E+00 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
3.34E+03 93% VU ICP-OES 1 1/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
4.09E+03 92% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
3.38E+03 87% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-644
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-LRef-1313-T01-D 1
B SWA-LRef-1313-T02-D 1
B SWA-LRef-1313-T03-D 1
B SWA-LRef-1313-T04-D 1
B SWA-LRef-1313-T05-D 1
B SWA-LRef-1313-T06-D 1
B SWA-LRef-1313-T07-D 1
B SWA-LRef-1313-T08-D 1
B SWA-LRef-1313-T09-D 1
B SWA-LRef-1313-T01-E 1
B SWA-LRef-1313-T02-E 1
B SWA-LRef-1313-T03-E 1
B SWA-LRef-1313-T04-E 1
B SWA-LRef-1313-T05-E 1
B SWA-LRef-1313-T06-E 1
B SWA-LRef-1313-T07-E 1
B SWA-LRef-1313-T08-E 1
B SWA-LRef-1313-T09-E 1
B SWA-LRef-1313-T01-F 1
B SWA-LRef-1313-T02-F 1
B SWA-LRef-1313-T03-F 1
B SWA-LRef-1313-T04-F 1
B SWA-LRef-1313-T05-F 1
B SWA-LRef-1313-T06-F 1
B SWA-LRef-1313-T07-F 1
B SWA-LRef-1313-T08-F 1
B SWA-LRef-1313-T09-F 1
Sample I
Cone. Qualifier
ug/L I
1.10E+03
1.05E+03
8.84E+02
1.73E+03
3.19E+03
3.92E+03
5.74E+03
6.79E+03
7.18E+03
1.19E+03
1.05E+03
9.71 E+02
1.39E+03
2.46E+03
3.58E+03
5.78E+03
7.12E+03
6.99E+03
1.16E+03
9.77E+02
9.21 E+02
1.82E+03
2.42E+03
3.59E+03
5.63E+03
7.29E+03
6.84E+03
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+03 7.9E-01 1.0E+00 3.2E+00
1.05E+03 9.3E-02 1.0E+00 3.2E+00
8.84E+02 5.4E-01 1.0E+00 3.2E+00 1000 100
1.73E+03 9.1E-01 1.0E+00 3.2E+00
3.19E+03 6.0E-01 1.0E+00 3.2E+00
3.92E+03 3.8E-01 1.0E+00 3.2E+00
5.74E+03 7.8E-01 1.0E+00 3.2E+00
6.79E+03 6.6E-01 1.0E+00 3.2E+00
7.18E+03 9.2E-01 1.0E+00 3.2E+00
1.19E+03 5.8E-01 1.0E+00 3.2E+00
1.05E+03 1.4E+00 1.0E+00 3.2E+00
9.71 E+02 1.3E-01 1.0E+00 3.2E+00 1000 100
1.39E+03 4.2E-01 1.0E+00 3.2E+00
2.46E+03 6.8E-01 1.0E+00 3.2E+00
3.58E+03 6.2E-01 1.0E+00 3.2E+00
5.78E+03 6.5E-01 1.0E+00 3.2E+00
7.12E+03 6.4E-01 1.0E+00 3.2E+00
6.99E+03 1.0E+00 1.0E+00 3.2E+00
1.16E+03 8.2E-01 1.0E+00 3.2E+00
9.77E+02 6.7E-01 1.0E+00 3.2E+00
9.21 E+02 7.6E-01 1.0E+00 3.2E+00 1000 100
1.82E+03 6.4E-01 1.0E+00 3.2E+00
2.42E+03 8.8E-01 1.0E+00 3.2E+00
3.59E+03 2.9E-01 1.0E+00 3.2E+00
5.63E+03 5.0E-01 1.0E+00 3.2E+00
7.29E+03 5.2E-01 1.0E+00 3.2E+00
6.84E+03 1.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1 .88E+03 100% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.93E+03 96% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
1.85E+03 92% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-645
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone.
1 1 ug/L
Ba SWA-LRef-1313-T01-D 1 2.19E+02
Ba SWA-LRef-1313-T02-D 1 1.62E+02
Ba SWA-LRef-1313-T03-D 1 1.68E+02
Ba SWA-LRef-1313-T04-D 1 1.01E+03
Ba SWA-LRef-1313-T05-D 1 1.14E+03
Ba SWA-LRef-1313-T06-D 1 1.15E+03
Ba SWA-LRef-1313-T07-D 1 1.53E+03
Ba SWA-LRef-1313-T08-D 1 8.96E+02
Ba SWA-LRef-1313-T09-D 1 9.05E+02
Ba SWA-LRef-1313-T01-E 1 1.94E+02
Ba SWA-LRef-1313-T02-E 1 1.51E+02
Ba SWA-LRef-1313-T03-E 1 1.65E+02
Ba SWA-LRef-1313-T04-E 1 1.16E+03
Ba SWA-LRef-1313-T05-E 1 1.10E+03
Ba SWA-LRef-1313-T06-E 1 1.19E+03
Ba SWA-LRef-1313-T07-E 1 1.68E+03
Ba SWA-LRef-1313-T08-E 1 9.57E+02
Ba SWA-LRef-1313-T09-E 1 1.02E+03
Ba SWA-LRef-1313-T01-F 1 2.81E+01
Ba SWA-LRef-1313-T02-F 1 1.60E+02
Ba SWA-LRef-1313-T03-F 1 2.03E+02
Ba SWA-LRef-1313-T04-F 1 9.49E+02
Ba SWA-LRef-1313-T05-F 1 1.12E+03
Ba SWA-LRef-1313-T06-F 1 1.22E+03
Ba SWA-LRef-1313-T07-F 1 1.67E+03
Ba SWA-LRef-1313-T08-F 1 1.02E+03
Ba SWA-LRef-1313-T09-F 1 9.36E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.19E+02 1.7E+00 1.0E+00 3.2E+00
1.62E+02 2.2E-01 1.0E+00 3.2E+00
1.68E+02 3.4E-01 1.0E+00 3.2E+00 10 100
1.01E+03 9.0E-01 1.0E+00 3.2E+00
1.14E+03 4.7E-01 1.0E+00 3.2E+00
1.15E+03 4.0E-01 1.0E+00 3.2E+00
1.53E+03 6.7E-01 1.0E+00 3.2E+00
8.96E+02 3.0E-01 1.0E+00 3.2E+00
9.05E+02 6.1E-01 1.0E+00 3.2E+00
1.94E+02 8.2E-01 1.0E+00 3.2E+00
1.51E+02 6.3E-01 1.0E+00 3.2E+00
1.65E+02 5.5E-01 1.0E+00 3.2E+00 10 100
1.16E+03 7.3E-01 1.0E+00 3.2E+00
1.10E+03 7.3E-01 1.0E+00 3.2E+00
1.19E+03 1.1E+00 1.0E+00 3.2E+00
1.68E+03 7.4E-01 1.0E+00 3.2E+00
9.57E+02 1.0E+00 1.0E+00 3.2E+00
1.02E+03 1.4E+00 1.0E+00 3.2E+00
2.81 E+01 1.1E+00 1.0E+00 3.2E+00
1.60E+02 5.3E-01 1.0E+00 3.2E+00
2.03E+02 2.9E-01 1.0E+00 3.2E+00 10 100
9.49E+02 6.2E-01 1.0E+00 3.2E+00
1.12E+03 5.0E-01 1.0E+00 3.2E+00
1.22E+03 2.8E-01 1.0E+00 3.2E+00
1.67E+03 4.0E-01 1.0E+00 3.2E+00
1.02E+03 4.1E-01 1.0E+00 3.2E+00
9.36E+02 1.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.22E+03 105% VUICP-OES 1 1/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.16E+03 100% VU ICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
1.14E+03 93% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-646
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-LRef-1313-T01-D 1
Be SWA-LRef-1313-T02-D 1
Be SWA-LRef-1313-T03-D 1
Be SWA-LRef-1313-T04-D 1
Be SWA-LRef-1313-T05-D 1
Be SWA-LRef-1313-T06-D 1
Be SWA-LRef-1313-T07-D 1
Be SWA-LRef-1313-T08-D 1
Be SWA-LRef-1313-T09-D 1
Be SWA-LRef-1313-T01-E 1
Be SWA-LRef-1313-T02-E 1
Be SWA-LRef-1313-T03-E 1
Be SWA-LRef-1313-T04-E 1
Be SWA-LRef-1313-T05-E 1
Be SWA-LRef-1313-T06-E 1
Be SWA-LRef-1313-T07-E 1
Be SWA-LRef-1313-T08-E 1
Be SWA-LRef-1313-T09-E 1
Be SWA-LRef-1313-T01-F 1
Be SWA-LRef-1313-T02-F 1
Be SWA-LRef-1313-T03-F 1
Be SWA-LRef-1313-T04-F 1
Be SWA-LRef-1313-T05-F 1
Be SWA-LRef-1313-T06-F 1
Be SWA-LRef-1313-T07-F 1
Be SWA-LRef-1313-T08-F 1
Be SWA-LRef-1313-T09-F 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
3.35E+01
1.37E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
1.24E+01
1.39E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
8.17E+00
1.31E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.2E+02 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 4.2E+02 1.9E+00 6.0E+00 10 100
9.50E-01 6.2E+01 1.9E+00 6.0E+00
9.50E-01 6.3E+01 1.9E+00 6.0E+00
9.50E-01 9.6E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
3.35E+01 2.6E+00 1.9E+00 6.0E+00
1.37E+02 7.6E-01 1.9E+00 6.0E+00
9.50E-01 8.1E+01 1.9E+00 6.0E+00
9.50E-01 2.1E+03 1.9E+00 6.0E+00
9.50E-01 1.5E+04 1.9E+00 6.0E+00 10 100
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 3.3E+02 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00
1.24E+01 8.0E+00 1.9E+00 6.0E+00
1.39E+02 4.1E+00 1.9E+00 6.0E+00
9.50E-01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00
9.50E-01 7.6E+02 1.9E+00 6.0E+00 10 100
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 9.7E+01 1.9E+00 6.0E+00
9.50E-01 5.5E+01 1.9E+00 6.0E+00
8.17E+00 3.3E+01 1.9E+00 6.0E+00
1.31E+02 1.1E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.10E+03 110% VUICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.07E+03 107% VU ICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/1012:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
9.99E+02 100% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-647
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd SWA-LRef-1313-T01-D 1
Cd SWA-LRef-1313-T02-D 1
Cd SWA-LRef-1313-T03-D 1
Cd SWA-LRef-1313-T04-D 1
Cd SWA-LRef-1313-T05-D 1
Cd SWA-LRef-1313-T06-D 1
Cd SWA-LRef-1313-T07-D 1
Cd SWA-LRef-1313-T08-D 1
Cd SWA-LRef-1313-T09-D 1
Cd SWA-LRef-1313-T01-E 1
Cd SWA-LRef-1313-T02-E 1
Cd SWA-LRef-1313-T03-E 1
Cd SWA-LRef-1313-T04-E 1
Cd SWA-LRef-1313-T05-E 1
Cd SWA-LRef-1313-T06-E 1
Cd SWA-LRef-1313-T07-E 1
Cd SWA-LRef-1313-T08-E 1
Cd SWA-LRef-1313-T09-E 1
Cd SWA-LRef-1313-T01-F 1
Cd SWA-LRef-1313-T02-F 1
Cd SWA-LRef-1313-T03-F 1
Cd SWA-LRef-1313-T04-F 1
Cd SWA-LRef-1313-T05-F 1
Cd SWA-LRef-1313-T06-F 1
Cd SWA-LRef-1313-T07-F 1
Cd SWA-LRef-1313-T08-F 1
Cd SWA-LRef-1313-T09-F 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.49E+01
1.78E+01
4.21E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.06E+01
1.55E+01
4.30E+01
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
7.68E+00
1.50E+01
3.88E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 2.1E+02 2.2E+00 7.0E+00
1.10E+00 5.9E+02 2.2E+00 7.0E+00
1.10E+00 4.2E+01 2.2E+00 7.0E+00 10 100
1.10E+00 1.6E+02 2.2E+00 7.0E+00
1.10E+00 5.1E+01 2.2E+00 7.0E+00
1.10E+00 6.8E+01 2.2E+00 7.0E+00
1.49E+01 1.2E+00 2.2E+00 7.0E+00
1.78E+01 1.6E+00 2.2E+00 7.0E+00
4.21 E+01 3.4E+00 2.2E+00 7.0E+00
1.10E+00 1.6E+02 2.2E+00 7.0E+00
1.10E+00 2.7E+02 2.2E+00 7.0E+00
1.10E+00 2.4E+02 2.2E+00 7.0E+00 10 100
1.10E+00 4.1 E+01 2.2E+00 7.0E+00
1.10E+00 6.3E+01 2.2E+00 7.0E+00
1.10E+00 6.2E+02 2.2E+00 7.0E+00
1.06E+01 1.6E+00 2.2E+00 7.0E+00
1.55E+01 8.1E-01 2.2E+00 7.0E+00
4.30E+01 1.2E+00 2.2E+00 7.0E+00
1.10E+00 1.6E+02 2.2E+00 7.0E+00
1.10E+00 2.3E+03 2.2E+00 7.0E+00
1.10E+00 9.2E+02 2.2E+00 7.0E+00 10 100
1.10E+00 9.7E+00 2.2E+00 7.0E+00
1.10E+00 7.4E+01 2.2E+00 7.0E+00
1.10E+00 6.1 E+01 2.2E+00 7.0E+00
7.68E+00 8.0E+00 2.2E+00 7.0E+00
1.50E+01 1.8E+00 2.2E+00 7.0E+00
3.88E+01 1.9E+00 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.06E+03 106% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.05E+03 105% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
9.84E+02 98% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-648
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca SWA-LRef-1313-T01-D 1
Ca SWA-LRef-1313-T02-D 1
Ca SWA-LRef-1313-T03-D 1
Ca SWA-LRef-1313-T04-D 1
Ca SWA-LRef-1313-T05-D 1
Ca SWA-LRef-1313-T06-D 1
Ca SWA-LRef-1313-T07-D 1
Ca SWA-LRef-1313-T08-D 1
Ca SWA-LRef-1313-T09-D 1
Ca SWA-LRef-1313-T01-E 1
Ca SWA-LRef-1313-T02-E 1
Ca SWA-LRef-1313-T03-E 1
Ca SWA-LRef-1313-T04-E 1
Ca SWA-LRef-1313-T05-E 1
Ca SWA-LRef-1313-T06-E 1
Ca SWA-LRef-1313-T07-E 1
Ca SWA-LRef-1313-T08-E 1
Ca SWA-LRef-1313-T09-E 1
Ca SWA-LRef-1313-T01-F 1
Ca SWA-LRef-1313-T02-F 1
Ca SWA-LRef-1313-T03-F 1
Ca SWA-LRef-1313-T04-F 1
Ca SWA-LRef-1313-T05-F 1
Ca SWA-LRef-1313-T06-F 1
Ca SWA-LRef-1313-T07-F 1
Ca SWA-LRef-1313-T08-F 1
Ca SWA-LRef-1313-T09-F 1
Sample I
Cone. Qualifier
ug/L I
7.57E+03
1.46E+04
2.26E+04
4.95E+06
7.39E+06
7.30E+06
7.80E+06
5.14E+06
3.55E+06
7.52E+03
1.35E+04
2.15E+04
4.35E+06
6.76E+06
7.36E+06
8.87E+06
5.43E+06
3.58E+06
4.62E+03
1.43E+04
2.32E+04
5.16E+06
6.78E+06
7.34E+06
9.14E+06
5.71 E+06
3.59E+06
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.57E+03 1.3E+00 2.6E+00 8.3E+00
1.46E+04 1.2E-01 2.6E+00 8.3E+00
2.26E+04 3.1E-01 2.6E+00 8.3E+00 1000 100
4.95E+06 8.5E-01 2.6E+00 8.3E+00
7.39E+06 9.6E-01 2.6E+00 8.3E+00
7.30E+06 5.0E-01 2.6E+00 8.3E+00
7.80E+06 9.8E-01 2.6E+00 8.3E+00
5.14E+06 1.5E+00 2.6E+00 8.3E+00
3.55E+06 7.7E-01 2.6E+00 8.3E+00
7.52E+03 7.8E-01 2.6E+00 8.3E+00
1.35E+04 1.2E+00 2.6E+00 8.3E+00
2.15E+04 4.8E-01 2.6E+00 8.3E+00 1000 100
4.35E+06 7.8E-01 2.6E+00 8.3E+00
6.76E+06 4.3E-01 2.6E+00 8.3E+00
7.36E+06 7.4E-01 2.6E+00 8.3E+00
8.87E+06 8.2E-01 2.6E+00 8.3E+00
5.43E+06 5.7E-01 2.6E+00 8.3E+00
3.58E+06 1.2E+00 2.6E+00 8.3E+00
4.62E+03 1.0E+00 2.6E+00 8.3E+00
1.43E+04 4.4E-01 2.6E+00 8.3E+00
2.32E+04 3.0E-01 2.6E+00 8.3E+00 1000 100
5.16E+06 8.6E-01 2.6E+00 8.3E+00
6.78E+06 1.1E+00 2.6E+00 8.3E+00
7.34E+06 4.9E-01 2.6E+00 8.3E+00
9.14E+06 6.2E-01 2.6E+00 8.3E+00
5.71 E+06 1.1E+00 2.6E+00 8.3E+00
3.59E+06 3.3E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
2.35E+04 90% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
2.24E+04 89% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
2.41E+04 85% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-649
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qu
1 1 ug/L
Cr SWA-LRef-1313-T01-D 1 1.19E+03
Cr SWA-LRef-1313-T02-D 1 1.36E+03
Cr SWA-LRef-1313-T03-D 1 3.93E+02
Cr SWA-LRef-1313-T04-D 1 4.26E+00
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.19E+03 2.5E+00 1.2E+00 3.8E+00
1.36E+03 3.2E-01 1.2E+00 3.8E+00
3.93E+02 3.9E-01 1.2E+00 3.8E+00 10 100
4.26E+00 2.3E+01 1.2E+00 3.8E+00
Cr SWA-LRef-1313-T05-D 1 6.00E-01 U1/2 6.00E-01 8.5E+01 1.2E+00 3.8E+00
Cr SWA-LRef-1313-T06-D 1 6.00E-01 U1/2 6.00E-01 9.7E+02 1.2E+00 3.8E+00
Cr SWA-LRef-1313-T07-D 1 7.90E+00
Cr SWA-LRef-1313-T08-D 1 3.66E+03
Cr SWA-LRef-1313-T09-D 1 1.95E+04
Cr SWA-LRef-1313-T01-E 1 1.54E+03
Cr SWA-LRef-1313-T02-E 1 1.19E+03
Cr SWA-LRef-1313-T03-E 1 4.46E+02
Cr SWA-LRef-1313-T04-E 1 2.48E+00 E
Cr SWA-LRef-1313-T05-E 1 3.54E+00 E
7.90E+00 2.1E-01 1.2E+00 3.8E+00
3.66E+03 9.0E-01 1.2E+00 3.8E+00
1.95E+04 4.9E-01 1.2E+00 3.8E+00
1.54E+03 1.0E+00 1.2E+00 3.8E+00
1.19E+03 9.6E-01 1.2E+00 3.8E+00
4.46E+02 8.1E-01 1.2E+00 3.8E+00 10 100
2.48E+00 4.3E+01 1.2E+00 3.8E+00
3.54E+00 2.4E+01 1.2E+00 3.8E+00
Cr SWA-LRef-1313-T06-E 1 6.00E-01 U1/2 6.00E-01 2.7E+01 1.2E+00 3.8E+00
Cr SWA-LRef-1313-T07-E 1 3.87E+00
Cr SWA-LRef-1313-T08-E 1 2.17E+03
Cr SWA-LRef-1313-T09-E 1 1.79E+04
Cr SWA-LRef-1313-T01-F 1 7.95E+02
Cr SWA-LRef-1313-T02-F 1 1.15E+03
Cr SWA-LRef-1313-T03-F 1 3.69E+02
Cr SWA-LRef-1313-T04-F 1 6.39E+00
Cr SWA-LRef-1313-T05-F 1 4.02E+00
3.87E+00 1.3E+01 1.2E+00 3.8E+00
2.17E+03 4.9E-01 1.2E+00 3.8E+00
1.79E+04 7.6E-01 1.2E+00 3.8E+00
7.95E+02 1.3E+00 1.2E+00 3.8E+00
1.15E+03 9.2E-01 1.2E+00 3.8E+00
3.69E+02 9.7E-01 1.2E+00 3.8E+00 10 100
6.39E+00 5.0E-01 1.2E+00 3.8E+00
4.02E+00 7.6E+00 1.2E+00 3.8E+00
Cr SWA-LRef-1313-T06-F 1 6.00E-01 U1/2 6.00E-01 2.2E+01 1.2E+00 3.8E+00
Cr SWA-LRef-1313-T07-F 1 3.73E+00 E
Cr SWA-LRef-1313-T08-F 1 1.59E+03
Cr SWA-LRef-1313-T09-F 1 1.84E+04
3.73E+00 1.1E+02 1.2E+00 3.8E+00
1.59E+03 4.2E-01 1.2E+00 3.8E+00
1.84E+04 1.1E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.44E+03 105% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.42E+03 97% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/1012:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
1.29E+03 92% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-650
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co SWA-LRef-1313-T01-D 1
Co SWA-LRef-1313-T02-D 1
Co SWA-LRef-1313-T03-D 1
Co SWA-LRef-1313-T04-D 1
Co SWA-LRef-1313-T05-D 1
Co SWA-LRef-1313-T06-D 1
Co SWA-LRef-1313-T07-D 1
Co SWA-LRef-1313-T08-D 1
Co SWA-LRef-1313-T09-D 1
Co SWA-LRef-1313-T01-E 1
Co SWA-LRef-1313-T02-E 1
Co SWA-LRef-1313-T03-E 1
Co SWA-LRef-1313-T04-E 1
Co SWA-LRef-1313-T05-E 1
Co SWA-LRef-1313-T06-E 1
Co SWA-LRef-1313-T07-E 1
Co SWA-LRef-1313-T08-E 1
Co SWA-LRef-1313-T09-E 1
Co SWA-LRef-1313-T01-F 1
Co SWA-LRef-1313-T02-F 1
Co SWA-LRef-1313-T03-F 1
Co SWA-LRef-1313-T04-F 1
Co SWA-LRef-1313-T05-F 1
Co SWA-LRef-1313-T06-F 1
Co SWA-LRef-1313-T07-F 1
Co SWA-LRef-1313-T08-F 1
Co SWA-LRef-1313-T09-F 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.15E+00 E
1.43E+01
3.12E+01
2.07E+02
1.84E+02
2.62E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.50E+00 E
6.50E+00
3.45E+01
2.00E+02
1.86E+02
2.59E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
2.23E+00 E
5.05E+00 E
4.73E+01
1.76E+02
1.93E+02
2.45E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 6.0E+01 1.8E+00 5.7E+00
9.00E-01 9.3E+01 1.8E+00 5.7E+00
9.00E-01 1.3E+01 1.8E+00 5.7E+00 10 100
2.15E+00 3.5E+01 1.8E+00 5.7E+00
1.43E+01 6.9E+00 1.8E+00 5.7E+00
3.12E+01 8.0E+00 1.8E+00 5.7E+00
2.07E+02 1.6E+00 1.8E+00 5.7E+00
1.84E+02 1.6E+00 1.8E+00 5.7E+00
2.62E+02 2.1E+00 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 1.7E+01 1.8E+00 5.7E+00
9.00E-01 4.8E+01 1.8E+00 5.7E+00 10 100
2.50E+00 7.6E+02 1.8E+00 5.7E+00
6.50E+00 8.5E+00 1.8E+00 5.7E+00
3.45E+01 4.6E+00 1.8E+00 5.7E+00
2.00E+02 7.6E-01 1.8E+00 5.7E+00
1.86E+02 5.8E-01 1.8E+00 5.7E+00
2.59E+02 1.4E+00 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 2.3E+01 1.8E+00 5.7E+00
9.00E-01 6.9E+02 1.8E+00 5.7E+00 10 100
2.23E+00 6.3E+01 1.8E+00 5.7E+00
5.05E+00 1.7E+01 1.8E+00 5.7E+00
4.73E+01 3.8E+00 1.8E+00 5.7E+00
1.76E+02 1.3E+00 1.8E+00 5.7E+00
1.93E+02 4.5E-01 1.8E+00 5.7E+00
2.45E+02 1.9E+00 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.03E+03 103% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
9.82E+02 98% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/1012:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
9.18E+02 92% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 1 :01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-651
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu SWA-LRef-1313-T01-D 1
Cu SWA-LRef-1313-T02-D 1
Cu SWA-LRef-1313-T03-D 1
Cu SWA-LRef-1313-T04-D 1
Cu SWA-LRef-1313-T05-D 1
Cu SWA-LRef-1313-T06-D 1
Cu SWA-LRef-1313-T07-D 1
Cu SWA-LRef-1313-T08-D 1
Cu SWA-LRef-1313-T09-D 1
Cu SWA-LRef-1313-T01-E 1
Cu SWA-LRef-1313-T02-E 1
Cu SWA-LRef-1313-T03-E 1
Cu SWA-LRef-1313-T04-E 1
Cu SWA-LRef-1313-T05-E 1
Cu SWA-LRef-1313-T06-E 1
Cu SWA-LRef-1313-T07-E 1
Cu SWA-LRef-1313-T08-E 1
Cu SWA-LRef-1313-T09-E 1
Cu SWA-LRef-1313-T01-F 1
Cu SWA-LRef-1313-T02-F 1
Cu SWA-LRef-1313-T03-F 1
Cu SWA-LRef-1313-T04-F 1
Cu SWA-LRef-1313-T05-F 1
Cu SWA-LRef-1313-T06-F 1
Cu SWA-LRef-1313-T07-F 1
Cu SWA-LRef-1313-T08-F 1
Cu SWA-LRef-1313-T09-F 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
7.29E+00 E
1.03E+01 E
1.07E+01 E
1.53E+01
2.76E+01
1.40E+03
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
8.03E+00 E
9.48E+00 E
6.43E+00 E
1.43E+01
1.52E+01
1.39E+03
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
9.43E+00 E
6.29E+00 E
1.04E+01 E
1.56E+01
1.34E+01
1.38E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 1.8E+03 3.7E+00 1.2E+01
1.85E+00 4.9E+02 3.7E+00 1.2E+01
1.85E+00 3.8E+03 3.7E+00 1.2E+01 10 100
7.29E+00 1.6E+01 3.7E+00 1.2E+01
1.03E+01 4.6E+01 3.7E+00 1.2E+01
1.07E+01 2.1E+01 3.7E+00 1.2E+01
1.53E+01 2.9E+01 3.7E+00 1.2E+01
2.76E+01 5.7E+00 3.7E+00 1.2E+01
1.40E+03 6.0E-01 3.7E+00 1.2E+01
1.85E+00 4.3E+02 3.7E+00 1.2E+01
1.85E+00 7.5E+03 3.7E+00 1.2E+01
1.85E+00 2.0E+01 3.7E+00 1.2E+01 10 100
8.03E+00 4.6E+01 3.7E+00 1.2E+01
9.48E+00 2.2E+01 3.7E+00 1.2E+01
6.43E+00 8.9E+01 3.7E+00 1.2E+01
1.43E+01 2.1E+01 3.7E+00 1.2E+01
1.52E+01 9.6E+00 3.7E+00 1 .2E+01
1.39E+03 1.0E+00 3.7E+00 1 .2E+01
1.85E+00 3.3E+02 3.7E+00 1 .2E+01
1.85E+00 9.8E+01 3.7E+00 1 .2E+01
1.85E+00 4.7E+01 3.7E+00 1 .2E+01 10 100
9.43E+00 5.4E+01 3.7E+00 1 .2E+01
6.29E+00 2.8E+01 3.7E+00 1 .2E+01
1.04E+01 6.3E+00 3.7E+00 1 .2E+01
1.56E+01 4.3E+00 3.7E+00 1 .2E+01
1.34E+01 1.3E+01 3.7E+00 1 .2E+01
1.38E+03 6.6E-01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.04E+03 104% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
9.82E+02 98% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/1012:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
9.23E+02 92% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 1 :01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-652
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. Qu
1 1 ug/L
Fe SWA-LRef-1313-T01-D 1 6.99E+01
Fe SWA-LRef-1313-T02-D 1 9.37E+01
Fe SWA-LRef-1313-T03-D 1 6.59E+01
Fe SWA-LRef-1313-T04-D 1 2.66E+01
Fe SWA-LRef-1313-T05-D 1 7.68E+01
Fe SWA-LRef-1313-T06-D 1 3.29E+01
Fe SWA-LRef-1313-T07-D 1 1.31E+05
Fe SWA-LRef-1313-T08-D 1 1.28E+05
Fe SWA-LRef-1313-T09-D 1 1.62E+05
Fe SWA-LRef-1313-T01-E 1 9.22E+01
Fe SWA-LRef-1313-T02-E 1 8.39E+01
Fe SWA-LRef-1313-T03-E 1 7.69E+01
Fe SWA-LRef-1313-T04-E 1 1.55E+01
Fe SWA-LRef-1313-T05-E 1 4.61 E+01
Fe SWA-LRef-1313-T06-E 1 6.31 E+01
Fe SWA-LRef-1313-T07-E 1 9.92E+04
Fe SWA-LRef-1313-T08-E 1 1.23E+05
Fe SWA-LRef-1313-T09-E 1 1.69E+05
Fe SWA-LRef-1313-T01-F 1 4.48E+01
Fe SWA-LRef-1313-T02-F 1 7.35E+01
Fe SWA-LRef-1313-T03-F 1 6.80E+01
Fe SWA-LRef-1313-T04-F 1 2.26E+01
Fe SWA-LRef-1313-T05-F 1 6.93E+01
Fe SWA-LRef-1313-T06-F 1 2.38E+02
Fe SWA-LRef-1313-T07-F 1 7.27E+04
Fe SWA-LRef-1313-T08-F 1 1.23E+05
Fe SWA-LRef-1313-T09-F 1 1.70E+05
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.99E+01 3.8E+00 2.0E+00 6.4E+00
9.37E+01 1.3E+00 2.0E+00 6.4E+00
6.59E+01 8.0E-01 2.0E+00 6.4E+00 1000 100
2.66E+01 3.7E+00 2.0E+00 6.4E+00
7.68E+01 1.2E+00 2.0E+00 6.4E+00
3.29E+01 2.8E+00 2.0E+00 6.4E+00
1.31E+05 7.5E-01 2.0E+00 6.4E+00
1.28E+05 2.1E+00 2.0E+00 6.4E+00
1.62E+05 3.1E-01 2.0E+00 6.4E+00
9.22E+01 1.6E-01 2.0E+00 6.4E+00
8.39E+01 9.5E-01 2.0E+00 6.4E+00
7.69E+01 7.6E-01 2.0E+00 6.4E+00 1000 100
1.55E+01 2.7E+00 2.0E+00 6.4E+00
4.61 E+01 1.4E+00 2.0E+00 6.4E+00
6.31 E+01 1.4E+00 2.0E+00 6.4E+00
9.92E+04 3.7E-01 2.0E+00 6.4E+00
1.23E+05 3.0E-01 2.0E+00 6.4E+00
1.69E+05 2.6E-01 2.0E+00 6.4E+00
4.48E+01 8.7E-01 2.0E+00 6.4E+00
7.35E+01 1.4E+00 2.0E+00 6.4E+00
6.80E+01 1.1E+00 2.0E+00 6.4E+00 1000 100
2.26E+01 7.6E-02 2.0E+00 6.4E+00
6.93E+01 2.2E+00 2.0E+00 6.4E+00
2.38E+02 1.0E+00 2.0E+00 6.4E+00
7.27E+04 8.4E-01 2.0E+00 6.4E+00
1.23E+05 9.9E-01 2.0E+00 6.4E+00
1.70E+05 1.2E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1 .13E+03 107% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.09E+03 101% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
1.01E+03 95% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-653
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb SWA-LRef-1313-T01-D 1
Pb SWA-LRef-1313-T02-D 1
Pb SWA-LRef-1313-T03-D 1
Pb SWA-LRef-1313-T04-D 1
Pb SWA-LRef-1313-T05-D 1
Pb SWA-LRef-1313-T06-D 1
Pb SWA-LRef-1313-T07-D 1
Pb SWA-LRef-1313-T08-D 1
Pb SWA-LRef-1313-T09-D 1
Pb SWA-LRef-1313-T01-E 1
Pb SWA-LRef-1313-T02-E 1
Pb SWA-LRef-1313-T03-E 1
Pb SWA-LRef-1313-T04-E 1
Pb SWA-LRef-1313-T05-E 1
Pb SWA-LRef-1313-T06-E 1
Pb SWA-LRef-1313-T07-E 1
Pb SWA-LRef-1313-T08-E 1
Pb SWA-LRef-1313-T09-E 1
Pb SWA-LRef-1313-T01-F 1
Pb SWA-LRef-1313-T02-F 1
Pb SWA-LRef-1313-T03-F 1
Pb SWA-LRef-1313-T04-F 1
Pb SWA-LRef-1313-T05-F 1
Pb SWA-LRef-1313-T06-F 1
Pb SWA-LRef-1313-T07-F 1
Pb SWA-LRef-1313-T08-F 1
Pb SWA-LRef-1313-T09-F 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.63E+01
1.37E+01 E
1.10E+01 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
1.57E+02
3.83E+03
4.82E+01
9.97E+00 E
8.07E+00 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
5.50E+01
3.38E+03
4.15E+01
1.60E+01 E
7.36E+00 E
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
2.66E+01
3.22E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.63E+01 1.6E+01 6.8E+00 2.2E+01
1.37E+01 3.9E+01 6.8E+00 2.2E+01
1.10E+01 5.6E+01 6.8E+00 2.2E+01 10 100
3.40E+00 1.8E+01 6.8E+00 2.2E+01
3.40E+00 3.5E+01 6.8E+00 2.2E+01
3.40E+00 6.5E+01 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
1.57E+02 8.9E-01 6.8E+00 2.2E+01
3.83E+03 1.2E-01 6.8E+00 2.2E+01
4.82E+01 1.2E+01 6.8E+00 2.2E+01
9.97E+00 5.2E+01 6.8E+00 2.2E+01
8.07E+00 5.2E+01 6.8E+00 2.2E+01 10 100
3.40E+00 2.2E+02 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01
3.40E+00 7.8E+01 6.8E+00 2.2E+01
3.40E+00 8.1E+01 6.8E+00 2.2E+01
5.50E+01 7.8E+00 6.8E+00 2.2E+01
3.38E+03 1.0E+00 6.8E+00 2.2E+01
4.15E+01 6.8E+01 6.8E+00 2.2E+01
1.60E+01 1.8E+01 6.8E+00 2.2E+01
7.36E+00 1.6E+02 6.8E+00 2.2E+01 10 100
3.40E+00 6.7E+01 6.8E+00 2.2E+01
3.40E+00 2.4E+01 6.8E+00 2.2E+01
3.40E+00 3.0E+01 6.8E+00 2.2E+01
3.40E+00 6.6E+01 6.8E+00 2.2E+01
2.66E+01 3.3E+01 6.8E+00 2.2E+01
3.22E+03 9.8E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.00E+03 99% VUICP-OES 1 1/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
9.53E+02 94% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/1012:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
9.01E+02 89% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-654
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li SWA-LRef-1313-T01-D 1
Li SWA-LRef-1313-T02-D 1
Li SWA-LRef-1313-T03-D 1
Li SWA-LRef-1313-T04-D 1
Li SWA-LRef-1313-T05-D 1
Li SWA-LRef-1313-T06-D 1
Li SWA-LRef-1313-T07-D 1
Li SWA-LRef-1313-T08-D 1
Li SWA-LRef-1313-T09-D 1
Li SWA-LRef-1313-T01-E 1
Li SWA-LRef-1313-T02-E 1
Li SWA-LRef-1313-T03-E 1
Li SWA-LRef-1313-T04-E 1
Li SWA-LRef-1313-T05-E 1
Li SWA-LRef-1313-T06-E 1
Li SWA-LRef-1313-T07-E 1
Li SWA-LRef-1313-T08-E 1
Li SWA-LRef-1313-T09-E 1
Li SWA-LRef-1313-T01-F 1
Li SWA-LRef-1313-T02-F 1
Li SWA-LRef-1313-T03-F 1
Li SWA-LRef-1313-T04-F 1
Li SWA-LRef-1313-T05-F 1
Li SWA-LRef-1313-T06-F 1
Li SWA-LRef-1313-T07-F 1
Li SWA-LRef-1313-T08-F 1
Li SWA-LRef-1313-T09-F 1
Sample I
Cone. Qualifier
ug/L I
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
5.96E+02
1.13E+03
1.12E+03
1.25E+03
9.10E+02
9.81 E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
4.51 E+02
9.92E+02
1.12E+03
1.36E+03
9.80E+02
9.81 E+02
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
6.75E+02
1.02E+03
1.12E+03
1.48E+03
1.08E+03
9.58E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.9E+01 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 2.1E+01 1.9E+00 6.0E+00 10 100
5.96E+02 4.7E+00 1.9E+00 6.0E+00
1.13E+03 4.0E+00 1.9E+00 6.0E+00
1.12E+03 1.8E+00 1.9E+00 6.0E+00
1.25E+03 7.8E+00 1.9E+00 6.0E+00
9.10E+02 3.3E+00 1.9E+00 6.0E+00
9.81 E+02 1.6E+01 1.9E+00 6.0E+00
9.50E-01 3.0E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 3.4E+02 1.9E+00 6.0E+00 10 100
4.51 E+02 4.9E+00 1.9E+00 6.0E+00
9.92E+02 2.7E+00 1.9E+00 6.0E+00
1.12E+03 2.0E+00 1.9E+00 6.0E+00
1.36E+03 4.9E+00 1.9E+00 6.0E+00
9.80E+02 1.2E+00 1.9E+00 6.0E+00
9.81 E+02 6.8E+00 1.9E+00 6.0E+00
9.50E-01 4.7E+01 1.9E+00 6.0E+00
9.50E-01 2.6E+02 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00 10 100
6.75E+02 1.9E+00 1.9E+00 6.0E+00
1.02E+03 1.9E+00 1.9E+00 6.0E+00
1.12E+03 5.1E+00 1.9E+00 6.0E+00
1.48E+03 2.7E+00 1.9E+00 6.0E+00
1.08E+03 4.5E+00 1.9E+00 6.0E+00
9.58E+02 3.9E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
8.68E+02 87% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
8.51E+02 85% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/1012:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
8.42E+02 84% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-655
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn SWA-LRef-1313-T01-D 1
Mn SWA-LRef-1313-T02-D 1
Mn SWA-LRef-1313-T03-D 1
Mn SWA-LRef-1313-T04-D 1
Mn SWA-LRef-1313-T05-D 1
Mn SWA-LRef-1313-T06-D 1
Mn SWA-LRef-1313-T07-D 1
Mn SWA-LRef-1313-T08-D 1
Mn SWA-LRef-1313-T09-D 1
Mn SWA-LRef-1313-T01-E 1
Mn SWA-LRef-1313-T02-E 1
Mn SWA-LRef-1313-T03-E 1
Mn SWA-LRef-1313-T04-E 1
Mn SWA-LRef-1313-T05-E 1
Mn SWA-LRef-1313-T06-E 1
Mn SWA-LRef-1313-T07-E 1
Mn SWA-LRef-1313-T08-E 1
Mn SWA-LRef-1313-T09-E 1
Mn SWA-LRef-1313-T01-F 1
Mn SWA-LRef-1313-T02-F 1
Mn SWA-LRef-1313-T03-F 1
Mn SWA-LRef-1313-T04-F 1
Mn SWA-LRef-1313-T05-F 1
Mn SWA-LRef-1313-T06-F 1
Mn SWA-LRef-1313-T07-F 1
Mn SWA-LRef-1313-T08-F 1
Mn SWA-LRef-1313-T09-F 1
Sample I
Cone. Qualifier
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
6.24E+01
5.52E+03
9.75E+03
2.39E+04
1.90E+04
2.06E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.53E+01
2.79E+03
9.68E+03
2.53E+04
1.98E+04
2.06E+04
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.22E+02
2.22E+03
1.10E+04
2.43E+04
2.06E+04
2.08E+04
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 8.1E+00 2.0E+00 6.4E+00
1.00E+00 8.6E+00 2.0E+00 6.4E+00 10 100
6.24E+01 1.0E+00 2.0E+00 6.4E+00
5.52E+03 5.8E-01 2.0E+00 6.4E+00
9.75E+03 3.9E-01 2.0E+00 6.4E+00
2.39E+04 1.4E-01 2.0E+00 6.4E+00
1.90E+04 1.5E+00 2.0E+00 6.4E+00
2.06E+04 5.4E-01 2.0E+00 6.4E+00
1.00E+00 8.3E+00 2.0E+00 6.4E+00
1.00E+00 9.4E-01 2.0E+00 6.4E+00
1.00E+00 7.9E+00 2.0E+00 6.4E+00 10 100
4.53E+01 4.9E+00 2.0E+00 6.4E+00
2.79E+03 3.7E-01 2.0E+00 6.4E+00
9.68E+03 1.5E+00 2.0E+00 6.4E+00
2.53E+04 4.3E-01 2.0E+00 6.4E+00
1.98E+04 1.1E+00 2.0E+00 6.4E+00
2.06E+04 3.9E-01 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+00 2.0E+00 6.4E+00
1.00E+00 3.2E+00 2.0E+00 6.4E+00 10 100
4.22E+02 1.7E-01 2.0E+00 6.4E+00
2.22E+03 6.3E-01 2.0E+00 6.4E+00
1.10E+04 5.8E-01 2.0E+00 6.4E+00
2.43E+04 4.1E-01 2.0E+00 6.4E+00
2.06E+04 8.1E-01 2.0E+00 6.4E+00
2.08E+04 1.0E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.05E+03 105% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
9.93E+02 99% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/1012:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
9.25E+02 92% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-656
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qu
1 1 ug/L
Mg SWA-LRef-1313-T01-D 1 1.11E+01
Mg SWA-LRef-1313-T02-D 1 2.13E+01
Mg SWA-LRef-1313-T03-D 1 5.39E+00
Mg SWA-LRef-1313-T04-D 1 5.22E+05
Mg SWA-LRef-1313-T05-D 1 1.12E+06
Mg SWA-LRef-1313-T06-D 1 1.17E+06
Mg SWA-LRef-1313-T07-D 1 1.31E+06
Mg SWA-LRef-1313-T08-D 1 9.09E+05
Mg SWA-LRef-1313-T09-D 1 8.29E+05
Mg SWA-LRef-1313-T01-E 1 5.07E+00
Mg SWA-LRef-1313-T02-E 1 8.11E+00
Mg SWA-LRef-1313-T03-E 1 8.88E+00
Mg SWA-LRef-1313-T04-E 1 2.84E+05
Mg SWA-LRef-1313-T05-E 1 9.54E+05
Mg SWA-LRef-1313-T06-E 1 1.13E+06
Mg SWA-LRef-1313-T07-E 1 1.47E+06
Mg SWA-LRef-1313-T08-E 1 9.62E+05
Mg SWA-LRef-1313-T09-E 1 8.28E+05
Mg SWA-LRef-1313-T01-F 1 1.72E+01
Mg SWA-LRef-1313-T02-F 1 1.46E+01
Mg SWA-LRef-1313-T03-F 1 1.90E+01
Mg SWA-LRef-1313-T04-F 1 6.16E+05
Mg SWA-LRef-1313-T05-F 1 9.42E+05
Mg SWA-LRef-1313-T06-F 1 1.11E+06
Mg SWA-LRef-1313-T07-F 1 1.52E+06
Mg SWA-LRef-1313-T08-F 1 1.02E+06
Mg SWA-LRef-1313-T09-F 1 8.33E+05
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.11E+01 1.0E+02 1.0E+00 3.2E+00
2.13E+01 1.9E+01 1.0E+00 3.2E+00
5.39E+00 9.3E+01 1.0E+00 3.2E+00 1000 100
5.22E+05 1.4E+00 1.0E+00 3.2E+00
1.12E+06 1.0E+00 1.0E+00 3.2E+00
1.17E+06 1.1E+00 1.0E+00 3.2E+00
1.31E+06 1.4E-01 1.0E+00 3.2E+00
9.09E+05 5.6E-01 1.0E+00 3.2E+00
8.29E+05 4.7E-01 1.0E+00 3.2E+00
5.07E+00 1.8E+02 1.0E+00 3.2E+00
8.11E+00 1.1E+02 1.0E+00 3.2E+00
8.88E+00 5.8E+01 1.0E+00 3.2E+00 1000 100
2.84E+05 4.1E-01 1.0E+00 3.2E+00
9.54E+05 7.5E-01 1.0E+00 3.2E+00
1.13E+06 1.2E+00 1.0E+00 3.2E+00
1.47E+06 3.4E-01 1.0E+00 3.2E+00
9.62E+05 8.2E-01 1.0E+00 3.2E+00
8.28E+05 1.7E+00 1.0E+00 3.2E+00
1.72E+01 4.2E+01 1.0E+00 3.2E+00
1.46E+01 2.1E+01 1.0E+00 3.2E+00
1.90E+01 5.0E+01 1.0E+00 3.2E+00 1000 100
6.16E+05 1.1E+00 1.0E+00 3.2E+00
9.42E+05 2.0E-01 1.0E+00 3.2E+00
1.11E+06 1.2E+00 1.0E+00 3.2E+00
1.52E+06 6.3E-01 1.0E+00 3.2E+00
1.02E+06 1.4E+00 1.0E+00 3.2E+00
8.33E+05 9.0E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1 .02E+03 102% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
9.80E+02 97% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
9.14E+02 89% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-657
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo SWA-LRef-1313-T01-D 1
Mo SWA-LRef-1313-T02-D 1
Mo SWA-LRef-1313-T03-D 1
Mo SWA-LRef-1313-T04-D 1
Mo SWA-LRef-1313-T05-D 1
Mo SWA-LRef-1313-T06-D 1
Mo SWA-LRef-1313-T07-D 1
Mo SWA-LRef-1313-T08-D 1
Mo SWA-LRef-1313-T09-D 1
Mo SWA-LRef-1313-T01-E 1
Mo SWA-LRef-1313-T02-E 1
Mo SWA-LRef-1313-T03-E 1
Mo SWA-LRef-1313-T04-E 1
Mo SWA-LRef-1313-T05-E 1
Mo SWA-LRef-1313-T06-E 1
Mo SWA-LRef-1313-T07-E 1
Mo SWA-LRef-1313-T08-E 1
Mo SWA-LRef-1313-T09-E 1
Mo SWA-LRef-1313-T01-F 1
Mo SWA-LRef-1313-T02-F 1
Mo SWA-LRef-1313-T03-F 1
Mo SWA-LRef-1313-T04-F 1
Mo SWA-LRef-1313-T05-F 1
Mo SWA-LRef-1313-T06-F 1
Mo SWA-LRef-1313-T07-F 1
Mo SWA-LRef-1313-T08-F 1
Mo SWA-LRef-1313-T09-F 1
Sample I
Cone. Qualifier
ug/L I
1.27E+02
1.44E+02
1.39E+02
1.33E+02
1.15E+02
1.05E+02
1.01E+01
1.74E+01
1.37E+01
1.39E+02
1.42E+02
1.42E+02
1.11E+02
1.06E+02
8.95E+01
9.76E+00
2.06E+01
1.66E+01
1.33E+02
1.35E+02
1.24E+02
1.00E+02
1.09E+02
7.58E+01
1.31E+01
2.14E+01
1.62E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+02 1.7E+00 1.2E+00 3.8E+00
1.44E+02 1.2E+00 1.2E+00 3.8E+00
1.39E+02 4.9E-01 1.2E+00 3.8E+00 10 100
1.33E+02 2.5E+00 1.2E+00 3.8E+00
1.15E+02 2.4E+00 1.2E+00 3.8E+00
1.05E+02 4.6E-01 1.2E+00 3.8E+00
1.01E+01 2.1E+01 1.2E+00 3.8E+00
1.74E+01 5.5E+00 1.2E+00 3.8E+00
1.37E+01 2.8E+00 1.2E+00 3.8E+00
1.39E+02 2.8E+00 1.2E+00 3.8E+00
1.42E+02 7.6E-01 1.2E+00 3.8E+00
1.42E+02 6.9E-01 1.2E+00 3.8E+00 10 100
1.11E+02 2.1E+00 1.2E+00 3.8E+00
1.06E+02 2.0E+00 1.2E+00 3.8E+00
8.95E+01 3.7E+00 1.2E+00 3.8E+00
9.76E+00 2.5E+01 1.2E+00 3.8E+00
2.06E+01 1.2E+01 1.2E+00 3.8E+00
1.66E+01 1.1E+01 1.2E+00 3.8E+00
1.33E+02 2.6E+00 1.2E+00 3.8E+00
1.35E+02 1.0E+00 1.2E+00 3.8E+00
1.24E+02 6.1E-02 1.2E+00 3.8E+00 10 100
1.00E+02 3.0E+00 1.2E+00 3.8E+00
1.09E+02 2.5E+00 1.2E+00 3.8E+00
7.58E+01 4.6E+00 1.2E+00 3.8E+00
1.31E+01 7.7E+00 1.2E+00 3.8E+00
2.14E+01 9.4E+00 1.2E+00 3.8E+00
1.62E+01 1.1E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1 .18E+03 104% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.10E+03 96% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
1.04E+03 92% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-658
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni SWA-LRef-1313-T01-D 1
Ni SWA-LRef-1313-T02-D 1
Ni SWA-LRef-1313-T03-D 1
Ni SWA-LRef-1313-T04-D 1
Ni SWA-LRef-1313-T05-D 1
Ni SWA-LRef-1313-T06-D 1
Ni SWA-LRef-1313-T07-D 1
Ni SWA-LRef-1313-T08-D 1
Ni SWA-LRef-1313-T09-D 1
Ni SWA-LRef-1313-T01-E 1
Ni SWA-LRef-1313-T02-E 1
Ni SWA-LRef-1313-T03-E 1
Ni SWA-LRef-1313-T04-E 1
Ni SWA-LRef-1313-T05-E 1
Ni SWA-LRef-1313-T06-E 1
Ni SWA-LRef-1313-T07-E 1
Ni SWA-LRef-1313-T08-E 1
Ni SWA-LRef-1313-T09-E 1
Ni SWA-LRef-1313-T01-F
Ni SWA-LRef-1313-T02-F
Ni SWA-LRef-1313-T03-F
Ni SWA-LRef-1313-T04-F
Ni SWA-LRef-1313-T05-F
Ni SWA-LRef-1313-T06-F
Ni SWA-LRef-1313-T07-F
Ni SWA-LRef-1313-T08-F
Ni SWA-LRef-1313-T09-F
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
3.67E+00 E
4.54E+01
1.05E+02
4.46E+02
3.77E+02
4.38E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
4.98E+00 E
2.64E+01
1.07E+02
4.44E+02
3.90E+02
4.33E+02
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
7.26E+00 U1/2
2.20E+01 U1/2
1.35E+02 U1/2
3.98E+02 U1/2
4.12E+02 U1/2
4.40E+02 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.8E+01 1.8E+00 5.7E+00
9.00E-01 9.0E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00 10 100
3.67E+00 8.1E+01 1.8E+00 5.7E+00
4.54E+01 2.5E+00 1.8E+00 5.7E+00
1.05E+02 3.1E+00 1.8E+00 5.7E+00
4.46E+02 3.7E-01 1.8E+00 5.7E+00
3.77E+02 9.5E-01 1.8E+00 5.7E+00
4.38E+02 2.8E+00 1.8E+00 5.7E+00
9.00E-01 7.4E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+03 1.8E+00 5.7E+00
9.00E-01 7.4E+01 1.8E+00 5.7E+00 10 100
4.98E+00 3.0E+01 1.8E+00 5.7E+00
2.64E+01 9.5E+00 1.8E+00 5.7E+00
1.07E+02 9.8E-01 1.8E+00 5.7E+00
4.44E+02 9.8E-01 1.8E+00 5.7E+00
3.90E+02 3.6E-01 1.8E+00 5.7E+00
4.33E+02 1.7E+00 1.8E+00 5.7E+00
O.OOE+00 4.2E+01 1.8E+00 5.7E+00
O.OOE+00 8.3E+01 1.8E+00 5.7E+00
O.OOE+00 7.0E+01 1.8E+00 5.7E+00 10 100
O.OOE+00 2.5E+01 1.8E+00 5.7E+00
O.OOE+00 1.5E+01 1.8E+00 5.7E+00
O.OOE+00 9.4E-01 1.8E+00 5.7E+00
O.OOE+00 9.7E-01 1.8E+00 5.7E+00
O.OOE+00 1.0E+00 1.8E+00 5.7E+00
O.OOE+00 9.4E-01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.02E+03 102% VU ICP-OES 11/19/102:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
9.83E+02 98% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/1012:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
9.25E+02 92% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-659
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone.
1 ug/L
P SWA-LRef-1313-T01-D 1 1.03E+02
P SWA-LRef-1313-T02-D 1 3.80E+01
P SWA-LRef-1313-T03-D 1 2.23E+01
P SWA-LRef-1313-T04-D 1 6.18E+01
P SWA-LRef-1313-T05-D 1 5.90E+01
P SWA-LRef-1313-T06-D 1 6.83E+01
P SWA-LRef-1313-T07-D 1 6.25E+01
P SWA-LRef-1313-T08-D 1 8.32E+02
P SWA-LRef-1313-T09-D 1 1.08E+04
P SWA-LRef-1313-T01-E 1 1.55E+02
P SWA-LRef-1313-T02-E 1 8.83E+01
P SWA-LRef-1313-T03-E 1 2.35E+01
P SWA-LRef-1313-T04-E 1 6.74E+01
P SWA-LRef-1313-T05-E 1 5.93E+01
P SWA-LRef-1313-T06-E 1 7.85E+01
P SWA-LRef-1313-T07-E 1 2.41 E+01
P SWA-LRef-1313-T08-E 1 8.23E+02
P SWA-LRef-1313-T09-E 1 1.16E+04
P SWA-LRef-1313-T01-F 1 1.36E+02
P SWA-LRef-1313-T02-F 1 3.62E+01
P SWA-LRef-1313-T03-F 1 2.16E+01
P SWA-LRef-1313-T04-F 1 7.15E+01
P SWA-LRef-1313-T05-F 1 6.24E+01
P SWA-LRef-1313-T06-F 1 7.33E+01
P SWA-LRef-1313-T07-F 1 1.81 E+01
P SWA-LRef-1313-T08-F 1 8.01 E+02
P SWA-LRef-1313-T09-F 1 1.09E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.03E+02 5.1E+00 3.7E+00 1.2E+01
3.80E+01 1.6E+01 3.7E+00 1 .2E+01
2.23E+01 5.3E+01 3.7E+00 1 .2E+01 1000 100
6.18E+01 1.5E+01 3.7E+00 1 .2E+01
5.90E+01 3.0E+01 3.7E+00 1 .2E+01
6.83E+01 3.0E+01 3.7E+00 1 .2E+01
6.25E+01 3.4E+01 3.7E+00 1.2E+01
8.32E+02 1.6E+00 3.7E+00 1.2E+01
1.08E+04 5.7E-01 3.7E+00 1.2E+01
1.55E+02 5.8E+00 3.7E+00 1.2E+01
8.83E+01 1.4E+01 3.7E+00 1.2E+01
2.35E+01 3.4E+01 3.7E+00 1.2E+01 1000 100
6.74E+01 4.6E+01 3.7E+00 1.2E+01
5.93E+01 3.1 E+01 3.7E+00 1.2E+01
7.85E+01 1.4E+01 3.7E+00 1.2E+01
2.41 E+01 9.2E+01 3.7E+00 1.2E+01
8.23E+02 2.8E+00 3.7E+00 1.2E+01
1.16E+04 2.6E+00 3.7E+00 1.2E+01
1.36E+02 4.7E+00 3.7E+00 1.2E+01
3.62E+01 4.0E+01 3.7E+00 1.2E+01
2.16E+01 5.3E+01 3.7E+00 1.2E+01 1000 100
7.15E+01 8.3E+00 3.7E+00 1.2E+01
6.24E+01 1.4E+01 3.7E+00 1.2E+01
7.33E+01 1.9E+01 3.7E+00 1.2E+01
1.81 E+01 6.0E+01 3.7E+00 1.2E+01
8.01 E+02 2.2E+00 3.7E+00 1.2E+01
1.09E+04 2.7E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1 .03E+03 101% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
9.90E+02 97% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
1.03E+03 101% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-660
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K SWA-LRef-1313-T01-D 1
K SWA-LRef-1313-T02-D 1
K SWA-LRef-1313-T03-D 1
K SWA-LRef-1313-T04-D 1
K SWA-LRef-1313-T05-D 1
K SWA-LRef-1313-T06-D 1
K SWA-LRef-1313-T07-D 1
K SWA-LRef-1313-T08-D 1
K SWA-LRef-1313-T09-D 1
K SWA-LRef-1313-T01-E 1
K SWA-LRef-1313-T02-E 1
K SWA-LRef-1313-T03-E 1
K SWA-LRef-1313-T04-E 1
K SWA-LRef-1313-T05-E 1
K SWA-LRef-1313-T06-E 1
K SWA-LRef-1313-T07-E 1
K SWA-LRef-1313-T08-E 1
K SWA-LRef-1313-T09-E 1
K SWA-LRef-1313-T01-F 1
K SWA-LRef-1313-T02-F 1
K SWA-LRef-1313-T03-F 1
K SWA-LRef-1313-T04-F 1
K SWA-LRef-1313-T05-F 1
K SWA-LRef-1313-T06-F 1
K SWA-LRef-1313-T07-F 1
K SWA-LRef-1313-T08-F 1
K SWA-LRef-1313-T09-F 1
Sample I
Cone. Qualifier
ug/L I
2.27E+06
2.95E+05
2.84E+05
4.17E+05
4.46E+05
4.35E+05
4.06E+05
2.95E+05
3.49E+05
2.28E+06
2.84E+05
2.98E+05
4.17E+05
4.38E+05
4.48E+05
4.58E+05
3.20E+05
3.37E+05
2.28E+06
2.83E+05
2.92E+05
4.15E+05
4.38E+05
4.48E+05
4.70E+05
3.12E+05
3.27E+05
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.27E+06 4.6E-01 1.6E+00 5.1E+00
2.95E+05 4.5E-01 1.6E+00 5.1E+00
2.84E+05 4.2E-01 1.6E+00 5.1E+00 1000 100
4.17E+05 2.5E+00 1.6E+00 5.1E+00
4.46E+05 2.9E+00 1.6E+00 5.1E+00
4.35E+05 5.7E-01 1.6E+00 5.1E+00
4.06E+05 8.8E-01 1.6E+00 5.1E+00
2.95E+05 4.3E+00 1.6E+00 5.1E+00
3.49E+05 5.3E-01 1.6E+00 5.1E+00
2.28E+06 3.6E-01 1.6E+00 5.1E+00
2.84E+05 1.6E+00 1.6E+00 5.1E+00
2.98E+05 6.6E-01 1.6E+00 5.1E+00 1000 100
4.17E+05 7.9E-01 1.6E+00 5.1E+00
4.38E+05 4.4E-01 1.6E+00 5.1E+00
4.48E+05 4.9E-01 1.6E+00 5.1E+00
4.58E+05 9.4E-01 1.6E+00 5.1E+00
3.20E+05 6.4E+00 1.6E+00 5.1E+00
3.37E+05 5.4E-01 1.6E+00 5.1E+00
2.28E+06 7.1E-01 1.6E+00 5.1E+00
2.83E+05 5.5E-01 1.6E+00 5.1E+00
2.92E+05 8.2E-01 1.6E+00 5.1E+00 1000 100
4.15E+05 5.8E-01 1.6E+00 5.1E+00
4.38E+05 5.0E-01 1.6E+00 5.1E+00
4.48E+05 4.7E-01 1.6E+00 5.1E+00
4.70E+05 1.0E+00 1.6E+00 5.1E+00
3.12E+05 2.5E+00 1.6E+00 5.1E+00
3.27E+05 6.2E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
2.85E+05 90% VUICP-OES 1 1/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
2.99E+05 86% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
2.93E+05 82% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-661
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
1 ug/L
Se SWA-LRef-1313-T01-D 1 8.20E+04
Se SWA-LRef-1313-T02-D 1 9.69E+04
Se SWA-LRef-1313-T03-D 1 9.97E+04
Se SWA-LRef-1313-T04-D 1 1.13E+05
Se SWA-LRef-1313-T05-D 1 1.27E+05
Se SWA-LRef-1313-T06-D 1 1.24E+05
Se SWA-LRef-1313-T07-D 1 1.02E+05
Se SWA-LRef-1313-T08-D 1 6.05E+04
Se SWA-LRef-1313-T09-D 1 3.99E+04
Se SWA-LRef-1313-T01-E 1 1.04E+05
Se SWA-LRef-1313-T02-E 1 1.04E+05
Se SWA-LRef-1313-T03-E 1 1.04E+05
Se SWA-LRef-1313-T04-E 1 1.07E+05
Se SWA-LRef-1313-T05-E 1 1.19E+05
Se SWA-LRef-1313-T06-E 1 1.22E+05
Se SWA-LRef-1313-T07-E 1 1.18E+05
Se SWA-LRef-1313-T08-E 1 6.52E+04
Se SWA-LRef-1313-T09-E 1 4.04E+04
Se SWA-LRef-1313-T01-F 1 9.87E+04
Se SWA-LRef-1313-T02-F 1 9.33E+04
Se SWA-LRef-1313-T03-F 1 9.50E+04
Se SWA-LRef-1313-T04-F 1 1.09E+05
Se SWA-LRef-1313-T05-F 1 1.21E+05
Se SWA-LRef-1313-T06-F 1 1.18E+05
Se SWA-LRef-1313-T07-F 1 1.27E+05
Se SWA-LRef-1313-T08-F 1 6.96E+04
Se SWA-LRef-1313-T09-F 1 4.06E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
8.20E+04 3.4E-01 1.5E+01 4.8E+01
9.69E+04 2.0E-01 1.5E+01 4.8E+01
9.97E+04 1.4E-01 1.5E+01 4.8E+01 10 100
1.13E+05 1.3E+00 1.5E+01 4.8E+01
1.27E+05 5.5E-01 1.5E+01 4.8E+01
1.24E+05 2.7E-01 1.5E+01 4.8E+01
1.02E+05 5.7E-01 1.5E+01 4.8E+01
6.05E+04 3.0E-01 1.5E+01 4.8E+01
3.99E+04 8.3E-01 1.5E+01 4.8E+01
1.04E+05 9.3E-01 1.5E+01 4.8E+01
1.04E+05 1.3E+00 1.5E+01 4.8E+01
1.04E+05 5.1E-01 1.5E+01 4.8E+01 10 100
1.07E+05 6.5E-01 1.5E+01 4.8E+01
1.19E+05 7.7E-01 1.5E+01 4.8E+01
1.22E+05 7.9E-01 1.5E+01 4.8E+01
1.18E+05 2.6E-01 1.5E+01 4.8E+01
6.52E+04 5.1E-01 1.5E+01 4.8E+01
4.04E+04 6.9E-01 1.5E+01 4.8E+01
9.87E+04 6.2E-01 1.5E+01 4.8E+01
9.33E+04 2.3E-01 1.5E+01 4.8E+01
9.50E+04 3.3E-01 1.5E+01 4.8E+01 10 100
1.09E+05 5.1E-01 1.5E+01 4.8E+01
1.21E+05 4.1E-01 1.5E+01 4.8E+01
1.18E+05 2.2E-01 1.5E+01 4.8E+01
1.27E+05 6.1E-01 1.5E+01 4.8E+01
6.96E+04 2.4E-01 1.5E+01 4.8E+01
4.06E+04 8.8E-01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.01E+05 99% VUICP-OES 1 1/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.05E+05 91% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
9.59E+04 87% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-662
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-LRef-1313-T01-D 1
Si SWA-LRef-1313-T02-D 1
Si SWA-LRef-1313-T03-D 1
Si SWA-LRef-1313-T04-D 1
Si SWA-LRef-1313-T05-D 1
Si SWA-LRef-1313-T06-D 1
Si SWA-LRef-1313-T07-D 1
Si SWA-LRef-1313-T08-D 1
Si SWA-LRef-1313-T09-D 1
Si SWA-LRef-1313-T01-E 1
Si SWA-LRef-1313-T02-E 1
Si SWA-LRef-1313-T03-E 1
Si SWA-LRef-1313-T04-E 1
Si SWA-LRef-1313-T05-E 1
Si SWA-LRef-1313-T06-E 1
Si SWA-LRef-1313-T07-E 1
Si SWA-LRef-1313-T08-E 1
Si SWA-LRef-1313-T09-E 1
Si SWA-LRef-1313-T01-F 1
Si SWA-LRef-1313-T02-F 1
Si SWA-LRef-1313-T03-F 1
Si SWA-LRef-1313-T04-F 1
Si SWA-LRef-1313-T05-F 1
Si SWA-LRef-1313-T06-F 1
Si SWA-LRef-1313-T07-F 1
Si SWA-LRef-1313-T08-F 1
Si SWA-LRef-1313-T09-F 1
Sample I
Cone. Qualifier
ug/L I
7.09E+03
5.68E+03
5.04E+03
9.69E+02
1.30E+03
1.74E+03
2.82E+03
1.45E+04
1.24E+04
7.83E+03
5.68E+03
4.83E+03
1.09E+03
1.01E+03
1.59E+03
2.34E+03
1.68E+04
1.53E+04
3.95E+03
5.46E+03
4.74E+03
1.04E+03
1.13E+03
1.65E+03
2.22E+03
1.65E+04
1.28E+04
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.09E+03 3.8E-01 1.1E+00 3.5E+00
5.68E+03 3.1E-01 1.1E+00 3.5E+00
5.04E+03 6.7E-01 1.1E+00 3.5E+00 1000 100
9.69E+02 8.4E-01 1.1E+00 3.5E+00
1.30E+03 4.2E-01 1.1E+00 3.5E+00
1.74E+03 4.0E-01 1.1E+00 3.5E+00
2.82E+03 5.6E-01 1.1E+00 3.5E+00
1.45E+04 8.3E-01 1.1E+00 3.5E+00
1.24E+04 1.7E+00 1.1E+00 3.5E+00
7.83E+03 9.6E-01 1.1E+00 3.5E+00
5.68E+03 1.3E+00 1.1E+00 3.5E+00
4.83E+03 1.2E+00 1.1E+00 3.5E+00 1000 100
1.09E+03 5.4E-01 1.1E+00 3.5E+00
1.01E+03 4.2E-01 1.1E+00 3.5E+00
1.59E+03 9.1E-01 1.1E+00 3.5E+00
2.34E+03 2.6E-01 1.1E+00 3.5E+00
1.68E+04 7.8E-01 1.1E+00 3.5E+00
1.53E+04 4.5E+00 1.1E+00 3.5E+00
3.95E+03 5.3E-01 1.1E+00 3.5E+00
5.46E+03 1.1E-01 1.1E+00 3.5E+00
4.74E+03 3.2E-01 1.1E+00 3.5E+00 1000 100
1.04E+03 4.2E-01 1.1E+00 3.5E+00
1.13E+03 5.1E-01 1.1E+00 3.5E+00
1.65E+03 2.6E-01 1.1E+00 3.5E+00
2.22E+03 4.0E-01 1.1E+00 3.5E+00
1.65E+04 1.2E-01 1.1E+00 3.5E+00
1.28E+04 1.8E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
6.09E+03 106% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
5.81E+03 99% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
5.70E+03 96% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-663
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na SWA-LRef-1313-T01-D 1
Na SWA-LRef-1313-T02-D 1
Na SWA-LRef-1313-T03-D 1
Na SWA-LRef-1313-T04-D 1
Na SWA-LRef-1313-T05-D 1
Na SWA-LRef-1313-T06-D 1
Na SWA-LRef-1313-T07-D 1
Na SWA-LRef-1313-T08-D 1
Na SWA-LRef-1313-T09-D 1
Na SWA-LRef-1313-T01-E 1
Na SWA-LRef-1313-T02-E 1
Na SWA-LRef-1313-T03-E 1
Na SWA-LRef-1313-T04-E 1
Na SWA-LRef-1313-T05-E 1
Na SWA-LRef-1313-T06-E 1
Na SWA-LRef-1313-T07-E 1
Na SWA-LRef-1313-T08-E 1
Na SWA-LRef-1313-T09-E 1
Na SWA-LRef-1313-T01-F 1
Na SWA-LRef-1313-T02-F 1
Na SWA-LRef-1313-T03-F 1
Na SWA-LRef-1313-T04-F 1
Na SWA-LRef-1313-T05-F 1
Na SWA-LRef-1313-T06-F 1
Na SWA-LRef-1313-T07-F 1
Na SWA-LRef-1313-T08-F 1
Na SWA-LRef-1313-T09-F 1
Sample I
Cone. Qualifier
ug/L I
4.61 E+05
4.52E+05
4.40E+05
5.46E+05
5.67E+05
5.63E+05
4.80E+05
2.77E+05
1.87E+05
4.43E+05
4.29E+05
4.49E+05
5.31 E+05
5.54E+05
5.53E+05
5.32E+05
2.88E+05
1.86E+05
4.38E+05
4.19E+05
4.30E+05
5.31 E+05
5.42E+05
5.39E+05
5.43E+05
2.98E+05
1.86E+05
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.61 E+05 3.8E-01 2.5E+00 8.0E+00
4.52E+05 3.8E-01 2.5E+00 8.0E+00
4.40E+05 1.7E-01 2.5E+00 8.0E+00 1000 100
5.46E+05 7.7E-01 2.5E+00 8.0E+00
5.67E+05 6.2E-01 2.5E+00 8.0E+00
5.63E+05 7.1E-01 2.5E+00 8.0E+00
4.80E+05 1.4E-01 2.5E+00 8.0E+00
2.77E+05 1.0E+00 2.5E+00 8.0E+00
1.87E+05 1.0E-01 2.5E+00 8.0E+00
4.43E+05 5.6E-01 2.5E+00 8.0E+00
4.29E+05 1.3E+00 2.5E+00 8.0E+00
4.49E+05 6.3E-01 2.5E+00 8.0E+00 1000 100
5.31 E+05 2.3E-01 2.5E+00 8.0E+00
5.54E+05 6.6E-01 2.5E+00 8.0E+00
5.53E+05 5.5E-01 2.5E+00 8.0E+00
5.32E+05 9.5E-01 2.5E+00 8.0E+00
2.88E+05 6.1E-01 2.5E+00 8.0E+00
1.86E+05 8.9E-01 2.5E+00 8.0E+00
4.38E+05 1.0E+00 2.5E+00 8.0E+00
4.19E+05 4.4E-02 2.5E+00 8.0E+00
4.30E+05 1.6E-01 2.5E+00 8.0E+00 1000 100
5.31 E+05 6.7E-01 2.5E+00 8.0E+00
5.42E+05 8.0E-01 2.5E+00 8.0E+00
5.39E+05 5.8E-01 2.5E+00 8.0E+00
5.43E+05 1.4E-01 2.5E+00 8.0E+00
2.98E+05 1.1E+00 2.5E+00 8.0E+00
1.86E+05 2.4E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
4.41E+05 91% VUICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
4.50E+05 87% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
4.31E+05 86% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-664
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
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Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-LRef-1313-T01-D 1
SWA-LRef-1313-T02-D 1
SWA-LRef-1313-T03-D 1
SWA-LRef-1313-T04-D 1
SWA-LRef-1313-T05-D 1
SWA-LRef-1313-T06-D 1
SWA-LRef-1313-T07-D 1
SWA-LRef-1313-T08-D 1
SWA-LRef-1313-T09-D 1
SWA-LRef-1313-T01-E 1
SWA-LRef-1313-T02-E 1
SWA-LRef-1313-T03-E 1
SWA-LRef-1313-T04-E 1
SWA-LRef-1313-T05-E 1
SWA-LRef-1313-T06-E 1
SWA-LRef-1313-T07-E 1
SWA-LRef-1313-T08-E 1
SWA-LRef-1313-T09-E 1
SWA-LRef-1313-T01-F 1
SWA-LRef-1313-T02-F 1
SWA-LRef-1313-T03-F 1
SWA-LRef-1313-T04-F 1
SWA-LRef-1313-T05-F 1
SWA-LRef-1313-T06-F 1
SWA-LRef-1313-T07-F 1
SWA-LRef-1313-T08-F 1
SWA-LRef-1313-T09-F 1
Sample I
Cone. Qualifier
ug/L I
3.46E+02
3.64E+02
5.48E+02
2.85E+04
4.11E+04
4.03E+04
4.55E+04
3.19E+04
2.29E+04
3.30E+02
3.27E+02
5.20E+02
2.58E+04
3.70E+04
4.08E+04
5.11E+04
3.32E+04
2.28E+04
1.58E+02
3.43E+02
5.40E+02
2.92E+04
3.73E+04
4.13E+04
5.26E+04
3.50E+04
2.54E+04
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.46E+02 5.5E-01 1.0E+00 3.2E+00
3.64E+02 3.4E-01 1.0E+00 3.2E+00
5.48E+02 1.4E+00 1.0E+00 3.2E+00 1000 100
2.85E+04 1.7E-01 1.0E+00 3.2E+00
4.11E+04 1.9E-01 1.0E+00 3.2E+00
4.03E+04 5.3E-01 1.0E+00 3.2E+00
4.55E+04 1.2E+00 1.0E+00 3.2E+00
3.19E+04 9.0E-01 1.0E+00 3.2E+00
2.29E+04 2.1E-01 1.0E+00 3.2E+00
3.30E+02 1.1E+00 1.0E+00 3.2E+00
3.27E+02 3.3E-01 1.0E+00 3.2E+00
5.20E+02 4.9E-01 1.0E+00 3.2E+00 1000 100
2.58E+04 4.5E-01 1.0E+00 3.2E+00
3.70E+04 7.0E-01 1.0E+00 3.2E+00
4.08E+04 1.3E+00 1.0E+00 3.2E+00
5.11E+04 5.6E-01 1.0E+00 3.2E+00
3.32E+04 7.4E-01 1.0E+00 3.2E+00
2.28E+04 1.3E+00 1.0E+00 3.2E+00
1.58E+02 1.0E+00 1.0E+00 3.2E+00
3.43E+02 3.2E-01 1.0E+00 3.2E+00
5.40E+02 1.0E+00 1.0E+00 3.2E+00 1000 100
2.92E+04 5.1E-01 1.0E+00 3.2E+00
3.73E+04 9.5E-01 1.0E+00 3.2E+00
4.13E+04 4.6E-01 1.0E+00 3.2E+00
5.26E+04 1.2E+00 1.0E+00 3.2E+00
3.50E+04 8.5E-01 1.0E+00 3.2E+00
2.54E+04 9.1E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1 .59E+03 105% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.49E+03 97% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
1.46E+03 92% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-665
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qu
1 1 ug/L
S SWA-LRef-1313-T01-D 1 3.91E+05
S SWA-LRef-1313-T02-D 1 6.22E+05
S SWA-LRef-1313-T03-D 1 5.16E+05
S SWA-LRef-1313-T04-D 1 7.92E+05
S SWA-LRef-1313-T05-D 1 8.76E+05
S SWA-LRef-1313-T06-D 1 7.85E+05
S SWA-LRef-1313-T07-D 1 4.11E+05
S SWA-LRef-1313-T08-D 1 2.44E+05
S SWA-LRef-1313-T09-D 1 1.85E+05
S SWA-LRef-1313-T01-E 1 4.59E+05
S SWA-LRef-1313-T02-E 1 4.18E+05
S SWA-LRef-1313-T03-E 1 3.95E+05
S SWA-LRef-1313-T04-E 1 7.14E+05
S SWA-LRef-1313-T05-E 1 7.23E+05
S SWA-LRef-1313-T06-E 1 6.59E+05
S SWA-LRef-1313-T07-E 1 4.38E+05
S SWA-LRef-1313-T08-E 1 2.55E+05
S SWA-LRef-1313-T09-E 1 1.86E+05
S SWA-LRef-1313-T01-F 1 4.05E+05
S SWA-LRef-1313-T02-F 1 3.50E+05
S SWA-LRef-1313-T03-F 1 3.34E+05
S SWA-LRef-1313-T04-F 1 7.03E+05
S SWA-LRef-1313-T05-F 1 7.10E+05
S SWA-LRef-1313-T06-F 1 6.72E+05
S SWA-LRef-1313-T07-F 1 4.73E+05
S SWA-LRef-1313-T08-F 1 2.73E+05
S SWA-LRef-1313-T09-F 1 1.78E+05
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.91 E+05 4.2E-01 6.8E+00 2.2E+01
6.22E+05 2.6E-01 6.8E+00 2.2E+01
5.16E+05 2.0E-01 6.8E+00 2.2E+01 1000 100
7.92E+05 9.3E-01 6.8E+00 2.2E+01
8.76E+05 3.8E-01 6.8E+00 2.2E+01
7.85E+05 6.8E-01 6.8E+00 2.2E+01
4.11 E+05 2.2E-01 6.8E+00 2.2E+01
2.44E+05 7.2E-01 6.8E+00 2.2E+01
1.85E+05 3.2E-01 6.8E+00 2.2E+01
4.59E+05 6.8E-01 6.8E+00 2.2E+01
4.18E+05 1.3E+00 6.8E+00 2.2E+01
3.95E+05 5.4E-01 6.8E+00 2.2E+01 1000 100
7.14E+05 6.0E-01 6.8E+00 2.2E+01
7.23E+05 7.0E-01 6.8E+00 2.2E+01
6.59E+05 1.1E+00 6.8E+00 2.2E+01
4.38E+05 3.8E-01 6.8E+00 2.2E+01
2.55E+05 2.7E-01 6.8E+00 2.2E+01
1.86E+05 5.3E-01 6.8E+00 2.2E+01
4.05E+05 5.3E-01 6.8E+00 2.2E+01
3.50E+05 2.9E-01 6.8E+00 2.2E+01
3.34E+05 1.5E-01 6.8E+00 2.2E+01 1000 100
7.03E+05 4.3E-01 6.8E+00 2.2E+01
7.10E+05 4.1E-01 6.8E+00 2.2E+01
6.72E+05 1.9E-01 6.8E+00 2.2E+01
4.73E+05 3.6E-01 6.8E+00 2.2E+01
2.73E+05 3.4E-01 6.8E+00 2.2E+01
1.78E+05 1.4E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
5.17E+05 96% VUICP-OES 1 1/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
3.96E+05 90% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
3.35E+05 87% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-666
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl SWA-LRef-1313-T01-D 1
Tl SWA-LRef-1313-T02-D 1
Tl SWA-LRef-1313-T03-D 1
Tl SWA-LRef-1313-T04-D 1
Tl SWA-LRef-1313-T05-D 1
Tl SWA-LRef-1313-T06-D 1
Tl SWA-LRef-1313-T07-D 1
Tl SWA-LRef-1313-T08-D 1
Tl SWA-LRef-1313-T09-D 1
Tl SWA-LRef-1313-T01-E 1
Tl SWA-LRef-1313-T02-E 1
Tl SWA-LRef-1313-T03-E 1
Tl SWA-LRef-1313-T04-E 1
Tl SWA-LRef-1313-T05-E 1
Tl SWA-LRef-1313-T06-E 1
Tl SWA-LRef-1313-T07-E 1
Tl SWA-LRef-1313-T08-E 1
Tl SWA-LRef-1313-T09-E 1
Tl SWA-LRef-1313-T01-F 1
Tl SWA-LRef-1313-T02-F 1
Tl SWA-LRef-1313-T03-F 1
Tl SWA-LRef-1313-T04-F 1
Tl SWA-LRef-1313-T05-F 1
Tl SWA-LRef-1313-T06-F 1
Tl SWA-LRef-1313-T07-F 1
Tl SWA-LRef-1313-T08-F 1
Tl SWA-LRef-1313-T09-F 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
8.47E+00 E
2.14E+01
1.37E+01 E
1.44E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
7.34E+00 E
2.68E+01
1.10E+01 E
1.30E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
1.06E+01 E
2.62E+01
1.04E+01 E
1.24E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 4.0E+01 4.6E+00 1.5E+01
2.30E+00 3.3E+01 4.6E+00 1.5E+01
2.30E+00 8.8E+01 4.6E+00 1.5E+01 10 100
2.30E+00 3.3E+01 4.6E+00 1.5E+01
2.30E+00 2.7E+02 4.6E+00 1.5E+01
8.47E+00 4.4E+01 4.6E+00 1 .5E+01
2.14E+01 1.1E+01 4.6E+00 1 .5E+01
1.37E+01 5.3E+01 4.6E+00 1 .5E+01
1.44E+01 1.8E+01 4.6E+00 1 .5E+01
2.30E+00 1.1E+02 4.6E+00 1 .5E+01
2.30E+00 8.3E+01 4.6E+00 1 .5E+01
2.30E+00 9.1E+01 4.6E+00 1 .5E+01 10 100
2.30E+00 2.3E+02 4.6E+00 1 .5E+01
2.30E+00 3.2E+02 4.6E+00 1 .5E+01
7.34E+00 4.5E+02 4.6E+00 1.5E+01
2.68E+01 5.8E+01 4.6E+00 1.5E+01
1.10E+01 4.6E+01 4.6E+00 1.5E+01
1.30E+01 7.2E+01 4.6E+00 1.5E+01
2.30E+00 8.1E+01 4.6E+00 1.5E+01
2.30E+00 4.7E+01 4.6E+00 1.5E+01
2.30E+00 2.1E+02 4.6E+00 1.5E+01 10 100
2.30E+00 5.0E+02 4.6E+00 1.5E+01
2.30E+00 2.1E+02 4.6E+00 1.5E+01
1.06E+01 7.9E+01 4.6E+00 1.5E+01
2.62E+01 1.4E+01 4.6E+00 1.5E+01
1.04E+01 4.9E+01 4.6E+00 1.5E+01
1.24E+01 8.1E+00 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
9.59E+02 96% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/19/10 2:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
9.32E+02 93% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
8.86E+02 88% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-667
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti SWA-LRef-1313-T01-D 1
Ti SWA-LRef-1313-T02-D 1
Ti SWA-LRef-1313-T03-D 1
Ti SWA-LRef-1313-T04-D 1
Ti SWA-LRef-1313-T05-D 1
Ti SWA-LRef-1313-T06-D 1
Ti SWA-LRef-1313-T07-D 1
Ti SWA-LRef-1313-T08-D 1
Ti SWA-LRef-1313-T09-D 1
Ti SWA-LRef-1313-T01-E 1
Ti SWA-LRef-1313-T02-E 1
Ti SWA-LRef-1313-T03-E 1
Ti SWA-LRef-1313-T04-E 1
Ti SWA-LRef-1313-T05-E 1
Ti SWA-LRef-1313-T06-E 1
Ti SWA-LRef-1313-T07-E 1
Ti SWA-LRef-1313-T08-E 1
Ti SWA-LRef-1313-T09-E 1
Ti SWA-LRef-1313-T01-F 1
Ti SWA-LRef-1313-T02-F 1
Ti SWA-LRef-1313-T03-F 1
Ti SWA-LRef-1313-T04-F 1
Ti SWA-LRef-1313-T05-F 1
Ti SWA-LRef-1313-T06-F 1
Ti SWA-LRef-1313-T07-F 1
Ti SWA-LRef-1313-T08-F 1
Ti SWA-LRef-1313-T09-F 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.93E+01
6.84E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.51E+01
6.72E+03
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.54E+01
7.24E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.9E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+02 2.0E+00 6.4E+00 10 100
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 9.2E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
3.93E+01 2.8E+00 2.0E+00 6.4E+00
6.84E+03 5.0E-01 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+03 2.0E+00 6.4E+00 10 100
1.00E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+02 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 9.7E+02 2.0E+00 6.4E+00
4.51 E+01 3.1E+00 2.0E+00 6.4E+00
6.72E+03 3.4E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+02 2.0E+00 6.4E+00
1.00E+00 5.1 E+01 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00 10 100
1.00E+00 6.1E-01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 7.1 E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
4.54E+01 4.2E+00 2.0E+00 6.4E+00
7.24E+03 3.0E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.03E+03 103% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
9.20E+02 92% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/1012:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
8.80E+02 88% VU ICP-OES 11/22/10 12:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 1 1/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-668
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
V SWA-LRef-1313-T01-D 1 3.81E+02
V SWA-LRef-1313-T02-D 1 3.68E+02
V SWA-LRef-1313-T03-D 1 2.40E+02
V SWA-LRef-1313-T04-D 1 2.29E+02
V SWA-LRef-1313-T05-D 1 2.25E+02
V SWA-LRef-1313-T06-D 1 2.14E+02
V SWA-LRef-1313-T07-D 1 1.73E+02
V SWA-LRef-1313-T08-D 1 1.24E+02
V SWA-LRef-1313-T09-D 1 1.06E+03
V SWA-LRef-1313-T01-E 1 4.36E+02
V SWA-LRef-1313-T02-E 1 3.49E+02
V SWA-LRef-1313-T03-E 1 2.87E+02
V SWA-LRef-1313-T04-E 1 1.85E+02
V SWA-LRef-1313-T05-E 1 2.09E+02
V SWA-LRef-1313-T06-E 1 2.07E+02
V SWA-LRef-1313-T07-E 1 1.94E+02
V SWA-LRef-1313-T08-E 1 1.25E+02
V SWA-LRef-1313-T09-E 1 1.11E+03
V SWA-LRef-1313-T01-F 1 4.08E+02
V SWA-LRef-1313-T02-F 1 3.20E+02
V SWA-LRef-1313-T03-F 1 2.44E+02
V SWA-LRef-1313-T04-F 1 2.16E+02
V SWA-LRef-1313-T05-F 1 2.19E+02
V SWA-LRef-1313-T06-F 1 2.01 E+02
V SWA-LRef-1313-T07-F 1 1.99E+02
V SWA-LRef-1313-T08-F 1 1.28E+02
V SWA-LRef-1313-T09-F 1 1.23E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.81 E+02 6.8E-01 1.5E+00 4.8E+00
3.68E+02 4.5E-01 1.5E+00 4.8E+00
2.40E+02 6.1E-01 1.5E+00 4.8E+00 10 100
2.29E+02 4.5E-01 1.5E+00 4.8E+00
2.25E+02 1.4E+00 1.5E+00 4.8E+00
2.14E+02 1.4E+00 1.5E+00 4.8E+00
1.73E+02 1.4E+00 1.5E+00 4.8E+00
1.24E+02 1.5E+00 1.5E+00 4.8E+00
1.06E+03 6.0E-01 1.5E+00 4.8E+00
4.36E+02 5.4E-01 1.5E+00 4.8E+00
3.49E+02 1.5E+00 1.5E+00 4.8E+00
2.87E+02 7.1E-01 1.5E+00 4.8E+00 10 100
1.85E+02 1.3E+00 1.5E+00 4.8E+00
2.09E+02 1.2E+00 1.5E+00 4.8E+00
2.07E+02 1.6E+00 1.5E+00 4.8E+00
1.94E+02 2.4E+00 1.5E+00 4.8E+00
1.25E+02 2.1E+00 1.5E+00 4.8E+00
1.11E+03 5.8E-01 1.5E+00 4.8E+00
4.08E+02 1.2E+00 1.5E+00 4.8E+00
3.20E+02 1.0E+00 1.5E+00 4.8E+00
2.44E+02 2.5E-01 1.5E+00 4.8E+00 10 100
2.16E+02 4.1E-01 1.5E+00 4.8E+00
2.19E+02 7.1E-01 1.5E+00 4.8E+00
2.01 E+02 1.5E+00 1.5E+00 4.8E+00
1.99E+02 1.5E+00 1.5E+00 4.8E+00
1.28E+02 3.1E+00 1.5E+00 4.8E+00
1.23E+03 9.8E-01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1 .30E+03 106% VU ICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.28E+03 99% VU ICP-OES 11/22/10 12:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
1.19E+03 94% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-669
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-LRef-1313-T01-D 1
Zn SWA-LRef-1313-T02-D 1
Zn SWA-LRef-1313-T03-D 1
Zn SWA-LRef-1313-T04-D 1
Zn SWA-LRef-1313-T05-D 1
Zn SWA-LRef-1313-T06-D 1
Zn SWA-LRef-1313-T07-D 1
Zn SWA-LRef-1313-T08-D 1
Zn SWA-LRef-1313-T09-D 1
Zn SWA-LRef-1313-T01-E 1
Zn SWA-LRef-1313-T02-E 1
Zn SWA-LRef-1313-T03-E 1
Zn SWA-LRef-1313-T04-E 1
Zn SWA-LRef-1313-T05-E 1
Zn SWA-LRef-1313-T06-E 1
Zn SWA-LRef-1313-T07-E 1
Zn SWA-LRef-1313-T08-E 1
Zn SWA-LRef-1313-T09-E 1
Zn SWA-LRef-1313-T01-F 1
Zn SWA-LRef-1313-T02-F 1
Zn SWA-LRef-1313-T03-F 1
Zn SWA-LRef-1313-T04-F 1
Zn SWA-LRef-1313-T05-F 1
Zn SWA-LRef-1313-T06-F 1
Zn SWA-LRef-1313-T07-F 1
Zn SWA-LRef-1313-T08-F 1
Zn SWA-LRef-1313-T09-F 1
Sample Internal
Cone. Qualifier Review
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
1.86E+00 E
1.15E+00 E
1.03E+03
1.42E+03
2.20E+03
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
1.51E+00 E
6.06E+02
1.29E+03
2.13E+03
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
8.15E+00
3.39E+02
1.29E+03
2.17E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 3.9E+00 1.0E+00 3.2E+00
5.00E-01 2.1E-01 1.0E+00 3.2E+00
5.00E-01 8.4E+00 1.0E+00 3.2E+00 10 100
5.00E-01 6.1E+00 1.0E+00 3.2E+00
1.86E+00 1.3E+01 1.0E+00 3.2E+00
1.15E+00 3.8E+01 1.0E+00 3.2E+00
1.03E+03 6.8E-01 1.0E+00 3.2E+00
1.42E+03 2.1E-01 1.0E+00 3.2E+00
2.20E+03 4.9E-01 1.0E+00 3.2E+00
5.00E-01 3.1E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+02 1.0E+00 3.2E+00
5.00E-01 1.1E+01 1.0E+00 3.2E+00 10 100
5.00E-01 2.3E+01 1.0E+00 3.2E+00
5.00E-01 4.3E+01 1.0E+00 3.2E+00
1.51E+00 1.0E+01 1.0E+00 3.2E+00
6.06E+02 1.5E+00 1.0E+00 3.2E+00
1.29E+03 6.7E-01 1.0E+00 3.2E+00
2.13E+03 5.9E-01 1.0E+00 3.2E+00
5.00E-01 2.0E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00
5.00E-01 9.9E+00 1.0E+00 3.2E+00 10 100
5.00E-01 1.2E+00 1.0E+00 3.2E+00
5.00E-01 1.7E+02 1.0E+00 3.2E+00
8.15E+00 1.0E+01 1.0E+00 3.2E+00
3.39E+02 9.8E-01 1.0E+00 3.2E+00
1.29E+03 5.9E-01 1.0E+00 3.2E+00
2.17E+03 1.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/19/10 2:10 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:11 PM EPA Interlab LRef 1313-1316 SWA
1.16E+03 116% VUICP-OES 11/19/10 2:13 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:14 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:18 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 1 1/19/10 2:19 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/102:21 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/19/10 2:23 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:28 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:30 PM EPA Interlab LRef 1313-1316 SWA
1.10E+03 110% VUICP-OES 11/22/1012:31 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:33 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:34 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:36 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:38 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:41 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:48 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/10 12:49 PM EPA Interlab LRef 1313-1316 SWA
1.04E+03 104% VUICP-OES 11/22/1012:51 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:53 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:56 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:58 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 11/22/10 12:59 PM EPA Interlab LRef 1313-1316 SWA
VUICP-OES 11/22/101:01 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                          1-670
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample Internal
Sample Dilution Cone. Qualifier Review
I I ug/L I
CFS-L01-1313-T01-A 1 8.88E+01
CFS-L01-1313-T02-A 1 9.30E+01
CFS-L01-1313-T03-A 1 9.81 E+01
CFS-L01-1313-T04-A 1 6.09E+01
CFS-L01-1313-T05-A 1 3.71E+01
CFS-L01-1313-T06-A 1 3.40E+01
CFS-L01-1313-T07-A 1 4.25E+03
CFS-L01-1313-T08-A 1 4.44E+04
CFS-L01-1313-T09-A 1 8.31 E+04
CFS-L01-1313-T01-B 1 8.12E+01
CFS-L01-1313-T02-B 1 9.18E+01
CFS-L01-1313-T03-B 1 9.78E+01
CFS-L01-1313-T04-B 1 5.95E+01
CFS-L01-1313-T05-B 1 4.10E+01
CFS-L01-1313-T06-B 1 5.19E+01
CFS-L01-1313-T07-B 1 3.82E+03
CFS-L01-1313-T08-B 1 3.93E+04
CFS-L01-1313-T09-B 1 8.14E+04
CFS-L01-1313-T01-C 1 8.38E+01
CFS-L01-1313-T02-C 1 8.85E+01
CFS-L01-1313-T03-C 1 8.69E+01
CFS-L01-1313-T04-C 1 6.36E+01
CFS-L01-1313-T05-C 1 3.78E+01
CFS-L01-1313-T06-C 1 3.13E+01
CFS-L01-1313-T07-C 1 4.35E+03
CFS-L01-1313-T08-C 1 4.23E+04
CFS-L01-1313-T09-C 1 8.52E+04
CFS-L01-1313-B01-A 1 5.00E-01 U1/2
CFS-L01-1313-B02-A 1 5.00E-01 U1/2
CFS-L01-1313-B03-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.88E+01 3.9E+00 1.0E+00 3.2E+00
9.30E+01 4.5E+00 1.0E+00 3.2E+00
9.81E+01 9.5E-01 1.0E+00 3.2E+00 1000 100
6.09E+01 4.6E+00 1.0E+00 3.2E+00
3.71 E+01 4.7E+00 1.0E+00 3.2E+00
3.40E+01 2.0E+01 1.0E+00 3.2E+00
4.25E+03 1.1E+00 1.0E+00 3.2E+00
4.44E+04 6.4E-01 1.0E+00 3.2E+00
8.31 E+04 1.1E+00 1.0E+00 3.2E+00
8.12E+01 3.6E+00 1.0E+00 3.2E+00
9.18E+01 4.0E+00 1.0E+00 3.2E+00
9.78E+01 2.6E+00 1.0E+00 3.2E+00 1000 100
5.95E+01 1.5E+02 1.0E+00 3.2E+00
4.10E+01 1.4E+01 1.0E+00 3.2E+00
5.19E+01 5.0E+00 1.0E+00 3.2E+00
3.82E+03 9.7E-01 1.0E+00 3.2E+00
3.93E+04 9.9E-01 1.0E+00 3.2E+00
8.14E+04 6.3E-01 1.0E+00 3.2E+00
8.38E+01 2.3E+00 1.0E+00 3.2E+00
8.85E+01 3.2E+00 1.0E+00 3.2E+00
8.69E+01 3.5E+00 1.0E+00 3.2E+00 1000 100
6.36E+01 6.0E+00 1.0E+00 3.2E+00
3.78E+01 1.4E+01 1.0E+00 3.2E+00
3.13E+01 2.8E+01 1.0E+00 3.2E+00
4.35E+03 8.5E-01 1.0E+00 3.2E+00
4.23E+04 4.4E-01 1.0E+00 3.2E+00
8.52E+04 3.8E-01 1.0E+00 3.2E+00
5.00E-01 7.2E+00 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
5.00E-01 1.1 E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.23E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316CFS
                                                                                                                                                                                    1-671
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb CFS-L01-1313-T01-A
Sb CFS-L01-1313-T02-A
Sb CFS-L01-1313-T03-A
Sb CFS-L01-1313-T04-A
Sb CFS-L01-1313-T05-A
Sb CFS-L01-1313-T06-A
Sb CFS-L01-1313-T07-A
Sb CFS-L01-1313-T08-A
Sb CFS-L01-1313-T09-A
Sb CFS-L01-1313-T01-B
Sb CFS-L01-1313-T02-B
Sb CFS-L01-1313-T03-B
Sb CFS-L01-1313-T04-B
Sb CFS-L01-1313-T05-B
Sb CFS-L01-1313-T06-B
Sb CFS-L01-1313-T07-B
Sb CFS-L01-1313-T08-B
Sb CFS-L01-1313-T09-B
Sb CFS-L01-1313-T01-C
Sb CFS-L01-1313-T02-C
Sb CFS-L01-1313-T03-C
Sb CFS-L01-1313-T04-C
Sb CFS-L01-1313-T05-C
Sb CFS-L01-1313-T06-C
Sb CFS-L01-1313-T07-C
Sb CFS-L01-1313-T08-C
Sb CFS-L01-1313-T09-C
Sb CFS-L01-1313-B01-A
Sb CFS-L01-1313-B02-A
Sb CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.08E+01 E
1 9.09E+00 E
1 2.32E+01 E
1 2.12E+01 E
1 2.70E+01
1 2.54E+01
1 1.05E+02
1 1.46E+03
1 1.79E+03
1 1.35E+01 E
1 9.97E+00 E
1 2.19E+01 E
1 2.62E+01
1 2.41 E+01
1 2.75E+01
1 1.12E+02
1 1.18E+03
1 1.79E+03
1 1.21E+01 E
1 9.37E+00 E
1 2.35E+01 E
1 2.88E+01
1 2.27E+01 E
1 3.58E+01
1 1.21E+02
1 1.41E+03
1 1.75E+03
1 3.75E+00 U1/2
1 7.99E+00 E
1 1.36E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+01 4.9E+01 7.5E+00 2.4E+01
9.09E+00 5.9E+01 7.5E+00 2.4E+01
2.32E+01 1.8E+01 7.5E+00 2.4E+01 10 100
2.12E+01 6.0E+01 7.5E+00 2.4E+01
2.70E+01 1.2E+01 7.5E+00 2.4E+01
2.54E+01 5.2E+01 7.5E+00 2.4E+01
1.05E+02 3.8E+00 7.5E+00 2.4E+01
1.46E+03 1.2E+01 7.5E+00 2.4E+01
1.79E+03 2.1E+00 7.5E+00 2.4E+01
1.35E+01 1.0E+02 7.5E+00 2.4E+01
9.97E+00 1.6E+02 7.5E+00 2.4E+01
2.19E+01 3.2E+01 7.5E+00 2.4E+01 10 100
2.62E+01 1.2E+02 7.5E+00 2.4E+01
2.41 E+01 3.1 E+01 7.5E+00 2.4E+01
2.75E+01 2.9E+01 7.5E+00 2.4E+01
1.12E+02 7.2E+00 7.5E+00 2.4E+01
1.18E+03 3.8E+00 7.5E+00 2.4E+01
1.79E+03 1.3E+01 7.5E+00 2.4E+01
1.21E+01 6.0E+01 7.5E+00 2.4E+01
9.37E+00 6.1 E+01 7.5E+00 2.4E+01
2.35E+01 3.0E+01 7.5E+00 2.4E+01 10 100
2.88E+01 1.1 E+01 7.5E+00 2.4E+01
2.27E+01 5.1E+00 7.5E+00 2.4E+01
3.58E+01 1.4E+00 7.5E+00 2.4E+01
1.21E+02 2.8E+00 7.5E+00 2.4E+01
1.41E+03 1.0E+00 7.5E+00 2.4E+01
1.75E+03 2.1E+00 7.5E+00 2.4E+01
3.75E+00 2.0E+02 7.5E+00 2.4E+01
7.99E+00 5.6E+01 7.5E+00 2.4E+01
1.36E+01 5.6E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.20E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-672
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As CFS-L01-1313-T01-A
As CFS-L01-1313-T02-A
As CFS-L01-1313-T03-A
As CFS-L01-1313-T04-A
As CFS-L01-1313-T05-A
As CFS-L01-1313-T06-A
As CFS-L01-1313-T07-A
As CFS-L01-1313-T08-A
As CFS-L01-1313-T09-A
As CFS-L01-1313-T01-B
As CFS-L01-1313-T02-B
As CFS-L01-1313-T03-B
As CFS-L01-1313-T04-B
As CFS-L01-1313-T05-B
As CFS-L01-1313-T06-B
As CFS-L01-1313-T07-B
As CFS-L01-1313-T08-B
As CFS-L01-1313-T09-B
As CFS-L01-1313-T01-C
As CFS-L01-1313-T02-C
As CFS-L01-1313-T03-C
As CFS-L01-1313-T04-C
As CFS-L01-1313-T05-C
As CFS-L01-1313-T06-C
As CFS-L01-1313-T07-C
As CFS-L01-1313-T08-C
As CFS-L01-1313-T09-C
As CFS-L01-1313-B01-A
As CFS-L01-1313-B02-A
As CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.26E+02
1 1.88E+02
1 1.00E+02
1 4.20E+01
1 2.96E+01 E
1 2.41E+01 E
1 1.32E+02
1 2.22E+03
1 8.51 E+04
1 2.04E+02
1 1.81E+02
1 9.32E+01
1 4.43E+01
1 3.03E+01 E
1 2.55E+01 E
1 1.27E+02
1 1.64E+03
1 7.64E+04
1 2.20E+02
1 2.04E+02
1 1.04E+02
1 5.34E+01
1 2.61E+01 E
1 2.30E+01 E
1 1.41E+02
1 2.23E+03
1 7.62E+04
1 5.50E+00 U1/2
1 1.50E+01 E
1 1.60E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.26E+02 6.0E+00 1.1E+01 3.5E+01
1.88E+02 5.4E+00 1.1E+01 3.5E+01
1.00E+02 6.7E+00 1.1E+01 3.5E+01 10 100
4.20E+01 1.3E+01 1.1E+01 3.5E+01
2.96E+01 1.9E+01 1.1E+01 3.5E+01
2.41E+01 2.5E+01 1.1E+01 3.5E+01
1.32E+02 6.9E+00 1.1E+01 3.5E+01
2.22E+03 9.0E-01 1.1E+01 3.5E+01
8.51E+04 1.1E+00 1.1E+01 3.5E+01
2.04E+02 1.7E+00 1.1E+01 3.5E+01
1.81E+02 4.0E+00 1.1E+01 3.5E+01
9.32E+01 1.0E+01 1.1E+01 3.5E+01 10 100
4.43E+01 6.5E+01 1.1E+01 3.5E+01
3.03E+01 4.8E+01 1.1E+01 3.5E+01
2.55E+01 2.9E+01 1.1E+01 3.5E+01
1.27E+02 7.2E+00 1.1E+01 3.5E+01
1.64E+03 7.5E-01 1.1E+01 3.5E+01
7.64E+04 1.0E+00 1.1E+01 3.5E+01
2.20E+02 8.2E+00 1.1E+01 3.5E+01
2.04E+02 4.3E+00 1.1E+01 3.5E+01
1.04E+02 5.3E+00 1.1E+01 3.5E+01 10 100
5.34E+01 5.6E+00 1.1E+01 3.5E+01
2.61E+01 1.6E+01 1.1E+01 3.5E+01
2.30E+01 4.5E+01 1.1E+01 3.5E+01
1.41E+02 3.5E+00 1.1E+01 3.5E+01
2.23E+03 5.0E-01 1.1E+01 3.5E+01
7.62E+04 1.1E+00 1.1E+01 3.5E+01
5.50E+00 5.2E+01 1.1E+01 3.5E+01
1.50E+01 1.2E+01 1.1E+01 3.5E+01
1.60E+01 6.7E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.15E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-673
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B CFS-L01-1313-T01-A
B CFS-L01-1313-T02-A
B CFS-L01-1313-T03-A
B CFS-L01-1313-T04-A
B CFS-L01-1313-T05-A
B CFS-L01-1313-T06-A
B CFS-L01-1313-T07-A
B CFS-L01-1313-T08-A
B CFS-L01-1313-T09-A
B CFS-L01-1313-T01-B
B CFS-L01-1313-T02-B
B CFS-L01-1313-T03-B
B CFS-L01-1313-T04-B
B CFS-L01-1313-T05-B
B CFS-L01-1313-T06-B
B CFS-L01-1313-T07-B
B CFS-L01-1313-T08-B
B CFS-L01-1313-T09-B
B CFS-L01-1313-T01-C
B CFS-L01-1313-T02-C
B CFS-L01-1313-T03-C
B CFS-L01-1313-T04-C
B CFS-L01-1313-T05-C
B CFS-L01-1313-T06-C
B CFS-L01-1313-T07-C
B CFS-L01-1313-T08-C
B CFS-L01-1313-T09-C
B CFS-L01-1313-B01-A
B CFS-L01-1313-B02-A
B CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.65E+01
1 7.47E+01
1 1.50E+02
1 1.24E+02
1 1.27E+02
1 1.44E+02
1 3.21 E+02
1 6.56E+02
1 7.24E+02
1 5.76E+01
1 7.39E+01
1 1.47E+02
1 1.22E+02
1 1.30E+02
1 1.44E+02
1 3. 11 E+02
1 6.67E+02
1 7.77E+02
1 6.17E+01
1 7.28E+01
1 1.48E+02
1 1.22E+02
1 1.29E+02
1 1.45E+02
1 3.18E+02
1 6.79E+02
1 7.49E+02
1 6.82E+00
1 5.68E+00
1 4.52E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.65E+01 3.4E+00 1.0E+00 3.2E+00
7.47E+01 1.1E+00 1.0E+00 3.2E+00
1.50E+02 2.2E+00 1.0E+00 3.2E+00 1000 100
1.24E+02 2.1E+00 1.0E+00 3.2E+00
1.27E+02 2.1E+00 1.0E+00 3.2E+00
1.44E+02 1.1E+00 1.0E+00 3.2E+00
3.21 E+02 6.1E-01 1.0E+00 3.2E+00
6.56E+02 1.4E+00 1.0E+00 3.2E+00
7.24E+02 7.1E-01 1.0E+00 3.2E+00
5.76E+01 1.5E+00 1.0E+00 3.2E+00
7.39E+01 6.9E+00 1.0E+00 3.2E+00
1.47E+02 8.3E-01 1.0E+00 3.2E+00 1000 100
1.22E+02 8.4E+01 1.0E+00 3.2E+00
1.30E+02 1.9E+00 1.0E+00 3.2E+00
1.44E+02 1.3E+00 1.0E+00 3.2E+00
3.11E+02 9.6E-01 1.0E+00 3.2E+00
6.67E+02 6.5E-01 1.0E+00 3.2E+00
7.77E+02 1.8E+00 1.0E+00 3.2E+00
6.17E+01 1.3E+00 1.0E+00 3.2E+00
7.28E+01 2.1E+00 1.0E+00 3.2E+00
1.48E+02 4.0E-01 1.0E+00 3.2E+00 1000 100
1.22E+02 7.9E-01 1.0E+00 3.2E+00
1.29E+02 6.0E-01 1.0E+00 3.2E+00
1.45E+02 2.4E+00 1.0E+00 3.2E+00
3.18E+02 4.0E-01 1.0E+00 3.2E+00
6.79E+02 1.0E+00 1.0E+00 3.2E+00
7.49E+02 4.7E+00 1.0E+00 3.2E+00
6.82E+00 2.8E+01 1.0E+00 3.2E+00
5.68E+00 6.6E+00 1.0E+00 3.2E+00
4.52E+00 4.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.23E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-674
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba CFS-L01-1313-T01-A
Ba CFS-L01-1313-T02-A
Ba CFS-L01-1313-T03-A
Ba CFS-L01-1313-T04-A
Ba CFS-L01-1313-T05-A
Ba CFS-L01-1313-T06-A
Ba CFS-L01-1313-T07-A
Ba CFS-L01-1313-T08-A
Ba CFS-L01-1313-T09-A
Ba CFS-L01-1313-T01-B
Ba CFS-L01-1313-T02-B
Ba CFS-L01-1313-T03-B
Ba CFS-L01-1313-T04-B
Ba CFS-L01-1313-T05-B
Ba CFS-L01-1313-T06-B
Ba CFS-L01-1313-T07-B
Ba CFS-L01-1313-T08-B
Ba CFS-L01-1313-T09-B
Ba CFS-L01-1313-T01-C
Ba CFS-L01-1313-T02-C
Ba CFS-L01-1313-T03-C
Ba CFS-L01-1313-T04-C
Ba CFS-L01-1313-T05-C
Ba CFS-L01-1313-T06-C
Ba CFS-L01-1313-T07-C
Ba CFS-L01-1313-T08-C
Ba CFS-L01-1313-T09-C
Ba CFS-L01-1313-B01-A
Ba CFS-L01-1313-B02-A
Ba CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.32E+00 E
1 6.93E+00
1 1.45E+02
1 7.79E+01
1 6.33E+01
1 8.52E+01
1 1.98E+01
1 3.96E+01
1 6.60E+00
1 1.69E+00 E
1 8.31 E+00
1 1.40E+02
1 8.06E+01
1 5.79E+01
1 8.79E+01
1 2.12E+01
1 4.12E+01
1 5.18E+00
1 1.35E+00 E
1 7.00E+00
1 1.39E+02
1 8.84E+01
1 6.23E+01
1 8.75E+01
1 2.10E+01
1 3.91 E+01
1 5.86E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.32E+00 4.8E-01 1.0E+00 3.2E+00
6.93E+00 5.7E-01 1.0E+00 3.2E+00
1.45E+02 5.9E-01 1.0E+00 3.2E+00 10 100
7.79E+01 7.9E-01 1.0E+00 3.2E+00
6.33E+01 3.5E-01 1.0E+00 3.2E+00
8.52E+01 4.8E-01 1.0E+00 3.2E+00
1.98E+01 6.1E-01 1.0E+00 3.2E+00
3.96E+01 3.8E-01 1.0E+00 3.2E+00
6.60E+00 1.3E+00 1.0E+00 3.2E+00
1.69E+00 1.3E+00 1.0E+00 3.2E+00
8.31 E+00 9.1E-01 1.0E+00 3.2E+00
1.40E+02 2.3E-01 1.0E+00 3.2E+00 10 100
8.06E+01 8.6E+01 1.0E+00 3.2E+00
5.79E+01 4.8E-01 1.0E+00 3.2E+00
8.79E+01 6.9E-01 1.0E+00 3.2E+00
2.12E+01 3.3E-01 1.0E+00 3.2E+00
4.12E+01 6.6E-01 1.0E+00 3.2E+00
5.18E+00 5.3E-01 1.0E+00 3.2E+00
1.35E+00 3.0E+00 1.0E+00 3.2E+00
7.00E+00 1.3E+00 1.0E+00 3.2E+00
1.39E+02 5.6E-01 1.0E+00 3.2E+00 10 100
8.84E+01 6.7E-01 1.0E+00 3.2E+00
6.23E+01 7.6E-02 1.0E+00 3.2E+00
8.75E+01 6.9E-01 1.0E+00 3.2E+00
2.10E+01 3.0E-01 1.0E+00 3.2E+00
3.91 E+01 1.0E+00 1.0E+00 3.2E+00
5.86E+00 1.3E+00 1.0E+00 3.2E+00
5.00E-01 2.3E+00 1.0E+00 3.2E+00
5.00E-01 7.9E+00 1.0E+00 3.2E+00
5.00E-01 6.1 E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.64E+02 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.78E+02 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-675
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be CFS-L01-1313-T01-A
Be CFS-L01-1313-T02-A
Be CFS-L01-1313-T03-A
Be CFS-L01-1313-T04-A
Be CFS-L01-1313-T05-A
Be CFS-L01-1313-T06-A
Be CFS-L01-1313-T07-A
Be CFS-L01-1313-T08-A
Be CFS-L01-1313-T09-A
Be CFS-L01-1313-T01-B
Be CFS-L01-1313-T02-B
Be CFS-L01-1313-T03-B
Be CFS-L01-1313-T04-B
Be CFS-L01-1313-T05-B
Be CFS-L01-1313-T06-B
Be CFS-L01-1313-T07-B
Be CFS-L01-1313-T08-B
Be CFS-L01-1313-T09-B
Be CFS-L01-1313-T01-C
Be CFS-L01-1313-T02-C
Be CFS-L01-1313-T03-C
Be CFS-L01-1313-T04-C
Be CFS-L01-1313-T05-C
Be CFS-L01-1313-T06-C
Be CFS-L01-1313-T07-C
Be CFS-L01-1313-T08-C
Be CFS-L01-1313-T09-C
Be CFS-L01-1313-B01-A
Be CFS-L01-1313-B02-A
Be CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.53E+00 E
1 7.37E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.56E+00 E
1 6.32E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.65E+00 E
1 7.14E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 9.4E+01 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
9.50E-01 6.2E+02 1.9E+00 6.0E+00 10 100
9.50E-01 9.9E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 2.8E+01 1.9E+00 6.0E+00
2.53E+00 1.1E+00 1.9E+00 6.0E+00
7.37E+00 4.2E+00 1.9E+00 6.0E+00
9.50E-01 8.6E+00 1.9E+00 6.0E+00
9.50E-01 6.9E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00 10 100
9.50E-01 4.2E+03 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
2.56E+00 4.9E+00 1.9E+00 6.0E+00
6.32E+00 6.0E+00 1.9E+00 6.0E+00
9.50E-01 7.8E+00 1.9E+00 6.0E+00
9.50E-01 3.6E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00 10 100
9.50E-01 8.2E+02 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 8.3E+01 1.9E+00 6.0E+00
2.65E+00 4.0E+00 1.9E+00 6.0E+00
7.14E+00 7.3E+00 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 9.8E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 9.9E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-676
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd CFS-L01-1313-T01-A
Cd CFS-L01-1313-T02-A
Cd CFS-L01-1313-T03-A
Cd CFS-L01-1313-T04-A
Cd CFS-L01-1313-T05-A
Cd CFS-L01-1313-T06-A
Cd CFS-L01-1313-T07-A
Cd CFS-L01-1313-T08-A
Cd CFS-L01-1313-T09-A
Cd CFS-L01-1313-T01-B
Cd CFS-L01-1313-T02-B
Cd CFS-L01-1313-T03-B
Cd CFS-L01-1313-T04-B
Cd CFS-L01-1313-T05-B
Cd CFS-L01-1313-T06-B
Cd CFS-L01-1313-T07-B
Cd CFS-L01-1313-T08-B
Cd CFS-L01-1313-T09-B
Cd CFS-L01-1313-T01-C
Cd CFS-L01-1313-T02-C
Cd CFS-L01-1313-T03-C
Cd CFS-L01-1313-T04-C
Cd CFS-L01-1313-T05-C
Cd CFS-L01-1313-T06-C
Cd CFS-L01-1313-T07-C
Cd CFS-L01-1313-T08-C
Cd CFS-L01-1313-T09-C
Cd CFS-L01-1313-B01-A
Cd CFS-L01-1313-B02-A
Cd CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 8.52E+00
1 2.22E+00 E
1 1.10E+00 U1/2
1 5.72E+00 E
1 2.49E+02
1 4.33E+03
1 2.39E+04
1 4.81 E+04
1 4.70E+04
1 1.01E+01
1 2.46E+00 E
1 1.10E+00 U1/2
1 3.59E+00 E
1 2.88E+02
1 4.33E+03
1 2.36E+04
1 4.65E+04
1 4.88E+04
1 1.01E+01
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 4.66E+00 E
1 2.63E+02
1 4.52E+03
1 2.42E+04
1 5.76E+04
1 4.93E+04
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.52E+00 9.2E+00 2.2E+00 7.0E+00
2.22E+00 1.2E+01 2.2E+00 7.0E+00
1.10E+00 5.1E+01 2.2E+00 7.0E+00 10 100
5.72E+00 5.4E+00 2.2E+00 7.0E+00
2.49E+02 3.7E-01 2.2E+00 7.0E+00
4.33E+03 9.2E-01 2.2E+00 7.0E+00
2.39E+04 1.4E-01 2.2E+00 7.0E+00
4.81 E+04 7.6E-01 2.2E+00 7.0E+00
4.70E+04 7.0E-01 2.2E+00 7.0E+00
1.01E+01 3.1E+00 2.2E+00 7.0E+00
2.46E+00 1.1E+01 2.2E+00 7.0E+00
1.10E+00 3.0E+01 2.2E+00 7.0E+00 10 100
3.59E+00 9.5E+01 2.2E+00 7.0E+00
2.88E+02 4.1E-01 2.2E+00 7.0E+00
4.33E+03 7.3E-01 2.2E+00 7.0E+00
2.36E+04 1.4E+00 2.2E+00 7.0E+00
4.65E+04 2.7E-01 2.2E+00 7.0E+00
4.88E+04 1.0E+00 2.2E+00 7.0E+00
1.01E+01 1.3E+00 2.2E+00 7.0E+00
1.10E+00 1.3E+01 2.2E+00 7.0E+00
1.10E+00 3.6E+01 2.2E+00 7.0E+00 10 100
4.66E+00 6.3E+00 2.2E+00 7.0E+00
2.63E+02 2.2E-01 2.2E+00 7.0E+00
4.52E+03 1.1E+00 2.2E+00 7.0E+00
2.42E+04 8.7E-01 2.2E+00 7.0E+00
5.76E+04 1.2E+00 2.2E+00 7.0E+00
4.93E+04 5.2E-01 2.2E+00 7.0E+00
1.10E+00 3.9E+02 2.2E+00 7.0E+00
1.10E+00 1.5E+02 2.2E+00 7.0E+00
1.10E+00 1.4E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-677
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
CFS-L01-1313-T01-A
CFS-L01-1313-T02-A
CFS-L01-1313-T03-A
CFS-L01-1313-T04-A
CFS-L01-1313-T05-A
CFS-L01-1313-T06-A
CFS-L01-1313-T07-A
CFS-L01-1313-T08-A
CFS-L01-1313-T09-A
CFS-L01-1313-T01-B
CFS-L01-1313-T02-B
CFS-L01-1313-T03-B
CFS-L01-1313-T04-B
CFS-L01-1313-T05-B
CFS-L01-1313-T06-B
CFS-L01-1313-T07-B
CFS-L01-1313-T08-B
CFS-L01-1313-T09-B
CFS-L01-1313-T01-C
CFS-L01-1313-T02-C
CFS-L01-1313-T03-C
CFS-L01-1313-T04-C
CFS-L01-1313-T05-C
CFS-L01-1313-T06-C
CFS-L01-1313-T07-C
CFS-L01-1313-T08-C
CFS-L01-1313-T09-C
CFS-L01-1313-B01-A
CFS-L01-1313-B02-A
CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.37E+05
1 5.48E+05
1 5.60E+05
1 5.63E+05
1 6.11E+05
1 6.55E+05
1 8.56E+05
1 1.35E+06
1 1.49E+06
1 5.66E+05
1 5.50E+05
1 5.63E+05
1 5.55E+05
1 5.82E+05
1 6.62E+05
1 8.59E+05
1 1.30E+06
1 1.48E+06
1 5.75E+05
1 5.42E+05
1 5.68E+05
1 5.93E+05
1 5.99E+05
1 6.64E+05
1 8.68E+05
1 1.30E+06
1 1.48E+06
1 7.44E+01
1 7.45E+01
1 6.85E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.37E+05 4.7E-01 2.6E+00 8.3E+00
5.48E+05 5.9E-01 2.6E+00 8.3E+00
5.60E+05 5.9E-01 2.6E+00 8.3E+00 1000 100
5.63E+05 1.7E+00 2.6E+00 8.3E+00
6.11E+05 8.6E-01 2.6E+00 8.3E+00
6.55E+05 7.6E-01 2.6E+00 8.3E+00
8.56E+05 9.0E-01 2.6E+00 8.3E+00
1.35E+06 6.9E-01 2.6E+00 8.3E+00
1.49E+06 3.2E-01 2.6E+00 8.3E+00
5.66E+05 6.8E-01 2.6E+00 8.3E+00
5.50E+05 9.6E-01 2.6E+00 8.3E+00
5.63E+05 7.3E-01 2.6E+00 8.3E+00 1000 100
5.55E+05 8.7E+01 2.6E+00 8.3E+00
5.82E+05 6.0E-01 2.6E+00 8.3E+00
6.62E+05 6.4E-01 2.6E+00 8.3E+00
8.59E+05 9.9E-01 2.6E+00 8.3E+00
1.30E+06 2.4E-01 2.6E+00 8.3E+00
1.48E+06 1.4E+00 2.6E+00 8.3E+00
5.75E+05 3.8E-01 2.6E+00 8.3E+00
5.42E+05 4.8E-01 2.6E+00 8.3E+00
5.68E+05 5.2E-01 2.6E+00 8.3E+00 1000 100
5.93E+05 6.3E-01 2.6E+00 8.3E+00
5.99E+05 3.1E-01 2.6E+00 8.3E+00
6.64E+05 1.6E+00 2.6E+00 8.3E+00
8.68E+05 8.8E-01 2.6E+00 8.3E+00
1.30E+06 1.3E+00 2.6E+00 8.3E+00
1.48E+06 8.9E-01 2.6E+00 8.3E+00
7.44E+01 2.3E+00 2.6E+00 8.3E+00
7.45E+01 1.4E+01 2.6E+00 8.3E+00
6.85E+01 2.3E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.61 E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.64E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.68E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-678
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr CFS-L01-1313-T01-A
Cr CFS-L01-1313-T02-A
Cr CFS-L01-1313-T03-A
Cr CFS-L01-1313-T04-A
Cr CFS-L01-1313-T05-A
Cr CFS-L01-1313-T06-A
Cr CFS-L01-1313-T07-A
Cr CFS-L01-1313-T08-A
Cr CFS-L01-1313-T09-A
Cr CFS-L01-1313-T01-B
Cr CFS-L01-1313-T02-B
Cr CFS-L01-1313-T03-B
Cr CFS-L01-1313-T04-B
Cr CFS-L01-1313-T05-B
Cr CFS-L01-1313-T06-B
Cr CFS-L01-1313-T07-B
Cr CFS-L01-1313-T08-B
Cr CFS-L01-1313-T09-B
Cr CFS-L01-1313-T01-C
Cr CFS-L01-1313-T02-C
Cr CFS-L01-1313-T03-C
Cr CFS-L01-1313-T04-C
Cr CFS-L01-1313-T05-C
Cr CFS-L01-1313-T06-C
Cr CFS-L01-1313-T07-C
Cr CFS-L01-1313-T08-C
Cr CFS-L01-1313-T09-C
Cr CFS-L01-1313-B01-A
Cr CFS-L01-1313-B02-A
Cr CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.11E+02
1 5.43E+01
1 7.43E+00
1 1.63E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.19E+02
1 2.10E+03
1 1.25E+02
1 6.04E+01
1 5.86E+00
1 1.45E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 9.40E+01
1 2.08E+03
1 1.06E+02
1 5.54E+01
1 7.33E+00
1 2.34E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.23E+02
1 2.06E+03
1 6.00E-01 U1/2
1 2.11E+OOE
1 1.73E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.11E+02 1.6E-01 1.2E+00 3.8E+00
5.43E+01 1.2E+00 1.2E+00 3.8E+00
7.43E+00 1.2E+01 1.2E+00 3.8E+00 10 100
1.63E+00 5.8E+01 1.2E+00 3.8E+00
6.00E-01 1.0E+02 1.2E+00 3.8E+00
6.00E-01 3.9E+03 1.2E+00 3.8E+00
6.00E-01 6.1E+01 1.2E+00 3.8E+00
1.19E+02 7.1E-01 1.2E+00 3.8E+00
2.10E+03 6.0E-01 1.2E+00 3.8E+00
1.25E+02 8.5E-02 1.2E+00 3.8E+00
6.04E+01 1.3E+00 1.2E+00 3.8E+00
5.86E+00 9.0E+00 1.2E+00 3.8E+00 10 100
1.45E+00 1.1E+02 1.2E+00 3.8E+00
6.00E-01 2.0E+02 1.2E+00 3.8E+00
6.00E-01 2.4E+01 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
9.40E+01 9.1E-01 1.2E+00 3.8E+00
2.08E+03 6.4E-01 1.2E+00 3.8E+00
1.06E+02 1.2E+00 1.2E+00 3.8E+00
5.54E+01 1.2E+00 1.2E+00 3.8E+00
7.33E+00 5.2E+00 1.2E+00 3.8E+00 10 100
2.34E+00 7.6E+00 1.2E+00 3.8E+00
6.00E-01 6.1E+01 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.00E-01 7.0E+01 1.2E+00 3.8E+00
1.23E+02 1.4E+00 1.2E+00 3.8E+00
2.06E+03 4.7E-01 1.2E+00 3.8E+00
6.00E-01 3.1E+02 1.2E+00 3.8E+00
2.11E+00 1.8E+01 1.2E+00 3.8E+00
1.73E+00 5.1E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316CFS
                                                                                                                                                                          1-679
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
CFS-L01-1313-T01-A
CFS-L01-1313-T02-A
CFS-L01-1313-T03-A
CFS-L01-1313-T04-A
CFS-L01-1313-T05-A
CFS-L01-1313-T06-A
CFS-L01-1313-T07-A
CFS-L01-1313-T08-A
CFS-L01-1313-T09-A
CFS-L01-1313-T01-B
CFS-L01-1313-T02-B
CFS-L01-1313-T03-B
CFS-L01-1313-T04-B
CFS-L01-1313-T05-B
CFS-L01-1313-T06-B
CFS-L01-1313-T07-B
CFS-L01-1313-T08-B
CFS-L01-1313-T09-B
CFS-L01-1313-T01-C
CFS-L01-1313-T02-C
CFS-L01-1313-T03-C
CFS-L01-1313-T04-C
CFS-L01-1313-T05-C
CFS-L01-1313-T06-C
CFS-L01-1313-T07-C
CFS-L01-1313-T08-C
CFS-L01-1313-T09-C
CFS-L01-1313-B01-A
CFS-L01-1313-B02-A
CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 3.98E+00 E
1 8.66E+01
1 5.71E+02
1 1.54E+03
1 1.67E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 5.55E+00 E
1 8.90E+01
1 5.61 E+02
1 1.57E+03
1 1.69E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 3.87E+00 E
1 9.33E+01
1 5.81 E+02
1 1.55E+03
1 1.71E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 6.4E+02 1.8E+00 5.7E+00
9.00E-01 9.4E+01 1.8E+00 5.7E+00 10 100
9.00E-01 4.0E+02 1.8E+00 5.7E+00
3.98E+00 2.3E+01 1.8E+00 5.7E+00
8.66E+01 1.0E+00 1.8E+00 5.7E+00
5.71 E+02 1.3E+00 1.8E+00 5.7E+00
1.54E+03 5.3E-01 1.8E+00 5.7E+00
1.67E+03 7.0E-01 1.8E+00 5.7E+00
9.00E-01 5.4E+01 1.8E+00 5.7E+00
9.00E-01 8.0E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00 10 100
9.00E-01 9.8E+01 1.8E+00 5.7E+00
5.55E+00 5.2E+00 1.8E+00 5.7E+00
8.90E+01 1.7E+00 1.8E+00 5.7E+00
5.61 E+02 5.5E-01 1.8E+00 5.7E+00
1.57E+03 7.9E-01 1.8E+00 5.7E+00
1.69E+03 1.3E+00 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 6.1E+02 1.8E+00 5.7E+00 10 100
9.00E-01 3.8E+02 1.8E+00 5.7E+00
3.87E+00 2.5E+01 1.8E+00 5.7E+00
9.33E+01 1.1E+00 1.8E+00 5.7E+00
5.81 E+02 6.5E-01 1.8E+00 5.7E+00
1.55E+03 1.1E+00 1.8E+00 5.7E+00
1.71E+03 1.2E+00 1.8E+00 5.7E+00
9.00E-01 1.8E+01 1.8E+00 5.7E+00
9.00E-01 9.4E+01 1.8E+00 5.7E+00
9.00E-01 2.1 E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-680
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu CFS-L01-1313-T01-A
Cu CFS-L01-1313-T02-A
Cu CFS-L01-1313-T03-A
Cu CFS-L01-1313-T04-A
Cu CFS-L01-1313-T05-A
Cu CFS-L01-1313-T06-A
Cu CFS-L01-1313-T07-A
Cu CFS-L01-1313-T08-A
Cu CFS-L01-1313-T09-A
Cu CFS-L01-1313-T01-B
Cu CFS-L01-1313-T02-B
Cu CFS-L01-1313-T03-B
Cu CFS-L01-1313-T04-B
Cu CFS-L01-1313-T05-B
Cu CFS-L01-1313-T06-B
Cu CFS-L01-1313-T07-B
Cu CFS-L01-1313-T08-B
Cu CFS-L01-1313-T09-B
Cu CFS-L01-1313-T01-C
Cu CFS-L01-1313-T02-C
Cu CFS-L01-1313-T03-C
Cu CFS-L01-1313-T04-C
Cu CFS-L01-1313-T05-C
Cu CFS-L01-1313-T06-C
Cu CFS-L01-1313-T07-C
Cu CFS-L01-1313-T08-C
Cu CFS-L01-1313-T09-C
Cu CFS-L01-1313-B01-A
Cu CFS-L01-1313-B02-A
Cu CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.68E+03
1 8.54E+02
1 1.37E+02
1 6.43E+01
1 6.52E+01
1 7.81 E+02
1 2.21 E+05
1 9.34E+05
1 1.07E+06
1 5.45E+03
1 8.49E+02
1 1.30E+02
1 5.79E+01
1 6.35E+01
1 7.65E+02
1 2.04E+05
1 9.03E+05
1 1.02E+06
1 5.27E+03
1 8.18E+02
1 1.29E+02
1 6.97E+01
1 6.00E+01
1 9.39E+02
1 2.26E+05
1 9.22E+05
1 1.06E+06
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.68E+03 1.1E+00 3.7E+00 1.2E+01
8.54E+02 1.7E-01 3.7E+00 1.2E+01
1.37E+02 1.5E+00 3.7E+00 1.2E+01 10 100
6.43E+01 6.3E+00 3.7E+00 1.2E+01
6.52E+01 1.2E+00 3.7E+00 1.2E+01
7.81 E+02 7.5E-01 3.7E+00 1.2E+01
2.21 E+05 1.0E+00 3.7E+00 1.2E+01
9.34E+05 1.2E+00 3.7E+00 1.2E+01
1.07E+06 1.2E+00 3.7E+00 1.2E+01
5.45E+03 6.9E-01 3.7E+00 1.2E+01
8.49E+02 1.2E+00 3.7E+00 1.2E+01
1.30E+02 1.9E+00 3.7E+00 1.2E+01 10 100
5.79E+01 8.5E+01 3.7E+00 1.2E+01
6.35E+01 1.8E+00 3.7E+00 1.2E+01
7.65E+02 5.0E-01 3.7E+00 1.2E+01
2.04E+05 1.2E+00 3.7E+00 1.2E+01
9.03E+05 4.8E-01 3.7E+00 1.2E+01
1.02E+06 9.5E-01 3.7E+00 1.2E+01
5.27E+03 6.2E-01 3.7E+00 1.2E+01
8.18E+02 2.9E-01 3.7E+00 1.2E+01
1.29E+02 1.9E+00 3.7E+00 1.2E+01 10 100
6.97E+01 5.7E+00 3.7E+00 1.2E+01
6.00E+01 1.7E+00 3.7E+00 1.2E+01
9.39E+02 1.3E+00 3.7E+00 1.2E+01
2.26E+05 1.8E-01 3.7E+00 1.2E+01
9.22E+05 9.0E-01 3.7E+00 1.2E+01
1.06E+06 4.5E-01 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.85E+00 2.2E+02 3.7E+00 1.2E+01
1.85E+00 6.0E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.21E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.24E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-681
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe CFS-L01-1313-T01-A
Fe CFS-L01-1313-T02-A
Fe CFS-L01-1313-T03-A
Fe CFS-L01-1313-T04-A
Fe CFS-L01-1313-T05-A
Fe CFS-L01-1313-T06-A
Fe CFS-L01-1313-T07-A
Fe CFS-L01-1313-T08-A
Fe CFS-L01-1313-T09-A
Fe CFS-L01-1313-T01-B
Fe CFS-L01-1313-T02-B
Fe CFS-L01-1313-T03-B
Fe CFS-L01-1313-T04-B
Fe CFS-L01-1313-T05-B
Fe CFS-L01-1313-T06-B
Fe CFS-L01-1313-T07-B
Fe CFS-L01-1313-T08-B
Fe CFS-L01-1313-T09-B
Fe CFS-L01-1313-T01-C
Fe CFS-L01-1313-T02-C
Fe CFS-L01-1313-T03-C
Fe CFS-L01-1313-T04-C
Fe CFS-L01-1313-T05-C
Fe CFS-L01-1313-T06-C
Fe CFS-L01-1313-T07-C
Fe CFS-L01-1313-T08-C
Fe CFS-L01-1313-T09-C
Fe CFS-L01-1313-B01-A
Fe CFS-L01-1313-B02-A
Fe CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 4.92E+00 E
1 8.27E+04
1 2.73E+05
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 5.37E+00 E
1 7.00E+04
1 2.56E+05
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 7.39E+00
1 7.22E+04
1 2.65E+05
1 1.00E+OOU1/2
1 1.90E+01
1 3.96E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 7.6E+01 2.0E+00 6.4E+00
1.00E+00 7.5E+01 2.0E+00 6.4E+00
1.00E+00 7.2E+03 2.0E+00 6.4E+00 1000 100
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
4.92E+00 6.8E+00 2.0E+00 6.4E+00
8.27E+04 1.1E+00 2.0E+00 6.4E+00
2.73E+05 3.2E+00 2.0E+00 6.4E+00
1.00E+00 4.7E+01 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00
1.00E+00 3.2E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+02 2.0E+00 6.4E+00
5.37E+00 4.4E+00 2.0E+00 6.4E+00
7.00E+04 4.2E-01 2.0E+00 6.4E+00
2.56E+05 6.6E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 5.5E+00 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 6.3E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+03 2.0E+00 6.4E+00
7.39E+00 6.2E+00 2.0E+00 6.4E+00
7.22E+04 3.7E-01 2.0E+00 6.4E+00
2.65E+05 3.9E+00 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.90E+01 1.0E+00 2.0E+00 6.4E+00
3.96E+00 1.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-682
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb CFS-L01-1313-T01-A
Pb CFS-L01-1313-T02-A
Pb CFS-L01-1313-T03-A
Pb CFS-L01-1313-T04-A
Pb CFS-L01-1313-T05-A
Pb CFS-L01-1313-T06-A
Pb CFS-L01-1313-T07-A
Pb CFS-L01-1313-T08-A
Pb CFS-L01-1313-T09-A
Pb CFS-L01-1313-T01-B
Pb CFS-L01-1313-T02-B
Pb CFS-L01-1313-T03-B
Pb CFS-L01-1313-T04-B
Pb CFS-L01-1313-T05-B
Pb CFS-L01-1313-T06-B
Pb CFS-L01-1313-T07-B
Pb CFS-L01-1313-T08-B
Pb CFS-L01-1313-T09-B
Pb CFS-L01-1313-T01-C
Pb CFS-L01-1313-T02-C
Pb CFS-L01-1313-T03-C
Pb CFS-L01-1313-T04-C
Pb CFS-L01-1313-T05-C
Pb CFS-L01-1313-T06-C
Pb CFS-L01-1313-T07-C
Pb CFS-L01-1313-T08-C
Pb CFS-L01-1313-T09-C
Pb CFS-L01-1313-B01-A
Pb CFS-L01-1313-B02-A
Pb CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.19E+03
1 8.12E+03
1 9.83E+02
1 1.72E+02
1 1.82E+02
1 1.09E+03
1 7.19E+03
1 5.95E+03
1 8.24E+03
1 5.71 E+03
1 9.13E+03
1 7.90E+02
1 1.72E+02
1 1.89E+02
1 1.06E+03
1 7.15E+03
1 5.49E+03
1 8.30E+03
1 6.59E+03
1 8.88E+03
1 6.95E+02
1 1.98E+02
1 1.88E+02
1 1.09E+03
1 6.71 E+03
1 5.83E+03
1 8.16E+03
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.19E+03 1.3E+00 6.8E+00 2.2E+01
8.12E+03 6.7E-01 6.8E+00 2.2E+01
9.83E+02 6.7E-01 6.8E+00 2.2E+01 10 100
1.72E+02 3.1E+00 6.8E+00 2.2E+01
1.82E+02 3.0E+00 6.8E+00 2.2E+01
1.09E+03 1.3E+00 6.8E+00 2.2E+01
7.19E+03 9.9E-01 6.8E+00 2.2E+01
5.95E+03 8.7E-01 6.8E+00 2.2E+01
8.24E+03 8.3E-01 6.8E+00 2.2E+01
5.71 E+03 8.3E-01 6.8E+00 2.2E+01
9.13E+03 1.6E+00 6.8E+00 2.2E+01
7.90E+02 1.5E+00 6.8E+00 2.2E+01 10 100
1.72E+02 1.0E+02 6.8E+00 2.2E+01
1.89E+02 2.5E+00 6.8E+00 2.2E+01
1.06E+03 7.2E-01 6.8E+00 2.2E+01
7.15E+03 8.9E-01 6.8E+00 2.2E+01
5.49E+03 1.0E+00 6.8E+00 2.2E+01
8.30E+03 6.4E-01 6.8E+00 2.2E+01
6.59E+03 3.3E-01 6.8E+00 2.2E+01
8.88E+03 5.3E-01 6.8E+00 2.2E+01
6.95E+02 9.6E-01 6.8E+00 2.2E+01 10 100
1.98E+02 1.3E+00 6.8E+00 2.2E+01
1.88E+02 3.2E+00 6.8E+00 2.2E+01
1.09E+03 7.4E-01 6.8E+00 2.2E+01
6.71 E+03 8.2E-01 6.8E+00 2.2E+01
5.83E+03 1.2E+00 6.8E+00 2.2E+01
8.16E+03 4.8E-01 6.8E+00 2.2E+01
3.40E+00 1.7E+01 6.8E+00 2.2E+01
3.40E+00 4.2E+01 6.8E+00 2.2E+01
3.40E+00 3.4E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.92E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.91E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.77E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-683
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li CFS-L01-1313-T01-A
Li CFS-L01-1313-T02-A
Li CFS-L01-1313-T03-A
Li CFS-L01-1313-T04-A
Li CFS-L01-1313-T05-A
Li CFS-L01-1313-T06-A
Li CFS-L01-1313-T07-A
Li CFS-L01-1313-T08-A
Li CFS-L01-1313-T09-A
Li CFS-L01-1313-T01-B
Li CFS-L01-1313-T02-B
Li CFS-L01-1313-T03-B
Li CFS-L01-1313-T04-B
Li CFS-L01-1313-T05-B
Li CFS-L01-1313-T06-B
Li CFS-L01-1313-T07-B
Li CFS-L01-1313-T08-B
Li CFS-L01-1313-T09-B
Li CFS-L01-1313-T01-C
Li CFS-L01-1313-T02-C
Li CFS-L01-1313-T03-C
Li CFS-L01-1313-T04-C
Li CFS-L01-1313-T05-C
Li CFS-L01-1313-T06-C
Li CFS-L01-1313-T07-C
Li CFS-L01-1313-T08-C
Li CFS-L01-1313-T09-C
Li CFS-L01-1313-B01-A
Li CFS-L01-1313-B02-A
Li CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.33E+01
1 1.02E+01
1 9.51 E+00
1 1.14E+01
1 9.31 E+00
1 9.51 E+00
1 9.29E+00
1 7.69E+00
1 2.32E+01
1 1.38E+01
1 1.16E+01
1 1.14E+01
1 9.05E+00
1 1.08E+01
1 9.51 E+00
1 1.02E+01
1 9.65E+00
1 1.18E+01
1 1.25E+01
1 1.30E+01
1 9.99E+00
1 1.35E+01
1 1.34E+01
1 9.33E+00
1 7.82E+00
1 1.12E+01
1 2.03E+01
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+01 3.2E+00 1.9E+00 6.0E+00
1.02E+01 5.7E+00 1.9E+00 6.0E+00
9.51E+00 1.5E+01 1.9E+00 6.0E+00 10 100
1.14E+01 1.6E+01 1.9E+00 6.0E+00
9.31 E+00 4.6E+00 1.9E+00 6.0E+00
9.51 E+00 1.6E+01 1.9E+00 6.0E+00
9.29E+00 2.9E+01 1.9E+00 6.0E+00
7.69E+00 1.2E+01 1.9E+00 6.0E+00
2.32E+01 5.8E+00 1.9E+00 6.0E+00
1.38E+01 5.3E+00 1.9E+00 6.0E+00
1.16E+01 3.1E+00 1.9E+00 6.0E+00
1.14E+01 1.0E+01 1.9E+00 6.0E+00 10 100
9.05E+00 2.8E+01 1.9E+00 6.0E+00
1.08E+01 1.7E+01 1.9E+00 6.0E+00
9.51 E+00 2.6E+01 1.9E+00 6.0E+00
1.02E+01 6.1 E+00 1.9E+00 6.0E+00
9.65E+00 9.8E+00 1.9E+00 6.0E+00
1.18E+01 4.0E+00 1.9E+00 6.0E+00
1.25E+01 1.8E+00 1.9E+00 6.0E+00
1.30E+01 1.0E+00 1.9E+00 6.0E+00
9.99E+00 1.5E+01 1.9E+00 6.0E+00 10 100
1.35E+01 1.8E+01 1.9E+00 6.0E+00
1.34E+01 1.1E+01 1.9E+00 6.0E+00
9.33E+00 6.2E+00 1.9E+00 6.0E+00
7.82E+00 2.8E+01 1.9E+00 6.0E+00
1.12E+01 9.3E+00 1.9E+00 6.0E+00
2.03E+01 2.3E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+01 1.9E+00 6.0E+00
9.50E-01 1.9E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.62E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.95E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.76E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-684
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn CFS-L01-1313-T01-A
Mn CFS-L01-1313-T02-A
Mn CFS-L01-1313-T03-A
Mn CFS-L01-1313-T04-A
Mn CFS-L01-1313-T05-A
Mn CFS-L01-1313-T06-A
Mn CFS-L01-1313-T07-A
Mn CFS-L01-1313-T08-A
Mn CFS-L01-1313-T09-A
Mn CFS-L01-1313-T01-B
Mn CFS-L01-1313-T02-B
Mn CFS-L01-1313-T03-B
Mn CFS-L01-1313-T04-B
Mn CFS-L01-1313-T05-B
Mn CFS-L01-1313-T06-B
Mn CFS-L01-1313-T07-B
Mn CFS-L01-1313-T08-B
Mn CFS-L01-1313-T09-B
Mn CFS-L01-1313-T01-C
Mn CFS-L01-1313-T02-C
Mn CFS-L01-1313-T03-C
Mn CFS-L01-1313-T04-C
Mn CFS-L01-1313-T05-C
Mn CFS-L01-1313-T06-C
Mn CFS-L01-1313-T07-C
Mn CFS-L01-1313-T08-C
Mn CFS-L01-1313-T09-C
Mn CFS-L01-1313-B01-A
Mn CFS-L01-1313-B02-A
Mn CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.10E+02
1 1.42E+03
1 5.93E+03
1 2.39E+04
1 3.42E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.38E+02
1 1.42E+03
1 5.88E+03
1 2.39E+04
1 3.16E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.36E+02
1 1.51E+03
1 6.08E+03
1 2.35E+04
1 3.30E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 7.2E+01 2.0E+00 6.4E+00
1.00E+00 4.4E+01 2.0E+00 6.4E+00 10 100
1.00E+00 4.1E+00 2.0E+00 6.4E+00
1.10E+02 1.1E+00 2.0E+00 6.4E+00
1.42E+03 8.0E-01 2.0E+00 6.4E+00
5.93E+03 9.2E-01 2.0E+00 6.4E+00
2.39E+04 9.7E-01 2.0E+00 6.4E+00
3.42E+04 4.4E-01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00 10 100
1.00E+00 9.9E+01 2.0E+00 6.4E+00
1.38E+02 1.0E+00 2.0E+00 6.4E+00
1.42E+03 1.2E+00 2.0E+00 6.4E+00
5.88E+03 9.8E-01 2.0E+00 6.4E+00
2.39E+04 3.3E-01 2.0E+00 6.4E+00
3.16E+04 6.5E-01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00 10 100
1.00E+00 3.6E+01 2.0E+00 6.4E+00
1.36E+02 1.0E+00 2.0E+00 6.4E+00
1.51E+03 1.6E+00 2.0E+00 6.4E+00
6.08E+03 7.7E-01 2.0E+00 6.4E+00
2.35E+04 9.5E-01 2.0E+00 6.4E+00
3.30E+04 9.2E-01 2.0E+00 6.4E+00
1.00E+00 4.6E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-685
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg CFS-L01-1313-T01-A
Mg CFS-L01-1313-T02-A
Mg CFS-L01-1313-T03-A
Mg CFS-L01-1313-T04-A
Mg CFS-L01-1313-T05-A
Mg CFS-L01-1313-T06-A
Mg CFS-L01-1313-T07-A
Mg CFS-L01-1313-T08-A
Mg CFS-L01-1313-T09-A
Mg CFS-L01-1313-T01-B
Mg CFS-L01-1313-T02-B
Mg CFS-L01-1313-T03-B
Mg CFS-L01-1313-T04-B
Mg CFS-L01-1313-T05-B
Mg CFS-L01-1313-T06-B
Mg CFS-L01-1313-T07-B
Mg CFS-L01-1313-T08-B
Mg CFS-L01-1313-T09-B
Mg CFS-L01-1313-T01-C
Mg CFS-L01-1313-T02-C
Mg CFS-L01-1313-T03-C
Mg CFS-L01-1313-T04-C
Mg CFS-L01-1313-T05-C
Mg CFS-L01-1313-T06-C
Mg CFS-L01-1313-T07-C
Mg CFS-L01-1313-T08-C
Mg CFS-L01-1313-T09-C
Mg CFS-L01-1313-B01-A
Mg CFS-L01-1313-B02-A
Mg CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.14E+01
1 2.76E+01
1 7.60E+02
1 1.64E+04
1 6.35E+04
1 5.83E+04
1 6.94E+04
1 1.52E+05
1 2.47E+05
1 2.19E+01
1 2.35E+01
1 1.02E+03
1 1.60E+04
1 6.25E+04
1 6.19E+04
1 7.30E+04
1 1.70E+05
1 2.42E+05
1 1.65E+01
1 2.53E+01
1 1.21E+03
1 1.53E+04
1 6.46E+04
1 6.22E+04
1 7.25E+04
1 1.63E+05
1 2.33E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.14E+01 6.5E+00 1.0E+00 3.2E+00
2.76E+01 4.9E+01 1.0E+00 3.2E+00
7.60E+02 5.0E-01 1.0E+00 3.2E+00 1000 100
1.64E+04 4.1E-01 1.0E+00 3.2E+00
6.35E+04 4.6E-01 1.0E+00 3.2E+00
5.83E+04 7.7E-01 1.0E+00 3.2E+00
6.94E+04 2.0E-01 1.0E+00 3.2E+00
1.52E+05 2.0E-01 1.0E+00 3.2E+00
2.47E+05 8.3E-01 1.0E+00 3.2E+00
2.19E+01 7.4E+01 1.0E+00 3.2E+00
2.35E+01 3.8E+01 1.0E+00 3.2E+00
1.02E+03 1.2E+00 1.0E+00 3.2E+00 1000 100
1.60E+04 9.1E+01 1.0E+00 3.2E+00
6.25E+04 1.4E+00 1.0E+00 3.2E+00
6.19E+04 4.6E-01 1.0E+00 3.2E+00
7.30E+04 1.1E+00 1.0E+00 3.2E+00
1.70E+05 4.6E-01 1.0E+00 3.2E+00
2.42E+05 1.0E+00 1.0E+00 3.2E+00
1.65E+01 4.8E+01 1.0E+00 3.2E+00
2.53E+01 2.0E+01 1.0E+00 3.2E+00
1.21E+03 9.8E-01 1.0E+00 3.2E+00 1000 100
1.53E+04 1.5E+00 1.0E+00 3.2E+00
6.46E+04 9.5E-01 1.0E+00 3.2E+00
6.22E+04 7.0E-01 1.0E+00 3.2E+00
7.25E+04 5.3E-01 1.0E+00 3.2E+00
1.63E+05 1.4E+00 1.0E+00 3.2E+00
2.33E+05 5.6E-01 1.0E+00 3.2E+00
5.00E-01 1.3E+02 1.0E+00 3.2E+00
5.00E-01 5.0E+01 1.0E+00 3.2E+00
5.00E-01 9.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.67E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.97E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.17E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-686
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo CFS-L01-1313-T01-A
Mo CFS-L01-1313-T02-A
Mo CFS-L01-1313-T03-A
Mo CFS-L01-1313-T04-A
Mo CFS-L01-1313-T05-A
Mo CFS-L01-1313-T06-A
Mo CFS-L01-1313-T07-A
Mo CFS-L01-1313-T08-A
Mo CFS-L01-1313-T09-A
Mo CFS-L01-1313-T01-B
Mo CFS-L01-1313-T02-B
Mo CFS-L01-1313-T03-B
Mo CFS-L01-1313-T04-B
Mo CFS-L01-1313-T05-B
Mo CFS-L01-1313-T06-B
Mo CFS-L01-1313-T07-B
Mo CFS-L01-1313-T08-B
Mo CFS-L01-1313-T09-B
Mo CFS-L01-1313-T01-C
Mo CFS-L01-1313-T02-C
Mo CFS-L01-1313-T03-C
Mo CFS-L01-1313-T04-C
Mo CFS-L01-1313-T05-C
Mo CFS-L01-1313-T06-C
Mo CFS-L01-1313-T07-C
Mo CFS-L01-1313-T08-C
Mo CFS-L01-1313-T09-C
Mo CFS-L01-1313-B01-A
Mo CFS-L01-1313-B02-A
Mo CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.28E+03
1 1.57E+03
1 9.82E+02
1 5.67E+02
1 6.23E+01
1 8.40E+00
1 6.41 E+00
1 2.60E+01
1 1.08E+02
1 1.29E+03
1 1.50E+03
1 9.74E+02
1 6.20E+02
1 5.80E+01
1 8.22E+00
1 4.46E+00
1 8.39E+00
1 1.06E+02
1 1.29E+03
1 1.54E+03
1 9.87E+02
1 6.16E+02
1 5.95E+01
1 9.37E+00
1 4.05E+00
1 3.95E+00
1 8.53E+01
1 5.18E+00
1 6.00E-01 U1/2
1 1.65E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.28E+03 5.4E-01 1.2E+00 3.8E+00
1.57E+03 3.7E-01 1.2E+00 3.8E+00
9.82E+02 1.4E+00 1.2E+00 3.8E+00 10 100
5.67E+02 9.3E-01 1.2E+00 3.8E+00
6.23E+01 1.5E+00 1.2E+00 3.8E+00
8.40E+00 5.5E+00 1.2E+00 3.8E+00
6.41 E+00 2.3E+01 1.2E+00 3.8E+00
2.60E+01 8.2E+01 1.2E+00 3.8E+00
1.08E+02 1.7E+01 1.2E+00 3.8E+00
1.29E+03 1.6E-01 1.2E+00 3.8E+00
1.50E+03 1.2E+00 1.2E+00 3.8E+00
9.74E+02 1.1 E+00 1.2E+00 3.8E+00 10 100
6.20E+02 8.9E+01 1.2E+00 3.8E+00
5.80E+01 1.9E+00 1.2E+00 3.8E+00
8.22E+00 9.1 E+00 1.2E+00 3.8E+00
4.46E+00 7.6E+01 1.2E+00 3.8E+00
8.39E+00 6.5E+01 1.2E+00 3.8E+00
1.06E+02 2.0E+01 1.2E+00 3.8E+00
1.29E+03 3.7E-01 1.2E+00 3.8E+00
1.54E+03 5.3E-01 1.2E+00 3.8E+00
9.87E+02 6.2E-01 1.2E+00 3.8E+00 10 100
6.16E+02 7.3E-01 1.2E+00 3.8E+00
5.95E+01 1.3E-01 1.2E+00 3.8E+00
9.37E+00 5.7E+00 1.2E+00 3.8E+00
4.05E+00 6.0E+01 1.2E+00 3.8E+00
3.95E+00 5.6E+01 1.2E+00 3.8E+00
8.53E+01 3.5E+00 1.2E+00 3.8E+00
5.18E+00 1.3E+01 1.2E+00 3.8E+00
6.00E-01 1.0E+02 1.2E+00 3.8E+00
1.65E+01 1.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.04E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.00E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.10E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-687
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni CFS-L01-1313-T01-A
Ni CFS-L01-1313-T02-A
Ni CFS-L01-1313-T03-A
Ni CFS-L01-1313-T04-A
Ni CFS-L01-1313-T05-A
Ni CFS-L01-1313-T06-A
Ni CFS-L01-1313-T07-A
Ni CFS-L01-1313-T08-A
Ni CFS-L01-1313-T09-A
Ni CFS-L01-1313-T01-B
Ni CFS-L01-1313-T02-B
Ni CFS-L01-1313-T03-B
Ni CFS-L01-1313-T04-B
Ni CFS-L01-1313-T05-B
Ni CFS-L01-1313-T06-B
Ni CFS-L01-1313-T07-B
Ni CFS-L01-1313-T08-B
Ni CFS-L01-1313-T09-B
Ni CFS-L01-1313-T01-C
Ni CFS-L01-1313-T02-C
Ni CFS-L01-1313-T03-C
Ni CFS-L01-1313-T04-C
Ni CFS-L01-1313-T05-C
Ni CFS-L01-1313-T06-C
Ni CFS-L01-1313-T07-C
Ni CFS-L01-1313-T08-C
Ni CFS-L01-1313-T09-C
Ni CFS-L01-1313-B01-A
Ni CFS-L01-1313-B02-A
Ni CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 6.75E+00
1 2.00E+02
1 2.16E+03
1 6.14E+03
1 6.35E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.61 E+00
1 2.00E+02
1 2.05E+03
1 6.01 E+03
1 6.48E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.48E+00
1 2.07E+02
1 2.21 E+03
1 6.08E+03
1 6.31 E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 8.5E+01 1.8E+00 5.7E+00
9.00E-01 7.8E+01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00 10 100
9.00E-01 2.5E+02 1.8E+00 5.7E+00
6.75E+00 3.3E+01 1.8E+00 5.7E+00
2.00E+02 8.4E-01 1.8E+00 5.7E+00
2.16E+03 1.1 E+00 1.8E+00 5.7E+00
6.14E+03 1.1 E+00 1.8E+00 5.7E+00
6.35E+03 1.9E+00 1.8E+00 5.7E+00
9.00E-01 9.7E+01 1.8E+00 5.7E+00
9.00E-01 9.0E+01 1.8E+00 5.7E+00
9.00E-01 7.3E+02 1.8E+00 5.7E+00 10 100
9.00E-01 1.2E+03 1.8E+00 5.7E+00
9.61 E+00 1.3E+01 1.8E+00 5.7E+00
2.00E+02 8.6E-01 1.8E+00 5.7E+00
2.05E+03 3.7E-01 1.8E+00 5.7E+00
6.01 E+03 2.5E-01 1.8E+00 5.7E+00
6.48E+03 9.7E-01 1.8E+00 5.7E+00
9.00E-01 5.1E+01 1.8E+00 5.7E+00
9.00E-01 7.6E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00 10 100
9.00E-01 5.6E+01 1.8E+00 5.7E+00
9.48E+00 1.9E+01 1.8E+00 5.7E+00
2.07E+02 1.3E+00 1.8E+00 5.7E+00
2.21 E+03 4.6E-01 1.8E+00 5.7E+00
6.08E+03 4.0E-01 1.8E+00 5.7E+00
6.31 E+03 2.2E-01 1.8E+00 5.7E+00
9.00E-01 3.2E+02 1.8E+00 5.7E+00
9.00E-01 3.1E+01 1.8E+00 5.7E+00
9.00E-01 8.4E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-688
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P CFS-L01-1313-T01-A
P CFS-L01-1313-T02-A
P CFS-L01-1313-T03-A
P CFS-L01-1313-T04-A
P CFS-L01-1313-T05-A
P CFS-L01-1313-T06-A
P CFS-L01-1313-T07-A
P CFS-L01-1313-T08-A
P CFS-L01-1313-T09-A
P CFS-L01-1313-T01-B
P CFS-L01-1313-T02-B
P CFS-L01-1313-T03-B
P CFS-L01-1313-T04-B
P CFS-L01-1313-T05-B
P CFS-L01-1313-T06-B
P CFS-L01-1313-T07-B
P CFS-L01-1313-T08-B
P CFS-L01-1313-T09-B
P CFS-L01-1313-T01-C
P CFS-L01-1313-T02-C
P CFS-L01-1313-T03-C
P CFS-L01-1313-T04-C
P CFS-L01-1313-T05-C
P CFS-L01-1313-T06-C
P CFS-L01-1313-T07-C
P CFS-L01-1313-T08-C
P CFS-L01-1313-T09-C
P CFS-L01-1313-B01-A
P CFS-L01-1313-B02-A
P CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 8.50E+01
1 7.91 E+01
1 6.58E+01
1 1.85E+00 U1/2
1 4.44E+00 E
1 1.85E+00 U1/2
1 2.80E+01
1 6.24E+01
1 3.47E+03
1 9.71E+01
1 7.28E+01
1 5.92E+01
1 3.71E+01
1 5.84E+00 E
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 2.32E+01
1 3.02E+03
1 8.86E+01
1 8.53E+01
1 5.16E+01
1 3.37E+01
1 4.77E+00 E
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 3.48E+01
1 3.03E+03
1 1.67E+01
1 4.63E+01
1 5.65E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.50E+01 7.6E+00 3.7E+00 1.2E+01
7.91E+01 1.3E+01 3.7E+00 1.2E+01
6.58E+01 2.7E+01 3.7E+00 1.2E+01 1000 100
1.85E+00 1.3E+01 3.7E+00 1.2E+01
4.44E+00 3.0E+02 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
2.80E+01 7.3E+01 3.7E+00 1.2E+01
6.24E+01 1.1E+01 3.7E+00 1.2E+01
3.47E+03 1.8E+00 3.7E+00 1.2E+01
9.71 E+01 7.0E+00 3.7E+00 1.2E+01
7.28E+01 3.7E+01 3.7E+00 1.2E+01
5.92E+01 1.8E+01 3.7E+00 1.2E+01 1000 100
3.71E+01 1.1E+02 3.7E+00 1.2E+01
5.84E+00 1.0E+02 3.7E+00 1.2E+01
1.85E+00 7.3E+02 3.7E+00 1.2E+01
1.85E+00 2.8E+01 3.7E+00 1.2E+01
2.32E+01 6.3E+01 3.7E+00 1.2E+01
3.02E+03 2.0E+00 3.7E+00 1.2E+01
8.86E+01 1.9E+01 3.7E+00 1.2E+01
8.53E+01 9.8E+00 3.7E+00 1.2E+01
5.16E+01 6.9E+00 3.7E+00 1.2E+01 1000 100
3.37E+01 9.6E+00 3.7E+00 1.2E+01
4.77E+00 6.5E+01 3.7E+00 1.2E+01
1.85E+00 5.7E+01 3.7E+00 1.2E+01
1.85E+00 2.7E+01 3.7E+00 1.2E+01
3.48E+01 1.3E+01 3.7E+00 1.2E+01
3.03E+03 1.0E+00 3.7E+00 1.2E+01
1.67E+01 4.5E+01 3.7E+00 1.2E+01
4.63E+01 3.4E+01 3.7E+00 1.2E+01
5.65E+01 7.8E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-689
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L01-1313-T01-A
CFS-L01-1313-T02-A
CFS-L01-1313-T03-A
CFS-L01-1313-T04-A
CFS-L01-1313-T05-A
CFS-L01-1313-T06-A
CFS-L01-1313-T07-A
CFS-L01-1313-T08-A
CFS-L01-1313-T09-A
CFS-L01-1313-T01-B
CFS-L01-1313-T02-B
CFS-L01-1313-T03-B
CFS-L01-1313-T04-B
CFS-L01-1313-T05-B
CFS-L01-1313-T06-B
CFS-L01-1313-T07-B
CFS-L01-1313-T08-B
CFS-L01-1313-T09-B
CFS-L01-1313-T01-C
CFS-L01-1313-T02-C
CFS-L01-1313-T03-C
CFS-L01-1313-T04-C
CFS-L01-1313-T05-C
CFS-L01-1313-T06-C
CFS-L01-1313-T07-C
CFS-L01-1313-T08-C
CFS-L01-1313-T09-C
CFS-L01-1313-B01-A
CFS-L01-1313-B02-A
CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.13E+06
1 2.10E+06
1 4.80E+05
1 3.52E+05
1 2.02E+05
1 8.71 E+03
1 1.08E+04
1 1.71E+04
1 2.30E+04
1 2.15E+06
1 2.11E+06
1 4.66E+05
1 3.62E+05
1 1.82E+05
1 9.26E+03
1 1.09E+04
1 1.69E+04
1 2.16E+04
1 2.09E+06
1 2.07E+06
1 4.69E+05
1 3.71 E+05
1 1.91 E+05
1 8.93E+03
1 1.09E+04
1 1.69E+04
1 2.32E+04
1 1.42E+01
1 2.13E+06
1 2.14E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.13E+06 6.8E-01 1.6E+00 5.1E+00
2.10E+06 9.8E-01 1.6E+00 5.1E+00
4.80E+05 1.1E+00 1.6E+00 5.1E+00 1000 100
3.52E+05 1.0E+00 1.6E+00 5.1E+00
2.02E+05 5.5E-01 1.6E+00 5.1E+00
8.71 E+03 6.8E-01 1.6E+00 5.1E+00
1.08E+04 1.0E+00 1.6E+00 5.1E+00
1.71E+04 5.8E-01 1.6E+00 5.1E+00
2.30E+04 8.3E-01 1.6E+00 5.1E+00
2.15E+06 1.1E+00 1.6E+00 5.1E+00
2.11E+06 1.1E-01 1.6E+00 5.1E+00
4.66E+05 2.5E-01 1.6E+00 5.1E+00 1000 100
3.62E+05 8.8E+01 1.6E+00 5.1E+00
1.82E+05 6.6E-01 1.6E+00 5.1E+00
9.26E+03 5.8E-01 1.6E+00 5.1E+00
1.09E+04 9.2E-01 1.6E+00 5.1E+00
1.69E+04 8.1E-01 1.6E+00 5.1E+00
2.16E+04 5.1E-01 1.6E+00 5.1E+00
2.09E+06 1.1E+00 1.6E+00 5.1E+00
2.07E+06 7.3E-01 1.6E+00 5.1E+00
4.69E+05 2.4E-01 1.6E+00 5.1E+00 1000 100
3.71 E+05 7.6E-01 1.6E+00 5.1E+00
1.91 E+05 3.5E-01 1.6E+00 5.1E+00
8.93E+03 8.8E-01 1.6E+00 5.1E+00
1.09E+04 8.4E-01 1.6E+00 5.1E+00
1.69E+04 1.0E+00 1.6E+00 5.1E+00
2.32E+04 7.3E-01 1.6E+00 5.1E+00
1.42E+01 2.0E+01 1.6E+00 5.1E+00
2.13E+06 1.6E+00 1.6E+00 5.1E+00
2.14E+06 1.2E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.81 E+05 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.67E+05 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.70E+05 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-690
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L01-1313-T01-A
CFS-L01-1313-T02-A
CFS-L01-1313-T03-A
CFS-L01-1313-T04-A
CFS-L01-1313-T05-A
CFS-L01-1313-T06-A
CFS-L01-1313-T07-A
CFS-L01-1313-T08-A
CFS-L01-1313-T09-A
CFS-L01-1313-T01-B
CFS-L01-1313-T02-B
CFS-L01-1313-T03-B
CFS-L01-1313-T04-B
CFS-L01-1313-T05-B
CFS-L01-1313-T06-B
CFS-L01-1313-T07-B
CFS-L01-1313-T08-B
CFS-L01-1313-T09-B
CFS-L01-1313-T01-C
CFS-L01-1313-T02-C
CFS-L01-1313-T03-C
CFS-L01-1313-T04-C
CFS-L01-1313-T05-C
CFS-L01-1313-T06-C
CFS-L01-1313-T07-C
CFS-L01-1313-T08-C
CFS-L01-1313-T09-C
CFS-L01-1313-B01-A
CFS-L01-1313-B02-A
CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.88E+02
1 4.12E+02
1 5.72E+02
1 1.98E+02
1 8.15E+01
1 7.45E+01
1 1.27E+02
1 2.37E+02
1 5.13E+02
1 2.75E+02
1 4.04E+02
1 5.17E+02
1 2.23E+02
1 9.39E+01
1 6.65E+01
1 1.18E+02
1 2.04E+02
1 4.69E+02
1 2.93E+02
1 3.91 E+02
1 5.15E+02
1 2.25E+02
1 7.70E+01
1 6.96E+01
1 1.09E+02
1 2.46E+02
1 4.70E+02
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.88E+02 2.7E+00 1.5E+01 4.8E+01
4.12E+02 2.1E+00 1.5E+01 4.8E+01
5.72E+02 6.4E-01 1.5E+01 4.8E+01 10 100
1.98E+02 4.7E+00 1.5E+01 4.8E+01
8.15E+01 2.0E+01 1.5E+01 4.8E+01
7.45E+01 5.9E+00 1.5E+01 4.8E+01
1.27E+02 2.0E+01 1.5E+01 4.8E+01
2.37E+02 4.6E+00 1.5E+01 4.8E+01
5.13E+02 4.4E+00 1.5E+01 4.8E+01
2.75E+02 7.9E+00 1.5E+01 4.8E+01
4.04E+02 7.1E-01 1.5E+01 4.8E+01
5.17E+02 1.9E+00 1.5E+01 4.8E+01 10 100
2.23E+02 9.2E+01 1.5E+01 4.8E+01
9.39E+01 9.9E+00 1.5E+01 4.8E+01
6.65E+01 1.6E+01 1.5E+01 4.8E+01
1.18E+02 1.7E+01 1.5E+01 4.8E+01
2.04E+02 8.3E+00 1.5E+01 4.8E+01
4.69E+02 8.7E+00 1.5E+01 4.8E+01
2.93E+02 4.5E+00 1.5E+01 4.8E+01
3.91 E+02 4.7E+00 1.5E+01 4.8E+01
5.15E+02 1.7E+00 1.5E+01 4.8E+01 10 100
2.25E+02 8.5E+00 1.5E+01 4.8E+01
7.70E+01 6.3E+00 1.5E+01 4.8E+01
6.96E+01 1.6E+01 1.5E+01 4.8E+01
1.09E+02 1.7E+01 1.5E+01 4.8E+01
2.46E+02 5.2E+00 1.5E+01 4.8E+01
4.70E+02 3.0E+00 1.5E+01 4.8E+01
7.50E+00 1.8E+02 1.5E+01 4.8E+01
7.50E+00 7.5E+01 1.5E+01 4.8E+01
7.50E+00 1.4E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.56E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.48E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.49E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-691
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si CFS-L01-1313-T01-A
Si CFS-L01-1313-T02-A
Si CFS-L01-1313-T03-A
Si CFS-L01-1313-T04-A
Si CFS-L01-1313-T05-A
Si CFS-L01-1313-T06-A
Si CFS-L01-1313-T07-A
Si CFS-L01-1313-T08-A
Si CFS-L01-1313-T09-A
Si CFS-L01-1313-T01-B
Si CFS-L01-1313-T02-B
Si CFS-L01-1313-T03-B
Si CFS-L01-1313-T04-B
Si CFS-L01-1313-T05-B
Si CFS-L01-1313-T06-B
Si CFS-L01-1313-T07-B
Si CFS-L01-1313-T08-B
Si CFS-L01-1313-T09-B
Si CFS-L01-1313-T01-C
Si CFS-L01-1313-T02-C
Si CFS-L01-1313-T03-C
Si CFS-L01-1313-T04-C
Si CFS-L01-1313-T05-C
Si CFS-L01-1313-T06-C
Si CFS-L01-1313-T07-C
Si CFS-L01-1313-T08-C
Si CFS-L01-1313-T09-C
Si CFS-L01-1313-B01-A
Si CFS-L01-1313-B02-A
Si CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.14E+02
1 2.07E+02
1 4.70E+02
1 4.56E+02
1 1.19E+03
1 3.75E+03
1 2.61E+04
1 1.00E+05
1 1.56E+05
1 2.14E+02
1 2.04E+02
1 5.24E+02
1 4.74E+02
1 1.29E+03
1 3.71 E+03
1 2.50E+04
1 9.43E+04
1 1.51E+05
1 2.43E+02
1 2.49E+02
1 5.31 E+02
1 4.65E+02
1 1.25E+03
1 3.68E+03
1 2.68E+04
1 9.43E+04
1 1.62E+05
1 5.50E-01 U1/2
1 6.99E+02
1 1.40E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.14E+02 2.1E+00 1.1E+00 3.5E+00
2.07E+02 2.2E+00 1.1E+00 3.5E+00
4.70E+02 2.6E+00 1.1E+00 3.5E+00 1000 100
4.56E+02 6.8E-01 1.1E+00 3.5E+00
1.19E+03 1.3E+00 1.1E+00 3.5E+00
3.75E+03 1.0E+00 1.1E+00 3.5E+00
2.61E+04 9.5E-01 1.1E+00 3.5E+00
1.00E+05 4.9E-01 1.1E+00 3.5E+00
1.56E+05 9.7E-01 1.1E+00 3.5E+00
2.14E+02 1.7E+00 1.1E+00 3.5E+00
2.04E+02 6.0E-01 1.1E+00 3.5E+00
5.24E+02 3.3E-01 1.1E+00 3.5E+00 1000 100
4.74E+02 8.2E+01 1.1E+00 3.5E+00
1.29E+03 1.4E+00 1.1E+00 3.5E+00
3.71E+03 5.2E-01 1.1E+00 3.5E+00
2.50E+04 4.4E-01 1.1E+00 3.5E+00
9.43E+04 4.0E-01 1.1E+00 3.5E+00
1.51E+05 6.1E-01 1.1E+00 3.5E+00
2.43E+02 1.8E+00 1.1E+00 3.5E+00
2.49E+02 1.1E+00 1.1E+00 3.5E+00
5.31E+02 1.1E+00 1.1E+00 3.5E+00 1000 100
4.65E+02 5.0E-01 1.1E+00 3.5E+00
1.25E+03 2.3E-01 1.1E+00 3.5E+00
3.68E+03 1.3E+00 1.1E+00 3.5E+00
2.68E+04 6.3E-01 1.1E+00 3.5E+00
9.43E+04 1.3E-01 1.1E+00 3.5E+00
1.62E+05 5.2E-01 1.1E+00 3.5E+00
5.50E-01 1.0E+02 1.1E+00 3.5E+00
6.99E+02 3.0E+00 1.1E+00 3.5E+00
1.40E+03 6.0E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.53E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.40E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.38E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-692
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na CFS-L01-1313-T01-A
Na CFS-L01-1313-T02-A
Na CFS-L01-1313-T03-A
Na CFS-L01-1313-T04-A
Na CFS-L01-1313-T05-A
Na CFS-L01-1313-T06-A
Na CFS-L01-1313-T07-A
Na CFS-L01-1313-T08-A
Na CFS-L01-1313-T09-A
Na CFS-L01-1313-T01-B
Na CFS-L01-1313-T02-B
Na CFS-L01-1313-T03-B
Na CFS-L01-1313-T04-B
Na CFS-L01-1313-T05-B
Na CFS-L01-1313-T06-B
Na CFS-L01-1313-T07-B
Na CFS-L01-1313-T08-B
Na CFS-L01-1313-T09-B
Na CFS-L01-1313-T01-C
Na CFS-L01-1313-T02-C
Na CFS-L01-1313-T03-C
Na CFS-L01-1313-T04-C
Na CFS-L01-1313-T05-C
Na CFS-L01-1313-T06-C
Na CFS-L01-1313-T07-C
Na CFS-L01-1313-T08-C
Na CFS-L01-1313-T09-C
Na CFS-L01-1313-B01-A
Na CFS-L01-1313-B02-A
Na CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.52E+04
1 1.59E+04
1 1.59E+04
1 1.67E+04
1 1.77E+04
1 1.66E+04
1 1.78E+04
1 2.35E+04
1 2.58E+04
1 1.57E+04
1 1.57E+04
1 1.64E+04
1 1.61E+04
1 1.70E+04
1 1.69E+04
1 1.85E+04
1 2.40E+04
1 2.70E+04
1 1.57E+04
1 1.56E+04
1 1.68E+04
1 1.70E+04
1 1.77E+04
1 1.78E+04
1 1.88E+04
1 2.52E+04
1 2.82E+04
1 1.25E+00 U1/2
1 9.89E+02
1 1.01E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.52E+04 3.2E-01 2.5E+00 8.0E+00
1.59E+04 4.2E-01 2.5E+00 8.0E+00
1.59E+04 2.4E-01 2.5E+00 8.0E+00 1000 100
1.67E+04 6.6E-01 2.5E+00 8.0E+00
1.77E+04 8.3E-01 2.5E+00 8.0E+00
1.66E+04 8.1E-01 2.5E+00 8.0E+00
1.78E+04 6.1E-01 2.5E+00 8.0E+00
2.35E+04 7.1E-01 2.5E+00 8.0E+00
2.58E+04 1.1E+00 2.5E+00 8.0E+00
1.57E+04 5.8E-01 2.5E+00 8.0E+00
1.57E+04 8.5E-01 2.5E+00 8.0E+00
1.64E+04 6.8E-01 2.5E+00 8.0E+00 1000 100
1.61E+04 8.9E+01 2.5E+00 8.0E+00
1.70E+04 7.0E-01 2.5E+00 8.0E+00
1.69E+04 7.1E-01 2.5E+00 8.0E+00
1.85E+04 9.0E-01 2.5E+00 8.0E+00
2.40E+04 8.3E-01 2.5E+00 8.0E+00
2.70E+04 1.7E+00 2.5E+00 8.0E+00
1.57E+04 2.6E-01 2.5E+00 8.0E+00
1.56E+04 8.4E-01 2.5E+00 8.0E+00
1.68E+04 5.6E-01 2.5E+00 8.0E+00 1000 100
1.70E+04 6.7E-01 2.5E+00 8.0E+00
1.77E+04 2.1E-01 2.5E+00 8.0E+00
1.78E+04 9.8E-01 2.5E+00 8.0E+00
1.88E+04 1.2E+00 2.5E+00 8.0E+00
2.52E+04 9.9E-01 2.5E+00 8.0E+00
2.82E+04 1.3E+00 2.5E+00 8.0E+00
1.25E+00 3.1E+01 2.5E+00 8.0E+00
9.89E+02 2.6E+00 2.5E+00 8.0E+00
1.01E+03 1.0E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.68E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.74E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.78E+04 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-693
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr CFS-L01-1313-T01-A
Sr CFS-L01-1313-T02-A
Sr CFS-L01-1313-T03-A
Sr CFS-L01-1313-T04-A
Sr CFS-L01-1313-T05-A
Sr CFS-L01-1313-T06-A
Sr CFS-L01-1313-T07-A
Sr CFS-L01-1313-T08-A
Sr CFS-L01-1313-T09-A
Sr CFS-L01-1313-T01-B
Sr CFS-L01-1313-T02-B
Sr CFS-L01-1313-T03-B
Sr CFS-L01-1313-T04-B
Sr CFS-L01-1313-T05-B
Sr CFS-L01-1313-T06-B
Sr CFS-L01-1313-T07-B
Sr CFS-L01-1313-T08-B
Sr CFS-L01-1313-T09-B
Sr CFS-L01-1313-T01-C
Sr CFS-L01-1313-T02-C
Sr CFS-L01-1313-T03-C
Sr CFS-L01-1313-T04-C
Sr CFS-L01-1313-T05-C
Sr CFS-L01-1313-T06-C
Sr CFS-L01-1313-T07-C
Sr CFS-L01-1313-T08-C
Sr CFS-L01-1313-T09-C
Sr CFS-L01-1313-B01-A
Sr CFS-L01-1313-B02-A
Sr CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.77E+03
1 3.55E+03
1 3.79E+03
1 3.65E+03
1 3.49E+03
1 1.37E+03
1 9.29E+02
1 1.34E+03
1 1.39E+03
1 2.53E+03
1 3.42E+03
1 3.73E+03
1 3.68E+03
1 3.28E+03
1 1.41E+03
1 9.36E+02
1 1.35E+03
1 1.32E+03
1 2.81 E+03
1 3.37E+03
1 3.82E+03
1 3.64E+03
1 3.33E+03
1 1.38E+03
1 9.34E+02
1 1.33E+03
1 1.40E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.77E+03 1.7E+00 1.0E+00 3.2E+00
3.55E+03 1.1E+00 1.0E+00 3.2E+00
3.79E+03 1.7E+00 1.0E+00 3.2E+00 1000 100
3.65E+03 1.4E+00 1.0E+00 3.2E+00
3.49E+03 8.9E-01 1.0E+00 3.2E+00
1.37E+03 1.9E+00 1.0E+00 3.2E+00
9.29E+02 1.2E+00 1.0E+00 3.2E+00
1.34E+03 9.4E-01 1.0E+00 3.2E+00
1.39E+03 1.3E+00 1.0E+00 3.2E+00
2.53E+03 1.1E+00 1.0E+00 3.2E+00
3.42E+03 1.8E+00 1.0E+00 3.2E+00
3.73E+03 1.3E+00 1.0E+00 3.2E+00 1000 100
3.68E+03 8.5E+01 1.0E+00 3.2E+00
3.28E+03 1.1E+00 1.0E+00 3.2E+00
1.41 E+03 7.6E-01 1.0E+00 3.2E+00
9.36E+02 1.2E+00 1.0E+00 3.2E+00
1.35E+03 1.2E-01 1.0E+00 3.2E+00
1.32E+03 5.3E-01 1.0E+00 3.2E+00
2.81 E+03 4.7E-01 1.0E+00 3.2E+00
3.37E+03 3.5E-01 1.0E+00 3.2E+00
3.82E+03 7.1E-01 1.0E+00 3.2E+00 1000 100
3.64E+03 9.3E-01 1.0E+00 3.2E+00
3.33E+03 1.1E+00 1.0E+00 3.2E+00
1.38E+03 1.1E+00 1.0E+00 3.2E+00
9.34E+02 3.2E-01 1.0E+00 3.2E+00
1.33E+03 1.0E-01 1.0E+00 3.2E+00
1.40E+03 3.8E-01 1.0E+00 3.2E+00
5.00E-01 3.1E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+02 1.0E+00 3.2E+00
5.00E-01 1.5E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.89E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.71 E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.86E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-694
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S CFS-L01-1313-T01-A
S CFS-L01-1313-T02-A
S CFS-L01-1313-T03-A
S CFS-L01-1313-T04-A
S CFS-L01-1313-T05-A
S CFS-L01-1313-T06-A
S CFS-L01-1313-T07-A
S CFS-L01-1313-T08-A
S CFS-L01-1313-T09-A
S CFS-L01-1313-T01-B
S CFS-L01-1313-T02-B
S CFS-L01-1313-T03-B
S CFS-L01-1313-T04-B
S CFS-L01-1313-T05-B
S CFS-L01-1313-T06-B
S CFS-L01-1313-T07-B
S CFS-L01-1313-T08-B
S CFS-L01-1313-T09-B
S CFS-L01-1313-T01-C
S CFS-L01-1313-T02-C
S CFS-L01-1313-T03-C
S CFS-L01-1313-T04-C
S CFS-L01-1313-T05-C
S CFS-L01-1313-T06-C
S CFS-L01-1313-T07-C
S CFS-L01-1313-T08-C
S CFS-L01-1313-T09-C
S CFS-L01-1313-B01-A
S CFS-L01-1313-B02-A
S CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.27E+06
1 1.01E+06
1 7.73E+05
1 7.59E+05
1 6.94E+05
1 6.18E+05
1 6.47E+05
1 7.31 E+05
1 8.03E+05
1 1.26E+06
1 1.01E+06
1 7.71 E+05
1 7.20E+05
1 7.19E+05
1 6.18E+05
1 6.39E+05
1 7.39E+05
1 8. 12 E+05
1 1.29E+06
1 1.02E+06
1 7.71 E+05
1 7.22E+05
1 7. 11 E+05
1 6. 17 E+05
1 6.47E+05
1 7.41 E+05
1 8.16E+05
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+06 3.4E-01 6.8E+00 2.2E+01
1.01E+06 4.1E-01 6.8E+00 2.2E+01
7.73E+05 2.3E-01 6.8E+00 2.2E+01 1000 100
7.59E+05 6.6E-01 6.8E+00 2.2E+01
6.94E+05 5.2E-01 6.8E+00 2.2E+01
6.18E+05 8.2E-01 6.8E+00 2.2E+01
6.47E+05 7.5E-01 6.8E+00 2.2E+01
7.31 E+05 7.4E-01 6.8E+00 2.2E+01
8.03E+05 1.2E+00 6.8E+00 2.2E+01
1.26E+06 2.7E-01 6.8E+00 2.2E+01
1.01E+06 9.7E-01 6.8E+00 2.2E+01
7.71E+05 3.7E-01 6.8E+00 2.2E+01 1000 100
7.20E+05 8.9E+01 6.8E+00 2.2E+01
7.19E+05 2.6E-02 6.8E+00 2.2E+01
6.18E+05 5.3E-01 6.8E+00 2.2E+01
6.39E+05 1.1E+00 6.8E+00 2.2E+01
7.39E+05 4.7E-01 6.8E+00 2.2E+01
8.12E+05 1.0E+00 6.8E+00 2.2E+01
1.29E+06 2.1E-01 6.8E+00 2.2E+01
1.02E+06 5.0E-01 6.8E+00 2.2E+01
7.71E+05 3.2E-01 6.8E+00 2.2E+01 1000 100
7.22E+05 6.2E-01 6.8E+00 2.2E+01
7.11E+05 4.2E-01 6.8E+00 2.2E+01
6.17E+05 1.1E+00 6.8E+00 2.2E+01
6.47E+05 5.3E-01 6.8E+00 2.2E+01
7.41 E+05 1.0E+00 6.8E+00 2.2E+01
8.16E+05 4.0E-01 6.8E+00 2.2E+01
3.40E+00 3.9E+01 6.8E+00 2.2E+01
3.40E+00 6.8E+00 6.8E+00 2.2E+01
3.40E+00 6.1E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.74E+05 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.73E+05 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.72E+05 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-695
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample Dilutic
CFS-L01-1313-T01-A
CFS-L01-1313-T02-A
CFS-L01-1313-T03-A
CFS-L01-1313-T04-A
CFS-L01-1313-T05-A
CFS-L01-1313-T06-A
CFS-L01-1313-T07-A
CFS-L01-1313-T08-A
CFS-L01-1313-T09-A
CFS-L01-1313-T01-B
CFS-L01-1313-T02-B
CFS-L01-1313-T03-B
CFS-L01-1313-T04-B
CFS-L01-1313-T05-B
CFS-L01-1313-T06-B
CFS-L01-1313-T07-B
CFS-L01-1313-T08-B
CFS-L01-1313-T09-B
CFS-L01-1313-T01-C
CFS-L01-1313-T02-C
CFS-L01-1313-T03-C
CFS-L01-1313-T04-C
CFS-L01-1313-T05-C
CFS-L01-1313-T06-C
CFS-L01-1313-T07-C
CFS-L01-1313-T08-C
CFS-L01-1313-T09-C
CFS-L01-1313-B01-A
CFS-L01-1313-B02-A
CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.91E+02
1 1.97E+02
1 2.94E+02
1 4.54E+02
1 6.84E+02
1 3.18E+02
1 5.68E+02
1 9.84E+02
1 1.60E+03
1 2.06E+02
1 1.89E+02
1 3.07E+02
1 4.50E+02
1 6.59E+02
1 3.16E+02
1 5.65E+02
1 9.74E+02
1 1.60E+03
1 1.98E+02
1 1.86E+02
1 3.18E+02
1 4.60E+02
1 6.75E+02
1 3.18E+02
1 5.75E+02
1 9.99E+02
1 1.63E+03
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 5.67E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.91E+02 5.2E+00 4.6E+00 1.5E+01
1.97E+02 1.3E+00 4.6E+00 1.5E+01
2.94E+02 1.8E+00 4.6E+00 1.5E+01 10 100
4.54E+02 1.8E+00 4.6E+00 1.5E+01
6.84E+02 6.1E-01 4.6E+00 1.5E+01
3.18E+02 6.0E-01 4.6E+00 1.5E+01
5.68E+02 2.1E+00 4.6E+00 1.5E+01
9.84E+02 1.9E+00 4.6E+00 1.5E+01
1.60E+03 9.9E-01 4.6E+00 1.5E+01
2.06E+02 2.2E+00 4.6E+00 1.5E+01
1.89E+02 2.9E+00 4.6E+00 1.5E+01
3.07E+02 1.6E+00 4.6E+00 1.5E+01 10 100
4.50E+02 8.9E+01 4.6E+00 1.5E+01
6.59E+02 7.9E-01 4.6E+00 1.5E+01
3.16E+02 2.1E+00 4.6E+00 1.5E+01
5.65E+02 1.2E+00 4.6E+00 1.5E+01
9.74E+02 3.3E-01 4.6E+00 1.5E+01
1.60E+03 6.3E-01 4.6E+00 1.5E+01
1.98E+02 1.3E+00 4.6E+00 1.5E+01
1.86E+02 3.1E+00 4.6E+00 1.5E+01
3.18E+02 4.4E-01 4.6E+00 1.5E+01 10 100
4.60E+02 1.1E+00 4.6E+00 1.5E+01
6.75E+02 6.5E-01 4.6E+00 1.5E+01
3.18E+02 1.7E+00 4.6E+00 1.5E+01
5.75E+02 2.3E+00 4.6E+00 1.5E+01
9.99E+02 1.6E+00 4.6E+00 1.5E+01
1.63E+03 4.1E-01 4.6E+00 1.5E+01
2.30E+00 3.2E+01 4.6E+00 1.5E+01
2.30E+00 2.1E+01 4.6E+00 1.5E+01
5.67E+00 5.8E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.22E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-696
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutic
CFS-L01-1313-T01-A
CFS-L01-1313-T02-A
CFS-L01-1313-T03-A
CFS-L01-1313-T04-A
CFS-L01-1313-T05-A
CFS-L01-1313-T06-A
CFS-L01-1313-T07-A
CFS-L01-1313-T08-A
CFS-L01-1313-T09-A
CFS-L01-1313-T01-B
CFS-L01-1313-T02-B
CFS-L01-1313-T03-B
CFS-L01-1313-T04-B
CFS-L01-1313-T05-B
CFS-L01-1313-T06-B
CFS-L01-1313-T07-B
CFS-L01-1313-T08-B
CFS-L01-1313-T09-B
CFS-L01-1313-T01-C
CFS-L01-1313-T02-C
CFS-L01-1313-T03-C
CFS-L01-1313-T04-C
CFS-L01-1313-T05-C
CFS-L01-1313-T06-C
CFS-L01-1313-T07-C
CFS-L01-1313-T08-C
CFS-L01-1313-T09-C
CFS-L01-1313-B01-A
CFS-L01-1313-B02-A
CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.82E+00 E
1 2.15E+01
1 4.19E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 2.60E+00 E
1 1.98E+01
1 4.00E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 2.70E+00 E
1 2.04E+01
1 4.13E+01
1 1.00E+OOU1/2
1 1.01E+01
1 3.64E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.8E+00 2.0E+00 6.4E+00
1.00E+00 7.1E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+02 2.0E+00 6.4E+00 10 100
1.00E+00 4.9E+02 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 9.1E+01 2.0E+00 6.4E+00
2.82E+00 5.5E+00 2.0E+00 6.4E+00
2.15E+01 7.1E+00 2.0E+00 6.4E+00
4.19E+01 8.9E-01 2.0E+00 6.4E+00
1.00E+00 7.0E+02 2.0E+00 6.4E+00
1.00E+00 8.1E+01 2.0E+00 6.4E+00
1.00E+00 8.2E+01 2.0E+00 6.4E+00 10 100
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 8.1E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+03 2.0E+00 6.4E+00
2.60E+00 9.7E+00 2.0E+00 6.4E+00
1.98E+01 9.7E+00 2.0E+00 6.4E+00
4.00E+01 7.0E-01 2.0E+00 6.4E+00
1.00E+00 3.1E+02 2.0E+00 6.4E+00
1.00E+00 9.1E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00 10 100
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 6.1E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+01 2.0E+00 6.4E+00
2.70E+00 8.6E+00 2.0E+00 6.4E+00
2.04E+01 1.6E+00 2.0E+00 6.4E+00
4.13E+01 9.5E-01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.01E+01 3.8E-01 2.0E+00 6.4E+00
3.64E+00 1.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-697
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V CFS-L01-1313-T01-A
V CFS-L01-1313-T02-A
V CFS-L01-1313-T03-A
V CFS-L01-1313-T04-A
V CFS-L01-1313-T05-A
V CFS-L01-1313-T06-A
V CFS-L01-1313-T07-A
V CFS-L01-1313-T08-A
V CFS-L01-1313-T09-A
V CFS-L01-1313-T01-B
V CFS-L01-1313-T02-B
V CFS-L01-1313-T03-B
V CFS-L01-1313-T04-B
V CFS-L01-1313-T05-B
V CFS-L01-1313-T06-B
V CFS-L01-1313-T07-B
V CFS-L01-1313-T08-B
V CFS-L01-1313-T09-B
V CFS-L01-1313-T01-C
V CFS-L01-1313-T02-C
V CFS-L01-1313-T03-C
V CFS-L01-1313-T04-C
V CFS-L01-1313-T05-C
V CFS-L01-1313-T06-C
V CFS-L01-1313-T07-C
V CFS-L01-1313-T08-C
V CFS-L01-1313-T09-C
V CFS-L01-1313-B01-A
V CFS-L01-1313-B02-A
V CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.56E+01
1 2.41 E+01
1 2.58E+01
1 2.66E+01
1 2.89E+01
1 2.84E+01
1 3.71 E+01
1 5.57E+01
1 5.03E+02
1 2.70E+01
1 2.43E+01
1 2.57E+01
1 2.59E+01
1 2.64E+01
1 2.94E+01
1 3.70E+01
1 4.89E+01
1 5.08E+02
1 2.78E+01
1 2.31 E+01
1 2.56E+01
1 2.77E+01
1 2.86E+01
1 3.03E+01
1 3.71 E+01
1 5.22E+01
1 4.81 E+02
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 3.66E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.56E+01 3.7E+00 1.5E+00 4.8E+00
2.41 E+01 6.0E+00 1.5E+00 4.8E+00
2.58E+01 1.5E+00 1.5E+00 4.8E+00 10 100
2.66E+01 2.9E+00 1.5E+00 4.8E+00
2.89E+01 2.5E+00 1.5E+00 4.8E+00
2.84E+01 6.5E+00 1.5E+00 4.8E+00
3.71 E+01 3.3E+00 1.5E+00 4.8E+00
5.57E+01 1.6E+00 1.5E+00 4.8E+00
5.03E+02 1.1E+00 1.5E+00 4.8E+00
2.70E+01 5.4E+00 1.5E+00 4.8E+00
2.43E+01 3.5E+00 1.5E+00 4.8E+00
2.57E+01 8.1E+00 1.5E+00 4.8E+00 10 100
2.59E+01 8.8E+01 1.5E+00 4.8E+00
2.64E+01 2.1E+00 1.5E+00 4.8E+00
2.94E+01 2.4E+00 1.5E+00 4.8E+00
3.70E+01 1.3E+00 1.5E+00 4.8E+00
4.89E+01 1.1 E+01 1.5E+00 4.8E+00
5.08E+02 1.8E+00 1.5E+00 4.8E+00
2.78E+01 3.7E+00 1.5E+00 4.8E+00
2.31 E+01 7.6E+00 1.5E+00 4.8E+00
2.56E+01 3.0E+00 1.5E+00 4.8E+00 10 100
2.77E+01 3.4E+00 1.5E+00 4.8E+00
2.86E+01 5.1E-01 1.5E+00 4.8E+00
3.03E+01 5.8E+00 1.5E+00 4.8E+00
3.71 E+01 3.5E-01 1.5E+00 4.8E+00
5.22E+01 5.6E+00 1.5E+00 4.8E+00
4.81 E+02 1.3E+00 1.5E+00 4.8E+00
7.50E-01 1.0E+02 1.5E+00 4.8E+00
7.50E-01 5.2E+01 1.5E+00 4.8E+00
3.66E+00 1.6E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/1 1 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-698
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn CFS-L01-1313-T01-A
Zn CFS-L01-1313-T02-A
Zn CFS-L01-1313-T03-A
Zn CFS-L01-1313-T04-A
Zn CFS-L01-1313-T05-A
Zn CFS-L01-1313-T06-A
Zn CFS-L01-1313-T07-A
Zn CFS-L01-1313-T08-A
Zn CFS-L01-1313-T09-A
Zn CFS-L01-1313-T01-B
Zn CFS-L01-1313-T02-B
Zn CFS-L01-1313-T03-B
Zn CFS-L01-1313-T04-B
Zn CFS-L01-1313-T05-B
Zn CFS-L01-1313-T06-B
Zn CFS-L01-1313-T07-B
Zn CFS-L01-1313-T08-B
Zn CFS-L01-1313-T09-B
Zn CFS-L01-1313-T01-C
Zn CFS-L01-1313-T02-C
Zn CFS-L01-1313-T03-C
Zn CFS-L01-1313-T04-C
Zn CFS-L01-1313-T05-C
Zn CFS-L01-1313-T06-C
Zn CFS-L01-1313-T07-C
Zn CFS-L01-1313-T08-C
Zn CFS-L01-1313-T09-C
Zn CFS-L01-1313-B01-A
Zn CFS-L01-1313-B02-A
Zn CFS-L01-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.59E+03
1 3.11E+03
1 3.84E+01
1 9.39E+00
1 2.45E+02
1 2.04E+04
1 1.76E+05
1 1.92E+05
1 1.75E+05
1 6.22E+03
1 3.24E+03
1 3.10E+01
1 9.71 E+00
1 2.99E+02
1 1.99E+04
1 1.72E+05
1 1.85E+05
1 1.79E+05
1 5.95E+03
1 2.59E+03
1 2.93E+01
1 1.10E+01
1 2.63E+02
1 2.08E+04
1 1.76E+05
1 1.97E+05
1 1.84E+05
1 1.97E+00 E
1 1.50E+00 E
1 1.23E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.59E+03 1.9E+00 1.0E+00 3.2E+00
3.11E+03 6.8E-01 1.0E+00 3.2E+00
3.84E+01 1.8E+00 1.0E+00 3.2E+00 10 100
9.39E+00 1.2E+00 1.0E+00 3.2E+00
2.45E+02 5.5E-01 1.0E+00 3.2E+00
2.04E+04 9.9E-02 1.0E+00 3.2E+00
1.76E+05 1.1 E+00 1.0E+00 3.2E+00
1.92E+05 1.5E+00 1.0E+00 3.2E+00
1.75E+05 2.7E+00 1.0E+00 3.2E+00
6.22E+03 1.7E+00 1.0E+00 3.2E+00
3.24E+03 1.2E+00 1.0E+00 3.2E+00
3.10E+01 1.1 E+00 1.0E+00 3.2E+00 10 100
9.71 E+00 8.8E+01 1.0E+00 3.2E+00
2.99E+02 9.5E-01 1.0E+00 3.2E+00
1.99E+04 1.2E+00 1.0E+00 3.2E+00
1.72E+05 6.8E-01 1.0E+00 3.2E+00
1.85E+05 2.5E+00 1.0E+00 3.2E+00
1.79E+05 4.3E+00 1.0E+00 3.2E+00
5.95E+03 7.0E-01 1.0E+00 3.2E+00
2.59E+03 3.5E-01 1.0E+00 3.2E+00
2.93E+01 2.3E-01 1.0E+00 3.2E+00 10 100
1.10E+01 6.0E+00 1.0E+00 3.2E+00
2.63E+02 1.6E-01 1.0E+00 3.2E+00
2.08E+04 1.3E+00 1.0E+00 3.2E+00
1.76E+05 1.6E+00 1.0E+00 3.2E+00
1.97E+05 4.8E+00 1.0E+00 3.2E+00
1.84E+05 2.7E+00 1.0E+00 3.2E+00
1.97E+00 1.0E+01 1.0E+00 3.2E+00
1.50E+00 1.9E+01 1.0E+00 3.2E+00
1.23E+00 1.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 2:27 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:28 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:30 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:32 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:33 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:35 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:36 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:38 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:40 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:48 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:50 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:51 PM EPA Interlab L01 1313-1316CFS
3/1/11 2:53 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:55 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:56 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:58 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:00 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:01 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:03 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:05 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:06 PM EPA Interlab L01 1313-1316CFS
3/1/11 3:08 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:10 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:11 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:13 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:15 PM EPA Interlab L01 1313-1316 CFS
3/1/11 3:16 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:22 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:23 PM EPA Interlab L01 1313-1316 CFS
3/1/11 2:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                          1-699
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L04-1313-T01-A 1 1.10E+02
CFS-L04-1313-T02-A 1 1.08E+02
CFS-L04-1313-T03-A 1 9.09E+01
CFS-L04-1313-T04-A 1 7.36E+01
CFS-L04-1313-T05-A 1 4.86E+01
CFS-L04-1313-T06-A 1 4.78E+01
CFS-L04-1313-T07-A 1 1.97E+03
CFS-L04-1313-T08-A 1 3.21E+04
CFS-L04-1313-T09-A 1 9.63E+04
CFS-L04-1313-T01-B 1 1.40E+02
CFS-L04-1313-T02-B 1 1.71E+02
CFS-L04-1313-T03-B 1 1.16E+02
CFS-L04-1313-T04-B 1 6.16E+01
CFS-L04-1313-T05-B 1 4.70E+01
CFS-L04-1313-T06-B 1 5.48E+01
CFS-L04-1313-T07-B 1 6.39E+03
CFS-L04-1313-T08-B 1 2.99E+04
CFS-L04-1313-T09-B 1 9.07E+04
CFS-L04-1313-T01-C 1 1.15E+02
CFS-L04-1313-T02-C 1 1.18E+02
CFS-L04-1313-T03-C 1 9.79E+01
CFS-L04-1313-T04-C 1 6.12E+01
CFS-L04-1313-T05-C 1 4.15E+01
CFS-L04-1313-T06-C 1 5.46E+01
CFS-L04-1313-T07-C 1 6.51 E+03
CFS-L04-1313-T08-C 1 6.31 E+04
CFS-L04-1313-T09-C 1 9.25E+04
CFS-L04-1313-B01-A 1 5.00E-01 U1/2
CFS-L04-1313-B02-A 1 5.00E-01 U1/2
CFS-L04-1313-B03-A 1 5.00E-01 U1/2
CFS-L04-1313-B01-B 1 5.00E-01 U1/2
CFS-L04-1313-B02-B 1 9.89E+00
CFS-L04-1313-B03-B 1 5.00E-01 U1/2
CFS-L04-1313-B01-C 1 5.00E-01 U1/2
CFS-L04-1313-B02-C 1 5.00E-01 U1/2
CFS-L04-1313-B03-C 1 5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+02 1.7E+00 1.0E+00 3.2E+00
1.08E+02 2.0E+00 1.0E+00 3.2E+00 1000 100
9.09E+01 1.3E+00 1.0E+00 3.2E+00
7.36E+01 4.7E+00 1.0E+00 3.2E+00
4.86E+01 5.1E+00 1.0E+00 3.2E+00
4.78E+01 4.8E+00 1.0E+00 3.2E+00
1.97E+03 1.3E+00 1.0E+00 3.2E+00
3.21 E+04 5.8E-01 1.0E+00 3.2E+00
9.63E+04 8.9E-01 1.0E+00 3.2E+00
1.40E+02 1.5E+00 1.0E+00 3.2E+00
1.71E+02 1.7E+00 1.0E+00 3.2E+00 1000 100
1.16E+02 1.4E+00 1.0E+00 3.2E+00
6.16E+01 1.7E+00 1.0E+00 3.2E+00
4.70E+01 5.2E+00 1.0E+00 3.2E+00
5.48E+01 3.7E+00 1.0E+00 3.2E+00
6.39E+03 8.4E-01 1.0E+00 3.2E+00
2.99E+04 1.2E+00 1.0E+00 3.2E+00
9.07E+04 1.5E+00 1.0E+00 3.2E+00
1.15E+02 1.4E+00 1.0E+00 3.2E+00
1.18E+02 3.1E+00 1.0E+00 3.2E+00 1000 100
9.79E+01 1.9E+00 1.0E+00 3.2E+00
6.12E+01 4.1E+00 1.0E+00 3.2E+00
4.15E+01 7.0E+00 1.0E+00 3.2E+00
5.46E+01 5.0E+00 1.0E+00 3.2E+00
6.51 E+03 1.3E+00 1.0E+00 3.2E+00
6.31 E+04 2.2E-01 1.0E+00 3.2E+00
9.25E+04 1.2E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
5.00E-01 3.9E+01 1.0E+00 3.2E+00
5.00E-01 2.0E+02 1.0E+00 3.2E+00
5.00E-01 5.3E+01 1.0E+00 3.2E+00
9.89E+00 1.9E+01 1.0E+00 3.2E+00
5.00E-01 4.8E+01 1.0E+00 3.2E+00
5.00E-01 3.7E+01 1.0E+00 3.2E+00
5.00E-01 4.1E+01 1.0E+00 3.2E+00
5.00E-01 2.5E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.27E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316CFS
                                                                                                                                                                                     1-700
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb CFS-L04-1313-T01-A
Sb CFS-L04-1313-T02-A
Sb CFS-L04-1313-T03-A
Sb CFS-L04-1313-T04-A
Sb CFS-L04-1313-T05-A
Sb CFS-L04-1313-T06-A
Sb CFS-L04-1313-T07-A
Sb CFS-L04-1313-T08-A
Sb CFS-L04-1313-T09-A
Sb CFS-L04-1313-T01-B
Sb CFS-L04-1313-T02-B
Sb CFS-L04-1313-T03-B
Sb CFS-L04-1313-T04-B
Sb CFS-L04-1313-T05-B
Sb CFS-L04-1313-T06-B
Sb CFS-L04-1313-T07-B
Sb CFS-L04-1313-T08-B
Sb CFS-L04-1313-T09-B
Sb CFS-L04-1313-T01-C
Sb CFS-L04-1313-T02-C
Sb CFS-L04-1313-T03-C
Sb CFS-L04-1313-T04-C
Sb CFS-L04-1313-T05-C
Sb CFS-L04-1313-T06-C
Sb CFS-L04-1313-T07-C
Sb CFS-L04-1313-T08-C
Sb CFS-L04-1313-T09-C
Sb CFS-L04-1313-B01-A
Sb CFS-L04-1313-B02-A
Sb CFS-L04-1313-B03-A
Sb CFS-L04-1313-B01-B
Sb CFS-L04-1313-B02-B
Sb CFS-L04-1313-B03-B
Sb CFS-L04-1313-B01-C
Sb CFS-L04-1313-B02-C
Sb CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.21E+01
1 2.88E+01
1 3.01 E+01
1 3.44E+01
1 7. 11 E+01
1 6.81 E+02
1 1.69E+03
1 3.75E+00 U1/2
1 1.33E+01 E
1 2.65E+01
1 4.37E+01
1 2.67E+01
1 3.64E+01
1 1.55E+02
1 8.23E+02
1 1.47E+03
1 8.21 E+00 E
1 3.75E+00 U1/2
1 2.70E+01
1 4.05E+01
1 1.71E+01 E
1 3.21E+01
1 1.84E+02
1 1.73E+03
1 1.51E+03
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 8.52E+00 E
1 3.75E+00 U1/2
1 1.43E+01 E
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 1.22E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 1.2E+02 7.5E+00 2.4E+01
3.75E+00 1.4E+02 7.5E+00 2.4E+01 10 100
3.21 E+01 1.4E+01 7.5E+00 2.4E+01
2.88E+01 5.5E+00 7.5E+00 2.4E+01
3.01 E+01 3.2E+01 7.5E+00 2.4E+01
3.44E+01 2.2E+01 7.5E+00 2.4E+01
7. 11 E+01 4.2E+00 7.5E+00 2.4E+01
6.81 E+02 5.3E+00 7.5E+00 2.4E+01
1.69E+03 5.5E+00 7.5E+00 2.4E+01
3.75E+00 8.5E+01 7.5E+00 2.4E+01
1.33E+01 7.0E+01 7.5E+00 2.4E+01 10 100
2.65E+01 3.0E+01 7.5E+00 2.4E+01
4.37E+01 1.7E+01 7.5E+00 2.4E+01
2.67E+01 4.6E+01 7.5E+00 2.4E+01
3.64E+01 3.6E+01 7.5E+00 2.4E+01
1.55E+02 1.2E+01 7.5E+00 2.4E+01
8.23E+02 1.1E+01 7.5E+00 2.4E+01
1.47E+03 4.2E+00 7.5E+00 2.4E+01
8.21 E+00 1.2E+02 7.5E+00 2.4E+01
3.75E+00 2.0E+02 7.5E+00 2.4E+01 10 100
2.70E+01 1.9E+01 7.5E+00 2.4E+01
4.05E+01 1.9E+01 7.5E+00 2.4E+01
1.71E+01 4.0E+01 7.5E+00 2.4E+01
3.21 E+01 1.1 E+01 7.5E+00 2.4E+01
1.84E+02 9.1 E+00 7.5E+00 2.4E+01
1.73E+03 1.3E+01 7.5E+00 2.4E+01
1.51E+03 2.8E+00 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
3.75E+00 8.4E+01 7.5E+00 2.4E+01
8.52E+00 6.8E+01 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
1.43E+01 2.7E+01 7.5E+00 2.4E+01
3.75E+00 2.1 E+02 7.5E+00 2.4E+01
3.75E+00 1.1 E+02 7.5E+00 2.4E+01
3.75E+00 4.7E+01 7.5E+00 2.4E+01
1.22E+01 1.2E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.14E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-701
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As CFS-L04-1313-T01-A
As CFS-L04-1313-T02-A
As CFS-L04-1313-T03-A
As CFS-L04-1313-T04-A
As CFS-L04-1313-T05-A
As CFS-L04-1313-T06-A
As CFS-L04-1313-T07-A
As CFS-L04-1313-T08-A
As CFS-L04-1313-T09-A
As CFS-L04-1313-T01-B
As CFS-L04-1313-T02-B
As CFS-L04-1313-T03-B
As CFS-L04-1313-T04-B
As CFS-L04-1313-T05-B
As CFS-L04-1313-T06-B
As CFS-L04-1313-T07-B
As CFS-L04-1313-T08-B
As CFS-L04-1313-T09-B
As CFS-L04-1313-T01-C
As CFS-L04-1313-T02-C
As CFS-L04-1313-T03-C
As CFS-L04-1313-T04-C
As CFS-L04-1313-T05-C
As CFS-L04-1313-T06-C
As CFS-L04-1313-T07-C
As CFS-L04-1313-T08-C
As CFS-L04-1313-T09-C
As CFS-L04-1313-B01-A
As CFS-L04-1313-B02-A
As CFS-L04-1313-B03-A
As CFS-L04-1313-B01-B
As CFS-L04-1313-B02-B
As CFS-L04-1313-B03-B
As CFS-L04-1313-B01-C
As CFS-L04-1313-B02-C
As CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.79E+02
1 2.33E+02
1 7.69E+01
1 4.20E+01
1 3.22E+01 E
1 1.23E+01 E
1 8.31 E+01
1 1.02E+03
1 1.22E+05
1 4.35E+02
1 2.16E+02
1 1.11E+02
1 3.56E+01
1 2.58E+01 E
1 3.46E+01 E
1 1.92E+02
1 9.40E+02
1 9.07E+04
1 3.90E+02
1 3.21 E+02
1 1.29E+02
1 5.00E+01
1 2.14E+01 E
1 2.60E+01 E
1 1.75E+02
1 5.31 E+03
1 7.54E+04
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 1.88E+01 E
1 5.50E+00 U1/2
1 3.45E+01 E
1 5.50E+00 U1/2
1 1.17E+01 E
1 5.50E+00 U1/2
1 1.52E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.79E+02 5.8E+00 1.1E+01 3.5E+01
2.33E+02 6.1E+00 1.1E+01 3.5E+01 10 100
7.69E+01 3.7E-01 1.1E+01 3.5E+01
4.20E+01 7.8E+00 1.1E+01 3.5E+01
3.22E+01 1.6E+01 1.1E+01 3.5E+01
1.23E+01 6.7E+00 1.1E+01 3.5E+01
8.31E+01 1.0E+01 1.1E+01 3.5E+01
1.02E+03 2.0E+00 1.1E+01 3.5E+01
1.22E+05 1.4E+00 1.1E+01 3.5E+01
4.35E+02 1.7E+00 1.1E+01 3.5E+01
2.16E+02 9.7E-01 1.1E+01 3.5E+01 10 100
1.11E+02 4.1E+00 1.1E+01 3.5E+01
3.56E+01 6.4E+00 1.1E+01 3.5E+01
2.58E+01 2.7E+01 1.1E+01 3.5E+01
3.46E+01 2.2E+01 1.1E+01 3.5E+01
1.92E+02 3.5E+00 1.1E+01 3.5E+01
9.40E+02 2.2E+00 1.1E+01 3.5E+01
9.07E+04 6.9E-01 1.1E+01 3.5E+01
3.90E+02 3.6E+00 1.1E+01 3.5E+01
3.21E+02 1.4E+00 1.1E+01 3.5E+01 10 100
1.29E+02 1.1E+00 1.1E+01 3.5E+01
5.00E+01 1.8E+01 1.1E+01 3.5E+01
2.14E+01 4.2E+01 1.1E+01 3.5E+01
2.60E+01 2.1E+01 1.1E+01 3.5E+01
1.75E+02 5.5E+00 1.1E+01 3.5E+01
5.31E+03 2.3E+00 1.1E+01 3.5E+01
7.54E+04 1.5E+00 1.1E+01 3.5E+01
5.50E+00 2.9E+03 1.1E+01 3.5E+01
5.50E+00 2.6E+02 1.1E+01 3.5E+01
1.88E+01 7.1E+00 1.1E+01 3.5E+01
5.50E+00 7.2E+01 1.1E+01 3.5E+01
3.45E+01 1.3E+01 1.1 E+01 3.5E+01
5.50E+00 6.2E+00 1.1 E+01 3.5E+01
1.17E+01 4.0E+01 1.1 E+01 3.5E+01
5.50E+00 5.6E+01 1.1E+01 3.5E+01
1.52E+01 2.8E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.41E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.39E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.51E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-702
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B CFS-L04-1313-T01-A
B CFS-L04-1313-T02-A
B CFS-L04-1313-T03-A
B CFS-L04-1313-T04-A
B CFS-L04-1313-T05-A
B CFS-L04-1313-T06-A
B CFS-L04-1313-T07-A
B CFS-L04-1313-T08-A
B CFS-L04-1313-T09-A
B CFS-L04-1313-T01-B
B CFS-L04-1313-T02-B
B CFS-L04-1313-T03-B
B CFS-L04-1313-T04-B
B CFS-L04-1313-T05-B
B CFS-L04-1313-T06-B
B CFS-L04-1313-T07-B
B CFS-L04-1313-T08-B
B CFS-L04-1313-T09-B
B CFS-L04-1313-T01-C
B CFS-L04-1313-T02-C
B CFS-L04-1313-T03-C
B CFS-L04-1313-T04-C
B CFS-L04-1313-T05-C
B CFS-L04-1313-T06-C
B CFS-L04-1313-T07-C
B CFS-L04-1313-T08-C
B CFS-L04-1313-T09-C
B CFS-L04-1313-B01-A
B CFS-L04-1313-B02-A
B CFS-L04-1313-B03-A
B CFS-L04-1313-B01-B
B CFS-L04-1313-B02-B
B CFS-L04-1313-B03-B
B CFS-L04-1313-B01-C
B CFS-L04-1313-B02-C
B CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 7.88E+01
1 7.75E+01
1 1.55E+02
1 1.26E+02
1 1.55E+02
1 1.56E+02
1 2.74E+02
1 6.45E+02
1 7.44E+02
1 8.21E+01
1 6.39E+01
1 1.65E+02
1 1.07E+02
1 1.44E+02
1 1.74E+02
1 3.41 E+02
1 6.12E+02
1 6.74E+02
1 4.33E+01
1 4.35E+01
1 1.25E+02
1 9.02E+01
1 1.03E+02
1 1.52E+02
1 3.62E+02
1 6.87E+02
1 7.52E+02
1 1.28E+01
1 2.29E+01
1 3.89E+01
1 3.19E+00
1 1.02E+01
1 1.47E+01
1 3.07E+00 E
1 6.80E+00
1 3.60E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.88E+01 3.5E+00 1.0E+00 3.2E+00
7.75E+01 2.1E-01 1.0E+00 3.2E+00 1000 100
1.55E+02 1.5E+00 1.0E+00 3.2E+00
1.26E+02 2.6E+00 1.0E+00 3.2E+00
1.55E+02 8.9E-01 1.0E+00 3.2E+00
1.56E+02 2.2E+00 1.0E+00 3.2E+00
2.74E+02 1.5E-01 1.0E+00 3.2E+00
6.45E+02 9.7E-01 1.0E+00 3.2E+00
7.44E+02 6.4E-01 1.0E+00 3.2E+00
8.21 E+01 3.0E+00 1.0E+00 3.2E+00
6.39E+01 3.9E+00 1.0E+00 3.2E+00 1000 100
1.65E+02 1.6E+00 1.0E+00 3.2E+00
1.07E+02 1.4E+00 1.0E+00 3.2E+00
1.44E+02 2.1E+00 1.0E+00 3.2E+00
1.74E+02 2.3E+00 1.0E+00 3.2E+00
3.41 E+02 9.2E-01 1.0E+00 3.2E+00
6.12E+02 1.6E+00 1.0E+00 3.2E+00
6.74E+02 1.3E+00 1.0E+00 3.2E+00
4.33E+01 3.8E+00 1.0E+00 3.2E+00
4.35E+01 3.1E+00 1.0E+00 3.2E+00 1000 100
1.25E+02 1.3E+00 1.0E+00 3.2E+00
9.02E+01 1.6E+00 1.0E+00 3.2E+00
1.03E+02 1.7E+00 1.0E+00 3.2E+00
1.52E+02 1.2E+00 1.0E+00 3.2E+00
3.62E+02 7.0E-01 1.0E+00 3.2E+00
6.87E+02 1.1E+00 1.0E+00 3.2E+00
7.52E+02 8.0E-01 1.0E+00 3.2E+00
1.28E+01 1.6E+01 1.0E+00 3.2E+00
2.29E+01 1.2E+01 1.0E+00 3.2E+00
3.89E+01 6.0E-01 1.0E+00 3.2E+00
3.19E+00 2.9E+01 1.0E+00 3.2E+00
1.02E+01 7.0E+00 1.0E+00 3.2E+00
1.47E+01 1.6E+01 1.0E+00 3.2E+00
3.07E+00 1.1 E+02 1.0E+00 3.2E+00
6.80E+00 2.2E+01 1.0E+00 3.2E+00
3.60E+01 4.7E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.22E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316CFS
                                                                                                                                                                          1-703
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba CFS-L04-1313-T01-A
Ba CFS-L04-1313-T02-A
Ba CFS-L04-1313-T03-A
Ba CFS-L04-1313-T04-A
Ba CFS-L04-1313-T05-A
Ba CFS-L04-1313-T06-A
Ba CFS-L04-1313-T07-A
Ba CFS-L04-1313-T08-A
Ba CFS-L04-1313-T09-A
Ba CFS-L04-1313-T01-B
Ba CFS-L04-1313-T02-B
Ba CFS-L04-1313-T03-B
Ba CFS-L04-1313-T04-B
Ba CFS-L04-1313-T05-B
Ba CFS-L04-1313-T06-B
Ba CFS-L04-1313-T07-B
Ba CFS-L04-1313-T08-B
Ba CFS-L04-1313-T09-B
Ba CFS-L04-1313-T01-C
Ba CFS-L04-1313-T02-C
Ba CFS-L04-1313-T03-C
Ba CFS-L04-1313-T04-C
Ba CFS-L04-1313-T05-C
Ba CFS-L04-1313-T06-C
Ba CFS-L04-1313-T07-C
Ba CFS-L04-1313-T08-C
Ba CFS-L04-1313-T09-C
Ba CFS-L04-1313-B01-A
Ba CFS-L04-1313-B02-A
Ba CFS-L04-1313-B03-A
Ba CFS-L04-1313-B01-B
Ba CFS-L04-1313-B02-B
Ba CFS-L04-1313-B03-B
Ba CFS-L04-1313-B01-C
Ba CFS-L04-1313-B02-C
Ba CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.50E+02
1 6.86E+01
1 2.83E+02
1 2.04E+02
1 2.27E+02
1 2.27E+02
1 9.92E+01
1 1.01E+02
1 1.11E+02
1 1.64E+02
1 7.32E+01
1 3.63E+02
1 1.90E+02
1 2.25E+02
1 1.46E+02
1 1.04E+02
1 1.12E+02
1 1.08E+02
1 1.43E+02
1 6.61 E+01
1 3.41 E+02
1 1.88E+02
1 2.17E+02
1 1.87E+02
1 9.93E+01
1 1.76E+02
1 1.07E+02
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 3.06E+00 E
1 5.00E-01 U1/2
1 3.66E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 4.42E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.50E+02 3.2E+00 1.0E+00 3.2E+00
6.86E+01 8.4E-01 1.0E+00 3.2E+00 10 100
2.83E+02 2.8E-01 1.0E+00 3.2E+00
2.04E+02 7.2E-01 1.0E+00 3.2E+00
2.27E+02 3.0E-01 1.0E+00 3.2E+00
2.27E+02 7.8E-01 1.0E+00 3.2E+00
9.92E+01 2.1E+00 1.0E+00 3.2E+00
1.01 E+02 3.8E+00 1.0E+00 3.2E+00
1.11E+02 1.1E+00 1.0E+00 3.2E+00
1.64E+02 1.1E+00 1.0E+00 3.2E+00
7.32E+01 1.1E+00 1.0E+00 3.2E+00 10 100
3.63E+02 9.1E-01 1.0E+00 3.2E+00
1.90E+02 5.0E-01 1.0E+00 3.2E+00
2.25E+02 2.8E-01 1.0E+00 3.2E+00
1.46E+02 7.2E-01 1.0E+00 3.2E+00
1.04E+02 6.0E-01 1.0E+00 3.2E+00
1.12E+02 2.2E+00 1.0E+00 3.2E+00
1.08E+02 1.9E+00 1.0E+00 3.2E+00
1.43E+02 1.8E+00 1.0E+00 3.2E+00
6.61E+01 7.5E-01 1.0E+00 3.2E+00 10 100
3.41 E+02 3.5E-01 1.0E+00 3.2E+00
1.88E+02 1.5E-01 1.0E+00 3.2E+00
2.17E+02 1.1E+00 1.0E+00 3.2E+00
1.87E+02 5.7E-01 1.0E+00 3.2E+00
9.93E+01 7.6E-01 1.0E+00 3.2E+00
1.76E+02 6.2E+00 1.0E+00 3.2E+00
1.07E+02 2.5E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+02 1.0E+00 3.2E+00
5.00E-01 3.4E+01 1.0E+00 3.2E+00
3.06E+00 2.5E+01 1.0E+00 3.2E+00
5.00E-01 2.3E+01 1.0E+00 3.2E+00
3.66E+00 1.8E+01 1.0E+00 3.2E+00
5.00E-01 7.1 E+02 1.0E+00 3.2E+00
5.00E-01 1.8E+01 1.0E+00 3.2E+00
5.00E-01 1.9E+03 1.0E+00 3.2E+00
4.42E+00 4.6E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.97E+02 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.47E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-704
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be CFS-L04-1313-T01-A
Be CFS-L04-1313-T02-A
Be CFS-L04-1313-T03-A
Be CFS-L04-1313-T04-A
Be CFS-L04-1313-T05-A
Be CFS-L04-1313-T06-A
Be CFS-L04-1313-T07-A
Be CFS-L04-1313-T08-A
Be CFS-L04-1313-T09-A
Be CFS-L04-1313-T01-B
Be CFS-L04-1313-T02-B
Be CFS-L04-1313-T03-B
Be CFS-L04-1313-T04-B
Be CFS-L04-1313-T05-B
Be CFS-L04-1313-T06-B
Be CFS-L04-1313-T07-B
Be CFS-L04-1313-T08-B
Be CFS-L04-1313-T09-B
Be CFS-L04-1313-T01-C
Be CFS-L04-1313-T02-C
Be CFS-L04-1313-T03-C
Be CFS-L04-1313-T04-C
Be CFS-L04-1313-T05-C
Be CFS-L04-1313-T06-C
Be CFS-L04-1313-T07-C
Be CFS-L04-1313-T08-C
Be CFS-L04-1313-T09-C
Be CFS-L04-1313-B01-A
Be CFS-L04-1313-B02-A
Be CFS-L04-1313-B03-A
Be CFS-L04-1313-B01-B
Be CFS-L04-1313-B02-B
Be CFS-L04-1313-B03-B
Be CFS-L04-1313-B01-C
Be CFS-L04-1313-B02-C
Be CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.30E+00 E
1 8.66E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 3.32E+00 E
1 6.46E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 3.61E+OOE
1 7.18E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 3.7E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+01 1.9E+00 6.0E+00 10 100
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 6.2E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
2.30E+00 4.8E+00 1.9E+00 6.0E+00
8.66E+00 1.4E+00 1.9E+00 6.0E+00
9.50E-01 6.7E+00 1.9E+00 6.0E+00
9.50E-01 4.2E+01 1.9E+00 6.0E+00
9.50E-01 2.5E+01 1.9E+00 6.0E+00 10 100
9.50E-01 6.5E+02 1.9E+00 6.0E+00
9.50E-01 5.6E+01 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 6.0E+01 1.9E+00 6.0E+00
3.32E+00 2.7E+00 1.9E+00 6.0E+00
6.46E+00 2.0E+01 1.9E+00 6.0E+00
9.50E-01 3.4E+00 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 9.1E+01 1.9E+00 6.0E+00 10 100
9.50E-01 7.3E+02 1.9E+00 6.0E+00
9.50E-01 8.3E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 5.9E+00 1.9E+00 6.0E+00
3.61 E+00 4.3E+00 1.9E+00 6.0E+00
7.18E+00 3.0E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
9.50E-01 2.2E+01 1.9E+00 6.0E+00
9.50E-01 6.8E+00 1.9E+00 6.0E+00
9.50E-01 1.3E+01 1.9E+00 6.0E+00
9.50E-01 2.8E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 4.3E+01 1.9E+00 6.0E+00
9.50E-01 6.0E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-705
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd CFS-L04-1313-T01-A
Cd CFS-L04-1313-T02-A
Cd CFS-L04-1313-T03-A
Cd CFS-L04-1313-T04-A
Cd CFS-L04-1313-T05-A
Cd CFS-L04-1313-T06-A
Cd CFS-L04-1313-T07-A
Cd CFS-L04-1313-T08-A
Cd CFS-L04-1313-T09-A
Cd CFS-L04-1313-T01-B
Cd CFS-L04-1313-T02-B
Cd CFS-L04-1313-T03-B
Cd CFS-L04-1313-T04-B
Cd CFS-L04-1313-T05-B
Cd CFS-L04-1313-T06-B
Cd CFS-L04-1313-T07-B
Cd CFS-L04-1313-T08-B
Cd CFS-L04-1313-T09-B
Cd CFS-L04-1313-T01-C
Cd CFS-L04-1313-T02-C
Cd CFS-L04-1313-T03-C
Cd CFS-L04-1313-T04-C
Cd CFS-L04-1313-T05-C
Cd CFS-L04-1313-T06-C
Cd CFS-L04-1313-T07-C
Cd CFS-L04-1313-T08-C
Cd CFS-L04-1313-T09-C
Cd CFS-L04-1313-B01-A
Cd CFS-L04-1313-B02-A
Cd CFS-L04-1313-B03-A
Cd CFS-L04-1313-B01-B
Cd CFS-L04-1313-B02-B
Cd CFS-L04-1313-B03-B
Cd CFS-L04-1313-B01-C
Cd CFS-L04-1313-B02-C
Cd CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.23E+01
1 1.01E+01
1 1.10E+00 U1/2
1 1.66E+01
1 4.46E+03
1 4.20E+03
1 2.02E+04
1 4.71E+04
1 5.09E+04
1 1.38E+01
1 6.08E+00 E
1 1.10E+00 U1/2
1 1.72E+01
1 4.14E+03
1 9.60E+03
1 2.80E+04
1 4.66E+04
1 4.50E+04
1 1.13E+01
1 5.34E+00 E
1 1.10E+00 U1/2
1 1.57E+01
1 1.77E+03
1 7.37E+03
1 2.98E+04
1 5.01 E+04
1 5.00E+04
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 6.90E+00 E
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.23E+01 2.6E+00 2.2E+00 7.0E+00
1.01E+01 1.8E+00 2.2E+00 7.0E+00 10 100
1.10E+00 4.3E+00 2.2E+00 7.0E+00
1.66E+01 3.1E+00 2.2E+00 7.0E+00
4.46E+03 1.7E-01 2.2E+00 7.0E+00
4.20E+03 6.7E-01 2.2E+00 7.0E+00
2.02E+04 1.5E+00 2.2E+00 7.0E+00
4.71E+04 1.2E+00 2.2E+00 7.0E+00
5.09E+04 1.4E+00 2.2E+00 7.0E+00
1.38E+01 5.1E-01 2.2E+00 7.0E+00
6.08E+00 5.4E+00 2.2E+00 7.0E+00 10 100
1.10E+00 5.8E+01 2.2E+00 7.0E+00
1.72E+01 4.3E+00 2.2E+00 7.0E+00
4.14E+03 4.5E-01 2.2E+00 7.0E+00
9.60E+03 3.3E-01 2.2E+00 7.0E+00
2.80E+04 1.2E+00 2.2E+00 7.0E+00
4.66E+04 6.2E-01 2.2E+00 7.0E+00
4.50E+04 1.0E+00 2.2E+00 7.0E+00
1.13E+01 3.5E+00 2.2E+00 7.0E+00
5.34E+00 4.0E+00 2.2E+00 7.0E+00 10 100
1.10E+00 3.7E+01 2.2E+00 7.0E+00
1.57E+01 1.9E+00 2.2E+00 7.0E+00
1.77E+03 7.8E-01 2.2E+00 7.0E+00
7.37E+03 5.5E-01 2.2E+00 7.0E+00
2.98E+04 8.1E-01 2.2E+00 7.0E+00
5.01 E+04 1.6E+00 2.2E+00 7.0E+00
5.00E+04 4.0E-01 2.2E+00 7.0E+00
1.10E+00 5.1E+01 2.2E+00 7.0E+00
1.10E+00 6.4E+01 2.2E+00 7.0E+00
1.10E+00 6.0E+01 2.2E+00 7.0E+00
1.10E+00 2.5E+03 2.2E+00 7.0E+00
6.90E+00 5.5E+00 2.2E+00 7.0E+00
1.10E+00 5.9E+02 2.2E+00 7.0E+00
1.10E+00 4.4E+01 2.2E+00 7.0E+00
1.10E+00 4.5E+01 2.2E+00 7.0E+00
1.10E+00 1.2E+03 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.16E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-706
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
CFS-L04-1313-T01-A
CFS-L04-1313-T02-A
CFS-L04-1313-T03-A
CFS-L04-1313-T04-A
CFS-L04-1313-T05-A
CFS-L04-1313-T06-A
CFS-L04-1313-T07-A
CFS-L04-1313-T08-A
CFS-L04-1313-T09-A
CFS-L04-1313-T01-B
CFS-L04-1313-T02-B
CFS-L04-1313-T03-B
CFS-L04-1313-T04-B
CFS-L04-1313-T05-B
CFS-L04-1313-T06-B
CFS-L04-1313-T07-B
CFS-L04-1313-T08-B
CFS-L04-1313-T09-B
CFS-L04-1313-T01-C
CFS-L04-1313-T02-C
CFS-L04-1313-T03-C
CFS-L04-1313-T04-C
CFS-L04-1313-T05-C
CFS-L04-1313-T06-C
CFS-L04-1313-T07-C
CFS-L04-1313-T08-C
CFS-L04-1313-T09-C
CFS-L04-1313-B01-A
CFS-L04-1313-B02-A
CFS-L04-1313-B03-A
CFS-L04-1313-B01-B
CFS-L04-1313-B02-B
CFS-L04-1313-B03-B
CFS-L04-1313-B01-C
CFS-L04-1313-B02-C
CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.98E+05
1 5.64E+05
1 5.84E+05
1 5.86E+05
1 6.67E+05
1 6.51 E+05
1 8.04E+05
1 1.19E+06
1 1.67E+06
1 4.79E+05
1 6.39E+05
1 6.03E+05
1 5.90E+05
1 6.39E+05
1 6.79E+05
1 8.85E+05
1 1.19E+06
1 1.54E+06
1 3.75E+05
1 5.75E+05
1 5.34E+05
1 5.70E+05
1 5.99E+05
1 6.79E+05
1 9.24E+05
1 1.35E+06
1 1.54E+06
1 8.09E+00 E
1 6.91 E+01
1 2.08E+01
1 5.94E+00 E
1 1.33E+02
1 1.01E+01
1 1.30E+00 U1/2
1 6.43E+01
1 1.65E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.98E+05 3.0E-01 2.6E+00 8.3E+00
5.64E+05 2.7E-01 2.6E+00 8.3E+00 1000 100
5.84E+05 2.9E-01 2.6E+00 8.3E+00
5.86E+05 1.1E-01 2.6E+00 8.3E+00
6.67E+05 3.1E-01 2.6E+00 8.3E+00
6.51 E+05 1.0E+00 2.6E+00 8.3E+00
8.04E+05 2.8E+00 2.6E+00 8.3E+00
1.19E+06 4.8E-01 2.6E+00 8.3E+00
1.67E+06 1.5E+00 2.6E+00 8.3E+00
4.79E+05 6.4E-01 2.6E+00 8.3E+00
6.39E+05 9.6E-01 2.6E+00 8.3E+00 1000 100
6.03E+05 2.4E-01 2.6E+00 8.3E+00
5.90E+05 3.8E-01 2.6E+00 8.3E+00
6.39E+05 9.7E-01 2.6E+00 8.3E+00
6.79E+05 4.4E-01 2.6E+00 8.3E+00
8.85E+05 3.7E-01 2.6E+00 8.3E+00
1.19E+06 1.3E+00 2.6E+00 8.3E+00
1.54E+06 7.0E-01 2.6E+00 8.3E+00
3.75E+05 2.0E-01 2.6E+00 8.3E+00
5.75E+05 4.2E-01 2.6E+00 8.3E+00 1000 100
5.34E+05 6.1E-01 2.6E+00 8.3E+00
5.70E+05 3.7E-01 2.6E+00 8.3E+00
5.99E+05 6.4E-01 2.6E+00 8.3E+00
6.79E+05 1.0E-01 2.6E+00 8.3E+00
9.24E+05 7.6E-01 2.6E+00 8.3E+00
1.35E+06 2.6E+00 2.6E+00 8.3E+00
1.54E+06 9.8E-01 2.6E+00 8.3E+00
8.09E+00 1.2E+02 2.6E+00 8.3E+00
6.91 E+01 1.1 E+01 2.6E+00 8.3E+00
2.08E+01 2.3E+01 2.6E+00 8.3E+00
5.94E+00 7.0E+01 2.6E+00 8.3E+00
1.33E+02 9.6E+00 2.6E+00 8.3E+00
1.01 E+01 2.8E+01 2.6E+00 8.3E+00
1.30E+00 1.0E+03 2.6E+00 8.3E+00
6.43E+01 1.5E+01 2.6E+00 8.3E+00
1.65E+01 1.3E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.65E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.40E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.76E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-707
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr CFS-L04-1313-T01-A
Cr CFS-L04-1313-T02-A
Cr CFS-L04-1313-T03-A
Cr CFS-L04-1313-T04-A
Cr CFS-L04-1313-T05-A
Cr CFS-L04-1313-T06-A
Cr CFS-L04-1313-T07-A
Cr CFS-L04-1313-T08-A
Cr CFS-L04-1313-T09-A
Cr CFS-L04-1313-T01-B
Cr CFS-L04-1313-T02-B
Cr CFS-L04-1313-T03-B
Cr CFS-L04-1313-T04-B
Cr CFS-L04-1313-T05-B
Cr CFS-L04-1313-T06-B
Cr CFS-L04-1313-T07-B
Cr CFS-L04-1313-T08-B
Cr CFS-L04-1313-T09-B
Cr CFS-L04-1313-T01-C
Cr CFS-L04-1313-T02-C
Cr CFS-L04-1313-T03-C
Cr CFS-L04-1313-T04-C
Cr CFS-L04-1313-T05-C
Cr CFS-L04-1313-T06-C
Cr CFS-L04-1313-T07-C
Cr CFS-L04-1313-T08-C
Cr CFS-L04-1313-T09-C
Cr CFS-L04-1313-B01-A
Cr CFS-L04-1313-B02-A
Cr CFS-L04-1313-B03-A
Cr CFS-L04-1313-B01-B
Cr CFS-L04-1313-B02-B
Cr CFS-L04-1313-B03-B
Cr CFS-L04-1313-B01-C
Cr CFS-L04-1313-B02-C
Cr CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.27E+02
1 1.15E+02
1 6.37E+00
1 2.38E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 4.34E+01
1 2.28E+03
1 1.59E+02
1 9.14E+01
1 9.93E+00
1 1.43E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 3.58E+01
1 2.06E+03
1 1.39E+02
1 9.20E+01
1 1.03E+01
1 2.24E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 3.25E+02
1 2.05E+03
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+02 3.6E-01 1.2E+00 3.8E+00
1.15E+02 1.5E+00 1.2E+00 3.8E+00 10 100
6.37E+00 1.1E+01 1.2E+00 3.8E+00
2.38E+00 2.8E+01 1.2E+00 3.8E+00
6.00E-01 4.7E+02 1.2E+00 3.8E+00
6.00E-01 2.0E+02 1.2E+00 3.8E+00
6.00E-01 1.8E+02 1.2E+00 3.8E+00
4.34E+01 1.5E+00 1.2E+00 3.8E+00
2.28E+03 8.0E-01 1.2E+00 3.8E+00
1.59E+02 4.9E-01 1.2E+00 3.8E+00
9.14E+01 9.0E-01 1.2E+00 3.8E+00 10 100
9.93E+00 4.8E+00 1.2E+00 3.8E+00
1.43E+00 4.9E+01 1.2E+00 3.8E+00
6.00E-01 1.9E+02 1.2E+00 3.8E+00
6.00E-01 4.1E+02 1.2E+00 3.8E+00
6.00E-01 3.7E+01 1.2E+00 3.8E+00
3.58E+01 1.6E+00 1.2E+00 3.8E+00
2.06E+03 1.1E+00 1.2E+00 3.8E+00
1.39E+02 3.6E-01 1.2E+00 3.8E+00
9.20E+01 2.6E-01 1.2E+00 3.8E+00 10 100
1.03E+01 2.9E+00 1.2E+00 3.8E+00
2.24E+00 1.1E+01 1.2E+00 3.8E+00
6.00E-01 3.7E+01 1.2E+00 3.8E+00
6.00E-01 8.4E+01 1.2E+00 3.8E+00
6.00E-01 5.4E+01 1.2E+00 3.8E+00
3.25E+02 3.9E-01 1.2E+00 3.8E+00
2.05E+03 6.0E-01 1.2E+00 3.8E+00
6.00E-01 2.9E+02 1.2E+00 3.8E+00
6.00E-01 1.6E+03 1.2E+00 3.8E+00
6.00E-01 6.0E+01 1.2E+00 3.8E+00
6.00E-01 7.7E+02 1.2E+00 3.8E+00
6.00E-01 5.3E+01 1.2E+00 3.8E+00
6.00E-01 6.7E+01 1.2E+00 3.8E+00
6.00E-01 3.5E+01 1.2E+00 3.8E+00
6.00E-01 2.7E+02 1.2E+00 3.8E+00
6.00E-01 2.1E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.24E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-708
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
CFS-L04-1313-T01-A
CFS-L04-1313-T02-A
CFS-L04-1313-T03-A
CFS-L04-1313-T04-A
CFS-L04-1313-T05-A
CFS-L04-1313-T06-A
CFS-L04-1313-T07-A
CFS-L04-1313-T08-A
CFS-L04-1313-T09-A
CFS-L04-1313-T01-B
CFS-L04-1313-T02-B
CFS-L04-1313-T03-B
CFS-L04-1313-T04-B
CFS-L04-1313-T05-B
CFS-L04-1313-T06-B
CFS-L04-1313-T07-B
CFS-L04-1313-T08-B
CFS-L04-1313-T09-B
CFS-L04-1313-T01-C
CFS-L04-1313-T02-C
CFS-L04-1313-T03-C
CFS-L04-1313-T04-C
CFS-L04-1313-T05-C
CFS-L04-1313-T06-C
CFS-L04-1313-T07-C
CFS-L04-1313-T08-C
CFS-L04-1313-T09-C
CFS-L04-1313-B01-A
CFS-L04-1313-B02-A
CFS-L04-1313-B03-A
CFS-L04-1313-B01-B
CFS-L04-1313-B02-B
CFS-L04-1313-B03-B
CFS-L04-1313-B01-C
CFS-L04-1313-B02-C
CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.01E+02
1 9.34E+01
1 4.86E+02
1 1.63E+03
1 1.91E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 8.92E+01
1 1.99E+02
1 7.75E+02
1 1.62E+03
1 1.67E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 3.79E+01
1 1.53E+02
1 8.44E+02
1 1.84E+03
1 1.80E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.2E+01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00 10 100
9.00E-01 5.9E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
1.01E+02 3.8E-01 1.8E+00 5.7E+00
9.34E+01 1.5E+00 1.8E+00 5.7E+00
4.86E+02 9.2E-01 1.8E+00 5.7E+00
1.63E+03 9.8E-01 1.8E+00 5.7E+00
1.91E+03 2.2E+00 1.8E+00 5.7E+00
9.00E-01 9.1E+01 1.8E+00 5.7E+00
9.00E-01 5.2E+01 1.8E+00 5.7E+00 10 100
9.00E-01 6.0E+01 1.8E+00 5.7E+00
9.00E-01 5.0E+02 1.8E+00 5.7E+00
8.92E+01 2.3E+00 1.8E+00 5.7E+00
1.99E+02 5.8E-01 1.8E+00 5.7E+00
7.75E+02 1.0E+00 1.8E+00 5.7E+00
1.62E+03 9.0E-01 1.8E+00 5.7E+00
1.67E+03 6.1E-01 1.8E+00 5.7E+00
9.00E-01 2.4E+01 1.8E+00 5.7E+00
9.00E-01 2.4E+01 1.8E+00 5.7E+00 10 100
9.00E-01 3.4E+01 1.8E+00 5.7E+00
9.00E-01 3.1E+01 1.8E+00 5.7E+00
3.79E+01 7.3E-01 1.8E+00 5.7E+00
1.53E+02 8.8E-01 1.8E+00 5.7E+00
8.44E+02 5.6E-01 1.8E+00 5.7E+00
1.84E+03 7.6E+00 1.8E+00 5.7E+00
1.80E+03 8.7E-01 1.8E+00 5.7E+00
9.00E-01 3.2E+02 1.8E+00 5.7E+00
9.00E-01 6.0E+01 1.8E+00 5.7E+00
9.00E-01 6.4E+01 1.8E+00 5.7E+00
9.00E-01 5.7E+01 1.8E+00 5.7E+00
9.00E-01 4.8E+01 1.8E+00 5.7E+00
9.00E-01 8.9E+01 1.8E+00 5.7E+00
9.00E-01 2.9E+01 1.8E+00 5.7E+00
9.00E-01 4.9E+01 1.8E+00 5.7E+00
9.00E-01 3.1E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-709
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu CFS-L04-1313-T01-A
Cu CFS-L04-1313-T02-A
Cu CFS-L04-1313-T03-A
Cu CFS-L04-1313-T04-A
Cu CFS-L04-1313-T05-A
Cu CFS-L04-1313-T06-A
Cu CFS-L04-1313-T07-A
Cu CFS-L04-1313-T08-A
Cu CFS-L04-1313-T09-A
Cu CFS-L04-1313-T01-B
Cu CFS-L04-1313-T02-B
Cu CFS-L04-1313-T03-B
Cu CFS-L04-1313-T04-B
Cu CFS-L04-1313-T05-B
Cu CFS-L04-1313-T06-B
Cu CFS-L04-1313-T07-B
Cu CFS-L04-1313-T08-B
Cu CFS-L04-1313-T09-B
Cu CFS-L04-1313-T01-C
Cu CFS-L04-1313-T02-C
Cu CFS-L04-1313-T03-C
Cu CFS-L04-1313-T04-C
Cu CFS-L04-1313-T05-C
Cu CFS-L04-1313-T06-C
Cu CFS-L04-1313-T07-C
Cu CFS-L04-1313-T08-C
Cu CFS-L04-1313-T09-C
Cu CFS-L04-1313-B01-A
Cu CFS-L04-1313-B02-A
Cu CFS-L04-1313-B03-A
Cu CFS-L04-1313-B01-B
Cu CFS-L04-1313-B02-B
Cu CFS-L04-1313-B03-B
Cu CFS-L04-1313-B01-C
Cu CFS-L04-1313-B02-C
Cu CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 7.88E+03
1 6.65E+03
1 1.23E+02
1 6.97E+01
1 7.79E+02
1 6.96E+02
1 1.17E+05
1 9.34E+05
1 1.12E+06
1 8.46E+03
1 2.32E+03
1 1.73E+02
1 5.65E+01
1 6.54E+02
1 6.32E+03
1 3.30E+05
1 8.96E+05
1 1.01E+06
1 7.51 E+03
1 2.20E+03
1 1.62E+02
1 5.89E+01
1 1.66E+02
1 4.37E+03
1 3.29E+05
1 1.00E+06
1 1.08E+06
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 5.04E+00 E
1 2.27E+02
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.88E+03 1.4E+00 3.7E+00 1.2E+01
6.65E+03 1.7E+00 3.7E+00 1.2E+01 10 100
1.23E+02 2.0E+00 3.7E+00 1.2E+01
6.97E+01 1.3E+00 3.7E+00 1.2E+01
7.79E+02 3.6E-01 3.7E+00 1.2E+01
6.96E+02 7.5E-01 3.7E+00 1.2E+01
1.17E+05 3.7E+00 3.7E+00 1.2E+01
9.34E+05 1.1E+00 3.7E+00 1.2E+01
1.12E+06 1.5E+00 3.7E+00 1.2E+01
8.46E+03 1.5E+00 3.7E+00 1.2E+01
2.32E+03 9.2E-01 3.7E+00 1.2E+01 10 100
1.73E+02 8.6E-01 3.7E+00 1.2E+01
5.65E+01 1.4E+00 3.7E+00 1.2E+01
6.54E+02 1.1E+00 3.7E+00 1.2E+01
6.32E+03 6.1E-01 3.7E+00 1.2E+01
3.30E+05 1.1E+00 3.7E+00 1.2E+01
8.96E+05 1.6E+00 3.7E+00 1.2E+01
1.01E+06 1.5E+00 3.7E+00 1.2E+01
7.51 E+03 4.7E-01 3.7E+00 1.2E+01
2.20E+03 8.4E-01 3.7E+00 1.2E+01 10 100
1.62E+02 1.4E+00 3.7E+00 1.2E+01
5.89E+01 1.8E+00 3.7E+00 1.2E+01
1.66E+02 2.0E+00 3.7E+00 1.2E+01
4.37E+03 5.6E-01 3.7E+00 1.2E+01
3.29E+05 6.6E-01 3.7E+00 1.2E+01
1.00E+06 1.6E+00 3.7E+00 1.2E+01
1.08E+06 1.2E+00 3.7E+00 1.2E+01
1.85E+00 2.2E+02 3.7E+00 1.2E+01
1.85E+00 1.7E+02 3.7E+00 1.2E+01
1.85E+00 3.6E+02 3.7E+00 1.2E+01
5.04E+00 2.8E+00 3.7E+00 1.2E+01
2.27E+02 9.2E-01 3.7E+00 1.2E+01
1.85E+00 1.8E+02 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.85E+00 1.6E+01 3.7E+00 1.2E+01
1.85E+00 2.0E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
7.66E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.28E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.26E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-710
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe CFS-L04-1313-T01-A
Fe CFS-L04-1313-T02-A
Fe CFS-L04-1313-T03-A
Fe CFS-L04-1313-T04-A
Fe CFS-L04-1313-T05-A
Fe CFS-L04-1313-T06-A
Fe CFS-L04-1313-T07-A
Fe CFS-L04-1313-T08-A
Fe CFS-L04-1313-T09-A
Fe CFS-L04-1313-T01-B
Fe CFS-L04-1313-T02-B
Fe CFS-L04-1313-T03-B
Fe CFS-L04-1313-T04-B
Fe CFS-L04-1313-T05-B
Fe CFS-L04-1313-T06-B
Fe CFS-L04-1313-T07-B
Fe CFS-L04-1313-T08-B
Fe CFS-L04-1313-T09-B
Fe CFS-L04-1313-T01-C
Fe CFS-L04-1313-T02-C
Fe CFS-L04-1313-T03-C
Fe CFS-L04-1313-T04-C
Fe CFS-L04-1313-T05-C
Fe CFS-L04-1313-T06-C
Fe CFS-L04-1313-T07-C
Fe CFS-L04-1313-T08-C
Fe CFS-L04-1313-T09-C
Fe CFS-L04-1313-B01-A
Fe CFS-L04-1313-B02-A
Fe CFS-L04-1313-B03-A
Fe CFS-L04-1313-B01-B
Fe CFS-L04-1313-B02-B
Fe CFS-L04-1313-B03-B
Fe CFS-L04-1313-B01-C
Fe CFS-L04-1313-B02-C
Fe CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.07E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 5.51 E+03
1 2.86E+05
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.27E+01
1 3.50E+04
1 2.57E+05
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.94E+01
1 1.26E+05
1 2.29E+05
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.60E+02
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 9.3E+00 2.0E+00 6.4E+00
1.07E+01 4.1E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
5.51 E+03 1.4E+00 2.0E+00 6.4E+00
2.86E+05 2.0E+00 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00
1.27E+01 2.0E+00 2.0E+00 6.4E+00
3.50E+04 1.6E+00 2.0E+00 6.4E+00
2.57E+05 3.2E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 9.3E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 5.8E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.94E+01 3.8E+00 2.0E+00 6.4E+00
1.26E+05 1.5E+00 2.0E+00 6.4E+00
2.29E+05 5.5E-01 2.0E+00 6.4E+00
1.00E+00 7.6E+00 2.0E+00 6.4E+00
1.00E+00 3.8E+00 2.0E+00 6.4E+00
1.00E+00 9.9E+01 2.0E+00 6.4E+00
1.00E+00 9.4E+00 2.0E+00 6.4E+00
1.60E+02 8.5E-01 2.0E+00 6.4E+00
1.00E+00 7.2E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01 E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01 E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-711
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb CFS-L04-1313-T01-A
Pb CFS-L04-1313-T02-A
Pb CFS-L04-1313-T03-A
Pb CFS-L04-1313-T04-A
Pb CFS-L04-1313-T05-A
Pb CFS-L04-1313-T06-A
Pb CFS-L04-1313-T07-A
Pb CFS-L04-1313-T08-A
Pb CFS-L04-1313-T09-A
Pb CFS-L04-1313-T01-B
Pb CFS-L04-1313-T02-B
Pb CFS-L04-1313-T03-B
Pb CFS-L04-1313-T04-B
Pb CFS-L04-1313-T05-B
Pb CFS-L04-1313-T06-B
Pb CFS-L04-1313-T07-B
Pb CFS-L04-1313-T08-B
Pb CFS-L04-1313-T09-B
Pb CFS-L04-1313-T01-C
Pb CFS-L04-1313-T02-C
Pb CFS-L04-1313-T03-C
Pb CFS-L04-1313-T04-C
Pb CFS-L04-1313-T05-C
Pb CFS-L04-1313-T06-C
Pb CFS-L04-1313-T07-C
Pb CFS-L04-1313-T08-C
Pb CFS-L04-1313-T09-C
Pb CFS-L04-1313-B01-A
Pb CFS-L04-1313-B02-A
Pb CFS-L04-1313-B03-A
Pb CFS-L04-1313-B01-B
Pb CFS-L04-1313-B02-B
Pb CFS-L04-1313-B03-B
Pb CFS-L04-1313-B01-C
Pb CFS-L04-1313-B02-C
Pb CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.57E+03
1 6.17E+03
1 4.73E+02
1 1.44E+02
1 1.19E+03
1 1.14E+03
1 6.10E+03
1 6.88E+03
1 9.59E+03
1 2.10E+03
1 9.86E+03
1 1.00E+03
1 1.49E+02
1 1.14E+03
1 1.67E+03
1 7.92E+03
1 6.50E+03
1 8.88E+03
1 1.54E+03
1 8.69E+03
1 7.19E+02
1 1.50E+02
1 8.14E+02
1 1.42E+03
1 8.15E+03
1 6.97E+03
1 8.85E+03
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 1.85E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.57E+03 7.1E-01 6.8E+00 2.2E+01
6.17E+03 2.6E+00 6.8E+00 2.2E+01 10 100
4.73E+02 1.3E+00 6.8E+00 2.2E+01
1.44E+02 2.9E+00 6.8E+00 2.2E+01
1.19E+03 4.4E-01 6.8E+00 2.2E+01
1.14E+03 1.2E+00 6.8E+00 2.2E+01
6.10E+03 7.0E+00 6.8E+00 2.2E+01
6.88E+03 1.3E+00 6.8E+00 2.2E+01
9.59E+03 8.5E-01 6.8E+00 2.2E+01
2.10E+03 7.0E-01 6.8E+00 2.2E+01
9.86E+03 6.0E-01 6.8E+00 2.2E+01 10 100
1.00E+03 7.0E-01 6.8E+00 2.2E+01
1.49E+02 3.3E+00 6.8E+00 2.2E+01
1.14E+03 6.0E-01 6.8E+00 2.2E+01
1.67E+03 4.0E-01 6.8E+00 2.2E+01
7.92E+03 1.2E+00 6.8E+00 2.2E+01
6.50E+03 1.2E+00 6.8E+00 2.2E+01
8.88E+03 1.5E+00 6.8E+00 2.2E+01
1.54E+03 2.2E+00 6.8E+00 2.2E+01
8.69E+03 8.5E-01 6.8E+00 2.2E+01 10 100
7.19E+02 3.5E-01 6.8E+00 2.2E+01
1.50E+02 1.1E+00 6.8E+00 2.2E+01
8.14E+02 3.8E-01 6.8E+00 2.2E+01
1.42E+03 4.2E-01 6.8E+00 2.2E+01
8.15E+03 1.7E+00 6.8E+00 2.2E+01
6.97E+03 1.7E+00 6.8E+00 2.2E+01
8.85E+03 9.2E-01 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01
3.40E+00 1.6E+01 6.8E+00 2.2E+01
3.40E+00 2.7E+01 6.8E+00 2.2E+01
3.40E+00 8.7E+00 6.8E+00 2.2E+01
1.85E+02 2.0E+00 6.8E+00 2.2E+01
3.40E+00 2.1E+01 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01
3.40E+00 1.2E+02 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
7.05E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.67E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-712
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li CFS-L04-1313-T01-A
Li CFS-L04-1313-T02-A
Li CFS-L04-1313-T03-A
Li CFS-L04-1313-T04-A
Li CFS-L04-1313-T05-A
Li CFS-L04-1313-T06-A
Li CFS-L04-1313-T07-A
Li CFS-L04-1313-T08-A
Li CFS-L04-1313-T09-A
Li CFS-L04-1313-T01-B
Li CFS-L04-1313-T02-B
Li CFS-L04-1313-T03-B
Li CFS-L04-1313-T04-B
Li CFS-L04-1313-T05-B
Li CFS-L04-1313-T06-B
Li CFS-L04-1313-T07-B
Li CFS-L04-1313-T08-B
Li CFS-L04-1313-T09-B
Li CFS-L04-1313-T01-C
Li CFS-L04-1313-T02-C
Li CFS-L04-1313-T03-C
Li CFS-L04-1313-T04-C
Li CFS-L04-1313-T05-C
Li CFS-L04-1313-T06-C
Li CFS-L04-1313-T07-C
Li CFS-L04-1313-T08-C
Li CFS-L04-1313-T09-C
Li CFS-L04-1313-B01-A
Li CFS-L04-1313-B02-A
Li CFS-L04-1313-B03-A
Li CFS-L04-1313-B01-B
Li CFS-L04-1313-B02-B
Li CFS-L04-1313-B03-B
Li CFS-L04-1313-B01-C
Li CFS-L04-1313-B02-C
Li CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.01E+01
1 1.99E+01
1 2.01E+01
1 2.03E+01
1 1.88E+01
1 1.82E+01
1 1.97E+01
1 2.02E+01
1 5.64E+01
1 2.19E+01
1 2.09E+01
1 2.04E+01
1 1.81E+01
1 1.68E+01
1 1.76E+01
1 1.62E+01
1 2.16E+01
1 4.34E+01
1 2.01E+01
1 1.96E+01
1 1.86E+01
1 1.91E+01
1 1.98E+01
1 1.72E+01
1 1.99E+01
1 2.46E+01
1 4.41E+01
1 6.01 E+00
1 6.91 E+00
1 5.76E+00 E
1 6.16E+00
1 5.68E+00 E
1 5.11E+OOE
1 5.68E+00 E
1 6.66E+00
1 4.97E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01E+01 6.0E+00 1.9E+00 6.0E+00
1.99E+01 4.9E-02 1.9E+00 6.0E+00 10 100
2.01 E+01 6.6E-01 1.9E+00 6.0E+00
2.03E+01 7.2E+00 1.9E+00 6.0E+00
1.88E+01 7.4E+00 1.9E+00 6.0E+00
1.82E+01 1.0E+01 1.9E+00 6.0E+00
1.97E+01 2.6E+00 1.9E+00 6.0E+00
2.02E+01 1.7E+01 1.9E+00 6.0E+00
5.64E+01 9.9E+00 1.9E+00 6.0E+00
2.19E+01 6.1E+00 1.9E+00 6.0E+00
2.09E+01 3.0E+00 1.9E+00 6.0E+00 10 100
2.04E+01 8.1E-01 1.9E+00 6.0E+00
1.81 E+01 3.2E+00 1.9E+00 6.0E+00
1.68E+01 7.4E+00 1.9E+00 6.0E+00
1.76E+01 5.1 E+00 1.9E+00 6.0E+00
1.62E+01 5.7E+00 1.9E+00 6.0E+00
2.16E+01 1.1E+01 1.9E+00 6.0E+00
4.34E+01 1.6E+01 1.9E+00 6.0E+00
2.01 E+01 6.3E+00 1.9E+00 6.0E+00
1.96E+01 5.3E+00 1.9E+00 6.0E+00 10 100
1.86E+01 2.6E+00 1.9E+00 6.0E+00
1.91 E+01 4.8E+00 1.9E+00 6.0E+00
1.98E+01 1.4E+01 1.9E+00 6.0E+00
1.72E+01 1.1E+01 1.9E+00 6.0E+00
1.99E+01 1.9E+01 1.9E+00 6.0E+00
2.46E+01 1.8E+01 1.9E+00 6.0E+00
4.41 E+01 1.4E+01 1.9E+00 6.0E+00
6.01 E+00 1.4E+01 1.9E+00 6.0E+00
6.91 E+00 1.7E+01 1.9E+00 6.0E+00
5.76E+00 2.0E+01 1.9E+00 6.0E+00
6.16E+00 1.9E+01 1.9E+00 6.0E+00
5.68E+00 7.2E+00 1.9E+00 6.0E+00
5.11E+00 2.1E+01 1.9E+00 6.0E+00
5.68E+00 1.1E+01 1.9E+00 6.0E+00
6.66E+00 7.0E+00 1.9E+00 6.0E+00
4.97E+00 3.4E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.94E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.64E+02 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.76E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-713
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn CFS-L04-1313-T01-A
Mn CFS-L04-1313-T02-A
Mn CFS-L04-1313-T03-A
Mn CFS-L04-1313-T04-A
Mn CFS-L04-1313-T05-A
Mn CFS-L04-1313-T06-A
Mn CFS-L04-1313-T07-A
Mn CFS-L04-1313-T08-A
Mn CFS-L04-1313-T09-A
Mn CFS-L04-1313-T01-B
Mn CFS-L04-1313-T02-B
Mn CFS-L04-1313-T03-B
Mn CFS-L04-1313-T04-B
Mn CFS-L04-1313-T05-B
Mn CFS-L04-1313-T06-B
Mn CFS-L04-1313-T07-B
Mn CFS-L04-1313-T08-B
Mn CFS-L04-1313-T09-B
Mn CFS-L04-1313-T01-C
Mn CFS-L04-1313-T02-C
Mn CFS-L04-1313-T03-C
Mn CFS-L04-1313-T04-C
Mn CFS-L04-1313-T05-C
Mn CFS-L04-1313-T06-C
Mn CFS-L04-1313-T07-C
Mn CFS-L04-1313-T08-C
Mn CFS-L04-1313-T09-C
Mn CFS-L04-1313-B01-A
Mn CFS-L04-1313-B02-A
Mn CFS-L04-1313-B03-A
Mn CFS-L04-1313-B01-B
Mn CFS-L04-1313-B02-B
Mn CFS-L04-1313-B03-B
Mn CFS-L04-1313-B01-C
Mn CFS-L04-1313-B02-C
Mn CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.06E+00 E
1 1.50E+03
1 1.42E+03
1 4.66E+03
1 1.98E+04
1 3.30E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.38E+03
1 2.16E+03
1 6.85E+03
1 1.95E+04
1 2.99E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 7.70E+02
1 1.91E+03
1 7.99E+03
1 2.30E+04
1 3.07E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.22E+00 E
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.6E+01 2.0E+00 6.4E+00
1.00E+00 5.2E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.5E+01 2.0E+00 6.4E+00
2.06E+00 7.2E+00 2.0E+00 6.4E+00
1.50E+03 1.8E+00 2.0E+00 6.4E+00
1.42E+03 1.4E+00 2.0E+00 6.4E+00
4.66E+03 3.2E+00 2.0E+00 6.4E+00
1.98E+04 6.1E-01 2.0E+00 6.4E+00
3.30E+04 3.8E-01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 3.7E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 3.2E+00 2.0E+00 6.4E+00
1.38E+03 3.9E-01 2.0E+00 6.4E+00
2.16E+03 1.1E+00 2.0E+00 6.4E+00
6.85E+03 1.2E+00 2.0E+00 6.4E+00
1.95E+04 9.3E-01 2.0E+00 6.4E+00
2.99E+04 1.2E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 4.9E+00 2.0E+00 6.4E+00 10 100
1.00E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+00 2.0E+00 6.4E+00
7.70E+02 8.5E-01 2.0E+00 6.4E+00
1.91E+03 2.0E-01 2.0E+00 6.4E+00
7.99E+03 1.3E+00 2.0E+00 6.4E+00
2.30E+04 2.8E+00 2.0E+00 6.4E+00
3.07E+04 4.0E-01 2.0E+00 6.4E+00
1.00E+00 3.2E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
2.22E+00 2.8E+00 2.0E+00 6.4E+00
1.00E+00 8.9E+01 2.0E+00 6.4E+00
1.00E+00 4.5E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 6.1E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.27E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-714
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg CFS-L04-1313-T01-A
Mg CFS-L04-1313-T02-A
Mg CFS-L04-1313-T03-A
Mg CFS-L04-1313-T04-A
Mg CFS-L04-1313-T05-A
Mg CFS-L04-1313-T06-A
Mg CFS-L04-1313-T07-A
Mg CFS-L04-1313-T08-A
Mg CFS-L04-1313-T09-A
Mg CFS-L04-1313-T01-B
Mg CFS-L04-1313-T02-B
Mg CFS-L04-1313-T03-B
Mg CFS-L04-1313-T04-B
Mg CFS-L04-1313-T05-B
Mg CFS-L04-1313-T06-B
Mg CFS-L04-1313-T07-B
Mg CFS-L04-1313-T08-B
Mg CFS-L04-1313-T09-B
Mg CFS-L04-1313-T01-C
Mg CFS-L04-1313-T02-C
Mg CFS-L04-1313-T03-C
Mg CFS-L04-1313-T04-C
Mg CFS-L04-1313-T05-C
Mg CFS-L04-1313-T06-C
Mg CFS-L04-1313-T07-C
Mg CFS-L04-1313-T08-C
Mg CFS-L04-1313-T09-C
Mg CFS-L04-1313-B01-A
Mg CFS-L04-1313-B02-A
Mg CFS-L04-1313-B03-A
Mg CFS-L04-1313-B01-B
Mg CFS-L04-1313-B02-B
Mg CFS-L04-1313-B03-B
Mg CFS-L04-1313-B01-C
Mg CFS-L04-1313-B02-C
Mg CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.40E+01
1 3.05E+01
1 2.67E+03
1 3.60E+04
1 6.88E+04
1 6.74E+04
1 7.18E+04
1 1.30E+05
1 2.18E+05
1 1.78E+01
1 2.70E+01
1 8.18E+02
1 3.61 E+04
1 6.91 E+04
1 6.89E+04
1 7. 91 E+04
1 1.34E+05
1 2.20E+05
1 6.74E+00
1 2.01E+01
1 1.34E+03
1 3.80E+04
1 6.68E+04
1 7.25E+04
1 8.45E+04
1 1.88E+05
1 2.21 E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.75E+00 E
1 8.26E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.40E+01 2.9E+01 1.0E+00 3.2E+00
3.05E+01 5.6E+00 1.0E+00 3.2E+00 1000 100
2.67E+03 1.1E+00 1.0E+00 3.2E+00
3.60E+04 3.9E-01 1.0E+00 3.2E+00
6.88E+04 1.2E-01 1.0E+00 3.2E+00
6.74E+04 1.3E+00 1.0E+00 3.2E+00
7.18E+04 9.3E-01 1.0E+00 3.2E+00
1.30E+05 5.6E-01 1.0E+00 3.2E+00
2.18E+05 9.9E-01 1.0E+00 3.2E+00
1.78E+01 2.9E+01 1.0E+00 3.2E+00
2.70E+01 4.6E+01 1.0E+00 3.2E+00 1000 100
8.18E+02 6.8E-01 1.0E+00 3.2E+00
3.61 E+04 4.9E-01 1.0E+00 3.2E+00
6.91 E+04 3.8E-01 1.0E+00 3.2E+00
6.89E+04 7.5E-01 1.0E+00 3.2E+00
7.91 E+04 8.3E-01 1.0E+00 3.2E+00
1.34E+05 9.0E-01 1.0E+00 3.2E+00
2.20E+05 1.8E+00 1.0E+00 3.2E+00
6.74E+00 8.8E+01 1.0E+00 3.2E+00
2.01E+01 5.4E+01 1.0E+00 3.2E+00 1000 100
1.34E+03 8.9E-01 1.0E+00 3.2E+00
3.80E+04 7.9E-01 1.0E+00 3.2E+00
6.68E+04 5.4E-01 1.0E+00 3.2E+00
7.25E+04 4.8E-01 1.0E+00 3.2E+00
8.45E+04 4.8E-01 1.0E+00 3.2E+00
1.88E+05 6.5E-01 1.0E+00 3.2E+00
2.21 E+05 9.1E-01 1.0E+00 3.2E+00
5.00E-01 1.0E+02 1.0E+00 3.2E+00
5.00E-01 2.7E+02 1.0E+00 3.2E+00
5.00E-01 8.1E+01 1.0E+00 3.2E+00
1.75E+00 3.0E+02 1.0E+00 3.2E+00
8.26E+00 6.1E+01 1.0E+00 3.2E+00
5.00E-01 5.2E+01 1.0E+00 3.2E+00
5.00E-01 4.6E+02 1.0E+00 3.2E+00
5.00E-01 2.1E+01 1.0E+00 3.2E+00
5.00E-01 1.8E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.13E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-715
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo CFS-L04-1313-T01-A
Mo CFS-L04-1313-T02-A
Mo CFS-L04-1313-T03-A
Mo CFS-L04-1313-T04-A
Mo CFS-L04-1313-T05-A
Mo CFS-L04-1313-T06-A
Mo CFS-L04-1313-T07-A
Mo CFS-L04-1313-T08-A
Mo CFS-L04-1313-T09-A
Mo CFS-L04-1313-T01-B
Mo CFS-L04-1313-T02-B
Mo CFS-L04-1313-T03-B
Mo CFS-L04-1313-T04-B
Mo CFS-L04-1313-T05-B
Mo CFS-L04-1313-T06-B
Mo CFS-L04-1313-T07-B
Mo CFS-L04-1313-T08-B
Mo CFS-L04-1313-T09-B
Mo CFS-L04-1313-T01-C
Mo CFS-L04-1313-T02-C
Mo CFS-L04-1313-T03-C
Mo CFS-L04-1313-T04-C
Mo CFS-L04-1313-T05-C
Mo CFS-L04-1313-T06-C
Mo CFS-L04-1313-T07-C
Mo CFS-L04-1313-T08-C
Mo CFS-L04-1313-T09-C
Mo CFS-L04-1313-B01-A
Mo CFS-L04-1313-B02-A
Mo CFS-L04-1313-B03-A
Mo CFS-L04-1313-B01-B
Mo CFS-L04-1313-B02-B
Mo CFS-L04-1313-B03-B
Mo CFS-L04-1313-B01-C
Mo CFS-L04-1313-B02-C
Mo CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.99E+03
1 1.91E+03
1 1.02E+03
1 3.71 E+02
1 1.28E+01
1 1.09E+01
1 7.95E+00
1 1.04E+01
1 1.83E+02
1 2.70E+03
1 1.75E+03
1 1.18E+03
1 3.75E+02
1 1.23E+01
1 1.05E+01
1 8.84E+00
1 1.20E+01
1 1.45E+02
1 2.06E+03
1 2.13E+03
1 1.21E+03
1 3.80E+02
1 1.74E+01
1 1.03E+01
1 7.71 E+00
1 2.52E+01
1 1.07E+02
1 1.61 E+00 E
1 1.65E+00 E
1 6.14E+00
1 1.65E+00 E
1 3.99E+00
1 1.74E+00 E
1 1.44E+00 E
1 6.00E-01 U1/2
1 3.13E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.99E+03 9.0E-01 1.2E+00 3.8E+00
1.91E+03 6.2E-01 1.2E+00 3.8E+00 10 100
1.02E+03 4.8E-02 1.2E+00 3.8E+00
3.71 E+02 5.7E-01 1.2E+00 3.8E+00
1.28E+01 1.4E+00 1.2E+00 3.8E+00
1.09E+01 4.8E+00 1.2E+00 3.8E+00
7.95E+00 4.9E+01 1.2E+00 3.8E+00
1.04E+01 1.7E+01 1.2E+00 3.8E+00
1.83E+02 9.7E+00 1.2E+00 3.8E+00
2.70E+03 3.3E-01 1.2E+00 3.8E+00
1.75E+03 3.3E-01 1.2E+00 3.8E+00 10 100
1.18E+03 1.4E+00 1.2E+00 3.8E+00
3.75E+02 4.2E-01 1.2E+00 3.8E+00
1.23E+01 8.9E+00 1.2E+00 3.8E+00
1.05E+01 4.2E+00 1.2E+00 3.8E+00
8.84E+00 2.2E+01 1.2E+00 3.8E+00
1.20E+01 1.4E+01 1.2E+00 3.8E+00
1.45E+02 3.9E+00 1.2E+00 3.8E+00
2.06E+03 1.3E-01 1.2E+00 3.8E+00
2.13E+03 4.2E-01 1.2E+00 3.8E+00 10 100
1.21E+03 1.8E+00 1.2E+00 3.8E+00
3.80E+02 5.8E-01 1.2E+00 3.8E+00
1.74E+01 3.6E+00 1.2E+00 3.8E+00
1.03E+01 1.1E+01 1.2E+00 3.8E+00
7.71 E+00 4.5E+00 1.2E+00 3.8E+00
2.52E+01 8.5E+01 1.2E+00 3.8E+00
1.07E+02 3.5E+00 1.2E+00 3.8E+00
1.61 E+00 6.4E+01 1.2E+00 3.8E+00
1.65E+00 3.6E+01 1.2E+00 3.8E+00
6.14E+00 3.3E+01 1.2E+00 3.8E+00
1.65E+00 5.1E+01 1.2E+00 3.8E+00
3.99E+00 3.1 E+00 1.2E+00 3.8E+00
1.74E+00 3.5E+01 1.2E+00 3.8E+00
1.44E+00 3.3E+01 1.2E+00 3.8E+00
6.00E-01 3.7E+01 1.2E+00 3.8E+00
3.13E+00 9.8E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.90E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.71 E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.14E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-716
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni CFS-L04-1313-T01-A
Ni CFS-L04-1313-T02-A
Ni CFS-L04-1313-T03-A
Ni CFS-L04-1313-T04-A
Ni CFS-L04-1313-T05-A
Ni CFS-L04-1313-T06-A
Ni CFS-L04-1313-T07-A
Ni CFS-L04-1313-T08-A
Ni CFS-L04-1313-T09-A
Ni CFS-L04-1313-T01-B
Ni CFS-L04-1313-T02-B
Ni CFS-L04-1313-T03-B
Ni CFS-L04-1313-T04-B
Ni CFS-L04-1313-T05-B
Ni CFS-L04-1313-T06-B
Ni CFS-L04-1313-T07-B
Ni CFS-L04-1313-T08-B
Ni CFS-L04-1313-T09-B
Ni CFS-L04-1313-T01-C
Ni CFS-L04-1313-T02-C
Ni CFS-L04-1313-T03-C
Ni CFS-L04-1313-T04-C
Ni CFS-L04-1313-T05-C
Ni CFS-L04-1313-T06-C
Ni CFS-L04-1313-T07-C
Ni CFS-L04-1313-T08-C
Ni CFS-L04-1313-T09-C
Ni CFS-L04-1313-B01-A
Ni CFS-L04-1313-B02-A
Ni CFS-L04-1313-B03-A
Ni CFS-L04-1313-B01-B
Ni CFS-L04-1313-B02-B
Ni CFS-L04-1313-B03-B
Ni CFS-L04-1313-B01-C
Ni CFS-L04-1313-B02-C
Ni CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 2.15E+02
1 1.87E+02
1 1.70E+03
1 6.04E+03
1 6.75E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.80E+02
1 5.18E+02
1 2.87E+03
1 6.05E+03
1 6.15E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 6.36E+01
1 3.75E+02
1 2.95E+03
1 6.42E+03
1 6.70E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.3E+02 1.8E+00 5.7E+00
9.00E-01 6.2E+03 1.8E+00 5.7E+00 10 100
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 2.2E+02 1.8E+00 5.7E+00
2.15E+02 1.4E+00 1.8E+00 5.7E+00
1.87E+02 1.8E+00 1.8E+00 5.7E+00
1.70E+03 7.2E+00 1.8E+00 5.7E+00
6.04E+03 1.1E+00 1.8E+00 5.7E+00
6.75E+03 1.6E+00 1.8E+00 5.7E+00
9.00E-01 8.4E+02 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00 10 100
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
1.80E+02 8.6E-01 1.8E+00 5.7E+00
5.18E+02 1.0E+00 1.8E+00 5.7E+00
2.87E+03 4.5E-01 1.8E+00 5.7E+00
6.05E+03 1.2E+00 1.8E+00 5.7E+00
6.15E+03 1.1E+00 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00 10 100
9.00E-01 4.8E+02 1.8E+00 5.7E+00
9.00E-01 4.1E+02 1.8E+00 5.7E+00
6.36E+01 1.8E+00 1.8E+00 5.7E+00
3.75E+02 1.1E+00 1.8E+00 5.7E+00
2.95E+03 5.0E-01 1.8E+00 5.7E+00
6.42E+03 1.1E+00 1.8E+00 5.7E+00
6.70E+03 7.7E-01 1.8E+00 5.7E+00
9.00E-01 9.1E+01 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 6.9E+02 1.8E+00 5.7E+00
9.00E-01 2.9E+01 1.8E+00 5.7E+00
9.00E-01 2.2E+02 1.8E+00 5.7E+00
9.00E-01 5.5E+01 1.8E+00 5.7E+00
9.00E-01 1.3E+01 1.8E+00 5.7E+00
9.00E-01 2.7E+02 1.8E+00 5.7E+00
9.00E-01 9.5E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-717
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P CFS-L04-1313-T01-A
P CFS-L04-1313-T02-A
P CFS-L04-1313-T03-A
P CFS-L04-1313-T04-A
P CFS-L04-1313-T05-A
P CFS-L04-1313-T06-A
P CFS-L04-1313-T07-A
P CFS-L04-1313-T08-A
P CFS-L04-1313-T09-A
P CFS-L04-1313-T01-B
P CFS-L04-1313-T02-B
P CFS-L04-1313-T03-B
P CFS-L04-1313-T04-B
P CFS-L04-1313-T05-B
P CFS-L04-1313-T06-B
P CFS-L04-1313-T07-B
P CFS-L04-1313-T08-B
P CFS-L04-1313-T09-B
P CFS-L04-1313-T01-C
P CFS-L04-1313-T02-C
P CFS-L04-1313-T03-C
P CFS-L04-1313-T04-C
P CFS-L04-1313-T05-C
P CFS-L04-1313-T06-C
P CFS-L04-1313-T07-C
P CFS-L04-1313-T08-C
P CFS-L04-1313-T09-C
P CFS-L04-1313-B01-A
P CFS-L04-1313-B02-A
P CFS-L04-1313-B03-A
P CFS-L04-1313-B01-B
P CFS-L04-1313-B02-B
P CFS-L04-1313-B03-B
P CFS-L04-1313-B01-C
P CFS-L04-1313-B02-C
P CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 7.06E+01
1 8.38E+01
1 7.01 E+01
1 3.66E+01
1 2.20E+01
1 3.79E+01
1 4.80E+01
1 4. 11 E+01
1 5.51 E+03
1 1.17E+02
1 9.91 E+01
1 7.58E+01
1 4.03E+01
1 5.69E+01
1 5.59E+01
1 4.22E+01
1 5.18E+01
1 4.16E+03
1 9.99E+01
1 1.07E+02
1 6.22E+01
1 3.72E+01
1 2.86E+01
1 3.65E+01
1 3.00E+01
1 1.28E+02
1 2.68E+03
1 3.42E+01
1 3.21 E+01
1 5.99E+01
1 3.07E+01
1 4.15E+01
1 5.50E+01
1 4.02E+01
1 3.16E+01
1 1.35E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.06E+01 1.6E+01 3.7E+00 1.2E+01
8.38E+01 1.0E+01 3.7E+00 1.2E+01 1000 100
7.01E+01 2.3E+01 3.7E+00 1.2E+01
3.66E+01 2.2E+01 3.7E+00 1.2E+01
2.20E+01 2.9E+01 3.7E+00 1.2E+01
3.79E+01 2.3E+01 3.7E+00 1.2E+01
4.80E+01 3.8E+01 3.7E+00 1.2E+01
4.11E+01 3.8E+01 3.7E+00 1.2E+01
5.51 E+03 7.0E-01 3.7E+00 1.2E+01
1.17E+02 7.8E+00 3.7E+00 1.2E+01
9.91E+01 5.3E+00 3.7E+00 1.2E+01 1000 100
7.58E+01 3.2E+01 3.7E+00 1.2E+01
4.03E+01 8.0E+00 3.7E+00 1.2E+01
5.69E+01 3.4E+01 3.7E+00 1.2E+01
5.59E+01 2.1 E+01 3.7E+00 1.2E+01
4.22E+01 1.8E+01 3.7E+00 1.2E+01
5.18E+01 1.8E+01 3.7E+00 1.2E+01
4.16E+03 1.8E+00 3.7E+00 1.2E+01
9.99E+01 3.4E+00 3.7E+00 1.2E+01
1.07E+02 4.9E+00 3.7E+00 1.2E+01 1000 100
6.22E+01 8.5E+00 3.7E+00 1.2E+01
3.72E+01 2.3E+01 3.7E+00 1.2E+01
2.86E+01 3.5E+01 3.7E+00 1.2E+01
3.65E+01 3.8E+01 3.7E+00 1.2E+01
3.00E+01 2.3E+01 3.7E+00 1.2E+01
1.28E+02 1.3E+01 3.7E+00 1.2E+01
2.68E+03 1.5E-01 3.7E+00 1.2E+01
3.42E+01 1.1 E+01 3.7E+00 1.2E+01
3.21E+01 7.2E+00 3.7E+00 1.2E+01
5.99E+01 1.3E+01 3.7E+00 1.2E+01
3.07E+01 3.2E+01 3.7E+00 1.2E+01
4.15E+01 1.2E+01 3.7E+00 1.2E+01
5.50E+01 2.2E+01 3.7E+00 1.2E+01
4.02E+01 2.4E+01 3.7E+00 1.2E+01
3.16E+01 2.6E+01 3.7E+00 1.2E+01
1.35E+02 9.6E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.21E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316CFS
                                                                                                                                                                          1-718
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L04-1313-T01-A
CFS-L04-1313-T02-A
CFS-L04-1313-T03-A
CFS-L04-1313-T04-A
CFS-L04-1313-T05-A
CFS-L04-1313-T06-A
CFS-L04-1313-T07-A
CFS-L04-1313-T08-A
CFS-L04-1313-T09-A
CFS-L04-1313-T01-B
CFS-L04-1313-T02-B
CFS-L04-1313-T03-B
CFS-L04-1313-T04-B
CFS-L04-1313-T05-B
CFS-L04-1313-T06-B
CFS-L04-1313-T07-B
CFS-L04-1313-T08-B
CFS-L04-1313-T09-B
CFS-L04-1313-T01-C
CFS-L04-1313-T02-C
CFS-L04-1313-T03-C
CFS-L04-1313-T04-C
CFS-L04-1313-T05-C
CFS-L04-1313-T06-C
CFS-L04-1313-T07-C
CFS-L04-1313-T08-C
CFS-L04-1313-T09-C
CFS-L04-1313-B01-A
CFS-L04-1313-B02-A
CFS-L04-1313-B03-A
CFS-L04-1313-B01-B
CFS-L04-1313-B02-B
CFS-L04-1313-B03-B
CFS-L04-1313-B01-C
CFS-L04-1313-B02-C
CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.59E+06
1 2.64E+06
1 5.23E+05
1 3.43E+05
1 1.04E+04
1 1.01E+04
1 1.21E+04
1 1.74E+04
1 2.74E+04
1 2.75E+06
1 2.69E+06
1 5.82E+05
1 3.38E+05
1 1.03E+04
1 1.04E+04
1 1.30E+04
1 1.71E+04
1 2.74E+04
1 2.63E+06
1 2.46E+06
1 5.29E+05
1 3.13E+05
1 1.07E+05
1 1.06E+04
1 1.34E+04
1 2.15E+04
1 2.64E+04
1 7.34E+01
1 9.45E+01
1 2.59E+06
1 2.27E+02
1 1.05E+02
1 4.78E+05
1 1.02E+02
1 1.53E+02
1 2.62E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.59E+06 1.3E+00 1.6E+00 5.1E+00
2.64E+06 6.4E-01 1.6E+00 5.1E+00 1000 100
5.23E+05 4.5E-01 1.6E+00 5.1E+00
3.43E+05 7.1E-01 1.6E+00 5.1E+00
1.04E+04 4.9E-01 1.6E+00 5.1E+00
1.01E+04 6.8E-01 1.6E+00 5.1E+00
1.21E+04 8.1E-01 1.6E+00 5.1E+00
1.74E+04 5.1E-01 1.6E+00 5.1E+00
2.74E+04 2.7E-01 1.6E+00 5.1E+00
2.75E+06 6.4E-02 1.6E+00 5.1E+00
2.69E+06 1.8E+00 1.6E+00 5.1E+00 1000 100
5.82E+05 4.3E-01 1.6E+00 5.1E+00
3.38E+05 5.3E-01 1.6E+00 5.1E+00
1.03E+04 4.4E-01 1.6E+00 5.1E+00
1.04E+04 7.2E-01 1.6E+00 5.1E+00
1.30E+04 9.2E-01 1.6E+00 5.1E+00
1.71E+04 1.0E+00 1.6E+00 5.1E+00
2.74E+04 1.8E+00 1.6E+00 5.1E+00
2.63E+06 2.3E+00 1.6E+00 5.1E+00
2.46E+06 5.5E-01 1.6E+00 5.1E+00 1000 100
5.29E+05 1.6E+00 1.6E+00 5.1E+00
3.13E+05 2.8E-01 1.6E+00 5.1E+00
1.07E+05 8.7E-01 1.6E+00 5.1E+00
1.06E+04 4.0E-01 1.6E+00 5.1E+00
1.34E+04 8.7E-01 1.6E+00 5.1E+00
2.15E+04 2.9E+00 1.6E+00 5.1E+00
2.64E+04 1.0E+00 1.6E+00 5.1E+00
7.34E+01 4.0E+00 1.6E+00 5.1E+00
9.45E+01 5.6E+00 1.6E+00 5.1E+00
2.59E+06 3.2E-01 1.6E+00 5.1E+00
2.27E+02 1.1E+01 1.6E+00 5.1E+00
1.05E+02 9.9E-02 1.6E+00 5.1E+00
4.78E+05 6.4E-01 1.6E+00 5.1E+00
1.02E+02 3.2E+00 1.6E+00 5.1E+00
1.53E+02 9.1E-01 1.6E+00 5.1E+00
2.62E+06 2.7E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.64E+06 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.69E+06 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.46E+06 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316CFS
                                                                                                                                                                          1-719
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Sample Dilutic
CFS-L04-1313-T01-A
CFS-L04-1313-T02-A
CFS-L04-1313-T03-A
CFS-L04-1313-T04-A
CFS-L04-1313-T05-A
CFS-L04-1313-T06-A
CFS-L04-1313-T07-A
CFS-L04-1313-T08-A
CFS-L04-1313-T09-A
CFS-L04-1313-T01-B
CFS-L04-1313-T02-B
CFS-L04-1313-T03-B
CFS-L04-1313-T04-B
CFS-L04-1313-T05-B
CFS-L04-1313-T06-B
CFS-L04-1313-T07-B
CFS-L04-1313-T08-B
CFS-L04-1313-T09-B
CFS-L04-1313-T01-C
CFS-L04-1313-T02-C
CFS-L04-1313-T03-C
CFS-L04-1313-T04-C
CFS-L04-1313-T05-C
CFS-L04-1313-T06-C
CFS-L04-1313-T07-C
CFS-L04-1313-T08-C
CFS-L04-1313-T09-C
CFS-L04-1313-B01-A
CFS-L04-1313-B02-A
CFS-L04-1313-B03-A
CFS-L04-1313-B01-B
CFS-L04-1313-B02-B
CFS-L04-1313-B03-B
CFS-L04-1313-B01-C
CFS-L04-1313-B02-C
CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.42E+02
1 3.39E+02
1 4.01 E+02
1 1.52E+02
1 8.46E+01
1 7.31E+01
1 1.01 E+02
1 2.15E+02
1 7.27E+02
1 4.77E+02
1 3.34E+02
1 5.74E+02
1 1.48E+02
1 8.95E+01
1 8.44E+01
1 1.34E+02
1 2.19E+02
1 5.97E+02
1 4.06E+02
1 3.69E+02
1 5.74E+02
1 1.44E+02
1 8.43E+01
1 9.04E+01
1 1.65E+02
1 2.42E+02
1 4.99E+02
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.42E+02 1.3E+00 1.5E+01 4.8E+01
3.39E+02 4.0E+00 1.5E+01 4.8E+01 10 100
4.01 E+02 3.6E+00 1.5E+01 4.8E+01
1.52E+02 4.6E+00 1.5E+01 4.8E+01
8.46E+01 1.5E+01 1.5E+01 4.8E+01
7.31E+01 1.5E+01 1.5E+01 4.8E+01
1.01 E+02 4.6E+01 1.5E+01 4.8E+01
2.15E+02 8.5E+00 1.5E+01 4.8E+01
7.27E+02 2.2E+00 1.5E+01 4.8E+01
4.77E+02 7.0E+00 1.5E+01 4.8E+01
3.34E+02 2.8E-01 1.5E+01 4.8E+01 10 100
5.74E+02 1.5E+00 1.5E+01 4.8E+01
1.48E+02 3.6E+00 1.5E+01 4.8E+01
8.95E+01 9.2E+00 1.5E+01 4.8E+01
8.44E+01 1.2E+01 1.5E+01 4.8E+01
1.34E+02 5.5E+00 1.5E+01 4.8E+01
2.19E+02 3.7E+00 1.5E+01 4.8E+01
5.97E+02 1.1E+00 1.5E+01 4.8E+01
4.06E+02 2.1E+00 1.5E+01 4.8E+01
3.69E+02 1.7E+00 1.5E+01 4.8E+01 10 100
5.74E+02 1.7E+00 1.5E+01 4.8E+01
1.44E+02 9.9E+00 1.5E+01 4.8E+01
8.43E+01 6.0E+00 1.5E+01 4.8E+01
9.04E+01 9.4E-01 1.5E+01 4.8E+01
1.65E+02 3.3E+00 1.5E+01 4.8E+01
2.42E+02 1.0E+01 1.5E+01 4.8E+01
4.99E+02 5.2E+00 1.5E+01 4.8E+01
7.50E+00 5.9E+02 1.5E+01 4.8E+01
7.50E+00 6.4E+01 1.5E+01 4.8E+01
7.50E+00 6.2E+01 1.5E+01 4.8E+01
7.50E+00 6.0E+02 1.5E+01 4.8E+01
7.50E+00 1.7E+02 1.5E+01 4.8E+01
7.50E+00 1.1E+03 1.5E+01 4.8E+01
7.50E+00 1.8E+02 1.5E+01 4.8E+01
7.50E+00 2.1 E+02 1.5E+01 4.8E+01
7.50E+00 1.8E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.49E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.45E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.54E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-720
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si CFS-L04-1313-T01-A
Si CFS-L04-1313-T02-A
Si CFS-L04-1313-T03-A
Si CFS-L04-1313-T04-A
Si CFS-L04-1313-T05-A
Si CFS-L04-1313-T06-A
Si CFS-L04-1313-T07-A
Si CFS-L04-1313-T08-A
Si CFS-L04-1313-T09-A
Si CFS-L04-1313-T01-B
Si CFS-L04-1313-T02-B
Si CFS-L04-1313-T03-B
Si CFS-L04-1313-T04-B
Si CFS-L04-1313-T05-B
Si CFS-L04-1313-T06-B
Si CFS-L04-1313-T07-B
Si CFS-L04-1313-T08-B
Si CFS-L04-1313-T09-B
Si CFS-L04-1313-T01-C
Si CFS-L04-1313-T02-C
Si CFS-L04-1313-T03-C
Si CFS-L04-1313-T04-C
Si CFS-L04-1313-T05-C
Si CFS-L04-1313-T06-C
Si CFS-L04-1313-T07-C
Si CFS-L04-1313-T08-C
Si CFS-L04-1313-T09-C
Si CFS-L04-1313-B01-A
Si CFS-L04-1313-B02-A
Si CFS-L04-1313-B03-A
Si CFS-L04-1313-B01-B
Si CFS-L04-1313-B02-B
Si CFS-L04-1313-B03-B
Si CFS-L04-1313-B01-C
Si CFS-L04-1313-B02-C
Si CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.85E+02
1 1.92E+02
1 4.69E+02
1 6.42E+02
1 3.90E+03
1 3.74E+03
1 2.12E+04
1 6.02E+04
1 1.48E+05
1 2.53E+02
1 2.89E+02
1 5.46E+02
1 5.98E+02
1 3.57E+03
1 7.44E+03
1 3.17E+04
1 5.84E+04
1 1.54E+05
1 2.23E+02
1 2.54E+02
1 4.67E+02
1 5.53E+02
1 2.08E+03
1 5.76E+03
1 3.32E+04
1 1.29E+05
1 1.55E+05
1 7.88E+00
1 1.29E+01
1 2.86E+02
1 4.92E+00
1 3.46E+01
1 1.15E+01
1 4.24E+00
1 6.31 E+00
1 2.02E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+02 2.0E+00 1.1 E+00 3.5E+00
1.92E+02 4.2E+00 1.1 E+00 3.5E+00 1000 100
4.69E+02 6.5E-01 1.1 E+00 3.5E+00
6.42E+02 5.4E-01 1.1 E+00 3.5E+00
3.90E+03 8.9E-01 1.1 E+00 3.5E+00
3.74E+03 1.2E+00 1.1 E+00 3.5E+00
2.12E+04 6.9E+00 1.1 E+00 3.5E+00
6.02E+04 3.5E-01 1.1 E+00 3.5E+00
1.48E+05 1.4E+00 1.1 E+00 3.5E+00
2.53E+02 6.0E-01 1.1 E+00 3.5E+00
2.89E+02 1.5E+00 1.1 E+00 3.5E+00 1000 100
5.46E+02 4.3E-01 1.1 E+00 3.5E+00
5.98E+02 8.0E-01 1.1 E+00 3.5E+00
3.57E+03 1.4E+00 1.1 E+00 3.5E+00
7.44E+03 7.5E-01 1.1 E+00 3.5E+00
3.17E+04 9.3E-01 1.1 E+00 3.5E+00
5.84E+04 3.1E-01 1.1 E+00 3.5E+00
1.54E+05 1.0E+00 1.1 E+00 3.5E+00
2.23E+02 1.4E+00 1.1 E+00 3.5E+00
2.54E+02 2.1E+00 1.1 E+00 3.5E+00 1000 100
4.67E+02 1.4E+00 1.1 E+00 3.5E+00
5.53E+02 5.9E-01 1.1 E+00 3.5E+00
2.08E+03 5.8E-01 1.1 E+00 3.5E+00
5.76E+03 8.2E-01 1.1 E+00 3.5E+00
3.32E+04 1.7E+00 1.1 E+00 3.5E+00
1.29E+05 3.8E-01 1.1 E+00 3.5E+00
1.55E+05 8.8E-01 1.1 E+00 3.5E+00
7.88E+00 2.6E+01 1.1 E+00 3.5E+00
1.29E+01 1.5E+01 1.1 E+00 3.5E+00
2.86E+02 3.1E+01 1.1 E+00 3.5E+00
4.92E+00 4.1E+01 1.1 E+00 3.5E+00
3.46E+01 8.7E+00 1.1 E+00 3.5E+00
1.15E+01 2.7E+01 1.1 E+00 3.5E+00
4.24E+00 4.6E+01 1.1 E+00 3.5E+00
6.31 E+00 2.9E+01 1.1 E+00 3.5E+00
2.02E+02 1.7E+01 1.1 E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.10E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-721
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na CFS-L04-1313-T01-A
Na CFS-L04-1313-T02-A
Na CFS-L04-1313-T03-A
Na CFS-L04-1313-T04-A
Na CFS-L04-1313-T05-A
Na CFS-L04-1313-T06-A
Na CFS-L04-1313-T07-A
Na CFS-L04-1313-T08-A
Na CFS-L04-1313-T09-A
Na CFS-L04-1313-T01-B
Na CFS-L04-1313-T02-B
Na CFS-L04-1313-T03-B
Na CFS-L04-1313-T04-B
Na CFS-L04-1313-T05-B
Na CFS-L04-1313-T06-B
Na CFS-L04-1313-T07-B
Na CFS-L04-1313-T08-B
Na CFS-L04-1313-T09-B
Na CFS-L04-1313-T01-C
Na CFS-L04-1313-T02-C
Na CFS-L04-1313-T03-C
Na CFS-L04-1313-T04-C
Na CFS-L04-1313-T05-C
Na CFS-L04-1313-T06-C
Na CFS-L04-1313-T07-C
Na CFS-L04-1313-T08-C
Na CFS-L04-1313-T09-C
Na CFS-L04-1313-B01-A
Na CFS-L04-1313-B02-A
Na CFS-L04-1313-B03-A
Na CFS-L04-1313-B01-B
Na CFS-L04-1313-B02-B
Na CFS-L04-1313-B03-B
Na CFS-L04-1313-B01-C
Na CFS-L04-1313-B02-C
Na CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.13E+04
1 2.10E+04
1 2.01E+04
1 2.22E+04
1 1.95E+04
1 1.91E+04
1 2.03E+04
1 2.65E+04
1 3.13E+04
1 2.11E+04
1 2.08E+04
1 2.11E+04
1 2.06E+04
1 1.97E+04
1 1.99E+04
1 2.30E+04
1 2.76E+04
1 3.36E+04
1 1.90E+04
1 2.10E+04
1 2.07E+04
1 1.93E+04
1 2.08E+04
1 2.15E+04
1 2.29E+04
1 2.86E+04
1 3.19E+04
1 1.49E+01
1 1.99E+01
1 1.53E+03
1 2.87E+01
1 2.29E+01
1 1.82E+02
1 2.10E+01
1 1.59E+01
1 1.64E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.13E+04 5.5E-01 2.5E+00 8.0E+00
2.10E+04 2.3E-01 2.5E+00 8.0E+00 1000 100
2.01 E+04 2.5E-01 2.5E+00 8.0E+00
2.22E+04 6.3E-01 2.5E+00 8.0E+00
1.95E+04 4.7E-01 2.5E+00 8.0E+00
1.91 E+04 3.2E-01 2.5E+00 8.0E+00
2.03E+04 2.2E-01 2.5E+00 8.0E+00
2.65E+04 8.7E-01 2.5E+00 8.0E+00
3.13E+04 6.3E-01 2.5E+00 8.0E+00
2.11E+04 5.6E-01 2.5E+00 8.0E+00
2.08E+04 6.3E-01 2.5E+00 8.0E+00 1000 100
2.11E+04 1.3E+00 2.5E+00 8.0E+00
2.06E+04 5.2E-01 2.5E+00 8.0E+00
1.97E+04 6.2E-01 2.5E+00 8.0E+00
1.99E+04 8.4E-01 2.5E+00 8.0E+00
2.30E+04 7.9E-01 2.5E+00 8.0E+00
2.76E+04 6.2E-01 2.5E+00 8.0E+00
3.36E+04 8.3E-01 2.5E+00 8.0E+00
1.90E+04 1.2E+00 2.5E+00 8.0E+00
2.10E+04 5.9E-01 2.5E+00 8.0E+00 1000 100
2.07E+04 3.5E-01 2.5E+00 8.0E+00
1.93E+04 3.6E-01 2.5E+00 8.0E+00
2.08E+04 6.4E-01 2.5E+00 8.0E+00
2.15E+04 4.1E-01 2.5E+00 8.0E+00
2.29E+04 3.8E-01 2.5E+00 8.0E+00
2.86E+04 2.0E+00 2.5E+00 8.0E+00
3.19E+04 6.1E-01 2.5E+00 8.0E+00
1.49E+01 9.6E+00 2.5E+00 8.0E+00
1.99E+01 7.8E+00 2.5E+00 8.0E+00
1.53E+03 9.7E-01 2.5E+00 8.0E+00
2.87E+01 9.5E+00 2.5E+00 8.0E+00
2.29E+01 2.0E+01 2.5E+00 8.0E+00
1.82E+02 6.4E-01 2.5E+00 8.0E+00
2.10E+01 9.2E+00 2.5E+00 8.0E+00
1.59E+01 1.4E+01 2.5E+00 8.0E+00
1.64E+03 6.5E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.19E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.16E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.19E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-722
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr CFS-L04-1313-T01-A
Sr CFS-L04-1313-T02-A
Sr CFS-L04-1313-T03-A
Sr CFS-L04-1313-T04-A
Sr CFS-L04-1313-T05-A
Sr CFS-L04-1313-T06-A
Sr CFS-L04-1313-T07-A
Sr CFS-L04-1313-T08-A
Sr CFS-L04-1313-T09-A
Sr CFS-L04-1313-T01-B
Sr CFS-L04-1313-T02-B
Sr CFS-L04-1313-T03-B
Sr CFS-L04-1313-T04-B
Sr CFS-L04-1313-T05-B
Sr CFS-L04-1313-T06-B
Sr CFS-L04-1313-T07-B
Sr CFS-L04-1313-T08-B
Sr CFS-L04-1313-T09-B
Sr CFS-L04-1313-T01-C
Sr CFS-L04-1313-T02-C
Sr CFS-L04-1313-T03-C
Sr CFS-L04-1313-T04-C
Sr CFS-L04-1313-T05-C
Sr CFS-L04-1313-T06-C
Sr CFS-L04-1313-T07-C
Sr CFS-L04-1313-T08-C
Sr CFS-L04-1313-T09-C
Sr CFS-L04-1313-B01-A
Sr CFS-L04-1313-B02-A
Sr CFS-L04-1313-B03-A
Sr CFS-L04-1313-B01-B
Sr CFS-L04-1313-B02-B
Sr CFS-L04-1313-B03-B
Sr CFS-L04-1313-B01-C
Sr CFS-L04-1313-B02-C
Sr CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.76E+03
1 1.77E+03
1 4.16E+03
1 3.57E+03
1 1.60E+03
1 1.63E+03
1 9.44E+02
1 1.11E+03
1 1.60E+03
1 1.73E+03
1 3.51 E+03
1 4.45E+03
1 3.70E+03
1 1.62E+03
1 9.56E+02
1 9.71 E+02
1 1.18E+03
1 1.36E+03
1 1.37E+03
1 2.85E+03
1 3.69E+03
1 3.37E+03
1 2.63E+03
1 1.28E+03
1 1.05E+03
1 1.70E+03
1 1.33E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.76E+03 3.3E-01 1.0E+00 3.2E+00
1.77E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
4.16E+03 5.2E-01 1.0E+00 3.2E+00
3.57E+03 2.5E-01 1.0E+00 3.2E+00
1.60E+03 1.1E+00 1.0E+00 3.2E+00
1.63E+03 1.2E+00 1.0E+00 3.2E+00
9.44E+02 7.7E+00 1.0E+00 3.2E+00
1.11E+03 1.5E+00 1.0E+00 3.2E+00
1.60E+03 3.4E+00 1.0E+00 3.2E+00
1.73E+03 8.8E-01 1.0E+00 3.2E+00
3.51E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
4.45E+03 8.4E-01 1.0E+00 3.2E+00
3.70E+03 1.3E+00 1.0E+00 3.2E+00
1.62E+03 9.2E-01 1.0E+00 3.2E+00
9.56E+02 1.5E-01 1.0E+00 3.2E+00
9.71 E+02 2.6E-01 1.0E+00 3.2E+00
1.18E+03 1.5E+00 1.0E+00 3.2E+00
1.36E+03 1.4E+00 1.0E+00 3.2E+00
1.37E+03 1.1E+00 1.0E+00 3.2E+00
2.85E+03 2.6E-01 1.0E+00 3.2E+00 1000 100
3.69E+03 4.1E-01 1.0E+00 3.2E+00
3.37E+03 1.1E+00 1.0E+00 3.2E+00
2.63E+03 8.3E-01 1.0E+00 3.2E+00
1.28E+03 7.8E-01 1.0E+00 3.2E+00
1.05E+03 9.0E-01 1.0E+00 3.2E+00
1.70E+03 2.5E+00 1.0E+00 3.2E+00
1.33E+03 3.0E-01 1.0E+00 3.2E+00
5.00E-01 1.9E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
5.00E-01 7.0E+01 1.0E+00 3.2E+00
5.00E-01 4.7E+01 1.0E+00 3.2E+00
5.00E-01 5.8E+01 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
5.00E-01 3.2E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
5.00E-01 2.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.80E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.45E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.84E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-723
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S CFS-L04-1313-T01-A
S CFS-L04-1313-T02-A
S CFS-L04-1313-T03-A
S CFS-L04-1313-T04-A
S CFS-L04-1313-T05-A
S CFS-L04-1313-T06-A
S CFS-L04-1313-T07-A
S CFS-L04-1313-T08-A
S CFS-L04-1313-T09-A
S CFS-L04-1313-T01-B
S CFS-L04-1313-T02-B
S CFS-L04-1313-T03-B
S CFS-L04-1313-T04-B
S CFS-L04-1313-T05-B
S CFS-L04-1313-T06-B
S CFS-L04-1313-T07-B
S CFS-L04-1313-T08-B
S CFS-L04-1313-T09-B
S CFS-L04-1313-T01-C
S CFS-L04-1313-T02-C
S CFS-L04-1313-T03-C
S CFS-L04-1313-T04-C
S CFS-L04-1313-T05-C
S CFS-L04-1313-T06-C
S CFS-L04-1313-T07-C
S CFS-L04-1313-T08-C
S CFS-L04-1313-T09-C
S CFS-L04-1313-B01-A
S CFS-L04-1313-B02-A
S CFS-L04-1313-B03-A
S CFS-L04-1313-B01-B
S CFS-L04-1313-B02-B
S CFS-L04-1313-B03-B
S CFS-L04-1313-B01-C
S CFS-L04-1313-B02-C
S CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.35E+06
1 1.39E+06
1 7.89E+05
1 7.05E+05
1 6.26E+05
1 6.09E+05
1 6.13E+05
1 7.05E+05
1 9.02E+05
1 1.46E+06
1 1.33E+06
1 8.65E+05
1 7.20E+05
1 6.10E+05
1 6.01 E+05
1 6.57E+05
1 6.94E+05
1 8.23E+05
1 1.26E+06
1 1.21E+06
1 7.78E+05
1 6.91 E+05
1 6.35E+05
1 6.40E+05
1 6.76E+05
1 7.63E+05
1 8.63E+05
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 1.15E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 1.26E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.35E+06 5.0E-01 6.8E+00 2.2E+01
1.39E+06 5.3E-01 6.8E+00 2.2E+01 1000 100
7.89E+05 2.4E-01 6.8E+00 2.2E+01
7.05E+05 6.1E-01 6.8E+00 2.2E+01
6.26E+05 4.3E-01 6.8E+00 2.2E+01
6.09E+05 1.1E+00 6.8E+00 2.2E+01
6.13E+05 6.9E-01 6.8E+00 2.2E+01
7.05E+05 8.4E-01 6.8E+00 2.2E+01
9.02E+05 7.7E-01 6.8E+00 2.2E+01
1.46E+06 5.2E-01 6.8E+00 2.2E+01
1.33E+06 6.3E-01 6.8E+00 2.2E+01 1000 100
8.65E+05 3.9E-01 6.8E+00 2.2E+01
7.20E+05 7.2E-01 6.8E+00 2.2E+01
6.10E+05 4.4E-01 6.8E+00 2.2E+01
6.01 E+05 6.7E-01 6.8E+00 2.2E+01
6.57E+05 4.2E-01 6.8E+00 2.2E+01
6.94E+05 7.1E-01 6.8E+00 2.2E+01
8.23E+05 1.2E+00 6.8E+00 2.2E+01
1.26E+06 3.3E-01 6.8E+00 2.2E+01
1.21E+06 4.0E-01 6.8E+00 2.2E+01 1000 100
7.78E+05 3.6E-01 6.8E+00 2.2E+01
6.91 E+05 6.2E-01 6.8E+00 2.2E+01
6.35E+05 6.5E-01 6.8E+00 2.2E+01
6.40E+05 3.0E-01 6.8E+00 2.2E+01
6.76E+05 6.5E-01 6.8E+00 2.2E+01
7.63E+05 1.8E+00 6.8E+00 2.2E+01
8.63E+05 8.9E-01 6.8E+00 2.2E+01
3.40E+00 3.0E+01 6.8E+00 2.2E+01
3.40E+00 3.9E+01 6.8E+00 2.2E+01
1.15E+02 1.0E+01 6.8E+00 2.2E+01
3.40E+00 6.5E+00 6.8E+00 2.2E+01
3.40E+00 1.3E+01 6.8E+00 2.2E+01
3.40E+00 3.7E+00 6.8E+00 2.2E+01
3.40E+00 4.1E+00 6.8E+00 2.2E+01
3.40E+00 5.2E+00 6.8E+00 2.2E+01
1.26E+02 2.2E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.39E+06 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.33E+06 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+06 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-724
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample Dilutic
CFS-L04-1313-T01-A
CFS-L04-1313-T02-A
CFS-L04-1313-T03-A
CFS-L04-1313-T04-A
CFS-L04-1313-T05-A
CFS-L04-1313-T06-A
CFS-L04-1313-T07-A
CFS-L04-1313-T08-A
CFS-L04-1313-T09-A
CFS-L04-1313-T01-B
CFS-L04-1313-T02-B
CFS-L04-1313-T03-B
CFS-L04-1313-T04-B
CFS-L04-1313-T05-B
CFS-L04-1313-T06-B
CFS-L04-1313-T07-B
CFS-L04-1313-T08-B
CFS-L04-1313-T09-B
CFS-L04-1313-T01-C
CFS-L04-1313-T02-C
CFS-L04-1313-T03-C
CFS-L04-1313-T04-C
CFS-L04-1313-T05-C
CFS-L04-1313-T06-C
CFS-L04-1313-T07-C
CFS-L04-1313-T08-C
CFS-L04-1313-T09-C
CFS-L04-1313-B01-A
CFS-L04-1313-B02-A
CFS-L04-1313-B03-A
CFS-L04-1313-B01-B
CFS-L04-1313-B02-B
CFS-L04-1313-B03-B
CFS-L04-1313-B01-C
CFS-L04-1313-B02-C
CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.05E+02
1 2.03E+02
1 3.98E+02
1 6.03E+02
1 3.24E+02
1 3.25E+02
1 5.46E+02
1 9.00E+02
1 1.86E+03
1 2.36E+02
1 2.19E+02
1 3.49E+02
1 5.86E+02
1 3.23E+02
1 3.69E+02
1 6.07E+02
1 8.98E+02
1 1.70E+03
1 2.06E+02
1 2.20E+02
1 3.68E+02
1 5.50E+02
1 6.87E+02
1 3.41 E+02
1 6.35E+02
1 1.09E+03
1 1.66E+03
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.05E+02 3.3E-01 4.6E+00 1.5E+01
2.03E+02 1.9E+00 4.6E+00 1.5E+01 10 100
3.98E+02 1.3E+00 4.6E+00 1.5E+01
6.03E+02 3.4E-01 4.6E+00 1.5E+01
3.24E+02 2.7E+00 4.6E+00 1.5E+01
3.25E+02 1.5E+00 4.6E+00 1.5E+01
5.46E+02 4.8E+00 4.6E+00 1.5E+01
9.00E+02 9.0E-01 4.6E+00 1.5E+01
1.86E+03 1.2E+00 4.6E+00 1.5E+01
2.36E+02 3.4E+00 4.6E+00 1.5E+01
2.19E+02 2.5E+00 4.6E+00 1.5E+01 10 100
3.49E+02 1.0E+00 4.6E+00 1.5E+01
5.86E+02 1.2E+00 4.6E+00 1.5E+01
3.23E+02 7.3E-01 4.6E+00 1.5E+01
3.69E+02 5.0E-01 4.6E+00 1.5E+01
6.07E+02 1.6E+00 4.6E+00 1.5E+01
8.98E+02 4.2E-01 4.6E+00 1.5E+01
1.70E+03 1.7E+00 4.6E+00 1.5E+01
2.06E+02 2.4E+00 4.6E+00 1.5E+01
2.20E+02 3.0E+00 4.6E+00 1.5E+01 10 100
3.68E+02 1.7E+00 4.6E+00 1.5E+01
5.50E+02 1.4E+00 4.6E+00 1.5E+01
6.87E+02 2.2E+00 4.6E+00 1.5E+01
3.41 E+02 5.0E-01 4.6E+00 1.5E+01
6.35E+02 8.1E-01 4.6E+00 1.5E+01
1.09E+03 3.1E+00 4.6E+00 1.5E+01
1.66E+03 1.2E+00 4.6E+00 1.5E+01
2.30E+00 1.3E+02 4.6E+00 1.5E+01
2.30E+00 7.9E+02 4.6E+00 1.5E+01
2.30E+00 6.1E+01 4.6E+00 1.5E+01
2.30E+00 3.0E+01 4.6E+00 1.5E+01
2.30E+00 7.1E+01 4.6E+00 1.5E+01
2.30E+00 4.5E+02 4.6E+00 1.5E+01
2.30E+00 7.5E+01 4.6E+00 1.5E+01
2.30E+00 2.6E+02 4.6E+00 1.5E+01
2.30E+00 6.5E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-725
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutic
CFS-L04-1313-T01-A
CFS-L04-1313-T02-A
CFS-L04-1313-T03-A
CFS-L04-1313-T04-A
CFS-L04-1313-T05-A
CFS-L04-1313-T06-A
CFS-L04-1313-T07-A
CFS-L04-1313-T08-A
CFS-L04-1313-T09-A
CFS-L04-1313-T01-B
CFS-L04-1313-T02-B
CFS-L04-1313-T03-B
CFS-L04-1313-T04-B
CFS-L04-1313-T05-B
CFS-L04-1313-T06-B
CFS-L04-1313-T07-B
CFS-L04-1313-T08-B
CFS-L04-1313-T09-B
CFS-L04-1313-T01-C
CFS-L04-1313-T02-C
CFS-L04-1313-T03-C
CFS-L04-1313-T04-C
CFS-L04-1313-T05-C
CFS-L04-1313-T06-C
CFS-L04-1313-T07-C
CFS-L04-1313-T08-C
CFS-L04-1313-T09-C
CFS-L04-1313-B01-A
CFS-L04-1313-B02-A
CFS-L04-1313-B03-A
CFS-L04-1313-B01-B
CFS-L04-1313-B02-B
CFS-L04-1313-B03-B
CFS-L04-1313-B01-C
CFS-L04-1313-B02-C
CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 7.21 E+00
1 6.50E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 8.49E+00
1 6.28E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 9.75E+00
1 3.59E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.9E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+00 2.0E+00 6.4E+00 10 100
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 4.4E+00 2.0E+00 6.4E+00
1.00E+00 6.9E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
7.21 E+00 2.5E+00 2.0E+00 6.4E+00
6.50E+01 3.1E-01 2.0E+00 6.4E+00
1.00E+00 4.7E+00 2.0E+00 6.4E+00
1.00E+00 9.4E+00 2.0E+00 6.4E+00 10 100
1.00E+00 9.6E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+00 2.0E+00 6.4E+00
1.00E+00 3.5E+00 2.0E+00 6.4E+00
1.00E+00 8.2E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
8.49E+00 1.6E+01 2.0E+00 6.4E+00
6.28E+01 1.7E+00 2.0E+00 6.4E+00
1.00E+00 3.1E+00 2.0E+00 6.4E+00
1.00E+00 1.5E+00 2.0E+00 6.4E+00 10 100
1.00E+00 2.1E+00 2.0E+00 6.4E+00
1.00E+00 9.3E+00 2.0E+00 6.4E+00
1.00E+00 6.8E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+00 2.0E+00 6.4E+00
1.00E+00 5.9E+01 2.0E+00 6.4E+00
9.75E+00 2.0E+01 2.0E+00 6.4E+00
3.59E+01 1.1 E+00 2.0E+00 6.4E+00
1.00E+00 3.4E+00 2.0E+00 6.4E+00
1.00E+00 3.6E+00 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+00 2.0E+00 6.4E+00
1.00E+00 3.1 E+00 2.0E+00 6.4E+00
1.00E+00 5.0E+00 2.0E+00 6.4E+00
1.00E+00 9.7E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-726
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V CFS-L04-1313-T01-A
V CFS-L04-1313-T02-A
V CFS-L04-1313-T03-A
V CFS-L04-1313-T04-A
V CFS-L04-1313-T05-A
V CFS-L04-1313-T06-A
V CFS-L04-1313-T07-A
V CFS-L04-1313-T08-A
V CFS-L04-1313-T09-A
V CFS-L04-1313-T01-B
V CFS-L04-1313-T02-B
V CFS-L04-1313-T03-B
V CFS-L04-1313-T04-B
V CFS-L04-1313-T05-B
V CFS-L04-1313-T06-B
V CFS-L04-1313-T07-B
V CFS-L04-1313-T08-B
V CFS-L04-1313-T09-B
V CFS-L04-1313-T01-C
V CFS-L04-1313-T02-C
V CFS-L04-1313-T03-C
V CFS-L04-1313-T04-C
V CFS-L04-1313-T05-C
V CFS-L04-1313-T06-C
V CFS-L04-1313-T07-C
V CFS-L04-1313-T08-C
V CFS-L04-1313-T09-C
V CFS-L04-1313-B01-A
V CFS-L04-1313-B02-A
V CFS-L04-1313-B03-A
V CFS-L04-1313-B01-B
V CFS-L04-1313-B02-B
V CFS-L04-1313-B03-B
V CFS-L04-1313-B01-C
V CFS-L04-1313-B02-C
V CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.90E+01
1 3.19E+01
1 3.07E+01
1 3.20E+01
1 3.51 E+01
1 3.37E+01
1 4.01 E+01
1 5.83E+01
1 5.77E+02
1 2.73E+01
1 3.51 E+01
1 3.37E+01
1 3.12E+01
1 3.42E+01
1 3.57E+01
1 4.51 E+01
1 5.54E+01
1 5.09E+02
1 2.51 E+01
1 2.99E+01
1 2.92E+01
1 3.12E+01
1 3.18E+01
1 3.53E+01
1 4.75E+01
1 2.62E+02
1 5.21 E+02
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.90E+01 3.7E+00 1.5E+00 4.8E+00
3.19E+01 6.2E-01 1.5E+00 4.8E+00 10 100
3.07E+01 2.2E+00 1.5E+00 4.8E+00
3.20E+01 6.9E+00 1.5E+00 4.8E+00
3.51 E+01 3.2E+00 1.5E+00 4.8E+00
3.37E+01 4.4E+00 1.5E+00 4.8E+00
4.01 E+01 1.4E+00 1.5E+00 4.8E+00
5.83E+01 9.9E-01 1.5E+00 4.8E+00
5.77E+02 6.1E-01 1.5E+00 4.8E+00
2.73E+01 1.2E+01 1.5E+00 4.8E+00
3.51E+01 4.3E-01 1.5E+00 4.8E+00 10 100
3.37E+01 2.9E+00 1.5E+00 4.8E+00
3.12E+01 2.4E+00 1.5E+00 4.8E+00
3.42E+01 2.3E+00 1.5E+00 4.8E+00
3.57E+01 2.5E+00 1.5E+00 4.8E+00
4.51 E+01 2.2E+00 1.5E+00 4.8E+00
5.54E+01 1.4E+00 1.5E+00 4.8E+00
5.09E+02 1.1E+00 1.5E+00 4.8E+00
2.51 E+01 5.6E+00 1.5E+00 4.8E+00
2.99E+01 3.9E+00 1.5E+00 4.8E+00 10 100
2.92E+01 3.0E+00 1.5E+00 4.8E+00
3.12E+01 2.7E+00 1.5E+00 4.8E+00
3.18E+01 3.1E+00 1.5E+00 4.8E+00
3.53E+01 3.7E+00 1.5E+00 4.8E+00
4.75E+01 1.3E+00 1.5E+00 4.8E+00
2.62E+02 4.2E+00 1.5E+00 4.8E+00
5.21 E+02 1.0E+00 1.5E+00 4.8E+00
7.50E-01 1.1 E+02 1.5E+00 4.8E+00
7.50E-01 8.3E+01 1.5E+00 4.8E+00
7.50E-01 1.0E+02 1.5E+00 4.8E+00
7.50E-01 2.2E+04 1.5E+00 4.8E+00
7.50E-01 2.2E+02 1.5E+00 4.8E+00
7.50E-01 1.3E+02 1.5E+00 4.8E+00
7.50E-01 3.3E+02 1.5E+00 4.8E+00
7.50E-01 1.6E+02 1.5E+00 4.8E+00
7.50E-01 8.7E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.20E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/1 1 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                          1-727
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn CFS-L04-1313-T01-A
Zn CFS-L04-1313-T02-A
Zn CFS-L04-1313-T03-A
Zn CFS-L04-1313-T04-A
Zn CFS-L04-1313-T05-A
Zn CFS-L04-1313-T06-A
Zn CFS-L04-1313-T07-A
Zn CFS-L04-1313-T08-A
Zn CFS-L04-1313-T09-A
Zn CFS-L04-1313-T01-B
Zn CFS-L04-1313-T02-B
Zn CFS-L04-1313-T03-B
Zn CFS-L04-1313-T04-B
Zn CFS-L04-1313-T05-B
Zn CFS-L04-1313-T06-B
Zn CFS-L04-1313-T07-B
Zn CFS-L04-1313-T08-B
Zn CFS-L04-1313-T09-B
Zn CFS-L04-1313-T01-C
Zn CFS-L04-1313-T02-C
Zn CFS-L04-1313-T03-C
Zn CFS-L04-1313-T04-C
Zn CFS-L04-1313-T05-C
Zn CFS-L04-1313-T06-C
Zn CFS-L04-1313-T07-C
Zn CFS-L04-1313-T08-C
Zn CFS-L04-1313-T09-C
Zn CFS-L04-1313-B01-A
Zn CFS-L04-1313-B02-A
Zn CFS-L04-1313-B03-A
Zn CFS-L04-1313-B01-B
Zn CFS-L04-1313-B02-B
Zn CFS-L04-1313-B03-B
Zn CFS-L04-1313-B01-C
Zn CFS-L04-1313-B02-C
Zn CFS-L04-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 7.87E+03
1 6.67E+03
1 1.94E+01
1 2.23E+01
1 2.00E+04
1 1.78E+04
1 1.46E+05
1 1.87E+05
1 1.79E+05
1 8.82E+03
1 3.91 E+03
1 4.13E+01
1 1.39E+01
1 1.69E+04
1 6.66E+04
1 1.63E+05
1 1.71E+05
1 1.62E+05
1 7.87E+03
1 3.54E+03
1 3.41 E+01
1 1.49E+01
1 3.87E+03
1 4.81 E+04
1 1.67E+05
1 1.78E+05
1 1.70E+05
1 4.72E+00
1 5.92E+00
1 4.77E+00
1 7.33E+00
1 9.45E+01
1 2.37E+00 E
1 1.74E+00 E
1 4.43E+00
1 3.02E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.87E+03 1.7E+00 1.0E+00 3.2E+00
6.67E+03 7.5E-01 1.0E+00 3.2E+00 10 100
1.94E+01 2.4E+00 1.0E+00 3.2E+00
2.23E+01 1.4E+00 1.0E+00 3.2E+00
2.00E+04 1.2E+00 1.0E+00 3.2E+00
1.78E+04 1.2E+00 1.0E+00 3.2E+00
1.46E+05 1.1E+00 1.0E+00 3.2E+00
1.87E+05 1.7E+00 1.0E+00 3.2E+00
1.79E+05 8.6E-01 1.0E+00 3.2E+00
8.82E+03 9.5E-01 1.0E+00 3.2E+00
3.91E+03 1.4E+00 1.0E+00 3.2E+00 10 100
4.13E+01 9.0E-01 1.0E+00 3.2E+00
1.39E+01 3.1E+00 1.0E+00 3.2E+00
1.69E+04 1.2E+00 1.0E+00 3.2E+00
6.66E+04 3.2E-01 1.0E+00 3.2E+00
1.63E+05 1.2E+00 1.0E+00 3.2E+00
1.71E+05 1.8E+00 1.0E+00 3.2E+00
1.62E+05 2.2E+00 1.0E+00 3.2E+00
7.87E+03 2.0E+00 1.0E+00 3.2E+00
3.54E+03 5.7E-01 1.0E+00 3.2E+00 10 100
3.41 E+01 8.7E-01 1.0E+00 3.2E+00
1.49E+01 3.7E+00 1.0E+00 3.2E+00
3.87E+03 4.5E-01 1.0E+00 3.2E+00
4.81 E+04 6.5E-01 1.0E+00 3.2E+00
1.67E+05 9.0E-01 1.0E+00 3.2E+00
1.78E+05 2.7E+00 1.0E+00 3.2E+00
1.70E+05 2.0E+00 1.0E+00 3.2E+00
4.72E+00 9.0E+00 1.0E+00 3.2E+00
5.92E+00 2.9E+00 1.0E+00 3.2E+00
4.77E+00 1.1E+00 1.0E+00 3.2E+00
7.33E+00 2.1E+00 1.0E+00 3.2E+00
9.45E+01 1.1E+00 1.0E+00 3.2E+00
2.37E+00 7.2E+00 1.0E+00 3.2E+00
1.74E+00 2.1 E+01 1.0E+00 3.2E+00
4.43E+00 6.5E+00 1.0E+00 3.2E+00
3.02E+00 7.9E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
7.60E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.90E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.64E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/25/11 2:55 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:57 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:58 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:00 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:02 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:03 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:05 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:07 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:08 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:15 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:16 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:18 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:20 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:21 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:23 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:25 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:26 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:28 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:35 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:36 PM EPA Interlab L04 1313-1316CFS
5/25/11 3:38 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:41 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:43 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:46 PM EPA Interlab L04 1313-1316 CFS
5/25/11 3:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:40 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:42 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:44 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:45 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:47 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:48 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:50 PM EPA Interlab L04 1313-1316 CFS
5/25/11 2:52 PM EPA Interlab L04 1313-1316CFS
5/25/11 2:53 PM EPA Interlab L04 1313-1316CFS
                                                                                                                                                                          1-728
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L06-1313-T01-A 1 1.18E+02
CFS-L06-1313-T02-A 1 1.17E+02
CFS-L06-1313-T03-A 1 1.34E+00 E
CFS-L06-1313-T04-A 1 1.26E+02
CFS-L06-1313-T05-A 1 4.74E+01
CFS-L06-1313-T06-A 1 7.95E+00
CFS-L06-1313-T07-A 1 9.38E+03
CFS-L06-1313-T08-A 1 2.30E+04
CFS-L06-1313-T09-A 1 8.68E+04
CFS-L06-1313-T01-B 1 1.17E+02
CFS-L06-1313-T02-B 1 5.88E+01
CFS-L06-1313-T03-B 1 1.64E+02
CFS-L06-1313-T04-B 1 1.33E+02
CFS-L06-1313-T05-B 1 5.01 E+01
CFS-L06-1313-T06-B 1 4.64E+01
CFS-L06-1313-T07-B 1 8.90E+03
CFS-L06-1313-T08-B 1 2.49E+04
CFS-L06-1313-T09-B 1 8.37E+04
CFS-L06-1313-T01-C 1 1.28E+02
CFS-L06-1313-T02-C 1 1.11E+02
CFS-L06-1313-T03-C 1 1.52E+02
CFS-L06-1313-T04-C 1 1.19E+02
CFS-L06-1313-T05-C 1 5.80E+01
CFS-L06-1313-T06-C 1 4.72E+01
CFS-L06-1313-T07-C 1 9.20E+03
CFS-L06-1313-T08-C 1 2.51 E+04
CFS-L06-1313-T09-C 1 8.54E+04
CFS-L06-1313-B01-A 1 5.00E-01 U1/2
CFS-L06-1313-B02-A 1 5.00E-01 U1/2
CFS-L06-1313-B03-A 1 8.41 E+00
CFS-L06-1313-B01-B 1 5.00E-01 U1/2
CFS-L06-1313-B02-B 1 2.31 E+00 E
CFS-L06-1313-B03-B 1 5.00E-01 U1/2
CFS-L06-1313-B01-C 1 5.00E-01 U1/2
CFS-L06-1313-B02-C 1 6.78E+00
CFS-L06-1313-B03-C 1 5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+02 1.2E+00 1.0E+00 3.2E+00
1.17E+02 1.0E+00 1.0E+00 3.2E+00 1000 120
1.34E+00 4.1E+02 1.0E+00 3.2E+00
1.26E+02 1.5E+00 1.0E+00 3.2E+00
4.74E+01 4.5E+00 1.0E+00 3.2E+00
7.95E+00 2.1E+02 1.0E+00 3.2E+00
9.38E+03 8.0E-01 1.0E+00 3.2E+00
2.30E+04 4.7E+00 1.0E+00 3.2E+00
8.68E+04 2.6E-01 1.0E+00 3.2E+00
1.17E+02 1.8E+00 1.0E+00 3.2E+00
5.88E+01 9.9E+01 1.0E+00 3.2E+00 1000 120
1.64E+02 4.8E-01 1.0E+00 3.2E+00
1.33E+02 4.7E+00 1.0E+00 3.2E+00
5.01 E+01 6.1 E+00 1.0E+00 3.2E+00
4.64E+01 4.1 E+00 1.0E+00 3.2E+00
8.90E+03 1.2E-01 1.0E+00 3.2E+00
2.49E+04 1.9E-02 1.0E+00 3.2E+00
8.37E+04 6.5E-01 1.0E+00 3.2E+00
1.28E+02 1.0E+00 1.0E+00 3.2E+00
1.11E+02 3.2E+00 1.0E+00 3.2E+00 1000 120
1.52E+02 2.5E+00 1.0E+00 3.2E+00
1.19E+02 1.4E+00 1.0E+00 3.2E+00
5.80E+01 5.2E+00 1.0E+00 3.2E+00
4.72E+01 1.6E+01 1.0E+00 3.2E+00
9.20E+03 9.7E-01 1.0E+00 3.2E+00
2.51 E+04 1.7E+00 1.0E+00 3.2E+00
8.54E+04 1.3E-01 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
5.00E-01 1.7E+02 1.0E+00 3.2E+00
8.41 E+00 2.4E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+02 1.0E+00 3.2E+00
2.31 E+00 1.3E+02 1.0E+00 3.2E+00
5.00E-01 3.7E+01 1.0E+00 3.2E+00
5.00E-01 1.3E+02 1.0E+00 3.2E+00
6.78E+00 6.4E+00 1.0E+00 3.2E+00
5.00E-01 1.7E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
1.43E+03 110% VU ICP-OES 4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
1.47E+03 118% VU ICP-OES 4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:14 PM EPA Interlab L06 1313-1316CFS
1.44E+03 110% VU ICP-OES 4/14/11 4:15 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 4:17 PM EPA Interlab L06 131 3-1 31 6 CFS
VU ICP-OES 4/14/11 4:19 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 4:20 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 4:22 PM EPA Interlab L06 131 3-1 31 6 CFS
VU ICP-OES 4/14/11 4:23 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 4:25 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 4:27 PM EPA Interlab L06 131 3-1 31 6 CFS
VU ICP-OES 4/14/11 3:24 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 3:26 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:29 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:32 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 3:34 PM EPA Interlab L06 1313-1316CFS
VU ICP-OES 4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 3:37 PM EPA Interlab L06 1313-1316CFS
                                                                                                                                                                                     1-729
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb CFS-L06-1313-T01-A
Sb CFS-L06-1313-T02-A
Sb CFS-L06-1313-T03-A
Sb CFS-L06-1313-T04-A
Sb CFS-L06-1313-T05-A
Sb CFS-L06-1313-T06-A
Sb CFS-L06-1313-T07-A
Sb CFS-L06-1313-T08-A
Sb CFS-L06-1313-T09-A
Sb CFS-L06-1313-T01-B
Sb CFS-L06-1313-T02-B
Sb CFS-L06-1313-T03-B
Sb CFS-L06-1313-T04-B
Sb CFS-L06-1313-T05-B
Sb CFS-L06-1313-T06-B
Sb CFS-L06-1313-T07-B
Sb CFS-L06-1313-T08-B
Sb CFS-L06-1313-T09-B
Sb CFS-L06-1313-T01-C
Sb CFS-L06-1313-T02-C
Sb CFS-L06-1313-T03-C
Sb CFS-L06-1313-T04-C
Sb CFS-L06-1313-T05-C
Sb CFS-L06-1313-T06-C
Sb CFS-L06-1313-T07-C
Sb CFS-L06-1313-T08-C
Sb CFS-L06-1313-T09-C
Sb CFS-L06-1313-B01-A
Sb CFS-L06-1313-B02-A
Sb CFS-L06-1313-B03-A
Sb CFS-L06-1313-B01-B
Sb CFS-L06-1313-B02-B
Sb CFS-L06-1313-B03-B
Sb CFS-L06-1313-B01-C
Sb CFS-L06-1313-B02-C
Sb CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.03E+01 E
1 1.08E+01 E
1 3.75E+00 U1/2
1 3.84E+01
1 3.69E+01
1 3.75E+00 U1/2
1 3.03E+02
1 7.44E+02
1 1.56E+03
1 8.57E+00 E
1 7.77E+00 E
1 3.36E+01
1 4.87E+01
1 2.15E+01 E
1 4.58E+01
1 2.85E+02
1 8.56E+02
1 1.65E+03
1 3.75E+00 U1/2
1 1.49E+01 E
1 2.62E+01
1 4.11E+01
1 3.42E+01
1 3.38E+01
1 3.02E+02
1 8.03E+02
1 1.55E+03
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 1.85E+01 E
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 8.02E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.03E+01 1.2E+02 7.5E+00 2.4E+01
1.08E+01 1.1E+02 7.5E+00 2.4E+01 10 120
3.75E+00 6.6E+02 7.5E+00 2.4E+01
3.84E+01 2.3E+01 7.5E+00 2.4E+01
3.69E+01 2.6E+01 7.5E+00 2.4E+01
3.75E+00 1.8E+02 7.5E+00 2.4E+01
3.03E+02 1.2E+01 7.5E+00 2.4E+01
7.44E+02 7.7E+00 7.5E+00 2.4E+01
1.56E+03 6.0E+00 7.5E+00 2.4E+01
8.57E+00 8.9E+01 7.5E+00 2.4E+01
7.77E+00 5.8E+01 7.5E+00 2.4E+01 10 120
3.36E+01 2.3E+00 7.5E+00 2.4E+01
4.87E+01 9.7E+00 7.5E+00 2.4E+01
2.15E+01 1.6E+01 7.5E+00 2.4E+01
4.58E+01 2.5E+01 7.5E+00 2.4E+01
2.85E+02 1.8E+01 7.5E+00 2.4E+01
8.56E+02 7.3E+00 7.5E+00 2.4E+01
1.65E+03 6.6E+00 7.5E+00 2.4E+01
3.75E+00 1.0E+02 7.5E+00 2.4E+01
1.49E+01 3.3E+01 7.5E+00 2.4E+01 10 150
2.62E+01 1.9E+01 7.5E+00 2.4E+01
4.11E+01 3.8E+01 7.5E+00 2.4E+01
3.42E+01 1.3E+01 7.5E+00 2.4E+01
3.38E+01 5.5E+01 7.5E+00 2.4E+01
3.02E+02 8.2E+00 7.5E+00 2.4E+01
8.03E+02 5.7E+00 7.5E+00 2.4E+01
1.55E+03 3.8E+00 7.5E+00 2.4E+01
3.75E+00 1.0E+02 7.5E+00 2.4E+01
3.75E+00 6.9E+01 7.5E+00 2.4E+01
1.85E+01 6.0E+01 7.5E+00 2.4E+01
3.75E+00 9.1E+01 7.5E+00 2.4E+01
3.75E+00 3.4E+01 7.5E+00 2.4E+01
3.75E+00 5.4E+01 7.5E+00 2.4E+01
3.75E+00 6.2E+01 7.5E+00 2.4E+01
3.75E+00 1.8E+01 7.5E+00 2.4E+01
8.02E+00 3.0E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.36E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.40E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.67E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-730
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As CFS-L06-1313-T01-A
As CFS-L06-1313-T02-A
As CFS-L06-1313-T03-A
As CFS-L06-1313-T04-A
As CFS-L06-1313-T05-A
As CFS-L06-1313-T06-A
As CFS-L06-1313-T07-A
As CFS-L06-1313-T08-A
As CFS-L06-1313-T09-A
As CFS-L06-1313-T01-B
As CFS-L06-1313-T02-B
As CFS-L06-1313-T03-B
As CFS-L06-1313-T04-B
As CFS-L06-1313-T05-B
As CFS-L06-1313-T06-B
As CFS-L06-1313-T07-B
As CFS-L06-1313-T08-B
As CFS-L06-1313-T09-B
As CFS-L06-1313-T01-C
As CFS-L06-1313-T02-C
As CFS-L06-1313-T03-C
As CFS-L06-1313-T04-C
As CFS-L06-1313-T05-C
As CFS-L06-1313-T06-C
As CFS-L06-1313-T07-C
As CFS-L06-1313-T08-C
As CFS-L06-1313-T09-C
As CFS-L06-1313-B01-A
As CFS-L06-1313-B02-A
As CFS-L06-1313-B03-A
As CFS-L06-1313-B01-B
As CFS-L06-1313-B02-B
As CFS-L06-1313-B03-B
As CFS-L06-1313-B01-C
As CFS-L06-1313-B02-C
As CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.21 E+02
1 3.82E+02
1 5.50E+00 U1/2
1 5.47E+01
1 2.62E+01 E
1 5.50E+00 U1/2
1 2.92E+02
1 6.22E+02
1 5.55E+04
1 5.73E+02
1 1.57E+02
1 1.34E+02
1 4.94E+01
1 2.65E+01 E
1 1.91E+01 E
1 3.08E+02
1 7.56E+02
1 7.59E+04
1 4.56E+02
1 3.01 E+02
1 1.40E+02
1 4.87E+01
1 2.90E+01 E
1 2.28E+01 E
1 3.01 E+02
1 8.07E+02
1 7.34E+04
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 1.45E+01 E
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.21E+02 2.0E+00 1.1E+01 3.5E+01
3.82E+02 3.9E+00 1.1E+01 3.5E+01 10 120
5.50E+00 3.1E+01 1.1E+01 3.5E+01
5.47E+01 4.9E+00 1.1E+01 3.5E+01
2.62E+01 8.5E+00 1.1E+01 3.5E+01
5.50E+00 3.6E+02 1.1E+01 3.5E+01
2.92E+02 4.5E+00 1.1E+01 3.5E+01
6.22E+02 4.3E+00 1.1E+01 3.5E+01
5.55E+04 1.1E+00 1.1E+01 3.5E+01
5.73E+02 1.8E+00 1.1E+01 3.5E+01
1.57E+02 1.0E+02 1.1E+01 3.5E+01 10 120
1.34E+02 3.3E+00 1.1E+01 3.5E+01
4.94E+01 2.2E+01 1.1E+01 3.5E+01
2.65E+01 2.5E+01 1.1E+01 3.5E+01
1.91E+01 2.6E+01 1.1E+01 3.5E+01
3.08E+02 2.8E+00 1.1E+01 3.5E+01
7.56E+02 1.0E+00 1.1E+01 3.5E+01
7.59E+04 4.0E-01 1.1E+01 3.5E+01
4.56E+02 3.4E+00 1.1E+01 3.5E+01
3.01E+02 3.2E+00 1.1E+01 3.5E+01 10 150
1.40E+02 7.4E+00 1.1E+01 3.5E+01
4.87E+01 2.5E+01 1.1E+01 3.5E+01
2.90E+01 3.0E+01 1.1E+01 3.5E+01
2.28E+01 6.2E+01 1.1E+01 3.5E+01
3.01E+02 1.6E+00 1.1E+01 3.5E+01
8.07E+02 1.2E+00 1.1E+01 3.5E+01
7.34E+04 1.2E+00 1.1E+01 3.5E+01
5.50E+00 9.1E+01 1.1E+01 3.5E+01
5.50E+00 7.8E+01 1.1E+01 3.5E+01
1.45E+01 2.3E+01 1.1E+01 3.5E+01
5.50E+00 1.2E+03 1.1E+01 3.5E+01
5.50E+00 1.5E+02 1.1E+01 3.5E+01
5.50E+00 1.4E+01 1.1E+01 3.5E+01
5.50E+00 8.8E+01 1.1E+01 3.5E+01
5.50E+00 7.8E+02 1.1E+01 3.5E+01
5.50E+00 9.0E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.73E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.50E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.98E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-731
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B CFS-L06-1313-T01-A
B CFS-L06-1313-T02-A
B CFS-L06-1313-T03-A
B CFS-L06-1313-T04-A
B CFS-L06-1313-T05-A
B CFS-L06-1313-T06-A
B CFS-L06-1313-T07-A
B CFS-L06-1313-T08-A
B CFS-L06-1313-T09-A
B CFS-L06-1313-T01-B
B CFS-L06-1313-T02-B
B CFS-L06-1313-T03-B
B CFS-L06-1313-T04-B
B CFS-L06-1313-T05-B
B CFS-L06-1313-T06-B
B CFS-L06-1313-T07-B
B CFS-L06-1313-T08-B
B CFS-L06-1313-T09-B
B CFS-L06-1313-T01-C
B CFS-L06-1313-T02-C
B CFS-L06-1313-T03-C
B CFS-L06-1313-T04-C
B CFS-L06-1313-T05-C
B CFS-L06-1313-T06-C
B CFS-L06-1313-T07-C
B CFS-L06-1313-T08-C
B CFS-L06-1313-T09-C
B CFS-L06-1313-B01-A
B CFS-L06-1313-B02-A
B CFS-L06-1313-B03-A
B CFS-L06-1313-B01-B
B CFS-L06-1313-B02-B
B CFS-L06-1313-B03-B
B CFS-L06-1313-B01-C
B CFS-L06-1313-B02-C
B CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 8.30E+01
1 7.31E+01
1 6.71 E+00
1 1.31E+02
1 1.51E+02
1 2.36E+01
1 4.66E+02
1 6.68E+02
1 9.03E+02
1 8.43E+01
1 3.68E+01
1 1.82E+02
1 1.32E+02
1 1.44E+02
1 1.75E+02
1 4.41 E+02
1 6.55E+02
1 8.14E+02
1 9.04E+01
1 7.21E+01
1 1.83E+02
1 1.30E+02
1 1.47E+02
1 1.47E+02
1 4.63E+02
1 6.49E+02
1 7.68E+02
1 3.71 E+00
1 5.00E+00
1 1.15E+01
1 3.81 E+00
1 4.63E+00
1 1.21E+01
1 4.96E+00
1 5. 11 E+00
1 1.04E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.30E+01 4.5E+00 1.0E+00 3.2E+00
7.31E+01 1.1 E+00 1.0E+00 3.2E+00 1000 120
6.71 E+00 6.5E+01 1.0E+00 3.2E+00
1.31 E+02 8.4E-01 1.0E+00 3.2E+00
1.51 E+02 1.8E+00 1.0E+00 3.2E+00
2.36E+01 1.3E+02 1.0E+00 3.2E+00
4.66E+02 7.9E-01 1.0E+00 3.2E+00
6.68E+02 5.5E+00 1.0E+00 3.2E+00
9.03E+02 2.3E+00 1.0E+00 3.2E+00
8.43E+01 1.8E+00 1.0E+00 3.2E+00
3.68E+01 9.2E+01 1.0E+00 3.2E+00 1000 120
1.82E+02 1.1 E+00 1.0E+00 3.2E+00
1.32E+02 1.2E+00 1.0E+00 3.2E+00
1.44E+02 2.4E-01 1.0E+00 3.2E+00
1.75E+02 4.2E-01 1.0E+00 3.2E+00
4.41 E+02 8.6E-02 1.0E+00 3.2E+00
6.55E+02 6.8E-01 1.0E+00 3.2E+00
8.14E+02 6.1E-01 1.0E+00 3.2E+00
9.04E+01 1.8E+00 1.0E+00 3.2E+00
7.21E+01 9.0E-01 1.0E+00 3.2E+00 1000 120
1.83E+02 1.9E+00 1.0E+00 3.2E+00
1.30E+02 1.4E+00 1.0E+00 3.2E+00
1.47E+02 2.0E-01 1.0E+00 3.2E+00
1.47E+02 3.2E+01 1.0E+00 3.2E+00
4.63E+02 1.3E+00 1.0E+00 3.2E+00
6.49E+02 6.9E-01 1.0E+00 3.2E+00
7.68E+02 6.3E-01 1.0E+00 3.2E+00
3.71 E+00 3.9E+01 1.0E+00 3.2E+00
5.00E+00 5.0E+00 1.0E+00 3.2E+00
1.15E+01 5.4E+00 1.0E+00 3.2E+00
3.81 E+00 4.0E+01 1.0E+00 3.2E+00
4.63E+00 2.6E+01 1.0E+00 3.2E+00
1.21E+01 1.6E+01 1.0E+00 3.2E+00
4.96E+00 9.0E+00 1.0E+00 3.2E+00
5.11E+00 5.9E+00 1.0E+00 3.2E+00
1.04E+01 1.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.40E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.45E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.30E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316CFS
                                                                                                                                                                          1-732
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba CFS-L06-1313-T01-A
Ba CFS-L06-1313-T02-A
Ba CFS-L06-1313-T03-A
Ba CFS-L06-1313-T04-A
Ba CFS-L06-1313-T05-A
Ba CFS-L06-1313-T06-A
Ba CFS-L06-1313-T07-A
Ba CFS-L06-1313-T08-A
Ba CFS-L06-1313-T09-A
Ba CFS-L06-1313-T01-B
Ba CFS-L06-1313-T02-B
Ba CFS-L06-1313-T03-B
Ba CFS-L06-1313-T04-B
Ba CFS-L06-1313-T05-B
Ba CFS-L06-1313-T06-B
Ba CFS-L06-1313-T07-B
Ba CFS-L06-1313-T08-B
Ba CFS-L06-1313-T09-B
Ba CFS-L06-1313-T01-C
Ba CFS-L06-1313-T02-C
Ba CFS-L06-1313-T03-C
Ba CFS-L06-1313-T04-C
Ba CFS-L06-1313-T05-C
Ba CFS-L06-1313-T06-C
Ba CFS-L06-1313-T07-C
Ba CFS-L06-1313-T08-C
Ba CFS-L06-1313-T09-C
Ba CFS-L06-1313-B01-A
Ba CFS-L06-1313-B02-A
Ba CFS-L06-1313-B03-A
Ba CFS-L06-1313-B01-B
Ba CFS-L06-1313-B02-B
Ba CFS-L06-1313-B03-B
Ba CFS-L06-1313-B01-C
Ba CFS-L06-1313-B02-C
Ba CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.00E-01 U1/2
1 6.91 E+00
1 4.08E+00
1 9.00E+01
1 8.36E+01
1 9.55E+00
1 3.62E+01
1 3.89E+01
1 1.07E+01
1 5.00E-01 U1/2
1 1.63E+00 E
1 2.56E+02
1 8.86E+01
1 8.38E+01
1 1.32E+02
1 3.13E+01
1 3.77E+01
1 8.14E+00
1 5.00E-01 U1/2
1 5.43E+00
1 2.48E+02
1 9.11E+01
1 8.48E+01
1 1.08E+02
1 3.66E+01
1 3.61 E+01
1 7.31 E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 7.98E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 8.34E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 8.41 E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 1.1 E+01 1.0E+00 3.2E+00
6.91E+00 3.8E+00 1.0E+00 3.2E+00 10 120
4.08E+00 9.3E+01 1.0E+00 3.2E+00
9.00E+01 7.4E-01 1.0E+00 3.2E+00
8.36E+01 6.4E-01 1.0E+00 3.2E+00
9.55E+00 1.5E+02 1.0E+00 3.2E+00
3.62E+01 9.4E-01 1.0E+00 3.2E+00
3.89E+01 4.3E+00 1.0E+00 3.2E+00
1.07E+01 1.2E+00 1.0E+00 3.2E+00
5.00E-01 6.0E+00 1.0E+00 3.2E+00
1.63E+00 9.1E+01 1.0E+00 3.2E+00 10 120
2.56E+02 8.4E-01 1.0E+00 3.2E+00
8.86E+01 4.4E-01 1.0E+00 3.2E+00
8.38E+01 6.7E-01 1.0E+00 3.2E+00
1.32E+02 8.2E-01 1.0E+00 3.2E+00
3.13E+01 2.5E-01 1.0E+00 3.2E+00
3.77E+01 2.8E-01 1.0E+00 3.2E+00
8.14E+00 1.0E+00 1.0E+00 3.2E+00
5.00E-01 2.3E+01 1.0E+00 3.2E+00
5.43E+00 8.7E+00 1.0E+00 3.2E+00 10 150
2.48E+02 5.0E-01 1.0E+00 3.2E+00
9.11E+01 3.7E-01 1.0E+00 3.2E+00
8.48E+01 8.5E-01 1.0E+00 3.2E+00
1.08E+02 4.1 E+01 1.0E+00 3.2E+00
3.66E+01 4.7E-01 1.0E+00 3.2E+00
3.61 E+01 5.6E-01 1.0E+00 3.2E+00
7.31 E+00 7.7E-01 1.0E+00 3.2E+00
5.00E-01 2.6E+01 1.0E+00 3.2E+00
5.00E-01 8.7E+00 1.0E+00 3.2E+00
7.98E+00 1.2E+00 1.0E+00 3.2E+00
5.00E-01 2.0E+01 1.0E+00 3.2E+00
5.00E-01 9.3E+00 1.0E+00 3.2E+00
8.34E+00 1.3E+00 1.0E+00 3.2E+00
5.00E-01 1.6E+01 1.0E+00 3.2E+00
5.00E-01 4.1 E+01 1.0E+00 3.2E+00
8.41 E+00 1.1 E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.04E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.42E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316CFS
                                                                                                                                                                          1-733
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be CFS-L06-1313-T01-A
Be CFS-L06-1313-T02-A
Be CFS-L06-1313-T03-A
Be CFS-L06-1313-T04-A
Be CFS-L06-1313-T05-A
Be CFS-L06-1313-T06-A
Be CFS-L06-1313-T07-A
Be CFS-L06-1313-T08-A
Be CFS-L06-1313-T09-A
Be CFS-L06-1313-T01-B
Be CFS-L06-1313-T02-B
Be CFS-L06-1313-T03-B
Be CFS-L06-1313-T04-B
Be CFS-L06-1313-T05-B
Be CFS-L06-1313-T06-B
Be CFS-L06-1313-T07-B
Be CFS-L06-1313-T08-B
Be CFS-L06-1313-T09-B
Be CFS-L06-1313-T01-C
Be CFS-L06-1313-T02-C
Be CFS-L06-1313-T03-C
Be CFS-L06-1313-T04-C
Be CFS-L06-1313-T05-C
Be CFS-L06-1313-T06-C
Be CFS-L06-1313-T07-C
Be CFS-L06-1313-T08-C
Be CFS-L06-1313-T09-C
Be CFS-L06-1313-B01-A
Be CFS-L06-1313-B02-A
Be CFS-L06-1313-B03-A
Be CFS-L06-1313-B01-B
Be CFS-L06-1313-B02-B
Be CFS-L06-1313-B03-B
Be CFS-L06-1313-B01-C
Be CFS-L06-1313-B02-C
Be CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.39E+00 E
1 7.01 E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.24E+00 E
1 6.43E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.47E+00 E
1 7.28E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+03 1.9E+00 6.0E+00 10 120
9.50E-01 8.6E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 6.7E+01 1.9E+00 6.0E+00
9.50E-01 2.9E+01 1.9E+00 6.0E+00
4.39E+00 1.4E+00 1.9E+00 6.0E+00
7.01 E+00 8.6E+00 1.9E+00 6.0E+00
9.50E-01 9.6E+00 1.9E+00 6.0E+00
9.50E-01 2.5E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00 10 120
9.50E-01 6.1E+02 1.9E+00 6.0E+00
9.50E-01 1.2E+03 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 8.2E+01 1.9E+00 6.0E+00
4.24E+00 3.4E+00 1.9E+00 6.0E+00
6.43E+00 6.9E+00 1.9E+00 6.0E+00
9.50E-01 8.7E+00 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+03 1.9E+00 6.0E+00 10 150
9.50E-01 6.4E+01 1.9E+00 6.0E+00
9.50E-01 4.5E+02 1.9E+00 6.0E+00
9.50E-01 6.8E+01 1.9E+00 6.0E+00
9.50E-01 6.3E+02 1.9E+00 6.0E+00
4.47E+00 1.1 E+00 1.9E+00 6.0E+00
7.28E+00 7.8E+00 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+03 1.9E+00 6.0E+00
9.50E-01 8.5E+02 1.9E+00 6.0E+00
9.50E-01 9.4E+01 1.9E+00 6.0E+00
9.50E-01 9.0E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 8.7E+02 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 3.9E+02 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.37E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.70E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-734
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd CFS-L06-1313-T01-A
Cd CFS-L06-1313-T02-A
Cd CFS-L06-1313-T03-A
Cd CFS-L06-1313-T04-A
Cd CFS-L06-1313-T05-A
Cd CFS-L06-1313-T06-A
Cd CFS-L06-1313-T07-A
Cd CFS-L06-1313-T08-A
Cd CFS-L06-1313-T09-A
Cd CFS-L06-1313-T01-B
Cd CFS-L06-1313-T02-B
Cd CFS-L06-1313-T03-B
Cd CFS-L06-1313-T04-B
Cd CFS-L06-1313-T05-B
Cd CFS-L06-1313-T06-B
Cd CFS-L06-1313-T07-B
Cd CFS-L06-1313-T08-B
Cd CFS-L06-1313-T09-B
Cd CFS-L06-1313-T01-C
Cd CFS-L06-1313-T02-C
Cd CFS-L06-1313-T03-C
Cd CFS-L06-1313-T04-C
Cd CFS-L06-1313-T05-C
Cd CFS-L06-1313-T06-C
Cd CFS-L06-1313-T07-C
Cd CFS-L06-1313-T08-C
Cd CFS-L06-1313-T09-C
Cd CFS-L06-1313-B01-A
Cd CFS-L06-1313-B02-A
Cd CFS-L06-1313-B03-A
Cd CFS-L06-1313-B01-B
Cd CFS-L06-1313-B02-B
Cd CFS-L06-1313-B03-B
Cd CFS-L06-1313-B01-C
Cd CFS-L06-1313-B02-C
Cd CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.67E+01
1 5.91E+OOE
1 1.10E+00 U1/2
1 4.79E+01
1 3.70E+02
1 4.67E+02
1 3.61 E+04
1 4.95E+04
1 5.02E+04
1 1.76E+01
1 2.63E+00 E
1 1.10E+00 U1/2
1 5.82E+01
1 5.14E+02
1 4.82E+03
1 3.38E+04
1 4.85E+04
1 5. 11 E+04
1 1.77E+01
1 6.38E+00 E
1 1.10E+00 U1/2
1 4.15E+01
1 4.13E+02
1 4.08E+03
1 3.62E+04
1 4.88E+04
1 4.97E+04
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.67E+01 3.2E+00 2.2E+00 7.0E+00
5.91E+00 2.9E+00 2.2E+00 7.0E+00 10 120
1.10E+00 1.2E+02 2.2E+00 7.0E+00
4.79E+01 4.6E-01 2.2E+00 7.0E+00
3.70E+02 5.6E-01 2.2E+00 7.0E+00
4.67E+02 1.6E+02 2.2E+00 7.0E+00
3.61 E+04 7.3E-01 2.2E+00 7.0E+00
4.95E+04 5.6E+00 2.2E+00 7.0E+00
5.02E+04 3.2E-01 2.2E+00 7.0E+00
1.76E+01 1.3E+00 2.2E+00 7.0E+00
2.63E+00 1.1E+02 2.2E+00 7.0E+00 10 120
1.10E+00 2.3E+01 2.2E+00 7.0E+00
5.82E+01 3.0E-01 2.2E+00 7.0E+00
5.14E+02 5.9E-01 2.2E+00 7.0E+00
4.82E+03 4.2E-01 2.2E+00 7.0E+00
3.38E+04 9.5E-01 2.2E+00 7.0E+00
4.85E+04 1.2E+00 2.2E+00 7.0E+00
5.11E+04 8.1E-01 2.2E+00 7.0E+00
1.77E+01 2.0E+00 2.2E+00 7.0E+00
6.38E+00 2.1E+00 2.2E+00 7.0E+00 10 150
1.10E+00 2.8E+01 2.2E+00 7.0E+00
4.15E+01 4.9E-01 2.2E+00 7.0E+00
4.13E+02 5.1E-01 2.2E+00 7.0E+00
4.08E+03 3.3E+01 2.2E+00 7.0E+00
3.62E+04 4.2E-01 2.2E+00 7.0E+00
4.88E+04 1.6E+00 2.2E+00 7.0E+00
4.97E+04 5.7E-01 2.2E+00 7.0E+00
1.10E+00 5.1E+01 2.2E+00 7.0E+00
1.10E+00 6.8E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+02 2.2E+00 7.0E+00
1.10E+00 2.1E+02 2.2E+00 7.0E+00
1.10E+00 3.1E+01 2.2E+00 7.0E+00
1.10E+00 2.5E+02 2.2E+00 7.0E+00
1.10E+00 6.8E+02 2.2E+00 7.0E+00
1.10E+00 4.3E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.28E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.61E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-735
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
CFS-L06-1313-T01-A
CFS-L06-1313-T02-A
CFS-L06-1313-T03-A
CFS-L06-1313-T04-A
CFS-L06-1313-T05-A
CFS-L06-1313-T06-A
CFS-L06-1313-T07-A
CFS-L06-1313-T08-A
CFS-L06-1313-T09-A
CFS-L06-1313-T01-B
CFS-L06-1313-T02-B
CFS-L06-1313-T03-B
CFS-L06-1313-T04-B
CFS-L06-1313-T05-B
CFS-L06-1313-T06-B
CFS-L06-1313-T07-B
CFS-L06-1313-T08-B
CFS-L06-1313-T09-B
CFS-L06-1313-T01-C
CFS-L06-1313-T02-C
CFS-L06-1313-T03-C
CFS-L06-1313-T04-C
CFS-L06-1313-T05-C
CFS-L06-1313-T06-C
CFS-L06-1313-T07-C
CFS-L06-1313-T08-C
CFS-L06-1313-T09-C
CFS-L06-1313-B01-A
CFS-L06-1313-B02-A
CFS-L06-1313-B03-A
CFS-L06-1313-B01-B
CFS-L06-1313-B02-B
CFS-L06-1313-B03-B
CFS-L06-1313-B01-C
CFS-L06-1313-B02-C
CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.31 E+05
1 6.73E+05
1 1.14E+04
1 6.81 E+05
1 7.14E+05
1 9.72E+04
1 1.08E+06
1 1.27E+06
1 1.62E+06
1 4.39E+05
1 3.37E+05
1 6.39E+05
1 6.69E+05
1 6.97E+05
1 7.24E+05
1 1.01E+06
1 1.25E+06
1 1.61E+06
1 4.74E+05
1 6.73E+05
1 6.47E+05
1 6.70E+05
1 7.02E+05
1 6.61 E+05
1 1.10E+06
1 1.29E+06
1 1.60E+06
1 7.75E+00 E
1 1.78E+01
1 2.83E+03
1 1.82E+01
1 2.21E+01
1 2.92E+03
1 2.21E+01
1 2.17E+01
1 2.99E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.31 E+05 3.9E-01 2.6E+00 8.3E+00
6.73E+05 6.7E-01 2.6E+00 8.3E+00 1000 120
1.14E+04 1.3E+02 2.6E+00 8.3E+00
6.81 E+05 5.0E-01 2.6E+00 8.3E+00
7.14E+05 4.6E-01 2.6E+00 8.3E+00
9.72E+04 1.7E+02 2.6E+00 8.3E+00
1.08E+06 9.7E-01 2.6E+00 8.3E+00
1.27E+06 5.2E+00 2.6E+00 8.3E+00
1.62E+06 7.9E-01 2.6E+00 8.3E+00
4.39E+05 3.7E-01 2.6E+00 8.3E+00
3.37E+05 9.8E+01 2.6E+00 8.3E+00 1000 120
6.39E+05 9.4E-01 2.6E+00 8.3E+00
6.69E+05 1.5E-01 2.6E+00 8.3E+00
6.97E+05 7.3E-01 2.6E+00 8.3E+00
7.24E+05 4.5E-01 2.6E+00 8.3E+00
1.01E+06 5.3E-01 2.6E+00 8.3E+00
1.25E+06 1.5E+00 2.6E+00 8.3E+00
1.61E+06 7.8E-01 2.6E+00 8.3E+00
4.74E+05 7.8E-01 2.6E+00 8.3E+00
6.73E+05 3.4E-01 2.6E+00 8.3E+00 1000 120
6.47E+05 2.6E-01 2.6E+00 8.3E+00
6.70E+05 4.1E-01 2.6E+00 8.3E+00
7.02E+05 8.4E-01 2.6E+00 8.3E+00
6.61 E+05 2.5E+01 2.6E+00 8.3E+00
1.10E+06 8.8E-01 2.6E+00 8.3E+00
1.29E+06 2.1E+00 2.6E+00 8.3E+00
1.60E+06 6.4E-01 2.6E+00 8.3E+00
7.75E+00 6.7E+01 2.6E+00 8.3E+00
1.78E+01 2.2E+01 2.6E+00 8.3E+00
2.83E+03 1.8E+00 2.6E+00 8.3E+00
1.82E+01 1.7E+01 2.6E+00 8.3E+00
2.21 E+01 1.5E+01 2.6E+00 8.3E+00
2.92E+03 6.3E-01 2.6E+00 8.3E+00
2.21 E+01 2.6E+01 2.6E+00 8.3E+00
2.17E+01 1.1 E+01 2.6E+00 8.3E+00
2.99E+03 4.0E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
6.74E+05 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.38E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.74E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-736
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr CFS-L06-1313-T01-A
Cr CFS-L06-1313-T02-A
Cr CFS-L06-1313-T03-A
Cr CFS-L06-1313-T04-A
Cr CFS-L06-1313-T05-A
Cr CFS-L06-1313-T06-A
Cr CFS-L06-1313-T07-A
Cr CFS-L06-1313-T08-A
Cr CFS-L06-1313-T09-A
Cr CFS-L06-1313-T01-B
Cr CFS-L06-1313-T02-B
Cr CFS-L06-1313-T03-B
Cr CFS-L06-1313-T04-B
Cr CFS-L06-1313-T05-B
Cr CFS-L06-1313-T06-B
Cr CFS-L06-1313-T07-B
Cr CFS-L06-1313-T08-B
Cr CFS-L06-1313-T09-B
Cr CFS-L06-1313-T01-C
Cr CFS-L06-1313-T02-C
Cr CFS-L06-1313-T03-C
Cr CFS-L06-1313-T04-C
Cr CFS-L06-1313-T05-C
Cr CFS-L06-1313-T06-C
Cr CFS-L06-1313-T07-C
Cr CFS-L06-1313-T08-C
Cr CFS-L06-1313-T09-C
Cr CFS-L06-1313-B01-A
Cr CFS-L06-1313-B02-A
Cr CFS-L06-1313-B03-A
Cr CFS-L06-1313-B01-B
Cr CFS-L06-1313-B02-B
Cr CFS-L06-1313-B03-B
Cr CFS-L06-1313-B01-C
Cr CFS-L06-1313-B02-C
Cr CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.42E+02
1 1.27E+02
1 6.00E-01 U1/2
1 1.69E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.50E+01
1 2.34E+03
1 1.65E+02
1 5.14E+01
1 1.20E+01
1 1.78E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 2.49E+01
1 2.11E+03
1 1.52E+02
1 9.76E+01
1 9.81 E+00
1 2.36E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 2.36E+01
1 1.97E+03
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.42E+02 1.2E+00 3.8E+00
1.27E+02 1.2E+00 3.8E+00 10 120
6.00E-01 1.2E+00 3.8E+00
1.69E+00 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
1.50E+01 1.2E+00 3.8E+00
2.34E+03 1.2E+00 3.8E+00
1.65E+02 1.2E+00 3.8E+00
5.14E+01 1.2E+00 3.8E+00 10 120
1.20E+01 1.2E+00 3.8E+00
1.78E+00 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
2.49E+01 1.2E+00 3.8E+00
2.11E+03 1.2E+00 3.8E+00
1.52E+02 1.2E+00 3.8E+00
9.76E+01 1.2E+00 3.8E+00 10 150
9.81 E+00 1.2E+00 3.8E+00
2.36E+00 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
2.36E+01 1.2E+00 3.8E+00
1.97E+03 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
6.00E-01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.36E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.41E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.63E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-737
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
CFS-L06-1313-T01-A
CFS-L06-1313-T02-A
CFS-L06-1313-T03-A
CFS-L06-1313-T04-A
CFS-L06-1313-T05-A
CFS-L06-1313-T06-A
CFS-L06-1313-T07-A
CFS-L06-1313-T08-A
CFS-L06-1313-T09-A
CFS-L06-1313-T01-B
CFS-L06-1313-T02-B
CFS-L06-1313-T03-B
CFS-L06-1313-T04-B
CFS-L06-1313-T05-B
CFS-L06-1313-T06-B
CFS-L06-1313-T07-B
CFS-L06-1313-T08-B
CFS-L06-1313-T09-B
CFS-L06-1313-T01-C
CFS-L06-1313-T02-C
CFS-L06-1313-T03-C
CFS-L06-1313-T04-C
CFS-L06-1313-T05-C
CFS-L06-1313-T06-C
CFS-L06-1313-T07-C
CFS-L06-1313-T08-C
CFS-L06-1313-T09-C
CFS-L06-1313-B01-A
CFS-L06-1313-B02-A
CFS-L06-1313-B03-A
CFS-L06-1313-B01-B
CFS-L06-1313-B02-B
CFS-L06-1313-B03-B
CFS-L06-1313-B01-C
CFS-L06-1313-B02-C
CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 6.20E+00
1 1.12E+01
1 1.05E+03
1 1.81E+03
1 1.84E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.45E+00
1 1.03E+02
1 9.78E+02
1 1.63E+03
1 1.81E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 7.29E+00
1 8.74E+01
1 1.05E+03
1 1.69E+03
1 1.79E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 6.4E+01 1.8E+00 5.7E+00 10 120
9.00E-01 2.1E+01 1.8E+00 5.7E+00
9.00E-01 5.6E+01 1.8E+00 5.7E+00
6.20E+00 1.2E+01 1.8E+00 5.7E+00
1.12E+01 1.8E+02 1.8E+00 5.7E+00
1.05E+03 1.0E+00 1.8E+00 5.7E+00
1.81E+03 2.1E+01 1.8E+00 5.7E+00
1.84E+03 4.8E-01 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 4.5E+02 1.8E+00 5.7E+00 10 120
9.00E-01 3.3E+02 1.8E+00 5.7E+00
9.00E-01 4.0E+01 1.8E+00 5.7E+00
9.45E+00 1.5E+01 1.8E+00 5.7E+00
1.03E+02 1.6E+00 1.8E+00 5.7E+00
9.78E+02 6.2E-01 1.8E+00 5.7E+00
1.63E+03 6.3E-01 1.8E+00 5.7E+00
1.81E+03 1.7E+00 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00 10 150
9.00E-01 3.7E+02 1.8E+00 5.7E+00
9.00E-01 7.3E+01 1.8E+00 5.7E+00
7.29E+00 8.7E+00 1.8E+00 5.7E+00
8.74E+01 2.9E+01 1.8E+00 5.7E+00
1.05E+03 2.4E-01 1.8E+00 5.7E+00
1.69E+03 6.9E+00 1.8E+00 5.7E+00
1.79E+03 1.8E-01 1.8E+00 5.7E+00
9.00E-01 1.3E+03 1.8E+00 5.7E+00
9.00E-01 3.6E+02 1.8E+00 5.7E+00
9.00E-01 1.9E+01 1.8E+00 5.7E+00
9.00E-01 5.1E+02 1.8E+00 5.7E+00
9.00E-01 2.6E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 2.1E+03 1.8E+00 5.7E+00
9.00E-01 1.8E+03 1.8E+00 5.7E+00
9.00E-01 5.6E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.22E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.52E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-738
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu CFS-L06-1313-T01-A
Cu CFS-L06-1313-T02-A
Cu CFS-L06-1313-T03-A
Cu CFS-L06-1313-T04-A
Cu CFS-L06-1313-T05-A
Cu CFS-L06-1313-T06-A
Cu CFS-L06-1313-T07-A
Cu CFS-L06-1313-T08-A
Cu CFS-L06-1313-T09-A
Cu CFS-L06-1313-T01-B
Cu CFS-L06-1313-T02-B
Cu CFS-L06-1313-T03-B
Cu CFS-L06-1313-T04-B
Cu CFS-L06-1313-T05-B
Cu CFS-L06-1313-T06-B
Cu CFS-L06-1313-T07-B
Cu CFS-L06-1313-T08-B
Cu CFS-L06-1313-T09-B
Cu CFS-L06-1313-T01-C
Cu CFS-L06-1313-T02-C
Cu CFS-L06-1313-T03-C
Cu CFS-L06-1313-T04-C
Cu CFS-L06-1313-T05-C
Cu CFS-L06-1313-T06-C
Cu CFS-L06-1313-T07-C
Cu CFS-L06-1313-T08-C
Cu CFS-L06-1313-T09-C
Cu CFS-L06-1313-B01-A
Cu CFS-L06-1313-B02-A
Cu CFS-L06-1313-B03-A
Cu CFS-L06-1313-B01-B
Cu CFS-L06-1313-B02-B
Cu CFS-L06-1313-B03-B
Cu CFS-L06-1313-B01-C
Cu CFS-L06-1313-B02-C
Cu CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.11E+04
1 2.23E+03
1 1.85E+00 U1/2
1 1.06E+03
1 1.26E+02
1 1.92E+02
1 4.98E+05
1 8.68E+05
1 1.08E+06
1 1.03E+04
1 1.26E+03
1 2.04E+02
1 1.23E+03
1 1.65E+02
1 8.12E+02
1 4.79E+05
1 8.82E+05
1 1.08E+06
1 1.04E+04
1 2.29E+03
1 1.96E+02
1 9.39E+02
1 7.43E+02
1 7.85E+02
1 4.98E+05
1 8.97E+05
1 1.05E+06
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.11E+04 2.6E+00 3.7E+00 1.2E+01
2.23E+03 7.6E-01 3.7E+00 1.2E+01 10 120
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.06E+03 7.5E-01 3.7E+00 1.2E+01
1.26E+02 2.0E+00 3.7E+00 1.2E+01
1.92E+02 1.7E+02 3.7E+00 1.2E+01
4.98E+05 1.5E+00 3.7E+00 1.2E+01
8.68E+05 4.4E+00 3.7E+00 1.2E+01
1.08E+06 1.6E+00 3.7E+00 1.2E+01
1.03E+04 1.2E-01 3.7E+00 1.2E+01
1.26E+03 8.9E+01 3.7E+00 1.2E+01 10 120
2.04E+02 2.0E+00 3.7E+00 1.2E+01
1.23E+03 1.7E-01 3.7E+00 1.2E+01
1.65E+02 9.0E-01 3.7E+00 1.2E+01
8.12E+02 1.4E+00 3.7E+00 1.2E+01
4.79E+05 6.7E-01 3.7E+00 1.2E+01
8.82E+05 4.2E-01 3.7E+00 1.2E+01
1.08E+06 1.3E+00 3.7E+00 1.2E+01
1.04E+04 1.1E+00 3.7E+00 1.2E+01
2.29E+03 1.3E+00 3.7E+00 1.2E+01 10 150
1.96E+02 1.8E+00 3.7E+00 1.2E+01
9.39E+02 2.1E-01 3.7E+00 1.2E+01
7.43E+02 1.4E+00 3.7E+00 1.2E+01
7.85E+02 1.3E+01 3.7E+00 1.2E+01
4.98E+05 7.5E-01 3.7E+00 1.2E+01
8.97E+05 1.1E+00 3.7E+00 1.2E+01
1.05E+06 4.5E-01 3.7E+00 1.2E+01
1.85E+00 6.9E+01 3.7E+00 1.2E+01
1.85E+00 1.5E+03 3.7E+00 1.2E+01
1.85E+00 4.7E+01 3.7E+00 1.2E+01
1.85E+00 1.0E+02 3.7E+00 1.2E+01
1.85E+00 4.7E+02 3.7E+00 1.2E+01
1.85E+00 7.8E+01 3.7E+00 1.2E+01
1.85E+00 1.8E+02 3.7E+00 1.2E+01
1.85E+00 1.0E+02 3.7E+00 1.2E+01
1.85E+00 9.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.25E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.38E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.58E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-739
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe CFS-L06-1313-T01-A
Fe CFS-L06-1313-T02-A
Fe CFS-L06-1313-T03-A
Fe CFS-L06-1313-T04-A
Fe CFS-L06-1313-T05-A
Fe CFS-L06-1313-T06-A
Fe CFS-L06-1313-T07-A
Fe CFS-L06-1313-T08-A
Fe CFS-L06-1313-T09-A
Fe CFS-L06-1313-T01-B
Fe CFS-L06-1313-T02-B
Fe CFS-L06-1313-T03-B
Fe CFS-L06-1313-T04-B
Fe CFS-L06-1313-T05-B
Fe CFS-L06-1313-T06-B
Fe CFS-L06-1313-T07-B
Fe CFS-L06-1313-T08-B
Fe CFS-L06-1313-T09-B
Fe CFS-L06-1313-T01-C
Fe CFS-L06-1313-T02-C
Fe CFS-L06-1313-T03-C
Fe CFS-L06-1313-T04-C
Fe CFS-L06-1313-T05-C
Fe CFS-L06-1313-T06-C
Fe CFS-L06-1313-T07-C
Fe CFS-L06-1313-T08-C
Fe CFS-L06-1313-T09-C
Fe CFS-L06-1313-B01-A
Fe CFS-L06-1313-B02-A
Fe CFS-L06-1313-B03-A
Fe CFS-L06-1313-B01-B
Fe CFS-L06-1313-B02-B
Fe CFS-L06-1313-B03-B
Fe CFS-L06-1313-B01-C
Fe CFS-L06-1313-B02-C
Fe CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 3.31 E+00 E
1 1.00E+00 U1/2
1 2.87E+00 E
1 2.38E+00 E
1 1.00E+00 U1/2
1 4.82E+01
1 6.12E+03
1 2.39E+05
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.91 E+00 E
1 3.98E+00 E
1 2.93E+00 E
1 1.00E+00 U1/2
1 3.48E+01
1 1.49E+04
1 2.60E+05
1 5.94E+00 E
1 2.12E+00 E
1 2.01 E+00 E
1 3.37E+00 E
1 2.62E+00 E
1 1.00E+00 U1/2
1 3.77E+01
1 1.46E+04
1 2.59E+05
1 1.00E+00 U1/2
1 2.25E+00 E
1 2.72E+00 E
1 1.00E+00 U1/2
1 2.78E+00 E
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.7E+01 2.0E+00 6.4E+00
3.31E+00 2.0E+01 2.0E+00 6.4E+00 1000 120
1.00E+00 5.3E+01 2.0E+00 6.4E+00
2.87E+00 6.8E+00 2.0E+00 6.4E+00
2.38E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
4.82E+01 1.4E+00 2.0E+00 6.4E+00
6.12E+03 1.1E+01 2.0E+00 6.4E+00
2.39E+05 6.0E-01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00 1000 120
2.91 E+00 1.0E+01 2.0E+00 6.4E+00
3.98E+00 8.3E+00 2.0E+00 6.4E+00
2.93E+00 5.1E+00 2.0E+00 6.4E+00
1.00E+00 4.4E+01 2.0E+00 6.4E+00
3.48E+01 1.2E+00 2.0E+00 6.4E+00
1.49E+04 7.7E-01 2.0E+00 6.4E+00
2.60E+05 6.3E+00 2.0E+00 6.4E+00
5.94E+00 8.7E+00 2.0E+00 6.4E+00
2.12E+00 5.1E+00 2.0E+00 6.4E+00 1000 120
2.01 E+00 2.2E+01 2.0E+00 6.4E+00
3.37E+00 1.8E+01 2.0E+00 6.4E+00
2.62E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 4.2E+01 2.0E+00 6.4E+00
3.77E+01 1.2E+00 2.0E+00 6.4E+00
1.46E+04 1.1 E+00 2.0E+00 6.4E+00
2.59E+05 1.9E+00 2.0E+00 6.4E+00
1.00E+00 5.5E+01 2.0E+00 6.4E+00
2.25E+00 1.4E+01 2.0E+00 6.4E+00
2.72E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
2.78E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 3.7E+01 2.0E+00 6.4E+00
1.00E+00 5.4E+00 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.28E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.39E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-740
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb CFS-L06-1313-T01-A
Pb CFS-L06-1313-T02-A
Pb CFS-L06-1313-T03-A
Pb CFS-L06-1313-T04-A
Pb CFS-L06-1313-T05-A
Pb CFS-L06-1313-T06-A
Pb CFS-L06-1313-T07-A
Pb CFS-L06-1313-T08-A
Pb CFS-L06-1313-T09-A
Pb CFS-L06-1313-T01-B
Pb CFS-L06-1313-T02-B
Pb CFS-L06-1313-T03-B
Pb CFS-L06-1313-T04-B
Pb CFS-L06-1313-T05-B
Pb CFS-L06-1313-T06-B
Pb CFS-L06-1313-T07-B
Pb CFS-L06-1313-T08-B
Pb CFS-L06-1313-T09-B
Pb CFS-L06-1313-T01-C
Pb CFS-L06-1313-T02-C
Pb CFS-L06-1313-T03-C
Pb CFS-L06-1313-T04-C
Pb CFS-L06-1313-T05-C
Pb CFS-L06-1313-T06-C
Pb CFS-L06-1313-T07-C
Pb CFS-L06-1313-T08-C
Pb CFS-L06-1313-T09-C
Pb CFS-L06-1313-B01-A
Pb CFS-L06-1313-B02-A
Pb CFS-L06-1313-B03-A
Pb CFS-L06-1313-B01-B
Pb CFS-L06-1313-B02-B
Pb CFS-L06-1313-B03-B
Pb CFS-L06-1313-B01-C
Pb CFS-L06-1313-B02-C
Pb CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.64E+03
1 7.45E+03
1 3.40E+00 U1/2
1 1.03E+02
1 1.76E+02
1 4.29E+01
1 6.93E+03
1 5.71E+03
1 8.88E+03
1 4.81 E+03
1 3.83E+03
1 1.27E+03
1 1.01E+02
1 2.21 E+02
1 1.12E+03
1 6.65E+03
1 5.61 E+03
1 8.64E+03
1 4.33E+03
1 7.24E+03
1 1.32E+03
1 9.85E+01
1 2.92E+02
1 9.51 E+02
1 6.76E+03
1 6.12E+03
1 8.41 E+03
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.64E+03 1.7E+00 6.8E+00 2.2E+01
7.45E+03 1.6E+00 6.8E+00 2.2E+01 10 120
3.40E+00 3.1E+01 6.8E+00 2.2E+01
1.03E+02 6.7E+00 6.8E+00 2.2E+01
1.76E+02 4.3E+00 6.8E+00 2.2E+01
4.29E+01 5.3E+02 6.8E+00 2.2E+01
6.93E+03 1.4E+00 6.8E+00 2.2E+01
5.71E+03 7.5E+00 6.8E+00 2.2E+01
8.88E+03 3.3E-01 6.8E+00 2.2E+01
4.81 E+03 1.3E+00 6.8E+00 2.2E+01
3.83E+03 9.2E+01 6.8E+00 2.2E+01 10 120
1.27E+03 1.0E+00 6.8E+00 2.2E+01
1.01 E+02 1.7E+00 6.8E+00 2.2E+01
2.21E+02 3.8E+00 6.8E+00 2.2E+01
1.12E+03 1.4E+00 6.8E+00 2.2E+01
6.65E+03 1.4E+00 6.8E+00 2.2E+01
5.61 E+03 3.2E-01 6.8E+00 2.2E+01
8.64E+03 2.3E-01 6.8E+00 2.2E+01
4.33E+03 1.5E+00 6.8E+00 2.2E+01
7.24E+03 1.0E+00 6.8E+00 2.2E+01 10 150
1.32E+03 1.8E-02 6.8E+00 2.2E+01
9.85E+01 3.2E+00 6.8E+00 2.2E+01
2.92E+02 1.4E+00 6.8E+00 2.2E+01
9.51 E+02 3.4E+01 6.8E+00 2.2E+01
6.76E+03 1.4E+00 6.8E+00 2.2E+01
6.12E+03 8.3E+00 6.8E+00 2.2E+01
8.41 E+03 3.2E-01 6.8E+00 2.2E+01
3.40E+00 1.9E+00 6.8E+00 2.2E+01
3.40E+00 2.2E+00 6.8E+00 2.2E+01
3.40E+00 7.3E+00 6.8E+00 2.2E+01
3.40E+00 3.4E+00 6.8E+00 2.2E+01
3.40E+00 1.4E+00 6.8E+00 2.2E+01
3.40E+00 5.8E+00 6.8E+00 2.2E+01
3.40E+00 4.0E+00 6.8E+00 2.2E+01
3.40E+00 1.6E+00 6.8E+00 2.2E+01
3.40E+00 2.8E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.60E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.94E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.57E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-741
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li CFS-L06-1313-T01-A
Li CFS-L06-1313-T02-A
Li CFS-L06-1313-T03-A
Li CFS-L06-1313-T04-A
Li CFS-L06-1313-T05-A
Li CFS-L06-1313-T06-A
Li CFS-L06-1313-T07-A
Li CFS-L06-1313-T08-A
Li CFS-L06-1313-T09-A
Li CFS-L06-1313-T01-B
Li CFS-L06-1313-T02-B
Li CFS-L06-1313-T03-B
Li CFS-L06-1313-T04-B
Li CFS-L06-1313-T05-B
Li CFS-L06-1313-T06-B
Li CFS-L06-1313-T07-B
Li CFS-L06-1313-T08-B
Li CFS-L06-1313-T09-B
Li CFS-L06-1313-T01-C
Li CFS-L06-1313-T02-C
Li CFS-L06-1313-T03-C
Li CFS-L06-1313-T04-C
Li CFS-L06-1313-T05-C
Li CFS-L06-1313-T06-C
Li CFS-L06-1313-T07-C
Li CFS-L06-1313-T08-C
Li CFS-L06-1313-T09-C
Li CFS-L06-1313-B01-A
Li CFS-L06-1313-B02-A
Li CFS-L06-1313-B03-A
Li CFS-L06-1313-B01-B
Li CFS-L06-1313-B02-B
Li CFS-L06-1313-B03-B
Li CFS-L06-1313-B01-C
Li CFS-L06-1313-B02-C
Li CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.04E+01
1 4.20E+01
1 2.99E+01
1 4.23E+01
1 4.03E+01
1 3.33E+01
1 3.77E+01
1 4.57E+01
1 9.09E+01
1 4.12E+01
1 3.56E+01
1 4.03E+01
1 3.97E+01
1 3.88E+01
1 4.02E+01
1 3.60E+01
1 4.14E+01
1 6.98E+01
1 4.18E+01
1 4.27E+01
1 3.97E+01
1 4.13E+01
1 4.00E+01
1 3.90E+01
1 4.08E+01
1 4.46E+01
1 6.91E+01
1 2.83E+01
1 2.82E+01
1 2.89E+01
1 2.87E+01
1 2.82E+01
1 2.85E+01
1 2.76E+01
1 2.95E+01
1 2.96E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.04E+01 4.0E+00 1.9E+00 6.0E+00
4.20E+01 1.4E+00 1.9E+00 6.0E+00 10 120
2.99E+01 1.3E+00 1.9E+00 6.0E+00
4.23E+01 3.5E+00 1.9E+00 6.0E+00
4.03E+01 3.6E+00 1.9E+00 6.0E+00
3.33E+01 3.5E+00 1.9E+00 6.0E+00
3.77E+01 1.2E+01 1.9E+00 6.0E+00
4.57E+01 9.2E+00 1.9E+00 6.0E+00
9.09E+01 2.1E+00 1.9E+00 6.0E+00
4.12E+01 2.3E+00 1.9E+00 6.0E+00
3.56E+01 8.9E+00 1.9E+00 6.0E+00 10 120
4.03E+01 2.5E+00 1.9E+00 6.0E+00
3.97E+01 7.5E+00 1.9E+00 6.0E+00
3.88E+01 5.3E+00 1.9E+00 6.0E+00
4.02E+01 7.0E+00 1.9E+00 6.0E+00
3.60E+01 4.2E+00 1.9E+00 6.0E+00
4.14E+01 4.9E+00 1.9E+00 6.0E+00
6.98E+01 9.7E+00 1.9E+00 6.0E+00
4.18E+01 1.5E+00 1.9E+00 6.0E+00
4.27E+01 2.5E+00 1.9E+00 6.0E+00 10 150
3.97E+01 3.4E+00 1.9E+00 6.0E+00
4.13E+01 1.7E+00 1.9E+00 6.0E+00
4.00E+01 1.2E+01 1.9E+00 6.0E+00
3.90E+01 5.7E+00 1.9E+00 6.0E+00
4.08E+01 4.9E+00 1.9E+00 6.0E+00
4.46E+01 8.1E+00 1.9E+00 6.0E+00
6.91 E+01 4.4E+00 1.9E+00 6.0E+00
2.83E+01 1.1E+00 1.9E+00 6.0E+00
2.82E+01 2.6E+00 1.9E+00 6.0E+00
2.89E+01 1.7E+00 1.9E+00 6.0E+00
2.87E+01 3.5E+00 1.9E+00 6.0E+00
2.82E+01 1.1E-01 1.9E+00 6.0E+00
2.85E+01 4.4E+00 1.9E+00 6.0E+00
2.76E+01 3.6E+00 1.9E+00 6.0E+00
2.95E+01 4.6E+00 1.9E+00 6.0E+00
2.96E+01 2.2E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.14E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-742
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn CFS-L06-1313-T01-A
Mn CFS-L06-1313-T02-A
Mn CFS-L06-1313-T03-A
Mn CFS-L06-1313-T04-A
Mn CFS-L06-1313-T05-A
Mn CFS-L06-1313-T06-A
Mn CFS-L06-1313-T07-A
Mn CFS-L06-1313-T08-A
Mn CFS-L06-1313-T09-A
Mn CFS-L06-1313-T01-B
Mn CFS-L06-1313-T02-B
Mn CFS-L06-1313-T03-B
Mn CFS-L06-1313-T04-B
Mn CFS-L06-1313-T05-B
Mn CFS-L06-1313-T06-B
Mn CFS-L06-1313-T07-B
Mn CFS-L06-1313-T08-B
Mn CFS-L06-1313-T09-B
Mn CFS-L06-1313-T01-C
Mn CFS-L06-1313-T02-C
Mn CFS-L06-1313-T03-C
Mn CFS-L06-1313-T04-C
Mn CFS-L06-1313-T05-C
Mn CFS-L06-1313-T06-C
Mn CFS-L06-1313-T07-C
Mn CFS-L06-1313-T08-C
Mn CFS-L06-1313-T09-C
Mn CFS-L06-1313-B01-A
Mn CFS-L06-1313-B02-A
Mn CFS-L06-1313-B03-A
Mn CFS-L06-1313-B01-B
Mn CFS-L06-1313-B02-B
Mn CFS-L06-1313-B03-B
Mn CFS-L06-1313-B01-C
Mn CFS-L06-1313-B02-C
Mn CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 7.51 E+00
1 1.63E+02
1 4.36E+02
1 1.09E+04
1 2.03E+04
1 3.21E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 9.67E+00
1 2.55E+02
1 1.61E+03
1 9.83E+03
1 1.99E+04
1 3.18E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 6.34E+00 E
1 1.70E+02
1 1.34E+03
1 1.06E+04
1 1.98E+04
1 3.39E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 7.2E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00 10 120
1.00E+00 6.1E+01 2.0E+00 6.4E+00
7.51 E+00 7.4E-01 2.0E+00 6.4E+00
1.63E+02 1.1 E+00 2.0E+00 6.4E+00
4.36E+02 1.7E+02 2.0E+00 6.4E+00
1.09E+04 1.2E+00 2.0E+00 6.4E+00
2.03E+04 5.2E+00 2.0E+00 6.4E+00
3.21 E+04 1.3E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00 10 120
1.00E+00 1.0E+01 2.0E+00 6.4E+00
9.67E+00 1.2E+00 2.0E+00 6.4E+00
2.55E+02 7.8E-01 2.0E+00 6.4E+00
1.61E+03 1.6E+00 2.0E+00 6.4E+00
9.83E+03 4.7E-01 2.0E+00 6.4E+00
1.99E+04 6.3E-01 2.0E+00 6.4E+00
3.18E+04 1.3E+00 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00 10 150
1.00E+00 3.5E+01 2.0E+00 6.4E+00
6.34E+00 9.7E-02 2.0E+00 6.4E+00
1.70E+02 1.3E+00 2.0E+00 6.4E+00
1.34E+03 3.7E+01 2.0E+00 6.4E+00
1.06E+04 1.2E+00 2.0E+00 6.4E+00
1.98E+04 4.4E-01 2.0E+00 6.4E+00
3.39E+04 9.0E-01 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 9.2E+01 2.0E+00 6.4E+00
1.00E+00 9.6E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.50E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-743
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg CFS-L06-1313-T01-A
Mg CFS-L06-1313-T02-A
Mg CFS-L06-1313-T03-A
Mg CFS-L06-1313-T04-A
Mg CFS-L06-1313-T05-A
Mg CFS-L06-1313-T06-A
Mg CFS-L06-1313-T07-A
Mg CFS-L06-1313-T08-A
Mg CFS-L06-1313-T09-A
Mg CFS-L06-1313-T01-B
Mg CFS-L06-1313-T02-B
Mg CFS-L06-1313-T03-B
Mg CFS-L06-1313-T04-B
Mg CFS-L06-1313-T05-B
Mg CFS-L06-1313-T06-B
Mg CFS-L06-1313-T07-B
Mg CFS-L06-1313-T08-B
Mg CFS-L06-1313-T09-B
Mg CFS-L06-1313-T01-C
Mg CFS-L06-1313-T02-C
Mg CFS-L06-1313-T03-C
Mg CFS-L06-1313-T04-C
Mg CFS-L06-1313-T05-C
Mg CFS-L06-1313-T06-C
Mg CFS-L06-1313-T07-C
Mg CFS-L06-1313-T08-C
Mg CFS-L06-1313-T09-C
Mg CFS-L06-1313-B01-A
Mg CFS-L06-1313-B02-A
Mg CFS-L06-1313-B03-A
Mg CFS-L06-1313-B01-B
Mg CFS-L06-1313-B02-B
Mg CFS-L06-1313-B03-B
Mg CFS-L06-1313-B01-C
Mg CFS-L06-1313-B02-C
Mg CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.11E+01
1 4.19E+01
1 5.00E-01 U1/2
1 3.47E+04
1 7.45E+04
1 5.33E+03
1 8.41 E+04
1 1.25E+05
1 2.86E+05
1 3.59E+01
1 2.15E+01
1 3.58E+02
1 3.43E+04
1 6.67E+04
1 6.82E+04
1 7.73E+04
1 1.21E+05
1 2.29E+05
1 3.03E+01
1 3.22E+01
1 4.00E+02
1 3.30E+04
1 6.51 E+04
1 6.08E+04
1 8.09E+04
1 1.16E+05
1 2.00E+05
1 5.00E-01 U1/2
1 7.67E+00
1 2.30E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.36E+01
1 2.33E+00 E
1 5.00E-01 U1/2
1 1.47E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.11E+01 1.9E+01 1.0E+00 3.2E+00
4.19E+01 2.4E+01 1.0E+00 3.2E+00 1000 120
5.00E-01 4.9E+02 1.0E+00 3.2E+00
3.47E+04 5.9E-01 1.0E+00 3.2E+00
7.45E+04 4.9E-01 1.0E+00 3.2E+00
5.33E+03 1.6E+02 1.0E+00 3.2E+00
8.41 E+04 7.7E-01 1.0E+00 3.2E+00
1.25E+05 1.1E+01 1.0E+00 3.2E+00
2.86E+05 1.2E+00 1.0E+00 3.2E+00
3.59E+01 3.2E+01 1.0E+00 3.2E+00
2.15E+01 1.5E+02 1.0E+00 3.2E+00 1000 120
3.58E+02 4.1E+00 1.0E+00 3.2E+00
3.43E+04 7.5E-01 1.0E+00 3.2E+00
6.67E+04 8.1E-01 1.0E+00 3.2E+00
6.82E+04 1.0E+00 1.0E+00 3.2E+00
7.73E+04 6.0E-01 1.0E+00 3.2E+00
1.21E+05 8.8E-01 1.0E+00 3.2E+00
2.29E+05 7.3E-01 1.0E+00 3.2E+00
3.03E+01 2.1E+01 1.0E+00 3.2E+00
3.22E+01 1.8E+01 1.0E+00 3.2E+00 1000 120
4.00E+02 1.6E+00 1.0E+00 3.2E+00
3.30E+04 5.6E-01 1.0E+00 3.2E+00
6.51 E+04 5.9E-01 1.0E+00 3.2E+00
6.08E+04 2.5E+01 1.0E+00 3.2E+00
8.09E+04 7.5E-01 1.0E+00 3.2E+00
1.16E+05 7.5E-01 1.0E+00 3.2E+00
2.00E+05 4.9E-01 1.0E+00 3.2E+00
5.00E-01 7.6E+01 1.0E+00 3.2E+00
7.67E+00 3.9E+01 1.0E+00 3.2E+00
2.30E+01 4.5E+01 1.0E+00 3.2E+00
5.00E-01 2.3E+02 1.0E+00 3.2E+00
5.00E-01 4.6E+01 1.0E+00 3.2E+00
1.36E+01 1.2E+01 1.0E+00 3.2E+00
2.33E+00 5.0E+02 1.0E+00 3.2E+00
5.00E-01 1.4E+03 1.0E+00 3.2E+00
1.47E+01 2.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-744
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo CFS-L06-1313-T01-A
Mo CFS-L06-1313-T02-A
Mo CFS-L06-1313-T03-A
Mo CFS-L06-1313-T04-A
Mo CFS-L06-1313-T05-A
Mo CFS-L06-1313-T06-A
Mo CFS-L06-1313-T07-A
Mo CFS-L06-1313-T08-A
Mo CFS-L06-1313-T09-A
Mo CFS-L06-1313-T01-B
Mo CFS-L06-1313-T02-B
Mo CFS-L06-1313-T03-B
Mo CFS-L06-1313-T04-B
Mo CFS-L06-1313-T05-B
Mo CFS-L06-1313-T06-B
Mo CFS-L06-1313-T07-B
Mo CFS-L06-1313-T08-B
Mo CFS-L06-1313-T09-B
Mo CFS-L06-1313-T01-C
Mo CFS-L06-1313-T02-C
Mo CFS-L06-1313-T03-C
Mo CFS-L06-1313-T04-C
Mo CFS-L06-1313-T05-C
Mo CFS-L06-1313-T06-C
Mo CFS-L06-1313-T07-C
Mo CFS-L06-1313-T08-C
Mo CFS-L06-1313-T09-C
Mo CFS-L06-1313-B01-A
Mo CFS-L06-1313-B02-A
Mo CFS-L06-1313-B03-A
Mo CFS-L06-1313-B01-B
Mo CFS-L06-1313-B02-B
Mo CFS-L06-1313-B03-B
Mo CFS-L06-1313-B01-C
Mo CFS-L06-1313-B02-C
Mo CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.01E+03
1 1.95E+03
1 2.43E+01
1 4.33E+02
1 6.41 E+01
1 6.00E-01 U1/2
1 6.26E+00
1 6.66E+00
1 7.26E+01
1 2.03E+03
1 9.64E+02
1 1.28E+03
1 4.36E+02
1 4.92E+01
1 1.10E+01
1 7.41 E+00
1 9.09E+00
1 1.00E+02
1 2.06E+03
1 1.89E+03
1 1.27E+03
1 4.36E+02
1 5.68E+01
1 9.29E+00
1 9.53E+00
1 8.20E+00
1 9.46E+01
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.62E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01E+03 3.2E-01 1.2E+00 3.8E+00
1.95E+03 5.8E-01 1.2E+00 3.8E+00 10 120
2.43E+01 8.6E+01 1.2E+00 3.8E+00
4.33E+02 3.8E-01 1.2E+00 3.8E+00
6.41 E+01 3.4E+00 1.2E+00 3.8E+00
6.00E-01 4.2E+02 1.2E+00 3.8E+00
6.26E+00 3.2E+01 1.2E+00 3.8E+00
6.66E+00 3.4E+01 1.2E+00 3.8E+00
7.26E+01 1.9E+00 1.2E+00 3.8E+00
2.03E+03 4.1E-01 1.2E+00 3.8E+00
9.64E+02 9.7E+01 1.2E+00 3.8E+00 10 120
1.28E+03 1.4E+00 1.2E+00 3.8E+00
4.36E+02 6.8E-01 1.2E+00 3.8E+00
4.92E+01 3.7E+00 1.2E+00 3.8E+00
1.10E+01 4.3E+00 1.2E+00 3.8E+00
7.41 E+00 3.4E+01 1.2E+00 3.8E+00
9.09E+00 1.6E+01 1.2E+00 3.8E+00
1.00E+02 9.0E+00 1.2E+00 3.8E+00
2.06E+03 4.6E-01 1.2E+00 3.8E+00
1.89E+03 7.6E-01 1.2E+00 3.8E+00 10 150
1.27E+03 2.1E-01 1.2E+00 3.8E+00
4.36E+02 2.7E-01 1.2E+00 3.8E+00
5.68E+01 2.1 E+00 1.2E+00 3.8E+00
9.29E+00 2.9E+01 1.2E+00 3.8E+00
9.53E+00 1.4E+01 1.2E+00 3.8E+00
8.20E+00 3.1 E+01 1.2E+00 3.8E+00
9.46E+01 2.4E+00 1.2E+00 3.8E+00
6.00E-01 9.1 E+01 1.2E+00 3.8E+00
6.00E-01 5.5E+01 1.2E+00 3.8E+00
6.00E-01 1.0E+02 1.2E+00 3.8E+00
6.00E-01 6.6E+01 1.2E+00 3.8E+00
6.00E-01 1.8E+02 1.2E+00 3.8E+00
1.62E+00 4.0E+01 1.2E+00 3.8E+00
6.00E-01 2.8E+01 1.2E+00 3.8E+00
6.00E-01 7.0E+02 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.99E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.05E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.24E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-745
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni CFS-L06-1313-T01-A
Ni CFS-L06-1313-T02-A
Ni CFS-L06-1313-T03-A
Ni CFS-L06-1313-T04-A
Ni CFS-L06-1313-T05-A
Ni CFS-L06-1313-T06-A
Ni CFS-L06-1313-T07-A
Ni CFS-L06-1313-T08-A
Ni CFS-L06-1313-T09-A
Ni CFS-L06-1313-T01-B
Ni CFS-L06-1313-T02-B
Ni CFS-L06-1313-T03-B
Ni CFS-L06-1313-T04-B
Ni CFS-L06-1313-T05-B
Ni CFS-L06-1313-T06-B
Ni CFS-L06-1313-T07-B
Ni CFS-L06-1313-T08-B
Ni CFS-L06-1313-T09-B
Ni CFS-L06-1313-T01-C
Ni CFS-L06-1313-T02-C
Ni CFS-L06-1313-T03-C
Ni CFS-L06-1313-T04-C
Ni CFS-L06-1313-T05-C
Ni CFS-L06-1313-T06-C
Ni CFS-L06-1313-T07-C
Ni CFS-L06-1313-T08-C
Ni CFS-L06-1313-T09-C
Ni CFS-L06-1313-B01-A
Ni CFS-L06-1313-B02-A
Ni CFS-L06-1313-B03-A
Ni CFS-L06-1313-B01-B
Ni CFS-L06-1313-B02-B
Ni CFS-L06-1313-B03-B
Ni CFS-L06-1313-B01-C
Ni CFS-L06-1313-B02-C
Ni CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.50E+00 E
1 3.73E+00 E
1 9.00E-01 U1/2
1 3.64E+00 E
1 1.17E+01
1 2.42E+01
1 4.05E+03
1 6.34E+03
1 6.96E+03
1 2.98E+00 E
1 9.00E-01 U1/2
1 2.45E+00 E
1 3.88E+00 E
1 1.78E+01
1 2.25E+02
1 3.86E+03
1 6.31 E+03
1 6.83E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.80E+00 E
1 3.69E+00 E
1 1.14E+01
1 1.94E+02
1 4.06E+03
1 6.29E+03
1 6.53E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 2.93E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 2.7E+01 1.8E+00 5.7E+00
3.73E+00 4.5E+01 1.8E+00 5.7E+00 10 120
9.00E-01 1.4E+02 1.8E+00 5.7E+00
3.64E+00 5.5E+01 1.8E+00 5.7E+00
1.17E+01 5.9E+00 1.8E+00 5.7E+00
2.42E+01 1.7E+02 1.8E+00 5.7E+00
4.05E+03 4.0E-01 1.8E+00 5.7E+00
6.34E+03 8.3E+00 1.8E+00 5.7E+00
6.96E+03 3.5E-01 1.8E+00 5.7E+00
2.98E+00 1.1E+02 1.8E+00 5.7E+00
9.00E-01 5.4E+02 1.8E+00 5.7E+00 10 120
2.45E+00 7.4E+01 1.8E+00 5.7E+00
3.88E+00 4.1E+01 1.8E+00 5.7E+00
1.78E+01 7.3E+00 1.8E+00 5.7E+00
2.25E+02 6.3E-01 1.8E+00 5.7E+00
3.86E+03 3.0E-01 1.8E+00 5.7E+00
6.31 E+03 1.4E+00 1.8E+00 5.7E+00
6.83E+03 5.7E-01 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00 10 150
1.80E+00 1.2E+02 1.8E+00 5.7E+00
3.69E+00 3.2E+01 1.8E+00 5.7E+00
1.14E+01 1.8E+01 1.8E+00 5.7E+00
1.94E+02 3.0E+01 1.8E+00 5.7E+00
4.06E+03 1.8E-01 1.8E+00 5.7E+00
6.29E+03 1.8E+00 1.8E+00 5.7E+00
6.53E+03 3.1E-01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
2.93E+00 3.9E+01 1.8E+00 5.7E+00
9.00E-01 4.7E+02 1.8E+00 5.7E+00
9.00E-01 9.1E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
9.00E-01 4.3E+02 1.8E+00 5.7E+00
9.00E-01 8.0E+01 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.26E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.33E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.59E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-746
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P CFS-L06-1313-T01-A
P CFS-L06-1313-T02-A
P CFS-L06-1313-T03-A
P CFS-L06-1313-T04-A
P CFS-L06-1313-T05-A
P CFS-L06-1313-T06-A
P CFS-L06-1313-T07-A
P CFS-L06-1313-T08-A
P CFS-L06-1313-T09-A
P CFS-L06-1313-T01-B
P CFS-L06-1313-T02-B
P CFS-L06-1313-T03-B
P CFS-L06-1313-T04-B
P CFS-L06-1313-T05-B
P CFS-L06-1313-T06-B
P CFS-L06-1313-T07-B
P CFS-L06-1313-T08-B
P CFS-L06-1313-T09-B
P CFS-L06-1313-T01-C
P CFS-L06-1313-T02-C
P CFS-L06-1313-T03-C
P CFS-L06-1313-T04-C
P CFS-L06-1313-T05-C
P CFS-L06-1313-T06-C
P CFS-L06-1313-T07-C
P CFS-L06-1313-T08-C
P CFS-L06-1313-T09-C
P CFS-L06-1313-B01-A
P CFS-L06-1313-B02-A
P CFS-L06-1313-B03-A
P CFS-L06-1313-B01-B
P CFS-L06-1313-B02-B
P CFS-L06-1313-B03-B
P CFS-L06-1313-B01-C
P CFS-L06-1313-B02-C
P CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.76E+01
1 5.72E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.86E+01
1 1.38E+01
1 2.05E+03
1 8.48E+01
1 2.36E+01
1 4.51 E+01
1 1.85E+00 U1/2
1 5.37E+00 E
1 7.29E+00 E
1 1.85E+00 U1/2
1 6.00E+00 E
1 2.81 E+03
1 9.00E+01
1 8.58E+01
1 2.77E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 5.51E+OOE
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 2.77E+03
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 2.22E+01
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 1.88E+01
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 1.68E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.76E+01 4.9E+00 3.7E+00 1.2E+01
5.72E+01 9.9E+00 3.7E+00 1.2E+01 1000 120
1.85E+00 2.1 E+01 3.7E+00 1.2E+01
1.85E+00 7.2E+01 3.7E+00 1.2E+01
1.85E+00 4.0E+01 3.7E+00 1.2E+01
1.85E+00 1.7E+01 3.7E+00 1.2E+01
1.86E+01 4.8E+01 3.7E+00 1.2E+01
1.38E+01 1.4E+02 3.7E+00 1.2E+01
2.05E+03 3.7E-01 3.7E+00 1.2E+01
8.48E+01 1.8E+01 3.7E+00 1.2E+01
2.36E+01 1.6E+02 3.7E+00 1.2E+01 1000 120
4.51 E+01 5.2E+01 3.7E+00 1.2E+01
1.85E+00 7.1E+02 3.7E+00 1.2E+01
5.37E+00 2.2E+02 3.7E+00 1.2E+01
7.29E+00 3.1E+02 3.7E+00 1.2E+01
1.85E+00 6.5E+02 3.7E+00 1.2E+01
6.00E+00 3.7E+02 3.7E+00 1.2E+01
2.81 E+03 6.3E-01 3.7E+00 1.2E+01
9.00E+01 2.4E+01 3.7E+00 1.2E+01
8.58E+01 7.2E+00 3.7E+00 1.2E+01 1000 120
2.77E+01 1.4E+01 3.7E+00 1.2E+01
1.85E+00 2.1E+03 3.7E+00 1.2E+01
1.85E+00 6.6E+01 3.7E+00 1.2E+01
5.51 E+00 3.8E+02 3.7E+00 1.2E+01
1.85E+00 6.8E+02 3.7E+00 1.2E+01
1.85E+00 1.5E+03 3.7E+00 1.2E+01
2.77E+03 6.0E-01 3.7E+00 1.2E+01
1.85E+00 1.4E+02 3.7E+00 1.2E+01
1.85E+00 1.6E+02 3.7E+00 1.2E+01
2.22E+01 3.7E+01 3.7E+00 1.2E+01
1.85E+00 2.7E+01 3.7E+00 1.2E+01
1.85E+00 5.7E+01 3.7E+00 1.2E+01
1.88E+01 7.2E+01 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.85E+00 5.4E+01 3.7E+00 1.2E+01
1.68E+01 4.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.39E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.43E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-747
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L06-1313-T01-A
CFS-L06-1313-T02-A
CFS-L06-1313-T03-A
CFS-L06-1313-T04-A
CFS-L06-1313-T05-A
CFS-L06-1313-T06-A
CFS-L06-1313-T07-A
CFS-L06-1313-T08-A
CFS-L06-1313-T09-A
CFS-L06-1313-T01-B
CFS-L06-1313-T02-B
CFS-L06-1313-T03-B
CFS-L06-1313-T04-B
CFS-L06-1313-T05-B
CFS-L06-1313-T06-B
CFS-L06-1313-T07-B
CFS-L06-1313-T08-B
CFS-L06-1313-T09-B
CFS-L06-1313-T01-C
CFS-L06-1313-T02-C
CFS-L06-1313-T03-C
CFS-L06-1313-T04-C
CFS-L06-1313-T05-C
CFS-L06-1313-T06-C
CFS-L06-1313-T07-C
CFS-L06-1313-T08-C
CFS-L06-1313-T09-C
CFS-L06-1313-B01-A
CFS-L06-1313-B02-A
CFS-L06-1313-B03-A
CFS-L06-1313-B01-B
CFS-L06-1313-B02-B
CFS-L06-1313-B03-B
CFS-L06-1313-B01-C
CFS-L06-1313-B02-C
CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.33E+04
1 2.45E+04
1 1.50E+02
1 1.34E+04
1 1.24E+04
1 1.01E+03
1 1.43E+04
1 1.78E+04
1 2.66E+04
1 3.47E+04
1 1.23E+04
1 1.53E+04
1 1.35E+04
1 1.20E+04
1 1.06E+04
1 1.37E+04
1 1.72E+04
1 2.50E+04
1 3.25E+04
1 2.26E+04
1 1.45E+04
1 1.26E+04
1 1.18E+04
1 8.82E+03
1 1.39E+04
1 1.68E+04
1 2.58E+04
1 2.88E+01
1 2.81E+01
1 1.27E+03
1 2.95E+01
1 3.33E+01
1 1.30E+03
1 2.99E+01
1 3.00E+01
1 1.29E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.33E+04 8.2E-01 1.6E+00 5.1E+00
2.45E+04 3.4E-01 1.6E+00 5.1E+00 1000 120
1.50E+02 1.0E+02 1.6E+00 5.1E+00
1.34E+04 3.8E-01 1.6E+00 5.1E+00
1.24E+04 7.5E-01 1.6E+00 5.1E+00
1.01E+03 1.7E+02 1.6E+00 5.1E+00
1.43E+04 6.3E-01 1.6E+00 5.1E+00
1.78E+04 5.7E+00 1.6E+00 5.1E+00
2.66E+04 7.3E-01 1.6E+00 5.1E+00
3.47E+04 6.2E-01 1.6E+00 5.1E+00
1.23E+04 1.0E+02 1.6E+00 5.1E+00 1000 120
1.53E+04 5.1E-01 1.6E+00 5.1E+00
1.35E+04 5.8E-01 1.6E+00 5.1E+00
1.20E+04 5.4E-01 1.6E+00 5.1E+00
1.06E+04 9.0E-02 1.6E+00 5.1E+00
1.37E+04 3.2E-01 1.6E+00 5.1E+00
1.72E+04 4.9E-01 1.6E+00 5.1E+00
2.50E+04 5.4E-01 1.6E+00 5.1E+00
3.25E+04 1.3E+00 1.6E+00 5.1E+00
2.26E+04 5.4E-01 1.6E+00 5.1E+00 1000 120
1.45E+04 5.0E-01 1.6E+00 5.1E+00
1.26E+04 3.6E-02 1.6E+00 5.1E+00
1.18E+04 3.0E-01 1.6E+00 5.1E+00
8.82E+03 3.5E+01 1.6E+00 5.1E+00
1.39E+04 7.4E-01 1.6E+00 5.1E+00
1.68E+04 5.6E-01 1.6E+00 5.1E+00
2.58E+04 5.4E-01 1.6E+00 5.1E+00
2.88E+01 2.3E+00 1.6E+00 5.1E+00
2.81 E+01 5.0E+00 1.6E+00 5.1E+00
1.27E+03 4.8E-01 1.6E+00 5.1E+00
2.95E+01 1.5E+01 1.6E+00 5.1E+00
3.33E+01 2.2E+00 1.6E+00 5.1E+00
1.30E+03 1.3E+00 1.6E+00 5.1E+00
2.99E+01 9.5E+00 1.6E+00 5.1E+00
3.00E+01 4.3E+00 1.6E+00 5.1E+00
1.29E+03 1.4E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.57E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.36E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316CFS
                                                                                                                                                                          1-748
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L06-1313-T01-A
CFS-L06-1313-T02-A
CFS-L06-1313-T03-A
CFS-L06-1313-T04-A
CFS-L06-1313-T05-A
CFS-L06-1313-T06-A
CFS-L06-1313-T07-A
CFS-L06-1313-T08-A
CFS-L06-1313-T09-A
CFS-L06-1313-T01-B
CFS-L06-1313-T02-B
CFS-L06-1313-T03-B
CFS-L06-1313-T04-B
CFS-L06-1313-T05-B
CFS-L06-1313-T06-B
CFS-L06-1313-T07-B
CFS-L06-1313-T08-B
CFS-L06-1313-T09-B
CFS-L06-1313-T01-C
CFS-L06-1313-T02-C
CFS-L06-1313-T03-C
CFS-L06-1313-T04-C
CFS-L06-1313-T05-C
CFS-L06-1313-T06-C
CFS-L06-1313-T07-C
CFS-L06-1313-T08-C
CFS-L06-1313-T09-C
CFS-L06-1313-B01-A
CFS-L06-1313-B02-A
CFS-L06-1313-B03-A
CFS-L06-1313-B01-B
CFS-L06-1313-B02-B
CFS-L06-1313-B03-B
CFS-L06-1313-B01-C
CFS-L06-1313-B02-C
CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.49E+02
1 3.37E+02
1 7.50E+00 U1/2
1 1.73E+02
1 9.96E+01
1 7.50E+00 U1/2
1 1.89E+02
1 2.51 E+02
1 4. 21 E+02
1 5.09E+02
1 1.63E+02
1 7.37E+02
1 1.69E+02
1 9.34E+01
1 1.04E+02
1 1.93E+02
1 2.65E+02
1 5.14E+02
1 4.20E+02
1 3.22E+02
1 6.92E+02
1 1.66E+02
1 9.22E+01
1 6.55E+01
1 2.06E+02
1 2.53E+02
1 4.79E+02
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 1.52E+01 E
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 2.87E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.49E+02 9.1E-01 1.5E+01 4.8E+01
3.37E+02 3.3E+00 1.5E+01 4.8E+01 10 120
7.50E+00 1.7E+02 1.5E+01 4.8E+01
1.73E+02 4.1E+00 1.5E+01 4.8E+01
9.96E+01 2.9E+01 1.5E+01 4.8E+01
7.50E+00 3.5E+02 1.5E+01 4.8E+01
1.89E+02 1.4E+01 1.5E+01 4.8E+01
2.51 E+02 5.3E+00 1.5E+01 4.8E+01
4.21E+02 3.2E+00 1.5E+01 4.8E+01
5.09E+02 4.1E+00 1.5E+01 4.8E+01
1.63E+02 1.1 E+02 1.5E+01 4.8E+01 10 120
7.37E+02 1.2E+00 1.5E+01 4.8E+01
1.69E+02 7.8E+00 1.5E+01 4.8E+01
9.34E+01 8.3E+00 1.5E+01 4.8E+01
1.04E+02 5.6E+00 1.5E+01 4.8E+01
1.93E+02 3.9E+00 1.5E+01 4.8E+01
2.65E+02 2.2E+01 1.5E+01 4.8E+01
5.14E+02 4.2E+00 1.5E+01 4.8E+01
4.20E+02 1.7E+00 1.5E+01 4.8E+01
3.22E+02 3.2E+00 1.5E+01 4.8E+01 10 150
6.92E+02 3.1E+00 1.5E+01 4.8E+01
1.66E+02 4.0E+00 1.5E+01 4.8E+01
9.22E+01 2.0E+00 1.5E+01 4.8E+01
6.55E+01 4.8E+01 1.5E+01 4.8E+01
2.06E+02 1.9E+01 1.5E+01 4.8E+01
2.53E+02 6.8E+00 1.5E+01 4.8E+01
4.79E+02 5.8E+00 1.5E+01 4.8E+01
7.50E+00 2.8E+01 1.5E+01 4.8E+01
7.50E+00 7.4E+01 1.5E+01 4.8E+01
1.52E+01 8.2E+01 1.5E+01 4.8E+01
7.50E+00 2.7E+02 1.5E+01 4.8E+01
7.50E+00 4.2E+02 1.5E+01 4.8E+01
7.50E+00 6.8E+01 1.5E+01 4.8E+01
7.50E+00 2.7E+02 1.5E+01 4.8E+01
7.50E+00 1.8E+03 1.5E+01 4.8E+01
2.87E+01 4.2E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.68E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.44E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.92E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-749
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si CFS-L06-1313-T01-A
Si CFS-L06-1313-T02-A
Si CFS-L06-1313-T03-A
Si CFS-L06-1313-T04-A
Si CFS-L06-1313-T05-A
Si CFS-L06-1313-T06-A
Si CFS-L06-1313-T07-A
Si CFS-L06-1313-T08-A
Si CFS-L06-1313-T09-A
Si CFS-L06-1313-T01-B
Si CFS-L06-1313-T02-B
Si CFS-L06-1313-T03-B
Si CFS-L06-1313-T04-B
Si CFS-L06-1313-T05-B
Si CFS-L06-1313-T06-B
Si CFS-L06-1313-T07-B
Si CFS-L06-1313-T08-B
Si CFS-L06-1313-T09-B
Si CFS-L06-1313-T01-C
Si CFS-L06-1313-T02-C
Si CFS-L06-1313-T03-C
Si CFS-L06-1313-T04-C
Si CFS-L06-1313-T05-C
Si CFS-L06-1313-T06-C
Si CFS-L06-1313-T07-C
Si CFS-L06-1313-T08-C
Si CFS-L06-1313-T09-C
Si CFS-L06-1313-B01-A
Si CFS-L06-1313-B02-A
Si CFS-L06-1313-B03-A
Si CFS-L06-1313-B01-B
Si CFS-L06-1313-B02-B
Si CFS-L06-1313-B03-B
Si CFS-L06-1313-B01-C
Si CFS-L06-1313-B02-C
Si CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.08E+02
1 3.11E+02
1 1.29E+01
1 6.90E+02
1 1.58E+03
1 1.12E+03
1 3.85E+04
1 5.82E+04
1 1.66E+05
1 2.88E+02
1 1.64E+02
1 5.92E+02
1 7.23E+02
1 1.62E+03
1 4.21 E+03
1 3.69E+04
1 5.92E+04
1 1.53E+05
1 3.09E+02
1 3.17E+02
1 5.81 E+02
1 6.75E+02
1 1.57E+03
1 4.05E+03
1 3.86E+04
1 5.89E+04
1 1.59E+05
1 1.48E+01
1 1.59E+01
1 1.80E+02
1 5.13E+00
1 2.28E+01
1 1.69E+02
1 6.19E+00
1 1.33E+01
1 1.47E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+02 2.9E+00 1.1E+00 3.5E+00
3.11E+02 2.1E+00 1.1E+00 3.5E+00 1000 120
1.29E+01 8.3E+01 1.1E+00 3.5E+00
6.90E+02 2.7E-01 1.1E+00 3.5E+00
1.58E+03 8.9E-01 1.1E+00 3.5E+00
1.12E+03 1.7E+02 1.1E+00 3.5E+00
3.85E+04 8.7E-01 1.1E+00 3.5E+00
5.82E+04 8.4E+00 1.1E+00 3.5E+00
1.66E+05 6.8E-01 1.1E+00 3.5E+00
2.88E+02 1.9E+00 1.1E+00 3.5E+00
1.64E+02 9.1E+01 1.1E+00 3.5E+00 1000 120
5.92E+02 1.7E+00 1.1E+00 3.5E+00
7.23E+02 7.4E-01 1.1E+00 3.5E+00
1.62E+03 4.6E-01 1.1E+00 3.5E+00
4.21E+03 9.8E-01 1.1E+00 3.5E+00
3.69E+04 7.6E-01 1.1E+00 3.5E+00
5.92E+04 1.5E-01 1.1E+00 3.5E+00
1.53E+05 5.8E-01 1.1E+00 3.5E+00
3.09E+02 1.3E+00 1.1E+00 3.5E+00
3.17E+02 1.6E+00 1.1E+00 3.5E+00 1000 120
5.81E+02 7.9E-01 1.1E+00 3.5E+00
6.75E+02 1.1E+00 1.1E+00 3.5E+00
1.57E+03 7.3E-01 1.1E+00 3.5E+00
4.05E+03 1.3E+01 1.1E+00 3.5E+00
3.86E+04 9.4E-01 1.1E+00 3.5E+00
5.89E+04 1.0E+00 1.1E+00 3.5E+00
1.59E+05 8.2E-01 1.1E+00 3.5E+00
1.48E+01 3.5E+01 1.1E+00 3.5E+00
1.59E+01 3.1E+01 1.1E+00 3.5E+00
1.80E+02 3.1E+00 1.1E+00 3.5E+00
5.13E+00 6.2E+01 1.1E+00 3.5E+00
2.28E+01 5.0E+00 1.1E+00 3.5E+00
1.69E+02 6.0E+00 1.1E+00 3.5E+00
6.19E+00 6.5E+01 1.1E+00 3.5E+00
1.33E+01 3.4E+01 1.1E+00 3.5E+00
1.47E+02 2.9E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.73E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.54E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.65E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-750
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na CFS-L06-1313-T01-A
Na CFS-L06-1313-T02-A
Na CFS-L06-1313-T03-A
Na CFS-L06-1313-T04-A
Na CFS-L06-1313-T05-A
Na CFS-L06-1313-T06-A
Na CFS-L06-1313-T07-A
Na CFS-L06-1313-T08-A
Na CFS-L06-1313-T09-A
Na CFS-L06-1313-T01-B
Na CFS-L06-1313-T02-B
Na CFS-L06-1313-T03-B
Na CFS-L06-1313-T04-B
Na CFS-L06-1313-T05-B
Na CFS-L06-1313-T06-B
Na CFS-L06-1313-T07-B
Na CFS-L06-1313-T08-B
Na CFS-L06-1313-T09-B
Na CFS-L06-1313-T01-C
Na CFS-L06-1313-T02-C
Na CFS-L06-1313-T03-C
Na CFS-L06-1313-T04-C
Na CFS-L06-1313-T05-C
Na CFS-L06-1313-T06-C
Na CFS-L06-1313-T07-C
Na CFS-L06-1313-T08-C
Na CFS-L06-1313-T09-C
Na CFS-L06-1313-B01-A
Na CFS-L06-1313-B02-A
Na CFS-L06-1313-B03-A
Na CFS-L06-1313-B01-B
Na CFS-L06-1313-B02-B
Na CFS-L06-1313-B03-B
Na CFS-L06-1313-B01-C
Na CFS-L06-1313-B02-C
Na CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.84E+05
1 2.69E+05
1 2.02E+03
1 8.12E+04
1 4.81 E+04
1 5.51 E+02
1 8.17E+03
1 9.15E+03
1 1.01 E+04
1 3.82E+05
1 1.32E+05
1 1.25E+05
1 7.89E+04
1 4.72E+04
1 7.28E+03
1 7.55E+03
1 8.65E+03
1 9.64E+03
1 3.79E+05
1 2.73E+05
1 1.30E+05
1 8.18E+04
1 4.79E+04
1 5.91 E+03
1 7.49E+03
1 8.14E+03
1 9.23E+03
1 1.25E+00 U1/2
1 1.25E+00 U1/2
1 3.77E+05
1 2.57E+01
1 1.25E+00 U1/2
1 3.81 E+05
1 1.36E+01
1 3.64E+00 E
1 3.83E+05
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.84E+05 4.4E-01 2.5E+00 8.0E+00
2.69E+05 1.7E-01 2.5E+00 8.0E+00 1000 120
2.02E+03 1.1 E+02 2.5E+00 8.0E+00
8.12E+04 3.7E-01 2.5E+00 8.0E+00
4.81 E+04 6.0E-01 2.5E+00 8.0E+00
5.51 E+02 1.6E+02 2.5E+00 8.0E+00
8.17E+03 6.4E-01 2.5E+00 8.0E+00
9.15E+03 1.5E+00 2.5E+00 8.0E+00
1.01 E+04 7.9E-01 2.5E+00 8.0E+00
3.82E+05 8.0E-02 2.5E+00 8.0E+00
1.32E+05 8.3E+01 2.5E+00 8.0E+00 1000 120
1.25E+05 8.2E-01 2.5E+00 8.0E+00
7.89E+04 5.1E-01 2.5E+00 8.0E+00
4.72E+04 5.4E-01 2.5E+00 8.0E+00
7.28E+03 4.2E-01 2.5E+00 8.0E+00
7.55E+03 6.3E-01 2.5E+00 8.0E+00
8.65E+03 8.4E-01 2.5E+00 8.0E+00
9.64E+03 1.0E+00 2.5E+00 8.0E+00
3.79E+05 2.5E-01 2.5E+00 8.0E+00
2.73E+05 2.8E-01 2.5E+00 8.0E+00 1000 120
1.30E+05 2.9E-01 2.5E+00 8.0E+00
8.18E+04 1.2E+00 2.5E+00 8.0E+00
4.79E+04 4.8E-01 2.5E+00 8.0E+00
5.91 E+03 3.0E+01 2.5E+00 8.0E+00
7.49E+03 8.6E-01 2.5E+00 8.0E+00
8.14E+03 1.2E+00 2.5E+00 8.0E+00
9.23E+03 5.9E-01 2.5E+00 8.0E+00
1.25E+00 9.6E+02 2.5E+00 8.0E+00
1.25E+00 8.7E+00 2.5E+00 8.0E+00
3.77E+05 7.3E-01 2.5E+00 8.0E+00
2.57E+01 8.1E+00 2.5E+00 8.0E+00
1.25E+00 4.3E+00 2.5E+00 8.0E+00
3.81 E+05 3.3E-01 2.5E+00 8.0E+00
1.36E+01 2.8E+00 2.5E+00 8.0E+00
3.64E+00 5.5E+00 2.5E+00 8.0E+00
3.83E+05 8.8E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.70E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.74E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-751
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr CFS-L06-1313-T01-A
Sr CFS-L06-1313-T02-A
Sr CFS-L06-1313-T03-A
Sr CFS-L06-1313-T04-A
Sr CFS-L06-1313-T05-A
Sr CFS-L06-1313-T06-A
Sr CFS-L06-1313-T07-A
Sr CFS-L06-1313-T08-A
Sr CFS-L06-1313-T09-A
Sr CFS-L06-1313-T01-B
Sr CFS-L06-1313-T02-B
Sr CFS-L06-1313-T03-B
Sr CFS-L06-1313-T04-B
Sr CFS-L06-1313-T05-B
Sr CFS-L06-1313-T06-B
Sr CFS-L06-1313-T07-B
Sr CFS-L06-1313-T08-B
Sr CFS-L06-1313-T09-B
Sr CFS-L06-1313-T01-C
Sr CFS-L06-1313-T02-C
Sr CFS-L06-1313-T03-C
Sr CFS-L06-1313-T04-C
Sr CFS-L06-1313-T05-C
Sr CFS-L06-1313-T06-C
Sr CFS-L06-1313-T07-C
Sr CFS-L06-1313-T08-C
Sr CFS-L06-1313-T09-C
Sr CFS-L06-1313-B01-A
Sr CFS-L06-1313-B02-A
Sr CFS-L06-1313-B03-A
Sr CFS-L06-1313-B01-B
Sr CFS-L06-1313-B02-B
Sr CFS-L06-1313-B03-B
Sr CFS-L06-1313-B01-C
Sr CFS-L06-1313-B02-C
Sr CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.16E+03
1 2.73E+03
1 1.52E+02
1 3.71 E+03
1 3.74E+03
1 4.19E+02
1 1.05E+03
1 1.19E+03
1 1.46E+03
1 2.40E+03
1 1.80E+03
1 4.08E+03
1 3.61 E+03
1 3.56E+03
1 1.60E+03
1 9.93E+02
1 1.17E+03
1 1.27E+03
1 2.19E+03
1 3.19E+03
1 4.15E+03
1 3.55E+03
1 3.64E+03
1 1.53E+03
1 1.09E+03
1 1.19E+03
1 1.32E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.14E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.14E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.19E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.16E+03 7.0E-01 1.0E+00 3.2E+00
2.73E+03 3.2E-01 1.0E+00 3.2E+00 1000 120
1.52E+02 1.3E+02 1.0E+00 3.2E+00
3.71 E+03 6.7E-01 1.0E+00 3.2E+00
3.74E+03 4.6E-01 1.0E+00 3.2E+00
4.19E+02 1.7E+02 1.0E+00 3.2E+00
1.05E+03 1.9E+00 1.0E+00 3.2E+00
1.19E+03 7.0E+00 1.0E+00 3.2E+00
1.46E+03 7.3E-01 1.0E+00 3.2E+00
2.40E+03 6.7E-01 1.0E+00 3.2E+00
1.80E+03 8.9E+01 1.0E+00 3.2E+00 1000 120
4.08E+03 1.1E+00 1.0E+00 3.2E+00
3.61 E+03 8.1E-01 1.0E+00 3.2E+00
3.56E+03 6.5E-01 1.0E+00 3.2E+00
1.60E+03 8.8E-01 1.0E+00 3.2E+00
9.93E+02 3.5E-01 1.0E+00 3.2E+00
1.17E+03 1.8E+00 1.0E+00 3.2E+00
1.27E+03 1.3E+00 1.0E+00 3.2E+00
2.19E+03 1.3E+00 1.0E+00 3.2E+00
3.19E+03 1.2E+00 1.0E+00 3.2E+00 1000 120
4.15E+03 2.4E-01 1.0E+00 3.2E+00
3.55E+03 1.1E+00 1.0E+00 3.2E+00
3.64E+03 1.3E+00 1.0E+00 3.2E+00
1.53E+03 1.3E+01 1.0E+00 3.2E+00
1.09E+03 5.1E-01 1.0E+00 3.2E+00
1.19E+03 3.4E+00 1.0E+00 3.2E+00
1.32E+03 6.2E-01 1.0E+00 3.2E+00
5.00E-01 8.5E+01 1.0E+00 3.2E+00
5.00E-01 3.8E+01 1.0E+00 3.2E+00
1.14E+01 1.1E+01 1.0E+00 3.2E+00
5.00E-01 2.3E+03 1.0E+00 3.2E+00
5.00E-01 6.3E+01 1.0E+00 3.2E+00
1.14E+01 1.1E+01 1.0E+00 3.2E+00
5.00E-01 1.8E+02 1.0E+00 3.2E+00
5.00E-01 1.3E+04 1.0E+00 3.2E+00
1.19E+01 7.7E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.91 E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.91 E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.31 E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-752
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S CFS-L06-1313-T01-A
S CFS-L06-1313-T02-A
S CFS-L06-1313-T03-A
S CFS-L06-1313-T04-A
S CFS-L06-1313-T05-A
S CFS-L06-1313-T06-A
S CFS-L06-1313-T07-A
S CFS-L06-1313-T08-A
S CFS-L06-1313-T09-A
S CFS-L06-1313-T01-B
S CFS-L06-1313-T02-B
S CFS-L06-1313-T03-B
S CFS-L06-1313-T04-B
S CFS-L06-1313-T05-B
S CFS-L06-1313-T06-B
S CFS-L06-1313-T07-B
S CFS-L06-1313-T08-B
S CFS-L06-1313-T09-B
S CFS-L06-1313-T01-C
S CFS-L06-1313-T02-C
S CFS-L06-1313-T03-C
S CFS-L06-1313-T04-C
S CFS-L06-1313-T05-C
S CFS-L06-1313-T06-C
S CFS-L06-1313-T07-C
S CFS-L06-1313-T08-C
S CFS-L06-1313-T09-C
S CFS-L06-1313-B01-A
S CFS-L06-1313-B02-A
S CFS-L06-1313-B03-A
S CFS-L06-1313-B01-B
S CFS-L06-1313-B02-B
S CFS-L06-1313-B03-B
S CFS-L06-1313-B01-C
S CFS-L06-1313-B02-C
S CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.46E+06
1 1.29E+06
1 1.38E+04
1 7.54E+05
1 7.22E+05
1 5.85E+04
1 6.94E+05
1 7.34E+05
1 8.02E+05
1 1.48E+06
1 6.25E+05
1 8.53E+05
1 7.43E+05
1 7.01 E+05
1 6.35E+05
1 6.56E+05
1 7.09E+05
1 7.96E+05
1 1.40E+06
1 1.27E+06
1 8.35E+05
1 7.19E+05
1 6.83E+05
1 5.36E+05
1 6.85E+05
1 6.94E+05
1 7.82E+05
1 3.40E+00 U1/2
1 1.65E+01 E
1 5.41 E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 2.36E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 4.80E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.46E+06 1.1E-01 6.8E+00 2.2E+01
1.29E+06 6.4E-01 6.8E+00 2.2E+01 1000 120
1.38E+04 8.3E+01 6.8E+00 2.2E+01
7.54E+05 5.5E-01 6.8E+00 2.2E+01
7.22E+05 7.8E-01 6.8E+00 2.2E+01
5.85E+04 1.6E+02 6.8E+00 2.2E+01
6.94E+05 1.5E+00 6.8E+00 2.2E+01
7.34E+05 6.0E+00 6.8E+00 2.2E+01
8.02E+05 5.8E-01 6.8E+00 2.2E+01
1.48E+06 1.7E-01 6.8E+00 2.2E+01
6.25E+05 1.0E+02 6.8E+00 2.2E+01 1000 120
8.53E+05 8.7E-01 6.8E+00 2.2E+01
7.43E+05 8.3E-01 6.8E+00 2.2E+01
7.01 E+05 2.4E-01 6.8E+00 2.2E+01
6.35E+05 2.6E-01 6.8E+00 2.2E+01
6.56E+05 3.2E-01 6.8E+00 2.2E+01
7.09E+05 4.8E-01 6.8E+00 2.2E+01
7.96E+05 1.9E-01 6.8E+00 2.2E+01
1.40E+06 6.6E-01 6.8E+00 2.2E+01
1.27E+06 2.8E-01 6.8E+00 2.2E+01 1000 120
8.35E+05 9.0E-01 6.8E+00 2.2E+01
7.19E+05 1.1E-01 6.8E+00 2.2E+01
6.83E+05 5.2E-01 6.8E+00 2.2E+01
5.36E+05 3.4E+01 6.8E+00 2.2E+01
6.85E+05 8.4E-01 6.8E+00 2.2E+01
6.94E+05 1.3E+00 6.8E+00 2.2E+01
7.82E+05 1.5E-01 6.8E+00 2.2E+01
3.40E+00 3.8E+02 6.8E+00 2.2E+01
1.65E+01 7.3E+01 6.8E+00 2.2E+01
5.41 E+02 7.6E+00 6.8E+00 2.2E+01
3.40E+00 4.5E+01 6.8E+00 2.2E+01
3.40E+00 6.4E+02 6.8E+00 2.2E+01
2.36E+02 6.8E+00 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
4.80E+01 4.7E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.29E+06 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.26E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+06 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-753
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample Dilutic
CFS-L06-1313-T01-A
CFS-L06-1313-T02-A
CFS-L06-1313-T03-A
CFS-L06-1313-T04-A
CFS-L06-1313-T05-A
CFS-L06-1313-T06-A
CFS-L06-1313-T07-A
CFS-L06-1313-T08-A
CFS-L06-1313-T09-A
CFS-L06-1313-T01-B
CFS-L06-1313-T02-B
CFS-L06-1313-T03-B
CFS-L06-1313-T04-B
CFS-L06-1313-T05-B
CFS-L06-1313-T06-B
CFS-L06-1313-T07-B
CFS-L06-1313-T08-B
CFS-L06-1313-T09-B
CFS-L06-1313-T01-C
CFS-L06-1313-T02-C
CFS-L06-1313-T03-C
CFS-L06-1313-T04-C
CFS-L06-1313-T05-C
CFS-L06-1313-T06-C
CFS-L06-1313-T07-C
CFS-L06-1313-T08-C
CFS-L06-1313-T09-C
CFS-L06-1313-B01-A
CFS-L06-1313-B02-A
CFS-L06-1313-B03-A
CFS-L06-1313-B01-B
CFS-L06-1313-B02-B
CFS-L06-1313-B03-B
CFS-L06-1313-B01-C
CFS-L06-1313-B02-C
CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.61 E+01
1 9.64E+01
1 2.30E+00 U1/2
1 2.48E+02
1 3.28E+02
1 1.93E+01
1 7.26E+02
1 9.57E+02
1 1.61E+03
1 1.09E+02
1 3.29E+01
1 1.23E+02
1 2.47E+02
1 3.13E+02
1 3.49E+02
1 7.14E+02
1 9.01 E+02
1 1.67E+03
1 1.07E+02
1 8.30E+01
1 1.27E+02
1 2.33E+02
1 3.27E+02
1 2.89E+02
1 7.41 E+02
1 9.20E+02
1 1.70E+03
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.61 E+01 9.6E+00 4.6E+00 1.5E+01
9.64E+01 3.6E+00 4.6E+00 1.5E+01 10 120
2.30E+00 1.2E+01 4.6E+00 1.5E+01
2.48E+02 1.1E+00 4.6E+00 1.5E+01
3.28E+02 1.6E+00 4.6E+00 1.5E+01
1.93E+01 4.0E+02 4.6E+00 1.5E+01
7.26E+02 1.7E+00 4.6E+00 1.5E+01
9.57E+02 5.9E+00 4.6E+00 1.5E+01
1.61E+03 1.2E+00 4.6E+00 1.5E+01
1.09E+02 3.6E+00 4.6E+00 1.5E+01
3.29E+01 1.8E+02 4.6E+00 1.5E+01 10 120
1.23E+02 4.9E+00 4.6E+00 1.5E+01
2.47E+02 2.1E+00 4.6E+00 1.5E+01
3.13E+02 1.9E+00 4.6E+00 1.5E+01
3.49E+02 5.6E-01 4.6E+00 1.5E+01
7.14E+02 1.5E+00 4.6E+00 1.5E+01
9.01 E+02 1.6E+00 4.6E+00 1.5E+01
1.67E+03 5.9E-01 4.6E+00 1.5E+01
1.07E+02 3.3E+00 4.6E+00 1.5E+01
8.30E+01 6.7E+00 4.6E+00 1.5E+01 10 150
1.27E+02 5.5E+00 4.6E+00 1.5E+01
2.33E+02 4.5E+00 4.6E+00 1.5E+01
3.27E+02 1.4E+00 4.6E+00 1.5E+01
2.89E+02 3.6E+01 4.6E+00 1.5E+01
7.41 E+02 2.2E+00 4.6E+00 1.5E+01
9.20E+02 2.5E+00 4.6E+00 1.5E+01
1.70E+03 2.7E-01 4.6E+00 1.5E+01
2.30E+00 1.7E+01 4.6E+00 1.5E+01
2.30E+00 6.2E+00 4.6E+00 1.5E+01
2.30E+00 2.7E+01 4.6E+00 1.5E+01
2.30E+00 9.7E+00 4.6E+00 1.5E+01
2.30E+00 6.1E+00 4.6E+00 1.5E+01
2.30E+00 2.0E+01 4.6E+00 1.5E+01
2.30E+00 1.2E+01 4.6E+00 1.5E+01
2.30E+00 1.6E+01 4.6E+00 1.5E+01
2.30E+00 8.7E+00 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.23E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.31E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.54E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-754
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutic
CFS-L06-1313-T01-A
CFS-L06-1313-T02-A
CFS-L06-1313-T03-A
CFS-L06-1313-T04-A
CFS-L06-1313-T05-A
CFS-L06-1313-T06-A
CFS-L06-1313-T07-A
CFS-L06-1313-T08-A
CFS-L06-1313-T09-A
CFS-L06-1313-T01-B
CFS-L06-1313-T02-B
CFS-L06-1313-T03-B
CFS-L06-1313-T04-B
CFS-L06-1313-T05-B
CFS-L06-1313-T06-B
CFS-L06-1313-T07-B
CFS-L06-1313-T08-B
CFS-L06-1313-T09-B
CFS-L06-1313-T01-C
CFS-L06-1313-T02-C
CFS-L06-1313-T03-C
CFS-L06-1313-T04-C
CFS-L06-1313-T05-C
CFS-L06-1313-T06-C
CFS-L06-1313-T07-C
CFS-L06-1313-T08-C
CFS-L06-1313-T09-C
CFS-L06-1313-B01-A
CFS-L06-1313-B02-A
CFS-L06-1313-B03-A
CFS-L06-1313-B01-B
CFS-L06-1313-B02-B
CFS-L06-1313-B03-B
CFS-L06-1313-B01-C
CFS-L06-1313-B02-C
CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 9.26E+00
1 1.92E+01
1 3.39E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 8.55E+00
1 1.98E+01
1 4.47E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 9.19E+00
1 1.93E+01
1 4.89E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.2E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00 10 120
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 7.8E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+02 2.0E+00 6.4E+00
1.00E+00 3.8E+00 2.0E+00 6.4E+00
9.26E+00 2.4E+00 2.0E+00 6.4E+00
1.92E+01 3.1E+00 2.0E+00 6.4E+00
3.39E+01 4.0E-01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 7.7E+02 2.0E+00 6.4E+00 10 120
1.00E+00 9.4E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 3.2E+01 2.0E+00 6.4E+00
8.55E+00 2.4E+00 2.0E+00 6.4E+00
1.98E+01 2.8E+00 2.0E+00 6.4E+00
4.47E+01 1.5E-01 2.0E+00 6.4E+00
1.00E+00 8.8E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00 10 150
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 2.0E+02 2.0E+00 6.4E+00
1.00E+00 4.4E+01 2.0E+00 6.4E+00
1.00E+00 7.2E+01 2.0E+00 6.4E+00
9.19E+00 5.4E+00 2.0E+00 6.4E+00
1.93E+01 1.4E+00 2.0E+00 6.4E+00
4.89E+01 1.1E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+02 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 8.8E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+01 2.0E+00 6.4E+00
1.00E+00 5.6E+01 2.0E+00 6.4E+00
1.00E+00 9.6E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 9.2E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.48E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/1 4/1 1 3:27 P M EPA Interlab L06 1 31 3-1 31 6 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-755
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V CFS-L06-1313-T01-A
V CFS-L06-1313-T02-A
V CFS-L06-1313-T03-A
V CFS-L06-1313-T04-A
V CFS-L06-1313-T05-A
V CFS-L06-1313-T06-A
V CFS-L06-1313-T07-A
V CFS-L06-1313-T08-A
V CFS-L06-1313-T09-A
V CFS-L06-1313-T01-B
V CFS-L06-1313-T02-B
V CFS-L06-1313-T03-B
V CFS-L06-1313-T04-B
V CFS-L06-1313-T05-B
V CFS-L06-1313-T06-B
V CFS-L06-1313-T07-B
V CFS-L06-1313-T08-B
V CFS-L06-1313-T09-B
V CFS-L06-1313-T01-C
V CFS-L06-1313-T02-C
V CFS-L06-1313-T03-C
V CFS-L06-1313-T04-C
V CFS-L06-1313-T05-C
V CFS-L06-1313-T06-C
V CFS-L06-1313-T07-C
V CFS-L06-1313-T08-C
V CFS-L06-1313-T09-C
V CFS-L06-1313-B01-A
V CFS-L06-1313-B02-A
V CFS-L06-1313-B03-A
V CFS-L06-1313-B01-B
V CFS-L06-1313-B02-B
V CFS-L06-1313-B03-B
V CFS-L06-1313-B01-C
V CFS-L06-1313-B02-C
V CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.57E+01
1 2.56E+01
1 7.50E-01 U1/2
1 2.80E+01
1 2.90E+01
1 3.86E+00 E
1 4.02E+01
1 4.15E+01
1 5.36E+02
1 2.53E+01
1 1.26E+01
1 2.37E+01
1 2.63E+01
1 2.86E+01
1 2.85E+01
1 4.01 E+01
1 4.81 E+01
1 5.21E+02
1 2.34E+01
1 2.61E+01
1 2.39E+01
1 2.76E+01
1 2.83E+01
1 2.47E+01
1 4.27E+01
1 4.60E+01
1 5.01 E+02
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 2.17E+00 E
1 1.54E+00 E
1 7.50E-01 U1/2
1 2.29E+00 E
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.57E+01 1.2E+01 1.5E+00 4.8E+00
2.56E+01 2.5E+00 1.5E+00 4.8E+00 10 120
7.50E-01 9.4E+01 1.5E+00 4.8E+00
2.80E+01 5.1E+00 1.5E+00 4.8E+00
2.90E+01 1.2E+00 1.5E+00 4.8E+00
3.86E+00 1.4E+02 1.5E+00 4.8E+00
4.02E+01 1.5E+00 1.5E+00 4.8E+00
4.15E+01 2.4E+01 1.5E+00 4.8E+00
5.36E+02 9.1E-01 1.5E+00 4.8E+00
2.53E+01 6.8E+00 1.5E+00 4.8E+00
1.26E+01 8.4E+01 1.5E+00 4.8E+00 10 120
2.37E+01 3.9E+00 1.5E+00 4.8E+00
2.63E+01 2.9E+00 1.5E+00 4.8E+00
2.86E+01 3.5E+00 1.5E+00 4.8E+00
2.85E+01 3.0E+00 1.5E+00 4.8E+00
4.01 E+01 1.3E+00 1.5E+00 4.8E+00
4.81 E+01 2.8E+00 1.5E+00 4.8E+00
5.21E+02 2.4E-01 1.5E+00 4.8E+00
2.34E+01 4.2E+00 1.5E+00 4.8E+00
2.61E+01 3.0E+00 1.5E+00 4.8E+00 10 150
2.39E+01 4.0E+00 1.5E+00 4.8E+00
2.76E+01 3.2E+00 1.5E+00 4.8E+00
2.83E+01 5.9E-01 1.5E+00 4.8E+00
2.47E+01 3.4E+01 1.5E+00 4.8E+00
4.27E+01 2.8E+00 1.5E+00 4.8E+00
4.60E+01 4.3E+00 1.5E+00 4.8E+00
5.01 E+02 8.6E-01 1.5E+00 4.8E+00
7.50E-01 6.8E+01 1.5E+00 4.8E+00
7.50E-01 4.2E+01 1.5E+00 4.8E+00
2.17E+00 1.4E+01 1.5E+00 4.8E+00
1.54E+00 5.9E+01 1.5E+00 4.8E+00
7.50E-01 3.9E+01 1.5E+00 4.8E+00
2.29E+00 5.1E+01 1.5E+00 4.8E+00
7.50E-01 6.0E+01 1.5E+00 4.8E+00
7.50E-01 5.8E+01 1.5E+00 4.8E+00
7.50E-01 2.1 E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.29E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.59E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/1 1 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-756
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn CFS-L06-1313-T01-A
Zn CFS-L06-1313-T02-A
Zn CFS-L06-1313-T03-A
Zn CFS-L06-1313-T04-A
Zn CFS-L06-1313-T05-A
Zn CFS-L06-1313-T06-A
Zn CFS-L06-1313-T07-A
Zn CFS-L06-1313-T08-A
Zn CFS-L06-1313-T09-A
Zn CFS-L06-1313-T01-B
Zn CFS-L06-1313-T02-B
Zn CFS-L06-1313-T03-B
Zn CFS-L06-1313-T04-B
Zn CFS-L06-1313-T05-B
Zn CFS-L06-1313-T06-B
Zn CFS-L06-1313-T07-B
Zn CFS-L06-1313-T08-B
Zn CFS-L06-1313-T09-B
Zn CFS-L06-1313-T01-C
Zn CFS-L06-1313-T02-C
Zn CFS-L06-1313-T03-C
Zn CFS-L06-1313-T04-C
Zn CFS-L06-1313-T05-C
Zn CFS-L06-1313-T06-C
Zn CFS-L06-1313-T07-C
Zn CFS-L06-1313-T08-C
Zn CFS-L06-1313-T09-C
Zn CFS-L06-1313-B01-A
Zn CFS-L06-1313-B02-A
Zn CFS-L06-1313-B03-A
Zn CFS-L06-1313-B01-B
Zn CFS-L06-1313-B02-B
Zn CFS-L06-1313-B03-B
Zn CFS-L06-1313-B01-C
Zn CFS-L06-1313-B02-C
Zn CFS-L06-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.86E+03
1 4.07E+03
1 5.00E-01 U1/2
1 3.73E+02
1 5.34E+02
1 3.00E+03
1 1.67E+05
1 1.77E+05
1 1.60E+05
1 1.06E+04
1 2.21 E+03
1 5.86E+01
1 5.25E+02
1 6.82E+02
1 2.04E+04
1 1.64E+05
1 1.70E+05
1 1.71E+05
1 1.01E+04
1 4.03E+03
1 5.75E+01
1 3.36E+02
1 6.24E+02
1 1.70E+04
1 1.89E+05
1 1.88E+05
1 1.79E+05
1 5.00E-01 U1/2
1 5.12E+00
1 3.50E+00
1 1.39E+00 E
1 2.69E+00 E
1 2.70E+00 E
1 5.00E-01 U1/2
1 3.14E+00 E
1 2.23E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.86E+03 1.3E+00 1.0E+00 3.2E+00
4.07E+03 1.2E+00 1.0E+00 3.2E+00 10 120
5.00E-01 1.6E+02 1.0E+00 3.2E+00
3.73E+02 3.9E-01 1.0E+00 3.2E+00
5.34E+02 2.7E-01 1.0E+00 3.2E+00
3.00E+03 1.6E+02 1.0E+00 3.2E+00
1.67E+05 2.6E+00 1.0E+00 3.2E+00
1.77E+05 7.9E+00 1.0E+00 3.2E+00
1.60E+05 7.8E-01 1.0E+00 3.2E+00
1.06E+04 1.6E+00 1.0E+00 3.2E+00
2.21E+03 8.9E+01 1.0E+00 3.2E+00 10 120
5.86E+01 1.1E+00 1.0E+00 3.2E+00
5.25E+02 8.6E-01 1.0E+00 3.2E+00
6.82E+02 1.5E+00 1.0E+00 3.2E+00
2.04E+04 1.7E+00 1.0E+00 3.2E+00
1.64E+05 3.1E-01 1.0E+00 3.2E+00
1.70E+05 1.9E+00 1.0E+00 3.2E+00
1.71E+05 1.4E+00 1.0E+00 3.2E+00
1.01E+04 7.9E-01 1.0E+00 3.2E+00
4.03E+03 2.4E-01 1.0E+00 3.2E+00 10 150
5.75E+01 6.7E-01 1.0E+00 3.2E+00
3.36E+02 3.0E-01 1.0E+00 3.2E+00
6.24E+02 1.4E+00 1.0E+00 3.2E+00
1.70E+04 3.9E+01 1.0E+00 3.2E+00
1.89E+05 1.5E+00 1.0E+00 3.2E+00
1.88E+05 1.0E+00 1.0E+00 3.2E+00
1.79E+05 1.1E+00 1.0E+00 3.2E+00
5.00E-01 4.6E+03 1.0E+00 3.2E+00
5.12E+00 6.0E+00 1.0E+00 3.2E+00
3.50E+00 5.7E+00 1.0E+00 3.2E+00
1.39E+00 3.1E+01 1.0E+00 3.2E+00
2.69E+00 8.9E+00 1.0E+00 3.2E+00
2.70E+00 1.5E+00 1.0E+00 3.2E+00
5.00E-01 4.7E+01 1.0E+00 3.2E+00
3.14E+00 4.4E+00 1.0E+00 3.2E+00
2.23E+00 2.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.13E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.21 E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.38E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/14/11 3:39 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:40 PM EPA Interlab L06 1313-1316CFS
4/14/11 3:42 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:44 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:45 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:47 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:49 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:50 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:52 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:59 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:00 PM EPA Interlab L06 1313-1316CFS
4/14/11 4:02 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:04 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:05 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:07 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:09 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:10 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:12 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:14 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:15 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:17 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:19 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:20 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:22 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:23 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:25 PM EPA Interlab L06 1313-1316 CFS
4/14/11 4:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:24 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:26 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:27 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:29 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:30 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:32 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:34 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:35 PM EPA Interlab L06 1313-1316 CFS
4/14/11 3:37 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                          1-757
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample Internal
Sample Dilution Cone. Qualifier Review
I I ug/L I
CFS-L07-1313-T01-A 1 8.94E+01
CFS-L07-1313-T02-A 1 1.00E+02
CFS-L07-1313-T03-A 1 8.67E+01
CFS-L07-1313-T04-A 1 5.33E+01
CFS-L07-1313-T05-A 1 4.00E+01
CFS-L07-1313-T06-A 1 4.42E+01
CFS-L07-1313-T07-A 1 8.44E+03
CFS-L07-1313-T08-A 1 2.62E+04
CFS-L07-1313-T09-A 1 8.71E+04
CFS-L07-1313-T01-B 1 9.79E+01
CFS-L07-1313-T02-B 1 9.67E+01
CFS-L07-1313-T03-B 1 8.79E+01
CFS-L07-1313-T04-B 1 6.06E+01
CFS-L07-1313-T05-B 1 4.61 E+01
CFS-L07-1313-T06-B 1 3.69E+01
CFS-L07-1313-T07-B 1 7.84E+03
CFS-L07-1313-T08-B 1 1.89E+04
CFS-L07-1313-T09-B 1 8.71E+04
CFS-L07-1313-T01-C 1 1.03E+02
CFS-L07-1313-T02-C 1 1.01E+02
CFS-L07-1313-T03-C 1 8.50E+01
CFS-L07-1313-T04-C 1 6.08E+01
CFS-L07-1313-T05-C 1 4.49E+01
CFS-L07-1313-T06-C 1 4.91 E+01
CFS-L07-1313-T07-C 1 8.47E+03
CFS-L07-1313-T08-C 1 2.81 E+04
CFS-L07-1313-T09-C 1 8.83E+04
CFS-L07-1313-B01-A 1 5.00E-01 U1/2
CFS-L07-1313-B02-A 1 1.45E+00 E
CFS-L07-1313-B03-A 1 5.00E-01 U1/2
CFS-L07-1313-B01-B 1 5.00E-01 U1/2
CFS-L07-1313-B02-B 1 5.00E-01 U1/2
CFS-L07-1313-B03-B 1 5.00E-01 U1/2
CFS-L07-1313-B01-C 1 5.00E-01 U1/2
CFS-L07-1313-B02-C 1 5.00E-01 U1/2
CFS-L07-1313-B03-C 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.94E+01 2.8E+00 1.0E+00 3.2E+00
1.00E+02 3.4E+00 1.0E+00 3.2E+00 1000 100
8.67E+01 3.0E+00 1.0E+00 3.2E+00
5.33E+01 4.6E+00 1.0E+00 3.2E+00
4.00E+01 6.2E+00 1.0E+00 3.2E+00
4.42E+01 6.8E+00 1.0E+00 3.2E+00
8.44E+03 4.7E-01 1.0E+00 3.2E+00
2.62E+04 1.2E-01 1.0E+00 3.2E+00
8.71 E+04 7.3E-01 1.0E+00 3.2E+00
9.79E+01 2.2E+00 1.0E+00 3.2E+00
9.67E+01 1.1E+00 1.0E+00 3.2E+00 1000 100
8.79E+01 4.8E+00 1.0E+00 3.2E+00
6.06E+01 6.8E+00 1.0E+00 3.2E+00
4.61 E+01 7.4E+00 1.0E+00 3.2E+00
3.69E+01 1.2E+01 1.0E+00 3.2E+00
7.84E+03 9.4E-01 1.0E+00 3.2E+00
1.89E+04 6.5E+01 1.0E+00 3.2E+00
8.71 E+04 3.2E-01 1.0E+00 3.2E+00
1.03E+02 1.9E+00 1.0E+00 3.2E+00
1.01E+02 2.3E+00 1.0E+00 3.2E+00 1000 100
8.50E+01 7.5E-01 1.0E+00 3.2E+00
6.08E+01 1.9E+00 1.0E+00 3.2E+00
4.49E+01 3.8E+00 1.0E+00 3.2E+00
4.91 E+01 7.5E+00 1.0E+00 3.2E+00
8.47E+03 1.9E+00 1.0E+00 3.2E+00
2.81 E+04 1.6E-01 1.0E+00 3.2E+00
8.83E+04 1.1E-01 1.0E+00 3.2E+00
5.00E-01 7.9E+00 1.0E+00 3.2E+00
1.45E+00 3.8E+01 1.0E+00 3.2E+00
5.00E-01 3.3E+01 1.0E+00 3.2E+00
5.00E-01 4.8E+00 1.0E+00 3.2E+00
5.00E-01 6.1 E+01 1.0E+00 3.2E+00
5.00E-01 2.9E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
5.00E-01 6.1 E+01 1.0E+00 3.2E+00
5.00E-01 2.4E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.18E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                                     1-758
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb CFS-L07-1313-T01-A
Sb CFS-L07-1313-T02-A
Sb CFS-L07-1313-T03-A
Sb CFS-L07-1313-T04-A
Sb CFS-L07-1313-T05-A
Sb CFS-L07-1313-T06-A
Sb CFS-L07-1313-T07-A
Sb CFS-L07-1313-T08-A
Sb CFS-L07-1313-T09-A
Sb CFS-L07-1313-T01-B
Sb CFS-L07-1313-T02-B
Sb CFS-L07-1313-T03-B
Sb CFS-L07-1313-T04-B
Sb CFS-L07-1313-T05-B
Sb CFS-L07-1313-T06-B
Sb CFS-L07-1313-T07-B
Sb CFS-L07-1313-T08-B
Sb CFS-L07-1313-T09-B
Sb CFS-L07-1313-T01-C
Sb CFS-L07-1313-T02-C
Sb CFS-L07-1313-T03-C
Sb CFS-L07-1313-T04-C
Sb CFS-L07-1313-T05-C
Sb CFS-L07-1313-T06-C
Sb CFS-L07-1313-T07-C
Sb CFS-L07-1313-T08-C
Sb CFS-L07-1313-T09-C
Sb CFS-L07-1313-B01-A
Sb CFS-L07-1313-B02-A
Sb CFS-L07-1313-B03-A
Sb CFS-L07-1313-B01-B
Sb CFS-L07-1313-B02-B
Sb CFS-L07-1313-B03-B
Sb CFS-L07-1313-B01-C
Sb CFS-L07-1313-B02-C
Sb CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.50E+01 E
1 1.38E+01 E
1 3.62E+01
1 3.76E+01
1 3.85E+01
1 3.36E+01
1 3.00E+02
1 8.21 E+02
1 1.20E+03
1 1.08E+01 E
1 1.80E+01 E
1 3.50E+01
1 3.51 E+01
1 3.51 E+01
1 3.73E+01
1 2.54E+02
1 6.00E+02
1 1.11E+03
1 3.75E+00 U1/2
1 1.31E+01 E
1 3.53E+01
1 4.43E+01
1 2.37E+01 E
1 2.91E+01
1 2.51 E+02
1 8.19E+02
1 9.93E+02
1 1.22E+01 E
1 3.75E+00 U1/2
1 1.44E+01 E
1 3.75E+00 U1/2
1 8.02E+00 E
1 8.99E+00 E
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.50E+01 3.1 E+01 7.5E+00 2.4E+01
1.38E+01 1.4E+01 7.5E+00 2.4E+01 10 100
3.62E+01 9.7E+00 7.5E+00 2.4E+01
3.76E+01 1.1 E+01 7.5E+00 2.4E+01
3.85E+01 6.0E+00 7.5E+00 2.4E+01
3.36E+01 2.7E+01 7.5E+00 2.4E+01
3.00E+02 1.6E+01 7.5E+00 2.4E+01
8.21 E+02 1.3E+01 7.5E+00 2.4E+01
1.20E+03 1.3E+01 7.5E+00 2.4E+01
1.08E+01 9.5E+01 7.5E+00 2.4E+01
1.80E+01 2.8E+01 7.5E+00 2.4E+01 10 100
3.50E+01 2.0E+01 7.5E+00 2.4E+01
3.51E+01 2.2E+01 7.5E+00 2.4E+01
3.51 E+01 2.3E+01 7.5E+00 2.4E+01
3.73E+01 6.6E+00 7.5E+00 2.4E+01
2.54E+02 2.6E+01 7.5E+00 2.4E+01
6.00E+02 7.2E+01 7.5E+00 2.4E+01
1.11E+03 8.0E+00 7.5E+00 2.4E+01
3.75E+00 7.0E+01 7.5E+00 2.4E+01
1.31E+01 1.6E+01 7.5E+00 2.4E+01 10 100
3.53E+01 2.1 E+01 7.5E+00 2.4E+01
4.43E+01 2.5E+00 7.5E+00 2.4E+01
2.37E+01 3.3E+00 7.5E+00 2.4E+01
2.91 E+01 8.3E+00 7.5E+00 2.4E+01
2.51 E+02 9.9E+00 7.5E+00 2.4E+01
8.19E+02 9.2E+00 7.5E+00 2.4E+01
9.93E+02 2.7E+00 7.5E+00 2.4E+01
1.22E+01 2.0E+01 7.5E+00 2.4E+01
3.75E+00 4.5E+01 7.5E+00 2.4E+01
1.44E+01 1.2E+01 7.5E+00 2.4E+01
3.75E+00 1.0E+02 7.5E+00 2.4E+01
8.02E+00 4.9E+01 7.5E+00 2.4E+01
8.99E+00 2.3E+01 7.5E+00 2.4E+01
3.75E+00 6.4E+01 7.5E+00 2.4E+01
3.75E+00 1.1 E+02 7.5E+00 2.4E+01
3.75E+00 1.2E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.16E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-759
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As CFS-L07-1313-T01-A
As CFS-L07-1313-T02-A
As CFS-L07-1313-T03-A
As CFS-L07-1313-T04-A
As CFS-L07-1313-T05-A
As CFS-L07-1313-T06-A
As CFS-L07-1313-T07-A
As CFS-L07-1313-T08-A
As CFS-L07-1313-T09-A
As CFS-L07-1313-T01-B
As CFS-L07-1313-T02-B
As CFS-L07-1313-T03-B
As CFS-L07-1313-T04-B
As CFS-L07-1313-T05-B
As CFS-L07-1313-T06-B
As CFS-L07-1313-T07-B
As CFS-L07-1313-T08-B
As CFS-L07-1313-T09-B
As CFS-L07-1313-T01-C
As CFS-L07-1313-T02-C
As CFS-L07-1313-T03-C
As CFS-L07-1313-T04-C
As CFS-L07-1313-T05-C
As CFS-L07-1313-T06-C
As CFS-L07-1313-T07-C
As CFS-L07-1313-T08-C
As CFS-L07-1313-T09-C
As CFS-L07-1313-B01-A
As CFS-L07-1313-B02-A
As CFS-L07-1313-B03-A
As CFS-L07-1313-B01-B
As CFS-L07-1313-B02-B
As CFS-L07-1313-B03-B
As CFS-L07-1313-B01-C
As CFS-L07-1313-B02-C
As CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 6.14E+02
1 3.09E+02
1 8.65E+01
1 3.70E+01
1 1.76E+01 E
1 1.88E+01 E
1 2.91 E+02
1 7.84E+02
1 6.42E+04
1 5.93E+02
1 3.08E+02
1 9.16E+01
1 3.60E+01
1 5.83E+01
1 1.96E+01 E
1 2.42E+02
1 4.61 E+02
1 7.08E+04
1 6.10E+02
1 3.35E+02
1 8.79E+01
1 3.96E+01
1 3.66E+01
1 3.16E+01 E
1 2.81 E+02
1 7.09E+02
1 6.96E+04
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 2.54E+01 E
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 1.29E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.14E+02 2.6E+00 1.1E+01 3.5E+01
3.09E+02 1.8E+00 1.1E+01 3.5E+01 10 100
8.65E+01 7.0E+00 1.1E+01 3.5E+01
3.70E+01 2.5E+01 1.1E+01 3.5E+01
1.76E+01 3.0E+01 1.1E+01 3.5E+01
1.88E+01 5.4E+01 1.1E+01 3.5E+01
2.91E+02 3.6E+00 1.1E+01 3.5E+01
7.84E+02 9.7E-01 1.1E+01 3.5E+01
6.42E+04 8.3E-01 1.1E+01 3.5E+01
5.93E+02 2.1E+00 1.1E+01 3.5E+01
3.08E+02 2.2E+00 1.1E+01 3.5E+01 10 100
9.16E+01 9.6E+00 1.1E+01 3.5E+01
3.60E+01 2.4E+01 1.1E+01 3.5E+01
5.83E+01 1.8E+01 1.1E+01 3.5E+01
1.96E+01 5.3E+01 1.1E+01 3.5E+01
2.42E+02 3.1E+00 1.1E+01 3.5E+01
4.61E+02 6.9E+01 1.1E+01 3.5E+01
7.08E+04 3.3E-01 1.1E+01 3.5E+01
6.10E+02 1.6E+00 1.1E+01 3.5E+01
3.35E+02 1.4E+00 1.1E+01 3.5E+01 10 100
8.79E+01 9.0E+00 1.1E+01 3.5E+01
3.96E+01 1.0E+01 1.1E+01 3.5E+01
3.66E+01 2.6E+01 1.1E+01 3.5E+01
3.16E+01 1.6E+01 1.1E+01 3.5E+01
2.81E+02 2.8E+00 1.1E+01 3.5E+01
7.09E+02 1.7E+00 1.1E+01 3.5E+01
6.96E+04 1.1E+00 1.1E+01 3.5E+01
5.50E+00 1.9E+02 1.1E+01 3.5E+01
5.50E+00 1.4E+02 1.1E+01 3.5E+01
5.50E+00 2.6E+02 1.1E+01 3.5E+01
5.50E+00 2.2E+02 1.1E+01 3.5E+01
5.50E+00 4.4E+01 1.1E+01 3.5E+01
2.54E+01 2.6E+01 1.1E+01 3.5E+01
5.50E+00 2.9E+01 1.1E+01 3.5E+01
5.50E+00 2.4E+02 1.1E+01 3.5E+01
1.29E+01 2.0E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.31E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.50E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-760
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B CFS-L07-1313-T01-A
B CFS-L07-1313-T02-A
B CFS-L07-1313-T03-A
B CFS-L07-1313-T04-A
B CFS-L07-1313-T05-A
B CFS-L07-1313-T06-A
B CFS-L07-1313-T07-A
B CFS-L07-1313-T08-A
B CFS-L07-1313-T09-A
B CFS-L07-1313-T01-B
B CFS-L07-1313-T02-B
B CFS-L07-1313-T03-B
B CFS-L07-1313-T04-B
B CFS-L07-1313-T05-B
B CFS-L07-1313-T06-B
B CFS-L07-1313-T07-B
B CFS-L07-1313-T08-B
B CFS-L07-1313-T09-B
B CFS-L07-1313-T01-C
B CFS-L07-1313-T02-C
B CFS-L07-1313-T03-C
B CFS-L07-1313-T04-C
B CFS-L07-1313-T05-C
B CFS-L07-1313-T06-C
B CFS-L07-1313-T07-C
B CFS-L07-1313-T08-C
B CFS-L07-1313-T09-C
B CFS-L07-1313-B01-A
B CFS-L07-1313-B02-A
B CFS-L07-1313-B03-A
B CFS-L07-1313-B01-B
B CFS-L07-1313-B02-B
B CFS-L07-1313-B03-B
B CFS-L07-1313-B01-C
B CFS-L07-1313-B02-C
B CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.26E+01
1 9.25E+01
1 1.70E+02
1 1.34E+02
1 1.57E+02
1 1.70E+02
1 4.32E+02
1 6.42E+02
1 7.47E+02
1 9.42E+01
1 9.13E+01
1 1.60E+02
1 1.25E+02
1 1.52E+02
1 1.65E+02
1 4.15E+02
1 4.50E+02
1 7.44E+02
1 8.40E+01
1 8.35E+01
1 1.64E+02
1 1.20E+02
1 1.37E+02
1 1.58E+02
1 4.19E+02
1 6.51 E+02
1 8.73E+02
1 1.95E+01
1 1.89E+01
1 2.74E+01
1 7.02E+00
1 6.79E+00
1 1.28E+01
1 1.67E+00 E
1 4.13E+00
1 1.04E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.26E+01 4.9E-01 1.0E+00 3.2E+00
9.25E+01 6.3E-01 1.0E+00 3.2E+00 1000 100
1.70E+02 1.5E+00 1.0E+00 3.2E+00
1.34E+02 1.6E+00 1.0E+00 3.2E+00
1.57E+02 1.7E+00 1.0E+00 3.2E+00
1.70E+02 1.2E+00 1.0E+00 3.2E+00
4.32E+02 4.1E-01 1.0E+00 3.2E+00
6.42E+02 2.0E-01 1.0E+00 3.2E+00
7.47E+02 9.3E-01 1.0E+00 3.2E+00
9.42E+01 3.7E+00 1.0E+00 3.2E+00
9.13E+01 1.5E+00 1.0E+00 3.2E+00 1000 100
1.60E+02 1.4E+00 1.0E+00 3.2E+00
1.25E+02 2.3E+00 1.0E+00 3.2E+00
1.52E+02 8.9E-01 1.0E+00 3.2E+00
1.65E+02 5.9E-01 1.0E+00 3.2E+00
4.15E+02 8.8E-01 1.0E+00 3.2E+00
4.50E+02 6.8E+01 1.0E+00 3.2E+00
7.44E+02 3.1E-01 1.0E+00 3.2E+00
8.40E+01 2.0E+00 1.0E+00 3.2E+00
8.35E+01 2.3E+00 1.0E+00 3.2E+00 1000 100
1.64E+02 5.2E-01 1.0E+00 3.2E+00
1.20E+02 9.3E-01 1.0E+00 3.2E+00
1.37E+02 4.4E-01 1.0E+00 3.2E+00
1.58E+02 8.6E-01 1.0E+00 3.2E+00
4.19E+02 2.6E+00 1.0E+00 3.2E+00
6.51 E+02 2.2E-01 1.0E+00 3.2E+00
8.73E+02 7.7E-01 1.0E+00 3.2E+00
1.95E+01 1.5E+00 1.0E+00 3.2E+00
1.89E+01 8.9E+00 1.0E+00 3.2E+00
2.74E+01 4.3E+00 1.0E+00 3.2E+00
7.02E+00 3.0E+00 1.0E+00 3.2E+00
6.79E+00 3.0E+01 1.0E+00 3.2E+00
1.28E+01 1.5E+01 1.0E+00 3.2E+00
1.67E+00 1.9E+02 1.0E+00 3.2E+00
4.13E+00 5.3E+01 1.0E+00 3.2E+00
1.04E+01 1.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.20E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-761
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba CFS-L07-1313-T01-A
Ba CFS-L07-1313-T02-A
Ba CFS-L07-1313-T03-A
Ba CFS-L07-1313-T04-A
Ba CFS-L07-1313-T05-A
Ba CFS-L07-1313-T06-A
Ba CFS-L07-1313-T07-A
Ba CFS-L07-1313-T08-A
Ba CFS-L07-1313-T09-A
Ba CFS-L07-1313-T01-B
Ba CFS-L07-1313-T02-B
Ba CFS-L07-1313-T03-B
Ba CFS-L07-1313-T04-B
Ba CFS-L07-1313-T05-B
Ba CFS-L07-1313-T06-B
Ba CFS-L07-1313-T07-B
Ba CFS-L07-1313-T08-B
Ba CFS-L07-1313-T09-B
Ba CFS-L07-1313-T01-C
Ba CFS-L07-1313-T02-C
Ba CFS-L07-1313-T03-C
Ba CFS-L07-1313-T04-C
Ba CFS-L07-1313-T05-C
Ba CFS-L07-1313-T06-C
Ba CFS-L07-1313-T07-C
Ba CFS-L07-1313-T08-C
Ba CFS-L07-1313-T09-C
Ba CFS-L07-1313-B01-A
Ba CFS-L07-1313-B02-A
Ba CFS-L07-1313-B03-A
Ba CFS-L07-1313-B01-B
Ba CFS-L07-1313-B02-B
Ba CFS-L07-1313-B03-B
Ba CFS-L07-1313-B01-C
Ba CFS-L07-1313-B02-C
Ba CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.63E+03
1 1.60E+03
1 1.10E+03
1 6.99E+02
1 4.53E+02
1 1.98E+02
1 9.55E+01
1 1.12E+02
1 9.74E+01
1 2.66E+03
1 1.64E+03
1 1.07E+03
1 6.88E+02
1 4.59E+02
1 1.93E+02
1 9.69E+01
1 7.56E+01
1 9.52E+01
1 2.75E+03
1 1.69E+03
1 1.13E+03
1 6.96E+02
1 4.38E+02
1 1.90E+02
1 9.46E+01
1 1.11E+02
1 9.42E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 2.71 E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 2.59E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 2.76E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.63E+03 6.9E-01 1.0E+00 3.2E+00
1.60E+03 2.4E-01 1.0E+00 3.2E+00 10 100
1.10E+03 8.8E-01 1.0E+00 3.2E+00
6.99E+02 3.4E-01 1.0E+00 3.2E+00
4.53E+02 6.3E-01 1.0E+00 3.2E+00
1.98E+02 5.3E-01 1.0E+00 3.2E+00
9.55E+01 7.8E-01 1.0E+00 3.2E+00
1.12E+02 9.9E-01 1.0E+00 3.2E+00
9.74E+01 2.4E+00 1.0E+00 3.2E+00
2.66E+03 1.6E-01 1.0E+00 3.2E+00
1.64E+03 1.4E-01 1.0E+00 3.2E+00 10 100
1.07E+03 4.7E-01 1.0E+00 3.2E+00
6.88E+02 1.1E+00 1.0E+00 3.2E+00
4.59E+02 3.0E-01 1.0E+00 3.2E+00
1.93E+02 1.4E+00 1.0E+00 3.2E+00
9.69E+01 7.6E-01 1.0E+00 3.2E+00
7.56E+01 6.9E+01 1.0E+00 3.2E+00
9.52E+01 7.0E-01 1.0E+00 3.2E+00
2.75E+03 3.6E-01 1.0E+00 3.2E+00
1.69E+03 5.0E-01 1.0E+00 3.2E+00 10 100
1.13E+03 6.6E-01 1.0E+00 3.2E+00
6.96E+02 3.6E-01 1.0E+00 3.2E+00
4.38E+02 5.6E-01 1.0E+00 3.2E+00
1.90E+02 1.4E+00 1.0E+00 3.2E+00
9.46E+01 3.6E+00 1.0E+00 3.2E+00
1.11E+02 1.0E+00 1.0E+00 3.2E+00
9.42E+01 9.1E-01 1.0E+00 3.2E+00
5.00E-01 5.2E+02 1.0E+00 3.2E+00
5.00E-01 5.7E+01 1.0E+00 3.2E+00
2.71 E+03 1.0E-01 1.0E+00 3.2E+00
5.00E-01 1.8E+02 1.0E+00 3.2E+00
5.00E-01 1.7E+02 1.0E+00 3.2E+00
2.59E+03 9.8E-01 1.0E+00 3.2E+00
5.00E-01 1.9E+02 1.0E+00 3.2E+00
5.00E-01 5.0E+02 1.0E+00 3.2E+00
2.76E+03 1.9E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.55E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.53E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.60E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-762
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be CFS-L07-1313-T01-A
Be CFS-L07-1313-T02-A
Be CFS-L07-1313-T03-A
Be CFS-L07-1313-T04-A
Be CFS-L07-1313-T05-A
Be CFS-L07-1313-T06-A
Be CFS-L07-1313-T07-A
Be CFS-L07-1313-T08-A
Be CFS-L07-1313-T09-A
Be CFS-L07-1313-T01-B
Be CFS-L07-1313-T02-B
Be CFS-L07-1313-T03-B
Be CFS-L07-1313-T04-B
Be CFS-L07-1313-T05-B
Be CFS-L07-1313-T06-B
Be CFS-L07-1313-T07-B
Be CFS-L07-1313-T08-B
Be CFS-L07-1313-T09-B
Be CFS-L07-1313-T01-C
Be CFS-L07-1313-T02-C
Be CFS-L07-1313-T03-C
Be CFS-L07-1313-T04-C
Be CFS-L07-1313-T05-C
Be CFS-L07-1313-T06-C
Be CFS-L07-1313-T07-C
Be CFS-L07-1313-T08-C
Be CFS-L07-1313-T09-C
Be CFS-L07-1313-B01-A
Be CFS-L07-1313-B02-A
Be CFS-L07-1313-B03-A
Be CFS-L07-1313-B01-B
Be CFS-L07-1313-B02-B
Be CFS-L07-1313-B03-B
Be CFS-L07-1313-B01-C
Be CFS-L07-1313-B02-C
Be CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.30E+00 E
1 6.82E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.13E+OOE
1 4.59E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 4.28E+00 E
1 6.63E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.2E+01 1.9E+00 6.0E+00
9.50E-01 7.8E+01 1.9E+00 6.0E+00 10 100
9.50E-01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 3.7E+01 1.9E+00 6.0E+00
9.50E-01 2.1E+01 1.9E+00 6.0E+00
9.50E-01 6.2E+01 1.9E+00 6.0E+00
4.30E+00 1.4E+00 1.9E+00 6.0E+00
6.82E+00 4.1E+00 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00
9.50E-01 1.9E+01 1.9E+00 6.0E+00
9.50E-01 5.4E+01 1.9E+00 6.0E+00 10 100
9.50E-01 4.3E+02 1.9E+00 6.0E+00
9.50E-01 2.6E+02 1.9E+00 6.0E+00
9.50E-01 8.0E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
4.13E+00 2.8E+00 1.9E+00 6.0E+00
4.59E+00 5.9E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+00 1.9E+00 6.0E+00
9.50E-01 3.3E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+03 1.9E+00 6.0E+00 10 100
9.50E-01 2.1E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 5.0E+01 1.9E+00 6.0E+00
9.50E-01 4.3E+01 1.9E+00 6.0E+00
4.28E+00 7.9E+00 1.9E+00 6.0E+00
6.63E+00 5.7E+00 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 7.3E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 9.1E+01 1.9E+00 6.0E+00
9.50E-01 7.0E+01 1.9E+00 6.0E+00
9.50E-01 3.0E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 9.5E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.15E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-763
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd CFS-L07-1313-T01-A
Cd CFS-L07-1313-T02-A
Cd CFS-L07-1313-T03-A
Cd CFS-L07-1313-T04-A
Cd CFS-L07-1313-T05-A
Cd CFS-L07-1313-T06-A
Cd CFS-L07-1313-T07-A
Cd CFS-L07-1313-T08-A
Cd CFS-L07-1313-T09-A
Cd CFS-L07-1313-T01-B
Cd CFS-L07-1313-T02-B
Cd CFS-L07-1313-T03-B
Cd CFS-L07-1313-T04-B
Cd CFS-L07-1313-T05-B
Cd CFS-L07-1313-T06-B
Cd CFS-L07-1313-T07-B
Cd CFS-L07-1313-T08-B
Cd CFS-L07-1313-T09-B
Cd CFS-L07-1313-T01-C
Cd CFS-L07-1313-T02-C
Cd CFS-L07-1313-T03-C
Cd CFS-L07-1313-T04-C
Cd CFS-L07-1313-T05-C
Cd CFS-L07-1313-T06-C
Cd CFS-L07-1313-T07-C
Cd CFS-L07-1313-T08-C
Cd CFS-L07-1313-T09-C
Cd CFS-L07-1313-B01-A
Cd CFS-L07-1313-B02-A
Cd CFS-L07-1313-B03-A
Cd CFS-L07-1313-B01-B
Cd CFS-L07-1313-B02-B
Cd CFS-L07-1313-B03-B
Cd CFS-L07-1313-B01-C
Cd CFS-L07-1313-B02-C
Cd CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.26E+01
1 1.78E+01
1 1.10E+00 U1/2
1 2.26E+01
1 5.10E+02
1 4.81 E+03
1 3.37E+04
1 4.73E+04
1 4.63E+04
1 1.21E+01
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.94E+01
1 4.56E+02
1 4.68E+03
1 3.28E+04
1 3.48E+04
1 4.83E+04
1 1.32E+01
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.45E+01
1 2.89E+02
1 4.65E+03
1 3.31 E+04
1 4.72E+04
1 4.99E+04
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.26E+01 3.7E+00 2.2E+00 7.0E+00
1.78E+01 2.0E+00 2.2E+00 7.0E+00 10 100
1.10E+00 4.0E+01 2.2E+00 7.0E+00
2.26E+01 9.8E-01 2.2E+00 7.0E+00
5.10E+02 4.7E-01 2.2E+00 7.0E+00
4.81 E+03 3.5E-01 2.2E+00 7.0E+00
3.37E+04 6.3E-01 2.2E+00 7.0E+00
4.73E+04 9.1E-01 2.2E+00 7.0E+00
4.63E+04 8.6E-02 2.2E+00 7.0E+00
1.21E+01 3.8E+00 2.2E+00 7.0E+00
1.10E+00 1.8E+02 2.2E+00 7.0E+00 10 100
1.10E+00 1.6E+01 2.2E+00 7.0E+00
1.94E+01 1.6E+00 2.2E+00 7.0E+00
4.56E+02 2.7E-01 2.2E+00 7.0E+00
4.68E+03 8.2E-01 2.2E+00 7.0E+00
3.28E+04 8.2E-01 2.2E+00 7.0E+00
3.48E+04 6.5E+01 2.2E+00 7.0E+00
4.83E+04 2.9E-01 2.2E+00 7.0E+00
1.32E+01 3.5E+00 2.2E+00 7.0E+00
1.10E+00 4.5E+01 2.2E+00 7.0E+00 10 100
1.10E+00 4.7E+01 2.2E+00 7.0E+00
1.45E+01 1.3E+00 2.2E+00 7.0E+00
2.89E+02 5.8E-01 2.2E+00 7.0E+00
4.65E+03 1.3E+00 2.2E+00 7.0E+00
3.31 E+04 2.4E+00 2.2E+00 7.0E+00
4.72E+04 7.8E-01 2.2E+00 7.0E+00
4.99E+04 1.8E-01 2.2E+00 7.0E+00
1.10E+00 5.9E+00 2.2E+00 7.0E+00
1.10E+00 2.7E+00 2.2E+00 7.0E+00
1.10E+00 4.3E+00 2.2E+00 7.0E+00
1.10E+00 7.7E+00 2.2E+00 7.0E+00
1.10E+00 7.3E+00 2.2E+00 7.0E+00
1.10E+00 4.1E+00 2.2E+00 7.0E+00
1.10E+00 1.8E+01 2.2E+00 7.0E+00
1.10E+00 3.7E+00 2.2E+00 7.0E+00
1.10E+00 2.6E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.11 E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-764
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
CFS-L07-1313-T01-A
CFS-L07-1313-T02-A
CFS-L07-1313-T03-A
CFS-L07-1313-T04-A
CFS-L07-1313-T05-A
CFS-L07-1313-T06-A
CFS-L07-1313-T07-A
CFS-L07-1313-T08-A
CFS-L07-1313-T09-A
CFS-L07-1313-T01-B
CFS-L07-1313-T02-B
CFS-L07-1313-T03-B
CFS-L07-1313-T04-B
CFS-L07-1313-T05-B
CFS-L07-1313-T06-B
CFS-L07-1313-T07-B
CFS-L07-1313-T08-B
CFS-L07-1313-T09-B
CFS-L07-1313-T01-C
CFS-L07-1313-T02-C
CFS-L07-1313-T03-C
CFS-L07-1313-T04-C
CFS-L07-1313-T05-C
CFS-L07-1313-T06-C
CFS-L07-1313-T07-C
CFS-L07-1313-T08-C
CFS-L07-1313-T09-C
CFS-L07-1313-B01-A
CFS-L07-1313-B02-A
CFS-L07-1313-B03-A
CFS-L07-1313-B01-B
CFS-L07-1313-B02-B
CFS-L07-1313-B03-B
CFS-L07-1313-B01-C
CFS-L07-1313-B02-C
CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.22E+05
1 5.88E+05
1 6.04E+05
1 6.24E+05
1 6.48E+05
1 6.81 E+05
1 1.04E+06
1 1.27E+06
1 1.62E+06
1 3.15E+05
1 5.97E+05
1 5.95E+05
1 6.06E+05
1 6.66E+05
1 6.70E+05
1 9.88E+05
1 9.37E+05
1 1.61E+06
1 3.48E+05
1 6.22E+05
1 6.32E+05
1 6.21 E+05
1 6.50E+05
1 6.75E+05
1 1.01E+06
1 1.26E+06
1 1.58E+06
1 2.94E+01
1 2.34E+01
1 4.75E+01
1 2.88E+01
1 2.82E+01
1 7.44E+01
1 2.53E+01
1 1.99E+01
1 5.58E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.22E+05 9.0E-02 2.6E+00 8.3E+00
5.88E+05 5.8E-01 2.6E+00 8.3E+00 1000 100
6.04E+05 9.1E-01 2.6E+00 8.3E+00
6.24E+05 1.5E-01 2.6E+00 8.3E+00
6.48E+05 5.9E-01 2.6E+00 8.3E+00
6.81 E+05 2.1E-01 2.6E+00 8.3E+00
1.04E+06 7.5E-02 2.6E+00 8.3E+00
1.27E+06 1.5E+00 2.6E+00 8.3E+00
1.62E+06 6.7E-01 2.6E+00 8.3E+00
3.15E+05 2.8E-01 2.6E+00 8.3E+00
5.97E+05 2.9E-01 2.6E+00 8.3E+00 1000 100
5.95E+05 7.3E-01 2.6E+00 8.3E+00
6.06E+05 7.5E-01 2.6E+00 8.3E+00
6.66E+05 5.9E-01 2.6E+00 8.3E+00
6.70E+05 2.1E-01 2.6E+00 8.3E+00
9.88E+05 3.3E-01 2.6E+00 8.3E+00
9.37E+05 6.6E+01 2.6E+00 8.3E+00
1.61E+06 9.6E-01 2.6E+00 8.3E+00
3.48E+05 8.8E-01 2.6E+00 8.3E+00
6.22E+05 8.3E-01 2.6E+00 8.3E+00 1000 100
6.32E+05 8.0E-01 2.6E+00 8.3E+00
6.21 E+05 4.3E-01 2.6E+00 8.3E+00
6.50E+05 6.7E-01 2.6E+00 8.3E+00
6.75E+05 9.8E-01 2.6E+00 8.3E+00
1.01E+06 1.6E+00 2.6E+00 8.3E+00
1.26E+06 8.7E-01 2.6E+00 8.3E+00
1.58E+06 6.1E-01 2.6E+00 8.3E+00
2.94E+01 1.1E+01 2.6E+00 8.3E+00
2.34E+01 1.9E+01 2.6E+00 8.3E+00
4.75E+01 4.6E+01 2.6E+00 8.3E+00
2.88E+01 1.4E+01 2.6E+00 8.3E+00
2.82E+01 2.0E+01 2.6E+00 8.3E+00
7.44E+01 2.0E+01 2.6E+00 8.3E+00
2.53E+01 1.2E+01 2.6E+00 8.3E+00
1.99E+01 1.9E+01 2.6E+00 8.3E+00
5.58E+01 1.4E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.89E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.98E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.23E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-765
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr CFS-L07-1313-T01-A
Cr CFS-L07-1313-T02-A
Cr CFS-L07-1313-T03-A
Cr CFS-L07-1313-T04-A
Cr CFS-L07-1313-T05-A
Cr CFS-L07-1313-T06-A
Cr CFS-L07-1313-T07-A
Cr CFS-L07-1313-T08-A
Cr CFS-L07-1313-T09-A
Cr CFS-L07-1313-T01-B
Cr CFS-L07-1313-T02-B
Cr CFS-L07-1313-T03-B
Cr CFS-L07-1313-T04-B
Cr CFS-L07-1313-T05-B
Cr CFS-L07-1313-T06-B
Cr CFS-L07-1313-T07-B
Cr CFS-L07-1313-T08-B
Cr CFS-L07-1313-T09-B
Cr CFS-L07-1313-T01-C
Cr CFS-L07-1313-T02-C
Cr CFS-L07-1313-T03-C
Cr CFS-L07-1313-T04-C
Cr CFS-L07-1313-T05-C
Cr CFS-L07-1313-T06-C
Cr CFS-L07-1313-T07-C
Cr CFS-L07-1313-T08-C
Cr CFS-L07-1313-T09-C
Cr CFS-L07-1313-B01-A
Cr CFS-L07-1313-B02-A
Cr CFS-L07-1313-B03-A
Cr CFS-L07-1313-B01-B
Cr CFS-L07-1313-B02-B
Cr CFS-L07-1313-B03-B
Cr CFS-L07-1313-B01-C
Cr CFS-L07-1313-B02-C
Cr CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.08E+02
1 6.96E+01
1 7.01 E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 2.36E+01
1 2.01 E+03
1 1.95E+02
1 8.23E+01
1 6.84E+00
1 1.37E+00 E
1 1.97E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.38E+01
1 2.07E+03
1 1.66E+02
1 7.60E+01
1 7.25E+00
1 1.49E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 2.78E+01
1 1.85E+03
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.45E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.94E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+02 1.2E+00 1.2E+00 3.8E+00
6.96E+01 4.7E-01 1.2E+00 3.8E+00 10 100
7.01 E+00 1.8E+01 1.2E+00 3.8E+00
6.00E-01 2.6E+01 1.2E+00 3.8E+00
6.00E-01 1.1E+02 1.2E+00 3.8E+00
6.00E-01 1.2E+02 1.2E+00 3.8E+00
6.00E-01 4.4E+01 1.2E+00 3.8E+00
2.36E+01 1.7E+00 1.2E+00 3.8E+00
2.01 E+03 5.0E-01 1.2E+00 3.8E+00
1.95E+02 7.5E-01 1.2E+00 3.8E+00
8.23E+01 5.1E-01 1.2E+00 3.8E+00 10 100
6.84E+00 8.9E+00 1.2E+00 3.8E+00
1.37E+00 1.4E+01 1.2E+00 3.8E+00
1.97E+00 2.8E+01 1.2E+00 3.8E+00
6.00E-01 1.5E+02 1.2E+00 3.8E+00
6.00E-01 7.5E+01 1.2E+00 3.8E+00
1.38E+01 6.7E+01 1.2E+00 3.8E+00
2.07E+03 7.7E-02 1.2E+00 3.8E+00
1.66E+02 8.6E-01 1.2E+00 3.8E+00
7.60E+01 1.3E+00 1.2E+00 3.8E+00 10 100
7.25E+00 1.2E+01 1.2E+00 3.8E+00
1.49E+00 1.1E+01 1.2E+00 3.8E+00
6.00E-01 8.1E+01 1.2E+00 3.8E+00
6.00E-01 6.6E+01 1.2E+00 3.8E+00
6.00E-01 7.8E+01 1.2E+00 3.8E+00
2.78E+01 2.7E+00 1.2E+00 3.8E+00
1.85E+03 4.9E-01 1.2E+00 3.8E+00
6.00E-01 1.8E+05 1.2E+00 3.8E+00
6.00E-01 2.4E+01 1.2E+00 3.8E+00
6.00E-01 1.5E+01 1.2E+00 3.8E+00
6.00E-01 2.6E+02 1.2E+00 3.8E+00
6.00E-01 6.6E+02 1.2E+00 3.8E+00
1.45E+00 4.7E+01 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
6.00E-01 6.1E+02 1.2E+00 3.8E+00
1.94E+00 2.6E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.14E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-766
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
CFS-L07-1313-T01-A
CFS-L07-1313-T02-A
CFS-L07-1313-T03-A
CFS-L07-1313-T04-A
CFS-L07-1313-T05-A
CFS-L07-1313-T06-A
CFS-L07-1313-T07-A
CFS-L07-1313-T08-A
CFS-L07-1313-T09-A
CFS-L07-1313-T01-B
CFS-L07-1313-T02-B
CFS-L07-1313-T03-B
CFS-L07-1313-T04-B
CFS-L07-1313-T05-B
CFS-L07-1313-T06-B
CFS-L07-1313-T07-B
CFS-L07-1313-T08-B
CFS-L07-1313-T09-B
CFS-L07-1313-T01-C
CFS-L07-1313-T02-C
CFS-L07-1313-T03-C
CFS-L07-1313-T04-C
CFS-L07-1313-T05-C
CFS-L07-1313-T06-C
CFS-L07-1313-T07-C
CFS-L07-1313-T08-C
CFS-L07-1313-T09-C
CFS-L07-1313-B01-A
CFS-L07-1313-B02-A
CFS-L07-1313-B03-A
CFS-L07-1313-B01-B
CFS-L07-1313-B02-B
CFS-L07-1313-B03-B
CFS-L07-1313-B01-C
CFS-L07-1313-B02-C
CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 6.01 E+00
1 1.09E+02
1 1.01E+03
1 1.62E+03
1 1.77E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 5.16E+00 E
1 1.04E+02
1 9.31 E+02
1 1.22E+03
1 1.88E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.43E+01
1 9.57E+02
1 1.58E+03
1 1.75E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.0E+01 1.8E+00 5.7E+00
9.00E-01 2.5E+01 1.8E+00 5.7E+00 10 100
9.00E-01 4.0E+01 1.8E+00 5.7E+00
9.00E-01 4.8E+00 1.8E+00 5.7E+00
6.01 E+00 8.8E+00 1.8E+00 5.7E+00
1.09E+02 2.6E+00 1.8E+00 5.7E+00
1.01E+03 2.4E+00 1.8E+00 5.7E+00
1.62E+03 1.7E+00 1.8E+00 5.7E+00
1.77E+03 1.0E+00 1.8E+00 5.7E+00
9.00E-01 2.6E+01 1.8E+00 5.7E+00
9.00E-01 4.4E+01 1.8E+00 5.7E+00 10 100
9.00E-01 2.8E+01 1.8E+00 5.7E+00
9.00E-01 4.1E+01 1.8E+00 5.7E+00
5.16E+00 1.9E+01 1.8E+00 5.7E+00
1.04E+02 1.1 E+00 1.8E+00 5.7E+00
9.31 E+02 3.5E+00 1.8E+00 5.7E+00
1.22E+03 5.9E+01 1.8E+00 5.7E+00
1.88E+03 1.2E+00 1.8E+00 5.7E+00
9.00E-01 2.9E+02 1.8E+00 5.7E+00
9.00E-01 1.9E+01 1.8E+00 5.7E+00 10 100
9.00E-01 6.2E+01 1.8E+00 5.7E+00
9.00E-01 3.8E+01 1.8E+00 5.7E+00
9.00E-01 9.3E+01 1.8E+00 5.7E+00
9.43E+01 7.3E-01 1.8E+00 5.7E+00
9.57E+02 1.4E-01 1.8E+00 5.7E+00
1.58E+03 9.2E-01 1.8E+00 5.7E+00
1.75E+03 4.5E-01 1.8E+00 5.7E+00
9.00E-01 2.1E+01 1.8E+00 5.7E+00
9.00E-01 8.0E+00 1.8E+00 5.7E+00
9.00E-01 5.5E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+01 1.8E+00 5.7E+00
9.00E-01 1.6E+01 1.8E+00 5.7E+00
9.00E-01 4.1E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+01 1.8E+00 5.7E+00
9.00E-01 3.7E+01 1.8E+00 5.7E+00
9.00E-01 7.6E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-767
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu CFS-L07-1313-T01-A
Cu CFS-L07-1313-T02-A
Cu CFS-L07-1313-T03-A
Cu CFS-L07-1313-T04-A
Cu CFS-L07-1313-T05-A
Cu CFS-L07-1313-T06-A
Cu CFS-L07-1313-T07-A
Cu CFS-L07-1313-T08-A
Cu CFS-L07-1313-T09-A
Cu CFS-L07-1313-T01-B
Cu CFS-L07-1313-T02-B
Cu CFS-L07-1313-T03-B
Cu CFS-L07-1313-T04-B
Cu CFS-L07-1313-T05-B
Cu CFS-L07-1313-T06-B
Cu CFS-L07-1313-T07-B
Cu CFS-L07-1313-T08-B
Cu CFS-L07-1313-T09-B
Cu CFS-L07-1313-T01-C
Cu CFS-L07-1313-T02-C
Cu CFS-L07-1313-T03-C
Cu CFS-L07-1313-T04-C
Cu CFS-L07-1313-T05-C
Cu CFS-L07-1313-T06-C
Cu CFS-L07-1313-T07-C
Cu CFS-L07-1313-T08-C
Cu CFS-L07-1313-T09-C
Cu CFS-L07-1313-B01-A
Cu CFS-L07-1313-B02-A
Cu CFS-L07-1313-B03-A
Cu CFS-L07-1313-B01-B
Cu CFS-L07-1313-B02-B
Cu CFS-L07-1313-B03-B
Cu CFS-L07-1313-B01-C
Cu CFS-L07-1313-B02-C
Cu CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.47E+03
1 1.31E+03
1 1.55E+02
1 7.40E+01
1 7.98E+01
1 9.12E+02
1 4.59E+05
1 8.77E+05
1 1.03E+06
1 9.10E+03
1 1.06E+03
1 1.50E+02
1 7.92E+01
1 1.66E+02
1 8.54E+02
1 4.21 E+05
1 6.59E+05
1 1.04E+06
1 1.01E+04
1 1.10E+03
1 1.59E+02
1 7.42E+01
1 1.02E+02
1 8.91 E+02
1 4.42E+05
1 8.87E+05
1 1.05E+06
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.47E+03 4.3E-01 3.7E+00 1.2E+01
1.31E+03 2.0E+00 3.7E+00 1.2E+01 10 100
1.55E+02 1.7E+00 3.7E+00 1.2E+01
7.40E+01 3.9E+00 3.7E+00 1.2E+01
7.98E+01 2.5E+00 3.7E+00 1.2E+01
9.12E+02 7.7E-01 3.7E+00 1.2E+01
4.59E+05 5.9E-01 3.7E+00 1.2E+01
8.77E+05 2.5E-01 3.7E+00 1.2E+01
1.03E+06 1.4E-01 3.7E+00 1.2E+01
9.10E+03 6.7E-01 3.7E+00 1.2E+01
1.06E+03 1.1E+00 3.7E+00 1.2E+01 10 100
1.50E+02 2.5E+00 3.7E+00 1.2E+01
7.92E+01 5.4E-01 3.7E+00 1.2E+01
1.66E+02 2.5E+00 3.7E+00 1.2E+01
8.54E+02 8.0E-01 3.7E+00 1.2E+01
4.21 E+05 9.0E-01 3.7E+00 1.2E+01
6.59E+05 6.1E+01 3.7E+00 1.2E+01
1.04E+06 3.3E-01 3.7E+00 1.2E+01
1.01E+04 1.6E+00 3.7E+00 1.2E+01
1.10E+03 1.4E+00 3.7E+00 1.2E+01 10 100
1.59E+02 7.6E-01 3.7E+00 1.2E+01
7.42E+01 4.5E+00 3.7E+00 1.2E+01
1.02E+02 2.3E+00 3.7E+00 1.2E+01
8.91 E+02 2.4E+00 3.7E+00 1.2E+01
4.42E+05 1.1E+00 3.7E+00 1.2E+01
8.87E+05 5.1E-01 3.7E+00 1.2E+01
1.05E+06 9.3E-01 3.7E+00 1.2E+01
1.85E+00 7.3E+00 3.7E+00 1.2E+01
1.85E+00 2.7E+01 3.7E+00 1.2E+01
1.85E+00 5.8E+01 3.7E+00 1.2E+01
1.85E+00 1.1E+03 3.7E+00 1.2E+01
1.85E+00 2.5E+01 3.7E+00 1.2E+01
1.85E+00 3.2E+01 3.7E+00 1.2E+01
1.85E+00 1.4E+02 3.7E+00 1.2E+01
1.85E+00 3.1E+01 3.7E+00 1.2E+01
1.85E+00 2.0E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.30E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.15E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.07E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-768
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe CFS-L07-1313-T01-A
Fe CFS-L07-1313-T02-A
Fe CFS-L07-1313-T03-A
Fe CFS-L07-1313-T04-A
Fe CFS-L07-1313-T05-A
Fe CFS-L07-1313-T06-A
Fe CFS-L07-1313-T07-A
Fe CFS-L07-1313-T08-A
Fe CFS-L07-1313-T09-A
Fe CFS-L07-1313-T01-B
Fe CFS-L07-1313-T02-B
Fe CFS-L07-1313-T03-B
Fe CFS-L07-1313-T04-B
Fe CFS-L07-1313-T05-B
Fe CFS-L07-1313-T06-B
Fe CFS-L07-1313-T07-B
Fe CFS-L07-1313-T08-B
Fe CFS-L07-1313-T09-B
Fe CFS-L07-1313-T01-C
Fe CFS-L07-1313-T02-C
Fe CFS-L07-1313-T03-C
Fe CFS-L07-1313-T04-C
Fe CFS-L07-1313-T05-C
Fe CFS-L07-1313-T06-C
Fe CFS-L07-1313-T07-C
Fe CFS-L07-1313-T08-C
Fe CFS-L07-1313-T09-C
Fe CFS-L07-1313-B01-A
Fe CFS-L07-1313-B02-A
Fe CFS-L07-1313-B03-A
Fe CFS-L07-1313-B01-B
Fe CFS-L07-1313-B02-B
Fe CFS-L07-1313-B03-B
Fe CFS-L07-1313-B01-C
Fe CFS-L07-1313-B02-C
Fe CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.98E+00 E
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 5.29E+01
1 1.66E+04
1 2.54E+05
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.82E+00 E
1 1.00E+00 U1/2
1 1.63E+02
1 3.18E+00 E
1 1.98E+01
1 1.41E+04
1 2.87E+05
1 4.69E+00 E
1 1.08E+01
1 3.86E+00 E
1 6.62E+00
1 2.80E+01
1 5.75E+01
1 5.59E+01
1 2.18E+04
1 2.54E+05
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.28E+01
1 3.69E+00 E
1 1.00E+OOU1/2
1 2.31E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.31E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00 1000 100
3.98E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 4.5E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
5.29E+01 1.4E+00 2.0E+00 6.4E+00
1.66E+04 6.7E-01 2.0E+00 6.4E+00
2.54E+05 2.7E-01 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00 1000 100
2.82E+00 5.1E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.63E+02 4.1E-01 2.0E+00 6.4E+00
3.18E+00 1.6E+01 2.0E+00 6.4E+00
1.98E+01 2.1E+00 2.0E+00 6.4E+00
1.41E+04 5.5E+01 2.0E+00 6.4E+00
2.87E+05 5.8E+00 2.0E+00 6.4E+00
4.69E+00 5.6E+00 2.0E+00 6.4E+00
1.08E+01 5.4E+00 2.0E+00 6.4E+00 1000 100
3.86E+00 1.4E+01 2.0E+00 6.4E+00
6.62E+00 3.4E+00 2.0E+00 6.4E+00
2.80E+01 3.7E+00 2.0E+00 6.4E+00
5.75E+01 2.7E+00 2.0E+00 6.4E+00
5.59E+01 2.0E+00 2.0E+00 6.4E+00
2.18E+04 3.8E-01 2.0E+00 6.4E+00
2.54E+05 4.7E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+02 2.0E+00 6.4E+00
1.28E+01 3.2E+00 2.0E+00 6.4E+00
3.69E+00 7.2E+00 2.0E+00 6.4E+00
1.00E+00 2.0E+00 2.0E+00 6.4E+00
2.31 E+01 2.5E+00 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 8.3E+00 2.0E+00 6.4E+00
1.31 E+01 4.0E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-769
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb CFS-L07-1313-T01-A
Pb CFS-L07-1313-T02-A
Pb CFS-L07-1313-T03-A
Pb CFS-L07-1313-T04-A
Pb CFS-L07-1313-T05-A
Pb CFS-L07-1313-T06-A
Pb CFS-L07-1313-T07-A
Pb CFS-L07-1313-T08-A
Pb CFS-L07-1313-T09-A
Pb CFS-L07-1313-T01-B
Pb CFS-L07-1313-T02-B
Pb CFS-L07-1313-T03-B
Pb CFS-L07-1313-T04-B
Pb CFS-L07-1313-T05-B
Pb CFS-L07-1313-T06-B
Pb CFS-L07-1313-T07-B
Pb CFS-L07-1313-T08-B
Pb CFS-L07-1313-T09-B
Pb CFS-L07-1313-T01-C
Pb CFS-L07-1313-T02-C
Pb CFS-L07-1313-T03-C
Pb CFS-L07-1313-T04-C
Pb CFS-L07-1313-T05-C
Pb CFS-L07-1313-T06-C
Pb CFS-L07-1313-T07-C
Pb CFS-L07-1313-T08-C
Pb CFS-L07-1313-T09-C
Pb CFS-L07-1313-B01-A
Pb CFS-L07-1313-B02-A
Pb CFS-L07-1313-B03-A
Pb CFS-L07-1313-B01-B
Pb CFS-L07-1313-B02-B
Pb CFS-L07-1313-B03-B
Pb CFS-L07-1313-B01-C
Pb CFS-L07-1313-B02-C
Pb CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.75E+03
1 7.98E+03
1 5.04E+02
1 1.77E+02
1 3.83E+02
1 1.32E+03
1 7.58E+03
1 6.33E+03
1 9.03E+03
1 4.91 E+03
1 6.96E+03
1 4.97E+02
1 1.73E+02
1 4.67E+02
1 1.34E+03
1 7.97E+03
1 4.38E+03
1 9.00E+03
1 4.34E+03
1 7.80E+03
1 5.60E+02
1 1.71E+02
1 2.91 E+02
1 1.33E+03
1 7.77E+03
1 6.00E+03
1 8.64E+03
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+03 4.8E-01 6.8E+00 2.2E+01
7.98E+03 1.1E+00 6.8E+00 2.2E+01 10 100
5.04E+02 1.5E+00 6.8E+00 2.2E+01
1.77E+02 4.9E-01 6.8E+00 2.2E+01
3.83E+02 1.7E+00 6.8E+00 2.2E+01
1.32E+03 5.5E-01 6.8E+00 2.2E+01
7.58E+03 3.2E-01 6.8E+00 2.2E+01
6.33E+03 3.8E-01 6.8E+00 2.2E+01
9.03E+03 5.3E-01 6.8E+00 2.2E+01
4.91 E+03 6.7E-01 6.8E+00 2.2E+01
6.96E+03 9.1E-01 6.8E+00 2.2E+01 10 100
4.97E+02 1.2E+00 6.8E+00 2.2E+01
1.73E+02 2.1E+00 6.8E+00 2.2E+01
4.67E+02 1.2E+00 6.8E+00 2.2E+01
1.34E+03 4.2E-01 6.8E+00 2.2E+01
7.97E+03 1.5E+00 6.8E+00 2.2E+01
4.38E+03 6.5E+01 6.8E+00 2.2E+01
9.00E+03 2.9E-01 6.8E+00 2.2E+01
4.34E+03 1.1E+00 6.8E+00 2.2E+01
7.80E+03 1.1E+00 6.8E+00 2.2E+01 10 100
5.60E+02 9.0E-01 6.8E+00 2.2E+01
1.71 E+02 2.9E+00 6.8E+00 2.2E+01
2.91 E+02 1.9E+00 6.8E+00 2.2E+01
1.33E+03 1.1E+00 6.8E+00 2.2E+01
7.77E+03 1.8E+00 6.8E+00 2.2E+01
6.00E+03 4.4E-01 6.8E+00 2.2E+01
8.64E+03 4.2E-01 6.8E+00 2.2E+01
3.40E+00 5.3E+01 6.8E+00 2.2E+01
3.40E+00 9.1 E+02 6.8E+00 2.2E+01
3.40E+00 5.8E+01 6.8E+00 2.2E+01
3.40E+00 6.1E+01 6.8E+00 2.2E+01
3.40E+00 6.1E+01 6.8E+00 2.2E+01
3.40E+00 6.6E+01 6.8E+00 2.2E+01
3.40E+00 1.2E+01 6.8E+00 2.2E+01
3.40E+00 1.8E+02 6.8E+00 2.2E+01
3.40E+00 4.8E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.82E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.82E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.72E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-770
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li CFS-L07-1313-T01-A
Li CFS-L07-1313-T02-A
Li CFS-L07-1313-T03-A
Li CFS-L07-1313-T04-A
Li CFS-L07-1313-T05-A
Li CFS-L07-1313-T06-A
Li CFS-L07-1313-T07-A
Li CFS-L07-1313-T08-A
Li CFS-L07-1313-T09-A
Li CFS-L07-1313-T01-B
Li CFS-L07-1313-T02-B
Li CFS-L07-1313-T03-B
Li CFS-L07-1313-T04-B
Li CFS-L07-1313-T05-B
Li CFS-L07-1313-T06-B
Li CFS-L07-1313-T07-B
Li CFS-L07-1313-T08-B
Li CFS-L07-1313-T09-B
Li CFS-L07-1313-T01-C
Li CFS-L07-1313-T02-C
Li CFS-L07-1313-T03-C
Li CFS-L07-1313-T04-C
Li CFS-L07-1313-T05-C
Li CFS-L07-1313-T06-C
Li CFS-L07-1313-T07-C
Li CFS-L07-1313-T08-C
Li CFS-L07-1313-T09-C
Li CFS-L07-1313-B01-A
Li CFS-L07-1313-B02-A
Li CFS-L07-1313-B03-A
Li CFS-L07-1313-B01-B
Li CFS-L07-1313-B02-B
Li CFS-L07-1313-B03-B
Li CFS-L07-1313-B01-C
Li CFS-L07-1313-B02-C
Li CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.01E+01
1 2.17E+01
1 2.00E+01
1 2.00E+01
1 2.05E+01
1 2.00E+01
1 2.31E+01
1 1.99E+01
1 5.08E+01
1 2.11E+01
1 2.13E+01
1 2.07E+01
1 1.93E+01
1 1.88E+01
1 2.15E+01
1 2.08E+01
1 2.07E+01
1 4.59E+01
1 2.03E+01
1 2.24E+01
1 2.24E+01
1 2.13E+01
1 1.97E+01
1 1.86E+01
1 2.26E+01
1 1.92E+01
1 4.10E+01
1 6.27E+00
1 7.39E+00
1 5.47E+00 E
1 7.38E+00
1 6.44E+00
1 5.62E+00 E
1 6.74E+00
1 7.31 E+00
1 4.89E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01E+01 6.0E+00 1.9E+00 6.0E+00
2.17E+01 7.5E-01 1.9E+00 6.0E+00 10 100
2.00E+01 2.0E+00 1.9E+00 6.0E+00
2.00E+01 2.8E+00 1.9E+00 6.0E+00
2.05E+01 6.3E+00 1.9E+00 6.0E+00
2.00E+01 6.4E+00 1.9E+00 6.0E+00
2.31 E+01 1.6E+01 1.9E+00 6.0E+00
1.99E+01 2.2E+01 1.9E+00 6.0E+00
5.08E+01 1.7E+01 1.9E+00 6.0E+00
2.11E+01 4.5E+00 1.9E+00 6.0E+00
2.13E+01 3.1E-01 1.9E+00 6.0E+00 10 100
2.07E+01 3.4E+00 1.9E+00 6.0E+00
1.93E+01 9.1 E+00 1.9E+00 6.0E+00
1.88E+01 1.2E+01 1.9E+00 6.0E+00
2.15E+01 9.1 E+00 1.9E+00 6.0E+00
2.08E+01 1.6E+01 1.9E+00 6.0E+00
2.07E+01 2.3E+01 1.9E+00 6.0E+00
4.59E+01 8.8E+00 1.9E+00 6.0E+00
2.03E+01 5.0E-01 1.9E+00 6.0E+00
2.24E+01 2.5E+00 1.9E+00 6.0E+00 10 100
2.24E+01 9.2E+00 1.9E+00 6.0E+00
2.13E+01 4.6E+00 1.9E+00 6.0E+00
1.97E+01 6.9E+00 1.9E+00 6.0E+00
1.86E+01 9.4E+00 1.9E+00 6.0E+00
2.26E+01 1.8E+00 1.9E+00 6.0E+00
1.92E+01 1.1E+01 1.9E+00 6.0E+00
4.10E+01 1.2E+01 1.9E+00 6.0E+00
6.27E+00 1.1E+01 1.9E+00 6.0E+00
7.39E+00 1.3E+01 1.9E+00 6.0E+00
5.47E+00 1.9E+01 1.9E+00 6.0E+00
7.38E+00 6.7E+00 1.9E+00 6.0E+00
6.44E+00 1.7E+01 1.9E+00 6.0E+00
5.62E+00 1.4E+01 1.9E+00 6.0E+00
6.74E+00 8.7E+00 1.9E+00 6.0E+00
7.31 E+00 1.0E+01 1.9E+00 6.0E+00
4.89E+00 6.6E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.82E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.61 E+02 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.96E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-771
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn CFS-L07-1313-T01-A
Mn CFS-L07-1313-T02-A
Mn CFS-L07-1313-T03-A
Mn CFS-L07-1313-T04-A
Mn CFS-L07-1313-T05-A
Mn CFS-L07-1313-T06-A
Mn CFS-L07-1313-T07-A
Mn CFS-L07-1313-T08-A
Mn CFS-L07-1313-T09-A
Mn CFS-L07-1313-T01-B
Mn CFS-L07-1313-T02-B
Mn CFS-L07-1313-T03-B
Mn CFS-L07-1313-T04-B
Mn CFS-L07-1313-T05-B
Mn CFS-L07-1313-T06-B
Mn CFS-L07-1313-T07-B
Mn CFS-L07-1313-T08-B
Mn CFS-L07-1313-T09-B
Mn CFS-L07-1313-T01-C
Mn CFS-L07-1313-T02-C
Mn CFS-L07-1313-T03-C
Mn CFS-L07-1313-T04-C
Mn CFS-L07-1313-T05-C
Mn CFS-L07-1313-T06-C
Mn CFS-L07-1313-T07-C
Mn CFS-L07-1313-T08-C
Mn CFS-L07-1313-T09-C
Mn CFS-L07-1313-B01-A
Mn CFS-L07-1313-B02-A
Mn CFS-L07-1313-B03-A
Mn CFS-L07-1313-B01-B
Mn CFS-L07-1313-B02-B
Mn CFS-L07-1313-B03-B
Mn CFS-L07-1313-B01-C
Mn CFS-L07-1313-B02-C
Mn CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 5.61 E+00 E
1 1.00E+00 U1/2
1 2.40E+00 E
1 2.69E+02
1 1.77E+03
1 1.08E+04
1 2.12E+04
1 3.51 E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.22E+02
1 1.72E+03
1 1.01 E+04
1 1.60E+04
1 3.36E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.32E+02
1 1.67E+03
1 1.02E+04
1 2.17E+04
1 3.39E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.6E+01 2.0E+00 6.4E+00
5.61E+00 1.7E+00 2.0E+00 6.4E+00 10 100
1.00E+00 1.2E+01 2.0E+00 6.4E+00
2.40E+00 6.2E+00 2.0E+00 6.4E+00
2.69E+02 9.5E-01 2.0E+00 6.4E+00
1.77E+03 7.3E-01 2.0E+00 6.4E+00
1.08E+04 4.2E-01 2.0E+00 6.4E+00
2.12E+04 3.3E-01 2.0E+00 6.4E+00
3.51 E+04 5.2E-01 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00 10 100
1.00E+00 9.8E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+00 2.0E+00 6.4E+00
2.22E+02 2.8E-01 2.0E+00 6.4E+00
1.72E+03 9.5E-01 2.0E+00 6.4E+00
1.01 E+04 1.5E+00 2.0E+00 6.4E+00
1.60E+04 6.3E+01 2.0E+00 6.4E+00
3.36E+04 4.7E-01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00 10 100
1.00E+00 6.3E+00 2.0E+00 6.4E+00
1.00E+00 4.0E+00 2.0E+00 6.4E+00
1.32E+02 7.7E-01 2.0E+00 6.4E+00
1.67E+03 7.2E-01 2.0E+00 6.4E+00
1.02E+04 1.4E+00 2.0E+00 6.4E+00
2.17E+04 2.8E-01 2.0E+00 6.4E+00
3.39E+04 1.1 E+00 2.0E+00 6.4E+00
1.00E+00 3.3E+02 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 7.0E+01 2.0E+00 6.4E+00
1.00E+00 5.9E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.2E+03 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-772
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg CFS-L07-1313-T01-A
Mg CFS-L07-1313-T02-A
Mg CFS-L07-1313-T03-A
Mg CFS-L07-1313-T04-A
Mg CFS-L07-1313-T05-A
Mg CFS-L07-1313-T06-A
Mg CFS-L07-1313-T07-A
Mg CFS-L07-1313-T08-A
Mg CFS-L07-1313-T09-A
Mg CFS-L07-1313-T01-B
Mg CFS-L07-1313-T02-B
Mg CFS-L07-1313-T03-B
Mg CFS-L07-1313-T04-B
Mg CFS-L07-1313-T05-B
Mg CFS-L07-1313-T06-B
Mg CFS-L07-1313-T07-B
Mg CFS-L07-1313-T08-B
Mg CFS-L07-1313-T09-B
Mg CFS-L07-1313-T01-C
Mg CFS-L07-1313-T02-C
Mg CFS-L07-1313-T03-C
Mg CFS-L07-1313-T04-C
Mg CFS-L07-1313-T05-C
Mg CFS-L07-1313-T06-C
Mg CFS-L07-1313-T07-C
Mg CFS-L07-1313-T08-C
Mg CFS-L07-1313-T09-C
Mg CFS-L07-1313-B01-A
Mg CFS-L07-1313-B02-A
Mg CFS-L07-1313-B03-A
Mg CFS-L07-1313-B01-B
Mg CFS-L07-1313-B02-B
Mg CFS-L07-1313-B03-B
Mg CFS-L07-1313-B01-C
Mg CFS-L07-1313-B02-C
Mg CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.58E+01
1 8.79E+01
1 1.60E+03
1 3.27E+04
1 7.20E+04
1 6.82E+04
1 8.36E+04
1 1.26E+05
1 2.63E+05
1 2.99E+01
1 2.92E+01
1 1.78E+03
1 2.82E+04
1 6.93E+04
1 6.83E+04
1 8.25E+04
1 9.07E+04
1 2.49E+05
1 2.17E+01
1 4.61 E+01
1 1.67E+03
1 2.90E+04
1 6.73E+04
1 6.88E+04
1 8.12E+04
1 1.27E+05
1 2.29E+05
1 5.00E-01 U1/2
1 3.38E+00
1 6.12E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 3.14E+00 E
1 3.74E+00
1 3.21 E+00
1 1.60E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.58E+01 1.3E+01 1.0E+00 3.2E+00
8.79E+01 9.3E+00 1.0E+00 3.2E+00 1000 100
1.60E+03 1.7E+00 1.0E+00 3.2E+00
3.27E+04 2.6E-01 1.0E+00 3.2E+00
7.20E+04 1.4E+00 1.0E+00 3.2E+00
6.82E+04 4.8E-01 1.0E+00 3.2E+00
8.36E+04 6.5E-01 1.0E+00 3.2E+00
1.26E+05 9.8E-01 1.0E+00 3.2E+00
2.63E+05 3.2E-01 1.0E+00 3.2E+00
2.99E+01 4.0E+01 1.0E+00 3.2E+00
2.92E+01 3.2E+01 1.0E+00 3.2E+00 1000 100
1.78E+03 8.7E-01 1.0E+00 3.2E+00
2.82E+04 1.4E+00 1.0E+00 3.2E+00
6.93E+04 1.4E+00 1.0E+00 3.2E+00
6.83E+04 1.2E+00 1.0E+00 3.2E+00
8.25E+04 1.2E+00 1.0E+00 3.2E+00
9.07E+04 6.3E+01 1.0E+00 3.2E+00
2.49E+05 7.6E-01 1.0E+00 3.2E+00
2.17E+01 2.7E+01 1.0E+00 3.2E+00
4.61E+01 1.5E+01 1.0E+00 3.2E+00 1000 100
1.67E+03 8.8E-01 1.0E+00 3.2E+00
2.90E+04 6.7E-01 1.0E+00 3.2E+00
6.73E+04 2.2E-01 1.0E+00 3.2E+00
6.88E+04 9.9E-01 1.0E+00 3.2E+00
8.12E+04 4.1E+00 1.0E+00 3.2E+00
1.27E+05 9.9E-01 1.0E+00 3.2E+00
2.29E+05 3.0E-01 1.0E+00 3.2E+00
5.00E-01 2.9E+03 1.0E+00 3.2E+00
3.38E+00 1.1E+02 1.0E+00 3.2E+00
6.12E+00 1.6E+02 1.0E+00 3.2E+00
5.00E-01 1.7E+02 1.0E+00 3.2E+00
5.00E-01 2.1E+02 1.0E+00 3.2E+00
3.14E+00 2.4E+02 1.0E+00 3.2E+00
3.74E+00 2.8E+02 1.0E+00 3.2E+00
3.21 E+00 3.6E+02 1.0E+00 3.2E+00
1.60E+00 3.9E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.16E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-773
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo CFS-L07-1313-T01-A
Mo CFS-L07-1313-T02-A
Mo CFS-L07-1313-T03-A
Mo CFS-L07-1313-T04-A
Mo CFS-L07-1313-T05-A
Mo CFS-L07-1313-T06-A
Mo CFS-L07-1313-T07-A
Mo CFS-L07-1313-T08-A
Mo CFS-L07-1313-T09-A
Mo CFS-L07-1313-T01-B
Mo CFS-L07-1313-T02-B
Mo CFS-L07-1313-T03-B
Mo CFS-L07-1313-T04-B
Mo CFS-L07-1313-T05-B
Mo CFS-L07-1313-T06-B
Mo CFS-L07-1313-T07-B
Mo CFS-L07-1313-T08-B
Mo CFS-L07-1313-T09-B
Mo CFS-L07-1313-T01-C
Mo CFS-L07-1313-T02-C
Mo CFS-L07-1313-T03-C
Mo CFS-L07-1313-T04-C
Mo CFS-L07-1313-T05-C
Mo CFS-L07-1313-T06-C
Mo CFS-L07-1313-T07-C
Mo CFS-L07-1313-T08-C
Mo CFS-L07-1313-T09-C
Mo CFS-L07-1313-B01-A
Mo CFS-L07-1313-B02-A
Mo CFS-L07-1313-B03-A
Mo CFS-L07-1313-B01-B
Mo CFS-L07-1313-B02-B
Mo CFS-L07-1313-B03-B
Mo CFS-L07-1313-B01-C
Mo CFS-L07-1313-B02-C
Mo CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.60E+03
1 1.86E+03
1 1.08E+03
1 3.98E+02
1 4.74E+01
1 1.13E+01
1 1.76E+01
1 7.71 E+00
1 9.29E+01
1 1.76E+03
1 1.85E+03
1 1.12E+03
1 4.58E+02
1 5.50E+01
1 9.03E+00
1 1.76E+01
1 8.89E+00
1 9.42E+01
1 1.94E+03
1 1.98E+03
1 1.22E+03
1 4.51 E+02
1 6.83E+01
1 9.52E+00
1 6.57E+00
1 1.52E+01
1 8.73E+01
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 7.60E+00
1 6.00E-01 U1/2
1 1.28E+00 E
1 3.10E+00 E
1 1.48E+00 E
1 1.52E+00 E
1 3.28E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.60E+03 2.8E-01 1.2E+00 3.8E+00
1.86E+03 2.1E-02 1.2E+00 3.8E+00 10 100
1.08E+03 1.1 E+00 1.2E+00 3.8E+00
3.98E+02 6.3E-01 1.2E+00 3.8E+00
4.74E+01 5.5E-01 1.2E+00 3.8E+00
1.13E+01 1.1E+01 1.2E+00 3.8E+00
1.76E+01 7.7E+01 1.2E+00 3.8E+00
7.71 E+00 2.3E+01 1.2E+00 3.8E+00
9.29E+01 1.6E+01 1.2E+00 3.8E+00
1.76E+03 1.7E-01 1.2E+00 3.8E+00
1.85E+03 6.5E-01 1.2E+00 3.8E+00 10 100
1.12E+03 1.1 E+00 1.2E+00 3.8E+00
4.58E+02 9.9E-01 1.2E+00 3.8E+00
5.50E+01 2.8E+00 1.2E+00 3.8E+00
9.03E+00 2.7E+00 1.2E+00 3.8E+00
1.76E+01 6.3E+01 1.2E+00 3.8E+00
8.89E+00 1.3E+02 1.2E+00 3.8E+00
9.42E+01 1.8E+01 1.2E+00 3.8E+00
1.94E+03 7.3E-01 1.2E+00 3.8E+00
1.98E+03 1.4E+00 1.2E+00 3.8E+00 10 100
1.22E+03 6.5E-01 1.2E+00 3.8E+00
4.51 E+02 3.0E-01 1.2E+00 3.8E+00
6.83E+01 1.5E+00 1.2E+00 3.8E+00
9.52E+00 1.0E+01 1.2E+00 3.8E+00
6.57E+00 4.0E+01 1.2E+00 3.8E+00
1.52E+01 1.0E+02 1.2E+00 3.8E+00
8.73E+01 5.3E+00 1.2E+00 3.8E+00
6.00E-01 2.0E+02 1.2E+00 3.8E+00
6.00E-01 3.4E+02 1.2E+00 3.8E+00
7.60E+00 1.8E+01 1.2E+00 3.8E+00
6.00E-01 8.8E+01 1.2E+00 3.8E+00
1.28E+00 5.8E+01 1.2E+00 3.8E+00
3.10E+00 1.8E+01 1.2E+00 3.8E+00
1.48E+00 8.9E+01 1.2E+00 3.8E+00
1.52E+00 7.2E+01 1.2E+00 3.8E+00
3.28E+00 3.6E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.77E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.85E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.89E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-774
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni CFS-L07-1313-T01-A
Ni CFS-L07-1313-T02-A
Ni CFS-L07-1313-T03-A
Ni CFS-L07-1313-T04-A
Ni CFS-L07-1313-T05-A
Ni CFS-L07-1313-T06-A
Ni CFS-L07-1313-T07-A
Ni CFS-L07-1313-T08-A
Ni CFS-L07-1313-T09-A
Ni CFS-L07-1313-T01-B
Ni CFS-L07-1313-T02-B
Ni CFS-L07-1313-T03-B
Ni CFS-L07-1313-T04-B
Ni CFS-L07-1313-T05-B
Ni CFS-L07-1313-T06-B
Ni CFS-L07-1313-T07-B
Ni CFS-L07-1313-T08-B
Ni CFS-L07-1313-T09-B
Ni CFS-L07-1313-T01-C
Ni CFS-L07-1313-T02-C
Ni CFS-L07-1313-T03-C
Ni CFS-L07-1313-T04-C
Ni CFS-L07-1313-T05-C
Ni CFS-L07-1313-T06-C
Ni CFS-L07-1313-T07-C
Ni CFS-L07-1313-T08-C
Ni CFS-L07-1313-T09-C
Ni CFS-L07-1313-B01-A
Ni CFS-L07-1313-B02-A
Ni CFS-L07-1313-B03-A
Ni CFS-L07-1313-B01-B
Ni CFS-L07-1313-B02-B
Ni CFS-L07-1313-B03-B
Ni CFS-L07-1313-B01-C
Ni CFS-L07-1313-B02-C
Ni CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.00E-01 U1/2
1 3.17E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.50E+01
1 2.29E+02
1 3.68E+03
1 6.06E+03
1 6.50E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.24E+01
1 2.16E+02
1 3.50E+03
1 4.97E+03
1 6.51 E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 8.50E+00
1 2.03E+02
1 3.63E+03
1 6.09E+03
1 6.48E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.2E+02 1.8E+00 5.7E+00
3.17E+00 6.1E+01 1.8E+00 5.7E+00 10 100
9.00E-01 8.6E+02 1.8E+00 5.7E+00
9.00E-01 3.7E+02 1.8E+00 5.7E+00
1.50E+01 5.5E+00 1.8E+00 5.7E+00
2.29E+02 8.0E-01 1.8E+00 5.7E+00
3.68E+03 1.9E+00 1.8E+00 5.7E+00
6.06E+03 4.7E-01 1.8E+00 5.7E+00
6.50E+03 5.3E-01 1.8E+00 5.7E+00
9.00E-01 2.5E+02 1.8E+00 5.7E+00
9.00E-01 8.1E+02 1.8E+00 5.7E+00 10 100
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 4.0E+02 1.8E+00 5.7E+00
1.24E+01 1.2E+01 1.8E+00 5.7E+00
2.16E+02 9.6E-02 1.8E+00 5.7E+00
3.50E+03 4.2E+00 1.8E+00 5.7E+00
4.97E+03 6.2E+01 1.8E+00 5.7E+00
6.51 E+03 3.3E-01 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00 10 100
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
8.50E+00 9.9E+00 1.8E+00 5.7E+00
2.03E+02 1.4E+00 1.8E+00 5.7E+00
3.63E+03 3.4E-01 1.8E+00 5.7E+00
6.09E+03 6.2E-01 1.8E+00 5.7E+00
6.48E+03 5.5E-01 1.8E+00 5.7E+00
9.00E-01 3.3E+01 1.8E+00 5.7E+00
9.00E-01 3.2E+02 1.8E+00 5.7E+00
9.00E-01 4.8E+02 1.8E+00 5.7E+00
9.00E-01 5.7E+01 1.8E+00 5.7E+00
9.00E-01 3.9E+01 1.8E+00 5.7E+00
9.00E-01 6.1E+01 1.8E+00 5.7E+00
9.00E-01 1.4E+01 1.8E+00 5.7E+00
9.00E-01 6.2E+02 1.8E+00 5.7E+00
9.00E-01 3.8E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-775
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P CFS-L07-1313-T01-A
P CFS-L07-1313-T02-A
P CFS-L07-1313-T03-A
P CFS-L07-1313-T04-A
P CFS-L07-1313-T05-A
P CFS-L07-1313-T06-A
P CFS-L07-1313-T07-A
P CFS-L07-1313-T08-A
P CFS-L07-1313-T09-A
P CFS-L07-1313-T01-B
P CFS-L07-1313-T02-B
P CFS-L07-1313-T03-B
P CFS-L07-1313-T04-B
P CFS-L07-1313-T05-B
P CFS-L07-1313-T06-B
P CFS-L07-1313-T07-B
P CFS-L07-1313-T08-B
P CFS-L07-1313-T09-B
P CFS-L07-1313-T01-C
P CFS-L07-1313-T02-C
P CFS-L07-1313-T03-C
P CFS-L07-1313-T04-C
P CFS-L07-1313-T05-C
P CFS-L07-1313-T06-C
P CFS-L07-1313-T07-C
P CFS-L07-1313-T08-C
P CFS-L07-1313-T09-C
P CFS-L07-1313-B01-A
P CFS-L07-1313-B02-A
P CFS-L07-1313-B03-A
P CFS-L07-1313-B01-B
P CFS-L07-1313-B02-B
P CFS-L07-1313-B03-B
P CFS-L07-1313-B01-C
P CFS-L07-1313-B02-C
P CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 7.44E+01
1 8.02E+01
1 4.07E+01
1 1.58E+01
1 3.74E+00 E
1 2.15E+01
1 2.38E+01
1 3.74E+01
1 2.26E+03
1 9.98E+01
1 6.65E+01
1 3.77E+01
1 7.77E+00 E
1 7.03E+00 E
1 1.20E+01
1 2.38E+01
1 4.13E+00 E
1 2.49E+03
1 7.81 E+01
1 6.74E+01
1 5.10E+01
1 2.08E+01
1 1.85E+00 U1/2
1 3.10E+01
1 4.84E+01
1 9.46E+00 E
1 2.56E+03
1 1.69E+01
1 1.35E+01
1 4.04E+01
1 7.84E+00 E
1 1.09E+01 E
1 2.70E+01
1 4.61E+OOE
1 2.78E+01
1 1.85E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.44E+01 1.3E+01 3.7E+00 1.2E+01
8.02E+01 1.7E+01 3.7E+00 1.2E+01 1000 100
4.07E+01 2.2E+01 3.7E+00 1.2E+01
1.58E+01 1.1E+02 3.7E+00 1.2E+01
3.74E+00 1.2E+02 3.7E+00 1.2E+01
2.15E+01 9.0E+01 3.7E+00 1.2E+01
2.38E+01 3.8E+01 3.7E+00 1.2E+01
3.74E+01 1.2E+01 3.7E+00 1.2E+01
2.26E+03 5.6E-01 3.7E+00 1.2E+01
9.98E+01 1.5E+01 3.7E+00 1.2E+01
6.65E+01 2.8E+01 3.7E+00 1.2E+01 1000 100
3.77E+01 2.8E+01 3.7E+00 1.2E+01
7.77E+00 1.8E+02 3.7E+00 1.2E+01
7.03E+00 1.3E+02 3.7E+00 1.2E+01
1.20E+01 5.9E+01 3.7E+00 1.2E+01
2.38E+01 4.9E+01 3.7E+00 1.2E+01
4.13E+00 3.2E+02 3.7E+00 1.2E+01
2.49E+03 4.0E-01 3.7E+00 1.2E+01
7.81E+01 2.1E+01 3.7E+00 1.2E+01
6.74E+01 3.7E+01 3.7E+00 1.2E+01 1000 100
5.10E+01 2.2E+01 3.7E+00 1.2E+01
2.08E+01 7.7E+01 3.7E+00 1.2E+01
1.85E+00 2.1E+02 3.7E+00 1.2E+01
3.10E+01 3.1E+01 3.7E+00 1.2E+01
4.84E+01 4.5E+01 3.7E+00 1.2E+01
9.46E+00 1.6E+02 3.7E+00 1.2E+01
2.56E+03 1.4E+00 3.7E+00 1.2E+01
1.69E+01 6.3E+01 3.7E+00 1.2E+01
1.35E+01 1.9E+01 3.7E+00 1.2E+01
4.04E+01 1.2E+01 3.7E+00 1.2E+01
7.84E+00 5.8E+01 3.7E+00 1.2E+01
1.09E+01 5.0E+01 3.7E+00 1.2E+01
2.70E+01 5.0E+01 3.7E+00 1.2E+01
4.61 E+00 1.3E+02 3.7E+00 1.2E+01
2.78E+01 4.4E+01 3.7E+00 1.2E+01
1.85E+01 1.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-776
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L07-1313-T01-A
CFS-L07-1313-T02-A
CFS-L07-1313-T03-A
CFS-L07-1313-T04-A
CFS-L07-1313-T05-A
CFS-L07-1313-T06-A
CFS-L07-1313-T07-A
CFS-L07-1313-T08-A
CFS-L07-1313-T09-A
CFS-L07-1313-T01-B
CFS-L07-1313-T02-B
CFS-L07-1313-T03-B
CFS-L07-1313-T04-B
CFS-L07-1313-T05-B
CFS-L07-1313-T06-B
CFS-L07-1313-T07-B
CFS-L07-1313-T08-B
CFS-L07-1313-T09-B
CFS-L07-1313-T01-C
CFS-L07-1313-T02-C
CFS-L07-1313-T03-C
CFS-L07-1313-T04-C
CFS-L07-1313-T05-C
CFS-L07-1313-T06-C
CFS-L07-1313-T07-C
CFS-L07-1313-T08-C
CFS-L07-1313-T09-C
CFS-L07-1313-B01-A
CFS-L07-1313-B02-A
CFS-L07-1313-B03-A
CFS-L07-1313-B01-B
CFS-L07-1313-B02-B
CFS-L07-1313-B03-B
CFS-L07-1313-B01-C
CFS-L07-1313-B02-C
CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.25E+04
1 1.98E+04
1 1.47E+04
1 1.28E+04
1 1.20E+04
1 9.97E+03
1 1.34E+04
1 1.70E+04
1 2.58E+04
1 3.24E+04
1 2.13E+04
1 1.40E+04
1 1.24E+04
1 1.22E+04
1 9.94E+03
1 1.35E+04
1 1.23E+04
1 2.48E+04
1 3.31 E+04
1 2.05E+04
1 1.46E+04
1 1.24E+04
1 1.19E+04
1 9.84E+03
1 1.34E+04
1 1.69E+04
1 2.49E+04
1 7.08E+00
1 9.89E+00
1 3.60E+02
1 7.50E+00
1 4.97E+00 E
1 2.89E+02
1 4.12E+00 E
1 1.31E+01
1 2.82E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.25E+04 4.9E-01 1.6E+00 5.1E+00
1.98E+04 4.4E-01 1.6E+00 5.1E+00 1000 100
1.47E+04 1.0E+00 1.6E+00 5.1E+00
1.28E+04 7.8E-02 1.6E+00 5.1E+00
1.20E+04 5.8E-01 1.6E+00 5.1E+00
9.97E+03 7.5E-01 1.6E+00 5.1E+00
1.34E+04 5.4E-01 1.6E+00 5.1E+00
1.70E+04 7.4E-01 1.6E+00 5.1E+00
2.58E+04 2.7E-01 1.6E+00 5.1E+00
3.24E+04 8.2E-01 1.6E+00 5.1E+00
2.13E+04 7.2E-01 1.6E+00 5.1E+00 1000 100
1.40E+04 9.5E-01 1.6E+00 5.1E+00
1.24E+04 7.7E-01 1.6E+00 5.1E+00
1.22E+04 4.5E-01 1.6E+00 5.1E+00
9.94E+03 7.0E-01 1.6E+00 5.1E+00
1.35E+04 3.8E-01 1.6E+00 5.1E+00
1.23E+04 7.1E+01 1.6E+00 5.1E+00
2.48E+04 6.5E-01 1.6E+00 5.1E+00
3.31 E+04 1.2E+00 1.6E+00 5.1E+00
2.05E+04 7.0E-01 1.6E+00 5.1E+00 1000 100
1.46E+04 9.1E-01 1.6E+00 5.1E+00
1.24E+04 2.3E-01 1.6E+00 5.1E+00
1.19E+04 6.0E-01 1.6E+00 5.1E+00
9.84E+03 1.6E+00 1.6E+00 5.1E+00
1.34E+04 3.1E+00 1.6E+00 5.1E+00
1.69E+04 4.3E-01 1.6E+00 5.1E+00
2.49E+04 5.5E-01 1.6E+00 5.1E+00
7.08E+00 6.5E+01 1.6E+00 5.1E+00
9.89E+00 2.8E+01 1.6E+00 5.1E+00
3.60E+02 1.3E+00 1.6E+00 5.1E+00
7.50E+00 2.2E+01 1.6E+00 5.1E+00
4.97E+00 4.3E+01 1.6E+00 5.1E+00
2.89E+02 3.8E-01 1.6E+00 5.1E+00
4.12E+00 2.9E+02 1.6E+00 5.1E+00
1.31E+01 1.4E+01 1.6E+00 5.1E+00
2.82E+02 3.2E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.08E+04 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.22E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.15E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-777
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L07-1313-T01-A
CFS-L07-1313-T02-A
CFS-L07-1313-T03-A
CFS-L07-1313-T04-A
CFS-L07-1313-T05-A
CFS-L07-1313-T06-A
CFS-L07-1313-T07-A
CFS-L07-1313-T08-A
CFS-L07-1313-T09-A
CFS-L07-1313-T01-B
CFS-L07-1313-T02-B
CFS-L07-1313-T03-B
CFS-L07-1313-T04-B
CFS-L07-1313-T05-B
CFS-L07-1313-T06-B
CFS-L07-1313-T07-B
CFS-L07-1313-T08-B
CFS-L07-1313-T09-B
CFS-L07-1313-T01-C
CFS-L07-1313-T02-C
CFS-L07-1313-T03-C
CFS-L07-1313-T04-C
CFS-L07-1313-T05-C
CFS-L07-1313-T06-C
CFS-L07-1313-T07-C
CFS-L07-1313-T08-C
CFS-L07-1313-T09-C
CFS-L07-1313-B01-A
CFS-L07-1313-B02-A
CFS-L07-1313-B03-A
CFS-L07-1313-B01-B
CFS-L07-1313-B02-B
CFS-L07-1313-B03-B
CFS-L07-1313-B01-C
CFS-L07-1313-B02-C
CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.81 E+02
1 3.81 E+02
1 4.43E+02
1 1.39E+02
1 1.08E+02
1 6.59E+01
1 1.70E+02
1 2.18E+02
1 3.97E+02
1 5.76E+02
1 4.60E+02
1 4.44E+02
1 1.46E+02
1 7.89E+01
1 6.19E+01
1 1.50E+02
1 1.60E+02
1 4.44E+02
1 5.02E+02
1 4.02E+02
1 5. 11 E+02
1 1.55E+02
1 1.03E+02
1 7.31E+01
1 1.80E+02
1 2.20E+02
1 4.32E+02
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.81 E+02 2.6E+00 1.5E+01 4.8E+01
3.81E+02 3.2E+00 1.5E+01 4.8E+01 10 100
4.43E+02 7.5E-01 1.5E+01 4.8E+01
1.39E+02 6.4E+00 1.5E+01 4.8E+01
1.08E+02 1.3E+00 1.5E+01 4.8E+01
6.59E+01 2.4E+01 1.5E+01 4.8E+01
1.70E+02 1.5E+01 1.5E+01 4.8E+01
2.18E+02 5.1E+00 1.5E+01 4.8E+01
3.97E+02 9.8E-01 1.5E+01 4.8E+01
5.76E+02 1.6E+00 1.5E+01 4.8E+01
4.60E+02 3.1E+00 1.5E+01 4.8E+01 10 100
4.44E+02 8.3E-01 1.5E+01 4.8E+01
1.46E+02 1.4E+01 1.5E+01 4.8E+01
7.89E+01 1.6E+01 1.5E+01 4.8E+01
6.19E+01 2.6E+01 1.5E+01 4.8E+01
1.50E+02 3.2E+00 1.5E+01 4.8E+01
1.60E+02 7.5E+01 1.5E+01 4.8E+01
4.44E+02 1.6E+00 1.5E+01 4.8E+01
5.02E+02 1.2E+00 1.5E+01 4.8E+01
4.02E+02 2.8E+00 1.5E+01 4.8E+01 10 100
5.11E+02 6.4E+00 1.5E+01 4.8E+01
1.55E+02 2.4E+00 1.5E+01 4.8E+01
1.03E+02 2.7E+00 1.5E+01 4.8E+01
7.31E+01 1.3E+01 1.5E+01 4.8E+01
1.80E+02 7.1E+00 1.5E+01 4.8E+01
2.20E+02 1.1E+01 1.5E+01 4.8E+01
4.32E+02 2.1E+00 1.5E+01 4.8E+01
7.50E+00 1.4E+02 1.5E+01 4.8E+01
7.50E+00 6.9E+02 1.5E+01 4.8E+01
7.50E+00 4.5E+02 1.5E+01 4.8E+01
7.50E+00 9.2E+02 1.5E+01 4.8E+01
7.50E+00 4.7E+02 1.5E+01 4.8E+01
7.50E+00 5.4E+02 1.5E+01 4.8E+01
7.50E+00 8.0E+02 1.5E+01 4.8E+01
7.50E+00 2.0E+02 1.5E+01 4.8E+01
7.50E+00 4.4E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.50E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.42E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.50E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-778
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si CFS-L07-1313-T01-A
Si CFS-L07-1313-T02-A
Si CFS-L07-1313-T03-A
Si CFS-L07-1313-T04-A
Si CFS-L07-1313-T05-A
Si CFS-L07-1313-T06-A
Si CFS-L07-1313-T07-A
Si CFS-L07-1313-T08-A
Si CFS-L07-1313-T09-A
Si CFS-L07-1313-T01-B
Si CFS-L07-1313-T02-B
Si CFS-L07-1313-T03-B
Si CFS-L07-1313-T04-B
Si CFS-L07-1313-T05-B
Si CFS-L07-1313-T06-B
Si CFS-L07-1313-T07-B
Si CFS-L07-1313-T08-B
Si CFS-L07-1313-T09-B
Si CFS-L07-1313-T01-C
Si CFS-L07-1313-T02-C
Si CFS-L07-1313-T03-C
Si CFS-L07-1313-T04-C
Si CFS-L07-1313-T05-C
Si CFS-L07-1313-T06-C
Si CFS-L07-1313-T07-C
Si CFS-L07-1313-T08-C
Si CFS-L07-1313-T09-C
Si CFS-L07-1313-B01-A
Si CFS-L07-1313-B02-A
Si CFS-L07-1313-B03-A
Si CFS-L07-1313-B01-B
Si CFS-L07-1313-B02-B
Si CFS-L07-1313-B03-B
Si CFS-L07-1313-B01-C
Si CFS-L07-1313-B02-C
Si CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.77E+02
1 2.92E+02
1 5.29E+02
1 6.67E+02
1 1.71E+03
1 4.17E+03
1 3.81 E+04
1 6.19E+04
1 1.69E+05
1 2.84E+02
1 2.69E+02
1 5.24E+02
1 5.93E+02
1 1.73E+03
1 4.16E+03
1 3.93E+04
1 4.55E+04
1 1.57E+05
1 2.97E+02
1 2.91 E+02
1 5.37E+02
1 5.85E+02
1 1.40E+03
1 3.98E+03
1 3.80E+04
1 6.37E+04
1 1.51E+05
1 5.50E-01 U1/2
1 5.43E+00
1 2.29E+02
1 4.16E+00
1 1.23E+01
1 3.35E+02
1 8.38E+00
1 1.26E+01
1 3.15E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.77E+02 9.9E-01 1.1E+00 3.5E+00
2.92E+02 1.3E+00 1.1E+00 3.5E+00 1000 100
5.29E+02 2.0E+00 1.1E+00 3.5E+00
6.67E+02 5.2E-01 1.1E+00 3.5E+00
1.71E+03 8.9E-01 1.1E+00 3.5E+00
4.17E+03 6.1E-02 1.1E+00 3.5E+00
3.81E+04 1.0E+00 1.1E+00 3.5E+00
6.19E+04 7.3E-01 1.1E+00 3.5E+00
1.69E+05 1.1E+00 1.1E+00 3.5E+00
2.84E+02 1.7E+00 1.1E+00 3.5E+00
2.69E+02 8.6E-01 1.1E+00 3.5E+00 1000 100
5.24E+02 1.6E+00 1.1E+00 3.5E+00
5.93E+02 1.6E+00 1.1E+00 3.5E+00
1.73E+03 4.8E-01 1.1E+00 3.5E+00
4.16E+03 4.7E-01 1.1E+00 3.5E+00
3.93E+04 1.0E+00 1.1E+00 3.5E+00
4.55E+04 5.8E+01 1.1E+00 3.5E+00
1.57E+05 2.3E-01 1.1E+00 3.5E+00
2.97E+02 2.2E+00 1.1E+00 3.5E+00
2.91E+02 2.3E+00 1.1E+00 3.5E+00 1000 100
5.37E+02 1.3E+00 1.1E+00 3.5E+00
5.85E+02 5.7E-01 1.1E+00 3.5E+00
1.40E+03 4.8E-01 1.1E+00 3.5E+00
3.98E+03 2.2E+00 1.1E+00 3.5E+00
3.80E+04 9.5E-01 1.1E+00 3.5E+00
6.37E+04 5.1E-01 1.1E+00 3.5E+00
1.51E+05 4.2E-01 1.1E+00 3.5E+00
5.50E-01 2.3E+01 1.1E+00 3.5E+00
5.43E+00 5.8E+01 1.1E+00 3.5E+00
2.29E+02 2.2E+01 1.1E+00 3.5E+00
4.16E+00 1.3E+02 1.1E+00 3.5E+00
1.23E+01 8.5E+00 1.1E+00 3.5E+00
3.35E+02 7.3E+00 1.1E+00 3.5E+00
8.38E+00 1.6E+02 1.1E+00 3.5E+00
1.26E+01 2.8E+01 1.1E+00 3.5E+00
3.15E+02 9.7E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.25E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-779
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na CFS-L07-1313-T01-A
Na CFS-L07-1313-T02-A
Na CFS-L07-1313-T03-A
Na CFS-L07-1313-T04-A
Na CFS-L07-1313-T05-A
Na CFS-L07-1313-T06-A
Na CFS-L07-1313-T07-A
Na CFS-L07-1313-T08-A
Na CFS-L07-1313-T09-A
Na CFS-L07-1313-T01-B
Na CFS-L07-1313-T02-B
Na CFS-L07-1313-T03-B
Na CFS-L07-1313-T04-B
Na CFS-L07-1313-T05-B
Na CFS-L07-1313-T06-B
Na CFS-L07-1313-T07-B
Na CFS-L07-1313-T08-B
Na CFS-L07-1313-T09-B
Na CFS-L07-1313-T01-C
Na CFS-L07-1313-T02-C
Na CFS-L07-1313-T03-C
Na CFS-L07-1313-T04-C
Na CFS-L07-1313-T05-C
Na CFS-L07-1313-T06-C
Na CFS-L07-1313-T07-C
Na CFS-L07-1313-T08-C
Na CFS-L07-1313-T09-C
Na CFS-L07-1313-B01-A
Na CFS-L07-1313-B02-A
Na CFS-L07-1313-B03-A
Na CFS-L07-1313-B01-B
Na CFS-L07-1313-B02-B
Na CFS-L07-1313-B03-B
Na CFS-L07-1313-B01-C
Na CFS-L07-1313-B02-C
Na CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 6.22E+05
1 4.25E+05
1 2.47E+05
1 1.80E+05
1 1.15E+05
1 2.08E+04
1 2.39E+04
1 2.80E+04
1 3.49E+04
1 6.10E+05
1 4.21 E+05
1 2.48E+05
1 1.84E+05
1 1.16E+05
1 2.08E+04
1 2.43E+04
1 2.13E+04
1 3.34E+04
1 6. 11 E+05
1 4.26E+05
1 2.52E+05
1 1.79E+05
1 1.20E+05
1 2.13E+04
1 2.46E+04
1 2.83E+04
1 3.38E+04
1 1.41E+01
1 9.97E+00
1 6.26E+05
1 1.39E+01
1 9.25E+00
1 6.27E+05
1 1.97E+01
1 1.29E+01
1 6.20E+05
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.22E+05 1.1E-01 2.5E+00 8.0E+00
4.25E+05 5.8E-02 2.5E+00 8.0E+00 1000 100
2.47E+05 4.8E-01 2.5E+00 8.0E+00
1.80E+05 4.5E-01 2.5E+00 8.0E+00
1.15E+05 8.3E-01 2.5E+00 8.0E+00
2.08E+04 1.4E-01 2.5E+00 8.0E+00
2.39E+04 6.9E-01 2.5E+00 8.0E+00
2.80E+04 4.6E-01 2.5E+00 8.0E+00
3.49E+04 1.6E-01 2.5E+00 8.0E+00
6.10E+05 5.8E-01 2.5E+00 8.0E+00
4.21E+05 4.6E-01 2.5E+00 8.0E+00 1000 100
2.48E+05 7.4E-01 2.5E+00 8.0E+00
1.84E+05 1.3E-01 2.5E+00 8.0E+00
1.16E+05 6.9E-01 2.5E+00 8.0E+00
2.08E+04 7.3E-01 2.5E+00 8.0E+00
2.43E+04 1.4E+00 2.5E+00 8.0E+00
2.13E+04 6.1E+01 2.5E+00 8.0E+00
3.34E+04 4.4E-01 2.5E+00 8.0E+00
6.11E+05 4.4E-01 2.5E+00 8.0E+00
4.26E+05 3.3E-01 2.5E+00 8.0E+00 1000 100
2.52E+05 5.9E-01 2.5E+00 8.0E+00
1.79E+05 6.2E-01 2.5E+00 8.0E+00
1.20E+05 7.8E-01 2.5E+00 8.0E+00
2.13E+04 3.9E-01 2.5E+00 8.0E+00
2.46E+04 2.5E+00 2.5E+00 8.0E+00
2.83E+04 4.4E-01 2.5E+00 8.0E+00
3.38E+04 4.3E-01 2.5E+00 8.0E+00
1.41E+01 1.6E+01 2.5E+00 8.0E+00
9.97E+00 1.8E+01 2.5E+00 8.0E+00
6.26E+05 3.9E-01 2.5E+00 8.0E+00
1.39E+01 9.7E+00 2.5E+00 8.0E+00
9.25E+00 2.8E+01 2.5E+00 8.0E+00
6.27E+05 5.2E-01 2.5E+00 8.0E+00
1.97E+01 2.6E+01 2.5E+00 8.0E+00
1.29E+01 8.1E+00 2.5E+00 8.0E+00
6.20E+05 2.0E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.26E+05 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.21 E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.27E+05 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-780
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr CFS-L07-1313-T01-A
Sr CFS-L07-1313-T02-A
Sr CFS-L07-1313-T03-A
Sr CFS-L07-1313-T04-A
Sr CFS-L07-1313-T05-A
Sr CFS-L07-1313-T06-A
Sr CFS-L07-1313-T07-A
Sr CFS-L07-1313-T08-A
Sr CFS-L07-1313-T09-A
Sr CFS-L07-1313-T01-B
Sr CFS-L07-1313-T02-B
Sr CFS-L07-1313-T03-B
Sr CFS-L07-1313-T04-B
Sr CFS-L07-1313-T05-B
Sr CFS-L07-1313-T06-B
Sr CFS-L07-1313-T07-B
Sr CFS-L07-1313-T08-B
Sr CFS-L07-1313-T09-B
Sr CFS-L07-1313-T01-C
Sr CFS-L07-1313-T02-C
Sr CFS-L07-1313-T03-C
Sr CFS-L07-1313-T04-C
Sr CFS-L07-1313-T05-C
Sr CFS-L07-1313-T06-C
Sr CFS-L07-1313-T07-C
Sr CFS-L07-1313-T08-C
Sr CFS-L07-1313-T09-C
Sr CFS-L07-1313-B01-A
Sr CFS-L07-1313-B02-A
Sr CFS-L07-1313-B03-A
Sr CFS-L07-1313-B01-B
Sr CFS-L07-1313-B02-B
Sr CFS-L07-1313-B03-B
Sr CFS-L07-1313-B01-C
Sr CFS-L07-1313-B02-C
Sr CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.15E+03
1 3.56E+03
1 3.95E+03
1 3.54E+03
1 3.75E+03
1 1.52E+03
1 1.09E+03
1 1.28E+03
1 1.43E+03
1 2.10E+03
1 3.52E+03
1 3.88E+03
1 3.62E+03
1 3.87E+03
1 1.54E+03
1 1.05E+03
1 8.13E+02
1 1.32E+03
1 2.50E+03
1 3.74E+03
1 4.28E+03
1 3.51 E+03
1 3.66E+03
1 1.52E+03
1 1.09E+03
1 1.20E+03
1 1.40E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.26E+00 E
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.16E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.15E+03 4.1E-01 1.0E+00 3.2E+00
3.56E+03 1.2E+00 1.0E+00 3.2E+00 1000 100
3.95E+03 6.9E-01 1.0E+00 3.2E+00
3.54E+03 6.0E-01 1.0E+00 3.2E+00
3.75E+03 9.9E-01 1.0E+00 3.2E+00
1.52E+03 2.2E-01 1.0E+00 3.2E+00
1.09E+03 3.7E-01 1.0E+00 3.2E+00
1.28E+03 1.2E+00 1.0E+00 3.2E+00
1.43E+03 1.7E-01 1.0E+00 3.2E+00
2.10E+03 4.9E-01 1.0E+00 3.2E+00
3.52E+03 2.3E-01 1.0E+00 3.2E+00 1000 100
3.88E+03 1.4E+00 1.0E+00 3.2E+00
3.62E+03 7.1E-01 1.0E+00 3.2E+00
3.87E+03 1.2E+00 1.0E+00 3.2E+00
1.54E+03 1.4E-01 1.0E+00 3.2E+00
1.05E+03 1.6E+00 1.0E+00 3.2E+00
8.13E+02 6.8E+01 1.0E+00 3.2E+00
1.32E+03 3.6E-01 1.0E+00 3.2E+00
2.50E+03 9.8E-01 1.0E+00 3.2E+00
3.74E+03 6.9E-01 1.0E+00 3.2E+00 1000 100
4.28E+03 1.0E+00 1.0E+00 3.2E+00
3.51 E+03 1.5E+00 1.0E+00 3.2E+00
3.66E+03 1.7E+00 1.0E+00 3.2E+00
1.52E+03 1.8E+00 1.0E+00 3.2E+00
1.09E+03 3.5E+00 1.0E+00 3.2E+00
1.20E+03 9.0E-01 1.0E+00 3.2E+00
1.40E+03 1.1E+00 1.0E+00 3.2E+00
5.00E-01 7.9E+01 1.0E+00 3.2E+00
5.00E-01 1.8E+02 1.0E+00 3.2E+00
1.26E+00 7.6E+01 1.0E+00 3.2E+00
5.00E-01 6.5E+01 1.0E+00 3.2E+00
5.00E-01 5.7E+01 1.0E+00 3.2E+00
5.00E-01 1.1E+02 1.0E+00 3.2E+00
5.00E-01 8.2E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+02 1.0E+00 3.2E+00
1.16E+00 2.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.55E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.49E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.68E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-781
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S CFS-L07-1313-T01-A
S CFS-L07-1313-T02-A
S CFS-L07-1313-T03-A
S CFS-L07-1313-T04-A
S CFS-L07-1313-T05-A
S CFS-L07-1313-T06-A
S CFS-L07-1313-T07-A
S CFS-L07-1313-T08-A
S CFS-L07-1313-T09-A
S CFS-L07-1313-T01-B
S CFS-L07-1313-T02-B
S CFS-L07-1313-T03-B
S CFS-L07-1313-T04-B
S CFS-L07-1313-T05-B
S CFS-L07-1313-T06-B
S CFS-L07-1313-T07-B
S CFS-L07-1313-T08-B
S CFS-L07-1313-T09-B
S CFS-L07-1313-T01-C
S CFS-L07-1313-T02-C
S CFS-L07-1313-T03-C
S CFS-L07-1313-T04-C
S CFS-L07-1313-T05-C
S CFS-L07-1313-T06-C
S CFS-L07-1313-T07-C
S CFS-L07-1313-T08-C
S CFS-L07-1313-T09-C
S CFS-L07-1313-B01-A
S CFS-L07-1313-B02-A
S CFS-L07-1313-B03-A
S CFS-L07-1313-B01-B
S CFS-L07-1313-B02-B
S CFS-L07-1313-B03-B
S CFS-L07-1313-B01-C
S CFS-L07-1313-B02-C
S CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.43E+06
1 1.11E+06
1 8.03E+05
1 7.24E+05
1 6.91 E+05
1 6.29E+05
1 6.96E+05
1 7.19E+05
1 8.09E+05
1 1.41E+06
1 1.14E+06
1 7.88E+05
1 7. 11 E+05
1 7. 11 E+05
1 6.25E+05
1 6.79E+05
1 5.13E+05
1 8.19E+05
1 1.48E+06
1 1.18E+06
1 8.39E+05
1 7.22E+05
1 7.13E+05
1 6.29E+05
1 6.94E+05
1 7.14E+05
1 8.19E+05
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.58E+01
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 2.63E+01
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.43E+06 1.9E-01 6.8E+00 2.2E+01
1.11E+06 2.1E-01 6.8E+00 2.2E+01 1000 100
8.03E+05 1.4E+00 6.8E+00 2.2E+01
7.24E+05 6.8E-02 6.8E+00 2.2E+01
6.91 E+05 6.8E-01 6.8E+00 2.2E+01
6.29E+05 3.3E-01 6.8E+00 2.2E+01
6.96E+05 6.0E-01 6.8E+00 2.2E+01
7.19E+05 2.4E-01 6.8E+00 2.2E+01
8.09E+05 3.0E-01 6.8E+00 2.2E+01
1.41E+06 3.9E-01 6.8E+00 2.2E+01
1.14E+06 4.0E-01 6.8E+00 2.2E+01 1000 100
7.88E+05 6.9E-01 6.8E+00 2.2E+01
7.11E+05 1.0E+00 6.8E+00 2.2E+01
7.11E+05 5.4E-01 6.8E+00 2.2E+01
6.25E+05 7.0E-01 6.8E+00 2.2E+01
6.79E+05 7.7E-01 6.8E+00 2.2E+01
5.13E+05 6.6E+01 6.8E+00 2.2E+01
8.19E+05 1.4E-01 6.8E+00 2.2E+01
1.48E+06 8.5E-01 6.8E+00 2.2E+01
1.18E+06 6.7E-01 6.8E+00 2.2E+01 1000 100
8.39E+05 8.8E-01 6.8E+00 2.2E+01
7.22E+05 6.3E-02 6.8E+00 2.2E+01
7.13E+05 6.6E-01 6.8E+00 2.2E+01
6.29E+05 1.8E+00 6.8E+00 2.2E+01
6.94E+05 2.0E+00 6.8E+00 2.2E+01
7.14E+05 5.1E-01 6.8E+00 2.2E+01
8.19E+05 5.0E-01 6.8E+00 2.2E+01
3.40E+00 1.3E+01 6.8E+00 2.2E+01
3.40E+00 3.0E+01 6.8E+00 2.2E+01
3.58E+01 5.5E+01 6.8E+00 2.2E+01
3.40E+00 2.8E+01 6.8E+00 2.2E+01
3.40E+00 1.7E+01 6.8E+00 2.2E+01
2.63E+01 3.5E+01 6.8E+00 2.2E+01
3.40E+00 9.7E+01 6.8E+00 2.2E+01
3.40E+00 2.0E+01 6.8E+00 2.2E+01
3.40E+00 6.4E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.11E+06 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+06 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+06 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-782
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample Dilutic
CFS-L07-1313-T01-A
CFS-L07-1313-T02-A
CFS-L07-1313-T03-A
CFS-L07-1313-T04-A
CFS-L07-1313-T05-A
CFS-L07-1313-T06-A
CFS-L07-1313-T07-A
CFS-L07-1313-T08-A
CFS-L07-1313-T09-A
CFS-L07-1313-T01-B
CFS-L07-1313-T02-B
CFS-L07-1313-T03-B
CFS-L07-1313-T04-B
CFS-L07-1313-T05-B
CFS-L07-1313-T06-B
CFS-L07-1313-T07-B
CFS-L07-1313-T08-B
CFS-L07-1313-T09-B
CFS-L07-1313-T01-C
CFS-L07-1313-T02-C
CFS-L07-1313-T03-C
CFS-L07-1313-T04-C
CFS-L07-1313-T05-C
CFS-L07-1313-T06-C
CFS-L07-1313-T07-C
CFS-L07-1313-T08-C
CFS-L07-1313-T09-C
CFS-L07-1313-B01-A
CFS-L07-1313-B02-A
CFS-L07-1313-B03-A
CFS-L07-1313-B01-B
CFS-L07-1313-B02-B
CFS-L07-1313-B03-B
CFS-L07-1313-B01-C
CFS-L07-1313-B02-C
CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.16E+02
1 9.79E+01
1 1.78E+02
1 2.65E+02
1 3.62E+02
1 3.56E+02
1 7.13E+02
1 9.42E+02
1 1.56E+03
1 1.26E+02
1 1.13E+02
1 1.77E+02
1 2.49E+02
1 3.65E+02
1 3.54E+02
1 7.30E+02
1 7.05E+02
1 1.65E+03
1 1.09E+02
1 1.04E+02
1 1.64E+02
1 2.32E+02
1 3.25E+02
1 3.38E+02
1 6.88E+02
1 9.44E+02
1 1.64E+03
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.16E+02 4.1E+00 4.6E+00 1.5E+01
9.79E+01 1.3E+00 4.6E+00 1.5E+01 10 100
1.78E+02 2.7E+00 4.6E+00 1.5E+01
2.65E+02 3.2E+00 4.6E+00 1.5E+01
3.62E+02 1.6E+00 4.6E+00 1.5E+01
3.56E+02 2.4E+00 4.6E+00 1.5E+01
7.13E+02 1.9E+00 4.6E+00 1.5E+01
9.42E+02 4.6E-01 4.6E+00 1.5E+01
1.56E+03 5.8E-01 4.6E+00 1.5E+01
1.26E+02 1.2E+00 4.6E+00 1.5E+01
1.13E+02 4.3E+00 4.6E+00 1.5E+01 10 100
1.77E+02 4.5E+00 4.6E+00 1.5E+01
2.49E+02 2.2E+00 4.6E+00 1.5E+01
3.65E+02 2.7E+00 4.6E+00 1.5E+01
3.54E+02 1.8E+00 4.6E+00 1.5E+01
7.30E+02 6.6E-01 4.6E+00 1.5E+01
7.05E+02 6.7E+01 4.6E+00 1.5E+01
1.65E+03 4.8E-01 4.6E+00 1.5E+01
1.09E+02 3.5E+00 4.6E+00 1.5E+01
1.04E+02 1.2E-01 4.6E+00 1.5E+01 10 100
1.64E+02 3.1E+00 4.6E+00 1.5E+01
2.32E+02 4.1E+00 4.6E+00 1.5E+01
3.25E+02 1.2E+00 4.6E+00 1.5E+01
3.38E+02 2.6E+00 4.6E+00 1.5E+01
6.88E+02 1.8E+00 4.6E+00 1.5E+01
9.44E+02 7.0E-01 4.6E+00 1.5E+01
1.64E+03 5.3E-01 4.6E+00 1.5E+01
2.30E+00 2.8E+00 4.6E+00 1.5E+01
2.30E+00 2.8E+01 4.6E+00 1.5E+01
2.30E+00 2.4E+01 4.6E+00 1.5E+01
2.30E+00 1.6E+01 4.6E+00 1.5E+01
2.30E+00 1.7E+01 4.6E+00 1.5E+01
2.30E+00 4.9E+01 4.6E+00 1.5E+01
2.30E+00 3.8E+01 4.6E+00 1.5E+01
2.30E+00 2.8E+01 4.6E+00 1.5E+01
2.30E+00 5.2E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.08E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-783
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutic
CFS-L07-1313-T01-A
CFS-L07-1313-T02-A
CFS-L07-1313-T03-A
CFS-L07-1313-T04-A
CFS-L07-1313-T05-A
CFS-L07-1313-T06-A
CFS-L07-1313-T07-A
CFS-L07-1313-T08-A
CFS-L07-1313-T09-A
CFS-L07-1313-T01-B
CFS-L07-1313-T02-B
CFS-L07-1313-T03-B
CFS-L07-1313-T04-B
CFS-L07-1313-T05-B
CFS-L07-1313-T06-B
CFS-L07-1313-T07-B
CFS-L07-1313-T08-B
CFS-L07-1313-T09-B
CFS-L07-1313-T01-C
CFS-L07-1313-T02-C
CFS-L07-1313-T03-C
CFS-L07-1313-T04-C
CFS-L07-1313-T05-C
CFS-L07-1313-T06-C
CFS-L07-1313-T07-C
CFS-L07-1313-T08-C
CFS-L07-1313-T09-C
CFS-L07-1313-B01-A
CFS-L07-1313-B02-A
CFS-L07-1313-B03-A
CFS-L07-1313-B01-B
CFS-L07-1313-B02-B
CFS-L07-1313-B03-B
CFS-L07-1313-B01-C
CFS-L07-1313-B02-C
CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.72E+00 E
1 8.93E+00
1 2.28E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 3.31E+OOE
1 7.28E+00
1 2.46E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 3.98E+00 E
1 9.49E+00
1 2.83E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 4.16E+OOE
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00 10 100
1.00E+00 5.5E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+02 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 8.5E+01 2.0E+00 6.4E+00
3.72E+00 4.6E+00 2.0E+00 6.4E+00
8.93E+00 8.0E+00 2.0E+00 6.4E+00
2.28E+01 3.1E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00 10 100
1.00E+00 3.9E+02 2.0E+00 6.4E+00
1.00E+00 2.0E+02 2.0E+00 6.4E+00
1.00E+00 3.3E+02 2.0E+00 6.4E+00
1.00E+00 2.0E+02 2.0E+00 6.4E+00
3.31 E+00 5.5E+00 2.0E+00 6.4E+00
7.28E+00 6.3E+01 2.0E+00 6.4E+00
2.46E+01 1.7E+00 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00 10 100
1.00E+00 8.3E+02 2.0E+00 6.4E+00
1.00E+00 6.1E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 3.5E+02 2.0E+00 6.4E+00
3.98E+00 1.1E+01 2.0E+00 6.4E+00
9.49E+00 3.3E+00 2.0E+00 6.4E+00
2.83E+01 1.5E+00 2.0E+00 6.4E+00
1.00E+00 2.0E+02 2.0E+00 6.4E+00
1.00E+00 6.6E+01 2.0E+00 6.4E+00
4.16E+00 3.3E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 8.6E+01 2.0E+00 6.4E+00
1.00E+00 9.8E+00 2.0E+00 6.4E+00
1.00E+00 8.0E+02 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/1 8/1 1 3:25 P M EPA Interlab L07 1 31 3-1 31 6 CFS
5/1 8/1 1 3:47 P M EPA Interlab L07 1 31 3-1 31 6 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-784
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V CFS-L07-1313-T01-A
V CFS-L07-1313-T02-A
V CFS-L07-1313-T03-A
V CFS-L07-1313-T04-A
V CFS-L07-1313-T05-A
V CFS-L07-1313-T06-A
V CFS-L07-1313-T07-A
V CFS-L07-1313-T08-A
V CFS-L07-1313-T09-A
V CFS-L07-1313-T01-B
V CFS-L07-1313-T02-B
V CFS-L07-1313-T03-B
V CFS-L07-1313-T04-B
V CFS-L07-1313-T05-B
V CFS-L07-1313-T06-B
V CFS-L07-1313-T07-B
V CFS-L07-1313-T08-B
V CFS-L07-1313-T09-B
V CFS-L07-1313-T01-C
V CFS-L07-1313-T02-C
V CFS-L07-1313-T03-C
V CFS-L07-1313-T04-C
V CFS-L07-1313-T05-C
V CFS-L07-1313-T06-C
V CFS-L07-1313-T07-C
V CFS-L07-1313-T08-C
V CFS-L07-1313-T09-C
V CFS-L07-1313-B01-A
V CFS-L07-1313-B02-A
V CFS-L07-1313-B03-A
V CFS-L07-1313-B01-B
V CFS-L07-1313-B02-B
V CFS-L07-1313-B03-B
V CFS-L07-1313-B01-C
V CFS-L07-1313-B02-C
V CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.95E+01
1 3.05E+01
1 3.16E+01
1 3.13E+01
1 3.17E+01
1 3.28E+01
1 4.70E+01
1 5.51 E+01
1 5.59E+02
1 1.82E+01
1 2.99E+01
1 3.13E+01
1 2.96E+01
1 3.28E+01
1 3.32E+01
1 4.57E+01
1 3.70E+01
1 5.36E+02
1 2.26E+01
1 2.86E+01
1 3.15E+01
1 3.17E+01
1 3.19E+01
1 3.33E+01
1 4.66E+01
1 5.35E+01
1 5.04E+02
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.95E+01 6.5E+00 1.5E+00 4.8E+00
3.05E+01 4.6E+00 1.5E+00 4.8E+00 10 100
3.16E+01 1.9E+00 1.5E+00 4.8E+00
3.13E+01 5.1E-01 1.5E+00 4.8E+00
3.17E+01 2.6E+00 1.5E+00 4.8E+00
3.28E+01 6.4E+00 1.5E+00 4.8E+00
4.70E+01 3.3E+00 1.5E+00 4.8E+00
5.51 E+01 2.1E+00 1.5E+00 4.8E+00
5.59E+02 1.0E+00 1.5E+00 4.8E+00
1.82E+01 6.1E+00 1.5E+00 4.8E+00
2.99E+01 4.3E+00 1.5E+00 4.8E+00 10 100
3.13E+01 1.2E+00 1.5E+00 4.8E+00
2.96E+01 6.1E+00 1.5E+00 4.8E+00
3.28E+01 3.2E+00 1.5E+00 4.8E+00
3.32E+01 2.3E+00 1.5E+00 4.8E+00
4.57E+01 2.3E+00 1.5E+00 4.8E+00
3.70E+01 6.0E+01 1.5E+00 4.8E+00
5.36E+02 1.4E+00 1.5E+00 4.8E+00
2.26E+01 9.5E+00 1.5E+00 4.8E+00
2.86E+01 3.5E+00 1.5E+00 4.8E+00 10 100
3.15E+01 3.1E+00 1.5E+00 4.8E+00
3.17E+01 1.9E+00 1.5E+00 4.8E+00
3.19E+01 2.2E+00 1.5E+00 4.8E+00
3.33E+01 3.3E+00 1.5E+00 4.8E+00
4.66E+01 2.7E+00 1.5E+00 4.8E+00
5.35E+01 8.0E+00 1.5E+00 4.8E+00
5.04E+02 2.9E-01 1.5E+00 4.8E+00
7.50E-01 2.7E+02 1.5E+00 4.8E+00
7.50E-01 4.5E+02 1.5E+00 4.8E+00
7.50E-01 9.5E+01 1.5E+00 4.8E+00
7.50E-01 3.0E+02 1.5E+00 4.8E+00
7.50E-01 1.2E+02 1.5E+00 4.8E+00
7.50E-01 2.0E+01 1.5E+00 4.8E+00
7.50E-01 1.8E+02 1.5E+00 4.8E+00
7.50E-01 8.3E+01 1.5E+00 4.8E+00
7.50E-01 1.4E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.13E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 118% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/1 1 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-785
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn CFS-L07-1313-T01-A
Zn CFS-L07-1313-T02-A
Zn CFS-L07-1313-T03-A
Zn CFS-L07-1313-T04-A
Zn CFS-L07-1313-T05-A
Zn CFS-L07-1313-T06-A
Zn CFS-L07-1313-T07-A
Zn CFS-L07-1313-T08-A
Zn CFS-L07-1313-T09-A
Zn CFS-L07-1313-T01-B
Zn CFS-L07-1313-T02-B
Zn CFS-L07-1313-T03-B
Zn CFS-L07-1313-T04-B
Zn CFS-L07-1313-T05-B
Zn CFS-L07-1313-T06-B
Zn CFS-L07-1313-T07-B
Zn CFS-L07-1313-T08-B
Zn CFS-L07-1313-T09-B
Zn CFS-L07-1313-T01-C
Zn CFS-L07-1313-T02-C
Zn CFS-L07-1313-T03-C
Zn CFS-L07-1313-T04-C
Zn CFS-L07-1313-T05-C
Zn CFS-L07-1313-T06-C
Zn CFS-L07-1313-T07-C
Zn CFS-L07-1313-T08-C
Zn CFS-L07-1313-T09-C
Zn CFS-L07-1313-B01-A
Zn CFS-L07-1313-B02-A
Zn CFS-L07-1313-B03-A
Zn CFS-L07-1313-B01-B
Zn CFS-L07-1313-B02-B
Zn CFS-L07-1313-B03-B
Zn CFS-L07-1313-B01-C
Zn CFS-L07-1313-B02-C
Zn CFS-L07-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.79E+03
1 3.14E+03
1 2.64E+01
1 3.06E+01
1 5.51 E+02
1 2.09E+04
1 1.72E+05
1 1.73E+05
1 1.65E+05
1 1.00E+04
1 2.77E+03
1 2.40E+01
1 2.62E+01
1 5.40E+02
1 1.96E+04
1 1.66E+05
1 1.42E+05
1 1.69E+05
1 9.88E+03
1 2.92E+03
1 2.79E+01
1 2.26E+01
1 2.96E+02
1 1.96E+04
1 1.67E+05
1 1.75E+05
1 1.61E+05
1 5.00E-01 U1/2
1 1.29E+00 E
1 6.60E+00
1 3.35E+00
1 1.38E+00 E
1 7.67E+00
1 3.17E+00 E
1 2.36E+00 E
1 8.70E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.79E+03 5.9E-01 1.0E+00 3.2E+00
3.14E+03 3.4E+00 1.0E+00 3.2E+00 10 100
2.64E+01 4.7E+00 1.0E+00 3.2E+00
3.06E+01 9.3E-01 1.0E+00 3.2E+00
5.51 E+02 1.2E+00 1.0E+00 3.2E+00
2.09E+04 9.9E-01 1.0E+00 3.2E+00
1.72E+05 9.5E-01 1.0E+00 3.2E+00
1.73E+05 2.8E+00 1.0E+00 3.2E+00
1.65E+05 2.2E+00 1.0E+00 3.2E+00
1.00E+04 1.4E+00 1.0E+00 3.2E+00
2.77E+03 6.3E-01 1.0E+00 3.2E+00 10 100
2.40E+01 1.3E+00 1.0E+00 3.2E+00
2.62E+01 1.3E+00 1.0E+00 3.2E+00
5.40E+02 1.0E+00 1.0E+00 3.2E+00
1.96E+04 6.5E-01 1.0E+00 3.2E+00
1.66E+05 8.1E-01 1.0E+00 3.2E+00
1.42E+05 4.0E+01 1.0E+00 3.2E+00
1.69E+05 1.5E+00 1.0E+00 3.2E+00
9.88E+03 2.0E+00 1.0E+00 3.2E+00
2.92E+03 5.6E-01 1.0E+00 3.2E+00 10 100
2.79E+01 1.4E+00 1.0E+00 3.2E+00
2.26E+01 2.9E+00 1.0E+00 3.2E+00
2.96E+02 1.7E+00 1.0E+00 3.2E+00
1.96E+04 9.5E-01 1.0E+00 3.2E+00
1.67E+05 5.4E-01 1.0E+00 3.2E+00
1.75E+05 2.9E+00 1.0E+00 3.2E+00
1.61E+05 3.8E-01 1.0E+00 3.2E+00
5.00E-01 7.5E+01 1.0E+00 3.2E+00
1.29E+00 2.1E+01 1.0E+00 3.2E+00
6.60E+00 8.0E+00 1.0E+00 3.2E+00
3.35E+00 8.0E+00 1.0E+00 3.2E+00
1.38E+00 3.7E+01 1.0E+00 3.2E+00
7.67E+00 4.9E+00 1.0E+00 3.2E+00
3.17E+00 8.2E+01 1.0E+00 3.2E+00
2.36E+00 1.0E+01 1.0E+00 3.2E+00
8.70E+00 1.7E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.13E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.77E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.91 E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/18/11 3:27 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:29 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:32 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:34 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:35 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:37 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:39 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:40 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:52 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:53 PM EPA Interlab L07 1313-1316CFS
5/18/11 3:55 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:57 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:58 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:00 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:02 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:03 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:05 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:17 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:18 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:20 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:21 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:23 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:26 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:28 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:30 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:22 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:24 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:25 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:47 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:49 PM EPA Interlab L07 1313-1316 CFS
5/18/11 3:50 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:12 PM EPA Interlab L07 1313-1316CFS
5/18/11 4:13 PM EPA Interlab L07 1313-1316 CFS
5/18/11 4:15 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                          1-786
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample Internal
Sample Dilution Cone. Qualifier Review
I I ug/L I
CFS-L09-1313-T01-A 1 9.59E+01
CFS-L09-1313-T02-A 1 1.11E+02
CFS-L09-1313-T03-A 1 1.16E+02
CFS-L09-1313-T04-A 1 5.49E+01
CFS-L09-1313-T05-A 1 4.51 E+01
CFS-L09-1313-T06-A 1 5.74E+01
CFS-L09-1313-T07-A 1 8.11E+03
CFS-L09-1313-T08-A 1 3.68E+04
CFS-L09-1313-T09-A 1 9.09E+04
CFS-L09-1313-T01-B 1 1.21E+02
CFS-L09-1313-T02-B 1 9.87E+01
CFS-L09-1313-T03-B 1 9.20E+01
CFS-L09-1313-T04-B 1 5.79E+01
CFS-L09-1313-T05-B 1 4.69E+01
CFS-L09-1313-T06-B 1 6.52E+01
CFS-L09-1313-T07-B 1 2.21E+04
CFS-L09-1313-T08-B 1 2.12E+04
CFS-L09-1313-T09-B 1 9.39E+04
CFS-L09-1313-T01-C 1 9.78E+01
CFS-L09-1313-T02-C 1 1.00E+02
CFS-L09-1313-T03-C 1 1.07E+02
CFS-L09-1313-T04-C 1 5.91 E+01
CFS-L09-1313-T05-C 1 4.87E+01
CFS-L09-1313-T06-C 1 5.87E+01
CFS-L09-1313-T07-C 1 2.03E+03
CFS-L09-1313-T08-C 1 3.56E+04
CFS-L09-1313-T09-C 1 9.01 E+04
CFS-L09-1313-B01-A 1 5.00E-01 U1/2
CFS-L09-1313-B02-A 1 9.06E+01
CFS-L09-1313-B03-A 1 3.28E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.59E+01 3.0E+00 1.0E+00 3.2E+00
1.11E+02 2.8E+00 1.0E+00 3.2E+00 1000 100
1.16E+02 2.7E+00 1.0E+00 3.2E+00
5.49E+01 4.7E+00 1.0E+00 3.2E+00
4.51 E+01 6.2E+00 1.0E+00 3.2E+00
5.74E+01 4.3E+00 1.0E+00 3.2E+00
8.11E+03 3.9E-01 1.0E+00 3.2E+00
3.68E+04 9.9E-01 1.0E+00 3.2E+00
9.09E+04 3.3E-01 1.0E+00 3.2E+00
1.21E+02 6.6E-01 1.0E+00 3.2E+00
9.87E+01 1.1E+00 1.0E+00 3.2E+00 1000 100
9.20E+01 3.4E+00 1.0E+00 3.2E+00
5.79E+01 2.5E+00 1.0E+00 3.2E+00
4.69E+01 6.1E+00 1.0E+00 3.2E+00
6.52E+01 2.5E+00 1.0E+00 3.2E+00
2.21 E+04 6.6E-01 1.0E+00 3.2E+00
2.12E+04 7.4E-01 1.0E+00 3.2E+00
9.39E+04 1.2E+00 1.0E+00 3.2E+00
9.78E+01 1.2E+00 1.0E+00 3.2E+00
1.00E+02 1.7E+00 1.0E+00 3.2E+00 1000 100
1.07E+02 1.9E+00 1.0E+00 3.2E+00
5.91 E+01 8.0E+00 1.0E+00 3.2E+00
4.87E+01 6.2E+00 1.0E+00 3.2E+00
5.87E+01 5.4E+00 1.0E+00 3.2E+00
2.03E+03 3.2E-01 1.0E+00 3.2E+00
3.56E+04 9.5E-01 1.0E+00 3.2E+00
9.01 E+04 2.9E-01 1.0E+00 3.2E+00
5.00E-01 1.1E+02 1.0E+00 3.2E+00
9.06E+01 3.6E+00 1.0E+00 3.2E+00
3.28E+00 7.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
1.20E+03 109% VU ICP-OES 4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
VU ICP-OES 4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
1.16E+03 106% VU ICP-OES 4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
VU ICP-OES 4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 4:39 PM EPA Interlab L09 1313-1316CFS
1.16E+03 106% VU ICP-OES 4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
VU ICP-OES 4/19/11 4:42 PM EPA Interlab L09 131 3-1 31 6 CFS
VU ICP-OES 4/19/11 4:44 PM EPA Interlab L09 1313-1316CFS
VU ICP-OES 4/19/11 4:45 PM EPA Interlab L09 1313-1316CFS
VU ICP-OES 4/19/11 4:47 PM EPA Interlab L09 131 3-1 31 6 CFS
VU ICP-OES 4/19/11 5:41 PM EPA Interlab L09 1313-1316CFS
VU ICP-OES 4/19/11 5:43 PM EPA Interlab L09 1313-1316CFS
VU ICP-OES 4/19/11 4:52 PM EPA Interlab L09 131 3-1 31 6 CFS
VU ICP-OES 4/19/11 3:49 PM EPA Interlab L09 1313-1316CFS
VU ICP-OES 4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                                     1-787
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb CFS-L09-1313-T01-A
Sb CFS-L09-1313-T02-A
Sb CFS-L09-1313-T03-A
Sb CFS-L09-1313-T04-A
Sb CFS-L09-1313-T05-A
Sb CFS-L09-1313-T06-A
Sb CFS-L09-1313-T07-A
Sb CFS-L09-1313-T08-A
Sb CFS-L09-1313-T09-A
Sb CFS-L09-1313-T01-B
Sb CFS-L09-1313-T02-B
Sb CFS-L09-1313-T03-B
Sb CFS-L09-1313-T04-B
Sb CFS-L09-1313-T05-B
Sb CFS-L09-1313-T06-B
Sb CFS-L09-1313-T07-B
Sb CFS-L09-1313-T08-B
Sb CFS-L09-1313-T09-B
Sb CFS-L09-1313-T01-C
Sb CFS-L09-1313-T02-C
Sb CFS-L09-1313-T03-C
Sb CFS-L09-1313-T04-C
Sb CFS-L09-1313-T05-C
Sb CFS-L09-1313-T06-C
Sb CFS-L09-1313-T07-C
Sb CFS-L09-1313-T08-C
Sb CFS-L09-1313-T09-C
Sb CFS-L09-1313-B01-A
Sb CFS-L09-1313-B02-A
Sb CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.75E+00 U1/2
1 1.91E+01 E
1 2.83E+01
1 2.98E+01
1 3.34E+01
1 4.32E+01
1 2.36E+02
1 1.07E+03
1 1.56E+03
1 1.79E+01 E
1 3.75E+00 U1/2
1 2.71E+01
1 3.61 E+01
1 2.73E+01
1 4.84E+01
1 6.49E+02
1 6.53E+02
1 1.77E+03
1 1.05E+01 E
1 1.26E+01 E
1 3.32E+01
1 3.96E+01
1 4.67E+01
1 4.50E+01
1 8.24E+01
1 1.11E+03
1 1.79E+03
1 3.75E+00 U1/2
1 7.75E+00 E
1 3.38E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 1.0E+02 7.5E+00 2.4E+01
1.91E+01 4.9E+01 7.5E+00 2.4E+01 10 100
2.83E+01 1.9E+01 7.5E+00 2.4E+01
2.98E+01 1.0E+01 7.5E+00 2.4E+01
3.34E+01 2.4E+01 7.5E+00 2.4E+01
4.32E+01 9.6E+00 7.5E+00 2.4E+01
2.36E+02 3.3E+01 7.5E+00 2.4E+01
1.07E+03 4.0E+00 7.5E+00 2.4E+01
1.56E+03 6.7E+00 7.5E+00 2.4E+01
1.79E+01 4.8E+01 7.5E+00 2.4E+01
3.75E+00 9.2E+01 7.5E+00 2.4E+01 10 100
2.71E+01 3.3E+01 7.5E+00 2.4E+01
3.61E+01 2.2E+01 7.5E+00 2.4E+01
2.73E+01 2.9E+01 7.5E+00 2.4E+01
4.84E+01 8.7E+00 7.5E+00 2.4E+01
6.49E+02 8.1E+00 7.5E+00 2.4E+01
6.53E+02 9.6E+00 7.5E+00 2.4E+01
1.77E+03 4.1E+00 7.5E+00 2.4E+01
1.05E+01 1.1 E+01 7.5E+00 2.4E+01
1.26E+01 8.3E+01 7.5E+00 2.4E+01 10 100
3.32E+01 7.6E+00 7.5E+00 2.4E+01
3.96E+01 2.3E+01 7.5E+00 2.4E+01
4.67E+01 1.1 E+01 7.5E+00 2.4E+01
4.50E+01 1.4E+01 7.5E+00 2.4E+01
8.24E+01 9.1E+00 7.5E+00 2.4E+01
1.11E+03 1.0E+01 7.5E+00 2.4E+01
1.79E+03 4.3E+00 7.5E+00 2.4E+01
3.75E+00 8.3E+01 7.5E+00 2.4E+01
7.75E+00 5.2E+01 7.5E+00 2.4E+01
3.38E+01 4.7E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.02E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-788
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As CFS-L09-1313-T01-A
As CFS-L09-1313-T02-A
As CFS-L09-1313-T03-A
As CFS-L09-1313-T04-A
As CFS-L09-1313-T05-A
As CFS-L09-1313-T06-A
As CFS-L09-1313-T07-A
As CFS-L09-1313-T08-A
As CFS-L09-1313-T09-A
As CFS-L09-1313-T01-B
As CFS-L09-1313-T02-B
As CFS-L09-1313-T03-B
As CFS-L09-1313-T04-B
As CFS-L09-1313-T05-B
As CFS-L09-1313-T06-B
As CFS-L09-1313-T07-B
As CFS-L09-1313-T08-B
As CFS-L09-1313-T09-B
As CFS-L09-1313-T01-C
As CFS-L09-1313-T02-C
As CFS-L09-1313-T03-C
As CFS-L09-1313-T04-C
As CFS-L09-1313-T05-C
As CFS-L09-1313-T06-C
As CFS-L09-1313-T07-C
As CFS-L09-1313-T08-C
As CFS-L09-1313-T09-C
As CFS-L09-1313-B01-A
As CFS-L09-1313-B02-A
As CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.31E+02
1 1.44E+02
1 9.52E+01
1 3.46E+01 E
1 1.14E+01 E
1 2.70E+01 E
1 2.28E+02
1 1.58E+03
1 1.09E+05
1 5.45E+02
1 2.20E+02
1 9.30E+01
1 3.18E+01 E
1 1.12E+01 E
1 3.27E+01 E
1 4.91 E+02
1 5.09E+02
1 1.31E+05
1 1.57E+02
1 2.33E+02
1 7.82E+01
1 3.60E+01
1 3.04E+01 E
1 3.05E+01 E
1 9.35E+01
1 1.34E+03
1 1.40E+05
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 1.52E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.31E+02 7.7E+00 1.1E+01 3.5E+01
1.44E+02 1.0E+01 1.1E+01 3.5E+01 10 100
9.52E+01 1.0E+01 1.1E+01 3.5E+01
3.46E+01 1.9E+01 1.1E+01 3.5E+01
1.14E+01 3.7E+01 1.1E+01 3.5E+01
2.70E+01 1.7E+01 1.1E+01 3.5E+01
2.28E+02 4.6E+00 1.1E+01 3.5E+01
1.58E+03 4.6E-01 1.1E+01 3.5E+01
1.09E+05 1.5E+00 1.1E+01 3.5E+01
5.45E+02 1.3E+00 1.1E+01 3.5E+01
2.20E+02 5.9E+00 1.1E+01 3.5E+01 10 100
9.30E+01 3.1E+00 1.1E+01 3.5E+01
3.18E+01 3.0E+01 1.1E+01 3.5E+01
1.12E+01 4.5E+01 1.1E+01 3.5E+01
3.27E+01 2.1E+01 1.1E+01 3.5E+01
4.91E+02 2.3E+00 1.1E+01 3.5E+01
5.09E+02 2.7E+00 1.1E+01 3.5E+01
1.31E+05 5.6E-01 1.1E+01 3.5E+01
1.57E+02 6.9E+00 1.1E+01 3.5E+01
2.33E+02 2.9E+00 1.1E+01 3.5E+01 10 100
7.82E+01 1.4E+01 1.1E+01 3.5E+01
3.60E+01 2.6E+01 1.1E+01 3.5E+01
3.04E+01 1.0E+01 1.1E+01 3.5E+01
3.05E+01 9.6E+00 1.1E+01 3.5E+01
9.35E+01 5.3E+00 1.1E+01 3.5E+01
1.34E+03 9.2E-01 1.1E+01 3.5E+01
1.40E+05 2.0E-01 1.1E+01 3.5E+01
5.50E+00 9.1E+01 1.1E+01 3.5E+01
5.50E+00 1.4E+02 1.1E+01 3.5E+01
1.52E+01 3.4E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-789
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B CFS-L09-1313-T01-A
B CFS-L09-1313-T02-A
B CFS-L09-1313-T03-A
B CFS-L09-1313-T04-A
B CFS-L09-1313-T05-A
B CFS-L09-1313-T06-A
B CFS-L09-1313-T07-A
B CFS-L09-1313-T08-A
B CFS-L09-1313-T09-A
B CFS-L09-1313-T01-B
B CFS-L09-1313-T02-B
B CFS-L09-1313-T03-B
B CFS-L09-1313-T04-B
B CFS-L09-1313-T05-B
B CFS-L09-1313-T06-B
B CFS-L09-1313-T07-B
B CFS-L09-1313-T08-B
B CFS-L09-1313-T09-B
B CFS-L09-1313-T01-C
B CFS-L09-1313-T02-C
B CFS-L09-1313-T03-C
B CFS-L09-1313-T04-C
B CFS-L09-1313-T05-C
B CFS-L09-1313-T06-C
B CFS-L09-1313-T07-C
B CFS-L09-1313-T08-C
B CFS-L09-1313-T09-C
B CFS-L09-1313-B01-A
B CFS-L09-1313-B02-A
B CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.86E+01
1 8.61 E+01
1 1.49E+02
1 1.22E+02
1 1.49E+02
1 1.97E+02
1 3.91 E+02
1 6.28E+02
1 7.30E+02
1 5.69E+01
1 4.78E+01
1 1.69E+02
1 1.17E+02
1 1.42E+02
1 1.95E+02
1 5.51 E+02
1 5.52E+02
1 7.20E+02
1 6.57E+01
1 5.56E+01
1 1.56E+02
1 1.21 E+02
1 1.61 E+02
1 1.97E+02
1 3.00E+02
1 5.93E+02
1 7.48E+02
1 1.76E+01
1 2.10E+01
1 1.65E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.86E+01 2.8E+00 1.0E+00 3.2E+00
8.61E+01 6.4E-01 1.0E+00 3.2E+00 1000 100
1.49E+02 1.6E+00 1.0E+00 3.2E+00
1.22E+02 1.9E+00 1.0E+00 3.2E+00
1.49E+02 6.3E-01 1.0E+00 3.2E+00
1.97E+02 1.1E+00 1.0E+00 3.2E+00
3.91 E+02 2.9E-01 1.0E+00 3.2E+00
6.28E+02 1.2E+00 1.0E+00 3.2E+00
7.30E+02 1.0E+00 1.0E+00 3.2E+00
5.69E+01 1.3E+00 1.0E+00 3.2E+00
4.78E+01 6.5E-01 1.0E+00 3.2E+00 1000 100
1.69E+02 7.7E-01 1.0E+00 3.2E+00
1.17E+02 7.4E-01 1.0E+00 3.2E+00
1.42E+02 5.5E-01 1.0E+00 3.2E+00
1.95E+02 1.6E+00 1.0E+00 3.2E+00
5.51 E+02 1.6E+00 1.0E+00 3.2E+00
5.52E+02 1.1E+00 1.0E+00 3.2E+00
7.20E+02 2.1E-01 1.0E+00 3.2E+00
6.57E+01 2.6E+00 1.0E+00 3.2E+00
5.56E+01 2.8E+00 1.0E+00 3.2E+00 1000 100
1.56E+02 7.4E-01 1.0E+00 3.2E+00
1.21 E+02 2.0E+00 1.0E+00 3.2E+00
1.61 E+02 2.8E-01 1.0E+00 3.2E+00
1.97E+02 1.5E+00 1.0E+00 3.2E+00
3.00E+02 2.5E-03 1.0E+00 3.2E+00
5.93E+02 1.2E+00 1.0E+00 3.2E+00
7.48E+02 3.4E-01 1.0E+00 3.2E+00
1.76E+01 1.8E+00 1.0E+00 3.2E+00
2.10E+01 4.0E+00 1.0E+00 3.2E+00
1.65E+01 1.1 E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.12E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-790
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba CFS-L09-1313-T01-A
Ba CFS-L09-1313-T02-A
Ba CFS-L09-1313-T03-A
Ba CFS-L09-1313-T04-A
Ba CFS-L09-1313-T05-A
Ba CFS-L09-1313-T06-A
Ba CFS-L09-1313-T07-A
Ba CFS-L09-1313-T08-A
Ba CFS-L09-1313-T09-A
Ba CFS-L09-1313-T01-B
Ba CFS-L09-1313-T02-B
Ba CFS-L09-1313-T03-B
Ba CFS-L09-1313-T04-B
Ba CFS-L09-1313-T05-B
Ba CFS-L09-1313-T06-B
Ba CFS-L09-1313-T07-B
Ba CFS-L09-1313-T08-B
Ba CFS-L09-1313-T09-B
Ba CFS-L09-1313-T01-C
Ba CFS-L09-1313-T02-C
Ba CFS-L09-1313-T03-C
Ba CFS-L09-1313-T04-C
Ba CFS-L09-1313-T05-C
Ba CFS-L09-1313-T06-C
Ba CFS-L09-1313-T07-C
Ba CFS-L09-1313-T08-C
Ba CFS-L09-1313-T09-C
Ba CFS-L09-1313-B01-A
Ba CFS-L09-1313-B02-A
Ba CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.59E+00
1 1.53E+01
1 1.90E+02
1 9.53E+01
1 1.17E+02
1 7.31E+01
1 2.83E+01
1 4.28E+01
1 6.14E+00
1 5.93E+00
1 7.04E+00
1 1.32E+02
1 9.53E+01
1 1.13E+02
1 6.78E+01
1 3.37E+01
1 3.33E+01
1 6.91 E+00
1 7.29E+01
1 6.78E+00
1 1.78E+02
1 1.01E+02
1 1.25E+02
1 7.66E+01
1 4.18E+01
1 4.21E+01
1 7.09E+00
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.59E+00 3.3E+00 1.0E+00 3.2E+00
1.53E+01 7.7E-01 1.0E+00 3.2E+00 10 100
1.90E+02 4.8E-01 1.0E+00 3.2E+00
9.53E+01 7.1E-01 1.0E+00 3.2E+00
1.17E+02 1.1 E+00 1.0E+00 3.2E+00
7.31 E+01 1.5E+00 1.0E+00 3.2E+00
2.83E+01 2.9E-01 1.0E+00 3.2E+00
4.28E+01 1.3E+00 1.0E+00 3.2E+00
6.14E+00 3.2E-01 1.0E+00 3.2E+00
5.93E+00 4.1 E+00 1.0E+00 3.2E+00
7.04E+00 2.5E+00 1.0E+00 3.2E+00 10 100
1.32E+02 3.8E-01 1.0E+00 3.2E+00
9.53E+01 6.8E-01 1.0E+00 3.2E+00
1.13E+02 4.4E-01 1.0E+00 3.2E+00
6.78E+01 2.9E-01 1.0E+00 3.2E+00
3.37E+01 7.7E-01 1.0E+00 3.2E+00
3.33E+01 7.4E-01 1.0E+00 3.2E+00
6.91 E+00 1.4E+00 1.0E+00 3.2E+00
7.29E+01 3.1E-01 1.0E+00 3.2E+00
6.78E+00 9.2E+00 1.0E+00 3.2E+00 10 100
1.78E+02 2.9E-01 1.0E+00 3.2E+00
1.01E+02 3.2E-01 1.0E+00 3.2E+00
1.25E+02 1.1 E+00 1.0E+00 3.2E+00
7.66E+01 6.1E-01 1.0E+00 3.2E+00
4.18E+01 3.6E-01 1.0E+00 3.2E+00
4.21 E+01 9.1E-01 1.0E+00 3.2E+00
7.09E+00 3.9E-01 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
5.00E-01 2.0E+00 1.0E+00 3.2E+00
5.00E-01 1.8E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.10E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.94E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/17/11 11:03 AM EPA Interlab 1313-1316 CFS Reruns
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
6/17/11 11:24 AM EPA Interlab 1313-1316 CFS Reruns
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
6/17/11 11:45 AM EPA Interlab 1313-1316 CFS Reruns
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316CFS
                                                                                                                                                                          1-791
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be CFS-L09-1313-T01-A
Be CFS-L09-1313-T02-A
Be CFS-L09-1313-T03-A
Be CFS-L09-1313-T04-A
Be CFS-L09-1313-T05-A
Be CFS-L09-1313-T06-A
Be CFS-L09-1313-T07-A
Be CFS-L09-1313-T08-A
Be CFS-L09-1313-T09-A
Be CFS-L09-1313-T01-B
Be CFS-L09-1313-T02-B
Be CFS-L09-1313-T03-B
Be CFS-L09-1313-T04-B
Be CFS-L09-1313-T05-B
Be CFS-L09-1313-T06-B
Be CFS-L09-1313-T07-B
Be CFS-L09-1313-T08-B
Be CFS-L09-1313-T09-B
Be CFS-L09-1313-T01-C
Be CFS-L09-1313-T02-C
Be CFS-L09-1313-T03-C
Be CFS-L09-1313-T04-C
Be CFS-L09-1313-T05-C
Be CFS-L09-1313-T06-C
Be CFS-L09-1313-T07-C
Be CFS-L09-1313-T08-C
Be CFS-L09-1313-T09-C
Be CFS-L09-1313-B01-A
Be CFS-L09-1313-B02-A
Be CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 3.79E+00 E
1 6.79E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 5.86E+00 E
1 5.65E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.11E+OOE
1 6.25E+00
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.7E+01 1.9E+00 6.0E+00
9.50E-01 6.8E+01 1.9E+00 6.0E+00 10 100
9.50E-01 4.5E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 3.5E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
3.79E+00 5.3E-01 1.9E+00 6.0E+00
6.79E+00 7.0E+00 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00
9.50E-01 1.0E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00 10 100
9.50E-01 6.1E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 4.1E+01 1.9E+00 6.0E+00
5.86E+00 6.4E+00 1.9E+00 6.0E+00
5.65E+00 4.0E+00 1.9E+00 6.0E+00
9.50E-01 6.5E+00 1.9E+00 6.0E+00
9.50E-01 5.3E+01 1.9E+00 6.0E+00
9.50E-01 5.5E+01 1.9E+00 6.0E+00 10 100
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 4.3E+01 1.9E+00 6.0E+00
9.50E-01 9.3E+00 1.9E+00 6.0E+00
2.11E+00 2.9E+00 1.9E+00 6.0E+00
6.25E+00 6.6E+00 1.9E+00 6.0E+00
9.50E-01 5.0E+00 1.9E+00 6.0E+00
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-792
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd CFS-L09-1313-T01-A
Cd CFS-L09-1313-T02-A
Cd CFS-L09-1313-T03-A
Cd CFS-L09-1313-T04-A
Cd CFS-L09-1313-T05-A
Cd CFS-L09-1313-T06-A
Cd CFS-L09-1313-T07-A
Cd CFS-L09-1313-T08-A
Cd CFS-L09-1313-T09-A
Cd CFS-L09-1313-T01-B
Cd CFS-L09-1313-T02-B
Cd CFS-L09-1313-T03-B
Cd CFS-L09-1313-T04-B
Cd CFS-L09-1313-T05-B
Cd CFS-L09-1313-T06-B
Cd CFS-L09-1313-T07-B
Cd CFS-L09-1313-T08-B
Cd CFS-L09-1313-T09-B
Cd CFS-L09-1313-T01-C
Cd CFS-L09-1313-T02-C
Cd CFS-L09-1313-T03-C
Cd CFS-L09-1313-T04-C
Cd CFS-L09-1313-T05-C
Cd CFS-L09-1313-T06-C
Cd CFS-L09-1313-T07-C
Cd CFS-L09-1313-T08-C
Cd CFS-L09-1313-T09-C
Cd CFS-L09-1313-B01-A
Cd CFS-L09-1313-B02-A
Cd CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.06E+01
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 5.00E+01
1 4.42E+03
1 9.83E+03
1 3.01 E+04
1 4.57E+04
1 4.31 E+04
1 1.63E+01
1 1.06E+01
1 1.10E+00 U1/2
1 4.77E+01
1 3.98E+03
1 1.00E+04
1 4.14E+04
1 4.19E+04
1 4.50E+04
1 4.13E+00 E
1 1.21E+01
1 2.29E+00 E
1 4.33E+01
1 4.76E+03
1 1.00E+04
1 2.07E+04
1 4.30E+04
1 4.17E+04
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+01 3.3E+00 2.2E+00 7.0E+00
1.10E+00 1.7E+01 2.2E+00 7.0E+00 10 100
1.10E+00 1.6E+01 2.2E+00 7.0E+00
5.00E+01 4.2E-01 2.2E+00 7.0E+00
4.42E+03 7.1E-01 2.2E+00 7.0E+00
9.83E+03 6.0E-01 2.2E+00 7.0E+00
3.01 E+04 3.9E-01 2.2E+00 7.0E+00
4.57E+04 7.8E-01 2.2E+00 7.0E+00
4.31 E+04 1.0E+00 2.2E+00 7.0E+00
1.63E+01 1.7E+00 2.2E+00 7.0E+00
1.06E+01 2.4E+00 2.2E+00 7.0E+00 10 100
1.10E+00 8.2E+00 2.2E+00 7.0E+00
4.77E+01 9.0E-01 2.2E+00 7.0E+00
3.98E+03 4.4E-02 2.2E+00 7.0E+00
1.00E+04 6.2E-01 2.2E+00 7.0E+00
4.14E+04 2.0E+00 2.2E+00 7.0E+00
4.19E+04 4.6E-01 2.2E+00 7.0E+00
4.50E+04 1.0E+00 2.2E+00 7.0E+00
4.13E+00 9.9E+00 2.2E+00 7.0E+00
1.21E+01 2.7E+00 2.2E+00 7.0E+00 10 100
2.29E+00 1.6E+00 2.2E+00 7.0E+00
4.33E+01 1.7E+00 2.2E+00 7.0E+00
4.76E+03 5.4E-01 2.2E+00 7.0E+00
1.00E+04 5.2E-01 2.2E+00 7.0E+00
2.07E+04 4.4E-01 2.2E+00 7.0E+00
4.30E+04 7.6E-01 2.2E+00 7.0E+00
4.17E+04 4.1E-01 2.2E+00 7.0E+00
1.10E+00 8.2E+01 2.2E+00 7.0E+00
1.10E+00 3.1E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.64E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 131 3-1 31 6 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-793
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
CFS-L09-1313-T01-A
CFS-L09-1313-T02-A
CFS-L09-1313-T03-A
CFS-L09-1313-T04-A
CFS-L09-1313-T05-A
CFS-L09-1313-T06-A
CFS-L09-1313-T07-A
CFS-L09-1313-T08-A
CFS-L09-1313-T09-A
CFS-L09-1313-T01-B
CFS-L09-1313-T02-B
CFS-L09-1313-T03-B
CFS-L09-1313-T04-B
CFS-L09-1313-T05-B
CFS-L09-1313-T06-B
CFS-L09-1313-T07-B
CFS-L09-1313-T08-B
CFS-L09-1313-T09-B
CFS-L09-1313-T01-C
CFS-L09-1313-T02-C
CFS-L09-1313-T03-C
CFS-L09-1313-T04-C
CFS-L09-1313-T05-C
CFS-L09-1313-T06-C
CFS-L09-1313-T07-C
CFS-L09-1313-T08-C
CFS-L09-1313-T09-C
CFS-L09-1313-B01-A
CFS-L09-1313-B02-A
CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.08E+05
1 5.55E+05
1 5.44E+05
1 6.28E+05
1 6.74E+05
1 7.21 E+05
1 9.52E+05
1 1.25E+06
1 1.61E+06
1 2.96E+05
1 5.15E+05
1 5.80E+05
1 6.30E+05
1 6.33E+05
1 7.32E+05
1 1.12E+06
1 1.12E+06
1 1.61E+06
1 3.03E+05
1 5.21 E+05
1 6.07E+05
1 6.32E+05
1 6.83E+05
1 7.27E+05
1 8.51 E+05
1 1.21E+06
1 1.53E+06
1 3.07E+01
1 9.20E+01
1 4.04E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.08E+05 9.6E-01 2.6E+00 8.3E+00
5.55E+05 2.8E-01 2.6E+00 8.3E+00 1000 100
5.44E+05 3.5E-01 2.6E+00 8.3E+00
6.28E+05 9.0E-01 2.6E+00 8.3E+00
6.74E+05 7.4E-01 2.6E+00 8.3E+00
7.21 E+05 7.4E-01 2.6E+00 8.3E+00
9.52E+05 5.5E-01 2.6E+00 8.3E+00
1.25E+06 9.0E-01 2.6E+00 8.3E+00
1.61E+06 4.1E-01 2.6E+00 8.3E+00
2.96E+05 3.5E-01 2.6E+00 8.3E+00
5.15E+05 2.8E-01 2.6E+00 8.3E+00 1000 100
5.80E+05 2.0E-01 2.6E+00 8.3E+00
6.30E+05 3.4E-01 2.6E+00 8.3E+00
6.33E+05 3.2E-01 2.6E+00 8.3E+00
7.32E+05 7.4E-01 2.6E+00 8.3E+00
1.12E+06 4.4E-01 2.6E+00 8.3E+00
1.12E+06 6.5E-01 2.6E+00 8.3E+00
1.61E+06 4.1E-01 2.6E+00 8.3E+00
3.03E+05 8.4E-01 2.6E+00 8.3E+00
5.21E+05 1.4E+00 2.6E+00 8.3E+00 1000 100
6.07E+05 9.2E-01 2.6E+00 8.3E+00
6.32E+05 7.9E-01 2.6E+00 8.3E+00
6.83E+05 5.4E-01 2.6E+00 8.3E+00
7.27E+05 7.7E-01 2.6E+00 8.3E+00
8.51 E+05 3.8E-01 2.6E+00 8.3E+00
1.21E+06 2.9E-01 2.6E+00 8.3E+00
1.53E+06 6.8E-01 2.6E+00 8.3E+00
3.07E+01 6.9E+00 2.6E+00 8.3E+00
9.20E+01 1.2E+01 2.6E+00 8.3E+00
4.04E+01 6.7E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.55E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.16E+05 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.22E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-794
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr CFS-L09-1313-T01-A
Cr CFS-L09-1313-T02-A
Cr CFS-L09-1313-T03-A
Cr CFS-L09-1313-T04-A
Cr CFS-L09-1313-T05-A
Cr CFS-L09-1313-T06-A
Cr CFS-L09-1313-T07-A
Cr CFS-L09-1313-T08-A
Cr CFS-L09-1313-T09-A
Cr CFS-L09-1313-T01-B
Cr CFS-L09-1313-T02-B
Cr CFS-L09-1313-T03-B
Cr CFS-L09-1313-T04-B
Cr CFS-L09-1313-T05-B
Cr CFS-L09-1313-T06-B
Cr CFS-L09-1313-T07-B
Cr CFS-L09-1313-T08-B
Cr CFS-L09-1313-T09-B
Cr CFS-L09-1313-T01-C
Cr CFS-L09-1313-T02-C
Cr CFS-L09-1313-T03-C
Cr CFS-L09-1313-T04-C
Cr CFS-L09-1313-T05-C
Cr CFS-L09-1313-T06-C
Cr CFS-L09-1313-T07-C
Cr CFS-L09-1313-T08-C
Cr CFS-L09-1313-T09-C
Cr CFS-L09-1313-B01-A
Cr CFS-L09-1313-B02-A
Cr CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.11E+02
1 4.41 E+01
1 6.41 E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.78E+01
1 2.35E+03
1 1.45E+02
1 1.34E+02
1 8.04E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.60E+01
1 1.52E+01
1 2.25E+03
1 4.27E+01
1 1.37E+02
1 5. 71 E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 7.47E+01
1 2.18E+03
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.11E+02 1.1E+00 1.2E+00 3.8E+00
4.41E+01 9.4E-01 1.2E+00 3.8E+00 10 100
6.41 E+00 3.9E+00 1.2E+00 3.8E+00
6.00E-01 7.7E+01 1.2E+00 3.8E+00
6.00E-01 1.7E+03 1.2E+00 3.8E+00
6.00E-01 2.6E+03 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.78E+01 1.2E+00 1.2E+00 3.8E+00
2.35E+03 8.2E-02 1.2E+00 3.8E+00
1.45E+02 3.2E-01 1.2E+00 3.8E+00
1.34E+02 1.3E-01 1.2E+00 3.8E+00 10 100
8.04E+00 6.0E+00 1.2E+00 3.8E+00
6.00E-01 7.2E+01 1.2E+00 3.8E+00
6.00E-01 2.3E+02 1.2E+00 3.8E+00
6.00E-01 3.1E+02 1.2E+00 3.8E+00
1.60E+01 3.4E+00 1.2E+00 3.8E+00
1.52E+01 5.1E+00 1.2E+00 3.8E+00
2.25E+03 7.8E-01 1.2E+00 3.8E+00
4.27E+01 3.0E+00 1.2E+00 3.8E+00
1.37E+02 2.2E+00 1.2E+00 3.8E+00 10 100
5.71 E+00 1.2E+01 1.2E+00 3.8E+00
6.00E-01 5.5E+01 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.00E-01 1.4E+03 1.2E+00 3.8E+00
6.00E-01 2.3E+01 1.2E+00 3.8E+00
7.47E+01 1.2E+00 1.2E+00 3.8E+00
2.18E+03 3.8E-01 1.2E+00 3.8E+00
6.00E-01 5.7E+02 1.2E+00 3.8E+00
6.00E-01 3.9E+01 1.2E+00 3.8E+00
6.00E-01 7.8E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.05E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-795
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
CFS-L09-1313-T01-A
CFS-L09-1313-T02-A
CFS-L09-1313-T03-A
CFS-L09-1313-T04-A
CFS-L09-1313-T05-A
CFS-L09-1313-T06-A
CFS-L09-1313-T07-A
CFS-L09-1313-T08-A
CFS-L09-1313-T09-A
CFS-L09-1313-T01-B
CFS-L09-1313-T02-B
CFS-L09-1313-T03-B
CFS-L09-1313-T04-B
CFS-L09-1313-T05-B
CFS-L09-1313-T06-B
CFS-L09-1313-T07-B
CFS-L09-1313-T08-B
CFS-L09-1313-T09-B
CFS-L09-1313-T01-C
CFS-L09-1313-T02-C
CFS-L09-1313-T03-C
CFS-L09-1313-T04-C
CFS-L09-1313-T05-C
CFS-L09-1313-T06-C
CFS-L09-1313-T07-C
CFS-L09-1313-T08-C
CFS-L09-1313-T09-C
CFS-L09-1313-B01-A
CFS-L09-1313-B02-A
CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.60E+01
1 2.10E+02
1 8.74E+02
1 1.56E+03
1 1.67E+03
1 9.00E-01 U1/2
1 2.13E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 8.49E+01
1 2.09E+02
1 1.38E+03
1 1.40E+03
1 1.69E+03
1 2.34E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.08E+02
1 2.11E+02
1 4.68E+02
1 1.47E+03
1 1.59E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 7.9E+01 1.8E+00 5.7E+00 10 100
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.60E+01 1.8E+00 1.8E+00 5.7E+00
2.10E+02 7.5E-01 1.8E+00 5.7E+00
8.74E+02 2.5E-01 1.8E+00 5.7E+00
1.56E+03 2.4E+00 1.8E+00 5.7E+00
1.67E+03 1.2E+00 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
2.13E+00 2.9E+01 1.8E+00 5.7E+00 10 100
9.00E-01 3.4E+01 1.8E+00 5.7E+00
9.00E-01 3.7E+01 1.8E+00 5.7E+00
8.49E+01 6.0E-01 1.8E+00 5.7E+00
2.09E+02 2.5E+00 1.8E+00 5.7E+00
1.38E+03 4.7E-01 1.8E+00 5.7E+00
1.40E+03 8.1E-01 1.8E+00 5.7E+00
1.69E+03 1.1E+00 1.8E+00 5.7E+00
2.34E+00 1.3E+01 1.8E+00 5.7E+00
9.00E-01 3.1E+01 1.8E+00 5.7E+00 10 100
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 8.0E+01 1.8E+00 5.7E+00
1.08E+02 2.1E+00 1.8E+00 5.7E+00
2.11E+02 6.9E-01 1.8E+00 5.7E+00
4.68E+02 7.6E-02 1.8E+00 5.7E+00
1.47E+03 2.0E+00 1.8E+00 5.7E+00
1.59E+03 2.1E+00 1.8E+00 5.7E+00
9.00E-01 7.1E+01 1.8E+00 5.7E+00
9.00E-01 2.9E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.82E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.24E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/1 1 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 131 3-1 31 6 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-796
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu CFS-L09-1313-T01-A
Cu CFS-L09-1313-T02-A
Cu CFS-L09-1313-T03-A
Cu CFS-L09-1313-T04-A
Cu CFS-L09-1313-T05-A
Cu CFS-L09-1313-T06-A
Cu CFS-L09-1313-T07-A
Cu CFS-L09-1313-T08-A
Cu CFS-L09-1313-T09-A
Cu CFS-L09-1313-T01-B
Cu CFS-L09-1313-T02-B
Cu CFS-L09-1313-T03-B
Cu CFS-L09-1313-T04-B
Cu CFS-L09-1313-T05-B
Cu CFS-L09-1313-T06-B
Cu CFS-L09-1313-T07-B
Cu CFS-L09-1313-T08-B
Cu CFS-L09-1313-T09-B
Cu CFS-L09-1313-T01-C
Cu CFS-L09-1313-T02-C
Cu CFS-L09-1313-T03-C
Cu CFS-L09-1313-T04-C
Cu CFS-L09-1313-T05-C
Cu CFS-L09-1313-T06-C
Cu CFS-L09-1313-T07-C
Cu CFS-L09-1313-T08-C
Cu CFS-L09-1313-T09-C
Cu CFS-L09-1313-B01-A
Cu CFS-L09-1313-B02-A
Cu CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 7.19E+03
1 6.45E+02
1 1.35E+02
1 4.94E+01
1 8.24E+02
1 7.68E+03
1 3.98E+05
1 8.81 E+05
1 1.00E+06
1 1.17E+04
1 6.99E+03
1 2.20E+02
1 5.30E+01
1 6.71 E+02
1 8.32E+03
1 7.81 E+05
1 7.78E+05
1 1.00E+06
1 4.23E+03
1 7.34E+03
1 1.29E+02
1 5.70E+01
1 9.78E+02
1 7.46E+03
1 1.21 E+05
1 8.44E+05
1 9.45E+05
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.19E+03 1.7E+00 3.7E+00 1.2E+01
6.45E+02 8.4E-01 3.7E+00 1.2E+01 10 100
1.35E+02 2.9E-01 3.7E+00 1.2E+01
4.94E+01 1.6E+00 3.7E+00 1.2E+01
8.24E+02 4.6E-01 3.7E+00 1.2E+01
7.68E+03 4.2E-01 3.7E+00 1.2E+01
3.98E+05 1.1E+00 3.7E+00 1.2E+01
8.81 E+05 1.0E+00 3.7E+00 1.2E+01
1.00E+06 7.7E-01 3.7E+00 1.2E+01
1.17E+04 2.0E+00 3.7E+00 1.2E+01
6.99E+03 1.0E+00 3.7E+00 1.2E+01 10 100
2.20E+02 1.9E+00 3.7E+00 1.2E+01
5.30E+01 3.8E+00 3.7E+00 1.2E+01
6.71 E+02 2.6E-01 3.7E+00 1.2E+01
8.32E+03 1.8E+00 3.7E+00 1.2E+01
7.81 E+05 9.1E-02 3.7E+00 1.2E+01
7.78E+05 1.2E+00 3.7E+00 1.2E+01
1.00E+06 8.5E-01 3.7E+00 1.2E+01
4.23E+03 3.8E-01 3.7E+00 1.2E+01
7.34E+03 2.3E+00 3.7E+00 1.2E+01 10 100
1.29E+02 2.9E+00 3.7E+00 1.2E+01
5.70E+01 1.3E+00 3.7E+00 1.2E+01
9.78E+02 1.2E+00 3.7E+00 1.2E+01
7.46E+03 1.1E+00 3.7E+00 1.2E+01
1.21 E+05 7.3E-01 3.7E+00 1.2E+01
8.44E+05 1.2E+00 3.7E+00 1.2E+01
9.45E+05 1.5E+00 3.7E+00 1.2E+01
1.85E+00 1.7E+02 3.7E+00 1.2E+01
1.85E+00 4.1E+01 3.7E+00 1.2E+01
1.85E+00 3.2E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.61E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.87E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.30E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-797
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe CFS-L09-1313-T01-A
Fe CFS-L09-1313-T02-A
Fe CFS-L09-1313-T03-A
Fe CFS-L09-1313-T04-A
Fe CFS-L09-1313-T05-A
Fe CFS-L09-1313-T06-A
Fe CFS-L09-1313-T07-A
Fe CFS-L09-1313-T08-A
Fe CFS-L09-1313-T09-A
Fe CFS-L09-1313-T01-B
Fe CFS-L09-1313-T02-B
Fe CFS-L09-1313-T03-B
Fe CFS-L09-1313-T04-B
Fe CFS-L09-1313-T05-B
Fe CFS-L09-1313-T06-B
Fe CFS-L09-1313-T07-B
Fe CFS-L09-1313-T08-B
Fe CFS-L09-1313-T09-B
Fe CFS-L09-1313-T01-C
Fe CFS-L09-1313-T02-C
Fe CFS-L09-1313-T03-C
Fe CFS-L09-1313-T04-C
Fe CFS-L09-1313-T05-C
Fe CFS-L09-1313-T06-C
Fe CFS-L09-1313-T07-C
Fe CFS-L09-1313-T08-C
Fe CFS-L09-1313-T09-C
Fe CFS-L09-1313-B01-A
Fe CFS-L09-1313-B02-A
Fe CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 8.27E+00
1 5.60E+04
1 3.15E+05
1 2.23E+00 E
1 1.38E+02
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.58E+00 E
1 1.00E+00 U1/2
1 7.29E+03
1 6.45E+03
1 3.28E+05
1 8.13E+00
1 2.45E+00 E
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 3.81E+OOE
1 4.70E+04
1 3.43E+05
1 1.00E+OOU1/2
1 4.71E+01
1 4.63E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 5.7E+01 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
8.27E+00 7.7E+00 2.0E+00 6.4E+00
5.60E+04 4.4E-01 2.0E+00 6.4E+00
3.15E+05 3.1E+00 2.0E+00 6.4E+00
2.23E+00 2.1E+01 2.0E+00 6.4E+00
1.38E+02 2.2E-01 2.0E+00 6.4E+00 1000 100
1.00E+00 4.7E+01 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00
3.58E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
7.29E+03 6.1E-01 2.0E+00 6.4E+00
6.45E+03 5.5E-01 2.0E+00 6.4E+00
3.28E+05 3.3E+00 2.0E+00 6.4E+00
8.13E+00 1.1E+01 2.0E+00 6.4E+00
2.45E+00 2.2E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+00 2.0E+00 6.4E+00
1.00E+00 7.8E+01 2.0E+00 6.4E+00
3.81 E+00 7.6E+00 2.0E+00 6.4E+00
4.70E+04 1.2E+00 2.0E+00 6.4E+00
3.43E+05 3.7E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
4.71 E+01 1.2E+00 2.0E+00 6.4E+00
4.63E+00 7.9E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 131 3-1 31 6 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-798
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb CFS-L09-1313-T01-A
Pb CFS-L09-1313-T02-A
Pb CFS-L09-1313-T03-A
Pb CFS-L09-1313-T04-A
Pb CFS-L09-1313-T05-A
Pb CFS-L09-1313-T06-A
Pb CFS-L09-1313-T07-A
Pb CFS-L09-1313-T08-A
Pb CFS-L09-1313-T09-A
Pb CFS-L09-1313-T01-B
Pb CFS-L09-1313-T02-B
Pb CFS-L09-1313-T03-B
Pb CFS-L09-1313-T04-B
Pb CFS-L09-1313-T05-B
Pb CFS-L09-1313-T06-B
Pb CFS-L09-1313-T07-B
Pb CFS-L09-1313-T08-B
Pb CFS-L09-1313-T09-B
Pb CFS-L09-1313-T01-C
Pb CFS-L09-1313-T02-C
Pb CFS-L09-1313-T03-C
Pb CFS-L09-1313-T04-C
Pb CFS-L09-1313-T05-C
Pb CFS-L09-1313-T06-C
Pb CFS-L09-1313-T07-C
Pb CFS-L09-1313-T08-C
Pb CFS-L09-1313-T09-C
Pb CFS-L09-1313-B01-A
Pb CFS-L09-1313-B02-A
Pb CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.09E+03
1 1.38E+04
1 9.18E+02
1 1.45E+02
1 1.16E+03
1 1.76E+03
1 6.63E+03
1 5.97E+03
1 9.58E+03
1 5.67E+03
1 2.76E+04
1 3.47E+02
1 1.46E+02
1 1.09E+03
1 1.84E+03
1 5.07E+03
1 5.43E+03
1 1.18E+04
1 8.30E+03
1 5.15E+03
1 5.54E+02
1 1.49E+02
1 1.28E+03
1 1.79E+03
1 5.91 E+03
1 5.88E+03
1 1.43E+04
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.09E+03 1.6E+00 6.8E+00 2.2E+01
1.38E+04 6.3E-01 6.8E+00 2.2E+01 10 100
9.18E+02 3.6E-01 6.8E+00 2.2E+01
1.45E+02 3.1E+00 6.8E+00 2.2E+01
1.16E+03 6.8E-01 6.8E+00 2.2E+01
1.76E+03 1.3E+00 6.8E+00 2.2E+01
6.63E+03 9.5E-01 6.8E+00 2.2E+01
5.97E+03 4.5E-01 6.8E+00 2.2E+01
9.58E+03 1.2E-01 6.8E+00 2.2E+01
5.67E+03 7.2E-01 6.8E+00 2.2E+01
2.76E+04 4.2E-01 6.8E+00 2.2E+01 10 100
3.47E+02 8.0E-01 6.8E+00 2.2E+01
1.46E+02 2.7E+00 6.8E+00 2.2E+01
1.09E+03 2.4E-01 6.8E+00 2.2E+01
1.84E+03 2.0E+00 6.8E+00 2.2E+01
5.07E+03 7.6E-01 6.8E+00 2.2E+01
5.43E+03 9.7E-01 6.8E+00 2.2E+01
1.18E+04 7.2E-01 6.8E+00 2.2E+01
8.30E+03 1.0E+00 6.8E+00 2.2E+01
5.15E+03 1.5E+00 6.8E+00 2.2E+01 10 100
5.54E+02 3.4E-01 6.8E+00 2.2E+01
1.49E+02 3.7E+00 6.8E+00 2.2E+01
1.28E+03 8.0E-01 6.8E+00 2.2E+01
1.79E+03 1.2E+00 6.8E+00 2.2E+01
5.91 E+03 7.2E-01 6.8E+00 2.2E+01
5.88E+03 1.2E+00 6.8E+00 2.2E+01
1.43E+04 8.7E-01 6.8E+00 2.2E+01
3.40E+00 1.6E+01 6.8E+00 2.2E+01
3.40E+00 2.1E+02 6.8E+00 2.2E+01
3.40E+00 2.3E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.48E+04 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.86E+04 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.18E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-799
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li CFS-L09-1313-T01-A
Li CFS-L09-1313-T02-A
Li CFS-L09-1313-T03-A
Li CFS-L09-1313-T04-A
Li CFS-L09-1313-T05-A
Li CFS-L09-1313-T06-A
Li CFS-L09-1313-T07-A
Li CFS-L09-1313-T08-A
Li CFS-L09-1313-T09-A
Li CFS-L09-1313-T01-B
Li CFS-L09-1313-T02-B
Li CFS-L09-1313-T03-B
Li CFS-L09-1313-T04-B
Li CFS-L09-1313-T05-B
Li CFS-L09-1313-T06-B
Li CFS-L09-1313-T07-B
Li CFS-L09-1313-T08-B
Li CFS-L09-1313-T09-B
Li CFS-L09-1313-T01-C
Li CFS-L09-1313-T02-C
Li CFS-L09-1313-T03-C
Li CFS-L09-1313-T04-C
Li CFS-L09-1313-T05-C
Li CFS-L09-1313-T06-C
Li CFS-L09-1313-T07-C
Li CFS-L09-1313-T08-C
Li CFS-L09-1313-T09-C
Li CFS-L09-1313-B01-A
Li CFS-L09-1313-B02-A
Li CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.12E+01
1 1.05E+01
1 1.28E+01
1 9.83E+00
1 8.29E+00
1 7.23E+00
1 8.31 E+00
1 2.18E+01
1 6.70E+01
1 8.22E+00
1 1.25E+01
1 1.13E+01
1 1.01E+01
1 1.00E+01
1 9.50E+00
1 1.07E+01
1 1.03E+01
1 6.55E+01
1 9.86E+00
1 1.05E+01
1 1.11E+01
1 1.06E+01
1 9.06E+00
1 1.01E+01
1 8.32E+00
1 1.37E+01
1 7.06E+01
1 2.56E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.12E+01 4.6E+00 1.9E+00 6.0E+00
1.05E+01 1.6E+01 1.9E+00 6.0E+00 10 100
1.28E+01 2.3E+01 1.9E+00 6.0E+00
9.83E+00 2.3E+01 1.9E+00 6.0E+00
8.29E+00 2.3E+01 1.9E+00 6.0E+00
7.23E+00 8.0E+00 1.9E+00 6.0E+00
8.31 E+00 3.6E+01 1.9E+00 6.0E+00
2.18E+01 3.2E+01 1.9E+00 6.0E+00
6.70E+01 5.0E+00 1.9E+00 6.0E+00
8.22E+00 3.3E+00 1.9E+00 6.0E+00
1.25E+01 1.0E+01 1.9E+00 6.0E+00 10 100
1.13E+01 8.4E+00 1.9E+00 6.0E+00
1.01E+01 1.6E+01 1.9E+00 6.0E+00
1.00E+01 3.3E+01 1.9E+00 6.0E+00
9.50E+00 9.4E+00 1.9E+00 6.0E+00
1.07E+01 2.4E+01 1.9E+00 6.0E+00
1.03E+01 1.1E+01 1.9E+00 6.0E+00
6.55E+01 2.1E+01 1.9E+00 6.0E+00
9.86E+00 3.9E+00 1.9E+00 6.0E+00
1.05E+01 1.3E+01 1.9E+00 6.0E+00 10 100
1.11E+01 2.6E+01 1.9E+00 6.0E+00
1.06E+01 2.2E+01 1.9E+00 6.0E+00
9.06E+00 5.7E+00 1.9E+00 6.0E+00
1.01E+01 2.5E+01 1.9E+00 6.0E+00
8.32E+00 1.9E+01 1.9E+00 6.0E+00
1.37E+01 3.0E+01 1.9E+00 6.0E+00
7.06E+01 1.6E+01 1.9E+00 6.0E+00
2.56E+00 5.0E+00 1.9E+00 6.0E+00
9.50E-01 5.9E+02 1.9E+00 6.0E+00
9.50E-01 4.8E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.91 E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.99E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.03E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-800
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn CFS-L09-1313-T01-A
Mn CFS-L09-1313-T02-A
Mn CFS-L09-1313-T03-A
Mn CFS-L09-1313-T04-A
Mn CFS-L09-1313-T05-A
Mn CFS-L09-1313-T06-A
Mn CFS-L09-1313-T07-A
Mn CFS-L09-1313-T08-A
Mn CFS-L09-1313-T09-A
Mn CFS-L09-1313-T01-B
Mn CFS-L09-1313-T02-B
Mn CFS-L09-1313-T03-B
Mn CFS-L09-1313-T04-B
Mn CFS-L09-1313-T05-B
Mn CFS-L09-1313-T06-B
Mn CFS-L09-1313-T07-B
Mn CFS-L09-1313-T08-B
Mn CFS-L09-1313-T09-B
Mn CFS-L09-1313-T01-C
Mn CFS-L09-1313-T02-C
Mn CFS-L09-1313-T03-C
Mn CFS-L09-1313-T04-C
Mn CFS-L09-1313-T05-C
Mn CFS-L09-1313-T06-C
Mn CFS-L09-1313-T07-C
Mn CFS-L09-1313-T08-C
Mn CFS-L09-1313-T09-C
Mn CFS-L09-1313-B01-A
Mn CFS-L09-1313-B02-A
Mn CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.08E+01
1 1.50E+03
1 2.58E+03
1 8.62E+03
1 2.11E+04
1 3.40E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.04E+01
1 1.38E+03
1 2.59E+03
1 1.66E+04
1 1.68E+04
1 3.47E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 9.55E+00
1 1.75E+03
1 2.58E+03
1 4.82E+03
1 1.97E+04
1 3.19E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.00E+00 9.8E+00 2.0E+00 6.4E+00 10 100
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.08E+01 3.0E-01 2.0E+00 6.4E+00
1.50E+03 9.7E-01 2.0E+00 6.4E+00
2.58E+03 8.5E-01 2.0E+00 6.4E+00
8.62E+03 1.3E+00 2.0E+00 6.4E+00
2.11E+04 9.8E-01 2.0E+00 6.4E+00
3.40E+04 4.8E-02 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+00 2.0E+00 6.4E+00 10 100
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.04E+01 1.3E+00 2.0E+00 6.4E+00
1.38E+03 1.2E+00 2.0E+00 6.4E+00
2.59E+03 7.9E-01 2.0E+00 6.4E+00
1.66E+04 8.2E-01 2.0E+00 6.4E+00
1.68E+04 9.7E-01 2.0E+00 6.4E+00
3.47E+04 8.7E-01 2.0E+00 6.4E+00
1.00E+00 6.7E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00 10 100
1.00E+00 4.1E+01 2.0E+00 6.4E+00
9.55E+00 1.1E+00 2.0E+00 6.4E+00
1.75E+03 1.0E+00 2.0E+00 6.4E+00
2.58E+03 6.1E-01 2.0E+00 6.4E+00
4.82E+03 9.5E-01 2.0E+00 6.4E+00
1.97E+04 1.0E+00 2.0E+00 6.4E+00
3.19E+04 9.0E-01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 6.6E+00 2.0E+00 6.4E+00
1.00E+00 5.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.58E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.94E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 131 3-1 31 6 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-801
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg CFS-L09-1313-T01-A
Mg CFS-L09-1313-T02-A
Mg CFS-L09-1313-T03-A
Mg CFS-L09-1313-T04-A
Mg CFS-L09-1313-T05-A
Mg CFS-L09-1313-T06-A
Mg CFS-L09-1313-T07-A
Mg CFS-L09-1313-T08-A
Mg CFS-L09-1313-T09-A
Mg CFS-L09-1313-T01-B
Mg CFS-L09-1313-T02-B
Mg CFS-L09-1313-T03-B
Mg CFS-L09-1313-T04-B
Mg CFS-L09-1313-T05-B
Mg CFS-L09-1313-T06-B
Mg CFS-L09-1313-T07-B
Mg CFS-L09-1313-T08-B
Mg CFS-L09-1313-T09-B
Mg CFS-L09-1313-T01-C
Mg CFS-L09-1313-T02-C
Mg CFS-L09-1313-T03-C
Mg CFS-L09-1313-T04-C
Mg CFS-L09-1313-T05-C
Mg CFS-L09-1313-T06-C
Mg CFS-L09-1313-T07-C
Mg CFS-L09-1313-T08-C
Mg CFS-L09-1313-T09-C
Mg CFS-L09-1313-B01-A
Mg CFS-L09-1313-B02-A
Mg CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.01E+01
1 4.15E+01
1 7.67E+02
1 5.06E+04
1 6.37E+04
1 7.24E+04
1 7.72E+04
1 1.43E+05
1 2.16E+05
1 2.69E+01
1 2.76E+01
1 1.42E+03
1 4.90E+04
1 6.28E+04
1 7.08E+04
1 9.96E+04
1 1.06E+05
1 2.14E+05
1 1.43E+01
1 1.35E+01
1 2.43E+03
1 5.33E+04
1 6.88E+04
1 7.17E+04
1 7.88E+04
1 1.31E+05
1 1.97E+05
1 5.00E-01 U1/2
1 2.14E+01
1 1.55E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01E+01 4.0E+01 1.0E+00 3.2E+00
4.15E+01 6.3E+00 1.0E+00 3.2E+00 1000 100
7.67E+02 2.3E+00 1.0E+00 3.2E+00
5.06E+04 1.2E+00 1.0E+00 3.2E+00
6.37E+04 6.3E-01 1.0E+00 3.2E+00
7.24E+04 3.2E-01 1.0E+00 3.2E+00
7.72E+04 4.5E-01 1.0E+00 3.2E+00
1.43E+05 8.3E-01 1.0E+00 3.2E+00
2.16E+05 5.5E-01 1.0E+00 3.2E+00
2.69E+01 3.0E+01 1.0E+00 3.2E+00
2.76E+01 2.2E+01 1.0E+00 3.2E+00 1000 100
1.42E+03 1.0E+00 1.0E+00 3.2E+00
4.90E+04 4.2E-01 1.0E+00 3.2E+00
6.28E+04 5.2E-01 1.0E+00 3.2E+00
7.08E+04 1.4E+00 1.0E+00 3.2E+00
9.96E+04 7.3E-01 1.0E+00 3.2E+00
1.06E+05 3.0E-02 1.0E+00 3.2E+00
2.14E+05 4.7E-01 1.0E+00 3.2E+00
1.43E+01 7.3E+01 1.0E+00 3.2E+00
1.35E+01 8.8E+01 1.0E+00 3.2E+00 1000 100
2.43E+03 4.7E-01 1.0E+00 3.2E+00
5.33E+04 1.0E+00 1.0E+00 3.2E+00
6.88E+04 1.5E-01 1.0E+00 3.2E+00
7.17E+04 6.4E-01 1.0E+00 3.2E+00
7.88E+04 1.6E+00 1.0E+00 3.2E+00
1.31E+05 7.6E-01 1.0E+00 3.2E+00
1.97E+05 8.0E-01 1.0E+00 3.2E+00
5.00E-01 5.3E+03 1.0E+00 3.2E+00
2.14E+01 2.4E+01 1.0E+00 3.2E+00
1.55E+01 4.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.01E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.08E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-802
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo CFS-L09-1313-T01-A
Mo CFS-L09-1313-T02-A
Mo CFS-L09-1313-T03-A
Mo CFS-L09-1313-T04-A
Mo CFS-L09-1313-T05-A
Mo CFS-L09-1313-T06-A
Mo CFS-L09-1313-T07-A
Mo CFS-L09-1313-T08-A
Mo CFS-L09-1313-T09-A
Mo CFS-L09-1313-T01-B
Mo CFS-L09-1313-T02-B
Mo CFS-L09-1313-T03-B
Mo CFS-L09-1313-T04-B
Mo CFS-L09-1313-T05-B
Mo CFS-L09-1313-T06-B
Mo CFS-L09-1313-T07-B
Mo CFS-L09-1313-T08-B
Mo CFS-L09-1313-T09-B
Mo CFS-L09-1313-T01-C
Mo CFS-L09-1313-T02-C
Mo CFS-L09-1313-T03-C
Mo CFS-L09-1313-T04-C
Mo CFS-L09-1313-T05-C
Mo CFS-L09-1313-T06-C
Mo CFS-L09-1313-T07-C
Mo CFS-L09-1313-T08-C
Mo CFS-L09-1313-T09-C
Mo CFS-L09-1313-B01-A
Mo CFS-L09-1313-B02-A
Mo CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.37E+03
1 1.43E+03
1 9.38E+02
1 1.97E+02
1 9.92E+00
1 9.22E+00
1 7.49E+00
1 1.83E+01
1 2.49E+02
1 1.87E+03
1 1.41E+03
1 1.00E+03
1 1.95E+02
1 9.47E+00
1 8.13E+00
1 1.78E+01
1 1.00E+01
1 3.52E+02
1 1.07E+03
1 1.36E+03
1 9.83E+02
1 2.04E+02
1 9.53E+00
1 8.99E+00
1 4.14E+00
1 9.62E+00
1 4.95E+02
1 6.00E-01 U1/2
1 1.60E+00 E
1 4.94E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.37E+03 1.0E+00 1.2E+00 3.8E+00
1.43E+03 9.9E-02 1.2E+00 3.8E+00 10 100
9.38E+02 2.5E-01 1.2E+00 3.8E+00
1.97E+02 8.8E-01 1.2E+00 3.8E+00
9.92E+00 1.5E+01 1.2E+00 3.8E+00
9.22E+00 1.9E+01 1.2E+00 3.8E+00
7.49E+00 2.1E+01 1.2E+00 3.8E+00
1.83E+01 1.1E+02 1.2E+00 3.8E+00
2.49E+02 8.8E-01 1.2E+00 3.8E+00
1.87E+03 3.5E-01 1.2E+00 3.8E+00
1.41E+03 4.9E-01 1.2E+00 3.8E+00 10 100
1.00E+03 2.8E-01 1.2E+00 3.8E+00
1.95E+02 1.1E+00 1.2E+00 3.8E+00
9.47E+00 7.4E+00 1.2E+00 3.8E+00
8.13E+00 9.6E+00 1.2E+00 3.8E+00
1.78E+01 9.4E+01 1.2E+00 3.8E+00
1.00E+01 2.3E+01 1.2E+00 3.8E+00
3.52E+02 6.5E-01 1.2E+00 3.8E+00
1.07E+03 2.3E+00 1.2E+00 3.8E+00
1.36E+03 1.3E+00 1.2E+00 3.8E+00 10 100
9.83E+02 6.9E-01 1.2E+00 3.8E+00
2.04E+02 9.1E-01 1.2E+00 3.8E+00
9.53E+00 6.8E+00 1.2E+00 3.8E+00
8.99E+00 2.4E+01 1.2E+00 3.8E+00
4.14E+00 4.2E+01 1.2E+00 3.8E+00
9.62E+00 2.4E+01 1.2E+00 3.8E+00
4.95E+02 1.5E+00 1.2E+00 3.8E+00
6.00E-01 4.1E+01 1.2E+00 3.8E+00
1.60E+00 1.4E+01 1.2E+00 3.8E+00
4.94E+00 1.8E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.37E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.31 E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.28E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-803
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni CFS-L09-1313-T01-A
Ni CFS-L09-1313-T02-A
Ni CFS-L09-1313-T03-A
Ni CFS-L09-1313-T04-A
Ni CFS-L09-1313-T05-A
Ni CFS-L09-1313-T06-A
Ni CFS-L09-1313-T07-A
Ni CFS-L09-1313-T08-A
Ni CFS-L09-1313-T09-A
Ni CFS-L09-1313-T01-B
Ni CFS-L09-1313-T02-B
Ni CFS-L09-1313-T03-B
Ni CFS-L09-1313-T04-B
Ni CFS-L09-1313-T05-B
Ni CFS-L09-1313-T06-B
Ni CFS-L09-1313-T07-B
Ni CFS-L09-1313-T08-B
Ni CFS-L09-1313-T09-B
Ni CFS-L09-1313-T01-C
Ni CFS-L09-1313-T02-C
Ni CFS-L09-1313-T03-C
Ni CFS-L09-1313-T04-C
Ni CFS-L09-1313-T05-C
Ni CFS-L09-1313-T06-C
Ni CFS-L09-1313-T07-C
Ni CFS-L09-1313-T08-C
Ni CFS-L09-1313-T09-C
Ni CFS-L09-1313-B01-A
Ni CFS-L09-1313-B02-A
Ni CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.81E+00 E
1 9.00E-01 U1/2
1 2.60E+00 E
1 3.19E+00 E
1 2.05E+02
1 5.79E+02
1 3.31 E+03
1 5.72E+03
1 6.40E+03
1 4.68E+00 E
1 6.23E+00
1 9.00E-01 U1/2
1 3.06E+00 E
1 1.76E+02
1 5.80E+02
1 5.22E+03
1 5.39E+03
1 6.17E+03
1 9.00E-01 U1/2
1 2.80E+00 E
1 9.00E-01 U1/2
1 4.54E+00 E
1 2.34E+02
1 5.67E+02
1 1.60E+03
1 5.51 E+03
1 6.03E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 2.59E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.81E+00 3.4E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00 10 100
2.60E+00 1.1E+01 1.8E+00 5.7E+00
3.19E+00 1.7E+01 1.8E+00 5.7E+00
2.05E+02 1.9E+00 1.8E+00 5.7E+00
5.79E+02 6.7E-02 1.8E+00 5.7E+00
3.31 E+03 7.9E-01 1.8E+00 5.7E+00
5.72E+03 2.0E+00 1.8E+00 5.7E+00
6.40E+03 3.2E-01 1.8E+00 5.7E+00
4.68E+00 9.2E+01 1.8E+00 5.7E+00
6.23E+00 1.2E+01 1.8E+00 5.7E+00 10 100
9.00E-01 5.7E+01 1.8E+00 5.7E+00
3.06E+00 6.5E+01 1.8E+00 5.7E+00
1.76E+02 2.2E-01 1.8E+00 5.7E+00
5.80E+02 2.1E+00 1.8E+00 5.7E+00
5.22E+03 6.2E-01 1.8E+00 5.7E+00
5.39E+03 9.7E-01 1.8E+00 5.7E+00
6.17E+03 3.5E-01 1.8E+00 5.7E+00
9.00E-01 7.7E+01 1.8E+00 5.7E+00
2.80E+00 6.4E+01 1.8E+00 5.7E+00 10 100
9.00E-01 1.1E+02 1.8E+00 5.7E+00
4.54E+00 2.3E+01 1.8E+00 5.7E+00
2.34E+02 1.6E+00 1.8E+00 5.7E+00
5.67E+02 9.9E-01 1.8E+00 5.7E+00
1.60E+03 5.3E-01 1.8E+00 5.7E+00
5.51 E+03 1.0E+00 1.8E+00 5.7E+00
6.03E+03 1.4E+00 1.8E+00 5.7E+00
9.00E-01 1.6E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
2.59E+00 9.1E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.84E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.17E+02 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-804
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P CFS-L09-1313-T01-A
P CFS-L09-1313-T02-A
P CFS-L09-1313-T03-A
P CFS-L09-1313-T04-A
P CFS-L09-1313-T05-A
P CFS-L09-1313-T06-A
P CFS-L09-1313-T07-A
P CFS-L09-1313-T08-A
P CFS-L09-1313-T09-A
P CFS-L09-1313-T01-B
P CFS-L09-1313-T02-B
P CFS-L09-1313-T03-B
P CFS-L09-1313-T04-B
P CFS-L09-1313-T05-B
P CFS-L09-1313-T06-B
P CFS-L09-1313-T07-B
P CFS-L09-1313-T08-B
P CFS-L09-1313-T09-B
P CFS-L09-1313-T01-C
P CFS-L09-1313-T02-C
P CFS-L09-1313-T03-C
P CFS-L09-1313-T04-C
P CFS-L09-1313-T05-C
P CFS-L09-1313-T06-C
P CFS-L09-1313-T07-C
P CFS-L09-1313-T08-C
P CFS-L09-1313-T09-C
P CFS-L09-1313-B01-A
P CFS-L09-1313-B02-A
P CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.77E+01
1 6.21 E+01
1 4.45E+01
1 3.27E+01
1 1.85E+00 U1/2
1 7.23E+00 E
1 1.41E+01
1 2.37E+01
1 6.51 E+03
1 1.04E+02
1 8.77E+01
1 7.91E+01
1 1.75E+01
1 2.09E+01
1 2.35E+01
1 2.70E+01
1 1.29E+01
1 8.88E+03
1 1.10E+02
1 7.42E+01
1 4.20E+01
1 1.99E+01
1 1.45E+01
1 9.62E+00 E
1 8.27E+00 E
1 4.05E+01
1 1.05E+04
1 6.85E+00 E
1 2.36E+01
1 2.03E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.77E+01 7.9E+00 3.7E+00 1.2E+01
6.21E+01 1.1 E+01 3.7E+00 1.2E+01 1000 100
4.45E+01 1.4E+01 3.7E+00 1.2E+01
3.27E+01 2.5E+01 3.7E+00 1.2E+01
1.85E+00 3.4E+02 3.7E+00 1.2E+01
7.23E+00 1.2E+02 3.7E+00 1.2E+01
1.41 E+01 5.9E+01 3.7E+00 1.2E+01
2.37E+01 2.2E+01 3.7E+00 1.2E+01
6.51 E+03 4.6E-01 3.7E+00 1.2E+01
1.04E+02 2.4E+00 3.7E+00 1.2E+01
8.77E+01 9.8E+00 3.7E+00 1.2E+01 1000 100
7.91E+01 1.5E+01 3.7E+00 1.2E+01
1.75E+01 1.6E+01 3.7E+00 1.2E+01
2.09E+01 2.1 E+01 3.7E+00 1.2E+01
2.35E+01 8.8E+01 3.7E+00 1.2E+01
2.70E+01 5.6E+01 3.7E+00 1.2E+01
1.29E+01 5.2E+01 3.7E+00 1.2E+01
8.88E+03 8.2E-01 3.7E+00 1.2E+01
1.10E+02 3.6E+01 3.7E+00 1.2E+01
7.42E+01 1.5E+01 3.7E+00 1.2E+01 1000 100
4.20E+01 1.1 E+01 3.7E+00 1.2E+01
1.99E+01 7.1 E+01 3.7E+00 1.2E+01
1.45E+01 6.8E+01 3.7E+00 1.2E+01
9.62E+00 8.4E+01 3.7E+00 1.2E+01
8.27E+00 4.4E+01 3.7E+00 1.2E+01
4.05E+01 1.0E+01 3.7E+00 1.2E+01
1.05E+04 6.0E-01 3.7E+00 1.2E+01
6.85E+00 6.4E+01 3.7E+00 1.2E+01
2.36E+01 2.8E+01 3.7E+00 1.2E+01
2.03E+01 4.1 E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.15E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11 E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-805
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L09-1313-T01-A
CFS-L09-1313-T02-A
CFS-L09-1313-T03-A
CFS-L09-1313-T04-A
CFS-L09-1313-T05-A
CFS-L09-1313-T06-A
CFS-L09-1313-T07-A
CFS-L09-1313-T08-A
CFS-L09-1313-T09-A
CFS-L09-1313-T01-B
CFS-L09-1313-T02-B
CFS-L09-1313-T03-B
CFS-L09-1313-T04-B
CFS-L09-1313-T05-B
CFS-L09-1313-T06-B
CFS-L09-1313-T07-B
CFS-L09-1313-T08-B
CFS-L09-1313-T09-B
CFS-L09-1313-T01-C
CFS-L09-1313-T02-C
CFS-L09-1313-T03-C
CFS-L09-1313-T04-C
CFS-L09-1313-T05-C
CFS-L09-1313-T06-C
CFS-L09-1313-T07-C
CFS-L09-1313-T08-C
CFS-L09-1313-T09-C
CFS-L09-1313-B01-A
CFS-L09-1313-B02-A
CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.04E+06
1 2.09E+06
1 4.49E+05
1 2.55E+05
1 9.15E+03
1 9.84E+03
1 1.20E+04
1 1.65E+04
1 2.58E+04
1 2.30E+06
1 2.15E+06
1 4.96E+05
1 2.57E+05
1 8.63E+03
1 9.70E+03
1 1.41E+04
1 1.43E+04
1 2.57E+04
1 2.39E+06
1 2.20E+06
1 4.70E+05
1 2.60E+05
1 9.51 E+03
1 9.73E+03
1 1.13E+04
1 1.57E+04
1 2.46E+04
1 3.20E+01
1 2.02E+04
1 2.15E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.04E+06 1.5E+00 1.6E+00 5.1E+00
2.09E+06 2.0E-01 1.6E+00 5.1E+00 1000 100
4.49E+05 1.4E-01 1.6E+00 5.1E+00
2.55E+05 4.9E-01 1.6E+00 5.1E+00
9.15E+03 6.2E-01 1.6E+00 5.1E+00
9.84E+03 7.4E-01 1.6E+00 5.1E+00
1.20E+04 5.7E-01 1.6E+00 5.1E+00
1.65E+04 1.2E+00 1.6E+00 5.1E+00
2.58E+04 1.0E+00 1.6E+00 5.1E+00
2.30E+06 1.2E+00 1.6E+00 5.1E+00
2.15E+06 5.6E-01 1.6E+00 5.1E+00 1000 100
4.96E+05 2.4E+00 1.6E+00 5.1E+00
2.57E+05 2.7E-01 1.6E+00 5.1E+00
8.63E+03 1.9E-01 1.6E+00 5.1E+00
9.70E+03 6.3E-01 1.6E+00 5.1E+00
1.41E+04 1.2E+00 1.6E+00 5.1E+00
1.43E+04 7.3E-01 1.6E+00 5.1E+00
2.57E+04 5.1E-01 1.6E+00 5.1E+00
2.39E+06 6.1E-01 1.6E+00 5.1E+00
2.20E+06 1.4E+00 1.6E+00 5.1E+00 1000 100
4.70E+05 1.5E+00 1.6E+00 5.1E+00
2.60E+05 1.4E+00 1.6E+00 5.1E+00
9.51 E+03 5.9E-01 1.6E+00 5.1E+00
9.73E+03 6.2E-01 1.6E+00 5.1E+00
1.13E+04 2.6E-01 1.6E+00 5.1E+00
1.57E+04 1.3E+00 1.6E+00 5.1E+00
2.46E+04 8.3E-01 1.6E+00 5.1E+00
3.20E+01 3.4E+00 1.6E+00 5.1E+00
2.02E+04 1.2E+00 1.6E+00 5.1E+00
2.15E+06 1.5E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.09E+06 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.15E+06 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.20E+06 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-806
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L09-1313-T01-A
CFS-L09-1313-T02-A
CFS-L09-1313-T03-A
CFS-L09-1313-T04-A
CFS-L09-1313-T05-A
CFS-L09-1313-T06-A
CFS-L09-1313-T07-A
CFS-L09-1313-T08-A
CFS-L09-1313-T09-A
CFS-L09-1313-T01-B
CFS-L09-1313-T02-B
CFS-L09-1313-T03-B
CFS-L09-1313-T04-B
CFS-L09-1313-T05-B
CFS-L09-1313-T06-B
CFS-L09-1313-T07-B
CFS-L09-1313-T08-B
CFS-L09-1313-T09-B
CFS-L09-1313-T01-C
CFS-L09-1313-T02-C
CFS-L09-1313-T03-C
CFS-L09-1313-T04-C
CFS-L09-1313-T05-C
CFS-L09-1313-T06-C
CFS-L09-1313-T07-C
CFS-L09-1313-T08-C
CFS-L09-1313-T09-C
CFS-L09-1313-B01-A
CFS-L09-1313-B02-A
CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.93E+02
1 5.32E+02
1 5.12E+02
1 1.28E+02
1 9.28E+01
1 9.18E+01
1 1.69E+02
1 2.50E+02
1 7.09E+02
1 5.09E+02
1 2.77E+02
1 4.83E+02
1 1.30E+02
1 8.84E+01
1 1.06E+02
1 2.15E+02
1 2.27E+02
1 9.26E+02
1 4.94E+02
1 3.34E+02
1 4.50E+02
1 1.45E+02
1 9.45E+01
1 9.27E+01
1 1.22E+02
1 2.22E+02
1 1.09E+03
1 1.62E+01 E
1 2.37E+01 E
1 2.08E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.93E+02 5.5E+00 1.5E+01 4.8E+01
5.32E+02 6.1E+00 1.5E+01 4.8E+01 10 100
5.12E+02 1.7E+00 1.5E+01 4.8E+01
1.28E+02 8.6E+00 1.5E+01 4.8E+01
9.28E+01 1.3E+01 1.5E+01 4.8E+01
9.18E+01 3.3E+00 1.5E+01 4.8E+01
1.69E+02 1.0E+01 1.5E+01 4.8E+01
2.50E+02 1.2E+01 1.5E+01 4.8E+01
7.09E+02 3.9E+00 1.5E+01 4.8E+01
5.09E+02 2.1E+00 1.5E+01 4.8E+01
2.77E+02 5.5E+00 1.5E+01 4.8E+01 10 100
4.83E+02 1.0E+00 1.5E+01 4.8E+01
1.30E+02 7.0E+00 1.5E+01 4.8E+01
8.84E+01 2.7E+01 1.5E+01 4.8E+01
1.06E+02 4.8E+00 1.5E+01 4.8E+01
2.15E+02 3.8E+00 1.5E+01 4.8E+01
2.27E+02 6.1E+00 1.5E+01 4.8E+01
9.26E+02 8.1E-01 1.5E+01 4.8E+01
4.94E+02 3.8E+00 1.5E+01 4.8E+01
3.34E+02 9.8E+00 1.5E+01 4.8E+01 10 100
4.50E+02 3.9E+00 1.5E+01 4.8E+01
1.45E+02 7.1E+00 1.5E+01 4.8E+01
9.45E+01 2.6E+01 1.5E+01 4.8E+01
9.27E+01 9.6E+00 1.5E+01 4.8E+01
1.22E+02 2.5E+00 1.5E+01 4.8E+01
2.22E+02 3.6E+00 1.5E+01 4.8E+01
1.09E+03 1.9E+00 1.5E+01 4.8E+01
1.62E+01 2.0E+01 1.5E+01 4.8E+01
2.37E+01 2.0E+01 1.5E+01 4.8E+01
2.08E+01 3.5E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.50E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.28E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-807
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si CFS-L09-1313-T01-A
Si CFS-L09-1313-T02-A
Si CFS-L09-1313-T03-A
Si CFS-L09-1313-T04-A
Si CFS-L09-1313-T05-A
Si CFS-L09-1313-T06-A
Si CFS-L09-1313-T07-A
Si CFS-L09-1313-T08-A
Si CFS-L09-1313-T09-A
Si CFS-L09-1313-T01-B
Si CFS-L09-1313-T02-B
Si CFS-L09-1313-T03-B
Si CFS-L09-1313-T04-B
Si CFS-L09-1313-T05-B
Si CFS-L09-1313-T06-B
Si CFS-L09-1313-T07-B
Si CFS-L09-1313-T08-B
Si CFS-L09-1313-T09-B
Si CFS-L09-1313-T01-C
Si CFS-L09-1313-T02-C
Si CFS-L09-1313-T03-C
Si CFS-L09-1313-T04-C
Si CFS-L09-1313-T05-C
Si CFS-L09-1313-T06-C
Si CFS-L09-1313-T07-C
Si CFS-L09-1313-T08-C
Si CFS-L09-1313-T09-C
Si CFS-L09-1313-B01-A
Si CFS-L09-1313-B02-A
Si CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.53E+02
1 2.18E+02
1 4.18E+02
1 7.53E+02
1 3.53E+03
1 7.70E+03
1 3.35E+04
1 7.57E+04
1 1.40E+05
1 2.80E+02
1 1.57E+02
1 3.77E+02
1 7.55E+02
1 3.21 E+03
1 7.80E+03
1 4.88E+04
1 4.73E+04
1 1.29E+05
1 2.59E+02
1 1.98E+02
1 4.64E+02
1 7.55E+02
1 3.81 E+03
1 7.49E+03
1 1.97E+04
1 7.40E+04
1 1.12E+05
1 5.50E-01 U1/2
1 7.58E+01
1 1.47E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+02 2.0E+00 1.1E+00 3.5E+00
2.18E+02 3.7E-01 1.1E+00 3.5E+00 1000 100
4.18E+02 3.9E-01 1.1E+00 3.5E+00
7.53E+02 1.6E+00 1.1E+00 3.5E+00
3.53E+03 5.0E-01 1.1E+00 3.5E+00
7.70E+03 8.4E-01 1.1E+00 3.5E+00
3.35E+04 6.3E-01 1.1E+00 3.5E+00
7.57E+04 6.2E-01 1.1E+00 3.5E+00
1.40E+05 5.7E-01 1.1E+00 3.5E+00
2.80E+02 2.1E+00 1.1E+00 3.5E+00
1.57E+02 2.0E+00 1.1E+00 3.5E+00 1000 100
3.77E+02 2.2E+00 1.1E+00 3.5E+00
7.55E+02 2.0E-01 1.1E+00 3.5E+00
3.21E+03 8.9E-01 1.1E+00 3.5E+00
7.80E+03 1.5E+00 1.1E+00 3.5E+00
4.88E+04 5.9E-01 1.1E+00 3.5E+00
4.73E+04 1.3E+00 1.1E+00 3.5E+00
1.29E+05 4.6E-01 1.1E+00 3.5E+00
2.59E+02 1.1E+01 1.1E+00 3.5E+00
1.98E+02 2.7E+00 1.1E+00 3.5E+00 1000 100
4.64E+02 4.7E-01 1.1E+00 3.5E+00
7.55E+02 3.7E-01 1.1E+00 3.5E+00
3.81E+03 1.3E+00 1.1E+00 3.5E+00
7.49E+03 7.5E-02 1.1E+00 3.5E+00
1.97E+04 1.3E-01 1.1E+00 3.5E+00
7.40E+04 6.5E-01 1.1E+00 3.5E+00
1.12E+05 1.1E-01 1.1E+00 3.5E+00
5.50E-01 8.8E+03 1.1E+00 3.5E+00
7.58E+01 4.7E+00 1.1E+00 3.5E+00
1.47E+03 1.8E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-808
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na CFS-L09-1313-T01-A
Na CFS-L09-1313-T02-A
Na CFS-L09-1313-T03-A
Na CFS-L09-1313-T04-A
Na CFS-L09-1313-T05-A
Na CFS-L09-1313-T06-A
Na CFS-L09-1313-T07-A
Na CFS-L09-1313-T08-A
Na CFS-L09-1313-T09-A
Na CFS-L09-1313-T01-B
Na CFS-L09-1313-T02-B
Na CFS-L09-1313-T03-B
Na CFS-L09-1313-T04-B
Na CFS-L09-1313-T05-B
Na CFS-L09-1313-T06-B
Na CFS-L09-1313-T07-B
Na CFS-L09-1313-T08-B
Na CFS-L09-1313-T09-B
Na CFS-L09-1313-T01-C
Na CFS-L09-1313-T02-C
Na CFS-L09-1313-T03-C
Na CFS-L09-1313-T04-C
Na CFS-L09-1313-T05-C
Na CFS-L09-1313-T06-C
Na CFS-L09-1313-T07-C
Na CFS-L09-1313-T08-C
Na CFS-L09-1313-T09-C
Na CFS-L09-1313-B01-A
Na CFS-L09-1313-B02-A
Na CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.32E+03
1 9.47E+03
1 8.92E+03
1 9.76E+03
1 9.52E+03
1 9.71 E+03
1 9.93E+03
1 1.09E+04
1 1.21E+04
1 9.98E+03
1 8.76E+03
1 9.96E+03
1 9.65E+03
1 9.07E+03
1 9.36E+03
1 1.02E+04
1 1.05E+04
1 1.22E+04
1 1.07E+04
1 9.88E+03
1 9.83E+03
1 9.94E+03
1 9.79E+03
1 9.74E+03
1 9.96E+03
1 1.07E+04
1 1.17E+04
1 2.30E+01
1 3.77E+01
1 6.09E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.32E+03 5.5E-01 2.5E+00 8.0E+00
9.47E+03 2.2E-01 2.5E+00 8.0E+00 1000 100
8.92E+03 2.4E-02 2.5E+00 8.0E+00
9.76E+03 1.4E-01 2.5E+00 8.0E+00
9.52E+03 6.7E-01 2.5E+00 8.0E+00
9.71 E+03 8.1E-01 2.5E+00 8.0E+00
9.93E+03 4.1E-01 2.5E+00 8.0E+00
1.09E+04 1.3E-01 2.5E+00 8.0E+00
1.21E+04 5.9E-01 2.5E+00 8.0E+00
9.98E+03 1.1E+00 2.5E+00 8.0E+00
8.76E+03 4.4E-01 2.5E+00 8.0E+00 1000 100
9.96E+03 4.6E-01 2.5E+00 8.0E+00
9.65E+03 8.3E-01 2.5E+00 8.0E+00
9.07E+03 2.6E-01 2.5E+00 8.0E+00
9.36E+03 4.1E-01 2.5E+00 8.0E+00
1.02E+04 3.6E-01 2.5E+00 8.0E+00
1.05E+04 9.9E-01 2.5E+00 8.0E+00
1.22E+04 8.2E-01 2.5E+00 8.0E+00
1.07E+04 3.3E-01 2.5E+00 8.0E+00
9.88E+03 5.7E-01 2.5E+00 8.0E+00 1000 100
9.83E+03 6.7E-01 2.5E+00 8.0E+00
9.94E+03 4.7E-01 2.5E+00 8.0E+00
9.79E+03 1.1E+00 2.5E+00 8.0E+00
9.74E+03 1.1E+00 2.5E+00 8.0E+00
9.96E+03 8.4E-01 2.5E+00 8.0E+00
1.07E+04 8.2E-01 2.5E+00 8.0E+00
1.17E+04 9.6E-02 2.5E+00 8.0E+00
2.30E+01 4.5E+00 2.5E+00 8.0E+00
3.77E+01 2.1E+00 2.5E+00 8.0E+00
6.09E+02 2.8E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.03E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-809
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr CFS-L09-1313-T01-A
Sr CFS-L09-1313-T02-A
Sr CFS-L09-1313-T03-A
Sr CFS-L09-1313-T04-A
Sr CFS-L09-1313-T05-A
Sr CFS-L09-1313-T06-A
Sr CFS-L09-1313-T07-A
Sr CFS-L09-1313-T08-A
Sr CFS-L09-1313-T09-A
Sr CFS-L09-1313-T01-B
Sr CFS-L09-1313-T02-B
Sr CFS-L09-1313-T03-B
Sr CFS-L09-1313-T04-B
Sr CFS-L09-1313-T05-B
Sr CFS-L09-1313-T06-B
Sr CFS-L09-1313-T07-B
Sr CFS-L09-1313-T08-B
Sr CFS-L09-1313-T09-B
Sr CFS-L09-1313-T01-C
Sr CFS-L09-1313-T02-C
Sr CFS-L09-1313-T03-C
Sr CFS-L09-1313-T04-C
Sr CFS-L09-1313-T05-C
Sr CFS-L09-1313-T06-C
Sr CFS-L09-1313-T07-C
Sr CFS-L09-1313-T08-C
Sr CFS-L09-1313-T09-C
Sr CFS-L09-1313-B01-A
Sr CFS-L09-1313-B02-A
Sr CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.08E+03
1 3.71 E+03
1 3.67E+03
1 3.17E+03
1 1.43E+03
1 9.04E+02
1 9.58E+02
1 1.13E+03
1 1.37E+03
1 2.47E+03
1 2.86E+03
1 3.87E+03
1 3.26E+03
1 1.39E+03
1 8.90E+02
1 1.01 E+03
1 1.06E+03
1 1.37E+03
1 2.72E+03
1 2.43E+03
1 3.98E+03
1 3.15E+03
1 1.37E+03
1 9.13E+02
1 9.50E+02
1 1.10E+03
1 1.33E+03
1 5.00E-01 U1/2
1 3.14E+00 E
1 1.05E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+03 1.1E+00 1.0E+00 3.2E+00
3.71E+03 4.6E-01 1.0E+00 3.2E+00 1000 100
3.67E+03 6.4E-01 1.0E+00 3.2E+00
3.17E+03 1.2E+00 1.0E+00 3.2E+00
1.43E+03 3.5E-01 1.0E+00 3.2E+00
9.04E+02 1.2E+00 1.0E+00 3.2E+00
9.58E+02 9.8E-01 1.0E+00 3.2E+00
1.13E+03 1.5E+00 1.0E+00 3.2E+00
1.37E+03 4.8E-01 1.0E+00 3.2E+00
2.47E+03 1.2E-01 1.0E+00 3.2E+00
2.86E+03 1.8E-01 1.0E+00 3.2E+00 1000 100
3.87E+03 9.5E-01 1.0E+00 3.2E+00
3.26E+03 3.7E-01 1.0E+00 3.2E+00
1.39E+03 5.2E-01 1.0E+00 3.2E+00
8.90E+02 1.5E+00 1.0E+00 3.2E+00
1.01 E+03 1.3E+00 1.0E+00 3.2E+00
1.06E+03 1.7E+00 1.0E+00 3.2E+00
1.37E+03 7.8E-01 1.0E+00 3.2E+00
2.72E+03 1.4E+00 1.0E+00 3.2E+00
2.43E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
3.98E+03 1.0E+00 1.0E+00 3.2E+00
3.15E+03 1.0E+00 1.0E+00 3.2E+00
1.37E+03 2.0E+00 1.0E+00 3.2E+00
9.13E+02 7.9E-01 1.0E+00 3.2E+00
9.50E+02 7.5E-01 1.0E+00 3.2E+00
1.10E+03 1.0E+00 1.0E+00 3.2E+00
1.33E+03 1.4E+00 1.0E+00 3.2E+00
5.00E-01 4.4E+02 1.0E+00 3.2E+00
3.14E+00 3.7E+01 1.0E+00 3.2E+00
1.05E+00 2.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.68E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.82E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.41 E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-810
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S CFS-L09-1313-T01-A
S CFS-L09-1313-T02-A
S CFS-L09-1313-T03-A
S CFS-L09-1313-T04-A
S CFS-L09-1313-T05-A
S CFS-L09-1313-T06-A
S CFS-L09-1313-T07-A
S CFS-L09-1313-T08-A
S CFS-L09-1313-T09-A
S CFS-L09-1313-T01-B
S CFS-L09-1313-T02-B
S CFS-L09-1313-T03-B
S CFS-L09-1313-T04-B
S CFS-L09-1313-T05-B
S CFS-L09-1313-T06-B
S CFS-L09-1313-T07-B
S CFS-L09-1313-T08-B
S CFS-L09-1313-T09-B
S CFS-L09-1313-T01-C
S CFS-L09-1313-T02-C
S CFS-L09-1313-T03-C
S CFS-L09-1313-T04-C
S CFS-L09-1313-T05-C
S CFS-L09-1313-T06-C
S CFS-L09-1313-T07-C
S CFS-L09-1313-T08-C
S CFS-L09-1313-T09-C
S CFS-L09-1313-B01-A
S CFS-L09-1313-B02-A
S CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.20E+06
1 9.38E+05
1 7.48E+05
1 6.93E+05
1 6.08E+05
1 6.05E+05
1 6.34E+05
1 6.76E+05
1 8.22E+05
1 1.31E+06
1 1.25E+06
1 7.85E+05
1 6.85E+05
1 5.70E+05
1 6.05E+05
1 6.53E+05
1 6.62E+05
1 8.19E+05
1 1.42E+06
1 1.28E+06
1 7.87E+05
1 7.00E+05
1 6.14E+05
1 6.01 E+05
1 6.32E+05
1 6.57E+05
1 7.94E+05
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.20E+06 9.8E-01 6.8E+00 2.2E+01
9.38E+05 5.8E-02 6.8E+00 2.2E+01 1000 100
7.48E+05 2.1E-01 6.8E+00 2.2E+01
6.93E+05 7.1E-01 6.8E+00 2.2E+01
6.08E+05 5.6E-01 6.8E+00 2.2E+01
6.05E+05 8.0E-01 6.8E+00 2.2E+01
6.34E+05 2.7E-01 6.8E+00 2.2E+01
6.76E+05 7.6E-01 6.8E+00 2.2E+01
8.22E+05 3.4E-01 6.8E+00 2.2E+01
1.31E+06 2.6E-01 6.8E+00 2.2E+01
1.25E+06 2.6E-01 6.8E+00 2.2E+01 1000 100
7.85E+05 1.1E-01 6.8E+00 2.2E+01
6.85E+05 6.2E-01 6.8E+00 2.2E+01
5.70E+05 4.4E-01 6.8E+00 2.2E+01
6.05E+05 6.4E-01 6.8E+00 2.2E+01
6.53E+05 9.7E-01 6.8E+00 2.2E+01
6.62E+05 9.7E-01 6.8E+00 2.2E+01
8.19E+05 5.5E-01 6.8E+00 2.2E+01
1.42E+06 1.1E+00 6.8E+00 2.2E+01
1.28E+06 1.2E+00 6.8E+00 2.2E+01 1000 100
7.87E+05 5.5E-01 6.8E+00 2.2E+01
7.00E+05 7.9E-01 6.8E+00 2.2E+01
6.14E+05 3.5E-01 6.8E+00 2.2E+01
6.01 E+05 5.8E-01 6.8E+00 2.2E+01
6.32E+05 2.3E-01 6.8E+00 2.2E+01
6.57E+05 1.0E+00 6.8E+00 2.2E+01
7.94E+05 9.0E-01 6.8E+00 2.2E+01
3.40E+00 1.6E+01 6.8E+00 2.2E+01
3.40E+00 1.0E+01 6.8E+00 2.2E+01
3.40E+00 2.7E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.38E+05 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+06 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.28E+06 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-811
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample Dilutic
CFS-L09-1313-T01-A
CFS-L09-1313-T02-A
CFS-L09-1313-T03-A
CFS-L09-1313-T04-A
CFS-L09-1313-T05-A
CFS-L09-1313-T06-A
CFS-L09-1313-T07-A
CFS-L09-1313-T08-A
CFS-L09-1313-T09-A
CFS-L09-1313-T01-B
CFS-L09-1313-T02-B
CFS-L09-1313-T03-B
CFS-L09-1313-T04-B
CFS-L09-1313-T05-B
CFS-L09-1313-T06-B
CFS-L09-1313-T07-B
CFS-L09-1313-T08-B
CFS-L09-1313-T09-B
CFS-L09-1313-T01-C
CFS-L09-1313-T02-C
CFS-L09-1313-T03-C
CFS-L09-1313-T04-C
CFS-L09-1313-T05-C
CFS-L09-1313-T06-C
CFS-L09-1313-T07-C
CFS-L09-1313-T08-C
CFS-L09-1313-T09-C
CFS-L09-1313-B01-A
CFS-L09-1313-B02-A
CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.63E+02
1 1.90E+02
1 2.64E+02
1 6.16E+02
1 3.07E+02
1 3.90E+02
1 6.05E+02
1 9.32E+02
1 1.79E+03
1 1.93E+02
1 1.69E+02
1 3.16E+02
1 6.08E+02
1 2.92E+02
1 3.94E+02
1 7.57E+02
1 7.95E+02
1 1.94E+03
1 2.25E+02
1 2.01 E+02
1 3.67E+02
1 6. 11 E+02
1 3.37E+02
1 3.81 E+02
1 5.45E+02
1 8.93E+02
1 1.98E+03
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.63E+02 1.7E+00 4.6E+00 1.5E+01
1.90E+02 3.7E+00 4.6E+00 1.5E+01 10 100
2.64E+02 1.3E+00 4.6E+00 1.5E+01
6.16E+02 1.5E+00 4.6E+00 1.5E+01
3.07E+02 3.0E+00 4.6E+00 1.5E+01
3.90E+02 2.3E+00 4.6E+00 1.5E+01
6.05E+02 1.1E+00 4.6E+00 1.5E+01
9.32E+02 1.2E+00 4.6E+00 1.5E+01
1.79E+03 4.1E-01 4.6E+00 1.5E+01
1.93E+02 3.2E+00 4.6E+00 1.5E+01
1.69E+02 2.9E+00 4.6E+00 1.5E+01 10 100
3.16E+02 1.4E+00 4.6E+00 1.5E+01
6.08E+02 1.2E+00 4.6E+00 1.5E+01
2.92E+02 8.7E-01 4.6E+00 1.5E+01
3.94E+02 8.1E-01 4.6E+00 1.5E+01
7.57E+02 2.4E+00 4.6E+00 1.5E+01
7.95E+02 1.4E+00 4.6E+00 1.5E+01
1.94E+03 8.6E-01 4.6E+00 1.5E+01
2.25E+02 2.8E+00 4.6E+00 1.5E+01
2.01E+02 3.0E-01 4.6E+00 1.5E+01 10 100
3.67E+02 2.0E+00 4.6E+00 1.5E+01
6.11E+02 8.5E-01 4.6E+00 1.5E+01
3.37E+02 8.5E-01 4.6E+00 1.5E+01
3.81 E+02 4.7E-01 4.6E+00 1.5E+01
5.45E+02 7.2E-01 4.6E+00 1.5E+01
8.93E+02 5.4E-01 4.6E+00 1.5E+01
1.98E+03 7.6E-01 4.6E+00 1.5E+01
2.30E+00 8.8E+00 4.6E+00 1.5E+01
2.30E+00 3.8E+01 4.6E+00 1.5E+01
2.30E+00 2.2E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.08E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-812
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutic
CFS-L09-1313-T01-A
CFS-L09-1313-T02-A
CFS-L09-1313-T03-A
CFS-L09-1313-T04-A
CFS-L09-1313-T05-A
CFS-L09-1313-T06-A
CFS-L09-1313-T07-A
CFS-L09-1313-T08-A
CFS-L09-1313-T09-A
CFS-L09-1313-T01-B
CFS-L09-1313-T02-B
CFS-L09-1313-T03-B
CFS-L09-1313-T04-B
CFS-L09-1313-T05-B
CFS-L09-1313-T06-B
CFS-L09-1313-T07-B
CFS-L09-1313-T08-B
CFS-L09-1313-T09-B
CFS-L09-1313-T01-C
CFS-L09-1313-T02-C
CFS-L09-1313-T03-C
CFS-L09-1313-T04-C
CFS-L09-1313-T05-C
CFS-L09-1313-T06-C
CFS-L09-1313-T07-C
CFS-L09-1313-T08-C
CFS-L09-1313-T09-C
CFS-L09-1313-B01-A
CFS-L09-1313-B02-A
CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 9.13E+00
1 2.42E+01
1 1.89E+02
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 2.06E+01
1 2.07E+01
1 3.07E+02
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 2.38E+00 E
1 2.38E+01
1 4.01 E+02
1 1.00E+OOU1/2
1 6.78E+00
1 4.19E+OOE
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 5.6E+01 2.0E+00 6.4E+00 10 100
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 8.2E+01 2.0E+00 6.4E+00
9.13E+00 2.9E+00 2.0E+00 6.4E+00
2.42E+01 5.1E+00 2.0E+00 6.4E+00
1.89E+02 3.4E-01 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00 10 100
1.00E+00 8.5E+01 2.0E+00 6.4E+00
1.00E+00 1.1 E+02 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 5.5E+01 2.0E+00 6.4E+00
2.06E+01 1.9E+00 2.0E+00 6.4E+00
2.07E+01 3.1E+00 2.0E+00 6.4E+00
3.07E+02 7.5E-01 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 4.1E+01 2.0E+00 6.4E+00 10 100
1.00E+00 9.8E+01 2.0E+00 6.4E+00
1.00E+00 1.1 E+02 2.0E+00 6.4E+00
1.00E+00 8.8E+01 2.0E+00 6.4E+00
1.00E+00 8.5E+01 2.0E+00 6.4E+00
2.38E+00 1.2E+01 2.0E+00 6.4E+00
2.38E+01 9.3E+00 2.0E+00 6.4E+00
4.01 E+02 1.0E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
6.78E+00 1.5E+00 2.0E+00 6.4E+00
4.19E+00 8.8E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.42E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-813
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V CFS-L09-1313-T01-A
V CFS-L09-1313-T02-A
V CFS-L09-1313-T03-A
V CFS-L09-1313-T04-A
V CFS-L09-1313-T05-A
V CFS-L09-1313-T06-A
V CFS-L09-1313-T07-A
V CFS-L09-1313-T08-A
V CFS-L09-1313-T09-A
V CFS-L09-1313-T01-B
V CFS-L09-1313-T02-B
V CFS-L09-1313-T03-B
V CFS-L09-1313-T04-B
V CFS-L09-1313-T05-B
V CFS-L09-1313-T06-B
V CFS-L09-1313-T07-B
V CFS-L09-1313-T08-B
V CFS-L09-1313-T09-B
V CFS-L09-1313-T01-C
V CFS-L09-1313-T02-C
V CFS-L09-1313-T03-C
V CFS-L09-1313-T04-C
V CFS-L09-1313-T05-C
V CFS-L09-1313-T06-C
V CFS-L09-1313-T07-C
V CFS-L09-1313-T08-C
V CFS-L09-1313-T09-C
V CFS-L09-1313-B01-A
V CFS-L09-1313-B02-A
V CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.92E+01
1 1.82E+01
1 1.92E+01
1 2.42E+01
1 2.47E+01
1 2.55E+01
1 3.56E+01
1 4.12E+01
1 5.21 E+02
1 1.87E+01
1 1.84E+01
1 2.12E+01
1 2.19E+01
1 2.32E+01
1 2.62E+01
1 4.22E+01
1 3.99E+01
1 5.37E+02
1 1.91E+01
1 1.97E+01
1 2.20E+01
1 2.51 E+01
1 2.48E+01
1 2.58E+01
1 2.93E+01
1 3.76E+01
1 5.19E+02
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.92E+01 4.4E+00 1.5E+00 4.8E+00
1.82E+01 1.3E+01 1.5E+00 4.8E+00 10 100
1.92E+01 4.4E+00 1.5E+00 4.8E+00
2.42E+01 3.1E+00 1.5E+00 4.8E+00
2.47E+01 3.7E+00 1.5E+00 4.8E+00
2.55E+01 1.2E+00 1.5E+00 4.8E+00
3.56E+01 3.1E-01 1.5E+00 4.8E+00
4.12E+01 3.0E+00 1.5E+00 4.8E+00
5.21 E+02 1.7E+00 1.5E+00 4.8E+00
1.87E+01 1.3E+01 1.5E+00 4.8E+00
1.84E+01 1.9E+00 1.5E+00 4.8E+00 10 100
2.12E+01 5.2E+00 1.5E+00 4.8E+00
2.19E+01 1.6E+00 1.5E+00 4.8E+00
2.32E+01 2.5E+00 1.5E+00 4.8E+00
2.62E+01 5.2E-02 1.5E+00 4.8E+00
4.22E+01 2.2E+00 1.5E+00 4.8E+00
3.99E+01 4.9E+00 1.5E+00 4.8E+00
5.37E+02 1.1E+00 1.5E+00 4.8E+00
1.91 E+01 5.6E+00 1.5E+00 4.8E+00
1.97E+01 5.9E+00 1.5E+00 4.8E+00 10 100
2.20E+01 2.7E+00 1.5E+00 4.8E+00
2.51 E+01 2.8E+00 1.5E+00 4.8E+00
2.48E+01 1.9E+00 1.5E+00 4.8E+00
2.58E+01 2.4E+00 1.5E+00 4.8E+00
2.93E+01 3.5E+00 1.5E+00 4.8E+00
3.76E+01 4.6E+00 1.5E+00 4.8E+00
5.19E+02 1.2E+00 1.5E+00 4.8E+00
7.50E-01 4.0E+01 1.5E+00 4.8E+00
7.50E-01 5.8E+00 1.5E+00 4.8E+00
7.50E-01 1.8E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.01E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.56E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/1 1 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-814
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn CFS-L09-1313-T01-A
Zn CFS-L09-1313-T02-A
Zn CFS-L09-1313-T03-A
Zn CFS-L09-1313-T04-A
Zn CFS-L09-1313-T05-A
Zn CFS-L09-1313-T06-A
Zn CFS-L09-1313-T07-A
Zn CFS-L09-1313-T08-A
Zn CFS-L09-1313-T09-A
Zn CFS-L09-1313-T01-B
Zn CFS-L09-1313-T02-B
Zn CFS-L09-1313-T03-B
Zn CFS-L09-1313-T04-B
Zn CFS-L09-1313-T05-B
Zn CFS-L09-1313-T06-B
Zn CFS-L09-1313-T07-B
Zn CFS-L09-1313-T08-B
Zn CFS-L09-1313-T09-B
Zn CFS-L09-1313-T01-C
Zn CFS-L09-1313-T02-C
Zn CFS-L09-1313-T03-C
Zn CFS-L09-1313-T04-C
Zn CFS-L09-1313-T05-C
Zn CFS-L09-1313-T06-C
Zn CFS-L09-1313-T07-C
Zn CFS-L09-1313-T08-C
Zn CFS-L09-1313-T09-C
Zn CFS-L09-1313-B01-A
Zn CFS-L09-1313-B02-A
Zn CFS-L09-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 7.10E+03
1 1.57E+03
1 3.63E+01
1 3.38E+01
1 2.05E+04
1 6.89E+04
1 1.62E+05
1 1.62E+05
1 1.52E+05
1 1.25E+04
1 6.95E+03
1 2.28E+01
1 3.47E+01
1 1.72E+04
1 7.24E+04
1 1.62E+05
1 1.60E+05
1 1.55E+05
1 4.03E+03
1 7.56E+03
1 2.80E+01
1 3.30E+01
1 2.28E+04
1 7.09E+04
1 1.38E+05
1 1.59E+05
1 1.46E+05
1 2.61 E+00 E
1 3.98E+00
1 3.59E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.10E+03 2.8E+00 1.0E+00 3.2E+00
1.57E+03 2.3E-01 1.0E+00 3.2E+00 10 100
3.63E+01 9.0E-01 1.0E+00 3.2E+00
3.38E+01 1.6E+00 1.0E+00 3.2E+00
2.05E+04 6.9E-01 1.0E+00 3.2E+00
6.89E+04 2.0E+00 1.0E+00 3.2E+00
1.62E+05 9.2E-01 1.0E+00 3.2E+00
1.62E+05 2.2E+00 1.0E+00 3.2E+00
1.52E+05 2.1 E+00 1.0E+00 3.2E+00
1.25E+04 1.9E+00 1.0E+00 3.2E+00
6.95E+03 1.6E+00 1.0E+00 3.2E+00 10 100
2.28E+01 1.5E+00 1.0E+00 3.2E+00
3.47E+01 7.7E-01 1.0E+00 3.2E+00
1.72E+04 4.7E-01 1.0E+00 3.2E+00
7.24E+04 5.2E-01 1.0E+00 3.2E+00
1.62E+05 2.2E+00 1.0E+00 3.2E+00
1.60E+05 1.2E+00 1.0E+00 3.2E+00
1.55E+05 1.6E+00 1.0E+00 3.2E+00
4.03E+03 1.0E+00 1.0E+00 3.2E+00
7.56E+03 1.3E+00 1.0E+00 3.2E+00 10 100
2.80E+01 1.8E+00 1.0E+00 3.2E+00
3.30E+01 2.6E-01 1.0E+00 3.2E+00
2.28E+04 1.2E+00 1.0E+00 3.2E+00
7.09E+04 3.7E-01 1.0E+00 3.2E+00
1.38E+05 6.4E-01 1.0E+00 3.2E+00
1.59E+05 1.4E+00 1.0E+00 3.2E+00
1.46E+05 2.4E-01 1.0E+00 3.2E+00
2.61 E+00 4.5E+00 1.0E+00 3.2E+00
3.98E+00 1.7E+00 1.0E+00 3.2E+00
3.59E+00 2.7E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.49E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.81 E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.48E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/19/11 4:04 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:06 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:07 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:09 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:11 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:12 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:34 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:36 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:17 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:24 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:26 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:27 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:29 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:30 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:32 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:38 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:37 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:39 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:40 PM EPA Interlab L09 1313-1316CFS
4/19/11 4:42 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:44 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:45 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:47 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:41 PM EPA Interlab L09 1313-1316 CFS
4/19/11 5:43 PM EPA Interlab L09 1313-1316 CFS
4/19/11 4:52 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:49 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:51 PM EPA Interlab L09 1313-1316 CFS
4/19/11 3:53 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                          1-815
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L10-1313-T01-A 1 1.01E+02
CFS-L10-1313-T02-A 1 1.06E+02
CFS-L10-1313-T03-A 1 7.87E+01
CFS-L10-1313-T04-A 1 5.33E+01
CFS-L10-1313-T05-A 1 4.42E+01
CFS-L10-1313-T06-A 1 2.36E+02
CFS-L10-1313-T07-A 1 4.61 E+03
CFS-L10-1313-T08-A 1 2.72E+04
CFS-L10-1313-T09-A 1 7.10E+04
CFS-L10-1313-T10-A 1 5.06E+01
CFS-L10-1313-T01-B 1 1.08E+02
CFS-L10-1313-T02-B 1 1.20E+02
CFS-L10-1313-T03-B 1 8.60E+01
CFS-L10-1313-T04-B 1 5.02E+01
CFS-L10-1313-T05-B 1 4.59E+01
CFS-L10-1313-T06-B 1 1.97E+02
CFS-L10-1313-T07-B 1 4.58E+03
CFS-L10-1313-T08-B 1 2.66E+04
CFS-L10-1313-T09-B 1 6.73E+04
CFS-L10-1313-T10-B 1 4.65E+01
CFS-L10-1313-T01-C 1 1.04E+02
CFS-L10-1313-T02-C 1 1.25E+02
CFS-L10-1313-T03-C 1 8.94E+01
CFS-L10-1313-T04-C 1 5.50E+01
CFS-L10-1313-T05-C 1 4.79E+01
CFS-L10-1313-T06-C 1 1.94E+02
CFS-L10-1313-T07-C 1 4.53E+03
CFS-L10-1313-T08-C 1 2.71E+04
CFS-L10-1313-T09-C 1 6.92E+04
CFS-L10-1313-T10-C 1 5.01 E+01
CFS-L10-1313-B01-A 1 5.00E-01 U1/2
CFS-L10-1313-B02-A 1 5.00E-01 U1/2
CFS-L10-1313-B03-A 1 1.16E+00 E
CFS-L10-1313-B01-B 1 5.00E-01 U1/2
CFS-L10-1313-B02-B 1 5.00E-01 U1/2
CFS-L10-1313-B03-B 1 5.00E-01 U1/2
CFS-L10-1313-B01-C 1 5.00E-01 U1/2
CFS-L10-1313-B02-C 1 1.10E+00 E
CFS-L10-1313-B03-C 1 4.58E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.01E+02 2.5E+00 1.0E+00 3.2E+00
1.06E+02 2.0E+00 1.0E+00 3.2E+00 1000 100
7.87E+01 1.4E+00 1.0E+00 3.2E+00
5.33E+01 1.5E+00 1.0E+00 3.2E+00
4.42E+01 7.4E+00 1.0E+00 3.2E+00
2.36E+02 3.1E+00 1.0E+00 3.2E+00
4.61 E+03 3.2E-01 1.0E+00 3.2E+00
2.72E+04 9.9E-01 1.0E+00 3.2E+00
7.10E+04 5.3E-01 1.0E+00 3.2E+00
5.06E+01 7.2E+00 1.0E+00 3.2E+00
1.08E+02 2.0E+00 1.0E+00 3.2E+00
1.20E+02 3.1E+00 1.0E+00 3.2E+00 1000 100
8.60E+01 2.6E+00 1.0E+00 3.2E+00
5.02E+01 3.5E+00 1.0E+00 3.2E+00
4.59E+01 4.9E+00 1.0E+00 3.2E+00
1.97E+02 8.4E-01 1.0E+00 3.2E+00
4.58E+03 3.0E-01 1.0E+00 3.2E+00
2.66E+04 4.0E-01 1.0E+00 3.2E+00
6.73E+04 1.1E+00 1.0E+00 3.2E+00
4.65E+01 7.4E+00 1.0E+00 3.2E+00
1.04E+02 2.9E+00 1.0E+00 3.2E+00
1.25E+02 2.0E+00 1.0E+00 3.2E+00 1000 100
8.94E+01 3.5E+00 1.0E+00 3.2E+00
5.50E+01 4.3E+00 1.0E+00 3.2E+00
4.79E+01 2.9E+00 1.0E+00 3.2E+00
1.94E+02 2.2E+00 1.0E+00 3.2E+00
4.53E+03 6.5E-01 1.0E+00 3.2E+00
2.71 E+04 6.4E-01 1.0E+00 3.2E+00
6.92E+04 2.2E-01 1.0E+00 3.2E+00
5.01 E+01 5.4E+00 1.0E+00 3.2E+00
5.00E-01 2.2E+01 1.0E+00 3.2E+00
5.00E-01 1.8E+02 1.0E+00 3.2E+00
1.16E+00 7.4E+01 1.0E+00 3.2E+00
5.00E-01 3.6E+01 1.0E+00 3.2E+00
5.00E-01 1.7E+02 1.0E+00 3.2E+00
5.00E-01 3.0E+02 1.0E+00 3.2E+00
5.00E-01 7.2E+02 1.0E+00 3.2E+00
1.10E+00 1.0E+02 1.0E+00 3.2E+00
4.58E+00 8.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
1.16E+03 106% VU ICP-OES 4/13/11 2:39 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
1.11E+03 99% VU ICP-OES 4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:16 PM EPA Interlab L10 1313-1316CFS
1.17E+03 105% VU ICP-OES 4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:19 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 3:20 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:24 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 3:25 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:29 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 3:30 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 2:23 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 2:24 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:28 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 2:29 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 2:31 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 2:33 PM EPA Interlab L10 1313-1316CFS
VU ICP-OES 4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                                     1-816
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb CFS-L10-1313-T01-A
Sb CFS-L10-1313-T02-A
Sb CFS-L10-1313-T03-A
Sb CFS-L10-1313-T04-A
Sb CFS-L10-1313-T05-A
Sb CFS-L10-1313-T06-A
Sb CFS-L10-1313-T07-A
Sb CFS-L10-1313-T08-A
Sb CFS-L10-1313-T09-A
Sb CFS-L10-1313-T10-A
Sb CFS-L10-1313-T01-B
Sb CFS-L10-1313-T02-B
Sb CFS-L10-1313-T03-B
Sb CFS-L10-1313-T04-B
Sb CFS-L10-1313-T05-B
Sb CFS-L10-1313-T06-B
Sb CFS-L10-1313-T07-B
Sb CFS-L10-1313-T08-B
Sb CFS-L10-1313-T09-B
Sb CFS-L10-1313-T10-B
Sb CFS-L10-1313-T01-C
Sb CFS-L10-1313-T02-C
Sb CFS-L10-1313-T03-C
Sb CFS-L10-1313-T04-C
Sb CFS-L10-1313-T05-C
Sb CFS-L10-1313-T06-C
Sb CFS-L10-1313-T07-C
Sb CFS-L10-1313-T08-C
Sb CFS-L10-1313-T09-C
Sb CFS-L10-1313-T10-C
Sb CFS-L10-1313-B01-A
Sb CFS-L10-1313-B02-A
Sb CFS-L10-1313-B03-A
Sb CFS-L10-1313-B01-B
Sb CFS-L10-1313-B02-B
Sb CFS-L10-1313-B03-B
Sb CFS-L10-1313-B01-C
Sb CFS-L10-1313-B02-C
Sb CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.84E+01 E
1 1.45E+01 E
1 2.96E+01
1 2.41 E+01
1 2.95E+01
1 4.93E+01
1 1.16E+02
1 7.43E+02
1 1.34E+03
1 3.41 E+01
1 1.40E+01 E
1 1.69E+01 E
1 4.06E+01
1 2.73E+01
1 3.02E+01
1 5.42E+01
1 1.14E+02
1 6.89E+02
1 1.26E+03
1 2.57E+01
1 1.75E+01 E
1 1.39E+01 E
1 4.23E+01
1 3.70E+01
1 2.53E+01
1 4.56E+01
1 1.03E+02
1 7.99E+02
1 1.37E+03
1 4.48E+01
1 3.75E+00 U1/2
1 1.03E+01 E
1 4.53E+01
1 1.13E+01 E
1 8.85E+00 E
1 2.09E+01 E
1 9.82E+00 E
1 3.75E+00 U1/2
1 2.25E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.84E+01 5.6E+00 7.5E+00 2.4E+01
1.45E+01 8.9E+01 7.5E+00 2.4E+01 10 120
2.96E+01 1.9E+01 7.5E+00 2.4E+01
2.41E+01 2.8E+01 7.5E+00 2.4E+01
2.95E+01 2.9E+01 7.5E+00 2.4E+01
4.93E+01 5.5E+00 7.5E+00 2.4E+01
1.16E+02 1.2E+01 7.5E+00 2.4E+01
7.43E+02 1.6E+01 7.5E+00 2.4E+01
1.34E+03 6.6E+00 7.5E+00 2.4E+01
3.41 E+01 2.1 E+01 7.5E+00 2.4E+01
1.40E+01 6.3E+00 7.5E+00 2.4E+01
1.69E+01 5.3E+01 7.5E+00 2.4E+01 10 120
4.06E+01 5.6E+00 7.5E+00 2.4E+01
2.73E+01 2.6E+01 7.5E+00 2.4E+01
3.02E+01 1.2E+01 7.5E+00 2.4E+01
5.42E+01 1.5E+01 7.5E+00 2.4E+01
1.14E+02 7.0E+00 7.5E+00 2.4E+01
6.89E+02 2.0E+01 7.5E+00 2.4E+01
1.26E+03 1.0E+01 7.5E+00 2.4E+01
2.57E+01 2.8E+01 7.5E+00 2.4E+01
1.75E+01 1.8E+01 7.5E+00 2.4E+01
1.39E+01 3.1E+01 7.5E+00 2.4E+01 10 120
4.23E+01 8.2E+00 7.5E+00 2.4E+01
3.70E+01 1.2E+01 7.5E+00 2.4E+01
2.53E+01 2.4E+01 7.5E+00 2.4E+01
4.56E+01 2.2E+01 7.5E+00 2.4E+01
1.03E+02 1.6E+01 7.5E+00 2.4E+01
7.99E+02 3.4E+00 7.5E+00 2.4E+01
1.37E+03 4.4E+00 7.5E+00 2.4E+01
4.48E+01 2.3E+01 7.5E+00 2.4E+01
3.75E+00 1.5E+02 7.5E+00 2.4E+01
1.03E+01 1.4E+02 7.5E+00 2.4E+01
4.53E+01 9.2E+00 7.5E+00 2.4E+01
1.13E+01 5.3E+01 7.5E+00 2.4E+01
8.85E+00 6.6E+01 7.5E+00 2.4E+01
2.09E+01 2.6E+01 7.5E+00 2.4E+01
9.82E+00 1.0E+02 7.5E+00 2.4E+01
3.75E+00 4.6E+02 7.5E+00 2.4E+01
2.25E+01 2.0E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.16E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-817
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As CFS-L10-1313-T01-A
As CFS-L10-1313-T02-A
As CFS-L10-1313-T03-A
As CFS-L10-1313-T04-A
As CFS-L10-1313-T05-A
As CFS-L10-1313-T06-A
As CFS-L10-1313-T07-A
As CFS-L10-1313-T08-A
As CFS-L10-1313-T09-A
As CFS-L10-1313-T10-A
As CFS-L10-1313-T01-B
As CFS-L10-1313-T02-B
As CFS-L10-1313-T03-B
As CFS-L10-1313-T04-B
As CFS-L10-1313-T05-B
As CFS-L10-1313-T06-B
As CFS-L10-1313-T07-B
As CFS-L10-1313-T08-B
As CFS-L10-1313-T09-B
As CFS-L10-1313-T10-B
As CFS-L10-1313-T01-C
As CFS-L10-1313-T02-C
As CFS-L10-1313-T03-C
As CFS-L10-1313-T04-C
As CFS-L10-1313-T05-C
As CFS-L10-1313-T06-C
As CFS-L10-1313-T07-C
As CFS-L10-1313-T08-C
As CFS-L10-1313-T09-C
As CFS-L10-1313-T10-C
As CFS-L10-1313-B01-A
As CFS-L10-1313-B02-A
As CFS-L10-1313-B03-A
As CFS-L10-1313-B01-B
As CFS-L10-1313-B02-B
As CFS-L10-1313-B03-B
As CFS-L10-1313-B01-C
As CFS-L10-1313-B02-C
As CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.33E+02
1 1.90E+02
1 7.48E+01
1 2.72E+01 E
1 1.78E+01 E
1 3.62E+01
1 1.56E+02
1 6.56E+02
1 1.29E+04
1 2.19E+01 E
1 1.09E+02
1 1.89E+02
1 8.10E+01
1 2.92E+01 E
1 2.36E+01 E
1 3.22E+01 E
1 1.63E+02
1 6.18E+02
1 1.29E+04
1 1.31E+01 E
1 1.11E+02
1 2.00E+02
1 8.19E+01
1 2.00E+01 E
1 1.57E+01 E
1 3.40E+01 E
1 1.25E+02
1 7.10E+02
1 1.43E+04
1 1.87E+01 E
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 6.43E+01
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 1.67E+01 E
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+02 5.1E-01 1.1E+01 3.5E+01
1.90E+02 1.7E+00 1.1E+01 3.5E+01 10 120
7.48E+01 4.4E+00 1.1E+01 3.5E+01
2.72E+01 6.6E+00 1.1E+01 3.5E+01
1.78E+01 5.2E+01 1.1E+01 3.5E+01
3.62E+01 2.0E+01 1.1E+01 3.5E+01
1.56E+02 3.9E+00 1.1E+01 3.5E+01
6.56E+02 1.9E+00 1.1E+01 3.5E+01
1.29E+04 3.5E-01 1.1E+01 3.5E+01
2.19E+01 6.0E+01 1.1E+01 3.5E+01
1.09E+02 2.5E+00 1.1E+01 3.5E+01
1.89E+02 1.9E+00 1.1E+01 3.5E+01 10 120
8.10E+01 6.8E+00 1.1E+01 3.5E+01
2.92E+01 4.6E+00 1.1E+01 3.5E+01
2.36E+01 1.6E+01 1.1E+01 3.5E+01
3.22E+01 2.7E+01 1.1E+01 3.5E+01
1.63E+02 5.5E+00 1.1E+01 3.5E+01
6.18E+02 4.6E-01 1.1E+01 3.5E+01
1.29E+04 2.2E+00 1.1E+01 3.5E+01
1.31E+01 4.3E+01 1.1E+01 3.5E+01
1.11E+02 1.2E+00 1.1E+01 3.5E+01
2.00E+02 2.8E+00 1.1E+01 3.5E+01 10 120
8.19E+01 1.1E+01 1.1E+01 3.5E+01
2.00E+01 2.1E+01 1.1E+01 3.5E+01
1.57E+01 2.0E+01 1.1E+01 3.5E+01
3.40E+01 3.2E+01 1.1E+01 3.5E+01
1.25E+02 2.3E+00 1.1E+01 3.5E+01
7.10E+02 1.6E+00 1.1E+01 3.5E+01
1.43E+04 1.7E+00 1.1E+01 3.5E+01
1.87E+01 4.3E+01 1.1E+01 3.5E+01
5.50E+00 6.4E+02 1.1E+01 3.5E+01
5.50E+00 9.1E+01 1.1E+01 3.5E+01
6.43E+01 2.2E+01 1.1E+01 3.5E+01
5.50E+00 1.2E+03 1.1E+01 3.5E+01
5.50E+00 2.9E+02 1.1E+01 3.5E+01
1.67E+01 3.8E+01 1.1E+01 3.5E+01
5.50E+00 4.5E+01 1.1E+01 3.5E+01
5.50E+00 2.0E+02 1.1E+01 3.5E+01
5.50E+00 9.1E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.39E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.42E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-818
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B CFS-L10-1313-T01-A
B CFS-L10-1313-T02-A
B CFS-L10-1313-T03-A
B CFS-L10-1313-T04-A
B CFS-L10-1313-T05-A
B CFS-L10-1313-T06-A
B CFS-L10-1313-T07-A
B CFS-L10-1313-T08-A
B CFS-L10-1313-T09-A
B CFS-L10-1313-T10-A
B CFS-L10-1313-T01-B
B CFS-L10-1313-T02-B
B CFS-L10-1313-T03-B
B CFS-L10-1313-T04-B
B CFS-L10-1313-T05-B
B CFS-L10-1313-T06-B
B CFS-L10-1313-T07-B
B CFS-L10-1313-T08-B
B CFS-L10-1313-T09-B
B CFS-L10-1313-T10-B
B CFS-L10-1313-T01-C
B CFS-L10-1313-T02-C
B CFS-L10-1313-T03-C
B CFS-L10-1313-T04-C
B CFS-L10-1313-T05-C
B CFS-L10-1313-T06-C
B CFS-L10-1313-T07-C
B CFS-L10-1313-T08-C
B CFS-L10-1313-T09-C
B CFS-L10-1313-T10-C
B CFS-L10-1313-B01-A
B CFS-L10-1313-B02-A
B CFS-L10-1313-B03-A
B CFS-L10-1313-B01-B
B CFS-L10-1313-B02-B
B CFS-L10-1313-B03-B
B CFS-L10-1313-B01-C
B CFS-L10-1313-B02-C
B CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 8.29E+01
1 8.60E+01
1 1.46E+02
1 1.16E+02
1 1.39E+02
1 2.12E+02
1 3.34E+02
1 6.11E+02
1 7.49E+02
1 1.63E+02
1 7.81E+01
1 9.53E+01
1 1.55E+02
1 1.23E+02
1 1.57E+02
1 2.37E+02
1 3.41 E+02
1 6.27E+02
1 7.47E+02
1 1.64E+02
1 7.92E+01
1 1.16E+02
1 1.62E+02
1 1.32E+02
1 1.50E+02
1 2.27E+02
1 3.61 E+02
1 6.24E+02
1 7.01 E+02
1 1.72E+02
1 6.99E+00
1 7.08E+00
1 1.63E+01
1 6.43E+00
1 7.11E+00
1 1.54E+01
1 5.71 E+00
1 7.07E+00
1 1.52E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.29E+01 5.2E-01 1.0E+00 3.2E+00
8.60E+01 1.2E+00 1.0E+00 3.2E+00 1000 100
1.46E+02 1.0E+00 1.0E+00 3.2E+00
1.16E+02 2.4E+00 1.0E+00 3.2E+00
1.39E+02 1.4E+00 1.0E+00 3.2E+00
2.12E+02 2.5E-01 1.0E+00 3.2E+00
3.34E+02 7.8E-01 1.0E+00 3.2E+00
6.11E+02 3.9E-01 1.0E+00 3.2E+00
7.49E+02 5.7E-01 1.0E+00 3.2E+00
1.63E+02 1.4E+00 1.0E+00 3.2E+00
7.81 E+01 5.2E+00 1.0E+00 3.2E+00
9.53E+01 5.7E-01 1.0E+00 3.2E+00 1000 100
1.55E+02 3.6E-01 1.0E+00 3.2E+00
1.23E+02 1.3E+00 1.0E+00 3.2E+00
1.57E+02 1.2E+00 1.0E+00 3.2E+00
2.37E+02 1.4E+00 1.0E+00 3.2E+00
3.41 E+02 7.8E-01 1.0E+00 3.2E+00
6.27E+02 1.9E-01 1.0E+00 3.2E+00
7.47E+02 1.5E+00 1.0E+00 3.2E+00
1.64E+02 6.9E-01 1.0E+00 3.2E+00
7.92E+01 1.6E+00 1.0E+00 3.2E+00
1.16E+02 9.8E-01 1.0E+00 3.2E+00 1000 100
1.62E+02 9.9E-01 1.0E+00 3.2E+00
1.32E+02 1.7E-01 1.0E+00 3.2E+00
1.50E+02 1.4E+00 1.0E+00 3.2E+00
2.27E+02 1.4E+00 1.0E+00 3.2E+00
3.61 E+02 1.1 E+00 1.0E+00 3.2E+00
6.24E+02 5.2E-01 1.0E+00 3.2E+00
7.01 E+02 4.5E-01 1.0E+00 3.2E+00
1.72E+02 3.2E-01 1.0E+00 3.2E+00
6.99E+00 9.1 E+00 1.0E+00 3.2E+00
7.08E+00 1.5E+01 1.0E+00 3.2E+00
1.63E+01 6.2E+00 1.0E+00 3.2E+00
6.43E+00 2.4E+01 1.0E+00 3.2E+00
7.11E+00 2.1E+01 1.0E+00 3.2E+00
1.54E+01 1.8E+01 1.0E+00 3.2E+00
5.71 E+00 1.4E+01 1.0E+00 3.2E+00
7.07E+00 1.8E+01 1.0E+00 3.2E+00
1.52E+01 3.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.22E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-819
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba CFS-L10-1313-T01-A
Ba CFS-L10-1313-T02-A
Ba CFS-L10-1313-T03-A
Ba CFS-L10-1313-T04-A
Ba CFS-L10-1313-T05-A
Ba CFS-L10-1313-T06-A
Ba CFS-L10-1313-T07-A
Ba CFS-L10-1313-T08-A
Ba CFS-L10-1313-T09-A
Ba CFS-L10-1313-T10-A
Ba CFS-L10-1313-T01-B
Ba CFS-L10-1313-T02-B
Ba CFS-L10-1313-T03-B
Ba CFS-L10-1313-T04-B
Ba CFS-L10-1313-T05-B
Ba CFS-L10-1313-T06-B
Ba CFS-L10-1313-T07-B
Ba CFS-L10-1313-T08-B
Ba CFS-L10-1313-T09-B
Ba CFS-L10-1313-T10-B
Ba CFS-L10-1313-T01-C
Ba CFS-L10-1313-T02-C
Ba CFS-L10-1313-T03-C
Ba CFS-L10-1313-T04-C
Ba CFS-L10-1313-T05-C
Ba CFS-L10-1313-T06-C
Ba CFS-L10-1313-T07-C
Ba CFS-L10-1313-T08-C
Ba CFS-L10-1313-T09-C
Ba CFS-L10-1313-T10-C
Ba CFS-L10-1313-B01-A
Ba CFS-L10-1313-B02-A
Ba CFS-L10-1313-B03-A
Ba CFS-L10-1313-B01-B
Ba CFS-L10-1313-B02-B
Ba CFS-L10-1313-B03-B
Ba CFS-L10-1313-B01-C
Ba CFS-L10-1313-B02-C
Ba CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.872
1 1.42E+01
1 1.35E+02
1 6.40E+01
1 1.16E+02
1 4.18E+01
1 3.35E+01
1 3.67E+01
1 5.79E+01
1 1.12E+02
1 8.657
1 1.21E+01
1 1.26E+02
1 6.24E+01
1 1.17E+02
1 5.10E+01
1 3.47E+01
1 2.67E+01
1 4.40E+01
1 1.08E+02
1 8.323
1 1.10E+01
1 1.34E+02
1 6.43E+01
1 1.18E+02
1 4.57E+01
1 3.41 E+01
1 3.28E+01
1 4.99E+01
1 1.11E+02
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.92E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 2.36E+01
1 5.00E-01 U1/2
1 1.22E+00 E
1 2.68E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.87E+00 5.2E-01 1.0E+00 3.2E+00
1.42E+01 7.7E-01 1.0E+00 3.2E+00 10 120
1.35E+02 8.1E-01 1.0E+00 3.2E+00
6.40E+01 1.2E+00 1.0E+00 3.2E+00
1.16E+02 8.5E-01 1.0E+00 3.2E+00
4.18E+01 1.0E+00 1.0E+00 3.2E+00
3.35E+01 6.9E-01 1.0E+00 3.2E+00
3.67E+01 5.4E-01 1.0E+00 3.2E+00
5.79E+01 7.0E-01 1.0E+00 3.2E+00
1.12E+02 4.2E-01 1.0E+00 3.2E+00
8.66E+00 3.1E-01 1.0E+00 3.2E+00
1.21E+01 4.4E-01 1.0E+00 3.2E+00 10 120
1.26E+02 6.0E-01 1.0E+00 3.2E+00
6.24E+01 8.3E-01 1.0E+00 3.2E+00
1.17E+02 8.4E-01 1.0E+00 3.2E+00
5.10E+01 1.4E+00 1.0E+00 3.2E+00
3.47E+01 3.5E-01 1.0E+00 3.2E+00
2.67E+01 6.3E-01 1.0E+00 3.2E+00
4.40E+01 1.2E+00 1.0E+00 3.2E+00
1.08E+02 1.1E-01 1.0E+00 3.2E+00
8.32E+00 5.5E-01 1.0E+00 3.2E+00
1.10E+01 2.0E+00 1.0E+00 3.2E+00 10 120
1.34E+02 7.3E-02 1.0E+00 3.2E+00
6.43E+01 4.0E-01 1.0E+00 3.2E+00
1.18E+02 2.6E-01 1.0E+00 3.2E+00
4.57E+01 2.9E-01 1.0E+00 3.2E+00
3.41 E+01 1.0E+00 1.0E+00 3.2E+00
3.28E+01 3.8E-01 1.0E+00 3.2E+00
4.99E+01 3.6E-01 1.0E+00 3.2E+00
1.11E+02 7.4E-02 1.0E+00 3.2E+00
5.00E-01 3.1 E+01 1.0E+00 3.2E+00
5.00E-01 3.0E+00 1.0E+00 3.2E+00
1.92E+01 2.8E+00 1.0E+00 3.2E+00
5.00E-01 1.3E+01 1.0E+00 3.2E+00
5.00E-01 9.6E+00 1.0E+00 3.2E+00
2.36E+01 6.4E+00 1.0E+00 3.2E+00
5.00E-01 6.0E+00 1.0E+00 3.2E+00
1.22E+00 1.5E+00 1.0E+00 3.2E+00
2.68E+01 1.9E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.18E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/17/11 12:16 PM EPA Interlab 1313-1316 CFS Reruns
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
6/17/11 12:38 PM EPA Interlab 1313-1316 CFS Reruns
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
6/17/11 1:00 PM EPA Interlab 1313-1316 CFS Reruns
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-820
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be CFS-L10-1313-T01-A
Be CFS-L10-1313-T02-A
Be CFS-L10-1313-T03-A
Be CFS-L10-1313-T04-A
Be CFS-L10-1313-T05-A
Be CFS-L10-1313-T06-A
Be CFS-L10-1313-T07-A
Be CFS-L10-1313-T08-A
Be CFS-L10-1313-T09-A
Be CFS-L10-1313-T10-A
Be CFS-L10-1313-T01-B
Be CFS-L10-1313-T02-B
Be CFS-L10-1313-T03-B
Be CFS-L10-1313-T04-B
Be CFS-L10-1313-T05-B
Be CFS-L10-1313-T06-B
Be CFS-L10-1313-T07-B
Be CFS-L10-1313-T08-B
Be CFS-L10-1313-T09-B
Be CFS-L10-1313-T10-B
Be CFS-L10-1313-T01-C
Be CFS-L10-1313-T02-C
Be CFS-L10-1313-T03-C
Be CFS-L10-1313-T04-C
Be CFS-L10-1313-T05-C
Be CFS-L10-1313-T06-C
Be CFS-L10-1313-T07-C
Be CFS-L10-1313-T08-C
Be CFS-L10-1313-T09-C
Be CFS-L10-1313-T10-C
Be CFS-L10-1313-B01-A
Be CFS-L10-1313-B02-A
Be CFS-L10-1313-B03-A
Be CFS-L10-1313-B01-B
Be CFS-L10-1313-B02-B
Be CFS-L10-1313-B03-B
Be CFS-L10-1313-B01-C
Be CFS-L10-1313-B02-C
Be CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.66E+00 E
1 6.50E+00
1 2.70E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.82E+00 E
1 6.04E+00
1 2.78E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.88E+00 E
1 6.03E+00
1 2.68E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.6E+02 1.9E+00 6.0E+00
9.50E-01 3.0E+02 1.9E+00 6.0E+00 10 120
9.50E-01 1.9E+03 1.9E+00 6.0E+00
9.50E-01 5.0E+01 1.9E+00 6.0E+00
9.50E-01 8.0E+02 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
2.66E+00 5.2E+00 1.9E+00 6.0E+00
6.50E+00 5.8E+00 1.9E+00 6.0E+00
2.70E+00 1.9E+01 1.9E+00 6.0E+00
9.50E-01 3.2E+01 1.9E+00 6.0E+00
9.50E-01 4.2E+02 1.9E+00 6.0E+00
9.50E-01 2.9E+02 1.9E+00 6.0E+00 10 120
9.50E-01 3.9E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 2.8E+01 1.9E+00 6.0E+00
2.82E+00 6.5E+00 1.9E+00 6.0E+00
6.04E+00 5.2E+00 1.9E+00 6.0E+00
2.78E+00 1.6E+01 1.9E+00 6.0E+00
9.50E-01 3.9E+02 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+03 1.9E+00 6.0E+00 10 120
9.50E-01 4.0E+03 1.9E+00 6.0E+00
9.50E-01 3.3E+03 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 3.0E+01 1.9E+00 6.0E+00
2.88E+00 1.5E+00 1.9E+00 6.0E+00
6.03E+00 5.4E+00 1.9E+00 6.0E+00
2.68E+00 2.5E+01 1.9E+00 6.0E+00
9.50E-01 8.0E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 3.4E+02 1.9E+00 6.0E+00
9.50E-01 6.0E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 3.1E+02 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.18E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L1 01 31 3-1 31 6 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-821
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd CFS-L10-1313-T01-A
Cd CFS-L10-1313-T02-A
Cd CFS-L10-1313-T03-A
Cd CFS-L10-1313-T04-A
Cd CFS-L10-1313-T05-A
Cd CFS-L10-1313-T06-A
Cd CFS-L10-1313-T07-A
Cd CFS-L10-1313-T08-A
Cd CFS-L10-1313-T09-A
Cd CFS-L10-1313-T10-A
Cd CFS-L10-1313-T01-B
Cd CFS-L10-1313-T02-B
Cd CFS-L10-1313-T03-B
Cd CFS-L10-1313-T04-B
Cd CFS-L10-1313-T05-B
Cd CFS-L10-1313-T06-B
Cd CFS-L10-1313-T07-B
Cd CFS-L10-1313-T08-B
Cd CFS-L10-1313-T09-B
Cd CFS-L10-1313-T10-B
Cd CFS-L10-1313-T01-C
Cd CFS-L10-1313-T02-C
Cd CFS-L10-1313-T03-C
Cd CFS-L10-1313-T04-C
Cd CFS-L10-1313-T05-C
Cd CFS-L10-1313-T06-C
Cd CFS-L10-1313-T07-C
Cd CFS-L10-1313-T08-C
Cd CFS-L10-1313-T09-C
Cd CFS-L10-1313-T10-C
Cd CFS-L10-1313-B01-A
Cd CFS-L10-1313-B02-A
Cd CFS-L10-1313-B03-A
Cd CFS-L10-1313-B01-B
Cd CFS-L10-1313-B02-B
Cd CFS-L10-1313-B03-B
Cd CFS-L10-1313-B01-C
Cd CFS-L10-1313-B02-C
Cd CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 7.16E+00
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 9.50E+01
1 1.80E+03
1 1.25E+04
1 2.42E+04
1 4.52E+04
1 4.68E+04
1 4.17E+03
1 7.41 E+00
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 8.51 E+01
1 2.22E+03
1 1.34E+04
1 2.44E+04
1 4.47E+04
1 4.73E+04
1 4.15E+03
1 9.37E+00
1 1.10E+00 U1/2
1 2.24E+00 E
1 1.08E+02
1 2.21 E+03
1 1.28E+04
1 2.55E+04
1 4.57E+04
1 4.76E+04
1 4.39E+03
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.16E+00 1.3E+00 2.2E+00 7.0E+00
1.10E+00 3.2E+01 2.2E+00 7.0E+00 10 120
1.10E+00 8.3E+00 2.2E+00 7.0E+00
9.50E+01 1.8E+00 2.2E+00 7.0E+00
1.80E+03 4.9E-01 2.2E+00 7.0E+00
1.25E+04 9.6E-01 2.2E+00 7.0E+00
2.42E+04 7.1E-01 2.2E+00 7.0E+00
4.52E+04 1.1 E+00 2.2E+00 7.0E+00
4.68E+04 4.4E-01 2.2E+00 7.0E+00
4.17E+03 3.6E-01 2.2E+00 7.0E+00
7.41 E+00 7.8E+00 2.2E+00 7.0E+00
1.10E+00 1.6E+01 2.2E+00 7.0E+00 10 120
1.10E+00 2.1E+01 2.2E+00 7.0E+00
8.51 E+01 8.6E-01 2.2E+00 7.0E+00
2.22E+03 9.3E-01 2.2E+00 7.0E+00
1.34E+04 1.2E+00 2.2E+00 7.0E+00
2.44E+04 8.0E-01 2.2E+00 7.0E+00
4.47E+04 5.2E-01 2.2E+00 7.0E+00
4.73E+04 1.2E+00 2.2E+00 7.0E+00
4.15E+03 3.7E-01 2.2E+00 7.0E+00
9.37E+00 1.8E+00 2.2E+00 7.0E+00
1.10E+00 1.0E+01 2.2E+00 7.0E+00 10 120
2.24E+00 1.2E+01 2.2E+00 7.0E+00
1.08E+02 8.0E-01 2.2E+00 7.0E+00
2.21 E+03 4.2E-01 2.2E+00 7.0E+00
1.28E+04 4.2E-01 2.2E+00 7.0E+00
2.55E+04 6.6E-01 2.2E+00 7.0E+00
4.57E+04 1.7E-01 2.2E+00 7.0E+00
4.76E+04 2.4E-01 2.2E+00 7.0E+00
4.39E+03 5.6E-01 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00
1.10E+00 9.9E+01 2.2E+00 7.0E+00
1.10E+00 4.2E+02 2.2E+00 7.0E+00
1.10E+00 1.4E+02 2.2E+00 7.0E+00
1.10E+00 6.4E+01 2.2E+00 7.0E+00
1.10E+00 1.6E+01 2.2E+00 7.0E+00
1.10E+00 6.8E+01 2.2E+00 7.0E+00
1.10E+00 6.9E+01 2.2E+00 7.0E+00
1.10E+00 6.4E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 . 1 1 E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L1 01 31 3-1 31 6 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-822
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
CFS-L10-1313-T01-A
CFS-L10-1313-T02-A
CFS-L10-1313-T03-A
CFS-L10-1313-T04-A
CFS-L10-1313-T05-A
CFS-L10-1313-T06-A
CFS-L10-1313-T07-A
CFS-L10-1313-T08-A
CFS-L10-1313-T09-A
CFS-L10-1313-T10-A
CFS-L10-1313-T01-B
CFS-L10-1313-T02-B
CFS-L10-1313-T03-B
CFS-L10-1313-T04-B
CFS-L10-1313-T05-B
CFS-L10-1313-T06-B
CFS-L10-1313-T07-B
CFS-L10-1313-T08-B
CFS-L10-1313-T09-B
CFS-L10-1313-T10-B
CFS-L10-1313-T01-C
CFS-L10-1313-T02-C
CFS-L10-1313-T03-C
CFS-L10-1313-T04-C
CFS-L10-1313-T05-C
CFS-L10-1313-T06-C
CFS-L10-1313-T07-C
CFS-L10-1313-T08-C
CFS-L10-1313-T09-C
CFS-L10-1313-T10-C
CFS-L10-1313-B01-A
CFS-L10-1313-B02-A
CFS-L10-1313-B03-A
CFS-L10-1313-B01-B
CFS-L10-1313-B02-B
CFS-L10-1313-B03-B
CFS-L10-1313-B01-C
CFS-L10-1313-B02-C
CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.89E+05
1 5.62E+05
1 5.81 E+05
1 6.12E+05
1 6.32E+05
1 7. 11 E+05
1 8.60E+05
1 1.26E+06
1 1.47E+06
1 6.54E+05
1 2.04E+05
1 5.47E+05
1 5.76E+05
1 6.06E+05
1 6.38E+05
1 7.45E+05
1 8.77E+05
1 1.24E+06
1 1.40E+06
1 6.34E+05
1 1.99E+05
1 5.58E+05
1 6.03E+05
1 6.35E+05
1 6.56E+05
1 7.02E+05
1 8.96E+05
1 1.26E+06
1 1.44E+06
1 6.59E+05
1 2.63E+01
1 2.49E+01
1 7.46E+01
1 2.18E+01
1 1.71E+01
1 5.79E+01
1 2.12E+01
1 1.80E+01
1 8.13E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.89E+05 3.6E-01 2.6E+00 8.3E+00
5.62E+05 5.6E-01 2.6E+00 8.3E+00 1000 100
5.81 E+05 9.4E-01 2.6E+00 8.3E+00
6.12E+05 1.0E+00 2.6E+00 8.3E+00
6.32E+05 4.3E-01 2.6E+00 8.3E+00
7.11E+05 4.7E-01 2.6E+00 8.3E+00
8.60E+05 7.1E-01 2.6E+00 8.3E+00
1.26E+06 1.2E+00 2.6E+00 8.3E+00
1.47E+06 1.3E+00 2.6E+00 8.3E+00
6.54E+05 4.4E-01 2.6E+00 8.3E+00
2.04E+05 4.3E-01 2.6E+00 8.3E+00
5.47E+05 4.6E-01 2.6E+00 8.3E+00 1000 100
5.76E+05 9.8E-01 2.6E+00 8.3E+00
6.06E+05 9.6E-01 2.6E+00 8.3E+00
6.38E+05 6.3E-01 2.6E+00 8.3E+00
7.45E+05 1.1E+00 2.6E+00 8.3E+00
8.77E+05 2.8E-01 2.6E+00 8.3E+00
1.24E+06 6.5E-01 2.6E+00 8.3E+00
1.40E+06 1.5E+00 2.6E+00 8.3E+00
6.34E+05 3.8E-01 2.6E+00 8.3E+00
1.99E+05 5.6E-01 2.6E+00 8.3E+00
5.58E+05 1.7E+00 2.6E+00 8.3E+00 1000 100
6.03E+05 7.1E-01 2.6E+00 8.3E+00
6.35E+05 7.6E-01 2.6E+00 8.3E+00
6.56E+05 4.3E-01 2.6E+00 8.3E+00
7.02E+05 4.9E-01 2.6E+00 8.3E+00
8.96E+05 1.7E+00 2.6E+00 8.3E+00
1.26E+06 5.4E-01 2.6E+00 8.3E+00
1.44E+06 1.9E+00 2.6E+00 8.3E+00
6.59E+05 8.7E-01 2.6E+00 8.3E+00
2.63E+01 1.9E+01 2.6E+00 8.3E+00
2.49E+01 4.1E+00 2.6E+00 8.3E+00
7.46E+01 4.1E+01 2.6E+00 8.3E+00
2.18E+01 1.2E+01 2.6E+00 8.3E+00
1.71E+01 1.7E+01 2.6E+00 8.3E+00
5.79E+01 3.2E+01 2.6E+00 8.3E+00
2.12E+01 2.2E+01 2.6E+00 8.3E+00
1.80E+01 2.1E+01 2.6E+00 8.3E+00
8.13E+01 2.9E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.63E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.48E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.58E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-823
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr CFS-L10-1313-T01-A
Cr CFS-L10-1313-T02-A
Cr CFS-L10-1313-T03-A
Cr CFS-L10-1313-T04-A
Cr CFS-L10-1313-T05-A
Cr CFS-L10-1313-T06-A
Cr CFS-L10-1313-T07-A
Cr CFS-L10-1313-T08-A
Cr CFS-L10-1313-T09-A
Cr CFS-L10-1313-T10-A
Cr CFS-L10-1313-T01-B
Cr CFS-L10-1313-T02-B
Cr CFS-L10-1313-T03-B
Cr CFS-L10-1313-T04-B
Cr CFS-L10-1313-T05-B
Cr CFS-L10-1313-T06-B
Cr CFS-L10-1313-T07-B
Cr CFS-L10-1313-T08-B
Cr CFS-L10-1313-T09-B
Cr CFS-L10-1313-T10-B
Cr CFS-L10-1313-T01-C
Cr CFS-L10-1313-T02-C
Cr CFS-L10-1313-T03-C
Cr CFS-L10-1313-T04-C
Cr CFS-L10-1313-T05-C
Cr CFS-L10-1313-T06-C
Cr CFS-L10-1313-T07-C
Cr CFS-L10-1313-T08-C
Cr CFS-L10-1313-T09-C
Cr CFS-L10-1313-T10-C
Cr CFS-L10-1313-B01-A
Cr CFS-L10-1313-B02-A
Cr CFS-L10-1313-B03-A
Cr CFS-L10-1313-B01-B
Cr CFS-L10-1313-B02-B
Cr CFS-L10-1313-B03-B
Cr CFS-L10-1313-B01-C
Cr CFS-L10-1313-B02-C
Cr CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.60E+02
1 4.40E+01
1 4.29E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 2.91E+01
1 6.60E+02
1 6.00E-01 U1/2
1 1.58E+02
1 4.76E+01
1 5.41 E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 2.94E+01
1 8.26E+02
1 6.00E-01 U1/2
1 1.36E+02
1 4.70E+01
1 5.65E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 3.49E+01
1 7.61 E+02
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 2.09E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.52E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.78E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.60E+02 1.1 E+00 1.2E+00 3.8E+00
4.40E+01 1.4E+00 1.2E+00 3.8E+00 10 120
4.29E+00 1.5E+01 1.2E+00 3.8E+00
6.00E-01 3.7E+01 1.2E+00 3.8E+00
6.00E-01 2.1E+03 1.2E+00 3.8E+00
6.00E-01 1.5E+02 1.2E+00 3.8E+00
6.00E-01 2.3E+02 1.2E+00 3.8E+00
2.91 E+01 3.2E+00 1.2E+00 3.8E+00
6.60E+02 5.9E-01 1.2E+00 3.8E+00
6.00E-01 2.8E+02 1.2E+00 3.8E+00
1.58E+02 2.1E-01 1.2E+00 3.8E+00
4.76E+01 8.6E-01 1.2E+00 3.8E+00 10 120
5.41 E+00 1.4E+01 1.2E+00 3.8E+00
6.00E-01 8.9E+00 1.2E+00 3.8E+00
6.00E-01 3.6E+01 1.2E+00 3.8E+00
6.00E-01 1.1E+03 1.2E+00 3.8E+00
6.00E-01 1.1 E+02 1.2E+00 3.8E+00
2.94E+01 1.6E+00 1.2E+00 3.8E+00
8.26E+02 1.2E+00 1.2E+00 3.8E+00
6.00E-01 2.8E+02 1.2E+00 3.8E+00
1.36E+02 4.6E-01 1.2E+00 3.8E+00
4.70E+01 3.0E-01 1.2E+00 3.8E+00 10 120
5.65E+00 2.7E+00 1.2E+00 3.8E+00
6.00E-01 9.6E+01 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
6.00E-01 2.4E+02 1.2E+00 3.8E+00
6.00E-01 1.9E+02 1.2E+00 3.8E+00
3.49E+01 1.0E+00 1.2E+00 3.8E+00
7.61 E+02 2.9E-01 1.2E+00 3.8E+00
6.00E-01 8.9E+01 1.2E+00 3.8E+00
6.00E-01 1.5E+02 1.2E+00 3.8E+00
6.00E-01 1.8E+02 1.2E+00 3.8E+00
2.09E+00 1.7E+01 1.2E+00 3.8E+00
6.00E-01 6.2E+02 1.2E+00 3.8E+00
6.00E-01 2.8E+01 1.2E+00 3.8E+00
1.52E+00 7.4E+01 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
6.00E-01 9.3E+00 1.2E+00 3.8E+00
1.78E+00 2.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.16E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L1 01 31 3-1 31 6 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-824
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
CFS-L10-1313-T01-A
CFS-L10-1313-T02-A
CFS-L10-1313-T03-A
CFS-L10-1313-T04-A
CFS-L10-1313-T05-A
CFS-L10-1313-T06-A
CFS-L10-1313-T07-A
CFS-L10-1313-T08-A
CFS-L10-1313-T09-A
CFS-L10-1313-T10-A
CFS-L10-1313-T01-B
CFS-L10-1313-T02-B
CFS-L10-1313-T03-B
CFS-L10-1313-T04-B
CFS-L10-1313-T05-B
CFS-L10-1313-T06-B
CFS-L10-1313-T07-B
CFS-L10-1313-T08-B
CFS-L10-1313-T09-B
CFS-L10-1313-T10-B
CFS-L10-1313-T01-C
CFS-L10-1313-T02-C
CFS-L10-1313-T03-C
CFS-L10-1313-T04-C
CFS-L10-1313-T05-C
CFS-L10-1313-T06-C
CFS-L10-1313-T07-C
CFS-L10-1313-T08-C
CFS-L10-1313-T09-C
CFS-L10-1313-T10-C
CFS-L10-1313-B01-A
CFS-L10-1313-B02-A
CFS-L10-1313-B03-A
CFS-L10-1313-B01-B
CFS-L10-1313-B02-B
CFS-L10-1313-B03-B
CFS-L10-1313-B01-C
CFS-L10-1313-B02-C
CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 4.03E+01
1 2.88E+02
1 6.59E+02
1 1.59E+03
1 1.71E+03
1 9.65E+01
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 5.08E+01
1 3.12E+02
1 6.70E+02
1 1.57E+03
1 1.68E+03
1 9.69E+01
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 5.19E+01
1 2.95E+02
1 6.93E+02
1 1.60E+03
1 1.67E+03
1 1.02E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 9.7E+01 1.8E+00 5.7E+00
9.00E-01 7.8E+01 1.8E+00 5.7E+00 10 120
9.00E-01 9.4E+02 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00
4.03E+01 2.9E+00 1.8E+00 5.7E+00
2.88E+02 8.5E-01 1.8E+00 5.7E+00
6.59E+02 5.8E-01 1.8E+00 5.7E+00
1.59E+03 1.7E+00 1.8E+00 5.7E+00
1.71E+03 1.5E+00 1.8E+00 5.7E+00
9.65E+01 1.6E+00 1.8E+00 5.7E+00
9.00E-01 5.2E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00 10 120
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 8.8E+01 1.8E+00 5.7E+00
5.08E+01 2.8E+00 1.8E+00 5.7E+00
3.12E+02 1.3E+00 1.8E+00 5.7E+00
6.70E+02 1.3E+00 1.8E+00 5.7E+00
1.57E+03 4.7E-01 1.8E+00 5.7E+00
1.68E+03 6.0E-01 1.8E+00 5.7E+00
9.69E+01 2.3E+00 1.8E+00 5.7E+00
9.00E-01 7.3E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+03 1.8E+00 5.7E+00 10 120
9.00E-01 7.3E+01 1.8E+00 5.7E+00
9.00E-01 3.9E+01 1.8E+00 5.7E+00
5.19E+01 3.5E+00 1.8E+00 5.7E+00
2.95E+02 3.5E-01 1.8E+00 5.7E+00
6.93E+02 1.5E+00 1.8E+00 5.7E+00
1.60E+03 7.1E-01 1.8E+00 5.7E+00
1.67E+03 1.0E+00 1.8E+00 5.7E+00
1.02E+02 1.3E+00 1.8E+00 5.7E+00
9.00E-01 6.3E+02 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 6.0E+02 1.8E+00 5.7E+00
9.00E-01 8.2E+01 1.8E+00 5.7E+00
9.00E-01 3.9E+02 1.8E+00 5.7E+00
9.00E-01 2.4E+02 1.8E+00 5.7E+00
9.00E-01 4.2E+01 1.8E+00 5.7E+00
9.00E-01 7.1E+01 1.8E+00 5.7E+00
9.00E-01 2.7E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 . 1 1 E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L1 01 31 3-1 31 6 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-825
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu CFS-L10-1313-T01-A
Cu CFS-L10-1313-T02-A
Cu CFS-L10-1313-T03-A
Cu CFS-L10-1313-T04-A
Cu CFS-L10-1313-T05-A
Cu CFS-L10-1313-T06-A
Cu CFS-L10-1313-T07-A
Cu CFS-L10-1313-T08-A
Cu CFS-L10-1313-T09-A
Cu CFS-L10-1313-T10-A
Cu CFS-L10-1313-T01-B
Cu CFS-L10-1313-T02-B
Cu CFS-L10-1313-T03-B
Cu CFS-L10-1313-T04-B
Cu CFS-L10-1313-T05-B
Cu CFS-L10-1313-T06-B
Cu CFS-L10-1313-T07-B
Cu CFS-L10-1313-T08-B
Cu CFS-L10-1313-T09-B
Cu CFS-L10-1313-T10-B
Cu CFS-L10-1313-T01-C
Cu CFS-L10-1313-T02-C
Cu CFS-L10-1313-T03-C
Cu CFS-L10-1313-T04-C
Cu CFS-L10-1313-T05-C
Cu CFS-L10-1313-T06-C
Cu CFS-L10-1313-T07-C
Cu CFS-L10-1313-T08-C
Cu CFS-L10-1313-T09-C
Cu CFS-L10-1313-T10-C
Cu CFS-L10-1313-B01-A
Cu CFS-L10-1313-B02-A
Cu CFS-L10-1313-B03-A
Cu CFS-L10-1313-B01-B
Cu CFS-L10-1313-B02-B
Cu CFS-L10-1313-B03-B
Cu CFS-L10-1313-B01-C
Cu CFS-L10-1313-B02-C
Cu CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 8.63E+03
1 6.69E+02
1 1.05E+02
1 4.71 E+01
1 1.71E+02
1 3.00E+04
1 2.42E+05
1 8.91 E+05
1 1.03E+06
1 7.52E+02
1 8.38E+03
1 6.26E+02
1 1.25E+02
1 5.57E+01
1 2.28E+02
1 2.51 E+04
1 2.41 E+05
1 8.56E+05
1 9.87E+05
1 7.51 E+02
1 8.12E+03
1 6.42E+02
1 1.30E+02
1 5.53E+01
1 2. 11 E+02
1 2.51 E+04
1 2.47E+05
1 8.77E+05
1 1.02E+06
1 8.12E+02
1 1.85E+00 U1/2
1 7.31 E+00 E
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 4.12E+00 E
1 1.85E+00 U1/2
1 4.30E+00 E
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.63E+03 3.9E+00 3.7E+00 1.2E+01
6.69E+02 1.1 E+00 3.7E+00 1.2E+01 10 120
1.05E+02 1.3E+00 3.7E+00 1.2E+01
4.71 E+01 3.6E-01 3.7E+00 1.2E+01
1.71 E+02 3.5E-01 3.7E+00 1.2E+01
3.00E+04 2.9E-01 3.7E+00 1.2E+01
2.42E+05 9.6E-01 3.7E+00 1.2E+01
8.91 E+05 5.0E-01 3.7E+00 1.2E+01
1.03E+06 1.8E+00 3.7E+00 1.2E+01
7.52E+02 1.0E+00 3.7E+00 1.2E+01
8.38E+03 1.9E+00 3.7E+00 1.2E+01
6.26E+02 4.1E-01 3.7E+00 1.2E+01 10 120
1.25E+02 6.5E-02 3.7E+00 1.2E+01
5.57E+01 4.1 E+00 3.7E+00 1.2E+01
2.28E+02 1.9E+00 3.7E+00 1.2E+01
2.51 E+04 1.3E+00 3.7E+00 1.2E+01
2.41 E+05 1.3E+00 3.7E+00 1.2E+01
8.56E+05 6.9E-01 3.7E+00 1.2E+01
9.87E+05 2.0E+00 3.7E+00 1.2E+01
7.51 E+02 2.8E-01 3.7E+00 1.2E+01
8.12E+03 3.8E+00 3.7E+00 1.2E+01
6.42E+02 7.7E-01 3.7E+00 1.2E+01 10 120
1.30E+02 2.8E+00 3.7E+00 1.2E+01
5.53E+01 4.6E+00 3.7E+00 1.2E+01
2.11E+02 7.4E-01 3.7E+00 1.2E+01
2.51 E+04 3.0E-01 3.7E+00 1.2E+01
2.47E+05 2.2E+00 3.7E+00 1.2E+01
8.77E+05 3.2E-01 3.7E+00 1.2E+01
1.02E+06 6.8E-01 3.7E+00 1.2E+01
8.12E+02 1.4E+00 3.7E+00 1.2E+01
1.85E+00 1.9E+04 3.7E+00 1.2E+01
7.31 E+00 1.1 E+01 3.7E+00 1.2E+01
1.85E+00 2.8E+01 3.7E+00 1.2E+01
1.85E+00 6.2E+01 3.7E+00 1.2E+01
1.85E+00 1.0E+01 3.7E+00 1.2E+01
4.12E+00 2.3E+01 3.7E+00 1.2E+01
1.85E+00 6.3E+02 3.7E+00 1.2E+01
4.30E+00 9.2E+00 3.7E+00 1.2E+01
1.85E+00 1.0E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.70E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.72E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.71E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-826
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe CFS-L10-1313-T01-A
Fe CFS-L10-1313-T02-A
Fe CFS-L10-1313-T03-A
Fe CFS-L10-1313-T04-A
Fe CFS-L10-1313-T05-A
Fe CFS-L10-1313-T06-A
Fe CFS-L10-1313-T07-A
Fe CFS-L10-1313-T08-A
Fe CFS-L10-1313-T09-A
Fe CFS-L10-1313-T10-A
Fe CFS-L10-1313-T01-B
Fe CFS-L10-1313-T02-B
Fe CFS-L10-1313-T03-B
Fe CFS-L10-1313-T04-B
Fe CFS-L10-1313-T05-B
Fe CFS-L10-1313-T06-B
Fe CFS-L10-1313-T07-B
Fe CFS-L10-1313-T08-B
Fe CFS-L10-1313-T09-B
Fe CFS-L10-1313-T10-B
Fe CFS-L10-1313-T01-C
Fe CFS-L10-1313-T02-C
Fe CFS-L10-1313-T03-C
Fe CFS-L10-1313-T04-C
Fe CFS-L10-1313-T05-C
Fe CFS-L10-1313-T06-C
Fe CFS-L10-1313-T07-C
Fe CFS-L10-1313-T08-C
Fe CFS-L10-1313-T09-C
Fe CFS-L10-1313-T10-C
Fe CFS-L10-1313-B01-A
Fe CFS-L10-1313-B02-A
Fe CFS-L10-1313-B03-A
Fe CFS-L10-1313-B01-B
Fe CFS-L10-1313-B02-B
Fe CFS-L10-1313-B03-B
Fe CFS-L10-1313-B01-C
Fe CFS-L10-1313-B02-C
Fe CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 6.20E+00 E
1 2.31 E+04
1 1.89E+05
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 6.63E+00
1 2.02E+04
1 1.75E+05
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.40E+01
1 8.02E+00
1 2.66E+04
1 1.83E+05
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 3.15E+OOE
1 2.60E+01
1 1.00E+OOU1/2
1 4.02E+00 E
1 2.50E+01
1 2.05E+00 E
1 6.89E+00
1 2.56E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.5E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 2.1E+00 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
6.20E+00 1.0E+01 2.0E+00 6.4E+00
2.31 E+04 1.0E+00 2.0E+00 6.4E+00
1.89E+05 9.1E-01 2.0E+00 6.4E+00
1.00E+00 5.2E+00 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 9.2E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 7.7E+00 2.0E+00 6.4E+00
1.00E+00 3.4E+00 2.0E+00 6.4E+00
6.63E+00 1.5E+01 2.0E+00 6.4E+00
2.02E+04 3.0E-01 2.0E+00 6.4E+00
1.75E+05 1.3E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 4.4E+00 2.0E+00 6.4E+00
1.00E+00 6.7E+00 2.0E+00 6.4E+00
1.00E+00 5.2E+01 2.0E+00 6.4E+00
1.40E+01 4.3E+00 2.0E+00 6.4E+00
8.02E+00 3.7E+00 2.0E+00 6.4E+00
2.66E+04 7.1E-01 2.0E+00 6.4E+00
1.83E+05 4.7E-01 2.0E+00 6.4E+00
1.00E+00 1.9E-01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
3.15E+00 1.8E+01 2.0E+00 6.4E+00
2.60E+01 1.5E+00 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
4.02E+00 3.3E+00 2.0E+00 6.4E+00
2.50E+01 7.2E+00 2.0E+00 6.4E+00
2.05E+00 1.5E+01 2.0E+00 6.4E+00
6.89E+00 4.8E+00 2.0E+00 6.4E+00
2.56E+01 3.5E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L1 01 31 3-1 31 6 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/1 3/1 1 3:24 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/1 3/1 1 3:25 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/1 3/1 1 3:27 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/1 3/1 1 3:29 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/1 3/1 1 3:30 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-827
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb CFS-L10-1313-T01-A
Pb CFS-L10-1313-T02-A
Pb CFS-L10-1313-T03-A
Pb CFS-L10-1313-T04-A
Pb CFS-L10-1313-T05-A
Pb CFS-L10-1313-T06-A
Pb CFS-L10-1313-T07-A
Pb CFS-L10-1313-T08-A
Pb CFS-L10-1313-T09-A
Pb CFS-L10-1313-T10-A
Pb CFS-L10-1313-T01-B
Pb CFS-L10-1313-T02-B
Pb CFS-L10-1313-T03-B
Pb CFS-L10-1313-T04-B
Pb CFS-L10-1313-T05-B
Pb CFS-L10-1313-T06-B
Pb CFS-L10-1313-T07-B
Pb CFS-L10-1313-T08-B
Pb CFS-L10-1313-T09-B
Pb CFS-L10-1313-T10-B
Pb CFS-L10-1313-T01-C
Pb CFS-L10-1313-T02-C
Pb CFS-L10-1313-T03-C
Pb CFS-L10-1313-T04-C
Pb CFS-L10-1313-T05-C
Pb CFS-L10-1313-T06-C
Pb CFS-L10-1313-T07-C
Pb CFS-L10-1313-T08-C
Pb CFS-L10-1313-T09-C
Pb CFS-L10-1313-T10-C
Pb CFS-L10-1313-B01-A
Pb CFS-L10-1313-B02-A
Pb CFS-L10-1313-B03-A
Pb CFS-L10-1313-B01-B
Pb CFS-L10-1313-B02-B
Pb CFS-L10-1313-B03-B
Pb CFS-L10-1313-B01-C
Pb CFS-L10-1313-B02-C
Pb CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.23E+04
1 9.43E+03
1 2.75E+02
1 7.11E+01
1 7.12E+02
1 2.65E+03
1 5.80E+03
1 5.17E+03
1 5.93E+03
1 9.15E+02
1 1.32E+04
1 9.50E+03
1 2.33E+02
1 5.93E+01
1 8.09E+02
1 2.45E+03
1 6.05E+03
1 6.13E+03
1 6.01 E+03
1 9.02E+02
1 1.21E+04
1 9.46E+03
1 2.27E+02
1 7.84E+01
1 7.72E+02
1 2.46E+03
1 7.04E+03
1 5.32E+03
1 5.92E+03
1 9.55E+02
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.23E+04 1.5E+00 6.8E+00 2.2E+01
9.43E+03 1.4E+00 6.8E+00 2.2E+01 10 120
2.75E+02 2.9E+00 6.8E+00 2.2E+01
7.11E+01 2.8E+01 6.8E+00 2.2E+01
7.12E+02 4.6E-01 6.8E+00 2.2E+01
2.65E+03 8.8E-01 6.8E+00 2.2E+01
5.80E+03 4.1E-01 6.8E+00 2.2E+01
5.17E+03 1.6E+00 6.8E+00 2.2E+01
5.93E+03 3.3E-01 6.8E+00 2.2E+01
9.15E+02 4.3E-01 6.8E+00 2.2E+01
1.32E+04 2.6E-01 6.8E+00 2.2E+01
9.50E+03 7.1E-01 6.8E+00 2.2E+01 10 120
2.33E+02 1.8E+00 6.8E+00 2.2E+01
5.93E+01 6.7E+00 6.8E+00 2.2E+01
8.09E+02 7.4E-01 6.8E+00 2.2E+01
2.45E+03 9.3E-01 6.8E+00 2.2E+01
6.05E+03 7.2E-01 6.8E+00 2.2E+01
6.13E+03 8.1E-01 6.8E+00 2.2E+01
6.01 E+03 1.4E+00 6.8E+00 2.2E+01
9.02E+02 3.6E-01 6.8E+00 2.2E+01
1.21E+04 6.9E-01 6.8E+00 2.2E+01
9.46E+03 2.0E+00 6.8E+00 2.2E+01 10 120
2.27E+02 3.4E+00 6.8E+00 2.2E+01
7.84E+01 5.9E+00 6.8E+00 2.2E+01
7.72E+02 5.5E-01 6.8E+00 2.2E+01
2.46E+03 4.5E-01 6.8E+00 2.2E+01
7.04E+03 1.8E+00 6.8E+00 2.2E+01
5.32E+03 9.8E-01 6.8E+00 2.2E+01
5.92E+03 4.4E-01 6.8E+00 2.2E+01
9.55E+02 1.6E+00 6.8E+00 2.2E+01
3.40E+00 2.1E-01 6.8E+00 2.2E+01
3.40E+00 5.4E+00 6.8E+00 2.2E+01
3.40E+00 6.8E+00 6.8E+00 2.2E+01
3.40E+00 1.6E+00 6.8E+00 2.2E+01
3.40E+00 2.5E+00 6.8E+00 2.2E+01
3.40E+00 8.5E+00 6.8E+00 2.2E+01
3.40E+00 4.5E-01 6.8E+00 2.2E+01
3.40E+00 3.3E+00 6.8E+00 2.2E+01
3.40E+00 5.5E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.06E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+04 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-828
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li CFS-L10-1313-T01-A
Li CFS-L10-1313-T02-A
Li CFS-L10-1313-T03-A
Li CFS-L10-1313-T04-A
Li CFS-L10-1313-T05-A
Li CFS-L10-1313-T06-A
Li CFS-L10-1313-T07-A
Li CFS-L10-1313-T08-A
Li CFS-L10-1313-T09-A
Li CFS-L10-1313-T10-A
Li CFS-L10-1313-T01-B
Li CFS-L10-1313-T02-B
Li CFS-L10-1313-T03-B
Li CFS-L10-1313-T04-B
Li CFS-L10-1313-T05-B
Li CFS-L10-1313-T06-B
Li CFS-L10-1313-T07-B
Li CFS-L10-1313-T08-B
Li CFS-L10-1313-T09-B
Li CFS-L10-1313-T10-B
Li CFS-L10-1313-T01-C
Li CFS-L10-1313-T02-C
Li CFS-L10-1313-T03-C
Li CFS-L10-1313-T04-C
Li CFS-L10-1313-T05-C
Li CFS-L10-1313-T06-C
Li CFS-L10-1313-T07-C
Li CFS-L10-1313-T08-C
Li CFS-L10-1313-T09-C
Li CFS-L10-1313-T10-C
Li CFS-L10-1313-B01-A
Li CFS-L10-1313-B02-A
Li CFS-L10-1313-B03-A
Li CFS-L10-1313-B01-B
Li CFS-L10-1313-B02-B
Li CFS-L10-1313-B03-B
Li CFS-L10-1313-B01-C
Li CFS-L10-1313-B02-C
Li CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.42E+00
1 1.13E+01
1 1.17E+01
1 9.94E+00
1 7.58E+00
1 9.25E+00
1 1.14E+01
1 1.17E+01
1 2.06E+01
1 9.00E+00
1 9.70E+00
1 1.22E+01
1 1.10E+01
1 1.10E+01
1 9.69E+00
1 8.75E+00
1 1.05E+01
1 1.52E+01
1 2.05E+01
1 9.99E+00
1 9.58E+00
1 1.11E+01
1 1.27E+01
1 1.24E+01
1 1.22E+01
1 1.02E+01
1 1.01E+01
1 9.69E+00
1 1.94E+01
1 1.04E+01
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.42E+00 4.2E+00 1.9E+00 6.0E+00
1.13E+01 2.4E+00 1.9E+00 6.0E+00 10 120
1.17E+01 8.5E-01 1.9E+00 6.0E+00
9.94E+00 4.8E+00 1.9E+00 6.0E+00
7.58E+00 1.2E+01 1.9E+00 6.0E+00
9.25E+00 9.4E+00 1.9E+00 6.0E+00
1.14E+01 4.4E+00 1.9E+00 6.0E+00
1.17E+01 1.2E+01 1.9E+00 6.0E+00
2.06E+01 6.0E+00 1.9E+00 6.0E+00
9.00E+00 2.5E+00 1.9E+00 6.0E+00
9.70E+00 3.3E+00 1.9E+00 6.0E+00
1.22E+01 1.6E+00 1.9E+00 6.0E+00 10 120
1.10E+01 2.4E+00 1.9E+00 6.0E+00
1.10E+01 1.3E+00 1.9E+00 6.0E+00
9.69E+00 4.5E+00 1.9E+00 6.0E+00
8.75E+00 3.8E+00 1.9E+00 6.0E+00
1.05E+01 1.1E+01 1.9E+00 6.0E+00
1.52E+01 1.4E+01 1.9E+00 6.0E+00
2.05E+01 1.9E+01 1.9E+00 6.0E+00
9.99E+00 4.9E+00 1.9E+00 6.0E+00
9.58E+00 5.4E+00 1.9E+00 6.0E+00
1.11E+01 3.3E+00 1.9E+00 6.0E+00 10 120
1.27E+01 2.4E+00 1.9E+00 6.0E+00
1.24E+01 3.0E+00 1.9E+00 6.0E+00
1.22E+01 7.8E+00 1.9E+00 6.0E+00
1.02E+01 8.2E+00 1.9E+00 6.0E+00
1.01E+01 9.5E+00 1.9E+00 6.0E+00
9.69E+00 1.8E+00 1.9E+00 6.0E+00
1.94E+01 1.1E+01 1.9E+00 6.0E+00
1.04E+01 5.9E+00 1.9E+00 6.0E+00
9.50E-01 6.1E+00 1.9E+00 6.0E+00
9.50E-01 5.2E+00 1.9E+00 6.0E+00
9.50E-01 1.6E+00 1.9E+00 6.0E+00
9.50E-01 1.9E+00 1.9E+00 6.0E+00
9.50E-01 3.7E+00 1.9E+00 6.0E+00
9.50E-01 2.5E+00 1.9E+00 6.0E+00
9.50E-01 2.4E+00 1.9E+00 6.0E+00
9.50E-01 1.8E+00 1.9E+00 6.0E+00
9.50E-01 2.4E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.10E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L1 01 31 3-1 31 6 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-829
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn CFS-L10-1313-T01-A
Mn CFS-L10-1313-T02-A
Mn CFS-L10-1313-T03-A
Mn CFS-L10-1313-T04-A
Mn CFS-L10-1313-T05-A
Mn CFS-L10-1313-T06-A
Mn CFS-L10-1313-T07-A
Mn CFS-L10-1313-T08-A
Mn CFS-L10-1313-T09-A
Mn CFS-L10-1313-T10-A
Mn CFS-L10-1313-T01-B
Mn CFS-L10-1313-T02-B
Mn CFS-L10-1313-T03-B
Mn CFS-L10-1313-T04-B
Mn CFS-L10-1313-T05-B
Mn CFS-L10-1313-T06-B
Mn CFS-L10-1313-T07-B
Mn CFS-L10-1313-T08-B
Mn CFS-L10-1313-T09-B
Mn CFS-L10-1313-T10-B
Mn CFS-L10-1313-T01-C
Mn CFS-L10-1313-T02-C
Mn CFS-L10-1313-T03-C
Mn CFS-L10-1313-T04-C
Mn CFS-L10-1313-T05-C
Mn CFS-L10-1313-T06-C
Mn CFS-L10-1313-T07-C
Mn CFS-L10-1313-T08-C
Mn CFS-L10-1313-T09-C
Mn CFS-L10-1313-T10-C
Mn CFS-L10-1313-B01-A
Mn CFS-L10-1313-B02-A
Mn CFS-L10-1313-B03-A
Mn CFS-L10-1313-B01-B
Mn CFS-L10-1313-B02-B
Mn CFS-L10-1313-B03-B
Mn CFS-L10-1313-B01-C
Mn CFS-L10-1313-B02-C
Mn CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.96E+01
1 8.56E+02
1 3.45E+03
1 7.26E+03
1 2.03E+04
1 2.84E+04
1 1.52E+03
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.48E+01
1 1.03E+03
1 3.71E+03
1 7.65E+03
1 2.04E+04
1 2.77E+04
1 1.55E+03
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.82E+01
1 1.08E+03
1 3.42E+03
1 7.70E+03
1 2.06E+04
1 2.80E+04
1 1.61E+03
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.5E+01 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00 10 120
1.00E+00 4.3E+00 2.0E+00 6.4E+00
1.96E+01 1.9E+00 2.0E+00 6.4E+00
8.56E+02 1.9E-01 2.0E+00 6.4E+00
3.45E+03 1.5E-01 2.0E+00 6.4E+00
7.26E+03 6.0E-01 2.0E+00 6.4E+00
2.03E+04 1.1E+00 2.0E+00 6.4E+00
2.84E+04 7.3E-01 2.0E+00 6.4E+00
1.52E+03 1.2E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00 10 120
1.00E+00 6.8E+00 2.0E+00 6.4E+00
2.48E+01 7.8E-01 2.0E+00 6.4E+00
1.03E+03 9.0E-01 2.0E+00 6.4E+00
3.71 E+03 7.8E-01 2.0E+00 6.4E+00
7.65E+03 3.0E-01 2.0E+00 6.4E+00
2.04E+04 4.4E-01 2.0E+00 6.4E+00
2.77E+04 2.2E+00 2.0E+00 6.4E+00
1.55E+03 7.6E-01 2.0E+00 6.4E+00
1.00E+00 5.2E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00 10 120
1.00E+00 4.5E+01 2.0E+00 6.4E+00
3.82E+01 1.2E+00 2.0E+00 6.4E+00
1.08E+03 5.6E-01 2.0E+00 6.4E+00
3.42E+03 4.9E-01 2.0E+00 6.4E+00
7.70E+03 9.8E-01 2.0E+00 6.4E+00
2.06E+04 4.0E-01 2.0E+00 6.4E+00
2.80E+04 2.0E+00 2.0E+00 6.4E+00
1.61 E+03 9.4E-01 2.0E+00 6.4E+00
1.00E+00 2.5E+02 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 5.5E+01 2.0E+00 6.4E+00
1.00E+00 4.7E-01 2.0E+00 6.4E+00
1.00E+00 7.3E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.09E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L1 01 31 3-1 31 6 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-830
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg CFS-L10-1313-T01-A
Mg CFS-L10-1313-T02-A
Mg CFS-L10-1313-T03-A
Mg CFS-L10-1313-T04-A
Mg CFS-L10-1313-T05-A
Mg CFS-L10-1313-T06-A
Mg CFS-L10-1313-T07-A
Mg CFS-L10-1313-T08-A
Mg CFS-L10-1313-T09-A
Mg CFS-L10-1313-T10-A
Mg CFS-L10-1313-T01-B
Mg CFS-L10-1313-T02-B
Mg CFS-L10-1313-T03-B
Mg CFS-L10-1313-T04-B
Mg CFS-L10-1313-T05-B
Mg CFS-L10-1313-T06-B
Mg CFS-L10-1313-T07-B
Mg CFS-L10-1313-T08-B
Mg CFS-L10-1313-T09-B
Mg CFS-L10-1313-T10-B
Mg CFS-L10-1313-T01-C
Mg CFS-L10-1313-T02-C
Mg CFS-L10-1313-T03-C
Mg CFS-L10-1313-T04-C
Mg CFS-L10-1313-T05-C
Mg CFS-L10-1313-T06-C
Mg CFS-L10-1313-T07-C
Mg CFS-L10-1313-T08-C
Mg CFS-L10-1313-T09-C
Mg CFS-L10-1313-T10-C
Mg CFS-L10-1313-B01-A
Mg CFS-L10-1313-B02-A
Mg CFS-L10-1313-B03-A
Mg CFS-L10-1313-B01-B
Mg CFS-L10-1313-B02-B
Mg CFS-L10-1313-B03-B
Mg CFS-L10-1313-B01-C
Mg CFS-L10-1313-B02-C
Mg CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.96E+01
1 4.22E+01
1 4.00E+03
1 4.95E+04
1 6.74E+04
1 6.53E+04
1 7.23E+04
1 1.15E+05
1 2.29E+05
1 6.78E+04
1 2.68E+01
1 3.05E+01
1 3.64E+03
1 5.39E+04
1 7.05E+04
1 7.26E+04
1 7.69E+04
1 1.29E+05
1 2.16E+05
1 6.92E+04
1 3.04E+01
1 3.75E+01
1 4.10E+03
1 5.50E+04
1 6.66E+04
1 6.94E+04
1 8.04E+04
1 1.16E+05
1 2.05E+05
1 6.97E+04
1 1.13E+00 E
1 5.00E-01 U1/2
1 1.65E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.75E+01
1 1.91E+00 E
1 6.67E+00
1 6.64E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.96E+01 2.8E+00 1.0E+00 3.2E+00
4.22E+01 2.0E+01 1.0E+00 3.2E+00 1000 100
4.00E+03 1.9E+00 1.0E+00 3.2E+00
4.95E+04 1.1E+00 1.0E+00 3.2E+00
6.74E+04 2.6E-01 1.0E+00 3.2E+00
6.53E+04 1.2E+00 1.0E+00 3.2E+00
7.23E+04 2.5E-01 1.0E+00 3.2E+00
1.15E+05 5.8E-01 1.0E+00 3.2E+00
2.29E+05 3.2E-01 1.0E+00 3.2E+00
6.78E+04 6.2E-01 1.0E+00 3.2E+00
2.68E+01 3.1E+01 1.0E+00 3.2E+00
3.05E+01 8.1E+00 1.0E+00 3.2E+00 1000 100
3.64E+03 1.7E+00 1.0E+00 3.2E+00
5.39E+04 8.7E-01 1.0E+00 3.2E+00
7.05E+04 4.3E-01 1.0E+00 3.2E+00
7.26E+04 1.3E+00 1.0E+00 3.2E+00
7.69E+04 5.4E-01 1.0E+00 3.2E+00
1.29E+05 1.3E+00 1.0E+00 3.2E+00
2.16E+05 7.1E-01 1.0E+00 3.2E+00
6.92E+04 9.5E-01 1.0E+00 3.2E+00
3.04E+01 1.1E+01 1.0E+00 3.2E+00
3.75E+01 1.9E+01 1.0E+00 3.2E+00 1000 100
4.10E+03 9.0E-01 1.0E+00 3.2E+00
5.50E+04 8.7E-01 1.0E+00 3.2E+00
6.66E+04 6.8E-01 1.0E+00 3.2E+00
6.94E+04 1.1E+00 1.0E+00 3.2E+00
8.04E+04 5.5E-01 1.0E+00 3.2E+00
1.16E+05 7.4E-01 1.0E+00 3.2E+00
2.05E+05 3.3E-01 1.0E+00 3.2E+00
6.97E+04 1.2E+00 1.0E+00 3.2E+00
1.13E+00 9.1E+02 1.0E+00 3.2E+00
5.00E-01 5.2E+01 1.0E+00 3.2E+00
1.65E+01 2.5E+01 1.0E+00 3.2E+00
5.00E-01 1.7E+02 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00
1.75E+01 1.3E+01 1.0E+00 3.2E+00
1.91E+00 4.5E+02 1.0E+00 3.2E+00
6.67E+00 1.5E+02 1.0E+00 3.2E+00
6.64E+00 1.7E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.15E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-831
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo CFS-L10-1313-T01-A
Mo CFS-L10-1313-T02-A
Mo CFS-L10-1313-T03-A
Mo CFS-L10-1313-T04-A
Mo CFS-L10-1313-T05-A
Mo CFS-L10-1313-T06-A
Mo CFS-L10-1313-T07-A
Mo CFS-L10-1313-T08-A
Mo CFS-L10-1313-T09-A
Mo CFS-L10-1313-T10-A
Mo CFS-L10-1313-T01-B
Mo CFS-L10-1313-T02-B
Mo CFS-L10-1313-T03-B
Mo CFS-L10-1313-T04-B
Mo CFS-L10-1313-T05-B
Mo CFS-L10-1313-T06-B
Mo CFS-L10-1313-T07-B
Mo CFS-L10-1313-T08-B
Mo CFS-L10-1313-T09-B
Mo CFS-L10-1313-T10-B
Mo CFS-L10-1313-T01-C
Mo CFS-L10-1313-T02-C
Mo CFS-L10-1313-T03-C
Mo CFS-L10-1313-T04-C
Mo CFS-L10-1313-T05-C
Mo CFS-L10-1313-T06-C
Mo CFS-L10-1313-T07-C
Mo CFS-L10-1313-T08-C
Mo CFS-L10-1313-T09-C
Mo CFS-L10-1313-T10-C
Mo CFS-L10-1313-B01-A
Mo CFS-L10-1313-B02-A
Mo CFS-L10-1313-B03-A
Mo CFS-L10-1313-B01-B
Mo CFS-L10-1313-B02-B
Mo CFS-L10-1313-B03-B
Mo CFS-L10-1313-B01-C
Mo CFS-L10-1313-B02-C
Mo CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.65E+03
1 1.63E+03
1 9.37E+02
1 1.33E+02
1 1.81E+01
1 6.00E+00
1 5.24E+00
1 6.60E+00
1 3.27E+01
1 9.66E+00
1 1.89E+03
1 1.76E+03
1 1.03E+03
1 1.23E+02
1 1.69E+01
1 7.17E+00
1 5.39E+00
1 8.63E+00
1 2.64E+01
1 8.16E+00
1 1.77E+03
1 1.82E+03
1 1.05E+03
1 1.15E+02
1 1.75E+01
1 4.79E+00
1 3.50E+00 E
1 9.33E+00
1 2.24E+01
1 9.32E+00
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 3.06E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.43E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.65E+03 1.2E-01 1.2E+00 3.8E+00
1.63E+03 4.2E-01 1.2E+00 3.8E+00 10 120
9.37E+02 1.1E+00 1.2E+00 3.8E+00
1.33E+02 2.1E+00 1.2E+00 3.8E+00
1.81E+01 5.7E+00 1.2E+00 3.8E+00
6.00E+00 3.0E+01 1.2E+00 3.8E+00
5.24E+00 5.6E+01 1.2E+00 3.8E+00
6.60E+00 3.1E+01 1.2E+00 3.8E+00
3.27E+01 5.6E+01 1.2E+00 3.8E+00
9.66E+00 1.2E+01 1.2E+00 3.8E+00
1.89E+03 1.0E-01 1.2E+00 3.8E+00
1.76E+03 4.9E-01 1.2E+00 3.8E+00 10 120
1.03E+03 1.4E+00 1.2E+00 3.8E+00
1.23E+02 1.4E+00 1.2E+00 3.8E+00
1.69E+01 6.4E+00 1.2E+00 3.8E+00
7.17E+00 5.5E+00 1.2E+00 3.8E+00
5.39E+00 3.1E+01 1.2E+00 3.8E+00
8.63E+00 1.4E+02 1.2E+00 3.8E+00
2.64E+01 2.7E+01 1.2E+00 3.8E+00
8.16E+00 9.3E+00 1.2E+00 3.8E+00
1.77E+03 1.7E-01 1.2E+00 3.8E+00
1.82E+03 1.5E+00 1.2E+00 3.8E+00 10 120
1.05E+03 1.4E+00 1.2E+00 3.8E+00
1.15E+02 8.4E-01 1.2E+00 3.8E+00
1.75E+01 5.1E+00 1.2E+00 3.8E+00
4.79E+00 2.1E+01 1.2E+00 3.8E+00
3.50E+00 7.8E+01 1.2E+00 3.8E+00
9.33E+00 3.9E+01 1.2E+00 3.8E+00
2.24E+01 4.1E+01 1.2E+00 3.8E+00
9.32E+00 1.4E+01 1.2E+00 3.8E+00
6.00E-01 2.5E+02 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
3.06E+00 8.1E+01 1.2E+00 3.8E+00
6.00E-01 1.2E+02 1.2E+00 3.8E+00
6.00E-01 8.3E+01 1.2E+00 3.8E+00
1.43E+00 1.3E+02 1.2E+00 3.8E+00
6.00E-01 1.7E+03 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.00E-01 9.1E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.70E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.87E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.90E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-832
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni CFS-L10-1313-T01-A
Ni CFS-L10-1313-T02-A
Ni CFS-L10-1313-T03-A
Ni CFS-L10-1313-T04-A
Ni CFS-L10-1313-T05-A
Ni CFS-L10-1313-T06-A
Ni CFS-L10-1313-T07-A
Ni CFS-L10-1313-T08-A
Ni CFS-L10-1313-T09-A
Ni CFS-L10-1313-T10-A
Ni CFS-L10-1313-T01-B
Ni CFS-L10-1313-T02-B
Ni CFS-L10-1313-T03-B
Ni CFS-L10-1313-T04-B
Ni CFS-L10-1313-T05-B
Ni CFS-L10-1313-T06-B
Ni CFS-L10-1313-T07-B
Ni CFS-L10-1313-T08-B
Ni CFS-L10-1313-T09-B
Ni CFS-L10-1313-T10-B
Ni CFS-L10-1313-T01-C
Ni CFS-L10-1313-T02-C
Ni CFS-L10-1313-T03-C
Ni CFS-L10-1313-T04-C
Ni CFS-L10-1313-T05-C
Ni CFS-L10-1313-T06-C
Ni CFS-L10-1313-T07-C
Ni CFS-L10-1313-T08-C
Ni CFS-L10-1313-T09-C
Ni CFS-L10-1313-T10-C
Ni CFS-L10-1313-B01-A
Ni CFS-L10-1313-B02-A
Ni CFS-L10-1313-B03-A
Ni CFS-L10-1313-B01-B
Ni CFS-L10-1313-B02-B
Ni CFS-L10-1313-B03-B
Ni CFS-L10-1313-B01-C
Ni CFS-L10-1313-B02-C
Ni CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 3.27E+00 E
1 7.73E+01
1 8.45E+02
1 2.24E+03
1 6.00E+03
1 6.58E+03
1 2.03E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 2.97E+00 E
1 9.92E+01
1 9.11E+02
1 2.25E+03
1 5.89E+03
1 6.30E+03
1 2.05E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 3.35E+00 E
1 9.83E+01
1 8.61 E+02
1 2.33E+03
1 6.00E+03
1 6.35E+03
1 2.18E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 2.14E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 6.8E+01 1.8E+00 5.7E+00
9.00E-01 4.4E+02 1.8E+00 5.7E+00 10 120
9.00E-01 3.3E+01 1.8E+00 5.7E+00
3.27E+00 1.5E+01 1.8E+00 5.7E+00
7.73E+01 3.8E-01 1.8E+00 5.7E+00
8.45E+02 5.3E-01 1.8E+00 5.7E+00
2.24E+03 3.7E-01 1.8E+00 5.7E+00
6.00E+03 1.3E+00 1.8E+00 5.7E+00
6.58E+03 1.3E+00 1.8E+00 5.7E+00
2.03E+02 7.8E-01 1.8E+00 5.7E+00
9.00E-01 8.2E+01 1.8E+00 5.7E+00
9.00E-01 1.1 E+02 1.8E+00 5.7E+00 10 120
9.00E-01 4.6E+01 1.8E+00 5.7E+00
2.97E+00 2.8E+01 1.8E+00 5.7E+00
9.92E+01 2.0E+00 1.8E+00 5.7E+00
9.11E+02 1.0E+00 1.8E+00 5.7E+00
2.25E+03 6.7E-01 1.8E+00 5.7E+00
5.89E+03 3.5E-01 1.8E+00 5.7E+00
6.30E+03 7.0E-01 1.8E+00 5.7E+00
2.05E+02 1.5E+00 1.8E+00 5.7E+00
9.00E-01 7.3E+01 1.8E+00 5.7E+00
9.00E-01 2.8E+02 1.8E+00 5.7E+00 10 120
9.00E-01 4.3E+01 1.8E+00 5.7E+00
3.35E+00 2.5E+01 1.8E+00 5.7E+00
9.83E+01 1.5E+00 1.8E+00 5.7E+00
8.61 E+02 3.3E-01 1.8E+00 5.7E+00
2.33E+03 2.0E+00 1.8E+00 5.7E+00
6.00E+03 9.5E-01 1.8E+00 5.7E+00
6.35E+03 1.1E+00 1.8E+00 5.7E+00
2.18E+02 4.6E-01 1.8E+00 5.7E+00
9.00E-01 3.1 E+02 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
9.00E-01 9.5E+01 1.8E+00 5.7E+00
9.00E-01 2.4E+02 1.8E+00 5.7E+00
9.00E-01 2.4E+03 1.8E+00 5.7E+00
2.14E+00 5.1E+01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.12E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/17/11 12:16 PM EPA Interlab 1313-1316 CFS Reruns
6/17/11 12:18 PM EPA Interlab 1313-1316 CFS Reruns
6/17/11 12:21 PM EPA Interlab 1313-1316 CFS Reruns
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
6/17/11 12:38 PM EPA Interlab 1313-1316 CFS Reruns
6/17/11 12:41 PM EPA Interlab 1313-1316 CFS Reruns
6/17/11 12:43 PM EPA Interlab 1313-1316 CFS Reruns
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
6/17/11 1:00 PM EPA Interlab 1313-1316 CFS Reruns
6/17/11 1:02 PM EPA Interlab 1313-1316 CFS Reruns
6/17/11 1:04 PM EPA Interlab 1313-1316 CFS Reruns
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-833
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P CFS-L10-1313-T01-A
P CFS-L10-1313-T02-A
P CFS-L10-1313-T03-A
P CFS-L10-1313-T04-A
P CFS-L10-1313-T05-A
P CFS-L10-1313-T06-A
P CFS-L10-1313-T07-A
P CFS-L10-1313-T08-A
P CFS-L10-1313-T09-A
P CFS-L10-1313-T10-A
P CFS-L10-1313-T01-B
P CFS-L10-1313-T02-B
P CFS-L10-1313-T03-B
P CFS-L10-1313-T04-B
P CFS-L10-1313-T05-B
P CFS-L10-1313-T06-B
P CFS-L10-1313-T07-B
P CFS-L10-1313-T08-B
P CFS-L10-1313-T09-B
P CFS-L10-1313-T10-B
P CFS-L10-1313-T01-C
P CFS-L10-1313-T02-C
P CFS-L10-1313-T03-C
P CFS-L10-1313-T04-C
P CFS-L10-1313-T05-C
P CFS-L10-1313-T06-C
P CFS-L10-1313-T07-C
P CFS-L10-1313-T08-C
P CFS-L10-1313-T09-C
P CFS-L10-1313-T10-C
P CFS-L10-1313-B01-A
P CFS-L10-1313-B02-A
P CFS-L10-1313-B03-A
P CFS-L10-1313-B01-B
P CFS-L10-1313-B02-B
P CFS-L10-1313-B03-B
P CFS-L10-1313-B01-C
P CFS-L10-1313-B02-C
P CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.79E+01
1 5.40E+01
1 9.82E+00 E
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 2.42E+02
1 1.85E+00 U1/2
1 8.26E+01
1 6.16E+01
1 2.53E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 2.87E+02
1 1.85E+OOU1/2
1 1.06E+02
1 7.71E+01
1 1.65E+01
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 2.63E+02
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 7.14E+OOE
1 1.85E+OOU1/2
1 1.85E+OOU1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.79E+01 2.3E+01 3.7E+00 1.2E+01
5.40E+01 1.2E+01 3.7E+00 1.2E+01 1000 100
9.82E+00 9.4E+01 3.7E+00 1.2E+01
1.85E+00 6.9E+01 3.7E+00 1.2E+01
1.85E+00 1.0E+02 3.7E+00 1.2E+01
1.85E+00 2.6E+02 3.7E+00 1.2E+01
1.85E+00 2.9E+02 3.7E+00 1.2E+01
1.85E+00 6.4E+01 3.7E+00 1.2E+01
2.42E+02 7.4E+00 3.7E+00 1.2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01
8.26E+01 1.4E+01 3.7E+00 1.2E+01
6.16E+01 1.5E+01 3.7E+00 1.2E+01 1000 100
2.53E+01 3.7E+01 3.7E+00 1.2E+01
1.85E+00 1.2E+02 3.7E+00 1.2E+01
1.85E+00 2.9E+01 3.7E+00 1.2E+01
1.85E+00 8.4E+01 3.7E+00 1.2E+01
1.85E+00 9.6E+01 3.7E+00 1.2E+01
1.85E+00 5.8E+02 3.7E+00 1.2E+01
2.87E+02 5.5E+00 3.7E+00 1.2E+01
1.85E+00 3.7E+01 3.7E+00 1.2E+01
1.06E+02 4.2E+00 3.7E+00 1.2E+01
7.71E+01 2.5E+01 3.7E+00 1.2E+01 1000 100
1.65E+01 1.3E+02 3.7E+00 1.2E+01
1.85E+00 8.9E+01 3.7E+00 1.2E+01
1.85E+00 2.0E+02 3.7E+00 1.2E+01
1.85E+00 2.5E+02 3.7E+00 1.2E+01
1.85E+00 1.5E+01 3.7E+00 1.2E+01
1.85E+00 4.9E+02 3.7E+00 1.2E+01
2.63E+02 8.4E+00 3.7E+00 1.2E+01
1.85E+00 5.7E+01 3.7E+00 1.2E+01
1.85E+00 8.4E+01 3.7E+00 1.2E+01
1.85E+00 3.1E+01 3.7E+00 1.2E+01
7.14E+00 1.2E+02 3.7E+00 1.2E+01
1.85E+00 2.0E+02 3.7E+00 1.2E+01
1.85E+00 4.9E+01 3.7E+00 1.2E+01
1.85E+00 2.6E+02 3.7E+00 1.2E+01
1.85E+00 7.5E+01 3.7E+00 1.2E+01
1.85E+00 5.6E+01 3.7E+00 1.2E+01
1.85E+00 1.9E+03 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.23E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L1 01 31 3-1 31 6 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/1 3/1 1 3:29 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/1 3/1 1 3:30 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-834
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L10-1313-T01-A
CFS-L10-1313-T02-A
CFS-L10-1313-T03-A
CFS-L10-1313-T04-A
CFS-L10-1313-T05-A
CFS-L10-1313-T06-A
CFS-L10-1313-T07-A
CFS-L10-1313-T08-A
CFS-L10-1313-T09-A
CFS-L10-1313-T10-A
CFS-L10-1313-T01-B
CFS-L10-1313-T02-B
CFS-L10-1313-T03-B
CFS-L10-1313-T04-B
CFS-L10-1313-T05-B
CFS-L10-1313-T06-B
CFS-L10-1313-T07-B
CFS-L10-1313-T08-B
CFS-L10-1313-T09-B
CFS-L10-1313-T10-B
CFS-L10-1313-T01-C
CFS-L10-1313-T02-C
CFS-L10-1313-T03-C
CFS-L10-1313-T04-C
CFS-L10-1313-T05-C
CFS-L10-1313-T06-C
CFS-L10-1313-T07-C
CFS-L10-1313-T08-C
CFS-L10-1313-T09-C
CFS-L10-1313-T10-C
CFS-L10-1313-B01-A
CFS-L10-1313-B02-A
CFS-L10-1313-B03-A
CFS-L10-1313-B01-B
CFS-L10-1313-B02-B
CFS-L10-1313-B03-B
CFS-L10-1313-B01-C
CFS-L10-1313-B02-C
CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.67E+04
1 1.58E+04
1 1.26E+04
1 1.09E+04
1 9.83E+03
1 9.93E+03
1 1.16E+04
1 1.60E+04
1 2.17E+04
1 9.02E+03
1 3.73E+04
1 1.54E+04
1 1.27E+04
1 1.09E+04
1 1.02E+04
1 1.05E+04
1 1.15E+04
1 1.55E+04
1 2.08E+04
1 8.92E+03
1 3.71 E+04
1 1.58E+04
1 1.30E+04
1 1.15E+04
1 1.01 E+04
1 9.95E+03
1 1.19E+04
1 1.55E+04
1 2.06E+04
1 9.12E+03
1 2.84E+01
1 3.18E+01
1 2.05E+03
1 4.53E+01
1 9.85E+01
1 2.25E+03
1 8.83E+01
1 2.85E+01
1 2.07E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.67E+04 4.9E-01 1.6E+00 5.1E+00
1.58E+04 7.2E-01 1.6E+00 5.1E+00 1000 100
1.26E+04 7.4E-01 1.6E+00 5.1E+00
1.09E+04 7.7E-01 1.6E+00 5.1E+00
9.83E+03 9.0E-01 1.6E+00 5.1E+00
9.93E+03 7.2E-01 1.6E+00 5.1E+00
1.16E+04 5.9E-01 1.6E+00 5.1E+00
1.60E+04 9.0E-01 1.6E+00 5.1E+00
2.17E+04 1.9E+00 1.6E+00 5.1E+00
9.02E+03 6.9E-01 1.6E+00 5.1E+00
3.73E+04 6.7E-01 1.6E+00 5.1E+00
1.54E+04 5.4E-01 1.6E+00 5.1E+00 1000 100
1.27E+04 4.7E-01 1.6E+00 5.1E+00
1.09E+04 4.9E-01 1.6E+00 5.1E+00
1.02E+04 6.4E-01 1.6E+00 5.1E+00
1.05E+04 1.3E+00 1.6E+00 5.1E+00
1.15E+04 3.2E-01 1.6E+00 5.1E+00
1.55E+04 2.1E-01 1.6E+00 5.1E+00
2.08E+04 9.3E-01 1.6E+00 5.1E+00
8.92E+03 3.9E-01 1.6E+00 5.1E+00
3.71 E+04 3.9E-01 1.6E+00 5.1E+00
1.58E+04 1.3E+00 1.6E+00 5.1E+00 1000 100
1.30E+04 3.8E-01 1.6E+00 5.1E+00
1.15E+04 7.0E-01 1.6E+00 5.1E+00
1.01 E+04 6.4E-01 1.6E+00 5.1E+00
9.95E+03 1.6E-01 1.6E+00 5.1E+00
1.19E+04 1.1E+00 1.6E+00 5.1E+00
1.55E+04 6.0E-01 1.6E+00 5.1E+00
2.06E+04 6.1E-01 1.6E+00 5.1E+00
9.12E+03 5.1E-01 1.6E+00 5.1E+00
2.84E+01 1.8E+01 1.6E+00 5.1E+00
3.18E+01 1.4E+01 1.6E+00 5.1E+00
2.05E+03 8.0E-01 1.6E+00 5.1E+00
4.53E+01 2.0E+00 1.6E+00 5.1E+00
9.85E+01 2.0E+00 1.6E+00 5.1E+00
2.25E+03 6.3E+00 1.6E+00 5.1E+00
8.83E+01 1.2E+00 1.6E+00 5.1E+00
2.85E+01 1.2E+01 1.6E+00 5.1E+00
2.07E+03 1.2E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.67E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.63E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.66E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-835
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se
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Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Sample Dilutic
CFS-L10-1313-T01-A
CFS-L10-1313-T02-A
CFS-L10-1313-T03-A
CFS-L10-1313-T04-A
CFS-L10-1313-T05-A
CFS-L10-1313-T06-A
CFS-L10-1313-T07-A
CFS-L10-1313-T08-A
CFS-L10-1313-T09-A
CFS-L10-1313-T10-A
CFS-L10-1313-T01-B
CFS-L10-1313-T02-B
CFS-L10-1313-T03-B
CFS-L10-1313-T04-B
CFS-L10-1313-T05-B
CFS-L10-1313-T06-B
CFS-L10-1313-T07-B
CFS-L10-1313-T08-B
CFS-L10-1313-T09-B
CFS-L10-1313-T10-B
CFS-L10-1313-T01-C
CFS-L10-1313-T02-C
CFS-L10-1313-T03-C
CFS-L10-1313-T04-C
CFS-L10-1313-T05-C
CFS-L10-1313-T06-C
CFS-L10-1313-T07-C
CFS-L10-1313-T08-C
CFS-L10-1313-T09-C
CFS-L10-1313-T10-C
CFS-L10-1313-B01-A
CFS-L10-1313-B02-A
CFS-L10-1313-B03-A
CFS-L10-1313-B01-B
CFS-L10-1313-B02-B
CFS-L10-1313-B03-B
CFS-L10-1313-B01-C
CFS-L10-1313-B02-C
CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.63E+02
1 5.68E+02
1 3.89E+02
1 1.19E+02
1 8.39E+01
1 8.53E+01
1 1.32E+02
1 2.28E+02
1 2.92E+02
1 8.94E+01
1 6.33E+02
1 5.82E+02
1 3.90E+02
1 1.22E+02
1 8.46E+01
1 7.87E+01
1 1.27E+02
1 2.38E+02
1 2.79E+02
1 7.56E+01
1 7.80E+02
1 6.71 E+02
1 3.87E+02
1 1.12E+02
1 7.83E+01
1 1.13E+02
1 1.80E+02
1 2.58E+02
1 2.74E+02
1 7.54E+01
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.63E+02 2.2E+00 1.5E+01 4.8E+01
5.68E+02 3.2E+00 1.5E+01 4.8E+01 10 120
3.89E+02 3.8E-01 1.5E+01 4.8E+01
1.19E+02 2.0E+01 1.5E+01 4.8E+01
8.39E+01 2.2E+01 1.5E+01 4.8E+01
8.53E+01 1.5E+01 1.5E+01 4.8E+01
1.32E+02 9.7E+00 1.5E+01 4.8E+01
2.28E+02 4.2E+00 1.5E+01 4.8E+01
2.92E+02 2.3E+00 1.5E+01 4.8E+01
8.94E+01 1.2E+01 1.5E+01 4.8E+01
6.33E+02 1.3E+00 1.5E+01 4.8E+01
5.82E+02 1.9E+00 1.5E+01 4.8E+01 10 120
3.90E+02 5.1E+00 1.5E+01 4.8E+01
1.22E+02 1.3E+01 1.5E+01 4.8E+01
8.46E+01 1.0E+01 1.5E+01 4.8E+01
7.87E+01 2.5E+01 1.5E+01 4.8E+01
1.27E+02 2.6E+01 1.5E+01 4.8E+01
2.38E+02 8.7E+00 1.5E+01 4.8E+01
2.79E+02 1.6E+00 1.5E+01 4.8E+01
7.56E+01 1.7E+01 1.5E+01 4.8E+01
7.80E+02 2.1E+00 1.5E+01 4.8E+01
6.71E+02 3.8E+00 1.5E+01 4.8E+01 10 120
3.87E+02 5.4E+00 1.5E+01 4.8E+01
1.12E+02 6.8E+00 1.5E+01 4.8E+01
7.83E+01 1.7E+01 1.5E+01 4.8E+01
1.13E+02 2.0E+01 1.5E+01 4.8E+01
1.80E+02 2.7E+01 1.5E+01 4.8E+01
2.58E+02 1.3E+01 1.5E+01 4.8E+01
2.74E+02 2.6E+00 1.5E+01 4.8E+01
7.54E+01 2.8E+00 1.5E+01 4.8E+01
7.50E+00 3.1 E+02 1.5E+01 4.8E+01
7.50E+00 1.2E+02 1.5E+01 4.8E+01
7.50E+00 5.7E+01 1.5E+01 4.8E+01
7.50E+00 5.9E+01 1.5E+01 4.8E+01
7.50E+00 3.9E+02 1.5E+01 4.8E+01
7.50E+00 7.9E+01 1.5E+01 4.8E+01
7.50E+00 2.9E+02 1.5E+01 4.8E+01
7.50E+00 9.6E+01 1.5E+01 4.8E+01
7.50E+00 4.9E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.65E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.69E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.71E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-836
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si CFS-L10-1313-T01-A
Si CFS-L10-1313-T02-A
Si CFS-L10-1313-T03-A
Si CFS-L10-1313-T04-A
Si CFS-L10-1313-T05-A
Si CFS-L10-1313-T06-A
Si CFS-L10-1313-T07-A
Si CFS-L10-1313-T08-A
Si CFS-L10-1313-T09-A
Si CFS-L10-1313-T10-A
Si CFS-L10-1313-T01-B
Si CFS-L10-1313-T02-B
Si CFS-L10-1313-T03-B
Si CFS-L10-1313-T04-B
Si CFS-L10-1313-T05-B
Si CFS-L10-1313-T06-B
Si CFS-L10-1313-T07-B
Si CFS-L10-1313-T08-B
Si CFS-L10-1313-T09-B
Si CFS-L10-1313-T10-B
Si CFS-L10-1313-T01-C
Si CFS-L10-1313-T02-C
Si CFS-L10-1313-T03-C
Si CFS-L10-1313-T04-C
Si CFS-L10-1313-T05-C
Si CFS-L10-1313-T06-C
Si CFS-L10-1313-T07-C
Si CFS-L10-1313-T08-C
Si CFS-L10-1313-T09-C
Si CFS-L10-1313-T10-C
Si CFS-L10-1313-B01-A
Si CFS-L10-1313-B02-A
Si CFS-L10-1313-B03-A
Si CFS-L10-1313-B01-B
Si CFS-L10-1313-B02-B
Si CFS-L10-1313-B03-B
Si CFS-L10-1313-B01-C
Si CFS-L10-1313-B02-C
Si CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.93E+02
1 2.51 E+02
1 4.60E+02
1 7.20E+02
1 2.26E+03
1 1.10E+04
1 2.50E+04
1 5.81 E+04
1 1.37E+05
1 3.83E+03
1 3.80E+02
1 2.85E+02
1 4.99E+02
1 8.75E+02
1 2.67E+03
1 1.20E+04
1 2.52E+04
1 5.57E+04
1 1.30E+05
1 3.67E+03
1 3.77E+02
1 3.33E+02
1 5.08E+02
1 9.63E+02
1 2.49E+03
1 1.10E+04
1 2.64E+04
1 5.86E+04
1 1.34E+05
1 3.90E+03
1 7.71 E+00
1 7.29E+00
1 4.27E+02
1 7.93E+00
1 1.10E+01
1 7.33E+02
1 1.39E+01
1 9.98E+00
1 8. 11 E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.93E+02 2.5E+00 1.1E+00 3.5E+00
2.51E+02 3.2E+00 1.1 E+00 3.5E+00 1000 100
4.60E+02 9.1E-01 1.1 E+00 3.5E+00
7.20E+02 4.2E-01 1.1 E+00 3.5E+00
2.26E+03 5.5E-01 1.1 E+00 3.5E+00
1.10E+04 1.1 E+00 1.1 E+00 3.5E+00
2.50E+04 1.1 E+00 1.1 E+00 3.5E+00
5.81E+04 9.9E-02 1.1 E+00 3.5E+00
1.37E+05 1.1E-01 1.1 E+00 3.5E+00
3.83E+03 1.1 E+00 1.1 E+00 3.5E+00
3.80E+02 4.9E-01 1.1 E+00 3.5E+00
2.85E+02 7.1E-01 1.1 E+00 3.5E+00 1000 100
4.99E+02 9.3E-01 1.1 E+00 3.5E+00
8.75E+02 2.8E-01 1.1 E+00 3.5E+00
2.67E+03 1.8E+00 1.1 E+00 3.5E+00
1.20E+04 1.1 E+00 1.1 E+00 3.5E+00
2.52E+04 1.5E+00 1.1 E+00 3.5E+00
5.57E+04 3.8E-01 1.1 E+00 3.5E+00
1.30E+05 5.6E-01 1.1 E+00 3.5E+00
3.67E+03 3.9E-01 1.1 E+00 3.5E+00
3.77E+02 1.1 E+00 1.1 E+00 3.5E+00
3.33E+02 1.5E+00 1.1 E+00 3.5E+00 1000 100
5.08E+02 1.3E+00 1.1 E+00 3.5E+00
9.63E+02 6.5E-01 1.1 E+00 3.5E+00
2.49E+03 2.1E-01 1.1 E+00 3.5E+00
1.10E+04 4.7E-01 1.1 E+00 3.5E+00
2.64E+04 2.0E-01 1.1 E+00 3.5E+00
5.86E+04 4.1E-01 1.1 E+00 3.5E+00
1.34E+05 6.6E-01 1.1 E+00 3.5E+00
3.90E+03 1.1 E+00 1.1 E+00 3.5E+00
7.71E+00 2.1E+01 1.1 E+00 3.5E+00
7.29E+00 3.3E+01 1.1 E+00 3.5E+00
4.27E+02 1.1E+01 1.1 E+00 3.5E+00
7.93E+00 1.2E+01 1.1 E+00 3.5E+00
1.10E+01 9.5E+00 1.1 E+00 3.5E+00
7.33E+02 8.6E+00 1.1 E+00 3.5E+00
1.39E+01 1.2E+01 1.1 E+00 3.5E+00
9.98E+00 3.4E+01 1.1 E+00 3.5E+00
8.11E+02 6.7E+00 1.1 E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.32E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.28E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-837
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na CFS-L10-1313-T01-A
Na CFS-L10-1313-T02-A
Na CFS-L10-1313-T03-A
Na CFS-L10-1313-T04-A
Na CFS-L10-1313-T05-A
Na CFS-L10-1313-T06-A
Na CFS-L10-1313-T07-A
Na CFS-L10-1313-T08-A
Na CFS-L10-1313-T09-A
Na CFS-L10-1313-T10-A
Na CFS-L10-1313-T01-B
Na CFS-L10-1313-T02-B
Na CFS-L10-1313-T03-B
Na CFS-L10-1313-T04-B
Na CFS-L10-1313-T05-B
Na CFS-L10-1313-T06-B
Na CFS-L10-1313-T07-B
Na CFS-L10-1313-T08-B
Na CFS-L10-1313-T09-B
Na CFS-L10-1313-T10-B
Na CFS-L10-1313-T01-C
Na CFS-L10-1313-T02-C
Na CFS-L10-1313-T03-C
Na CFS-L10-1313-T04-C
Na CFS-L10-1313-T05-C
Na CFS-L10-1313-T06-C
Na CFS-L10-1313-T07-C
Na CFS-L10-1313-T08-C
Na CFS-L10-1313-T09-C
Na CFS-L10-1313-T10-C
Na CFS-L10-1313-B01-A
Na CFS-L10-1313-B02-A
Na CFS-L10-1313-B03-A
Na CFS-L10-1313-B01-B
Na CFS-L10-1313-B02-B
Na CFS-L10-1313-B03-B
Na CFS-L10-1313-B01-C
Na CFS-L10-1313-B02-C
Na CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.21 E+05
1 3.46E+05
1 2.19E+05
1 1.32E+05
1 6.38E+04
1 1.88E+04
1 2.05E+04
1 2.44E+04
1 2.82E+04
1 1.80E+04
1 6.14E+05
1 3.34E+05
1 2.19E+05
1 1.31 E+05
1 6.15E+04
1 1.92E+04
1 1.96E+04
1 2.35E+04
1 2.64E+04
1 1.84E+04
1 6.21 E+05
1 3.30E+05
1 2.13E+05
1 1.27E+05
1 6.20E+04
1 1.87E+04
1 1.99E+04
1 2.32E+04
1 2.54E+04
1 1.73E+04
1 5.77E+01
1 6.71E+01
1 6.23E+05
1 1.60E+02
1 9.99E+01
1 6.28E+05
1 2.06E+02
1 6.67E+01
1 6.33E+05
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.21 E+05 2.1E+00 2.5E+00 8.0E+00
3.46E+05 1.5E-01 2.5E+00 8.0E+00 1000 100
2.19E+05 3.4E-01 2.5E+00 8.0E+00
1.32E+05 5.7E-01 2.5E+00 8.0E+00
6.38E+04 8.7E-01 2.5E+00 8.0E+00
1.88E+04 1.2E+00 2.5E+00 8.0E+00
2.05E+04 3.1E-01 2.5E+00 8.0E+00
2.44E+04 1.2E+00 2.5E+00 8.0E+00
2.82E+04 5.2E-01 2.5E+00 8.0E+00
1.80E+04 8.6E-01 2.5E+00 8.0E+00
6.14E+05 2.7E+00 2.5E+00 8.0E+00
3.34E+05 5.0E-01 2.5E+00 8.0E+00 1000 100
2.19E+05 8.8E-01 2.5E+00 8.0E+00
1.31 E+05 2.5E-01 2.5E+00 8.0E+00
6.15E+04 2.1E-01 2.5E+00 8.0E+00
1.92E+04 9.7E-01 2.5E+00 8.0E+00
1.96E+04 4.3E-01 2.5E+00 8.0E+00
2.35E+04 9.2E-01 2.5E+00 8.0E+00
2.64E+04 3.7E-01 2.5E+00 8.0E+00
1.84E+04 6.0E-01 2.5E+00 8.0E+00
6.21 E+05 3.6E+00 2.5E+00 8.0E+00
3.30E+05 6.0E-01 2.5E+00 8.0E+00 1000 100
2.13E+05 3.2E-01 2.5E+00 8.0E+00
1.27E+05 7.7E-01 2.5E+00 8.0E+00
6.20E+04 4.5E-01 2.5E+00 8.0E+00
1.87E+04 2.4E-01 2.5E+00 8.0E+00
1.99E+04 8.3E-01 2.5E+00 8.0E+00
2.32E+04 9.8E-01 2.5E+00 8.0E+00
2.54E+04 1.1E+00 2.5E+00 8.0E+00
1.73E+04 6.5E-01 2.5E+00 8.0E+00
5.77E+01 3.2E+00 2.5E+00 8.0E+00
6.71 E+01 3.7E+00 2.5E+00 8.0E+00
6.23E+05 1.2E+00 2.5E+00 8.0E+00
1.60E+02 3.4E+00 2.5E+00 8.0E+00
9.99E+01 5.3E+00 2.5E+00 8.0E+00
6.28E+05 2.8E+00 2.5E+00 8.0E+00
2.06E+02 2.5E+00 2.5E+00 8.0E+00
6.67E+01 3.1E+00 2.5E+00 8.0E+00
6.33E+05 1.0E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.47E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.31 E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-838
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr CFS-L10-1313-T01-A
Sr CFS-L10-1313-T02-A
Sr CFS-L10-1313-T03-A
Sr CFS-L10-1313-T04-A
Sr CFS-L10-1313-T05-A
Sr CFS-L10-1313-T06-A
Sr CFS-L10-1313-T07-A
Sr CFS-L10-1313-T08-A
Sr CFS-L10-1313-T09-A
Sr CFS-L10-1313-T10-A
Sr CFS-L10-1313-T01-B
Sr CFS-L10-1313-T02-B
Sr CFS-L10-1313-T03-B
Sr CFS-L10-1313-T04-B
Sr CFS-L10-1313-T05-B
Sr CFS-L10-1313-T06-B
Sr CFS-L10-1313-T07-B
Sr CFS-L10-1313-T08-B
Sr CFS-L10-1313-T09-B
Sr CFS-L10-1313-T10-B
Sr CFS-L10-1313-T01-C
Sr CFS-L10-1313-T02-C
Sr CFS-L10-1313-T03-C
Sr CFS-L10-1313-T04-C
Sr CFS-L10-1313-T05-C
Sr CFS-L10-1313-T06-C
Sr CFS-L10-1313-T07-C
Sr CFS-L10-1313-T08-C
Sr CFS-L10-1313-T09-C
Sr CFS-L10-1313-T10-C
Sr CFS-L10-1313-B01-A
Sr CFS-L10-1313-B02-A
Sr CFS-L10-1313-B03-A
Sr CFS-L10-1313-B01-B
Sr CFS-L10-1313-B02-B
Sr CFS-L10-1313-B03-B
Sr CFS-L10-1313-B01-C
Sr CFS-L10-1313-B02-C
Sr CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.07E+03
1 3.35E+03
1 3.81 E+03
1 3.07E+03
1 2.46E+03
1 8.91 E+02
1 9.55E+02
1 1.10E+03
1 1.30E+03
1 1.46E+03
1 2.98E+03
1 3.19E+03
1 3.56E+03
1 3.39E+03
1 2.40E+03
1 9.42E+02
1 9.82E+02
1 1.07E+03
1 1.22E+03
1 1.41 E+03
1 2.95E+03
1 3.41 E+03
1 3.76E+03
1 3.52E+03
1 2.38E+03
1 8.80E+02
1 1.05E+03
1 1.14E+03
1 1.44E+03
1 1.45E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.44E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.54E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.72E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.07E+03 6.4E-01 1.0E+00 3.2E+00
3.35E+03 1.6E+00 1.0E+00 3.2E+00 1000 100
3.81 E+03 5.2E-01 1.0E+00 3.2E+00
3.07E+03 1.0E+00 1.0E+00 3.2E+00
2.46E+03 1.4E+00 1.0E+00 3.2E+00
8.91 E+02 1.1E+00 1.0E+00 3.2E+00
9.55E+02 2.8E-01 1.0E+00 3.2E+00
1.10E+03 1.1E+00 1.0E+00 3.2E+00
1.30E+03 2.5E-01 1.0E+00 3.2E+00
1.46E+03 1.0E+00 1.0E+00 3.2E+00
2.98E+03 6.8E-01 1.0E+00 3.2E+00
3.19E+03 8.8E-01 1.0E+00 3.2E+00 1000 100
3.56E+03 9.8E-01 1.0E+00 3.2E+00
3.39E+03 1.8E+00 1.0E+00 3.2E+00
2.40E+03 1.4E+00 1.0E+00 3.2E+00
9.42E+02 8.4E-01 1.0E+00 3.2E+00
9.82E+02 1.2E+00 1.0E+00 3.2E+00
1.07E+03 8.4E-01 1.0E+00 3.2E+00
1.22E+03 1.6E+00 1.0E+00 3.2E+00
1.41 E+03 2.1E-01 1.0E+00 3.2E+00
2.95E+03 4.2E-01 1.0E+00 3.2E+00
3.41E+03 1.9E+00 1.0E+00 3.2E+00 1000 100
3.76E+03 6.4E-01 1.0E+00 3.2E+00
3.52E+03 4.7E-01 1.0E+00 3.2E+00
2.38E+03 5.0E-01 1.0E+00 3.2E+00
8.80E+02 5.0E-01 1.0E+00 3.2E+00
1.05E+03 1.7E+00 1.0E+00 3.2E+00
1.14E+03 1.2E+00 1.0E+00 3.2E+00
1.44E+03 7.4E-01 1.0E+00 3.2E+00
1.45E+03 9.5E-01 1.0E+00 3.2E+00
5.00E-01 3.9E+03 1.0E+00 3.2E+00
5.00E-01 2.6E+02 1.0E+00 3.2E+00
1.44E+01 5.2E+00 1.0E+00 3.2E+00
5.00E-01 1.7E+02 1.0E+00 3.2E+00
5.00E-01 2.1 E+02 1.0E+00 3.2E+00
1.54E+01 1.1E+01 1.0E+00 3.2E+00
5.00E-01 8.1E+01 1.0E+00 3.2E+00
5.00E-01 1.6E+02 1.0E+00 3.2E+00
1.72E+01 2.6E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.25E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.13E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.34E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-839
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S CFS-L10-1313-T01-A
S CFS-L10-1313-T02-A
S CFS-L10-1313-T03-A
S CFS-L10-1313-T04-A
S CFS-L10-1313-T05-A
S CFS-L10-1313-T06-A
S CFS-L10-1313-T07-A
S CFS-L10-1313-T08-A
S CFS-L10-1313-T09-A
S CFS-L10-1313-T10-A
S CFS-L10-1313-T01-B
S CFS-L10-1313-T02-B
S CFS-L10-1313-T03-B
S CFS-L10-1313-T04-B
S CFS-L10-1313-T05-B
S CFS-L10-1313-T06-B
S CFS-L10-1313-T07-B
S CFS-L10-1313-T08-B
S CFS-L10-1313-T09-B
S CFS-L10-1313-T10-B
S CFS-L10-1313-T01-C
S CFS-L10-1313-T02-C
S CFS-L10-1313-T03-C
S CFS-L10-1313-T04-C
S CFS-L10-1313-T05-C
S CFS-L10-1313-T06-C
S CFS-L10-1313-T07-C
S CFS-L10-1313-T08-C
S CFS-L10-1313-T09-C
S CFS-L10-1313-T10-C
S CFS-L10-1313-B01-A
S CFS-L10-1313-B02-A
S CFS-L10-1313-B03-A
S CFS-L10-1313-B01-B
S CFS-L10-1313-B02-B
S CFS-L10-1313-B03-B
S CFS-L10-1313-B01-C
S CFS-L10-1313-B02-C
S CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.47E+06
1 9.43E+05
1 7.39E+05
1 6.58E+05
1 6.06E+05
1 5.62E+05
1 5.97E+05
1 6.77E+05
1 7.26E+05
1 5.75E+05
1 1.47E+06
1 9.22E+05
1 7.41 E+05
1 6.55E+05
1 6.04E+05
1 5.85E+05
1 5.95E+05
1 6.58E+05
1 6.98E+05
1 5.70E+05
1 1.44E+06
1 9.38E+05
1 7.61 E+05
1 6.78E+05
1 6. 17 E+05
1 5.57E+05
1 6.16E+05
1 6.73E+05
1 6.96E+05
1 5.85E+05
1 2.16E+01 E
1 9.09E+01
1 5.21 E+02
1 4.05E+02
1 2.58E+02
1 2.37E+02
1 2.24E+02
1 1.09E+02
1 4.23E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.47E+06 3.1E-01 6.8E+00 2.2E+01
9.43E+05 6.6E-01 6.8E+00 2.2E+01 1000 100
7.39E+05 7.6E-01 6.8E+00 2.2E+01
6.58E+05 8.4E-01 6.8E+00 2.2E+01
6.06E+05 1.0E+00 6.8E+00 2.2E+01
5.62E+05 5.4E-01 6.8E+00 2.2E+01
5.97E+05 6.4E-01 6.8E+00 2.2E+01
6.77E+05 5.3E-01 6.8E+00 2.2E+01
7.26E+05 5.6E-01 6.8E+00 2.2E+01
5.75E+05 5.8E-01 6.8E+00 2.2E+01
1.47E+06 1.1E-01 6.8E+00 2.2E+01
9.22E+05 4.7E-01 6.8E+00 2.2E+01 1000 100
7.41 E+05 7.6E-01 6.8E+00 2.2E+01
6.55E+05 4.6E-01 6.8E+00 2.2E+01
6.04E+05 1.0E+00 6.8E+00 2.2E+01
5.85E+05 9.6E-01 6.8E+00 2.2E+01
5.95E+05 4.3E-01 6.8E+00 2.2E+01
6.58E+05 2.7E-01 6.8E+00 2.2E+01
6.98E+05 1.0E+00 6.8E+00 2.2E+01
5.70E+05 3.1E-01 6.8E+00 2.2E+01
1.44E+06 4.0E-01 6.8E+00 2.2E+01
9.38E+05 1.3E+00 6.8E+00 2.2E+01 1000 100
7.61 E+05 3.0E-01 6.8E+00 2.2E+01
6.78E+05 8.6E-01 6.8E+00 2.2E+01
6.17E+05 7.5E-01 6.8E+00 2.2E+01
5.57E+05 4.9E-01 6.8E+00 2.2E+01
6.16E+05 1.2E+00 6.8E+00 2.2E+01
6.73E+05 4.0E-01 6.8E+00 2.2E+01
6.96E+05 3.2E-01 6.8E+00 2.2E+01
5.85E+05 2.8E-01 6.8E+00 2.2E+01
2.16E+01 8.0E+00 6.8E+00 2.2E+01
9.09E+01 1.2E+01 6.8E+00 2.2E+01
5.21 E+02 2.7E+01 6.8E+00 2.2E+01
4.05E+02 1.4E+01 6.8E+00 2.2E+01
2.58E+02 3.1E+00 6.8E+00 2.2E+01
2.37E+02 1.2E+01 6.8E+00 2.2E+01
2.24E+02 5.4E+00 6.8E+00 2.2E+01
1.09E+02 1.1E+01 6.8E+00 2.2E+01
4.23E+02 7.1E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.44E+05 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.23E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-840
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
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Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
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Tl
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Sample Dilutic
CFS-L10-1313-T01-A
CFS-L10-1313-T02-A
CFS-L10-1313-T03-A
CFS-L10-1313-T04-A
CFS-L10-1313-T05-A
CFS-L10-1313-T06-A
CFS-L10-1313-T07-A
CFS-L10-1313-T08-A
CFS-L10-1313-T09-A
CFS-L10-1313-T10-A
CFS-L10-1313-T01-B
CFS-L10-1313-T02-B
CFS-L10-1313-T03-B
CFS-L10-1313-T04-B
CFS-L10-1313-T05-B
CFS-L10-1313-T06-B
CFS-L10-1313-T07-B
CFS-L10-1313-T08-B
CFS-L10-1313-T09-B
CFS-L10-1313-T10-B
CFS-L10-1313-T01-C
CFS-L10-1313-T02-C
CFS-L10-1313-T03-C
CFS-L10-1313-T04-C
CFS-L10-1313-T05-C
CFS-L10-1313-T06-C
CFS-L10-1313-T07-C
CFS-L10-1313-T08-C
CFS-L10-1313-T09-C
CFS-L10-1313-T10-C
CFS-L10-1313-B01-A
CFS-L10-1313-B02-A
CFS-L10-1313-B03-A
CFS-L10-1313-B01-B
CFS-L10-1313-B02-B
CFS-L10-1313-B03-B
CFS-L10-1313-B01-C
CFS-L10-1313-B02-C
CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.26E+01
1 6.74E+01
1 1.32E+02
1 2.14E+02
1 2.93E+02
1 3.90E+02
1 5.46E+02
1 8.71 E+02
1 1.19E+03
1 2.86E+02
1 9.39E+01
1 6.69E+01
1 1.32E+02
1 2.32E+02
1 3.24E+02
1 4.24E+02
1 5.52E+02
1 8.85E+02
1 1.18E+03
1 2.72E+02
1 9.43E+01
1 6.68E+01
1 1.44E+02
1 2.56E+02
1 3.15E+02
1 4.07E+02
1 5.86E+02
1 8.66E+02
1 1.15E+03
1 2.83E+02
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.26E+01 4.0E+00 4.6E+00 1.5E+01
6.74E+01 1.2E+01 4.6E+00 1.5E+01 10 120
1.32E+02 4.3E+00 4.6E+00 1.5E+01
2.14E+02 6.1E+00 4.6E+00 1.5E+01
2.93E+02 2.7E+00 4.6E+00 1.5E+01
3.90E+02 1.3E+00 4.6E+00 1.5E+01
5.46E+02 1.3E+00 4.6E+00 1.5E+01
8.71 E+02 5.6E-01 4.6E+00 1.5E+01
1.19E+03 1.0E+00 4.6E+00 1.5E+01
2.86E+02 7.3E-01 4.6E+00 1.5E+01
9.39E+01 2.2E+00 4.6E+00 1.5E+01
6.69E+01 4.1E+00 4.6E+00 1.5E+01 10 120
1.32E+02 2.0E+00 4.6E+00 1.5E+01
2.32E+02 2.3E+00 4.6E+00 1.5E+01
3.24E+02 2.5E+00 4.6E+00 1.5E+01
4.24E+02 1.4E+00 4.6E+00 1.5E+01
5.52E+02 8.5E-01 4.6E+00 1.5E+01
8.85E+02 4.2E-01 4.6E+00 1.5E+01
1.18E+03 1.3E+00 4.6E+00 1.5E+01
2.72E+02 4.8E-01 4.6E+00 1.5E+01
9.43E+01 2.2E+00 4.6E+00 1.5E+01
6.68E+01 1.1E+01 4.6E+00 1.5E+01 10 120
1.44E+02 2.7E+00 4.6E+00 1.5E+01
2.56E+02 3.0E+00 4.6E+00 1.5E+01
3.15E+02 1.9E+00 4.6E+00 1.5E+01
4.07E+02 1.6E+00 4.6E+00 1.5E+01
5.86E+02 2.4E+00 4.6E+00 1.5E+01
8.66E+02 7.4E-01 4.6E+00 1.5E+01
1.15E+03 1.4E+00 4.6E+00 1.5E+01
2.83E+02 2.8E-01 4.6E+00 1.5E+01
2.30E+00 6.8E+00 4.6E+00 1.5E+01
2.30E+00 1.4E+01 4.6E+00 1.5E+01
2.30E+00 3.6E+00 4.6E+00 1.5E+01
2.30E+00 4.6E+00 4.6E+00 1.5E+01
2.30E+00 1.8E+01 4.6E+00 1.5E+01
2.30E+00 5.6E+00 4.6E+00 1.5E+01
2.30E+00 6.4E+00 4.6E+00 1.5E+01
2.30E+00 7.1E+00 4.6E+00 1.5E+01
2.30E+00 2.6E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.09E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.39E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-841
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
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Ti
Ti
Ti
Ti
Ti
Ti
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Ti
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Sample Dilutic
CFS-L10-1313-T01-A
CFS-L10-1313-T02-A
CFS-L10-1313-T03-A
CFS-L10-1313-T04-A
CFS-L10-1313-T05-A
CFS-L10-1313-T06-A
CFS-L10-1313-T07-A
CFS-L10-1313-T08-A
CFS-L10-1313-T09-A
CFS-L10-1313-T10-A
CFS-L10-1313-T01-B
CFS-L10-1313-T02-B
CFS-L10-1313-T03-B
CFS-L10-1313-T04-B
CFS-L10-1313-T05-B
CFS-L10-1313-T06-B
CFS-L10-1313-T07-B
CFS-L10-1313-T08-B
CFS-L10-1313-T09-B
CFS-L10-1313-T10-B
CFS-L10-1313-T01-C
CFS-L10-1313-T02-C
CFS-L10-1313-T03-C
CFS-L10-1313-T04-C
CFS-L10-1313-T05-C
CFS-L10-1313-T06-C
CFS-L10-1313-T07-C
CFS-L10-1313-T08-C
CFS-L10-1313-T09-C
CFS-L10-1313-T10-C
CFS-L10-1313-B01-A
CFS-L10-1313-B02-A
CFS-L10-1313-B03-A
CFS-L10-1313-B01-B
CFS-L10-1313-B02-B
CFS-L10-1313-B03-B
CFS-L10-1313-B01-C
CFS-L10-1313-B02-C
CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.47E+00 E
1 1.86E+01
1 2.33E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 3.61E+OOE
1 1.77E+01
1 2.20E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 4.35E+00 E
1 1.83E+01
1 2.10E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.2E+01 2.0E+00 6.4E+00
1.00E+00 9.5E+01 2.0E+00 6.4E+00 10 120
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 8.1E+00 2.0E+00 6.4E+00
1.00E+00 9.3E+01 2.0E+00 6.4E+00
1.00E+00 4.4E+01 2.0E+00 6.4E+00
3.47E+00 1.4E+01 2.0E+00 6.4E+00
1.86E+01 2.0E+00 2.0E+00 6.4E+00
2.33E+01 2.8E+00 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 5.9E+01 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00 10 120
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
3.61 E+00 1.4E+01 2.0E+00 6.4E+00
1.77E+01 5.6E-01 2.0E+00 6.4E+00
2.20E+01 5.1E+00 2.0E+00 6.4E+00
1.00E+00 7.7E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+00 2.0E+00 6.4E+00 10 120
1.00E+00 3.1E+01 2.0E+00 6.4E+00
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
4.35E+00 3.4E+00 2.0E+00 6.4E+00
1.83E+01 1.4E+00 2.0E+00 6.4E+00
2.10E+01 8.7E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 2.3E-01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.15E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L1 01 31 3-1 31 6 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/1 3/1 1 3:25 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/1 3/1 1 3:27 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/1 3/1 1 3:29 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/1 3/1 1 3:30 P M EPA Interlab L1 0 1 31 3-1 31 6 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-842
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V CFS-L10-1313-T01-A
V CFS-L10-1313-T02-A
V CFS-L10-1313-T03-A
V CFS-L10-1313-T04-A
V CFS-L10-1313-T05-A
V CFS-L10-1313-T06-A
V CFS-L10-1313-T07-A
V CFS-L10-1313-T08-A
V CFS-L10-1313-T09-A
V CFS-L10-1313-T10-A
V CFS-L10-1313-T01-B
V CFS-L10-1313-T02-B
V CFS-L10-1313-T03-B
V CFS-L10-1313-T04-B
V CFS-L10-1313-T05-B
V CFS-L10-1313-T06-B
V CFS-L10-1313-T07-B
V CFS-L10-1313-T08-B
V CFS-L10-1313-T09-B
V CFS-L10-1313-T10-B
V CFS-L10-1313-T01-C
V CFS-L10-1313-T02-C
V CFS-L10-1313-T03-C
V CFS-L10-1313-T04-C
V CFS-L10-1313-T05-C
V CFS-L10-1313-T06-C
V CFS-L10-1313-T07-C
V CFS-L10-1313-T08-C
V CFS-L10-1313-T09-C
V CFS-L10-1313-T10-C
V CFS-L10-1313-B01-A
V CFS-L10-1313-B02-A
V CFS-L10-1313-B03-A
V CFS-L10-1313-B01-B
V CFS-L10-1313-B02-B
V CFS-L10-1313-B03-B
V CFS-L10-1313-B01-C
V CFS-L10-1313-B02-C
V CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.27E+01
1 2.36E+01
1 2.57E+01
1 2.67E+01
1 2.68E+01
1 3.01 E+01
1 3.77E+01
1 5.39E+01
1 3.87E+02
1 2.91 E+01
1 1.35E+01
1 2.22E+01
1 2.40E+01
1 2.72E+01
1 2.81 E+01
1 3.13E+01
1 3.69E+01
1 4.66E+01
1 3.75E+02
1 2.78E+01
1 1.34E+01
1 2.36E+01
1 2.60E+01
1 2.78E+01
1 3.03E+01
1 3.02E+01
1 3.76E+01
1 4.49E+01
1 3.77E+02
1 2.88E+01
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 1.88E+00 E
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+01 1.7E+01 1.5E+00 4.8E+00
2.36E+01 6.7E+00 1.5E+00 4.8E+00 10 120
2.57E+01 4.1E+00 1.5E+00 4.8E+00
2.67E+01 2.4E+00 1.5E+00 4.8E+00
2.68E+01 6.8E+00 1.5E+00 4.8E+00
3.01 E+01 1.2E+00 1.5E+00 4.8E+00
3.77E+01 2.0E+00 1.5E+00 4.8E+00
5.39E+01 2.7E+00 1.5E+00 4.8E+00
3.87E+02 1.8E-01 1.5E+00 4.8E+00
2.91 E+01 2.2E+00 1.5E+00 4.8E+00
1.35E+01 5.2E+00 1.5E+00 4.8E+00
2.22E+01 6.1E+00 1.5E+00 4.8E+00 10 120
2.40E+01 7.6E+00 1.5E+00 4.8E+00
2.72E+01 3.2E+00 1.5E+00 4.8E+00
2.81 E+01 3.0E+00 1.5E+00 4.8E+00
3.13E+01 1.8E+00 1.5E+00 4.8E+00
3.69E+01 2.6E+00 1.5E+00 4.8E+00
4.66E+01 2.0E+00 1.5E+00 4.8E+00
3.75E+02 2.8E-01 1.5E+00 4.8E+00
2.78E+01 2.9E+00 1.5E+00 4.8E+00
1.34E+01 1.5E+00 1.5E+00 4.8E+00
2.36E+01 5.7E+00 1.5E+00 4.8E+00 10 120
2.60E+01 2.5E+00 1.5E+00 4.8E+00
2.78E+01 4.1E+00 1.5E+00 4.8E+00
3.03E+01 3.1E+00 1.5E+00 4.8E+00
3.02E+01 4.2E+00 1.5E+00 4.8E+00
3.76E+01 1.1E+00 1.5E+00 4.8E+00
4.49E+01 6.9E+00 1.5E+00 4.8E+00
3.77E+02 5.9E-01 1.5E+00 4.8E+00
2.88E+01 3.1E+00 1.5E+00 4.8E+00
7.50E-01 1.9E+01 1.5E+00 4.8E+00
7.50E-01 5.4E+01 1.5E+00 4.8E+00
7.50E-01 2.9E+01 1.5E+00 4.8E+00
7.50E-01 6.9E+01 1.5E+00 4.8E+00
7.50E-01 2.9E+01 1.5E+00 4.8E+00
1.88E+00 5.6E+01 1.5E+00 4.8E+00
7.50E-01 6.5E+01 1.5E+00 4.8E+00
7.50E-01 4.5E+01 1.5E+00 4.8E+00
7.50E-01 3.6E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.16E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/1 1 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-843
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn CFS-L10-1313-T01-A
Zn CFS-L10-1313-T02-A
Zn CFS-L10-1313-T03-A
Zn CFS-L10-1313-T04-A
Zn CFS-L10-1313-T05-A
Zn CFS-L10-1313-T06-A
Zn CFS-L10-1313-T07-A
Zn CFS-L10-1313-T08-A
Zn CFS-L10-1313-T09-A
Zn CFS-L10-1313-T10-A
Zn CFS-L10-1313-T01-B
Zn CFS-L10-1313-T02-B
Zn CFS-L10-1313-T03-B
Zn CFS-L10-1313-T04-B
Zn CFS-L10-1313-T05-B
Zn CFS-L10-1313-T06-B
Zn CFS-L10-1313-T07-B
Zn CFS-L10-1313-T08-B
Zn CFS-L10-1313-T09-B
Zn CFS-L10-1313-T10-B
Zn CFS-L10-1313-T01-C
Zn CFS-L10-1313-T02-C
Zn CFS-L10-1313-T03-C
Zn CFS-L10-1313-T04-C
Zn CFS-L10-1313-T05-C
Zn CFS-L10-1313-T06-C
Zn CFS-L10-1313-T07-C
Zn CFS-L10-1313-T08-C
Zn CFS-L10-1313-T09-C
Zn CFS-L10-1313-T10-C
Zn CFS-L10-1313-B01-A
Zn CFS-L10-1313-B02-A
Zn CFS-L10-1313-B03-A
Zn CFS-L10-1313-B01-B
Zn CFS-L10-1313-B02-B
Zn CFS-L10-1313-B03-B
Zn CFS-L10-1313-B01-C
Zn CFS-L10-1313-B02-C
Zn CFS-L10-1313-B03-C
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.57E+04
1 1.81E+03
1 2.09E+01
1 6.37E+01
1 4.34E+03
1 9.72E+04
1 1.52E+05
1 1.81E+05
1 1.79E+05
1 1.95E+04
1 1.85E+04
1 1.61E+03
1 2.03E+01
1 7.31E+01
1 6.22E+03
1 1.04E+05
1 1.60E+05
1 1.86E+05
1 1.76E+05
1 1.98E+04
1 1.79E+04
1 1.48E+03
1 2.00E+01
1 1.01E+02
1 6.07E+03
1 1.00E+05
1 1.60E+05
1 1.86E+05
1 1.84E+05
1 2.11E+04
1 3.14E+00 E
1 7.81 E+00
1 6.43E+00
1 3.49E+00
1 5.60E+00
1 1.24E+01
1 4.61 E+00
1 1.61E+01
1 6.68E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.57E+04 2.0E+00 1.0E+00 3.2E+00
1.81E+03 1.5E+00 1.0E+00 3.2E+00 10 120
2.09E+01 2.5E-01 1.0E+00 3.2E+00
6.37E+01 6.3E-01 1.0E+00 3.2E+00
4.34E+03 1.4E+00 1.0E+00 3.2E+00
9.72E+04 7.0E-01 1.0E+00 3.2E+00
1.52E+05 1.7E+00 1.0E+00 3.2E+00
1.81E+05 5.7E-01 1.0E+00 3.2E+00
1.79E+05 2.8E+00 1.0E+00 3.2E+00
1.95E+04 8.8E-01 1.0E+00 3.2E+00
1.85E+04 7.7E-01 1.0E+00 3.2E+00
1.61E+03 1.1 E+00 1.0E+00 3.2E+00 10 120
2.03E+01 1.9E+00 1.0E+00 3.2E+00
7.31 E+01 3.8E-01 1.0E+00 3.2E+00
6.22E+03 1.0E+00 1.0E+00 3.2E+00
1.04E+05 8.7E-01 1.0E+00 3.2E+00
1.60E+05 1.2E+00 1.0E+00 3.2E+00
1.86E+05 1.0E+00 1.0E+00 3.2E+00
1.76E+05 1.6E+00 1.0E+00 3.2E+00
1.98E+04 3.9E-01 1.0E+00 3.2E+00
1.79E+04 1.4E+00 1.0E+00 3.2E+00
1.48E+03 2.2E+00 1.0E+00 3.2E+00 10 120
2.00E+01 9.6E-01 1.0E+00 3.2E+00
1.01E+02 1.2E+00 1.0E+00 3.2E+00
6.07E+03 1.2E+00 1.0E+00 3.2E+00
1.00E+05 7.7E-01 1.0E+00 3.2E+00
1.60E+05 8.6E-01 1.0E+00 3.2E+00
1.86E+05 5.2E-01 1.0E+00 3.2E+00
1.84E+05 8.8E-01 1.0E+00 3.2E+00
2.11E+04 3.5E-01 1.0E+00 3.2E+00
3.14E+00 6.2E+00 1.0E+00 3.2E+00
7.81 E+00 1.9E+00 1.0E+00 3.2E+00
6.43E+00 7.3E+00 1.0E+00 3.2E+00
3.49E+00 1.1 E+01 1.0E+00 3.2E+00
5.60E+00 3.3E+00 1.0E+00 3.2E+00
1.24E+01 5.3E+00 1.0E+00 3.2E+00
4.61 E+00 7.1 E+00 1.0E+00 3.2E+00
1.61 E+01 2.5E+00 1.0E+00 3.2E+00
6.68E+00 6.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.94E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.72E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.54E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
4/13/11 2:38 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:39 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:41 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:43 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:44 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:46 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:47 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:49 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:51 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:52 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:59 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:01 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:02 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:04 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:06 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:07 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:09 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:11 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:12 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:14 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:16 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:17 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:19 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:20 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:22 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:25 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:27 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 3:30 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:23 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:24 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:26 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:28 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:29 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:31 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:33 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:34 PM EPA Interlab L10 1313-1316 CFS
4/13/11 2:36 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                          1-844
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample Internal
Sample Dilution Cone. Qualifier Review
I I ug/L I
CFS-L11-1313-T01-A 1 9.48E+01
CFS-L11-1313-T02-A 1 9.60E+01
CFS-L11-1313-T03-A 1 7.08E+01
CFS-L11-1313-T04-A 1 6.09E+01
CFS-L11-1313-T05-A 1 4.59E+01
CFS-L11-1313-T06-A 1 4.51 E+01
CFS-L11-1313-T07-A 1 4.07E+03
CFS-L11-1313-T08-A 1 2.40E+04
CFS-L11-1313-T09-A 1 8.40E+04
CFS-L11-1313-T01-B 1 1.03E+02
CFS-L11-1313-T02-B 1 9.82E+01
CFS-L11-1313-T03-B 1 9.47E+01
CFS-L11-1313-T04-B 1 6. 11 E+01
CFS-L11-1313-T05-B 1 4.95E+01
CFS-L11-1313-T06-B 1 4.95E+01
CFS-L11-1313-T07-B 1 3.94E+03
CFS-L11-1313-T08-B 1 2.24E+04
CFS-L11-1313-T09-B 1 7.88E+04
CFS-L11-1313-T01-C 1 1.16E+02
CFS-L11-1313-T02-C 1 1.16E+02
CFS-L11-1313-T03-C 1 7.38E+01
CFS-L11-1313-T04-C 1 5.72E+01
CFS-L11-1313-T05-C 1 4.79E+01
CFS-L11-1313-T06-C 1 4.80E+01
CFS-L11-1313-T07-C 1 4.16E+03
CFS-L11-1313-T08-C 1 2.35E+04
CFS-L11-1313-T09-C 1 8.36E+04
CFS-L11-1313-B01-A 1 5.00E-01 U1/2
CFS-L11-1313-B02-A 1 2.29E+00 E
CFS-L11-1313-B03-A 1 7.87E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.48E+01 2.0E+00 1.0E+00 3.2E+00
9.60E+01 2.7E+00 1.0E+00 3.2E+00 1000 100
7.08E+01 6.0E+00 1.0E+00 3.2E+00
6.09E+01 2.5E+00 1.0E+00 3.2E+00
4.59E+01 2.8E+00 1.0E+00 3.2E+00
4.51 E+01 5.0E+00 1.0E+00 3.2E+00
4.07E+03 2.2E-01 1.0E+00 3.2E+00
2.40E+04 4.4E-01 1.0E+00 3.2E+00
8.40E+04 7.0E-01 1.0E+00 3.2E+00
1.03E+02 2.0E+00 1.0E+00 3.2E+00
9.82E+01 3.9E+00 1.0E+00 3.2E+00 1000 100
9.47E+01 3.3E+00 1.0E+00 3.2E+00
6.11E+01 3.9E+00 1.0E+00 3.2E+00
4.95E+01 3.2E+00 1.0E+00 3.2E+00
4.95E+01 4.8E+00 1.0E+00 3.2E+00
3.94E+03 1.2E-01 1.0E+00 3.2E+00
2.24E+04 2.7E-01 1.0E+00 3.2E+00
7.88E+04 3.8E-01 1.0E+00 3.2E+00
1.16E+02 6.2E-01 1.0E+00 3.2E+00
1.16E+02 9.9E+00 1.0E+00 3.2E+00 1000 100
7.38E+01 1.1E+00 1.0E+00 3.2E+00
5.72E+01 4.3E+00 1.0E+00 3.2E+00
4.79E+01 2.3E+00 1.0E+00 3.2E+00
4.80E+01 7.6E+00 1.0E+00 3.2E+00
4.16E+03 1.3E+00 1.0E+00 3.2E+00
2.35E+04 5.9E-01 1.0E+00 3.2E+00
8.36E+04 5.3E-01 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
2.29E+00 8.9E+01 1.0E+00 3.2E+00
7.87E+02 1.4E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.24E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.24E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                                     1-845
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutic
Sb CFS-L11-1313-T01-A
Sb CFS-L11-1313-T02-A
Sb CFS-L11-1313-T03-A
Sb CFS-L11-1313-T04-A
Sb CFS-L11-1313-T05-A
Sb CFS-L11-1313-T06-A
Sb CFS-L11-1313-T07-A
Sb CFS-L11-1313-T08-A
Sb CFS-L11-1313-T09-A
Sb CFS-L11-1313-T01-B
Sb CFS-L11-1313-T02-B
Sb CFS-L11-1313-T03-B
Sb CFS-L11-1313-T04-B
Sb CFS-L11-1313-T05-B
Sb CFS-L11-1313-T06-B
Sb CFS-L11-1313-T07-B
Sb CFS-L11-1313-T08-B
Sb CFS-L11-1313-T09-B
Sb CFS-L11-1313-T01-C
Sb CFS-L11-1313-T02-C
Sb CFS-L11-1313-T03-C
Sb CFS-L11-1313-T04-C
Sb CFS-L11-1313-T05-C
Sb CFS-L11-1313-T06-C
Sb CFS-L11-1313-T07-C
Sb CFS-L11-1313-T08-C
Sb CFS-L11-1313-T09-C
Sb CFS-L11-1313-B01-A
Sb CFS-L11-1313-B02-A
Sb CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 2.34E+01 E
1 2.35E+01 E
1 1.68E+01 E
1 3.53E+01
1 9.00E+01
1 7.10E+02
1 1.63E+03
1 3.75E+00 U1/2
1 1.03E+01 E
1 3.19E+01
1 3.41 E+01
1 1.56E+01 E
1 2.71E+01
1 9.30E+01
1 7.01 E+02
1 1.56E+03
1 3.75E+00 U1/2
1 3.75E+00 U1/2
1 4.30E+01
1 3.21E+01
1 1.64E+01 E
1 2.25E+01 E
1 8.24E+01
1 6.91 E+02
1 1.65E+03
1 3.75E+00 U1/2
1 1.61E+01 E
1 8.75E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 1.6E+02 7.5E+00 2.4E+01
3.75E+00 7.4E+01 7.5E+00 2.4E+01 10 100
2.34E+01 8.7E+00 7.5E+00 2.4E+01
2.35E+01 2.2E+01 7.5E+00 2.4E+01
1.68E+01 1.7E+01 7.5E+00 2.4E+01
3.53E+01 1.7E+01 7.5E+00 2.4E+01
9.00E+01 6.8E+00 7.5E+00 2.4E+01
7.10E+02 3.2E+00 7.5E+00 2.4E+01
1.63E+03 4.0E+00 7.5E+00 2.4E+01
3.75E+00 9.8E+00 7.5E+00 2.4E+01
1.03E+01 3.9E+01 7.5E+00 2.4E+01 10 100
3.19E+01 1.5E+01 7.5E+00 2.4E+01
3.41 E+01 2.8E+01 7.5E+00 2.4E+01
1.56E+01 1.9E+01 7.5E+00 2.4E+01
2.71 E+01 8.7E+00 7.5E+00 2.4E+01
9.30E+01 1.1E+01 7.5E+00 2.4E+01
7.01 E+02 2.0E+01 7.5E+00 2.4E+01
1.56E+03 7.4E+00 7.5E+00 2.4E+01
3.75E+00 8.7E+02 7.5E+00 2.4E+01
3.75E+00 9.0E+01 7.5E+00 2.4E+01 10 100
4.30E+01 8.7E+00 7.5E+00 2.4E+01
3.21E+01 4.5E+01 7.5E+00 2.4E+01
1.64E+01 2.6E+01 7.5E+00 2.4E+01
2.25E+01 3.8E+01 7.5E+00 2.4E+01
8.24E+01 1.1 E+01 7.5E+00 2.4E+01
6.91 E+02 1.8E+01 7.5E+00 2.4E+01
1.65E+03 9.9E+00 7.5E+00 2.4E+01
3.75E+00 9.9E+01 7.5E+00 2.4E+01
1.61 E+01 1.2E+02 7.5E+00 2.4E+01
8.75E+00 9.6E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.08E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.79E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.41 E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-846
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As CFS-L11-1313-T01-A
As CFS-L11-1313-T02-A
As CFS-L11-1313-T03-A
As CFS-L11-1313-T04-A
As CFS-L11-1313-T05-A
As CFS-L11-1313-T06-A
As CFS-L11-1313-T07-A
As CFS-L11-1313-T08-A
As CFS-L11-1313-T09-A
As CFS-L11-1313-T01-B
As CFS-L11-1313-T02-B
As CFS-L11-1313-T03-B
As CFS-L11-1313-T04-B
As CFS-L11-1313-T05-B
As CFS-L11-1313-T06-B
As CFS-L11-1313-T07-B
As CFS-L11-1313-T08-B
As CFS-L11-1313-T09-B
As CFS-L11-1313-T01-C
As CFS-L11-1313-T02-C
As CFS-L11-1313-T03-C
As CFS-L11-1313-T04-C
As CFS-L11-1313-T05-C
As CFS-L11-1313-T06-C
As CFS-L11-1313-T07-C
As CFS-L11-1313-T08-C
As CFS-L11-1313-T09-C
As CFS-L11-1313-B01-A
As CFS-L11-1313-B02-A
As CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.07E+02
1 1.44E+02
1 5.09E+01
1 4.46E+01
1 1.90E+01 E
1 1.95E+01 E
1 1.10E+02
1 6.04E+02
1 4.26E+04
1 1.97E+02
1 1.50E+02
1 5.18E+01
1 3.09E+01 E
1 1.96E+01 E
1 1.98E+01 E
1 1.16E+02
1 6.03E+02
1 3.41 E+04
1 1.97E+02
1 1.45E+02
1 5.11E+01
1 3.26E+01 E
1 5.50E+00 U1/2
1 1.32E+01 E
1 9.82E+01
1 5.90E+02
1 3.46E+04
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 1.37E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+02 3.9E+00 1.1E+01 3.5E+01
1.44E+02 3.7E+00 1.1E+01 3.5E+01 10 100
5.09E+01 7.8E+00 1.1E+01 3.5E+01
4.46E+01 3.7E+00 1.1E+01 3.5E+01
1.90E+01 2.1E+01 1.1E+01 3.5E+01
1.95E+01 3.2E+01 1.1E+01 3.5E+01
1.10E+02 9.8E+00 1.1E+01 3.5E+01
6.04E+02 2.4E+00 1.1E+01 3.5E+01
4.26E+04 5.6E-01 1.1E+01 3.5E+01
1.97E+02 4.6E+00 1.1E+01 3.5E+01
1.50E+02 8.0E+00 1.1E+01 3.5E+01 10 100
5.18E+01 1.8E+01 1.1E+01 3.5E+01
3.09E+01 1.5E+01 1.1E+01 3.5E+01
1.96E+01 2.4E+01 1.1E+01 3.5E+01
1.98E+01 1.8E+01 1.1E+01 3.5E+01
1.16E+02 8.9E+00 1.1E+01 3.5E+01
6.03E+02 2.0E+00 1.1E+01 3.5E+01
3.41E+04 1.0E+00 1.1E+01 3.5E+01
1.97E+02 1.7E+00 1.1E+01 3.5E+01
1.45E+02 7.6E+00 1.1E+01 3.5E+01 10 100
5.11E+01 1.1E+01 1.1E+01 3.5E+01
3.26E+01 2.0E+01 1.1E+01 3.5E+01
5.50E+00 1.4E+02 1.1E+01 3.5E+01
1.32E+01 9.4E+01 1.1E+01 3.5E+01
9.82E+01 6.5E+00 1.1E+01 3.5E+01
5.90E+02 1.7E+00 1.1E+01 3.5E+01
3.46E+04 2.1E-01 1.1E+01 3.5E+01
5.50E+00 1.2E+03 1.1E+01 3.5E+01
5.50E+00 5.7E+01 1.1E+01 3.5E+01
1.37E+01 5.6E+00 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.06E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-847
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B CFS-L11-1313-T01-A
B CFS-L11-1313-T02-A
B CFS-L11-1313-T03-A
B CFS-L11-1313-T04-A
B CFS-L11-1313-T05-A
B CFS-L11-1313-T06-A
B CFS-L11-1313-T07-A
B CFS-L11-1313-T08-A
B CFS-L11-1313-T09-A
B CFS-L11-1313-T01-B
B CFS-L11-1313-T02-B
B CFS-L11-1313-T03-B
B CFS-L11-1313-T04-B
B CFS-L11-1313-T05-B
B CFS-L11-1313-T06-B
B CFS-L11-1313-T07-B
B CFS-L11-1313-T08-B
B CFS-L11-1313-T09-B
B CFS-L11-1313-T01-C
B CFS-L11-1313-T02-C
B CFS-L11-1313-T03-C
B CFS-L11-1313-T04-C
B CFS-L11-1313-T05-C
B CFS-L11-1313-T06-C
B CFS-L11-1313-T07-C
B CFS-L11-1313-T08-C
B CFS-L11-1313-T09-C
B CFS-L11-1313-B01-A
B CFS-L11-1313-B02-A
B CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.32E+02
1 5.75E+02
1 2.85E+02
1 1.74E+02
1 1.33E+02
1 7.45E+01
1 2.15E+02
1 4.27E+02
1 6.57E+02
1 8.23E+02
1 5.59E+02
1 2.68E+02
1 1.70E+02
1 1.27E+02
1 9.15E+01
1 2.29E+02
1 4.32E+02
1 5.79E+02
1 8.96E+02
1 6.03E+02
1 2.65E+02
1 1.57E+02
1 1.18E+02
1 5.92E+01
1 1.95E+02
1 3.98E+02
1 5.89E+02
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 2.24E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.32E+02 1.3E+00 1.0E+00 3.2E+00
5.75E+02 6.3E-01 1.0E+00 3.2E+00 1000 100
2.85E+02 1.8E+00 1.0E+00 3.2E+00
1.74E+02 9.5E-01 1.0E+00 3.2E+00
1.33E+02 2.3E-01 1.0E+00 3.2E+00
7.45E+01 2.8E+00 1.0E+00 3.2E+00
2.15E+02 5.7E-01 1.0E+00 3.2E+00
4.27E+02 1.0E+00 1.0E+00 3.2E+00
6.57E+02 9.5E-01 1.0E+00 3.2E+00
8.23E+02 9.1E-01 1.0E+00 3.2E+00
5.59E+02 2.7E-01 1.0E+00 3.2E+00 1000 100
2.68E+02 9.5E-01 1.0E+00 3.2E+00
1.70E+02 5.3E+00 1.0E+00 3.2E+00
1.27E+02 2.9E+00 1.0E+00 3.2E+00
9.15E+01 9.4E-01 1.0E+00 3.2E+00
2.29E+02 5.4E-01 1.0E+00 3.2E+00
4.32E+02 1.1E+00 1.0E+00 3.2E+00
5.79E+02 1.8E-01 1.0E+00 3.2E+00
8.96E+02 1.1E+00 1.0E+00 3.2E+00
6.03E+02 8.4E+00 1.0E+00 3.2E+00 1000 100
2.65E+02 1.3E+00 1.0E+00 3.2E+00
1.57E+02 2.5E+00 1.0E+00 3.2E+00
1.18E+02 2.7E+00 1.0E+00 3.2E+00
5.92E+01 2.9E+00 1.0E+00 3.2E+00
1.95E+02 1.2E+00 1.0E+00 3.2E+00
3.98E+02 1.1E+00 1.0E+00 3.2E+00
5.89E+02 6.9E-01 1.0E+00 3.2E+00
5.00E-01 5.7E+00 1.0E+00 3.2E+00
5.00E-01 4.9E+00 1.0E+00 3.2E+00
2.24E+03 6.5E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.51E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.45E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.53E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-848
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba CFS-L11-1313-T01-A
Ba CFS-L11-1313-T02-A
Ba CFS-L11-1313-T03-A
Ba CFS-L11-1313-T04-A
Ba CFS-L11-1313-T05-A
Ba CFS-L11-1313-T06-A
Ba CFS-L11-1313-T07-A
Ba CFS-L11-1313-T08-A
Ba CFS-L11-1313-T09-A
Ba CFS-L11-1313-T01-B
Ba CFS-L11-1313-T02-B
Ba CFS-L11-1313-T03-B
Ba CFS-L11-1313-T04-B
Ba CFS-L11-1313-T05-B
Ba CFS-L11-1313-T06-B
Ba CFS-L11-1313-T07-B
Ba CFS-L11-1313-T08-B
Ba CFS-L11-1313-T09-B
Ba CFS-L11-1313-T01-C
Ba CFS-L11-1313-T02-C
Ba CFS-L11-1313-T03-C
Ba CFS-L11-1313-T04-C
Ba CFS-L11-1313-T05-C
Ba CFS-L11-1313-T06-C
Ba CFS-L11-1313-T07-C
Ba CFS-L11-1313-T08-C
Ba CFS-L11-1313-T09-C
Ba CFS-L11-1313-B01-A
Ba CFS-L11-1313-B02-A
Ba CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.40E+03
1 1.77E+03
1 9.81 E+02
1 6.97E+02
1 4.75E+02
1 2.23E+02
1 1.10E+02
1 1.24E+02
1 1.19E+02
1 2.54E+03
1 1.80E+03
1 9.60E+02
1 7.13E+02
1 4.83E+02
1 2.17E+02
1 1.04E+02
1 1.16E+02
1 1.14E+02
1 2.53E+03
1 1.91E+03
1 9.76E+02
1 6.94E+02
1 4.86E+02
1 2.18E+02
1 1.03E+02
1 1.15E+02
1 1.27E+02
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 2.57E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.40E+03 6.1E-01 1.0E+00 3.2E+00
1.77E+03 9.7E-01 1.0E+00 3.2E+00 10 100
9.81 E+02 1.0E+00 1.0E+00 3.2E+00
6.97E+02 5.6E-01 1.0E+00 3.2E+00
4.75E+02 3.9E-01 1.0E+00 3.2E+00
2.23E+02 1.7E-01 1.0E+00 3.2E+00
1.10E+02 1.8E+00 1.0E+00 3.2E+00
1.24E+02 5.3E-01 1.0E+00 3.2E+00
1.19E+02 9.9E-01 1.0E+00 3.2E+00
2.54E+03 8.6E-01 1.0E+00 3.2E+00
1.80E+03 2.3E-01 1.0E+00 3.2E+00 10 100
9.60E+02 1.2E+00 1.0E+00 3.2E+00
7.13E+02 2.4E+00 1.0E+00 3.2E+00
4.83E+02 7.9E-01 1.0E+00 3.2E+00
2.17E+02 5.7E-01 1.0E+00 3.2E+00
1.04E+02 3.1E-01 1.0E+00 3.2E+00
1.16E+02 8.4E-01 1.0E+00 3.2E+00
1.14E+02 2.3E+00 1.0E+00 3.2E+00
2.53E+03 5.3E-01 1.0E+00 3.2E+00
1.91E+03 7.4E+00 1.0E+00 3.2E+00 10 100
9.76E+02 6.7E-01 1.0E+00 3.2E+00
6.94E+02 8.0E-01 1.0E+00 3.2E+00
4.86E+02 6.9E-01 1.0E+00 3.2E+00
2.18E+02 8.1E-01 1.0E+00 3.2E+00
1.03E+02 1.5E+00 1.0E+00 3.2E+00
1.15E+02 6.9E-01 1.0E+00 3.2E+00
1.27E+02 3.4E+00 1.0E+00 3.2E+00
5.00E-01 5.2E+01 1.0E+00 3.2E+00
5.00E-01 5.3E+01 1.0E+00 3.2E+00
2.57E+03 9.7E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.66E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.65E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.80E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10AM EPA Interlab L11 1313-1316CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-849
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be CFS-L11-1313-T01-A
Be CFS-L11-1313-T02-A
Be CFS-L11-1313-T03-A
Be CFS-L11-1313-T04-A
Be CFS-L11-1313-T05-A
Be CFS-L11-1313-T06-A
Be CFS-L11-1313-T07-A
Be CFS-L11-1313-T08-A
Be CFS-L11-1313-T09-A
Be CFS-L11-1313-T01-B
Be CFS-L11-1313-T02-B
Be CFS-L11-1313-T03-B
Be CFS-L11-1313-T04-B
Be CFS-L11-1313-T05-B
Be CFS-L11-1313-T06-B
Be CFS-L11-1313-T07-B
Be CFS-L11-1313-T08-B
Be CFS-L11-1313-T09-B
Be CFS-L11-1313-T01-C
Be CFS-L11-1313-T02-C
Be CFS-L11-1313-T03-C
Be CFS-L11-1313-T04-C
Be CFS-L11-1313-T05-C
Be CFS-L11-1313-T06-C
Be CFS-L11-1313-T07-C
Be CFS-L11-1313-T08-C
Be CFS-L11-1313-T09-C
Be CFS-L11-1313-B01-A
Be CFS-L11-1313-B02-A
Be CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.23E+00 E
1 5.22E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.01E+OOE
1 4.93E+00 E
1 3.39E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 2.00E+00 E
1 4.97E+00 E
1 3.63E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.2E+02 1.9E+00 6.0E+00
9.50E-01 2.5E+01 1.9E+00 6.0E+00 10 100
9.50E-01 3.4E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 4.0E+01 1.9E+00 6.0E+00
9.50E-01 9.0E+01 1.9E+00 6.0E+00
2.23E+00 5.8E+00 1.9E+00 6.0E+00
5.22E+00 4.3E+00 1.9E+00 6.0E+00
9.50E-01 8.7E+00 1.9E+00 6.0E+00
9.50E-01 4.9E+01 1.9E+00 6.0E+00
9.50E-01 3.4E+02 1.9E+00 6.0E+00 10 100
9.50E-01 6.3E+01 1.9E+00 6.0E+00
9.50E-01 9.7E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+03 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
2.01 E+00 2.8E+00 1.9E+00 6.0E+00
4.93E+00 1.3E+00 1.9E+00 6.0E+00
3.39E+00 1.6E+02 1.9E+00 6.0E+00
9.50E-01 6.9E+01 1.9E+00 6.0E+00
9.50E-01 6.8E+01 1.9E+00 6.0E+00 10 100
9.50E-01 5.4E+01 1.9E+00 6.0E+00
9.50E-01 3.3E+03 1.9E+00 6.0E+00
9.50E-01 1.9E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00
2.00E+00 3.7E+00 1.9E+00 6.0E+00
4.97E+00 5.4E+00 1.9E+00 6.0E+00
3.63E+00 1.7E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 4.7E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.17E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.82E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.35E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-850
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutic
Cd CFS-L11-1313-T01-A
Cd CFS-L11-1313-T02-A
Cd CFS-L11-1313-T03-A
Cd CFS-L11-1313-T04-A
Cd CFS-L11-1313-T05-A
Cd CFS-L11-1313-T06-A
Cd CFS-L11-1313-T07-A
Cd CFS-L11-1313-T08-A
Cd CFS-L11-1313-T09-A
Cd CFS-L11-1313-T01-B
Cd CFS-L11-1313-T02-B
Cd CFS-L11-1313-T03-B
Cd CFS-L11-1313-T04-B
Cd CFS-L11-1313-T05-B
Cd CFS-L11-1313-T06-B
Cd CFS-L11-1313-T07-B
Cd CFS-L11-1313-T08-B
Cd CFS-L11-1313-T09-B
Cd CFS-L11-1313-T01-C
Cd CFS-L11-1313-T02-C
Cd CFS-L11-1313-T03-C
Cd CFS-L11-1313-T04-C
Cd CFS-L11-1313-T05-C
Cd CFS-L11-1313-T06-C
Cd CFS-L11-1313-T07-C
Cd CFS-L11-1313-T08-C
Cd CFS-L11-1313-T09-C
Cd CFS-L11-1313-B01-A
Cd CFS-L11-1313-B02-A
Cd CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.47E+00 E
1 1.10E+00 U1/2
1 2.71 E+00 E
1 2.02E+01
1 2.26E+02
1 3.19E+03
1 1.74E+04
1 3.31 E+04
1 3.84E+04
1 3.09E+00 E
1 1.10E+00 U1/2
1 3.26E+00 E
1 1.18E+01
1 2.24E+02
1 2.99E+03
1 1.67E+04
1 3.29E+04
1 3.52E+04
1 3.26E+00 E
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 1.24E+01
1 1.51E+02
1 2.87E+03
1 1.65E+04
1 3.14E+04
1 3.65E+04
1 1.10E+00 U1/2
1 4.28E+00 E
1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.47E+00 5.8E+00 2.2E+00 7.0E+00
1.10E+00 4.4E+01 2.2E+00 7.0E+00 10 100
2.71 E+00 7.0E+00 2.2E+00 7.0E+00
2.02E+01 2.5E+00 2.2E+00 7.0E+00
2.26E+02 4.7E-01 2.2E+00 7.0E+00
3.19E+03 3.4E-01 2.2E+00 7.0E+00
1.74E+04 3.9E-01 2.2E+00 7.0E+00
3.31 E+04 1.2E+00 2.2E+00 7.0E+00
3.84E+04 7.7E-01 2.2E+00 7.0E+00
3.09E+00 4.5E+00 2.2E+00 7.0E+00
1.10E+00 3.7E+01 2.2E+00 7.0E+00 10 100
3.26E+00 9.9E+00 2.2E+00 7.0E+00
1.18E+01 6.1E+00 2.2E+00 7.0E+00
2.24E+02 8.9E-01 2.2E+00 7.0E+00
2.99E+03 4.0E-01 2.2E+00 7.0E+00
1.67E+04 1.1 E+00 2.2E+00 7.0E+00
3.29E+04 4.3E-01 2.2E+00 7.0E+00
3.52E+04 4.9E-01 2.2E+00 7.0E+00
3.26E+00 5.8E+00 2.2E+00 7.0E+00
1.10E+00 9.6E+01 2.2E+00 7.0E+00 10 100
1.10E+00 5.2E-01 2.2E+00 7.0E+00
1.24E+01 1.4E+00 2.2E+00 7.0E+00
1.51E+02 7.5E-01 2.2E+00 7.0E+00
2.87E+03 6.9E-01 2.2E+00 7.0E+00
1.65E+04 3.1E-01 2.2E+00 7.0E+00
3.14E+04 1.0E+00 2.2E+00 7.0E+00
3.65E+04 6.8E-01 2.2E+00 7.0E+00
1.10E+00 8.1E+02 2.2E+00 7.0E+00
4.28E+00 1.7E+00 2.2E+00 7.0E+00
1.10E+00 1.4E+03 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.57E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.36E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.67E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-851
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
CFS-L11-1313-T01-A
CFS-L11-1313-T02-A
CFS-L11-1313-T03-A
CFS-L11-1313-T04-A
CFS-L11-1313-T05-A
CFS-L11-1313-T06-A
CFS-L11-1313-T07-A
CFS-L11-1313-T08-A
CFS-L11-1313-T09-A
CFS-L11-1313-T01-B
CFS-L11-1313-T02-B
CFS-L11-1313-T03-B
CFS-L11-1313-T04-B
CFS-L11-1313-T05-B
CFS-L11-1313-T06-B
CFS-L11-1313-T07-B
CFS-L11-1313-T08-B
CFS-L11-1313-T09-B
CFS-L11-1313-T01-C
CFS-L11-1313-T02-C
CFS-L11-1313-T03-C
CFS-L11-1313-T04-C
CFS-L11-1313-T05-C
CFS-L11-1313-T06-C
CFS-L11-1313-T07-C
CFS-L11-1313-T08-C
CFS-L11-1313-T09-C
CFS-L11-1313-B01-A
CFS-L11-1313-B02-A
CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.37E+05
1 5.65E+05
1 5.82E+05
1 5.87E+05
1 6.01 E+05
1 6.38E+05
1 8.28E+05
1 1.15E+06
1 1.43E+06
1 6. 11 E+05
1 5.60E+05
1 5.49E+05
1 5.90E+05
1 6.10E+05
1 6.30E+05
1 8.13E+05
1 1.10E+06
1 1.36E+06
1 6.27E+05
1 6.00E+05
1 5.73E+05
1 5.87E+05
1 6.09E+05
1 6.33E+05
1 8.29E+05
1 1.11E+06
1 1.42E+06
1 1.03E+01
1 3.38E+02
1 2.15E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.37E+05 7.7E-02 2.6E+00 8.3E+00
5.65E+05 7.2E-01 2.6E+00 8.3E+00 1000 100
5.82E+05 7.9E-01 2.6E+00 8.3E+00
5.87E+05 1.7E-01 2.6E+00 8.3E+00
6.01 E+05 4.4E-01 2.6E+00 8.3E+00
6.38E+05 2.6E-01 2.6E+00 8.3E+00
8.28E+05 4.3E-01 2.6E+00 8.3E+00
1.15E+06 3.5E-01 2.6E+00 8.3E+00
1.43E+06 1.4E+00 2.6E+00 8.3E+00
6.11E+05 8.3E-01 2.6E+00 8.3E+00
5.60E+05 4.5E-01 2.6E+00 8.3E+00 1000 100
5.49E+05 9.6E-01 2.6E+00 8.3E+00
5.90E+05 2.8E+00 2.6E+00 8.3E+00
6.10E+05 4.6E-01 2.6E+00 8.3E+00
6.30E+05 7.2E-01 2.6E+00 8.3E+00
8.13E+05 2.4E-01 2.6E+00 8.3E+00
1.10E+06 4.8E-01 2.6E+00 8.3E+00
1.36E+06 2.7E-01 2.6E+00 8.3E+00
6.27E+05 5.5E-01 2.6E+00 8.3E+00
6.00E+05 7.9E+00 2.6E+00 8.3E+00 1000 100
5.73E+05 1.2E+00 2.6E+00 8.3E+00
5.87E+05 6.9E-01 2.6E+00 8.3E+00
6.09E+05 1.2E+00 2.6E+00 8.3E+00
6.33E+05 5.0E-01 2.6E+00 8.3E+00
8.29E+05 2.8E-01 2.6E+00 8.3E+00
1.11E+06 6.2E-01 2.6E+00 8.3E+00
1.42E+06 5.8E-01 2.6E+00 8.3E+00
1.03E+01 4.3E+01 2.6E+00 8.3E+00
3.38E+02 5.2E+00 2.6E+00 8.3E+00
2.15E+01 3.1E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.66E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.61 E+05 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.01 E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10AM EPA Interlab L11 1313-1316CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-852
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr CFS-L11-1313-T01-A
Cr CFS-L11-1313-T02-A
Cr CFS-L11-1313-T03-A
Cr CFS-L11-1313-T04-A
Cr CFS-L11-1313-T05-A
Cr CFS-L11-1313-T06-A
Cr CFS-L11-1313-T07-A
Cr CFS-L11-1313-T08-A
Cr CFS-L11-1313-T09-A
Cr CFS-L11-1313-T01-B
Cr CFS-L11-1313-T02-B
Cr CFS-L11-1313-T03-B
Cr CFS-L11-1313-T04-B
Cr CFS-L11-1313-T05-B
Cr CFS-L11-1313-T06-B
Cr CFS-L11-1313-T07-B
Cr CFS-L11-1313-T08-B
Cr CFS-L11-1313-T09-B
Cr CFS-L11-1313-T01-C
Cr CFS-L11-1313-T02-C
Cr CFS-L11-1313-T03-C
Cr CFS-L11-1313-T04-C
Cr CFS-L11-1313-T05-C
Cr CFS-L11-1313-T06-C
Cr CFS-L11-1313-T07-C
Cr CFS-L11-1313-T08-C
Cr CFS-L11-1313-T09-C
Cr CFS-L11-1313-B01-A
Cr CFS-L11-1313-B02-A
Cr CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 7.54E+01
1 5.18E+01
1 3.01 E+00 E
1 2.98E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 2.15E+01
1 1.87E+03
1 7.83E+01
1 5.08E+01
1 3.16E+00 E
1 1.23E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 2.06E+01
1 1.31E+03
1 8.19E+01
1 5.16E+01
1 2.48E+00 E
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.20E+00 E
1 2.35E+01
1 1.44E+03
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.94E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.54E+01 6.9E-01 1.2E+00 3.8E+00
5.18E+01 7.8E-01 1.2E+00 3.8E+00 10 100
3.01 E+00 7.2E+00 1.2E+00 3.8E+00
2.98E+00 2.4E+01 1.2E+00 3.8E+00
6.00E-01 3.9E+01 1.2E+00 3.8E+00
6.00E-01 2.2E+02 1.2E+00 3.8E+00
6.00E-01 4.7E+01 1.2E+00 3.8E+00
2.15E+01 3.2E+00 1.2E+00 3.8E+00
1.87E+03 6.5E-01 1.2E+00 3.8E+00
7.83E+01 1.5E+00 1.2E+00 3.8E+00
5.08E+01 5.4E-01 1.2E+00 3.8E+00 10 100
3.16E+00 7.1E+00 1.2E+00 3.8E+00
1.23E+00 3.4E+01 1.2E+00 3.8E+00
6.00E-01 1.1E+02 1.2E+00 3.8E+00
6.00E-01 9.7E+01 1.2E+00 3.8E+00
6.00E-01 3.5E+01 1.2E+00 3.8E+00
2.06E+01 1.6E+00 1.2E+00 3.8E+00
1.31E+03 5.4E-01 1.2E+00 3.8E+00
8.19E+01 4.9E-01 1.2E+00 3.8E+00
5.16E+01 9.3E+00 1.2E+00 3.8E+00 10 100
2.48E+00 1.9E+01 1.2E+00 3.8E+00
6.00E-01 3.3E+01 1.2E+00 3.8E+00
6.00E-01 6.2E+01 1.2E+00 3.8E+00
6.00E-01 3.8E+01 1.2E+00 3.8E+00
1.20E+00 4.4E+01 1.2E+00 3.8E+00
2.35E+01 9.8E-01 1.2E+00 3.8E+00
1.44E+03 1.9E-01 1.2E+00 3.8E+00
6.00E-01 6.7E+02 1.2E+00 3.8E+00
6.00E-01 1.0E+02 1.2E+00 3.8E+00
1.94E+00 2.8E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.89E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.90E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-853
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutic
CFS-L11-1313-T01-A
CFS-L11-1313-T02-A
CFS-L11-1313-T03-A
CFS-L11-1313-T04-A
CFS-L11-1313-T05-A
CFS-L11-1313-T06-A
CFS-L11-1313-T07-A
CFS-L11-1313-T08-A
CFS-L11-1313-T09-A
CFS-L11-1313-T01-B
CFS-L11-1313-T02-B
CFS-L11-1313-T03-B
CFS-L11-1313-T04-B
CFS-L11-1313-T05-B
CFS-L11-1313-T06-B
CFS-L11-1313-T07-B
CFS-L11-1313-T08-B
CFS-L11-1313-T09-B
CFS-L11-1313-T01-C
CFS-L11-1313-T02-C
CFS-L11-1313-T03-C
CFS-L11-1313-T04-C
CFS-L11-1313-T05-C
CFS-L11-1313-T06-C
CFS-L11-1313-T07-C
CFS-L11-1313-T08-C
CFS-L11-1313-T09-C
CFS-L11-1313-B01-A
CFS-L11-1313-B02-A
CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 6.36E+00
1 9.19E+01
1 5.69E+02
1 1.50E+03
1 1.83E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 5.22E+00 E
1 8.58E+01
1 5.35E+02
1 1.43E+03
1 1.65E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 4.45E+00 E
1 8.17E+01
1 5.42E+02
1 1.40E+03
1 1.79E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.2E+01 1.8E+00 5.7E+00
9.00E-01 6.3E+01 1.8E+00 5.7E+00 10 100
9.00E-01 5.2E+01 1.8E+00 5.7E+00
9.00E-01 8.2E+01 1.8E+00 5.7E+00
6.36E+00 4.8E+00 1.8E+00 5.7E+00
9.19E+01 2.1E+00 1.8E+00 5.7E+00
5.69E+02 3.2E-01 1.8E+00 5.7E+00
1.50E+03 3.9E-01 1.8E+00 5.7E+00
1.83E+03 1.1E+00 1.8E+00 5.7E+00
9.00E-01 1.4E+01 1.8E+00 5.7E+00
9.00E-01 4.5E+01 1.8E+00 5.7E+00 10 100
9.00E-01 8.4E+01 1.8E+00 5.7E+00
9.00E-01 2.9E+01 1.8E+00 5.7E+00
5.22E+00 1.3E+01 1.8E+00 5.7E+00
8.58E+01 1.8E+00 1.8E+00 5.7E+00
5.35E+02 3.7E-01 1.8E+00 5.7E+00
1.43E+03 8.1E-01 1.8E+00 5.7E+00
1.65E+03 1.1E+00 1.8E+00 5.7E+00
9.00E-01 9.1E+01 1.8E+00 5.7E+00
9.00E-01 9.4E+01 1.8E+00 5.7E+00 10 100
9.00E-01 1.7E+01 1.8E+00 5.7E+00
9.00E-01 8.4E+01 1.8E+00 5.7E+00
4.45E+00 2.8E+01 1.8E+00 5.7E+00
8.17E+01 9.1E-01 1.8E+00 5.7E+00
5.42E+02 1.5E-01 1.8E+00 5.7E+00
1.40E+03 5.8E-01 1.8E+00 5.7E+00
1.79E+03 9.0E-01 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 8.5E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.83E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-854
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutic
Cu CFS-L11-1313-T01-A
Cu CFS-L11-1313-T02-A
Cu CFS-L11-1313-T03-A
Cu CFS-L11-1313-T04-A
Cu CFS-L11-1313-T05-A
Cu CFS-L11-1313-T06-A
Cu CFS-L11-1313-T07-A
Cu CFS-L11-1313-T08-A
Cu CFS-L11-1313-T09-A
Cu CFS-L11-1313-T01-B
Cu CFS-L11-1313-T02-B
Cu CFS-L11-1313-T03-B
Cu CFS-L11-1313-T04-B
Cu CFS-L11-1313-T05-B
Cu CFS-L11-1313-T06-B
Cu CFS-L11-1313-T07-B
Cu CFS-L11-1313-T08-B
Cu CFS-L11-1313-T09-B
Cu CFS-L11-1313-T01-C
Cu CFS-L11-1313-T02-C
Cu CFS-L11-1313-T03-C
Cu CFS-L11-1313-T04-C
Cu CFS-L11-1313-T05-C
Cu CFS-L11-1313-T06-C
Cu CFS-L11-1313-T07-C
Cu CFS-L11-1313-T08-C
Cu CFS-L11-1313-T09-C
Cu CFS-L11-1313-B01-A
Cu CFS-L11-1313-B02-A
Cu CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.12E+03
1 8.56E+02
1 7.26E+01
1 1.57E+02
1 5.17E+01
1 8.76E+02
1 2.16E+05
1 8.18E+05
1 1.06E+06
1 2.65E+03
1 8.10E+02
1 1.04E+02
1 4.46E+01
1 5.54E+01
1 7.41 E+02
1 2.15E+05
1 7.79E+05
1 9.66E+05
1 2.90E+03
1 8.74E+02
1 6.89E+01
1 4.62E+01
1 6.64E+01
1 7.21 E+02
1 2.18E+05
1 7.78E+05
1 1.05E+06
1 1.43E+01
1 1.52E+02
1 3.76E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.12E+03 6.3E-01 3.7E+00 1.2E+01
8.56E+02 1.6E+00 3.7E+00 1.2E+01 10 100
7.26E+01 9.1E-01 3.7E+00 1.2E+01
1.57E+02 1.6E+00 3.7E+00 1.2E+01
5.17E+01 5.6E+00 3.7E+00 1.2E+01
8.76E+02 5.7E-01 3.7E+00 1.2E+01
2.16E+05 9.2E-01 3.7E+00 1.2E+01
8.18E+05 3.9E-01 3.7E+00 1.2E+01
1.06E+06 3.7E-01 3.7E+00 1.2E+01
2.65E+03 1.4E+00 3.7E+00 1.2E+01
8.10E+02 5.2E-01 3.7E+00 1.2E+01 10 100
1.04E+02 1.7E+00 3.7E+00 1.2E+01
4.46E+01 2.6E+00 3.7E+00 1.2E+01
5.54E+01 9.9E-01 3.7E+00 1.2E+01
7.41 E+02 1.3E+00 3.7E+00 1.2E+01
2.15E+05 4.6E-01 3.7E+00 1.2E+01
7.79E+05 2.4E-01 3.7E+00 1.2E+01
9.66E+05 3.1E-01 3.7E+00 1.2E+01
2.90E+03 4.9E-01 3.7E+00 1.2E+01
8.74E+02 6.6E+00 3.7E+00 1.2E+01 10 100
6.89E+01 1.4E+00 3.7E+00 1.2E+01
4.62E+01 2.5E+00 3.7E+00 1.2E+01
6.64E+01 3.3E+00 3.7E+00 1.2E+01
7.21 E+02 6.9E-01 3.7E+00 1.2E+01
2.18E+05 1.3E-01 3.7E+00 1.2E+01
7.78E+05 5.9E-01 3.7E+00 1.2E+01
1.05E+06 1.8E+00 3.7E+00 1.2E+01
1.43E+01 3.0E+00 3.7E+00 1.2E+01
1.52E+02 4.1E+00 3.7E+00 1.2E+01
3.76E+01 3.1E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.82E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.69E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.82E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-855
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutic
Fe CFS-L11-1313-T01-A
Fe CFS-L11-1313-T02-A
Fe CFS-L11-1313-T03-A
Fe CFS-L11-1313-T04-A
Fe CFS-L11-1313-T05-A
Fe CFS-L11-1313-T06-A
Fe CFS-L11-1313-T07-A
Fe CFS-L11-1313-T08-A
Fe CFS-L11-1313-T09-A
Fe CFS-L11-1313-T01-B
Fe CFS-L11-1313-T02-B
Fe CFS-L11-1313-T03-B
Fe CFS-L11-1313-T04-B
Fe CFS-L11-1313-T05-B
Fe CFS-L11-1313-T06-B
Fe CFS-L11-1313-T07-B
Fe CFS-L11-1313-T08-B
Fe CFS-L11-1313-T09-B
Fe CFS-L11-1313-T01-C
Fe CFS-L11-1313-T02-C
Fe CFS-L11-1313-T03-C
Fe CFS-L11-1313-T04-C
Fe CFS-L11-1313-T05-C
Fe CFS-L11-1313-T06-C
Fe CFS-L11-1313-T07-C
Fe CFS-L11-1313-T08-C
Fe CFS-L11-1313-T09-C
Fe CFS-L11-1313-B01-A
Fe CFS-L11-1313-B02-A
Fe CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 4.94E+03
1 1.81E+05
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 4.64E+03
1 1.79E+05
1 1.19E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 4.84E+00 E
1 7.51 E+03
1 1.71E+05
1 1.00E+OOU1/2
1 3.25E+00 E
1 2.00E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.9E+01 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 4.2E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
4.94E+03 1.1E+00 2.0E+00 6.4E+00
1.81E+05 5.8E-01 2.0E+00 6.4E+00
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 5.5E+00 2.0E+00 6.4E+00
1.00E+00 6.0E+00 2.0E+00 6.4E+00
1.00E+00 7.6E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
4.64E+03 6.7E-01 2.0E+00 6.4E+00
1.79E+05 2.5E+00 2.0E+00 6.4E+00
1.19E+01 1.2E+00 2.0E+00 6.4E+00
1.00E+00 4.1E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 7.2E-01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+00 2.0E+00 6.4E+00
1.00E+00 8.3E+00 2.0E+00 6.4E+00
4.84E+00 2.4E+00 2.0E+00 6.4E+00
7.51 E+03 8.7E-01 2.0E+00 6.4E+00
1.71E+05 1.1E+00 2.0E+00 6.4E+00
1.00E+00 7.7E+00 2.0E+00 6.4E+00
3.25E+00 1.8E+01 2.0E+00 6.4E+00
2.00E+01 9.6E-01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.88E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.41 E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-856
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutic
Pb CFS-L11-1313-T01-A
Pb CFS-L11-1313-T02-A
Pb CFS-L11-1313-T03-A
Pb CFS-L11-1313-T04-A
Pb CFS-L11-1313-T05-A
Pb CFS-L11-1313-T06-A
Pb CFS-L11-1313-T07-A
Pb CFS-L11-1313-T08-A
Pb CFS-L11-1313-T09-A
Pb CFS-L11-1313-T01-B
Pb CFS-L11-1313-T02-B
Pb CFS-L11-1313-T03-B
Pb CFS-L11-1313-T04-B
Pb CFS-L11-1313-T05-B
Pb CFS-L11-1313-T06-B
Pb CFS-L11-1313-T07-B
Pb CFS-L11-1313-T08-B
Pb CFS-L11-1313-T09-B
Pb CFS-L11-1313-T01-C
Pb CFS-L11-1313-T02-C
Pb CFS-L11-1313-T03-C
Pb CFS-L11-1313-T04-C
Pb CFS-L11-1313-T05-C
Pb CFS-L11-1313-T06-C
Pb CFS-L11-1313-T07-C
Pb CFS-L11-1313-T08-C
Pb CFS-L11-1313-T09-C
Pb CFS-L11-1313-B01-A
Pb CFS-L11-1313-B02-A
Pb CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.10E+03
1 5.43E+03
1 1.23E+02
1 7.63E+01
1 1.56E+02
1 8.58E+02
1 5.15E+03
1 5.07E+03
1 7.93E+03
1 4.89E+03
1 6.30E+03
1 1.08E+02
1 7.24E+01
1 1.79E+02
1 7.48E+02
1 5.73E+03
1 4.38E+03
1 7.23E+03
1 5.44E+03
1 8.27E+03
1 1.21E+02
1 7.15E+01
1 1.08E+02
1 8.87E+02
1 6.19E+03
1 4.94E+03
1 7.51 E+03
1 3.40E+00 U1/2
1 7.44E+02
1 3.28E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.10E+03 1.7E+00 6.8E+00 2.2E+01
5.43E+03 7.4E-01 6.8E+00 2.2E+01 10 100
1.23E+02 1.2E+00 6.8E+00 2.2E+01
7.63E+01 2.0E+00 6.8E+00 2.2E+01
1.56E+02 6.9E-01 6.8E+00 2.2E+01
8.58E+02 1.9E-01 6.8E+00 2.2E+01
5.15E+03 1.4E+00 6.8E+00 2.2E+01
5.07E+03 6.0E-01 6.8E+00 2.2E+01
7.93E+03 6.3E-01 6.8E+00 2.2E+01
4.89E+03 8.4E-01 6.8E+00 2.2E+01
6.30E+03 1.0E+00 6.8E+00 2.2E+01 10 100
1.08E+02 1.2E+00 6.8E+00 2.2E+01
7.24E+01 5.5E+00 6.8E+00 2.2E+01
1.79E+02 1.2E+00 6.8E+00 2.2E+01
7.48E+02 4.3E-01 6.8E+00 2.2E+01
5.73E+03 4.2E-01 6.8E+00 2.2E+01
4.38E+03 6.0E-01 6.8E+00 2.2E+01
7.23E+03 3.2E-01 6.8E+00 2.2E+01
5.44E+03 1.1E+00 6.8E+00 2.2E+01
8.27E+03 6.7E+00 6.8E+00 2.2E+01 10 100
1.21E+02 1.6E+00 6.8E+00 2.2E+01
7.15E+01 3.1E+00 6.8E+00 2.2E+01
1.08E+02 2.6E+00 6.8E+00 2.2E+01
8.87E+02 9.7E-01 6.8E+00 2.2E+01
6.19E+03 6.0E-01 6.8E+00 2.2E+01
4.94E+03 6.4E-01 6.8E+00 2.2E+01
7.51 E+03 2.0E-01 6.8E+00 2.2E+01
3.40E+00 4.0E+02 6.8E+00 2.2E+01
7.44E+02 2.5E+00 6.8E+00 2.2E+01
3.28E+01 3.3E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
6.45E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.25E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.25E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-857
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutic
Li CFS-L11-1313-T01-A
Li CFS-L11-1313-T02-A
Li CFS-L11-1313-T03-A
Li CFS-L11-1313-T04-A
Li CFS-L11-1313-T05-A
Li CFS-L11-1313-T06-A
Li CFS-L11-1313-T07-A
Li CFS-L11-1313-T08-A
Li CFS-L11-1313-T09-A
Li CFS-L11-1313-T01-B
Li CFS-L11-1313-T02-B
Li CFS-L11-1313-T03-B
Li CFS-L11-1313-T04-B
Li CFS-L11-1313-T05-B
Li CFS-L11-1313-T06-B
Li CFS-L11-1313-T07-B
Li CFS-L11-1313-T08-B
Li CFS-L11-1313-T09-B
Li CFS-L11-1313-T01-C
Li CFS-L11-1313-T02-C
Li CFS-L11-1313-T03-C
Li CFS-L11-1313-T04-C
Li CFS-L11-1313-T05-C
Li CFS-L11-1313-T06-C
Li CFS-L11-1313-T07-C
Li CFS-L11-1313-T08-C
Li CFS-L11-1313-T09-C
Li CFS-L11-1313-B01-A
Li CFS-L11-1313-B02-A
Li CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.03E+01
1 1.94E+01
1 1.94E+01
1 1.96E+01
1 1.99E+01
1 1.77E+01
1 1.76E+01
1 2.11E+01
1 2.83E+01
1 2.30E+01
1 2.18E+01
1 2.13E+01
1 2.11E+01
1 2.01E+01
1 1.94E+01
1 1.91E+01
1 2.08E+01
1 3.04E+01
1 2.21E+01
1 2.25E+01
1 2.02E+01
1 2.05E+01
1 2.01E+01
1 1.80E+01
1 1.95E+01
1 2.20E+01
1 2.98E+01
1 6.06E+00
1 7.87E+00
1 6.89E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.03E+01 3.9E+00 1.9E+00 6.0E+00
1.94E+01 3.2E+00 1.9E+00 6.0E+00 10 100
1.94E+01 3.1E+00 1.9E+00 6.0E+00
1.96E+01 4.0E+00 1.9E+00 6.0E+00
1.99E+01 6.5E+00 1.9E+00 6.0E+00
1.77E+01 1.8E+00 1.9E+00 6.0E+00
1.76E+01 1.7E+01 1.9E+00 6.0E+00
2.11E+01 4.4E+00 1.9E+00 6.0E+00
2.83E+01 1.3E+01 1.9E+00 6.0E+00
2.30E+01 3.1E+00 1.9E+00 6.0E+00
2.18E+01 1.6E+00 1.9E+00 6.0E+00 10 100
2.13E+01 3.9E+00 1.9E+00 6.0E+00
2.11E+01 2.7E+00 1.9E+00 6.0E+00
2.01 E+01 1.9E+00 1.9E+00 6.0E+00
1.94E+01 1.0E+01 1.9E+00 6.0E+00
1.91 E+01 1.4E+00 1.9E+00 6.0E+00
2.08E+01 7.5E+00 1.9E+00 6.0E+00
3.04E+01 1.1E+01 1.9E+00 6.0E+00
2.21 E+01 8.3E-01 1.9E+00 6.0E+00
2.25E+01 4.1E+00 1.9E+00 6.0E+00 10 100
2.02E+01 5.2E+00 1.9E+00 6.0E+00
2.05E+01 3.1E+00 1.9E+00 6.0E+00
2.01 E+01 7.0E-01 1.9E+00 6.0E+00
1.80E+01 6.8E+00 1.9E+00 6.0E+00
1.95E+01 7.2E+00 1.9E+00 6.0E+00
2.20E+01 9.2E+00 1.9E+00 6.0E+00
2.98E+01 2.2E+01 1.9E+00 6.0E+00
6.06E+00 1.1E+01 1.9E+00 6.0E+00
7.87E+00 5.8E+00 1.9E+00 6.0E+00
6.89E+00 2.1E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.80E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.52E+02 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.74E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-858
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutic
Mn CFS-L11-1313-T01-A
Mn CFS-L11-1313-T02-A
Mn CFS-L11-1313-T03-A
Mn CFS-L11-1313-T04-A
Mn CFS-L11-1313-T05-A
Mn CFS-L11-1313-T06-A
Mn CFS-L11-1313-T07-A
Mn CFS-L11-1313-T08-A
Mn CFS-L11-1313-T09-A
Mn CFS-L11-1313-T01-B
Mn CFS-L11-1313-T02-B
Mn CFS-L11-1313-T03-B
Mn CFS-L11-1313-T04-B
Mn CFS-L11-1313-T05-B
Mn CFS-L11-1313-T06-B
Mn CFS-L11-1313-T07-B
Mn CFS-L11-1313-T08-B
Mn CFS-L11-1313-T09-B
Mn CFS-L11-1313-T01-C
Mn CFS-L11-1313-T02-C
Mn CFS-L11-1313-T03-C
Mn CFS-L11-1313-T04-C
Mn CFS-L11-1313-T05-C
Mn CFS-L11-1313-T06-C
Mn CFS-L11-1313-T07-C
Mn CFS-L11-1313-T08-C
Mn CFS-L11-1313-T09-C
Mn CFS-L11-1313-B01-A
Mn CFS-L11-1313-B02-A
Mn CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.75E+00 E
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.82E+00 E
1 1.32E+02
1 1.31E+03
1 4.78E+03
1 1.51E+04
1 2.63E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.23E+02
1 1.21E+03
1 4.49E+03
1 1.43E+04
1 2.47E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 7.81E+01
1 1.15E+03
1 4.54E+03
1 1.42E+04
1 2.59E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.75E+00 1.1E+00 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00 10 100
1.00E+00 6.0E+00 2.0E+00 6.4E+00
3.82E+00 1.1E+00 2.0E+00 6.4E+00
1.32E+02 1.0E+00 2.0E+00 6.4E+00
1.31E+03 2.1E+00 2.0E+00 6.4E+00
4.78E+03 3.1E-01 2.0E+00 6.4E+00
1.51E+04 7.3E-01 2.0E+00 6.4E+00
2.63E+04 1.0E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00 10 100
1.00E+00 5.6E+00 2.0E+00 6.4E+00
1.00E+00 5.7E+00 2.0E+00 6.4E+00
1.23E+02 4.0E-01 2.0E+00 6.4E+00
1.21E+03 9.2E-01 2.0E+00 6.4E+00
4.49E+03 8.2E-01 2.0E+00 6.4E+00
1.43E+04 2.1E-01 2.0E+00 6.4E+00
2.47E+04 4.0E-01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00 10 100
1.00E+00 3.5E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+00 2.0E+00 6.4E+00
7.81 E+01 5.5E-01 2.0E+00 6.4E+00
1.15E+03 7.8E-01 2.0E+00 6.4E+00
4.54E+03 8.1E-01 2.0E+00 6.4E+00
1.42E+04 3.8E-01 2.0E+00 6.4E+00
2.59E+04 1.7E+00 2.0E+00 6.4E+00
1.00E+00 6.5E+00 2.0E+00 6.4E+00
1.00E+00 7.1E+00 2.0E+00 6.4E+00
1.00E+00 1.9E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.93E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.60E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.51 E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-859
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutic
Mg CFS-L11-1313-T01-A
Mg CFS-L11-1313-T02-A
Mg CFS-L11-1313-T03-A
Mg CFS-L11-1313-T04-A
Mg CFS-L11-1313-T05-A
Mg CFS-L11-1313-T06-A
Mg CFS-L11-1313-T07-A
Mg CFS-L11-1313-T08-A
Mg CFS-L11-1313-T09-A
Mg CFS-L11-1313-T01-B
Mg CFS-L11-1313-T02-B
Mg CFS-L11-1313-T03-B
Mg CFS-L11-1313-T04-B
Mg CFS-L11-1313-T05-B
Mg CFS-L11-1313-T06-B
Mg CFS-L11-1313-T07-B
Mg CFS-L11-1313-T08-B
Mg CFS-L11-1313-T09-B
Mg CFS-L11-1313-T01-C
Mg CFS-L11-1313-T02-C
Mg CFS-L11-1313-T03-C
Mg CFS-L11-1313-T04-C
Mg CFS-L11-1313-T05-C
Mg CFS-L11-1313-T06-C
Mg CFS-L11-1313-T07-C
Mg CFS-L11-1313-T08-C
Mg CFS-L11-1313-T09-C
Mg CFS-L11-1313-B01-A
Mg CFS-L11-1313-B02-A
Mg CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.10E+02
1 4.87E+01
1 1.27E+04
1 3.74E+04
1 6.88E+04
1 6.84E+04
1 7.66E+04
1 1.03E+05
1 2.16E+05
1 3.25E+01
1 4.27E+01
1 1.13E+04
1 3.84E+04
1 6.07E+04
1 6.64E+04
1 7.12E+04
1 9.89E+04
1 1.88E+05
1 4.74E+01
1 4.04E+01
1 1.10E+04
1 3.99E+04
1 6.48E+04
1 6.45E+04
1 7.14E+04
1 9.31 E+04
1 2.26E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 6.43E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+02 7.3E+00 1.0E+00 3.2E+00
4.87E+01 6.6E+00 1.0E+00 3.2E+00 1000 100
1.27E+04 7.9E-01 1.0E+00 3.2E+00
3.74E+04 4.5E-01 1.0E+00 3.2E+00
6.88E+04 1.4E+00 1.0E+00 3.2E+00
6.84E+04 5.8E-01 1.0E+00 3.2E+00
7.66E+04 1.0E+00 1.0E+00 3.2E+00
1.03E+05 3.0E-01 1.0E+00 3.2E+00
2.16E+05 4.6E-01 1.0E+00 3.2E+00
3.25E+01 7.9E+00 1.0E+00 3.2E+00
4.27E+01 2.6E+01 1.0E+00 3.2E+00 1000 100
1.13E+04 9.5E-01 1.0E+00 3.2E+00
3.84E+04 2.2E+00 1.0E+00 3.2E+00
6.07E+04 9.1E-01 1.0E+00 3.2E+00
6.64E+04 7.2E-01 1.0E+00 3.2E+00
7.12E+04 5.1E-01 1.0E+00 3.2E+00
9.89E+04 5.9E-01 1.0E+00 3.2E+00
1.88E+05 4.3E-01 1.0E+00 3.2E+00
4.74E+01 1.4E+01 1.0E+00 3.2E+00
4.04E+01 1.6E+01 1.0E+00 3.2E+00 1000 100
1.10E+04 1.1E+00 1.0E+00 3.2E+00
3.99E+04 1.1E+00 1.0E+00 3.2E+00
6.48E+04 9.1E-01 1.0E+00 3.2E+00
6.45E+04 1.4E+00 1.0E+00 3.2E+00
7.14E+04 1.2E+00 1.0E+00 3.2E+00
9.31 E+04 1.1E+00 1.0E+00 3.2E+00
2.26E+05 6.7E-01 1.0E+00 3.2E+00
5.00E-01 2.4E+03 1.0E+00 3.2E+00
5.00E-01 9.3E+02 1.0E+00 3.2E+00
6.43E+00 4.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.04E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-860
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutic
Mo CFS-L11-1313-T01-A
Mo CFS-L11-1313-T02-A
Mo CFS-L11-1313-T03-A
Mo CFS-L11-1313-T04-A
Mo CFS-L11-1313-T05-A
Mo CFS-L11-1313-T06-A
Mo CFS-L11-1313-T07-A
Mo CFS-L11-1313-T08-A
Mo CFS-L11-1313-T09-A
Mo CFS-L11-1313-T01-B
Mo CFS-L11-1313-T02-B
Mo CFS-L11-1313-T03-B
Mo CFS-L11-1313-T04-B
Mo CFS-L11-1313-T05-B
Mo CFS-L11-1313-T06-B
Mo CFS-L11-1313-T07-B
Mo CFS-L11-1313-T08-B
Mo CFS-L11-1313-T09-B
Mo CFS-L11-1313-T01-C
Mo CFS-L11-1313-T02-C
Mo CFS-L11-1313-T03-C
Mo CFS-L11-1313-T04-C
Mo CFS-L11-1313-T05-C
Mo CFS-L11-1313-T06-C
Mo CFS-L11-1313-T07-C
Mo CFS-L11-1313-T08-C
Mo CFS-L11-1313-T09-C
Mo CFS-L11-1313-B01-A
Mo CFS-L11-1313-B02-A
Mo CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.52E+03
1 1.37E+03
1 6.99E+02
1 3.20E+02
1 5.08E+01
1 1.00E+01
1 7.05E+00
1 1.13E+01
1 6.74E+01
1 1.40E+03
1 1.30E+03
1 6.85E+02
1 3.18E+02
1 5.68E+01
1 1.08E+01
1 4.79E+00
1 1.91E+01
1 5.09E+01
1 1.51E+03
1 1.39E+03
1 6.99E+02
1 3.15E+02
1 6.75E+01
1 1.08E+01
1 6.73E+00
1 9.06E+00
1 7.19E+01
1 1.29E+00 E
1 1.57E+00 E
1 5.82E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.52E+03 4.4E-01 1.2E+00 3.8E+00
1.37E+03 1.2E+00 1.2E+00 3.8E+00 10 100
6.99E+02 6.7E-01 1.2E+00 3.8E+00
3.20E+02 8.7E-01 1.2E+00 3.8E+00
5.08E+01 2.4E+00 1.2E+00 3.8E+00
1.00E+01 9.1E+00 1.2E+00 3.8E+00
7.05E+00 4.3E+01 1.2E+00 3.8E+00
1.13E+01 7.0E+01 1.2E+00 3.8E+00
6.74E+01 2.6E+01 1.2E+00 3.8E+00
1.40E+03 4.2E-01 1.2E+00 3.8E+00
1.30E+03 2.3E-01 1.2E+00 3.8E+00 10 100
6.85E+02 8.5E-01 1.2E+00 3.8E+00
3.18E+02 3.8E+00 1.2E+00 3.8E+00
5.68E+01 8.4E-01 1.2E+00 3.8E+00
1.08E+01 5.9E+00 1.2E+00 3.8E+00
4.79E+00 9.5E+00 1.2E+00 3.8E+00
1.91E+01 7.7E+01 1.2E+00 3.8E+00
5.09E+01 5.3E+00 1.2E+00 3.8E+00
1.51E+03 1.7E-01 1.2E+00 3.8E+00
1.39E+03 9.4E+00 1.2E+00 3.8E+00 10 100
6.99E+02 7.7E-01 1.2E+00 3.8E+00
3.15E+02 1.1E+00 1.2E+00 3.8E+00
6.75E+01 2.0E+00 1.2E+00 3.8E+00
1.08E+01 1.2E+01 1.2E+00 3.8E+00
6.73E+00 1.3E+01 1.2E+00 3.8E+00
9.06E+00 4.9E+01 1.2E+00 3.8E+00
7.19E+01 9.3E+00 1.2E+00 3.8E+00
1.29E+00 6.3E+01 1.2E+00 3.8E+00
1.57E+00 5.2E+01 1.2E+00 3.8E+00
5.82E+00 2.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.26E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.16E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.26E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-861
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutic
Ni CFS-L11-1313-T01-A
Ni CFS-L11-1313-T02-A
Ni CFS-L11-1313-T03-A
Ni CFS-L11-1313-T04-A
Ni CFS-L11-1313-T05-A
Ni CFS-L11-1313-T06-A
Ni CFS-L11-1313-T07-A
Ni CFS-L11-1313-T08-A
Ni CFS-L11-1313-T09-A
Ni CFS-L11-1313-T01-B
Ni CFS-L11-1313-T02-B
Ni CFS-L11-1313-T03-B
Ni CFS-L11-1313-T04-B
Ni CFS-L11-1313-T05-B
Ni CFS-L11-1313-T06-B
Ni CFS-L11-1313-T07-B
Ni CFS-L11-1313-T08-B
Ni CFS-L11-1313-T09-B
Ni CFS-L11-1313-T01-C
Ni CFS-L11-1313-T02-C
Ni CFS-L11-1313-T03-C
Ni CFS-L11-1313-T04-C
Ni CFS-L11-1313-T05-C
Ni CFS-L11-1313-T06-C
Ni CFS-L11-1313-T07-C
Ni CFS-L11-1313-T08-C
Ni CFS-L11-1313-T09-C
Ni CFS-L11-1313-B01-A
Ni CFS-L11-1313-B02-A
Ni CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 7.68E+00
1 1.64E+02
1 1.78E+03
1 4.78E+03
1 5.80E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 7.71 E+00
1 1.48E+02
1 1.69E+03
1 4.59E+03
1 5.22E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 2.09E+00 E
1 5.32E+00 E
1 1.43E+02
1 1.70E+03
1 4.54E+03
1 5.54E+03
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.5E+02 1.8E+00 5.7E+00
9.00E-01 3.6E+02 1.8E+00 5.7E+00 10 100
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
7.68E+00 1.7E+01 1.8E+00 5.7E+00
1.64E+02 1.4E+00 1.8E+00 5.7E+00
1.78E+03 6.7E-01 1.8E+00 5.7E+00
4.78E+03 4.3E-01 1.8E+00 5.7E+00
5.80E+03 3.3E-01 1.8E+00 5.7E+00
9.00E-01 2.8E+02 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00 10 100
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 2.5E+04 1.8E+00 5.7E+00
7.71 E+00 1.1E+01 1.8E+00 5.7E+00
1.48E+02 1.6E+00 1.8E+00 5.7E+00
1.69E+03 2.5E-01 1.8E+00 5.7E+00
4.59E+03 1.7E+00 1.8E+00 5.7E+00
5.22E+03 5.4E-01 1.8E+00 5.7E+00
9.00E-01 5.0E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00 10 100
9.00E-01 7.5E+02 1.8E+00 5.7E+00
2.09E+00 2.7E+01 1.8E+00 5.7E+00
5.32E+00 4.6E+00 1.8E+00 5.7E+00
1.43E+02 8.3E-01 1.8E+00 5.7E+00
1.70E+03 7.4E-01 1.8E+00 5.7E+00
4.54E+03 1.2E+00 1.8E+00 5.7E+00
5.54E+03 4.5E-01 1.8E+00 5.7E+00
9.00E-01 5.9E+02 1.8E+00 5.7E+00
9.00E-01 3.1E+02 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.60E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.75E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.75E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-862
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutic
P CFS-L11-1313-T01-A
P CFS-L11-1313-T02-A
P CFS-L11-1313-T03-A
P CFS-L11-1313-T04-A
P CFS-L11-1313-T05-A
P CFS-L11-1313-T06-A
P CFS-L11-1313-T07-A
P CFS-L11-1313-T08-A
P CFS-L11-1313-T09-A
P CFS-L11-1313-T01-B
P CFS-L11-1313-T02-B
P CFS-L11-1313-T03-B
P CFS-L11-1313-T04-B
P CFS-L11-1313-T05-B
P CFS-L11-1313-T06-B
P CFS-L11-1313-T07-B
P CFS-L11-1313-T08-B
P CFS-L11-1313-T09-B
P CFS-L11-1313-T01-C
P CFS-L11-1313-T02-C
P CFS-L11-1313-T03-C
P CFS-L11-1313-T04-C
P CFS-L11-1313-T05-C
P CFS-L11-1313-T06-C
P CFS-L11-1313-T07-C
P CFS-L11-1313-T08-C
P CFS-L11-1313-T09-C
P CFS-L11-1313-B01-A
P CFS-L11-1313-B02-A
P CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.15E+01
1 8.33E+01
1 4.41 E+01
1 2.95E+01
1 2.25E+01
1 2.71 E+01
1 4.29E+01
1 4.40E+01
1 1.27E+03
1 8.29E+01
1 6.45E+01
1 4.09E+01
1 3.98E+01
1 3.50E+01
1 2.69E+01
1 2.88E+01
1 4.71 E+01
1 9.50E+02
1 7.02E+01
1 7.91 E+01
1 5.27E+01
1 2.96E+01
1 3.64E+01
1 1.73E+01
1 3.57E+01
1 3.31 E+01
1 1.04E+03
1 2.52E+01
1 3.84E+01
1 3.78E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.15E+01 1.3E+01 3.7E+00 1.2E+01
8.33E+01 9.1E+00 3.7E+00 1.2E+01 1000 100
4.41 E+01 1.1 E+01 3.7E+00 1.2E+01
2.95E+01 2.4E+01 3.7E+00 1.2E+01
2.25E+01 4.6E+01 3.7E+00 1.2E+01
2.71E+01 2.5E+01 3.7E+00 1.2E+01
4.29E+01 1.5E+01 3.7E+00 1.2E+01
4.40E+01 4.5E+01 3.7E+00 1.2E+01
1.27E+03 5.1E-01 3.7E+00 1.2E+01
8.29E+01 6.3E+00 3.7E+00 1.2E+01
6.45E+01 1.2E+01 3.7E+00 1.2E+01 1000 100
4.09E+01 1.1 E+01 3.7E+00 1.2E+01
3.98E+01 2.4E+01 3.7E+00 1.2E+01
3.50E+01 2.3E+01 3.7E+00 1.2E+01
2.69E+01 3.0E+01 3.7E+00 1.2E+01
2.88E+01 6.6E+01 3.7E+00 1.2E+01
4.71E+01 2.3E+01 3.7E+00 1.2E+01
9.50E+02 1.6E+00 3.7E+00 1.2E+01
7.02E+01 1.4E+01 3.7E+00 1.2E+01
7.91E+01 4.8E+00 3.7E+00 1.2E+01 1000 100
5.27E+01 1.8E+01 3.7E+00 1.2E+01
2.96E+01 3.3E+01 3.7E+00 1.2E+01
3.64E+01 1.6E+01 3.7E+00 1.2E+01
1.73E+01 1.1 E+01 3.7E+00 1.2E+01
3.57E+01 1.5E+01 3.7E+00 1.2E+01
3.31 E+01 6.0E+01 3.7E+00 1.2E+01
1.04E+03 1.4E+00 3.7E+00 1.2E+01
2.52E+01 3.6E+00 3.7E+00 1.2E+01
3.84E+01 1.1 E+01 3.7E+00 1.2E+01
3.78E+01 2.5E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.70E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.78E+02 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.65E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-863
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L11-1313-T01-A
CFS-L11-1313-T02-A
CFS-L11-1313-T03-A
CFS-L11-1313-T04-A
CFS-L11-1313-T05-A
CFS-L11-1313-T06-A
CFS-L11-1313-T07-A
CFS-L11-1313-T08-A
CFS-L11-1313-T09-A
CFS-L11-1313-T01-B
CFS-L11-1313-T02-B
CFS-L11-1313-T03-B
CFS-L11-1313-T04-B
CFS-L11-1313-T05-B
CFS-L11-1313-T06-B
CFS-L11-1313-T07-B
CFS-L11-1313-T08-B
CFS-L11-1313-T09-B
CFS-L11-1313-T01-C
CFS-L11-1313-T02-C
CFS-L11-1313-T03-C
CFS-L11-1313-T04-C
CFS-L11-1313-T05-C
CFS-L11-1313-T06-C
CFS-L11-1313-T07-C
CFS-L11-1313-T08-C
CFS-L11-1313-T09-C
CFS-L11-1313-B01-A
CFS-L11-1313-B02-A
CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.44E+04
1 1.81E+04
1 1.36E+04
1 1.18E+04
1 1.14E+04
1 9.75E+03
1 1.24E+04
1 1.54E+04
1 2.24E+04
1 2.15E+04
1 1.66E+04
1 1.17E+04
1 1.16E+04
1 1.08E+04
1 9.24E+03
1 1.16E+04
1 1.46E+04
1 2.16E+04
1 2.20E+04
1 1.82E+04
1 1.22E+04
1 1.18E+04
1 1.08E+04
1 9.46E+03
1 1.18E+04
1 1.42E+04
1 2.25E+04
1 6.44E+01
1 9.66E+01
1 1.78E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.44E+04 2.4E-01 1.6E+00 5.1E+00
1.81E+04 9.2E-01 1.6E+00 5.1E+00 1000 100
1.36E+04 4.8E-01 1.6E+00 5.1E+00
1.18E+04 3.9E-01 1.6E+00 5.1E+00
1.14E+04 3.1E-01 1.6E+00 5.1E+00
9.75E+03 2.0E-01 1.6E+00 5.1E+00
1.24E+04 3.8E-01 1.6E+00 5.1E+00
1.54E+04 2.0E-01 1.6E+00 5.1E+00
2.24E+04 7.3E-01 1.6E+00 5.1E+00
2.15E+04 1.1E+00 1.6E+00 5.1E+00
1.66E+04 3.5E-01 1.6E+00 5.1E+00 1000 100
1.17E+04 1.0E+00 1.6E+00 5.1E+00
1.16E+04 2.7E+00 1.6E+00 5.1E+00
1.08E+04 5.1E-01 1.6E+00 5.1E+00
9.24E+03 1.2E-01 1.6E+00 5.1E+00
1.16E+04 7.8E-01 1.6E+00 5.1E+00
1.46E+04 1.3E-01 1.6E+00 5.1E+00
2.16E+04 4.3E-01 1.6E+00 5.1E+00
2.20E+04 5.3E-01 1.6E+00 5.1E+00
1.82E+04 8.2E+00 1.6E+00 5.1E+00 1000 100
1.22E+04 1.0E+00 1.6E+00 5.1E+00
1.18E+04 1.2E+00 1.6E+00 5.1E+00
1.08E+04 9.1E-01 1.6E+00 5.1E+00
9.46E+03 2.3E-01 1.6E+00 5.1E+00
1.18E+04 7.5E-01 1.6E+00 5.1E+00
1.42E+04 1.7E-01 1.6E+00 5.1E+00
2.25E+04 3.4E-01 1.6E+00 5.1E+00
6.44E+01 2.3E+00 1.6E+00 5.1E+00
9.66E+01 4.5E+00 1.6E+00 5.1E+00
1.78E+03 1.2E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.90E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.76E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.91E+04 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-864
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-L11-1313-T01-A
CFS-L11-1313-T02-A
CFS-L11-1313-T03-A
CFS-L11-1313-T04-A
CFS-L11-1313-T05-A
CFS-L11-1313-T06-A
CFS-L11-1313-T07-A
CFS-L11-1313-T08-A
CFS-L11-1313-T09-A
CFS-L11-1313-T01-B
CFS-L11-1313-T02-B
CFS-L11-1313-T03-B
CFS-L11-1313-T04-B
CFS-L11-1313-T05-B
CFS-L11-1313-T06-B
CFS-L11-1313-T07-B
CFS-L11-1313-T08-B
CFS-L11-1313-T09-B
CFS-L11-1313-T01-C
CFS-L11-1313-T02-C
CFS-L11-1313-T03-C
CFS-L11-1313-T04-C
CFS-L11-1313-T05-C
CFS-L11-1313-T06-C
CFS-L11-1313-T07-C
CFS-L11-1313-T08-C
CFS-L11-1313-T09-C
CFS-L11-1313-B01-A
CFS-L11-1313-B02-A
CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.48E+02
1 5.98E+02
1 2.28E+02
1 1.24E+02
1 8.12E+01
1 7.00E+01
1 1.30E+02
1 2.05E+02
1 3.17E+02
1 5.44E+02
1 6.03E+02
1 2.15E+02
1 1.26E+02
1 8.40E+01
1 7.79E+01
1 9.56E+01
1 1.87E+02
1 3.06E+02
1 5.27E+02
1 6.23E+02
1 2.24E+02
1 1.30E+02
1 7.43E+01
1 6.44E+01
1 1.12E+02
1 1.99E+02
1 3.02E+02
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.48E+02 2.4E+00 1.5E+01 4.8E+01
5.98E+02 2.7E+00 1.5E+01 4.8E+01 10 100
2.28E+02 2.8E+00 1.5E+01 4.8E+01
1.24E+02 1.0E+01 1.5E+01 4.8E+01
8.12E+01 1.9E+00 1.5E+01 4.8E+01
7.00E+01 1.0E+01 1.5E+01 4.8E+01
1.30E+02 7.3E+00 1.5E+01 4.8E+01
2.05E+02 2.0E+00 1.5E+01 4.8E+01
3.17E+02 2.9E+00 1.5E+01 4.8E+01
5.44E+02 5.6E+00 1.5E+01 4.8E+01
6.03E+02 1.1E+00 1.5E+01 4.8E+01 10 100
2.15E+02 6.3E+00 1.5E+01 4.8E+01
1.26E+02 1.2E+01 1.5E+01 4.8E+01
8.40E+01 1.0E+01 1.5E+01 4.8E+01
7.79E+01 3.4E+01 1.5E+01 4.8E+01
9.56E+01 8.1E+00 1.5E+01 4.8E+01
1.87E+02 9.4E+00 1.5E+01 4.8E+01
3.06E+02 6.4E+00 1.5E+01 4.8E+01
5.27E+02 2.2E+00 1.5E+01 4.8E+01
6.23E+02 5.2E+00 1.5E+01 4.8E+01 10 100
2.24E+02 8.7E+00 1.5E+01 4.8E+01
1.30E+02 6.3E+00 1.5E+01 4.8E+01
7.43E+01 1.0E+01 1.5E+01 4.8E+01
6.44E+01 1.6E+01 1.5E+01 4.8E+01
1.12E+02 1.5E+01 1.5E+01 4.8E+01
1.99E+02 1.9E+01 1.5E+01 4.8E+01
3.02E+02 7.1E+00 1.5E+01 4.8E+01
7.50E+00 5.1E+02 1.5E+01 4.8E+01
7.50E+00 1.6E+02 1.5E+01 4.8E+01
7.50E+00 6.0E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.47E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.48E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.52E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10AM EPA Interlab L11 1313-1316CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-865
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutic
Si CFS-L11-1313-T01-A
Si CFS-L11-1313-T02-A
Si CFS-L11-1313-T03-A
Si CFS-L11-1313-T04-A
Si CFS-L11-1313-T05-A
Si CFS-L11-1313-T06-A
Si CFS-L11-1313-T07-A
Si CFS-L11-1313-T08-A
Si CFS-L11-1313-T09-A
Si CFS-L11-1313-T01-B
Si CFS-L11-1313-T02-B
Si CFS-L11-1313-T03-B
Si CFS-L11-1313-T04-B
Si CFS-L11-1313-T05-B
Si CFS-L11-1313-T06-B
Si CFS-L11-1313-T07-B
Si CFS-L11-1313-T08-B
Si CFS-L11-1313-T09-B
Si CFS-L11-1313-T01-C
Si CFS-L11-1313-T02-C
Si CFS-L11-1313-T03-C
Si CFS-L11-1313-T04-C
Si CFS-L11-1313-T05-C
Si CFS-L11-1313-T06-C
Si CFS-L11-1313-T07-C
Si CFS-L11-1313-T08-C
Si CFS-L11-1313-T09-C
Si CFS-L11-1313-B01-A
Si CFS-L11-1313-B02-A
Si CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 3.23E+02
1 3.04E+02
1 5.31 E+02
1 6.56E+02
1 1.28E+03
1 3.41 E+03
1 2.35E+04
1 4.93E+04
1 1.45E+05
1 3.16E+02
1 3.25E+02
1 5.02E+02
1 6.79E+02
1 1.25E+03
1 3.26E+03
1 2.25E+04
1 4.71 E+04
1 1.51E+05
1 3.34E+02
1 3.37E+02
1 5.29E+02
1 6.54E+02
1 1.17E+03
1 3.18E+03
1 2.27E+04
1 4.78E+04
1 1.51E+05
1 8.96E+00
1 6.53E+01
1 2.49E+04
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.23E+02 7.5E-01 1.1E+00 3.5E+00
3.04E+02 3.1E-01 1.1E+00 3.5E+00 1000 100
5.31E+02 8.5E-01 1.1E+00 3.5E+00
6.56E+02 5.8E-01 1.1E+00 3.5E+00
1.28E+03 5.7E-01 1.1E+00 3.5E+00
3.41E+03 1.1E+00 1.1E+00 3.5E+00
2.35E+04 8.5E-01 1.1E+00 3.5E+00
4.93E+04 2.7E-01 1.1E+00 3.5E+00
1.45E+05 4.9E-01 1.1E+00 3.5E+00
3.16E+02 5.9E-01 1.1E+00 3.5E+00
3.25E+02 6.1E-01 1.1E+00 3.5E+00 1000 100
5.02E+02 4.2E-01 1.1E+00 3.5E+00
6.79E+02 3.5E+00 1.1E+00 3.5E+00
1.25E+03 4.0E-01 1.1E+00 3.5E+00
3.26E+03 1.2E+00 1.1E+00 3.5E+00
2.25E+04 3.9E-01 1.1E+00 3.5E+00
4.71E+04 1.9E-01 1.1E+00 3.5E+00
1.51E+05 8.8E-01 1.1E+00 3.5E+00
3.34E+02 1.3E+00 1.1E+00 3.5E+00
3.37E+02 9.5E+00 1.1E+00 3.5E+00 1000 100
5.29E+02 1.2E+00 1.1E+00 3.5E+00
6.54E+02 1.2E+00 1.1E+00 3.5E+00
1.17E+03 4.8E-01 1.1E+00 3.5E+00
3.18E+03 4.1E-01 1.1E+00 3.5E+00
2.27E+04 5.3E-01 1.1E+00 3.5E+00
4.78E+04 1.7E+00 1.1E+00 3.5E+00
1.51E+05 6.5E-01 1.1E+00 3.5E+00
8.96E+00 2.3E+01 1.1E+00 3.5E+00
6.53E+01 7.5E+00 1.1E+00 3.5E+00
2.49E+04 8.9E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.40E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.36E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.42E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10AM EPA Interlab L11 1313-1316CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-866
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na CFS-L11-1313-T01-A
Na CFS-L11-1313-T02-A
Na CFS-L11-1313-T03-A
Na CFS-L11-1313-T04-A
Na CFS-L11-1313-T05-A
Na CFS-L11-1313-T06-A
Na CFS-L11-1313-T07-A
Na CFS-L11-1313-T08-A
Na CFS-L11-1313-T09-A
Na CFS-L11-1313-T01-B
Na CFS-L11-1313-T02-B
Na CFS-L11-1313-T03-B
Na CFS-L11-1313-T04-B
Na CFS-L11-1313-T05-B
Na CFS-L11-1313-T06-B
Na CFS-L11-1313-T07-B
Na CFS-L11-1313-T08-B
Na CFS-L11-1313-T09-B
Na CFS-L11-1313-T01-C
Na CFS-L11-1313-T02-C
Na CFS-L11-1313-T03-C
Na CFS-L11-1313-T04-C
Na CFS-L11-1313-T05-C
Na CFS-L11-1313-T06-C
Na CFS-L11-1313-T07-C
Na CFS-L11-1313-T08-C
Na CFS-L11-1313-T09-C
Na CFS-L11-1313-B01-A
Na CFS-L11-1313-B02-A
Na CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 5.91 E+05
1 4.51 E+05
1 2.47E+05
1 1.85E+05
1 1.24E+05
1 2.50E+04
1 2.62E+04
1 3.01 E+04
1 3.81 E+04
1 5.66E+05
1 4.35E+05
1 2.26E+05
1 1.77E+05
1 1.17E+05
1 2.23E+04
1 2.39E+04
1 2.83E+04
1 3.51 E+04
1 5.71 E+05
1 4.38E+05
1 2.33E+05
1 1.86E+05
1 1.23E+05
1 2.13E+04
1 2.32E+04
1 2.69E+04
1 3.63E+04
1 1.32E+02
1 3.42E+02
1 5.90E+05
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.91 E+05 6.6E-01 2.5E+00 8.0E+00
4.51E+05 3.4E-02 2.5E+00 8.0E+00 1000 100
2.47E+05 6.1E-01 2.5E+00 8.0E+00
1.85E+05 1.3E-01 2.5E+00 8.0E+00
1.24E+05 1.4E-01 2.5E+00 8.0E+00
2.50E+04 1.0E+00 2.5E+00 8.0E+00
2.62E+04 5.6E-02 2.5E+00 8.0E+00
3.01 E+04 8.2E-01 2.5E+00 8.0E+00
3.81 E+04 3.7E-01 2.5E+00 8.0E+00
5.66E+05 2.7E-01 2.5E+00 8.0E+00
4.35E+05 2.3E-01 2.5E+00 8.0E+00 1000 100
2.26E+05 4.7E-01 2.5E+00 8.0E+00
1.77E+05 1.4E+00 2.5E+00 8.0E+00
1.17E+05 4.0E-01 2.5E+00 8.0E+00
2.23E+04 1.2E+00 2.5E+00 8.0E+00
2.39E+04 6.6E-01 2.5E+00 8.0E+00
2.83E+04 4.7E-01 2.5E+00 8.0E+00
3.51 E+04 9.4E-01 2.5E+00 8.0E+00
5.71 E+05 4.3E-01 2.5E+00 8.0E+00
4.38E+05 1.3E+00 2.5E+00 8.0E+00 1000 100
2.33E+05 2.6E-01 2.5E+00 8.0E+00
1.86E+05 2.2E-01 2.5E+00 8.0E+00
1.23E+05 3.7E-01 2.5E+00 8.0E+00
2.13E+04 5.3E-01 2.5E+00 8.0E+00
2.32E+04 4.2E-01 2.5E+00 8.0E+00
2.69E+04 7.1E-01 2.5E+00 8.0E+00
3.63E+04 2.6E-01 2.5E+00 8.0E+00
1.32E+02 1.6E+00 2.5E+00 8.0E+00
3.42E+02 1.2E+00 2.5E+00 8.0E+00
5.90E+05 4.3E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.52E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.36E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.39E+05 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10AM EPA Interlab L11 1313-1316CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-867
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr CFS-L11-1313-T01-A
Sr CFS-L11-1313-T02-A
Sr CFS-L11-1313-T03-A
Sr CFS-L11-1313-T04-A
Sr CFS-L11-1313-T05-A
Sr CFS-L11-1313-T06-A
Sr CFS-L11-1313-T07-A
Sr CFS-L11-1313-T08-A
Sr CFS-L11-1313-T09-A
Sr CFS-L11-1313-T01-B
Sr CFS-L11-1313-T02-B
Sr CFS-L11-1313-T03-B
Sr CFS-L11-1313-T04-B
Sr CFS-L11-1313-T05-B
Sr CFS-L11-1313-T06-B
Sr CFS-L11-1313-T07-B
Sr CFS-L11-1313-T08-B
Sr CFS-L11-1313-T09-B
Sr CFS-L11-1313-T01-C
Sr CFS-L11-1313-T02-C
Sr CFS-L11-1313-T03-C
Sr CFS-L11-1313-T04-C
Sr CFS-L11-1313-T05-C
Sr CFS-L11-1313-T06-C
Sr CFS-L11-1313-T07-C
Sr CFS-L11-1313-T08-C
Sr CFS-L11-1313-T09-C
Sr CFS-L11-1313-B01-A
Sr CFS-L11-1313-B02-A
Sr CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 2.91E+03
1 3.41 E+03
1 3.91 E+03
1 3.31 E+03
1 3.31 E+03
1 1.44E+03
1 9.81 E+02
1 1.07E+03
1 1.33E+03
1 2.91 E+03
1 3.30E+03
1 3.55E+03
1 3.24E+03
1 3.17E+03
1 1.45E+03
1 9.49E+02
1 1.03E+03
1 1.44E+03
1 2.79E+03
1 3.57E+03
1 3.74E+03
1 3.29E+03
1 3.36E+03
1 1.43E+03
1 9.67E+02
1 1.03E+03
1 1.42E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.25E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2. 91 E+03 9.4E-01 1.0E+00 3.2E+00
3.41E+03 7.0E-01 1.0E+00 3.2E+00 1000 100
3.91 E+03 8.6E-01 1.0E+00 3.2E+00
3.31 E+03 6.1E-01 1.0E+00 3.2E+00
3.31 E+03 8.9E-01 1.0E+00 3.2E+00
1.44E+03 9.5E-01 1.0E+00 3.2E+00
9.81 E+02 4.6E-01 1.0E+00 3.2E+00
1.07E+03 6.1E-01 1.0E+00 3.2E+00
1.33E+03 3.6E-01 1.0E+00 3.2E+00
2.91 E+03 9.2E-01 1.0E+00 3.2E+00
3.30E+03 1.8E+00 1.0E+00 3.2E+00 1000 100
3.55E+03 1.1E+00 1.0E+00 3.2E+00
3.24E+03 2.6E+00 1.0E+00 3.2E+00
3.17E+03 1.1E+00 1.0E+00 3.2E+00
1.45E+03 1.1E+00 1.0E+00 3.2E+00
9.49E+02 8.9E-01 1.0E+00 3.2E+00
1.03E+03 1.4E-01 1.0E+00 3.2E+00
1.44E+03 5.3E-01 1.0E+00 3.2E+00
2.79E+03 4.9E-01 1.0E+00 3.2E+00
3.57E+03 6.5E+00 1.0E+00 3.2E+00 1000 100
3.74E+03 1.3E+00 1.0E+00 3.2E+00
3.29E+03 1.3E+00 1.0E+00 3.2E+00
3.36E+03 1.1E+00 1.0E+00 3.2E+00
1.43E+03 3.2E-01 1.0E+00 3.2E+00
9.67E+02 1.3E+00 1.0E+00 3.2E+00
1.03E+03 1.2E+00 1.0E+00 3.2E+00
1.42E+03 1.1E+00 1.0E+00 3.2E+00
5.00E-01 3.0E+01 1.0E+00 3.2E+00
5.00E-01 2.3E+02 1.0E+00 3.2E+00
1.25E+01 2.9E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.30E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.15E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.50E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-868
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutic
S CFS-L11-1313-T01-A
S CFS-L11-1313-T02-A
S CFS-L11-1313-T03-A
S CFS-L11-1313-T04-A
S CFS-L11-1313-T05-A
S CFS-L11-1313-T06-A
S CFS-L11-1313-T07-A
S CFS-L11-1313-T08-A
S CFS-L11-1313-T09-A
S CFS-L11-1313-T01-B
S CFS-L11-1313-T02-B
S CFS-L11-1313-T03-B
S CFS-L11-1313-T04-B
S CFS-L11-1313-T05-B
S CFS-L11-1313-T06-B
S CFS-L11-1313-T07-B
S CFS-L11-1313-T08-B
S CFS-L11-1313-T09-B
S CFS-L11-1313-T01-C
S CFS-L11-1313-T02-C
S CFS-L11-1313-T03-C
S CFS-L11-1313-T04-C
S CFS-L11-1313-T05-C
S CFS-L11-1313-T06-C
S CFS-L11-1313-T07-C
S CFS-L11-1313-T08-C
S CFS-L11-1313-T09-C
S CFS-L11-1313-B01-A
S CFS-L11-1313-B02-A
S CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 1.29E+06
1 1.02E+06
1 7.47E+05
1 6.83E+05
1 6.60E+05
1 6.11E+05
1 6.32E+05
1 7.14E+05
1 7.75E+05
1 1.21E+06
1 9.77E+05
1 6.86E+05
1 6.85E+05
1 6.53E+05
1 5.97E+05
1 6.29E+05
1 6.89E+05
1 7.23E+05
1 1.24E+06
1 1.05E+06
1 7.15E+05
1 6.87E+05
1 6.57E+05
1 5.90E+05
1 6.29E+05
1 6.86E+05
1 7.70E+05
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.29E+06 1.9E-01 6.8E+00 2.2E+01
1.02E+06 1.0E+00 6.8E+00 2.2E+01 1000 100
7.47E+05 7.0E-01 6.8E+00 2.2E+01
6.83E+05 1.4E-01 6.8E+00 2.2E+01
6.60E+05 3.5E-01 6.8E+00 2.2E+01
6.11E+05 1.4E-01 6.8E+00 2.2E+01
6.32E+05 4.3E-01 6.8E+00 2.2E+01
7.14E+05 4.5E-01 6.8E+00 2.2E+01
7.75E+05 1.8E-01 6.8E+00 2.2E+01
1.21E+06 7.7E-01 6.8E+00 2.2E+01
9.77E+05 2.3E-01 6.8E+00 2.2E+01 1000 100
6.86E+05 1.1E+00 6.8E+00 2.2E+01
6.85E+05 2.9E+00 6.8E+00 2.2E+01
6.53E+05 4.2E-01 6.8E+00 2.2E+01
5.97E+05 4.6E-01 6.8E+00 2.2E+01
6.29E+05 4.1E-01 6.8E+00 2.2E+01
6.89E+05 5.8E-01 6.8E+00 2.2E+01
7.23E+05 2.1E-01 6.8E+00 2.2E+01
1.24E+06 4.6E-01 6.8E+00 2.2E+01
1.05E+06 8.0E+00 6.8E+00 2.2E+01 1000 100
7.15E+05 1.1E+00 6.8E+00 2.2E+01
6.87E+05 1.1E+00 6.8E+00 2.2E+01
6.57E+05 8.3E-01 6.8E+00 2.2E+01
5.90E+05 3.7E-01 6.8E+00 2.2E+01
6.29E+05 4.2E-01 6.8E+00 2.2E+01
6.86E+05 5.8E-01 6.8E+00 2.2E+01
7.70E+05 5.1E-02 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01
3.40E+00 3.1E+01 6.8E+00 2.2E+01
3.40E+00 4.5E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.02E+06 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.78E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+06 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-869
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample Dilutic
CFS-L11-1313-T01-A
CFS-L11-1313-T02-A
CFS-L11-1313-T03-A
CFS-L11-1313-T04-A
CFS-L11-1313-T05-A
CFS-L11-1313-T06-A
CFS-L11-1313-T07-A
CFS-L11-1313-T08-A
CFS-L11-1313-T09-A
CFS-L11-1313-T01-B
CFS-L11-1313-T02-B
CFS-L11-1313-T03-B
CFS-L11-1313-T04-B
CFS-L11-1313-T05-B
CFS-L11-1313-T06-B
CFS-L11-1313-T07-B
CFS-L11-1313-T08-B
CFS-L11-1313-T09-B
CFS-L11-1313-T01-C
CFS-L11-1313-T02-C
CFS-L11-1313-T03-C
CFS-L11-1313-T04-C
CFS-L11-1313-T05-C
CFS-L11-1313-T06-C
CFS-L11-1313-T07-C
CFS-L11-1313-T08-C
CFS-L11-1313-T09-C
CFS-L11-1313-B01-A
CFS-L11-1313-B02-A
CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.67E+01
1 6.65E+01
1 1.53E+02
1 1.68E+02
1 2.27E+02
1 2.41 E+02
1 4.50E+02
1 6.84E+02
1 1.19E+03
1 6.00E+01
1 6.41 E+01
1 1.29E+02
1 1.74E+02
1 2.26E+02
1 2.33E+02
1 4.32E+02
1 6.59E+02
1 1.09E+03
1 6.77E+01
1 6.95E+01
1 1.34E+02
1 1.71 E+02
1 2.09E+02
1 2.34E+02
1 4.26E+02
1 6.53E+02
1 1.15E+03
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.67E+01 4.8E+00 4.6E+00 1.5E+01
6.65E+01 7.2E+00 4.6E+00 1.5E+01 10 100
1.53E+02 6.4E+00 4.6E+00 1.5E+01
1.68E+02 3.2E+00 4.6E+00 1.5E+01
2.27E+02 2.4E+00 4.6E+00 1.5E+01
2.41 E+02 2.2E+00 4.6E+00 1.5E+01
4.50E+02 2.0E+00 4.6E+00 1.5E+01
6.84E+02 7.1E-01 4.6E+00 1.5E+01
1.19E+03 1.3E+00 4.6E+00 1.5E+01
6.00E+01 9.6E+00 4.6E+00 1.5E+01
6.41E+01 1.2E+01 4.6E+00 1.5E+01 10 100
1.29E+02 3.9E+00 4.6E+00 1.5E+01
1.74E+02 2.5E+00 4.6E+00 1.5E+01
2.26E+02 1.6E+00 4.6E+00 1.5E+01
2.33E+02 3.5E+00 4.6E+00 1.5E+01
4.32E+02 1.6E+00 4.6E+00 1.5E+01
6.59E+02 1.9E+00 4.6E+00 1.5E+01
1.09E+03 5.2E-01 4.6E+00 1.5E+01
6.77E+01 5.0E+00 4.6E+00 1.5E+01
6.95E+01 1.5E+01 4.6E+00 1.5E+01 10 100
1.34E+02 3.1E+00 4.6E+00 1.5E+01
1.71 E+02 1.8E+00 4.6E+00 1.5E+01
2.09E+02 2.0E+00 4.6E+00 1.5E+01
2.34E+02 7.7E+00 4.6E+00 1.5E+01
4.26E+02 9.4E-01 4.6E+00 1.5E+01
6.53E+02 2.6E+00 4.6E+00 1.5E+01
1.15E+03 7.2E-01 4.6E+00 1.5E+01
2.30E+00 1.2E+02 4.6E+00 1.5E+01
2.30E+00 8.1 E+01 4.6E+00 1.5E+01
2.30E+00 3.1 E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.67E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.42E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.75E+02 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-870
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutic
CFS-L11-1313-T01-A
CFS-L11-1313-T02-A
CFS-L11-1313-T03-A
CFS-L11-1313-T04-A
CFS-L11-1313-T05-A
CFS-L11-1313-T06-A
CFS-L11-1313-T07-A
CFS-L11-1313-T08-A
CFS-L11-1313-T09-A
CFS-L11-1313-T01-B
CFS-L11-1313-T02-B
CFS-L11-1313-T03-B
CFS-L11-1313-T04-B
CFS-L11-1313-T05-B
CFS-L11-1313-T06-B
CFS-L11-1313-T07-B
CFS-L11-1313-T08-B
CFS-L11-1313-T09-B
CFS-L11-1313-T01-C
CFS-L11-1313-T02-C
CFS-L11-1313-T03-C
CFS-L11-1313-T04-C
CFS-L11-1313-T05-C
CFS-L11-1313-T06-C
CFS-L11-1313-T07-C
CFS-L11-1313-T08-C
CFS-L11-1313-T09-C
CFS-L11-1313-B01-A
CFS-L11-1313-B02-A
CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.94E+00 E
1 1.14E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 2.28E+00 E
1 9.53E+00
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 2.56E+00 E
1 1.04E+01
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 6.72E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.2E+00 2.0E+00 6.4E+00
1.00E+00 2.6E+00 2.0E+00 6.4E+00 10 100
1.00E+00 8.5E+00 2.0E+00 6.4E+00
1.00E+00 3.6E+00 2.0E+00 6.4E+00
1.00E+00 6.0E+00 2.0E+00 6.4E+00
1.00E+00 6.0E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
2.94E+00 3.6E+01 2.0E+00 6.4E+00
1.14E+01 3.4E+00 2.0E+00 6.4E+00
1.00E+00 6.1E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+00 2.0E+00 6.4E+00
1.00E+00 6.5E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
2.28E+00 1.5E+01 2.0E+00 6.4E+00
9.53E+00 2.2E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+00 2.0E+00 6.4E+00 10 100
1.00E+00 5.9E+00 2.0E+00 6.4E+00
1.00E+00 4.4E+00 2.0E+00 6.4E+00
1.00E+00 7.6E+00 2.0E+00 6.4E+00
1.00E+00 3.4E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
2.56E+00 2.2E+00 2.0E+00 6.4E+00
1.04E+01 8.4E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+00 2.0E+00 6.4E+00
1.00E+00 4.6E+00 2.0E+00 6.4E+00
6.72E+00 9.8E-01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.49E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.05E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.67E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L1 1 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-871
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutic
V CFS-L11-1313-T01-A
V CFS-L11-1313-T02-A
V CFS-L11-1313-T03-A
V CFS-L11-1313-T04-A
V CFS-L11-1313-T05-A
V CFS-L11-1313-T06-A
V CFS-L11-1313-T07-A
V CFS-L11-1313-T08-A
V CFS-L11-1313-T09-A
V CFS-L11-1313-T01-B
V CFS-L11-1313-T02-B
V CFS-L11-1313-T03-B
V CFS-L11-1313-T04-B
V CFS-L11-1313-T05-B
V CFS-L11-1313-T06-B
V CFS-L11-1313-T07-B
V CFS-L11-1313-T08-B
V CFS-L11-1313-T09-B
V CFS-L11-1313-T01-C
V CFS-L11-1313-T02-C
V CFS-L11-1313-T03-C
V CFS-L11-1313-T04-C
V CFS-L11-1313-T05-C
V CFS-L11-1313-T06-C
V CFS-L11-1313-T07-C
V CFS-L11-1313-T08-C
V CFS-L11-1313-T09-C
V CFS-L11-1313-B01-A
V CFS-L11-1313-B02-A
V CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.36E+01
1 4.07E+01
1 4.03E+01
1 4.05E+01
1 4.14E+01
1 4.31 E+01
1 5.35E+01
1 7.00E+01
1 4.90E+02
1 4.36E+01
1 3.95E+01
1 3.92E+01
1 4.09E+01
1 4.21 E+01
1 4.29E+01
1 5.29E+01
1 6.63E+01
1 4.43E+02
1 4.61 E+01
1 4.27E+01
1 4.02E+01
1 4.08E+01
1 4.16E+01
1 4.24E+01
1 5.36E+01
1 6.92E+01
1 4.63E+02
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.36E+01 1.2E+00 1.5E+00 4.8E+00
4.07E+01 2.9E+00 1.5E+00 4.8E+00 10 100
4.03E+01 6.1E-01 1.5E+00 4.8E+00
4.05E+01 1.6E+00 1.5E+00 4.8E+00
4.14E+01 2.4E+00 1.5E+00 4.8E+00
4.31 E+01 1.1E+00 1.5E+00 4.8E+00
5.35E+01 2.1E+00 1.5E+00 4.8E+00
7.00E+01 3.7E+00 1.5E+00 4.8E+00
4.90E+02 7.8E-01 1.5E+00 4.8E+00
4.36E+01 4.3E-01 1.5E+00 4.8E+00
3.95E+01 9.7E-01 1.5E+00 4.8E+00 10 100
3.92E+01 1.1E+00 1.5E+00 4.8E+00
4.09E+01 4.0E+00 1.5E+00 4.8E+00
4.21 E+01 1.6E+00 1.5E+00 4.8E+00
4.29E+01 2.0E+00 1.5E+00 4.8E+00
5.29E+01 3.9E+00 1.5E+00 4.8E+00
6.63E+01 3.4E+00 1.5E+00 4.8E+00
4.43E+02 5.4E-01 1.5E+00 4.8E+00
4.61 E+01 5.6E+00 1.5E+00 4.8E+00
4.27E+01 9.6E+00 1.5E+00 4.8E+00 10 100
4.02E+01 2.2E+00 1.5E+00 4.8E+00
4.08E+01 2.6E+00 1.5E+00 4.8E+00
4.16E+01 1.4E+00 1.5E+00 4.8E+00
4.24E+01 3.4E+00 1.5E+00 4.8E+00
5.36E+01 2.4E+00 1.5E+00 4.8E+00
6.92E+01 2.8E+00 1.5E+00 4.8E+00
4.63E+02 9.3E-01 1.5E+00 4.8E+00
7.50E-01 9.5E+01 1.5E+00 4.8E+00
7.50E-01 8.7E+01 1.5E+00 4.8E+00
7.50E-01 6.3E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.07E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-872
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutic
Zn CFS-L11-1313-T01-A
Zn CFS-L11-1313-T02-A
Zn CFS-L11-1313-T03-A
Zn CFS-L11-1313-T04-A
Zn CFS-L11-1313-T05-A
Zn CFS-L11-1313-T06-A
Zn CFS-L11-1313-T07-A
Zn CFS-L11-1313-T08-A
Zn CFS-L11-1313-T09-A
Zn CFS-L11-1313-T01-B
Zn CFS-L11-1313-T02-B
Zn CFS-L11-1313-T03-B
Zn CFS-L11-1313-T04-B
Zn CFS-L11-1313-T05-B
Zn CFS-L11-1313-T06-B
Zn CFS-L11-1313-T07-B
Zn CFS-L11-1313-T08-B
Zn CFS-L11-1313-T09-B
Zn CFS-L11-1313-T01-C
Zn CFS-L11-1313-T02-C
Zn CFS-L11-1313-T03-C
Zn CFS-L11-1313-T04-C
Zn CFS-L11-1313-T05-C
Zn CFS-L11-1313-T06-C
Zn CFS-L11-1313-T07-C
Zn CFS-L11-1313-T08-C
Zn CFS-L11-1313-T09-C
Zn CFS-L11-1313-B01-A
Zn CFS-L11-1313-B02-A
Zn CFS-L11-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L I I
1 4.29E+03
1 2.43E+03
1 1.04E+01
1 1.61E+02
1 2.74E+02
1 1.80E+04
1 1.46E+05
1 1.74E+05
1 1.68E+05
1 3.88E+03
1 2.13E+03
1 2.85E+01
1 9.50E+00
1 2.73E+02
1 1.64E+04
1 1.44E+05
1 1.72E+05
1 1.63E+05
1 4.07E+03
1 2.54E+03
1 8.08E+00
1 8.87E+00
1 2.13E+02
1 1.54E+04
1 1.44E+05
1 1.76E+05
1 1.65E+05
1 1.20E+01
1 1.98E+02
1 4.66E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.29E+03 2.2E+00 1.0E+00 3.2E+00
2.43E+03 8.1E-01 1.0E+00 3.2E+00 10 100
1.04E+01 5.3E+00 1.0E+00 3.2E+00
1.61E+02 8.3E-01 1.0E+00 3.2E+00
2.74E+02 3.2E-01 1.0E+00 3.2E+00
1.80E+04 1.3E+00 1.0E+00 3.2E+00
1.46E+05 1.3E+00 1.0E+00 3.2E+00
1.74E+05 7.4E-01 1.0E+00 3.2E+00
1.68E+05 1.4E+00 1.0E+00 3.2E+00
3.88E+03 5.5E-01 1.0E+00 3.2E+00
2.13E+03 2.1E+00 1.0E+00 3.2E+00 10 100
2.85E+01 1.6E+00 1.0E+00 3.2E+00
9.50E+00 3.1E+00 1.0E+00 3.2E+00
2.73E+02 1.2E+00 1.0E+00 3.2E+00
1.64E+04 1.4E+00 1.0E+00 3.2E+00
1.44E+05 2.6E+00 1.0E+00 3.2E+00
1.72E+05 3.8E+00 1.0E+00 3.2E+00
1.63E+05 5.6E-01 1.0E+00 3.2E+00
4.07E+03 2.1E+00 1.0E+00 3.2E+00
2.54E+03 6.2E+00 1.0E+00 3.2E+00 10 100
8.08E+00 1.9E+00 1.0E+00 3.2E+00
8.87E+00 3.1E-01 1.0E+00 3.2E+00
2.13E+02 8.7E-01 1.0E+00 3.2E+00
1.54E+04 6.7E-01 1.0E+00 3.2E+00
1.44E+05 4.0E-01 1.0E+00 3.2E+00
1.76E+05 1.2E+00 1.0E+00 3.2E+00
1.65E+05 4.2E-01 1.0E+00 3.2E+00
1.20E+01 8.1E-01 1.0E+00 3.2E+00
1.98E+02 2.8E+00 1.0E+00 3.2E+00
4.66E+01 1.5E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.37E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.02E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.39E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/31/11 9:57 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:58 AM EPA Interlab L11 1313-1316CFS
5/31/11 10:00 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:02 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:03 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:05 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:07 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:08 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:10 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:17 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:18 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:20 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:22 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:23 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:25 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:27 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:28 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:30 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:37 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:38 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:40 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:42 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:43 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:45 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:47 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 10:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:48 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:50 AM EPA Interlab L11 1313-1316 CFS
5/31/11 9:55 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                          1-873
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample Internal
Sample Dilution Cone. Qualifier Review
I I ug/L I
CFS-LRef-1313-T01-A 1 9.81E+04
CFS-LRef-1313-T02-A 1 3.81E+04
CFS-LRef-1313-T03-A 1 3.20E+03
CFS-LRef-1313-T04-A 1 4.94E+01
CFS-LRef-1313-T05-A 1 4.28E+01
CFS-LRef-1313-T06-A 1 4.46E+01
CFS-LRef-1313-T07-A 1 1.30E+02
CFS-LRef-1313-T08-A 1 1.11E+02
CFS-LRef-1313-T09-A 1 8.33E+01
CFS-LRef-1313-T01-B 1 9.88E+04
CFS-LRef-1313-T02-B 1 3.71E+04
CFS-LRef-1313-T03-B 1 3.18E+03
CFS-LRef-1313-T04-B 1 3.86E+01
CFS-LRef-1313-T05-B 1 3.83E+01
CFS-LRef-1313-T06-B 1 5.13E+01
CFS-LRef-1313-T07-B 1 1.16E+02
CFS-LRef-1313-T08-B 1 1.03E+02
CFS-LRef-1313-T09-B 1 8.77E+01
CFS-LRef-1313-T01-C 1 9.91E+04
CFS-LRef-1313-T02-C 1 3.68E+04
CFS-LRef-1313-T03-C 1 3.20E+03
CFS-LRef-1313-T04-C 1 4.20E+01
CFS-LRef-1313-T05-C 1 4.67E+01
CFS-LRef-1313-T06-C 1 4.47E+01
CFS-LRef-1313-T07-C 1 1.10E+02
CFS-LRef-1313-T08-C 1 1.10E+02
CFS-LRef-1313-T09-C 1 9.23E+01
CFS-LRef-1313-B01-A 1 5.00E-01 U1/2
CFS-LRef-1313-B02-A 1 5.00E-01 U1/2
CFS-LRef-1313-B03-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.81 E+04 3.5E-01 1.0E+00 3.2E+00
3.81E+04 2.8E+00 1.0E+00 3.2E+00 1000 100
3.20E+03 1.1E+00 1.0E+00 3.2E+00
4.94E+01 8.0E+00 1.0E+00 3.2E+00
4.28E+01 7.4E+00 1.0E+00 3.2E+00
4.46E+01 2.1E+00 1.0E+00 3.2E+00
1.30E+02 7.1E+00 1.0E+00 3.2E+00
1.11E+02 2.8E+00 1.0E+00 3.2E+00
8.33E+01 3.1E+00 1.0E+00 3.2E+00
9.88E+04 4.5E-01 1.0E+00 3.2E+00
3.71E+04 1.0E+00 1.0E+00 3.2E+00 1000 100
3.18E+03 6.0E-01 1.0E+00 3.2E+00
3.86E+01 7.2E+00 1.0E+00 3.2E+00
3.83E+01 3.4E+00 1.0E+00 3.2E+00
5.13E+01 4.9E+00 1.0E+00 3.2E+00
1.16E+02 2.6E+00 1.0E+00 3.2E+00
1.03E+02 1.8E+00 1.0E+00 3.2E+00
8.77E+01 1.2E+00 1.0E+00 3.2E+00
9.91 E+04 7.1E-01 1.0E+00 3.2E+00
3.68E+04 1.2E+00 1.0E+00 3.2E+00 1000 100
3.20E+03 9.4E-01 1.0E+00 3.2E+00
4.20E+01 4.8E+00 1.0E+00 3.2E+00
4.67E+01 5.7E+00 1.0E+00 3.2E+00
4.47E+01 3.4E+00 1.0E+00 3.2E+00
1.10E+02 2.2E+00 1.0E+00 3.2E+00
1.10E+02 4.9E+00 1.0E+00 3.2E+00
9.23E+01 3.5E+00 1.0E+00 3.2E+00
5.00E-01 8.9E+00 1.0E+00 3.2E+00
5.00E-01 2.0E+01 1.0E+00 3.2E+00
5.00E-01 2.9E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.90E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.81 E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.78E+04 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                                     1-874
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutk
Sb CFS-LRef-1313-T01-A
Sb CFS-LRef-1313-T02-A
Sb CFS-LRef-1313-T03-A
Sb CFS-LRef-1313-T04-A
Sb CFS-LRef-1313-T05-A
Sb CFS-LRef-1313-T06-A
Sb CFS-LRef-1313-T07-A
Sb CFS-LRef-1313-T08-A
Sb CFS-LRef-1313-T09-A
Sb CFS-LRef-1313-T01-B
Sb CFS-LRef-1313-T02-B
Sb CFS-LRef-1313-T03-B
Sb CFS-LRef-1313-T04-B
Sb CFS-LRef-1313-T05-B
Sb CFS-LRef-1313-T06-B
Sb CFS-LRef-1313-T07-B
Sb CFS-LRef-1313-T08-B
Sb CFS-LRef-1313-T09-B
Sb CFS-LRef-1313-T01-C
Sb CFS-LRef-1313-T02-C
Sb CFS-LRef-1313-T03-C
Sb CFS-LRef-1313-T04-C
Sb CFS-LRef-1313-T05-C
Sb CFS-LRef-1313-T06-C
Sb CFS-LRef-1313-T07-C
Sb CFS-LRef-1313-T08-C
Sb CFS-LRef-1313-T09-C
Sb CFS-LRef-1313-B01-A
Sb CFS-LRef-1313-B02-A
Sb CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.46E+03
1 1.12E+03
1 8.04E+01
1 4.57E+01
1 2.84E+01
1 3.70E+01
1 2.54E+01
1 1.46E+01 E
1 9.61E+OOE
1 1.40E+03
1 1.04E+03
1 9.55E+01
1 3.29E+01
1 3.94E+01
1 2.75E+01
1 3.39E+01
1 1.01E+01 E
1 9.74E+00 E
1 1.36E+03
1 1.07E+03
1 9.07E+01
1 3.37E+01
1 3.97E+01
1 4.48E+01
1 2.52E+01
1 1.64E+01 E
1 8.28E+00 E
1 8.56E+00 E
1 9.51 E+00 E
1 2.07E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.46E+03 1.2E+01 7.5E+00 2.4E+01
1.12E+03 1.0E+01 7.5E+00 2.4E+01 10 100
8.04E+01 1.8E+01 7.5E+00 2.4E+01
4.57E+01 9.3E+00 7.5E+00 2.4E+01
2.84E+01 2.2E+01 7.5E+00 2.4E+01
3.70E+01 1.1E+01 7.5E+00 2.4E+01
2.54E+01 1.8E+01 7.5E+00 2.4E+01
1.46E+01 1.6E+01 7.5E+00 2.4E+01
9.61 E+00 9.6E+01 7.5E+00 2.4E+01
1.40E+03 3.7E+00 7.5E+00 2.4E+01
1.04E+03 8.0E+00 7.5E+00 2.4E+01 10 100
9.55E+01 2.8E+00 7.5E+00 2.4E+01
3.29E+01 3.3E+01 7.5E+00 2.4E+01
3.94E+01 2.6E+01 7.5E+00 2.4E+01
2.75E+01 3.2E+01 7.5E+00 2.4E+01
3.39E+01 5.1 E+00 7.5E+00 2.4E+01
1.01E+01 4.5E+01 7.5E+00 2.4E+01
9.74E+00 6.5E+01 7.5E+00 2.4E+01
1.36E+03 3.6E+00 7.5E+00 2.4E+01
1.07E+03 8.9E+00 7.5E+00 2.4E+01 10 100
9.07E+01 2.9E+00 7.5E+00 2.4E+01
3.37E+01 1.5E+01 7.5E+00 2.4E+01
3.97E+01 2.0E+01 7.5E+00 2.4E+01
4.48E+01 1.2E+01 7.5E+00 2.4E+01
2.52E+01 1.6E+01 7.5E+00 2.4E+01
1.64E+01 1.4E+01 7.5E+00 2.4E+01
8.28E+00 3.3E+01 7.5E+00 2.4E+01
8.56E+00 3.6E+01 7.5E+00 2.4E+01
9.51 E+00 3.3E+01 7.5E+00 2.4E+01
2.07E+01 1.2E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
2.03E+03 91% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
1.98E+03 93% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.97E+03 90% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-875
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As CFS-LRef-1313-T01-A
As CFS-LRef-1313-T02-A
As CFS-LRef-1313-T03-A
As CFS-LRef-1313-T04-A
As CFS-LRef-1313-T05-A
As CFS-LRef-1313-T06-A
As CFS-LRef-1313-T07-A
As CFS-LRef-1313-T08-A
As CFS-LRef-1313-T09-A
As CFS-LRef-1313-T01-B
As CFS-LRef-1313-T02-B
As CFS-LRef-1313-T03-B
As CFS-LRef-1313-T04-B
As CFS-LRef-1313-T05-B
As CFS-LRef-1313-T06-B
As CFS-LRef-1313-T07-B
As CFS-LRef-1313-T08-B
As CFS-LRef-1313-T09-B
As CFS-LRef-1313-T01-C
As CFS-LRef-1313-T02-C
As CFS-LRef-1313-T03-C
As CFS-LRef-1313-T04-C
As CFS-LRef-1313-T05-C
As CFS-LRef-1313-T06-C
As CFS-LRef-1313-T07-C
As CFS-LRef-1313-T08-C
As CFS-LRef-1313-T09-C
As CFS-LRef-1313-B01-A
As CFS-LRef-1313-B02-A
As CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 8.06E+04
1 1.22E+03
1 1.05E+02
1 2.54E+01 E
1 2.30E+01 E
1 2.94E+01 E
1 9.28E+01
1 1.83E+02
1 2.12E+02
1 7.93E+04
1 1.27E+03
1 1.09E+02
1 2.15E+01 E
1 3.25E+01 E
1 4.25E+01
1 1.04E+02
1 2.08E+02
1 2.04E+02
1 8.69E+04
1 1.03E+03
1 1.17E+02
1 2.26E+01 E
1 2.95E+01 E
1 3.89E+01
1 1.04E+02
1 2.52E+02
1 2.20E+02
1 5.50E+00 U1/2
1 5.50E+00 U1/2
1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.06E+04 2.0E+00 1.1E+01 3.5E+01
1.22E+03 1.5E+00 1.1E+01 3.5E+01 10 100
1.05E+02 5.7E+00 1.1E+01 3.5E+01
2.54E+01 2.3E+01 1.1E+01 3.5E+01
2.30E+01 2.8E+01 1.1E+01 3.5E+01
2.94E+01 1.3E+01 1.1E+01 3.5E+01
9.28E+01 6.0E+00 1.1E+01 3.5E+01
1.83E+02 8.6E-01 1.1E+01 3.5E+01
2.12E+02 6.5E+00 1.1E+01 3.5E+01
7.93E+04 5.7E-01 1.1E+01 3.5E+01
1.27E+03 6.9E-01 1.1E+01 3.5E+01 10 100
1.09E+02 7.0E+00 1.1E+01 3.5E+01
2.15E+01 5.8E+01 1.1E+01 3.5E+01
3.25E+01 6.2E+01 1.1E+01 3.5E+01
4.25E+01 1.1E+01 1.1E+01 3.5E+01
1.04E+02 7.3E+00 1.1E+01 3.5E+01
2.08E+02 3.4E+00 1.1E+01 3.5E+01
2.04E+02 1.0E+01 1.1E+01 3.5E+01
8.69E+04 6.9E-01 1.1E+01 3.5E+01
1.03E+03 1.5E+00 1.1E+01 3.5E+01 10 100
1.17E+02 5.4E+00 1.1E+01 3.5E+01
2.26E+01 4.5E+01 1.1E+01 3.5E+01
2.95E+01 2.7E+00 1.1E+01 3.5E+01
3.89E+01 8.9E+00 1.1E+01 3.5E+01
1.04E+02 4.9E+00 1.1E+01 3.5E+01
2.52E+02 5.3E+00 1.1E+01 3.5E+01
2.20E+02 7.9E+00 1.1E+01 3.5E+01
5.50E+00 1.0E+02 1.1E+01 3.5E+01
5.50E+00 2.5E+01 1.1E+01 3.5E+01
5.50E+00 8.3E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
2.12E+03 90% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
2.17E+03 90% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.94E+03 91% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-876
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B CFS-LRef-1313-T01-A
B CFS-LRef-1313-T02-A
B CFS-LRef-1313-T03-A
B CFS-LRef-1313-T04-A
B CFS-LRef-1313-T05-A
B CFS-LRef-1313-T06-A
B CFS-LRef-1313-T07-A
B CFS-LRef-1313-T08-A
B CFS-LRef-1313-T09-A
B CFS-LRef-1313-T01-B
B CFS-LRef-1313-T02-B
B CFS-LRef-1313-T03-B
B CFS-LRef-1313-T04-B
B CFS-LRef-1313-T05-B
B CFS-LRef-1313-T06-B
B CFS-LRef-1313-T07-B
B CFS-LRef-1313-T08-B
B CFS-LRef-1313-T09-B
B CFS-LRef-1313-T01-C
B CFS-LRef-1313-T02-C
B CFS-LRef-1313-T03-C
B CFS-LRef-1313-T04-C
B CFS-LRef-1313-T05-C
B CFS-LRef-1313-T06-C
B CFS-LRef-1313-T07-C
B CFS-LRef-1313-T08-C
B CFS-LRef-1313-T09-C
B CFS-LRef-1313-B01-A
B CFS-LRef-1313-B02-A
B CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 7.61E+02
1 6.78E+02
1 3.14E+02
1 1.63E+02
1 1.27E+02
1 1.23E+02
1 1.64E+02
1 7.74E+01
1 6.79E+01
1 7.78E+02
1 6.84E+02
1 3.12E+02
1 1.69E+02
1 1.30E+02
1 1.21E+02
1 1.71E+02
1 8.49E+01
1 7.58E+01
1 8.48E+02
1 6.94E+02
1 3.07E+02
1 1.61E+02
1 1.26E+02
1 1.18E+02
1 1.66E+02
1 8.36E+01
1 7.21 E+01
1 1.30E+01
1 1.36E+01
1 1.45E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.61E+02 1.8E+00 1.0E+00 3.2E+00
6.78E+02 1.7E+00 1.0E+00 3.2E+00 1000 100
3.14E+02 1.1E+00 1.0E+00 3.2E+00
1.63E+02 1.6E+00 1.0E+00 3.2E+00
1.27E+02 1.3E+00 1.0E+00 3.2E+00
1.23E+02 8.7E-01 1.0E+00 3.2E+00
1.64E+02 4.4E+00 1.0E+00 3.2E+00
7.74E+01 2.6E+00 1.0E+00 3.2E+00
6.79E+01 2.7E+00 1.0E+00 3.2E+00
7.78E+02 1.9E+00 1.0E+00 3.2E+00
6.84E+02 1.5E+00 1.0E+00 3.2E+00 1000 100
3.12E+02 1.1E+00 1.0E+00 3.2E+00
1.69E+02 5.3E-01 1.0E+00 3.2E+00
1.30E+02 6.2E-01 1.0E+00 3.2E+00
1.21E+02 1.9E+00 1.0E+00 3.2E+00
1.71E+02 9.2E-01 1.0E+00 3.2E+00
8.49E+01 7.1E-01 1.0E+00 3.2E+00
7.58E+01 8.5E-01 1.0E+00 3.2E+00
8.48E+02 1.6E+00 1.0E+00 3.2E+00
6.94E+02 1.5E+00 1.0E+00 3.2E+00 1000 100
3.07E+02 8.8E-01 1.0E+00 3.2E+00
1.61E+02 1.8E+00 1.0E+00 3.2E+00
1.26E+02 3.2E+00 1.0E+00 3.2E+00
1.18E+02 1.4E+00 1.0E+00 3.2E+00
1.66E+02 6.7E-01 1.0E+00 3.2E+00
8.36E+01 4.6E+00 1.0E+00 3.2E+00
7.21 E+01 6.5E-01 1.0E+00 3.2E+00
1.30E+01 5.5E+00 1.0E+00 3.2E+00
1.36E+01 6.5E+00 1.0E+00 3.2E+00
1.45E+01 1.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.60E+03 93% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
1.61E+03 92% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.61E+03 91% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-877
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba CFS-LRef-1313-T01-A
Ba CFS-LRef-1313-T02-A
Ba CFS-LRef-1313-T03-A
Ba CFS-LRef-1313-T04-A
Ba CFS-LRef-1313-T05-A
Ba CFS-LRef-1313-T06-A
Ba CFS-LRef-1313-T07-A
Ba CFS-LRef-1313-T08-A
Ba CFS-LRef-1313-T09-A
Ba CFS-LRef-1313-T01-B
Ba CFS-LRef-1313-T02-B
Ba CFS-LRef-1313-T03-B
Ba CFS-LRef-1313-T04-B
Ba CFS-LRef-1313-T05-B
Ba CFS-LRef-1313-T06-B
Ba CFS-LRef-1313-T07-B
Ba CFS-LRef-1313-T08-B
Ba CFS-LRef-1313-T09-B
Ba CFS-LRef-1313-T01-C
Ba CFS-LRef-1313-T02-C
Ba CFS-LRef-1313-T03-C
Ba CFS-LRef-1313-T04-C
Ba CFS-LRef-1313-T05-C
Ba CFS-LRef-1313-T06-C
Ba CFS-LRef-1313-T07-C
Ba CFS-LRef-1313-T08-C
Ba CFS-LRef-1313-T09-C
Ba CFS-LRef-1313-B01-A
Ba CFS-LRef-1313-B02-A
Ba CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.94E+00
1 3.70E+01
1 2.77E+01
1 9.34E+01
1 7.30E+01
1 7.69E+01
1 1.66E+02
1 5.36E+00
1 2.56E+00 E
1 5.06E+00
1 3.53E+01
1 2.73E+01
1 9.76E+01
1 7.73E+01
1 8.36E+01
1 1.69E+02
1 3.99E+00
1 2.45E+00 E
1 4.99E+00
1 3.82E+01
1 2.75E+01
1 9.70E+01
1 7.44E+01
1 8.19E+01
1 1.64E+02
1 3.91 E+00
1 1.37E+00 E
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.94E+00 7.1E-02 1.0E+00 3.2E+00
3.70E+01 2.6E+00 1.0E+00 3.2E+00 10 100
2.77E+01 1.2E+00 1.0E+00 3.2E+00
9.34E+01 1.2E+00 1.0E+00 3.2E+00
7.30E+01 1.1 E+00 1.0E+00 3.2E+00
7.69E+01 6.4E-01 1.0E+00 3.2E+00
1.66E+02 3.9E+00 1.0E+00 3.2E+00
5.36E+00 2.1 E+00 1.0E+00 3.2E+00
2.56E+00 6.6E+00 1.0E+00 3.2E+00
5.06E+00 1.5E+00 1.0E+00 3.2E+00
3.53E+01 1.5E+00 1.0E+00 3.2E+00 10 100
2.73E+01 9.2E-01 1.0E+00 3.2E+00
9.76E+01 6.8E-01 1.0E+00 3.2E+00
7.73E+01 1.1 E+00 1.0E+00 3.2E+00
8.36E+01 6.6E-01 1.0E+00 3.2E+00
1.69E+02 6.1E-01 1.0E+00 3.2E+00
3.99E+00 1.3E+00 1.0E+00 3.2E+00
2.45E+00 2.4E+01 1.0E+00 3.2E+00
4.99E+00 1.6E+00 1.0E+00 3.2E+00
3.82E+01 7.7E-01 1.0E+00 3.2E+00 10 100
2.75E+01 3.5E-01 1.0E+00 3.2E+00
9.70E+01 6.4E-01 1.0E+00 3.2E+00
7.44E+01 1.1 E+00 1.0E+00 3.2E+00
8.19E+01 8.5E-01 1.0E+00 3.2E+00
1.64E+02 2.5E-02 1.0E+00 3.2E+00
3.91 E+00 6.0E+00 1.0E+00 3.2E+00
1.37E+00 7.2E+00 1.0E+00 3.2E+00
5.00E-01 4.9E+00 1.0E+00 3.2E+00
5.00E-01 3.7E+01 1.0E+00 3.2E+00
5.00E-01 3.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.08E+03 105% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
1.09E+03 106% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.08E+03 104% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-878
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be CFS-LRef-1313-T01-A
Be CFS-LRef-1313-T02-A
Be CFS-LRef-1313-T03-A
Be CFS-LRef-1313-T04-A
Be CFS-LRef-1313-T05-A
Be CFS-LRef-1313-T06-A
Be CFS-LRef-1313-T07-A
Be CFS-LRef-1313-T08-A
Be CFS-LRef-1313-T09-A
Be CFS-LRef-1313-T01-B
Be CFS-LRef-1313-T02-B
Be CFS-LRef-1313-T03-B
Be CFS-LRef-1313-T04-B
Be CFS-LRef-1313-T05-B
Be CFS-LRef-1313-T06-B
Be CFS-LRef-1313-T07-B
Be CFS-LRef-1313-T08-B
Be CFS-LRef-1313-T09-B
Be CFS-LRef-1313-T01-C
Be CFS-LRef-1313-T02-C
Be CFS-LRef-1313-T03-C
Be CFS-LRef-1313-T04-C
Be CFS-LRef-1313-T05-C
Be CFS-LRef-1313-T06-C
Be CFS-LRef-1313-T07-C
Be CFS-LRef-1313-T08-C
Be CFS-LRef-1313-T09-C
Be CFS-LRef-1313-B01-A
Be CFS-LRef-1313-B02-A
Be CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.50E-01 U1/2
1 7.56E+00
1 2.54E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 6.72E+00
1 2.54E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 6.68E+00
1 2.68E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 3.9E+02 1.9E+00 6.0E+00
7.56E+00 7.7E+00 1.9E+00 6.0E+00 10 100
2.54E+00 2.2E+00 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00
9.50E-01 2.2E+02 1.9E+00 6.0E+00
9.50E-01 3.5E+02 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+03 1.9E+00 6.0E+00
9.50E-01 7.9E+02 1.9E+00 6.0E+00
9.50E-01 1.0E+01 1.9E+00 6.0E+00
6.72E+00 1.1E+01 1.9E+00 6.0E+00 10 100
2.54E+00 7.4E+00 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 6.5E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 2.6E+02 1.9E+00 6.0E+00
9.50E-01 9.7E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
6.68E+00 8.4E+00 1.9E+00 6.0E+00 10 100
2.68E+00 4.2E+00 1.9E+00 6.0E+00
9.50E-01 4.3E+02 1.9E+00 6.0E+00
9.50E-01 2.9E+02 1.9E+00 6.0E+00
9.50E-01 8.8E+01 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 2.6E+02 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.03E+03 102% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
1.04E+03 103% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.01E+03 100% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-879
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutk
Cd CFS-LRef-1313-T01-A
Cd CFS-LRef-1313-T02-A
Cd CFS-LRef-1313-T03-A
Cd CFS-LRef-1313-T04-A
Cd CFS-LRef-1313-T05-A
Cd CFS-LRef-1313-T06-A
Cd CFS-LRef-1313-T07-A
Cd CFS-LRef-1313-T08-A
Cd CFS-LRef-1313-T09-A
Cd CFS-LRef-1313-T01-B
Cd CFS-LRef-1313-T02-B
Cd CFS-LRef-1313-T03-B
Cd CFS-LRef-1313-T04-B
Cd CFS-LRef-1313-T05-B
Cd CFS-LRef-1313-T06-B
Cd CFS-LRef-1313-T07-B
Cd CFS-LRef-1313-T08-B
Cd CFS-LRef-1313-T09-B
Cd CFS-LRef-1313-T01-C
Cd CFS-LRef-1313-T02-C
Cd CFS-LRef-1313-T03-C
Cd CFS-LRef-1313-T04-C
Cd CFS-LRef-1313-T05-C
Cd CFS-LRef-1313-T06-C
Cd CFS-LRef-1313-T07-C
Cd CFS-LRef-1313-T08-C
Cd CFS-LRef-1313-T09-C
Cd CFS-LRef-1313-B01-A
Cd CFS-LRef-1313-B02-A
Cd CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.09E+04
1 5.18E+04
1 2.30E+04
1 5.25E+03
1 9.80E+01
1 1.90E+01
1 3.91 E+00 E
1 4.08E+00 E
1 6.19E+00 E
1 4.91 E+04
1 5. 11 E+04
1 2.31 E+04
1 5.36E+03
1 8.46E+01
1 1.82E+01
1 4.08E+00 E
1 4.08E+00 E
1 5.75E+00 E
1 5.03E+04
1 5.26E+04
1 2.32E+04
1 4.92E+03
1 9.72E+01
1 1.52E+01
1 4.08E+00 E
1 4.08E+00 E
1 6.50E+00 E
1 4.08E+00 E
1 4.08E+00 E
1 4.08E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.09E+04 5.6E-01 2.2E+00 7.0E+00
5.18E+04 2.0E+00 2.2E+00 7.0E+00 10 100
2.30E+04 7.2E-01 2.2E+00 7.0E+00
5.25E+03 7.5E-01 2.2E+00 7.0E+00
9.80E+01 7.5E-01 2.2E+00 7.0E+00
1.90E+01 8.5E-01 2.2E+00 7.0E+00
3.91 E+00 2.9E+01 2.2E+00 7.0E+00
4.08E+00 4.1 E+00 2.2E+00 7.0E+00
6.19E+00 5.4E+00 2.2E+00 7.0E+00
4.91 E+04 1.4E+00 2.2E+00 7.0E+00
5.11E+04 2.2E+00 2.2E+00 7.0E+00 10 100
2.31 E+04 8.8E-01 2.2E+00 7.0E+00
5.36E+03 2.3E-01 2.2E+00 7.0E+00
8.46E+01 1.8E-01 2.2E+00 7.0E+00
1.82E+01 8.4E-01 2.2E+00 7.0E+00
4.08E+00 4.3E+01 2.2E+00 7.0E+00
4.08E+00 2.7E+01 2.2E+00 7.0E+00
5.75E+00 1.4E+00 2.2E+00 7.0E+00
5.03E+04 2.4E-01 2.2E+00 7.0E+00
5.26E+04 1.5E+00 2.2E+00 7.0E+00 10 100
2.32E+04 6.2E-01 2.2E+00 7.0E+00
4.92E+03 1.0E+00 2.2E+00 7.0E+00
9.72E+01 1.8E+00 2.2E+00 7.0E+00
1.52E+01 2.3E+00 2.2E+00 7.0E+00
4.08E+00 3.9E+01 2.2E+00 7.0E+00
4.08E+00 2.9E+01 2.2E+00 7.0E+00
6.50E+00 5.5E+00 2.2E+00 7.0E+00
4.08E+00 2.0E+01 2.2E+00 7.0E+00
4.08E+00 6.1E+01 2.2E+00 7.0E+00
4.08E+00 6.5E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
5.26E+04 86% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
5.20E+04 93% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
5.36E+04 96% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-880
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
CFS-LRef-1313-T01-A
CFS-LRef-1313-T02-A
CFS-LRef-1313-T03-A
CFS-LRef-1313-T04-A
CFS-LRef-1313-T05-A
CFS-LRef-1313-T06-A
CFS-LRef-1313-T07-A
CFS-LRef-1313-T08-A
CFS-LRef-1313-T09-A
CFS-LRef-1313-T01-B
CFS-LRef-1313-T02-B
CFS-LRef-1313-T03-B
CFS-LRef-1313-T04-B
CFS-LRef-1313-T05-B
CFS-LRef-1313-T06-B
CFS-LRef-1313-T07-B
CFS-LRef-1313-T08-B
CFS-LRef-1313-T09-B
CFS-LRef-1313-T01-C
CFS-LRef-1313-T02-C
CFS-LRef-1313-T03-C
CFS-LRef-1313-T04-C
CFS-LRef-1313-T05-C
CFS-LRef-1313-T06-C
CFS-LRef-1313-T07-C
CFS-LRef-1313-T08-C
CFS-LRef-1313-T09-C
CFS-LRef-1313-B01-A
CFS-LRef-1313-B02-A
CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.67E+06
1 1.37E+06
1 8.76E+05
1 6.80E+05
1 6.19E+05
1 6.16E+05
1 5.98E+05
1 5.73E+05
1 6.15E+05
1 1.66E+06
1 1.39E+06
1 8.83E+05
1 7.07E+05
1 6.42E+05
1 6.13E+05
1 6.06E+05
1 5.63E+05
1 6.40E+05
1 1.68E+06
1 1.35E+06
1 8.88E+05
1 6.78E+05
1 6.26E+05
1 6.03E+05
1 5.96E+05
1 5.82E+05
1 6.35E+05
1 2.30E+00 U1/2
1 2.72E+00 E
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.67E+06 8.1E-01 2.6E+00 8.3E+00
1.37E+06 2.6E+00 2.6E+00 8.3E+00 1000 100
8.76E+05 9.8E-01 2.6E+00 8.3E+00
6.80E+05 5.1E-01 2.6E+00 8.3E+00
6.19E+05 1.1E+00 2.6E+00 8.3E+00
6.16E+05 4.6E-01 2.6E+00 8.3E+00
5.98E+05 5.2E+00 2.6E+00 8.3E+00
5.73E+05 1.4E+00 2.6E+00 8.3E+00
6.15E+05 3.0E-01 2.6E+00 8.3E+00
1.66E+06 1.4E+00 2.6E+00 8.3E+00
1.39E+06 1.9E+00 2.6E+00 8.3E+00 1000 100
8.83E+05 5.1E-01 2.6E+00 8.3E+00
7.07E+05 6.6E-01 2.6E+00 8.3E+00
6.42E+05 5.2E-01 2.6E+00 8.3E+00
6.13E+05 1.2E+00 2.6E+00 8.3E+00
6.06E+05 4.2E-01 2.6E+00 8.3E+00
5.63E+05 8.8E-01 2.6E+00 8.3E+00
6.40E+05 1.1E+00 2.6E+00 8.3E+00
1.68E+06 3.3E-01 2.6E+00 8.3E+00
1.35E+06 1.9E+00 2.6E+00 8.3E+00 1000 100
8.88E+05 5.2E-01 2.6E+00 8.3E+00
6.78E+05 9.5E-01 2.6E+00 8.3E+00
6.26E+05 7.9E-01 2.6E+00 8.3E+00
6.03E+05 8.7E-01 2.6E+00 8.3E+00
5.96E+05 6.5E-01 2.6E+00 8.3E+00
5.82E+05 4.6E+00 2.6E+00 8.3E+00
6.35E+05 1.5E+00 2.6E+00 8.3E+00
2.30E+00 5.1E+01 2.6E+00 8.3E+00
2.72E+00 2.0E+02 2.6E+00 8.3E+00
2.30E+00 8.1E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.37E+06 84% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
1.39E+06 89% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.35E+06 90% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-881
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr CFS-LRef-1313-T01-A
Cr CFS-LRef-1313-T02-A
Cr CFS-LRef-1313-T03-A
Cr CFS-LRef-1313-T04-A
Cr CFS-LRef-1313-T05-A
Cr CFS-LRef-1313-T06-A
Cr CFS-LRef-1313-T07-A
Cr CFS-LRef-1313-T08-A
Cr CFS-LRef-1313-T09-A
Cr CFS-LRef-1313-T01-B
Cr CFS-LRef-1313-T02-B
Cr CFS-LRef-1313-T03-B
Cr CFS-LRef-1313-T04-B
Cr CFS-LRef-1313-T05-B
Cr CFS-LRef-1313-T06-B
Cr CFS-LRef-1313-T07-B
Cr CFS-LRef-1313-T08-B
Cr CFS-LRef-1313-T09-B
Cr CFS-LRef-1313-T01-C
Cr CFS-LRef-1313-T02-C
Cr CFS-LRef-1313-T03-C
Cr CFS-LRef-1313-T04-C
Cr CFS-LRef-1313-T05-C
Cr CFS-LRef-1313-T06-C
Cr CFS-LRef-1313-T07-C
Cr CFS-LRef-1313-T08-C
Cr CFS-LRef-1313-T09-C
Cr CFS-LRef-1313-B01-A
Cr CFS-LRef-1313-B02-A
Cr CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.23E+03
1 5.34E+01
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 7.17E+00
1 6.35E+01
1 1.09E+02
1 2.16E+03
1 5.86E+01
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 8.59E+00
1 5.19E+01
1 1.30E+02
1 2.25E+03
1 5.65E+01
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 8.15E+00
1 6.32E+01
1 1.07E+02
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.23E+03 8.5E-01 1.2E+00 3.8E+00
5.34E+01 2.5E+00 1.2E+00 3.8E+00 10 100
6.00E-01 1.1E+03 1.2E+00 3.8E+00
6.00E-01 2.4E+03 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
6.00E-01 1.9E+02 1.2E+00 3.8E+00
7.17E+00 6.8E+00 1.2E+00 3.8E+00
6.35E+01 1.9E+00 1.2E+00 3.8E+00
1.09E+02 9.3E-01 1.2E+00 3.8E+00
2.16E+03 1.9E-01 1.2E+00 3.8E+00
5.86E+01 4.7E-01 1.2E+00 3.8E+00 10 100
6.00E-01 8.5E+02 1.2E+00 3.8E+00
6.00E-01 3.2E+01 1.2E+00 3.8E+00
6.00E-01 1.9E+02 1.2E+00 3.8E+00
6.00E-01 1.7E+01 1.2E+00 3.8E+00
8.59E+00 6.6E+00 1.2E+00 3.8E+00
5.19E+01 3.0E+00 1.2E+00 3.8E+00
1.30E+02 1.5E+00 1.2E+00 3.8E+00
2.25E+03 8.1E-01 1.2E+00 3.8E+00
5.65E+01 1.9E+00 1.2E+00 3.8E+00 10 100
6.00E-01 5.9E+02 1.2E+00 3.8E+00
6.00E-01 1.6E+01 1.2E+00 3.8E+00
6.00E-01 1.0E+01 1.2E+00 3.8E+00
6.00E-01 4.8E+01 1.2E+00 3.8E+00
8.15E+00 1.1E+01 1.2E+00 3.8E+00
6.32E+01 5.0E+00 1.2E+00 3.8E+00
1.07E+02 7.0E-01 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.00E-01 2.9E+02 1.2E+00 3.8E+00
6.00E-01 8.4E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.02E+03 96% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
1.03E+03 97% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.00E+03 95%VUICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-882
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutk
CFS-LRef-1313-T01-A
CFS-LRef-1313-T02-A
CFS-LRef-1313-T03-A
CFS-LRef-1313-T04-A
CFS-LRef-1313-T05-A
CFS-LRef-1313-T06-A
CFS-LRef-1313-T07-A
CFS-LRef-1313-T08-A
CFS-LRef-1313-T09-A
CFS-LRef-1313-T01-B
CFS-LRef-1313-T02-B
CFS-LRef-1313-T03-B
CFS-LRef-1313-T04-B
CFS-LRef-1313-T05-B
CFS-LRef-1313-T06-B
CFS-LRef-1313-T07-B
CFS-LRef-1313-T08-B
CFS-LRef-1313-T09-B
CFS-LRef-1313-T01-C
CFS-LRef-1313-T02-C
CFS-LRef-1313-T03-C
CFS-LRef-1313-T04-C
CFS-LRef-1313-T05-C
CFS-LRef-1313-T06-C
CFS-LRef-1313-T07-C
CFS-LRef-1313-T08-C
CFS-LRef-1313-T09-C
CFS-LRef-1313-B01-A
CFS-LRef-1313-B02-A
CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.81E+03
1 1.66E+03
1 5.60E+02
1 1.14E+02
1 1.99E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.81E+03
1 1.66E+03
1 5.51 E+02
1 1.15E+02
1 2.14E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.81E+03
1 1.71E+03
1 5.64E+02
1 1.04E+02
1 1.83E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.81E+03 8.7E-01 1.8E+00 5.7E+00
1.66E+03 1.4E+00 1.8E+00 5.7E+00 10 100
5.60E+02 9.9E-01 1.8E+00 5.7E+00
1.14E+02 3.9E-01 1.8E+00 5.7E+00
1.99E+00 2.7E+01 1.8E+00 5.7E+00
9.00E-01 2.7E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00
9.00E-01 9.3E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
1.81E+03 9.2E-01 1.8E+00 5.7E+00
1.66E+03 2.5E+00 1.8E+00 5.7E+00 10 100
5.51 E+02 4.7E-01 1.8E+00 5.7E+00
1.15E+02 1.4E+00 1.8E+00 5.7E+00
2.14E+00 5.2E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 7.9E+03 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 4.0E+01 1.8E+00 5.7E+00
1.81E+03 1.4E+00 1.8E+00 5.7E+00
1.71E+03 9.8E-01 1.8E+00 5.7E+00 10 100
5.64E+02 5.7E-01 1.8E+00 5.7E+00
1.04E+02 6.8E-01 1.8E+00 5.7E+00
1.83E+00 4.6E+01 1.8E+00 5.7E+00
9.00E-01 3.3E+01 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 3.8E+01 1.8E+00 5.7E+00
9.00E-01 6.6E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 2.7E+02 1.8E+00 5.7E+00
9.00E-01 4.7E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
2.57E+03 91% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
2.56E+03 90% VU ICP-OES 2/3/1 1 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
2.68E+03 96% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-883
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutk
Cu CFS-LRef-1313-T01-A
Cu CFS-LRef-1313-T02-A
Cu CFS-LRef-1313-T03-A
Cu CFS-LRef-1313-T04-A
Cu CFS-LRef-1313-T05-A
Cu CFS-LRef-1313-T06-A
Cu CFS-LRef-1313-T07-A
Cu CFS-LRef-1313-T08-A
Cu CFS-LRef-1313-T09-A
Cu CFS-LRef-1313-T01-B
Cu CFS-LRef-1313-T02-B
Cu CFS-LRef-1313-T03-B
Cu CFS-LRef-1313-T04-B
Cu CFS-LRef-1313-T05-B
Cu CFS-LRef-1313-T06-B
Cu CFS-LRef-1313-T07-B
Cu CFS-LRef-1313-T08-B
Cu CFS-LRef-1313-T09-B
Cu CFS-LRef-1313-T01-C
Cu CFS-LRef-1313-T02-C
Cu CFS-LRef-1313-T03-C
Cu CFS-LRef-1313-T04-C
Cu CFS-LRef-1313-T05-C
Cu CFS-LRef-1313-T06-C
Cu CFS-LRef-1313-T07-C
Cu CFS-LRef-1313-T08-C
Cu CFS-LRef-1313-T09-C
Cu CFS-LRef-1313-B01-A
Cu CFS-LRef-1313-B02-A
Cu CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.12E+06
1 9.69E+05
1 1.69E+05
1 1.06E+03
1 7.72E+01
1 5.76E+01
1 1.64E+02
1 9.08E+02
1 3.21E+03
1 1.12E+06
1 9.74E+05
1 1.71E+05
1 9.97E+02
1 6.30E+01
1 7.06E+01
1 1.69E+02
1 7.06E+02
1 3.35E+03
1 1.15E+06
1 9.70E+05
1 1.69E+05
1 8.92E+02
1 6.23E+01
1 6.08E+01
1 1.61E+02
1 7.92E+02
1 3.36E+03
1 1.85E+00 U1/2
1 8.46E+00 E
1 5.16E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.12E+06 5.4E-01 3.7E+00 1.2E+01
9.69E+05 3.3E+00 3.7E+00 1.2E+01 10 100
1.69E+05 7.7E-01 3.7E+00 1.2E+01
1.06E+03 1.0E+00 3.7E+00 1.2E+01
7.72E+01 3.8E+00 3.7E+00 1.2E+01
5.76E+01 4.8E+00 3.7E+00 1.2E+01
1.64E+02 4.0E+00 3.7E+00 1.2E+01
9.08E+02 8.6E-01 3.7E+00 1.2E+01
3.21E+03 1.4E+00 3.7E+00 1.2E+01
1.12E+06 8.4E-01 3.7E+00 1.2E+01
9.74E+05 4.8E-01 3.7E+00 1.2E+01 10 100
1.71E+05 6.6E-01 3.7E+00 1.2E+01
9.97E+02 1.5E+00 3.7E+00 1.2E+01
6.30E+01 4.2E-01 3.7E+00 1.2E+01
7.06E+01 1.6E+00 3.7E+00 1.2E+01
1.69E+02 1.6E+00 3.7E+00 1.2E+01
7.06E+02 1.2E+00 3.7E+00 1.2E+01
3.35E+03 1.3E+00 3.7E+00 1.2E+01
1.15E+06 1.7E+00 3.7E+00 1.2E+01
9.70E+05 7.6E-01 3.7E+00 1.2E+01 10 100
1.69E+05 6.0E-01 3.7E+00 1.2E+01
8.92E+02 1.4E+00 3.7E+00 1.2E+01
6.23E+01 6.6E-01 3.7E+00 1.2E+01
6.08E+01 4.4E+00 3.7E+00 1.2E+01
1.61E+02 8.8E-01 3.7E+00 1.2E+01
7.92E+02 4.8E+00 3.7E+00 1.2E+01
3.36E+03 2.4E+00 3.7E+00 1.2E+01
1.85E+00 8.2E+00 3.7E+00 1.2E+01
8.46E+00 7.3E+00 3.7E+00 1.2E+01
5.16E+00 1.1E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
9.70E+05 91% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
9.75E+05 95% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
9.71E+05 92% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-884
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutk
Fe CFS-LRef-1313-T01-A
Fe CFS-LRef-1313-T02-A
Fe CFS-LRef-1313-T03-A
Fe CFS-LRef-1313-T04-A
Fe CFS-LRef-1313-T05-A
Fe CFS-LRef-1313-T06-A
Fe CFS-LRef-1313-T07-A
Fe CFS-LRef-1313-T08-A
Fe CFS-LRef-1313-T09-A
Fe CFS-LRef-1313-T01-B
Fe CFS-LRef-1313-T02-B
Fe CFS-LRef-1313-T03-B
Fe CFS-LRef-1313-T04-B
Fe CFS-LRef-1313-T05-B
Fe CFS-LRef-1313-T06-B
Fe CFS-LRef-1313-T07-B
Fe CFS-LRef-1313-T08-B
Fe CFS-LRef-1313-T09-B
Fe CFS-LRef-1313-T01-C
Fe CFS-LRef-1313-T02-C
Fe CFS-LRef-1313-T03-C
Fe CFS-LRef-1313-T04-C
Fe CFS-LRef-1313-T05-C
Fe CFS-LRef-1313-T06-C
Fe CFS-LRef-1313-T07-C
Fe CFS-LRef-1313-T08-C
Fe CFS-LRef-1313-T09-C
Fe CFS-LRef-1313-B01-A
Fe CFS-LRef-1313-B02-A
Fe CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.71E+05
1 4.36E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.65E+05
1 4.68E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.94E+05
1 4.63E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.71E+05 5.9E-01 2.0E+00 6.4E+00
4.36E+04 1.9E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 4.1E+00 2.0E+00 6.4E+00
1.00E+00 5.2E+00 2.0E+00 6.4E+00
1.00E+00 7.5E+00 2.0E+00 6.4E+00
1.00E+00 8.0E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+00 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
2.65E+05 3.6E+00 2.0E+00 6.4E+00
4.68E+04 1.5E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 9.7E+00 2.0E+00 6.4E+00
1.00E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 4.9E+00 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 5.3E+00 2.0E+00 6.4E+00
2.94E+05 4.7E+00 2.0E+00 6.4E+00
4.63E+04 1.2E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 7.7E+00 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+00 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 7.5E-01 2.0E+00 6.4E+00
1.00E+00 9.3E+00 2.0E+00 6.4E+00
1.00E+00 2.7E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
4.45E+04 93% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
4.78E+04 98% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
4.71E+04 87% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-885
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutk
Pb CFS-LRef-1313-T01-A
Pb CFS-LRef-1313-T02-A
Pb CFS-LRef-1313-T03-A
Pb CFS-LRef-1313-T04-A
Pb CFS-LRef-1313-T05-A
Pb CFS-LRef-1313-T06-A
Pb CFS-LRef-1313-T07-A
Pb CFS-LRef-1313-T08-A
Pb CFS-LRef-1313-T09-A
Pb CFS-LRef-1313-T01-B
Pb CFS-LRef-1313-T02-B
Pb CFS-LRef-1313-T03-B
Pb CFS-LRef-1313-T04-B
Pb CFS-LRef-1313-T05-B
Pb CFS-LRef-1313-T06-B
Pb CFS-LRef-1313-T07-B
Pb CFS-LRef-1313-T08-B
Pb CFS-LRef-1313-T09-B
Pb CFS-LRef-1313-T01-C
Pb CFS-LRef-1313-T02-C
Pb CFS-LRef-1313-T03-C
Pb CFS-LRef-1313-T04-C
Pb CFS-LRef-1313-T05-C
Pb CFS-LRef-1313-T06-C
Pb CFS-LRef-1313-T07-C
Pb CFS-LRef-1313-T08-C
Pb CFS-LRef-1313-T09-C
Pb CFS-LRef-1313-B01-A
Pb CFS-LRef-1313-B02-A
Pb CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 8.64E+03
1 6.09E+03
1 5.38E+03
1 1.13E+03
1 1.24E+02
1 1.06E+02
1 7.23E+02
1 1.02E+04
1 8.04E+03
1 8.68E+03
1 6.07E+03
1 6.27E+03
1 1.16E+03
1 1.30E+02
1 1.00E+02
1 7.18E+02
1 1.03E+04
1 8.02E+03
1 8.77E+03
1 6.06E+03
1 6.01 E+03
1 1.10E+03
1 1.21E+02
1 1.05E+02
1 6.42E+02
1 1.05E+04
1 7.88E+03
1 3.40E+00 U1/2
1 1.53E+01 E
1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.64E+03 3.5E-01 6.8E+00 2.2E+01
6.09E+03 2.3E+00 6.8E+00 2.2E+01 10 100
5.38E+03 9.3E-01 6.8E+00 2.2E+01
1.13E+03 1.1E+00 6.8E+00 2.2E+01
1.24E+02 3.5E+00 6.8E+00 2.2E+01
1.06E+02 1.4E+00 6.8E+00 2.2E+01
7.23E+02 4.7E+00 6.8E+00 2.2E+01
1.02E+04 1.6E+00 6.8E+00 2.2E+01
8.04E+03 8.0E-01 6.8E+00 2.2E+01
8.68E+03 1.3E-01 6.8E+00 2.2E+01
6.07E+03 1.6E+00 6.8E+00 2.2E+01 10 100
6.27E+03 1.0E+00 6.8E+00 2.2E+01
1.16E+03 4.3E-01 6.8E+00 2.2E+01
1.30E+02 1.6E+00 6.8E+00 2.2E+01
1.00E+02 4.5E+00 6.8E+00 2.2E+01
7.18E+02 6.9E-01 6.8E+00 2.2E+01
1.03E+04 1.1E+00 6.8E+00 2.2E+01
8.02E+03 2.3E+00 6.8E+00 2.2E+01
8.77E+03 5.4E-01 6.8E+00 2.2E+01
6.06E+03 1.1E+00 6.8E+00 2.2E+01 10 100
6.01 E+03 9.9E-01 6.8E+00 2.2E+01
1.10E+03 8.0E-02 6.8E+00 2.2E+01
1.21E+02 3.9E+00 6.8E+00 2.2E+01
1.05E+02 5.7E+00 6.8E+00 2.2E+01
6.42E+02 1.1E+00 6.8E+00 2.2E+01
1.05E+04 5.0E+00 6.8E+00 2.2E+01
7.88E+03 2.0E+00 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01
1.53E+01 1.8E+01 6.8E+00 2.2E+01
3.40E+00 2.7E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
6.96E+03 86% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
7.00E+03 93% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
6.91E+03 85% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-886
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutk
Li CFS-LRef-1313-T01-A
Li CFS-LRef-1313-T02-A
Li CFS-LRef-1313-T03-A
Li CFS-LRef-1313-T04-A
Li CFS-LRef-1313-T05-A
Li CFS-LRef-1313-T06-A
Li CFS-LRef-1313-T07-A
Li CFS-LRef-1313-T08-A
Li CFS-LRef-1313-T09-A
Li CFS-LRef-1313-T01-B
Li CFS-LRef-1313-T02-B
Li CFS-LRef-1313-T03-B
Li CFS-LRef-1313-T04-B
Li CFS-LRef-1313-T05-B
Li CFS-LRef-1313-T06-B
Li CFS-LRef-1313-T07-B
Li CFS-LRef-1313-T08-B
Li CFS-LRef-1313-T09-B
Li CFS-LRef-1313-T01-C
Li CFS-LRef-1313-T02-C
Li CFS-LRef-1313-T03-C
Li CFS-LRef-1313-T04-C
Li CFS-LRef-1313-T05-C
Li CFS-LRef-1313-T06-C
Li CFS-LRef-1313-T07-C
Li CFS-LRef-1313-T08-C
Li CFS-LRef-1313-T09-C
Li CFS-LRef-1313-B01-A
Li CFS-LRef-1313-B02-A
Li CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.00E+01
1 1.39E+01
1 8.29E+00
1 1.19E+01
1 1.10E+01
1 9.38E+00
1 1.32E+01
1 1.20E+01
1 1.30E+01
1 3.61 E+01
1 1.38E+01
1 8.55E+00
1 1.06E+01
1 1.19E+01
1 1.17E+01
1 1.14E+01
1 1.22E+01
1 1.32E+01
1 3.59E+01
1 8.95E+00
1 9.79E+00
1 1.14E+01
1 1.08E+01
1 1.10E+01
1 1.23E+01
1 1.27E+01
1 1.38E+01
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.00E+01 7.5E+00 1.9E+00 6.0E+00
1.39E+01 2.9E+01 1.9E+00 6.0E+00 10 100
8.29E+00 5.7E+00 1.9E+00 6.0E+00
1.19E+01 1.5E+01 1.9E+00 6.0E+00
1.10E+01 4.2E+00 1.9E+00 6.0E+00
9.38E+00 3.0E+00 1.9E+00 6.0E+00
1.32E+01 6.9E+00 1.9E+00 6.0E+00
1.20E+01 5.7E+00 1.9E+00 6.0E+00
1.30E+01 2.5E+00 1.9E+00 6.0E+00
3.61 E+01 1.4E+01 1.9E+00 6.0E+00
1.38E+01 1.0E+01 1.9E+00 6.0E+00 10 100
8.55E+00 1.2E+01 1.9E+00 6.0E+00
1.06E+01 1.7E+01 1.9E+00 6.0E+00
1.19E+01 2.8E+00 1.9E+00 6.0E+00
1.17E+01 2.7E+00 1.9E+00 6.0E+00
1.14E+01 6.0E+00 1.9E+00 6.0E+00
1.22E+01 1.9E+00 1.9E+00 6.0E+00
1.32E+01 4.0E+00 1.9E+00 6.0E+00
3.59E+01 4.3E+00 1.9E+00 6.0E+00
8.95E+00 1.1 E+01 1.9E+00 6.0E+00 10 100
9.79E+00 1.6E+01 1.9E+00 6.0E+00
1.14E+01 7.5E+00 1.9E+00 6.0E+00
1.08E+01 1.4E+00 1.9E+00 6.0E+00
1.10E+01 3.6E+00 1.9E+00 6.0E+00
1.23E+01 6.5E+00 1.9E+00 6.0E+00
1.27E+01 3.4E+00 1.9E+00 6.0E+00
1.38E+01 5.5E+00 1.9E+00 6.0E+00
9.50E-01 2.1 E+01 1.9E+00 6.0E+00
9.50E-01 8.0E+00 1.9E+00 6.0E+00
9.50E-01 2.7E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
8.80E+02 87% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
8.73E+02 86% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
8.61E+02 85% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-887
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutk
Mn CFS-LRef-1313-T01-A
Mn CFS-LRef-1313-T02-A
Mn CFS-LRef-1313-T03-A
Mn CFS-LRef-1313-T04-A
Mn CFS-LRef-1313-T05-A
Mn CFS-LRef-1313-T06-A
Mn CFS-LRef-1313-T07-A
Mn CFS-LRef-1313-T08-A
Mn CFS-LRef-1313-T09-A
Mn CFS-LRef-1313-T01-B
Mn CFS-LRef-1313-T02-B
Mn CFS-LRef-1313-T03-B
Mn CFS-LRef-1313-T04-B
Mn CFS-LRef-1313-T05-B
Mn CFS-LRef-1313-T06-B
Mn CFS-LRef-1313-T07-B
Mn CFS-LRef-1313-T08-B
Mn CFS-LRef-1313-T09-B
Mn CFS-LRef-1313-T01-C
Mn CFS-LRef-1313-T02-C
Mn CFS-LRef-1313-T03-C
Mn CFS-LRef-1313-T04-C
Mn CFS-LRef-1313-T05-C
Mn CFS-LRef-1313-T06-C
Mn CFS-LRef-1313-T07-C
Mn CFS-LRef-1313-T08-C
Mn CFS-LRef-1313-T09-C
Mn CFS-LRef-1313-B01-A
Mn CFS-LRef-1313-B02-A
Mn CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.58E+04
1 2.46E+04
1 6.37E+03
1 1.82E+03
1 2.93E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.64E+04
1 2.52E+04
1 6.21E+03
1 1.91E+03
1 2.29E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.69E+04
1 2.53E+04
1 6.32E+03
1 1.76E+03
1 2.64E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.58E+04 1.3E+00 2.0E+00 6.4E+00
2.46E+04 1.4E+00 2.0E+00 6.4E+00 10 100
6.37E+03 7.8E-01 2.0E+00 6.4E+00
1.82E+03 1.0E+00 2.0E+00 6.4E+00
2.93E+01 3.7E-01 2.0E+00 6.4E+00
1.00E+00 1.4E-01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
3.64E+04 1.1E+00 2.0E+00 6.4E+00
2.52E+04 1.5E+00 2.0E+00 6.4E+00 10 100
6.21 E+03 6.3E-01 2.0E+00 6.4E+00
1.91E+03 6.7E-01 2.0E+00 6.4E+00
2.29E+01 4.6E-01 2.0E+00 6.4E+00
1.00E+00 4.3E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 9.6E+00 2.0E+00 6.4E+00
1.00E+00 5.7E+01 2.0E+00 6.4E+00
3.69E+04 2.8E-01 2.0E+00 6.4E+00
2.53E+04 1.7E+00 2.0E+00 6.4E+00 10 100
6.32E+03 2.7E-01 2.0E+00 6.4E+00
1.76E+03 7.2E-01 2.0E+00 6.4E+00
2.64E+01 1.1E+00 2.0E+00 6.4E+00
1.00E+00 3.6E+00 2.0E+00 6.4E+00
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 4.9E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 6.8E+01 2.0E+00 6.4E+00
1.00E+00 7.0E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
2.55E+04 93% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
2.61E+04 93% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
2.63E+04 97%VUICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          I-
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutk
Mg CFS-LRef-1313-T01-A
Mg CFS-LRef-1313-T02-A
Mg CFS-LRef-1313-T03-A
Mg CFS-LRef-1313-T04-A
Mg CFS-LRef-1313-T05-A
Mg CFS-LRef-1313-T06-A
Mg CFS-LRef-1313-T07-A
Mg CFS-LRef-1313-T08-A
Mg CFS-LRef-1313-T09-A
Mg CFS-LRef-1313-T01-B
Mg CFS-LRef-1313-T02-B
Mg CFS-LRef-1313-T03-B
Mg CFS-LRef-1313-T04-B
Mg CFS-LRef-1313-T05-B
Mg CFS-LRef-1313-T06-B
Mg CFS-LRef-1313-T07-B
Mg CFS-LRef-1313-T08-B
Mg CFS-LRef-1313-T09-B
Mg CFS-LRef-1313-T01-C
Mg CFS-LRef-1313-T02-C
Mg CFS-LRef-1313-T03-C
Mg CFS-LRef-1313-T04-C
Mg CFS-LRef-1313-T05-C
Mg CFS-LRef-1313-T06-C
Mg CFS-LRef-1313-T07-C
Mg CFS-LRef-1313-T08-C
Mg CFS-LRef-1313-T09-C
Mg CFS-LRef-1313-B01-A
Mg CFS-LRef-1313-B02-A
Mg CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.39E+05
1 1.44E+05
1 7.52E+04
1 6.26E+04
1 5.77E+04
1 2.84E+04
1 6.53E+02
1 4.53E+01
1 2.51 E+01
1 2.34E+05
1 1.51E+05
1 7.63E+04
1 6.49E+04
1 5.88E+04
1 3.10E+04
1 6.43E+02
1 3.77E+01
1 1.58E+01
1 2.38E+05
1 1.60E+05
1 7.59E+04
1 6.36E+04
1 5.80E+04
1 2.97E+04
1 6.66E+02
1 2.96E+01
1 2.11E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.39E+05 1.8E+00 1.0E+00 3.2E+00
1.44E+05 2.4E+00 1.0E+00 3.2E+00 1000 100
7.52E+04 1.4E+00 1.0E+00 3.2E+00
6.26E+04 3.0E-01 1.0E+00 3.2E+00
5.77E+04 1.6E+00 1.0E+00 3.2E+00
2.84E+04 1.5E-01 1.0E+00 3.2E+00
6.53E+02 5.0E+00 1.0E+00 3.2E+00
4.53E+01 1.8E+01 1.0E+00 3.2E+00
2.51 E+01 3.4E+01 1.0E+00 3.2E+00
2.34E+05 5.4E-01 1.0E+00 3.2E+00
1.51E+05 1.3E+00 1.0E+00 3.2E+00 1000 100
7.63E+04 4.3E-01 1.0E+00 3.2E+00
6.49E+04 8.1E-01 1.0E+00 3.2E+00
5.88E+04 2.9E-01 1.0E+00 3.2E+00
3.10E+04 1.7E+00 1.0E+00 3.2E+00
6.43E+02 1.1E+00 1.0E+00 3.2E+00
3.77E+01 1.7E+01 1.0E+00 3.2E+00
1.58E+01 9.4E+01 1.0E+00 3.2E+00
2.38E+05 1.5E+00 1.0E+00 3.2E+00
1.60E+05 3.7E-01 1.0E+00 3.2E+00 1000 100
7.59E+04 2.7E-01 1.0E+00 3.2E+00
6.36E+04 1.4E+00 1.0E+00 3.2E+00
5.80E+04 1.2E+00 1.0E+00 3.2E+00
2.97E+04 9.8E-01 1.0E+00 3.2E+00
6.66E+02 8.1E-01 1.0E+00 3.2E+00
2.96E+01 1.8E+01 1.0E+00 3.2E+00
2.11E+01 2.0E+01 1.0E+00 3.2E+00
5.00E-01 1.0E+03 1.0E+00 3.2E+00
5.00E-01 2.2E+02 1.0E+00 3.2E+00
5.00E-01 2.7E+03 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.45E+05 87% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
1.52E+05 93% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.61E+05 88% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-889
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutk
Mo CFS-LRef-1313-T01-A
Mo CFS-LRef-1313-T02-A
Mo CFS-LRef-1313-T03-A
Mo CFS-LRef-1313-T04-A
Mo CFS-LRef-1313-T05-A
Mo CFS-LRef-1313-T06-A
Mo CFS-LRef-1313-T07-A
Mo CFS-LRef-1313-T08-A
Mo CFS-LRef-1313-T09-A
Mo CFS-LRef-1313-T01-B
Mo CFS-LRef-1313-T02-B
Mo CFS-LRef-1313-T03-B
Mo CFS-LRef-1313-T04-B
Mo CFS-LRef-1313-T05-B
Mo CFS-LRef-1313-T06-B
Mo CFS-LRef-1313-T07-B
Mo CFS-LRef-1313-T08-B
Mo CFS-LRef-1313-T09-B
Mo CFS-LRef-1313-T01-C
Mo CFS-LRef-1313-T02-C
Mo CFS-LRef-1313-T03-C
Mo CFS-LRef-1313-T04-C
Mo CFS-LRef-1313-T05-C
Mo CFS-LRef-1313-T06-C
Mo CFS-LRef-1313-T07-C
Mo CFS-LRef-1313-T08-C
Mo CFS-LRef-1313-T09-C
Mo CFS-LRef-1313-B01-A
Mo CFS-LRef-1313-B02-A
Mo CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.22E+02
1 1.70E+01
1 8.34E+00
1 1.11E+01
1 1.19E+02
1 4.00E+02
1 1.06E+03
1 1.64E+03
1 1.46E+03
1 1.25E+02
1 1.53E+01
1 1.20E+01
1 9.08E+00
1 1.45E+02
1 4.27E+02
1 1.13E+03
1 1.72E+03
1 1.56E+03
1 1.35E+02
1 2.09E+01
1 9.37E+00
1 1.02E+01
1 1.33E+02
1 4.23E+02
1 1.10E+03
1 1.78E+03
1 1.57E+03
1 3.20E+00 E
1 2.29E+00 E
1 2.18E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.22E+02 9.4E+00 1.2E+00 3.8E+00
1.70E+01 7.6E+01 1.2E+00 3.8E+00 10 100
8.34E+00 2.0E+01 1.2E+00 3.8E+00
1.11E+01 1.7E+01 1.2E+00 3.8E+00
1.19E+02 1.9E+00 1.2E+00 3.8E+00
4.00E+02 3.9E-01 1.2E+00 3.8E+00
1.06E+03 5.8E+00 1.2E+00 3.8E+00
1.64E+03 1.1E+00 1.2E+00 3.8E+00
1.46E+03 2.1E-01 1.2E+00 3.8E+00
1.25E+02 2.4E+00 1.2E+00 3.8E+00
1.53E+01 6.3E+01 1.2E+00 3.8E+00 10 100
1.20E+01 1.7E+01 1.2E+00 3.8E+00
9.08E+00 7.1E+00 1.2E+00 3.8E+00
1.45E+02 1.4E+00 1.2E+00 3.8E+00
4.27E+02 1.0E+00 1.2E+00 3.8E+00
1.13E+03 3.8E-01 1.2E+00 3.8E+00
1.72E+03 1.1E+00 1.2E+00 3.8E+00
1.56E+03 8.8E-01 1.2E+00 3.8E+00
1.35E+02 1.5E+01 1.2E+00 3.8E+00
2.09E+01 2.6E+01 1.2E+00 3.8E+00 10 100
9.37E+00 4.8E+00 1.2E+00 3.8E+00
1.02E+01 3.2E+00 1.2E+00 3.8E+00
1.33E+02 1.6E+00 1.2E+00 3.8E+00
4.23E+02 6.6E-01 1.2E+00 3.8E+00
1.10E+03 1.2E+00 1.2E+00 3.8E+00
1.78E+03 4.5E+00 1.2E+00 3.8E+00
1.57E+03 1.7E+00 1.2E+00 3.8E+00
3.20E+00 5.1E+00 1.2E+00 3.8E+00
2.29E+00 3.6E+01 1.2E+00 3.8E+00
2.18E+00 2.7E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.02E+03 100% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
1.03E+03 101% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
9.88E+02 97% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-890
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutk
Ni CFS-LRef-1313-T01-A
Ni CFS-LRef-1313-T02-A
Ni CFS-LRef-1313-T03-A
Ni CFS-LRef-1313-T04-A
Ni CFS-LRef-1313-T05-A
Ni CFS-LRef-1313-T06-A
Ni CFS-LRef-1313-T07-A
Ni CFS-LRef-1313-T08-A
Ni CFS-LRef-1313-T09-A
Ni CFS-LRef-1313-T01-B
Ni CFS-LRef-1313-T02-B
Ni CFS-LRef-1313-T03-B
Ni CFS-LRef-1313-T04-B
Ni CFS-LRef-1313-T05-B
Ni CFS-LRef-1313-T06-B
Ni CFS-LRef-1313-T07-B
Ni CFS-LRef-1313-T08-B
Ni CFS-LRef-1313-T09-B
Ni CFS-LRef-1313-T01-C
Ni CFS-LRef-1313-T02-C
Ni CFS-LRef-1313-T03-C
Ni CFS-LRef-1313-T04-C
Ni CFS-LRef-1313-T05-C
Ni CFS-LRef-1313-T06-C
Ni CFS-LRef-1313-T07-C
Ni CFS-LRef-1313-T08-C
Ni CFS-LRef-1313-T09-C
Ni CFS-LRef-1313-B01-A
Ni CFS-LRef-1313-B02-A
Ni CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.80E+03
1 6.42E+03
1 2.09E+03
1 2.72E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 6.95E+03
1 6.50E+03
1 2.08E+03
1 2.65E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 6.90E+03
1 6.68E+03
1 2.09E+03
1 2.41 E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.80E+03 1.1E+00 1.8E+00 5.7E+00
6.42E+03 1.9E+00 1.8E+00 5.7E+00 10 100
2.09E+03 1.2E+00 1.8E+00 5.7E+00
2.72E+02 2.5E-01 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 2.5E+02 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 1.1 E+02 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00
6.95E+03 1.2E+00 1.8E+00 5.7E+00
6.50E+03 1.1E+00 1.8E+00 5.7E+00 10 100
2.08E+03 4.3E-01 1.8E+00 5.7E+00
2.65E+02 4.0E-01 1.8E+00 5.7E+00
9.00E-01 4.1E+01 1.8E+00 5.7E+00
9.00E-01 4.4E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 5.9E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+03 1.8E+00 5.7E+00
6.90E+03 4.9E-01 1.8E+00 5.7E+00
6.68E+03 9.5E-01 1.8E+00 5.7E+00 10 100
2.09E+03 9.6E-02 1.8E+00 5.7E+00
2.41 E+02 6.7E-01 1.8E+00 5.7E+00
9.00E-01 5.0E+02 1.8E+00 5.7E+00
9.00E-01 7.8E+01 1.8E+00 5.7E+00
9.00E-01 5.9E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+03 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 2.4E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+01 1.8E+00 5.7E+00
9.00E-01 3.2E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
7.37E+03 95% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
7.42E+03 91% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
7.62E+03 94% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-891
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutk
P CFS-LRef-1313-T01-A
P CFS-LRef-1313-T02-A
P CFS-LRef-1313-T03-A
P CFS-LRef-1313-T04-A
P CFS-LRef-1313-T05-A
P CFS-LRef-1313-T06-A
P CFS-LRef-1313-T07-A
P CFS-LRef-1313-T08-A
P CFS-LRef-1313-T09-A
P CFS-LRef-1313-T01-B
P CFS-LRef-1313-T02-B
P CFS-LRef-1313-T03-B
P CFS-LRef-1313-T04-B
P CFS-LRef-1313-T05-B
P CFS-LRef-1313-T06-B
P CFS-LRef-1313-T07-B
P CFS-LRef-1313-T08-B
P CFS-LRef-1313-T09-B
P CFS-LRef-1313-T01-C
P CFS-LRef-1313-T02-C
P CFS-LRef-1313-T03-C
P CFS-LRef-1313-T04-C
P CFS-LRef-1313-T05-C
P CFS-LRef-1313-T06-C
P CFS-LRef-1313-T07-C
P CFS-LRef-1313-T08-C
P CFS-LRef-1313-T09-C
P CFS-LRef-1313-B01-A
P CFS-LRef-1313-B02-A
P CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.13E+03
1 2.95E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 5.72E+00 E
1 8.37E+00 E
1 4.74E+01
1 5.30E+01
1 6.55E+01
1 3.21E+03
1 2.81E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 4.44E+00 E
1 9.38E+00 E
1 4.52E+01
1 6.68E+01
1 6.54E+01
1 3.52E+03
1 2.53E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 6.94E+00 E
1 1.23E+01
1 5.81 E+01
1 6.75E+01
1 5.48E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.13E+03 2.1E-01 3.7E+00 1.2E+01
2.95E+01 1.3E+02 3.7E+00 1.2E+01 1000 100
1.85E+00 2.9E+02 3.7E+00 1.2E+01
1.85E+00 6.7E+01 3.7E+00 1.2E+01
5.72E+00 1.1E+02 3.7E+00 1.2E+01
8.37E+00 6.2E+02 3.7E+00 1.2E+01
4.74E+01 4.6E+01 3.7E+00 1.2E+01
5.30E+01 1.0E+01 3.7E+00 1.2E+01
6.55E+01 1.0E+01 3.7E+00 1.2E+01
3.21E+03 6.6E-01 3.7E+00 1.2E+01
2.81E+01 1.1E+02 3.7E+00 1.2E+01 1000 100
1.85E+00 5.5E+01 3.7E+00 1.2E+01
1.85E+00 1.6E+02 3.7E+00 1.2E+01
4.44E+00 2.4E+02 3.7E+00 1.2E+01
9.38E+00 8.4E+02 3.7E+00 1.2E+01
4.52E+01 2.0E+01 3.7E+00 1.2E+01
6.68E+01 1.1 E+01 3.7E+00 1.2E+01
6.54E+01 6.3E+01 3.7E+00 1.2E+01
3.52E+03 9.7E-01 3.7E+00 1.2E+01
2.53E+01 2.8E+01 3.7E+00 1.2E+01 1000 100
1.85E+00 2.7E+02 3.7E+00 1.2E+01
1.85E+00 1.1E+03 3.7E+00 1.2E+01
6.94E+00 1.5E+02 3.7E+00 1.2E+01
1.23E+01 1.0E+02 3.7E+00 1.2E+01
5.81E+01 2.2E+01 3.7E+00 1.2E+01
6.75E+01 1.5E+01 3.7E+00 1.2E+01
5.48E+01 1.8E+01 3.7E+00 1.2E+01
1.85E+00 5.5E+02 3.7E+00 1.2E+01
1.85E+00 1.0E+02 3.7E+00 1.2E+01
1.85E+00 4.3E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.04E+03 101% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
1.05E+03 102% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.04E+03 101% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-892
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-LRef-1313-T01-A
CFS-LRef-1313-T02-A
CFS-LRef-1313-T03-A
CFS-LRef-1313-T04-A
CFS-LRef-1313-T05-A
CFS-LRef-1313-T06-A
CFS-LRef-1313-T07-A
CFS-LRef-1313-T08-A
CFS-LRef-1313-T09-A
CFS-LRef-1313-T01-B
CFS-LRef-1313-T02-B
CFS-LRef-1313-T03-B
CFS-LRef-1313-T04-B
CFS-LRef-1313-T05-B
CFS-LRef-1313-T06-B
CFS-LRef-1313-T07-B
CFS-LRef-1313-T08-B
CFS-LRef-1313-T09-B
CFS-LRef-1313-T01-C
CFS-LRef-1313-T02-C
CFS-LRef-1313-T03-C
CFS-LRef-1313-T04-C
CFS-LRef-1313-T05-C
CFS-LRef-1313-T06-C
CFS-LRef-1313-T07-C
CFS-LRef-1313-T08-C
CFS-LRef-1313-T09-C
CFS-LRef-1313-B01-A
CFS-LRef-1313-B02-A
CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.64E+04
1 1.93E+04
1 1.19E+04
1 9.58E+03
1 2.51 E+05
1 2.78E+05
1 5.59E+05
1 2.54E+06
1 2.56E+06
1 2.55E+04
1 1.88E+04
1 1.24E+04
1 1.01E+04
1 2.61 E+05
1 3.38E+05
1 5.65E+05
1 2.48E+06
1 2.54E+06
1 2.61E+04
1 1.88E+04
1 1.23E+04
1 9.76E+03
1 2.51 E+05
1 3.38E+05
1 5.62E+05
1 2.58E+06
1 2.67E+06
1 2.78E+01
1 2.77E+00 E
1 2.51 E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.64E+04 3.1E-01 1.6E+00 5.1E+00
1.93E+04 2.7E+00 1.6E+00 5.1E+00 1000 100
1.19E+04 1.0E+00 1.6E+00 5.1E+00
9.58E+03 9.4E-01 1.6E+00 5.1E+00
2.51 E+05 1.2E+00 1.6E+00 5.1E+00
2.78E+05 7.2E-01 1.6E+00 5.1E+00
5.59E+05 4.8E+00 1.6E+00 5.1E+00
2.54E+06 1.4E+00 1.6E+00 5.1E+00
2.56E+06 2.0E+00 1.6E+00 5.1E+00
2.55E+04 1.9E-01 1.6E+00 5.1E+00
1.88E+04 1.3E+00 1.6E+00 5.1E+00 1000 100
1.24E+04 1.6E-01 1.6E+00 5.1E+00
1.01E+04 3.4E-01 1.6E+00 5.1E+00
2.61 E+05 4.9E-01 1.6E+00 5.1E+00
3.38E+05 9.3E-01 1.6E+00 5.1E+00
5.65E+05 2.1E+00 1.6E+00 5.1E+00
2.48E+06 6.9E-01 1.6E+00 5.1E+00
2.54E+06 1.8E+00 1.6E+00 5.1E+00
2.61 E+04 8.1E-01 1.6E+00 5.1E+00
1.88E+04 9.7E-01 1.6E+00 5.1E+00 1000 100
1.23E+04 3.9E-01 1.6E+00 5.1E+00
9.76E+03 9.8E-01 1.6E+00 5.1E+00
2.51 E+05 9.2E-01 1.6E+00 5.1E+00
3.38E+05 1.2E+00 1.6E+00 5.1E+00
5.62E+05 3.1E+00 1.6E+00 5.1E+00
2.58E+06 1.6E+00 1.6E+00 5.1E+00
2.67E+06 1.1E+00 1.6E+00 5.1E+00
2.78E+01 1.6E+01 1.6E+00 5.1E+00
2.77E+00 7.4E+01 1.6E+00 5.1E+00
2.51 E+06 9.8E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
2.02E+04 92% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
1.97E+04 89% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.98E+04 99% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-893
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-LRef-1313-T01-A
CFS-LRef-1313-T02-A
CFS-LRef-1313-T03-A
CFS-LRef-1313-T04-A
CFS-LRef-1313-T05-A
CFS-LRef-1313-T06-A
CFS-LRef-1313-T07-A
CFS-LRef-1313-T08-A
CFS-LRef-1313-T09-A
CFS-LRef-1313-T01-B
CFS-LRef-1313-T02-B
CFS-LRef-1313-T03-B
CFS-LRef-1313-T04-B
CFS-LRef-1313-T05-B
CFS-LRef-1313-T06-B
CFS-LRef-1313-T07-B
CFS-LRef-1313-T08-B
CFS-LRef-1313-T09-B
CFS-LRef-1313-T01-C
CFS-LRef-1313-T02-C
CFS-LRef-1313-T03-C
CFS-LRef-1313-T04-C
CFS-LRef-1313-T05-C
CFS-LRef-1313-T06-C
CFS-LRef-1313-T07-C
CFS-LRef-1313-T08-C
CFS-LRef-1313-T09-C
CFS-LRef-1313-B01-A
CFS-LRef-1313-B02-A
CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.92E+02
1 2.57E+02
1 1.22E+02
1 7.49E+01
1 9.69E+01
1 1.15E+02
1 5.78E+02
1 4.12E+02
1 3.07E+02
1 4.93E+02
1 2.40E+02
1 1.21E+02
1 7.10E+01
1 1.06E+02
1 1.47E+02
1 6.21 E+02
1 5.28E+02
1 3.30E+02
1 5.58E+02
1 2.40E+02
1 1.02E+02
1 8.70E+01
1 1.05E+02
1 1.51 E+02
1 5.90E+02
1 4.37E+02
1 3.09E+02
1 7.50E+00 U1/2
1 7.50E+00 U1/2
1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.92E+02 2.8E+00 1.5E+01 4.8E+01
2.57E+02 7.6E+00 1.5E+01 4.8E+01 10 100
1.22E+02 7.8E+00 1.5E+01 4.8E+01
7.49E+01 1.4E+01 1.5E+01 4.8E+01
9.69E+01 1.6E+01 1.5E+01 4.8E+01
1.15E+02 1.2E+01 1.5E+01 4.8E+01
5.78E+02 2.2E+00 1.5E+01 4.8E+01
4.12E+02 3.1E+00 1.5E+01 4.8E+01
3.07E+02 2.3E+00 1.5E+01 4.8E+01
4.93E+02 1.1E+00 1.5E+01 4.8E+01
2.40E+02 6.7E+00 1.5E+01 4.8E+01 10 100
1.21 E+02 1.9E+00 1.5E+01 4.8E+01
7.10E+01 1.9E+01 1.5E+01 4.8E+01
1.06E+02 9.8E+00 1.5E+01 4.8E+01
1.47E+02 7.1E+00 1.5E+01 4.8E+01
6.21 E+02 7.3E-01 1.5E+01 4.8E+01
5.28E+02 1.3E+00 1.5E+01 4.8E+01
3.30E+02 2.8E+00 1.5E+01 4.8E+01
5.58E+02 1.4E+00 1.5E+01 4.8E+01
2.40E+02 1.2E+01 1.5E+01 4.8E+01 10 100
1.02E+02 9.2E+00 1.5E+01 4.8E+01
8.70E+01 1.1E+00 1.5E+01 4.8E+01
1.05E+02 8.0E+00 1.5E+01 4.8E+01
1.51 E+02 6.5E+00 1.5E+01 4.8E+01
5.90E+02 1.5E-01 1.5E+01 4.8E+01
4.37E+02 4.9E+00 1.5E+01 4.8E+01
3.09E+02 1.2E+00 1.5E+01 4.8E+01
7.50E+00 3.0E+02 1.5E+01 4.8E+01
7.50E+00 6.8E+01 1.5E+01 4.8E+01
7.50E+00 1.4E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.24E+03 98% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
1.24E+03 100% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.22E+03 98% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-894
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutk
Si CFS-LRef-1313-T01-A
Si CFS-LRef-1313-T02-A
Si CFS-LRef-1313-T03-A
Si CFS-LRef-1313-T04-A
Si CFS-LRef-1313-T05-A
Si CFS-LRef-1313-T06-A
Si CFS-LRef-1313-T07-A
Si CFS-LRef-1313-T08-A
Si CFS-LRef-1313-T09-A
Si CFS-LRef-1313-T01-B
Si CFS-LRef-1313-T02-B
Si CFS-LRef-1313-T03-B
Si CFS-LRef-1313-T04-B
Si CFS-LRef-1313-T05-B
Si CFS-LRef-1313-T06-B
Si CFS-LRef-1313-T07-B
Si CFS-LRef-1313-T08-B
Si CFS-LRef-1313-T09-B
Si CFS-LRef-1313-T01-C
Si CFS-LRef-1313-T02-C
Si CFS-LRef-1313-T03-C
Si CFS-LRef-1313-T04-C
Si CFS-LRef-1313-T05-C
Si CFS-LRef-1313-T06-C
Si CFS-LRef-1313-T07-C
Si CFS-LRef-1313-T08-C
Si CFS-LRef-1313-T09-C
Si CFS-LRef-1313-B01-A
Si CFS-LRef-1313-B02-A
Si CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.60E+05
1 7.90E+04
1 2.54E+04
1 4.25E+03
1 1.02E+03
1 8.00E+02
1 5.63E+02
1 3.00E+02
1 2.23E+02
1 1.55E+05
1 7.78E+04
1 2.56E+04
1 4.45E+03
1 9.93E+02
1 5.96E+02
1 5.27E+02
1 2.07E+02
1 2.34E+02
1 1.58E+05
1 7.81 E+04
1 2.57E+04
1 4.15E+03
1 1.04E+03
1 6.01 E+02
1 5.36E+02
1 2.64E+02
1 2.45E+02
1 5.50E-01 U1/2
1 2.16E+01
1 1.00E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.60E+05 3.4E-01 1.1E+00 3.5E+00
7.90E+04 1.5E+00 1.1E+00 3.5E+00 1000 100
2.54E+04 9.6E-01 1.1E+00 3.5E+00
4.25E+03 7.7E-01 1.1E+00 3.5E+00
1.02E+03 1.0E+00 1.1E+00 3.5E+00
8.00E+02 2.0E-01 1.1E+00 3.5E+00
5.63E+02 4.8E+00 1.1E+00 3.5E+00
3.00E+02 2.3E+00 1.1E+00 3.5E+00
2.23E+02 2.1E+00 1.1E+00 3.5E+00
1.55E+05 7.9E-01 1.1E+00 3.5E+00
7.78E+04 8.3E-01 1.1E+00 3.5E+00 1000 100
2.56E+04 5.4E-01 1.1E+00 3.5E+00
4.45E+03 5.0E-01 1.1E+00 3.5E+00
9.93E+02 4.9E-01 1.1E+00 3.5E+00
5.96E+02 1.8E+00 1.1E+00 3.5E+00
5.27E+02 1.3E+00 1.1E+00 3.5E+00
2.07E+02 1.2E+00 1.1E+00 3.5E+00
2.34E+02 1.6E+00 1.1E+00 3.5E+00
1.58E+05 4.6E-01 1.1E+00 3.5E+00
7.81E+04 5.4E-02 1.1E+00 3.5E+00 1000 100
2.57E+04 1.0E+00 1.1E+00 3.5E+00
4.15E+03 6.0E-01 1.1E+00 3.5E+00
1.04E+03 8.5E-01 1.1E+00 3.5E+00
6.01E+02 4.5E-01 1.1E+00 3.5E+00
5.36E+02 8.7E-01 1.1E+00 3.5E+00
2.64E+02 5.8E+00 1.1E+00 3.5E+00
2.45E+02 2.5E+00 1.1E+00 3.5E+00
5.50E-01 1.7E+03 1.1E+00 3.5E+00
2.16E+01 4.0E+00 1.1E+00 3.5E+00
1.00E+02 3.2E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
8.00E+04 91% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
7.87E+04 90% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
7.90E+04 88% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-895
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na CFS-LRef-1313-T01-A
Na CFS-LRef-1313-T02-A
Na CFS-LRef-1313-T03-A
Na CFS-LRef-1313-T04-A
Na CFS-LRef-1313-T05-A
Na CFS-LRef-1313-T06-A
Na CFS-LRef-1313-T07-A
Na CFS-LRef-1313-T08-A
Na CFS-LRef-1313-T09-A
Na CFS-LRef-1313-T01-B
Na CFS-LRef-1313-T02-B
Na CFS-LRef-1313-T03-B
Na CFS-LRef-1313-T04-B
Na CFS-LRef-1313-T05-B
Na CFS-LRef-1313-T06-B
Na CFS-LRef-1313-T07-B
Na CFS-LRef-1313-T08-B
Na CFS-LRef-1313-T09-B
Na CFS-LRef-1313-T01-C
Na CFS-LRef-1313-T02-C
Na CFS-LRef-1313-T03-C
Na CFS-LRef-1313-T04-C
Na CFS-LRef-1313-T05-C
Na CFS-LRef-1313-T06-C
Na CFS-LRef-1313-T07-C
Na CFS-LRef-1313-T08-C
Na CFS-LRef-1313-T09-C
Na CFS-LRef-1313-B01-A
Na CFS-LRef-1313-B02-A
Na CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.19E+04
1 2.86E+04
1 2.19E+04
1 1.99E+04
1 2.00E+04
1 2.07E+04
1 1.94E+04
1 1.92E+04
1 1.99E+04
1 3.37E+04
1 2.78E+04
1 2.27E+04
1 2.03E+04
1 2.02E+04
1 2.06E+04
1 2.03E+04
1 1.98E+04
1 2.10E+04
1 3.29E+04
1 3.02E+04
1 2.17E+04
1 2.03E+04
1 2.07E+04
1 2.06E+04
1 2.03E+04
1 1.98E+04
1 1.99E+04
1 3.21 E+00 E
1 1.25E+00 U1/2
1 1.23E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.19E+04 1.1 E+00 2.5E+00 8.0E+00
2.86E+04 1.7E+00 2.5E+00 8.0E+00 1000 100
2.19E+04 3.6E-01 2.5E+00 8.0E+00
1.99E+04 7.1E-01 2.5E+00 8.0E+00
2.00E+04 2.2E-01 2.5E+00 8.0E+00
2.07E+04 5.2E-01 2.5E+00 8.0E+00
1.94E+04 1.3E+00 2.5E+00 8.0E+00
1.92E+04 2.9E-01 2.5E+00 8.0E+00
1.99E+04 4.0E-01 2.5E+00 8.0E+00
3.37E+04 5.8E-01 2.5E+00 8.0E+00
2.78E+04 8.5E-01 2.5E+00 8.0E+00 1000 100
2.27E+04 1.4E-01 2.5E+00 8.0E+00
2.03E+04 5.6E-01 2.5E+00 8.0E+00
2.02E+04 2.9E-01 2.5E+00 8.0E+00
2.06E+04 1.3E+00 2.5E+00 8.0E+00
2.03E+04 6.2E-01 2.5E+00 8.0E+00
1.98E+04 6.2E-01 2.5E+00 8.0E+00
2.10E+04 6.9E-01 2.5E+00 8.0E+00
3.29E+04 2.8E-01 2.5E+00 8.0E+00
3.02E+04 1.2E+00 2.5E+00 8.0E+00 1000 100
2.17E+04 5.3E-01 2.5E+00 8.0E+00
2.03E+04 1.2E+00 2.5E+00 8.0E+00
2.07E+04 5.1E-01 2.5E+00 8.0E+00
2.06E+04 2.2E-01 2.5E+00 8.0E+00
2.03E+04 4.7E-01 2.5E+00 8.0E+00
1.98E+04 3.0E+00 2.5E+00 8.0E+00
1.99E+04 5.1E-01 2.5E+00 8.0E+00
3.21 E+00 1.3E+02 2.5E+00 8.0E+00
1.25E+00 1.3E+01 2.5E+00 8.0E+00
1.23E+03 4.6E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
2.95E+04 90% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
2.87E+04 91% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
3.11E+04 96% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-896
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr CFS-LRef-1313-T01-A
Sr CFS-LRef-1313-T02-A
Sr CFS-LRef-1313-T03-A
Sr CFS-LRef-1313-T04-A
Sr CFS-LRef-1313-T05-A
Sr CFS-LRef-1313-T06-A
Sr CFS-LRef-1313-T07-A
Sr CFS-LRef-1313-T08-A
Sr CFS-LRef-1313-T09-A
Sr CFS-LRef-1313-T01-B
Sr CFS-LRef-1313-T02-B
Sr CFS-LRef-1313-T03-B
Sr CFS-LRef-1313-T04-B
Sr CFS-LRef-1313-T05-B
Sr CFS-LRef-1313-T06-B
Sr CFS-LRef-1313-T07-B
Sr CFS-LRef-1313-T08-B
Sr CFS-LRef-1313-T09-B
Sr CFS-LRef-1313-T01-C
Sr CFS-LRef-1313-T02-C
Sr CFS-LRef-1313-T03-C
Sr CFS-LRef-1313-T04-C
Sr CFS-LRef-1313-T05-C
Sr CFS-LRef-1313-T06-C
Sr CFS-LRef-1313-T07-C
Sr CFS-LRef-1313-T08-C
Sr CFS-LRef-1313-T09-C
Sr CFS-LRef-1313-B01-A
Sr CFS-LRef-1313-B02-A
Sr CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.35E+03
1 1.35E+03
1 9.43E+02
1 1.43E+03
1 3.45E+03
1 3.43E+03
1 4.18E+03
1 3.72E+03
1 3.24E+03
1 1.34E+03
1 1.34E+03
1 9.26E+02
1 1.57E+03
1 3.58E+03
1 3.58E+03
1 4.26E+03
1 3.87E+03
1 3.34E+03
1 1.35E+03
1 1.28E+03
1 9.41 E+02
1 1.51E+03
1 3.49E+03
1 3.53E+03
1 4.06E+03
1 3.83E+03
1 3.42E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.35E+03 1.5E+00 1.0E+00 3.2E+00
1.35E+03 1.9E+00 1.0E+00 3.2E+00 1000 100
9.43E+02 9.7E-01 1.0E+00 3.2E+00
1.43E+03 3.3E-01 1.0E+00 3.2E+00
3.45E+03 5.2E-01 1.0E+00 3.2E+00
3.43E+03 3.2E-01 1.0E+00 3.2E+00
4.18E+03 5.8E+00 1.0E+00 3.2E+00
3.72E+03 1.9E+00 1.0E+00 3.2E+00
3.24E+03 1.2E+00 1.0E+00 3.2E+00
1.34E+03 2.1E-01 1.0E+00 3.2E+00
1.34E+03 9.3E-01 1.0E+00 3.2E+00 1000 100
9.26E+02 6.3E-01 1.0E+00 3.2E+00
1.57E+03 3.9E-01 1.0E+00 3.2E+00
3.58E+03 1.0E+00 1.0E+00 3.2E+00
3.58E+03 1.4E+00 1.0E+00 3.2E+00
4.26E+03 1.2E-01 1.0E+00 3.2E+00
3.87E+03 9.8E-01 1.0E+00 3.2E+00
3.34E+03 1.4E+00 1.0E+00 3.2E+00
1.35E+03 4.2E-01 1.0E+00 3.2E+00
1.28E+03 9.0E-01 1.0E+00 3.2E+00 1000 100
9.41 E+02 4.4E-01 1.0E+00 3.2E+00
1.51E+03 6.9E-01 1.0E+00 3.2E+00
3.49E+03 7.9E-01 1.0E+00 3.2E+00
3.53E+03 1.5E+00 1.0E+00 3.2E+00
4.06E+03 2.2E-01 1.0E+00 3.2E+00
3.83E+03 5.2E+00 1.0E+00 3.2E+00
3.42E+03 2.4E+00 1.0E+00 3.2E+00
5.00E-01 5.8E+01 1.0E+00 3.2E+00
5.00E-01 4.5E+00 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
2.22E+03 87% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
2.21E+03 87% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
2.21E+03 93% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-897
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutk
S CFS-LRef-1313-T01-A
S CFS-LRef-1313-T02-A
S CFS-LRef-1313-T03-A
S CFS-LRef-1313-T04-A
S CFS-LRef-1313-T05-A
S CFS-LRef-1313-T06-A
S CFS-LRef-1313-T07-A
S CFS-LRef-1313-T08-A
S CFS-LRef-1313-T09-A
S CFS-LRef-1313-T01-B
S CFS-LRef-1313-T02-B
S CFS-LRef-1313-T03-B
S CFS-LRef-1313-T04-B
S CFS-LRef-1313-T05-B
S CFS-LRef-1313-T06-B
S CFS-LRef-1313-T07-B
S CFS-LRef-1313-T08-B
S CFS-LRef-1313-T09-B
S CFS-LRef-1313-T01-C
S CFS-LRef-1313-T02-C
S CFS-LRef-1313-T03-C
S CFS-LRef-1313-T04-C
S CFS-LRef-1313-T05-C
S CFS-LRef-1313-T06-C
S CFS-LRef-1313-T07-C
S CFS-LRef-1313-T08-C
S CFS-LRef-1313-T09-C
S CFS-LRef-1313-B01-A
S CFS-LRef-1313-B02-A
S CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 7.95E+05
1 7.06E+05
1 6.03E+05
1 5.74E+05
1 6.44E+05
1 6.61 E+05
1 7.72E+05
1 1.01E+06
1 1.28E+06
1 7.87E+05
1 7. 11 E+05
1 6.08E+05
1 5.96E+05
1 6.67E+05
1 6.84E+05
1 7.94E+05
1 9.81 E+05
1 1.32E+06
1 8.04E+05
1 7.16E+05
1 6.05E+05
1 5.77E+05
1 6.56E+05
1 6.79E+05
1 7.81 E+05
1 1.03E+06
1 1.31E+06
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 7.61 E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.95E+05 3.7E-01 6.8E+00 2.2E+01
7.06E+05 2.1E+00 6.8E+00 2.2E+01 1000 100
6.03E+05 8.2E-01 6.8E+00 2.2E+01
5.74E+05 7.5E-01 6.8E+00 2.2E+01
6.44E+05 1.1 E+00 6.8E+00 2.2E+01
6.61 E+05 4.0E-01 6.8E+00 2.2E+01
7.72E+05 4.4E+00 6.8E+00 2.2E+01
1.01E+06 1.5E+00 6.8E+00 2.2E+01
1.28E+06 2.4E-01 6.8E+00 2.2E+01
7.87E+05 2.1E-01 6.8E+00 2.2E+01
7.11E+05 1.1 E+00 6.8E+00 2.2E+01 1000 100
6.08E+05 4.3E-01 6.8E+00 2.2E+01
5.96E+05 3.4E-01 6.8E+00 2.2E+01
6.67E+05 4.9E-01 6.8E+00 2.2E+01
6.84E+05 6.7E-01 6.8E+00 2.2E+01
7.94E+05 4.9E-01 6.8E+00 2.2E+01
9.81 E+05 1.1 E+00 6.8E+00 2.2E+01
1.32E+06 8.6E-01 6.8E+00 2.2E+01
8.04E+05 4.7E-01 6.8E+00 2.2E+01
7.16E+05 1.1 E+00 6.8E+00 2.2E+01 1000 100
6.05E+05 3.6E-01 6.8E+00 2.2E+01
5.77E+05 8.3E-01 6.8E+00 2.2E+01
6.56E+05 1.1 E+00 6.8E+00 2.2E+01
6.79E+05 8.5E-01 6.8E+00 2.2E+01
7.81 E+05 3.8E-01 6.8E+00 2.2E+01
1.03E+06 5.0E+00 6.8E+00 2.2E+01
1.31E+06 1.4E+00 6.8E+00 2.2E+01
3.40E+00 7.5E+02 6.8E+00 2.2E+01
3.40E+00 3.0E+02 6.8E+00 2.2E+01
7.61 E+00 1.9E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
7.07E+05 84% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
7.12E+05 87% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
7.17E+05 91% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-898
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample Dilutk
CFS-LRef-1313-T01-A
CFS-LRef-1313-T02-A
CFS-LRef-1313-T03-A
CFS-LRef-1313-T04-A
CFS-LRef-1313-T05-A
CFS-LRef-1313-T06-A
CFS-LRef-1313-T07-A
CFS-LRef-1313-T08-A
CFS-LRef-1313-T09-A
CFS-LRef-1313-T01-B
CFS-LRef-1313-T02-B
CFS-LRef-1313-T03-B
CFS-LRef-1313-T04-B
CFS-LRef-1313-T05-B
CFS-LRef-1313-T06-B
CFS-LRef-1313-T07-B
CFS-LRef-1313-T08-B
CFS-LRef-1313-T09-B
CFS-LRef-1313-T01-C
CFS-LRef-1313-T02-C
CFS-LRef-1313-T03-C
CFS-LRef-1313-T04-C
CFS-LRef-1313-T05-C
CFS-LRef-1313-T06-C
CFS-LRef-1313-T07-C
CFS-LRef-1313-T08-C
CFS-LRef-1313-T09-C
CFS-LRef-1313-B01-A
CFS-LRef-1313-B02-A
CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.75E+03
1 1.04E+03
1 5.95E+02
1 3.57E+02
1 6.79E+02
1 6.21 E+02
1 3.29E+02
1 2.07E+02
1 2.14E+02
1 1.78E+03
1 1.04E+03
1 6.07E+02
1 3.85E+02
1 6.82E+02
1 5.73E+02
1 3.46E+02
1 2.19E+02
1 2.32E+02
1 1.80E+03
1 1.04E+03
1 6.14E+02
1 3.62E+02
1 7.02E+02
1 5.57E+02
1 3.36E+02
1 2.29E+02
1 2.25E+02
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.75E+03 4.5E-01 4.6E+00 1.5E+01
1.04E+03 1.4E+00 4.6E+00 1.5E+01 10 100
5.95E+02 2.3E+00 4.6E+00 1.5E+01
3.57E+02 5.1E-01 4.6E+00 1.5E+01
6.79E+02 2.1E+00 4.6E+00 1.5E+01
6.21 E+02 4.6E-01 4.6E+00 1.5E+01
3.29E+02 4.8E+00 4.6E+00 1.5E+01
2.07E+02 7.7E-01 4.6E+00 1.5E+01
2.14E+02 3.4E+00 4.6E+00 1.5E+01
1.78E+03 1.3E-01 4.6E+00 1.5E+01
1.04E+03 2.0E+00 4.6E+00 1.5E+01 10 100
6.07E+02 2.3E+00 4.6E+00 1.5E+01
3.85E+02 8.9E-01 4.6E+00 1.5E+01
6.82E+02 8.4E-01 4.6E+00 1.5E+01
5.73E+02 2.6E-01 4.6E+00 1.5E+01
3.46E+02 4.4E-01 4.6E+00 1.5E+01
2.19E+02 2.9E+00 4.6E+00 1.5E+01
2.32E+02 2.6E+00 4.6E+00 1.5E+01
1.80E+03 2.0E-01 4.6E+00 1.5E+01
1.04E+03 1.1E+00 4.6E+00 1.5E+01 10 100
6.14E+02 1.0E+00 4.6E+00 1.5E+01
3.62E+02 5.5E-01 4.6E+00 1.5E+01
7.02E+02 1.9E+00 4.6E+00 1.5E+01
5.57E+02 1.4E+00 4.6E+00 1.5E+01
3.36E+02 1.2E+00 4.6E+00 1.5E+01
2.29E+02 3.8E+00 4.6E+00 1.5E+01
2.25E+02 1.7E+00 4.6E+00 1.5E+01
2.30E+00 2.1 E+02 4.6E+00 1.5E+01
2.30E+00 1.6E+02 4.6E+00 1.5E+01
2.30E+00 2.1 E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
2.02E+03 99% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
2.04E+03 101% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.99E+03 94% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-899
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutk
CFS-LRef-1313-T01-A
CFS-LRef-1313-T02-A
CFS-LRef-1313-T03-A
CFS-LRef-1313-T04-A
CFS-LRef-1313-T05-A
CFS-LRef-1313-T06-A
CFS-LRef-1313-T07-A
CFS-LRef-1313-T08-A
CFS-LRef-1313-T09-A
CFS-LRef-1313-T01-B
CFS-LRef-1313-T02-B
CFS-LRef-1313-T03-B
CFS-LRef-1313-T04-B
CFS-LRef-1313-T05-B
CFS-LRef-1313-T06-B
CFS-LRef-1313-T07-B
CFS-LRef-1313-T08-B
CFS-LRef-1313-T09-B
CFS-LRef-1313-T01-C
CFS-LRef-1313-T02-C
CFS-LRef-1313-T03-C
CFS-LRef-1313-T04-C
CFS-LRef-1313-T05-C
CFS-LRef-1313-T06-C
CFS-LRef-1313-T07-C
CFS-LRef-1313-T08-C
CFS-LRef-1313-T09-C
CFS-LRef-1313-B01-A
CFS-LRef-1313-B02-A
CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.49E+01
1 1.22E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 4.46E+01
1 1.22E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 4.29E+01
1 1.23E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.49E+01 6.6E-01 2.0E+00 6.4E+00
1.22E+01 9.1E-01 2.0E+00 6.4E+00 10 100
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 9.1E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+01 2.0E+00 6.4E+00
1.00E+00 6.7E+01 2.0E+00 6.4E+00
4.46E+01 4.2E-01 2.0E+00 6.4E+00
1.22E+01 8.7E+00 2.0E+00 6.4E+00 10 100
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 9.4E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 9.0E+00 2.0E+00 6.4E+00
4.29E+01 5.3E-01 2.0E+00 6.4E+00
1.23E+01 1.0E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00
1.00E+00 6.7E+01 2.0E+00 6.4E+00
1.00E+00 4.6E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 9.1E+00 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
9.94E+02 98% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
9.92E+02 98% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
9.88E+02 98% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-900
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutk
V CFS-LRef-1313-T01-A
V CFS-LRef-1313-T02-A
V CFS-LRef-1313-T03-A
V CFS-LRef-1313-T04-A
V CFS-LRef-1313-T05-A
V CFS-LRef-1313-T06-A
V CFS-LRef-1313-T07-A
V CFS-LRef-1313-T08-A
V CFS-LRef-1313-T09-A
V CFS-LRef-1313-T01-B
V CFS-LRef-1313-T02-B
V CFS-LRef-1313-T03-B
V CFS-LRef-1313-T04-B
V CFS-LRef-1313-T05-B
V CFS-LRef-1313-T06-B
V CFS-LRef-1313-T07-B
V CFS-LRef-1313-T08-B
V CFS-LRef-1313-T09-B
V CFS-LRef-1313-T01-C
V CFS-LRef-1313-T02-C
V CFS-LRef-1313-T03-C
V CFS-LRef-1313-T04-C
V CFS-LRef-1313-T05-C
V CFS-LRef-1313-T06-C
V CFS-LRef-1313-T07-C
V CFS-LRef-1313-T08-C
V CFS-LRef-1313-T09-C
V CFS-LRef-1313-B01-A
V CFS-LRef-1313-B02-A
V CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.68E+02
1 6.56E+01
1 4.64E+01
1 3.70E+01
1 3.60E+01
1 3.60E+01
1 3.52E+01
1 3.57E+01
1 4.20E+01
1 5.64E+02
1 6.65E+01
1 4.88E+01
1 3.94E+01
1 3.61 E+01
1 3.61 E+01
1 3.63E+01
1 3.52E+01
1 4.15E+01
1 6.15E+02
1 6.83E+01
1 4.83E+01
1 3.84E+01
1 3.72E+01
1 3.63E+01
1 3.62E+01
1 3.78E+01
1 3.84E+01
1 7.50E-01 U1/2
1 7.50E-01 U1/2
1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.68E+02 1.1E+00 1.5E+00 4.8E+00
6.56E+01 3.6E+00 1.5E+00 4.8E+00 10 100
4.64E+01 1.7E+00 1.5E+00 4.8E+00
3.70E+01 3.1E+00 1.5E+00 4.8E+00
3.60E+01 4.1E+00 1.5E+00 4.8E+00
3.60E+01 2.8E+00 1.5E+00 4.8E+00
3.52E+01 4.4E+00 1.5E+00 4.8E+00
3.57E+01 4.4E+00 1.5E+00 4.8E+00
4.20E+01 3.1E+00 1.5E+00 4.8E+00
5.64E+02 7.1E-01 1.5E+00 4.8E+00
6.65E+01 4.9E+00 1.5E+00 4.8E+00 10 100
4.88E+01 2.3E+00 1.5E+00 4.8E+00
3.94E+01 5.5E+00 1.5E+00 4.8E+00
3.61 E+01 2.3E+00 1.5E+00 4.8E+00
3.61 E+01 1.4E+00 1.5E+00 4.8E+00
3.63E+01 1.6E+00 1.5E+00 4.8E+00
3.52E+01 4.4E+00 1.5E+00 4.8E+00
4.15E+01 5.9E+00 1.5E+00 4.8E+00
6.15E+02 3.6E-01 1.5E+00 4.8E+00
6.83E+01 3.0E+00 1.5E+00 4.8E+00 10 100
4.83E+01 1.8E+00 1.5E+00 4.8E+00
3.84E+01 4.0E+00 1.5E+00 4.8E+00
3.72E+01 7.1E-01 1.5E+00 4.8E+00
3.63E+01 2.7E+00 1.5E+00 4.8E+00
3.62E+01 6.8E-01 1.5E+00 4.8E+00
3.78E+01 4.8E+00 1.5E+00 4.8E+00
3.84E+01 1.6E+00 1.5E+00 4.8E+00
7.50E-01 2.6E+02 1.5E+00 4.8E+00
7.50E-01 3.3E+01 1.5E+00 4.8E+00
7.50E-01 1.6E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.05E+03 99% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27 PM EPA Interlab LRef 1313-1316 CFS
1.07E+03 100% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.04E+03 98% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-901
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutk
Zn CFS-LRef-1313-T01-A
Zn CFS-LRef-1313-T02-A
Zn CFS-LRef-1313-T03-A
Zn CFS-LRef-1313-T04-A
Zn CFS-LRef-1313-T05-A
Zn CFS-LRef-1313-T06-A
Zn CFS-LRef-1313-T07-A
Zn CFS-LRef-1313-T08-A
Zn CFS-LRef-1313-T09-A
Zn CFS-LRef-1313-T01-B
Zn CFS-LRef-1313-T02-B
Zn CFS-LRef-1313-T03-B
Zn CFS-LRef-1313-T04-B
Zn CFS-LRef-1313-T05-B
Zn CFS-LRef-1313-T06-B
Zn CFS-LRef-1313-T07-B
Zn CFS-LRef-1313-T08-B
Zn CFS-LRef-1313-T09-B
Zn CFS-LRef-1313-T01-C
Zn CFS-LRef-1313-T02-C
Zn CFS-LRef-1313-T03-C
Zn CFS-LRef-1313-T04-C
Zn CFS-LRef-1313-T05-C
Zn CFS-LRef-1313-T06-C
Zn CFS-LRef-1313-T07-C
Zn CFS-LRef-1313-T08-C
Zn CFS-LRef-1313-T09-C
Zn CFS-LRef-1313-B01-A
Zn CFS-LRef-1313-B02-A
Zn CFS-LRef-1313-B03-A
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.68E+05
1 1.79E+05
1 1.56E+05
1 2.69E+04
1 1.09E+02
1 3.81 E+01
1 2.93E+01
1 2.41 E+03
1 4.70E+03
1 1.68E+05
1 1.84E+05
1 1.55E+05
1 2.61E+04
1 7.74E+01
1 2.97E+01
1 2.91 E+01
1 2.66E+03
1 4.75E+03
1 1.66E+05
1 1.78E+05
1 1.58E+05
1 2.30E+04
1 8.91 E+01
1 3.52E+01
1 2.59E+01
1 2.66E+03
1 4.82E+03
1 5.00E-01 U1/2
1 1.16E+01
1 3.99E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.68E+05 1.2E+00 1.0E+00 3.2E+00
1.79E+05 2.4E+00 1.0E+00 3.2E+00 10 100
1.56E+05 7.7E-01 1.0E+00 3.2E+00
2.69E+04 1.2E+00 1.0E+00 3.2E+00
1.09E+02 1.9E+00 1.0E+00 3.2E+00
3.81 E+01 1.3E+00 1.0E+00 3.2E+00
2.93E+01 2.9E+00 1.0E+00 3.2E+00
2.41 E+03 1.7E+00 1.0E+00 3.2E+00
4.70E+03 1.6E+00 1.0E+00 3.2E+00
1.68E+05 1.8E-01 1.0E+00 3.2E+00
1.84E+05 1.3E+00 1.0E+00 3.2E+00 10 100
1.55E+05 9.2E-01 1.0E+00 3.2E+00
2.61 E+04 7.0E-01 1.0E+00 3.2E+00
7.74E+01 6.3E-01 1.0E+00 3.2E+00
2.97E+01 3.1E+00 1.0E+00 3.2E+00
2.91 E+01 1.2E+00 1.0E+00 3.2E+00
2.66E+03 7.6E-01 1.0E+00 3.2E+00
4.75E+03 2.2E-01 1.0E+00 3.2E+00
1.66E+05 1.7E+00 1.0E+00 3.2E+00
1.78E+05 1.4E+00 1.0E+00 3.2E+00 10 100
1.58E+05 5.3E-01 1.0E+00 3.2E+00
2.30E+04 1.2E+00 1.0E+00 3.2E+00
8.91 E+01 8.3E-01 1.0E+00 3.2E+00
3.52E+01 2.5E+00 1.0E+00 3.2E+00
2.59E+01 2.4E+00 1.0E+00 3.2E+00
2.66E+03 5.0E+00 1.0E+00 3.2E+00
4.82E+03 1.3E+00 1.0E+00 3.2E+00
5.00E-01 1.6E+01 1.0E+00 3.2E+00
1.16E+01 2.0E+00 1.0E+00 3.2E+00
3.99E+00 1.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 3:07 PM EPA Interlab LRef 1313-1316 CFS
1.79E+05 92% VU ICP-OES 2/3/11 3:09 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:12PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:17PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:18PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:29PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:27PM EPA Interlab LRef 1313-1316 CFS
1.85E+05 87% VU ICP-OES 2/3/11 3:28 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:30PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:33PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:32PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:34PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:35PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:41 PM EPA Interlab LRef 1313-1316 CFS
1.79E+05 90% VU ICP-OES 2/3/11 3:43 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:37PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:46PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:48PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:50PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:51 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:53PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:04 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 3:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-902
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1313:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample Internal
Sample Dilution Cone. Qualifier Review
I I ug/L I
CFS-LRef-1313-T01-D 1 9.59E+04
CFS-LRef-1313-T02-D 1 3.96E+04
CFS-LRef-1313-T03-D 1 3.30E+03
CFS-LRef-1313-T04-D 1 3.69E+01
CFS-LRef-1313-T05-D 1 4.67E+01
CFS-LRef-1313-T06-D 1 5.66E+01
CFS-LRef-1313-T07-D 1 1.14E+02
CFS-LRef-1313-T08-D 1 9.88E+01
CFS-LRef-1313-T09-D 1 8.96E+01
CFS-LRef-1313-T01-E 1 9.98E+04
CFS-LRef-1313-T02-E 1 3.87E+04
CFS-LRef-1313-T03-E 1 3.37E+03
CFS-LRef-1313-T04-E 1 3.79E+01
CFS-LRef-1313-T05-E 1 4.45E+01
CFS-LRef-1313-T06-E 1 5.35E+01
CFS-LRef-1313-T07-E 1 1.29E+02
CFS-LRef-1313-T08-E 1 1.12E+02
CFS-LRef-1313-T09-E 1 9.23E+01
CFS-LRef-1313-T01-F 1 9.77E+04
CFS-LRef-1313-T02-F 1 4.38E+04
CFS-LRef-1313-T03-F 1 3.33E+03
CFS-LRef-1313-T04-F 1 3.51 E+01
CFS-LRef-1313-T05-F 1 5.55E+01
CFS-LRef-1313-T06-F 1 5.76E+01
CFS-LRef-1313-T07-F 1 1.11E+02
CFS-LRef-1313-T08-F 1 1.02E+02
CFS-LRef-1313-T09-F 1 8.60E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.59E+04 1.4E+00 1.0E+00 3.2E+00
3.96E+04 4.7E-01 1.0E+00 3.2E+00 1000 100
3.30E+03 3.4E-01 1.0E+00 3.2E+00
3.69E+01 4.6E+00 1.0E+00 3.2E+00
4.67E+01 1.0E+01 1.0E+00 3.2E+00
5.66E+01 3.9E+00 1.0E+00 3.2E+00
1.14E+02 4.0E+00 1.0E+00 3.2E+00
9.88E+01 2.2E+00 1.0E+00 3.2E+00
8.96E+01 3.2E+00 1.0E+00 3.2E+00
9.98E+04 4.2E-01 1.0E+00 3.2E+00
3.87E+04 1.0E+00 1.0E+00 3.2E+00 1000 100
3.37E+03 7.7E-01 1.0E+00 3.2E+00
3.79E+01 7.7E+00 1.0E+00 3.2E+00
4.45E+01 5.6E-01 1.0E+00 3.2E+00
5.35E+01 2.4E+00 1.0E+00 3.2E+00
1.29E+02 3.4E+00 1.0E+00 3.2E+00
1.12E+02 1.8E+00 1.0E+00 3.2E+00
9.23E+01 9.5E-01 1.0E+00 3.2E+00
9.77E+04 1.6E+01 1.0E+00 3.2E+00
4.38E+04 2.6E-01 1.0E+00 3.2E+00 1000 100
3.33E+03 1.2E+00 1.0E+00 3.2E+00
3.51 E+01 4.1E+00 1.0E+00 3.2E+00
5.55E+01 5.0E+00 1.0E+00 3.2E+00
5.76E+01 3.3E+00 1.0E+00 3.2E+00
1.11E+02 9.0E-01 1.0E+00 3.2E+00
1.02E+02 4.0E+00 1.0E+00 3.2E+00
8.60E+01 2.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.05E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.96E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.47E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/3/11 4:03 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                                     1-903
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilutk
Sb CFS-LRef-1313-T01-D
Sb CFS-LRef-1313-T02-D
Sb CFS-LRef-1313-T03-D
Sb CFS-LRef-1313-T04-D
Sb CFS-LRef-1313-T05-D
Sb CFS-LRef-1313-T06-D
Sb CFS-LRef-1313-T07-D
Sb CFS-LRef-1313-T08-D
Sb CFS-LRef-1313-T09-D
Sb CFS-LRef-1313-T01-E
Sb CFS-LRef-1313-T02-E
Sb CFS-LRef-1313-T03-E
Sb CFS-LRef-1313-T04-E
Sb CFS-LRef-1313-T05-E
Sb CFS-LRef-1313-T06-E
Sb CFS-LRef-1313-T07-E
Sb CFS-LRef-1313-T08-E
Sb CFS-LRef-1313-T09-E
Sb CFS-LRef-1313-T01-F
Sb CFS-LRef-1313-T02-F
Sb CFS-LRef-1313-T03-F
Sb CFS-LRef-1313-T04-F
Sb CFS-LRef-1313-T05-F
Sb CFS-LRef-1313-T06-F
Sb CFS-LRef-1313-T07-F
Sb CFS-LRef-1313-T08-F
Sb CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.46E+03
1 1.11E+03
1 8.76E+01
1 3.60E+01
1 2.83E+01
1 3.32E+01
1 2.76E+01
1 8.76E+00 E
1 3.75E+00 U1/2
1 1.28E+03
1 1.08E+03
1 9.10E+01
1 4.35E+01
1 3.29E+01
1 3.85E+01
1 3.13E+01
1 8.89E+00 E
1 3.75E+00 U1/2
1 1.06E+03
1 1.22E+03
1 8.61 E+01
1 2.97E+01
1 3.27E+01
1 3.50E+01
1 3.22E+01
1 8.59E+00 E
1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.46E+03 1.1 E+01 7.5E+00 2.4E+01
1.11E+03 6.5E+00 7.5E+00 2.4E+01 10 100
8.76E+01 1.3E+01 7.5E+00 2.4E+01
3.60E+01 1.9E+01 7.5E+00 2.4E+01
2.83E+01 9.6E+00 7.5E+00 2.4E+01
3.32E+01 7.9E+00 7.5E+00 2.4E+01
2.76E+01 1.3E+01 7.5E+00 2.4E+01
8.76E+00 3.6E+01 7.5E+00 2.4E+01
3.75E+00 3.5E+02 7.5E+00 2.4E+01
1.28E+03 8.5E+00 7.5E+00 2.4E+01
1.08E+03 6.6E+00 7.5E+00 2.4E+01 10 100
9.10E+01 7.3E+00 7.5E+00 2.4E+01
4.35E+01 4.4E+01 7.5E+00 2.4E+01
3.29E+01 1.4E+01 7.5E+00 2.4E+01
3.85E+01 2.7E+01 7.5E+00 2.4E+01
3.13E+01 7.6E+00 7.5E+00 2.4E+01
8.89E+00 5.3E+00 7.5E+00 2.4E+01
3.75E+00 2.8E+02 7.5E+00 2.4E+01
1.06E+03 6.1 E+01 7.5E+00 2.4E+01
1.22E+03 3.7E+00 7.5E+00 2.4E+01 10 100
8.61 E+01 2.0E+01 7.5E+00 2.4E+01
2.97E+01 1.7E+01 7.5E+00 2.4E+01
3.27E+01 4.9E+00 7.5E+00 2.4E+01
3.50E+01 6.3E+00 7.5E+00 2.4E+01
3.22E+01 2.1 E+01 7.5E+00 2.4E+01
8.59E+00 9.1 E+01 7.5E+00 2.4E+01
3.75E+00 1.8E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
2.03E+03 92% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
1.98E+03 90% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
2.05E+03 83% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-904
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilutic
As CFS-LRef-1313-T01-D
As CFS-LRef-1313-T02-D
As CFS-LRef-1313-T03-D
As CFS-LRef-1313-T04-D
As CFS-LRef-1313-T05-D
As CFS-LRef-1313-T06-D
As CFS-LRef-1313-T07-D
As CFS-LRef-1313-T08-D
As CFS-LRef-1313-T09-D
As CFS-LRef-1313-T01-E
As CFS-LRef-1313-T02-E
As CFS-LRef-1313-T03-E
As CFS-LRef-1313-T04-E
As CFS-LRef-1313-T05-E
As CFS-LRef-1313-T06-E
As CFS-LRef-1313-T07-E
As CFS-LRef-1313-T08-E
As CFS-LRef-1313-T09-E
As CFS-LRef-1313-T01-F
As CFS-LRef-1313-T02-F
As CFS-LRef-1313-T03-F
As CFS-LRef-1313-T04-F
As CFS-LRef-1313-T05-F
As CFS-LRef-1313-T06-F
As CFS-LRef-1313-T07-F
As CFS-LRef-1313-T08-F
As CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 8.79E+04
1 1.43E+03
1 1.29E+02
1 2.33E+01 E
1 3.34E+01 E
1 3.85E+01
1 1.12E+02
1 2.36E+02
1 2.11E+02
1 7.16E+04
1 1.18E+03
1 1.11E+02
1 2.71 E+01 E
1 2.52E+01 E
1 4.35E+01
1 1.01E+02
1 2.42E+02
1 1.98E+02
1 7.67E+04
1 1.45E+03
1 1.19E+02
1 2.95E+01 E
1 3.22E+01 E
1 3.79E+01
1 9. 11 E+01
1 1.88E+02
1 1.98E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.79E+04 6.9E-01 1.1E+01 3.5E+01
1.43E+03 1.2E+00 1.1E+01 3.5E+01 10 100
1.29E+02 8.3E+00 1.1E+01 3.5E+01
2.33E+01 2.1E+01 1.1E+01 3.5E+01
3.34E+01 8.0E+00 1.1E+01 3.5E+01
3.85E+01 1.7E+01 1.1E+01 3.5E+01
1.12E+02 1.1 E+01 1.1E+01 3.5E+01
2.36E+02 4.2E+00 1.1E+01 3.5E+01
2.11E+02 1.8E+00 1.1E+01 3.5E+01
7.16E+04 1.5E+00 1.1E+01 3.5E+01
1.18E+03 5.4E-01 1.1E+01 3.5E+01 10 100
1.11E+02 9.5E+00 1.1E+01 3.5E+01
2.71E+01 2.3E+01 1.1E+01 3.5E+01
2.52E+01 3.4E+01 1.1E+01 3.5E+01
4.35E+01 3.1E+00 1.1E+01 3.5E+01
1.01E+02 4.2E+00 1.1E+01 3.5E+01
2.42E+02 1.7E+00 1.1E+01 3.5E+01
1.98E+02 3.7E+00 1.1E+01 3.5E+01
7.67E+04 8.6E+00 1.1E+01 3.5E+01
1.45E+03 1.5E+00 1.1E+01 3.5E+01 10 100
1.19E+02 9.8E+00 1.1E+01 3.5E+01
2.95E+01 9.7E+00 1.1E+01 3.5E+01
3.22E+01 3.9E+01 1.1E+01 3.5E+01
3.79E+01 2.6E+01 1.1E+01 3.5E+01
9.11E+01 8.6E+00 1.1E+01 3.5E+01
1.88E+02 6.7E+00 1.1E+01 3.5E+01
1.98E+02 4.0E+00 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
2.33E+03 90% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18PM EPA Interlab LRef 1313-1316 CFS
2.12E+03 93% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52PM EPA Interlab LRef 1313-1316 CFS
2.32E+03 87% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:OOPM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-905
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilutic
B CFS-LRef-1313-T01-D
B CFS-LRef-1313-T02-D
B CFS-LRef-1313-T03-D
B CFS-LRef-1313-T04-D
B CFS-LRef-1313-T05-D
B CFS-LRef-1313-T06-D
B CFS-LRef-1313-T07-D
B CFS-LRef-1313-T08-D
B CFS-LRef-1313-T09-D
B CFS-LRef-1313-T01-E
B CFS-LRef-1313-T02-E
B CFS-LRef-1313-T03-E
B CFS-LRef-1313-T04-E
B CFS-LRef-1313-T05-E
B CFS-LRef-1313-T06-E
B CFS-LRef-1313-T07-E
B CFS-LRef-1313-T08-E
B CFS-LRef-1313-T09-E
B CFS-LRef-1313-T01-F
B CFS-LRef-1313-T02-F
B CFS-LRef-1313-T03-F
B CFS-LRef-1313-T04-F
B CFS-LRef-1313-T05-F
B CFS-LRef-1313-T06-F
B CFS-LRef-1313-T07-F
B CFS-LRef-1313-T08-F
B CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 7.30E+02
1 6.71 E+02
1 3.13E+02
1 1.69E+02
1 1.28E+02
1 1.19E+02
1 1.62E+02
1 8.83E+01
1 6.62E+01
1 7.84E+02
1 6.85E+02
1 3.23E+02
1 1.62E+02
1 1.22E+02
1 1.20E+02
1 1.63E+02
1 9.47E+01
1 6.96E+01
1 7.54E+02
1 6.74E+02
1 3.14E+02
1 1.58E+02
1 1.23E+02
1 1.18E+02
1 1.56E+02
1 8.48E+01
1 6.29E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.30E+02 2.0E+00 1.0E+00 3.2E+00
6.71E+02 1.8E-01 1.0E+00 3.2E+00 1000 100
3.13E+02 5.1E-01 1.0E+00 3.2E+00
1.69E+02 1.2E+00 1.0E+00 3.2E+00
1.28E+02 1.4E+00 1.0E+00 3.2E+00
1.19E+02 5.5E-01 1.0E+00 3.2E+00
1.62E+02 1.1E+00 1.0E+00 3.2E+00
8.83E+01 2.1E+00 1.0E+00 3.2E+00
6.62E+01 2.2E+00 1.0E+00 3.2E+00
7.84E+02 1.0E+00 1.0E+00 3.2E+00
6.85E+02 1.2E+00 1.0E+00 3.2E+00 1000 100
3.23E+02 2.0E-01 1.0E+00 3.2E+00
1.62E+02 7.5E-01 1.0E+00 3.2E+00
1.22E+02 9.6E-01 1.0E+00 3.2E+00
1.20E+02 1.2E+00 1.0E+00 3.2E+00
1.63E+02 2.0E+00 1.0E+00 3.2E+00
9.47E+01 1.8E+00 1.0E+00 3.2E+00
6.96E+01 9.3E-01 1.0E+00 3.2E+00
7.54E+02 9.2E+00 1.0E+00 3.2E+00
6.74E+02 6.6E-01 1.0E+00 3.2E+00 1000 100
3.14E+02 1.6E+00 1.0E+00 3.2E+00
1.58E+02 9.4E-01 1.0E+00 3.2E+00
1.23E+02 1.4E+00 1.0E+00 3.2E+00
1.18E+02 1.8E+00 1.0E+00 3.2E+00
1.56E+02 2.7E+00 1.0E+00 3.2E+00
8.48E+01 2.6E+00 1.0E+00 3.2E+00
6.29E+01 3.6E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.63E+03 96% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18PM EPA Interlab LRef 1313-1316 CFS
1.57E+03 89% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52PM EPA Interlab LRef 1313-1316 CFS
1.62E+03 95% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:OOPM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-906
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilutic
Ba CFS-LRef-1313-T01-D
Ba CFS-LRef-1313-T02-D
Ba CFS-LRef-1313-T03-D
Ba CFS-LRef-1313-T04-D
Ba CFS-LRef-1313-T05-D
Ba CFS-LRef-1313-T06-D
Ba CFS-LRef-1313-T07-D
Ba CFS-LRef-1313-T08-D
Ba CFS-LRef-1313-T09-D
Ba CFS-LRef-1313-T01-E
Ba CFS-LRef-1313-T02-E
Ba CFS-LRef-1313-T03-E
Ba CFS-LRef-1313-T04-E
Ba CFS-LRef-1313-T05-E
Ba CFS-LRef-1313-T06-E
Ba CFS-LRef-1313-T07-E
Ba CFS-LRef-1313-T08-E
Ba CFS-LRef-1313-T09-E
Ba CFS-LRef-1313-T01-F
Ba CFS-LRef-1313-T02-F
Ba CFS-LRef-1313-T03-F
Ba CFS-LRef-1313-T04-F
Ba CFS-LRef-1313-T05-F
Ba CFS-LRef-1313-T06-F
Ba CFS-LRef-1313-T07-F
Ba CFS-LRef-1313-T08-F
Ba CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.82E+00
1 3.27E+01
1 2.37E+01
1 1.00E+02
1 7.59E+01
1 8.37E+01
1 1.65E+02
1 4.13E+00
1 1.40E+00 E
1 6.04E+00
1 3.40E+01
1 2.77E+01
1 9.45E+01
1 7.55E+01
1 8.52E+01
1 1.66E+02
1 6.13E+00
1 1.22E+00 E
1 5.58E+00
1 3.41 E+01
1 2.80E+01
1 9.20E+01
1 7.46E+01
1 8.23E+01
1 1.60E+02
1 6.47E+00
1 1.30E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.82E+00 5.2E-01 1.0E+00 3.2E+00
3.27E+01 1.8E+00 1.0E+00 3.2E+00 10 100
2.37E+01 3.6E-01 1.0E+00 3.2E+00
1.00E+02 1.9E+00 1.0E+00 3.2E+00
7.59E+01 7.4E-01 1.0E+00 3.2E+00
8.37E+01 6.2E-01 1.0E+00 3.2E+00
1.65E+02 2.3E-01 1.0E+00 3.2E+00
4.13E+00 1.1E+00 1.0E+00 3.2E+00
1.40E+00 1.7E+00 1.0E+00 3.2E+00
6.04E+00 1.2E+00 1.0E+00 3.2E+00
3.40E+01 2.4E+00 1.0E+00 3.2E+00 10 100
2.77E+01 5.6E-01 1.0E+00 3.2E+00
9.45E+01 9.3E-01 1.0E+00 3.2E+00
7.55E+01 8.3E-01 1.0E+00 3.2E+00
8.52E+01 3.6E-01 1.0E+00 3.2E+00
1.66E+02 5.7E-01 1.0E+00 3.2E+00
6.13E+00 2.6E+00 1.0E+00 3.2E+00
1.22E+00 1.1 E+01 1.0E+00 3.2E+00
5.58E+00 1.9E+01 1.0E+00 3.2E+00
3.41E+01 3.4E-01 1.0E+00 3.2E+00 10 100
2.80E+01 1.3E+00 1.0E+00 3.2E+00
9.20E+01 8.7E-01 1.0E+00 3.2E+00
7.46E+01 4.9E-01 1.0E+00 3.2E+00
8.23E+01 6.6E-01 1.0E+00 3.2E+00
1.60E+02 3.1E-01 1.0E+00 3.2E+00
6.47E+00 2.6E+00 1.0E+00 3.2E+00
1.30E+00 6.5E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.14E+03 111% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
1.04E+03 101% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.14E+03 110% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-907
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilutic
Be CFS-LRef-1313-T01-D
Be CFS-LRef-1313-T02-D
Be CFS-LRef-1313-T03-D
Be CFS-LRef-1313-T04-D
Be CFS-LRef-1313-T05-D
Be CFS-LRef-1313-T06-D
Be CFS-LRef-1313-T07-D
Be CFS-LRef-1313-T08-D
Be CFS-LRef-1313-T09-D
Be CFS-LRef-1313-T01-E
Be CFS-LRef-1313-T02-E
Be CFS-LRef-1313-T03-E
Be CFS-LRef-1313-T04-E
Be CFS-LRef-1313-T05-E
Be CFS-LRef-1313-T06-E
Be CFS-LRef-1313-T07-E
Be CFS-LRef-1313-T08-E
Be CFS-LRef-1313-T09-E
Be CFS-LRef-1313-T01-F
Be CFS-LRef-1313-T02-F
Be CFS-LRef-1313-T03-F
Be CFS-LRef-1313-T04-F
Be CFS-LRef-1313-T05-F
Be CFS-LRef-1313-T06-F
Be CFS-LRef-1313-T07-F
Be CFS-LRef-1313-T08-F
Be CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 9.50E-01 U1/2
1 6.80E+00
1 2.61 E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 7.89E+00
1 2.59E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 7.73E+00
1 2.66E+00 E
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 5.2E+00 1.9E+00 6.0E+00
6.80E+00 7.2E+00 1.9E+00 6.0E+00 10 100
2.61 E+00 4.6E+00 1.9E+00 6.0E+00
9.50E-01 8.6E+01 1.9E+00 6.0E+00
9.50E-01 4.7E+02 1.9E+00 6.0E+00
9.50E-01 8.7E+02 1.9E+00 6.0E+00
9.50E-01 2.7E+02 1.9E+00 6.0E+00
9.50E-01 2.7E+02 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 2.5E+02 1.9E+00 6.0E+00
7.89E+00 1.6E+01 1.9E+00 6.0E+00 10 100
2.59E+00 5.2E+00 1.9E+00 6.0E+00
9.50E-01 7.1E+01 1.9E+00 6.0E+00
9.50E-01 4.7E+01 1.9E+00 6.0E+00
9.50E-01 5.0E+01 1.9E+00 6.0E+00
9.50E-01 4.2E+02 1.9E+00 6.0E+00
9.50E-01 3.8E+02 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+01 1.9E+00 6.0E+00
7.73E+00 1.1E+01 1.9E+00 6.0E+00 10 100
2.66E+00 3.5E+00 1.9E+00 6.0E+00
9.50E-01 1.3E+04 1.9E+00 6.0E+00
9.50E-01 9.9E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+03 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
9.50E-01 4.7E+01 1.9E+00 6.0E+00
9.50E-01 5.4E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.08E+03 108% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
9.88E+02 98% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 131 3-1 31 6 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.06E+03 105% VU ICP-OES 2/3/114:54PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-908
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilutk
Cd CFS-LRef-1313-T01-D
Cd CFS-LRef-1313-T02-D
Cd CFS-LRef-1313-T03-D
Cd CFS-LRef-1313-T04-D
Cd CFS-LRef-1313-T05-D
Cd CFS-LRef-1313-T06-D
Cd CFS-LRef-1313-T07-D
Cd CFS-LRef-1313-T08-D
Cd CFS-LRef-1313-T09-D
Cd CFS-LRef-1313-T01-E
Cd CFS-LRef-1313-T02-E
Cd CFS-LRef-1313-T03-E
Cd CFS-LRef-1313-T04-E
Cd CFS-LRef-1313-T05-E
Cd CFS-LRef-1313-T06-E
Cd CFS-LRef-1313-T07-E
Cd CFS-LRef-1313-T08-E
Cd CFS-LRef-1313-T09-E
Cd CFS-LRef-1313-T01-F
Cd CFS-LRef-1313-T02-F
Cd CFS-LRef-1313-T03-F
Cd CFS-LRef-1313-T04-F
Cd CFS-LRef-1313-T05-F
Cd CFS-LRef-1313-T06-F
Cd CFS-LRef-1313-T07-F
Cd CFS-LRef-1313-T08-F
Cd CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.93E+04
1 5.14E+04
1 2.35E+04
1 5.22E+03
1 1.14E+02
1 1.73E+01
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 6.63E+00 E
1 5.13E+04
1 5.27E+04
1 2.37E+04
1 5.11E+03
1 9.98E+01
1 1.58E+01
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 5.98E+00 E
1 4.70E+04
1 5.10E+04
1 2.28E+04
1 4.97E+03
1 1.03E+02
1 1.82E+01
1 1.10E+00 U1/2
1 1.10E+00 U1/2
1 6.61 E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.93E+04 1.5E+00 2.2E+00 7.0E+00
5.14E+04 7.3E-01 2.2E+00 7.0E+00 10 100
2.35E+04 1.2E+00 2.2E+00 7.0E+00
5.22E+03 1.4E+00 2.2E+00 7.0E+00
1.14E+02 5.4E-01 2.2E+00 7.0E+00
1.73E+01 3.3E+00 2.2E+00 7.0E+00
1.10E+00 4.1E+01 2.2E+00 7.0E+00
1.10E+00 2.7E+01 2.2E+00 7.0E+00
6.63E+00 5.9E+00 2.2E+00 7.0E+00
5.13E+04 3.7E-01 2.2E+00 7.0E+00
5.27E+04 1.4E+00 2.2E+00 7.0E+00 10 100
2.37E+04 3.4E-01 2.2E+00 7.0E+00
5.11E+03 7.0E-01 2.2E+00 7.0E+00
9.98E+01 4.7E-01 2.2E+00 7.0E+00
1.58E+01 4.3E-01 2.2E+00 7.0E+00
1.10E+00 1.4E+01 2.2E+00 7.0E+00
1.10E+00 7.4E-01 2.2E+00 7.0E+00
5.98E+00 6.8E+00 2.2E+00 7.0E+00
4.70E+04 1.9E+01 2.2E+00 7.0E+00
5.10E+04 7.0E-01 2.2E+00 7.0E+00 10 100
2.28E+04 1.5E+00 2.2E+00 7.0E+00
4.97E+03 4.4E-01 2.2E+00 7.0E+00
1.03E+02 1.2E+00 2.2E+00 7.0E+00
1.82E+01 1.2E+00 2.2E+00 7.0E+00
1.10E+00 5.4E+01 2.2E+00 7.0E+00
1.10E+00 3.0E+01 2.2E+00 7.0E+00
6.61 E+00 1.7E+00 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
5.23E+04 92% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
5.36E+04 95% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
5.20E+04 97% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-909
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Sample Dilutic
CFS-LRef-1313-T01-D
CFS-LRef-1313-T02-D
CFS-LRef-1313-T03-D
CFS-LRef-1313-T04-D
CFS-LRef-1313-T05-D
CFS-LRef-1313-T06-D
CFS-LRef-1313-T07-D
CFS-LRef-1313-T08-D
CFS-LRef-1313-T09-D
CFS-LRef-1313-T01-E
CFS-LRef-1313-T02-E
CFS-LRef-1313-T03-E
CFS-LRef-1313-T04-E
CFS-LRef-1313-T05-E
CFS-LRef-1313-T06-E
CFS-LRef-1313-T07-E
CFS-LRef-1313-T08-E
CFS-LRef-1313-T09-E
CFS-LRef-1313-T01-F
CFS-LRef-1313-T02-F
CFS-LRef-1313-T03-F
CFS-LRef-1313-T04-F
CFS-LRef-1313-T05-F
CFS-LRef-1313-T06-F
CFS-LRef-1313-T07-F
CFS-LRef-1313-T08-F
CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.59E+06
1 1.39E+06
1 8.95E+05
1 7.04E+05
1 6.41 E+05
1 6.24E+05
1 5.94E+05
1 5.69E+05
1 6.43E+05
1 1.74E+06
1 1.37E+06
1 9.02E+05
1 6.88E+05
1 6.39E+05
1 6.25E+05
1 6.02E+05
1 5.89E+05
1 6.51 E+05
1 1.38E+06
1 1.42E+06
1 9.05E+05
1 6.77E+05
1 6.36E+05
1 6. 11 E+05
1 5.89E+05
1 5.81 E+05
1 6.33E+05
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+06 1.0E+00 2.6E+00 8.3E+00
1.39E+06 6.8E-01 2.6E+00 8.3E+00 1000 100
8.95E+05 7.0E-01 2.6E+00 8.3E+00
7.04E+05 1.5E+00 2.6E+00 8.3E+00
6.41 E+05 6.0E-01 2.6E+00 8.3E+00
6.24E+05 1.3E-01 2.6E+00 8.3E+00
5.94E+05 5.1E-01 2.6E+00 8.3E+00
5.69E+05 1.1E-01 2.6E+00 8.3E+00
6.43E+05 8.6E-01 2.6E+00 8.3E+00
1.74E+06 2.6E+00 2.6E+00 8.3E+00
1.37E+06 1.4E+00 2.6E+00 8.3E+00 1000 100
9.02E+05 3.9E-01 2.6E+00 8.3E+00
6.88E+05 5.5E-01 2.6E+00 8.3E+00
6.39E+05 7.5E-01 2.6E+00 8.3E+00
6.25E+05 7.2E-01 2.6E+00 8.3E+00
6.02E+05 9.0E-01 2.6E+00 8.3E+00
5.89E+05 6.9E-01 2.6E+00 8.3E+00
6.51 E+05 8.9E-01 2.6E+00 8.3E+00
1.38E+06 5.5E+01 2.6E+00 8.3E+00
1.42E+06 4.5E-01 2.6E+00 8.3E+00 1000 100
9.05E+05 9.3E-01 2.6E+00 8.3E+00
6.77E+05 9.8E-01 2.6E+00 8.3E+00
6.36E+05 6.4E-01 2.6E+00 8.3E+00
6.11E+05 5.7E-01 2.6E+00 8.3E+00
5.89E+05 4.9E-01 2.6E+00 8.3E+00
5.81 E+05 7.0E-01 2.6E+00 8.3E+00
6.33E+05 4.4E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.39E+06 87% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
1.37E+06 89% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.42E+06 92% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-910
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilutic
Cr CFS-LRef-1313-T01-D
Cr CFS-LRef-1313-T02-D
Cr CFS-LRef-1313-T03-D
Cr CFS-LRef-1313-T04-D
Cr CFS-LRef-1313-T05-D
Cr CFS-LRef-1313-T06-D
Cr CFS-LRef-1313-T07-D
Cr CFS-LRef-1313-T08-D
Cr CFS-LRef-1313-T09-D
Cr CFS-LRef-1313-T01-E
Cr CFS-LRef-1313-T02-E
Cr CFS-LRef-1313-T03-E
Cr CFS-LRef-1313-T04-E
Cr CFS-LRef-1313-T05-E
Cr CFS-LRef-1313-T06-E
Cr CFS-LRef-1313-T07-E
Cr CFS-LRef-1313-T08-E
Cr CFS-LRef-1313-T09-E
Cr CFS-LRef-1313-T01-F
Cr CFS-LRef-1313-T02-F
Cr CFS-LRef-1313-T03-F
Cr CFS-LRef-1313-T04-F
Cr CFS-LRef-1313-T05-F
Cr CFS-LRef-1313-T06-F
Cr CFS-LRef-1313-T07-F
Cr CFS-LRef-1313-T08-F
Cr CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.07E+03
1 6.36E+01
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 1.51E+00 E
1 7.97E+00
1 6.40E+01
1 1.04E+02
1 2.20E+03
1 5.57E+01
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 8.30E+00
1 6.31 E+01
1 1.13E+02
1 2.03E+03
1 8.26E+01
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 7.08E+00
1 5.28E+01
1 1.02E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+03 7.9E-01 1.2E+00 3.8E+00
6.36E+01 1.7E+00 1.2E+00 3.8E+00 10 100
6.00E-01 2.1E+02 1.2E+00 3.8E+00
6.00E-01 8.4E+01 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
1.51E+00 5.7E+00 1.2E+00 3.8E+00
7.97E+00 3.2E+00 1.2E+00 3.8E+00
6.40E+01 1.4E+00 1.2E+00 3.8E+00
1.04E+02 1.3E+00 1.2E+00 3.8E+00
2.20E+03 9.1E-01 1.2E+00 3.8E+00
5.57E+01 5.2E-01 1.2E+00 3.8E+00 10 100
6.00E-01 2.5E+02 1.2E+00 3.8E+00
6.00E-01 1.9E+02 1.2E+00 3.8E+00
6.00E-01 4.3E+01 1.2E+00 3.8E+00
6.00E-01 4.6E+01 1.2E+00 3.8E+00
8.30E+00 8.1E+00 1.2E+00 3.8E+00
6.31 E+01 2.5E+00 1.2E+00 3.8E+00
1.13E+02 1.6E+00 1.2E+00 3.8E+00
2.03E+03 1.7E+01 1.2E+00 3.8E+00
8.26E+01 4.4E-01 1.2E+00 3.8E+00 10 100
6.00E-01 8.2E+02 1.2E+00 3.8E+00
6.00E-01 1.1E+03 1.2E+00 3.8E+00
6.00E-01 2.7E+02 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
7.08E+00 1.1 E+01 1.2E+00 3.8E+00
5.28E+01 3.3E+00 1.2E+00 3.8E+00
1.02E+02 6.3E-01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.08E+03 102% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
9.94E+02 94% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.08E+03 100% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-911
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample Dilutk
CFS-LRef-1313-T01-D
CFS-LRef-1313-T02-D
CFS-LRef-1313-T03-D
CFS-LRef-1313-T04-D
CFS-LRef-1313-T05-D
CFS-LRef-1313-T06-D
CFS-LRef-1313-T07-D
CFS-LRef-1313-T08-D
CFS-LRef-1313-T09-D
CFS-LRef-1313-T01-E
CFS-LRef-1313-T02-E
CFS-LRef-1313-T03-E
CFS-LRef-1313-T04-E
CFS-LRef-1313-T05-E
CFS-LRef-1313-T06-E
CFS-LRef-1313-T07-E
CFS-LRef-1313-T08-E
CFS-LRef-1313-T09-E
CFS-LRef-1313-T01-F
CFS-LRef-1313-T02-F
CFS-LRef-1313-T03-F
CFS-LRef-1313-T04-F
CFS-LRef-1313-T05-F
CFS-LRef-1313-T06-F
CFS-LRef-1313-T07-F
CFS-LRef-1313-T08-F
CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.78E+03
1 1.71E+03
1 5.86E+02
1 1.14E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.79E+03
1 1.75E+03
1 5.89E+02
1 1.14E+02
1 2.58E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 1.82E+03
1 1.74E+03
1 5.83E+02
1 1.11E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.78E+03 3.4E-01 1.8E+00 5.7E+00
1.71E+03 1.2E+00 1.8E+00 5.7E+00 10 100
5.86E+02 7.2E-01 1.8E+00 5.7E+00
1.14E+02 9.3E-01 1.8E+00 5.7E+00
9.00E-01 3.6E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 8.7E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 2.9E+02 1.8E+00 5.7E+00
1.79E+03 3.4E+00 1.8E+00 5.7E+00
1.75E+03 2.2E+00 1.8E+00 5.7E+00 10 100
5.89E+02 1.8E+00 1.8E+00 5.7E+00
1.14E+02 1.7E+00 1.8E+00 5.7E+00
2.58E+00 3.5E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+01 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00
9.00E-01 2.5E+01 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00
1.82E+03 1.1E+01 1.8E+00 5.7E+00
1.74E+03 9.5E-01 1.8E+00 5.7E+00 10 100
5.83E+02 9.4E-01 1.8E+00 5.7E+00
1.11E+02 1.3E+00 1.8E+00 5.7E+00
9.00E-01 8.8E+00 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 3.9E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+01 1.8E+00 5.7E+00
9.00E-01 7.1E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
2.68E+03 97% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
2.74E+03 99% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
2.74E+03 101% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-912
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilutk
Cu CFS-LRef-1313-T01-D
Cu CFS-LRef-1313-T02-D
Cu CFS-LRef-1313-T03-D
Cu CFS-LRef-1313-T04-D
Cu CFS-LRef-1313-T05-D
Cu CFS-LRef-1313-T06-D
Cu CFS-LRef-1313-T07-D
Cu CFS-LRef-1313-T08-D
Cu CFS-LRef-1313-T09-D
Cu CFS-LRef-1313-T01-E
Cu CFS-LRef-1313-T02-E
Cu CFS-LRef-1313-T03-E
Cu CFS-LRef-1313-T04-E
Cu CFS-LRef-1313-T05-E
Cu CFS-LRef-1313-T06-E
Cu CFS-LRef-1313-T07-E
Cu CFS-LRef-1313-T08-E
Cu CFS-LRef-1313-T09-E
Cu CFS-LRef-1313-T01-F
Cu CFS-LRef-1313-T02-F
Cu CFS-LRef-1313-T03-F
Cu CFS-LRef-1313-T04-F
Cu CFS-LRef-1313-T05-F
Cu CFS-LRef-1313-T06-F
Cu CFS-LRef-1313-T07-F
Cu CFS-LRef-1313-T08-F
Cu CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.12E+06
1 9.75E+05
1 1.75E+05
1 9.64E+02
1 6.54E+01
1 6.90E+01
1 1.64E+02
1 7.67E+02
1 3.41 E+03
1 1.14E+06
1 9.79E+05
1 1.75E+05
1 9.89E+02
1 6.65E+01
1 6.81 E+01
1 1.95E+02
1 7.78E+02
1 3.31 E+03
1 1.13E+06
1 1.01E+06
1 1.67E+05
1 9.70E+02
1 6.48E+01
1 7.10E+01
1 1.60E+02
1 7.32E+02
1 3.30E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.12E+06 1.6E+00 3.7E+00 1.2E+01
9.75E+05 1.2E+00 3.7E+00 1.2E+01 10 100
1.75E+05 5.2E-01 3.7E+00 1.2E+01
9.64E+02 1.4E+00 3.7E+00 1.2E+01
6.54E+01 2.8E+00 3.7E+00 1.2E+01
6.90E+01 3.4E+00 3.7E+00 1.2E+01
1.64E+02 1.2E+00 3.7E+00 1.2E+01
7.67E+02 8.8E-01 3.7E+00 1.2E+01
3.41 E+03 8.8E-01 3.7E+00 1.2E+01
1.14E+06 2.3E+00 3.7E+00 1.2E+01
9.79E+05 1.3E+00 3.7E+00 1.2E+01 10 100
1.75E+05 8.8E-01 3.7E+00 1.2E+01
9.89E+02 1.3E-01 3.7E+00 1.2E+01
6.65E+01 1.8E-01 3.7E+00 1.2E+01
6.81 E+01 1.2E+00 3.7E+00 1.2E+01
1.95E+02 1.1E+00 3.7E+00 1.2E+01
7.78E+02 1.4E+00 3.7E+00 1.2E+01
3.31 E+03 1.3E-01 3.7E+00 1.2E+01
1.13E+06 1.0E+01 3.7E+00 1.2E+01
1.01E+06 6.2E-01 3.7E+00 1.2E+01 10 100
1.67E+05 1.2E+00 3.7E+00 1.2E+01
9.70E+02 9.9E-01 3.7E+00 1.2E+01
6.48E+01 1.3E+00 3.7E+00 1.2E+01
7.10E+01 2.6E+00 3.7E+00 1.2E+01
1.60E+02 7.6E-01 3.7E+00 1.2E+01
7.32E+02 1.7E+00 3.7E+00 1.2E+01
3.30E+03 8.7E-01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
9.75E+05 87% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
9.80E+05 89% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.01E+06 90% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-913
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilutk
Fe CFS-LRef-1313-T01-D
Fe CFS-LRef-1313-T02-D
Fe CFS-LRef-1313-T03-D
Fe CFS-LRef-1313-T04-D
Fe CFS-LRef-1313-T05-D
Fe CFS-LRef-1313-T06-D
Fe CFS-LRef-1313-T07-D
Fe CFS-LRef-1313-T08-D
Fe CFS-LRef-1313-T09-D
Fe CFS-LRef-1313-T01-E
Fe CFS-LRef-1313-T02-E
Fe CFS-LRef-1313-T03-E
Fe CFS-LRef-1313-T04-E
Fe CFS-LRef-1313-T05-E
Fe CFS-LRef-1313-T06-E
Fe CFS-LRef-1313-T07-E
Fe CFS-LRef-1313-T08-E
Fe CFS-LRef-1313-T09-E
Fe CFS-LRef-1313-T01-F
Fe CFS-LRef-1313-T02-F
Fe CFS-LRef-1313-T03-F
Fe CFS-LRef-1313-T04-F
Fe CFS-LRef-1313-T05-F
Fe CFS-LRef-1313-T06-F
Fe CFS-LRef-1313-T07-F
Fe CFS-LRef-1313-T08-F
Fe CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.68E+05
1 4.71E+04
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.54E+05
1 3.98E+04
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 2.19E+05
1 5.33E+04
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.68E+05 1.9E+00 2.0E+00 6.4E+00
4.71E+04 5.3E-01 2.0E+00 6.4E+00 1000 100
1.00E+00 2.3E+00 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 6.9E+00 2.0E+00 6.4E+00
1.00E+00 6.5E+01 2.0E+00 6.4E+00
1.00E+00 4.5E+01 2.0E+00 6.4E+00
1.00E+00 8.8E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
2.54E+05 4.4E+00 2.0E+00 6.4E+00
3.98E+04 6.6E-01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+00 2.0E+00 6.4E+00
1.00E+00 8.1E+00 2.0E+00 6.4E+00
2.19E+05 6.3E+01 2.0E+00 6.4E+00
5.33E+04 1.8E-01 2.0E+00 6.4E+00 1000 100
1.00E+00 5.7E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 4.4E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+00 2.0E+00 6.4E+00
1.00E+00 5.6E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03 PM EPA Interlab LRef 1313-1316 CFS
4.80E+04 90% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
4.08E+04 92% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 131 3-1 31 6 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
5.43E+04 96% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-914
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilutk
Pb CFS-LRef-1313-T01-D
Pb CFS-LRef-1313-T02-D
Pb CFS-LRef-1313-T03-D
Pb CFS-LRef-1313-T04-D
Pb CFS-LRef-1313-T05-D
Pb CFS-LRef-1313-T06-D
Pb CFS-LRef-1313-T07-D
Pb CFS-LRef-1313-T08-D
Pb CFS-LRef-1313-T09-D
Pb CFS-LRef-1313-T01-E
Pb CFS-LRef-1313-T02-E
Pb CFS-LRef-1313-T03-E
Pb CFS-LRef-1313-T04-E
Pb CFS-LRef-1313-T05-E
Pb CFS-LRef-1313-T06-E
Pb CFS-LRef-1313-T07-E
Pb CFS-LRef-1313-T08-E
Pb CFS-LRef-1313-T09-E
Pb CFS-LRef-1313-T01-F
Pb CFS-LRef-1313-T02-F
Pb CFS-LRef-1313-T03-F
Pb CFS-LRef-1313-T04-F
Pb CFS-LRef-1313-T05-F
Pb CFS-LRef-1313-T06-F
Pb CFS-LRef-1313-T07-F
Pb CFS-LRef-1313-T08-F
Pb CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 8.47E+03
1 6.62E+03
1 7.05E+03
1 1.12E+03
1 1.47E+02
1 1.14E+02
1 7.08E+02
1 1.04E+04
1 7.87E+03
1 8.88E+03
1 6.38E+03
1 6.53E+03
1 1.13E+03
1 1.40E+02
1 1.29E+02
1 6.83E+02
1 1.02E+04
1 7.54E+03
1 8.53E+03
1 6.56E+03
1 6.06E+03
1 1.06E+03
1 1.45E+02
1 1.27E+02
1 7.01 E+02
1 1.09E+04
1 7.52E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.47E+03 7.8E-01 6.8E+00 2.2E+01
6.62E+03 2.2E-01 6.8E+00 2.2E+01 10 100
7.05E+03 9.6E-01 6.8E+00 2.2E+01
1.12E+03 1.2E+00 6.8E+00 2.2E+01
1.47E+02 1.9E+00 6.8E+00 2.2E+01
1.14E+02 1.5E+00 6.8E+00 2.2E+01
7.08E+02 1.1E+00 6.8E+00 2.2E+01
1.04E+04 3.4E-01 6.8E+00 2.2E+01
7.87E+03 1.2E+00 6.8E+00 2.2E+01
8.88E+03 1.1E+00 6.8E+00 2.2E+01
6.38E+03 4.9E-01 6.8E+00 2.2E+01 10 100
6.53E+03 1.1E+00 6.8E+00 2.2E+01
1.13E+03 8.1E-01 6.8E+00 2.2E+01
1.40E+02 7.5E-01 6.8E+00 2.2E+01
1.29E+02 4.6E+00 6.8E+00 2.2E+01
6.83E+02 6.0E-01 6.8E+00 2.2E+01
1.02E+04 1.2E+00 6.8E+00 2.2E+01
7.54E+03 8.6E-01 6.8E+00 2.2E+01
8.53E+03 1.6E+01 6.8E+00 2.2E+01
6.56E+03 3.0E-01 6.8E+00 2.2E+01 10 100
6.06E+03 4.8E-01 6.8E+00 2.2E+01
1.06E+03 4.9E-01 6.8E+00 2.2E+01
1.45E+02 3.4E+00 6.8E+00 2.2E+01
1.27E+02 4.2E+00 6.8E+00 2.2E+01
7.01 E+02 6.0E-01 6.8E+00 2.2E+01
1.09E+04 1.1E+00 6.8E+00 2.2E+01
7.52E+03 7.6E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
7.61E+03 99% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
7.38E+03 100% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
7.47E+03 90% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-915
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilutk
Li CFS-LRef-1313-T01-D
Li CFS-LRef-1313-T02-D
Li CFS-LRef-1313-T03-D
Li CFS-LRef-1313-T04-D
Li CFS-LRef-1313-T05-D
Li CFS-LRef-1313-T06-D
Li CFS-LRef-1313-T07-D
Li CFS-LRef-1313-T08-D
Li CFS-LRef-1313-T09-D
Li CFS-LRef-1313-T01-E
Li CFS-LRef-1313-T02-E
Li CFS-LRef-1313-T03-E
Li CFS-LRef-1313-T04-E
Li CFS-LRef-1313-T05-E
Li CFS-LRef-1313-T06-E
Li CFS-LRef-1313-T07-E
Li CFS-LRef-1313-T08-E
Li CFS-LRef-1313-T09-E
Li CFS-LRef-1313-T01-F
Li CFS-LRef-1313-T02-F
Li CFS-LRef-1313-T03-F
Li CFS-LRef-1313-T04-F
Li CFS-LRef-1313-T05-F
Li CFS-LRef-1313-T06-F
Li CFS-LRef-1313-T07-F
Li CFS-LRef-1313-T08-F
Li CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.31E+01
1 1.10E+01
1 1.19E+01
1 1.04E+01
1 1.15E+01
1 1.23E+01
1 1.26E+01
1 1.22E+01
1 1.33E+01
1 3.67E+01
1 1.35E+01
1 1.25E+01
1 1.06E+01
1 1.22E+01
1 1.22E+01
1 1.28E+01
1 1.33E+01
1 1.29E+01
1 3.37E+01
1 1.54E+01
1 1.05E+01
1 1.04E+01
1 1.12E+01
1 1.15E+01
1 1.16E+01
1 1.25E+01
1 1.31E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.31E+01 1.8E+01 1.9E+00 6.0E+00
1.10E+01 7.7E+00 1.9E+00 6.0E+00 10 100
1.19E+01 1.5E+01 1.9E+00 6.0E+00
1.04E+01 1.8E+00 1.9E+00 6.0E+00
1.15E+01 1.7E+00 1.9E+00 6.0E+00
1.23E+01 3.1E+00 1.9E+00 6.0E+00
1.26E+01 4.2E+00 1.9E+00 6.0E+00
1.22E+01 4.8E+00 1.9E+00 6.0E+00
1.33E+01 6.9E+00 1.9E+00 6.0E+00
3.67E+01 2.5E+00 1.9E+00 6.0E+00
1.35E+01 2.4E+01 1.9E+00 6.0E+00 10 100
1.25E+01 5.8E+00 1.9E+00 6.0E+00
1.06E+01 1.2E+01 1.9E+00 6.0E+00
1.22E+01 2.2E+00 1.9E+00 6.0E+00
1.22E+01 7.5E+00 1.9E+00 6.0E+00
1.28E+01 5.1E+00 1.9E+00 6.0E+00
1.33E+01 4.6E+00 1.9E+00 6.0E+00
1.29E+01 1.6E-01 1.9E+00 6.0E+00
3.37E+01 1.2E+01 1.9E+00 6.0E+00
1.54E+01 1.2E+01 1.9E+00 6.0E+00 10 100
1.05E+01 1.1E+01 1.9E+00 6.0E+00
1.04E+01 6.1E+00 1.9E+00 6.0E+00
1.12E+01 5.5E+00 1.9E+00 6.0E+00
1.15E+01 5.4E+00 1.9E+00 6.0E+00
1.16E+01 3.7E+00 1.9E+00 6.0E+00
1.25E+01 3.2E+00 1.9E+00 6.0E+00
1.31E+01 2.1E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
8.82E+02 87% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
8.85E+02 87% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
8.77E+02 86% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-916
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Win Sample Dilutk
Mn CFS-LRef-1313-T01-D
Mn CFS-LRef-1313-T02-D
Mn CFS-LRef-1313-T03-D
Mn CFS-LRef-1313-T04-D
Mn CFS-LRef-1313-T05-D
Mn CFS-LRef-1313-T06-D
Mn CFS-LRef-1313-T07-D
Mn CFS-LRef-1313-T08-D
Mn CFS-LRef-1313-T09-D
Mn CFS-LRef-1313-T01-E
Mn CFS-LRef-1313-T02-E
Mn CFS-LRef-1313-T03-E
Mn CFS-LRef-1313-T04-E
Mn CFS-LRef-1313-T05-E
Mn CFS-LRef-1313-T06-E
Mn CFS-LRef-1313-T07-E
Mn CFS-LRef-1313-T08-E
Mn CFS-LRef-1313-T09-E
Mn CFS-LRef-1313-T01-F
Mn CFS-LRef-1313-T02-F
Mn CFS-LRef-1313-T03-F
Mn CFS-LRef-1313-T04-F
Mn CFS-LRef-1313-T05-F
Mn CFS-LRef-1313-T06-F
Mn CFS-LRef-1313-T07-F
Mn CFS-LRef-1313-T08-F
Mn CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.64E+04
1 2.48E+04
1 6.63E+03
1 1.90E+03
1 3.16E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.67E+04
1 2.56E+04
1 6.73E+03
1 1.85E+03
1 2.90E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 2.90E+04
1 2.58E+04
1 6.72E+03
1 1.79E+03
1 3.22E+01
1 4.78E+00 E
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.64E+04 6.1E-01 2.0E+00 6.4E+00
2.48E+04 2.5E-01 2.0E+00 6.4E+00 10 100
6.63E+03 9.8E-01 2.0E+00 6.4E+00
1.90E+03 8.7E-01 2.0E+00 6.4E+00
3.16E+01 1.8E+00 2.0E+00 6.4E+00
1.00E+00 9.6E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+02 2.0E+00 6.4E+00
3.67E+04 3.1E+00 2.0E+00 6.4E+00
2.56E+04 7.2E-01 2.0E+00 6.4E+00 10 100
6.73E+03 4.7E-01 2.0E+00 6.4E+00
1.85E+03 7.5E-01 2.0E+00 6.4E+00
2.90E+01 7.4E-01 2.0E+00 6.4E+00
1.00E+00 7.5E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 5.4E-01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
2.90E+04 6.2E+01 2.0E+00 6.4E+00
2.58E+04 3.2E-01 2.0E+00 6.4E+00 10 100
6.72E+03 1.1E+00 2.0E+00 6.4E+00
1.79E+03 1.1E+00 2.0E+00 6.4E+00
3.22E+01 1.4E+00 2.0E+00 6.4E+00
4.78E+00 2.1E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 8.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
2.58E+04 96% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
2.65E+04 93% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52PM EPA Interlab LRef 1313-1316 CFS
2.69E+04 104% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:OOPM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-917
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dilutk
Mg CFS-LRef-1313-T01-D
Mg CFS-LRef-1313-T02-D
Mg CFS-LRef-1313-T03-D
Mg CFS-LRef-1313-T04-D
Mg CFS-LRef-1313-T05-D
Mg CFS-LRef-1313-T06-D
Mg CFS-LRef-1313-T07-D
Mg CFS-LRef-1313-T08-D
Mg CFS-LRef-1313-T09-D
Mg CFS-LRef-1313-T01-E
Mg CFS-LRef-1313-T02-E
Mg CFS-LRef-1313-T03-E
Mg CFS-LRef-1313-T04-E
Mg CFS-LRef-1313-T05-E
Mg CFS-LRef-1313-T06-E
Mg CFS-LRef-1313-T07-E
Mg CFS-LRef-1313-T08-E
Mg CFS-LRef-1313-T09-E
Mg CFS-LRef-1313-T01-F
Mg CFS-LRef-1313-T02-F
Mg CFS-LRef-1313-T03-F
Mg CFS-LRef-1313-T04-F
Mg CFS-LRef-1313-T05-F
Mg CFS-LRef-1313-T06-F
Mg CFS-LRef-1313-T07-F
Mg CFS-LRef-1313-T08-F
Mg CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.15E+05
1 1.39E+05
1 7.39E+04
1 6.68E+04
1 5.79E+04
1 2.95E+04
1 6.76E+02
1 3.54E+01
1 2.21E+01
1 2.53E+05
1 1.42E+05
1 7.83E+04
1 6.50E+04
1 5.31 E+04
1 3.04E+04
1 6.55E+02
1 3.31 E+01
1 1.52E+01
1 1.93E+05
1 1.47E+05
1 7. 61 E+04
1 6.20E+04
1 5.76E+04
1 2. 91 E+04
1 6.89E+02
1 3.48E+01
1 1.91 E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.15E+05 4.3E-01 1.0E+00 3.2E+00
1.39E+05 5.5E-01 1.0E+00 3.2E+00 1000 100
7.39E+04 1.2E+00 1.0E+00 3.2E+00
6.68E+04 1.7E+00 1.0E+00 3.2E+00
5.79E+04 6.7E-01 1.0E+00 3.2E+00
2.95E+04 2.8E-01 1.0E+00 3.2E+00
6.76E+02 1.1E+00 1.0E+00 3.2E+00
3.54E+01 6.7E+00 1.0E+00 3.2E+00
2.21 E+01 6.0E+01 1.0E+00 3.2E+00
2.53E+05 2.7E+00 1.0E+00 3.2E+00
1.42E+05 1.0E+00 1.0E+00 3.2E+00 1000 100
7.83E+04 4.0E-01 1.0E+00 3.2E+00
6.50E+04 1.2E+00 1.0E+00 3.2E+00
5.31 E+04 8.3E-01 1.0E+00 3.2E+00
3.04E+04 1.3E+00 1.0E+00 3.2E+00
6.55E+02 5.8E-01 1.0E+00 3.2E+00
3.31 E+01 2.7E+00 1.0E+00 3.2E+00
1.52E+01 7.2E+01 1.0E+00 3.2E+00
1.93E+05 3.9E+01 1.0E+00 3.2E+00
1.47E+05 2.4E-01 1.0E+00 3.2E+00 1000 100
7.61 E+04 1.4E+00 1.0E+00 3.2E+00
6.20E+04 3.5E-01 1.0E+00 3.2E+00
5.76E+04 6.9E-01 1.0E+00 3.2E+00
2.91 E+04 5.0E-01 1.0E+00 3.2E+00
6.89E+02 2.2E+00 1.0E+00 3.2E+00
3.48E+01 2.9E+01 1.0E+00 3.2E+00
1.91 E+01 3.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.40E+05 90% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
1.43E+05 89% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.47E+05 85% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:OOPM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-918
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilutk
Mo CFS-LRef-1313-T01-D
Mo CFS-LRef-1313-T02-D
Mo CFS-LRef-1313-T03-D
Mo CFS-LRef-1313-T04-D
Mo CFS-LRef-1313-T05-D
Mo CFS-LRef-1313-T06-D
Mo CFS-LRef-1313-T07-D
Mo CFS-LRef-1313-T08-D
Mo CFS-LRef-1313-T09-D
Mo CFS-LRef-1313-T01-E
Mo CFS-LRef-1313-T02-E
Mo CFS-LRef-1313-T03-E
Mo CFS-LRef-1313-T04-E
Mo CFS-LRef-1313-T05-E
Mo CFS-LRef-1313-T06-E
Mo CFS-LRef-1313-T07-E
Mo CFS-LRef-1313-T08-E
Mo CFS-LRef-1313-T09-E
Mo CFS-LRef-1313-T01-F
Mo CFS-LRef-1313-T02-F
Mo CFS-LRef-1313-T03-F
Mo CFS-LRef-1313-T04-F
Mo CFS-LRef-1313-T05-F
Mo CFS-LRef-1313-T06-F
Mo CFS-LRef-1313-T07-F
Mo CFS-LRef-1313-T08-F
Mo CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.33E+02
1 1.09E+01
1 9.16E+00
1 1.10E+01
1 1.25E+02
1 4.27E+02
1 1.08E+03
1 1.74E+03
1 1.57E+03
1 1.11E+02
1 1.03E+01
1 7.13E+00
1 9.14E+00
1 1.35E+02
1 4.07E+02
1 1.09E+03
1 1.68E+03
1 1.47E+03
1 1.01E+02
1 1.09E+01
1 6.29E+00
1 9.61 E+00
1 1.25E+02
1 3.98E+02
1 1.05E+03
1 1.71E+03
1 1.40E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+02 1.2E+01 1.2E+00 3.8E+00
1.09E+01 1.0E+01 1.2E+00 3.8E+00 10 100
9.16E+00 2.1E+01 1.2E+00 3.8E+00
1.10E+01 7.2E+00 1.2E+00 3.8E+00
1.25E+02 7.8E-01 1.2E+00 3.8E+00
4.27E+02 7.7E-01 1.2E+00 3.8E+00
1.08E+03 1.2E+00 1.2E+00 3.8E+00
1.74E+03 5.5E-01 1.2E+00 3.8E+00
1.57E+03 8.6E-01 1.2E+00 3.8E+00
1.11E+02 7.2E+00 1.2E+00 3.8E+00
1.03E+01 3.2E+01 1.2E+00 3.8E+00 10 100
7.13E+00 3.1E+01 1.2E+00 3.8E+00
9.14E+00 1.8E+01 1.2E+00 3.8E+00
1.35E+02 1.9E+00 1.2E+00 3.8E+00
4.07E+02 8.7E-01 1.2E+00 3.8E+00
1.09E+03 9.2E-01 1.2E+00 3.8E+00
1.68E+03 3.0E-01 1.2E+00 3.8E+00
1.47E+03 2.9E-01 1.2E+00 3.8E+00
1.01E+02 5.5E+01 1.2E+00 3.8E+00
1.09E+01 1.8E+01 1.2E+00 3.8E+00 10 100
6.29E+00 1.2E+01 1.2E+00 3.8E+00
9.61 E+00 3.7E+00 1.2E+00 3.8E+00
1.25E+02 1.0E+00 1.2E+00 3.8E+00
3.98E+02 1.2E+00 1.2E+00 3.8E+00
1.05E+03 1.4E+00 1.2E+00 3.8E+00
1.71E+03 9.3E-01 1.2E+00 3.8E+00
1.40E+03 6.5E-01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.08E+03 107% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
9.85E+02 97% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.06E+03 105% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-919
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilutk
Ni CFS-LRef-1313-T01-D
Ni CFS-LRef-1313-T02-D
Ni CFS-LRef-1313-T03-D
Ni CFS-LRef-1313-T04-D
Ni CFS-LRef-1313-T05-D
Ni CFS-LRef-1313-T06-D
Ni CFS-LRef-1313-T07-D
Ni CFS-LRef-1313-T08-D
Ni CFS-LRef-1313-T09-D
Ni CFS-LRef-1313-T01-E
Ni CFS-LRef-1313-T02-E
Ni CFS-LRef-1313-T03-E
Ni CFS-LRef-1313-T04-E
Ni CFS-LRef-1313-T05-E
Ni CFS-LRef-1313-T06-E
Ni CFS-LRef-1313-T07-E
Ni CFS-LRef-1313-T08-E
Ni CFS-LRef-1313-T09-E
Ni CFS-LRef-1313-T01-F
Ni CFS-LRef-1313-T02-F
Ni CFS-LRef-1313-T03-F
Ni CFS-LRef-1313-T04-F
Ni CFS-LRef-1313-T05-F
Ni CFS-LRef-1313-T06-F
Ni CFS-LRef-1313-T07-F
Ni CFS-LRef-1313-T08-F
Ni CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 6.68E+03
1 6.58E+03
1 2.13E+03
1 2.61 E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 6.78E+03
1 6.69E+03
1 2.16E+03
1 2.58E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 5.80E+03
1 6.74E+03
1 2.08E+03
1 2.53E+02
1 2.91 E+00 E
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.68E+03 7.5E-01 1.8E+00 5.7E+00
6.58E+03 1.1 E+00 1.8E+00 5.7E+00 10 100
2.13E+03 6.7E-01 1.8E+00 5.7E+00
2.61 E+02 1.8E+00 1.8E+00 5.7E+00
9.00E-01 4.2E+03 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
9.00E-01 3.3E+02 1.8E+00 5.7E+00
9.00E-01 9.9E+01 1.8E+00 5.7E+00
9.00E-01 3.5E+01 1.8E+00 5.7E+00
6.78E+03 2.2E+00 1.8E+00 5.7E+00
6.69E+03 1.1 E+00 1.8E+00 5.7E+00 10 100
2.16E+03 1.3E+00 1.8E+00 5.7E+00
2.58E+02 5.5E-01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 3.5E+01 1.8E+00 5.7E+00
9.00E-01 1.4E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+01 1.8E+00 5.7E+00
9.00E-01 3.5E+01 1.8E+00 5.7E+00
5.80E+03 4.5E+01 1.8E+00 5.7E+00
6.74E+03 7.6E-01 1.8E+00 5.7E+00 10 100
2.08E+03 3.2E-01 1.8E+00 5.7E+00
2.53E+02 1.1 E+00 1.8E+00 5.7E+00
2.91 E+00 6.0E+00 1.8E+00 5.7E+00
9.00E-01 4.2E+01 1.8E+00 5.7E+00
9.00E-01 4.3E+01 1.8E+00 5.7E+00
9.00E-01 1.3E+03 1.8E+00 5.7E+00
9.00E-01 5.0E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
7.54E+03 96% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
7.59E+03 90% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
7.67E+03 94% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-920
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilutk
P CFS-LRef-1313-T01-D
P CFS-LRef-1313-T02-D
P CFS-LRef-1313-T03-D
P CFS-LRef-1313-T04-D
P CFS-LRef-1313-T05-D
P CFS-LRef-1313-T06-D
P CFS-LRef-1313-T07-D
P CFS-LRef-1313-T08-D
P CFS-LRef-1313-T09-D
P CFS-LRef-1313-T01-E
P CFS-LRef-1313-T02-E
P CFS-LRef-1313-T03-E
P CFS-LRef-1313-T04-E
P CFS-LRef-1313-T05-E
P CFS-LRef-1313-T06-E
P CFS-LRef-1313-T07-E
P CFS-LRef-1313-T08-E
P CFS-LRef-1313-T09-E
P CFS-LRef-1313-T01-F
P CFS-LRef-1313-T02-F
P CFS-LRef-1313-T03-F
P CFS-LRef-1313-T04-F
P CFS-LRef-1313-T05-F
P CFS-LRef-1313-T06-F
P CFS-LRef-1313-T07-F
P CFS-LRef-1313-T08-F
P CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 3.49E+03
1 3.77E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 4.39E+00 E
1 1.78E+01
1 5.12E+01
1 6.36E+01
1 7.26E+01
1 2.84E+03
1 2.84E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 5.88E+00 E
1 2.21E+01
1 5.65E+01
1 4.55E+01
1 6.51 E+01
1 2.90E+03
1 3.22E+01
1 1.85E+00 U1/2
1 1.85E+00 U1/2
1 5.10E+00 E
1 1.98E+01
1 4.79E+01
1 5.40E+01
1 7.55E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.49E+03 2.7E-01 3.7E+00 1.2E+01
3.77E+01 6.7E+01 3.7E+00 1.2E+01 1000 100
1.85E+00 2.4E+03 3.7E+00 1.2E+01
1.85E+00 3.3E+03 3.7E+00 1.2E+01
4.39E+00 8.4E+02 3.7E+00 1.2E+01
1.78E+01 2.4E+01 3.7E+00 1.2E+01
5.12E+01 4.1E+00 3.7E+00 1.2E+01
6.36E+01 3.3E+01 3.7E+00 1.2E+01
7.26E+01 7.0E+00 3.7E+00 1.2E+01
2.84E+03 2.5E+00 3.7E+00 1.2E+01
2.84E+01 3.9E+03 3.7E+00 1.2E+01 1000 100
1.85E+00 2.3E+02 3.7E+00 1.2E+01
1.85E+00 3.3E+02 3.7E+00 1.2E+01
5.88E+00 1.6E+02 3.7E+00 1.2E+01
2.21E+01 6.8E+01 3.7E+00 1.2E+01
5.65E+01 3.2E+01 3.7E+00 1.2E+01
4.55E+01 1.5E+01 3.7E+00 1.2E+01
6.51 E+01 1.9E+01 3.7E+00 1.2E+01
2.90E+03 1.7E+01 3.7E+00 1.2E+01
3.22E+01 2.8E+01 3.7E+00 1.2E+01 1000 100
1.85E+00 1.3E+01 3.7E+00 1.2E+01
1.85E+00 2.2E+01 3.7E+00 1.2E+01
5.10E+00 3.1E+01 3.7E+00 1.2E+01
1.98E+01 1.5E+03 3.7E+00 1.2E+01
4.79E+01 3.8E+01 3.7E+00 1.2E+01
5.40E+01 2.9E+01 3.7E+00 1.2E+01
7.55E+01 2.6E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03 PM EPA Interlab LRef 1313-1316 CFS
1.07E+03 103% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
9.44E+02 92% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/1 1 1 1 :35 AM EPA Interlab LRef 1 31 3-1 31 6 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.02E+03 99% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-921
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-LRef-1313-T01-D
CFS-LRef-1313-T02-D
CFS-LRef-1313-T03-D
CFS-LRef-1313-T04-D
CFS-LRef-1313-T05-D
CFS-LRef-1313-T06-D
CFS-LRef-1313-T07-D
CFS-LRef-1313-T08-D
CFS-LRef-1313-T09-D
CFS-LRef-1313-T01-E
CFS-LRef-1313-T02-E
CFS-LRef-1313-T03-E
CFS-LRef-1313-T04-E
CFS-LRef-1313-T05-E
CFS-LRef-1313-T06-E
CFS-LRef-1313-T07-E
CFS-LRef-1313-T08-E
CFS-LRef-1313-T09-E
CFS-LRef-1313-T01-F
CFS-LRef-1313-T02-F
CFS-LRef-1313-T03-F
CFS-LRef-1313-T04-F
CFS-LRef-1313-T05-F
CFS-LRef-1313-T06-F
CFS-LRef-1313-T07-F
CFS-LRef-1313-T08-F
CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.48E+04
1 1.84E+04
1 1.19E+04
1 1.02E+04
1 2.59E+05
1 3.52E+05
1 5.55E+05
1 2.56E+06
1 2.65E+06
1 2.57E+04
1 1.90E+04
1 1.23E+04
1 9.84E+03
1 2.57E+05
1 3.53E+05
1 5.71 E+05
1 2.69E+06
1 2.57E+06
1 2.61E+04
1 1.92E+04
1 1.22E+04
1 9.57E+03
1 2.58E+05
1 3.47E+05
1 5.61 E+05
1 2.60E+06
1 2.53E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.48E+04 1.6E+00 1.6E+00 5.1E+00
1.84E+04 5.9E-01 1.6E+00 5.1E+00 1000 100
1.19E+04 9.6E-01 1.6E+00 5.1E+00
1.02E+04 1.4E+00 1.6E+00 5.1E+00
2.59E+05 8.0E-01 1.6E+00 5.1E+00
3.52E+05 3.9E-01 1.6E+00 5.1E+00
5.55E+05 9.2E-01 1.6E+00 5.1E+00
2.56E+06 6.6E-01 1.6E+00 5.1E+00
2.65E+06 5.2E-01 1.6E+00 5.1E+00
2.57E+04 1.2E+00 1.6E+00 5.1E+00
1.90E+04 5.5E-01 1.6E+00 5.1E+00 1000 100
1.23E+04 5.3E-01 1.6E+00 5.1E+00
9.84E+03 9.6E-01 1.6E+00 5.1E+00
2.57E+05 4.9E-01 1.6E+00 5.1E+00
3.53E+05 1.0E+00 1.6E+00 5.1E+00
5.71 E+05 1.8E+00 1.6E+00 5.1E+00
2.69E+06 8.1E-01 1.6E+00 5.1E+00
2.57E+06 1.4E+00 1.6E+00 5.1E+00
2.61 E+04 1.5E+01 1.6E+00 5.1E+00
1.92E+04 4.9E-01 1.6E+00 5.1E+00 1000 100
1.22E+04 1.5E+00 1.6E+00 5.1E+00
9.57E+03 4.0E-01 1.6E+00 5.1E+00
2.58E+05 8.2E-01 1.6E+00 5.1E+00
3.47E+05 5.9E-01 1.6E+00 5.1E+00
5.61 E+05 2.0E+00 1.6E+00 5.1E+00
2.60E+06 1.1E+00 1.6E+00 5.1E+00
2.53E+06 6.6E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.93E+04 88% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18PM EPA Interlab LRef 1313-1316 CFS
1.98E+04 89% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52PM EPA Interlab LRef 1313-1316 CFS
2.00E+04 83% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:OOPM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-922
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
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Sample Dilutic
CFS-LRef-1313-T01-D
CFS-LRef-1313-T02-D
CFS-LRef-1313-T03-D
CFS-LRef-1313-T04-D
CFS-LRef-1313-T05-D
CFS-LRef-1313-T06-D
CFS-LRef-1313-T07-D
CFS-LRef-1313-T08-D
CFS-LRef-1313-T09-D
CFS-LRef-1313-T01-E
CFS-LRef-1313-T02-E
CFS-LRef-1313-T03-E
CFS-LRef-1313-T04-E
CFS-LRef-1313-T05-E
CFS-LRef-1313-T06-E
CFS-LRef-1313-T07-E
CFS-LRef-1313-T08-E
CFS-LRef-1313-T09-E
CFS-LRef-1313-T01-F
CFS-LRef-1313-T02-F
CFS-LRef-1313-T03-F
CFS-LRef-1313-T04-F
CFS-LRef-1313-T05-F
CFS-LRef-1313-T06-F
CFS-LRef-1313-T07-F
CFS-LRef-1313-T08-F
CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.48E+02
1 2.47E+02
1 9.78E+01
1 6.60E+01
1 1.04E+02
1 1.64E+02
1 5.89E+02
1 4.76E+02
1 2.95E+02
1 4.86E+02
1 2.38E+02
1 1.21E+02
1 8.55E+01
1 1.04E+02
1 1.57E+02
1 5.62E+02
1 4.04E+02
1 2.77E+02
1 4.28E+02
1 2.39E+02
1 1.16E+02
1 5.76E+01
1 9.58E+01
1 1.40E+02
1 5.49E+02
1 4.53E+02
1 2.78E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.48E+02 2.7E+00 1.5E+01 4.8E+01
2.47E+02 1.6E+01 1.5E+01 4.8E+01 10 100
9.78E+01 1.0E+01 1.5E+01 4.8E+01
6.60E+01 7.0E+00 1.5E+01 4.8E+01
1.04E+02 1.3E+01 1.5E+01 4.8E+01
1.64E+02 1.1E+01 1.5E+01 4.8E+01
5.89E+02 2.2E+00 1.5E+01 4.8E+01
4.76E+02 4.0E+00 1.5E+01 4.8E+01
2.95E+02 1.9E+00 1.5E+01 4.8E+01
4.86E+02 4.5E+00 1.5E+01 4.8E+01
2.38E+02 6.9E+00 1.5E+01 4.8E+01 10 100
1.21E+02 4.8E+00 1.5E+01 4.8E+01
8.55E+01 1.9E+01 1.5E+01 4.8E+01
1.04E+02 8.5E+00 1.5E+01 4.8E+01
1.57E+02 3.9E+00 1.5E+01 4.8E+01
5.62E+02 1.3E+00 1.5E+01 4.8E+01
4.04E+02 7.5E-01 1.5E+01 4.8E+01
2.77E+02 4.1E+00 1.5E+01 4.8E+01
4.28E+02 1.4E+01 1.5E+01 4.8E+01
2.39E+02 7.1E+00 1.5E+01 4.8E+01 10 100
1.16E+02 1.4E+01 1.5E+01 4.8E+01
5.76E+01 1.7E+01 1.5E+01 4.8E+01
9.58E+01 1.2E+01 1.5E+01 4.8E+01
1.40E+02 8.0E+00 1.5E+01 4.8E+01
5.49E+02 2.9E+00 1.5E+01 4.8E+01
4.53E+02 3.3E+00 1.5E+01 4.8E+01
2.78E+02 4.1E+00 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.27E+03 103% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
1.19E+03 95% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.25E+03 101% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-923
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilutk
Si CFS-LRef-1313-T01-D
Si CFS-LRef-1313-T02-D
Si CFS-LRef-1313-T03-D
Si CFS-LRef-1313-T04-D
Si CFS-LRef-1313-T05-D
Si CFS-LRef-1313-T06-D
Si CFS-LRef-1313-T07-D
Si CFS-LRef-1313-T08-D
Si CFS-LRef-1313-T09-D
Si CFS-LRef-1313-T01-E
Si CFS-LRef-1313-T02-E
Si CFS-LRef-1313-T03-E
Si CFS-LRef-1313-T04-E
Si CFS-LRef-1313-T05-E
Si CFS-LRef-1313-T06-E
Si CFS-LRef-1313-T07-E
Si CFS-LRef-1313-T08-E
Si CFS-LRef-1313-T09-E
Si CFS-LRef-1313-T01-F
Si CFS-LRef-1313-T02-F
Si CFS-LRef-1313-T03-F
Si CFS-LRef-1313-T04-F
Si CFS-LRef-1313-T05-F
Si CFS-LRef-1313-T06-F
Si CFS-LRef-1313-T07-F
Si CFS-LRef-1313-T08-F
Si CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.53E+05
1 7.97E+04
1 2.60E+04
1 4.35E+03
1 1.01E+03
1 5.76E+02
1 5.05E+02
1 2.40E+02
1 2.24E+02
1 1.54E+05
1 7.90E+04
1 2.61E+04
1 4.16E+03
1 9.84E+02
1 5.87E+02
1 5.34E+02
1 2.60E+02
1 2.25E+02
1 1.69E+05
1 8.77E+04
1 2.53E+04
1 4.20E+03
1 1.01E+03
1 5.63E+02
1 4.94E+02
1 2.17E+02
1 2.25E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+05 6.0E-01 1.1E+00 3.5E+00
7.97E+04 3.1E-01 1.1E+00 3.5E+00 1000 100
2.60E+04 1.1E+00 1.1E+00 3.5E+00
4.35E+03 1.2E+00 1.1E+00 3.5E+00
1.01E+03 9.3E-02 1.1E+00 3.5E+00
5.76E+02 8.4E-01 1.1E+00 3.5E+00
5.05E+02 8.0E-01 1.1E+00 3.5E+00
2.40E+02 2.5E+00 1.1E+00 3.5E+00
2.24E+02 2.3E+00 1.1E+00 3.5E+00
1.54E+05 1.2E+00 1.1E+00 3.5E+00
7.90E+04 5.7E-01 1.1E+00 3.5E+00 1000 100
2.61E+04 1.0E+00 1.1E+00 3.5E+00
4.16E+03 7.7E-01 1.1E+00 3.5E+00
9.84E+02 4.5E-01 1.1E+00 3.5E+00
5.87E+02 9.9E-01 1.1E+00 3.5E+00
5.34E+02 1.2E+00 1.1E+00 3.5E+00
2.60E+02 2.8E-01 1.1E+00 3.5E+00
2.25E+02 1.3E+00 1.1E+00 3.5E+00
1.69E+05 1.1E+01 1.1E+00 3.5E+00
8.77E+04 5.3E-01 1.1E+00 3.5E+00 1000 100
2.53E+04 1.2E+00 1.1E+00 3.5E+00
4.20E+03 1.1E+00 1.1E+00 3.5E+00
1.01E+03 5.5E-01 1.1E+00 3.5E+00
5.63E+02 3.7E-01 1.1E+00 3.5E+00
4.94E+02 1.8E+00 1.1E+00 3.5E+00
2.17E+02 3.3E+00 1.1E+00 3.5E+00
2.25E+02 1.4E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
8.06E+04 87% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
7.99E+04 86% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
8.86E+04 90% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-924
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilutic
Na CFS-LRef-1313-T01-D
Na CFS-LRef-1313-T02-D
Na CFS-LRef-1313-T03-D
Na CFS-LRef-1313-T04-D
Na CFS-LRef-1313-T05-D
Na CFS-LRef-1313-T06-D
Na CFS-LRef-1313-T07-D
Na CFS-LRef-1313-T08-D
Na CFS-LRef-1313-T09-D
Na CFS-LRef-1313-T01-E
Na CFS-LRef-1313-T02-E
Na CFS-LRef-1313-T03-E
Na CFS-LRef-1313-T04-E
Na CFS-LRef-1313-T05-E
Na CFS-LRef-1313-T06-E
Na CFS-LRef-1313-T07-E
Na CFS-LRef-1313-T08-E
Na CFS-LRef-1313-T09-E
Na CFS-LRef-1313-T01-F
Na CFS-LRef-1313-T02-F
Na CFS-LRef-1313-T03-F
Na CFS-LRef-1313-T04-F
Na CFS-LRef-1313-T05-F
Na CFS-LRef-1313-T06-F
Na CFS-LRef-1313-T07-F
Na CFS-LRef-1313-T08-F
Na CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 2.94E+04
1 2.77E+04
1 2.07E+04
1 2.04E+04
1 2.01E+04
1 1.91E+04
1 1.86E+04
1 1.94E+04
1 1.97E+04
1 3.14E+04
1 2.80E+04
1 2.24E+04
1 2.07E+04
1 2.02E+04
1 1.98E+04
1 1.90E+04
1 1.96E+04
1 2.29E+04
1 3.01 E+04
1 2.82E+04
1 2.15E+04
1 1.96E+04
1 2.07E+04
1 2.00E+04
1 2. 01 E+04
1 1.95E+04
1 2.02E+04
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.94E+04 5.2E-01 2.5E+00 8.0E+00
2.77E+04 3.7E-01 2.5E+00 8.0E+00 1000 100
2.07E+04 7.6E-01 2.5E+00 8.0E+00
2.04E+04 2.8E-01 2.5E+00 8.0E+00
2.01 E+04 8.4E-01 2.5E+00 8.0E+00
1.91 E+04 9.5E-01 2.5E+00 8.0E+00
1.86E+04 1.2E+00 2.5E+00 8.0E+00
1.94E+04 1.1E+00 2.5E+00 8.0E+00
1.97E+04 5.3E-01 2.5E+00 8.0E+00
3.14E+04 1.1E+00 2.5E+00 8.0E+00
2.80E+04 6.7E-01 2.5E+00 8.0E+00 1000 100
2.24E+04 3.3E-01 2.5E+00 8.0E+00
2.07E+04 1.3E+00 2.5E+00 8.0E+00
2.02E+04 1.1E+00 2.5E+00 8.0E+00
1.98E+04 1.2E+00 2.5E+00 8.0E+00
1.90E+04 9.8E-01 2.5E+00 8.0E+00
1.96E+04 7.0E-01 2.5E+00 8.0E+00
2.29E+04 7.0E-01 2.5E+00 8.0E+00
3.01 E+04 1.3E+01 2.5E+00 8.0E+00
2.82E+04 1.5E+00 2.5E+00 8.0E+00 1000 100
2.15E+04 9.0E-01 2.5E+00 8.0E+00
1.96E+04 9.4E-01 2.5E+00 8.0E+00
2.07E+04 9.4E-01 2.5E+00 8.0E+00
2.00E+04 5.0E-01 2.5E+00 8.0E+00
2.01 E+04 6.8E-01 2.5E+00 8.0E+00
1.95E+04 1.1E+00 2.5E+00 8.0E+00
2.02E+04 6.7E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
2.86E+04 89% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
2.88E+04 85% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
2.90E+04 87% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-925
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilutic
Sr CFS-LRef-1313-T01-D
Sr CFS-LRef-1313-T02-D
Sr CFS-LRef-1313-T03-D
Sr CFS-LRef-1313-T04-D
Sr CFS-LRef-1313-T05-D
Sr CFS-LRef-1313-T06-D
Sr CFS-LRef-1313-T07-D
Sr CFS-LRef-1313-T08-D
Sr CFS-LRef-1313-T09-D
Sr CFS-LRef-1313-T01-E
Sr CFS-LRef-1313-T02-E
Sr CFS-LRef-1313-T03-E
Sr CFS-LRef-1313-T04-E
Sr CFS-LRef-1313-T05-E
Sr CFS-LRef-1313-T06-E
Sr CFS-LRef-1313-T07-E
Sr CFS-LRef-1313-T08-E
Sr CFS-LRef-1313-T09-E
Sr CFS-LRef-1313-T01-F
Sr CFS-LRef-1313-T02-F
Sr CFS-LRef-1313-T03-F
Sr CFS-LRef-1313-T04-F
Sr CFS-LRef-1313-T05-F
Sr CFS-LRef-1313-T06-F
Sr CFS-LRef-1313-T07-F
Sr CFS-LRef-1313-T08-F
Sr CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.26E+03
1 1.31E+03
1 9.45E+02
1 1.56E+03
1 3.66E+03
1 3.63E+03
1 4.01 E+03
1 3.91 E+03
1 3.28E+03
1 1.43E+03
1 1.28E+03
1 9.67E+02
1 1.48E+03
1 3.49E+03
1 3.70E+03
1 4.06E+03
1 3.69E+03
1 3.20E+03
1 1.21 E+03
1 1.30E+03
1 9.46E+02
1 1.45E+03
1 3.50E+03
1 3.68E+03
1 4. 11 E+03
1 3.69E+03
1 3. 11 E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.26E+03 5.0E-01 1.0E+00 3.2E+00
1.31 E+03 1.2E+00 1.0E+00 3.2E+00 1000 100
9.45E+02 1.4E+00 1.0E+00 3.2E+00
1.56E+03 1.3E+00 1.0E+00 3.2E+00
3.66E+03 1.0E+00 1.0E+00 3.2E+00
3.63E+03 4.8E-01 1.0E+00 3.2E+00
4.01 E+03 2.0E+00 1.0E+00 3.2E+00
3.91 E+03 1.4E-01 1.0E+00 3.2E+00
3.28E+03 8.5E-01 1.0E+00 3.2E+00
1.43E+03 2.2E+00 1.0E+00 3.2E+00
1.28E+03 1.2E+00 1.0E+00 3.2E+00 1000 100
9.67E+02 8.0E-01 1.0E+00 3.2E+00
1.48E+03 1.3E+00 1.0E+00 3.2E+00
3.49E+03 1.2E+00 1.0E+00 3.2E+00
3.70E+03 5.7E-01 1.0E+00 3.2E+00
4.06E+03 5.6E-01 1.0E+00 3.2E+00
3.69E+03 1.5E+00 1.0E+00 3.2E+00
3.20E+03 4.2E-01 1.0E+00 3.2E+00
1.21 E+03 4.2E+01 1.0E+00 3.2E+00
1.30E+03 6.9E-01 1.0E+00 3.2E+00 1000 100
9.46E+02 5.5E-01 1.0E+00 3.2E+00
1.45E+03 7.0E-01 1.0E+00 3.2E+00
3.50E+03 8.1E-01 1.0E+00 3.2E+00
3.68E+03 4.5E-01 1.0E+00 3.2E+00
4.11E+03 1.4E+00 1.0E+00 3.2E+00
3.69E+03 9.4E-01 1.0E+00 3.2E+00
3.11E+03 5.9E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
2.23E+03 92% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18PM EPA Interlab LRef 1313-1316 CFS
2.23E+03 94% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52PM EPA Interlab LRef 1313-1316 CFS
2.26E+03 96% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:OOPM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-926
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilutk
S CFS-LRef-1313-T01-D
S CFS-LRef-1313-T02-D
S CFS-LRef-1313-T03-D
S CFS-LRef-1313-T04-D
S CFS-LRef-1313-T05-D
S CFS-LRef-1313-T06-D
S CFS-LRef-1313-T07-D
S CFS-LRef-1313-T08-D
S CFS-LRef-1313-T09-D
S CFS-LRef-1313-T01-E
S CFS-LRef-1313-T02-E
S CFS-LRef-1313-T03-E
S CFS-LRef-1313-T04-E
S CFS-LRef-1313-T05-E
S CFS-LRef-1313-T06-E
S CFS-LRef-1313-T07-E
S CFS-LRef-1313-T08-E
S CFS-LRef-1313-T09-E
S CFS-LRef-1313-T01-F
S CFS-LRef-1313-T02-F
S CFS-LRef-1313-T03-F
S CFS-LRef-1313-T04-F
S CFS-LRef-1313-T05-F
S CFS-LRef-1313-T06-F
S CFS-LRef-1313-T07-F
S CFS-LRef-1313-T08-F
S CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 7.75E+05
1 7.02E+05
1 6.07E+05
1 5.96E+05
1 6.60E+05
1 6.80E+05
1 7.63E+05
1 1.01E+06
1 1.31E+06
1 7.89E+05
1 7.10E+05
1 6.18E+05
1 5.87E+05
1 6.61 E+05
1 6.88E+05
1 7.73E+05
1 9.50E+05
1 1.19E+06
1 7.39E+05
1 7.25E+05
1 6.01 E+05
1 5.63E+05
1 6.52E+05
1 6.64E+05
1 7.50E+05
1 9.77E+05
1 1.26E+06
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.75E+05 8.9E-01 6.8E+00 2.2E+01
7.02E+05 3.8E-01 6.8E+00 2.2E+01 1000 100
6.07E+05 9.5E-01 6.8E+00 2.2E+01
5.96E+05 1.4E+00 6.8E+00 2.2E+01
6.60E+05 6.8E-01 6.8E+00 2.2E+01
6.80E+05 6.8E-01 6.8E+00 2.2E+01
7.63E+05 4.5E-01 6.8E+00 2.2E+01
1.01E+06 5.0E-01 6.8E+00 2.2E+01
1.31E+06 5.4E-01 6.8E+00 2.2E+01
7.89E+05 8.2E-01 6.8E+00 2.2E+01
7.10E+05 7.0E-01 6.8E+00 2.2E+01 1000 100
6.18E+05 5.5E-01 6.8E+00 2.2E+01
5.87E+05 9.3E-01 6.8E+00 2.2E+01
6.61 E+05 2.2E-01 6.8E+00 2.2E+01
6.88E+05 7.2E-01 6.8E+00 2.2E+01
7.73E+05 6.6E-01 6.8E+00 2.2E+01
9.50E+05 5.5E-01 6.8E+00 2.2E+01
1.19E+06 9.3E-01 6.8E+00 2.2E+01
7.39E+05 1.9E+01 6.8E+00 2.2E+01
7.25E+05 8.7E-01 6.8E+00 2.2E+01 1000 100
6.01 E+05 1.1E+00 6.8E+00 2.2E+01
5.63E+05 5.9E-01 6.8E+00 2.2E+01
6.52E+05 7.6E-01 6.8E+00 2.2E+01
6.64E+05 5.1E-01 6.8E+00 2.2E+01
7.50E+05 2.4E-01 6.8E+00 2.2E+01
9.77E+05 1.0E+00 6.8E+00 2.2E+01
1.26E+06 7.2E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03 PM EPA Interlab LRef 1313-1316 CFS
7.03E+05 85% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
7.11E+05 89% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
7.26E+05 84% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-927
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample Dilutk
CFS-LRef-1313-T01-D
CFS-LRef-1313-T02-D
CFS-LRef-1313-T03-D
CFS-LRef-1313-T04-D
CFS-LRef-1313-T05-D
CFS-LRef-1313-T06-D
CFS-LRef-1313-T07-D
CFS-LRef-1313-T08-D
CFS-LRef-1313-T09-D
CFS-LRef-1313-T01-E
CFS-LRef-1313-T02-E
CFS-LRef-1313-T03-E
CFS-LRef-1313-T04-E
CFS-LRef-1313-T05-E
CFS-LRef-1313-T06-E
CFS-LRef-1313-T07-E
CFS-LRef-1313-T08-E
CFS-LRef-1313-T09-E
CFS-LRef-1313-T01-F
CFS-LRef-1313-T02-F
CFS-LRef-1313-T03-F
CFS-LRef-1313-T04-F
CFS-LRef-1313-T05-F
CFS-LRef-1313-T06-F
CFS-LRef-1313-T07-F
CFS-LRef-1313-T08-F
CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.77E+03
1 1.04E+03
1 6.10E+02
1 3.78E+02
1 7.01 E+02
1 5.73E+02
1 3.43E+02
1 2.29E+02
1 2.18E+02
1 1.74E+03
1 1.06E+03
1 6.21 E+02
1 3.68E+02
1 7.02E+02
1 5.80E+02
1 3.57E+02
1 2.21 E+02
1 2.17E+02
1 1.65E+03
1 1.07E+03
1 6.22E+02
1 3.53E+02
1 6.94E+02
1 5.58E+02
1 3.40E+02
1 2.15E+02
1 2.05E+02
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+03 2.1E-01 4.6E+00 1.5E+01
1.04E+03 1.7E+00 4.6E+00 1.5E+01 10 100
6.10E+02 1.6E+00 4.6E+00 1.5E+01
3.78E+02 2.0E+00 4.6E+00 1.5E+01
7.01 E+02 1.4E+00 4.6E+00 1.5E+01
5.73E+02 7.1E-01 4.6E+00 1.5E+01
3.43E+02 1.4E+00 4.6E+00 1.5E+01
2.29E+02 2.8E+00 4.6E+00 1.5E+01
2.18E+02 2.4E+00 4.6E+00 1.5E+01
1.74E+03 8.9E-01 4.6E+00 1.5E+01
1.06E+03 8.1E-01 4.6E+00 1.5E+01 10 100
6.21 E+02 3.3E-01 4.6E+00 1.5E+01
3.68E+02 2.0E+00 4.6E+00 1.5E+01
7.02E+02 3.1E-01 4.6E+00 1.5E+01
5.80E+02 1.4E+00 4.6E+00 1.5E+01
3.57E+02 8.5E-01 4.6E+00 1.5E+01
2.21 E+02 6.8E-01 4.6E+00 1.5E+01
2.17E+02 3.7E+00 4.6E+00 1.5E+01
1.65E+03 1.8E+01 4.6E+00 1.5E+01
1.07E+03 5.4E-01 4.6E+00 1.5E+01 10 100
6.22E+02 2.6E+00 4.6E+00 1.5E+01
3.53E+02 9.0E-01 4.6E+00 1.5E+01
6.94E+02 4.6E-01 4.6E+00 1.5E+01
5.58E+02 7.9E-01 4.6E+00 1.5E+01
3.40E+02 2.4E+00 4.6E+00 1.5E+01
2.15E+02 3.1E+00 4.6E+00 1.5E+01
2.05E+02 5.2E+00 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
2.07E+03 102% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18PM EPA Interlab LRef 1313-1316 CFS
2.01E+03 95% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52PM EPA Interlab LRef 1313-1316 CFS
2.04E+03 97% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:OOPM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-928
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample Dilutk
CFS-LRef-1313-T01-D
CFS-LRef-1313-T02-D
CFS-LRef-1313-T03-D
CFS-LRef-1313-T04-D
CFS-LRef-1313-T05-D
CFS-LRef-1313-T06-D
CFS-LRef-1313-T07-D
CFS-LRef-1313-T08-D
CFS-LRef-1313-T09-D
CFS-LRef-1313-T01-E
CFS-LRef-1313-T02-E
CFS-LRef-1313-T03-E
CFS-LRef-1313-T04-E
CFS-LRef-1313-T05-E
CFS-LRef-1313-T06-E
CFS-LRef-1313-T07-E
CFS-LRef-1313-T08-E
CFS-LRef-1313-T09-E
CFS-LRef-1313-T01-F
CFS-LRef-1313-T02-F
CFS-LRef-1313-T03-F
CFS-LRef-1313-T04-F
CFS-LRef-1313-T05-F
CFS-LRef-1313-T06-F
CFS-LRef-1313-T07-F
CFS-LRef-1313-T08-F
CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 4.44E+01
1 1.14E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 4.25E+01
1 1.25E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 3.35E+01
1 1.25E+01
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.44E+01 2.5E+00 2.0E+00 6.4E+00
1.14E+01 5.1E-01 2.0E+00 6.4E+00 10 100
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 8.4E+01 2.0E+00 6.4E+00
1.00E+00 9.3E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+00 2.0E+00 6.4E+00
4.25E+01 3.3E+00 2.0E+00 6.4E+00
1.25E+01 1.1E+01 2.0E+00 6.4E+00 10 100
1.00E+00 4.3E+00 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+02 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00
1.00E+00 8.5E+01 2.0E+00 6.4E+00
1.00E+00 9.0E+00 2.0E+00 6.4E+00
1.00E+00 8.9E+01 2.0E+00 6.4E+00
3.35E+01 4.4E+01 2.0E+00 6.4E+00
1.25E+01 3.5E+00 2.0E+00 6.4E+00 10 100
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 3.7E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 2.4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.05E+03 104% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
9.62E+02 95% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 131 3-1 31 6 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.04E+03 102% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-929
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilutk
V CFS-LRef-1313-T01-D
V CFS-LRef-1313-T02-D
V CFS-LRef-1313-T03-D
V CFS-LRef-1313-T04-D
V CFS-LRef-1313-T05-D
V CFS-LRef-1313-T06-D
V CFS-LRef-1313-T07-D
V CFS-LRef-1313-T08-D
V CFS-LRef-1313-T09-D
V CFS-LRef-1313-T01-E
V CFS-LRef-1313-T02-E
V CFS-LRef-1313-T03-E
V CFS-LRef-1313-T04-E
V CFS-LRef-1313-T05-E
V CFS-LRef-1313-T06-E
V CFS-LRef-1313-T07-E
V CFS-LRef-1313-T08-E
V CFS-LRef-1313-T09-E
V CFS-LRef-1313-T01-F
V CFS-LRef-1313-T02-F
V CFS-LRef-1313-T03-F
V CFS-LRef-1313-T04-F
V CFS-LRef-1313-T05-F
V CFS-LRef-1313-T06-F
V CFS-LRef-1313-T07-F
V CFS-LRef-1313-T08-F
V CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 5.57E+02
1 6.76E+01
1 4.95E+01
1 3.86E+01
1 3.73E+01
1 3.69E+01
1 3.58E+01
1 3.04E+01
1 3.83E+01
1 5.77E+02
1 6.54E+01
1 4.76E+01
1 3.86E+01
1 3.73E+01
1 3.67E+01
1 3.72E+01
1 3.10E+01
1 3.75E+01
1 4.66E+02
1 6.64E+01
1 4.90E+01
1 3.81 E+01
1 3.79E+01
1 3.61 E+01
1 3.65E+01
1 3.52E+01
1 3.98E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.57E+02 5.1E-01 1.5E+00 4.8E+00
6.76E+01 1.1 E+01 1.5E+00 4.8E+00 10 100
4.95E+01 2.6E+00 1.5E+00 4.8E+00
3.86E+01 4.6E+00 1.5E+00 4.8E+00
3.73E+01 1.1E+00 1.5E+00 4.8E+00
3.69E+01 2.3E+00 1.5E+00 4.8E+00
3.58E+01 5.5E-01 1.5E+00 4.8E+00
3.04E+01 2.4E+00 1.5E+00 4.8E+00
3.83E+01 5.7E+00 1.5E+00 4.8E+00
5.77E+02 2.9E+00 1.5E+00 4.8E+00
6.54E+01 1.8E+00 1.5E+00 4.8E+00 10 100
4.76E+01 1.4E+00 1.5E+00 4.8E+00
3.86E+01 1.5E+00 1.5E+00 4.8E+00
3.73E+01 3.3E+00 1.5E+00 4.8E+00
3.67E+01 2.2E+00 1.5E+00 4.8E+00
3.72E+01 4.4E+00 1.5E+00 4.8E+00
3.10E+01 4.9E+00 1.5E+00 4.8E+00
3.75E+01 6.2E+00 1.5E+00 4.8E+00
4.66E+02 4.9E+01 1.5E+00 4.8E+00
6.64E+01 5.3E+00 1.5E+00 4.8E+00 10 100
4.90E+01 1.8E+00 1.5E+00 4.8E+00
3.81 E+01 3.9E+00 1.5E+00 4.8E+00
3.79E+01 1.3E+00 1.5E+00 4.8E+00
3.61 E+01 2.1E+00 1.5E+00 4.8E+00
3.65E+01 2.4E+00 1.5E+00 4.8E+00
3.52E+01 2.4E+00 1.5E+00 4.8E+00
3.98E+01 1.5E+00 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03 PM EPA Interlab LRef 1313-1316 CFS
1.13E+03 106% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18 PM EPA Interlab LRef 1313-1316 CFS
1.02E+03 96% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.12E+03 105% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:00 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-930
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilutk
Zn CFS-LRef-1313-T01-D
Zn CFS-LRef-1313-T02-D
Zn CFS-LRef-1313-T03-D
Zn CFS-LRef-1313-T04-D
Zn CFS-LRef-1313-T05-D
Zn CFS-LRef-1313-T06-D
Zn CFS-LRef-1313-T07-D
Zn CFS-LRef-1313-T08-D
Zn CFS-LRef-1313-T09-D
Zn CFS-LRef-1313-T01-E
Zn CFS-LRef-1313-T02-E
Zn CFS-LRef-1313-T03-E
Zn CFS-LRef-1313-T04-E
Zn CFS-LRef-1313-T05-E
Zn CFS-LRef-1313-T06-E
Zn CFS-LRef-1313-T07-E
Zn CFS-LRef-1313-T08-E
Zn CFS-LRef-1313-T09-E
Zn CFS-LRef-1313-T01-F
Zn CFS-LRef-1313-T02-F
Zn CFS-LRef-1313-T03-F
Zn CFS-LRef-1313-T04-F
Zn CFS-LRef-1313-T05-F
Zn CFS-LRef-1313-T06-F
Zn CFS-LRef-1313-T07-F
Zn CFS-LRef-1313-T08-F
Zn CFS-LRef-1313-T09-F
Sample Internal
>n Cone. Qualifier Review
ug/L | |
1 1.76E+05
1 1.89E+05
1 1.64E+05
1 2.50E+04
1 1.28E+02
1 2.43E+01
1 3.03E+01
1 2.63E+03
1 4.75E+03
1 1.76E+05
1 1.87E+05
1 1.59E+05
1 2.50E+04
1 1.04E+02
1 2.36E+01
1 4.42E+01
1 2.59E+03
1 4.60E+03
1 1.63E+05
1 1.92E+05
1 1.64E+05
1 2.50E+04
1 1.07E+02
1 3.31 E+01
1 3.01 E+01
1 2.76E+03
1 4.61 E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.76E+05 8.3E-01 1.0E+00 3.2E+00
1.89E+05 1.2E+00 1.0E+00 3.2E+00 10 100
1.64E+05 1.1E-01 1.0E+00 3.2E+00
2.50E+04 1.5E+00 1.0E+00 3.2E+00
1.28E+02 1.2E+00 1.0E+00 3.2E+00
2.43E+01 1.2E+00 1.0E+00 3.2E+00
3.03E+01 1.7E+00 1.0E+00 3.2E+00
2.63E+03 3.2E-01 1.0E+00 3.2E+00
4.75E+03 1.4E+00 1.0E+00 3.2E+00
1.76E+05 2.1E+00 1.0E+00 3.2E+00
1.87E+05 1.2E+00 1.0E+00 3.2E+00 10 100
1.59E+05 5.4E-01 1.0E+00 3.2E+00
2.50E+04 7.7E-01 1.0E+00 3.2E+00
1.04E+02 4.6E-01 1.0E+00 3.2E+00
2.36E+01 4.6E+00 1.0E+00 3.2E+00
4.42E+01 1.1E+00 1.0E+00 3.2E+00
2.59E+03 1.9E+00 1.0E+00 3.2E+00
4.60E+03 8.2E-01 1.0E+00 3.2E+00
1.63E+05 2.1 E+01 1.0E+00 3.2E+00
1.92E+05 7.2E-01 1.0E+00 3.2E+00 10 100
1.64E+05 1.9E+00 1.0E+00 3.2E+00
2.50E+04 1.1E+00 1.0E+00 3.2E+00
1.07E+02 3.8E-01 1.0E+00 3.2E+00
3.31 E+01 9.7E-01 1.0E+00 3.2E+00
3.01 E+01 1.1E+00 1.0E+00 3.2E+00
2.76E+03 1.4E+00 1.0E+00 3.2E+00
4.61 E+03 1.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 2/3/11 4:03PM EPA Interlab LRef 1313-1316 CFS
1.90E+05 92% VU ICP-OES 2/3/11 4:05 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:06PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:08PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:10PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:13PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:15PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:16PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:18PM EPA Interlab LRef 1313-1316 CFS
1.88E+05 89% VU ICP-OES 2/3/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:21 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:23PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:24PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:26PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:40PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:42PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 11:35 AM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:52PM EPA Interlab LRef 1313-1316 CFS
1.93E+05 93% VU ICP-OES 2/3/11 4:54 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:55PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:57PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 4:58PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:OOPM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:02PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:03PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 2/3/11 5:05PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                          1-931
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al EaFA-L01-1316-T01-A 1
Al EaFA-L01-1316-T02-A 1
Al EaFA-L01-1316-T03-A 1
Al EaFA-L01-1316-T04-A 1
Al EaFA-L01-1316-T05-A
Al EaFA-L01-1316-T01-B 1
Al EaFA-L01-1316-T02-B 1
Al EaFA-L01-1316-T03-B 1
Al EaFA-L01-1316-T04-B 1
Al EaFA-L01-1316-T05-B
Al EaFA-L01-1316-T01-C 1
Al EaFA-L01-1316-T02-C 1
Al EaFA-L01-1316-T03-C 1
Al EaFA-L01-1316-T04-C 1
Al EaFA-L01-1316-T05-C
Al EaFA-L01-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.24E+02
1.64E+02
2.43E+02
5.09E+02

1.30E+02
1.76E+02
2.52E+02
5.11E+02

1.18E+02
1.74E+02
2.41 E+02
4.74E+02

5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.24E+02 9.5E-01 1.0E+00 3.2E+00
1.64E+02 5.4E-01 1.0E+00 3.2E+00 1000 100
2.43E+02 2.0E+00 1.0E+00 3.2E+00
5.09E+02 3.4E+00 1.0E+00 3.2E+00

1.30E+02 2.2E+00 1.0E+00 3.2E+00
1.76E+02 1.7E+00 1.0E+00 3.2E+00 1000 100
2.52E+02 1.3E+00 1.0E+00 3.2E+00
5.11 E+02 9.1E-01 1.0E+00 3.2E+00

1.18E+02 1.3E+00 1.0E+00 3.2E+00
1.74E+02 4.6E-01 1.0E+00 3.2E+00 1000 100
2.41E+02 2.2E+00 1.0E+00 3.2E+00
4.74E+02 1.0E+00 1.0E+00 3.2E+00

5.00E-01 4.5E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.93E+02 83% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
9.83E+02 81 %VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
9.88E+02 81 %VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                                   1-932
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L01-1316-T01-A 1
Sb EaFA-L01-1316-T02-A 1
Sb EaFA-L01-1316-T03-A 1
Sb EaFA-L01-1316-T04-A 1
Sb EaFA-L01-1316-T05-A
Sb EaFA-L01-1316-T01-B 1
Sb EaFA-L01-1316-T02-B 1
Sb EaFA-L01-1316-T03-B 1
Sb EaFA-L01-1316-T04-B 1
Sb EaFA-L01-1316-T05-B
Sb EaFA-L01-1316-T01-C 1
Sb EaFA-L01-1316-T02-C 1
Sb EaFA-L01-1316-T03-C 1
Sb EaFA-L01-1316-T04-C 1
Sb EaFA-L01-1316-T05-C
Sb EaFA-L01-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.20E+02
3.20E+02
4.56E+02
6.51 E+02

2.09E+02
3.26E+02
4.52E+02
7.06E+02

1.86E+02
3.46E+02
4.62E+02
6.65E+02

3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.20E+02 8.7E+00 7.5E+00 2.4E+01
3.20E+02 4.5E+00 7.5E+00 2.4E+01 10 250
4.56E+02 1.3E+01 7.5E+00 2.4E+01
6.51E+02 3.7E+00 7.5E+00 2.4E+01

2.09E+02 6.6E+00 7.5E+00 2.4E+01
3.26E+02 1.1E+01 7.5E+00 2.4E+01 10 250
4.52E+02 2.2E+00 7.5E+00 2.4E+01
7.06E+02 2.9E+00 7.5E+00 2.4E+01

1.86E+02 6.1E+00 7.5E+00 2.4E+01
3.46E+02 7.6E+00 7.5E+00 2.4E+01 10 250
4.62E+02 5.1E+00 7.5E+00 2.4E+01
6.65E+02 1.2E+00 7.5E+00 2.4E+01

3.75E+00 1.4E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.92E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.65E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.73E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-933
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As EaFA-L01-1316-T01-A 1
As EaFA-L01-1316-T02-A 1
As EaFA-L01-1316-T03-A 1
As EaFA-L01-1316-T04-A 1
As EaFA-L01-1316-T05-A
As EaFA-L01-1316-T01-B 1
As EaFA-L01-1316-T02-B 1
As EaFA-L01-1316-T03-B 1
As EaFA-L01-1316-T04-B 1
As EaFA-L01-1316-T05-B
As EaFA-L01-1316-T01-C 1
As EaFA-L01-1316-T02-C 1
As EaFA-L01-1316-T03-C 1
As EaFA-L01-1316-T04-C 1
As EaFA-L01-1316-T05-C
As EaFA-L01-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.21E+02
1.47E+02
1.38E+02
2.12E+02

1.13E+02
1.37E+02
1.21E+02
1.82E+02

1.14E+02
1.53E+02
1.30E+02
1.72E+02

5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.21E+02 1.0E+01 1.1E+01 3.5E+01
1.47E+02 1.6E+01 1.1E+01 3.5E+01 10 250
1.38E+02 9.6E+00 1.1E+01 3.5E+01
2.12E+02 7.8E+00 1.1E+01 3.5E+01

1.13E+02 1.2E+01 1.1E+01 3.5E+01
1.37E+02 8.8E+00 1.1E+01 3.5E+01 10 250
1.21E+02 2.1E+01 1.1E+01 3.5E+01
1.82E+02 5.3E+00 1.1E+01 3.5E+01

1.14E+02 2.3E+01 1.1E+01 3.5E+01
1.53E+02 9.5E+00 1.1E+01 3.5E+01 10 250
1.30E+02 9.3E+00 1.1E+01 3.5E+01
1.72E+02 5.4E-01 1.1E+01 3.5E+01

5.50E+00 2.3E+02 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.74E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.48E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.56E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-934
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B EaFA-L01-1316-T01-A 1
B EaFA-L01-1316-T02-A 1
B EaFA-L01-1316-T03-A 1
B EaFA-L01-1316-T04-A 1
B EaFA-L01-1316-T05-A
B EaFA-L01-1316-T01-B 1
B EaFA-L01-1316-T02-B 1
B EaFA-L01-1316-T03-B 1
B EaFA-L01-1316-T04-B 1
B EaFA-L01-1316-T05-B
B EaFA-L01-1316-T01-C 1
B EaFA-L01-1316-T02-C 1
B EaFA-L01-1316-T03-C 1
B EaFA-L01-1316-T04-C 1
B EaFA-L01-1316-T05-C
B EaFA-L01-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
4.23E+03
8.52E+03
2.04E+04
3.68E+04

4.96E+03
8.98E+03
2.05E+04
3.86E+04

3.96E+03
8.80E+03
1.92E+04
3.73E+04

6.27E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.23E+03 1.5E+00 1.0E+00 3.2E+00
8.52E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
2.04E+04 3.0E+00 1.0E+00 3.2E+00
3.68E+04 3.2E+00 1.0E+00 3.2E+00

4.96E+03 1.0E+00 1.0E+00 3.2E+00
8.98E+03 1.2E+00 1.0E+00 3.2E+00 1000 100
2.05E+04 1.1E+00 1.0E+00 3.2E+00
3.86E+04 1.5E+00 1.0E+00 3.2E+00

3.96E+03 1.4E+00 1.0E+00 3.2E+00
8.80E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
1.92E+04 5.1E-01 1.0E+00 3.2E+00
3.73E+04 3.7E-01 1.0E+00 3.2E+00

6.27E+01 2.7E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.34E+03 82% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
9.80E+03 81 %VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
9.65E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-935
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFA-L01-1316-T01-A 1
Ba EaFA-L01-1316-T02-A 1
Ba EaFA-L01-1316-T03-A 1
Ba EaFA-L01-1316-T04-A 1
Ba EaFA-L01-1316-T05-A
Ba EaFA-L01-1316-T01-B 1
Ba EaFA-L01-1316-T02-B 1
Ba EaFA-L01-1316-T03-B 1
Ba EaFA-L01-1316-T04-B 1
Ba EaFA-L01-1316-T05-B
Ba EaFA-L01-1316-T01-C 1
Ba EaFA-L01-1316-T02-C 1
Ba EaFA-L01-1316-T03-C 1
Ba EaFA-L01-1316-T04-C 1
Ba EaFA-L01-1316-T05-C
Ba EaFA-L01-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.74E+02
2.13E+02
2.06E+02
2.21E+02

2.80E+02
2.31 E+02
2.08E+02
2.34E+02

2.56E+02
2.27E+02
1.97E+02
2.29E+02

1.41E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.74E+02 4.3E-01 1.0E+00 3.2E+00
2.13E+02 4.8E-01 1.0E+00 3.2E+00 10 250
2.06E+02 2.8E+00 1.0E+00 3.2E+00
2.21 E+02 3.1E+00 1.0E+00 3.2E+00

2.80E+02 3.7E-01 1.0E+00 3.2E+00
2.31 E+02 9.0E-01 1.0E+00 3.2E+00 10 250
2.08E+02 4.0E-01 1.0E+00 3.2E+00
2.34E+02 4.5E-01 1.0E+00 3.2E+00

2.56E+02 5.1E-01 1.0E+00 3.2E+00
2.27E+02 1.4E+00 1.0E+00 3.2E+00 10 250
1.97E+02 1.3E+00 1.0E+00 3.2E+00
2.29E+02 1.3E-01 1.0E+00 3.2E+00

1.41E+00 5.6E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.53E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.30E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.34E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-936
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L01-1316-T01-A 1
Be EaFA-L01-1316-T02-A 1
Be EaFA-L01-1316-T03-A 1
Be EaFA-L01-1316-T04-A 1
Be EaFA-L01-1316-T05-A
Be EaFA-L01-1316-T01-B 1
Be EaFA-L01-1316-T02-B 1
Be EaFA-L01-1316-T03-B 1
Be EaFA-L01-1316-T04-B 1
Be EaFA-L01-1316-T05-B
Be EaFA-L01-1316-T01-C 1
Be EaFA-L01-1316-T02-C 1
Be EaFA-L01-1316-T03-C 1
Be EaFA-L01-1316-T04-C 1
Be EaFA-L01-1316-T05-C
Be EaFA-L01-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2

9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2

9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2

9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.0E+03 1.9E+00 6.0E+00
9.50E-01 7.7E+01 1.9E+00 6.0E+00 10 250
9.50E-01 8.1E+01 1.9E+00 6.0E+00
9.50E-01 9.3E+02 1.9E+00 6.0E+00

9.50E-01 2.6E+02 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00 10 250
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00

9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 7.7E+01 1.9E+00 6.0E+00 10 250
9.50E-01 6.9E+01 1.9E+00 6.0E+00
9.50E-01 2.4E+01 1.9E+00 6.0E+00

9.50E-01 5.4E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.62E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.36E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.42E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-937
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-L01-1316-T01-A 1
Cd EaFA-L01-1316-T02-A 1
Cd EaFA-L01-1316-T03-A 1
Cd EaFA-L01-1316-T04-A 1
Cd EaFA-L01-1316-T05-A
Cd EaFA-L01-1316-T01-B 1
Cd EaFA-L01-1316-T02-B 1
Cd EaFA-L01-1316-T03-B 1
Cd EaFA-L01-1316-T04-B 1
Cd EaFA-L01-1316-T05-B
Cd EaFA-L01-1316-T01-C 1
Cd EaFA-L01-1316-T02-C 1
Cd EaFA-L01-1316-T03-C 1
Cd EaFA-L01-1316-T04-C 1
Cd EaFA-L01-1316-T05-C
Cd EaFA-L01-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2

1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2

1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2

1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 3.4E+01 2.2E+00 7.0E+00
1.10E+00 9.6E+00 2.2E+00 7.0E+00 10 250
1.10E+00 3.9E+01 2.2E+00 7.0E+00
1.10E+00 1.9E+01 2.2E+00 7.0E+00

1.10E+00 1.6E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00 10 250
1.10E+00 5.4E+01 2.2E+00 7.0E+00
1.10E+00 5.6E+00 2.2E+00 7.0E+00

1.10E+00 8.4E+00 2.2E+00 7.0E+00
1.10E+00 1.6E+01 2.2E+00 7.0E+00 10 250
1.10E+00 3.4E+01 2.2E+00 7.0E+00
1.10E+00 3.9E+01 2.2E+00 7.0E+00

1.10E+00 1.3E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.73E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.44E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.51E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1 :50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-938
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qu
1 1 ug/L
Ca EaFA-L01-1316-T01-A 1 1.58E+05
Ca EaFA-L01-1316-T02-A 1 3.20E+05
Ca EaFA-L01-1316-T03-A 1 7.38E+05
Ca EaFA-L01-1316-T04-A 1 5.82E+05
Ca EaFA-L01-1316-T05-A
Ca EaFA-L01-1316-T01-B 1 1.62E+05
Ca EaFA-L01-1316-T02-B 1 3.28E+05
Ca EaFA-L01-1316-T03-B 1 7.36E+05
Ca EaFA-L01-1316-T04-B 1 6.16E+05
Ca EaFA-L01-1316-T05-B
Ca EaFA-L01-1316-T01-C 1 1.40E+05
Ca EaFA-L01-1316-T02-C 1 3.31 E+05
Ca EaFA-L01-1316-T03-C 1 6.90E+05
Ca EaFA-L01-1316-T04-C 1 5.85E+05
Ca EaFA-L01-1316-T05-C
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.58E+05 8.1E-01 2.6E+00 8.3E+00
3.20E+05 3.7E-01 2.6E+00 8.3E+00 1000 100
7.38E+05 2.8E+00 2.6E+00 8.3E+00
5.82E+05 3.6E+00 2.6E+00 8.3E+00

1.62E+05 9.5E-02 2.6E+00 8.3E+00
3.28E+05 8.6E-01 2.6E+00 8.3E+00 1000 100
7.36E+05 4.5E-01 2.6E+00 8.3E+00
6.16E+05 5.8E-01 2.6E+00 8.3E+00

1.40E+05 6.9E-01 2.6E+00 8.3E+00
3.31E+05 1.5E+00 2.6E+00 8.3E+00 1000 100
6.90E+05 1.2E+00 2.6E+00 8.3E+00
5.85E+05 2.0E-01 2.6E+00 8.3E+00

Ca EaFA-L01-1316-B01-A 1 1.30E+OOU1/2 1.30E+00 4.1E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.21E+05 93% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3.29E+05 97% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3.32E+05 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-939
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qu
1 1 ug/L
Cr EaFA-L01-1316-T01-A 1 1.20E+01
Cr EaFA-L01-1316-T02-A 1 1.52E+01
Cr EaFA-L01-1316-T03-A 1 2.33E+01
Cr EaFA-L01-1316-T04-A 1 4.87E+01
Cr EaFA-L01-1316-T05-A
Cr EaFA-L01-1316-T01-B 1 1.10E+01
Cr EaFA-L01-1316-T02-B 1 1.70E+01
Cr EaFA-L01-1316-T03-B 1 2.27E+01
Cr EaFA-L01-1316-T04-B 1 4.75E+01
Cr EaFA-L01-1316-T05-B
Cr EaFA-L01-1316-T01-C 1 1.09E+01
Cr EaFA-L01-1316-T02-C 1 1.99E+01
Cr EaFA-L01-1316-T03-C 1 1.96E+01
Cr EaFA-L01-1316-T04-C 1 4.46E+01
Cr EaFA-L01-1316-T05-C
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.20E+01 1.7E+01 1.2E+00 3.8E+00
1.52E+01 1.2E+01 1.2E+00 3.8E+00 10 250
2.33E+01 4.9E+00 1.2E+00 3.8E+00
4.87E+01 6.0E+00 1.2E+00 3.8E+00

1.10E+01 3.2E+00 1.2E+00 3.8E+00
1.70E+01 7.2E+00 1.2E+00 3.8E+00 10 250
2.27E+01 6.6E+00 1.2E+00 3.8E+00
4.75E+01 1.1E+00 1.2E+00 3.8E+00

1.09E+01 9.2E+00 1.2E+00 3.8E+00
1.99E+01 8.4E+00 1.2E+00 3.8E+00 10 250
1.96E+01 4.7E+00 1.2E+00 3.8E+00
4.46E+01 2.5E+00 1.2E+00 3.8E+00

Cr EaFA-L01-1316-B01-A 1 6.00E-01 U1/2 6.00E-01 1 .2E+03 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.57E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.31E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.37E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-940
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-L01-1316-T01-A 1
Co EaFA-L01-1316-T02-A 1
Co EaFA-L01-1316-T03-A 1
Co EaFA-L01-1316-T04-A 1
Co EaFA-L01-1316-T05-A
Co EaFA-L01-1316-T01-B 1
Co EaFA-L01-1316-T02-B 1
Co EaFA-L01-1316-T03-B 1
Co EaFA-L01-1316-T04-B 1
Co EaFA-L01-1316-T05-B
Co EaFA-L01-1316-T01-C 1
Co EaFA-L01-1316-T02-C 1
Co EaFA-L01-1316-T03-C 1
Co EaFA-L01-1316-T04-C 1
Co EaFA-L01-1316-T05-C
Co EaFA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
7.61E+01
1.20E+02
2.36E+02
1.12E+02

7.79E+01
1.21E+02
2.16E+02
1.30E+02

6.35E+01
1.24E+02
2.15E+02
1.48E+02

9.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.61E+01 2.0E+00 1.8E+00 5.7E+00
1.20E+02 3.8E+00 1.8E+00 5.7E+00 10 250
2.36E+02 3.4E+00 1.8E+00 5.7E+00
1.12E+02 7.1E+00 1.8E+00 5.7E+00

7.79E+01 5.3E+00 1.8E+00 5.7E+00
1.21E+02 1.8E+00 1.8E+00 5.7E+00 10 250
2.16E+02 2.5E+00 1.8E+00 5.7E+00
1.30E+02 2.6E+00 1.8E+00 5.7E+00

6.35E+01 3.4E+00 1.8E+00 5.7E+00
1.24E+02 4.9E+00 1.8E+00 5.7E+00 10 250
2.15E+02 1.9E+00 1.8E+00 5.7E+00
1.48E+02 2.6E+00 1.8E+00 5.7E+00

9.00E-01 9.2E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.76E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.49E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.53E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-941
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qu
1 1 ug/L
Cu EaFA-L01-1316-T01-A 1 1.14E+01 E
Cu EaFA-L01-1316-T02-A 1 1.85E+01
Cu EaFA-L01-1316-T03-A 1 1.52E+01
Cu EaFA-L01-1316-T04-A 1 1.11E+01 E
Cu EaFA-L01-1316-T05-A
Cu EaFA-L01-1316-T01-B 1 1.16E+01 E
Cu EaFA-L01-1316-T02-B 1 1.34E+01
Cu EaFA-L01-1316-T03-B 1 1.74E+01
Cu EaFA-L01-1316-T04-B 1 1.56E+01
Cu EaFA-L01-1316-T05-B
Cu EaFA-L01-1316-T01-C 1 1.28E+01
Cu EaFA-L01-1316-T02-C 1 1.57E+01
Cu EaFA-L01-1316-T03-C 1 1.47E+01
Cu EaFA-L01-1316-T04-C 1 8.87E+00 E
Cu EaFA-L01-1316-T05-C
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.14E+01 7.9E+01 3.7E+00 1.2E+01
1.85E+01 5.7E+01 3.7E+00 1.2E+01 10 250
1.52E+01 3.4E+01 3.7E+00 1.2E+01
1.11E+01 2.8E+01 3.7E+00 1.2E+01

1.16E+01 4.3E+01 3.7E+00 1.2E+01
1.34E+01 3.8E+01 3.7E+00 1.2E+01 10 250
1.74E+01 1.5E+01 3.7E+00 1.2E+01
1.56E+01 5.3E+01 3.7E+00 1.2E+01

1.28E+01 5.7E+01 3.7E+00 1.2E+01
1.57E+01 3.7E+01 3.7E+00 1.2E+01 10 250
1.47E+01 1.8E+01 3.7E+00 1.2E+01
8.87E+00 4.4E+00 3.7E+00 1.2E+01

Cu EaFA-L01-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 4.4E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.57E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.33E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.38E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-942
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L01-1316-T01-A 1
Fe EaFA-L01-1316-T02-A 1
Fe EaFA-L01-1316-T03-A 1
Fe EaFA-L01-1316-T04-A 1
Fe EaFA-L01-1316-T05-A
Fe EaFA-L01-1316-T01-B 1
Fe EaFA-L01-1316-T02-B 1
Fe EaFA-L01-1316-T03-B 1
Fe EaFA-L01-1316-T04-B 1
Fe EaFA-L01-1316-T05-B
Fe EaFA-L01-1316-T01-C 1
Fe EaFA-L01-1316-T02-C 1
Fe EaFA-L01-1316-T03-C 1
Fe EaFA-L01-1316-T04-C 1
Fe EaFA-L01-1316-T05-C
Fe EaFA-L01-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2

1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2

1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2

1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.5E+03 2.0E+00 6.4E+00
1.00E+00 9.6E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 7.5E+00 2.0E+00 6.4E+00
1.00E+00 3.9E+00 2.0E+00 6.4E+00

1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 3.2E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00

1.00E+00 4.5E+00 2.0E+00 6.4E+00
1.00E+00 8.0E-01 2.0E+00 6.4E+00 1000 100
1.00E+00 6.4E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00

1.00E+00 4.6E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.68E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
8.47E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
8.45E+02 84% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-943
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L01-1316-T01-A 1
Pb EaFA-L01-1316-T02-A 1
Pb EaFA-L01-1316-T03-A 1
Pb EaFA-L01-1316-T04-A 1
Pb EaFA-L01-1316-T05-A
Pb EaFA-L01-1316-T01-B 1
Pb EaFA-L01-1316-T02-B 1
Pb EaFA-L01-1316-T03-B 1
Pb EaFA-L01-1316-T04-B 1
Pb EaFA-L01-1316-T05-B
Pb EaFA-L01-1316-T01-C 1
Pb EaFA-L01-1316-T02-C 1
Pb EaFA-L01-1316-T03-C 1
Pb EaFA-L01-1316-T04-C 1
Pb EaFA-L01-1316-T05-C
Pb EaFA-L01-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2

3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2

3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2

3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 2.7E+02 6.8E+00 2.2E+01
3.40E+00 8.5E+02 6.8E+00 2.2E+01 10 250
3.40E+00 2.2E+01 6.8E+00 2.2E+01
3.40E+00 3.3E+01 6.8E+00 2.2E+01

3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 1.5E+01 6.8E+00 2.2E+01 10 250
3.40E+00 2.2E+02 6.8E+00 2.2E+01
3.40E+00 4.7E+01 6.8E+00 2.2E+01

3.40E+00 1.8E+02 6.8E+00 2.2E+01
3.40E+00 5.9E+02 6.8E+00 2.2E+01 10 250
3.40E+00 1.9E+02 6.8E+00 2.2E+01
3.40E+00 3.7E+02 6.8E+00 2.2E+01

3.40E+00 4.4E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.55E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.27E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.31E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-944
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFA-L01-1316-T01-A 1
Li EaFA-L01-1316-T02-A 1
Li EaFA-L01-1316-T03-A 1
Li EaFA-L01-1316-T04-A 1
Li EaFA-L01-1316-T05-A
Li EaFA-L01-1316-T01-B 1
Li EaFA-L01-1316-T02-B 1
Li EaFA-L01-1316-T03-B 1
Li EaFA-L01-1316-T04-B 1
Li EaFA-L01-1316-T05-B
Li EaFA-L01-1316-T01-C 1
Li EaFA-L01-1316-T02-C 1
Li EaFA-L01-1316-T03-C 1
Li EaFA-L01-1316-T04-C 1
Li EaFA-L01-1316-T05-C
Li EaFA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
5.40E+03
1.06E+04
2.52E+04
5.10E+04

5.51 E+03
1.09E+04
2.53E+04
5.30E+04

4.73E+03
1.10E+04
2.38E+04
4.98E+04

5.14E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.40E+03 5.0E-01 1.9E+00 6.0E+00
1.06E+04 3.9E-01 1.9E+00 6.0E+00 10 250
2.52E+04 2.4E+00 1.9E+00 6.0E+00
5.10E+04 3.8E+00 1.9E+00 6.0E+00

5.51 E+03 4.8E-01 1.9E+00 6.0E+00
1.09E+04 1.1E+00 1.9E+00 6.0E+00 10 250
2.53E+04 2.8E-01 1.9E+00 6.0E+00
5.30E+04 8.6E-01 1.9E+00 6.0E+00

4.73E+03 5.9E-01 1.9E+00 6.0E+00
1.10E+04 1.0E+00 1.9E+00 6.0E+00 10 250
2.38E+04 9.8E-01 1.9E+00 6.0E+00
4.98E+04 3.8E-01 1.9E+00 6.0E+00

5.14E+00 6.4E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.31E+04 100% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1 .33E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1 .33E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-945
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFA-L01-1316-T01-A 1
Mn EaFA-L01-1316-T02-A 1
Mn EaFA-L01-1316-T03-A 1
Mn EaFA-L01-1316-T04-A 1
Mn EaFA-L01-1316-T05-A
Mn EaFA-L01-1316-T01-B 1
Mn EaFA-L01-1316-T02-B 1
Mn EaFA-L01-1316-T03-B 1
Mn EaFA-L01-1316-T04-B 1
Mn EaFA-L01-1316-T05-B
Mn EaFA-L01-1316-T01-C 1
Mn EaFA-L01-1316-T02-C 1
Mn EaFA-L01-1316-T03-C 1
Mn EaFA-L01-1316-T04-C 1
Mn EaFA-L01-1316-T05-C
Mn EaFA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
4.64E+02
8.01 E+02
1.55E+03
1.11E+03

4.76E+02
8.04E+02
1.45E+03
1.23E+03

3.79E+02
7.85E+02
1.43E+03
1.36E+03

1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.64E+02 1.5E+00 2.0E+00 6.4E+00
8.01E+02 8.5E-01 2.0E+00 6.4E+00 10 250
1.55E+03 4.4E+00 2.0E+00 6.4E+00
1.11E+03 3.8E+00 2.0E+00 6.4E+00

4.76E+02 4.9E-01 2.0E+00 6.4E+00
8.04E+02 8.6E-01 2.0E+00 6.4E+00 10 250
1.45E+03 1.1E+00 2.0E+00 6.4E+00
1.23E+03 6.0E-01 2.0E+00 6.4E+00

3.79E+02 1.1E+00 2.0E+00 6.4E+00
7.85E+02 2.5E+00 2.0E+00 6.4E+00 10 250
1.43E+03 9.2E-01 2.0E+00 6.4E+00
1.36E+03 4.3E-01 2.0E+00 6.4E+00

1.00E+00 1.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.25E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3.00E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3.01 E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-946
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFA-L01-1316-T01-A 1
Mg EaFA-L01-1316-T02-A 1
Mg EaFA-L01-1316-T03-A 1
Mg EaFA-L01-1316-T04-A 1
Mg EaFA-L01-1316-T05-A
Mg EaFA-L01-1316-T01-B 1
Mg EaFA-L01-1316-T02-B 1
Mg EaFA-L01-1316-T03-B 1
Mg EaFA-L01-1316-T04-B 1
Mg EaFA-L01-1316-T05-B
Mg EaFA-L01-1316-T01-C 1
Mg EaFA-L01-1316-T02-C 1
Mg EaFA-L01-1316-T03-C 1
Mg EaFA-L01-1316-T04-C 1
Mg EaFA-L01-1316-T05-C
Mg EaFA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
7.03E+03
1.45E+04
3.59E+04
6.85E+04

7.22E+03
1.47E+04
3.62E+04
7.17E+04

6.11E+03
1.45E+04
3.36E+04
6.71 E+04

5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.03E+03 6.8E-01 1.0E+00 3.2E+00
1.45E+04 7.2E-01 1.0E+00 3.2E+00 1000 100
3.59E+04 3.0E+00 1.0E+00 3.2E+00
6.85E+04 2.9E+00 1.0E+00 3.2E+00

7.22E+03 4.2E-01 1.0E+00 3.2E+00
1.47E+04 9.8E-01 1.0E+00 3.2E+00 1000 100
3.62E+04 7.2E-01 1.0E+00 3.2E+00
7.17E+04 7.0E-01 1.0E+00 3.2E+00

6.11E+03 9.7E-01 1.0E+00 3.2E+00
1.45E+04 1.7E+00 1.0E+00 3.2E+00 1000 100
3.36E+04 7.8E-01 1.0E+00 3.2E+00
6.71 E+04 5.7E-01 1.0E+00 3.2E+00

5.00E-01 1.1E+03 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .56E+04 104% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1.59E+04 116% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1 .54E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-947
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 1 ug/L
Mo EaFA-L01-1316-T01-A 1 3.26E+03
Mo EaFA-L01-1316-T02-A 1 6.29E+03
Mo EaFA-L01-1316-T03-A 1 1.41E+04
Mo EaFA-L01-1316-T04-A 1 3.03E+04
Mo EaFA-L01-1316-T05-A
Mo EaFA-L01-1316-T01-B 1 3.36E+03
Mo EaFA-L01-1316-T02-B 1 6.50E+03
Mo EaFA-L01-1316-T03-B 1 1.41E+04
Mo EaFA-L01-1316-T04-B 1 3.11E+04
Mo EaFA-L01-1316-T05-B
Mo EaFA-L01-1316-T01-C 1 2.91E+03
Mo EaFA-L01-1316-T02-C 1 6.54E+03
Mo EaFA-L01-1316-T03-C 1 1.33E+04
Mo EaFA-L01-1316-T04-C 1 2.83E+04
Mo EaFA-L01-1316-T05-C
Mo EaFA-L01-1316-B01-A 1 4.28E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.26E+03 7.3E-01 1.2E+00 3.8E+00
6.29E+03 6.4E-01 1.2E+00 3.8E+00 10 250
1.41E+04 2.9E+00 1.2E+00 3.8E+00
3.03E+04 4.0E+00 1.2E+00 3.8E+00

3.36E+03 8.0E-02 1.2E+00 3.8E+00
6.50E+03 9.5E-01 1.2E+00 3.8E+00 10 250
1.41E+04 6.4E-01 1.2E+00 3.8E+00
3.11E+04 4.5E-01 1.2E+00 3.8E+00

2.91 E+03 4.0E-01 1.2E+00 3.8E+00
6.54E+03 1.6E+00 1.2E+00 3.8E+00 10 250
1.33E+04 1.4E+00 1.2E+00 3.8E+00
2.83E+04 6.2E-02 1.2E+00 3.8E+00

4.28E+00 6.5E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.47E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
8.72E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
8.63E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-948
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone.
1 1 ug/L
Ni EaFA-L01-1316-T01-A 1 1.69E+02
Ni EaFA-L01-1316-T02-A 1 2.63E+02
Ni EaFA-L01-1316-T03-A 1 5.11E+02
Ni EaFA-L01-1316-T04-A 1 2.69E+02
Ni EaFA-L01-1316-T05-A
Ni EaFA-L01-1316-T01-B 1 1.67E+02
Ni EaFA-L01-1316-T02-B 1 2.74E+02
Ni EaFA-L01-1316-T03-B 1 4.71 E+02
Ni EaFA-L01-1316-T04-B 1 3.09E+02
Ni EaFA-L01-1316-T05-B
Ni EaFA-L01-1316-T01-C 1 1.29E+02
Ni EaFA-L01-1316-T02-C 1 2.76E+02
Ni EaFA-L01-1316-T03-C 1 4.85E+02
Ni EaFA-L01-1316-T04-C 1 3.44E+02
Ni EaFA-L01-1316-T05-C
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.69E+02 2.0E+00 1.8E+00 5.7E+00
2.63E+02 6.5E-01 1.8E+00 5.7E+00 10 250
5.11E+02 2.5E+00 1.8E+00 5.7E+00
2.69E+02 4.0E+00 1.8E+00 5.7E+00

1.67E+02 4.2E+00 1.8E+00 5.7E+00
2.74E+02 1.3E+00 1.8E+00 5.7E+00 10 250
4.71 E+02 6.0E-01 1.8E+00 5.7E+00
3.09E+02 3.1E+00 1.8E+00 5.7E+00

1.29E+02 1.5E+00 1.8E+00 5.7E+00
2.76E+02 1.1E+00 1.8E+00 5.7E+00 10 250
4.85E+02 1.7E+00 1.8E+00 5.7E+00
3.44E+02 1.2E+00 1.8E+00 5.7E+00

Ni EaFA-L01-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 6.2E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.86E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.60E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.64E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-949
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone.
1 ug/L
P EaFA-L01-1316-T01-A 1 1.78E+01
P EaFA-L01-1316-T02-A 1 4.24E+01
P EaFA-L01-1316-T03-A 1 7.87E+01
P EaFA-L01-1316-T04-A 1 1.71E+02
P EaFA-L01-1316-T05-A
P EaFA-L01-1316-T01-B 1 3.11E+01
P EaFA-L01-1316-T02-B 1 3.00E+01
P EaFA-L01-1316-T03-B 1 3.81E+01
P EaFA-L01-1316-T04-B 1 1.11E+02
P EaFA-L01-1316-T05-B
P EaFA-L01-1316-T01-C 1 2.63E+01
P EaFA-L01-1316-T02-C 1 5.01 E+01
P EaFA-L01-1316-T03-C 1 3.77E+01
P EaFA-L01-1316-T04-C 1 1.88E+02
P EaFA-L01-1316-T05-C
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.78E+01 1.6E+01 3.7E+00 1.2E+01
4.24E+01 5.5E+00 3.7E+00 1 .2E+01 1000 100
7.87E+01 1.9E+01 3.7E+00 1 .2E+01
1.71E+02 1.0E+01 3.7E+00 1 .2E+01

3.11E+01 2.2E+01 3.7E+00 1 .2E+01
3.00E+01 1.8E+01 3.7E+00 1 .2E+01 1000 100
3.81 E+01 5.4E+00 3.7E+00 1 .2E+01
1.11E+02 8.1E+00 3.7E+00 1.2E+01

2.63E+01 2.5E+01 3.7E+00 1.2E+01
5.01 E+01 1.6E+01 3.7E+00 1.2E+01 1000 100
3.77E+01 2.4E+01 3.7E+00 1.2E+01
1.88E+02 6.0E+00 3.7E+00 1.2E+01

P EaFA-L01-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 2.1E+02 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.01 E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
8.50E+02 82% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
8.77E+02 83% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58AMEPAInterlabL01 1313-1316 EaFA
                                                                                                                                                                          1-950
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K EaFA-L01-1316-T01-A 1
K EaFA-L01-1316-T02-A 1
K EaFA-L01-1316-T03-A 1
K EaFA-L01-1316-T04-A 1
K EaFA-L01-1316-T05-A
K EaFA-L01-1316-T01-B 1
K EaFA-L01-1316-T02-B 1
K EaFA-L01-1316-T03-B 1
K EaFA-L01-1316-T04-B 1
K EaFA-L01-1316-T05-B
K EaFA-L01-1316-T01-C 1
K EaFA-L01-1316-T02-C 1
K EaFA-L01-1316-T03-C 1
K EaFA-L01-1316-T04-C 1
K EaFA-L01-1316-T05-C
K EaFA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.30E+04
4.90E+04
1.21E+05
2.05E+05

2.36E+04
4.96E+04
1.22E+05
2.14E+05

2.05E+04
5.01 E+04
1.16E+05
2.00E+05

4.01 E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+04 6.9E-01 1.6E+00 5.1 E+00
4.90E+04 4.6E-01 1.6E+00 5.1E+00 1000 100
1.21E+05 2.8E+00 1.6E+00 5.1E+00
2.05E+05 3.8E+00 1.6E+00 5.1 E+00

2.36E+04 2.5E-01 1.6E+00 5.1 E+00
4.96E+04 1.4E+00 1.6E+00 5.1E+00 1000 100
1.22E+05 2.5E-01 1.6E+00 5.1 E+00
2.14E+05 7.5E-01 1.6E+00 5.1E+00

2.05E+04 8.1E-01 1.6E+00 5.1 E+00
5.01E+04 1.1E+00 1.6E+00 5.1E+00 1000 100
1.16E+05 9.3E-01 1.6E+00 5.1E+00
2.00E+05 3.5E-01 1.6E+00 5.1 E+00

4.01 E+00 2.5E+01 1.6E+00 5.1 E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.99E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
5.05E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
5.09E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-951
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se EaFA-L01-1316-T01-A 1
Se EaFA-L01-1316-T02-A 1
Se EaFA-L01-1316-T03-A 1
Se EaFA-L01-1316-T04-A 1
Se EaFA-L01-1316-T05-A
Se EaFA-L01-1316-T01-B 1
Se EaFA-L01-1316-T02-B 1
Se EaFA-L01-1316-T03-B 1
Se EaFA-L01-1316-T04-B 1
Se EaFA-L01-1316-T05-B
Se EaFA-L01-1316-T01-C 1
Se EaFA-L01-1316-T02-C 1
Se EaFA-L01-1316-T03-C 1
Se EaFA-L01-1316-T04-C 1
Se EaFA-L01-1316-T05-C
Se EaFA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.10E+03
1.28E+03
1.51E+03
2.43E+03

1.11E+03
1.31E+03
1.38E+03
2.30E+03

1.03E+03
1.43E+03
1.52E+03
2.33E+03

7.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+03 1.0E+00 1.5E+01 4.8E+01
1.28E+03 2.9E+00 1.5E+01 4.8E+01 10 250
1.51E+03 2.6E+00 1.5E+01 4.8E+01
2.43E+03 3.6E+00 1.5E+01 4.8E+01

1.11E+03 3.1E+00 1.5E+01 4.8E+01
1.31E+03 2.8E+00 1.5E+01 4.8E+01 10 250
1.38E+03 6.2E-01 1.5E+01 4.8E+01
2.30E+03 4.7E-01 1.5E+01 4.8E+01

1.03E+03 4.4E+00 1.5E+01 4.8E+01
1.43E+03 3.5E+00 1.5E+01 4.8E+01 10 250
1.52E+03 2.3E+00 1.5E+01 4.8E+01
2.33E+03 1.0E+00 1.5E+01 4.8E+01

7.50E+00 3.1E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.70E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3.46E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3.67E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-952
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone.
1 ug/L
Si EaFA-L01-1316-T01-A 1 2.97E+03
Si EaFA-L01-1316-T02-A 1 3.17E+03
Si EaFA-L01-1316-T03-A 1 3.15E+03
Si EaFA-L01-1316-T04-A 1 2.31E+03
Si EaFA-L01-1316-T05-A
Si EaFA-L01-1316-T01-B 1 3.05E+03
Si EaFA-L01-1316-T02-B 1 3.08E+03
Si EaFA-L01-1316-T03-B 1 2.78E+03
Si EaFA-L01-1316-T04-B 1 2.42E+03
Si EaFA-L01-1316-T05-B
Si EaFA-L01-1316-T01-C 1 2.63E+03
Si EaFA-L01-1316-T02-C 1 3.56E+03
Si EaFA-L01-1316-T03-C 1 3.01E+03
Si EaFA-L01-1316-T04-C 1 2.57E+03
Si EaFA-L01-1316-T05-C
Si EaFA-L01-1316-B01-A 1 2.89E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.97E+03 7.9E-01 1.1E+00 3.5E+00
3.17E+03 6.3E-01 1.1E+00 3.5E+00 1000 100
3.15E+03 2.6E+00 1.1E+00 3.5E+00
2.31 E+03 3.2E+00 1.1E+00 3.5E+00

3.05E+03 6.7E-01 1.1E+00 3.5E+00
3.08E+03 9.6E-01 1.1E+00 3.5E+00 1000 100
2.78E+03 4.3E-01 1.1E+00 3.5E+00
2.42E+03 6.7E-01 1.1E+00 3.5E+00

2.63E+03 6.8E-01 1.1E+00 3.5E+00
3.56E+03 2.2E+00 1.1E+00 3.5E+00 1000 100
3.01 E+03 1.1E+00 1.1E+00 3.5E+00
2.57E+03 4.2E-01 1.1E+00 3.5E+00

2.89E+01 4.5E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.01 E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3.95E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
4.37E+03 81 %VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-953
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone.
Na EaFA-L01-1316-T01-A 1 5.39E+03
Na EaFA-L01-1316-T02-A 1 1.13E+04
Na EaFA-L01-1316-T03-A 1 2.82E+04
Na EaFA-L01-1316-T04-A 1 4.91 E+04
Na EaFA-L01-1316-T05-A
Na EaFA-L01-1316-T01-B 1 5.47E+03
Na EaFA-L01-1316-T02-B 1 1.15E+04
Na EaFA-L01-1316-T03-B 1 2.82E+04
Na EaFA-L01-1316-T04-B 1 5.03E+04
Na EaFA-L01-1316-T05-B
Na EaFA-L01-1316-T01-C 1 4.67E+03
Na EaFA-L01-1316-T02-C 1 1.16E+04
Na EaFA-L01-1316-T03-C 1 2.67E+04
Na EaFA-L01-1316-T04-C 1 4.69E+04
Na EaFA-L01-1316-T05-C
Na EaFA-L01-1316-B01-A 1 3.64E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.39E+03 3.3E-01 2.5E+00 8.0E+00
1.13E+04 5.5E-01 2.5E+00 8.0E+00 1000 100
2.82E+04 2.3E+00 2.5E+00 8.0E+00
4.91 E+04 4.0E+00 2.5E+00 8.0E+00

5.47E+03 9.9E-01 2.5E+00 8.0E+00
1.15E+04 1.3E+00 2.5E+00 8.0E+00 1000 100
2.82E+04 4.6E-01 2.5E+00 8.0E+00
5.03E+04 6.1E-01 2.5E+00 8.0E+00

4.67E+03 1.2E+00 2.5E+00 8.0E+00
1.16E+04 1.0E+00 2.5E+00 8.0E+00 1000 100
2.67E+04 8.7E-01 2.5E+00 8.0E+00
4.69E+04 5.1E-01 2.5E+00 8.0E+00

3.64E+01 2.2E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .22E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1 .24E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1 .24E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-954
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
EaFA-L01-1316-T01-A 1
EaFA-L01-1316-T02-A 1
EaFA-L01-1316-T03-A 1
EaFA-L01-1316-T04-A 1
EaFA-L01-1316-T05-A
EaFA-L01-1316-T01-B 1
EaFA-L01-1316-T02-B 1
EaFA-L01-1316-T03-B 1
EaFA-L01-1316-T04-B 1
EaFA-L01-1316-T05-B
EaFA-L01-1316-T01-C 1
EaFA-L01-1316-T02-C 1
EaFA-L01-1316-T03-C 1
EaFA-L01-1316-T04-C 1
EaFA-L01-1316-T05-C
EaFA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.09E+03
3.97E+03
8.54E+03
8.65E+03

2.14E+03
3.98E+03
8.34E+03
8.73E+03

1.84E+03
4.09E+03
8.15E+03
8.29E+03

5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.09E+03 1.4E+00 1.0E+00 3.2E+00
3.97E+03 1.5E+00 1.0E+00 3.2E+00 1000 100
8.54E+03 3.3E+00 1.0E+00 3.2E+00
8.65E+03 3.8E+00 1.0E+00 3.2E+00

2.14E+03 9.1E-01 1.0E+00 3.2E+00
3.98E+03 7.3E-01 1.0E+00 3.2E+00 1000 100
8.34E+03 7.2E-01 1.0E+00 3.2E+00
8.73E+03 3.9E-01 1.0E+00 3.2E+00

1.84E+03 4.0E-01 1.0E+00 3.2E+00
4.09E+03 2.7E+00 1.0E+00 3.2E+00 1000 100
8.15E+03 1.3E+00 1.0E+00 3.2E+00
8.29E+03 3.2E-01 1.0E+00 3.2E+00

5.00E-01 2.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.89E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
4.89E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
4.95E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-955
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S EaFA-L01-1316-T01-A 1
S EaFA-L01-1316-T02-A 1
S EaFA-L01-1316-T03-A 1
S EaFA-L01-1316-T04-A 1
S EaFA-L01-1316-T05-A
S EaFA-L01-1316-T01-B 1
S EaFA-L01-1316-T02-B 1
S EaFA-L01-1316-T03-B 1
S EaFA-L01-1316-T04-B 1
S EaFA-L01-1316-T05-B
S EaFA-L01-1316-T01-C 1
S EaFA-L01-1316-T02-C 1
S EaFA-L01-1316-T03-C 1
S EaFA-L01-1316-T04-C 1
S EaFA-L01-1316-T05-C
S EaFA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.54E+05
3.10E+05
7.08E+05
7.30E+05

1.56E+05
3.13E+05
6.98E+05
7.68E+05

1.34E+05
3.09E+05
6.62E+05
7.45E+05

3.40E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+05 5.6E-01 6.8E+00 2.2E+01
3.10E+05 3.0E-01 6.8E+00 2.2E+01 1000 100
7.08E+05 2.7E+00 6.8E+00 2.2E+01
7.30E+05 3.3E+00 6.8E+00 2.2E+01

1.56E+05 3.4E-01 6.8E+00 2.2E+01
3.13E+05 7.6E-01 6.8E+00 2.2E+01 1000 100
6.98E+05 2.8E-01 6.8E+00 2.2E+01
7.68E+05 1.8E-01 6.8E+00 2.2E+01

1.34E+05 9.9E-01 6.8E+00 2.2E+01
3.09E+05 1.2E+00 6.8E+00 2.2E+01 1000 100
6.62E+05 9.8E-01 6.8E+00 2.2E+01
7.45E+05 2.0E-01 6.8E+00 2.2E+01

3.40E+00 7.4E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.96E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3.96E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3.95E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58AMEPAInterlabL01 1313-1316 EaFA
                                                                                                                                                                          1-956
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-L01-1316-T01-A 1
Tl EaFA-L01-1316-T02-A 1
Tl EaFA-L01-1316-T03-A 1
Tl EaFA-L01-1316-T04-A 1
Tl EaFA-L01-1316-T05-A
Tl EaFA-L01-1316-T01-B 1
Tl EaFA-L01-1316-T02-B 1
Tl EaFA-L01-1316-T03-B 1
Tl EaFA-L01-1316-T04-B 1
Tl EaFA-L01-1316-T05-B
Tl EaFA-L01-1316-T01-C 1
Tl EaFA-L01-1316-T02-C 1
Tl EaFA-L01-1316-T03-C 1
Tl EaFA-L01-1316-T04-C 1
Tl EaFA-L01-1316-T05-C
Tl EaFA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
1.52E+01
1.64E+01

2.30E+00 U1/2
1.62E+01
7.91 E+00 E
1.70E+01

2.30E+00 U1/2
4.64E+00 E
2.70E+01
1.69E+01

2.30E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 9.4E+01 4.6E+00 1.5E+01
2.30E+00 2.8E+02 4.6E+00 1.5E+01 10 250
1.52E+01 6.6E+01 4.6E+00 1 .5E+01
1.64E+01 3.8E+01 4.6E+00 1 .5E+01

2.30E+00 9.0E+02 4.6E+00 1 .5E+01
1.62E+01 7.0E+01 4.6E+00 1 .5E+01 10 250
7.91 E+00 4.0E+01 4.6E+00 1 .5E+01
1.70E+01 6.0E+01 4.6E+00 1 .5E+01

2.30E+00 2.4E+02 4.6E+00 1 .5E+01
4.64E+00 2.4E+02 4.6E+00 1 .5E+01 10 250
2.70E+01 3.9E+01 4.6E+00 1 .5E+01
1.69E+01 1.3E+02 4.6E+00 1 .5E+01

2.30E+00 4.0E+01 4.6E+00 1 .5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.50E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.25E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.30E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-957
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L01-1316-T01-A 1
Ti EaFA-L01-1316-T02-A 1
Ti EaFA-L01-1316-T03-A 1
Ti EaFA-L01-1316-T04-A 1
Ti EaFA-L01-1316-T05-A
Ti EaFA-L01-1316-T01-B 1
Ti EaFA-L01-1316-T02-B 1
Ti EaFA-L01-1316-T03-B 1
Ti EaFA-L01-1316-T04-B 1
Ti EaFA-L01-1316-T05-B
Ti EaFA-L01-1316-T01-C 1
Ti EaFA-L01-1316-T02-C 1
Ti EaFA-L01-1316-T03-C 1
Ti EaFA-L01-1316-T04-C 1
Ti EaFA-L01-1316-T05-C
Ti EaFA-L01-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2

1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2

1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2

1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.7E+01 2.0E+00 6.4E+00
1.00E+00 5.6E+01 2.0E+00 6.4E+00 10 250
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00

1.00E+00 2.2E+02 2.0E+00 6.4E+00
1.00E+00 1.2E+03 2.0E+00 6.4E+00 10 250
1.00E+00 5.4E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00

1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 7.9E+01 2.0E+00 6.4E+00 10 250
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 6.8E+01 2.0E+00 6.4E+00

1.00E+00 1.5E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.54E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.31E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.35E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-958
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
V EaFA-L01-1316-T01-A 1 2.66E+02
V EaFA-L01-1316-T02-A 1 3.05E+02
V EaFA-L01-1316-T03-A 1 3.63E+02
V EaFA-L01-1316-T04-A 1 4.13E+02
V EaFA-L01-1316-T05-A
V EaFA-L01-1316-T01-B 1 2.72E+02
V EaFA-L01-1316-T02-B 1 3.09E+02
V EaFA-L01-1316-T03-B 1 3.35E+02
V EaFA-L01-1316-T04-B 1 4.23E+02
V EaFA-L01-1316-T05-B
V EaFA-L01-1316-T01-C 1 2.49E+02
V EaFA-L01-1316-T02-C 1 3.47E+02
V EaFA-L01-1316-T03-C 1 3.61 E+02
V EaFA-L01-1316-T04-C 1 4.33E+02
V EaFA-L01-1316-T05-C
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.66E+02 1.1E+00 1.5E+00 4.8E+00
3.05E+02 3.4E-01 1.5E+00 4.8E+00 10 250
3.63E+02 2.0E+00 1.5E+00 4.8E+00
4.13E+02 3.4E+00 1.5E+00 4.8E+00

2.72E+02 1.3E+00 1.5E+00 4.8E+00
3.09E+02 1.7E+00 1.5E+00 4.8E+00 10 250
3.35E+02 1.3E+00 1.5E+00 4.8E+00
4.23E+02 1.2E+00 1.5E+00 4.8E+00

2.49E+02 6.0E-01 1.5E+00 4.8E+00
3.47E+02 1.3E+00 1.5E+00 4.8E+00 10 250
3.61 E+02 1.1E+00 1.5E+00 4.8E+00
4.33E+02 4.2E-01 1.5E+00 4.8E+00

V EaFA-L01-1316-B01-A 1 7.50E-01 U1/2 7.50E-01 1 .6E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.80E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.70E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.62E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1 :51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58AMEPAInterlabL01 1313-1316 EaFA
                                                                                                                                                                          1-959
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone.
1 1 ug/L
Zn EaFA-L01-1316-T01-A 1 2.13E+01
Zn EaFA-L01-1316-T02-A 1 2.58E+01
Zn EaFA-L01-1316-T03-A 1 3.78E+01
Zn EaFA-L01-1316-T04-A 1 1.26E+01
Zn EaFA-L01-1316-T05-A
Zn EaFA-L01-1316-T01-B 1 2.39E+01
Zn EaFA-L01-1316-T02-B 1 2.36E+01
Zn EaFA-L01-1316-T03-B 1 3.15E+01
Zn EaFA-L01-1316-T04-B 1 1.69E+01
Zn EaFA-L01-1316-T05-B
Zn EaFA-L01-1316-T01-C 1 1.45E+01
Zn EaFA-L01-1316-T02-C 1 2.33E+01
Zn EaFA-L01-1316-T03-C 1 3.37E+01
Zn EaFA-L01-1316-T04-C 1 1.68E+01
Zn EaFA-L01-1316-T05-C
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.13E+01 5.0E+00 1.0E+00 3.2E+00
2.58E+01 2.2E+00 1.0E+00 3.2E+00 10 250
3.78E+01 5.3E+00 1.0E+00 3.2E+00
1.26E+01 6.4E+00 1.0E+00 3.2E+00

2.39E+01 2.9E+00 1.0E+00 3.2E+00
2.36E+01 4.4E+00 1.0E+00 3.2E+00 10 250
3.15E+01 1.4E+00 1.0E+00 3.2E+00
1.69E+01 5.5E+00 1.0E+00 3.2E+00

1.45E+01 8.0E+00 1.0E+00 3.2E+00
2.33E+01 2.7E+00 1.0E+00 3.2E+00 10 250
3.37E+01 1.8E+00 1.0E+00 3.2E+00
1.68E+01 4.9E+00 1.0E+00 3.2E+00

Zn EaFA-L01-1316-B01-A 1 2.47E+00 E 2.47E+00 1.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.67E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.62E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
2.46E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
6/9/10 1:50 PM EPA Interlab L01 1313-1316 EaFA
6/9/101:51 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:53 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:55 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:03 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 1:58 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:00 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:01 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 2:05 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:07 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:08 PM EPA Interlab L01 1313-1316 EaFA
6/9/10 2:10 PM EPA Interlab L01 1313-1316 EaFA

6/9/10 11:58 AM EPA Interlab L01 1313-1316 EaFA
                                                                                                                                                                          1-960
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al EaFa-L02-1316-T01-A 1
Al EaFa-L02-1316-T02-A 1
Al EaFa-L02-1316-T03-A 1
Al EaFa-L02-1316-T04-A 1
Al EaFa-L02-1316-T05-A 1
Al EaFa-L02-1316-T01-B 1
Al EaFa-L02-1316-T02-B 1
Al EaFa-L02-1316-T03-B 1
Al EaFa-L02-1316-T04-B 1
Al EaFa-L02-1316-T05-B 1
Al EaFa-L02-1316-T01-C 1
Al EaFa-L02-1316-T02-C 1
Al EaFa-L02-1316-T03-C 1
Al EaFa-L02-1316-T04-C 1
Al EaFa-L02-1316-T05-C 1
Al EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.75E+02
2.06E+02
2.25E+02
4.46E+02
3.61 E+02
1.85E+02
2.09E+02
2.35E+02
4.58E+02
4.31 E+02
1.65E+02
1.98E+02
2.35E+02
4.42E+02
3.92E+02
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.75E+02 1.2E+02 1.0E+00 3.2E+00
2.06E+02 1.2E+01 1.0E+00 3.2E+00 1000 100
2.25E+02 5.6E+00 1.0E+00 3.2E+00
4.46E+02 1.8E+02 1.0E+00 3.2E+00
3.61E+02 2.2E+00 1.0E+00 3.2E+00
1.85E+02 2.6E+01 1.0E+00 3.2E+00
2.09E+02 1.9E+00 1.0E+00 3.2E+00 1000 100
2.35E+02 3.9E-01 1.0E+00 3.2E+00
4.58E+02 6.7E-01 1.0E+00 3.2E+00
4.31 E+02 2.3E-01 1.0E+00 3.2E+00
1.65E+02 1.1E+00 1.0E+00 3.2E+00
1.98E+02 3.9E+00 1.0E+00 3.2E+00 1000 100
2.35E+02 3.2E+00 1.0E+00 3.2E+00
4.42E+02 7.0E-01 1.0E+00 3.2E+00
3.92E+02 1.9E+00 1.0E+00 3.2E+00
5.00E-01 4.8E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.28E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .20E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                                   1-961
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qu
1 ug"-
Sb EaFa-L02-1316-T01-A 1 2.06E+02
Sb EaFa-L02-1316-T02-A 1 2.61E+02
Sb EaFa-L02-1316-T03-A 1 4.25E+02
Sb EaFa-L02-1316-T04-A 1 6.73E+02
Sb EaFa-L02-1316-T05-A 1 5.94E+02
Sb EaFa-L02-1316-T01-B 1 1.74E+02
Sb EaFa-L02-1316-T02-B 1 3.47E+02
Sb EaFa-L02-1316-T03-B 1 5.17E+02
Sb EaFa-L02-1316-T04-B 1 7.26E+02
Sb EaFa-L02-1316-T05-B 1 7.09E+02
Sb EaFa-L02-1316-T01-C 1 2.39E+02
Sb EaFa-L02-1316-T02-C 1 3.48E+02
Sb EaFa-L02-1316-T03-C 1 5.25E+02
Sb EaFa-L02-1316-T04-C 1 6.86E+02
Sb EaFa-L02-1316-T05-C 1 6.25E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.06E+02 1.3E+02 7.5E+00 2.4E+01
2.61E+02 1.8E+01 7.5E+00 2.4E+01 10 300
4.25E+02 5.2E+00 7.5E+00 2.4E+01
6.73E+02 1.7E+02 7.5E+00 2.4E+01
5.94E+02 5.9E+00 7.5E+00 2.4E+01
1.74E+02 1.5E+01 7.5E+00 2.4E+01
3.47E+02 5.5E+00 7.5E+00 2.4E+01 10 300
5.17E+02 1.2E+00 7.5E+00 2.4E+01
7.26E+02 2.1E+00 7.5E+00 2.4E+01
7.09E+02 2.8E+00 7.5E+00 2.4E+01
2.39E+02 1.7E+01 7.5E+00 2.4E+01
3.48E+02 6.9E+00 7.5E+00 2.4E+01 10 300
5.25E+02 4.2E+00 7.5E+00 2.4E+01
6.86E+02 5.6E+00 7.5E+00 2.4E+01
6.25E+02 2.0E+00 7.5E+00 2.4E+01
Sb EaFa-L02-1316-B01-A 1 3.75E+00 U1/2 3.75E+00 1.0E+04 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.78E+03 1 1 7% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.72E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.64E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-962
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As EaFa-L02-1316-T01-A 1
As EaFa-L02-1316-T02-A 1
As EaFa-L02-1316-T03-A 1
As EaFa-L02-1316-T04-A 1
As EaFa-L02-1316-T05-A 1
As EaFa-L02-1316-T01-B 1
As EaFa-L02-1316-T02-B 1
As EaFa-L02-1316-T03-B 1
As EaFa-L02-1316-T04-B 1
As EaFa-L02-1316-T05-B 1
As EaFa-L02-1316-T01-C 1
As EaFa-L02-1316-T02-C 1
As EaFa-L02-1316-T03-C 1
As EaFa-L02-1316-T04-C 1
As EaFa-L02-1316-T05-C 1
As EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.36E+02
1.13E+02
1.24E+02
1.69E+02
2.20E+02
1.20E+02
1.67E+02
1.46E+02
1.95E+02
2.07E+02
1.20E+02
1.46E+02
1.30E+02
1.51E+02
1.86E+02
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.36E+02 1.5E+02 1.1E+01 3.5E+01
1.13E+02 3.1E+01 1.1E+01 3.5E+01 10 300
1.24E+02 3.8E+01 1.1E+01 3.5E+01
1.69E+02 1.9E+02 1.1E+01 3.5E+01
2.20E+02 2.0E+01 1.1E+01 3.5E+01
1.20E+02 6.3E+01 1.1E+01 3.5E+01
1.67E+02 1.9E+01 1.1E+01 3.5E+01 10 300
1.46E+02 9.8E+00 1.1E+01 3.5E+01
1.95E+02 2.0E+01 1.1E+01 3.5E+01
2.07E+02 2.0E+01 1.1E+01 3.5E+01
1.20E+02 4.3E+00 1.1E+01 3.5E+01
1.46E+02 2.2E+01 1.1E+01 3.5E+01 10 300
1.30E+02 8.2E+00 1.1E+01 3.5E+01
1.51E+02 1.6E+01 1.1E+01 3.5E+01
1.86E+02 1.6E+01 1.1E+01 3.5E+01
5.50E+00 5.7E+02 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.58E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.45E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.44E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-963
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B EaFa-L02-1316-T01-A 1
B EaFa-L02-1316-T02-A 1
B EaFa-L02-1316-T03-A 1
B EaFa-L02-1316-T04-A 1
B EaFa-L02-1316-T05-A 1
B EaFa-L02-1316-T01-B 1
B EaFa-L02-1316-T02-B 1
B EaFa-L02-1316-T03-B 1
B EaFa-L02-1316-T04-B 1
B EaFa-L02-1316-T05-B 1
B EaFa-L02-1316-T01-C 1
B EaFa-L02-1316-T02-C 1
B EaFa-L02-1316-T03-C 1
B EaFa-L02-1316-T04-C 1
B EaFa-L02-1316-T05-C 1
B EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
4.34E+03
7.64E+03
1.76E+04
3.80E+04
3.04E+04
5.19E+03
9.49E+03
2.18E+04
3.91 E+04
3.41 E+04
5.61 E+03
9.40E+03
2.20E+04
3.82E+04
3.15E+04
4.68E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.34E+03 7.2E+01 1.0E+00 3.2E+00
7.64E+03 6.2E+00 1.0E+00 3.2E+00 1000 100
1.76E+04 5.0E+00 1.0E+00 3.2E+00
3.80E+04 1.3E+02 1.0E+00 3.2E+00
3.04E+04 6.2E-01 1.0E+00 3.2E+00
5.19E+03 2.0E+01 1.0E+00 3.2E+00
9.49E+03 1.2E+00 1.0E+00 3.2E+00 1000 100
2.18E+04 1.8E+00 1.0E+00 3.2E+00
3.91 E+04 8.5E-01 1.0E+00 3.2E+00
3.41 E+04 4.6E-01 1.0E+00 3.2E+00
5.61 E+03 1.4E-01 1.0E+00 3.2E+00
9.40E+03 1.2E+00 1.0E+00 3.2E+00 1000 100
2.20E+04 1.9E+00 1.0E+00 3.2E+00
3.82E+04 2.1E-01 1.0E+00 3.2E+00
3.15E+04 6.6E-01 1.0E+00 3.2E+00
4.68E+01 5.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.52E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .04E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .03E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46AMEPAInterlabL02 1313-1316 EaFA
                                                                                                                                                                          1-964
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFa-L02-1316-T01-A 1
Ba EaFa-L02-1316-T02-A 1
Ba EaFa-L02-1316-T03-A 1
Ba EaFa-L02-1316-T04-A 1
Ba EaFa-L02-1316-T05-A 1
Ba EaFa-L02-1316-T01-B 1
Ba EaFa-L02-1316-T02-B 1
Ba EaFa-L02-1316-T03-B 1
Ba EaFa-L02-1316-T04-B 1
Ba EaFa-L02-1316-T05-B 1
Ba EaFa-L02-1316-T01-C 1
Ba EaFa-L02-1316-T02-C 1
Ba EaFa-L02-1316-T03-C 1
Ba EaFa-L02-1316-T04-C 1
Ba EaFa-L02-1316-T05-C 1
Ba EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.90E+02
2.20E+02
2.14E+02
2.42E+02
1.85E+02
2.81 E+02
2.79E+02
2.43E+02
2.64E+02
2.26E+02
3.31 E+02
2.73E+02
2.42E+02
2.53E+02
2.06E+02
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.90E+02 9.2E+01 1.0E+00 3.2E+00
2.20E+02 1.1E+01 1.0E+00 3.2E+00 10 300
2.14E+02 5.3E+00 1.0E+00 3.2E+00
2.42E+02 1.5E+02 1.0E+00 3.2E+00
1.85E+02 1.3E+00 1.0E+00 3.2E+00
2.81 E+02 6.7E+01 1.0E+00 3.2E+00
2.79E+02 9.6E-01 1.0E+00 3.2E+00 10 300
2.43E+02 1.0E+00 1.0E+00 3.2E+00
2.64E+02 3.7E-01 1.0E+00 3.2E+00
2.26E+02 1.2E+00 1.0E+00 3.2E+00
3.31 E+02 3.3E-01 1.0E+00 3.2E+00
2.73E+02 5.9E-01 1.0E+00 3.2E+00 10 300
2.42E+02 1.4E+00 1.0E+00 3.2E+00
2.53E+02 3.3E-01 1.0E+00 3.2E+00
2.06E+02 1.2E+00 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.35E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.27E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.23E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-965
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFa-L02-1316-T01-A 1
Be EaFa-L02-1316-T02-A 1
Be EaFa-L02-1316-T03-A 1
Be EaFa-L02-1316-T04-A 1
Be EaFa-L02-1316-T05-A 1
Be EaFa-L02-1316-T01-B 1
Be EaFa-L02-1316-T02-B 1
Be EaFa-L02-1316-T03-B 1
Be EaFa-L02-1316-T04-B 1
Be EaFa-L02-1316-T05-B 1
Be EaFa-L02-1316-T01-C 1
Be EaFa-L02-1316-T02-C 1
Be EaFa-L02-1316-T03-C 1
Be EaFa-L02-1316-T04-C 1
Be EaFa-L02-1316-T05-C 1
Be EaFa-L02-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 2.6E+01 1.9E+00 6.0E+00 10 300
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 4.7E+01 1.9E+00 6.0E+00
9.50E-01 2.4E+01 1.9E+00 6.0E+00
9.50E-01 5.5E+02 1.9E+00 6.0E+00 10 300
9.50E-01 4.3E+02 1.9E+00 6.0E+00
9.50E-01 4.2E+03 1.9E+00 6.0E+00
9.50E-01 6.5E+01 1.9E+00 6.0E+00
9.50E-01 4.2E+01 1.9E+00 6.0E+00
9.50E-01 2.5E+02 1.9E+00 6.0E+00 10 300
9.50E-01 6.4E+02 1.9E+00 6.0E+00
9.50E-01 5.7E+02 1.9E+00 6.0E+00
9.50E-01 6.3E+01 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.41E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.29E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.30E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/1012:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-966
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFa-L02-1316-T01-A 1
Cd EaFa-L02-1316-T02-A 1
Cd EaFa-L02-1316-T03-A 1
Cd EaFa-L02-1316-T04-A 1
Cd EaFa-L02-1316-T05-A 1
Cd EaFa-L02-1316-T01-B 1
Cd EaFa-L02-1316-T02-B 1
Cd EaFa-L02-1316-T03-B 1
Cd EaFa-L02-1316-T04-B 1
Cd EaFa-L02-1316-T05-B 1
Cd EaFa-L02-1316-T01-C 1
Cd EaFa-L02-1316-T02-C 1
Cd EaFa-L02-1316-T03-C 1
Cd EaFa-L02-1316-T04-C 1
Cd EaFa-L02-1316-T05-C 1
Cd EaFa-L02-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
1.10E+00 U1/2
1.10E+00 U1/2
3.11E+00 E
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
7.89E+00
2.84E+00 E
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
7.62E+00
3.28E+00 E
1.10E+00 U1/2
1.10E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 3.6E+01 2.2E+00 7.0E+00
1.10E+00 7.4E+02 2.2E+00 7.0E+00 10 300
3.11E+00 7.4E+00 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
1.10E+00 7.9E+00 2.2E+00 7.0E+00
1.10E+00 6.1E+01 2.2E+00 7.0E+00 10 300
7.89E+00 4.9E+00 2.2E+00 7.0E+00
2.84E+00 1.3E+01 2.2E+00 7.0E+00
1.10E+00 9.8E+01 2.2E+00 7.0E+00
1.10E+00 8.6E+02 2.2E+00 7.0E+00
1.10E+00 1.5E+02 2.2E+00 7.0E+00 10 300
7.62E+00 8.6E+00 2.2E+00 7.0E+00
3.28E+00 2.3E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
1.10E+00 1.1E+00 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.47E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.37E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.33E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/1012:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-967
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca EaFa-L02-1316-T01-A 1
Ca EaFa-L02-1316-T02-A 1
Ca EaFa-L02-1316-T03-A 1
Ca EaFa-L02-1316-T04-A 1
Ca EaFa-L02-1316-T05-A 1
Ca EaFa-L02-1316-T01-B 1
Ca EaFa-L02-1316-T02-B 1
Ca EaFa-L02-1316-T03-B 1
Ca EaFa-L02-1316-T04-B 1
Ca EaFa-L02-1316-T05-B 1
Ca EaFa-L02-1316-T01-C 1
Ca EaFa-L02-1316-T02-C 1
Ca EaFa-L02-1316-T03-C 1
Ca EaFa-L02-1316-T04-C 1
Ca EaFa-L02-1316-T05-C 1
Ca EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.66E+05
2.94E+05
6.46E+05
5.95E+05
6.70E+05
1.81E+05
3.57E+05
7.75E+05
6.12E+05
6.64E+05
1.78E+05
3.47E+05
7.74E+05
5.91 E+05
6.04E+05
1.30E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.66E+05 8.7E+01 2.6E+00 8.3E+00
2.94E+05 1.1E+01 2.6E+00 8.3E+00 1000 100
6.46E+05 5.1E+00 2.6E+00 8.3E+00
5.95E+05 1.5E+02 2.6E+00 8.3E+00
6.70E+05 1.9E-01 2.6E+00 8.3E+00
1.81 E+05 6.8E+01 2.6E+00 8.3E+00
3.57E+05 1.2E+00 2.6E+00 8.3E+00 1000 100
7.75E+05 6.3E-01 2.6E+00 8.3E+00
6.12E+05 7.5E-01 2.6E+00 8.3E+00
6.64E+05 1.1E+00 2.6E+00 8.3E+00
1.78E+05 2.0E-01 2.6E+00 8.3E+00
3.47E+05 4.9E-01 2.6E+00 8.3E+00 1000 100
7.74E+05 1.1E+00 2.6E+00 8.3E+00
5.91 E+05 7.9E-01 2.6E+00 8.3E+00
6.04E+05 6.3E-01 2.6E+00 8.3E+00
1.30E+00 7.9E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
2.95E+05 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.58E+05 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.48E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-968
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr EaFa-L02-1316-T01-A 1
Cr EaFa-L02-1316-T02-A 1
Cr EaFa-L02-1316-T03-A 1
Cr EaFa-L02-1316-T04-A 1
Cr EaFa-L02-1316-T05-A 1
Cr EaFa-L02-1316-T01-B 1
Cr EaFa-L02-1316-T02-B 1
Cr EaFa-L02-1316-T03-B 1
Cr EaFa-L02-1316-T04-B 1
Cr EaFa-L02-1316-T05-B 1
Cr EaFa-L02-1316-T01-C 1
Cr EaFa-L02-1316-T02-C 1
Cr EaFa-L02-1316-T03-C 1
Cr EaFa-L02-1316-T04-C 1
Cr EaFa-L02-1316-T05-C 1
Cr EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.71E+01
1.90E+01
1.85E+01
3.60E+01
4.35E+01
1.68E+01
1.94E+01
1.86E+01
4.27E+01
4.92E+01
1.47E+01
1.86E+01
1.86E+01
4.16E+01
4.37E+01
6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.71E+01 1.1E+02 1.2E+00 3.8E+00
1.90E+01 1.4E+01 1.2E+00 3.8E+00 10 300
1.85E+01 6.9E+00 1.2E+00 3.8E+00
3.60E+01 1.8E+02 1.2E+00 3.8E+00
4.35E+01 3.7E+00 1.2E+00 3.8E+00
1.68E+01 2.9E+01 1.2E+00 3.8E+00
1.94E+01 4.8E+00 1.2E+00 3.8E+00 10 300
1.86E+01 3.4E+00 1.2E+00 3.8E+00
4.27E+01 2.6E+00 1.2E+00 3.8E+00
4.92E+01 3.1E+00 1.2E+00 3.8E+00
1.47E+01 7.3E+00 1.2E+00 3.8E+00
1.86E+01 1.4E+01 1.2E+00 3.8E+00 10 300
1.86E+01 7.3E+00 1.2E+00 3.8E+00
4.16E+01 4.7E+00 1.2E+00 3.8E+00
4.37E+01 2.0E+00 1.2E+00 3.8E+00
6.00E-01 1.9E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.28E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.37E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-969
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFa-L02-1316-T01-A 1
Co EaFa-L02-1316-T02-A 1
Co EaFa-L02-1316-T03-A 1
Co EaFa-L02-1316-T04-A 1
Co EaFa-L02-1316-T05-A 1
Co EaFa-L02-1316-T01-B 1
Co EaFa-L02-1316-T02-B 1
Co EaFa-L02-1316-T03-B 1
Co EaFa-L02-1316-T04-B 1
Co EaFa-L02-1316-T05-B 1
Co EaFa-L02-1316-T01-C 1
Co EaFa-L02-1316-T02-C 1
Co EaFa-L02-1316-T03-C 1
Co EaFa-L02-1316-T04-C 1
Co EaFa-L02-1316-T05-C 1
Co EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.76E+01
5.36E+01
1.89E+02
1.60E+02
1.01E+02
3.61E+01
1.02E+02
2.96E+02
1.79E+02
1.19E+02
5.16E+01
1.03E+02
2.94E+02
1.72E+02
1.07E+02
9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.76E+01 1.4E+02 1.8E+00 5.7E+00
5.36E+01 1.1E+01 1.8E+00 5.7E+00 10 300
1.89E+02 7.2E+00 1.8E+00 5.7E+00
1.60E+02 1.7E+02 1.8E+00 5.7E+00
1.01E+02 4.2E-01 1.8E+00 5.7E+00
3.61 E+01 1.9E+01 1.8E+00 5.7E+00
1.02E+02 3.1E+00 1.8E+00 5.7E+00 10 300
2.96E+02 1.7E+00 1.8E+00 5.7E+00
1.79E+02 2.9E+00 1.8E+00 5.7E+00
1.19E+02 3.9E+00 1.8E+00 5.7E+00
5.16E+01 5.5E+00 1.8E+00 5.7E+00
1.03E+02 2.6E+00 1.8E+00 5.7E+00 10 300
2.94E+02 2.6E+00 1.8E+00 5.7E+00
1.72E+02 2.0E+00 1.8E+00 5.7E+00
1.07E+02 3.6E+00 1.8E+00 5.7E+00
9.00E-01 2.4E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.39E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.31E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.39E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-970
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone.
1 ug/L
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Cu EaFa-L02-1316-T01-A 1 1.01E+01 E 1.01E+01 1.1E+02 3.7E+00 1.2E+01
Cu EaFa-L02-1316-T02-A 1 1.49E+01
Cu EaFa-L02-1316-T03-A 1 2.30E+01
Cu EaFa-L02-1316-T04-A 1 1.71E+01
Cu EaFa-L02-1316-T05-A 1 1.64E+01
Cu EaFa-L02-1316-T01-B 1 1.74E+01
Cu EaFa-L02-1316-T02-B 1 1.41E+01
Cu EaFa-L02-1316-T03-B 1 1.51E+01
Cu EaFa-L02-1316-T04-B 1 1.47E+01
Cu EaFa-L02-1316-T05-B 1 1.32E+01
1.49E+01 5.6E+01 3.7E+00 1.2E+01 10 300
2.30E+01 3.4E+01 3.7E+00 1.2E+01
1.71E+01 3.2E+02 3.7E+00 1.2E+01
1.64E+01 2.6E+01 3.7E+00 1.2E+01
1.74E+01 5.6E+01 3.7E+00 1.2E+01
1.41E+01 2.2E+01 3.7E+00 1.2E+01 10 300
1.51E+01 9.7E+00 3.7E+00 1.2E+01
1.47E+01 4.4E+01 3.7E+00 1.2E+01
1.32E+01 8.2E+00 3.7E+00 1.2E+01
Cu EaFa-L02-1316-T01-C 1 8.90E+00 E 8.90E+00 2.0E+01 3.7E+00 1.2E+01
Cu EaFa-L02-1316-T02-C 1 9.23E+00 E 9.23E+00 4.8E+01 3.7E+00 1.2E+01 10 300
Cu EaFa-L02-1316-T03-C 1 1.33E+01
Cu EaFa-L02-1316-T04-C 1 1.32E+01
1.33E+01 2.5E+01 3.7E+00 1.2E+01
1.32E+01 4.1E+01 3.7E+00 1.2E+01
Cu EaFa-L02-1316-T05-C 1 1.16E+01 E 1.16E+01 7.3E+01 3.7E+00 1.2E+01
Cu EaFa-L02-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 1.1E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.31E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.20E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.39E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46AMEPAInterlabL02 1313-1316 EaFA
                                                                                                                                                                          1-971
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. (
1 ug/L 1
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Fe EaFa-L02-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 1.2E+01 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 6.6E+00 2.0E+00 6.4E+00 1000 100
Fe EaFa-L02-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 3.4E+00 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T04-A 1 1.00E+OOU1/2 1.00E+00 1.7E+01 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T05-A 1 1.00E+OOU1/2 1.00E+00 1.8E+00 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 3.9E+00 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00 1000 100
Fe EaFa-L02-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 9.4E+00 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T04-B 1 1.00E+OOU1/2 1.00E+00 2.0E+01 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T05-B 1 1.00E+OOU1/2 1.00E+00 1.6E+01 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 7.8E+00 2.0E+00 6.4E+00 1000 100
Fe EaFa-L02-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 1.0E+01 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T04-C 1 1.00E+OOU1/2 1.00E+00 2.3E+01 2.0E+00 6.4E+00
Fe EaFa-L02-1316-T05-C 1 1.00E+OOU1/2 1.00E+00 9.7E+00 2.0E+00 6.4E+00
Fe EaFa-L02-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 1.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.83E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .04E+03 1 04% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/1012:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-972
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFa-L02-1316-T01-A 1
Pb EaFa-L02-1316-T02-A 1
Pb EaFa-L02-1316-T03-A 1
Pb EaFa-L02-1316-T04-A 1
Pb EaFa-L02-1316-T05-A 1
Pb EaFa-L02-1316-T01-B 1
Pb EaFa-L02-1316-T02-B 1
Pb EaFa-L02-1316-T03-B 1
Pb EaFa-L02-1316-T04-B 1
Pb EaFa-L02-1316-T05-B 1
Pb EaFa-L02-1316-T01-C 1
Pb EaFa-L02-1316-T02-C 1
Pb EaFa-L02-1316-T03-C 1
Pb EaFa-L02-1316-T04-C 1
Pb EaFa-L02-1316-T05-C 1
Pb EaFa-L02-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 3.3E+01 6.8E+00 2.2E+01
3.40E+00 7.6E+01 6.8E+00 2.2E+01 10 300
3.40E+00 3.0E+02 6.8E+00 2.2E+01
3.40E+00 2.4E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+01 6.8E+00 2.2E+01
3.40E+00 2.9E+01 6.8E+00 2.2E+01
3.40E+00 1.0E+02 6.8E+00 2.2E+01 10 300
3.40E+00 5.0E+01 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01
3.40E+00 5.2E+01 6.8E+00 2.2E+01
3.40E+00 1.8E+01 6.8E+00 2.2E+01
3.40E+00 8.8E+01 6.8E+00 2.2E+01 10 300
3.40E+00 4.6E+01 6.8E+00 2.2E+01
3.40E+00 2.4E+02 6.8E+00 2.2E+01
3.40E+00 2.3E+00 6.8E+00 2.2E+01
3.40E+00 1.6E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.24E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.17E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.12E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/1012:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-973
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFa-L02-1316-T01-A 1
Li EaFa-L02-1316-T02-A 1
Li EaFa-L02-1316-T03-A 1
Li EaFa-L02-1316-T04-A 1
Li EaFa-L02-1316-T05-A 1
Li EaFa-L02-1316-T01-B 1
Li EaFa-L02-1316-T02-B 1
Li EaFa-L02-1316-T03-B 1
Li EaFa-L02-1316-T04-B 1
Li EaFa-L02-1316-T05-B 1
Li EaFa-L02-1316-T01-C 1
Li EaFa-L02-1316-T02-C 1
Li EaFa-L02-1316-T03-C 1
Li EaFa-L02-1316-T04-C 1
Li EaFa-L02-1316-T05-C 1
Li EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.55E+03
5.91 E+03
1.40E+04
3.25E+04
2.76E+04
3.92E+03
9.05E+03
2.05E+04
4.03E+04
3.36E+04
4.59E+03
8.76E+03
2.06E+04
3.90E+04
3.07E+04
8.32E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.55E+03 1.0E+02 1.9E+00 6.0E+00
5.91E+03 1.1E+01 1.9E+00 6.0E+00 10 300
1.40E+04 4.8E+00 1.9E+00 6.0E+00
3.25E+04 1.5E+02 1.9E+00 6.0E+00
2.76E+04 2.7E-01 1.9E+00 6.0E+00
3.92E+03 9.0E+01 1.9E+00 6.0E+00
9.05E+03 9.4E-01 1.9E+00 6.0E+00 10 300
2.05E+04 9.1E-01 1.9E+00 6.0E+00
4.03E+04 4.6E-01 1.9E+00 6.0E+00
3.36E+04 1.4E+00 1.9E+00 6.0E+00
4.59E+03 2.9E-01 1.9E+00 6.0E+00
8.76E+03 3.0E-01 1.9E+00 6.0E+00 10 300
2.06E+04 1.4E+00 1.9E+00 6.0E+00
3.90E+04 9.3E-01 1.9E+00 6.0E+00
3.07E+04 3.1E-01 1.9E+00 6.0E+00
8.32E+00 1.1E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.94E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46AMEPAInterlabL02 1313-1316 EaFA
                                                                                                                                                                          1-974
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFa-L02-1316-T01-A 1
Mn EaFa-L02-1316-T02-A 1
Mn EaFa-L02-1316-T03-A 1
Mn EaFa-L02-1316-T04-A 1
Mn EaFa-L02-1316-T05-A 1
Mn EaFa-L02-1316-T01-B 1
Mn EaFa-L02-1316-T02-B 1
Mn EaFa-L02-1316-T03-B 1
Mn EaFa-L02-1316-T04-B 1
Mn EaFa-L02-1316-T05-B 1
Mn EaFa-L02-1316-T01-C 1
Mn EaFa-L02-1316-T02-C 1
Mn EaFa-L02-1316-T03-C 1
Mn EaFa-L02-1316-T04-C 1
Mn EaFa-L02-1316-T05-C 1
Mn EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.37E+02
5.06E+02
1.35E+03
1.61E+03
1.01E+03
3.30E+02
7.66E+02
1.92E+03
1.68E+03
1.11E+03
4.11E+02
7.48E+02
1.92E+03
1.63E+03
1.03E+03
1.00E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.37E+02 7.3E+01 2.0E+00 6.4E+00
5.06E+02 9.2E+00 2.0E+00 6.4E+00 10 300
1.35E+03 3.9E+00 2.0E+00 6.4E+00
1.61E+03 1.4E+02 2.0E+00 6.4E+00
1.01E+03 6.4E-01 2.0E+00 6.4E+00
3.30E+02 6.8E+01 2.0E+00 6.4E+00
7.66E+02 1.4E+00 2.0E+00 6.4E+00 10 300
1.92E+03 7.8E-01 2.0E+00 6.4E+00
1.68E+03 5.5E-01 2.0E+00 6.4E+00
1.11E+03 1.9E+00 2.0E+00 6.4E+00
4.11E+02 7.1E-01 2.0E+00 6.4E+00
7.48E+02 5.9E-01 2.0E+00 6.4E+00 10 300
1.92E+03 6.9E-01 2.0E+00 6.4E+00
1.63E+03 1.1E+00 2.0E+00 6.4E+00
1.03E+03 1.8E-01 2.0E+00 6.4E+00
1.00E+00 9.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.74E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.75E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.75E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-975
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFa-L02-1316-T01-A 1
Mg EaFa-L02-1316-T02-A 1
Mg EaFa-L02-1316-T03-A 1
Mg EaFa-L02-1316-T04-A 1
Mg EaFa-L02-1316-T05-A 1
Mg EaFa-L02-1316-T01-B 1
Mg EaFa-L02-1316-T02-B 1
Mg EaFa-L02-1316-T03-B 1
Mg EaFa-L02-1316-T04-B 1
Mg EaFa-L02-1316-T05-B 1
Mg EaFa-L02-1316-T01-C 1
Mg EaFa-L02-1316-T02-C 1
Mg EaFa-L02-1316-T03-C 1
Mg EaFa-L02-1316-T04-C 1
Mg EaFa-L02-1316-T05-C 1
Mg EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
7.33E+03
1.25E+04
3.17E+04
7.13E+04
6.46E+04
7.61 E+03
1.57E+04
3.84E+04
7.10E+04
6.23E+04
7.83E+03
1.51E+04
3.80E+04
6.85E+04
5.76E+04
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.33E+03 9.9E+01 1.0E+00 3.2E+00
1.25E+04 1.1E+01 1.0E+00 3.2E+00 1000 100
3.17E+04 6.6E+00 1.0E+00 3.2E+00
7.13E+04 1.5E+02 1.0E+00 3.2E+00
6.46E+04 9.1E-01 1.0E+00 3.2E+00
7.61 E+03 6.4E+01 1.0E+00 3.2E+00
1.57E+04 3.8E-01 1.0E+00 3.2E+00 1000 100
3.84E+04 1.0E+00 1.0E+00 3.2E+00
7.10E+04 7.1E-01 1.0E+00 3.2E+00
6.23E+04 1.6E+00 1.0E+00 3.2E+00
7.83E+03 7.7E-01 1.0E+00 3.2E+00
1.51E+04 9.5E-01 1.0E+00 3.2E+00 1000 100
3.80E+04 9.4E-01 1.0E+00 3.2E+00
6.85E+04 4.1E-01 1.0E+00 3.2E+00
5.76E+04 5.2E-01 1.0E+00 3.2E+00
5.00E-01 1.4E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.36E+04 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.67E+04 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .61 E+04 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-976
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo EaFa-L02-1316-T01-A 1
Mo EaFa-L02-1316-T02-A 1
Mo EaFa-L02-1316-T03-A 1
Mo EaFa-L02-1316-T04-A 1
Mo EaFa-L02-1316-T05-A 1
Mo EaFa-L02-1316-T01-B 1
Mo EaFa-L02-1316-T02-B 1
Mo EaFa-L02-1316-T03-B 1
Mo EaFa-L02-1316-T04-B 1
Mo EaFa-L02-1316-T05-B 1
Mo EaFa-L02-1316-T01-C 1
Mo EaFa-L02-1316-T02-C 1
Mo EaFa-L02-1316-T03-C 1
Mo EaFa-L02-1316-T04-C 1
Mo EaFa-L02-1316-T05-C 1
Mo EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.43E+03
5.77E+03
1.18E+04
2.72E+04
2.50E+04
3.32E+03
7.27E+03
1.44E+04
2.94E+04
2.81 E+04
3.68E+03
6.95E+03
1.43E+04
2.83E+04
2.55E+04
6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.43E+03 7.8E+01 1.2E+00 3.8E+00
5.77E+03 1.1E+01 1.2E+00 3.8E+00 10 300
1.18E+04 4.9E+00 1.2E+00 3.8E+00
2.72E+04 1.4E+02 1.2E+00 3.8E+00
2.50E+04 4.9E-01 1.2E+00 3.8E+00
3.32E+03 6.6E+01 1.2E+00 3.8E+00
7.27E+03 6.5E-01 1.2E+00 3.8E+00 10 300
1.44E+04 1.3E+00 1.2E+00 3.8E+00
2.94E+04 3.7E-01 1.2E+00 3.8E+00
2.81 E+04 1.9E+00 1.2E+00 3.8E+00
3.68E+03 2.4E-02 1.2E+00 3.8E+00
6.95E+03 3.9E-01 1.2E+00 3.8E+00 10 300
1.43E+04 1.3E+00 1.2E+00 3.8E+00
2.83E+04 4.3E-01 1.2E+00 3.8E+00
2.55E+04 1.4E+00 1.2E+00 3.8E+00
6.00E-01 3.5E+03 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.08E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .OOE+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.94E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-977
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFa-L02-1316-T01-A 1
Ni EaFa-L02-1316-T02-A 1
Ni EaFa-L02-1316-T03-A 1
Ni EaFa-L02-1316-T04-A 1
Ni EaFa-L02-1316-T05-A 1
Ni EaFa-L02-1316-T01-B 1
Ni EaFa-L02-1316-T02-B 1
Ni EaFa-L02-1316-T03-B 1
Ni EaFa-L02-1316-T04-B 1
Ni EaFa-L02-1316-T05-B 1
Ni EaFa-L02-1316-T01-C 1
Ni EaFa-L02-1316-T02-C 1
Ni EaFa-L02-1316-T03-C 1
Ni EaFa-L02-1316-T04-C 1
Ni EaFa-L02-1316-T05-C 1
Ni EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.03E+02
1.38E+02
4.36E+02
3.78E+02
2.52E+02
9.75E+01
2.51 E+02
6.71 E+02
4.28E+02
2.83E+02
1.35E+02
2.40E+02
6.75E+02
4.18E+02
2.58E+02
9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.03E+02 1.0E+02 1.8E+00 5.7E+00
1.38E+02 9.5E+00 1.8E+00 5.7E+00 10 300
4.36E+02 4.7E+00 1.8E+00 5.7E+00
3.78E+02 1.5E+02 1.8E+00 5.7E+00
2.52E+02 1.6E+00 1.8E+00 5.7E+00
9.75E+01 3.1 E+02 1.8E+00 5.7E+00
2.51E+02 2.3E+00 1.8E+00 5.7E+00 10 300
6.71 E+02 6.9E-01 1.8E+00 5.7E+00
4.28E+02 1.2E+00 1.8E+00 5.7E+00
2.83E+02 2.2E+00 1.8E+00 5.7E+00
1.35E+02 3.0E+00 1.8E+00 5.7E+00
2.40E+02 1.3E+00 1.8E+00 5.7E+00 10 300
6.75E+02 3.2E+00 1.8E+00 5.7E+00
4.18E+02 2.3E+00 1.8E+00 5.7E+00
2.58E+02 1.9E+00 1.8E+00 5.7E+00
9.00E-01 1.2E+03 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.51E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.44E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.54E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-978
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P EaFa-L02-1316-T01-A 1
P EaFa-L02-1316-T02-A 1
P EaFa-L02-1316-T03-A 1
P EaFa-L02-1316-T04-A 1
P EaFa-L02-1316-T05-A 1
P EaFa-L02-1316-T01-B 1
P EaFa-L02-1316-T02-B 1
P EaFa-L02-1316-T03-B 1
P EaFa-L02-1316-T04-B 1
P EaFa-L02-1316-T05-B 1
P EaFa-L02-1316-T01-C 1
P EaFa-L02-1316-T02-C 1
P EaFa-L02-1316-T03-C 1
P EaFa-L02-1316-T04-C 1
P EaFa-L02-1316-T05-C 1
P EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
4.74E+01
6.39E+01
6.73E+01
4.44E+02
1.30E+02
5.81E+01
7.74E+01
1.19E+02
5.31 E+02
1.16E+02
7.17E+01
8.23E+01
2.46E+02
5.67E+02
1.49E+02
1.99E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.74E+01 3.5E+01 3.7E+00 1.2E+01
6.39E+01 2.1E+01 3.7E+00 1.2E+01 1000 100
6.73E+01 8.2E+00 3.7E+00 1.2E+01
4.44E+02 8.4E+01 3.7E+00 1.2E+01
1.30E+02 1.7E+01 3.7E+00 1.2E+01
5.81E+01 3.3E+01 3.7E+00 1.2E+01
7.74E+01 1.8E+01 3.7E+00 1.2E+01 1000 100
1.19E+02 2.8E+00 3.7E+00 1.2E+01
5.31 E+02 6.7E+00 3.7E+00 1.2E+01
1.16E+02 6.6E+00 3.7E+00 1.2E+01
7.17E+01 1.0E+01 3.7E+00 1.2E+01
8.23E+01 1.4E+01 3.7E+00 1.2E+01 1000 100
2.46E+02 4.2E-01 3.7E+00 1.2E+01
5.67E+02 3.8E+00 3.7E+00 1.2E+01
1.49E+02 1.3E+01 3.7E+00 1.2E+01
1.99E+01 1.0E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.12E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .08E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .09E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-979
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K EaFa-L02-1316-T01-A 1
K EaFa-L02-1316-T02-A 1
K EaFa-L02-1316-T03-A 1
K EaFa-L02-1316-T04-A 1
K EaFa-L02-1316-T05-A 1
K EaFa-L02-1316-T01-B 1
K EaFa-L02-1316-T02-B 1
K EaFa-L02-1316-T03-B 1
K EaFa-L02-1316-T04-B 1
K EaFa-L02-1316-T05-B 1
K EaFa-L02-1316-T01-C 1
K EaFa-L02-1316-T02-C 1
K EaFa-L02-1316-T03-C 1
K EaFa-L02-1316-T04-C 1
K EaFa-L02-1316-T05-C 1
K EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.62E+04
4.68E+04
1.17E+05
2.12E+05
2.05E+05
3.02E+04
5.55E+04
1.31E+05
2.04E+05
1.88E+05
2.66E+04
5.36E+04
1.32E+05
1.98E+05
1.73E+05
9.47E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.62E+04 1.0E+02 1.6E+00 5.1E+00
4.68E+04 1.2E+01 1.6E+00 5.1E+00 1000 100
1.17E+05 5.5E+00 1.6E+00 5.1E+00
2.12E+05 1.5E+02 1.6E+00 5.1E+00
2.05E+05 1.5E-01 1.6E+00 5.1E+00
3.02E+04 9.2E+01 1.6E+00 5.1E+00
5.55E+04 1.1E+00 1.6E+00 5.1E+00 1000 100
1.31E+05 1.3E+00 1.6E+00 5.1E+00
2.04E+05 5.8E-01 1.6E+00 5.1E+00
1.88E+05 2.1E+00 1.6E+00 5.1E+00
2.66E+04 9.3E-01 1.6E+00 5.1E+00
5.36E+04 4.0E-01 1.6E+00 5.1E+00 1000 100
1.32E+05 1.8E+00 1.6E+00 5.1E+00
1.98E+05 9.1E-01 1.6E+00 5.1E+00
1.73E+05 1.2E+00 1.6E+00 5.1E+00
9.47E+00 3.2E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.76E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.63E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.45E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46AMEPAInterlabL02 1313-1316 EaFA
                                                                                                                                                                          1-980
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se EaFa-L02-1316-T01-A 1
Se EaFa-L02-1316-T02-A 1
Se EaFa-L02-1316-T03-A 1
Se EaFa-L02-1316-T04-A 1
Se EaFa-L02-1316-T05-A 1
Se EaFa-L02-1316-T01-B 1
Se EaFa-L02-1316-T02-B 1
Se EaFa-L02-1316-T03-B 1
Se EaFa-L02-1316-T04-B 1
Se EaFa-L02-1316-T05-B 1
Se EaFa-L02-1316-T01-C 1
Se EaFa-L02-1316-T02-C 1
Se EaFa-L02-1316-T03-C 1
Se EaFa-L02-1316-T04-C 1
Se EaFa-L02-1316-T05-C 1
Se EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.18E+03
1.24E+03
1.46E+03
2.22E+03
2.56E+03
1.18E+03
1.54E+03
1.63E+03
2.42E+03
2.72E+03
1.21E+03
1.46E+03
1.65E+03
2.33E+03
2.53E+03
7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+03 9.9E+01 1.5E+01 4.8E+01
1.24E+03 1.2E+01 1.5E+01 4.8E+01 10 300
1.46E+03 8.7E+00 1.5E+01 4.8E+01
2.22E+03 1.6E+02 1.5E+01 4.8E+01
2.56E+03 3.7E+00 1.5E+01 4.8E+01
1.18E+03 1.1E+03 1.5E+01 4.8E+01
1.54E+03 2.1E+00 1.5E+01 4.8E+01 10 300
1.63E+03 3.6E+00 1.5E+01 4.8E+01
2.42E+03 2.4E+00 1.5E+01 4.8E+01
2.72E+03 3.0E+00 1.5E+01 4.8E+01
1.21E+03 3.4E+00 1.5E+01 4.8E+01
1.46E+03 1.6E+00 1.5E+01 4.8E+01 10 300
1.65E+03 3.7E+00 1.5E+01 4.8E+01
2.33E+03 3.3E+00 1.5E+01 4.8E+01
2.53E+03 1.4E+00 1.5E+01 4.8E+01
7.50E+00 1.5E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.83E+03 120% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.60E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.52E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-981
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si EaFa-L02-1316-T01-A 1
Si EaFa-L02-1316-T02-A 1
Si EaFa-L02-1316-T03-A 1
Si EaFa-L02-1316-T04-A 1
Si EaFa-L02-1316-T05-A 1
Si EaFa-L02-1316-T01-B 1
Si EaFa-L02-1316-T02-B 1
Si EaFa-L02-1316-T03-B 1
Si EaFa-L02-1316-T04-B 1
Si EaFa-L02-1316-T05-B 1
Si EaFa-L02-1316-T01-C 1
Si EaFa-L02-1316-T02-C 1
Si EaFa-L02-1316-T03-C 1
Si EaFa-L02-1316-T04-C 1
Si EaFa-L02-1316-T05-C 1
Si EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.37E+03
2.04E+03
3.02E+03
2.67E+03
2.31 E+03
2.28E+03
3.15E+03
3.83E+03
2.85E+03
2.60E+03
2.77E+03
3.00E+03
3.82E+03
2.75E+03
2.37E+03
5.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.37E+03 8.1E+01 1.1E+00 3.5E+00
2.04E+03 1.0E+01 1.1E+00 3.5E+00 1000 100
3.02E+03 5.2E+00 1.1E+00 3.5E+00
2.67E+03 1.5E+02 1.1E+00 3.5E+00
2.31E+03 2.1E+00 1.1E+00 3.5E+00
2.28E+03 8.0E+01 1.1E+00 3.5E+00
3.15E+03 9.0E-01 1.1E+00 3.5E+00 1000 100
3.83E+03 8.3E-01 1.1E+00 3.5E+00
2.85E+03 6.1E-01 1.1E+00 3.5E+00
2.60E+03 1.6E+00 1.1E+00 3.5E+00
2.77E+03 9.9E-01 1.1E+00 3.5E+00
3.00E+03 7.0E-01 1.1E+00 3.5E+00 1000 100
3.82E+03 1.8E+00 1.1E+00 3.5E+00
2.75E+03 9.6E-01 1.1E+00 3.5E+00
2.37E+03 6.2E-01 1.1E+00 3.5E+00
5.50E-01 4.1E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.20E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.16E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.13E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-982
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFa-L02-1316-T01-A 1
Na EaFa-L02-1316-T02-A 1
Na EaFa-L02-1316-T03-A 1
Na EaFa-L02-1316-T04-A 1
Na EaFa-L02-1316-T05-A 1
Na EaFa-L02-1316-T01-B 1
Na EaFa-L02-1316-T02-B 1
Na EaFa-L02-1316-T03-B 1
Na EaFa-L02-1316-T04-B 1
Na EaFa-L02-1316-T05-B 1
Na EaFa-L02-1316-T01-C 1
Na EaFa-L02-1316-T02-C 1
Na EaFa-L02-1316-T03-C 1
Na EaFa-L02-1316-T04-C 1
Na EaFa-L02-1316-T05-C 1
Na EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
5.56E+03
9.77E+03
2.47E+04
4.75E+04
4.45E+04
6.34E+03
1.29E+04
3.09E+04
5.12E+04
4.46E+04
6.12E+03
1.25E+04
3.10E+04
4.93E+04
4.06E+04
1.25E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.56E+03 1.0E+02 2.5E+00 8.0E+00
9.77E+03 1.1E+01 2.5E+00 8.0E+00 1000 100
2.47E+04 5.7E+00 2.5E+00 8.0E+00
4.75E+04 1.5E+02 2.5E+00 8.0E+00
4.45E+04 1.2E+00 2.5E+00 8.0E+00
6.34E+03 7.0E+01 2.5E+00 8.0E+00
1.29E+04 1.2E+00 2.5E+00 8.0E+00 1000 100
3.09E+04 5.8E-01 2.5E+00 8.0E+00
5.12E+04 1.3E-01 2.5E+00 8.0E+00
4.46E+04 9.1E-01 2.5E+00 8.0E+00
6.12E+03 3.6E-01 2.5E+00 8.0E+00
1.25E+04 5.6E-01 2.5E+00 8.0E+00 1000 100
3.10E+04 1.7E+00 2.5E+00 8.0E+00
4.93E+04 3.0E-02 2.5E+00 8.0E+00
4.06E+04 1.8E+00 2.5E+00 8.0E+00
1.25E+00 1.6E+02 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .08E+04 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .38E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .34E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-983
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
EaFa-L02-1316-T01-A 1
EaFa-L02-1316-T02-A 1
EaFa-L02-1316-T03-A 1
EaFa-L02-1316-T04-A 1
EaFa-L02-1316-T05-A 1
EaFa-L02-1316-T01-B 1
EaFa-L02-1316-T02-B 1
EaFa-L02-1316-T03-B 1
EaFa-L02-1316-T04-B 1
EaFa-L02-1316-T05-B 1
EaFa-L02-1316-T01-C 1
EaFa-L02-1316-T02-C 1
EaFa-L02-1316-T03-C 1
EaFa-L02-1316-T04-C 1
EaFa-L02-1316-T05-C 1
EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.26E+03
3.75E+03
7.74E+03
8.33E+03
9.55E+03
2.32E+03
4.57E+03
9.07E+03
8.57E+03
1.00E+04
2.45E+03
4.42E+03
9.08E+03
8.26E+03
9.30E+03
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.26E+03 7.4E+01 1.0E+00 3.2E+00
3.75E+03 9.1E+00 1.0E+00 3.2E+00 1000 100
7.74E+03 4.8E+00 1.0E+00 3.2E+00
8.33E+03 1.4E+02 1.0E+00 3.2E+00
9.55E+03 7.0E-01 1.0E+00 3.2E+00
2.32E+03 6.7E+01 1.0E+00 3.2E+00
4.57E+03 1.5E+00 1.0E+00 3.2E+00 1000 100
9.07E+03 1.1E+00 1.0E+00 3.2E+00
8.57E+03 8.9E-01 1.0E+00 3.2E+00
1.00E+04 2.1E+00 1.0E+00 3.2E+00
2.45E+03 4.1E-01 1.0E+00 3.2E+00
4.42E+03 9.3E-01 1.0E+00 3.2E+00 1000 100
9.08E+03 1.1E+00 1.0E+00 3.2E+00
8.26E+03 1.2E+00 1.0E+00 3.2E+00
9.30E+03 4.7E-01 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.81E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.64E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.55E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-984
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S EaFa-L02-1316-T01-A 1
S EaFa-L02-1316-T02-A 1
S EaFa-L02-1316-T03-A 1
S EaFa-L02-1316-T04-A 1
S EaFa-L02-1316-T05-A 1
S EaFa-L02-1316-T01-B 1
S EaFa-L02-1316-T02-B 1
S EaFa-L02-1316-T03-B 1
S EaFa-L02-1316-T04-B 1
S EaFa-L02-1316-T05-B 1
S EaFa-L02-1316-T01-C 1
S EaFa-L02-1316-T02-C 1
S EaFa-L02-1316-T03-C 1
S EaFa-L02-1316-T04-C 1
S EaFa-L02-1316-T05-C 1
S EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.68E+05
2.91 E+05
6.62E+05
8.17E+05
8.73E+05
1.75E+05
3.69E+05
8.15E+05
8.49E+05
8.80E+05
1.84E+05
3.54E+05
8.25E+05
8.25E+05
8.12E+05
3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.68E+05 9.6E+01 6.8E+00 2.2E+01
2.91E+05 1.1E+01 6.8E+00 2.2E+01 1000 100
6.62E+05 4.9E+00 6.8E+00 2.2E+01
8.17E+05 1.5E+02 6.8E+00 2.2E+01
8.73E+05 8.9E-01 6.8E+00 2.2E+01
1.75E+05 6.7E+01 6.8E+00 2.2E+01
3.69E+05 8.8E-01 6.8E+00 2.2E+01 1000 100
8.15E+05 1.2E+00 6.8E+00 2.2E+01
8.49E+05 2.5E-01 6.8E+00 2.2E+01
8.80E+05 2.3E+00 6.8E+00 2.2E+01
1.84E+05 7.4E-02 6.8E+00 2.2E+01
3.54E+05 2.6E-01 6.8E+00 2.2E+01 1000 100
8.25E+05 2.0E+00 6.8E+00 2.2E+01
8.25E+05 6.5E-01 6.8E+00 2.2E+01
8.12E+05 6.7E-01 6.8E+00 2.2E+01
3.40E+00 3.0E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.83E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.58E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.52E+05 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-985
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFa-L02-1316-T01-A 1
Tl EaFa-L02-1316-T02-A 1
Tl EaFa-L02-1316-T03-A 1
Tl EaFa-L02-1316-T04-A 1
Tl EaFa-L02-1316-T05-A 1
Tl EaFa-L02-1316-T01-B 1
Tl EaFa-L02-1316-T02-B 1
Tl EaFa-L02-1316-T03-B 1
Tl EaFa-L02-1316-T04-B 1
Tl EaFa-L02-1316-T05-B 1
Tl EaFa-L02-1316-T01-C 1
Tl EaFa-L02-1316-T02-C 1
Tl EaFa-L02-1316-T03-C 1
Tl EaFa-L02-1316-T04-C 1
Tl EaFa-L02-1316-T05-C 1
Tl EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.30E+00 U1/2
2.30E+00 U1/2
2.17E+01
2.69E+01
2.09E+01
2.30E+00 U1/2
2.21E+01
2.28E+01
2.96E+01
4.11E+01
2.30E+00 U1/2
2.67E+01
3.32E+01
3.84E+01
2.23E+01
2.30E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 1.5E+02 4.6E+00 1.5E+01
2.30E+00 2.4E+02 4.6E+00 1.5E+01 10 300
2.17E+01 2.8E+01 4.6E+00 1.5E+01
2.69E+01 3.8E+03 4.6E+00 1.5E+01
2.09E+01 7.2E+01 4.6E+00 1.5E+01
2.30E+00 1.4E+01 4.6E+00 1.5E+01
2.21E+01 2.5E+01 4.6E+00 1.5E+01 10 300
2.28E+01 2.0E+00 4.6E+00 1.5E+01
2.96E+01 5.6E+01 4.6E+00 1.5E+01
4.11E+01 2.2E+01 4.6E+00 1.5E+01
2.30E+00 5.4E+02 4.6E+00 1.5E+01
2.67E+01 3.7E+01 4.6E+00 1.5E+01 10 300
3.32E+01 3.3E+01 4.6E+00 1.5E+01
3.84E+01 1.4E+01 4.6E+00 1.5E+01
2.23E+01 8.5E+01 4.6E+00 1.5E+01
2.30E+00 5.5E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.23E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.17E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.14E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/1012:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-986
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFa-L02-1316-T01-A 1
Ti EaFa-L02-1316-T02-A 1
Ti EaFa-L02-1316-T03-A 1
Ti EaFa-L02-1316-T04-A 1
Ti EaFa-L02-1316-T05-A 1
Ti EaFa-L02-1316-T01-B 1
Ti EaFa-L02-1316-T02-B 1
Ti EaFa-L02-1316-T03-B 1
Ti EaFa-L02-1316-T04-B 1
Ti EaFa-L02-1316-T05-B 1
Ti EaFa-L02-1316-T01-C 1
Ti EaFa-L02-1316-T02-C 1
Ti EaFa-L02-1316-T03-C 1
Ti EaFa-L02-1316-T04-C 1
Ti EaFa-L02-1316-T05-C 1
Ti EaFa-L02-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00 10 300
1.00E+00 3.8E+01 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 9.5E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00 10 300
1.00E+00 4.5E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+02 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00 10 300
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 6.9E+01 2.0E+00 6.4E+00
1.00E+00 4.2E+00 2.0E+00 6.4E+00
1.00E+00 2.7E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.27E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.20E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.17E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/1012:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-987
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFa-L02-1316-T01-A 1
V EaFa-L02-1316-T02-A 1
V EaFa-L02-1316-T03-A 1
V EaFa-L02-1316-T04-A 1
V EaFa-L02-1316-T05-A 1
V EaFa-L02-1316-T01-B 1
V EaFa-L02-1316-T02-B 1
V EaFa-L02-1316-T03-B 1
V EaFa-L02-1316-T04-B 1
V EaFa-L02-1316-T05-B 1
V EaFa-L02-1316-T01-C 1
V EaFa-L02-1316-T02-C 1
V EaFa-L02-1316-T03-C 1
V EaFa-L02-1316-T04-C 1
V EaFa-L02-1316-T05-C 1
V EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.86E+02
2.65E+02
3.36E+02
3.97E+02
3.94E+02
2.72E+02
3.58E+02
3.90E+02
4.35E+02
4.39E+02
2.88E+02
3.31 E+02
3.87E+02
4.07E+02
4.05E+02
1.63E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.86E+02 9.3E+01 1.5E+00 4.8E+00
2.65E+02 1.0E+01 1.5E+00 4.8E+00 10 300
3.36E+02 5.8E+00 1.5E+00 4.8E+00
3.97E+02 1.4E+02 1.5E+00 4.8E+00
3.94E+02 2.2E-01 1.5E+00 4.8E+00
2.72E+02 6.8E+01 1.5E+00 4.8E+00
3.58E+02 1.8E+00 1.5E+00 4.8E+00 10 300
3.90E+02 1.2E+00 1.5E+00 4.8E+00
4.35E+02 7.4E-01 1.5E+00 4.8E+00
4.39E+02 2.7E+00 1.5E+00 4.8E+00
2.88E+02 1.1E+00 1.5E+00 4.8E+00
3.31E+02 9.9E-01 1.5E+00 4.8E+00 10 300
3.87E+02 2.2E+00 1.5E+00 4.8E+00
4.07E+02 6.4E-01 1.5E+00 4.8E+00
4.05E+02 1.4E+00 1.5E+00 4.8E+00
1.63E+00 1.2E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.63E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.52E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.48E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46 AM EPA Interlab L02 1313-1316 EaFA
                                                                                                                                                                          1-988
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn EaFa-L02-1316-T01-A 1
Zn EaFa-L02-1316-T02-A 1
Zn EaFa-L02-1316-T03-A 1
Zn EaFa-L02-1316-T04-A 1
Zn EaFa-L02-1316-T05-A 1
Zn EaFa-L02-1316-T01-B 1
Zn EaFa-L02-1316-T02-B 1
Zn EaFa-L02-1316-T03-B 1
Zn EaFa-L02-1316-T04-B 1
Zn EaFa-L02-1316-T05-B 1
Zn EaFa-L02-1316-T01-C 1
Zn EaFa-L02-1316-T02-C 1
Zn EaFa-L02-1316-T03-C 1
Zn EaFa-L02-1316-T04-C 1
Zn EaFa-L02-1316-T05-C 1
Zn EaFa-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.96E+01
1.95E+01
3.21E+01
2.88E+01
2.18E+01
9.32E+00
2.27E+01
5.91E+01
3.56E+01
3.17E+01
1.42E+01
2.08E+01
6.14E+01
3.37E+01
2.30E+01
1.15E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.96E+01 9.4E+01 1.0E+00 3.2E+00
1.95E+01 8.7E+00 1.0E+00 3.2E+00 10 300
3.21 E+01 8.1E+00 1.0E+00 3.2E+00
2.88E+01 1.4E+02 1.0E+00 3.2E+00
2.18E+01 3.7E+00 1.0E+00 3.2E+00
9.32E+00 2.9E+02 1.0E+00 3.2E+00
2.27E+01 2.8E+00 1.0E+00 3.2E+00 10 300
5.91 E+01 3.2E-01 1.0E+00 3.2E+00
3.56E+01 1.5E+00 1.0E+00 3.2E+00
3.17E+01 4.1E+00 1.0E+00 3.2E+00
1.42E+01 6.2E+00 1.0E+00 3.2E+00
2.08E+01 4.2E+00 1.0E+00 3.2E+00 10 300
6.14E+01 4.3E+00 1.0E+00 3.2E+00
3.37E+01 2.6E+00 1.0E+00 3.2E+00
2.30E+01 5.7E+00 1.0E+00 3.2E+00
1.15E+00 7.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.45E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.34E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 4:25 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:27 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:29 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:30 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:32 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 4:33 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:01 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:03 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:04 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:06 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:08 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:09 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:11 PMEPAInterlabL02 1313-1316 EaFA
6/4/10 12:13 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 12:14 PM EPA Interlab L02 1313-1316 EaFA
6/4/10 11:46AMEPAInterlabL02 1313-1316 EaFA
                                                                                                                                                                          1-989
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
ug/L
1 1 .87E+02
1 2.00E+02
1 2.67E+02
1 6.16E+02
1 9.34E+02
1 1 .55E+02
1 2.43E+02
1 2.62E+02
1 4.98E+02
1 9.42E+02
1 1 .43E+02
1 1 J4E+02
1 2.85E+02
1 5.55E+02
1 1 .60E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES
Cone. RSD
ug/L %
1 .87E+02 1 .4E+00
2.00E+02 1.2E+00
2.67E+02 7.2E-01
6.16E+02 1.2E+00
9.34E+02 5.0E-02
1 .55E+02 1 .6E+00
2.43E+02 9.7E-01
2.62E+02 2.7E+00
4.98E+02 4.3E-01
9.42E+02 5.8E-01
1 .43E+02 8.9E-01
1.74E+02 6.2E-01
2.85E+02 2.3E+00
5.55E+02 1.4E-01
1 .60E+03 8.9E-01
5.00E-01 5.6E+02
5.00E-01 1.6E+01
5.00E-01 1.3E+01
MDL
ug/L
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.32E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .42E+03 1 1 7% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                                   1-990
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Sb Sample Dilution Cone. Qualifier Review
1 ug/L
Sb EaFA-L04-1316-T01-A 1 1.81E+02
Sb EaFA-L04-1316-T02-A 1 2.99E+02
Sb EaFA-L04-1316-T03-A 1 4.23E+02
Sb EaFA-L04-1316-T04-A 1 6.19E+02
Sb EaFA-L04-1316-T05-A 1 7.15E+02
Sb EaFA-L04-1316-T01-B 1 1.61E+02
Sb EaFA-L04-1316-T02-B 1 2.96E+02
Sb EaFA-L04-1316-T03-B 1 4.33E+02
Sb EaFA-L04-1316-T04-B 1 6.16E+02
Sb EaFA-L04-1316-T05-B 1 6.91E+02
Sb EaFA-L04-1316-T01-C 1 2.11E+02
Sb EaFA-L04-1316-T02-C 1 3.32E+02
Sb EaFA-L04-1316-T03-C 1 4.88E+02
Sb EaFA-L04-1316-T04-C 1 6.73E+02
Sb EaFA-L04-1316-T05-C 1 8.91E+02
Sb EaFA-L04-1316-B01-A 1 3.75E+00 U1/2
Sb EaFA-L04-1316-B02-A 1 3.75E+00 U1/2
Sb EaFA-L04-1316-B03-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.81E+02 7.6E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
2.99E+02 1.1E+01 7.5E+00 2.4E+01 10 325 3.91E+03 111% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
4.23E+02 7.1E+00 7.5E+00 2.4E+01
6.19E+02 3.3E+00 7.5E+00 2.4E+01
7.15E+02 1.6E+00 7.5E+00 2.4E+01
1.61E+02 1.3E+01 7.5E+00 2.4E+01
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
2.96E+02 7.0E+00 7.5E+00 2.4E+01 10 325 4.08E+03 117% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
4.33E+02 4.4E+00 7.5E+00 2.4E+01
6.16E+02 4.1E+00 7.5E+00 2.4E+01
6.91 E+02 1.7E+00 7.5E+00 2.4E+01
2.11E+02 9.2E+00 7.5E+00 2.4E+01
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
3.32E+02 2.4E+00 7.5E+00 2.4E+01 10 325 3.91E+03 110% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
4.88E+02 2.4E+00 7.5E+00 2.4E+01
6.73E+02 2.8E+00 7.5E+00 2.4E+01
8.91 E+02 2.3E+00 7.5E+00 2.4E+01
3.75E+00 5.7E+01 7.5E+00 2.4E+01
3.75E+00 1.9E+02 7.5E+00 2.4E+01
3.75E+00 6.6E+02 7.5E+00 2.4E+01
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                          1-991
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample In
As Sample Dilution Cone. Qualifier R<
ug/L
As EaFA-L04-1316-T01-A 1 1 .48E+02
As EaFA-L04-1316-T02-A 1 1 .49E+02
As EaFA-L04-1316-T03-A 1 1 .27E+02
As EaFA-L04-1316-T04-A 1 1 JOE+02
As EaFA-L04-1316-T05-A 1 2.27E+02
As EaFA-L04-1316-T01-B 1 1 .38E+02
As EaFA-L04-1316-T02-B 1 1 .52E+02
As EaFA-L04-1316-T03-B 1 1.16E+02
As EaFA-L04-1316-T04-B 1 1.91E+02
As EaFA-L04-1316-T05-B 1 2.45E+02
As EaFA-L04-1316-T01-C 1 1 .66E+02
As EaFA-L04-1316-T02-C 1 1 J6E+02
As EaFA-L04-1316-T03-C 1 1 J2E+02
As EaFA-L04-1316-T04-C 1 2.07E+02
As EaFA-L04-1316-T05-C 1 2.76E+02
As EaFA-L04-1316-B01-A 1 4.44E+01
As EaFA-L04-1316-B02-A 1 2.43E+01 E
As EaFA-L04-1316-B03-A 1 2.75E+01 E
ernal ICP-OES Spike Sol'n
;view Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.48E+02 1.2E+01 1.1E+01 3.5E+01
1.49E+02 2.4E+01 1.1E+01 3.5E+01 10 325
1.27E+02 1.3E+01 1.1E+01 3.5E+01
1.70E+02 1.5E+01 1.1E+01 3.5E+01
2.27E+02 1.3E+00 1.1E+01 3.5E+01
1.38E+02 4.0E+00 1.1E+01 3.5E+01
1.52E+02 9.9E+00 1.1E+01 3.5E+01 10 325
1.16E+02 1.2E+01 1.1E+01 3.5E+01
1.91E+02 6.4E+00 1.1E+01 3.5E+01
2.45E+02 5.0E+00 1.1E+01 3.5E+01
1.66E+02 7.4E+00 1.1E+01 3.5E+01
1.76E+02 1.3E+01 1.1E+01 3.5E+01 10 325
1.72E+02 9.5E+00 1.1E+01 3.5E+01
2.07E+02 4.6E+00 1.1E+01 3.5E+01
2.76E+02 2.8E+00 1.1E+01 3.5E+01
4.44E+01 8.4E+00 1.1E+01 3.5E+01
2.43E+01 4.1E+01 1.1E+01 3.5E+01
2.75E+01 4.2E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
3.84E+03 113% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
3.96E+03 117% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
3.82E+03 112% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                          1-992
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 4.54E+03
1 9.00E+03
1 2.02E+04
1 3.87E+04
1 6.43E+04
1 5.62E+03
1 9.32E+03
1 2.14E+04
1 3.97E+04
1 6.58E+04
1 5.75E+03
1 9.22E+03
1 2.30E+04
1 3.98E+04
1 6.74E+04
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES
Cone. RSD
ug/L %
4.54E+03 1.3E+00
9.00E+03 1.3E+00
2.02E+04 1.3E+00
3.87E+04 9.2E-01
6.43E+04 1.5E+00
5.62E+03 2.3E+00
9.32E+03 1.0E+00
2.14E+04 2.0E+00
3.97E+04 1.0E+00
6.58E+04 2.2E+00
5.75E+03 1.7E+00
9.22E+03 1.3E+00
2.30E+04 2.3E+00
3.98E+04 7.2E-01
6.74E+04 9.8E-01
5.00E-01 4.4E+00
5.00E-01 5.6E+00
5.00E-01 4.9E+00
MDL
ug/L
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1.0E+00
1 .OE+00
1 .OE+00
1. OE+00
1. OE+00
1. OE+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.90E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .02E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .01 E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                          1-993
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 3.29E+02
1 2.54E+02
1 2.37E+02
1 2.64E+02
1 3.37E+02
1 3.33E+02
1 2.47E+02
1 2.33E+02
1 2.96E+02
1 3.58E+02
1 3.41 E+02
1 2.59E+02
1 2.60E+02
1 2.89E+02
1 3.61 E+02
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES
Cone. RSD
ug/L %
3.29E+02 1.2E-01
2.54E+02 1.1E-01
2.37E+02 5.9E-01
2.64E+02 4.3E-01
3.37E+02 1.2E+00
3.33E+02 2.5E-01
2.47E+02 3.6E-01
2.33E+02 1.1E+00
2.96E+02 1.5E+00
3.58E+02 1.0E+00
3.41 E+02 8.1E-01
2.59E+02 8.4E-01
2.60E+02 2.0E+00
2.89E+02 5.5E-01
3.61 E+02 1.2E+00
5.00E-01 2.4E+02
5.00E-01 5.4E+00
5.00E-01 2.5E+00
MDL
ug/L
1 .OE+00
1 .OE+00
1 .OE+00
1 .OE+00
1. OE+00
1 .OE+00
1 .OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
3.2E+00
3.2E+00 10 325
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 10 325
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 10 325
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.83E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.96E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.83E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/1012:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                          1-994
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Be Sample Dilution Cone. Qualifier Review
1 ug/L
Be EaFA-L04-1316-T01-A 1 9.50E-01 U1/2
Be EaFA-L04-1316-T02-A 1 9.50E-01 U1/2
Be EaFA-L04-1316-T03-A 1 9.50E-01 U1/2
Be EaFA-L04-1316-T04-A 1 9.50E-01 U1/2
Be EaFA-L04-1316-T05-A 1 9.50E-01 U1/2
Be EaFA-L04-1316-T01-B 1 9.50E-01 U1/2
Be EaFA-L04-1316-T02-B 1 9.50E-01 U1/2
Be EaFA-L04-1316-T03-B 1 9.50E-01 U1/2
Be EaFA-L04-1316-T04-B 1 9.50E-01 U1/2
Be EaFA-L04-1316-T05-B 1 9.50E-01 U1/2
Be EaFA-L04-1316-T01-C 1 9.50E-01 U1/2
Be EaFA-L04-1316-T02-C 1 9.50E-01 U1/2
Be EaFA-L04-1316-T03-C 1 9.50E-01 U1/2
Be EaFA-L04-1316-T04-C 1 9.50E-01 U1/2
Be EaFA-L04-1316-T05-C 1 9.50E-01 U1/2
Be EaFA-L04-1316-B01-A 1 9.50E-01 U1/2
Be EaFA-L04-1316-B02-A 1 9.50E-01 U1/2
Be EaFA-L04-1316-B03-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 8.7E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
9.50E-01 1.2E+02 1.9E+00 6.0E+00 10 325 3.61E+03 111% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
9.50E-01 2.8E+01 1.9E+00 6.0E+00
9.50E-01 2.4E+01 1.9E+00 6.0E+00
9.50E-01 8.8E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
9.50E-01 1.1E+02 1.9E+00 6.0E+00 10 325 3.77E+03 116% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
9.50E-01 3.4E+02 1.9E+00 6.0E+00
9.50E-01 4.2E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
9.50E-01 1.3E+02 1.9E+00 6.0E+00 10 325 3.57E+03 110% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 5.5E+02 1.9E+00 6.0E+00
9.50E-01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 3.8E+01 1.9E+00 6.0E+00
9.50E-01 3.5E+01 1.9E+00 6.0E+00
9.50E-01 4.5E+02 1.9E+00 6.0E+00
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                          1-995
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 1.10E+OOU1/2
1 2.91E+OOE
1 5.63E+00 E
1 2.98E+00 E
1 2.88E+00 E
1 2.27E+00 E
1 2.90E+00 E
1 4.59E+00 E
1 2.68E+00 E
1 1.10E+OOU1/2
1 2.29E+00 E
1 2.51E+OOE
1 5.27E+00 E
1 1.10E+OOU1/2
1 3.13E+00 E
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 1.10E+OOU1/2
ICP-OES
Cone. RSD
ug/L %
1.10E+00 1.3E+01
2.91 E+00 1.5E+01
5.63E+00 7.1 E+00
2.98E+00 2.2E+01
2.88E+00 3.0E+01
2.27E+00 2.2E+01
2.90E+00 1.9E+01
4.59E+00 1.1E+01
2.68E+00 1.6E+01
1.10E+00 3.5E+01
2.29E+00 1.9E+01
2.51E+00 1.2E+01
5.27E+00 1.5E+01
1.10E+00 1.7E+01
3.13E+00 2.6E+01
1.10E+00 3.3E+04
1.10E+00 7.2E+01
1.10E+00 4.6E+02
MDL
ug/L
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
2.2E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
7.0E+00
7.0E+00 10 325
7.0E+00
7.0E+00
7.0E+00
7.0E+00
7.0E+00 10 325
7.0E+00
7.0E+00
7.0E+00
7.0E+00
7.0E+00 10 325
7.0E+00
7.0E+00
7.0E+00
7.0E+00
7.0E+00
7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.63E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.78E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.61 E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                          1-996
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample In
Ca Sample Dilution Cone. Qualifier R<
1 1 ug/L |
Ca EaFA-L04-1316-T01-A 1 1 .56E+05
Ca EaFA-L04-1316-T02-A 1 3.06E+05
Ca EaFA-L04-1316-T03-A 1 6.36E+05
Ca EaFA-L04-1316-T04-A 1 5.64E+05
Ca EaFA-L04-1316-T05-A 1 4.91E+05
Ca EaFA-L04-1316-T01-B 1 1.50E+05
Ca EaFA-L04-1316-T02-B 1 2.99E+05
Ca EaFA-L04-1316-T03-B 1 6.76E+05
Ca EaFA-L04-1316-T04-B 1 5.58E+05
Ca EaFA-L04-1316-T05-B 1 5.24E+05
Ca EaFA-L04-1316-T01-C 1 1.51E+05
Ca EaFA-L04-1316-T02-C 1 3.01E+05
Ca EaFA-L04-1316-T03-C 1 7.52E+05
Ca EaFA-L04-1316-T04-C 1 5.69E+05
Ca EaFA-L04-1316-T05-C 1 5.27E+05
Ca EaFA-L04-1316-B01-A 1 1.23E+01
Ca EaFA-L04-1316-B02-A 1 1.20E+01
Ca EaFA-L04-1316-B03-A 1 1.24E+01
ernal ICP-OES Spike Sol'n
;view Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.56E+05 5.2E-01 2.6E+00 8.3E+00
3.06E+05 4.9E-01 2.6E+00 8.3E+00 1000 100
6.36E+05 3.3E-01 2.6E+00 8.3E+00
5.64E+05 3.2E-01 2.6E+00 8.3E+00
4.91 E+05 1.4E+00 2.6E+00 8.3E+00
1.50E+05 1.0E+00 2.6E+00 8.3E+00
2.99E+05 3.2E-01 2.6E+00 8.3E+00 1000 100
6.76E+05 3.0E+00 2.6E+00 8.3E+00
5.58E+05 1.3E+00 2.6E+00 8.3E+00
5.24E+05 8.7E-01 2.6E+00 8.3E+00
1.51 E+05 7.3E-01 2.6E+00 8.3E+00
3.01E+05 1.1E+00 2.6E+00 8.3E+00 1000 100
7.52E+05 1.8E+00 2.6E+00 8.3E+00
5.69E+05 6.1E-01 2.6E+00 8.3E+00
5.27E+05 7.0E-01 2.6E+00 8.3E+00
1.23E+01 5.3E+01 2.6E+00 8.3E+00
1.20E+01 3.3E+00 2.6E+00 8.3E+00
1.24E+01 2.7E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
3.07E+05 86% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
3.00E+05 90% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
3.02E+05 89% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                          1-997
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 2.44E+01
1 2.82E+01
1 2.92E+01
1 4.90E+01
1 5.28E+01
1 1.96E+01
1 2.53E+01
1 3.49E+01
1 6.81 E+01
1 6.59E+01
1 1.24E+01
1 2.14E+01
1 3.02E+01
1 7.20E+01
1 5.28E+01
1 6.00E-01 U1/2
1 6.00E-01 U1/2
1 6.00E-01 U1/2
ICP-OES
Cone. RSD
ug/L %
2.44E+01 4.5E+00
2.82E+01 3.9E+00
2.92E+01 6.8E+00
4.90E+01 4.7E+00
5.28E+01 5.7E+00
1.96E+01 2.2E+00
2.53E+01 1.4E+00
3.49E+01 8.7E+00
6.81 E+01 1.9E+00
6.59E+01 3.6E-01
1.24E+01 5.7E+00
2.14E+01 4.0E+00
3.02E+01 5.2E+00
7.20E+01 3.0E+00
5.28E+01 3.1E+00
6.00E-01 7.4E+01
6.00E-01 1.2E+02
6.00E-01 2.7E+01
MDL
ug/L
1.2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1.2E+00
1.2E+00
1.2E+00
1.2E+00
1.2E+00
1.2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1 .2E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
3.8E+00
3.8E+00 10 325
3.8E+00
3.8E+00
3.8E+00
3.8E+00
3.8E+00 10 325
3.8E+00
3.8E+00
3.8E+00
3.8E+00
3.8E+00 10 325
3.8E+00
3.8E+00
3.8E+00
3.8E+00
3.8E+00
3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.48E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.65E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.46E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                          1-998
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 3.52E+01
1 7.46E+01
1 1.74E+02
1 1.27E+02
1 1.17E+02
1 4.56E+01
1 7.79E+01
1 1.49E+02
1 9.35E+01
1 8.63E+01
1 4.67E+01
1 8.71E+01
1 1.75E+02
1 8.97E+01
1 1.09E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES
Cone. RSD
ug/L %
3.52E+01 6.1E+00
7.46E+01 1.7E+00
1.74E+02 8.8E-01
1.27E+02 1.1E+00
1.17E+02 1.7E+00
4.56E+01 7.5E+00
7.79E+01 3.3E+00
1.49E+02 4.3E+00
9.35E+01 4.4E+00
8.63E+01 2.1E+00
4.67E+01 4.7E+00
8.71E+01 2.3E+00
1.75E+02 1.9E+00
8.97E+01 4.9E+00
1.09E+02 2.3E+00
9.00E-01 7.1E+01
9.00E-01 1.1E+02
9.00E-01 9.9E+01
MDL
ug/L
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
5.7E+00
5.7E+00 10 325
5.7E+00
5.7E+00
5.7E+00
5.7E+00
5.7E+00 10 325
5.7E+00
5.7E+00
5.7E+00
5.7E+00
5.7E+00 10 325
5.7E+00
5.7E+00
5.7E+00
5.7E+00
5.7E+00
5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.45E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.61E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.44E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/1012:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                          1-999
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample In
Cu Sample Dilution Cone. Qualifier R<
1 1 ug/L |
Cu EaFA-L04-1316-T01-A 1 1.00E+01 E
Cu EaFA-L04-1316-T02-A 1 1.17E+01 E
Cu EaFA-L04-1316-T03-A 1 1.41E+01
Cu EaFA-L04-1316-T04-A 1 1.19E+01
Cu EaFA-L04-1316-T05-A 1 3.75E+01
Cu EaFA-L04-1316-T01-B 1 6.20E+00 E
Cu EaFA-L04-1316-T02-B 1 1.18E+01
Cu EaFA-L04-1316-T03-B 1 1.21E+01
Cu EaFA-L04-1316-T04-B 1 9.72E+00 E
Cu EaFA-L04-1316-T05-B 1 3.01 E+01
Cu EaFA-L04-1316-T01-C 1 8.16E+00 E
Cu EaFA-L04-1316-T02-C 1 8.10E+00 E
Cu EaFA-L04-1316-T03-C 1 1.21E+01
Cu EaFA-L04-1316-T04-C 1 1.40E+01
Cu EaFA-L04-1316-T05-C 1 3.41 E+01
Cu EaFA-L04-1316-B01-A 1 1.85E+OOU1/2
Cu EaFA-L04-1316-B02-A 1 1.85E+OOU1/2
Cu EaFA-L04-1316-B03-A 1 1.85E+OOU1/2
ernal ICP-OES Spike Sol'n
;view Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+01 3.5E+01 3.7E+00 1.2E+01
1.17E+01 1.1E+01 3.7E+00 1.2E+01 10 325
1.41 E+01 3.3E+01 3.7E+00 1.2E+01
1.19E+01 2.3E+01 3.7E+00 1.2E+01
3.75E+01 1.7E+01 3.7E+00 1.2E+01
6.20E+00 1.5E+01 3.7E+00 1.2E+01
1.18E+01 6.6E+01 3.7E+00 1.2E+01 10 325
1.21E+01 4.3E+01 3.7E+00 1.2E+01
9.72E+00 2.7E+01 3.7E+00 1.2E+01
3.01E+01 2.3E+01 3.7E+00 1.2E+01
8.16E+00 3.8E+01 3.7E+00 1.2E+01
8.10E+00 9.4E+01 3.7E+00 1.2E+01 10 325
1.21E+01 4.1E+01 3.7E+00 1.2E+01
1.40E+01 1.8E+01 3.7E+00 1.2E+01
3.41 E+01 1.3E+01 3.7E+00 1.2E+01
1.85E+00 1.8E+01 3.7E+00 1.2E+01
1.85E+00 7.4E+01 3.7E+00 1.2E+01
1.85E+00 5.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
3.45E+03 106% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
3.63E+03 111% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
3.44E+03 106% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1000
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample
Dilution Cone.
I I ug/L
1 1 .OOE+OO
1 1 .OOE+OO
1 2.60E+00
1 5.29E+01
1 7.27E+01
1 2.60E+00
1 2.11E+01
1 1 .OOE+OO
1 1 .OOE+OO
1 4.63E+01
1 1 .OOE+OO
1 1 .OOE+OO
1 2.02E+00
1 9.80E+00
1 2.32E+02
1 1 .OOE+OO
1 1. OOE+OO
1 1. OOE+OO
Internal
Qualifier Review
U1/2
U1/2
E


E

U1/2
U1/2

U1/2
U1/2
E


U1/2
U1/2
U1/2
ICP-OES
Cone. RSD
ug/L %
1. OOE+OO 2.7E+01
1 .OOE+OO 1 .4E+01
2.60E+00 1.0E+01
5.29E+01 4.9E-01
7.27E+01 1.2E+00
2.60E+00 2.0E+01
2.11E+01 2.2E+00
1. OOE+OO 3.3E+01
1. OOE+OO 4.5E+00
4.63E+01 2.6E+00
1. OOE+OO 1.1E+01
1. OOE+OO 3.0E+01
2.02E+00 1.4E+01
9.80E+00 4.8E+00
2.32E+02 8.6E-01
1. OOE+OO 1.2E+01
1. OOE+OO 1.7E+01
1. OOE+OO 2.0E+01
MDL
ug/L
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
6.4E+00
6.4E+00 1000 100
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00 1000 100
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00 1000 100
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU
1.04E+03 104%VU
VU
VU
VU
VU
1.11E+03 109% VU
VU
VU
VU
VU
1.04E+03 104%VU
VU
VU
VU
VU
VU
VU
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
Date/Time
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
Filename
12:1 3PM EPA Interlab L04
12:1 4PM EPA Interlab L04
12:16PMEPAInterlabL04
12:18PMEPAInterlabL04
12:19PMEPAInterlabL04
12:21 PMEPAInterlabL04
12:23PMEPAInterlabL04
12:24PMEPAInterlabL04
12:26PMEPAInterlabL04
12:28PMEPAInterlabL04
12:29PMEPAInterlabL04
12:31 PMEPAInterlabL04
12:32 PM EPA Interlab L04
12:34 PM EPA Interlab L04
12:36 PM EPA Interlab L04
12:08 PM EPA Interlab L04
12:09 PM EPA Interlab L04
12:11 PM EPA Interlab L04

1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
131 3-1 31 6 EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
                                                                                                                                                                         1-1001
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample
Dilution Cone.
I I ug/L
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
1 3.40E+00
Internal
Qualifier Review
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
U1/2
ICP-OES
Cone. RSD
ug/L %
3.40E+00 6.9E+01
3.40E+00 1.4E+02
3.40E+00 1.5E+03
3.40E+00 1.0E+02
3.40E+00 7.3E+01
3.40E+00 1.2E+01
3.40E+00 1.3E+02
3.40E+00 8.0E+01
3.40E+00 4.6E+01
3.40E+00 1.2E+01
3.40E+00 1.9E+02
3.40E+00 3.3E+01
3.40E+00 2.3E+01
3.40E+00 2.6E+01
3.40E+00 1.0E+01
3.40E+00 1.6E+01
3.40E+00 4.6E+01
3.40E+00 6.6E+01
MDL
ug/L
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
6.8E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
2.2E+01
2.2E+01 10 325
2.2E+01
2.2E+01
2.2E+01
2.2E+01
2.2E+01 10 325
2.2E+01
2.2E+01
2.2E+01
2.2E+01
2.2E+01 10 325
2.2E+01
2.2E+01
2.2E+01
2.2E+01
2.2E+01
2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU
3.40E+03 104% VU
VU
VU
VU
VU
3.55E+03 109% VU
VU
VU
VU
VU
3.40E+03 104% VU
VU
VU
VU
VU
VU
VU
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
Date/Time
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
Filename
12:13PMEPAInterlabL04
12:1 4PM EPA Interlab L04
12:16PMEPAInterlabL04
12:1 8PM EPA Interlab L04
12:1 9PM EPA Interlab L04
12:21 PM EPA Interlab L04
12:23PMEPAInterlabL04
12:24PMEPAInterlabL04
12:26 PM EPA Interlab L04
12:28 PM EPA Interlab L04
12:29 PM EPA Interlab L04
12:31 PM EPA Interlab L04
12:32 PM EPA Interlab L04
12:34 PM EPA Interlab L04
12:36 PM EPA Interlab L04
12:08 PM EPA Interlab L04
12:09 PM EPA Interlab L04
12:11 PM EPA Interlab L04

1313-1316 EaFA
1313-1316EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
131 3-1 31 6 EaFA
1313-1316 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
                                                                                                                                                                         1-1002
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 3.78E+03
1 7.35E+03
1 1.73E+04
1 3.52E+04
1 6.70E+04
1 3.67E+03
1 7.23E+03
1 1.70E+04
1 3.57E+04
1 6.98E+04
1 3.71 E+03
1 7.22E+03
1 1.88E+04
1 3.61 E+04
1 7.00E+04
1 3.33E+00 E
1 2.36E+00 E
1 4.56E+00 E
ICP-OES
Cone. RSD
ug/L %
3.78E+03 5.0E-01
7.35E+03 3.0E-01
1.73E+04 6.2E-01
3.52E+04 8.4E-01
6.70E+04 1.3E+00
3.67E+03 3.7E-01
7.23E+03 4.3E-01
1.70E+04 3.4E+00
3.57E+04 1.5E+00
6.98E+04 1.1E+00
3.71 E+03 7.4E-01
7.22E+03 9.6E-01
1.88E+04 1.5E+00
3.61 E+04 6.2E-01
7.00E+04 1.0E+00
3.33E+00 4.4E+01
2.36E+00 1.1E+02
4.56E+00 9.7E+01
MDL
ug/L
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
1.9E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
6.0E+00
6.0E+00 10 325
6.0E+00
6.0E+00
6.0E+00
6.0E+00
6.0E+00 10 325
6.0E+00
6.0E+00
6.0E+00
6.0E+00
6.0E+00 10 325
6.0E+00
6.0E+00
6.0E+00
6.0E+00
6.0E+00
6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .08E+04 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+04 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .08E+04 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/1012:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1003
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 3.14E+02
1 6.17E+02
1 1 .36E+03
1 1.31E+03
1 1 .45E+03
1 3.44E+02
1 6.05E+02
1 1.18E+03
1 1 .OOE+03
1 1 .20E+03
1 3.76E+02
1 6.62E+02
1 1.36E+03
1 9.73E+02
1 1.41E+03
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
ICP-OES
Cone. RSD
ug/L %
3.14E+02 4.8E-01
6.17E+02 5.7E-01
1 .36E+03 6.0E-01
1.31E+03 1.4E+00
1 .45E+03 3.5E-01
3.44E+02 1.1E+00
6.05E+02 9.5E-01
1.18E+03 1.9E+00
1 .OOE+03 4.5E-01
1.20E+03 1.1E+00
3.76E+02 7.3E-01
6.62E+02 6.1E-01
1.36E+03 2.9E+00
9.73E+02 5.4E-01
1.41E+03 1.4E+00
1.00E+00 1.6E+01
1.00E+00 3.7E+00
1.00E+00 4.1E+00
MDL
ug/L
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
6.4E+00
6.4E+00 10 325
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00 10 325
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00 10 325
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.02E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.14E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1004
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 7.48E+03
1 1 .45E+04
1 3.51 E+04
1 6.81 E+04
1 1 .22E+05
1 7.09E+03
1 1 .44E+04
1 3.47E+04
1 6.80E+04
1 1 .28E+05
1 7.24E+03
1 1.42E+04
1 3.87E+04
1 6.82E+04
1 1.25E+05
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES
Cone. RSD
ug/L %
7.48E+03 2.0E-01
1 .45E+04 3.5E-01
3.51 E+04 8.0E-01
6.81 E+04 1.1E+00
1.22E+05 2.1E+00
7.09E+03 3.3E-01
1 .44E+04 1 .4E+00
3.47E+04 6.8E+00
6.80E+04 1.1E-01
1 .28E+05 8.6E-01
7.24E+03 3.3E-01
1.42E+04 9.7E-01
3.87E+04 1.1E+00
6.82E+04 1.6E+00
1.25E+05 1.7E+00
5.00E-01 1.6E+02
5.00E-01 2.1E+00
5.00E-01 9.8E-01
MDL
ug/L
1 .OE+00
1 .OE+00
1 .OE+00
1. OE+00
1. OE+00
1 .OE+00
1. OE+00
1. OE+00
1 .OE+00
1 .OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
1. OE+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00 1000 100
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .55E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .54E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .52E+04 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1005
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 3.38E+03
1 6.30E+03
1 1 .35E+04
1 2.74E+04
1 4.54E+04
1 3.23E+03
1 6.29E+03
1 1 .39E+04
1 2.91E+04
1 5.13E+04
1 3.29E+03
1 6.24E+03
1 1.54E+04
1 3.04E+04
1 5.12E+04
1 9.12E+00
1 8.95E+00
1 6.26E+00
ICP-OES
Cone. RSD
ug/L %
3.38E+03 3.1E-01
6.30E+03 2.3E-01
1 .35E+04 7.5E-01
2.74E+04 7.4E-01
4.54E+04 8.2E-01
3.23E+03 5.9E-01
6.29E+03 7.6E-01
1.39E+04 3.1E+00
2.91E+04 1.1E+00
5.13E+04 8.0E-01
3.29E+03 7.1E-01
6.24E+03 8.1E-01
1.54E+04 1.9E+00
3.04E+04 8.9E-01
5.12E+04 1.2E+00
9.12E+00 3.0E+00
8.95E+00 1.0E+01
6.26E+00 1.7E+01
MDL
ug/L
1 .2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1 .2E+00
1.2E+00
1.2E+00
1 .2E+00
1.2E+00
1.2E+00
1.2E+00
1.2E+00
1.2E+00
1.2E+00
1.2E+00
1.2E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
3.8E+00
3.8E+00 10 325
3.8E+00
3.8E+00
3.8E+00
3.8E+00
3.8E+00 10 325
3.8E+00
3.8E+00
3.8E+00
3.8E+00
3.8E+00 10 325
3.8E+00
3.8E+00
3.8E+00
3.8E+00
3.8E+00
3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.36E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1006
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 8.66E+01
1 1.79E+02
1 3.79E+02
1 2.85E+02
1 2.80E+02
1 1.02E+02
1 1.83E+02
1 3.38E+02
1 2.19E+02
1 1.96E+02
1 1.11E+02
1 1.95E+02
1 4.05E+02
1 2.02E+02
1 2.50E+02
1 9.00E-01 U1/2
1 9.00E-01 U1/2
1 9.00E-01 U1/2
ICP-OES
Cone. RSD
ug/L %
8.66E+01 6.3E+00
1.79E+02 1.2E+00
3.79E+02 1.6E+00
2.85E+02 4.3E-01
2.80E+02 2.6E+00
1.02E+02 6.3E+00
1.83E+02 2.1E+00
3.38E+02 3.6E+00
2.19E+02 1.3E+00
1.96E+02 1.9E+00
1.11E+02 3.2E+00
1.95E+02 3.6E+00
4.05E+02 3.1E+00
2.02E+02 4.6E+00
2.50E+02 1.5E+00
9.00E-01 3.4E+02
9.00E-01 4.6E+01
9.00E-01 1.5E+03
MDL
ug/L
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
1.8E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
5.7E+00
5.7E+00 10 325
5.7E+00
5.7E+00
5.7E+00
5.7E+00
5.7E+00 10 325
5.7E+00
5.7E+00
5.7E+00
5.7E+00
5.7E+00 10 325
5.7E+00
5.7E+00
5.7E+00
5.7E+00
5.7E+00
5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.72E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.87E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.73E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/1012:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1007
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample In
P Sample Dilution Cone. Qualifier R<
1 1 ug/L |
P EaFA-L04-1316-T01-A 1 8.62E+01
P EaFA-L04-1316-T02-A 1 1.31E+02
P EaFA-L04-1316-T03-A 1 1 .48E+02
P EaFA-L04-1316-T04-A 1 2.71E+02
P EaFA-L04-1316-T05-A 1 6.74E+02
P EaFA-L04-1316-T01-B 1 8.72E+01
P EaFA-L04-1316-T02-B 1 1 .24E+02
P EaFA-L04-1316-T03-B 1 1 .35E+02
P EaFA-L04-1316-T04-B 1 1 .88E+02
P EaFA-L04-1316-T05-B 1 8.97E+02
P EaFA-L04-1316-T01-C 1 1 .06E+02
P EaFA-L04-1316-T02-C 1 1 .05E+02
P EaFA-L04-1316-T03-C 1 1.14E+02
P EaFA-L04-1316-T04-C 1 2.27E+02
P EaFA-L04-1316-T05-C 1 1 .20E+03
P EaFA-L04-1316-B01-A 1 3.95E+00 E
P EaFA-L04-1316-B02-A 1 6.86E+00 E
P EaFA-L04-1316-B03-A 1 5.10E+00 E
ernal ICP-OES Spike Sol'n
;view Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.62E+01 3.1E+01 3.7E+00 1.2E+01
1.31E+02 2.8E+01 3.7E+00 1.2E+01 1000 100
1.48E+02 1.9E+01 3.7E+00 1.2E+01
2.71E+02 4.9E+00 3.7E+00 1.2E+01
6.74E+02 6.0E+00 3.7E+00 1.2E+01
8.72E+01 3.8E+01 3.7E+00 1.2E+01
1.24E+02 2.2E+01 3.7E+00 1.2E+01 1000 100
1.35E+02 5.2E+00 3.7E+00 1.2E+01
1.88E+02 5.7E+00 3.7E+00 1.2E+01
8.97E+02 2.3E+00 3.7E+00 1.2E+01
1.06E+02 1.4E+01 3.7E+00 1.2E+01
1.05E+02 1.1E+01 3.7E+00 1.2E+01 1000 100
1.14E+02 1.0E+01 3.7E+00 1.2E+01
2.27E+02 6.1E+00 3.7E+00 1.2E+01
1.20E+03 2.2E+00 3.7E+00 1 .2E+01
3.95E+00 5.9E+00 3.7E+00 1 .2E+01
6.86E+00 2.6E+01 3.7E+00 1 .2E+01
5.10E+00 1.6E+01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
1.19E+03 106% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
1.25E+03 112% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
1.15E+03 105% VU ICP-OES 6/24/1012:31 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1008
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 2.40E+04
1 4.98E+04
1 1.23E+05
1 2.09E+05
1 3.25E+05
1 2.30E+04
1 4.92E+04
1 1.21E+05
1 2.08E+05
1 3.41 E+05
1 2.35E+04
1 4.87E+04
1 1.35E+05
1 2.15E+05
1 3.36E+05
1 6.09E+00
1 5.82E+00
1 4.12E+00 E
ICP-OES
Cone. RSD
ug/L %
2.40E+04 2.1E-01
4.98E+04 3.6E-01
1.23E+05 2.4E-01
2.09E+05 7.2E-01
3.25E+05 8.2E-01
2.30E+04 1.6E+00
4.92E+04 5.6E-01
1.21 E+05 4.0E+00
2.08E+05 6.4E-01
3.41 E+05 2.0E+00
2.35E+04 8.8E-01
4.87E+04 1.0E+00
1.35E+05 7.5E-01
2.15E+05 1.2E+00
3.36E+05 8.5E-01
6.09E+00 1.9E+01
5.82E+00 1.0E+01
4.12E+00 2.9E+00
MDL
ug/L
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
1.6E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
5.1E+00
5.1E+00 1000 100
5.1E+00
5.1E+00
5.1E+00
5.1E+00
5.1E+00 1000 100
5.1E+00
5.1E+00
5.1E+00
5.1E+00
5.1E+00 1000 100
5.1E+00
5.1E+00
5.1E+00
5.1E+00
5.1E+00
5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.07E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.01 E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.96E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1009
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Se Sample Dilution Cone. Qualifier Review
1 ug/L
Se EaFA-L04-1316-T01-A 1 1 .34E+03
Se EaFA-L04-1316-T02-A 1 1 J3E+03
Se EaFA-L04-1316-T03-A 1 1 .86E+03
Se EaFA-L04-1316-T04-A 1 2.72E+03
Se EaFA-L04-1316-T05-A 1 3.14E+03
Se EaFA-L04-1316-T01-B 1 1 .33E+03
Se EaFA-L04-1316-T02-B 1 1 .66E+03
Se EaFA-L04-1316-T03-B 1 1 .90E+03
Se EaFA-L04-1316-T04-B 1 2.74E+03
Se EaFA-L04-1316-T05-B 1 3.60E+03
Se EaFA-L04-1316-T01-C 1 1.34E+03
Se EaFA-L04-1316-T02-C 1 1.78E+03
Se EaFA-L04-1316-T03-C 1 1.94E+03
Se EaFA-L04-1316-T04-C 1 2.94E+03
Se EaFA-L04-1316-T05-C 1 3.90E+03
Se EaFA-L04-1316-B01-A 1 7.50E+00 U1/2
Se EaFA-L04-1316-B02-A 1 7.50E+00 U1/2
Se EaFA-L04-1316-B03-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.34E+03 9.4E-01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
1.73E+03 3.4E+00 1.5E+01 4.8E+01 10 325 5.15E+03 105% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
1.86E+03 3.1E+00 1.5E+01 4.8E+01
2.72E+03 1.7E+00 1.5E+01 4.8E+01
3.14E+03 1.5E+00 1.5E+01 4.8E+01
1.33E+03 2.9E+00 1.5E+01 4.8E+01
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
1.66E+03 1.9E+00 1.5E+01 4.8E+01 10 325 5.23E+03 110% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
1.90E+03 3.3E+00 1.5E+01 4.8E+01
2.74E+03 1.9E+00 1.5E+01 4.8E+01
3.60E+03 2.7E+00 1.5E+01 4.8E+01
1.34E+03 3.1E+00 1.5E+01 4.8E+01
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
1.78E+03 1.2E+00 1.5E+01 4.8E+01 10 325 5.14E+03 103% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
1.94E+03 1.9E+00 1.5E+01 4.8E+01
2.94E+03 1.3E+00 1.5E+01 4.8E+01
3.90E+03 3.2E+00 1.5E+01 4.8E+01
7.50E+00 1.9E+02 1.5E+01 4.8E+01
7.50E+00 4.8E+02 1.5E+01 4.8E+01
7.50E+00 2.8E+02 1.5E+01 4.8E+01
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1010
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample In
Si Sample Dilution Cone. Qualifier R<
1 1 ug/L |
Si EaFA-L04-1316-T01-A 1 2.07E+03
Si EaFA-L04-1316-T02-A 1 2.39E+03
Si EaFA-L04-1316-T03-A 1 2.57E+03
Si EaFA-L04-1316-T04-A 1 2.59E+03
Si EaFA-L04-1316-T05-A 1 2.70E+03
Si EaFA-L04-1316-T01-B 1 2.32E+03
Si EaFA-L04-1316-T02-B 1 2.74E+03
Si EaFA-L04-1316-T03-B 1 2.51E+03
Si EaFA-L04-1316-T04-B 1 2.07E+03
Si EaFA-L04-1316-T05-B 1 2.47E+03
Si EaFA-L04-1316-T01-C 1 2.56E+03
Si EaFA-L04-1316-T02-C 1 2.95E+03
Si EaFA-L04-1316-T03-C 1 2.75E+03
Si EaFA-L04-1316-T04-C 1 2.17E+03
Si EaFA-L04-1316-T05-C 1 3.96E+03
Si EaFA-L04-1316-B01-A 1 5.50E-01 U1/2
Si EaFA-L04-1316-B02-A 1 5.50E-01 U1/2
Si EaFA-L04-1316-B03-A 1 5.50E-01 U1/2
ernal ICP-OES Spike Sol'n
;view Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+03 1.8E-01 1.1E+00 3.5E+00
2.39E+03 1.2E+00 1.1E+00 3.5E+00 1000 100
2.57E+03 7.5E-01 1.1E+00 3.5E+00
2.59E+03 1.6E+00 1.1E+00 3.5E+00
2.70E+03 6.5E-01 1.1E+00 3.5E+00
2.32E+03 7.3E-01 1.1E+00 3.5E+00
2.74E+03 7.8E-01 1.1E+00 3.5E+00 1000 100
2.51E+03 2.3E+00 1.1E+00 3.5E+00
2.07E+03 1.5E+00 1.1E+00 3.5E+00
2.47E+03 1.2E+00 1.1E+00 3.5E+00
2.56E+03 5.7E-01 1.1E+00 3.5E+00
2.95E+03 5.6E-01 1.1E+00 3.5E+00 1000 100
2.75E+03 2.2E+00 1.1E+00 3.5E+00
2.17E+03 8.2E-01 1.1E+00 3.5E+00
3.96E+03 9.7E-01 1.1E+00 3.5E+00
5.50E-01 2.7E+00 1.1E+00 3.5E+00
5.50E-01 3.9E+00 1.1E+00 3.5E+00
5.50E-01 2.8E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
3.34E+03 95% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
3.81E+03 107% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
3.91E+03 96% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1011
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Na Sample Dilution Cone. Qualifier Review
1 ug/L
Na EaFA-L04-1316-T01-A 1 5.30E+03
Na EaFA-L04-1316-T02-A 1 1.07E+04
Na EaFA-L04-1316-T03-A 1 2.68E+04
Na EaFA-L04-1316-T04-A 1 4.60E+04
Na EaFA-L04-1316-T05-A 1 7.56E+04
Na EaFA-L04-1316-T01-B 1 5.08E+03
Na EaFA-L04-1316-T02-B 1 1.06E+04
Na EaFA-L04-1316-T03-B 1 2.59E+04
Na EaFA-L04-1316-T04-B 1 4.55E+04
Na EaFA-L04-1316-T05-B 1 7.95E+04
Na EaFA-L04-1316-T01-C 1 5.15E+03
Na EaFA-L04-1316-T02-C 1 1.05E+04
Na EaFA-L04-1316-T03-C 1 2.87E+04
Na EaFA-L04-1316-T04-C 1 4.73E+04
Na EaFA-L04-1316-T05-C 1 8.01 E+04
Na EaFA-L04-1316-B01-A 1 2.85E+01
Na EaFA-L04-1316-B02-A 1 2.93E+01
Na EaFA-L04-1316-B03-A 1 3.00E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.30E+03 5.4E-01 2.5E+00 8.0E+00
1.07E+04 1.3E-01 2.5E+00 8.0E+00 1000 100 1
2.68E+04 2.3E-01 2.5E+00 8.0E+00
4.60E+04 3.9E-01 2.5E+00 8.0E+00
7.56E+04 2.0E+00 2.5E+00 8.0E+00
5.08E+03 8.0E-01 2.5E+00 8.0E+00
1.06E+04 1.0E+00 2.5E+00 8.0E+00 1000 100 1
2.59E+04 4.1E+00 2.5E+00 8.0E+00
4.55E+04 1.3E+00 2.5E+00 8.0E+00
7.95E+04 8.8E-01 2.5E+00 8.0E+00
5.15E+03 3.5E-01 2.5E+00 8.0E+00
1.05E+04 5.8E-01 2.5E+00 8.0E+00 1000 100 1
2.87E+04 1.2E+00 2.5E+00 8.0E+00
4.73E+04 1.3E+00 2.5E+00 8.0E+00
8.01 E+04 7.6E-01 2.5E+00 8.0E+00
2.85E+01 9.9E-01 2.5E+00 8.0E+00
2.93E+01 1.1E+00 2.5E+00 8.0E+00
3.00E+01 1.6E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
.16E+04 89% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
.15E+04 87% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
.14E+04 90% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1012
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Internal
Sample Dilution Cone. Qualifier Review
ug/L
EaFA-L04-1316-T01-A 1 2.17E+03
EaFA-L04-1316-T02-A 1 3.86E+03
EaFA-L04-1316-T03-A 1 7.16E+03
EaFA-L04-1316-T04-A 1 7.43E+03
EaFA-L04-1316-T05-A 1 7.40E+03
EaFA-L04-1316-T01-B 1 2.04E+03
EaFA-L04-1316-T02-B 1 3.89E+03
EaFA-L04-1316-T03-B 1 7.74E+03
EaFA-L04-1316-T04-B 1 8.59E+03
EaFA-L04-1316-T05-B 1 7.67E+03
EaFA-L04-1316-T01-C 1 2.07E+03
EaFA-L04-1316-T02-C 1 3.85E+03
EaFA-L04-1316-T03-C 1 8.51E+03
EaFA-L04-1316-T04-C 1 8.98E+03
EaFA-L04-1316-T05-C 1 8.26E+03
EaFA-L04-1316-B01-A 1 5.00E-01 U1/2
EaFA-L04-1316-B02-A 1 5.00E-01 U1/2
EaFA-L04-1316-B03-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.17E+03 3.7E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
3.86E+03 6.1E-01 1.0E+00 3.2E+00 1000 100 4.67E+03 81% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
7.16E+03 1.3E+00 1.0E+00 3.2E+00
7.43E+03 1.8E+00 1.0E+00 3.2E+00
7.40E+03 6.8E-02 1.0E+00 3.2E+00
2.04E+03 4.7E-01 1.0E+00 3.2E+00
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
3.89E+03 9.9E-01 1.0E+00 3.2E+00 1000 100 4.81E+03 92% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
7.74E+03 1.7E+00 1.0E+00 3.2E+00
8.59E+03 8.3E-01 1.0E+00 3.2E+00
7.67E+03 1.2E+00 1.0E+00 3.2E+00
2.07E+03 7.8E-01 1.0E+00 3.2E+00
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
3.85E+03 4.4E-01 1.0E+00 3.2E+00 1000 100 4.68E+03 83% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
8.51 E+03 3.4E+00 1.0E+00 3.2E+00
8.98E+03 1.4E+00 1.0E+00 3.2E+00
8.26E+03 1.5E+00 1.0E+00 3.2E+00
5.00E-01 3.9E+02 1.0E+00 3.2E+00
5.00E-01 1.2E+01 1.0E+00 3.2E+00
5.00E-01 3.7E+01 1.0E+00 3.2E+00
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1013
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
S Sample Dilution Cone. Qualifier Review
1 ug/L
S EaFA-L04-1316-T01-A 1 2.66E+06
S EaFA-L04-1316-T02-A 1 2.69E+06
S EaFA-L04-1316-T03-A 1 2.83E+06
S EaFA-L04-1316-T04-A 1 2.84E+06
S EaFA-L04-1316-T05-A 1 2.74E+06
S EaFA-L04-1316-T01-B 1 2.59E+06
S EaFA-L04-1316-T02-B 1 2.60E+06
S EaFA-L04-1316-T03-B 1 2.65E+06
S EaFA-L04-1316-T04-B 1 2.72E+06
S EaFA-L04-1316-T05-B 1 2.94E+06
S EaFA-L04-1316-T01-C 1 2.53E+06
S EaFA-L04-1316-T02-C 1 2.58E+06
S EaFA-L04-1316-T03-C 1 2.85E+06
S EaFA-L04-1316-T04-C 1 2.97E+06
S EaFA-L04-1316-T05-C 1 2.89E+06
S EaFA-L04-1316-B01-A 1 2.83E+01
S EaFA-L04-1316-B02-A 1 1 .06E+01 E
S EaFA-L04-1316-B03-A 1 1 .27E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.66E+06 9.1E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
2.69E+06 6.9E-01 6.8E+00 2.2E+01 1000 500 2.70E+06 82% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
2.83E+06 2.0E-01 6.8E+00 2.2E+01
2.84E+06 1.2E+00 6.8E+00 2.2E+01
2.74E+06 2.3E+00 6.8E+00 2.2E+01
2.59E+06 5.9E-01 6.8E+00 2.2E+01
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
2.60E+06 1.1E+00 6.8E+00 2.2E+01 1000 500 2.60E+06 88% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
2.65E+06 4.8E+00 6.8E+00 2.2E+01
2.72E+06 1.1E+00 6.8E+00 2.2E+01
2.94E+06 1.4E+00 6.8E+00 2.2E+01
2.53E+06 3.8E-01 6.8E+00 2.2E+01
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
2.58E+06 1.1E+00 6.8E+00 2.2E+01 1000 500 2.59E+06 85% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
2.85E+06 1.1E+00 6.8E+00 2.2E+01
2.97E+06 1.7E+00 6.8E+00 2.2E+01
2.89E+06 1.4E+00 6.8E+00 2.2E+01
2.83E+01 5.3E-01 6.8E+00 2.2E+01
1.06E+01 9.4E-01 6.8E+00 2.2E+01
1.27E+01 5.3E-01 6.8E+00 2.2E+01
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VUICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1014
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample Internal
Dilution Cone. Qualifier Review
I I ug/L
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.73E+01
1 3.50E+01
1 5.58E+01
1 2.30E+00 U1/2
1 1.00E+01 E
1 2.21E+01
1 4.22E+01
1 4.30E+01
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+01
1 3.25E+01
1 5.37E+01
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
ICP-OES
Cone. RSD
ug/L %
2.30E+00 3.8E+01
2.30E+00 9.8E+02
2.73E+01 5.2E+01
3.50E+01 4.0E+01
5.58E+01 2.1E+01
2.30E+00 8.5E+01
1 .OOE+01 1 .6E+02
2.21E+01 5.1E+01
4.22E+01 7.9E+00
4.30E+01 4.8E+01
2.30E+00 3.8E+02
2.30E+00 1.7E+02
2.30E+01 1.8E+01
3.25E+01 9.4E+01
5.37E+01 1.3E+01
2.30E+00 1.1E+02
2.30E+00 2.5E+02
2.30E+00 6.5E+02
MDL
ug/L
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
4.6E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
1.5E+01
1.5E+01 10 325
1.5E+01
1.5E+01
1.5E+01
1.5E+01
1.5E+01 10 325
1.5E+01
1.5E+01
1.5E+01
1.5E+01
1.5E+01 10 325
1.5E+01
1.5E+01
1.5E+01
1.5E+01
1.5E+01
1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.37E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.52E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.38E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1015
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Sample
EaFA-L04-1316-T01-A
EaFA-L04-1316-T02-A
EaFA-L04-1316-T03-A
EaFA-L04-1316-T04-A
EaFA-L04-1316-T05-A
EaFA-L04-1316-T01-B
EaFA-L04-1316-T02-B
EaFA-L04-1316-T03-B
EaFA-L04-1316-T04-B
EaFA-L04-1316-T05-B
EaFA-L04-1316-T01-C
EaFA-L04-1316-T02-C
EaFA-L04-1316-T03-C
EaFA-L04-1316-T04-C
EaFA-L04-1316-T05-C
EaFA-L04-1316-B01-A
EaFA-L04-1316-B02-A
EaFA-L04-1316-B03-A
Sample
Dilution Cone.
I I ug/L
1 1 .OOE+OO
1 1 .OOE+OO
1 1 .OOE+OO
1 2.84E+01
1 2.07E+01
1 1 .OOE+OO
1 1.02E+01
1 1 .OOE+OO
1 1 .OOE+OO
1 7.28E+00
1 1 .OOE+OO
1 1 .OOE+OO
1 1 .OOE+OO
1 2.61 E+00
1 8.61E+01
1 1. OOE+OO
1 1. OOE+OO
1 1. OOE+OO
Internal
Qualifier Review
U1/2
U1/2
U1/2


U1/2

U1/2
U1/2

U1/2
U1/2
U1/2
E

U1/2
U1/2
U1/2
ICP-OES
Cone. RSD
ug/L %
1 .OOE+OO 1 .4E+02
1. OOE+OO 2.7E+02
1. OOE+OO 3.1E+02
2.84E+01 4.1E+00
2.07E+01 4.2E+00
1. OOE+OO 2.2E+02
1.02E+01 1.5E+01
1. OOE+OO 7.8E+01
1 .OOE+OO 1 .6E+02
7.28E+00 1.4E+01
1. OOE+OO 9.7E+01
1. OOE+OO 2.7E+02
1. OOE+OO 1.6E+02
2.61 E+00 5.0E+01
8.61 E+01 2.0E+00
1. OOE+OO 2.7E+01
1. OOE+OO 1.0E+03
1. OOE+OO 2.6E+02
MDL
ug/L
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
2.0E+00
Spike Sol'n
ML Cone. Volume
ug/L ug/L uL
6.4E+00
6.4E+00 10 325
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00 10 325
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00 10 325
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00
6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU
3.14E+03 96% VU
VU
VU
VU
VU
3.25E+03 100% VU
VU
VU
VU
VU
3.10E+03 95% VU
VU
VU
VU
VU
VU
VU
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
ICP-OES
Date/Time
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
6/24/10
Filename
12:13PMEPAInterlabL04
12:1 4PM EPA Interlab L04
12:16PMEPAInterlabL04
12:1 8PM EPA Interlab L04
12:19PMEPAInterlabL04
12:21 PMEPAInterlabL04
12:23PMEPAInterlabL04
12:24PMEPAInterlabL04
12:26PMEPAInterlabL04
12:28PMEPAInterlabL04
12:29PMEPAInterlabL04
12:31 PM EPA Interlab L04
12:32 PM EPA Interlab L04
12:34 PM EPA Interlab L04
12:36 PM EPA Interlab L04
12:08 PM EPA Interlab L04
12:09 PM EPA Interlab L04
6/24/10 12:11 PM EPA Interlab L04

1313-1316 EaFA
1313-1316EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
131 3-1 31 6 EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
1313-1316 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
131 3-1 31 6 EaFA
                                                                                                                                                                         1-1016
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
V Sample Dilution Cone. Qualifier Review
1 ug/L
V EaFA-L04-1316-T01-A 1 2.58E+02
V EaFA-L04-1316-T02-A 1 2.94E+02
V EaFA-L04-1316-T03-A 1 3.28E+02
V EaFA-L04-1316-T04-A 1 3.65E+02
V EaFA-L04-1316-T05-A 1 3.75E+02
V EaFA-L04-1316-T01-B 1 2.58E+02
V EaFA-L04-1316-T02-B 1 2.96E+02
V EaFA-L04-1316-T03-B 1 3.35E+02
V EaFA-L04-1316-T04-B 1 3.66E+02
V EaFA-L04-1316-T05-B 1 3.86E+02
V EaFA-L04-1316-T01-C 1 2.68E+02
V EaFA-L04-1316-T02-C 1 3.19E+02
V EaFA-L04-1316-T03-C 1 3.62E+02
V EaFA-L04-1316-T04-C 1 4.18E+02
V EaFA-L04-1316-T05-C 1 4.56E+02
V EaFA-L04-1316-B01-A 1 7.75E+00
V EaFA-L04-1316-B02-A 1 8.44E+00
V EaFA-L04-1316-B03-A 1 8.95E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.58E+02 3.0E+00 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
2.94E+02 8.2E-01 1.5E+00 4.8E+00 10 325 3.78E+03 107% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
3.28E+02 3.4E-01 1.5E+00 4.8E+00
3.65E+02 1.0E+00 1.5E+00 4.8E+00
3.75E+02 3.3E-01 1.5E+00 4.8E+00
2.58E+02 2.7E+00 1.5E+00 4.8E+00
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
2.96E+02 8.1E-01 1.5E+00 4.8E+00 10 325 3.93E+03 112% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
3.35E+02 3.9E+00 1.5E+00 4.8E+00
3.66E+02 1.7E+00 1.5E+00 4.8E+00
3.86E+02 1.7E+00 1.5E+00 4.8E+00
2.68E+02 2.6E+00 1.5E+00 4.8E+00
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
3.19E+02 8.9E-01 1.5E+00 4.8E+00 10 325 3.79E+03 107% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
3.62E+02 1.6E+00 1.5E+00 4.8E+00
4.18E+02 1.4E+00 1.5E+00 4.8E+00
4.56E+02 1.6E+00 1.5E+00 4.8E+00
7.75E+00 3.5E+01 1 .5E+00 4.8E+00
8.44E+00 5.8E+01 1 .5E+00 4.8E+00
8.95E+00 9.4E+01 1 .5E+00 4.8E+00
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1017
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Zn Sample Dilution Cone. Qualifier Review
1 ug/L
Zn EaFA-L04-1316-T01-A 1 9.02E+00
Zn EaFA-L04-1316-T02-A 1 2.46E+01
Zn EaFA-L04-1316-T03-A 1 3.06E+01
Zn EaFA-L04-1316-T04-A 1 3.01E+01
Zn EaFA-L04-1316-T05-A 1 1 .06E+02
Zn EaFA-L04-1316-T01-B 1 1.21E+01
Zn EaFA-L04-1316-T02-B 1 1 J7E+01
Zn EaFA-L04-1316-T03-B 1 2.42E+01
Zn EaFA-L04-1316-T04-B 1 1 .89E+01
Zn EaFA-L04-1316-T05-B 1 8.05E+01
Zn EaFA-L04-1316-T01-C 1 1 .40E+01
Zn EaFA-L04-1316-T02-C 1 1 .96E+01
Zn EaFA-L04-1316-T03-C 1 3.49E+01
Zn EaFA-L04-1316-T04-C 1 2.18E+01
Zn EaFA-L04-1316-T05-C 1 2.00E+02
Zn EaFA-L04-1316-B01-A 1 1 .26E+01
Zn EaFA-L04-1316-B02-A 1 1.29E+01
Zn EaFA-L04-1316-B03-A 1 1.12E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.02E+00 1.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/24/10 12:13 PM EPA Interlab L04 1313-1316 EaFA
2.46E+01 3.4E+00 1.0E+00 3.2E+00 10 325 3.61E+03 110% VU ICP-OES 6/24/10 12:14 PM EPA Interlab L04 1313-1316 EaFA
3.06E+01 1.3E+00 1.0E+00 3.2E+00
3.01 E+01 4.8E+00 1.0E+00 3.2E+00
1.06E+02 1.3E+00 1.0E+00 3.2E+00
1.21 E+01 6.1E+00 1.0E+00 3.2E+00
VU ICP-OES 6/24/10 12:16 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:18 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:19 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:21 PM EPA Interlab L04 1313-1316 EaFA
1.77E+01 1.1E+01 1.0E+00 3.2E+00 10 325 3.74E+03 115% VU ICP-OES 6/24/10 12:23 PM EPA Interlab L04 1313-1316 EaFA
2.42E+01 6.7E+00 1.0E+00 3.2E+00
1.89E+01 4.0E+00 1.0E+00 3.2E+00
8.05E+01 2.8E+00 1.0E+00 3.2E+00
1.40E+01 6.0E+00 1.0E+00 3.2E+00
VU ICP-OES 6/24/10 12:24 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:26 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:28 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:29 PM EPA Interlab L04 1313-1316 EaFA
1.96E+01 2.9E+00 1.0E+00 3.2E+00 10 325 3.60E+03 110% VU ICP-OES 6/24/10 12:31 PM EPA Interlab L04 1313-1316 EaFA
3.49E+01 5.3E+00 1.0E+00 3.2E+00
2.18E+01 5.4E+00 1 .OE+00 3.2E+00
2.00E+02 5.1E-01 1 .OE+00 3.2E+00
1.26E+01 4.4E+01 1 .OE+00 3.2E+00
1.29E+01 1.5E+02 1 .OE+00 3.2E+00
1.12E+01 1.1E+02 1.0E+00 3.2E+00
VU ICP-OES 6/24/10 12:32 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:34 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:36 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:08 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:09 PM EPA Interlab L04 1313-1316 EaFA
VU ICP-OES 6/24/10 12:11 PM EPA Interlab L04 1313-1316 EaFA
                                                                                                                                                                         1-1018
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al EaFA-L05-1316-T01-A 1 1.51E+03
Al EaFA-L05-1316-T02-A 1 9.62E+02
Al EaFA-L05-1316-T03-A 1 3.14E+02
Al EaFA-L05-1316-T04-A 1 2.09E+02
Al EaFA-L05-1316-T05-A
Al EaFA-L05-1316-T01-B 1 5.73E+02
Al EaFA-L05-1316-T02-B 1 3.28E+03
Al EaFA-L05-1316-T03-B 1 1.55E+02
Al EaFA-L05-1316-T04-B 1 1.97E+02
Al EaFA-L05-1316-T05-B
Al EaFA-L05-1316-T01-C 1 4.62E+03
Al EaFA-L05-1316-T02-C 1 1.40E+02
Al EaFA-L05-1316-T03-C 1 1.48E+02
Al EaFA-L05-1316-T04-C 1 2.26E+02
Al EaFA-L05-1316-T05-C
Al EaFA-L05-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.51E+03 9.29E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
9.62E+02 6.74E-01 1 .OE+00 3.2E+00 1000 100 1 .90E+03 93% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
3.14E+02 8.52E-01 1 .OE+00 3.2E+00
2.09E+02 1.83E+00 1 .OE+00 3.2E+00

5.73E+02 3.17E+00 1 .OE+00 3.2E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
3.28E+03 2.01E+00 1 .OE+00 3.2E+00 1000 100 4.18E+03 90% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
1.55E+02 4.15E-01 1 .OE+00 3.2E+00
1.97E+02 2.45E+00 1 .OE+00 3.2E+00

4.62E+03 7.04E-01 1 .OE+00 3.2E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
1.40E+02 1.64E+00 1 .OE+00 3.2E+00 1000 100 1.21E+03 107% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
1.48E+02 8.12E-01 1 .OE+00 3.2E+00
2.26E+02 1.03E+00 1 .OE+00 3.2E+00

5.00E-01 2.65E+02 1 .OE+00 3.2E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                                 1-1019
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb EaFA-L05-1316-T01-A 1 3.75E+01
Sb EaFA-L05-1316-T02-A 1 7.73E+01
Sb EaFA-L05-1316-T03-A 1 1.53E+02
Sb EaFA-L05-1316-T04-A 1 3.17E+02
Sb EaFA-L05-1316-T05-A
Sb EaFA-L05-1316-T01-B 1 7.86E+01
Sb EaFA-L05-1316-T02-B 1 4.22E+01
Sb EaFA-L05-1316-T03-B 1 2.53E+02
Sb EaFA-L05-1316-T04-B 1 3.06E+02
Sb EaFA-L05-1316-T05-B
Sb EaFA-L05-1316-T01-C 1 3.97E+01
Sb EaFA-L05-1316-T02-C 1 6.11E+01
Sb EaFA-L05-1316-T03-C 1 2.40E+02
Sb EaFA-L05-1316-T04-C 1 1.98E+02
Sb EaFA-L05-1316-T05-C
Sb EaFA-L05-1316-B01-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+01 5.01 E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
7.73E+01 7.12E+00 7.5E+00 2.4E+01 10 300 3.37E+03 1 10% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
1.53E+02 7.80E+00 7.5E+00 2.4E+01
3.17E+02 2.02E+00 7.5E+00 2.4E+01

7.86E+01 1.09E+01 7.5E+00 2.4E+01
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
4.22E+01 8.16E+00 7.5E+00 2.4E+01 10 300 3.12E+03 102% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
2.53E+02 6.47E+00 7.5E+00 2.4E+01
3.06E+02 7.19E-01 7.5E+00 2.4E+01

3.97E+01 1.53E+01 7.5E+00 2.4E+01
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
6.11E+01 3.23E+00 7.5E+00 2.4E+01 10 300 3.54E+03 1 16% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
2.40E+02 4.75E+00 7.5E+00 2.4E+01
1.98E+02 2.52E+00 7.5E+00 2.4E+01

3.75E+00 8.29E+01 7.5E+00 2.4E+01
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1020
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
ug/L
As EaFA-L05-1316-T01-A 1 2.23E+01 E
As EaFA-L05-1316-T02-A 1 2.56E+01 E
As EaFA-L05-1316-T03-A 1 2.73E+01 E
As EaFA-L05-1316-T04-A 1 2.36E+01 E
As EaFA-L05-1316-T05-A
As EaFA-L05-1316-T01-B 1 1.83E+01 E
As EaFA-L05-1316-T02-B 1 1.92E+01 E
As EaFA-L05-1316-T03-B 1 3.69E+01
As EaFA-L05-1316-T04-B 1 4.60E+01
As EaFA-L05-1316-T05-B
As EaFA-L05-1316-T01-C 1 1.88E+01 E
As EaFA-L05-1316-T02-C 1 3.75E+01
As EaFA-L05-1316-T03-C 1 3.61 E+01
As EaFA-L05-1316-T04-C 1 4.39E+01
As EaFA-L05-1316-T05-C
As EaFA-L05-1316-B01-A 1 5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.23E+01 2.42E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
2.56E+01 1.96E+01 1.1E+01 3.5E+01 10 300 3.25E+03 107% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
2.73E+01 7.34E+00 1.1E+01 3.5E+01
2.36E+01 2.22E+01 1.1E+01 3.5E+01

1.83E+01 1.10E+01 1.1E+01 3.5E+01
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
1.92E+01 1.88E+01 1.1E+01 3.5E+01 10 300 3.06E+03 101% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
3.69E+01 2.39E+01 1.1 E+01 3.5E+01
4.60E+01 3.39E+00 1.1 E+01 3.5E+01

1.88E+01 2.32E+01 1.1 E+01 3.5E+01
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
3.75E+01 2.24E+01 1.1E+01 3.5E+01 10 300 3.43E+03 1 13% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
3.61 E+01 8.72E+00 1.1 E+01 3.5E+01
4.39E+01 1.06E+01 1.1 E+01 3.5E+01

5.50E+00 4.48E+01 1.1 E+01 3.5E+01
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1021
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B EaFA-L05-1316-T01-A 1 3.39E+03
B EaFA-L05-1316-T02-A 1 6.96E+03
B EaFA-L05-1316-T03-A 1 1.86E+04
B EaFA-L05-1316-T04-A 1 3.44E+04
B EaFA-L05-1316-T05-A
B EaFA-L05-1316-T01-B 1 4.47E+03
B EaFA-L05-1316-T02-B 1 6.41 E+03
B EaFA-L05-1316-T03-B 1 1.95E+04
B EaFA-L05-1316-T04-B 1 3.45E+04
B EaFA-L05-1316-T05-B
B EaFA-L05-1316-T01-C 1 4.10E+03
B EaFA-L05-1316-T02-C 1 7.05E+03
B EaFA-L05-1316-T03-C 1 1.99E+04
B EaFA-L05-1316-T04-C 1 3.37E+04
B EaFA-L05-1316-T05-C
B EaFA-L05-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.39E+03 5.81 E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
6.96E+03 1.28E+00 1 .OE+00 3.2E+00 1000 100 8.04E+03 108% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
1.86E+04 8.50E-01 1 .OE+00 3.2E+00
3.44E+04 5.50E-01 1 .OE+00 3.2E+00

4.47E+03 4.73E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
6.41E+03 1.96E+00 1.0E+00 3.2E+00 1000 100 7.28E+03 87% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
1.95E+04 3.49E-01 1. OE+00 3.2E+00
3.45E+04 8.57E-01 1. OE+00 3.2E+00

4.10E+03 2.36E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
7.05E+03 1.73E+00 1.0E+00 3.2E+00 1000 100 8.03E+03 98% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
1.99E+04 5.15E-01 1. OE+00 3.2E+00
3.37E+04 1.07E+00 1. OE+00 3.2E+00

5.00E-01 1.16E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1022
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba EaFA-L05-1316-T01-A 1 5.60E+02
Ba EaFA-L05-1316-T02-A 1 5.85E+02
Ba EaFA-L05-1316-T03-A 1 1.95E+02
Ba EaFA-L05-1316-T04-A 1 2.28E+02
Ba EaFA-L05-1316-T05-A
Ba EaFA-L05-1316-T01-B 1 5.00E+02
Ba EaFA-L05-1316-T02-B 1 3.91 E+02
Ba EaFA-L05-1316-T03-B 1 2.04E+02
Ba EaFA-L05-1316-T04-B 1 2.20E+02
Ba EaFA-L05-1316-T05-B
Ba EaFA-L05-1316-T01-C 1 4.48E+02
Ba EaFA-L05-1316-T02-C 1 5.01 E+02
Ba EaFA-L05-1316-T03-C 1 2.07E+02
Ba EaFA-L05-1316-T04-C 1 2.54E+02
Ba EaFA-L05-1316-T05-C
Ba EaFA-L05-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.60E+02 1.39E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
5.85E+02 1.20E+00 1 .OE+00 3.2E+00 10 300 3.47E+03 96% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
1.95E+02 2.16E-01 1 .OE+00 3.2E+00
2.28E+02 1.19E-01 1 .OE+00 3.2E+00

5.00E+02 1.96E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
3.91E+02 5.66E-01 1.0E+00 3.2E+00 10 300 3.14E+03 92% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
2.04E+02 1.31E-01 1. OE+00 3.2E+00
2.20E+02 1.35E+00 1. OE+00 3.2E+00

4.48E+02 3.29E-01 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
5.01E+02 5.79E-01 1.0E+00 3.2E+00 10 300 3.52E+03 101% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
2.07E+02 3.68E-01 1. OE+00 3.2E+00
2.54E+02 1.23E+00 1. OE+00 3.2E+00

5.00E-01 7.67E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1023
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Be Sample Dilution Cone. Qualifier
ug/L
Be EaFA-L05-1316-T01-A 1 1.32E+01
Be EaFA-L05-1316-T02-A 1 9.30E+00
Be EaFA-L05-1316-T03-A 1 3.95E+00 E
Be EaFA-L05-1316-T04-A 1 9.50E-01 U1/2
Be EaFA-L05-1316-T05-A
Be EaFA-L05-1316-T01-B 1 5.97E+00 E
Be EaFA-L05-1316-T02-B 1 2.49E+01
Be EaFA-L05-1316-T03-B 1 9.50E-01 U1/2
Be EaFA-L05-1316-T04-B 1 9.50E-01 U1/2
Be EaFA-L05-1316-T05-B
Be EaFA-L05-1316-T01-C 1 2.90E+01
Be EaFA-L05-1316-T02-C 1 1.93E+OOE
Be EaFA-L05-1316-T03-C 1 9.50E-01 U1/2
Be EaFA-L05-1316-T04-C 1 3.09E+00 E
Be EaFA-L05-1316-T05-C
Be EaFA-L05-1316-B01-A 1 9.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.32E+01 2.02E+02 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
9.30E+00 1.24E+02 1 .9E+00 6.0E+00 10 300 3.30E+03 1 10% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
3.95E+00 2.75E+01 1 .9E+00 6.0E+00
9.50E-01 5.50E+02 1 .9E+00 6.0E+00

5.97E+00 2.99E+01 1 .9E+00 6.0E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
2.49E+01 3.08E+01 1.9E+00 6.0E+00 10 300 3.12E+03 103% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
9.50E-01 1.45E+02 1 .9E+00 6.0E+00
9.50E-01 1.25E+03 1 .9E+00 6.0E+00

2.90E+01 6.12E+02 1 .9E+00 6.0E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
1.93E+00 1.99E+02 1 .9E+00 6.0E+00 10 300 3.42E+03 1 14% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
9.50E-01 2.59E+02 1 .9E+00 6.0E+00
3.09E+00 9.88E+01 1 .9E+00 6.0E+00

9.50E-01 1.47E+02 1 .9E+00 6.0E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1024
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd EaFA-L05-1316-T01-A 1 1.77E+01
Cd EaFA-L05-1316-T02-A 1 2.80E+01
Cd EaFA-L05-1316-T03-A 1 9.61 E+01
Cd EaFA-L05-1316-T04-A 1 1.20E+01
Cd EaFA-L05-1316-T05-A
Cd EaFA-L05-1316-T01-B 1 1.11E+01
Cd EaFA-L05-1316-T02-B 1 3.17E+01
Cd EaFA-L05-1316-T03-B 1 1.31 E+01
Cd EaFA-L05-1316-T04-B 1 2.48E+01
Cd EaFA-L05-1316-T05-B
Cd EaFA-L05-1316-T01-C 1 2.31E+01
Cd EaFA-L05-1316-T02-C 1 9.52E+00
Cd EaFA-L05-1316-T03-C 1 1.68E+01
Cd EaFA-L05-1316-T04-C 1 1.09E+02
Cd EaFA-L05-1316-T05-C
Cd EaFA-L05-1316-B01-A 1 1.10E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+01 3.14E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
2.80E+01 1.75E+01 2.2E+00 7.0E+00 10 300 3.32E+03 110% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
9.61E+01 7.82E-01 2.2E+00 7.0E+00
1.20E+01 1.92E+01 2.2E+00 7.0E+00

1.11E+01 2.19E+01 2.2E+00 7.0E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
3.17E+01 9.41E+00 2.2E+00 7.0E+00 10 300 3.15E+03 104% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
1.31 E+01 1.05E+00 2.2E+00 7.0E+00
2.48E+01 8.55E+00 2.2E+00 7.0E+00

2.31E+01 2.99E+01 2.2E+00 7.0E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
9.52E+00 3.03E+01 2.2E+00 7.0E+00 10 300 3.45E+03 115% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
1.68E+01 3.70E+00 2.2E+00 7.0E+00
1.09E+02 2.15E+01 2.2E+00 7.0E+00

1.10E+00 1.38E+02 2.2E+00 7.0E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1025
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca EaFA-L05-1316-T01-A 1 1.09E+05
Ca EaFA-L05-1316-T02-A 1 2.50E+05
Ca EaFA-L05-1316-T03-A 1 6.45E+05
Ca EaFA-L05-1316-T04-A 1 5.69E+05
Ca EaFA-L05-1316-T05-A
Ca EaFA-L05-1316-T01-B 1 1.15E+05
Ca EaFA-L05-1316-T02-B 1 1.91E+05
Ca EaFA-L05-1316-T03-B 1 7.11E+05
Ca EaFA-L05-1316-T04-B 1 5.55E+05
Ca EaFA-L05-1316-T05-B
Ca EaFA-L05-1316-T01-C 1 1.16E+05
Ca EaFA-L05-1316-T02-C 1 2.12E+05
Ca EaFA-L05-1316-T03-C 1 7.16E+05
Ca EaFA-L05-1316-T04-C 1 5.13E+05
Ca EaFA-L05-1316-T05-C
Ca EaFA-L05-1316-B01-A 1 2.87E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.09E+05 1.43E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
2.50E+05 1.22E+00 2.6E+00 8.3E+00 1000 100 2.51E+05 83% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
6.45E+05 4.12E-01 2.6E+00 8.3E+00
5.69E+05 2.73E-01 2.6E+00 8.3E+00

1.15E+05 1.87E+00 2.6E+00 8.3E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
1.91E+05 6.14E-01 2.6E+00 8.3E+00 1000 100 1.92E+05 90% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
7.11E+05 7.37E-01 2.6E+00 8.3E+00
5.55E+05 1.27E+00 2.6E+00 8.3E+00

1.16E+05 6.15E-01 2.6E+00 8.3E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
2.12E+05 4.62E-01 2.6E+00 8.3E+00 1000 100 2.13E+05 87% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
7.16E+05 4.71E-01 2.6E+00 8.3E+00
5.13E+05 1.70E+00 2.6E+00 8.3E+00

2.87E+01 9.15E+01 2.6E+00 8.3E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1026
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qualifier
ug/L
Cr EaFA-L05-1316-T01-A 1 8.68E+00
Cr EaFA-L05-1316-T02-A 1 1.35E+01
Cr EaFA-L05-1316-T03-A 1 5.80E+00
Cr EaFA-L05-1316-T04-A 1 3.85E+01
Cr EaFA-L05-1316-T05-A
Cr EaFA-L05-1316-T01-B 1 1.10E+01
Cr EaFA-L05-1316-T02-B 1 7.96E+00
Cr EaFA-L05-1316-T03-B 1 2.56E+01
Cr EaFA-L05-1316-T04-B 1 2.05E+01
Cr EaFA-L05-1316-T05-B
Cr EaFA-L05-1316-T01-C 1 1.14E+01
Cr EaFA-L05-1316-T02-C 1 1.59E+01
Cr EaFA-L05-1316-T03-C 1 2.30E+01
Cr EaFA-L05-1316-T04-C 1 9.96E+00
Cr EaFA-L05-1316-T05-C
Cr EaFA-L05-1316-B01-A 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.68E+00 1.49E+01 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
1.35E+01 1.02E+01 1.2E+00 3.8E+00 10 300 3.18E+03 106% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
5.80E+00 5.18E+00 1.2E+00 3.8E+00
3.85E+01 3.62E+00 1.2E+00 3.8E+00

1.10E+01 9.45E+00 1.2E+00 3.8E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
7.96E+00 5.43E+00 1.2E+00 3.8E+00 10 300 3.01E+03 100% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
2.56E+01 1.04E+01 1.2E+00 3.8E+00
2.05E+01 4.82E+00 1.2E+00 3.8E+00

1.14E+01 2.94E+00 1.2E+00 3.8E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
1.59E+01 5.63E+00 1.2E+00 3.8E+00 10 300 3.30E+03 109% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
2.30E+01 1.06E+01 1.2E+00 3.8E+00
9.96E+00 3.14E+00 1.2E+00 3.8E+00

6.00E-01 1.69E+02 1.2E+00 3.8E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1027
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co EaFA-L05-1316-T01-A 1 1.39E+02
Co EaFA-L05-1316-T02-A 1 2.70E+02
Co EaFA-L05-1316-T03-A 1 9.51 E+02
Co EaFA-L05-1316-T04-A 1 4.80E+02
Co EaFA-L05-1316-T05-A
Co EaFA-L05-1316-T01-B 1 1.09E+02
Co EaFA-L05-1316-T02-B 1 2.37E+02
Co EaFA-L05-1316-T03-B 1 4.07E+02
Co EaFA-L05-1316-T04-B 1 7.11E+02
Co EaFA-L05-1316-T05-B
Co EaFA-L05-1316-T01-C 1 1.53E+02
Co EaFA-L05-1316-T02-C 1 1.75E+02
Co EaFA-L05-1316-T03-C 1 4.50E+02
Co EaFA-L05-1316-T04-C 1 1.48E+03
Co EaFA-L05-1316-T05-C
Co EaFA-L05-1316-B01-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.39E+02 7.87E+00 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
2.70E+02 4.41E+00 1 .8E+00 5.7E+00 10 300 3.41E+03 105% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
9.51 E+02 9.95E-01 1 .8E+00 5.7E+00
4.80E+02 7.82E-01 1 .8E+00 5.7E+00

1.09E+02 4.95E+00 1 .8E+00 5.7E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
2.37E+02 3.23E+00 1 .8E+00 5.7E+00 10 300 3.23E+03 100% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
4.07E+02 1.71E+00 1 .8E+00 5.7E+00
7. 11 E+02 1.96E+00 1 .8E+00 5.7E+00

1.53E+02 8.44E-01 1 .8E+00 5.7E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
1.75E+02 2.52E+00 1 .8E+00 5.7E+00 10 300 3.47E+03 110% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
4.50E+02 1.31E+00 1 .8E+00 5.7E+00
1.48E+03 1.60E+00 1 .8E+00 5.7E+00

9.00E-01 1.22E+02 1.8E+00 5.7E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1028
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu EaFA-L05-1316-T01-A 1 3.21E+02
Cu EaFA-L05-1316-T02-A 1 1.27E+02
Cu EaFA-L05-1316-T03-A 1 9.50E+01
Cu EaFA-L05-1316-T04-A 1 1.18E+01 E
Cu EaFA-L05-1316-T05-A
Cu EaFA-L05-1316-T01-B 1 8.74E+01
Cu EaFA-L05-1316-T02-B 1 5.82E+02
Cu EaFA-L05-1316-T03-B 1 1.71E+01
Cu EaFA-L05-1316-T04-B 1 1.09E+01 E
Cu EaFA-L05-1316-T05-B
Cu EaFA-L05-1316-T01-C 1 7.92E+02
Cu EaFA-L05-1316-T02-C 1 2.04E+01
Cu EaFA-L05-1316-T03-C 1 1.47E+01
Cu EaFA-L05-1316-T04-C 1 6.06E+01
Cu EaFA-L05-1316-T05-C
Cu EaFA-L05-1316-B01-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.21 E+02 2.48E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
1.27E+02 1.03E+01 3.7E+00 1.2E+01 10 300 3.32E+03 107% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
9.50E+01 4.00E+01 3.7E+00 1.2E+01
1.18E+01 3.45E+01 3.7E+00 1.2E+01

8.74E+01 1.35E+01 3.7E+00 1.2E+01
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
5.82E+02 2.49E+01 3.7E+00 1.2E+01 10 300 3.57E+03 99% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
1.71E+01 3.66E+01 3.7E+00 1.2E+01
1.09E+01 3.61 E+01 3.7E+00 1.2E+01

7.92E+02 3.54E+01 3.7E+00 1.2E+01
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
2.04E+01 1.44E+01 3.7E+00 1.2E+01 10 300 3.36E+03 11 1% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
1.47E+01 3.07E+01 3.7E+00 1.2E+01
6.06E+01 4.14E+01 3.7E+00 1.2E+01

1.85E+00 2.00E+02 3.7E+00 1.2E+01
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1029
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. Qualifier
ug/L
Fe EaFA-L05-1316-T01-A 1 1.00E+OOU1/2
Fe EaFA-L05-1316-T02-A 1 1.00E+OOU1/2
Fe EaFA-L05-1316-T03-A 1 1.00E+OOU1/2
Fe EaFA-L05-1316-T04-A 1 1.00E+OOU1/2
Fe EaFA-L05-1316-T05-A
Fe EaFA-L05-1316-T01-B 1 1.00E+OOU1/2
Fe EaFA-L05-1316-T02-B 1 5.40E+00 E
Fe EaFA-L05-1316-T03-B 1 1.00E+OOU1/2
Fe EaFA-L05-1316-T04-B 1 6.82E+00
Fe EaFA-L05-1316-T05-B
Fe EaFA-L05-1316-T01-C 1 1.30E+01
Fe EaFA-L05-1316-T02-C 1 1.00E+OOU1/2
Fe EaFA-L05-1316-T03-C 1 1.00E+OOU1/2
Fe EaFA-L05-1316-T04-C 1 1.00E+OOU1/2
Fe EaFA-L05-1316-T05-C
Fe EaFA-L05-1316-B01-A 1 1.00E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.99E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 1.35E+02 2.0E+00 6.4E+00 1000 100 9.78E+02 98% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 1.07E+02 2.0E+00 6.4E+00
1.00E+00 2.25E+00 2.0E+00 6.4E+00

1.00E+00 9.86E+01 2.0E+00 6.4E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
5.40E+00 1.12E+03 2.0E+00 6.4E+00 1000 100 9.25E+02 92% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 5.02E+01 2.0E+00 6.4E+00
6.82E+00 5.14E+01 2.0E+00 6.4E+00

1.30E+01 2.46E+02 2.0E+00 6.4E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 8.86E+01 2.0E+00 6.4E+00 1000 100 1.02E+03 102% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 2.20E+01 2.0E+00 6.4E+00
1.00E+00 3.54E+01 2.0E+00 6.4E+00

1.00E+00 1.09E+03 2.0E+00 6.4E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1030
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Pb Sample Dilution Cone. Qualifier Revi
ug/L
Pb EaFA-L05-1316-T01-A 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T02-A 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T03-A 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T04-A 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T05-A
Pb EaFA-L05-1316-T01-B 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T02-B 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T03-B 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T04-B 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T05-B
Pb EaFA-L05-1316-T01-C 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T02-C 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T03-C 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T04-C 1 3.40E+00 U1/2
Pb EaFA-L05-1316-T05-C
Pb EaFA-L05-1316-B01-A 1 3.40E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 9.16E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 5.04E+01 6.8E+00 2.2E+01 10 300 3.17E+03 106% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 1.31E+02 6.8E+00 2.2E+01
3.40E+00 4.69E+01 6.8E+00 2.2E+01

3.40E+00 2.80E+01 6.8E+00 2.2E+01
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 3.57E+01 6.8E+00 2.2E+01 10 300 2.97E+03 99% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 2.16E+01 6.8E+00 2.2E+01
3.40E+00 7.11E+01 6.8E+00 2.2E+01

3.40E+00 3.14E+01 6.8E+00 2.2E+01
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1 :22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1 :23 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 8.98E+01 6.8E+00 2.2E+01 10 300 3.29E+03 110% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 7.75E+01 6.8E+00 2.2E+01
3.40E+00 3.00E+01 6.8E+00 2.2E+01

3.40E+00 5.97E+01 6.8E+00 2.2E+01
VU ICP-OES 7/29/10 1 :27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1 :28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1 :05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1031
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li EaFA-L05-1316-T01-A 1 2.69E+03
Li EaFA-L05-1316-T02-A 1 5.28E+03
Li EaFA-L05-1316-T03-A 1 1.35E+04
Li EaFA-L05-1316-T04-A 1 2.80E+04
Li EaFA-L05-1316-T05-A
Li EaFA-L05-1316-T01-B 1 2.71E+03
Li EaFA-L05-1316-T02-B 1 4.69E+03
Li EaFA-L05-1316-T03-B 1 1.38E+04
Li EaFA-L05-1316-T04-B 1 2.70E+04
Li EaFA-L05-1316-T05-B
Li EaFA-L05-1316-T01-C 1 2.58E+03
Li EaFA-L05-1316-T02-C 1 4.93E+03
Li EaFA-L05-1316-T03-C 1 1.37E+04
Li EaFA-L05-1316-T04-C 1 2.65E+04
Li EaFA-L05-1316-T05-C
Li EaFA-L05-1316-B01-A 1 2.21E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.69E+03 1.64E+00 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
5.28E+03 6.64E-01 1 .9E+00 6.0E+00 10 300 7.94E+03 89% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
1.35E+04 6.17E-01 1 .9E+00 6.0E+00
2.80E+04 4.86E-01 1 .9E+00 6.0E+00

2.71E+03 2.26E+00 1 .9E+00 6.0E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
4.69E+03 7.06E-01 1 .9E+00 6.0E+00 10 300 7.25E+03 85% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
1.38E+04 5.33E-01 1 .9E+00 6.0E+00
2.70E+04 1.12E+00 1 .9E+00 6.0E+00

2.58E+03 4.86E-02 1 .9E+00 6.0E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
4.93E+03 6.07E-01 1 .9E+00 6.0E+00 10 300 7.66E+03 91%VUICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
1.37E+04 6.98E-01 1 .9E+00 6.0E+00
2.65E+04 1.47E+00 1 .9E+00 6.0E+00

2.21E+01 2.59E+01 1 .9E+00 6.0E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1032
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn EaFA-L05-1316-T01-A 1 3.61E+02
Mn EaFA-L05-1316-T02-A 1 7.48E+02
Mn EaFA-L05-1316-T03-A 1 2.81E+03
Mn EaFA-L05-1316-T04-A 1 3.07E+03
Mn EaFA-L05-1316-T05-A
Mn EaFA-L05-1316-T01-B 1 3.12E+02
Mn EaFA-L05-1316-T02-B 1 6.27E+02
Mn EaFA-L05-1316-T03-B 1 2.03E+03
Mn EaFA-L05-1316-T04-B 1 3.84E+03
Mn EaFA-L05-1316-T05-B
Mn EaFA-L05-1316-T01-C 1 3.65E+02
Mn EaFA-L05-1316-T02-C 1 5.67E+02
Mn EaFA-L05-1316-T03-C 1 2.10E+03
Mn EaFA-L05-1316-T04-C 1 5.08E+03
Mn EaFA-L05-1316-T05-C
Mn EaFA-L05-1316-B01-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.61E+02 3.89E+00 2.0E+00 6.4E+00
7.48E+02 1.07E+00 2.0E+00 6.4E+00 10 300
2.81E+03 5.12E-01 2.0E+00 6.4E+00
3.07E+03 9.60E-01 2.0E+00 6.4E+00

3.12E+02 1.55E+00 2.0E+00 6.4E+00
6.27E+02 1.91E+00 2.0E+00 6.4E+00 10 300
2.03E+03 4.24E-01 2.0E+00 6.4E+00
3.84E+03 6.76E-01 2.0E+00 6.4E+00

3.65E+02 1.31E+00 2.0E+00 6.4E+00
5.67E+02 1.21E+00 2.0E+00 6.4E+00 10 300
2.10E+03 5.71E-01 2.0E+00 6.4E+00
5.08E+03 4.17E-01 2.0E+00 6.4E+00

1.00E+00 1.03E+03 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
3.79E+03 101% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
3.51E+03 96% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
3.75E+03 106% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1033
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg EaFA-L05-1316-T01-A 1 5.30E+03
Mg EaFA-L05-1316-T02-A 1 1.14E+04
Mg EaFA-L05-1316-T03-A 1 3.49E+04
Mg EaFA-L05-1316-T04-A 1 7.26E+04
Mg EaFA-L05-1316-T05-A
Mg EaFA-L05-1316-T01-B 1 5.28E+03
Mg EaFA-L05-1316-T02-B 1 9.73E+03
Mg EaFA-L05-1316-T03-B 1 3.85E+04
Mg EaFA-L05-1316-T04-B 1 6.97E+04
Mg EaFA-L05-1316-T05-B
Mg EaFA-L05-1316-T01-C 1 5.06E+03
Mg EaFA-L05-1316-T02-C 1 1.03E+04
Mg EaFA-L05-1316-T03-C 1 3.84E+04
Mg EaFA-L05-1316-T04-C 1 6.57E+04
Mg EaFA-L05-1316-T05-C
Mg EaFA-L05-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.30E+03 1.44E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
1.14E+04 1.40E+00 1 .OE+00 3.2E+00 1000 100 1.24E+04 103% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
3.49E+04 6.60E-01 1. OE+00 3.2E+00
7.26E+04 1.19E+00 1. OE+00 3.2E+00

5.28E+03 4.57E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
9.73E+03 7.18E-01 1.0E+00 3.2E+00 1000 100 1.07E+04 93% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
3.85E+04 2.80E-01 1. OE+00 3.2E+00
6.97E+04 4.77E-01 1. OE+00 3.2E+00

5.06E+03 7.09E-01 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
1.03E+04 2.72E-01 1.0E+00 3.2E+00 1000 100 1.14E+04 108% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
3.84E+04 3.39E-02 1. OE+00 3.2E+00
6.57E+04 7.08E-01 1. OE+00 3.2E+00

5.00E-01 1.47E+01 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1034
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo EaFA-L05-1316-T01-A 1 4.56E+02
Mo EaFA-L05-1316-T02-A 1 9.04E+02
Mo EaFA-L05-1316-T03-A 1 2.29E+03
Mo EaFA-L05-1316-T04-A 1 1.39E+04
Mo EaFA-L05-1316-T05-A
Mo EaFA-L05-1316-T01-B 1 1.00E+03
Mo EaFA-L05-1316-T02-B 1 5.50E+02
Mo EaFA-L05-1316-T03-B 1 8.48E+03
Mo EaFA-L05-1316-T04-B 1 1.05E+04
Mo EaFA-L05-1316-T05-B
Mo EaFA-L05-1316-T01-C 1 3.17E+02
Mo EaFA-L05-1316-T02-C 1 1.98E+03
Mo EaFA-L05-1316-T03-C 1 8.09E+03
Mo EaFA-L05-1316-T04-C 1 3.44E+03
Mo EaFA-L05-1316-T05-C
Mo EaFA-L05-1316-B01-A 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.56E+02 2.86E+00 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
9.04E+02 1.21E+00 1 .2E+00 3.8E+00 10 300 4.04E+03 105% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
2.29E+03 3.54E-01 1.2E+00 3.8E+00
1.39E+04 1.92E-01 1.2E+00 3.8E+00

1.00E+03 1.58E+00 1.2E+00 3.8E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
5.50E+02 3.58E-01 1.2E+00 3.8E+00 10 300 3.51E+03 99% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
8.48E+03 2.93E-01 1.2E+00 3.8E+00
1.05E+04 8.71 E-01 1.2E+00 3.8E+00

3.17E+02 1.04E+00 1.2E+00 3.8E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
1.98E+03 5.05E-01 1.2E+00 3.8E+00 10 300 5.11E+03 104% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
8.09E+03 5.69E-01 1.2E+00 3.8E+00
3.44E+03 1.33E+00 1.2E+00 3.8E+00

6.00E-01 2.85E+01 1.2E+00 3.8E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1035
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni EaFA-L05-1316-T01-A 1 3.49E+02
Ni EaFA-L05-1316-T02-A 1 6.33E+02
Ni EaFA-L05-1316-T03-A 1 2.05E+03
Ni EaFA-L05-1316-T04-A 1 8.94E+02
Ni EaFA-L05-1316-T05-A
Ni EaFA-L05-1316-T01-B 1 2.76E+02
Ni EaFA-L05-1316-T02-B 1 5.88E+02
Ni EaFA-L05-1316-T03-B 1 7.99E+02
Ni EaFA-L05-1316-T04-B 1 1.30E+03
Ni EaFA-L05-1316-T05-B
Ni EaFA-L05-1316-T01-C 1 3.98E+02
Ni EaFA-L05-1316-T02-C 1 4.10E+02
Ni EaFA-L05-1316-T03-C 1 8.91 E+02
Ni EaFA-L05-1316-T04-C 1 2.97E+03
Ni EaFA-L05-1316-T05-C
Ni EaFA-L05-1316-B01-A 1 2.73E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.49E+02 2.94E+00 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
6.33E+02 5.42E+00 1 .8E+00 5.7E+00 10 300 3.75E+03 104% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
2.05E+03 1.32E+00 1 .8E+00 5.7E+00
8.94E+02 1.82E+00 1 .8E+00 5.7E+00

2.76E+02 1.79E+00 1 .8E+00 5.7E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
5.88E+02 7.20E-01 1 .8E+00 5.7E+00 10 300 3.53E+03 98% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
7.99E+02 6.39E-01 1 .8E+00 5.7E+00
1.30E+03 1.07E+00 1 .8E+00 5.7E+00

3.98E+02 1.81E+00 1 .8E+00 5.7E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
4.10E+02 1.07E+00 1 .8E+00 5.7E+00 10 300 3.66E+03 108% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
8.91 E+02 8.59E-01 1 .8E+00 5.7E+00
2.97E+03 1.39E+00 1 .8E+00 5.7E+00

2.73E+00 4.32E+02 1 .8E+00 5.7E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1036
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P EaFA-L05-1316-T01-A 1 2.29E+01
P EaFA-L05-1316-T02-A 1 2.48E+01
P EaFA-L05-1316-T03-A 1 9.87E+01
P EaFA-L05-1316-T04-A 1 7.70E+01
P EaFA-L05-1316-T05-A
P EaFA-L05-1316-T01-B 1 4.57E+01
P EaFA-L05-1316-T02-B 1 1.15E+01 E
P EaFA-L05-1316-T03-B 1 2.32E+02
P EaFA-L05-1316-T04-B 1 6.07E+01
P EaFA-L05-1316-T05-B
P EaFA-L05-1316-T01-C 1 2.03E+01
P EaFA-L05-1316-T02-C 1 8.03E+01
P EaFA-L05-1316-T03-C 1 1.02E+02
P EaFA-L05-1316-T04-C 1 1.58E+02
P EaFA-L05-1316-T05-C
P EaFA-L05-1316-B01-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.29E+01 1.75E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
2.48E+01 1.88E+01 3.7E+00 1.2E+01 1000 100 1.11E+03 109% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
9.87E+01 1.33E+01 3.7E+00 1.2E+01
7.70E+01 1.07E+01 3.7E+00 1.2E+01

4.57E+01 1.28E+01 3.7E+00 1.2E+01
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
1.15E+01 1.64E+01 3.7E+00 1.2E+01 1000 100 1 .04E+03 102% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
2.32E+02 6.72E+00 3.7E+00 1.2E+01
6.07E+01 2.02E+01 3.7E+00 1.2E+01

2.03E+01 1.84E+01 3.7E+00 1.2E+01
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
8.03E+01 4.32E+01 3.7E+00 1.2E+01 1000 100 1.16E+03 108% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
1.02E+02 9.47E-01 3.7E+00 1.2E+01
1.58E+02 1.31E+01 3.7E+00 1.2E+01

1.85E+00 1.08E+02 3.7E+00 1.2E+01
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1037
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K EaFA-L05-1316-T01-A 1 2.21E+04
K EaFA-L05-1316-T02-A 1 4.76E+04
K EaFA-L05-1316-T03-A 1 1.25E+05
K EaFA-L05-1316-T04-A 1 2.13E+05
K EaFA-L05-1316-T05-A
K EaFA-L05-1316-T01-B 1 2.30E+04
K EaFA-L05-1316-T02-B 1 4.12E+04
K EaFA-L05-1316-T03-B 1 1.28E+05
K EaFA-L05-1316-T04-B 1 2.06E+05
K EaFA-L05-1316-T05-B
K EaFA-L05-1316-T01-C 1 2.08E+04
K EaFA-L05-1316-T02-C 1 4.46E+04
K EaFA-L05-1316-T03-C 1 1.30E+05
K EaFA-L05-1316-T04-C 1 1.96E+05
K EaFA-L05-1316-T05-C
K EaFA-L05-1316-B01-A 1 1.07E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.21E+04 1.27E+00 1 .6E+00 5.1E+00
4.76E+04 1.19E+00 1 .6E+00 5.1E+00 1000 100
1.25E+05 1.88E-01 1 .6E+00 5.1E+00
2.13E+05 5.49E-01 1 .6E+00 5.1E+00

2.30E+04 1.07E+00 1.6E+00 5.1E+00
4.12E+04 8.12E-01 1.6E+00 5.1E+00 1000 100
1.28E+05 6.11E-01 1.6E+00 5.1E+00
2.06E+05 1.41E+00 1.6E+00 5.1E+00

2.08E+04 5.06E-01 1.6E+00 5.1E+00
4.46E+04 9.50E-01 1.6E+00 5.1E+00 1000 100
1.30E+05 2.05E-01 1.6E+00 5.1E+00
1.96E+05 1.69E+00 1.6E+00 5.1E+00

1.07E+01 1.98E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
4.85E+04 85% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
4.21E+04 92% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
4.55E+04 90% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1038
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se EaFA-L05-1316-T01-A 1 3.60E+02
Se EaFA-L05-1316-T02-A 1 4.55E+02
Se EaFA-L05-1316-T03-A 1 5.78E+02
Se EaFA-L05-1316-T04-A 1 1.11E+03
Se EaFA-L05-1316-T05-A
Se EaFA-L05-1316-T01-B 1 4.60E+02
Se EaFA-L05-1316-T02-B 1 3.69E+02
Se EaFA-L05-1316-T03-B 1 8.78E+02
Se EaFA-L05-1316-T04-B 1 1.07E+03
Se EaFA-L05-1316-T05-B
Se EaFA-L05-1316-T01-C 1 2.90E+02
Se EaFA-L05-1316-T02-C 1 5.33E+02
Se EaFA-L05-1316-T03-C 1 8.53E+02
Se EaFA-L05-1316-T04-C 1 7.36E+02
Se EaFA-L05-1316-T05-C
Se EaFA-L05-1316-B01-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.60E+02 5.23E+00 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
4.55E+02 2.59E+00 1 .5E+01 4.8E+01 10 300 3.68E+03 108% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
5.78E+02 1.33E+00 1 .5E+01 4.8E+01
1.11E+03 1.60E+00 1.5E+01 4.8E+01

4.60E+02 3.17E+00 1.5E+01 4.8E+01
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
3.69E+02 1.51E+00 1.5E+01 4.8E+01 10 300 3.40E+03 101% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
8.78E+02 3.54E+00 1.5E+01 4.8E+01
1.07E+03 9.30E-01 1.5E+01 4.8E+01

2.90E+02 3.30E+00 1.5E+01 4.8E+01
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
5.33E+02 1.74E+00 1.5E+01 4.8E+01 10 300 3.85E+03 1 11% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
8.53E+02 5.13E+00 1.5E+01 4.8E+01
7.36E+02 4.68E+00 1.5E+01 4.8E+01

7.50E+00 2.80E+02 1.5E+01 4.8E+01
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1039
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si EaFA-L05-1316-T01-A 1 1.82E+03
Si EaFA-L05-1316-T02-A 1 3.53E+03
Si EaFA-L05-1316-T03-A 1 8.76E+03
Si EaFA-L05-1316-T04-A 1 3.11E+03
Si EaFA-L05-1316-T05-A
Si EaFA-L05-1316-T01-B 1 1.65E+03
Si EaFA-L05-1316-T02-B 1 2.91E+03
Si EaFA-L05-1316-T03-B 1 3.09E+03
Si EaFA-L05-1316-T04-B 1 4.10E+03
Si EaFA-L05-1316-T05-B
Si EaFA-L05-1316-T01-C 1 1.84E+03
Si EaFA-L05-1316-T02-C 1 2.73E+03
Si EaFA-L05-1316-T03-C 1 3.39E+03
Si EaFA-L05-1316-T04-C 1 1.02E+04
Si EaFA-L05-1316-T05-C
Si EaFA-L05-1316-B01-A 1 4.30E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.82E+03 1.16E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
3.53E+03 1.53E+00 1.1E+00 3.5E+00 1000 100 4.55E+03 102% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
8.76E+03 5.55E-01 1.1E+00 3.5E+00
3.11E+03 1.06E+00 1.1E+00 3.5E+00

1.65E+03 1.87E+00 1.1E+00 3.5E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
2.91E+03 7.64E-01 1.1E+00 3.5E+00 1000 100 3.87E+03 97% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
3.09E+03 6.59E-02 1.1E+00 3.5E+00
4.10E+03 1.44E+00 1.1E+00 3.5E+00

1.84E+03 4.77E-01 1.1E+00 3.5E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
2.73E+03 5.71E-01 1.1E+00 3.5E+00 1000 100 3.87E+03 114% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
3.39E+03 5.28E-01 1.1E+00 3.5E+00
1.02E+04 1.12E+00 1.1E+00 3.5E+00

4.30E+00 1.67E+01 1.1E+00 3.5E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1040
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na EaFA-L05-1316-T01-A 1 4.37E+03
Na EaFA-L05-1316-T02-A 1 9.41 E+03
Na EaFA-L05-1316-T03-A 1 2.46E+04
Na EaFA-L05-1316-T04-A 1 4.35E+04
Na EaFA-L05-1316-T05-A
Na EaFA-L05-1316-T01-B 1 4.51 E+03
Na EaFA-L05-1316-T02-B 1 8.12E+03
Na EaFA-L05-1316-T03-B 1 2.55E+04
Na EaFA-L05-1316-T04-B 1 4.19E+04
Na EaFA-L05-1316-T05-B
Na EaFA-L05-1316-T01-C 1 4.20E+03
Na EaFA-L05-1316-T02-C 1 8.67E+03
Na EaFA-L05-1316-T03-C 1 2.57E+04
Na EaFA-L05-1316-T04-C 1 4.04E+04
Na EaFA-L05-1316-T05-C
Na EaFA-L05-1316-B01-A 1 1.38E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.37E+03 1.37E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
9.41E+03 9.77E-01 2.5E+00 8.0E+00 1000 100 1.03E+04 94% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
2.46E+04 1.98E-01 2.5E+00 8.0E+00
4.35E+04 1.19E-01 2.5E+00 8.0E+00

4.51E+03 2.39E+00 2.5E+00 8.0E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
8.12E+03 3.01E-01 2.5E+00 8.0E+00 1000 100 9.01E+03 89% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
2.55E+04 4.43E-01 2.5E+00 8.0E+00
4.19E+04 1.52E+00 2.5E+00 8.0E+00

4.20E+03 7.87E-01 2.5E+00 8.0E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/101:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
8.67E+03 8.75E-01 2.5E+00 8.0E+00 1000 100 9.61E+03 94% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
2.57E+04 4.51E-01 2.5E+00 8.0E+00
4.04E+04 1.17E+00 2.5E+00 8.0E+00

1.38E+01 1.66E+00 2.5E+00 8.0E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1041
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
EaFA-L05-1316-T01-A 1 1.76E+03
EaFA-L05-1316-T02-A 1 3.67E+03
EaFA-L05-1316-T03-A 1 8.83E+03
EaFA-L05-1316-T04-A 1 8.48E+03
EaFA-L05-1316-T05-A
EaFA-L05-1316-T01-B 1 1.76E+03
EaFA-L05-1316-T02-B 1 2.90E+03
EaFA-L05-1316-T03-B 1 8.49E+03
EaFA-L05-1316-T04-B 1 8.73E+03
EaFA-L05-1316-T05-B
EaFA-L05-1316-T01-C 1 1.93E+03
EaFA-L05-1316-T02-C 1 2.98E+03
EaFA-L05-1316-T03-C 1 8.68E+03
EaFA-L05-1316-T04-C 1 1.00E+04
EaFA-L05-1316-T05-C
EaFA-L05-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.76E+03 2.89E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
3.67E+03 1.23E+00 1 .OE+00 3.2E+00 1000 100 4.73E+03 105% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
8.83E+03 9.39E-01 1 .OE+00 3.2E+00
8.48E+03 1.19E+00 1 .OE+00 3.2E+00

1.76E+03 4.99E-01 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
2.90E+03 1.27E+00 1.0E+00 3.2E+00 1000 100 3.85E+03 95% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
8.49E+03 2.17E-01 1. OE+00 3.2E+00
8.73E+03 4.33E-01 1. OE+00 3.2E+00

1.93E+03 1.09E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
2.98E+03 9.93E-01 1.0E+00 3.2E+00 1000 100 3.97E+03 99% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
8.68E+03 9.82E-01 1. OE+00 3.2E+00
1.00E+04 4.42E-01 1. OE+00 3.2E+00

5.00E-01 1.81E+02 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1042
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S EaFA-L05-1316-T01-A 1 1.22E+05
S EaFA-L05-1316-T02-A 1 2.69E+05
S EaFA-L05-1316-T03-A 1 6.90E+05
S EaFA-L05-1316-T04-A 1 8.01E+05
S EaFA-L05-1316-T05-A
S EaFA-L05-1316-T01-B 1 1.27E+05
S EaFA-L05-1316-T02-B 1 2.22E+05
S EaFA-L05-1316-T03-B 1 7.55E+05
S EaFA-L05-1316-T04-B 1 7.94E+05
S EaFA-L05-1316-T05-B
S EaFA-L05-1316-T01-C 1 1.33E+05
S EaFA-L05-1316-T02-C 1 2.37E+05
S EaFA-L05-1316-T03-C 1 7.67E+05
S EaFA-L05-1316-T04-C 1 7.63E+05
S EaFA-L05-1316-T05-C
S EaFA-L05-1316-B01-A 1 1.09E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.22E+05 1.03E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
2.69E+05 1.25E+00 6.8E+00 2.2E+01 1000 100 3.53E+05 84% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
6.90E+05 5.99E-01 6.8E+00 2.2E+01
8.01 E+05 1.65E-01 6.8E+00 2.2E+01

1.27E+05 2.00E+00 6.8E+00 2.2E+01
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
2.22E+05 6.88E-01 6.8E+00 2.2E+01 1000 100 3.02E+05 80% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
7.55E+05 8.23E-02 6.8E+00 2.2E+01
7.94E+05 1.00E+00 6.8E+00 2.2E+01

1.33E+05 5.13E-01 6.8E+00 2.2E+01
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
2.37E+05 3.81E-01 6.8E+00 2.2E+01 1000 100 3.22E+05 85% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
7.67E+05 4.33E-01 6.8E+00 2.2E+01
7.63E+05 8.38E-01 6.8E+00 2.2E+01

1.09E+01 2.82E+01 6.8E+00 2.2E+01
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1043
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl EaFA-L05-1316-T01-A 1 1.43E+01 E
Tl EaFA-L05-1316-T02-A 1 3.11E+01
Tl EaFA-L05-1316-T03-A 1 4.69E+01
Tl EaFA-L05-1316-T04-A 1 1.07E+01 E
Tl EaFA-L05-1316-T05-A
Tl EaFA-L05-1316-T01-B 1 2.30E+00 U1/2
Tl EaFA-L05-1316-T02-B 1 2.28E+01
Tl EaFA-L05-1316-T03-B 1 2.30E+00 U1/2
Tl EaFA-L05-1316-T04-B 1 2.50E+01
Tl EaFA-L05-1316-T05-B
Tl EaFA-L05-1316-T01-C 1 2.24E+01
Tl EaFA-L05-1316-T02-C 1 7.67E+00 E
Tl EaFA-L05-1316-T03-C 1 5.24E+00 E
Tl EaFA-L05-1316-T04-C 1 6.52E+01
Tl EaFA-L05-1316-T05-C
Tl EaFA-L05-1316-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.43E+01 1.99E+03 4.6E+00 1.5E+01
3.11E+01 5.13E+01 4.6E+00 1.5E+01 10 300
4.69E+01 7.29E+01 4.6E+00 1.5E+01
1.07E+01 4.03E+01 4.6E+00 1.5E+01

2.30E+00 4.89E+02 4.6E+00 1.5E+01
2.28E+01 7.52E+01 4.6E+00 1.5E+01 10 300
2.30E+00 1.33E+02 4.6E+00 1.5E+01
2.50E+01 5.15E+01 4.6E+00 1.5E+01

2.24E+01 1.28E+02 4.6E+00 1.5E+01
7.67E+00 1.89E+02 4.6E+00 1.5E+01 10 300
5.24E+00 1.36E+02 4.6E+00 1.5E+01
6.52E+01 8.83E+01 4.6E+00 1.5E+01

2.30E+00 8.63E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
3.14E+03 104% VU ICP-OES 7/29/101:12 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
2.98E+03 99% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
3.25E+03 108% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1044
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti EaFA-L05-1316-T01-A 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T02-A 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T03-A 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T04-A 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T05-A
Ti EaFA-L05-1316-T01-B 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T02-B 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T03-B 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T04-B 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T05-B
Ti EaFA-L05-1316-T01-C 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T02-C 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T03-C 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T04-C 1 1.00E+OOU1/2
Ti EaFA-L05-1316-T05-C
Ti EaFA-L05-1316-B01-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.63E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 3.00E+02 2.0E+00 6.4E+00 10 300 3.15E+03 105% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 8.48E+01 2.0E+00 6.4E+00
1.00E+00 1.30E+02 2.0E+00 6.4E+00

1.00E+00 6.08E+01 2.0E+00 6.4E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 9.44E+01 2.0E+00 6.4E+00 10 300 2.95E+03 98% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 1.13E+01 2.0E+00 6.4E+00
1.00E+00 8.51 E+01 2.0E+00 6.4E+00

1.00E+00 1.96E+02 2.0E+00 6.4E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1 :22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1 :23 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 2.89E+02 2.0E+00 6.4E+00 10 300 3.25E+03 108% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 4.42E+01 2.0E+00 6.4E+00
1.00E+00 1.42E+02 2.0E+00 6.4E+00

1.00E+00 8.58E+01 2.0E+00 6.4E+00
VU ICP-OES 7/29/10 1 :27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1 :28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1 :05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1045
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V EaFA-L05-1316-T01-A 1 7.65E+01
V EaFA-L05-1316-T02-A 1 1.28E+02
V EaFA-L05-1316-T03-A 1 1.91E+02
V EaFA-L05-1316-T04-A 1 2.03E+02
V EaFA-L05-1316-T05-A
V EaFA-L05-1316-T01-B 1 9.02E+01
V EaFA-L05-1316-T02-B 1 9.91 E+01
V EaFA-L05-1316-T03-B 1 2.08E+02
V EaFA-L05-1316-T04-B 1 2.14E+02
V EaFA-L05-1316-T05-B
V EaFA-L05-1316-T01-C 1 6.87E+01
V EaFA-L05-1316-T02-C 1 1.19E+02
V EaFA-L05-1316-T03-C 1 2.14E+02
V EaFA-L05-1316-T04-C 1 1.89E+02
V EaFA-L05-1316-T05-C
V EaFA-L05-1316-B01-A 1 2.61E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.65E+01 3.36E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
1.28E+02 1.42E-01 1 .5E+00 4.8E+00 10 300 3.28E+03 105% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
1.91E+02 2.81E-01 1 .5E+00 4.8E+00
2.03E+02 3.78E-01 1 .5E+00 4.8E+00

9.02E+01 2.93E+00 1.5E+00 4.8E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
9.91E+01 8.97E-01 1.5E+00 4.8E+00 10 300 3.08E+03 99% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
2.08E+02 6.55E-01 1.5E+00 4.8E+00
2.14E+02 9.35E-01 1.5E+00 4.8E+00

6.87E+01 5.17E-01 1.5E+00 4.8E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
1.19E+02 5.55E-01 1.5E+00 4.8E+00 10 300 3.41E+03 1 10% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
2.14E+02 4.66E-01 1.5E+00 4.8E+00
1.89E+02 1.58E+00 1.5E+00 4.8E+00

2.61 E+00 5.98E+00 1.5E+00 4.8E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1046
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn EaFA-L05-1316-T01-A 1 6.71 E+02
Zn EaFA-L05-1316-T02-A 1 1.02E+03
Zn EaFA-L05-1316-T03-A 1 2.65E+03
Zn EaFA-L05-1316-T04-A 1 1.48E+02
Zn EaFA-L05-1316-T05-A
Zn EaFA-L05-1316-T01-B 1 4.54E+02
Zn EaFA-L05-1316-T02-B 1 1.12E+03
Zn EaFA-L05-1316-T03-B 1 1.52E+02
Zn EaFA-L05-1316-T04-B 1 3.01 E+02
Zn EaFA-L05-1316-T05-B
Zn EaFA-L05-1316-T01-C 1 8.19E+02
Zn EaFA-L05-1316-T02-C 1 3.25E+02
Zn EaFA-L05-1316-T03-C 1 1.94E+02
Zn EaFA-L05-1316-T04-C 1 2.96E+03
Zn EaFA-L05-1316-T05-C
Zn EaFA-L05-1316-B01-A 1 1.18E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.71E+02 4.18E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/29/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
1.02E+03 5.62E+00 1 .OE+00 3.2E+00 10 300 4.18E+03 105% VU ICP-OES 7/29/10 1:12 PM EPA Interlab LOS 1313-1316 EaFA
2.65E+03 6.15E-01 1 .OE+00 3.2E+00
1.48E+02 1.24E+00 1 .OE+00 3.2E+00

4.54E+02 2.61 E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:14 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:15 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:17 PM EPA Interlab LOS 1313-1316 EaFA
1.12E+03 3.23E+00 1.0E+00 3.2E+00 10 300 4.11E+03 100% VU ICP-OES 7/29/10 1:18 PM EPA Interlab LOS 1313-1316 EaFA
1.52E+02 1.82E+00 1. OE+00 3.2E+00
3.01 E+02 1.02E+00 1. OE+00 3.2E+00

8.19E+02 4.07E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:20 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:22 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:23 PM EPA Interlab LOS 1313-1316 EaFA
3.25E+02 3.67E+00 1.0E+00 3.2E+00 10 300 3.69E+03 1 12% VU ICP-OES 7/29/10 1:25 PM EPA Interlab LOS 1313-1316 EaFA
1.94E+02 2.10E+00 1. OE+00 3.2E+00
2.96E+03 2.72E-01 1. OE+00 3.2E+00

1.18E+01 4.14E+00 1. OE+00 3.2E+00
VU ICP-OES 7/29/10 1:27 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 7/29/10 1:28 PM EPA Interlab LOS 1313-1316 EaFA

VU ICP-OES 7/29/10 1:05 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1047
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al EaFA-L06-1316-T01-A 1
Al EaFA-L06-1316-T02-A 1
Al EaFA-L06-1316-T03-A 1
Al EaFA-L06-1316-T04-A 1
Al EaFA-L06-1316-T05-A 1
Al EaFA-L06-1316-T01-B 1
Al EaFA-L06-1316-T02-B 1
Al EaFA-L06-1316-T03-B 1
Al EaFA-L06-1316-T04-B 1
Al EaFA-L06-1316-T05-B 1
Al EaFA-L06-1316-T01-C 1
Al EaFA-L06-1316-T02-C 1
Al EaFA-L06-1316-T03-C 1
Al EaFA-L06-1316-T04-C 1
Al EaFA-L06-1316-T05-C 1
Al EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
9.05E+01
1.16E+02
2.01 E+02
3.76E+02
5.71 E+02
1.25E+02
1.43E+02
2.25E+02
5.35E+02
9.78E+02
1.31 E+02
1.39E+02
2.57E+02
4.98E+02
1.92E+03
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.05E+01 5.6E-01 1.0E+00 3.2E+00
1.16E+02 2.7E+00 1.0E+00 3.2E+00 1000 100
2.01 E+02 9.8E-01 1.0E+00 3.2E+00
3.76E+02 9.3E+00 1.0E+00 3.2E+00
5.71 E+02 1.4E+01 1.0E+00 3.2E+00
1.25E+02 7.6E-02 1.0E+00 3.2E+00
1.43E+02 4.7E+00 1.0E+00 3.2E+00 1000 100
2.25E+02 1.4E+00 1.0E+00 3.2E+00
5.35E+02 5.4E-01 1.0E+00 3.2E+00
9.78E+02 1.6E+00 1.0E+00 3.2E+00
1.31 E+02 1.0E+00 1.0E+00 3.2E+00
1.39E+02 1.4E+00 1.0E+00 3.2E+00 1000 100
2.57E+02 1.8E+00 1.0E+00 3.2E+00
4.98E+02 1.5E+00 1.0E+00 3.2E+00
1.92E+03 2.1E+00 1.0E+00 3.2E+00
5.00E-01 7.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .06E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .07E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                                 1-1048
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L06-1316-T01-A 1
Sb EaFA-L06-1316-T02-A 1
Sb EaFA-L06-1316-T03-A 1
Sb EaFA-L06-1316-T04-A 1
Sb EaFA-L06-1316-T05-A 1
Sb EaFA-L06-1316-T01-B 1
Sb EaFA-L06-1316-T02-B 1
Sb EaFA-L06-1316-T03-B 1
Sb EaFA-L06-1316-T04-B 1
Sb EaFA-L06-1316-T05-B 1
Sb EaFA-L06-1316-T01-C 1
Sb EaFA-L06-1316-T02-C 1
Sb EaFA-L06-1316-T03-C 1
Sb EaFA-L06-1316-T04-C 1
Sb EaFA-L06-1316-T05-C 1
Sb EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.12E+02
2.83E+02
4.30E+02
5.06E+02
5.67E+02
2.15E+02
3.23E+02
4.41 E+02
6.10E+02
7.56E+02
1.87E+02
3.15E+02
4.13E+02
5.52E+02
7.92E+02
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.12E+02 8.1E+00 7.5E+00 2.4E+01
2.83E+02 3.2E+00 7.5E+00 2.4E+01 10 300
4.30E+02 3.7E+00 7.5E+00 2.4E+01
5.06E+02 1.4E+01 7.5E+00 2.4E+01
5.67E+02 1.1E+01 7.5E+00 2.4E+01
2.15E+02 4.9E+00 7.5E+00 2.4E+01
3.23E+02 4.5E+00 7.5E+00 2.4E+01 10 300
4.41 E+02 1.0E+01 7.5E+00 2.4E+01
6.10E+02 5.5E+00 7.5E+00 2.4E+01
7.56E+02 4.0E-01 7.5E+00 2.4E+01
1.87E+02 8.3E+00 7.5E+00 2.4E+01
3.15E+02 5.6E+00 7.5E+00 2.4E+01 10 300
4.13E+02 3.5E+00 7.5E+00 2.4E+01
5.52E+02 5.0E+00 7.5E+00 2.4E+01
7.92E+02 3.0E+00 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.41E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.51E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.37E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1049
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As EaFA-L06-1316-T01-A 1
As EaFA-L06-1316-T02-A 1
As EaFA-L06-1316-T03-A 1
As EaFA-L06-1316-T04-A 1
As EaFA-L06-1316-T05-A 1
As EaFA-L06-1316-T01-B 1
As EaFA-L06-1316-T02-B 1
As EaFA-L06-1316-T03-B 1
As EaFA-L06-1316-T04-B 1
As EaFA-L06-1316-T05-B 1
As EaFA-L06-1316-T01-C 1
As EaFA-L06-1316-T02-C 1
As EaFA-L06-1316-T03-C 1
As EaFA-L06-1316-T04-C 1
As EaFA-L06-1316-T05-C 1
As EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.13E+02
1.29E+02
1.37E+02
1.39E+02
1.44E+02
9.73E+01
8.03E+01
1.22E+02
1.48E+02
1.68E+02
9.41 E+01
8.99E+01
1.11E+02
1.34E+02
5.09E+02
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.13E+02 9.2E+00 1.1E+01 3.5E+01
1.29E+02 2.6E+01 1.1E+01 3.5E+01 10 300
1.37E+02 5.9E+00 1.1 E+01 3.5E+01
1.39E+02 1.9E+01 1.1 E+01 3.5E+01
1.44E+02 3.1 E+01 1.1 E+01 3.5E+01
9.73E+01 2.0E+01 1.1E+01 3.5E+01
8.03E+01 1.8E+01 1.1E+01 3.5E+01 10 300
1.22E+02 4.2E+01 1.1 E+01 3.5E+01
1.48E+02 1.5E+01 1.1 E+01 3.5E+01
1.68E+02 1.6E+01 1.1 E+01 3.5E+01
9.41 E+01 1.8E+01 1.1 E+01 3.5E+01
8.99E+01 2.2E+01 1.1E+01 3.5E+01 10 300
1.11E+02 1.2E+01 1.1 E+01 3.5E+01
1.34E+02 7.3E+00 1.1 E+01 3.5E+01
5.09E+02 4.3E+00 1.1 E+01 3.5E+01
5.50E+00 9.5E+01 1.1 E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.29E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.41 E+03 111 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.22E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1050
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qu
B EaFA-L06-1316-T01-A 1 4.15E+03
B EaFA-L06-1316-T02-A 1 8.08E+03
B EaFA-L06-1316-T03-A 1 2.05E+04
B EaFA-L06-1316-T04-A 1 3.21E+04
B EaFA-L06-1316-T05-A 1 4.94E+04
B EaFA-L06-1316-T01-B 1 5.06E+03
B EaFA-L06-1316-T02-B 1 8.86E+03
B EaFA-L06-1316-T03-B 1 2.12E+04
B EaFA-L06-1316-T04-B 1 3.78E+04
B EaFA-L06-1316-T05-B 1 6.51 E+04
B EaFA-L06-1316-T01-C 1 6.21E+03
B EaFA-L06-1316-T02-C 1 9.60E+03
B EaFA-L06-1316-T03-C 1 1.98E+04
B EaFA-L06-1316-T04-C 1 3.63E+04
B EaFA-L06-1316-T05-C 1 5.52E+04
B EaFA-L06-1316-B01-A 1 2.20E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.15E+03 6.1E-01 1.0E+00 3.2E+00
8.08E+03 3.5E-01 1.0E+00 3.2E+00 1000 100
2.05E+04 2.6E-01 1.0E+00 3.2E+00
3.21 E+04 1.1E+01 1.0E+00 3.2E+00
4.94E+04 1.3E+01 1.0E+00 3.2E+00
5.06E+03 1.8E+00 1.0E+00 3.2E+00
8.86E+03 5.3E-01 1.0E+00 3.2E+00 1000 100
2.12E+04 1.4E+00 1.0E+00 3.2E+00
3.78E+04 2.2E+00 1.0E+00 3.2E+00
6.51 E+04 2.8E-01 1.0E+00 3.2E+00
6.21 E+03 2.5E+00 1.0E+00 3.2E+00
9.60E+03 4.3E-01 1.0E+00 3.2E+00 1000 100
1.98E+04 1.6E+00 1.0E+00 3.2E+00
3.63E+04 2.9E-01 1.0E+00 3.2E+00
5.52E+04 9.5E-01 1.0E+00 3.2E+00
2.20E+01 1.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.02E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.74E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .05E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1051
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFA-L06-1316-T01-A 1
Ba EaFA-L06-1316-T02-A 1
Ba EaFA-L06-1316-T03-A 1
Ba EaFA-L06-1316-T04-A 1
Ba EaFA-L06-1316-T05-A 1
Ba EaFA-L06-1316-T01-B 1
Ba EaFA-L06-1316-T02-B 1
Ba EaFA-L06-1316-T03-B 1
Ba EaFA-L06-1316-T04-B 1
Ba EaFA-L06-1316-T05-B 1
Ba EaFA-L06-1316-T01-C 1
Ba EaFA-L06-1316-T02-C 1
Ba EaFA-L06-1316-T03-C 1
Ba EaFA-L06-1316-T04-C 1
Ba EaFA-L06-1316-T05-C 1
Ba EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.71E+02
2.19E+02
2.20E+02
2.25E+02
2.15E+02
3.00E+02
2.46E+02
2.30E+02
2.68E+02
3.07E+02
2.90E+02
2.48E+02
2.22E+02
2.49E+02
3.66E+02
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.71 E+02 7.3E-01 1.0E+00 3.2E+00
2.19E+02 3.1E-01 1.0E+00 3.2E+00 10 300
2.20E+02 6.1E-01 1.0E+00 3.2E+00
2.25E+02 9.0E+00 1.0E+00 3.2E+00
2.15E+02 1.3E+01 1.0E+00 3.2E+00
3.00E+02 3.9E-01 1.0E+00 3.2E+00
2.46E+02 4.3E-01 1.0E+00 3.2E+00 10 300
2.30E+02 1.4E+00 1.0E+00 3.2E+00
2.68E+02 5.3E-01 1.0E+00 3.2E+00
3.07E+02 1.9E+00 1.0E+00 3.2E+00
2.90E+02 1.0E+00 1.0E+00 3.2E+00
2.48E+02 3.6E-01 1.0E+00 3.2E+00 10 300
2.22E+02 6.2E-01 1.0E+00 3.2E+00
2.49E+02 5.9E-01 1.0E+00 3.2E+00
3.66E+02 3.6E-01 1.0E+00 3.2E+00
5.00E-01 4.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.07E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.21E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.06E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1052
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L06-1316-T01-A 1
Be EaFA-L06-1316-T02-A 1
Be EaFA-L06-1316-T03-A 1
Be EaFA-L06-1316-T04-A 1
Be EaFA-L06-1316-T05-A 1
Be EaFA-L06-1316-T01-B 1
Be EaFA-L06-1316-T02-B 1
Be EaFA-L06-1316-T03-B 1
Be EaFA-L06-1316-T04-B 1
Be EaFA-L06-1316-T05-B 1
Be EaFA-L06-1316-T01-C 1
Be EaFA-L06-1316-T02-C 1
Be EaFA-L06-1316-T03-C 1
Be EaFA-L06-1316-T04-C 1
Be EaFA-L06-1316-T05-C 1
Be EaFA-L06-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 6.9E+02 1.9E+00 6.0E+00
9.50E-01 5.2E+03 1.9E+00 6.0E+00 10 300
9.50E-01 6.3E+02 1.9E+00 6.0E+00
9.50E-01 7.2E+01 1.9E+00 6.0E+00
9.50E-01 5.8E+01 1.9E+00 6.0E+00
9.50E-01 3.5E+02 1.9E+00 6.0E+00
9.50E-01 4.3E+02 1.9E+00 6.0E+00 10 300
9.50E-01 9.9E+02 1.9E+00 6.0E+00
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
9.50E-01 2.6E+01 1.9E+00 6.0E+00 10 300
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00
9.50E-01 1.2E+01 1.9E+00 6.0E+00
9.50E-01 4.1E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.13E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.29E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.10E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1053
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-L06-1316-T01-A 1
Cd EaFA-L06-1316-T02-A 1
Cd EaFA-L06-1316-T03-A 1
Cd EaFA-L06-1316-T04-A 1
Cd EaFA-L06-1316-T05-A 1
Cd EaFA-L06-1316-T01-B 1
Cd EaFA-L06-1316-T02-B 1
Cd EaFA-L06-1316-T03-B 1
Cd EaFA-L06-1316-T04-B 1
Cd EaFA-L06-1316-T05-B 1
Cd EaFA-L06-1316-T01-C 1
Cd EaFA-L06-1316-T02-C 1
Cd EaFA-L06-1316-T03-C 1
Cd EaFA-L06-1316-T04-C 1
Cd EaFA-L06-1316-T05-C 1
Cd EaFA-L06-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
1.10E+00 U1/2
3.25E+00 E
6.37E+00 E
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
6.02E+00 E
1.10E+00 U1/2
2.92E+00 E
1.10E+00 U1/2
3.08E+00 E
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 2.9E+01 2.2E+00 7.0E+00
3.25E+00 1.9E+01 2.2E+00 7.0E+00 10 300
6.37E+00 1.2E+01 2.2E+00 7.0E+00
1.10E+00 2.4E+02 2.2E+00 7.0E+00
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 6.0E+01 2.2E+00 7.0E+00
1.10E+00 2.2E+01 2.2E+00 7.0E+00 10 300
6.02E+00 8.6E+00 2.2E+00 7.0E+00
1.10E+00 2.4E+01 2.2E+00 7.0E+00
2.92E+00 9.7E+00 2.2E+00 7.0E+00
1.10E+00 1.2E+02 2.2E+00 7.0E+00
3.08E+00 3.0E+01 2.2E+00 7.0E+00 10 300
1.10E+00 1.1E+01 2.2E+00 7.0E+00
1.10E+00 1.5E+01 2.2E+00 7.0E+00
1.10E+00 1.7E+01 2.2E+00 7.0E+00
1.10E+00 5.4E+00 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.08E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.23E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1054
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca EaFA-L06-1316-T01-A 1
Ca EaFA-L06-1316-T02-A 1
Ca EaFA-L06-1316-T03-A 1
Ca EaFA-L06-1316-T04-A 1
Ca EaFA-L06-1316-T05-A 1
Ca EaFA-L06-1316-T01-B 1
Ca EaFA-L06-1316-T02-B 1
Ca EaFA-L06-1316-T03-B 1
Ca EaFA-L06-1316-T04-B 1
Ca EaFA-L06-1316-T05-B 1
Ca EaFA-L06-1316-T01-C 1
Ca EaFA-L06-1316-T02-C 1
Ca EaFA-L06-1316-T03-C 1
Ca EaFA-L06-1316-T04-C 1
Ca EaFA-L06-1316-T05-C 1
Ca EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.59E+05
3.06E+05
7.27E+05
5.06E+05
4.39E+05
1.63E+05
3.42E+05
7.75E+05
6.31 E+05
5.64E+05
1.92E+05
3.44E+05
7.24E+05
5.80E+05
5.67E+05
2.09E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+05 7.5E-01 2.6E+00 8.3E+00
3.06E+05 5.8E-01 2.6E+00 8.3E+00 1000 100
7.27E+05 4.9E-01 2.6E+00 8.3E+00
5.06E+05 9.6E+00 2.6E+00 8.3E+00
4.39E+05 1.3E+01 2.6E+00 8.3E+00
1.63E+05 6.8E-01 2.6E+00 8.3E+00
3.42E+05 5.8E-01 2.6E+00 8.3E+00 1000 100
7.75E+05 1.8E+00 2.6E+00 8.3E+00
6.31 E+05 8.3E-01 2.6E+00 8.3E+00
5.64E+05 5.0E-01 2.6E+00 8.3E+00
1.92E+05 1.9E+00 2.6E+00 8.3E+00
3.44E+05 7.7E-01 2.6E+00 8.3E+00 1000 100
7.24E+05 1.4E+00 2.6E+00 8.3E+00
5.80E+05 9.8E-01 2.6E+00 8.3E+00
5.67E+05 6.1E-01 2.6E+00 8.3E+00
2.09E+01 3.1E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.07E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.43E+05 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.45E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1055
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr EaFA-L06-1316-T01-A 1
Cr EaFA-L06-1316-T02-A 1
Cr EaFA-L06-1316-T03-A 1
Cr EaFA-L06-1316-T04-A 1
Cr EaFA-L06-1316-T05-A 1
Cr EaFA-L06-1316-T01-B 1
Cr EaFA-L06-1316-T02-B 1
Cr EaFA-L06-1316-T03-B 1
Cr EaFA-L06-1316-T04-B 1
Cr EaFA-L06-1316-T05-B 1
Cr EaFA-L06-1316-T01-C 1
Cr EaFA-L06-1316-T02-C 1
Cr EaFA-L06-1316-T03-C 1
Cr EaFA-L06-1316-T04-C 1
Cr EaFA-L06-1316-T05-C 1
Cr EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
6.66E+00
8.79E+00
1.55E+01
5.25E+01
5.34E+01
1.52E+01
1.24E+01
2.14E+01
8.21E+01
3.66E+01
1.61E+01
1.17E+01
3.21E+01
7.46E+01
9.52E+01
6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.66E+00 3.9E+00 1.2E+00 3.8E+00
8.79E+00 7.4E+00 1.2E+00 3.8E+00 10 300
1.55E+01 4.1E+00 1.2E+00 3.8E+00
5.25E+01 1.1E+01 1.2E+00 3.8E+00
5.34E+01 1.3E+01 1.2E+00 3.8E+00
1.52E+01 9.3E+00 1.2E+00 3.8E+00
1.24E+01 4.0E+00 1.2E+00 3.8E+00 10 300
2.14E+01 1.0E+01 1.2E+00 3.8E+00
8.21 E+01 1.9E+00 1.2E+00 3.8E+00
3.66E+01 2.7E+00 1.2E+00 3.8E+00
1.61 E+01 1.1 E+01 1.2E+00 3.8E+00
1.17E+01 1.2E+01 1.2E+00 3.8E+00 10 300
3.21E+01 2.5E+00 1.2E+00 3.8E+00
7.46E+01 2.1E+00 1.2E+00 3.8E+00
9.52E+01 2.9E+00 1.2E+00 3.8E+00
6.00E-01 3.3E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.18E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.25E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1056
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone.
1 ug/L
Co EaFA-L06-1316-T01-A 1 8.93E+01
Co EaFA-L06-1316-T02-A 1 1.51 E+02
Co EaFA-L06-1316-T03-A 1 2.61E+02
Co EaFA-L06-1316-T04-A 1 9.23E+01
Co EaFA-L06-1316-T05-A 1 9.43E+01
Co EaFA-L06-1316-T01-B 1 5.99E+01
Co EaFA-L06-1316-T02-B 1 1.34E+02
Co EaFA-L06-1316-T03-B 1 2.39E+02
Co EaFA-L06-1316-T04-B 1 8.94E+01
Co EaFA-L06-1316-T05-B 1 2.07E+02
Co EaFA-L06-1316-T01-C 1 7.25E+01
Co EaFA-L06-1316-T02-C 1 1.63E+02
Co EaFA-L06-1316-T03-C 1 1.40E+02
Co EaFA-L06-1316-T04-C 1 7.52E+01
Co EaFA-L06-1316-T05-C 1 1.94E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
8.93E+01 2.7E+00 1.8E+00 5.7E+00
1.51 E+02 1.9E+00 1.8E+00 5.7E+00 10 300
2.61 E+02 6.0E-01 1.8E+00 5.7E+00
9.23E+01 9.5E+00 1.8E+00 5.7E+00
9.43E+01 1.2E+01 1.8E+00 5.7E+00
5.99E+01 4.1E+00 1.8E+00 5.7E+00
1.34E+02 3.0E+00 1.8E+00 5.7E+00 10 300
2.39E+02 2.7E+00 1.8E+00 5.7E+00
8.94E+01 1.1E+00 1.8E+00 5.7E+00
2.07E+02 2.3E+00 1.8E+00 5.7E+00
7.25E+01 1.2E+00 1.8E+00 5.7E+00
1.63E+02 2.1E+00 1.8E+00 5.7E+00 10 300
1.40E+02 9.1E-01 1.8E+00 5.7E+00
7.52E+01 2.7E+00 1.8E+00 5.7E+00
1.94E+01 5.7E+00 1.8E+00 5.7E+00
Co EaFA-L06-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 1.7E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.30E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1057
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFA-L06-1316-T01-A 1
Cu EaFA-L06-1316-T02-A 1
Cu EaFA-L06-1316-T03-A 1
Cu EaFA-L06-1316-T04-A 1
Cu EaFA-L06-1316-T05-A 1
Cu EaFA-L06-1316-T01-B 1
Cu EaFA-L06-1316-T02-B 1
Cu EaFA-L06-1316-T03-B 1
Cu EaFA-L06-1316-T04-B 1
Cu EaFA-L06-1316-T05-B 1
Cu EaFA-L06-1316-T01-C 1
Cu EaFA-L06-1316-T02-C 1
Cu EaFA-L06-1316-T03-C 1
Cu EaFA-L06-1316-T04-C 1
Cu EaFA-L06-1316-T05-C 1
Cu EaFA-L06-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
5.31 E+00 E
3.81E+01
1.04E+01 E
7.09E+00 E
1.85E+00 U1/2
5.33E+00 E
4.17E+00 E
7.03E+00 E
1.32E+01
1.33E+01
4.48E+00 E
9.53E+00 E
6.91 E+00 E
6.45E+00 E
1.39E+01
1.85E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.31E+00 5.1E+01 3.7E+00 1.2E+01
3.81E+01 9.0E+00 3.7E+00 1.2E+01 10 300
1.04E+01 5.3E+01 3.7E+00 1.2E+01
7.09E+00 5.2E+01 3.7E+00 1.2E+01
1.85E+00 2.4E+01 3.7E+00 1.2E+01
5.33E+00 8.5E+01 3.7E+00 1.2E+01
4.17E+00 8.4E+01 3.7E+00 1.2E+01 10 300
7.03E+00 8.2E+01 3.7E+00 1.2E+01
1.32E+01 4.2E+01 3.7E+00 1.2E+01
1.33E+01 1.9E+01 3.7E+00 1.2E+01
4.48E+00 8.8E+01 3.7E+00 1.2E+01
9.53E+00 3.7E+01 3.7E+00 1.2E+01 10 300
6.91 E+00 1.1E+02 3.7E+00 1.2E+01
6.45E+00 3.8E+01 3.7E+00 1.2E+01
1.39E+01 3.1E+01 3.7E+00 1.2E+01
1.85E+00 7.7E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.24E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.31E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.12E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1058
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L06-1316-T01-A 1
Fe EaFA-L06-1316-T02-A 1
Fe EaFA-L06-1316-T03-A 1
Fe EaFA-L06-1316-T04-A 1
Fe EaFA-L06-1316-T05-A 1
Fe EaFA-L06-1316-T01-B 1
Fe EaFA-L06-1316-T02-B 1
Fe EaFA-L06-1316-T03-B 1
Fe EaFA-L06-1316-T04-B 1
Fe EaFA-L06-1316-T05-B 1
Fe EaFA-L06-1316-T01-C 1
Fe EaFA-L06-1316-T02-C 1
Fe EaFA-L06-1316-T03-C 1
Fe EaFA-L06-1316-T04-C 1
Fe EaFA-L06-1316-T05-C 1
Fe EaFA-L06-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L | |
2 22E+00 E
3.04E+00 E
2.69E+00 E
2.42E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
2.18E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.82E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
2.40E+01
l.OOE+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2 22E+00 8 9E+00 2 OE+00 6 4E+00
3.04E+00 2.2E+01 2.0E+00 6.4E+00 1000 100
2.69E+00 1.3E+00 2.0E+00 6.4E+00
2.42E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
2.18E+00 8.3E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+00 2.0E+00 6.4E+00
1.00E+00 7.2E+00 2.0E+00 6.4E+00
2.82E+00 1.2E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
2.40E+01 1.3E+01 2.0E+00 6.4E+00
l.OOE+00 8.8E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.97E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3'44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1059
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L06-1316-T01-A 1
Pb EaFA-L06-1316-T02-A 1
Pb EaFA-L06-1316-T03-A 1
Pb EaFA-L06-1316-T04-A 1
Pb EaFA-L06-1316-T05-A 1
Pb EaFA-L06-1316-T01-B 1
Pb EaFA-L06-1316-T02-B 1
Pb EaFA-L06-1316-T03-B 1
Pb EaFA-L06-1316-T04-B 1
Pb EaFA-L06-1316-T05-B 1
Pb EaFA-L06-1316-T01-C 1
Pb EaFA-L06-1316-T02-C 1
Pb EaFA-L06-1316-T03-C 1
Pb EaFA-L06-1316-T04-C 1
Pb EaFA-L06-1316-T05-C 1
Pb EaFA-L06-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 3.8E+01 6.8E+00 2.2E+01
3.40E+00 8.4E+01 6.8E+00 2.2E+01 10 300
3.40E+00 3.4E+01 6.8E+00 2.2E+01
3.40E+00 5.2E+01 6.8E+00 2.2E+01
3.40E+00 2.4E+01 6.8E+00 2.2E+01
3.40E+00 3.5E+01 6.8E+00 2.2E+01
3.40E+00 3.5E+00 6.8E+00 2.2E+01 10 300
3.40E+00 4.2E+01 6.8E+00 2.2E+01
3.40E+00 7.9E+01 6.8E+00 2.2E+01
3.40E+00 2.9E+01 6.8E+00 2.2E+01
3.40E+00 7.0E+01 6.8E+00 2.2E+01
3.40E+00 6.1E+01 6.8E+00 2.2E+01 10 300
3.40E+00 3.1E+01 6.8E+00 2.2E+01
3.40E+00 9.4E+00 6.8E+00 2.2E+01
3.40E+00 3.1E+01 6.8E+00 2.2E+01
3.40E+00 3.1E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.20E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1060
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFA-L06-1316-T01-A 1
Li EaFA-L06-1316-T02-A 1
Li EaFA-L06-1316-T03-A 1
Li EaFA-L06-1316-T04-A 1
Li EaFA-L06-1316-T05-A 1
Li EaFA-L06-1316-T01-B 1
Li EaFA-L06-1316-T02-B 1
Li EaFA-L06-1316-T03-B 1
Li EaFA-L06-1316-T04-B 1
Li EaFA-L06-1316-T05-B 1
Li EaFA-L06-1316-T01-C 1
Li EaFA-L06-1316-T02-C 1
Li EaFA-L06-1316-T03-C 1
Li EaFA-L06-1316-T04-C 1
Li EaFA-L06-1316-T05-C 1
Li EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.74E+03
7.05E+03
1.70E+04
2.92E+04
5.25E+04
3.83E+03
7.75E+03
1.80E+04
3.58E+04
7.03E+04
4.58E+03
7.85E+03
1.67E+04
3.33E+04
5.60E+04
9.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.74E+03 6.7E-01 1.9E+00 6.0E+00
7.05E+03 5.7E-01 1.9E+00 6.0E+00 10 300
1.70E+04 8.3E-01 1.9E+00 6.0E+00
2.92E+04 9.6E+00 1.9E+00 6.0E+00
5.25E+04 1.3E+01 1.9E+00 6.0E+00
3.83E+03 1.2E-01 1.9E+00 6.0E+00
7.75E+03 7.2E-01 1.9E+00 6.0E+00 10 300
1.80E+04 2.1E+00 1.9E+00 6.0E+00
3.58E+04 1.0E+00 1.9E+00 6.0E+00
7.03E+04 4.3E-01 1.9E+00 6.0E+00
4.58E+03 1.3E+00 1.9E+00 6.0E+00
7.85E+03 4.8E-01 1.9E+00 6.0E+00 10 300
1.67E+04 1.6E+00 1.9E+00 6.0E+00
3.33E+04 8.7E-01 1.9E+00 6.0E+00
5.60E+04 4.7E-01 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.91 E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .04E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .06E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1061
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone.
1 1 ug/L
Mn EaFA-L06-1316-T01-A 1 5.12E+02
Mn EaFA-L06-1316-T02-A 1 8.94E+02
Mn EaFA-L06-1316-T03-A 1 1.69E+03
Mn EaFA-L06-1316-T04-A 1 8.66E+02
Mn EaFA-L06-1316-T05-A 1 1.11E+03
Mn EaFA-L06-1316-T01-B 1 4.01E+02
Mn EaFA-L06-1316-T02-B 1 8.39E+02
Mn EaFA-L06-1316-T03-B 1 1.57E+03
Mn EaFA-L06-1316-T04-B 1 8.89E+02
Mn EaFA-L06-1316-T05-B 1 2.17E+03
Mn EaFA-L06-1316-T01-C 1 4.47E+02
Mn EaFA-L06-1316-T02-C 1 9.48E+02
Mn EaFA-L06-1316-T03-C 1 1.15E+03
Mn EaFA-L06-1316-T04-C 1 7.97E+02
Mn EaFA-L06-1316-T05-C 1 3.64E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.12E+02 1.5E+00 2.0E+00 6.4E+00
8.94E+02 1.3E+00 2.0E+00 6.4E+00 10 300
1.69E+03 3.2E-01 2.0E+00 6.4E+00
8.66E+02 1.6E+01 2.0E+00 6.4E+00
1.11E+03 1.0E+01 2.0E+00 6.4E+00
4.01 E+02 8.3E-01 2.0E+00 6.4E+00
8.39E+02 6.4E-01 2.0E+00 6.4E+00 10 300
1.57E+03 2.3E+00 2.0E+00 6.4E+00
8.89E+02 1.5E+00 2.0E+00 6.4E+00
2.17E+03 5.6E-01 2.0E+00 6.4E+00
4.47E+02 3.4E-01 2.0E+00 6.4E+00
9.48E+02 2.2E+00 2.0E+00 6.4E+00 10 300
1.15E+03 2.4E-01 2.0E+00 6.4E+00
7.97E+02 7.9E-01 2.0E+00 6.4E+00
3.64E+02 3.3E-01 2.0E+00 6.4E+00
Mn EaFA-L06-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 1.2E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.83E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.88E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.75E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1062
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFA-L06-1316-T01-A 1
Mg EaFA-L06-1316-T02-A 1
Mg EaFA-L06-1316-T03-A 1
Mg EaFA-L06-1316-T04-A 1
Mg EaFA-L06-1316-T05-A 1
Mg EaFA-L06-1316-T01-B 1
Mg EaFA-L06-1316-T02-B 1
Mg EaFA-L06-1316-T03-B 1
Mg EaFA-L06-1316-T04-B 1
Mg EaFA-L06-1316-T05-B 1
Mg EaFA-L06-1316-T01-C 1
Mg EaFA-L06-1316-T02-C 1
Mg EaFA-L06-1316-T03-C 1
Mg EaFA-L06-1316-T04-C 1
Mg EaFA-L06-1316-T05-C 1
Mg EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
7.33E+03
1.41E+04
3.73E+04
6.09E+04
1.00E+05
7.63E+03
1.59E+04
3.96E+04
7.40E+04
1.39E+05
8.63E+03
1.60E+04
3.65E+04
6.93E+04
1.02E+05
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.33E+03 1.8E-01 1.0E+00 3.2E+00
1.41E+04 1.4E-01 1.0E+00 3.2E+00 1000 100
3.73E+04 3.7E-01 1.0E+00 3.2E+00
6.09E+04 8.8E+00 1.0E+00 3.2E+00
1.00E+05 1.3E+01 1.0E+00 3.2E+00
7.63E+03 3.3E-01 1.0E+00 3.2E+00
1.59E+04 1.2E+00 1.0E+00 3.2E+00 1000 100
3.96E+04 3.2E+00 1.0E+00 3.2E+00
7.40E+04 1.6E+00 1.0E+00 3.2E+00
1.39E+05 2.4E-01 1.0E+00 3.2E+00
8.63E+03 1.2E+00 1.0E+00 3.2E+00
1.60E+04 1.2E+00 1.0E+00 3.2E+00 1000 100
3.65E+04 7.3E-01 1.0E+00 3.2E+00
6.93E+04 1.3E+00 1.0E+00 3.2E+00
1.02E+05 4.4E-01 1.0E+00 3.2E+00
5.00E-01 8.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .50E+04 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .68E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.71E+04 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1063
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 ug/L
Mo EaFA-L06-1316-T01-A 1 3.08E+03
Mo EaFA-L06-1316-T02-A 1 5.50E+03
Mo EaFA-L06-1316-T03-A 1 1.30E+04
Mo EaFA-L06-1316-T04-A 1 2.50E+04
Mo EaFA-L06-1316-T05-A 1 4.00E+04
Mo EaFA-L06-1316-T01-B 1 3.32E+03
Mo EaFA-L06-1316-T02-B 1 6.30E+03
Mo EaFA-L06-1316-T03-B 1 1.38E+04
Mo EaFA-L06-1316-T04-B 1 3.12E+04
Mo EaFA-L06-1316-T05-B 1 4.68E+04
Mo EaFA-L06-1316-T01-C 1 3.49E+03
Mo EaFA-L06-1316-T02-C 1 6.16E+03
Mo EaFA-L06-1316-T03-C 1 1.43E+04
Mo EaFA-L06-1316-T04-C 1 2.91E+04
Mo EaFA-L06-1316-T05-C 1 5.63E+04
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.08E+03 1.2E+00 1.2E+00 3.8E+00
5.50E+03 3.9E-01 1.2E+00 3.8E+00 10 300
1.30E+04 9.9E-01 1.2E+00 3.8E+00
2.50E+04 9.1 E+00 1.2E+00 3.8E+00
4.00E+04 1.3E+01 1.2E+00 3.8E+00
3.32E+03 9.7E-02 1.2E+00 3.8E+00
6.30E+03 7.2E-01 1.2E+00 3.8E+00 10 300
1.38E+04 1.4E+00 1.2E+00 3.8E+00
3.12E+04 9.8E-01 1.2E+00 3.8E+00
4.68E+04 4.1E-01 1.2E+00 3.8E+00
3.49E+03 6.6E-01 1.2E+00 3.8E+00
6.16E+03 2.4E-01 1.2E+00 3.8E+00 10 300
1.43E+04 1.1 E+00 1.2E+00 3.8E+00
2.91 E+04 9.5E-01 1.2E+00 3.8E+00
5.63E+04 5.9E-01 1.2E+00 3.8E+00
Mo EaFA-L06-1316-B01-A 1 2.41 E+00 E 2.41E+00 1.1E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.28E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.77E+03 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.83E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1064
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFA-L06-1316-T01-A 1
Ni EaFA-L06-1316-T02-A 1
Ni EaFA-L06-1316-T03-A 1
Ni EaFA-L06-1316-T04-A 1
Ni EaFA-L06-1316-T05-A 1
Ni EaFA-L06-1316-T01-B 1
Ni EaFA-L06-1316-T02-B 1
Ni EaFA-L06-1316-T03-B 1
Ni EaFA-L06-1316-T04-B 1
Ni EaFA-L06-1316-T05-B 1
Ni EaFA-L06-1316-T01-C 1
Ni EaFA-L06-1316-T02-C 1
Ni EaFA-L06-1316-T03-C 1
Ni EaFA-L06-1316-T04-C 1
Ni EaFA-L06-1316-T05-C 1
Ni EaFA-L06-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.04E+02
3.51 E+02
6.06E+02
2.34E+02
2.35E+02
1.47E+02
3.17E+02
5.36E+02
2.10E+02
4.74E+02
1.72E+02
3.66E+02
3.32E+02
1.89E+02
7.26E+01
2.37E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.04E+02 2.0E+00 1.8E+00 5.7E+00
3.51E+02 8.7E-01 1.8E+00 5.7E+00 10 300
6.06E+02 1.7E+00 1.8E+00 5.7E+00
2.34E+02 1.1E+01 1.8E+00 5.7E+00
2.35E+02 1.3E+01 1.8E+00 5.7E+00
1.47E+02 2.7E+00 1.8E+00 5.7E+00
3.17E+02 2.1E+00 1.8E+00 5.7E+00 10 300
5.36E+02 2.1E+00 1.8E+00 5.7E+00
2.10E+02 2.0E+00 1.8E+00 5.7E+00
4.74E+02 3.2E-01 1.8E+00 5.7E+00
1.72E+02 3.9E+00 1.8E+00 5.7E+00
3.66E+02 2.1E+00 1.8E+00 5.7E+00 10 300
3.32E+02 1.3E+00 1.8E+00 5.7E+00
1.89E+02 3.0E+00 1.8E+00 5.7E+00
7.26E+01 1.8E+00 1.8E+00 5.7E+00
2.37E+00 2.0E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.50E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.52E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.37E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1065
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P EaFA-L06-1316-T01-A 1
P EaFA-L06-1316-T02-A 1
P EaFA-L06-1316-T03-A 1
P EaFA-L06-1316-T04-A 1
P EaFA-L06-1316-T05-A 1
P EaFA-L06-1316-T01-B 1
P EaFA-L06-1316-T02-B 1
P EaFA-L06-1316-T03-B 1
P EaFA-L06-1316-T04-B 1
P EaFA-L06-1316-T05-B 1
P EaFA-L06-1316-T01-C 1
P EaFA-L06-1316-T02-C 1
P EaFA-L06-1316-T03-C 1
P EaFA-L06-1316-T04-C 1
P EaFA-L06-1316-T05-C 1
P EaFA-L06-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
6.45E+01
6.36E+01
9.74E+01
9.30E+01
1.19E+02
6.66E+01
5.85E+01
9.51 E+01
2.85E+02
1.52E+02
8.45E+01
1.06E+02
2.97E+02
5.90E+02
1.77E+02
4.12E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.45E+01 5.1E+00 3.7E+00 1.2E+01
6.36E+01 2.4E+01 3.7E+00 1 .2E+01 1000 100
9.74E+01 6.3E+00 3.7E+00 1 .2E+01
9.30E+01 1.8E+01 3.7E+00 1 .2E+01
1.19E+02 1.3E+01 3.7E+00 1 .2E+01
6.66E+01 7.5E+00 3.7E+00 1 .2E+01
5.85E+01 1.7E+01 3.7E+00 1.2E+01 1000 100
9.51 E+01 1.6E+01 3.7E+00 1.2E+01
2.85E+02 2.5E+00 3.7E+00 1.2E+01
1.52E+02 6.4E+00 3.7E+00 1.2E+01
8.45E+01 7.4E+00 3.7E+00 1.2E+01
1.06E+02 5.3E+00 3.7E+00 1.2E+01 1000 100
2.97E+02 6.6E-01 3.7E+00 1.2E+01
5.90E+02 2.2E+00 3.7E+00 1.2E+01
1.77E+02 8.6E+00 3.7E+00 1.2E+01
4.12E+01 1.0E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .01 E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .09E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .03E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1066
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
1 ug/L
K EaFA-L06-1316-T01-A 1 2.57E+04
K EaFA-L06-1316-T02-A 1 5.16E+04
K EaFA-L06-1316-T03-A 1 1.29E+05
K EaFA-L06-1316-T04-A 1 1.81E+05
K EaFA-L06-1316-T05-A 1 2.71E+05
K EaFA-L06-1316-T01-B 1 2.62E+04
K EaFA-L06-1316-T02-B 1 5.66E+04
K EaFA-L06-1316-T03-B 1 1.39E+05
K EaFA-L06-1316-T04-B 1 2.19E+05
K EaFA-L06-1316-T05-B 1 3.52E+05
K EaFA-L06-1316-T01-C 1 3.25E+04
K EaFA-L06-1316-T02-C 1 5.70E+04
K EaFA-L06-1316-T03-C 1 1.29E+05
K EaFA-L06-1316-T04-C 1 2.02E+05
K EaFA-L06-1316-T05-C 1 3.01 E+05
K EaFA-L06-1316-B01-A 1 1.30E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.57E+04 1.2E+00 1.6E+00 5.1E+00
5.16E+04 6.0E-01 1.6E+00 5.1E+00 1000 100
1.29E+05 2.7E-01 1.6E+00 5.1E+00
1.81 E+05 7.7E+00 1.6E+00 5.1E+00
2.71 E+05 1.2E+01 1.6E+00 5.1E+00
2.62E+04 1.0E+00 1.6E+00 5.1E+00
5.66E+04 8.4E-01 1.6E+00 5.1E+00 1000 100
1.39E+05 2.8E+00 1.6E+00 5.1E+00
2.19E+05 1.1E+00 1.6E+00 5.1E+00
3.52E+05 7.8E-01 1.6E+00 5.1E+00
3.25E+04 1.2E+00 1.6E+00 5.1E+00
5.70E+04 5.3E-01 1.6E+00 5.1E+00 1000 100
1.29E+05 1.7E+00 1.6E+00 5.1E+00
2.02E+05 9.2E-01 1.6E+00 5.1E+00
3.01 E+05 7.2E-01 1.6E+00 5.1E+00
1.30E+01 1.4E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.25E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.74E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.78E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1067
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se EaFA-L06-1316-T01-A 1
Se EaFA-L06-1316-T02-A 1
Se EaFA-L06-1316-T03-A 1
Se EaFA-L06-1316-T04-A 1
Se EaFA-L06-1316-T05-A 1
Se EaFA-L06-1316-T01-B 1
Se EaFA-L06-1316-T02-B 1
Se EaFA-L06-1316-T03-B 1
Se EaFA-L06-1316-T04-B 1
Se EaFA-L06-1316-T05-B 1
Se EaFA-L06-1316-T01-C 1
Se EaFA-L06-1316-T02-C 1
Se EaFA-L06-1316-T03-C 1
Se EaFA-L06-1316-T04-C 1
Se EaFA-L06-1316-T05-C 1
Se EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
9.93E+02
1.11E+03
1.34E+03
1.82E+03
2.17E+03
1.18E+03
1.26E+03
1.38E+03
2.26E+03
2.48E+03
1.26E+03
1.26E+03
1.54E+03
2.22E+03
4.84E+03
2.23E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.93E+02 3.9E+00 1.5E+01 4.8E+01
1.11E+03 5.4E+00 1.5E+01 4.8E+01 10 300
1.34E+03 1.7E+00 1.5E+01 4.8E+01
1.82E+03 1.1E+01 1.5E+01 4.8E+01
2.17E+03 1.3E+01 1.5E+01 4.8E+01
1.18E+03 1.8E+00 1.5E+01 4.8E+01
1.26E+03 3.2E+00 1.5E+01 4.8E+01 10 300
1.38E+03 4.5E+00 1.5E+01 4.8E+01
2.26E+03 2.4E+00 1.5E+01 4.8E+01
2.48E+03 1.7E+00 1.5E+01 4.8E+01
1.26E+03 2.8E+00 1.5E+01 4.8E+01
1.26E+03 2.3E+00 1.5E+01 4.8E+01 10 300
1.54E+03 3.0E+00 1.5E+01 4.8E+01
2.22E+03 2.4E+00 1.5E+01 4.8E+01
4.84E+03 1.7E+00 1.5E+01 4.8E+01
2.23E+01 1.5E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.21E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.44E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.25E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1068
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si EaFA-L06-1316-T01-A 1
Si EaFA-L06-1316-T02-A 1
Si EaFA-L06-1316-T03-A 1
Si EaFA-L06-1316-T04-A 1
Si EaFA-L06-1316-T05-A 1
Si EaFA-L06-1316-T01-B 1
Si EaFA-L06-1316-T02-B 1
Si EaFA-L06-1316-T03-B 1
Si EaFA-L06-1316-T04-B 1
Si EaFA-L06-1316-T05-B 1
Si EaFA-L06-1316-T01-C 1
Si EaFA-L06-1316-T02-C 1
Si EaFA-L06-1316-T03-C 1
Si EaFA-L06-1316-T04-C 1
Si EaFA-L06-1316-T05-C 1
Si EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.53E+03
3.91 E+03
3.54E+03
1.85E+03
1.65E+03
2.82E+03
3.40E+03
3.05E+03
1.91 E+03
3.33E+03
2.99E+03
3.82E+03
2.36E+03
1.75E+03
2.85E+03
5.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.53E+03 7.1E-01 1.1E+00 3.5E+00
3.91E+03 6.5E-01 1.1E+00 3.5E+00 1000 100
3.54E+03 8.6E-01 1.1E+00 3.5E+00
1.85E+03 9.9E+00 1.1E+00 3.5E+00
1.65E+03 1.3E+01 1.1E+00 3.5E+00
2.82E+03 3.2E-01 1.1E+00 3.5E+00
3.40E+03 8.3E-01 1.1E+00 3.5E+00 1000 100
3.05E+03 1.9E+00 1.1E+00 3.5E+00
1.91 E+03 4.9E-01 1.1E+00 3.5E+00
3.33E+03 8.5E-01 1.1E+00 3.5E+00
2.99E+03 9.3E-01 1.1E+00 3.5E+00
3.82E+03 3.6E-01 1.1E+00 3.5E+00 1000 100
2.36E+03 1.6E+00 1.1E+00 3.5E+00
1.75E+03 1.7E+00 1.1E+00 3.5E+00
2.85E+03 4.9E+00 1.1E+00 3.5E+00
5.50E-01 7.2E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.79E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.33E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.70E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1069
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFA-L06-1316-T01-A 1
Na EaFA-L06-1316-T02-A 1
Na EaFA-L06-1316-T03-A 1
Na EaFA-L06-1316-T04-A 1
Na EaFA-L06-1316-T05-A 1
Na EaFA-L06-1316-T01-B 1
Na EaFA-L06-1316-T02-B 1
Na EaFA-L06-1316-T03-B 1
Na EaFA-L06-1316-T04-B 1
Na EaFA-L06-1316-T05-B 1
Na EaFA-L06-1316-T01-C 1
Na EaFA-L06-1316-T02-C 1
Na EaFA-L06-1316-T03-C 1
Na EaFA-L06-1316-T04-C 1
Na EaFA-L06-1316-T05-C 1
Na EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
5.22E+03
1.05E+04
2.64E+04
3.90E+04
6.17E+04
5.34E+03
1.17E+04
2.89E+04
4.97E+04
8.21 E+04
6.88E+03
1.18E+04
2.72E+04
4.53E+04
6.87E+04
2.25E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.22E+03 1.0E+00 2.5E+00 8.0E+00
1.05E+04 8.9E-01 2.5E+00 8.0E+00 1000 100
2.64E+04 2.4E-01 2.5E+00 8.0E+00
3.90E+04 9.3E+00 2.5E+00 8.0E+00
6.17E+04 1.2E+01 2.5E+00 8.0E+00
5.34E+03 6.6E-01 2.5E+00 8.0E+00
1.17E+04 3.3E-01 2.5E+00 8.0E+00 1000 100
2.89E+04 1.8E+00 2.5E+00 8.0E+00
4.97E+04 6.9E-01 2.5E+00 8.0E+00
8.21 E+04 7.2E-01 2.5E+00 8.0E+00
6.88E+03 1.5E+00 2.5E+00 8.0E+00
1.18E+04 1.2E+00 2.5E+00 8.0E+00 1000 100
2.72E+04 1.4E+00 2.5E+00 8.0E+00
4.53E+04 1.8E+00 2.5E+00 8.0E+00
6.87E+04 7.0E-01 2.5E+00 8.0E+00
2.25E+01 1.0E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.13E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .27E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .27E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1070
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
EaFA-L06-1316-T01-A 1
EaFA-L06-1316-T02-A 1
EaFA-L06-1316-T03-A 1
EaFA-L06-1316-T04-A 1
EaFA-L06-1316-T05-A 1
EaFA-L06-1316-T01-B 1
EaFA-L06-1316-T02-B 1
EaFA-L06-1316-T03-B 1
EaFA-L06-1316-T04-B 1
EaFA-L06-1316-T05-B 1
EaFA-L06-1316-T01-C 1
EaFA-L06-1316-T02-C 1
EaFA-L06-1316-T03-C 1
EaFA-L06-1316-T04-C 1
EaFA-L06-1316-T05-C 1
EaFA-L06-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.15E+03
3.86E+03
8.59E+03
7.94E+03
7.01 E+03
2.21 E+03
4.15E+03
8.80E+03
9.67E+03
9.03E+03
2.43E+03
4.29E+03
7.85E+03
9.10E+03
7.85E+03
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.15E+03 1.8E+00 1.0E+00 3.2E+00
3.86E+03 2.1E-01 1.0E+00 3.2E+00 1000 100
8.59E+03 3.0E-01 1.0E+00 3.2E+00
7.94E+03 8.9E+00 1.0E+00 3.2E+00
7.01 E+03 1.1E+01 1.0E+00 3.2E+00
2.21 E+03 1.4E+00 1.0E+00 3.2E+00
4.15E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
8.80E+03 2.0E+00 1.0E+00 3.2E+00
9.67E+03 1.6E+00 1.0E+00 3.2E+00
9.03E+03 4.4E-01 1.0E+00 3.2E+00
2.43E+03 3.7E-01 1.0E+00 3.2E+00
4.29E+03 7.7E-01 1.0E+00 3.2E+00 1000 100
7.85E+03 6.5E-01 1.0E+00 3.2E+00
9.10E+03 1.1E+00 1.0E+00 3.2E+00
7.85E+03 4.7E-01 1.0E+00 3.2E+00
5.00E-01 7.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.75E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.20E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.17E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1071
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
1 ug/L
S EaFA-L06-1316-T01-A 1 1.69E+05
S EaFA-L06-1316-T02-A 1 3.25E+05
S EaFA-L06-1316-T03-A 1 7.77E+05
S EaFA-L06-1316-T04-A 1 7.22E+05
S EaFA-L06-1316-T05-A 1 8.58E+05
S EaFA-L06-1316-T01-B 1 1.72E+05
S EaFA-L06-1316-T02-B 1 3.55E+05
S EaFA-L06-1316-T03-B 1 8.24E+05
S EaFA-L06-1316-T04-B 1 8.62E+05
S EaFA-L06-1316-T05-B 1 1.12E+06
S EaFA-L06-1316-T01-C 1 1.95E+05
S EaFA-L06-1316-T02-C 1 3.57E+05
S EaFA-L06-1316-T03-C 1 7.64E+05
S EaFA-L06-1316-T04-C 1 8.35E+05
S EaFA-L06-1316-T05-C 1 9.67E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.69E+05 7.2E-01 6.8E+00 2.2E+01
3.25E+05 3.3E-01 6.8E+00 2.2E+01 1000 100
7.77E+05 4.4E-01 6.8E+00 2.2E+01
7.22E+05 9.0E+00 6.8E+00 2.2E+01
8.58E+05 1.3E+01 6.8E+00 2.2E+01
1.72E+05 3.6E-01 6.8E+00 2.2E+01
3.55E+05 9.2E-01 6.8E+00 2.2E+01 1000 100
8.24E+05 2.2E+00 6.8E+00 2.2E+01
8.62E+05 1.1E+00 6.8E+00 2.2E+01
1.12E+06 1.9E-01 6.8E+00 2.2E+01
1.95E+05 1.0E+00 6.8E+00 2.2E+01
3.57E+05 4.9E-01 6.8E+00 2.2E+01 1000 100
7.64E+05 1.6E+00 6.8E+00 2.2E+01
8.35E+05 1.8E+00 6.8E+00 2.2E+01
9.67E+05 8.1E-01 6.8E+00 2.2E+01
S EaFA-L06-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 1.5E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.17E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.37E+05 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.55E+05 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1072
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-L06-1316-T01-A 1
Tl EaFA-L06-1316-T02-A 1
Tl EaFA-L06-1316-T03-A 1
Tl EaFA-L06-1316-T04-A 1
Tl EaFA-L06-1316-T05-A 1
Tl EaFA-L06-1316-T01-B 1
Tl EaFA-L06-1316-T02-B 1
Tl EaFA-L06-1316-T03-B 1
Tl EaFA-L06-1316-T04-B 1
Tl EaFA-L06-1316-T05-B 1
Tl EaFA-L06-1316-T01-C 1
Tl EaFA-L06-1316-T02-C 1
Tl EaFA-L06-1316-T03-C 1
Tl EaFA-L06-1316-T04-C 1
Tl EaFA-L06-1316-T05-C 1
Tl EaFA-L06-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
7.99E+00 E
1.19E+01 E
9.05E+00 E
1.79E+01
2.30E+00 U1/2
2.30E+00 U1/2
3.11E+01
3.52E+01
3.88E+01
2.30E+00 U1/2
8.62E+00 E
1.24E+01 E
1.34E+01 E
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 1.8E+03 4.6E+00 1.5E+01
7.99E+00 1.4E+02 4.6E+00 1 .5E+01 10 300
1.19E+01 1.4E+02 4.6E+00 1 .5E+01
9.05E+00 1.1E+02 4.6E+00 1 .5E+01
1.79E+01 5.3E+01 4.6E+00 1 .5E+01
2.30E+00 1.4E+02 4.6E+00 1 .5E+01
2.30E+00 7.0E+02 4.6E+00 1 .5E+01 10 300
3.11E+01 3.7E+01 4.6E+00 1.5E+01
3.52E+01 4.1E+01 4.6E+00 1.5E+01
3.88E+01 3.5E+01 4.6E+00 1.5E+01
2.30E+00 3.1E+02 4.6E+00 1.5E+01
8.62E+00 2.2E+01 4.6E+00 1.5E+01 10 300
1.24E+01 9.5E+01 4.6E+00 1.5E+01
1.34E+01 5.7E+01 4.6E+00 1.5E+01
2.30E+00 4.4E+02 4.6E+00 1.5E+01
2.30E+00 4.2E+01 4.6E+00 1 .5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.19E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1073
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Ti Sample Dilution Cone. Qualifier Review
ug/L
Ti EaFA-L06-1316-T01-A 1 1 OOE+00 U1/2
Ti EaFA-L06-1316-T02-A 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T03-A 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T04-A 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T05-A 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T01-B 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T02-B 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T03-B 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T04-B 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T05-B 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T01-C 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T02-C 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T03-C 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T04-C 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-T05-C 1 1. OOE+00 U1/2
Ti EaFA-L06-1316-B01-A 1 l.OOE+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1 OOE+00 5 4E+01 2 OE+00 6 4E+00
1. OOE+00 5.8E+01 2.0E+00 6.4E+00 10 300
1. OOE+00 2.7E+01 2.0E+00 6.4E+00
1. OOE+00 5.5E+01 2.0E+00 6.4E+00
1. OOE+00 4.5E+01 2.0E+00 6.4E+00
1. OOE+00 2.2E+02 2.0E+00 6.4E+00
1. OOE+00 6.9E+01 2.0E+00 6.4E+00 10 300
1. OOE+00 2.4E+01 2.0E+00 6.4E+00
1. OOE+00 1.6E+01 2.0E+00 6.4E+00
1. OOE+00 5.8E+00 2.0E+00 6.4E+00
1. OOE+00 1.6E+03 2.0E+00 6.4E+00
1. OOE+00 2.9E+01 2.0E+00 6.4E+00 10 300
1. OOE+00 6.5E+01 2.0E+00 6.4E+00
1. OOE+00 3.0E+01 2.0E+00 6.4E+00
1. OOE+00 1.0E+01 2.0E+00 6.4E+00
l.OOE+00 1.4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP OES
3.19E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.34E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.13E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3'44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1074
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFA-L06-1316-T01-A 1
V EaFA-L06-1316-T02-A 1
V EaFA-L06-1316-T03-A 1
V EaFA-L06-1316-T04-A 1
V EaFA-L06-1316-T05-A 1
V EaFA-L06-1316-T01-B 1
V EaFA-L06-1316-T02-B 1
V EaFA-L06-1316-T03-B 1
V EaFA-L06-1316-T04-B 1
V EaFA-L06-1316-T05-B 1
V EaFA-L06-1316-T01-C 1
V EaFA-L06-1316-T02-C 1
V EaFA-L06-1316-T03-C 1
V EaFA-L06-1316-T04-C 1
V EaFA-L06-1316-T05-C 1
V EaFA-L06-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.43E+02
2.73E+02
3.43E+02
3.18E+02
3.07E+02
2.62E+02
2.85E+02
3.29E+02
3.75E+02
4.09E+02
2.55E+02
2.86E+02
3.36E+02
3.43E+02
5.91 E+02
7.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.43E+02 5.1E-01 1.5E+00 4.8E+00
2.73E+02 8.2E-01 1.5E+00 4.8E+00 10 300
3.43E+02 7.0E-01 1.5E+00 4.8E+00
3.18E+02 8.1E+00 1.5E+00 4.8E+00
3.07E+02 1.3E+01 1.5E+00 4.8E+00
2.62E+02 9.5E-01 1.5E+00 4.8E+00
2.85E+02 9.5E-01 1.5E+00 4.8E+00 10 300
3.29E+02 1.7E+00 1.5E+00 4.8E+00
3.75E+02 4.9E-01 1.5E+00 4.8E+00
4.09E+02 1.3E+00 1.5E+00 4.8E+00
2.55E+02 2.8E+00 1.5E+00 4.8E+00
2.86E+02 9.7E-01 1.5E+00 4.8E+00 10 300
3.36E+02 2.8E+00 1.5E+00 4.8E+00
3.43E+02 6.2E-01 1.5E+00 4.8E+00
5.91 E+02 1.3E+00 1.5E+00 4.8E+00
7.50E-01 1.5E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.42E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.56E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.37E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3:44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1075
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Zn Sample Dilution Cone. Qualifier Review
ug/L
Zn EaFA-L06-1316-T01-A 1 5 76E+01
Zn EaFA-L06-1316-T02-A 1 7.16E+01
Zn EaFA-L06-1316-T03-A 1 6.89E+01
Zn EaFA-L06-1316-T04-A 1 3.21E+01
Zn EaFA-L06-1316-T05-A 1 3.58E+01
Zn EaFA-L06-1316-T01-B 1 2.29E+01
Zn EaFA-L06-1316-T02-B 1 4.64E+01
Zn EaFA-L06-1316-T03-B 1 5.69E+01
Zn EaFA-L06-1316-T04-B 1 2.20E+01
Zn EaFA-L06-1316-T05-B 1 5.62E+01
Zn EaFA-L06-1316-T01-C 1 3.22E+01
Zn EaFA-L06-1316-T02-C 1 6.59E+01
Zn EaFA-L06-1316-T03-C 1 2.90E+01
Zn EaFA-L06-1316-T04-C 1 1.88E+01
Zn EaFA-L06-1316-T05-C 1 2.33E+01
Zn EaFA-L06-1316-B01-A 1 9.40E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5 76E+01 3 4E+00 1 OE+00 3 2E+00
7.16E+01 2.8E+00 1.0E+00 3.2E+00 10 300
6.89E+01 2.3E+00 1. OE+00 3.2E+00
3.21 E+01 1.2E+01 1. OE+00 3.2E+00
3.58E+01 1.2E+01 1. OE+00 3.2E+00
2.29E+01 2.9E+00 1. OE+00 3.2E+00
4.64E+01 8.8E-01 1. OE+00 3.2E+00 10 300
5.69E+01 3.0E+00 1. OE+00 3.2E+00
2.20E+01 6.6E+00 1. OE+00 3.2E+00
5.62E+01 2.9E+00 1. OE+00 3.2E+00
3.22E+01 4.3E+00 1. OE+00 3.2E+00
6.59E+01 9.6E-01 1. OE+00 3.2E+00 10 300
2.90E+01 4.3E+00 1. OE+00 3.2E+00
1.88E+01 5.0E+00 1. OE+00 3.2E+00
2.33E+01 2.2E+00 1. OE+00 3.2E+00
9.40E+00 5.0E+00 1. OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP OES
3.37E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.46E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.29E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/10 3'44 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:46 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:47 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:49 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:50 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:52 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:27 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:29 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:30 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:32 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:33 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:35 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:37 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:38 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 4:40 PM EPA Interlab L06 1313-1316 EaFA
6/7/10 3:41 PM EPA Interlab L06 1313-1316 EaFA
                                                                                                                                                                         1-1076
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al EaFA-L07-1316-T01-A 1
Al EaFA-L07-1316-T02-A 1
Al EaFA-L07-1316-T03-A 1
Al EaFA-L07-1316-T04-A 1
Al EaFA-L07-1316-T05-A 1
Al EaFA-L07-1316-T01-B 1
Al EaFA-L07-1316-T02-B 1
Al EaFA-L07-1316-T03-B 1
Al EaFA-L07-1316-T04-B 1
Al EaFA-L07-1316-T05-B 1
Al EaFA-L07-1316-T01-C 1
Al EaFA-L07-1316-T02-C 1
Al EaFA-L07-1316-T03-C 1
Al EaFA-L07-1316-T04-C 1
Al EaFA-L07-1316-T05-C 1
Al EaFA-L07-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.66E+02
1.60E+02
2.43E+02
4.68E+02
9.10E+02
1.21E+02
1.46E+02
2.21E+02
4.41 E+02
1.23E+03
1.10E+02
1.60E+02
2.34E+02
5.02E+02
8.14E+02
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.66E+02 1.8E+00 1.0E+00 3.2E+00
1.60E+02 1.7E+00 1.0E+00 3.2E+00 1000 100
2.43E+02 3.6E+00 1.0E+00 3.2E+00
4.68E+02 4.3E-01 1.0E+00 3.2E+00
9.10E+02 7.2E-01 1.0E+00 3.2E+00
1.21 E+02 1.1E+00 1.0E+00 3.2E+00
1.46E+02 3.9E+00 1.0E+00 3.2E+00 1000 100
2.21E+02 2.6E+00 1.0E+00 3.2E+00
4.41 E+02 7.8E-01 1.0E+00 3.2E+00
1.23E+03 1.9E+00 1.0E+00 3.2E+00
1.10E+02 3.0E+00 1.0E+00 3.2E+00
1.60E+02 2.6E+00 1.0E+00 3.2E+00 1000 100
2.34E+02 1.2E+00 1.0E+00 3.2E+00
5.02E+02 7.6E-01 1.0E+00 3.2E+00
8.14E+02 8.4E-01 1.0E+00 3.2E+00
5.00E-01 1.6E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.26E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                                 1-1077
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L07-1316-T01-A 1
Sb EaFA-L07-1316-T02-A 1
Sb EaFA-L07-1316-T03-A 1
Sb EaFA-L07-1316-T04-A 1
Sb EaFA-L07-1316-T05-A 1
Sb EaFA-L07-1316-T01-B 1
Sb EaFA-L07-1316-T02-B 1
Sb EaFA-L07-1316-T03-B 1
Sb EaFA-L07-1316-T04-B 1
Sb EaFA-L07-1316-T05-B 1
Sb EaFA-L07-1316-T01-C 1
Sb EaFA-L07-1316-T02-C 1
Sb EaFA-L07-1316-T03-C 1
Sb EaFA-L07-1316-T04-C 1
Sb EaFA-L07-1316-T05-C 1
Sb EaFA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.05E+02
3.08E+02
4.69E+02
6.58E+02
7.86E+02
2.15E+02
3.39E+02
4.60E+02
6.41 E+02
7.86E+02
2.01 E+02
3.28E+02
4.59E+02
6.64E+02
6.80E+02
1.06E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.05E+02 4.3E+00 7.5E+00 2.4E+01
3.08E+02 1.2E+01 7.5E+00 2.4E+01 10 300
4.69E+02 8.1E-01 7.5E+00 2.4E+01
6.58E+02 2.8E+00 7.5E+00 2.4E+01
7.86E+02 6.0E+00 7.5E+00 2.4E+01
2.15E+02 1.4E+01 7.5E+00 2.4E+01
3.39E+02 6.9E+00 7.5E+00 2.4E+01 10 300
4.60E+02 2.7E+00 7.5E+00 2.4E+01
6.41 E+02 4.2E+00 7.5E+00 2.4E+01
7.86E+02 3.7E-01 7.5E+00 2.4E+01
2.01 E+02 1.7E+01 7.5E+00 2.4E+01
3.28E+02 6.8E+00 7.5E+00 2.4E+01 10 300
4.59E+02 4.6E+00 7.5E+00 2.4E+01
6.64E+02 2.2E+00 7.5E+00 2.4E+01
6.80E+02 1.3E+00 7.5E+00 2.4E+01
1.06E+01 6.2E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.51E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.56E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.46E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1078
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As EaFA-L07-1316-T01-A 1
As EaFA-L07-1316-T02-A 1
As EaFA-L07-1316-T03-A 1
As EaFA-L07-1316-T04-A 1
As EaFA-L07-1316-T05-A 1
As EaFA-L07-1316-T01-B 1
As EaFA-L07-1316-T02-B 1
As EaFA-L07-1316-T03-B 1
As EaFA-L07-1316-T04-B 1
As EaFA-L07-1316-T05-B 1
As EaFA-L07-1316-T01-C 1
As EaFA-L07-1316-T02-C 1
As EaFA-L07-1316-T03-C 1
As EaFA-L07-1316-T04-C 1
As EaFA-L07-1316-T05-C 1
As EaFA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.40E+02
1.23E+02
1.33E+02
1.93E+02
2.96E+02
1.20E+02
1.36E+02
1.35E+02
1.72E+02
2.53E+02
1.10E+02
1.29E+02
1.54E+02
2.17E+02
1.91E+02
5.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.40E+02 8.4E+00 1.1E+01 3.5E+01
1.23E+02 1.3E+01 1.1E+01 3.5E+01 10 300
1.33E+02 5.5E+00 1.1E+01 3.5E+01
1.93E+02 1.2E+00 1.1E+01 3.5E+01
2.96E+02 9.6E+00 1.1E+01 3.5E+01
1.20E+02 1.3E+01 1.1E+01 3.5E+01
1.36E+02 8.7E+00 1.1E+01 3.5E+01 10 300
1.35E+02 2.3E+01 1.1E+01 3.5E+01
1.72E+02 2.2E+00 1.1E+01 3.5E+01
2.53E+02 5.7E+00 1.1E+01 3.5E+01
1.10E+02 6.2E+00 1.1E+01 3.5E+01
1.29E+02 7.5E+00 1.1E+01 3.5E+01 10 300
1.54E+02 1.7E+01 1.1E+01 3.5E+01
2.17E+02 3.8E+00 1.1E+01 3.5E+01
1.91E+02 3.2E-01 1.1E+01 3.5E+01
5.50E+00 2.9E+02 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.38E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.31E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1079
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone.
ug/L
B EaFA-L07-1316-T01-A 1 4.25E+03
B EaFA-L07-1316-T02-A 1 8.37E+03
B EaFA-L07-1316-T03-A 1 2.02E+04
B EaFA-L07-1316-T04-A 1 3.61E+04
B EaFA-L07-1316-T05-A 1 5.41E+04
B EaFA-L07-1316-T01-B 1 5.30E+03
B EaFA-L07-1316-T02-B 1 8.76E+03
B EaFA-L07-1316-T03-B 1 1.96E+04
B EaFA-L07-1316-T04-B 1 3.55E+04
B EaFA-L07-1316-T05-B 1 6.42E+04
B EaFA-L07-1316-T01-C 1 4.18E+03
B EaFA-L07-1316-T02-C 1 9.26E+03
B EaFA-L07-1316-T03-C 1 2.10E+04
B EaFA-L07-1316-T04-C 1 3.73E+04
B EaFA-L07-1316-T05-C 1 5.59E+04
B EaFA-L07-1316-B01-A 1 3.55E+01
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.25E+03 4.2E-01 1.0E+00 3.2E+00
8.37E+03 6.0E-01 1.0E+00 3.2E+00 1000 100
2.02E+04 3.5E+00 1.0E+00 3.2E+00
3.61 E+04 7.1E-01 1.0E+00 3.2E+00
5.41 E+04 2.0E+00 1.0E+00 3.2E+00
5.30E+03 2.2E+00 1.0E+00 3.2E+00
8.76E+03 9.2E-01 1.0E+00 3.2E+00 1000 100
1.96E+04 1.7E+00 1.0E+00 3.2E+00
3.55E+04 1.6E+00 1.0E+00 3.2E+00
6.42E+04 1.9E+00 1.0E+00 3.2E+00
4.18E+03 1.3E+00 1.0E+00 3.2E+00
9.26E+03 6.5E-01 1.0E+00 3.2E+00 1000 100
2.10E+04 1.8E+00 1.0E+00 3.2E+00
3.73E+04 1.2E+00 1.0E+00 3.2E+00
5.59E+04 8.2E-01 1.0E+00 3.2E+00
3.55E+01 6.8E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.38E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.70E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .01 E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1080
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone.
ug/L
Ba EaFA-L07-1316-T01-A 1 2.69E+02
Ba EaFA-L07-1316-T02-A 1 2.18E+02
Ba EaFA-L07-1316-T03-A 1 2.06E+02
Ba EaFA-L07-1316-T04-A 1 2.15E+02
Ba EaFA-L07-1316-T05-A 1 2.41 E+02
Ba EaFA-L07-1316-T01-B 1 2.85E+02
Ba EaFA-L07-1316-T02-B 1 2.13E+02
Ba EaFA-L07-1316-T03-B 1 1.91 E+02
Ba EaFA-L07-1316-T04-B 1 2.16E+02
Ba EaFA-L07-1316-T05-B 1 2.86E+02
Ba EaFA-L07-1316-T01-C 1 2.67E+02
Ba EaFA-L07-1316-T02-C 1 2.16E+02
Ba EaFA-L07-1316-T03-C 1 2.06E+02
Ba EaFA-L07-1316-T04-C 1 2.17E+02
Ba EaFA-L07-1316-T05-C 1 2.26E+02
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.69E+02 3.6E-01 1.0E+00 3.2E+00
2.18E+02 7.1E-02 1.0E+00 3.2E+00 10 300
2.06E+02 3.8E+00 1.0E+00 3.2E+00
2.15E+02 2.4E-01 1.0E+00 3.2E+00
2.41 E+02 1.3E+00 1.0E+00 3.2E+00
2.85E+02 3.7E-01 1.0E+00 3.2E+00
2.13E+02 5.7E-01 1.0E+00 3.2E+00 10 300
1.91 E+02 2.9E+00 1.0E+00 3.2E+00
2.16E+02 5.3E-01 1.0E+00 3.2E+00
2.86E+02 1.7E+00 1.0E+00 3.2E+00
2.67E+02 2.1E+00 1.0E+00 3.2E+00
2.16E+02 3.5E-01 1.0E+00 3.2E+00 10 300
2.06E+02 9.9E-01 1.0E+00 3.2E+00
2.17E+02 5.6E-01 1.0E+00 3.2E+00
2.26E+02 4.1E-01 1.0E+00 3.2E+00
Ba EaFA-L07-1316-B01-A 1 5.00E-01 U1/2 5.00E-01 5.9E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.23E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.19E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.16E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1081
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L07-1316-T01-A 1
Be EaFA-L07-1316-T02-A 1
Be EaFA-L07-1316-T03-A 1
Be EaFA-L07-1316-T04-A 1
Be EaFA-L07-1316-T05-A 1
Be EaFA-L07-1316-T01-B 1
Be EaFA-L07-1316-T02-B 1
Be EaFA-L07-1316-T03-B 1
Be EaFA-L07-1316-T04-B 1
Be EaFA-L07-1316-T05-B 1
Be EaFA-L07-1316-T01-C 1
Be EaFA-L07-1316-T02-C 1
Be EaFA-L07-1316-T03-C 1
Be EaFA-L07-1316-T04-C 1
Be EaFA-L07-1316-T05-C 1
Be EaFA-L07-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 8.5E+01 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00 10 300
9.50E-01 6.3E+02 1.9E+00 6.0E+00
9.50E-01 2.2E+04 1.9E+00 6.0E+00
9.50E-01 9.9E+01 1.9E+00 6.0E+00
9.50E-01 2.4E+02 1.9E+00 6.0E+00
9.50E-01 3.0E+03 1.9E+00 6.0E+00 10 300
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 7.9E+01 1.9E+00 6.0E+00
9.50E-01 8.4E+00 1.9E+00 6.0E+00
9.50E-01 6.3E+02 1.9E+00 6.0E+00
9.50E-01 4.0E+01 1.9E+00 6.0E+00 10 300
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 6.7E+02 1.9E+00 6.0E+00
9.50E-01 2.3E+01 1.9E+00 6.0E+00
9.50E-01 2.5E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.27E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.26E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.22E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1082
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-L07-1316-T01-A 1
Cd EaFA-L07-1316-T02-A 1
Cd EaFA-L07-1316-T03-A 1
Cd EaFA-L07-1316-T04-A 1
Cd EaFA-L07-1316-T05-A 1
Cd EaFA-L07-1316-T01-B 1
Cd EaFA-L07-1316-T02-B 1
Cd EaFA-L07-1316-T03-B 1
Cd EaFA-L07-1316-T04-B 1
Cd EaFA-L07-1316-T05-B 1
Cd EaFA-L07-1316-T01-C 1
Cd EaFA-L07-1316-T02-C 1
Cd EaFA-L07-1316-T03-C 1
Cd EaFA-L07-1316-T04-C 1
Cd EaFA-L07-1316-T05-C 1
Cd EaFA-L07-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.10E+00 U1/2
1.10E+00 U1/2
2.57E+00 E
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
2.95E+00 E
1.10E+00 U1/2
6.60E+00 E
1.10E+00 U1/2
1.10E+00 U1/2
3.45E+00 E
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 2.1E+00 2.2E+00 7.0E+00
1.10E+00 5.8E+02 2.2E+00 7.0E+00 10 300
2.57E+00 2.7E+01 2.2E+00 7.0E+00
1.10E+00 5.3E+01 2.2E+00 7.0E+00
1.10E+00 4.2E+01 2.2E+00 7.0E+00
1.10E+00 4.3E+00 2.2E+00 7.0E+00
1.10E+00 2.7E+02 2.2E+00 7.0E+00 10 300
2.95E+00 3.1E+01 2.2E+00 7.0E+00
1.10E+00 8.7E+01 2.2E+00 7.0E+00
6.60E+00 1.9E+01 2.2E+00 7.0E+00
1.10E+00 5.2E+01 2.2E+00 7.0E+00
1.10E+00 4.0E+01 2.2E+00 7.0E+00 10 300
3.45E+00 9.9E+00 2.2E+00 7.0E+00
1.10E+00 3.8E+03 2.2E+00 7.0E+00
1.10E+00 1.8E+01 2.2E+00 7.0E+00
1.10E+00 2.4E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.24E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.19E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1083
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
ug/L
Ca EaFA-L07-1316-T01-A 1 1.64E+05
Ca EaFA-L07-1316-T02-A 1 3.18E+05
Ca EaFA-L07-1316-T03-A 1 7.46E+05
Ca EaFA-L07-1316-T04-A 1 5.77E+05
Ca EaFA-L07-1316-T05-A 1 5.17E+05
Ca EaFA-L07-1316-T01-B 1 1.59E+05
Ca EaFA-L07-1316-T02-B 1 3.14E+05
Ca EaFA-L07-1316-T03-B 1 6.75E+05
Ca EaFA-L07-1316-T04-B 1 5.66E+05
Ca EaFA-L07-1316-T05-B 1 5.18E+05
Ca EaFA-L07-1316-T01-C 1 1.59E+05
Ca EaFA-L07-1316-T02-C 1 3.35E+05
Ca EaFA-L07-1316-T03-C 1 7.65E+05
Ca EaFA-L07-1316-T04-C 1 5.91 E+05
Ca EaFA-L07-1316-T05-C 1 5.21E+05
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.64E+05 4.9E-01 2.6E+00 8.3E+00
3.18E+05 2.2E-01 2.6E+00 8.3E+00 1000 100
7.46E+05 3.4E+00 2.6E+00 8.3E+00
5.77E+05 3.3E-01 2.6E+00 8.3E+00
5.17E+05 1.2E+00 2.6E+00 8.3E+00
1.59E+05 5.4E-01 2.6E+00 8.3E+00
3.14E+05 1.1E-01 2.6E+00 8.3E+00 1000 100
6.75E+05 2.0E+00 2.6E+00 8.3E+00
5.66E+05 2.7E-01 2.6E+00 8.3E+00
5.18E+05 1.8E+00 2.6E+00 8.3E+00
1.59E+05 2.3E+00 2.6E+00 8.3E+00
3.35E+05 7.1E-01 2.6E+00 8.3E+00 1000 100
7.65E+05 9.5E-01 2.6E+00 8.3E+00
5.91 E+05 1.2E-01 2.6E+00 8.3E+00
5.21 E+05 6.1E-01 2.6E+00 8.3E+00
Ca EaFA-L07-1316-B01-A 1 6.24E+00 E 6.24E+00 2.4E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.19E+05 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.15E+05 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.36E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1084
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qu
ug/L
Cr EaFA-L07-1316-T01-A 1 1.26E+01
Cr EaFA-L07-1316-T02-A 1 1.33E+01
Cr EaFA-L07-1316-T03-A 1 2.04E+01
Cr EaFA-L07-1316-T04-A 1 4.17E+01
Cr EaFA-L07-1316-T05-A 1 9.24E+01
Cr EaFA-L07-1316-T01-B 1 9.72E+00
Cr EaFA-L07-1316-T02-B 1 1.63E+01
Cr EaFA-L07-1316-T03-B 1 1.81E+01
Cr EaFA-L07-1316-T04-B 1 4.22E+01
Cr EaFA-L07-1316-T05-B 1 9.07E+01
Cr EaFA-L07-1316-T01-C 1 8.97E+00
Cr EaFA-L07-1316-T02-C 1 1.50E+01
Cr EaFA-L07-1316-T03-C 1 2.14E+01
Cr EaFA-L07-1316-T04-C 1 4.67E+01
Cr EaFA-L07-1316-T05-C 1 5.91 E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.26E+01 7.1E+00 1.2E+00 3.8E+00
1.33E+01 9.8E+00 1.2E+00 3.8E+00 10 300
2.04E+01 7.8E+00 1.2E+00 3.8E+00
4.17E+01 2.7E+00 1.2E+00 3.8E+00
9.24E+01 3.6E-01 1.2E+00 3.8E+00
9.72E+00 3.1E+00 1.2E+00 3.8E+00
1.63E+01 8.6E+00 1.2E+00 3.8E+00 10 300
1.81 E+01 8.2E+00 1.2E+00 3.8E+00
4.22E+01 5.7E+00 1.2E+00 3.8E+00
9.07E+01 2.2E+00 1.2E+00 3.8E+00
8.97E+00 1.5E+01 1.2E+00 3.8E+00
1.50E+01 7.2E+00 1.2E+00 3.8E+00 10 300
2.14E+01 5.7E+00 1.2E+00 3.8E+00
4.67E+01 2.9E+00 1.2E+00 3.8E+00
5.91E+01 2.1E+00 1.2E+00 3.8E+00
Cr EaFA-L07-1316-B01-A 1 6.00E-01 U1/2 6.00E-01 2.9E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.23E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.16E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.14E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1085
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qu
ug/L
Co EaFA-L07-1316-T01-A 1 3.90E+01
Co EaFA-L07-1316-T02-A 1 9.97E+01
Co EaFA-L07-1316-T03-A 1 1.91E+02
Co EaFA-L07-1316-T04-A 1 1.08E+02
Co EaFA-L07-1316-T05-A 1 7.85E+01
Co EaFA-L07-1316-T01-B 1 5.56E+01
Co EaFA-L07-1316-T02-B 1 1.01E+02
Co EaFA-L07-1316-T03-B 1 1.88E+02
Co EaFA-L07-1316-T04-B 1 1.26E+02
Co EaFA-L07-1316-T05-B 1 2.50E+02
Co EaFA-L07-1316-T01-C 1 6.37E+01
Co EaFA-L07-1316-T02-C 1 1.08E+02
Co EaFA-L07-1316-T03-C 1 2.15E+02
Co EaFA-L07-1316-T04-C 1 9.97E+01
Co EaFA-L07-1316-T05-C 1 1.18E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.90E+01 6.3E+00 1.8E+00 5.7E+00
9.97E+01 1.6E+00 1.8E+00 5.7E+00 10 300
1.91E+02 3.3E+00 1.8E+00 5.7E+00
1.08E+02 1.1E+00 1.8E+00 5.7E+00
7.85E+01 2.9E+00 1.8E+00 5.7E+00
5.56E+01 4.3E+00 1.8E+00 5.7E+00
1.01E+02 2.3E+00 1.8E+00 5.7E+00 10 300
1.88E+02 2.8E+00 1.8E+00 5.7E+00
1.26E+02 2.1E+00 1.8E+00 5.7E+00
2.50E+02 2.6E+00 1.8E+00 5.7E+00
6.37E+01 9.2E+00 1.8E+00 5.7E+00
1.08E+02 9.2E-01 1.8E+00 5.7E+00 10 300
2.15E+02 2.0E+00 1.8E+00 5.7E+00
9.97E+01 3.6E+00 1.8E+00 5.7E+00
1.18E+02 2.1E+00 1.8E+00 5.7E+00
Co EaFA-L07-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 6.9E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.27E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.22E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1086
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qu
ug/L
Cu EaFA-L07-1316-T01-A 1 1.11E+01 E
Cu EaFA-L07-1316-T02-A 1 1.28E+01
Cu EaFA-L07-1316-T03-A 1 1.70E+01
Cu EaFA-L07-1316-T04-A 1 1.77E+01
Cu EaFA-L07-1316-T05-A 1 1.80E+01
Cu EaFA-L07-1316-T01-B 1 1.40E+01
Cu EaFA-L07-1316-T02-B 1 1.80E+01
Cu EaFA-L07-1316-T03-B 1 1.98E+01
Cu EaFA-L07-1316-T04-B 1 2.05E+01
Cu EaFA-L07-1316-T05-B 1 4.78E+01
Cu EaFA-L07-1316-T01-C 1 1.48E+01
Cu EaFA-L07-1316-T02-C 1 2.40E+01
Cu EaFA-L07-1316-T03-C 1 1.47E+01
Cu EaFA-L07-1316-T04-C 1 2.05E+01
Cu EaFA-L07-1316-T05-C 1 2.13E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.11E+01 6.1E+01 3.7E+00 1.2E+01
1.28E+01 8.3E+00 3.7E+00 1.2E+01 10 300
1.70E+01 1.4E+01 3.7E+00 1.2E+01
1.77E+01 6.8E+00 3.7E+00 1.2E+01
1.80E+01 3.7E+01 3.7E+00 1.2E+01
1.40E+01 4.5E+00 3.7E+00 1.2E+01
1.80E+01 3.1E+01 3.7E+00 1.2E+01 10 300
1.98E+01 9.3E+00 3.7E+00 1.2E+01
2.05E+01 9.7E+00 3.7E+00 1.2E+01
4.78E+01 1.1E+01 3.7E+00 1.2E+01
1.48E+01 2.8E+01 3.7E+00 1.2E+01
2.40E+01 3.1E+01 3.7E+00 1.2E+01 10 300
1.47E+01 1.3E+01 3.7E+00 1.2E+01
2.05E+01 3.2E+01 3.7E+00 1.2E+01
2.13E+01 1.5E+01 3.7E+00 1.2E+01
Cu EaFA-L07-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 3.0E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.25E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.20E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.16E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1087
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L07-1316-T01-A 1
Fe EaFA-L07-1316-T02-A 1
Fe EaFA-L07-1316-T03-A 1
Fe EaFA-L07-1316-T04-A 1
Fe EaFA-L07-1316-T05-A 1
Fe EaFA-L07-1316-T01-B 1
Fe EaFA-L07-1316-T02-B 1
Fe EaFA-L07-1316-T03-B 1
Fe EaFA-L07-1316-T04-B 1
Fe EaFA-L07-1316-T05-B 1
Fe EaFA-L07-1316-T01-C 1
Fe EaFA-L07-1316-T02-C 1
Fe EaFA-L07-1316-T03-C 1
Fe EaFA-L07-1316-T04-C 1
Fe EaFA-L07-1316-T05-C 1
Fe EaFA-L07-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.26E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
5.74E+01
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
9.00E+00
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
2.26E+00 8.9E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
5.74E+01 5.7E-02 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.0E+01 2.0E+00 6.4E+00
1.00E+00 3.5E+00 2.0E+00 6.4E+00
9.00E+00 9.3E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1088
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L07-1316-T01-A 1
Pb EaFA-L07-1316-T02-A 1
Pb EaFA-L07-1316-T03-A 1
Pb EaFA-L07-1316-T04-A 1
Pb EaFA-L07-1316-T05-A 1
Pb EaFA-L07-1316-T01-B 1
Pb EaFA-L07-1316-T02-B 1
Pb EaFA-L07-1316-T03-B 1
Pb EaFA-L07-1316-T04-B 1
Pb EaFA-L07-1316-T05-B 1
Pb EaFA-L07-1316-T01-C 1
Pb EaFA-L07-1316-T02-C 1
Pb EaFA-L07-1316-T03-C 1
Pb EaFA-L07-1316-T04-C 1
Pb EaFA-L07-1316-T05-C 1
Pb EaFA-L07-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 3.0E+01 6.8E+00 2.2E+01
3.40E+00 5.9E+01 6.8E+00 2.2E+01 10 300
3.40E+00 2.0E+01 6.8E+00 2.2E+01
3.40E+00 2.1E+01 6.8E+00 2.2E+01
3.40E+00 1.8E+01 6.8E+00 2.2E+01
3.40E+00 3.8E+00 6.8E+00 2.2E+01
3.40E+00 1.7E+01 6.8E+00 2.2E+01 10 300
3.40E+00 1.1E+01 6.8E+00 2.2E+01
3.40E+00 6.0E+01 6.8E+00 2.2E+01
3.40E+00 2.2E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 6.6E+01 6.8E+00 2.2E+01 10 300
3.40E+00 2.2E+01 6.8E+00 2.2E+01
3.40E+00 9.1E+01 6.8E+00 2.2E+01
3.40E+00 3.7E+01 6.8E+00 2.2E+01
3.40E+00 1.7E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.10E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.08E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.05E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1089
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFA-L07-1316-T01-A 1
Li EaFA-L07-1316-T02-A 1
Li EaFA-L07-1316-T03-A 1
Li EaFA-L07-1316-T04-A 1
Li EaFA-L07-1316-T05-A 1
Li EaFA-L07-1316-T01-B 1
Li EaFA-L07-1316-T02-B 1
Li EaFA-L07-1316-T03-B 1
Li EaFA-L07-1316-T04-B 1
Li EaFA-L07-1316-T05-B 1
Li EaFA-L07-1316-T01-C 1
Li EaFA-L07-1316-T02-C 1
Li EaFA-L07-1316-T03-C 1
Li EaFA-L07-1316-T04-C 1
Li EaFA-L07-1316-T05-C 1
Li EaFA-L07-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.51 E+03
6.73E+03
1.60E+04
3.16E+04
5.11E+04
3.48E+03
6.68E+03
1.47E+04
3.03E+04
5.93E+04
3.51 E+03
7.05E+03
1.64E+04
3.26E+04
5.55E+04
1.46E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.51 E+03 2.7E-01 1.9E+00 6.0E+00
6.73E+03 2.1E-01 1.9E+00 6.0E+00 10 300
1.60E+04 3.5E+00 1.9E+00 6.0E+00
3.16E+04 3.3E-01 1.9E+00 6.0E+00
5.11E+04 9.6E-01 1.9E+00 6.0E+00
3.48E+03 2.3E-01 1.9E+00 6.0E+00
6.68E+03 5.6E-01 1.9E+00 6.0E+00 10 300
1.47E+04 1.9E+00 1.9E+00 6.0E+00
3.03E+04 5.4E-01 1.9E+00 6.0E+00
5.93E+04 2.0E+00 1.9E+00 6.0E+00
3.51E+03 2.1E+00 1.9E+00 6.0E+00
7.05E+03 2.0E-01 1.9E+00 6.0E+00 10 300
1.64E+04 1.4E+00 1.9E+00 6.0E+00
3.26E+04 2.9E-01 1.9E+00 6.0E+00
5.55E+04 4.1E-01 1.9E+00 6.0E+00
1.46E+01 3.8E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.56E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.30E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.53E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1090
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFA-L07-1316-T01-A 1
Mn EaFA-L07-1316-T02-A 1
Mn EaFA-L07-1316-T03-A 1
Mn EaFA-L07-1316-T04-A 1
Mn EaFA-L07-1316-T05-A 1
Mn EaFA-L07-1316-T01-B 1
Mn EaFA-L07-1316-T02-B 1
Mn EaFA-L07-1316-T03-B 1
Mn EaFA-L07-1316-T04-B 1
Mn EaFA-L07-1316-T05-B 1
Mn EaFA-L07-1316-T01-C 1
Mn EaFA-L07-1316-T02-C 1
Mn EaFA-L07-1316-T03-C 1
Mn EaFA-L07-1316-T04-C 1
Mn EaFA-L07-1316-T05-C 1
Mn EaFA-L07-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.37E+02
7.62E+02
1.42E+03
1.12E+03
9.68E+02
4.17E+02
7.36E+02
1.38E+03
1.28E+03
2.02E+03
4.48E+02
7.99E+02
1.54E+03
1.09E+03
1.39E+03
1.00E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.37E+02 5.8E-01 2.0E+00 6.4E+00
7.62E+02 3.5E-01 2.0E+00 6.4E+00 10 300
1.42E+03 2.4E+00 2.0E+00 6.4E+00
1.12E+03 9.2E-01 2.0E+00 6.4E+00
9.68E+02 1.3E+00 2.0E+00 6.4E+00
4.17E+02 4.2E-01 2.0E+00 6.4E+00
7.36E+02 9.4E-01 2.0E+00 6.4E+00 10 300
1.38E+03 2.4E+00 2.0E+00 6.4E+00
1.28E+03 1.2E+00 2.0E+00 6.4E+00
2.02E+03 1.7E+00 2.0E+00 6.4E+00
4.48E+02 1.5E+00 2.0E+00 6.4E+00
7.99E+02 3.9E-01 2.0E+00 6.4E+00 10 300
1.54E+03 1.6E+00 2.0E+00 6.4E+00
1.09E+03 1.1E+00 2.0E+00 6.4E+00
1.39E+03 8.4E-01 2.0E+00 6.4E+00
1.00E+00 3.5E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.96E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.90E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.90E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1091
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFA-L07-1316-T01-A 1
Mg EaFA-L07-1316-T02-A 1
Mg EaFA-L07-1316-T03-A 1
Mg EaFA-L07-1316-T04-A 1
Mg EaFA-L07-1316-T05-A 1
Mg EaFA-L07-1316-T01-B 1
Mg EaFA-L07-1316-T02-B 1
Mg EaFA-L07-1316-T03-B 1
Mg EaFA-L07-1316-T04-B 1
Mg EaFA-L07-1316-T05-B 1
Mg EaFA-L07-1316-T01-C 1
Mg EaFA-L07-1316-T02-C 1
Mg EaFA-L07-1316-T03-C 1
Mg EaFA-L07-1316-T04-C 1
Mg EaFA-L07-1316-T05-C 1
Mg EaFA-L07-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
7.32E+03
1.44E+04
3.76E+04
6.88E+04
1.00E+05
7.05E+03
1.43E+04
3.39E+04
6.61 E+04
1.20E+05
7.18E+03
1.52E+04
3.79E+04
7.12E+04
1.10E+05
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.32E+03 5.5E-01 1.0E+00 3.2E+00
1.44E+04 3.1E-01 1.0E+00 3.2E+00 1000 100
3.76E+04 3.3E+00 1.0E+00 3.2E+00
6.88E+04 3.0E-01 1.0E+00 3.2E+00
1.00E+05 8.6E-01 1.0E+00 3.2E+00
7.05E+03 9.3E-01 1.0E+00 3.2E+00
1.43E+04 6.9E-01 1.0E+00 3.2E+00 1000 100
3.39E+04 2.4E+00 1.0E+00 3.2E+00
6.61 E+04 8.3E-01 1.0E+00 3.2E+00
1.20E+05 2.0E+00 1.0E+00 3.2E+00
7.18E+03 3.2E+00 1.0E+00 3.2E+00
1.52E+04 1.1E+00 1.0E+00 3.2E+00 1000 100
3.79E+04 1.3E+00 1.0E+00 3.2E+00
7.12E+04 7.8E-01 1.0E+00 3.2E+00
1.10E+05 1.2E+00 1.0E+00 3.2E+00
5.00E-01 5.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .54E+04 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .53E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .61 E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1092
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
ug/L
Mo EaFA-L07-1316-T01-A 1 3.38E+03
Mo EaFA-L07-1316-T02-A 1 6.15E+03
Mo EaFA-L07-1316-T03-A 1 1.40E+04
Mo EaFA-L07-1316-T04-A 1 2.83E+04
Mo EaFA-L07-1316-T05-A 1 5.02E+04
Mo EaFA-L07-1316-T01-B 1 3.21E+03
Mo EaFA-L07-1316-T02-B 1 6.16E+03
Mo EaFA-L07-1316-T03-B 1 1.29E+04
Mo EaFA-L07-1316-T04-B 1 2.67E+04
Mo EaFA-L07-1316-T05-B 1 4.61 E+04
Mo EaFA-L07-1316-T01-C 1 3.18E+03
Mo EaFA-L07-1316-T02-C 1 6.34E+03
Mo EaFA-L07-1316-T03-C 1 1.41 E+04
Mo EaFA-L07-1316-T04-C 1 2.96E+04
Mo EaFA-L07-1316-T05-C 1 4.61 E+04
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.38E+03 3.8E-01 1.2E+00 3.8E+00
6.15E+03 2.1E-01 1.2E+00 3.8E+00 10 300
1.40E+04 3.7E+00 1.2E+00 3.8E+00
2.83E+04 1.5E-01 1.2E+00 3.8E+00
5.02E+04 1.2E+00 1.2E+00 3.8E+00
3.21 E+03 6.1E-01 1.2E+00 3.8E+00
6.16E+03 6.1E-01 1.2E+00 3.8E+00 10 300
1.29E+04 2.6E+00 1.2E+00 3.8E+00
2.67E+04 2.1E-01 1.2E+00 3.8E+00
4.61E+04 2.0E+00 1.2E+00 3.8E+00
3.18E+03 2.0E+00 1.2E+00 3.8E+00
6.34E+03 6.3E-01 1.2E+00 3.8E+00 10 300
1.41 E+04 1.1E+00 1.2E+00 3.8E+00
2.96E+04 3.6E-01 1.2E+00 3.8E+00
4.61 E+04 7.1E-01 1.2E+00 3.8E+00
Mo EaFA-L07-1316-B01-A 1 6.00E-01 U1/2 6.00E-01 3.5E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8.99E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.88E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.77E+03 81 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1093
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qu
ug/L
Ni EaFA-L07-1316-T01-A 1 9.90E+01
Ni EaFA-L07-1316-T02-A 1 2.39E+02
Ni EaFA-L07-1316-T03-A 1 4.42E+02
Ni EaFA-L07-1316-T04-A 1 2.65E+02
Ni EaFA-L07-1316-T05-A 1 2.11E+02
Ni EaFA-L07-1316-T01-B 1 1.36E+02
Ni EaFA-L07-1316-T02-B 1 2.43E+02
Ni EaFA-L07-1316-T03-B 1 4.40E+02
Ni EaFA-L07-1316-T04-B 1 3.06E+02
Ni EaFA-L07-1316-T05-B 1 5.65E+02
Ni EaFA-L07-1316-T01-C 1 1.50E+02
Ni EaFA-L07-1316-T02-C 1 2.54E+02
Ni EaFA-L07-1316-T03-C 1 4.91 E+02
Ni EaFA-L07-1316-T04-C 1 2.46E+02
Ni EaFA-L07-1316-T05-C 1 2.64E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.90E+01 5.7E+00 1.8E+00 5.7E+00
2.39E+02 2.1E+00 1.8E+00 5.7E+00 10 300
4.42E+02 4.4E+00 1.8E+00 5.7E+00
2.65E+02 4.4E+00 1.8E+00 5.7E+00
2. 11 E+02 1.3E+00 1.8E+00 5.7E+00
1.36E+02 1.3E+00 1.8E+00 5.7E+00
2.43E+02 9.9E-01 1.8E+00 5.7E+00 10 300
4.40E+02 2.2E+00 1.8E+00 5.7E+00
3.06E+02 5.6E-01 1.8E+00 5.7E+00
5.65E+02 9.4E-01 1.8E+00 5.7E+00
1.50E+02 2.4E+00 1.8E+00 5.7E+00
2.54E+02 1.6E+00 1.8E+00 5.7E+00 10 300
4.91 E+02 1.2E+00 1.8E+00 5.7E+00
2.46E+02 2.9E+00 1.8E+00 5.7E+00
2.64E+02 2.0E+00 1.8E+00 5.7E+00
Ni EaFA-L07-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 8.1E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.39E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.34E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.29E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1094
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P EaFA-L07-1316-T01-A 1
P EaFA-L07-1316-T02-A 1
P EaFA-L07-1316-T03-A 1
P EaFA-L07-1316-T04-A 1
P EaFA-L07-1316-T05-A 1
P EaFA-L07-1316-T01-B 1
P EaFA-L07-1316-T02-B 1
P EaFA-L07-1316-T03-B 1
P EaFA-L07-1316-T04-B 1
P EaFA-L07-1316-T05-B 1
P EaFA-L07-1316-T01-C 1
P EaFA-L07-1316-T02-C 1
P EaFA-L07-1316-T03-C 1
P EaFA-L07-1316-T04-C 1
P EaFA-L07-1316-T05-C 1
P EaFA-L07-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
3.79E+01
4.93E+01
1.04E+02
2.87E+02
2.82E+02
5.72E+01
6.36E+01
1.14E+02
3.35E+02
3.17E+02
3.50E+01
5.44E+01
1.67E+02
4.06E+02
1.16E+03
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.79E+01 1.5E+01 3.7E+00 1.2E+01
4.93E+01 1.1E+01 3.7E+00 1 .2E+01 1000 100
1.04E+02 7.5E+00 3.7E+00 1 .2E+01
2.87E+02 3.0E+00 3.7E+00 1 .2E+01
2.82E+02 5.3E+00 3.7E+00 1 .2E+01
5.72E+01 1.1E+01 3.7E+00 1 .2E+01
6.36E+01 1.8E+01 3.7E+00 1.2E+01 1000 100
1.14E+02 7.7E+00 3.7E+00 1.2E+01
3.35E+02 3.1E+00 3.7E+00 1.2E+01
3.17E+02 3.5E+00 3.7E+00 1.2E+01
3.50E+01 3.4E+01 3.7E+00 1.2E+01
5.44E+01 1.3E+01 3.7E+00 1.2E+01 1000 100
1.67E+02 9.3E+00 3.7E+00 1.2E+01
4.06E+02 7.6E+00 3.7E+00 1.2E+01
1.16E+03 3.7E+00 3.7E+00 1.2E+01
1.85E+00 5.7E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .03E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .OOE+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .02E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1095
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K EaFA-L07-1316-T01-A 1
K EaFA-L07-1316-T02-A 1
K EaFA-L07-1316-T03-A 1
K EaFA-L07-1316-T04-A 1
K EaFA-L07-1316-T05-A 1
K EaFA-L07-1316-T01-B 1
K EaFA-L07-1316-T02-B 1
K EaFA-L07-1316-T03-B 1
K EaFA-L07-1316-T04-B 1
K EaFA-L07-1316-T05-B 1
K EaFA-L07-1316-T01-C 1
K EaFA-L07-1316-T02-C 1
K EaFA-L07-1316-T03-C 1
K EaFA-L07-1316-T04-C 1
K EaFA-L07-1316-T05-C 1
K EaFA-L07-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.61 E+04
5.31 E+04
1.33E+05
2.12E+05
2.95E+05
2.57E+04
5.25E+04
1.22E+05
2.06E+05
3.51 E+05
2.56E+04
5.55E+04
1.35E+05
2.19E+05
3.22E+05
1.13E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.61 E+04 4.2E-01 1.6E+00 5.1E+00
5.31E+04 2.2E-01 1.6E+00 5.1E+00 1000 100
1.33E+05 3.7E+00 1.6E+00 5.1E+00
2.12E+05 2.3E-01 1.6E+00 5.1E+00
2.95E+05 1.3E+00 1.6E+00 5.1E+00
2.57E+04 4.4E-01 1.6E+00 5.1E+00
5.25E+04 4.0E-01 1.6E+00 5.1E+00 1000 100
1.22E+05 1.9E+00 1.6E+00 5.1E+00
2.06E+05 3.7E-02 1.6E+00 5.1E+00
3.51 E+05 9.2E-01 1.6E+00 5.1E+00
2.56E+04 3.1E+00 1.6E+00 5.1E+00
5.55E+04 6.4E-01 1.6E+00 5.1E+00 1000 100
1.35E+05 1.1E+00 1.6E+00 5.1E+00
2.19E+05 7.0E-01 1.6E+00 5.1E+00
3.22E+05 1.2E+00 1.6E+00 5.1E+00
1.13E+01 6.8E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
5.41 E+04 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.34E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.64E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1096
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qu
ug/L
Se EaFA-L07-1316-T01-A 1 1.11E+03
Se EaFA-L07-1316-T02-A 1 1.19E+03
Se EaFA-L07-1316-T03-A 1 1.37E+03
Se EaFA-L07-1316-T04-A 1 2.17E+03
Se EaFA-L07-1316-T05-A 1 3.65E+03
Se EaFA-L07-1316-T01-B 1 1.10E+03
Se EaFA-L07-1316-T02-B 1 1.38E+03
Se EaFA-L07-1316-T03-B 1 1.49E+03
Se EaFA-L07-1316-T04-B 1 2.09E+03
Se EaFA-L07-1316-T05-B 1 3.21E+03
Se EaFA-L07-1316-T01-C 1 1.05E+03
Se EaFA-L07-1316-T02-C 1 1.30E+03
Se EaFA-L07-1316-T03-C 1 1.53E+03
Se EaFA-L07-1316-T04-C 1 2.37E+03
Se EaFA-L07-1316-T05-C 1 2.70E+03
Se EaFA-L07-1316-B01-A 1 2.78E+01 E
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.11E+03 4.6E+00 1.5E+01 4.8E+01
1.19E+03 3.9E+00 1.5E+01 4.8E+01 10 300
1.37E+03 1.4E+00 1.5E+01 4.8E+01
2.17E+03 1.8E-01 1.5E+01 4.8E+01
3.65E+03 1.1E+00 1.5E+01 4.8E+01
1.10E+03 1.5E+00 1.5E+01 4.8E+01
1.38E+03 1.0E+00 1.5E+01 4.8E+01 10 300
1.49E+03 3.2E+00 1.5E+01 4.8E+01
2.09E+03 1.8E+00 1.5E+01 4.8E+01
3.21E+03 2.1E+00 1.5E+01 4.8E+01
1.05E+03 5.5E+00 1.5E+01 4.8E+01
1.30E+03 5.0E+00 1.5E+01 4.8E+01 10 300
1.53E+03 1.1E+00 1.5E+01 4.8E+01
2.37E+03 8.0E-01 1.5E+01 4.8E+01
2.70E+03 2.0E-01 1.5E+01 4.8E+01
2.78E+01 1.4E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.37E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.40E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.30E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1097
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si EaFA-L07-1316-T01-A 1
Si EaFA-L07-1316-T02-A 1
Si EaFA-L07-1316-T03-A 1
Si EaFA-L07-1316-T04-A 1
Si EaFA-L07-1316-T05-A 1
Si EaFA-L07-1316-T01-B 1
Si EaFA-L07-1316-T02-B 1
Si EaFA-L07-1316-T03-B 1
Si EaFA-L07-1316-T04-B 1
Si EaFA-L07-1316-T05-B 1
Si EaFA-L07-1316-T01-C 1
Si EaFA-L07-1316-T02-C 1
Si EaFA-L07-1316-T03-C 1
Si EaFA-L07-1316-T04-C 1
Si EaFA-L07-1316-T05-C 1
Si EaFA-L07-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
2.22E+03
2.91 E+03
2.74E+03
2.19E+03
1.93E+03
2.90E+03
3.34E+03
2.93E+03
2.40E+03
3.07E+03
2.87E+03
3.16E+03
3.15E+03
2.22E+03
2.06E+03
5.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.22E+03 2.9E-01 1.1E+00 3.5E+00
2.91E+03 4.0E-01 1.1E+00 3.5E+00 1000 100
2.74E+03 4.4E+00 1.1E+00 3.5E+00
2.19E+03 1.0E+00 1.1E+00 3.5E+00
1.93E+03 5.0E-01 1.1E+00 3.5E+00
2.90E+03 8.0E-01 1.1E+00 3.5E+00
3.34E+03 5.0E-01 1.1E+00 3.5E+00 1000 100
2.93E+03 2.4E+00 1.1E+00 3.5E+00
2.40E+03 5.7E-01 1.1E+00 3.5E+00
3.07E+03 1.4E+00 1.1E+00 3.5E+00
2.87E+03 1.5E+00 1.1E+00 3.5E+00
3.16E+03 3.1E-01 1.1E+00 3.5E+00 1000 100
3.15E+03 1.2E+00 1.1E+00 3.5E+00
2.22E+03 4.6E-01 1.1E+00 3.5E+00
2.06E+03 1.8E+00 1.1E+00 3.5E+00
5.50E-01 7.1E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.79E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.18E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.03E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1098
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone.
ug/L
Na EaFA-L07-1316-T01-A 1 5.36E+03
Na EaFA-L07-1316-T02-A 1 1.10E+04
Na EaFA-L07-1316-T03-A 1 2.80E+04
Na EaFA-L07-1316-T04-A 1 4.70E+04
Na EaFA-L07-1316-T05-A 1 6.83E+04
Na EaFA-L07-1316-T01-B 1 5.28E+03
Na EaFA-L07-1316-T02-B 1 1.09E+04
Na EaFA-L07-1316-T03-B 1 2.54E+04
Na EaFA-L07-1316-T04-B 1 4.48E+04
Na EaFA-L07-1316-T05-B 1 7.45E+04
Na EaFA-L07-1316-T01-C 1 5.29E+03
Na EaFA-L07-1316-T02-C 1 1.15E+04
Na EaFA-L07-1316-T03-C 1 2.83E+04
Na EaFA-L07-1316-T04-C 1 4.82E+04
Na EaFA-L07-1316-T05-C 1 7.46E+04
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.36E+03 6.1E-02 2.5E+00 8.0E+00
1.10E+04 7.7E-01 2.5E+00 8.0E+00 1000 100
2.80E+04 3.8E+00 2.5E+00 8.0E+00
4.70E+04 4.4E-01 2.5E+00 8.0E+00
6.83E+04 1.1E+00 2.5E+00 8.0E+00
5.28E+03 7.3E-01 2.5E+00 8.0E+00
1.09E+04 6.5E-01 2.5E+00 8.0E+00 1000 100
2.54E+04 1.8E+00 2.5E+00 8.0E+00
4.48E+04 5.1E-01 2.5E+00 8.0E+00
7.45E+04 1.7E+00 2.5E+00 8.0E+00
5.29E+03 2.3E+00 2.5E+00 8.0E+00
1.15E+04 4.0E-01 2.5E+00 8.0E+00 1000 100
2.83E+04 6.0E-01 2.5E+00 8.0E+00
4.82E+04 2.1E-01 2.5E+00 8.0E+00
7.46E+04 4.1E-01 2.5E+00 8.0E+00
Na EaFA-L07-1316-B01-A 1 3.39E+00 E 3.39E+00 6.4E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.19E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+04 81% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .24E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1099
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
EaFA-L07-1316-T01-A 1
EaFA-L07-1316-T02-A 1
EaFA-L07-1316-T03-A 1
EaFA-L07-1316-T04-A 1
EaFA-L07-1316-T05-A 1
EaFA-L07-1316-T01-B 1
EaFA-L07-1316-T02-B 1
EaFA-L07-1316-T03-B 1
EaFA-L07-1316-T04-B 1
EaFA-L07-1316-T05-B 1
EaFA-L07-1316-T01-C 1
EaFA-L07-1316-T02-C 1
EaFA-L07-1316-T03-C 1
EaFA-L07-1316-T04-C 1
EaFA-L07-1316-T05-C 1
EaFA-L07-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
2.23E+03
4.04E+03
8.70E+03
8.61 E+03
8.58E+03
2.15E+03
4.12E+03
8.36E+03
8.35E+03
9.53E+03
2.15E+03
4.24E+03
9.08E+03
9.16E+03
7.73E+03
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.23E+03 2.4E-01 1.0E+00 3.2E+00
4.04E+03 5.8E-02 1.0E+00 3.2E+00 1000 100
8.70E+03 3.6E+00 1.0E+00 3.2E+00
8.61 E+03 1.1E+00 1.0E+00 3.2E+00
8.58E+03 1.2E+00 1.0E+00 3.2E+00
2.15E+03 2.1E-01 1.0E+00 3.2E+00
4.12E+03 1.4E+00 1.0E+00 3.2E+00 1000 100
8.36E+03 1.9E+00 1.0E+00 3.2E+00
8.35E+03 1.6E+00 1.0E+00 3.2E+00
9.53E+03 1.7E+00 1.0E+00 3.2E+00
2.15E+03 1.0E+00 1.0E+00 3.2E+00
4.24E+03 6.2E-01 1.0E+00 3.2E+00 1000 100
9.08E+03 1.7E+00 1.0E+00 3.2E+00
9.16E+03 5.9E-01 1.0E+00 3.2E+00
7.73E+03 8.3E-01 1.0E+00 3.2E+00
5.00E-01 1.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.85E+03 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.95E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.07E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1100
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
ug/L
S EaFA-L07-1316-T01-A 1 1.68E+05
S EaFA-L07-1316-T02-A 1 3.29E+05
S EaFA-L07-1316-T03-A 1 7.61 E+05
S EaFA-L07-1316-T04-A 1 7.78E+05
S EaFA-L07-1316-T05-A 1 9.05E+05
S EaFA-L07-1316-T01-B 1 1.63E+05
S EaFA-L07-1316-T02-B 1 3.27E+05
S EaFA-L07-1316-T03-B 1 7.25E+05
S EaFA-L07-1316-T04-B 1 7.65E+05
S EaFA-L07-1316-T05-B 1 1.02E+06
S EaFA-L07-1316-T01-C 1 1.63E+05
S EaFA-L07-1316-T02-C 1 3.44E+05
S EaFA-L07-1316-T03-C 1 7.90E+05
S EaFA-L07-1316-T04-C 1 7.94E+05
S EaFA-L07-1316-T05-C 1 9.53E+05
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.68E+05 4.8E-01 6.8E+00 2.2E+01
3.29E+05 4.2E-01 6.8E+00 2.2E+01 1000 100
7.61E+05 3.5E+00 6.8E+00 2.2E+01
7.78E+05 2.0E-01 6.8E+00 2.2E+01
9.05E+05 1.1E+00 6.8E+00 2.2E+01
1.63E+05 7.5E-01 6.8E+00 2.2E+01
3.27E+05 6.9E-01 6.8E+00 2.2E+01 1000 100
7.25E+05 2.0E+00 6.8E+00 2.2E+01
7.65E+05 6.8E-01 6.8E+00 2.2E+01
1.02E+06 1.5E+00 6.8E+00 2.2E+01
1.63E+05 2.0E+00 6.8E+00 2.2E+01
3.44E+05 6.4E-01 6.8E+00 2.2E+01 1000 100
7.90E+05 1.6E+00 6.8E+00 2.2E+01
7.94E+05 4.5E-01 6.8E+00 2.2E+01
9.53E+05 2.7E-01 6.8E+00 2.2E+01
S EaFA-L07-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 3.1E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.30E+05 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.28E+05 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.45E+05 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1101
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-L07-1316-T01-A 1
Tl EaFA-L07-1316-T02-A 1
Tl EaFA-L07-1316-T03-A 1
Tl EaFA-L07-1316-T04-A 1
Tl EaFA-L07-1316-T05-A 1
Tl EaFA-L07-1316-T01-B 1
Tl EaFA-L07-1316-T02-B 1
Tl EaFA-L07-1316-T03-B 1
Tl EaFA-L07-1316-T04-B 1
Tl EaFA-L07-1316-T05-B 1
Tl EaFA-L07-1316-T01-C 1
Tl EaFA-L07-1316-T02-C 1
Tl EaFA-L07-1316-T03-C 1
Tl EaFA-L07-1316-T04-C 1
Tl EaFA-L07-1316-T05-C 1
Tl EaFA-L07-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.30E+00 U1/2
2.30E+00 U1/2
8.39E+00 E
2.23E+01
2.82E+01
2.30E+00 U1/2
2.30E+00 U1/2
6.47E+00 E
2.14E+01
3.09E+01
2.30E+00 U1/2
2.30E+00 U1/2
1.62E+01
2.30E+01
2.45E+01
2.30E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 3.2E+01 4.6E+00 1.5E+01
2.30E+00 2.3E+02 4.6E+00 1.5E+01 10 300
8.39E+00 2.1E+02 4.6E+00 1 .5E+01
2.23E+01 6.2E+01 4.6E+00 1 .5E+01
2.82E+01 3.8E+01 4.6E+00 1 .5E+01
2.30E+00 7.9E+01 4.6E+00 1 .5E+01
2.30E+00 2.4E+03 4.6E+00 1 .5E+01 10 300
6.47E+00 2.3E+02 4.6E+00 1 .5E+01
2.14E+01 7.0E+01 4.6E+00 1.5E+01
3.09E+01 3.0E+01 4.6E+00 1.5E+01
2.30E+00 4.4E+03 4.6E+00 1.5E+01
2.30E+00 1.2E+02 4.6E+00 1 .5E+01 10 300
1.62E+01 1.8E+01 4.6E+00 1 .5E+01
2.30E+01 3.6E+01 4.6E+00 1 .5E+01
2.45E+01 3.8E+01 4.6E+00 1 .5E+01
2.30E+00 1.6E+01 4.6E+00 1 .5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.08E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1102
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L07-1316-T01-A 1
Ti EaFA-L07-1316-T02-A 1
Ti EaFA-L07-1316-T03-A 1
Ti EaFA-L07-1316-T04-A 1
Ti EaFA-L07-1316-T05-A 1
Ti EaFA-L07-1316-T01-B 1
Ti EaFA-L07-1316-T02-B 1
Ti EaFA-L07-1316-T03-B 1
Ti EaFA-L07-1316-T04-B 1
Ti EaFA-L07-1316-T05-B 1
Ti EaFA-L07-1316-T01-C 1
Ti EaFA-L07-1316-T02-C 1
Ti EaFA-L07-1316-T03-C 1
Ti EaFA-L07-1316-T04-C 1
Ti EaFA-L07-1316-T05-C 1
Ti EaFA-L07-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.90E+00 E
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00 10 300
1.00E+00 7.0E+01 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00
1.00E+00 9.7E+01 2.0E+00 6.4E+00
1.00E+00 6.0E+02 2.0E+00 6.4E+00
1.00E+00 3.3E+02 2.0E+00 6.4E+00 10 300
1.00E+00 3.6E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+01 2.0E+00 6.4E+00
1.00E+00 4.9E+00 2.0E+00 6.4E+00
1.00E+00 7.9E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+02 2.0E+00 6.4E+00 10 300
1.00E+00 6.8E+01 2.0E+00 6.4E+00
1.00E+00 8.9E+01 2.0E+00 6.4E+00
4.90E+00 2.8E+01 2.0E+00 6.4E+00
1.00E+00 6.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.18E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.17E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.13E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1103
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFA-L07-1316-T01-A 1
V EaFA-L07-1316-T02-A 1
V EaFA-L07-1316-T03-A 1
V EaFA-L07-1316-T04-A 1
V EaFA-L07-1316-T05-A 1
V EaFA-L07-1316-T01-B 1
V EaFA-L07-1316-T02-B 1
V EaFA-L07-1316-T03-B 1
V EaFA-L07-1316-T04-B 1
V EaFA-L07-1316-T05-B 1
V EaFA-L07-1316-T01-C 1
V EaFA-L07-1316-T02-C 1
V EaFA-L07-1316-T03-C 1
V EaFA-L07-1316-T04-C 1
V EaFA-L07-1316-T05-C 1
V EaFA-L07-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
2.70E+02
2.83E+02
3.25E+02
3.73E+02
4.69E+02
2.71E+02
3.15E+02
3.39E+02
4.00E+02
4.38E+02
2.48E+02
2.99E+02
3.53E+02
3.95E+02
3.46E+02
7.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.70E+02 5.9E-01 1.5E+00 4.8E+00
2.83E+02 8.5E-01 1.5E+00 4.8E+00 10 300
3.25E+02 4.0E+00 1.5E+00 4.8E+00
3.73E+02 1.6E+00 1.5E+00 4.8E+00
4.69E+02 1.1E+00 1.5E+00 4.8E+00
2.71 E+02 9.6E-01 1.5E+00 4.8E+00
3.15E+02 6.4E-01 1.5E+00 4.8E+00 10 300
3.39E+02 2.0E+00 1.5E+00 4.8E+00
4.00E+02 6.9E-01 1.5E+00 4.8E+00
4.38E+02 1.7E+00 1.5E+00 4.8E+00
2.48E+02 2.8E+00 1.5E+00 4.8E+00
2.99E+02 2.3E+00 1.5E+00 4.8E+00 10 300
3.53E+02 2.1E+00 1.5E+00 4.8E+00
3.95E+02 1.8E+00 1.5E+00 4.8E+00
3.46E+02 1.8E+00 1.5E+00 4.8E+00
7.50E-01 4.0E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.55E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.53E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.48E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1104
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn EaFA-L07-1316-T01-A 1
Zn EaFA-L07-1316-T02-A 1
Zn EaFA-L07-1316-T03-A 1
Zn EaFA-L07-1316-T04-A 1
Zn EaFA-L07-1316-T05-A 1
Zn EaFA-L07-1316-T01-B 1
Zn EaFA-L07-1316-T02-B 1
Zn EaFA-L07-1316-T03-B 1
Zn EaFA-L07-1316-T04-B 1
Zn EaFA-L07-1316-T05-B 1
Zn EaFA-L07-1316-T01-C 1
Zn EaFA-L07-1316-T02-C 1
Zn EaFA-L07-1316-T03-C 1
Zn EaFA-L07-1316-T04-C 1
Zn EaFA-L07-1316-T05-C 1
Zn EaFA-L07-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
8.33E+00
2.10E+01
3.06E+01
1.45E+01
2.02E+01
1.36E+01
2.08E+01
3.26E+01
1.65E+01
2.48E+02
2.03E+01
2.36E+01
3.68E+01
1.14E+01
1.90E+01
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.33E+00 2.7E+01 1.0E+00 3.2E+00
2.10E+01 3.5E+00 1.0E+00 3.2E+00 10 300
3.06E+01 9.0E+00 1.0E+00 3.2E+00
1.45E+01 3.1E+00 1.0E+00 3.2E+00
2.02E+01 1.2E+01 1.0E+00 3.2E+00
1.36E+01 5.0E+00 1.0E+00 3.2E+00
2.08E+01 4.7E+00 1.0E+00 3.2E+00 10 300
3.26E+01 1.8E+00 1.0E+00 3.2E+00
1.65E+01 1.2E+01 1.0E+00 3.2E+00
2.48E+02 1.0E+00 1.0E+00 3.2E+00
2.03E+01 1.1E+00 1.0E+00 3.2E+00
2.36E+01 5.2E+00 1.0E+00 3.2E+00 10 300
3.68E+01 4.4E+00 1.0E+00 3.2E+00
1.14E+01 6.3E+00 1.0E+00 3.2E+00
1.90E+01 3.6E+00 1.0E+00 3.2E+00
5.00E-01 7.0E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.29E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.26E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.25E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/4/10 3:09 PM EPA Interlab L07 1313-1316 EaFA
6/4/103:11 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:12 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:14 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:17 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:19 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:20 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:22 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:24 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:15 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:27 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:29 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:30 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 4:07 PM EPA Interlab L07 1313-1316 EaFA
6/4/10 3:04 PM EPA Interlab L07 1313-1316 EaFA
                                                                                                                                                                         1-1105
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al EaFA-L08-1316-T01-A 1 1.43E+02
Al EaFA-L08-1316-T02-A 1 1.63E+02
Al EaFA-L08-1316-T03-A 1 2.98E+02
Al EaFA-L08-1316-T04-A 1 5.02E+02
Al EaFA-L08-1316-T05-A 1 6.37E+02
Al EaFA-L08-1316-T01-B 1 1.54E+02
Al EaFA-L08-1316-T02-B 1 2.28E+02
Al EaFA-L08-1316-T03-B 1 2.45E+02
Al EaFA-L08-1316-T04-B 1 4.76E+02
Al EaFA-L08-1316-T05-B 1 6.15E+02
Al EaFA-L08-1316-T01-C 1 1.77E+02
Al EaFA-L08-1316-T02-C 1 1.62E+02
Al EaFA-L08-1316-T03-C 1 2.52E+02
Al EaFA-L08-1316-T04-C 1 4.65E+02
Al EaFA-L08-1316-T05-C 1 6.22E+02
Al EaFA-L08-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.43E+02 6.1E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.63E+02 9.0E+00 1 .OE+00 3.2E+00 1000 100 1 .09E+03 93% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
2.98E+02 5.8E-01 1 .OE+00 3.2E+00
5.02E+02 1.1E+00 1 .OE+00 3.2E+00
6.37E+02 4.4E-01 1 .OE+00 3.2E+00
1.54E+02 1.4E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
2.28E+02 1.1E+00 1 .OE+00 3.2E+00 1000 100 1.14E+03 91%VUICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
2.45E+02 1.1E+01 1 .OE+00 3.2E+00
4.76E+02 3.7E-01 1 .OE+00 3.2E+00
6.15E+02 1.7E+00 1 .OE+00 3.2E+00
1.77E+02 7.5E-01 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.62E+02 8.4E-01 1 .OE+00 3.2E+00 1000 100 1 .07E+03 90% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
2.52E+02 2.3E+00 1 .OE+00 3.2E+00
4.65E+02 6.7E+00 1 .OE+00 3.2E+00
6.22E+02 4.3E-01 1 .OE+00 3.2E+00
5.00E-01 6.3E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                                 1-1106
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb EaFA-L08-1316-T01-A 1 2.05E+02
Sb EaFA-L08-1316-T02-A 1 3.10E+02
Sb EaFA-L08-1316-T03-A 1 5.99E+02
Sb EaFA-L08-1316-T04-A 1 8.29E+02
Sb EaFA-L08-1316-T05-A 1 1.19E+03
Sb EaFA-L08-1316-T01-B 1 2.46E+02
Sb EaFA-L08-1316-T02-B 1 4.07E+02
Sb EaFA-L08-1316-T03-B 1 5.25E+02
Sb EaFA-L08-1316-T04-B 1 7.17E+02
Sb EaFA-L08-1316-T05-B 1 1.26E+03
Sb EaFA-L08-1316-T01-C 1 2.73E+02
Sb EaFA-L08-1316-T02-C 1 3.24E+02
Sb EaFA-L08-1316-T03-C 1 5.50E+02
Sb EaFA-L08-1316-T04-C 1 6.87E+02
Sb EaFA-L08-1316-T05-C 1 1.20E+03
Sb EaFA-L08-1316-B01-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.05E+02 8.9E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.10E+02 7.5E+00 7.5E+00 2.4E+01 10 300 3.57E+03 109% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
5.99E+02 2.9E+00 7.5E+00 2.4E+01
8.29E+02 1.2E+00 7.5E+00 2.4E+01
1.19E+03 1.8E+00 7.5E+00 2.4E+01
2.46E+02 1.9E+00 7.5E+00 2.4E+01
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
4.07E+02 3.4E+00 7.5E+00 2.4E+01 10 300 3.64E+03 108% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
5.25E+02 8.5E+00 7.5E+00 2.4E+01
7.17E+02 2.0E+00 7.5E+00 2.4E+01
1.26E+03 1.0E+00 7.5E+00 2.4E+01
2.73E+02 7.7E+00 7.5E+00 2.4E+01
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
3.24E+02 5.7E+00 7.5E+00 2.4E+01 10 300 3.47E+03 105% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
5.50E+02 2.5E+00 7.5E+00 2.4E+01
6.87E+02 3.0E+00 7.5E+00 2.4E+01
1.20E+03 1.3E+00 7.5E+00 2.4E+01
3.75E+00 8.4E+01 7.5E+00 2.4E+01
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1107
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
ug/L
As EaFA-L08-1316-T01-A 1 1.76E+02
As EaFA-L08-1316-T02-A 1 1.62E+02
As EaFA-L08-1316-T03-A 1 2.62E+02
As EaFA-L08-1316-T04-A 1 3.11E+02
As EaFA-L08-1316-T05-A 1 4.16E+02
As EaFA-L08-1316-T01-B 1 1.60E+02
As EaFA-L08-1316-T02-B 1 2.40E+02
As EaFA-L08-1316-T03-B 1 2.04E+02
As EaFA-L08-1316-T04-B 1 2.26E+02
As EaFA-L08-1316-T05-B 1 4.06E+02
As EaFA-L08-1316-T01-C 1 1.65E+02
As EaFA-L08-1316-T02-C 1 1.65E+02
As EaFA-L08-1316-T03-C 1 2.22E+02
As EaFA-L08-1316-T04-C 1 2.07E+02
As EaFA-L08-1316-T05-C 1 4.22E+02
As EaFA-L08-1316-B01-A 1 5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.76E+02 5.9E+00 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.62E+02 7.3E+00 1.1E+01 3.5E+01 10 300 3.39E+03 107% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
2.62E+02 1.2E+01 1.1E+01 3.5E+01
3.11E+02 8.2E+00 1.1E+01 3.5E+01
4.16E+02 2.5E+00 1.1E+01 3.5E+01
1.60E+02 7.5E+00 1.1E+01 3.5E+01
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
2.40E+02 4.5E+00 1.1E+01 3.5E+01 10 300 3.50E+03 109% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
2.04E+02 3.8E+00 1.1E+01 3.5E+01
2.26E+02 5.1E+00 1.1E+01 3.5E+01
4.06E+02 5.3E+00 1.1E+01 3.5E+01
1.65E+02 1.6E+01 1.1E+01 3.5E+01
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.65E+02 2.0E+01 1.1E+01 3.5E+01 10 300 3.31E+03 105% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
2.22E+02 2.0E+01 1.1E+01 3.5E+01
2.07E+02 9.9E+00 1.1E+01 3.5E+01
4.22E+02 5.6E+00 1.1E+01 3.5E+01
5.50E+00 3.4E+02 1.1E+01 3.5E+01
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1108
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B EaFA-L08-1316-T01-A 1 4.21E+03
B EaFA-L08-1316-T02-A 1 7.67E+03
B EaFA-L08-1316-T03-A 1 2.08E+04
B EaFA-L08-1316-T04-A 1 3.86E+04
B EaFA-L08-1316-T05-A 1 6.90E+04
B EaFA-L08-1316-T01-B 1 5.49E+03
B EaFA-L08-1316-T02-B 1 9.20E+03
B EaFA-L08-1316-T03-B 1 1.88E+04
B EaFA-L08-1316-T04-B 1 3.70E+04
B EaFA-L08-1316-T05-B 1 6.60E+04
B EaFA-L08-1316-T01-C 1 4.90E+03
B EaFA-L08-1316-T02-C 1 8.43E+03
B EaFA-L08-1316-T03-C 1 2.11E+04
B EaFA-L08-1316-T04-C 1 3.61 E+04
B EaFA-L08-1316-T05-C 1 6.48E+04
B EaFA-L08-1316-B01-A 1 2.65E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.21 E+03 6.5E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
7.67E+03 8.3E+00 1 .OE+00 3.2E+00 1000 100 8.58E+03 90% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
2.08E+04 2.0E+00 1 .OE+00 3.2E+00
3.86E+04 2.2E+00 1 .OE+00 3.2E+00
6.90E+04 8.9E-01 1 .OE+00 3.2E+00
5.49E+03 1.6E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
9.20E+03 2.5E+00 1 .OE+00 3.2E+00 1000 100 1.01 E+04 86% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
1.88E+04 9.2E+00 1 .OE+00 3.2E+00
3.70E+04 7.3E-01 1 .OE+00 3.2E+00
6.60E+04 1.2E+00 1 .OE+00 3.2E+00
4.90E+03 1.4E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
8.43E+03 1.5E+00 1 .OE+00 3.2E+00 1000 100 9.28E+03 85% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
2.11E+04 3.4E-01 1.0E+00 3.2E+00
3.61 E+04 6.6E+00 1. OE+00 3.2E+00
6.48E+04 1.3E+00 1. OE+00 3.2E+00
2.65E+01 6.4E+00 1. OE+00 3.2E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1109
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba EaFA-L08-1316-T01-A 1 2.69E+02
Ba EaFA-L08-1316-T02-A 1 1.93E+02
Ba EaFA-L08-1316-T03-A 1 2.06E+02
Ba EaFA-L08-1316-T04-A 1 2.58E+02
Ba EaFA-L08-1316-T05-A 1 2.45E+02
Ba EaFA-L08-1316-T01-B 1 2.65E+02
Ba EaFA-L08-1316-T02-B 1 2.39E+02
Ba EaFA-L08-1316-T03-B 1 1.91E+02
Ba EaFA-L08-1316-T04-B 1 2.41E+02
Ba EaFA-L08-1316-T05-B 1 2.57E+02
Ba EaFA-L08-1316-T01-C 1 2.79E+02
Ba EaFA-L08-1316-T02-C 1 1.99E+02
Ba EaFA-L08-1316-T03-C 1 2.03E+02
Ba EaFA-L08-1316-T04-C 1 2.28E+02
Ba EaFA-L08-1316-T05-C 1 2.54E+02
Ba EaFA-L08-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.69E+02 1.7E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.93E+02 8.9E+00 1 .OE+00 3.2E+00 10 300 3.11E+03 97% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
2.06E+02 6.8E-01 1 .OE+00 3.2E+00
2.58E+02 5.6E-01 1 .OE+00 3.2E+00
2.45E+02 2.8E-01 1. OE+00 3.2E+00
2.65E+02 7.5E-01 1. OE+00 3.2E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
2.39E+02 1.2E+00 1.0E+00 3.2E+00 10 300 3.14E+03 97% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
1.91E+02 9.7E+00 1. OE+00 3.2E+00
2.41 E+02 5.4E-01 1. OE+00 3.2E+00
2.57E+02 1. OE+00 1. OE+00 3.2E+00
2.79E+02 3.1E-01 1. OE+00 3.2E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.99E+02 1.3E+00 1.0E+00 3.2E+00 10 300 3.04E+03 95% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
2.03E+02 3.8E-01 1. OE+00 3.2E+00
2.28E+02 6.2E+00 1. OE+00 3.2E+00
2.54E+02 2.0E-01 1. OE+00 3.2E+00
5.00E-01 1.0E+01 1. OE+00 3.2E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1110
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be EaFA-L08-1316-T01-A 1 9.50E-01 U1/2
Be EaFA-L08-1316-T02-A 1 9.50E-01 U1/2
Be EaFA-L08-1316-T03-A 1 9.50E-01 U1/2
Be EaFA-L08-1316-T04-A 1 9.50E-01 U1/2
Be EaFA-L08-1316-T05-A 1 9.50E-01 U1/2
Be EaFA-L08-1316-T01-B 1 9.50E-01 U1/2
Be EaFA-L08-1316-T02-B 1 9.50E-01 U1/2
Be EaFA-L08-1316-T03-B 1 9.50E-01 U1/2
Be EaFA-L08-1316-T04-B 1 9.50E-01 U1/2
Be EaFA-L08-1316-T05-B 1 9.50E-01 U1/2
Be EaFA-L08-1316-T01-C 1 9.50E-01 U1/2
Be EaFA-L08-1316-T02-C 1 9.50E-01 U1/2
Be EaFA-L08-1316-T03-C 1 9.50E-01 U1/2
Be EaFA-L08-1316-T04-C 1 9.50E-01 U1/2
Be EaFA-L08-1316-T05-C 1 9.50E-01 U1/2
Be EaFA-L08-1316-B01-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.2E+02 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
9.50E-01 2.3E+02 1 .9E+00 6.0E+00 10 300 3.33E+03 11 1% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
9.50E-01 8.4E+01 1 .9E+00 6.0E+00
9.50E-01 4.7E+01 1 .9E+00 6.0E+00
9.50E-01 5.3E+01 1 .9E+00 6.0E+00
9.50E-01 2.4E+03 1 .9E+00 6.0E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
9.50E-01 7.2E+02 1 .9E+00 6.0E+00 10 300 3.34E+03 11 1% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
9.50E-01 5.1E+02 1 .9E+00 6.0E+00
9.50E-01 1.0E+03 1 .9E+00 6.0E+00
9.50E-01 7.4E+01 1 .9E+00 6.0E+00
9.50E-01 2.4E+02 1.9E+00 6.0E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
9.50E-01 1.7E+03 1.9E+00 6.0E+00 10 300 3.28E+03 109% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
9.50E-01 4.0E+02 1.9E+00 6.0E+00
9.50E-01 6.0E+01 1.9E+00 6.0E+00
9.50E-01 5.0E+02 1.9E+00 6.0E+00
9.50E-01 6.5E+01 1.9E+00 6.0E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1111
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cd Sample Dilution Cone. Qualifier Revi
ug/L
Cd EaFA-L08-1316-T01-A 1 1.10E+OOU1/2
Cd EaFA-L08-1316-T02-A 1 1.10E+OOU1/2
Cd EaFA-L08-1316-T03-A 1 4.05E+00 E
Cd EaFA-L08-1316-T04-A 1 1.10E+OOU1/2
Cd EaFA-L08-1316-T05-A 1 2.88E+00 E
Cd EaFA-L08-1316-T01-B 1 1.10E+OOU1/2
Cd EaFA-L08-1316-T02-B 1 1.10E+OOU1/2
Cd EaFA-L08-1316-T03-B 1 4.56E+00 E
Cd EaFA-L08-1316-T04-B 1 1.10E+OOU1/2
Cd EaFA-L08-1316-T05-B 1 3.58E+00 E
Cd EaFA-L08-1316-T01-C 1 1.10E+OOU1/2
Cd EaFA-L08-1316-T02-C 1 1.10E+OOU1/2
Cd EaFA-L08-1316-T03-C 1 4.36E+00 E
Cd EaFA-L08-1316-T04-C 1 1.10E+OOU1/2
Cd EaFA-L08-1316-T05-C 1 1.10E+OOU1/2
Cd EaFA-L08-1316-B01-A 1 1.10E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.1E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.10E+00 4.3E+01 2.2E+00 7.0E+00 10 300 3.27E+03 109% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
4.05E+00 1.4E+01 2.2E+00 7.0E+00
1.10E+00 2.7E+01 2.2E+00 7.0E+00
2.88E+00 2.4E+01 2.2E+00 7.0E+00
1.10E+00 6.3E+01 2.2E+00 7.0E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
1.10E+00 6.3E+01 2.2E+00 7.0E+00 10 300 3.28E+03 109% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
4.56E+00 1.8E+01 2.2E+00 7.0E+00
1.10E+00 4.2E+01 2.2E+00 7.0E+00
3.58E+00 2.5E+01 2.2E+00 7.0E+00
1.10E+00 8.1E+01 2.2E+00 7.0E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.10E+00 4.6E+01 2.2E+00 7.0E+00 10 300 3.21E+03 107% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
4.36E+00 1.9E+01 2.2E+00 7.0E+00
1.10E+00 7.6E+01 2.2E+00 7.0E+00
1.10E+00 3.7E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1112
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca EaFA-L08-1316-T01-A 1 1.54E+05
Ca EaFA-L08-1316-T02-A 1 2.73E+05
Ca EaFA-L08-1316-T03-A 1 7.49E+05
Ca EaFA-L08-1316-T04-A 1 5.65E+05
Ca EaFA-L08-1316-T05-A 1 5.09E+05
Ca EaFA-L08-1316-T01-B 1 1.52E+05
Ca EaFA-L08-1316-T02-B 1 3.04E+05
Ca EaFA-L08-1316-T03-B 1 6.46E+05
Ca EaFA-L08-1316-T04-B 1 5.62E+05
Ca EaFA-L08-1316-T05-B 1 4.89E+05
Ca EaFA-L08-1316-T01-C 1 1.66E+05
Ca EaFA-L08-1316-T02-C 1 2.92E+05
Ca EaFA-L08-1316-T03-C 1 7.26E+05
Ca EaFA-L08-1316-T04-C 1 5.44E+05
Ca EaFA-L08-1316-T05-C 1 4.98E+05
Ca EaFA-L08-1316-B01-A 1 6.43E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+05 2.3E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
2.73E+05 9.4E+00 2.6E+00 8.3E+00 1000 100 2.74E+05 95% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
7.49E+05 7.1E-01 2.6E+00 8.3E+00
5.65E+05 1.2E+00 2.6E+00 8.3E+00
5.09E+05 4.2E-01 2.6E+00 8.3E+00
1.52E+05 4.9E-01 2.6E+00 8.3E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
3.04E+05 1.4E+00 2.6E+00 8.3E+00 1000 100 3.05E+05 90% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
6.46E+05 9.5E+00 2.6E+00 8.3E+00
5.62E+05 6.2E-01 2.6E+00 8.3E+00
4.89E+05 1.1E+00 2.6E+00 8.3E+00
1.66E+05 4.9E-01 2.6E+00 8.3E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
2.92E+05 1.0E+00 2.6E+00 8.3E+00 1000 100 2.93E+05 85% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
7.26E+05 1.1E-01 2.6E+00 8.3E+00
5.44E+05 6.4E+00 2.6E+00 8.3E+00
4.98E+05 4.5E-01 2.6E+00 8.3E+00
6.43E+00 2.6E+01 2.6E+00 8.3E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1113
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qualifier
ug/L
Cr EaFA-L08-1316-T01-A 1 1.72E+01
Cr EaFA-L08-1316-T02-A 1 1.89E+01
Cr EaFA-L08-1316-T03-A 1 3.00E+01
Cr EaFA-L08-1316-T04-A 1 4.99E+01
Cr EaFA-L08-1316-T05-A 1 1.58E+01
Cr EaFA-L08-1316-T01-B 1 1.82E+01
Cr EaFA-L08-1316-T02-B 1 2.33E+01
Cr EaFA-L08-1316-T03-B 1 2.16E+01
Cr EaFA-L08-1316-T04-B 1 5.36E+01
Cr EaFA-L08-1316-T05-B 1 1.45E+01
Cr EaFA-L08-1316-T01-C 1 2.05E+01
Cr EaFA-L08-1316-T02-C 1 1.93E+01
Cr EaFA-L08-1316-T03-C 1 2.48E+01
Cr EaFA-L08-1316-T04-C 1 6.02E+01
Cr EaFA-L08-1316-T05-C 1 2.19E+01
Cr EaFA-L08-1316-B01-A 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.72E+01 1.7E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.89E+01 1.5E+01 1.2E+00 3.8E+00 10 300 3.10E+03 103% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
3.00E+01 1.0E+01 1.2E+00 3.8E+00
4.99E+01 1.2E+00 1.2E+00 3.8E+00
1.58E+01 4.8E+00 1.2E+00 3.8E+00
1.82E+01 1.1E+01 1.2E+00 3.8E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
2.33E+01 8.8E+00 1.2E+00 3.8E+00 10 300 3.09E+03 102% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
2.16E+01 1.9E+01 1.2E+00 3.8E+00
5.36E+01 3.4E+00 1.2E+00 3.8E+00
1.45E+01 9.6E+00 1.2E+00 3.8E+00
2.05E+01 8.7E+00 1.2E+00 3.8E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.93E+01 1.3E+00 1.2E+00 3.8E+00 10 300 3.04E+03 101% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
2.48E+01 8.3E+00 1.2E+00 3.8E+00
6.02E+01 4.7E+00 1.2E+00 3.8E+00
2.19E+01 2.2E+00 1.2E+00 3.8E+00
6.00E-01 1.5E+02 1.2E+00 3.8E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1114
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co EaFA-L08-1316-T01-A 1 5.33E+01
Co EaFA-L08-1316-T02-A 1 8.12E+01
Co EaFA-L08-1316-T03-A 1 1.56E+02
Co EaFA-L08-1316-T04-A 1 9.60E+01
Co EaFA-L08-1316-T05-A 1 1.63E+02
Co EaFA-L08-1316-T01-B 1 4.98E+01
Co EaFA-L08-1316-T02-B 1 7.22E+01
Co EaFA-L08-1316-T03-B 1 1.47E+02
Co EaFA-L08-1316-T04-B 1 9.48E+01
Co EaFA-L08-1316-T05-B 1 1.72E+02
Co EaFA-L08-1316-T01-C 1 4.97E+01
Co EaFA-L08-1316-T02-C 1 9.19E+01
Co EaFA-L08-1316-T03-C 1 1.76E+02
Co EaFA-L08-1316-T04-C 1 8.56E+01
Co EaFA-L08-1316-T05-C 1 1.39E+02
Co EaFA-L08-1316-B01-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.33E+01 1.1E+00 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
8.12E+01 1.0E+01 1.8E+00 5.7E+00 10 300 3.17E+03 103% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
1.56E+02 3.9E+00 1 .8E+00 5.7E+00
9.60E+01 2.4E+00 1 .8E+00 5.7E+00
1.63E+02 1.1E+00 1.8E+00 5.7E+00
4.98E+01 9.4E-01 1 .8E+00 5.7E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
7.22E+01 1.3E+00 1 .8E+00 5.7E+00 10 300 3.16E+03 103% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
1.47E+02 8.6E+00 1 .8E+00 5.7E+00
9.48E+01 1.8E+00 1 .8E+00 5.7E+00
1.72E+02 1.3E+00 1 .8E+00 5.7E+00
4.97E+01 6.5E+00 1 .8E+00 5.7E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
9.19E+01 1.7E+00 1.8E+00 5.7E+00 10 300 3.11E+03 101% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
1.76E+02 8.2E-01 1 .8E+00 5.7E+00
8.56E+01 6.5E+00 1 .8E+00 5.7E+00
1.39E+02 2.2E+00 1 .8E+00 5.7E+00
9.00E-01 3.5E+01 1.8E+00 5.7E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1115
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu EaFA-L08-1316-T01-A 1 9.72E+00 E
Cu EaFA-L08-1316-T02-A 1 8.35E+00 E
Cu EaFA-L08-1316-T03-A 1 1.62E+01
Cu EaFA-L08-1316-T04-A 1 1.11E+01 E
Cu EaFA-L08-1316-T05-A 1 1.37E+01
Cu EaFA-L08-1316-T01-B 1 7.11E+OOE
Cu EaFA-L08-1316-T02-B 1 7.04E+00 E
Cu EaFA-L08-1316-T03-B 1 1.34E+01
Cu EaFA-L08-1316-T04-B 1 1.20E+01
Cu EaFA-L08-1316-T05-B 1 1.39E+01
Cu EaFA-L08-1316-T01-C 1 7.38E+00 E
Cu EaFA-L08-1316-T02-C 1 1.39E+01
Cu EaFA-L08-1316-T03-C 1 1.08E+01 E
Cu EaFA-L08-1316-T04-C 1 7.91E+00 E
Cu EaFA-L08-1316-T05-C 1 1.07E+01 E
Cu EaFA-L08-1316-B01-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.72E+00 2.0E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
8.35E+00 4.3E+01 3.7E+00 1.2E+01 10 300 3.11E+03 103% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
1.62E+01 3.6E+01 3.7E+00 1.2E+01
1.11E+01 2.4E+01 3.7E+00 1.2E+01
1.37E+01 2.6E+01 3.7E+00 1.2E+01
7.11E+00 2.2E+01 3.7E+00 1.2E+01
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
7.04E+00 9.1E+01 3.7E+00 1.2E+01 10 300 3.12E+03 104% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
1.34E+01 1.1E+01 3.7E+00 1.2E+01
1.20E+01 1.8E+01 3.7E+00 1.2E+01
1.39E+01 9.1E+00 3.7E+00 1.2E+01
7.38E+00 1.2E+02 3.7E+00 1.2E+01
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.39E+01 1.7E+01 3.7E+00 1.2E+01 10 300 3.06E+03 101% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
1.08E+01 3.4E+01 3.7E+00 1.2E+01
7.91 E+00 3.9E+01 3.7E+00 1.2E+01
1.07E+01 5.2E+01 3.7E+00 1.2E+01
1.85E+00 7.8E+01 3.7E+00 1.2E+01
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1116
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe EaFA-L08-1316-T01-A 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T02-A 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T03-A 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T04-A 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T05-A 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T01-B 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T02-B 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T03-B 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T04-B 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T05-B 1 3.25E+00 E
Fe EaFA-L08-1316-T01-C 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T02-C 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T03-C 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T04-C 1 1.00E+OOU1/2
Fe EaFA-L08-1316-T05-C 1 1.00E+OOU1/2
Fe EaFA-L08-1316-B01-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.4E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 1.2E+01 2.0E+00 6.4E+00 1000 100 1.01E+03 101% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+00 2.0E+00 6.4E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 1.9E+01 2.0E+00 6.4E+00 1000 100 1.00E+03 100% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 7.7E+00 2.0E+00 6.4E+00
3.25E+00 3.4E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 4.1E+00 2.0E+00 6.4E+00 1000 100 9.86E+02 99% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 7.0E+00 2.0E+00 6.4E+00
1.00E+00 3.0E+00 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 8.5E+00 2.0E+00 6.4E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1117
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Pb Sample Dilution Cone. Qualifier Revi
ug/L
Pb EaFA-L08-1316-T01-A 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T02-A 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T03-A 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T04-A 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T05-A 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T01-B 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T02-B 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T03-B 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T04-B 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T05-B 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T01-C 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T02-C 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T03-C 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T04-C 1 3.40E+00 U1/2
Pb EaFA-L08-1316-T05-C 1 3.40E+00 U1/2
Pb EaFA-L08-1316-B01-A 1 3.40E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 1.3E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 6.6E+01 6.8E+00 2.2E+01 10 300 3.11E+03 104% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 6.9E+03 6.8E+00 2.2E+01
3.40E+00 6.5E+01 6.8E+00 2.2E+01
3.40E+00 5.4E+01 6.8E+00 2.2E+01
3.40E+00 6.8E+02 6.8E+00 2.2E+01
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 1.0E+02 6.8E+00 2.2E+01 10 300 3.11E+03 104% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 3.5E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
3.40E+00 5.1E+01 6.8E+00 2.2E+01
3.40E+00 1.3E+02 6.8E+00 2.2E+01
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 4.6E+01 6.8E+00 2.2E+01 10 300 3.05E+03 101% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+00 2.8E+01 6.8E+00 2.2E+01
3.40E+00 5.9E+01 6.8E+00 2.2E+01
3.40E+00 6.2E+00 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1118
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li EaFA-L08-1316-T01-A 1 3.42E+03
Li EaFA-L08-1316-T02-A 1 5.83E+03
Li EaFA-L08-1316-T03-A 1 1.58E+04
Li EaFA-L08-1316-T04-A 1 2.95E+04
Li EaFA-L08-1316-T05-A 1 5.85E+04
Li EaFA-L08-1316-T01-B 1 3.37E+03
Li EaFA-L08-1316-T02-B 1 6.40E+03
Li EaFA-L08-1316-T03-B 1 1.37E+04
Li EaFA-L08-1316-T04-B 1 2.99E+04
Li EaFA-L08-1316-T05-B 1 5.48E+04
Li EaFA-L08-1316-T01-C 1 3.65E+03
Li EaFA-L08-1316-T02-C 1 6.23E+03
Li EaFA-L08-1316-T03-C 1 1.54E+04
Li EaFA-L08-1316-T04-C 1 2.87E+04
Li EaFA-L08-1316-T05-C 1 5.48E+04
Li EaFA-L08-1316-B01-A 1 5.11E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.42E+03 1.8E+00 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
5.83E+03 9.1E+00 1 .9E+00 6.0E+00 10 300 8.52E+03 90% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
1.58E+04 5.6E-01 1 .9E+00 6.0E+00
2.95E+04 9.5E-01 1 .9E+00 6.0E+00
5.85E+04 4.0E-01 1 .9E+00 6.0E+00
3.37E+03 9.3E-01 1 .9E+00 6.0E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
6.40E+03 8.0E-01 1 .9E+00 6.0E+00 10 300 8.95E+03 85% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
1.37E+04 9.6E+00 1 .9E+00 6.0E+00
2.99E+04 7.1E-01 1 .9E+00 6.0E+00
5.48E+04 1.1E+00 1 .9E+00 6.0E+00
3.65E+03 4.7E-01 1 .9E+00 6.0E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
6.23E+03 1.3E+00 1 .9E+00 6.0E+00 10 300 8.95E+03 91%VUICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
1.54E+04 5.7E-01 1 .9E+00 6.0E+00
2.87E+04 6.1E+00 1 .9E+00 6.0E+00
5.48E+04 3.7E-01 1 .9E+00 6.0E+00
5.11E+01 1.2E+00 1.9E+00 6.0E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1119
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn EaFA-L08-1316-T01-A 1 3.96E+02
Mn EaFA-L08-1316-T02-A 1 6.23E+02
Mn EaFA-L08-1316-T03-A 1 1.30E+03
Mn EaFA-L08-1316-T04-A 1 1.10E+03
Mn EaFA-L08-1316-T05-A 1 1.94E+03
Mn EaFA-L08-1316-T01-B 1 3.79E+02
Mn EaFA-L08-1316-T02-B 1 6.24E+02
Mn EaFA-L08-1316-T03-B 1 1.19E+03
Mn EaFA-L08-1316-T04-B 1 1.10E+03
Mn EaFA-L08-1316-T05-B 1 2.07E+03
Mn EaFA-L08-1316-T01-C 1 3.98E+02
Mn EaFA-L08-1316-T02-C 1 6.70E+02
Mn EaFA-L08-1316-T03-C 1 1.40E+03
Mn EaFA-L08-1316-T04-C 1 9.82E+02
Mn EaFA-L08-1316-T05-C 1 1.70E+03
Mn EaFA-L08-1316-B01-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.96E+02 1.3E+00 2.0E+00 6.4E+00
6.23E+02 8.5E+00 2.0E+00 6.4E+00 10 300
1.30E+03 4.4E-01 2.0E+00 6.4E+00
1.10E+03 5.4E-01 2.0E+00 6.4E+00
1.94E+03 3.5E-01 2.0E+00 6.4E+00
3.79E+02 6.3E-01 2.0E+00 6.4E+00
6.24E+02 6.0E+00 2.0E+00 6.4E+00 10 300
1.19E+03 9.7E+00 2.0E+00 6.4E+00
1.10E+03 7.0E-01 2.0E+00 6.4E+00
2.07E+03 5.8E-01 2.0E+00 6.4E+00
3.98E+02 1.7E-01 2.0E+00 6.4E+00
6.70E+02 1.7E+00 2.0E+00 6.4E+00 10 300
1.40E+03 1.1E+00 2.0E+00 6.4E+00
9.82E+02 4.2E+00 2.0E+00 6.4E+00
1.70E+03 6.3E-01 2.0E+00 6.4E+00
1.00E+00 6.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.84E+03 107% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
3.78E+03 105% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
3.81E+03 105% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1120
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg EaFA-L08-1316-T01-A 1 6.75E+03
Mg EaFA-L08-1316-T02-A 1 1.19E+04
Mg EaFA-L08-1316-T03-A 1 3.53E+04
Mg EaFA-L08-1316-T04-A 1 6.40E+04
Mg EaFA-L08-1316-T05-A 1 1.21E+05
Mg EaFA-L08-1316-T01-B 1 6.73E+03
Mg EaFA-L08-1316-T02-B 1 1.37E+04
Mg EaFA-L08-1316-T03-B 1 2.99E+04
Mg EaFA-L08-1316-T04-B 1 6.36E+04
Mg EaFA-L08-1316-T05-B 1 1.12E+05
Mg EaFA-L08-1316-T01-C 1 7.27E+03
Mg EaFA-L08-1316-T02-C 1 1.26E+04
Mg EaFA-L08-1316-T03-C 1 3.37E+04
Mg EaFA-L08-1316-T04-C 1 6.09E+04
Mg EaFA-L08-1316-T05-C 1 1.11E+05
Mg EaFA-L08-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.75E+03 1.6E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.19E+04 8.5E+00 1 .OE+00 3.2E+00 1000 100 1.28E+04 86% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
3.53E+04 6.9E-01 1. OE+00 3.2E+00
6.40E+04 8.4E-01 1. OE+00 3.2E+00
1.21E+05 3.1E-01 1.0E+00 3.2E+00
6.73E+03 9.7E-01 1. OE+00 3.2E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
1.37E+04 1.6E+00 1.0E+00 3.2E+00 1000 100 1.46E+04 93% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
2.99E+04 1.2E+01 1. OE+00 3.2E+00
6.36E+04 1.1E+00 1. OE+00 3.2E+00
1.12E+05 8.2E-01 1. OE+00 3.2E+00
7.27E+03 3.6E-01 1. OE+00 3.2E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.26E+04 1.1E+00 1.0E+00 3.2E+00 1000 100 1.35E+04 89% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
3.37E+04 7.1E-01 1.0E+00 3.2E+00
6.09E+04 5.6E+00 1. OE+00 3.2E+00
1.11E+05 3.7E-01 1.0E+00 3.2E+00
5.00E-01 5.5E+01 1. OE+00 3.2E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1121
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo EaFA-L08-1316-T01-A 1 3.32E+03
Mo EaFA-L08-1316-T02-A 1 5.76E+03
Mo EaFA-L08-1316-T03-A 1 1.58E+04
Mo EaFA-L08-1316-T04-A 1 2.96E+04
Mo EaFA-L08-1316-T05-A 1 5.36E+04
Mo EaFA-L08-1316-T01-B 1 3.35E+03
Mo EaFA-L08-1316-T02-B 1 6.67E+03
Mo EaFA-L08-1316-T03-B 1 1.37E+04
Mo EaFA-L08-1316-T04-B 1 2.88E+04
Mo EaFA-L08-1316-T05-B 1 4.91 E+04
Mo EaFA-L08-1316-T01-C 1 3.61 E+03
Mo EaFA-L08-1316-T02-C 1 5.99E+03
Mo EaFA-L08-1316-T03-C 1 1.49E+04
Mo EaFA-L08-1316-T04-C 1 2.79E+04
Mo EaFA-L08-1316-T05-C 1 5.23E+04
Mo EaFA-L08-1316-B01-A 1 6.25E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.32E+03 2.3E+00 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
5.76E+03 8.9E+00 1 .2E+00 3.8E+00 10 300 8.65E+03 96% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
1.58E+04 8.0E-01 1.2E+00 3.8E+00
2.96E+04 7.0E-01 1.2E+00 3.8E+00
5.36E+04 2.8E-01 1.2E+00 3.8E+00
3.35E+03 9.1E-01 1.2E+00 3.8E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
6.67E+03 8.9E-01 1.2E+00 3.8E+00 10 300 9.16E+03 83% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
1.37E+04 8.3E+00 1.2E+00 3.8E+00
2.88E+04 2.4E-01 1.2E+00 3.8E+00
4.91 E+04 9.4E-01 1.2E+00 3.8E+00
3.61E+03 5.1E-02 1.2E+00 3.8E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
5.99E+03 1.5E+00 1.2E+00 3.8E+00 10 300 8.60E+03 87% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
1.49E+04 4.5E-01 1.2E+00 3.8E+00
2.79E+04 6.3E+00 1.2E+00 3.8E+00
5.23E+04 2.4E-01 1.2E+00 3.8E+00
6.25E+00 1.9E+01 1.2E+00 3.8E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1122
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni EaFA-L08-1316-T01-A 1 1.24E+02
Ni EaFA-L08-1316-T02-A 1 1.96E+02
Ni EaFA-L08-1316-T03-A 1 3.82E+02
Ni EaFA-L08-1316-T04-A 1 2.13E+02
Ni EaFA-L08-1316-T05-A 1 3.69E+02
Ni EaFA-L08-1316-T01-B 1 1.11E+02
Ni EaFA-L08-1316-T02-B 1 1.80E+02
Ni EaFA-L08-1316-T03-B 1 3.54E+02
Ni EaFA-L08-1316-T04-B 1 2.27E+02
Ni EaFA-L08-1316-T05-B 1 4.08E+02
Ni EaFA-L08-1316-T01-C 1 1.24E+02
Ni EaFA-L08-1316-T02-C 1 2.14E+02
Ni EaFA-L08-1316-T03-C 1 4.19E+02
Ni EaFA-L08-1316-T04-C 1 2.03E+02
Ni EaFA-L08-1316-T05-C 1 3.31 E+02
Ni EaFA-L08-1316-B01-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.24E+02 4.6E+00 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.96E+02 9.1E+00 1 .8E+00 5.7E+00 10 300 3.33E+03 105% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
3.82E+02 1.4E+00 1 .8E+00 5.7E+00
2.13E+02 1.8E+00 1 .8E+00 5.7E+00
3.69E+02 2.4E-01 1 .8E+00 5.7E+00
1.11 E+02 2.5E+00 1.8E+00 5.7E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
1.80E+02 2.0E+00 1 .8E+00 5.7E+00 10 300 3.30E+03 104% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
3.54E+02 9.3E+00 1 .8E+00 5.7E+00
2.27E+02 1.6E+00 1 .8E+00 5.7E+00
4.08E+02 1.2E+00 1 .8E+00 5.7E+00
1.24E+02 3.0E+00 1 .8E+00 5.7E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
2.14E+02 5.4E+00 1 .8E+00 5.7E+00 10 300 3.28E+03 102% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
4.19E+02 3.7E-01 1 .8E+00 5.7E+00
2.03E+02 8.0E+00 1 .8E+00 5.7E+00
3.31 E+02 4.6E-01 1 .8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1123
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P EaFA-L08-1316-T01-A 1 1.93E+01
P EaFA-L08-1316-T02-A 1 4.03E+01
P EaFA-L08-1316-T03-A 1 1.90E+02
P EaFA-L08-1316-T04-A 1 3.94E+02
P EaFA-L08-1316-T05-A 1 1.51E+02
P EaFA-L08-1316-T01-B 1 3.18E+01
P EaFA-L08-1316-T02-B 1 4.55E+01
P EaFA-L08-1316-T03-B 1 1.51E+02
P EaFA-L08-1316-T04-B 1 3.56E+02
P EaFA-L08-1316-T05-B 1 1.31E+03
P EaFA-L08-1316-T01-C 1 2.71E+01
P EaFA-L08-1316-T02-C 1 1.23E+02
P EaFA-L08-1316-T03-C 1 2.15E+02
P EaFA-L08-1316-T04-C 1 3.35E+02
P EaFA-L08-1316-T05-C 1 1.11E+03
P EaFA-L08-1316-B01-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.93E+01 5.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
4.03E+01 3.0E+01 3.7E+00 1.2E+01 1000 100 1.10E+03 106% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
1.90E+02 1.3E+01 3.7E+00 1.2E+01
3.94E+02 6.6E+00 3.7E+00 1.2E+01
1.51E+02 1.2E+01 3.7E+00 1.2E+01
3.18E+01 2.3E+01 3.7E+00 1.2E+01
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
4.55E+01 1.4E+01 3.7E+00 1.2E+01 1000 100 1.15E+03 11 1% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
1.51E+02 1.5E+01 3.7E+00 1.2E+01
3.56E+02 2.3E+00 3.7E+00 1.2E+01
1.31E+03 4.7E+00 3.7E+00 1.2E+01
2.71E+01 3.7E+01 3.7E+00 1.2E+01
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.23E+02 4.6E+00 3.7E+00 1.2E+01 1000 100 1.12E+03 100% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
2.15E+02 5.9E+00 3.7E+00 1.2E+01
3.35E+02 1.0E+01 3.7E+00 1.2E+01
1.11E+03 2.7E+00 3.7E+00 1.2E+01
1.85E+00 1.3E+03 3.7E+00 1.2E+01
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1124
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K EaFA-L08-1316-T01-A 1 2.39E+04
K EaFA-L08-1316-T02-A 1 4.33E+04
K EaFA-L08-1316-T03-A 1 1.26E+05
K EaFA-L08-1316-T04-A 1 1.87E+05
K EaFA-L08-1316-T05-A 1 2.96E+05
K EaFA-L08-1316-T01-B 1 2.35E+04
K EaFA-L08-1316-T02-B 1 4.77E+04
K EaFA-L08-1316-T03-B 1 1.07E+05
K EaFA-L08-1316-T04-B 1 1.91E+05
K EaFA-L08-1316-T05-B 1 2.79E+05
K EaFA-L08-1316-T01-C 1 2.55E+04
K EaFA-L08-1316-T02-C 1 4.65E+04
K EaFA-L08-1316-T03-C 1 1.22E+05
K EaFA-L08-1316-T04-C 1 1.85E+05
K EaFA-L08-1316-T05-C 1 2.80E+05
K EaFA-L08-1316-B01-A 1 3.38E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.39E+04 1.5E+00 1 .6E+00 5.1E+00
4.33E+04 9.6E+00 1 .6E+00 5.1E+00 1000 100
1.26E+05 9.5E-01 1 .6E+00 5.1E+00
1.87E+05 4.1E-01 1 .6E+00 5.1E+00
2.96E+05 2.7E-01 1 .6E+00 5.1E+00
2.35E+04 6.7E-01 1 .6E+00 5.1E+00
4.77E+04 4.8E-01 1 .6E+00 5.1E+00 1000 100
1.07E+05 1.0E+01 1.6E+00 5.1E+00
1.91E+05 5.0E-01 1.6E+00 5.1E+00
2.79E+05 4.8E-01 1 .6E+00 5.1E+00
2.55E+04 5.6E-01 1 .6E+00 5.1E+00
4.65E+04 9.6E-01 1 .6E+00 5.1E+00 1000 100
1.22E+05 2.5E-01 1.6E+00 5.1E+00
1.85E+05 4.6E+00 1.6E+00 5.1E+00
2.80E+05 1.2E+00 1.6E+00 5.1E+00
3.38E+01 6.8E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
4.42E+04 87% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
4.86E+04 83% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
4.74E+04 82% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1125
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se EaFA-L08-1316-T01-A 1 1.54E+03
Se EaFA-L08-1316-T02-A 1 1.73E+03
Se EaFA-L08-1316-T03-A 1 2.68E+03
Se EaFA-L08-1316-T04-A 1 3.90E+03
Se EaFA-L08-1316-T05-A 1 4.55E+03
Se EaFA-L08-1316-T01-B 1 1.60E+03
Se EaFA-L08-1316-T02-B 1 2.72E+03
Se EaFA-L08-1316-T03-B 1 2.39E+03
Se EaFA-L08-1316-T04-B 1 3.02E+03
Se EaFA-L08-1316-T05-B 1 4.63E+03
Se EaFA-L08-1316-T01-C 1 1.77E+03
Se EaFA-L08-1316-T02-C 1 1.74E+03
Se EaFA-L08-1316-T03-C 1 2.22E+03
Se EaFA-L08-1316-T04-C 1 2.92E+03
Se EaFA-L08-1316-T05-C 1 4.78E+03
Se EaFA-L08-1316-B01-A 1 6.75E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+03 1.2E+00 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.73E+03 9.4E+00 1 .5E+01 4.8E+01 10 300 4.94E+03 107% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
2.68E+03 4.1E-01 1 .5E+01 4.8E+01
3.90E+03 1.3E+00 1 .5E+01 4.8E+01
4.55E+03 5.2E-01 1.5E+01 4.8E+01
1.60E+03 1.7E+00 1.5E+01 4.8E+01
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
2.72E+03 1.6E+00 1.5E+01 4.8E+01 10 300 5.70E+03 99% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
2.39E+03 9.3E+00 1.5E+01 4.8E+01
3.02E+03 4.9E-01 1.5E+01 4.8E+01
4.63E+03 9.6E-01 1.5E+01 4.8E+01
1.77E+03 3.4E+00 1.5E+01 4.8E+01
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.74E+03 1.1E+00 1.5E+01 4.8E+01 10 300 4.82E+03 103% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
2.22E+03 1.5E+00 1.5E+01 4.8E+01
2.92E+03 6.8E+00 1.5E+01 4.8E+01
4.78E+03 4.8E-01 1.5E+01 4.8E+01
6.75E+01 3.8E+01 1.5E+01 4.8E+01
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1126
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si EaFA-L08-1316-T01-A 1 3.07E+03
Si EaFA-L08-1316-T02-A 1 3.00E+03
Si EaFA-L08-1316-T03-A 1 3.40E+03
Si EaFA-L08-1316-T04-A 1 3.12E+03
Si EaFA-L08-1316-T05-A 1 4.16E+03
Si EaFA-L08-1316-T01-B 1 3.03E+03
Si EaFA-L08-1316-T02-B 1 3.97E+03
Si EaFA-L08-1316-T03-B 1 3.22E+03
Si EaFA-L08-1316-T04-B 1 2.51E+03
Si EaFA-L08-1316-T05-B 1 4.57E+03
Si EaFA-L08-1316-T01-C 1 3.28E+03
Si EaFA-L08-1316-T02-C 1 3.08E+03
Si EaFA-L08-1316-T03-C 1 3.27E+03
Si EaFA-L08-1316-T04-C 1 2.29E+03
Si EaFA-L08-1316-T05-C 1 3.91E+03
Si EaFA-L08-1316-B01-A 1 5.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.07E+03 1.6E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.00E+03 8.6E+00 1.1E+00 3.5E+00 1000 100 3.88E+03 87% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
3.40E+03 1.3E+00 1.1E+00 3.5E+00
3.12E+03 8.9E-01 1.1E+00 3.5E+00
4.16E+03 5.6E-01 1.1E+00 3.5E+00
3.03E+03 7.3E-01 1.1E+00 3.5E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
3.97E+03 1.1E+00 1.1E+00 3.5E+00 1000 100 4.85E+03 88% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
3.22E+03 9.6E+00 1.1E+00 3.5E+00
2.51E+03 9.8E-01 1.1E+00 3.5E+00
4.57E+03 1.1E+00 1.1E+00 3.5E+00
3.28E+03 3.5E-01 1.1E+00 3.5E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
3.08E+03 1.4E+00 1.1E+00 3.5E+00 1000 100 4.02E+03 94% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
3.27E+03 1.3E-01 1.1E+00 3.5E+00
2.29E+03 6.2E+00 1.1E+00 3.5E+00
3.91E+03 5.4E-01 1.1E+00 3.5E+00
5.50E-01 3.3E+01 1.1E+00 3.5E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1127
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na EaFA-L08-1316-T01-A 1 4.87E+03
Na EaFA-L08-1316-T02-A 1 8.85E+03
Na EaFA-L08-1316-T03-A 1 2.58E+04
Na EaFA-L08-1316-T04-A 1 4.04E+04
Na EaFA-L08-1316-T05-A 1 6.83E+04
Na EaFA-L08-1316-T01-B 1 4.80E+03
Na EaFA-L08-1316-T02-B 1 9.63E+03
Na EaFA-L08-1316-T03-B 1 2.21E+04
Na EaFA-L08-1316-T04-B 1 4.16E+04
Na EaFA-L08-1316-T05-B 1 6.45E+04
Na EaFA-L08-1316-T01-C 1 5.15E+03
Na EaFA-L08-1316-T02-C 1 9.45E+03
Na EaFA-L08-1316-T03-C 1 2.50E+04
Na EaFA-L08-1316-T04-C 1 3.96E+04
Na EaFA-L08-1316-T05-C 1 6.44E+04
Na EaFA-L08-1316-B01-A 1 2.32E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.87E+03 2.4E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
8.85E+03 9.5E+00 2.5E+00 8.0E+00 1000 100 9.74E+03 89% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
2.58E+04 8.2E-01 2.5E+00 8.0E+00
4.04E+04 7.8E-01 2.5E+00 8.0E+00
6.83E+04 3.4E-01 2.5E+00 8.0E+00
4.80E+03 7.7E-01 2.5E+00 8.0E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
9.63E+03 5.6E-01 2.5E+00 8.0E+00 1000 100 1.06E+04 94% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
2.21E+04 9.9E+00 2.5E+00 8.0E+00
4.16E+04 6.4E-01 2.5E+00 8.0E+00
6.45E+04 8.0E-01 2.5E+00 8.0E+00
5.15E+03 2.8E-01 2.5E+00 8.0E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
9.45E+03 1.6E+00 2.5E+00 8.0E+00 1000 100 1.03E+04 89% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
2.50E+04 7.0E-01 2.5E+00 8.0E+00
3.96E+04 6.0E+00 2.5E+00 8.0E+00
6.44E+04 3.2E-01 2.5E+00 8.0E+00
2.32E+01 3.7E+00 2.5E+00 8.0E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1128
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
EaFA-L08-1316-T01-A 1 2.07E+03
EaFA-L08-1316-T02-A 1 3.50E+03
EaFA-L08-1316-T03-A 1 8.59E+03
EaFA-L08-1316-T04-A 1 7.95E+03
EaFA-L08-1316-T05-A 1 6.49E+03
EaFA-L08-1316-T01-B 1 2.07E+03
EaFA-L08-1316-T02-B 1 4.05E+03
EaFA-L08-1316-T03-B 1 7.10E+03
EaFA-L08-1316-T04-B 1 8.60E+03
EaFA-L08-1316-T05-B 1 6.16E+03
EaFA-L08-1316-T01-C 1 2.24E+03
EaFA-L08-1316-T02-C 1 3.63E+03
EaFA-L08-1316-T03-C 1 8.08E+03
EaFA-L08-1316-T04-C 1 7.90E+03
EaFA-L08-1316-T05-C 1 6.73E+03
EaFA-L08-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+03 1.6E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.50E+03 7.9E+00 1 .OE+00 3.2E+00 1000 100 4.39E+03 89% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
8.59E+03 1.7E+00 1 .OE+00 3.2E+00
7.95E+03 7.9E-01 1 .OE+00 3.2E+00
6.49E+03 1.9E-01 1 .OE+00 3.2E+00
2.07E+03 1.1E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
4.05E+03 5.1E+00 1 .OE+00 3.2E+00 1000 100 4.96E+03 91%VUICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
7.10E+03 7.8E+00 1 .OE+00 3.2E+00
8.60E+03 8.7E-01 1 .OE+00 3.2E+00
6.16E+03 1.1E+00 1.0E+00 3.2E+00
2.24E+03 2.7E-01 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
3.63E+03 1.4E+00 1 .OE+00 3.2E+00 1000 100 4.58E+03 95% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
8.08E+03 2.9E-01 1. OE+00 3.2E+00
7.90E+03 3.8E+00 1. OE+00 3.2E+00
6.73E+03 3.1E-01 1.0E+00 3.2E+00
5.00E-01 1.9E+01 1. OE+00 3.2E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1129
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S EaFA-L08-1316-T01-A 1 1.50E+05
S EaFA-L08-1316-T02-A 1 2.66E+05
S EaFA-L08-1316-T03-A 1 7.09E+05
S EaFA-L08-1316-T04-A 1 7.14E+05
S EaFA-L08-1316-T05-A 1 8.98E+05
S EaFA-L08-1316-T01-B 1 1.49E+05
S EaFA-L08-1316-T02-B 1 2.95E+05
S EaFA-L08-1316-T03-B 1 6.25E+05
S EaFA-L08-1316-T04-B 1 7.14E+05
S EaFA-L08-1316-T05-B 1 8.52E+05
S EaFA-L08-1316-T01-C 1 1.57E+05
S EaFA-L08-1316-T02-C 1 2.81E+05
S EaFA-L08-1316-T03-C 1 7.01 E+05
S EaFA-L08-1316-T04-C 1 6.95E+05
S EaFA-L08-1316-T05-C 1 8.53E+05
S EaFA-L08-1316-B01-A 1 2.07E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.50E+05 2.6E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
2.66E+05 8.6E+00 6.8E+00 2.2E+01 1000 100 3.55E+05 89% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
7.09E+05 1.5E+00 6.8E+00 2.2E+01
7.14E+05 1.2E+00 6.8E+00 2.2E+01
8.98E+05 2.9E-01 6.8E+00 2.2E+01
1.49E+05 8.8E-01 6.8E+00 2.2E+01
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
2.95E+05 6.1E-01 6.8E+00 2.2E+01 1000 100 3.91E+05 96% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
6.25E+05 9.2E+00 6.8E+00 2.2E+01
7.14E+05 6.7E-01 6.8E+00 2.2E+01
8.52E+05 1.1E+00 6.8E+00 2.2E+01
1.57E+05 5.8E-01 6.8E+00 2.2E+01
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
2.81E+05 1.4E+00 6.8E+00 2.2E+01 1000 100 3.74E+05 92% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
7.01 E+05 3.3E-01 6.8E+00 2.2E+01
6.95E+05 6.3E+00 6.8E+00 2.2E+01
8.53E+05 2.8E-01 6.8E+00 2.2E+01
2.07E+01 8.0E+00 6.8E+00 2.2E+01
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1130
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl EaFA-L08-1316-T01-A 1 2.30E+00 U1/2
Tl EaFA-L08-1316-T02-A 1 2.30E+00 U1/2
Tl EaFA-L08-1316-T03-A 1 2.36E+01
Tl EaFA-L08-1316-T04-A 1 4.97E+01
Tl EaFA-L08-1316-T05-A 1 4.71E+01
Tl EaFA-L08-1316-T01-B 1 2.30E+00 U1/2
Tl EaFA-L08-1316-T02-B 1 2.40E+01
Tl EaFA-L08-1316-T03-B 1 2.17E+01
Tl EaFA-L08-1316-T04-B 1 2.22E+01
Tl EaFA-L08-1316-T05-B 1 5.56E+01
Tl EaFA-L08-1316-T01-C 1 5.63E+00 E
Tl EaFA-L08-1316-T02-C 1 1.51E+01
Tl EaFA-L08-1316-T03-C 1 2.04E+01
Tl EaFA-L08-1316-T04-C 1 3.20E+01
Tl EaFA-L08-1316-T05-C 1 4.02E+01
Tl EaFA-L08-1316-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 2.6E+02 4.6E+00 1.5E+01
2.30E+00 4.9E+02 4.6E+00 1.5E+01 10 300
2.36E+01 1.0E+02 4.6E+00 1.5E+01
4.97E+01 2.9E+01 4.6E+00 1.5E+01
4.71 E+01 5.5E+01 4.6E+00 1.5E+01
2.30E+00 1.7E+02 4.6E+00 1.5E+01
2.40E+01 1.3E+01 4.6E+00 1.5E+01 10 300
2.17E+01 3.6E+01 4.6E+00 1.5E+01
2.22E+01 4.4E+01 4.6E+00 1.5E+01
5.56E+01 8.0E+00 4.6E+00 1.5E+01
5.63E+00 1.8E+02 4.6E+00 1.5E+01
1.51 E+01 1.0E+01 4.6E+00 1.5E+01 10 300
2.04E+01 3.2E+01 4.6E+00 1.5E+01
3.20E+01 4.5E+01 4.6E+00 1.5E+01
4.02E+01 3.0E+01 4.6E+00 1.5E+01
2.30E+00 1.3E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.14E+03 104% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
3.13E+03 104% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
3.08E+03 102% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1131
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti EaFA-L08-1316-T01-A 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T02-A 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T03-A 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T04-A 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T05-A 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T01-B 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T02-B 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T03-B 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T04-B 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T05-B 1 2.22E+00 E
Ti EaFA-L08-1316-T01-C 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T02-C 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T03-C 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T04-C 1 1.00E+OOU1/2
Ti EaFA-L08-1316-T05-C 1 1.00E+OOU1/2
Ti EaFA-L08-1316-B01-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 1.0E+03 2.0E+00 6.4E+00 10 300 3.07E+03 102% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 9.2E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+03 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 8.6E+01 2.0E+00 6.4E+00 10 300 3.06E+03 102% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 6.4E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
2.22E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+03 2.0E+00 6.4E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 1.7E+02 2.0E+00 6.4E+00 10 300 2.99E+03 100% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
1.00E+00 4.7E+01 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 2.8E+02 2.0E+00 6.4E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1132
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V EaFA-L08-1316-T01-A 1 3.54E+02
V EaFA-L08-1316-T02-A 1 3.71 E+02
V EaFA-L08-1316-T03-A 1 5.42E+02
V EaFA-L08-1316-T04-A 1 6.31 E+02
V EaFA-L08-1316-T05-A 1 6.88E+02
V EaFA-L08-1316-T01-B 1 3.79E+02
V EaFA-L08-1316-T02-B 1 6.29E+02
V EaFA-L08-1316-T03-B 1 4.86E+02
V EaFA-L08-1316-T04-B 1 4.67E+02
V EaFA-L08-1316-T05-B 1 7.42E+02
V EaFA-L08-1316-T01-C 1 4.35E+02
V EaFA-L08-1316-T02-C 1 3.63E+02
V EaFA-L08-1316-T03-C 1 4.57E+02
V EaFA-L08-1316-T04-C 1 4.45E+02
V EaFA-L08-1316-T05-C 1 7.15E+02
V EaFA-L08-1316-B01-A 1 1.81E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.54E+02 4.0E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
3.71E+02 9.3E+00 1 .5E+00 4.8E+00 10 300 3.50E+03 104% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
5.42E+02 5.0E-01 1 .5E+00 4.8E+00
6.31 E+02 2.2E+00 1 .5E+00 4.8E+00
6.88E+02 1.0E+00 1 .5E+00 4.8E+00
3.79E+02 1.3E+00 1 .5E+00 4.8E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
6.29E+02 4.7E-01 1 .5E+00 4.8E+00 10 300 3.72E+03 103% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
4.86E+02 9.9E+00 1 .5E+00 4.8E+00
4.67E+02 1.6E+00 1 .5E+00 4.8E+00
7.42E+02 1.3E+00 1 .5E+00 4.8E+00
4.35E+02 9.0E-01 1 .5E+00 4.8E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
3.63E+02 1.0E+00 1 .5E+00 4.8E+00 10 300 3.41E+03 102% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
4.57E+02 3.2E-01 1.5E+00 4.8E+00
4.45E+02 6.9E+00 1.5E+00 4.8E+00
7.15E+02 4.3E-01 1.5E+00 4.8E+00
1.81E+00 5.8E+01 1.5E+00 4.8E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1133
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn EaFA-L08-1316-T01-A 1 2.23E+01
Zn EaFA-L08-1316-T02-A 1 2.23E+01
Zn EaFA-L08-1316-T03-A 1 4.54E+01
Zn EaFA-L08-1316-T04-A 1 3.26E+01
Zn EaFA-L08-1316-T05-A 1 6.33E+01
Zn EaFA-L08-1316-T01-B 1 2.36E+01
Zn EaFA-L08-1316-T02-B 1 2.83E+01
Zn EaFA-L08-1316-T03-B 1 3.76E+01
Zn EaFA-L08-1316-T04-B 1 3.72E+01
Zn EaFA-L08-1316-T05-B 1 7.85E+01
Zn EaFA-L08-1316-T01-C 1 2.55E+01
Zn EaFA-L08-1316-T02-C 1 2.77E+01
Zn EaFA-L08-1316-T03-C 1 4.18E+01
Zn EaFA-L08-1316-T04-C 1 2.84E+01
Zn EaFA-L08-1316-T05-C 1 5.40E+01
Zn EaFA-L08-1316-B01-A 1 1.00E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.23E+01 5.5E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 12:47 PM EPA Interlab LOS 1313-1316 EaFA
2.23E+01 6.3E+00 1 .OE+00 3.2E+00 10 300 3.26E+03 108% VU ICP-OES 6/7/10 12:49 PM EPA Interlab LOS 1313-1316 EaFA
4.54E+01 3.2E+00 1 .OE+00 3.2E+00
3.26E+01 6.7E-01 1 .OE+00 3.2E+00
6.33E+01 2.2E+00 1 .OE+00 3.2E+00
2.36E+01 4.2E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 1:47 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:52 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:54 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 12:56 PM EPA Interlab LOS 1313-1316 EaFA
2.83E+01 2.3E+00 1 .OE+00 3.2E+00 10 300 3.27E+03 108% VU ICP-OES 6/7/10 12:57 PM EPA Interlab LOS 1313-1316 EaFA
3.76E+01 1.1E+01 1. OE+00 3.2E+00
3.72E+01 2.3E+00 1 .OE+00 3.2E+00
7.85E+01 6.2E-01 1 .OE+00 3.2E+00
2.55E+01 3.9E+00 1 .OE+00 3.2E+00
VU ICP-OES 6/7/10 12:59 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:01 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/101:02 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:49 PM EPA Interlab LOS 1313-1316 EaFA
2.77E+01 4.8E+00 1 .OE+00 3.2E+00 10 300 3.21E+03 106% VU ICP-OES 6/7/10 1:06 PM EPA Interlab LOS 1313-1316 EaFA
4.18E+01 2.0E+00 1. OE+00 3.2E+00
2.84E+01 8.6E+00 1. OE+00 3.2E+00
5.40E+01 2.0E+00 1. OE+00 3.2E+00
1.00E+01 4.7E+00 1. OE+00 3.2E+00
VU ICP-OES 6/7/10 1:07 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:09 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/10 1:10 PM EPA Interlab LOS 1313-1316 EaFA
VU ICP-OES 6/7/1012:42 PM EPA Interlab LOS 1313-1316 EaFA
                                                                                                                                                                         1-1134
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al EaFA-L09-1316-T01-A 1
Al EaFA-L09-1316-T02-A 1
Al EaFA-L09-1316-T03-A 1
Al EaFA-L09-1316-T04-A 1
Al EaFA-L09-1316-T05-A 1
Al EaFA-L09-1316-T01-B 1
Al EaFA-L09-1316-T02-B 1
Al EaFA-L09-1316-T03-B 1
Al EaFA-L09-1316-T04-B 1
Al EaFA-L09-1316-T05-B 1
Al EaFA-L09-1316-T01-C 1
Al EaFA-L09-1316-T02-C 1
Al EaFA-L09-1316-T03-C 1
Al EaFA-L09-1316-T04-C 1
Al EaFA-L09-1316-T05-C 1
Al EaFA-L09-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.86E+02
2.21E+02
2.72E+02
5.00E+02
4.59E+02
1.75E+02
2.03E+02
2.76E+02
4.85E+02
5.05E+02
1.73E+02
2.10E+02
2.70E+02
4.81 E+02
5.12E+02
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.86E+02 1.5E+00 1.00E+00 3.18E+00
2.21E+02 7.9E-01 1.00E+00 3.18E+00 1000 100
2.72E+02 1.7E+00 1.00E+00 3.18E+00
5.00E+02 1.5E+00 1.00E+00 3.18E+00
4.59E+02 9.0E+00 1.00E+00 3.18E+00
1.75E+02 1.2E+00 1.00E+00 3.18E+00
2.03E+02 9.5E-01 1.00E+00 3.18E+00 1000 100
2.76E+02 1.0E+00 1.00E+00 3.18E+00
4.85E+02 2.1E+00 1.00E+00 3.18E+00
5.05E+02 8.7E+01 1.00E+00 3.18E+00
1.73E+02 1.3E+00 1.00E+00 3.18E+00
2.10E+02 6.4E-01 1.00E+00 3.18E+00 1000 100
2.70E+02 1.6E-01 1.00E+00 3.18E+00
4.81E+02 1.3E+00 1.00E+00 3.18E+00
5.12E+02 4.1E+01 1.00E+00 3.18E+00
5.00E-01 2.2E+01 1.00E+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.29E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.33E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                                  1-1135
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L09-1316-T01-A 1
Sb EaFA-L09-1316-T02-A 1
Sb EaFA-L09-1316-T03-A 1
Sb EaFA-L09-1316-T04-A 1
Sb EaFA-L09-1316-T05-A 1
Sb EaFA-L09-1316-T01-B 1
Sb EaFA-L09-1316-T02-B 1
Sb EaFA-L09-1316-T03-B 1
Sb EaFA-L09-1316-T04-B 1
Sb EaFA-L09-1316-T05-B 1
Sb EaFA-L09-1316-T01-C 1
Sb EaFA-L09-1316-T02-C 1
Sb EaFA-L09-1316-T03-C 1
Sb EaFA-L09-1316-T04-C 1
Sb EaFA-L09-1316-T05-C 1
Sb EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
2.08E+02
2.97E+02
4.49E+02
5.98E+02
5.90E+02
2.22E+02
3.44E+02
4.63E+02
5.94E+02
3.77E+02
2.08E+02
3.38E+02
4.60E+02
5.75E+02
3.77E+02
1.79E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+02 1.3E+00 7.50E+00 2.39E+01
2.97E+02 5.9E+00 7.50E+00 2.39E+01 10 325
4.49E+02 2.4E+00 7.50E+00 2.39E+01
5.98E+02 4.4E+00 7.50E+00 2.39E+01
5.90E+02 1.1E+01 7.50E+00 2.39E+01
2.22E+02 1.1E+01 7.50E+00 2.39E+01
3.44E+02 2.0E+00 7.50E+00 2.39E+01 10 325
4.63E+02 6.9E+00 7.50E+00 2.39E+01
5.94E+02 7.3E+00 7.50E+00 2.39E+01
3.77E+02 8.5E+01 7.50E+00 2.39E+01
2.08E+02 6.3E+00 7.50E+00 2.39E+01
3.38E+02 7.8E+00 7.50E+00 2.39E+01 10 325
4.60E+02 8.1E+00 7.50E+00 2.39E+01
5.75E+02 4.5E+00 7.50E+00 2.39E+01
3.77E+02 4.9E+01 7.50E+00 2.39E+01
1.79E+01 6.2E+01 7.50E+00 2.39E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.55E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.73E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.72E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1136
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qu
ug/L
As EaFA-L09-1316-T01-A 1 1.53E+02
As EaFA-L09-1316-T02-A 1 1.65E+02
As EaFA-L09-1316-T03-A 1 1.52E+02
As EaFA-L09-1316-T04-A 1 2.41E+02
As EaFA-L09-1316-T05-A 1 1.69E+02
As EaFA-L09-1316-T01-B 1 1.57E+02
As EaFA-L09-1316-T02-B 1 1.37E+02
As EaFA-L09-1316-T03-B 1 1.40E+02
As EaFA-L09-1316-T04-B 1 1.80E+02
As EaFA-L09-1316-T05-B 1 2.56E+02
As EaFA-L09-1316-T01-C 1 1.52E+02
As EaFA-L09-1316-T02-C 1 1.44E+02
As EaFA-L09-1316-T03-C 1 1.72E+02
As EaFA-L09-1316-T04-C 1 1.88E+02
As EaFA-L09-1316-T05-C 1 1.32E+02
As EaFA-L09-1316-B01-A 1 3.77E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+02 9.8E+00 1.10E+01 3.50E+01
1.65E+02 4.3E+00 1.10E+01 3.50E+01 10 325
1.52E+02 1.6E+01 1.10E+01 3.50E+01
2.41E+02 6.5E+00 1.10E+01 3.50E+01
1.69E+02 1.8E+01 1.10E+01 3.50E+01
1.57E+02 6.0E+00 1.10E+01 3.50E+01
1.37E+02 6.1E+00 1.10E+01 3.50E+01 10 325
1.40E+02 1.7E+01 1.10E+01 3.50E+01
1.80E+02 1.3E+01 1.10E+01 3.50E+01
2.56E+02 7.3E+01 1.10E+01 3.50E+01
1.52E+02 1.5E+01 1.10E+01 3.50E+01
1.44E+02 1.5E+01 1.10E+01 3.50E+01 10 325
1.72E+02 3.5E+00 1.10E+01 3.50E+01
1.88E+02 1.2E+01 1.10E+01 3.50E+01
1.32E+02 4.0E+01 1.10E+01 3.50E+01
3.77E+01 5.4E+01 1.10E+01 3.50E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.36E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.52E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.53E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1137
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B EaFA-L09-1316-T01-A 1
B EaFA-L09-1316-T02-A 1
B EaFA-L09-1316-T03-A 1
B EaFA-L09-1316-T04-A 1
B EaFA-L09-1316-T05-A 1
B EaFA-L09-1316-T01-B 1
B EaFA-L09-1316-T02-B 1
B EaFA-L09-1316-T03-B 1
B EaFA-L09-1316-T04-B 1
B EaFA-L09-1316-T05-B 1
B EaFA-L09-1316-T01-C 1
B EaFA-L09-1316-T02-C 1
B EaFA-L09-1316-T03-C 1
B EaFA-L09-1316-T04-C 1
B EaFA-L09-1316-T05-C 1
B EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
4.48E+03
8.83E+03
2.12E+04
3.77E+04
6.39E+04
5.14E+03
9.14E+03
2.18E+04
3.67E+04
3.20E+04
4.84E+03
8.90E+03
2.14E+04
3.74E+04
4.83E+04
4.64E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.48E+03 2.9E-01 1.00E+00 3.18E+00
8.83E+03 2.1E+00 1.00E+00 3.18E+00 1000 100
2.12E+04 7.6E-01 1.00E+00 3.18E+00
3.77E+04 1.9E+00 1.00E+00 3.18E+00
6.39E+04 7.4E+00 1.00E+00 3.18E+00
5.14E+03 1.3E+00 1.00E+00 3.18E+00
9.14E+03 7.5E-01 1.00E+00 3.18E+00 1000 100
2.18E+04 9.4E-01 1.00E+00 3.18E+00
3.67E+04 2.5E+00 1.00E+00 3.18E+00
3.20E+04 6.8E+01 1.00E+00 3.18E+00
4.84E+03 6.2E-01 1.00E+00 3.18E+00
8.90E+03 2.0E-01 1.00E+00 3.18E+00 1000 100
2.14E+04 1.2E+00 1.00E+00 3.18E+00
3.74E+04 6.1E-01 1.00E+00 3.18E+00
4.83E+04 3.0E+01 1.00E+00 3.18E+00
4.64E+01 3.6E+00 1.00E+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.69E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.99E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.74E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1138
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone.
ug/L
Ba EaFA-L09-1316-T01-A 1 2.57E+02
Ba EaFA-L09-1316-T02-A 1 2.14E+02
Ba EaFA-L09-1316-T03-A 1 2.04E+02
Ba EaFA-L09-1316-T04-A 1 2.24E+02
Ba EaFA-L09-1316-T05-A 1 2.30E+02
Ba EaFA-L09-1316-T01-B 1 2.65E+02
Ba EaFA-L09-1316-T02-B 1 2.06E+02
Ba EaFA-L09-1316-T03-B 1 2.08E+02
Ba EaFA-L09-1316-T04-B 1 2.20E+02
Ba EaFA-L09-1316-T05-B 1 1.88E+02
Ba EaFA-L09-1316-T01-C 1 2.63E+02
Ba EaFA-L09-1316-T02-C 1 2.05E+02
Ba EaFA-L09-1316-T03-C 1 2.07E+02
Ba EaFA-L09-1316-T04-C 1 2.29E+02
Ba EaFA-L09-1316-T05-C 1 1.87E+02
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.57E+02 1.0E+00 1.00E+00 3.18E+00
2.14E+02 2.7E-01 1.00E+00 3.18E+00 10 325
2.04E+02 1.0E+00 1.00E+00 3.18E+00
2.24E+02 1.1E+00 1.00E+00 3.18E+00
2.30E+02 9.4E+00 1.00E+00 3.18E+00
2.65E+02 4.6E-01 1.00E+00 3.18E+00
2.06E+02 8.7E-01 1.00E+00 3.18E+00 10 325
2.08E+02 4.4E-01 1.00E+00 3.18E+00
2.20E+02 2.6E+00 1.00E+00 3.18E+00
1.88E+02 8.2E+01 1.00E+00 3.18E+00
2.63E+02 7.9E-01 1.00E+00 3.18E+00
2.05E+02 7.7E-02 1.00E+00 3.18E+00 10 325
2.07E+02 4.4E-01 1.00E+00 3.18E+00
2.29E+02 2.4E-01 1.00E+00 3.18E+00
1.87E+02 5.2E+01 1.00E+00 3.18E+00
Ba EaFA-L09-1316-B01-A 1 5.00E-01 U1/2 5.00E-01 2.8E+01 1.00E+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.16E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.28E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.27E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54AML091313-1316EaFA
                                                                                                                                                                         1-1139
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L09-1316-T01-A 1
Be EaFA-L09-1316-T02-A 1
Be EaFA-L09-1316-T03-A 1
Be EaFA-L09-1316-T04-A 1
Be EaFA-L09-1316-T05-A 1
Be EaFA-L09-1316-T01-B 1
Be EaFA-L09-1316-T02-B 1
Be EaFA-L09-1316-T03-B 1
Be EaFA-L09-1316-T04-B 1
Be EaFA-L09-1316-T05-B 1
Be EaFA-L09-1316-T01-C 1
Be EaFA-L09-1316-T02-C 1
Be EaFA-L09-1316-T03-C 1
Be EaFA-L09-1316-T04-C 1
Be EaFA-L09-1316-T05-C 1
Be EaFA-L09-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 9.4E+03 1.90E+00 6.00E+00
9.50E-01 8.4E+01 1.90E+00 6.00E+00 10 325
9.50E-01 4.5E+02 1.90E+00 6.00E+00
9.50E-01 7.6E+01 1.90E+00 6.00E+00
9.50E-01 5.2E+02 1.90E+00 6.00E+00
9.50E-01 6.0E+03 1.90E+00 6.00E+00
9.50E-01 2.2E+02 1.90E+00 6.00E+00 10 325
9.50E-01 2.6E+02 1.90E+00 6.00E+00
9.50E-01 5.4E+02 1.90E+00 6.00E+00
9.50E-01 2.2E+01 1.90E+00 6.00E+00
9.50E-01 4.8E+02 1.90E+00 6.00E+00
9.50E-01 7.5E+01 1.90E+00 6.00E+00 10 325
9.50E-01 3.6E+02 1.90E+00 6.00E+00
9.50E-01 5.2E+01 1.90E+00 6.00E+00
9.50E-01 1.2E+02 1.90E+00 6.00E+00
9.50E-01 2.3E+01 1.90E+00 6.00E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.36E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.53E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.51E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 131 3-1 31 6 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1140
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd EaFA-L09-1316-T01-A 1
Cd EaFA-L09-1316-T02-A 1
Cd EaFA-L09-1316-T03-A 1
Cd EaFA-L09-1316-T04-A 1
Cd EaFA-L09-1316-T05-A 1
Cd EaFA-L09-1316-T01-B 1
Cd EaFA-L09-1316-T02-B 1
Cd EaFA-L09-1316-T03-B 1
Cd EaFA-L09-1316-T04-B 1
Cd EaFA-L09-1316-T05-B 1
Cd EaFA-L09-1316-T01-C 1
Cd EaFA-L09-1316-T02-C 1
Cd EaFA-L09-1316-T03-C 1
Cd EaFA-L09-1316-T04-C 1
Cd EaFA-L09-1316-T05-C 1
Cd EaFA-L09-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.3E+01 2.20E+00 7.00E+00
1.10E+00 1.2E+01 2.20E+00 7.00E+00 10 325
1.10E+00 1.9E+01 2.20E+00 7.00E+00
1.10E+00 1.3E+01 2.20E+00 7.00E+00
1.10E+00 4.8E+01 2.20E+00 7.00E+00
1.10E+00 1.1E+01 2.20E+00 7.00E+00
1.10E+00 8.9E+00 2.20E+00 7.00E+00 10 325
1.10E+00 4.6E+01 2.20E+00 7.00E+00
1.10E+00 2.2E+01 2.20E+00 7.00E+00
1.10E+00 7.9E-01 2.20E+00 7.00E+00
1.10E+00 1.6E+01 2.20E+00 7.00E+00
1.10E+00 7.1E+00 2.20E+00 7.00E+00 10 325
1.10E+00 8.6E+01 2.20E+00 7.00E+00
1.10E+00 1.8E+01 2.20E+00 7.00E+00
1.10E+00 6.6E+01 2.20E+00 7.00E+00
1.10E+00 9.1E+00 2.20E+00 7.00E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.34E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.51E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.51E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/1 1/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 131 3-1 31 6 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1141
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
ug/L
Ca EaFA-L09-1316-T01-A 1 1.60E+05
Ca EaFA-L09-1316-T02-A 1 3.24E+05
Ca EaFA-L09-1316-T03-A 1 7.66E+05
Ca EaFA-L09-1316-T04-A 1 5.90E+05
Ca EaFA-L09-1316-T05-A 1 4.51 E+05
Ca EaFA-L09-1316-T01-B 1 1.64E+05
Ca EaFA-L09-1316-T02-B 1 3.27E+05
Ca EaFA-L09-1316-T03-B 1 7.74E+05
Ca EaFA-L09-1316-T04-B 1 5.74E+05
Ca EaFA-L09-1316-T05-B 1 2.84E+05
Ca EaFA-L09-1316-T01-C 1 1.59E+05
Ca EaFA-L09-1316-T02-C 1 3.23E+05
Ca EaFA-L09-1316-T03-C 1 7.76E+05
Ca EaFA-L09-1316-T04-C 1 5.97E+05
Ca EaFA-L09-1316-T05-C 1 3.52E+05
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.60E+05 7.3E-01 2.60E+00 8.30E+00
3.24E+05 4.2E-01 2.60E+00 8.30E+00 1000 100
7.66E+05 1.4E+00 2.60E+00 8.30E+00
5.90E+05 1.4E+00 2.60E+00 8.30E+00
4.51 E+05 8.6E+00 2.60E+00 8.30E+00
1.64E+05 4.3E-01 2.60E+00 8.30E+00
3.27E+05 8.0E-01 2.60E+00 8.30E+00 1000 100
7.74E+05 4.6E-01 2.60E+00 8.30E+00
5.74E+05 2.7E+00 2.60E+00 8.30E+00
2.84E+05 8.1E+01 2.60E+00 8.30E+00
1.59E+05 5.0E-01 2.60E+00 8.30E+00
3.23E+05 4.5E-01 2.60E+00 8.30E+00 1000 100
7.76E+05 6.8E-01 2.60E+00 8.30E+00
5.97E+05 3.9E-01 2.60E+00 8.30E+00
3.52E+05 4.4E+01 2.60E+00 8.30E+00
Ca EaFA-L09-1316-B01-A 1 1.30E+OOU1/2 1.30E+00 3.8E+02 2.60E+00 8.30E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.25E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.27E+05 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.24E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1142
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone.
ug/L
Cr EaFA-L09-1316-T01-A 1 1.70E+01
Cr EaFA-L09-1316-T02-A 1 2.24E+01
Cr EaFA-L09-1316-T03-A 1 2.62E+01
Cr EaFA-L09-1316-T04-A 1 4.89E+01
Cr EaFA-L09-1316-T05-A 1 2.16E+01
Cr EaFA-L09-1316-T01-B 1 1.52E+01
Cr EaFA-L09-1316-T02-B 1 2.30E+01
Cr EaFA-L09-1316-T03-B 1 2.63E+01
Cr EaFA-L09-1316-T04-B 1 4.96E+01
Cr EaFA-L09-1316-T05-B 1 4.30E+01
Cr EaFA-L09-1316-T01-C 1 1.51E+01
Cr EaFA-L09-1316-T02-C 1 2.41E+01
Cr EaFA-L09-1316-T03-C 1 2.55E+01
Cr EaFA-L09-1316-T04-C 1 4.88E+01
Cr EaFA-L09-1316-T05-C 1 3.09E+01
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.70E+01 2.2E+00 1.20E+00 3.82E+00
2.24E+01 3.5E+00 1.20E+00 3.82E+00 10 325
2.62E+01 1.1E+00 1.20E+00 3.82E+00
4.89E+01 3.4E+00 1.20E+00 3.82E+00
2.16E+01 1.1E+01 1.20E+00 3.82E+00
1.52E+01 1.3E+01 1.20E+00 3.82E+00
2.30E+01 4.5E+00 1.20E+00 3.82E+00 10 325
2.63E+01 1.4E+00 1.20E+00 3.82E+00
4.96E+01 8.4E-01 1.20E+00 3.82E+00
4.30E+01 8.5E+01 1.20E+00 3.82E+00
1.51E+01 6.7E+00 1.20E+00 3.82E+00
2.41E+01 6.3E+00 1.20E+00 3.82E+00 10 325
2.55E+01 7.1E+00 1.20E+00 3.82E+00
4.88E+01 2.3E+00 1.20E+00 3.82E+00
3.09E+01 5.1E+01 1.20E+00 3.82E+00
Cr EaFA-L09-1316-B01-A 1 1.23E+OOE 1.23E+00 1.7E+02 1.20E+00 3.82E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.26E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.37E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.38E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1143
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-L09-1316-T01-A 1
Co EaFA-L09-1316-T02-A 1
Co EaFA-L09-1316-T03-A 1
Co EaFA-L09-1316-T04-A 1
Co EaFA-L09-1316-T05-A 1
Co EaFA-L09-1316-T01-B 1
Co EaFA-L09-1316-T02-B 1
Co EaFA-L09-1316-T03-B 1
Co EaFA-L09-1316-T04-B 1
Co EaFA-L09-1316-T05-B 1
Co EaFA-L09-1316-T01-C 1
Co EaFA-L09-1316-T02-C 1
Co EaFA-L09-1316-T03-C 1
Co EaFA-L09-1316-T04-C 1
Co EaFA-L09-1316-T05-C 1
Co EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
4.36E+01
7.93E+01
2.11E+02
1.27E+02
4.10E+02
4.99E+01
9.19E+01
2.15E+02
1.23E+02
4.91E+01
4.59E+01
8.47E+01
2.19E+02
1 .36E+02
3.14E+02
9.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.36E+01 6.0E+00 1.80E+00 5.72E+00
7.93E+01 3.9E+00 1.80E+00 5.72E+00 10 325
2.11E+02 1.6E+00 1.80E+00 5.72E+00
1.27E+02 3.1E+00 1.80E+00 5.72E+00
4.10E+02 7.7E+00 1.80E+00 5.72E+00
4.99E+01 2.1E+00 1.80E+00 5.72E+00
9.19E+01 3.4E+00 1.80E+00 5.72E+00 10 325
2.15E+02 9.0E-01 1.80E+00 5.72E+00
1.23E+02 3.1E+00 1.80E+00 5.72E+00
4.91 E+01 8.0E+01 1.80E+00 5.72E+00
4.59E+01 1.8E+00 1.80E+00 5.72E+00
8.47E+01 1.9E+00 1.80E+00 5.72E+00 10 325
2.19E+02 1.2E+00 1.80E+00 5.72E+00
1.36E+02 2.2E+00 1.80E+00 5.72E+00
3.14E+02 4.8E+01 1.80E+00 5.72E+00
9.00E-01 1.7E+02 1.80E+00 5.72E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.30E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.43E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.43E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1144
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone.
ug/L
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cu EaFA-L09-1316-T01-A 1 1.01E+01 E 1.01E+01 4.4E+01 3.70E+00 1.18E+01
Cu EaFA-L09-1316-T02-A 1 1.37E+01
Cu EaFA-L09-1316-T03-A 1 1.65E+01
Cu EaFA-L09-1316-T04-A 1 1.52E+01
Cu EaFA-L09-1316-T05-A 1 1.93E+01
1.37E+01 2.9E+01 3.70E+00 1.18E+01 10 325
1.65E+01 3.1E+01 3.70E+00 1.18E+01
1.52E+01 1.5E+01 3.70E+00 1.18E+01
1.93E+01 5.2E+01 3.70E+00 1.18E+01
Cu EaFA-L09-1316-T01-B 1 1.02E+01 E 1.02E+01 4.4E+01 3.70E+00 1.18E+01
Cu EaFA-L09-1316-T02-B 1 1.33E+01
Cu EaFA-L09-1316-T03-B 1 1.40E+01
Cu EaFA-L09-1316-T04-B 1 1.37E+01
Cu EaFA-L09-1316-T05-B 1 1.34E+01
1.33E+01 5.4E+01 3.70E+00 1.18E+01 10 325
1.40E+01 6.6E+00 3.70E+00 1.18E+01
1.37E+01 1.1E+01 3.70E+00 1.18E+01
1.34E+01 9.7E+01 3.70E+00 1.18E+01
Cu EaFA-L09-1316-T01-C 1 8.47E+00 E 8.47E+00 2.7E+01 3.70E+00 1.18E+01
Cu EaFA-L09-1316-T02-C 1 7.14E+00 E 7.14E+00 6.4E+01 3.70E+00 1.18E+01 10 325
Cu EaFA-L09-1316-T03-C 1 1.76E+01
Cu EaFA-L09-1316-T04-C 1 1.48E+01
Cu EaFA-L09-1316-T05-C 1 2.17E+01
1.76E+01 3.1E+01 3.70E+00 1.18E+01
1.48E+01 2.4E+01 3.70E+00 1.18E+01
2.17E+01 4.9E+01 3.70E+00 1.18E+01
Cu EaFA-L09-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 2.3E+02 3.70E+00 1.18E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.29E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.38E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.40E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1145
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L09-1316-T01-A 1
Fe EaFA-L09-1316-T02-A 1
Fe EaFA-L09-1316-T03-A 1
Fe EaFA-L09-1316-T04-A 1
Fe EaFA-L09-1316-T05-A 1
Fe EaFA-L09-1316-T01-B 1
Fe EaFA-L09-1316-T02-B 1
Fe EaFA-L09-1316-T03-B 1
Fe EaFA-L09-1316-T04-B 1
Fe EaFA-L09-1316-T05-B 1
Fe EaFA-L09-1316-T01-C 1
Fe EaFA-L09-1316-T02-C 1
Fe EaFA-L09-1316-T03-C 1
Fe EaFA-L09-1316-T04-C 1
Fe EaFA-L09-1316-T05-C 1
Fe EaFA-L09-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.97E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.45E+00 E
2.40E+00 E
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.0E+02 2.00E+00 6.40E+00
1.00E+00 1.3E+02 2.00E+00 6.40E+00 1000 100
1.00E+00 1.8E+02 2.00E+00 6.40E+00
1.00E+00 3.1E+02 2.00E+00 6.40E+00
2.97E+00 1.9E+01 2.00E+00 6.40E+00
1.00E+00 1.1E+01 2.00E+00 6.40E+00
1.00E+00 1.1E+02 2.00E+00 6.40E+00 1000 100
1.00E+00 8.0E+02 2.00E+00 6.40E+00
1.00E+00 1.5E+02 2.00E+00 6.40E+00
1.00E+00 2.1E+02 2.00E+00 6.40E+00
1.00E+00 1.4E+02 2.00E+00 6.40E+00
1.00E+00 2.0E+02 2.00E+00 6.40E+00 1000 100
1.00E+00 5.8E+02 2.00E+00 6.40E+00
2.45E+00 1.4E+01 2.00E+00 6.40E+00
2.40E+00 1.0E+02 2.00E+00 6.40E+00
1.00E+00 1.9E+02 2.00E+00 6.40E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1146
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L09-1316-T01-A 1
Pb EaFA-L09-1316-T02-A 1
Pb EaFA-L09-1316-T03-A 1
Pb EaFA-L09-1316-T04-A 1
Pb EaFA-L09-1316-T05-A 1
Pb EaFA-L09-1316-T01-B 1
Pb EaFA-L09-1316-T02-B 1
Pb EaFA-L09-1316-T03-B 1
Pb EaFA-L09-1316-T04-B 1
Pb EaFA-L09-1316-T05-B 1
Pb EaFA-L09-1316-T01-C 1
Pb EaFA-L09-1316-T02-C 1
Pb EaFA-L09-1316-T03-C 1
Pb EaFA-L09-1316-T04-C 1
Pb EaFA-L09-1316-T05-C 1
Pb EaFA-L09-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 2.4E+02 6.80E+00 2.16E+01
3.40E+00 8.2E+01 6.80E+00 2.16E+01 10 325
3.40E+00 7.6E+02 6.80E+00 2.16E+01
3.40E+00 8.4E+01 6.80E+00 2.16E+01
3.40E+00 5.0E+01 6.80E+00 2.16E+01
3.40E+00 3.6E+01 6.80E+00 2.16E+01
3.40E+00 1.2E+02 6.80E+00 2.16E+01 10 325
3.40E+00 8.0E+01 6.80E+00 2.16E+01
3.40E+00 2.0E+01 6.80E+00 2.16E+01
3.40E+00 1.3E+02 6.80E+00 2.16E+01
3.40E+00 2.8E+02 6.80E+00 2.16E+01
3.40E+00 2.4E+01 6.80E+00 2.16E+01 10 325
3.40E+00 2.5E+03 6.80E+00 2.16E+01
3.40E+00 2.5E+03 6.80E+00 2.16E+01
3.40E+00 8.7E+01 6.80E+00 2.16E+01
3.40E+00 1.3E+02 6.80E+00 2.16E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.20E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.33E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1147
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFA-L09-1316-T01-A 1
Li EaFA-L09-1316-T02-A 1
Li EaFA-L09-1316-T03-A 1
Li EaFA-L09-1316-T04-A 1
Li EaFA-L09-1316-T05-A 1
Li EaFA-L09-1316-T01-B 1
Li EaFA-L09-1316-T02-B 1
Li EaFA-L09-1316-T03-B 1
Li EaFA-L09-1316-T04-B 1
Li EaFA-L09-1316-T05-B 1
Li EaFA-L09-1316-T01-C 1
Li EaFA-L09-1316-T02-C 1
Li EaFA-L09-1316-T03-C 1
Li EaFA-L09-1316-T04-C 1
Li EaFA-L09-1316-T05-C 1
Li EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
4.05E+03
7.99E+03
1.94E+04
3.80E+04
7.38E+04
4.15E+03
8.09E+03
1.98E+04
3.74E+04
3.69E+04
4.04E+03
8.00E+03
1.98E+04
3.90E+04
5.24E+04
2.00E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.05E+03 8.8E-01 1.90E+00 6.00E+00
7.99E+03 2.3E-01 1.90E+00 6.00E+00 10 325
1.94E+04 1.1E+00 1.90E+00 6.00E+00
3.80E+04 1.3E+00 1.90E+00 6.00E+00
7.38E+04 8.5E+00 1.90E+00 6.00E+00
4.15E+03 6.8E-01 1.90E+00 6.00E+00
8.09E+03 5.9E-01 1.90E+00 6.00E+00 10 325
1.98E+04 8.0E-01 1.90E+00 6.00E+00
3.74E+04 2.5E+00 1.90E+00 6.00E+00
3.69E+04 8.3E+01 1.90E+00 6.00E+00
4.04E+03 1.1E+00 1.90E+00 6.00E+00
8.00E+03 4.1E-01 1.90E+00 6.00E+00 10 325
1.98E+04 7.6E-01 1.90E+00 6.00E+00
3.90E+04 2.5E-01 1.90E+00 6.00E+00
5.24E+04 4.4E+01 1.90E+00 6.00E+00
2.00E+00 1.2E+02 1.90E+00 6.00E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .08E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1148
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. Qu
ug/L
Mn EaFA-L09-1316-T01-A 1 3.66E+02
Mn EaFA-L09-1316-T02-A 1 6.64E+02
Mn EaFA-L09-1316-T03-A 1 1.63E+03
Mn EaFA-L09-1316-T04-A 1 1.32E+03
Mn EaFA-L09-1316-T05-A 1 4.02E+03
Mn EaFA-L09-1316-T01-B 1 4.05E+02
Mn EaFA-L09-1316-T02-B 1 7.23E+02
Mn EaFA-L09-1316-T03-B 1 1.66E+03
Mn EaFA-L09-1316-T04-B 1 1.29E+03
Mn EaFA-L09-1316-T05-B 1 7.74E+02
Mn EaFA-L09-1316-T01-C 1 3.84E+02
Mn EaFA-L09-1316-T02-C 1 6.82E+02
Mn EaFA-L09-1316-T03-C 1 1.70E+03
Mn EaFA-L09-1316-T04-C 1 1.44E+03
Mn EaFA-L09-1316-T05-C 1 2.64E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.66E+02 7.2E-01 2.00E+00 6.40E+00
6.64E+02 1.5E-01 2.00E+00 6.40E+00 10 325
1.63E+03 9.7E-01 2.00E+00 6.40E+00
1.32E+03 1.2E+00 2.00E+00 6.40E+00
4.02E+03 8.7E+00 2.00E+00 6.40E+00
4.05E+02 5.3E-01 2.00E+00 6.40E+00
7.23E+02 1.6E+00 2.00E+00 6.40E+00 10 325
1.66E+03 6.8E-01 2.00E+00 6.40E+00
1.29E+03 2.4E+00 2.00E+00 6.40E+00
7.74E+02 7.6E+01 2.00E+00 6.40E+00
3.84E+02 2.1E-01 2.00E+00 6.40E+00
6.82E+02 6.9E-01 2.00E+00 6.40E+00 10 325
1.70E+03 8.6E-01 2.00E+00 6.40E+00
1.44E+03 7.3E-01 2.00E+00 6.40E+00
2.64E+03 4.9E+01 2.00E+00 6.40E+00
Mn EaFA-L09-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 1.8E+01 2.00E+00 6.40E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.01E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.22E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.18E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1149
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFA-L09-1316-T01-A 1
Mg EaFA-L09-1316-T02-A 1
Mg EaFA-L09-1316-T03-A 1
Mg EaFA-L09-1316-T04-A 1
Mg EaFA-L09-1316-T05-A 1
Mg EaFA-L09-1316-T01-B 1
Mg EaFA-L09-1316-T02-B 1
Mg EaFA-L09-1316-T03-B 1
Mg EaFA-L09-1316-T04-B 1
Mg EaFA-L09-1316-T05-B 1
Mg EaFA-L09-1316-T01-C 1
Mg EaFA-L09-1316-T02-C 1
Mg EaFA-L09-1316-T03-C 1
Mg EaFA-L09-1316-T04-C 1
Mg EaFA-L09-1316-T05-C 1
Mg EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
7.56E+03
1.54E+04
3.90E+04
7.17E+04
1.35E+05
7.77E+03
1.55E+04
3.98E+04
7.07E+04
6.32E+04
7.55E+03
1.52E+04
3.98E+04
7.49E+04
9.15E+04
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.56E+03 1.4E+00 1.00E+00 3.18E+00
1.54E+04 2.7E-01 1.00E+00 3.18E+00 1000 100
3.90E+04 6.3E-01 1.00E+00 3.18E+00
7.17E+04 1.7E+00 1.00E+00 3.18E+00
1.35E+05 8.9E+00 1.00E+00 3.18E+00
7.77E+03 8.4E-01 1.00E+00 3.18E+00
1.55E+04 7.6E-01 1.00E+00 3.18E+00 1000 100
3.98E+04 2.7E-01 1.00E+00 3.18E+00
7.07E+04 3.0E+00 1.00E+00 3.18E+00
6.32E+04 8.0E+01 1.00E+00 3.18E+00
7.55E+03 1.3E+00 1.00E+00 3.18E+00
1.52E+04 7.8E-01 1.00E+00 3.18E+00 1000 100
3.98E+04 4.3E-01 1.00E+00 3.18E+00
7.49E+04 3.7E-01 1.00E+00 3.18E+00
9.15E+04 5.1E+01 1.00E+00 3.18E+00
5.00E-01 4.1E+01 1.00E+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .63E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .63E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .61 E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1150
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo EaFA-L09-1316-T01-A 1
Mo EaFA-L09-1316-T02-A 1
Mo EaFA-L09-1316-T03-A 1
Mo EaFA-L09-1316-T04-A 1
Mo EaFA-L09-1316-T05-A 1
Mo EaFA-L09-1316-T01-B 1
Mo EaFA-L09-1316-T02-B 1
Mo EaFA-L09-1316-T03-B 1
Mo EaFA-L09-1316-T04-B 1
Mo EaFA-L09-1316-T05-B 1
Mo EaFA-L09-1316-T01-C 1
Mo EaFA-L09-1316-T02-C 1
Mo EaFA-L09-1316-T03-C 1
Mo EaFA-L09-1316-T04-C 1
Mo EaFA-L09-1316-T05-C 1
Mo EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
3.64E+03
6.91 E+03
1.48E+04
2.97E+04
3.14E+04
3.69E+03
6.85E+03
1.51E+04
2.87E+04
2.73E+04
3.63E+03
6.83E+03
1 .49E+04
2.88E+04
2.45E+04
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.64E+03 2.0E-01 1.20E+00 3.82E+00
6.91E+03 2.4E-01 1.20E+00 3.82E+00 10 325
1.48E+04 1.2E+00 1.20E+00 3.82E+00
2.97E+04 1.3E+00 1.20E+00 3.82E+00
3.14E+04 9.1E+00 1.20E+00 3.82E+00
3.69E+03 1.3E+00 1.20E+00 3.82E+00
6.85E+03 9.5E-01 1.20E+00 3.82E+00 10 325
1.51E+04 3.9E-01 1.20E+00 3.82E+00
2.87E+04 2.3E+00 1.20E+00 3.82E+00
2.73E+04 7.6E+01 1.20E+00 3.82E+00
3.63E+03 8.2E-01 1.20E+00 3.82E+00
6.83E+03 5.3E-01 1.20E+00 3.82E+00 10 325
1.49E+04 9.7E-01 1.20E+00 3.82E+00
2.88E+04 2.3E-01 1.20E+00 3.82E+00
2.45E+04 4.6E+01 1.20E+00 3.82E+00
6.00E-01 1.1 E+03 1.20E+00 3.82E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.58E+03 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91 E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1151
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone.
ug/L
Ni EaFA-L09-1316-T01-A 1 1.01E+02
Ni EaFA-L09-1316-T02-A 1 1.82E+02
Ni EaFA-L09-1316-T03-A 1 4.76E+02
Ni EaFA-L09-1316-T04-A 1 2.95E+02
Ni EaFA-L09-1316-T05-A 1 8.56E+02
Ni EaFA-L09-1316-T01-B 1 1.16E+02
Ni EaFA-L09-1316-T02-B 1 2.12E+02
Ni EaFA-L09-1316-T03-B 1 4.85E+02
Ni EaFA-L09-1316-T04-B 1 2.79E+02
Ni EaFA-L09-1316-T05-B 1 1.22E+02
Ni EaFA-L09-1316-T01-C 1 1.11E+02
Ni EaFA-L09-1316-T02-C 1 1.97E+02
Ni EaFA-L09-1316-T03-C 1 4.94E+02
Ni EaFA-L09-1316-T04-C 1 3.14E+02
Ni EaFA-L09-1316-T05-C 1 6.68E+02
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.01E+02 4.7E+00 1.80E+00 5.70E+00
1.82E+02 1.2E+00 1.80E+00 5.70E+00 10 325
4.76E+02 6.6E-01 1.80E+00 5.70E+00
2.95E+02 2.2E+00 1.80E+00 5.70E+00
8.56E+02 8.3E+00 1.80E+00 5.70E+00
1.16E+02 2.9E+00 1.80E+00 5.70E+00
2.12E+02 3.9E-01 1.80E+00 5.70E+00 10 325
4.85E+02 6.6E-01 1.80E+00 5.70E+00
2.79E+02 8.4E-01 1.80E+00 5.70E+00
1.22E+02 8.6E+01 1.80E+00 5.70E+00
1.11E+02 3.9E+00 1.80E+00 5.70E+00
1.97E+02 1.8E+00 1.80E+00 5.70E+00 10 325
4.94E+02 7.3E-01 1.80E+00 5.70E+00
3.14E+02 1.1E+00 1.80E+00 5.70E+00
6.68E+02 4.9E+01 1.80E+00 5.70E+00
Ni EaFA-L09-1316-B01-A 1 3.71E+00 E 3.71E+00 6.8E+01 1.80E+00 5.70E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.44E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.60E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.58E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1152
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P EaFA-L09-1316-T01-A 1
P EaFA-L09-1316-T02-A 1
P EaFA-L09-1316-T03-A 1
P EaFA-L09-1316-T04-A 1
P EaFA-L09-1316-T05-A 1
P EaFA-L09-1316-T01-B 1
P EaFA-L09-1316-T02-B 1
P EaFA-L09-1316-T03-B 1
P EaFA-L09-1316-T04-B 1
P EaFA-L09-1316-T05-B 1
P EaFA-L09-1316-T01-C 1
P EaFA-L09-1316-T02-C 1
P EaFA-L09-1316-T03-C 1
P EaFA-L09-1316-T04-C 1
P EaFA-L09-1316-T05-C 1
P EaFA-L09-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
2.47E+01
5.27E+01
8.21E+01
4.40E+02
1.47E+02
5.20E+01
5.07E+01
2.21E+02
2.68E+02
1.40E+02
5.85E+01
6.98E+01
2.32E+02
4.79E+02
1.08E+02
1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.47E+01 8.3E+00 3.70E+00 1.18E+01
5.27E+01 1.4E+01 3.70E+00 1.18E+01 1000 100
8.21E+01 3.1E+01 3.70E+00 1.18E+01
4.40E+02 7.2E+00 3.70E+00 1.18E+01
1.47E+02 3.5E+01 3.70E+00 1.18E+01
5.20E+01 1.5E+01 3.70E+00 1.18E+01
5.07E+01 7.5E+00 3.70E+00 1.18E+01 1000 100
2.21E+02 7.5E+00 3.70E+00 1.18E+01
2.68E+02 8.6E+00 3.70E+00 1.18E+01
1.40E+02 1.4E+02 3.70E+00 1.18E+01
5.85E+01 2.4E+01 3.70E+00 1.18E+01
6.98E+01 1.6E+01 3.70E+00 1.18E+01 1000 100
2.32E+02 1.3E+01 3.70E+00 1.18E+01
4.79E+02 3.8E+00 3.70E+00 1.18E+01
1.08E+02 2.2E+01 3.70E+00 1.18E+01
1.85E+00 1.0E+01 3.70E+00 1.18E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.08E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1153
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K EaFA-L09-1316-T01-A 1
K EaFA-L09-1316-T02-A 1
K EaFA-L09-1316-T03-A 1
K EaFA-L09-1316-T04-A 1
K EaFA-L09-1316-T05-A 1
K EaFA-L09-1316-T01-B 1
K EaFA-L09-1316-T02-B 1
K EaFA-L09-1316-T03-B 1
K EaFA-L09-1316-T04-B 1
K EaFA-L09-1316-T05-B 1
K EaFA-L09-1316-T01-C 1
K EaFA-L09-1316-T02-C 1
K EaFA-L09-1316-T03-C 1
K EaFA-L09-1316-T04-C 1
K EaFA-L09-1316-T05-C 1
K EaFA-L09-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
2.47E+01
5.27E+01
8.21E+01
4.40E+02
1.47E+02
5.20E+01
5.07E+01
2.21E+02
2.68E+02
1.40E+02
5.85E+01
6.98E+01
2.32E+02
4.79E+02
1.08E+02
7.73E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.47E+01 6.5E-01 1.60E+00 5.09E+00
5.27E+01 8.3E-01 1.60E+00 5.09E+00 1000 100
8.21 E+01 7.1E-01 1.60E+00 5.09E+00
4.40E+02 8.0E-01 1.60E+00 5.09E+00
1.47E+02 8.9E+00 1.60E+00 5.09E+00
5.20E+01 3.7E-01 1.60E+00 5.09E+00
5.07E+01 7.9E-01 1.60E+00 5.09E+00 1000 100
2.21 E+02 3.8E-01 1.60E+00 5.09E+00
2.68E+02 2.1E+00 1.60E+00 5.09E+00
1.40E+02 8.3E+01 1.60E+00 5.09E+00
5.85E+01 8.6E-01 1.60E+00 5.09E+00
6.98E+01 4.1E-01 1.60E+00 5.09E+00 1000 100
2.32E+02 3.5E-01 1.60E+00 5.09E+00
4.79E+02 9.2E-01 1.60E+00 5.09E+00
1.08E+02 5.3E+01 1.60E+00 5.09E+00
7.73E+01 3.0E+00 1.60E+00 5.09E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9.28E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91 E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .02E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1154
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se EaFA-L09-1316-T01-A 1
Se EaFA-L09-1316-T02-A 1
Se EaFA-L09-1316-T03-A 1
Se EaFA-L09-1316-T04-A 1
Se EaFA-L09-1316-T05-A 1
Se EaFA-L09-1316-T01-B 1
Se EaFA-L09-1316-T02-B 1
Se EaFA-L09-1316-T03-B 1
Se EaFA-L09-1316-T04-B 1
Se EaFA-L09-1316-T05-B 1
Se EaFA-L09-1316-T01-C 1
Se EaFA-L09-1316-T02-C 1
Se EaFA-L09-1316-T03-C 1
Se EaFA-L09-1316-T04-C 1
Se EaFA-L09-1316-T05-C 1
Se EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
1.24E+03
1.44E+03
1.52E+03
2.21E+03
1.87E+03
1.27E+03
1.45E+03
1.58E+03
2.17E+03
2.19E+03
1.17E+03
1.45E+03
1.53E+03
2.00E+03
1.81E+03
8.30E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.24E+03 1.5E+00 1.50E+01 4.77E+01
1.44E+03 7.2E-01 1.50E+01 4.77E+01 10 325
1.52E+03 1.2E+00 1.50E+01 4.77E+01
2.21 E+03 1.3E+00 1.50E+01 4.77E+01
1.87E+03 7.9E+00 1.50E+01 4.77E+01
1.27E+03 2.5E+00 1.50E+01 4.77E+01
1.45E+03 1.8E+00 1.50E+01 4.77E+01 10 325
1.58E+03 2.3E+00 1.50E+01 4.77E+01
2.17E+03 4.5E+00 1.50E+01 4.77E+01
2.19E+03 8.0E+01 1.50E+01 4.77E+01
1.17E+03 1.6E+00 1.50E+01 4.77E+01
1.45E+03 1.4E+00 1.50E+01 4.77E+01 10 325
1.53E+03 4.1E+00 1.50E+01 4.77E+01
2.00E+03 1.2E+00 1.50E+01 4.77E+01
1.81 E+03 4.6E+01 1.50E+01 4.77E+01
8.30E+01 3.4E+01 1.50E+01 4.77E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.57E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.72E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.75E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1155
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si EaFA-L09-1316-T01-A 1
Si EaFA-L09-1316-T02-A 1
Si EaFA-L09-1316-T03-A 1
Si EaFA-L09-1316-T04-A 1
Si EaFA-L09-1316-T05-A 1
Si EaFA-L09-1316-T01-B 1
Si EaFA-L09-1316-T02-B 1
Si EaFA-L09-1316-T03-B 1
Si EaFA-L09-1316-T04-B 1
Si EaFA-L09-1316-T05-B 1
Si EaFA-L09-1316-T01-C 1
Si EaFA-L09-1316-T02-C 1
Si EaFA-L09-1316-T03-C 1
Si EaFA-L09-1316-T04-C 1
Si EaFA-L09-1316-T05-C 1
Si EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
2.21E+03
2.30E+03
2.64E+03
2.12E+03
2.80E+03
2.36E+03
2.47E+03
2.71E+03
2.08E+03
1.08E+03
2.26E+03
2.38E+03
2.72E+03
2.12E+03
2.02E+03
5.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.21E+03 1.1E+00 1.10E+00 3.50E+00
2.30E+03 1.7E-01 1.10E+00 3.50E+00 1000 100
2.64E+03 1.8E+00 1.10E+00 3.50E+00
2.12E+03 5.5E-01 1.10E+00 3.50E+00
2.80E+03 1.0E+01 1.10E+00 3.50E+00
2.36E+03 9.7E-01 1.10E+00 3.50E+00
2.47E+03 2.1E+00 1.10E+00 3.50E+00 1000 100
2.71E+03 8.3E-01 1.10E+00 3.50E+00
2.08E+03 2.3E+00 1.10E+00 3.50E+00
1.08E+03 8.5E+01 1.10E+00 3.50E+00
2.26E+03 9.2E-01 1.10E+00 3.50E+00
2.38E+03 6.8E-01 1.10E+00 3.50E+00 1000 100
2.72E+03 8.6E-01 1.10E+00 3.50E+00
2.12E+03 4.4E-01 1.10E+00 3.50E+00
2.02E+03 5.9E+01 1.10E+00 3.50E+00
5.50E-01 1.6E+02 1.10E+00 3.50E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.16E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.34E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.28E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1156
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFA-L09-1316-T01-A 1
Na EaFA-L09-1316-T02-A 1
Na EaFA-L09-1316-T03-A 1
Na EaFA-L09-1316-T04-A 1
Na EaFA-L09-1316-T05-A 1
Na EaFA-L09-1316-T01-B 1
Na EaFA-L09-1316-T02-B 1
Na EaFA-L09-1316-T03-B 1
Na EaFA-L09-1316-T04-B 1
Na EaFA-L09-1316-T05-B 1
Na EaFA-L09-1316-T01-C 1
Na EaFA-L09-1316-T02-C 1
Na EaFA-L09-1316-T03-C 1
Na EaFA-L09-1316-T04-C 1
Na EaFA-L09-1316-T05-C 1
Na EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
5.45E+03
1.13E+04
2.87E+04
4.73E+04
8.84E+04
5.54E+03
1.14E+04
2.91 E+04
4.67E+04
4.81 E+04
5.42E+03
1.13E+04
2.94E+04
4.93E+04
6.15E+04
2.46E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.45E+03 1.0E+00 2.50E+00 8.00E+00
1.13E+04 4.5E-01 2.50E+00 8.00E+00 1000 100
2.87E+04 8.5E-01 2.50E+00 8.00E+00
4.73E+04 1.5E+00 2.50E+00 8.00E+00
8.84E+04 8.6E+00 2.50E+00 8.00E+00
5.54E+03 3.7E-01 2.50E+00 8.00E+00
1.14E+04 3.0E-01 2.50E+00 8.00E+00 1000 100
2.91 E+04 5.1E-01 2.50E+00 8.00E+00
4.67E+04 2.3E+00 2.50E+00 8.00E+00
4.81 E+04 8.4E+01 2.50E+00 8.00E+00
5.42E+03 7.0E-01 2.50E+00 8.00E+00
1.13E+04 6.7E-01 2.50E+00 8.00E+00 1000 100
2.94E+04 6.8E-01 2.50E+00 8.00E+00
4.93E+04 5.0E-01 2.50E+00 8.00E+00
6.15E+04 5.2E+01 2.50E+00 8.00E+00
2.46E+01 1.1E+00 2.50E+00 8.00E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1 .22E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .23E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .24E+04 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/1012:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1157
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone.
EaFA-L09-1316-T01-A 1 2.18E+03
EaFA-L09-1316-T02-A 1 3.98E+03
EaFA-L09-1316-T03-A 1 8.52E+03
EaFA-L09-1316-T04-A 1 7.93E+03
EaFA-L09-1316-T05-A 1 7.93E+03
EaFA-L09-1316-T01-B 1 2.23E+03
EaFA-L09-1316-T02-B 1 4.08E+03
EaFA-L09-1316-T03-B 1 8.69E+03
EaFA-L09-1316-T04-B 1 7.94E+03
EaFA-L09-1316-T05-B 1 4.36E+03
EaFA-L09-1316-T01-C 1 2.17E+03
EaFA-L09-1316-T02-C 1 3.97E+03
EaFA-L09-1316-T03-C 1 8.65E+03
EaFA-L09-1316-T04-C 1 8.23E+03
EaFA-L09-1316-T05-C 1 6.58E+03
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.18E+03 6.1E-01 1.00E+00 3.18E+00
3.98E+03 5.8E-01 1.00E+00 3.18E+00 1000 100
8.52E+03 9.2E-01 1.00E+00 3.18E+00
7.93E+03 8.1E-01 1.00E+00 3.18E+00
7.93E+03 7.6E+00 1.00E+00 3.18E+00
2.23E+03 5.3E-01 1.00E+00 3.18E+00
4.08E+03 1.2E+00 1.00E+00 3.18E+00 1000 100
8.69E+03 5.5E-01 1.00E+00 3.18E+00
7.94E+03 2.3E+00 1.00E+00 3.18E+00
4.36E+03 7.6E+01 1.00E+00 3.18E+00
2.17E+03 5.5E-01 1.00E+00 3.18E+00
3.97E+03 7.9E-01 1.00E+00 3.18E+00 1000 100
8.65E+03 1.0E+00 1.00E+00 3.18E+00
8.23E+03 8.1E-01 1.00E+00 3.18E+00
6.58E+03 2.2E+01 1.00E+00 3.18E+00
EaFA-L09-1316-B01-A 1 5.00E-01 U1/2 5.00E-01 2.7E+02 1.00E+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4.86E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.97E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.79E+03 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1158
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S EaFA-L09-1316-T01-A 1
S EaFA-L09-1316-T02-A 1
S EaFA-L09-1316-T03-A 1
S EaFA-L09-1316-T04-A 1
S EaFA-L09-1316-T05-A 1
S EaFA-L09-1316-T01-B 1
S EaFA-L09-1316-T02-B 1
S EaFA-L09-1316-T03-B 1
S EaFA-L09-1316-T04-B 1
S EaFA-L09-1316-T05-B 1
S EaFA-L09-1316-T01-C 1
S EaFA-L09-1316-T02-C 1
S EaFA-L09-1316-T03-C 1
S EaFA-L09-1316-T04-C 1
S EaFA-L09-1316-T05-C 1
S EaFA-L09-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L 1
1.59E+05
3.16E+05
7.35E+05
7.55E+05
9.36E+05
1.62E+05
3.17E+05
7.53E+05
7.38E+05
5.05E+05
1.58E+05
3.15E+05
7.43E+05
7.56E+05
6.56E+05
3.40E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+05 6.0E-01 6.80E+00 2.16E+01
3.16E+05 2.0E-01 6.80E+00 2.16E+01 1000 100
7.35E+05 8.7E-01 6.80E+00 2.16E+01
7.55E+05 1.2E+00 6.80E+00 2.16E+01
9.36E+05 9.1E+00 6.80E+00 2.16E+01
1.62E+05 6.9E-01 6.80E+00 2.16E+01
3.17E+05 6.8E-01 6.80E+00 2.16E+01 1000 100
7.53E+05 3.1E-01 6.80E+00 2.16E+01
7.38E+05 2.3E+00 6.80E+00 2.16E+01
5.05E+05 8.3E+01 6.80E+00 2.16E+01
1.58E+05 5.5E-01 6.80E+00 2.16E+01
3.15E+05 5.2E-01 6.80E+00 2.16E+01 1000 100
7.43E+05 7.8E-01 6.80E+00 2.16E+01
7.56E+05 4.5E-01 6.80E+00 2.16E+01
6.56E+05 5.4E+01 6.80E+00 2.16E+01
3.40E+00 1.9E+02 6.80E+00 2.16E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.17E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+05 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.16E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/1 1/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1159
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone.
ug/L
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl EaFA-L09-1316-T01-A 1 8.41 E+00 E 8.41 E+00 1 .4E+02 4.60E+00 1 .46E+01
Tl EaFA-L09-1316-T02-A 1 1.11E+01 E 1.11E+01 8.9E+01 4.60E+00 1 .46E+01 10 325
Tl EaFA-L09-1316-T03-A 1 1.81E+01
1.81E+01 4.4E+01 4.60E+00 1 .46E+01
Tl EaFA-L09-1316-T04-A 1 2.30E+00 U1/2 2.30E+00 2.6E+02 4.60E+00 1 .46E+01
Tl EaFA-L09-1316-T05-A 1 4.27E+01
4.27E+01 4.6E+01 4.60E+00 1 .46E+01
Tl EaFA-L09-1316-T01-B 1 9.64E+00 E 9.64E+00 2.1E+02 4.60E+00 1 .46E+01
Tl EaFA-L09-1316-T02-B 1 2.08E+01
2.08E+01 2.1E+01 4.60E+00 1 .46E+01 10 325
Tl EaFA-L09-1316-T03-B 1 6.71 E+00 E 6.71E+00 1.1E+02 4.60E+00 1 .46E+01
Tl EaFA-L09-1316-T04-B 1 2.24E+01
2.24E+01 8.3E+01 4.60E+00 1 .46E+01
Tl EaFA-L09-1316-T05-B 1 2.30E+00 U1/2 2.30E+00 1 .4E+03 4.60E+00 1 .46E+01
Tl EaFA-L09-1316-T01-C 1 7.82E+00 E 7.82E+00 8.8E+01 4.60E+00 1 .46E+01
Tl EaFA-L09-1316-T02-C 1 1.13E+01 E 1.13E+01 2.6E+01 4.60E+00 1 .46E+01 10 325
Tl EaFA-L09-1316-T03-C 1 2.64E+01
Tl EaFA-L09-1316-T04-C 1 1.53E+01
Tl EaFA-L09-1316-T05-C 1 1.75E+01
2.64E+01 3.0E+01 4.60E+00 1 .46E+01
1.53E+01 4.6E+01 4.60E+00 1.46E+01
1.75E+01 2.6E+02 4.60E+00 1.46E+01
Tl EaFA-L09-1316-B01-A 1 2.30E+00 U1/2 2.30E+00 1.7E+01 4.60E+00 1.46E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.20E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.34E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.34E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57 AM L09 1313-1316 EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1160
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L09-1316-T01-A 1
Ti EaFA-L09-1316-T02-A 1
Ti EaFA-L09-1316-T03-A 1
Ti EaFA-L09-1316-T04-A 1
Ti EaFA-L09-1316-T05-A 1
Ti EaFA-L09-1316-T01-B 1
Ti EaFA-L09-1316-T02-B 1
Ti EaFA-L09-1316-T03-B 1
Ti EaFA-L09-1316-T04-B 1
Ti EaFA-L09-1316-T05-B 1
Ti EaFA-L09-1316-T01-C 1
Ti EaFA-L09-1316-T02-C 1
Ti EaFA-L09-1316-T03-C 1
Ti EaFA-L09-1316-T04-C 1
Ti EaFA-L09-1316-T05-C 1
Ti EaFA-L09-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.44E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.08E+00 E
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.3E+01 2.00E+00 6.40E+00
1.00E+00 1.7E+02 2.00E+00 6.40E+00 10 325
1.00E+00 9.7E+01 2.00E+00 6.40E+00
1.00E+00 5.5E+01 2.00E+00 6.40E+00
2.44E+00 5.2E+01 2.00E+00 6.40E+00
1.00E+00 3.0E+01 2.00E+00 6.40E+00
1.00E+00 7.6E+01 2.00E+00 6.40E+00 10 325
1.00E+00 2.0E+02 2.00E+00 6.40E+00
1.00E+00 8.2E+02 2.00E+00 6.40E+00
1.00E+00 6.1E+01 2.00E+00 6.40E+00
1.00E+00 9.8E+01 2.00E+00 6.40E+00
1.00E+00 4.0E+02 2.00E+00 6.40E+00 10 325
1.00E+00 3.2E+01 2.00E+00 6.40E+00
1.00E+00 7.6E+01 2.00E+00 6.40E+00
3.08E+00 3.3E+01 2.00E+00 6.40E+00
1.00E+00 2.6E+01 2.00E+00 6.40E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.25E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.40E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.39E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54 AM L09 1313-1316 EaFA
                                                                                                                                                                         1-1161
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
ug/L
V EaFA-L09-1316-T01-A 1 2.64E+02
V EaFA-L09-1316-T02-A 1 3.04E+02
V EaFA-L09-1316-T03-A 1 3.40E+02
V EaFA-L09-1316-T04-A 1 3.70E+02
V EaFA-L09-1316-T05-A 1 3.05E+02
V EaFA-L09-1316-T01-B 1 2.62E+02
V EaFA-L09-1316-T02-B 1 2.93E+02
V EaFA-L09-1316-T03-B 1 3.50E+02
V EaFA-L09-1316-T04-B 1 3.54E+02
V EaFA-L09-1316-T05-B 1 2.54E+02
V EaFA-L09-1316-T01-C 1 2.61E+02
V EaFA-L09-1316-T02-C 1 2.92E+02
V EaFA-L09-1316-T03-C 1 3.41 E+02
V EaFA-L09-1316-T04-C 1 3.32E+02
V EaFA-L09-1316-T05-C 1 2.38E+02
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.64E+02 8.6E-01 1.50E+00 4.77E+00
3.04E+02 1.1E+00 1.50E+00 4.77E+00 10 325
3.40E+02 1.8E+00 1.50E+00 4.77E+00
3.70E+02 1.9E+00 1.50E+00 4.77E+00
3.05E+02 9.6E+00 1.50E+00 4.77E+00
2.62E+02 5.8E-01 1.50E+00 4.77E+00
2.93E+02 2.4E+00 1.50E+00 4.77E+00 10 325
3.50E+02 6.3E-01 1.50E+00 4.77E+00
3.54E+02 2.9E+00 1.50E+00 4.77E+00
2.54E+02 7.3E+01 1.50E+00 4.77E+00
2.61 E+02 3.6E+00 1.50E+00 4.77E+00
2.92E+02 1.1E+00 1.50E+00 4.77E+00 10 325
3.41 E+02 3.3E-01 1.50E+00 4.77E+00
3.32E+02 5.5E-01 1.50E+00 4.77E+00
2.38E+02 4.8E+01 1.50E+00 4.77E+00
V EaFA-L09-1316-B01-A 1 3.08E+00 E 3.08E+00 5.1E+01 1.50E+00 4.77E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.64E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.81E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.80E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56AML091313-1316EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59AML091313-1316EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54AML091313-1316EaFA
                                                                                                                                                                         1-1162
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone.
ug/L
Zn EaFA-L09-1316-T01-A 1 1.67E+01
Zn EaFA-L09-1316-T02-A 1 2.23E+01
Zn EaFA-L09-1316-T03-A 1 4.52E+01
Zn EaFA-L09-1316-T04-A 1 2.72E+01
Zn EaFA-L09-1316-T05-A 1 1.83E+02
Zn EaFA-L09-1316-T01-B 1 2.04E+01
Zn EaFA-L09-1316-T02-B 1 2.57E+01
Zn EaFA-L09-1316-T03-B 1 4.52E+01
Zn EaFA-L09-1316-T04-B 1 3.21E+01
Zn EaFA-L09-1316-T05-B 1 6.15E+01
Zn EaFA-L09-1316-T01-C 1 1.92E+01
Zn EaFA-L09-1316-T02-C 1 2.40E+01
Zn EaFA-L09-1316-T03-C 1 4.79E+01
Zn EaFA-L09-1316-T04-C 1 3.71 E+01
Zn EaFA-L09-1316-T05-C 1 2.31E+02
Zn EaFA-L09-1316-B01-A 1 6.89E+00
Internal ICP-OES Spike Sol'n
aualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.67E+01 7.8E+00 1.00E+00 3.18E+00
2.23E+01 3.0E+00 1.00E+00 3.18E+00 10 325
4.52E+01 1.5E+00 1.00E+00 3.18E+00
2.72E+01 1.5E+00 1.00E+00 3.18E+00
1.83E+02 5.1E+00 1.00E+00 3.18E+00
2.04E+01 1.1E+01 1.00E+00 3.18E+00
2.57E+01 1.1E+00 1.00E+00 3.18E+00 10 325
4.52E+01 3.2E+00 1.00E+00 3.18E+00
3.21E+01 3.0E-01 1.00E+00 3.18E+00
6.15E+01 5.4E+00 1.00E+00 3.18E+00
1.92E+01 9.2E+01 1.00E+00 3.18E+00
2.40E+01 7.6E+00 1.00E+00 3.18E+00 10 325
4.79E+01 3.5E+00 1.00E+00 3.18E+00
3.71E+01 2.7E+00 1.00E+00 3.18E+00
2.31E+02 2.6E+00 1.00E+00 3.18E+00
6.89E+00 5.0E+01 1.00E+00 3.18E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3.48E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.43E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.42E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/11/10 11:56 AM L09 1313-1316 EaFA
6/11/10 11:57AML091313-1316EaFA
6/11/10 11:59 AM L09 1313-1316 EaFA
6/11/10 12:01 PM L09 1313-1316 EaFA
6/11/10 12:02 PM L09 1313-1316 EaFA
6/11/10 12:04 PM L09 1313-1316 EaFA
6/11/10 12:06 PM L09 1313-1316 EaFA
6/11/10 12:07 PM L09 1313-1316 EaFA
6/11/10 12:09 PM L09 1313-1316 EaFA
6/11/10 12:11 PM L09 1313-1316 EaFA
6/11/10 12:12 PM L09 1313-1316 EaFA
6/11/10 12:14 PM L09 1313-1316 EaFA
6/11/10 12:16 PM L09 1313-1316 EaFA
6/11/10 12:17 PM L09 1313-1316 EaFA
6/11/10 12:19 PM L09 1313-1316 EaFA
6/11/10 11:54AML091313-1316EaFA
                                                                                                                                                                         1-1163
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
I I I ug/L
Al EaFA-L10-1316-T01-A 1 1.87E+02
Al EaFA-L10-1316-T02-A 1 2.10E+02
Al EaFA-L10-1316-T03-A 1 8.90E+02
Al EaFA-L10-1316-T04-A 1 7.47E+02
Al EaFA-L10-1316-T05-A 1 8.08E+02
Al EaFA-L10-1316-T01-B 1 1.61E+02
Al EaFA-L10-1316-T02-B 1 1.77E+02
Al EaFA-L10-1316-T03-B 1 2.04E+02
Al EaFA-L10-1316-T04-B 1 4.40E+02
Al EaFA-L10-1316-T05-B 1 7.13E+02
Al EaFA-L10-1316-T01-C 1 1.15E+02
Al EaFA-L10-1316-T02-C 1 1.74E+02
Al EaFA-L10-1316-T03-C 1 2.76E+02
Al EaFA-L10-1316-T04-C 1 4.86E+02
Al EaFA-L10-1316-T05-C 1 7.32E+02
Al EaFA-L10-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.87E+02 2.1E+00 1.0E+00 3.2E+00
2.10E+02 3.9E+00 1.0E+00 3.2E+00 1000 100
8.90E+02 4.6E-01 1.0E+00 3.2E+00
7.47E+02 4.0E+00 1.0E+00 3.2E+00
8.08E+02 6.7E+00 1.0E+00 3.2E+00
1.61E+02 7.5E-01 1.0E+00 3.2E+00
1.77E+02 4.4E+00 1.0E+00 3.2E+00 1000 100
2.04E+02 1.4E+00 1.0E+00 3.2E+00
4.40E+02 8.2E-01 1.0E+00 3.2E+00
7.13E+02 8.5E-01 1.0E+00 3.2E+00
1.15E+02 5.6E-01 1.0E+00 3.2E+00
1.74E+02 5.1E-01 1.0E+00 3.2E+00 1000 100
2.76E+02 1.4E+00 1.0E+00 3.2E+00
4.86E+02 5.0E-01 1.0E+00 3.2E+00
7.32E+02 1.0E+00 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
1.04E+03 83% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
9.83E+02 81% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05PM EPA Interlab L10 1313-1316 EaFA
1.05E+03 87% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                                 1-1164
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L10-1316-T01-A 1
Sb EaFA-L10-1316-T02-A 1
Sb EaFA-L10-1316-T03-A 1
Sb EaFA-L10-1316-T04-A 1
Sb EaFA-L10-1316-T05-A 1
Sb EaFA-L10-1316-T01-B 1
Sb EaFA-L10-1316-T02-B 1
Sb EaFA-L10-1316-T03-B 1
Sb EaFA-L10-1316-T04-B 1
Sb EaFA-L10-1316-T05-B 1
Sb EaFA-L10-1316-T01-C 1
Sb EaFA-L10-1316-T02-C 1
Sb EaFA-L10-1316-T03-C 1
Sb EaFA-L10-1316-T04-C 1
Sb EaFA-L10-1316-T05-C 1
Sb EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
1 .66E+02
2.65E+02
2.87E+02
3.05E+02
4.98E+02
1 .69E+02
2.48E+02
3.82E+02
5.75E+02
6.50E+02
1.73E+02
2.68E+02
4.20E+02
6.22E+02
6.23E+02
1.86E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.66E+02 6.0E+00 7.5E+00 2.4E+01
2.65E+02 7.5E+00 7.5E+00 2.4E+01 10 300
2.87E+02 3.5E+00 7.5E+00 2.4E+01
3.05E+02 3.8E+00 7.5E+00 2.4E+01
4.98E+02 5.7E+00 7.5E+00 2.4E+01
1.69E+02 5.3E+00 7.5E+00 2.4E+01
2.48E+02 1.2E+01 7.5E+00 2.4E+01 10 300
3.82E+02 3.7E+00 7.5E+00 2.4E+01
5.75E+02 5.7E+00 7.5E+00 2.4E+01
6.50E+02 5.8E-01 7.5E+00 2.4E+01
1.73E+02 1.7E+01 7.5E+00 2.4E+01
2.68E+02 1.5E+01 7.5E+00 2.4E+01 10 300
4.20E+02 7.8E+00 7.5E+00 2.4E+01
6.22E+02 3.8E+00 7.5E+00 2.4E+01
6.23E+02 6.7E-01 7.5E+00 2.4E+01
1.86E+01 1.4E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.97E+03 90% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.90E+03 88% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
3.12E+03 95% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1165
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As EaFA-L10-1316-T01-A 1
As EaFA-L10-1316-T02-A 1
As EaFA-L10-1316-T03-A 1
As EaFA-L10-1316-T04-A 1
As EaFA-L10-1316-T05-A 1
As EaFA-L10-1316-T01-B 1
As EaFA-L10-1316-T02-B 1
As EaFA-L10-1316-T03-B 1
As EaFA-L10-1316-T04-B 1
As EaFA-L10-1316-T05-B 1
As EaFA-L10-1316-T01-C 1
As EaFA-L10-1316-T02-C 1
As EaFA-L10-1316-T03-C 1
As EaFA-L10-1316-T04-C 1
As EaFA-L10-1316-T05-C 1
As EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
1.13E+02
1.41E+02
2.47E+02
2.12E+02
1 .67E+02
1.17E+02
1.33E+02
1.37E+02
1 .99E+02
2.29E+02
1.02E+02
1.08E+02
1 .66E+02
2.09E+02
2.12E+02
3.79E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.13E+02 3.1E+01 1.1E+01 3.5E+01
1.41E+02 2.2E+01 1.1E+01 3.5E+01 10 300
2.47E+02 9.1E+00 1.1E+01 3.5E+01
2.12E+02 1.3E+00 1.1E+01 3.5E+01
1.67E+02 6.1E+00 1.1E+01 3.5E+01
1.17E+02 6.1E+00 1.1E+01 3.5E+01
1.33E+02 1.7E+01 1.1E+01 3.5E+01 10 300
1.37E+02 2.2E+00 1.1E+01 3.5E+01
1.99E+02 5.2E+00 1.1E+01 3.5E+01
2.29E+02 7.0E+00 1.1E+01 3.5E+01
1.02E+02 7.5E+00 1.1E+01 3.5E+01
1.08E+02 3.3E+01 1.1E+01 3.5E+01 10 300
1.66E+02 4.7E+00 1.1E+01 3.5E+01
2.09E+02 2.5E+00 1.1E+01 3.5E+01
2.12E+02 7.9E+00 1.1E+01 3.5E+01
3.79E+01 6.7E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.97E+03 94% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.88E+03 92% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:OOPM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05PM EPA Interlab L10 1313-1316 EaFA
3.10E+03 100% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1166
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B EaFA-L10-1316-T01-A 1
B EaFA-L10-1316-T02-A 1
B EaFA-L10-1316-T03-A 1
B EaFA-L10-1316-T04-A 1
B EaFA-L10-1316-T05-A 1
B EaFA-L10-1316-T01-B 1
B EaFA-L10-1316-T02-B 1
B EaFA-L10-1316-T03-B 1
B EaFA-L10-1316-T04-B 1
B EaFA-L10-1316-T05-B 1
B EaFA-L10-1316-T01-C 1
B EaFA-L10-1316-T02-C 1
B EaFA-L10-1316-T03-C 1
B EaFA-L10-1316-T04-C 1
B EaFA-L10-1316-T05-C 1
B EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
4.21 E+03
8.03E+03
1.68E+04
2.82E+04
5.19E+04
4.85E+03
7.92E+03
2.01 E+04
3.25E+04
5.26E+04
5.49E+03
8.45E+03
1 .89E+04
3.64E+04
5.39E+04
1.36E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.21 E+03 1.3E+00 1.0E+00 3.2E+00
8.03E+03 2.2E+00 1.0E+00 3.2E+00 1000 100
1.68E+04 3.0E-01 1.0E+00 3.2E+00
2.82E+04 3.5E+00 1.0E+00 3.2E+00
5.19E+04 7.3E+00 1.0E+00 3.2E+00
4.85E+03 2.2E+00 1.0E+00 3.2E+00
7.92E+03 2.5E+00 1.0E+00 3.2E+00 1000 100
2.01 E+04 2.0E+00 1.0E+00 3.2E+00
3.25E+04 1.2E+00 1.0E+00 3.2E+00
5.26E+04 1.0E+00 1.0E+00 3.2E+00
5.49E+03 1.9E+00 1.0E+00 3.2E+00
8.45E+03 1.9E+00 1.0E+00 3.2E+00 1000 100
1.89E+04 2.1E+00 1.0E+00 3.2E+00
3.64E+04 1.3E+00 1.0E+00 3.2E+00
5.39E+04 6.0E-01 1.0E+00 3.2E+00
1.36E+02 1.7E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
8.92E+03 90% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
8.76E+03 84% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
9.34E+03 88% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1167
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFA-L10-1316-T01-A 1
Ba EaFA-L10-1316-T02-A 1
Ba EaFA-L10-1316-T03-A 1
Ba EaFA-L10-1316-T04-A 1
Ba EaFA-L10-1316-T05-A 1
Ba EaFA-L10-1316-T01-B 1
Ba EaFA-L10-1316-T02-B 1
Ba EaFA-L10-1316-T03-B 1
Ba EaFA-L10-1316-T04-B 1
Ba EaFA-L10-1316-T05-B 1
Ba EaFA-L10-1316-T01-C 1
Ba EaFA-L10-1316-T02-C 1
Ba EaFA-L10-1316-T03-C 1
Ba EaFA-L10-1316-T04-C 1
Ba EaFA-L10-1316-T05-C 1
Ba EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
2.80E+02
2.25E+02
2.92E+02
2.76E+02
2.47E+02
3.04E+02
2.31 E+02
2.18E+02
2.41 E+02
2.64E+02
2.78E+02
2.31 E+02
2.03E+02
2.77E+02
2.69E+02
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.80E+02 1.1E+00 1.0E+00 3.2E+00
2.25E+02 5.9E-01 1.0E+00 3.2E+00 10 300
2.92E+02 1.0E+00 1.0E+00 3.2E+00
2.76E+02 3.7E+00 1.0E+00 3.2E+00
2.47E+02 7.0E+00 1.0E+00 3.2E+00
3.04E+02 4.4E-01 1.0E+00 3.2E+00
2.31E+02 2.3E+00 1.0E+00 3.2E+00 10 300
2.18E+02 1.7E+00 1.0E+00 3.2E+00
2.41 E+02 4.4E-01 1.0E+00 3.2E+00
2.64E+02 1.4E-01 1.0E+00 3.2E+00
2.78E+02 5.7E-01 1.0E+00 3.2E+00
2.31 E+02 1.5E+00 1.0E+00 3.2E+00 10 300
2.03E+02 2.8E+00 1.0E+00 3.2E+00
2.77E+02 1.5E+00 1.0E+00 3.2E+00
2.69E+02 5.3E-01 1.0E+00 3.2E+00
5.00E-01 3.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.70E+03 83% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.63E+03 80% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.79E+03 85% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1168
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Sample Dilution
EaFA-L10-1316-T01-A 1
EaFA-L10-1316-T02-A 1
EaFA-L10-1316-T03-A 1
EaFA-L10-1316-T04-A 1
EaFA-L10-1316-T05-A 1
EaFA-L10-1316-T01-B 1
EaFA-L10-1316-T02-B 1
EaFA-L10-1316-T03-B 1
EaFA-L10-1316-T04-B 1
EaFA-L10-1316-T05-B 1
EaFA-L10-1316-T01-C 1
EaFA-L10-1316-T02-C 1
EaFA-L10-1316-T03-C 1
EaFA-L10-1316-T04-C 1
EaFA-L10-1316-T05-C 1
EaFA-L10-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.1E+02 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00 10 300
9.50E-01 5.7E+01 1.9E+00 6.0E+00
9.50E-01 9.3E+01 1.9E+00 6.0E+00
9.50E-01 6.1E+01 1.9E+00 6.0E+00
9.50E-01 6.3E+01 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00 10 300
9.50E-01 2.1E+01 1.9E+00 6.0E+00
9.50E-01 3.0E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00
9.50E-01 2.4E+02 1.9E+00 6.0E+00 10 300
9.50E-01 3.9E+01 1.9E+00 6.0E+00
9.50E-01 3.3E+01 1.9E+00 6.0E+00
9.50E-01 6.3E+01 1.9E+00 6.0E+00
9.50E-01 5.0E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.83E+03 94% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.72E+03 91% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.93E+03 98% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1169
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Sample Dilution
EaFA-L10-1316-T01-A 1
EaFA-L10-1316-T02-A 1
EaFA-L10-1316-T03-A 1
EaFA-L10-1316-T04-A 1
EaFA-L10-1316-T05-A 1
EaFA-L10-1316-T01-B 1
EaFA-L10-1316-T02-B 1
EaFA-L10-1316-T03-B 1
EaFA-L10-1316-T04-B 1
EaFA-L10-1316-T05-B 1
EaFA-L10-1316-T01-C 1
EaFA-L10-1316-T02-C 1
EaFA-L10-1316-T03-C 1
EaFA-L10-1316-T04-C 1
EaFA-L10-1316-T05-C 1
EaFA-L10-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+OOU1/2
1.10E+OOU1/2
1.10E+00 U1/2
1.10E+00 U1/2
2.60E+00 E
7.43E+00
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+OOU1/2
1.10E+OOU1/2
3.02E+00 E
1.10E+00 U1/2
1.10E+OOU1/2
1.10E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 3.1E+03 2.2E+00 7.0E+00
1.10E+00 4.8E+01 2.2E+00 7.0E+00 10 300
1.10E+00 2.5E+02 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
1.10E+00 7.7E+01 2.2E+00 7.0E+00
1.10E+00 1.7E+02 2.2E+00 7.0E+00
2.60E+00 2.1E+01 2.2E+00 7.0E+00 10 300
7.43E+00 4.8E-01 2.2E+00 7.0E+00
1.10E+00 8.3E+01 2.2E+00 7.0E+00
1.10E+00 2.1E+02 2.2E+00 7.0E+00
1.10E+00 1.3E+02 2.2E+00 7.0E+00
1.10E+00 4.0E+01 2.2E+00 7.0E+00 10 300
3.02E+00 4.0E+01 2.2E+00 7.0E+00
1.10E+00 4.9E+01 2.2E+00 7.0E+00
1.10E+00 6.9E+01 2.2E+00 7.0E+00
1.10E+00 5.6E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.81E+03 93% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.73E+03 91% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:OOPM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05PM EPA Interlab L10 1313-1316 EaFA
2.91E+03 97% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1170
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca EaFA-L10-1316-T01-A 1
Ca EaFA-L10-1316-T02-A 1
Ca EaFA-L10-1316-T03-A 1
Ca EaFA-L10-1316-T04-A 1
Ca EaFA-L10-1316-T05-A 1
Ca EaFA-L10-1316-T01-B 1
Ca EaFA-L10-1316-T02-B 1
Ca EaFA-L10-1316-T03-B 1
Ca EaFA-L10-1316-T04-B 1
Ca EaFA-L10-1316-T05-B 1
Ca EaFA-L10-1316-T01-C 1
Ca EaFA-L10-1316-T02-C 1
Ca EaFA-L10-1316-T03-C 1
Ca EaFA-L10-1316-T04-C 1
Ca EaFA-L10-1316-T05-C 1
Ca EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
1 .53E+05
3.01 E+05
6.38E+05
5.68E+05
4.65E+05
1 .50E+05
2.87E+05
7.01 E+05
4.87E+05
4.67E+05
1 .43E+05
2.87E+05
6.62E+05
5.76E+05
4.76E+05
1 .97E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+05 8.5E-01 2.6E+00 8.3E+00
3.01E+05 3.3E-01 2.6E+00 8.3E+00 1000 100
6.38E+05 5.3E-01 2.6E+00 8.3E+00
5.68E+05 4.3E+00 2.6E+00 8.3E+00
4.65E+05 7.4E+00 2.6E+00 8.3E+00
1.50E+05 6.8E-01 2.6E+00 8.3E+00
2.87E+05 2.0E+00 2.6E+00 8.3E+00 1000 100
7.01 E+05 1.8E+00 2.6E+00 8.3E+00
4.87E+05 4.3E-01 2.6E+00 8.3E+00
4.67E+05 6.4E-01 2.6E+00 8.3E+00
1.43E+05 5.7E-01 2.6E+00 8.3E+00
2.87E+05 1.4E+00 2.6E+00 8.3E+00 1000 100
6.62E+05 3.5E-01 2.6E+00 8.3E+00
5.76E+05 8.5E-01 2.6E+00 8.3E+00
4.76E+05 1.8E-01 2.6E+00 8.3E+00
1.97E+01 2.5E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
3.02E+05 83% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.88E+05 83% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.88E+05 90% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1171
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr EaFA-L10-1316-T01-A 1
Cr EaFA-L10-1316-T02-A 1
Cr EaFA-L10-1316-T03-A 1
Cr EaFA-L10-1316-T04-A 1
Cr EaFA-L10-1316-T05-A 1
Cr EaFA-L10-1316-T01-B 1
Cr EaFA-L10-1316-T02-B 1
Cr EaFA-L10-1316-T03-B 1
Cr EaFA-L10-1316-T04-B 1
Cr EaFA-L10-1316-T05-B 1
Cr EaFA-L10-1316-T01-C 1
Cr EaFA-L10-1316-T02-C 1
Cr EaFA-L10-1316-T03-C 1
Cr EaFA-L10-1316-T04-C 1
Cr EaFA-L10-1316-T05-C 1
Cr EaFA-L10-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.90E+01
2.91 E+01
3.03E+02
5.65E+02
5.86E+01
2.02E+01
2.34E+01
1.14E+01
2.94E+01
6.63E+01
1.18E+01
2.33E+01
3.03E+01
3.46E+01
6.63E+01
6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.90E+01 4.8E+00 1.2E+00 3.8E+00
2.91 E+01 8.9E+00 1.2E+00 3.8E+00 10 300
3.03E+02 6.8E-01 1.2E+00 3.8E+00
5.65E+02 4.0E+00 1.2E+00 3.8E+00
5.86E+01 8.0E+00 1.2E+00 3.8E+00
2.02E+01 4.0E+00 1.2E+00 3.8E+00
2.34E+01 2.1E+00 1.2E+00 3.8E+00 10 300
1.14E+01 1.2E+01 1.2E+00 3.8E+00
2.94E+01 4.2E+00 1.2E+00 3.8E+00
6.63E+01 3.1E+00 1.2E+00 3.8E+00
1.18E+01 4.0E+00 1.2E+00 3.8E+00
2.33E+01 5.7E+00 1.2E+00 3.8E+00 10 300
3.03E+01 3.4E+00 1.2E+00 3.8E+00
3.46E+01 6.0E+00 1.2E+00 3.8E+00
6.63E+01 2.5E+00 1.2E+00 3.8E+00
6.00E-01 6.9E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.68E+03 88% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.61E+03 86% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:OOPM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05PM EPA Interlab L10 1313-1316 EaFA
2.75E+03 91% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1172
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-L10-1316-T01-A 1
Co EaFA-L10-1316-T02-A 1
Co EaFA-L10-1316-T03-A 1
Co EaFA-L10-1316-T04-A 1
Co EaFA-L10-1316-T05-A 1
Co EaFA-L10-1316-T01-B 1
Co EaFA-L10-1316-T02-B 1
Co EaFA-L10-1316-T03-B 1
Co EaFA-L10-1316-T04-B 1
Co EaFA-L10-1316-T05-B 1
Co EaFA-L10-1316-T01-C 1
Co EaFA-L10-1316-T02-C 1
Co EaFA-L10-1316-T03-C 1
Co EaFA-L10-1316-T04-C 1
Co EaFA-L10-1316-T05-C 1
Co EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
3.43E+01
5.73E+01
4.96E+00 E
1.18E+01
9.70E+01
4.83E+01
8.48E+01
2.45E+02
8.65E+01
7.19E+01
6.07E+01
8.99E+01
1 .42E+02
1 .05E+02
7.29E+01
9.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.43E+01 1.0E+01 1.8E+00 5.7E+00
5.73E+01 8.1E-01 1.8E+00 5.7E+00 10 300
4.96E+00 2.3E+01 1.8E+00 5.7E+00
1.18E+01 1.3E+01 1.8E+00 5.7E+00
9.70E+01 6.5E+00 1.8E+00 5.7E+00
4.83E+01 4.7E+00 1.8E+00 5.7E+00
8.48E+01 4.7E+00 1.8E+00 5.7E+00 10 300
2.45E+02 2.4E+00 1.8E+00 5.7E+00
8.65E+01 1.2E+00 1.8E+00 5.7E+00
7.19E+01 2.9E+00 1.8E+00 5.7E+00
6.07E+01 1.6E-01 1.8E+00 5.7E+00
8.99E+01 8.3E-01 1.8E+00 5.7E+00 10 300
1.42E+02 1.3E+00 1.8E+00 5.7E+00
1.05E+02 2.7E+00 1.8E+00 5.7E+00
7.29E+01 2.0E+00 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.73E+03 89% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.68E+03 87% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.84E+03 92% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1173
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFA-L10-1316-T01-A 1
Cu EaFA-L10-1316-T02-A 1
Cu EaFA-L10-1316-T03-A 1
Cu EaFA-L10-1316-T04-A 1
Cu EaFA-L10-1316-T05-A 1
Cu EaFA-L10-1316-T01-B 1
Cu EaFA-L10-1316-T02-B 1
Cu EaFA-L10-1316-T03-B 1
Cu EaFA-L10-1316-T04-B 1
Cu EaFA-L10-1316-T05-B 1
Cu EaFA-L10-1316-T01-C 1
Cu EaFA-L10-1316-T02-C 1
Cu EaFA-L10-1316-T03-C 1
Cu EaFA-L10-1316-T04-C 1
Cu EaFA-L10-1316-T05-C 1
Cu EaFA-L10-1316-B01-A 1
Sample
Cone. Qualifier
Mg/L
8.93E+00 E
1.21E+01
7.21E+OOE
1.70E+01
3.15E+01
5.27E+00 E
7.35E+01
1.20E+01
1.06E+01 E
1 .34E+01
1 .29E+01
6.50E+00 E
7.45E+00 E
1 .33E+01
1 .37E+01
4.58E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
|jg/L % pglL pglL pglL pL
8.93E+00 7.6E+01 3.7E+00 1.2E+01
1.21E+01 5.3E+01 3.7E+00 1.2E+01 10 300
7.21 E+00 6.3E+01 3.7E+00 1.2E+01
1.70E+01 3.5E+01 3.7E+00 1.2E+01
3.15E+01 3.9E+00 3.7E+00 1.2E+01
5.27E+00 6.4E+01 3.7E+00 1.2E+01
7.35E+01 1.1E+01 3.7E+00 1.2E+01 10 300
1.20E+01 2.3E+01 3.7E+00 1.2E+01
1.06E+01 1.5E+01 3.7E+00 1.2E+01
1.34E+01 1.4E+01 3.7E+00 1.2E+01
1.29E+01 1.1E+01 3.7E+00 1.2E+01
6.50E+00 9.7E+01 3.7E+00 1.2E+01 10 300
7.45E+00 4.0E+01 3.7E+00 1.2E+01
1.33E+01 5.4E+01 3.7E+00 1.2E+01
1.37E+01 2.5E+01 3.7E+00 1.2E+01
4.58E+00 9.2E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
(jg/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.70E+03 90% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.67E+03 86% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:OOPM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.78E+03 93% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1174
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L10-1316-T01-A 1
Fe EaFA-L10-1316-T02-A 1
Fe EaFA-L10-1316-T03-A 1
Fe EaFA-L10-1316-T04-A 1
Fe EaFA-L10-1316-T05-A 1
Fe EaFA-L10-1316-T01-B 1
Fe EaFA-L10-1316-T02-B 1
Fe EaFA-L10-1316-T03-B 1
Fe EaFA-L10-1316-T04-B 1
Fe EaFA-L10-1316-T05-B 1
Fe EaFA-L10-1316-T01-C 1
Fe EaFA-L10-1316-T02-C 1
Fe EaFA-L10-1316-T03-C 1
Fe EaFA-L10-1316-T04-C 1
Fe EaFA-L10-1316-T05-C 1
Fe EaFA-L10-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+OOU1/2
3.06E+00 E
2.92E+01
1.00E+00 U1/2
1.00E+OOU1/2
1.00E+OOU1/2
1.00E+00 U1/2
3.27E+00 E
1.00E+OOU1/2
1.00E+OOU1/2
2.23E+00 E
1.00E+00 U1/2
1.00E+OOU1/2
6.33E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 2.8E+01 2.0E+00 6.4E+00
3.06E+00 2.9E+00 2.0E+00 6.4E+00
2.92E+01 6.9E+00 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 8.5E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
3.27E+00 8.9E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00 1000 100
2.23E+00 7.4E+00 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+00 2.0E+00 6.4E+00
6.33E+00 3.7E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
8.22E+02 82% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
7.99E+02 80% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
8.50E+02 85% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1175
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L10-1316-T01-A 1
Pb EaFA-L10-1316-T02-A 1
Pb EaFA-L10-1316-T03-A 1
Pb EaFA-L10-1316-T04-A 1
Pb EaFA-L10-1316-T05-A 1
Pb EaFA-L10-1316-T01-B 1
Pb EaFA-L10-1316-T02-B 1
Pb EaFA-L10-1316-T03-B 1
Pb EaFA-L10-1316-T04-B 1
Pb EaFA-L10-1316-T05-B 1
Pb EaFA-L10-1316-T01-C 1
Pb EaFA-L10-1316-T02-C 1
Pb EaFA-L10-1316-T03-C 1
Pb EaFA-L10-1316-T04-C 1
Pb EaFA-L10-1316-T05-C 1
Pb EaFA-L10-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
6.88E+01
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 2.1E+03 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01 10 300
3.40E+00 1.6E+02 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
6.88E+01 2.1E+01 6.8E+00 2.2E+01
3.40E+00 6.6E+01 6.8E+00 2.2E+01
3.40E+00 1.9E+02 6.8E+00 2.2E+01 10 300
3.40E+00 8.9E+01 6.8E+00 2.2E+01
3.40E+00 2.9E+01 6.8E+00 2.2E+01
3.40E+00 1.8E+01 6.8E+00 2.2E+01
3.40E+00 2.9E+01 6.8E+00 2.2E+01
3.40E+00 5.4E+01 6.8E+00 2.2E+01 10 300
3.40E+00 5.7E+01 6.8E+00 2.2E+01
3.40E+00 4.8E+01 6.8E+00 2.2E+01
3.40E+00 4.6E+01 6.8E+00 2.2E+01
3.40E+00 9.3E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.70E+03 90% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.62E+03 87% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.77E+03 92% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1176
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li EaFA-L10-1316-T01-A 1
Li EaFA-L10-1316-T02-A 1
Li EaFA-L10-1316-T03-A 1
Li EaFA-L10-1316-T04-A 1
Li EaFA-L10-1316-T05-A 1
Li EaFA-L10-1316-T01-B 1
Li EaFA-L10-1316-T02-B 1
Li EaFA-L10-1316-T03-B 1
Li EaFA-L10-1316-T04-B 1
Li EaFA-L10-1316-T05-B 1
Li EaFA-L10-1316-T01-C 1
Li EaFA-L10-1316-T02-C 1
Li EaFA-L10-1316-T03-C 1
Li EaFA-L10-1316-T04-C 1
Li EaFA-L10-1316-T05-C 1
Li EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
3.35E+03
6.54E+03
1.14E+04
2.14E+04
5.89E+04
3.34E+03
6.30E+03
1.51E+04
2.75E+04
5.35E+04
3.21 E+03
6.35E+03
1 .50E+04
3.13E+04
5.44E+04
9.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.35E+03 1.7E+00 1.9E+00 6.0E+00
6.54E+03 8.1E-01 1.9E+00 6.0E+00 10 300
1.14E+04 1.3E-01 1.9E+00 6.0E+00
2.14E+04 4.4E+00 1.9E+00 6.0E+00
5.89E+04 7.1E+00 1.9E+00 6.0E+00
3.34E+03 4.7E-01 1.9E+00 6.0E+00
6.30E+03 2.3E+00 1.9E+00 6.0E+00 10 300
1.51E+04 1.8E+00 1.9E+00 6.0E+00
2.75E+04 7.5E-01 1.9E+00 6.0E+00
5.35E+04 7.3E-01 1.9E+00 6.0E+00
3.21 E+03 2.2E-01 1.9E+00 6.0E+00
6.35E+03 1.5E+00 1.9E+00 6.0E+00 10 300
1.50E+04 1.7E-01 1.9E+00 6.0E+00
3.13E+04 1.1E+00 1.9E+00 6.0E+00
5.44E+04 1.7E-01 1.9E+00 6.0E+00
9.50E-01 8.0E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
8.98E+03 82% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
9.02E+03 91% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05PM EPA Interlab L10 1313-1316 EaFA
8.87E+03 84% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1177
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn EaFA-L10-1316-T01-A 1
Mn EaFA-L10-1316-T02-A 1
Mn EaFA-L10-1316-T03-A 1
Mn EaFA-L10-1316-T04-A 1
Mn EaFA-L10-1316-T05-A 1
Mn EaFA-L10-1316-T01-B 1
Mn EaFA-L10-1316-T02-B 1
Mn EaFA-L10-1316-T03-B 1
Mn EaFA-L10-1316-T04-B 1
Mn EaFA-L10-1316-T05-B 1
Mn EaFA-L10-1316-T01-C 1
Mn EaFA-L10-1316-T02-C 1
Mn EaFA-L10-1316-T03-C 1
Mn EaFA-L10-1316-T04-C 1
Mn EaFA-L10-1316-T05-C 1
Mn EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
2.95E+02
5.38E+02
8.10E+01
2.18E+02
1.01E+03
3.52E+02
6.27E+02
1.72E+03
9.64E+02
8.88E+02
4.07E+02
6.44E+02
1 .08E+03
1.16E+03
9.15E+02
1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.95E+02 2.8E-01 2.0E+00 6.4E+00
5.38E+02 2.8E-01 2.0E+00 6.4E+00 10 300
8.10E+01 5.2E-01 2.0E+00 6.4E+00
2.18E+02 4.7E+00 2.0E+00 6.4E+00
1.01E+03 7.4E+00 2.0E+00 6.4E+00
3.52E+02 1.1E+00 2.0E+00 6.4E+00
6.27E+02 2.1E+00 2.0E+00 6.4E+00 10 300
1.72E+03 9.3E-01 2.0E+00 6.4E+00
9.64E+02 6.0E-01 2.0E+00 6.4E+00
8.88E+02 1.1E+00 2.0E+00 6.4E+00
4.07E+02 3.4E-01 2.0E+00 6.4E+00
6.44E+02 1.8E+00 2.0E+00 6.4E+00 10 300
1.08E+03 7.5E-01 2.0E+00 6.4E+00
1.16E+03 5.7E-01 2.0E+00 6.4E+00
9.15E+02 7.3E-01 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
3.09E+03 85% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
3.07E+03 81% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
3.28E+03 88% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1178
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Sample Dilution
EaFA-L10-1316-T01-A 1
EaFA-L10-1316-T02-A 1
EaFA-L10-1316-T03-A 1
EaFA-L10-1316-T04-A 1
EaFA-L10-1316-T05-A 1
EaFA-L10-1316-T01-B 1
EaFA-L10-1316-T02-B 1
EaFA-L10-1316-T03-B 1
EaFA-L10-1316-T04-B 1
EaFA-L10-1316-T05-B 1
EaFA-L10-1316-T01-C 1
EaFA-L10-1316-T02-C 1
EaFA-L10-1316-T03-C 1
EaFA-L10-1316-T04-C 1
EaFA-L10-1316-T05-C 1
EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
7.51 E+03
1 .46E+04
3.60E+04
6.19E+04
1.15E+05
7.14E+03
1.37E+04
3.86E+04
6.05E+04
1 .08E+05
7.39E+03
1.39E+04
3.57E+04
7.10E+04
1.13E+05
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.51 E+03 1.4E+00 1.0E+00 3.2E+00
1.46E+04 1.1E+00 1.0E+00 3.2E+00 1000 100
3.60E+04 5.4E-01 1.0E+00 3.2E+00
6.19E+04 4.9E+00 1.0E+00 3.2E+00
1.15E+05 6.5E+00 1.0E+00 3.2E+00
7.14E+03 8.0E-02 1.0E+00 3.2E+00
1.37E+04 2.8E+00 1.0E+00 3.2E+00 1000 100
3.86E+04 9.6E-01 1.0E+00 3.2E+00
6.05E+04 5.8E-01 1.0E+00 3.2E+00
1.08E+05 1.1E+00 1.0E+00 3.2E+00
7.39E+03 1.0E+00 1.0E+00 3.2E+00
1.39E+04 9.8E-01 1.0E+00 3.2E+00 1000 100
3.57E+04 7.6E-01 1.0E+00 3.2E+00
7.10E+04 1.8E+00 1.0E+00 3.2E+00
1.13E+05 5.7E-01 1.0E+00 3.2E+00
5.00E-01 9.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
1.55E+04 90% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
1.47E+04 97% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
1.47E+04 83% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1179
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo EaFA-L10-1316-T01-A 1
Mo EaFA-L10-1316-T02-A 1
Mo EaFA-L10-1316-T03-A 1
Mo EaFA-L10-1316-T04-A 1
Mo EaFA-L10-1316-T05-A 1
Mo EaFA-L10-1316-T01-B 1
Mo EaFA-L10-1316-T02-B 1
Mo EaFA-L10-1316-T03-B 1
Mo EaFA-L10-1316-T04-B 1
Mo EaFA-L10-1316-T05-B 1
Mo EaFA-L10-1316-T01-C 1
Mo EaFA-L10-1316-T02-C 1
Mo EaFA-L10-1316-T03-C 1
Mo EaFA-L10-1316-T04-C 1
Mo EaFA-L10-1316-T05-C 1
Mo EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
3.27E+03
6.12E+03
1 .64E+04
2.74E+04
3.77E+04
3.20E+03
5.62E+03
1.16E+04
2.55E+04
4.53E+04
3.08E+03
5.71 E+03
1 .32E+04
2.83E+04
4.65E+04
8.98E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.27E+03 5.1E-02 1.2E+00 3.8E+00
6.12E+03 8.3E-01 1.2E+00 3.8E+00 10 300
1.64E+04 3.1E-01 1.2E+00 3.8E+00
2.74E+04 4.1E+00 1.2E+00 3.8E+00
3.77E+04 7.3E+00 1.2E+00 3.8E+00
3.20E+03 7.3E-01 1.2E+00 3.8E+00
5.62E+03 2.5E+00 1.2E+00 3.8E+00 10 300
1.16E+04 1.9E+00 1.2E+00 3.8E+00
2.55E+04 4.7E-01 1.2E+00 3.8E+00
4.53E+04 4.4E-01 1.2E+00 3.8E+00
3.08E+03 7.8E-01 1.2E+00 3.8E+00
5.71E+03 1.2E+00 1.2E+00 3.8E+00 10 300
1.32E+04 1.7E+00 1.2E+00 3.8E+00
2.83E+04 5.3E-01 1.2E+00 3.8E+00
4.65E+04 1.8E-01 1.2E+00 3.8E+00
8.98E+00 5.5E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
8.75E+03 88% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
8.22E+03 87% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
8.59E+03 96% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1180
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFA-L10-1316-T01-A 1
Ni EaFA-L10-1316-T02-A 1
Ni EaFA-L10-1316-T03-A 1
Ni EaFA-L10-1316-T04-A 1
Ni EaFA-L10-1316-T05-A 1
Ni EaFA-L10-1316-T01-B 1
Ni EaFA-L10-1316-T02-B 1
Ni EaFA-L10-1316-T03-B 1
Ni EaFA-L10-1316-T04-B 1
Ni EaFA-L10-1316-T05-B 1
Ni EaFA-L10-1316-T01-C 1
Ni EaFA-L10-1316-T02-C 1
Ni EaFA-L10-1316-T03-C 1
Ni EaFA-L10-1316-T04-C 1
Ni EaFA-L10-1316-T05-C 1
Ni EaFA-L10-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
8.67E+01
1 .44E+02
7.11E+00
4.60E+01
2.79E+02
1.10E+02
1 .97E+02
5.41 E+02
2.11E+02
2.38E+02
1 .30E+02
2.08E+02
3.20E+02
2.43E+02
2. 41 E+02
9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.67E+01 4.6E+00 1.8E+00 5.7E+00
1.44E+02 3.3E+00 1.8E+00 5.7E+00 10 300
7.11E+00 3.1E+01 1.8E+00 5.7E+00
4.60E+01 1.4E+01 1.8E+00 5.7E+00
2.79E+02 6.6E+00 1.8E+00 5.7E+00
1.10E+02 3.8E+00 1.8E+00 5.7E+00
1.97E+02 4.2E+00 1.8E+00 5.7E+00 10 300
5.41 E+02 2.5E+00 1.8E+00 5.7E+00
2. 11 E+02 9.3E-01 1.8E+00 5.7E+00
2.38E+02 9.8E-01 1.8E+00 5.7E+00
1.30E+02 4.5E+00 1.8E+00 5.7E+00
2.08E+02 1.1E+00 1.8E+00 5.7E+00 10 300
3.20E+02 1.9E+00 1.8E+00 5.7E+00
2.43E+02 6.1E-01 1.8E+00 5.7E+00
2.41 E+02 2.8E+00 1.8E+00 5.7E+00
9.00E-01 1.9E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.86E+03 90% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.82E+03 88% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
3.00E+03 93% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1181
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
p
p
p
p
p
p
p
p
p
p
p
p
p
p
p
p
p
Sample Dilution
EaFA-L10-1316-T01-A 1
EaFA-L10-1316-T02-A 1
EaFA-L10-1316-T03-A 1
EaFA-L10-1316-T04-A 1
EaFA-L10-1316-T05-A 1
EaFA-L10-1316-T01-B 1
EaFA-L10-1316-T02-B 1
EaFA-L10-1316-T03-B 1
EaFA-L10-1316-T04-B 1
EaFA-L10-1316-T05-B 1
EaFA-L10-1316-T01-C 1
EaFA-L10-1316-T02-C 1
EaFA-L10-1316-T03-C 1
EaFA-L10-1316-T04-C 1
EaFA-L10-1316-T05-C 1
EaFA-L10-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.81E+01
1.31E+02
3.96E+01
1.39E+02
7.16E+01
1.01E+01 E
6.64E+00 E
1.40E+01
5.96E+01
7.81 E+01
1.58E+01
1.85E+OOU1/2
1.04E+01 E
9.35E+01
5.26E+01
3.08E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.81 E+01 1.8E+01 3.7E+00 1.2E+01
1.31E+02 1.1E+01 3.7E+00 1.2E+01 1000 100
3.96E+01 2.3E+01 3.7E+00 1.2E+01
1.39E+02 1.5E+01 3.7E+00 1.2E+01
7.16E+01 3.2E+01 3.7E+00 1.2E+01
1.01 E+01 3.2E+01 3.7E+00 1.2E+01
6.64E+00 6.5E+01 3.7E+00 1.2E+01 1000 100
1.40E+01 6.2E+01 3.7E+00 1.2E+01
5.96E+01 2.8E+01 3.7E+00 1.2E+01
7.81 E+01 1.6E+01 3.7E+00 1.2E+01
1.58E+01 3.9E+01 3.7E+00 1.2E+01
1.85E+00 2.2E+02 3.7E+00 1.2E+01 1000 100
1.04E+01 8.8E+01 3.7E+00 1.2E+01
9.35E+01 1.6E+01 3.7E+00 1.2E+01
5.26E+01 2.9E+01 3.7E+00 1.2E+01
3.08E+01 4.0E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
9.95E+02 86% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
8.52E+02 85% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
9.41E+02 94% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1182
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K EaFA-L10-1316-T01-A 1
K EaFA-L10-1316-T02-A 1
K EaFA-L10-1316-T03-A 1
K EaFA-L10-1316-T04-A 1
K EaFA-L10-1316-T05-A 1
K EaFA-L10-1316-T01-B 1
K EaFA-L10-1316-T02-B 1
K EaFA-L10-1316-T03-B 1
K EaFA-L10-1316-T04-B 1
K EaFA-L10-1316-T05-B 1
K EaFA-L10-1316-T01-C 1
K EaFA-L10-1316-T02-C 1
K EaFA-L10-1316-T03-C 1
K EaFA-L10-1316-T04-C 1
K EaFA-L10-1316-T05-C 1
K EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
3.02E+04
5.63E+04
1.17E+05
1.85E+05
3.06E+05
2.74E+04
5.19E+04
1.25E+05
1 .83E+05
3.06E+05
2.72E+04
5.10E+04
1 .23E+05
2.05E+05
3.08E+05
5.40E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.02E+04 1.1E+00 1.6E+00 5.1E+00
5.63E+04 7.1E-01 1.6E+00 5.1E+00 1000 100
1.17E+05 6.8E-01 1.6E+00 5.1E+00
1.85E+05 3.6E+00 1.6E+00 5.1E+00
3.06E+05 7.0E+00 1.6E+00 5.1E+00
2.74E+04 3.5E-01 1.6E+00 5.1E+00
5.19E+04 1.8E+00 1.6E+00 5.1E+00 1000 100
1.25E+05 1.8E+00 1.6E+00 5.1E+00
1.83E+05 6.4E-01 1.6E+00 5.1E+00
3.06E+05 1.3E+00 1.6E+00 5.1E+00
2.72E+04 5.2E-01 1.6E+00 5.1E+00
5.10E+04 1.3E+00 1.6E+00 5.1E+00 1000 100
1.23E+05 4.1E-01 1.6E+00 5.1E+00
2.05E+05 1.4E+00 1.6E+00 5.1E+00
3.08E+05 4.4E-01 1.6E+00 5.1E+00
5.40E+01 5.1E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
5.72E+04 85% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
5.27E+04 84% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
5.19E+04 88% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1183
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se EaFA-L10-1316-T01-A 1
Se EaFA-L10-1316-T02-A 1
Se EaFA-L10-1316-T03-A 1
Se EaFA-L10-1316-T04-A 1
Se EaFA-L10-1316-T05-A 1
Se EaFA-L10-1316-T01-B 1
Se EaFA-L10-1316-T02-B 1
Se EaFA-L10-1316-T03-B 1
Se EaFA-L10-1316-T04-B 1
Se EaFA-L10-1316-T05-B 1
Se EaFA-L10-1316-T01-C 1
Se EaFA-L10-1316-T02-C 1
Se EaFA-L10-1316-T03-C 1
Se EaFA-L10-1316-T04-C 1
Se EaFA-L10-1316-T05-C 1
Se EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
1 .09E+03
1.18E+03
3.11E+03
2.95E+03
2.08E+03
9.20E+02
1.04E+03
1.15E+03
2.11E+03
2.72E+03
8.60E+02
1.08E+03
1 .53E+03
2.23E+03
2.78E+03
3.52E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.09E+03 1.6E+00 1.5E+01 4.8E+01
1.18E+03 1.4E+00 1.5E+01 4.8E+01 10 300
3.11E+03 3.0E+00 1.5E+01 4.8E+01
2.95E+03 2.5E+00 1.5E+01 4.8E+01
2.08E+03 9.8E+00 1.5E+01 4.8E+01
9.20E+02 1.8E-01 1.5E+01 4.8E+01
1.04E+03 5.9E+00 1.5E+01 4.8E+01 10 300
1.15E+03 1.9E+00 1.5E+01 4.8E+01
2.11E+03 1.5E+00 1.5E+01 4.8E+01
2.72E+03 5.0E-01 1.5E+01 4.8E+01
8.60E+02 2.7E+00 1.5E+01 4.8E+01
1.08E+03 2.2E+00 1.5E+01 4.8E+01 10 300
1.53E+03 1.9E+00 1.5E+01 4.8E+01
2.23E+03 5.6E-01 1.5E+01 4.8E+01
2.78E+03 8.2E-01 1.5E+01 4.8E+01
3.52E+01 1.2E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
3.83E+03 88% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
3.63E+03 86% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
3.93E+03 95% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1184
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si EaFA-L10-1316-T01-A 1
Si EaFA-L10-1316-T02-A 1
Si EaFA-L10-1316-T03-A 1
Si EaFA-L10-1316-T04-A 1
Si EaFA-L10-1316-T05-A 1
Si EaFA-L10-1316-T01-B 1
Si EaFA-L10-1316-T02-B 1
Si EaFA-L10-1316-T03-B 1
Si EaFA-L10-1316-T04-B 1
Si EaFA-L10-1316-T05-B 1
Si EaFA-L10-1316-T01-C 1
Si EaFA-L10-1316-T02-C 1
Si EaFA-L10-1316-T03-C 1
Si EaFA-L10-1316-T04-C 1
Si EaFA-L10-1316-T05-C 1
Si EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
1 .83E+03
2.02E+03
8.02E+02
1.07E+03
1 .59E+03
1 .97E+03
2.10E+03
2.88E+03
1 .92E+03
1 .67E+03
2.32E+03
2.16E+03
2.07E+03
2.17E+03
1.73E+03
5.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.83E+03 1.2E+00 1.1E+00 3.5E+00
2.02E+03 8.5E-01 1.1E+00 3.5E+00 1000 100
8.02E+02 1.3E-01 1.1E+00 3.5E+00
1.07E+03 3.6E+00 1.1E+00 3.5E+00
1.59E+03 7.4E+00 1.1E+00 3.5E+00
1.97E+03 5.7E-01 1.1E+00 3.5E+00
2.10E+03 2.7E+00 1.1E+00 3.5E+00 1000 100
2.88E+03 2.3E+00 1.1E+00 3.5E+00
1.92E+03 6.7E-01 1.1E+00 3.5E+00
1.67E+03 6.8E-01 1.1E+00 3.5E+00
2.32E+03 9.4E-01 1.1E+00 3.5E+00
2.16E+03 1.6E+00 1.1E+00 3.5E+00 1000 100
2.07E+03 1.5E+00 1.1E+00 3.5E+00
2.17E+03 4.1E-01 1.1E+00 3.5E+00
1.73E+03 1.3E+00 1.1E+00 3.5E+00
5.50E-01 3.2E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.98E+03 97% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
3.04E+03 95% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:OOPM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05PM EPA Interlab L10 1313-1316 EaFA
3.11E+03 95% VUICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1185
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na EaFA-L10-1316-T01-A 1
Na EaFA-L10-1316-T02-A 1
Na EaFA-L10-1316-T03-A 1
Na EaFA-L10-1316-T04-A 1
Na EaFA-L10-1316-T05-A 1
Na EaFA-L10-1316-T01-B 1
Na EaFA-L10-1316-T02-B 1
Na EaFA-L10-1316-T03-B 1
Na EaFA-L10-1316-T04-B 1
Na EaFA-L10-1316-T05-B 1
Na EaFA-L10-1316-T01-C 1
Na EaFA-L10-1316-T02-C 1
Na EaFA-L10-1316-T03-C 1
Na EaFA-L10-1316-T04-C 1
Na EaFA-L10-1316-T05-C 1
Na EaFA-L10-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
5.01 E+03
1 .04E+04
2.54E+04
4.29E+04
6.02E+04
5.00E+03
9.85E+03
2.83E+04
4.01 E+04
6.73E+04
4.80E+03
1.01 E+04
2.66E+04
4.56E+04
6.81 E+04
1.61E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.01 E+03 1.4E+00 2.5E+00 8.0E+00
1.04E+04 7.3E-01 2.5E+00 8.0E+00 1000 100
2.54E+04 4.2E-01 2.5E+00 8.0E+00
4.29E+04 3.6E+00 2.5E+00 8.0E+00
6.02E+04 7.0E+00 2.5E+00 8.0E+00
5.00E+03 8.8E-01 2.5E+00 8.0E+00
9.85E+03 2.5E+00 2.5E+00 8.0E+00 1000 100
2.83E+04 2.0E+00 2.5E+00 8.0E+00
4.01 E+04 1.1E+00 2.5E+00 8.0E+00
6.73E+04 1.7E-01 2.5E+00 8.0E+00
4.80E+03 6.1E-01 2.5E+00 8.0E+00
1.01 E+04 1.2E+00 2.5E+00 8.0E+00 1000 100
2.66E+04 6.6E-01 2.5E+00 8.0E+00
4.56E+04 6.3E-01 2.5E+00 8.0E+00
6.81 E+04 7.3E-01 2.5E+00 8.0E+00
1.61E+02 5.7E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
1.13E+04 91%VUICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
1.07E+04 89% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
1.10E+04 85% VUICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1186
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dilution
Sr EaFA-L10-1316-T01-A 1
Sr EaFA-L10-1316-T02-A 1
Sr EaFA-L10-1316-T03-A 1
Sr EaFA-L10-1316-T04-A 1
Sr EaFA-L10-1316-T05-A 1
Sr EaFA-L10-1316-T01-B 1
Sr EaFA-L10-1316-T02-B 1
Sr EaFA-L10-1316-T03-B 1
Sr EaFA-L10-1316-T04-B 1
Sr EaFA-L10-1316-T05-B 1
Sr EaFA-L10-1316-T01-C 1
Sr EaFA-L10-1316-T02-C 1
Sr EaFA-L10-1316-T03-C 1
Sr EaFA-L10-1316-T04-C 1
Sr EaFA-L10-1316-T05-C 1
Sr EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
2.21 E+03
3.89E+03
1 .04E+04
1 .04E+04
7.04E+03
2.07E+03
3.62E+03
8.46E+03
7.19E+03
7.17E+03
2.13E+03
3.68E+03
7.33E+03
8.56E+03
7.33E+03
1.32E+OOE
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.21 E+03 2.1E-01 1.0E+00 3.2E+00
3.89E+03 2.4E-01 1.0E+00 3.2E+00 1000 100
1.04E+04 5.4E-01 1.0E+00 3.2E+00
1.04E+04 4.6E+00 1.0E+00 3.2E+00
7.04E+03 7.8E+00 1.0E+00 3.2E+00
2.07E+03 7.2E-01 1.0E+00 3.2E+00
3.62E+03 2.4E+00 1.0E+00 3.2E+00 1000 100
8.46E+03 5.4E-01 1.0E+00 3.2E+00
7.19E+03 3.0E-01 1.0E+00 3.2E+00
7.17E+03 1.2E+00 1.0E+00 3.2E+00
2.13E+03 5.5E-01 1.0E+00 3.2E+00
3.68E+03 1.6E+00 1.0E+00 3.2E+00 1000 100
7.33E+03 6.3E-01 1.0E+00 3.2E+00
8.56E+03 2.7E-01 1.0E+00 3.2E+00
7.33E+03 1.1E+00 1.0E+00 3.2E+00
1.32E+00 4.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
4.78E+03 90% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
4.75E+03 113% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
4.59E+03 92% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1187
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S EaFA-L10-1316-T01-A 1
S EaFA-L10-1316-T02-A 1
S EaFA-L10-1316-T03-A 1
S EaFA-L10-1316-T04-A 1
S EaFA-L10-1316-T05-A 1
S EaFA-L10-1316-T01-B 1
S EaFA-L10-1316-T02-B 1
S EaFA-L10-1316-T03-B 1
S EaFA-L10-1316-T04-B 1
S EaFA-L10-1316-T05-B 1
S EaFA-L10-1316-T01-C 1
S EaFA-L10-1316-T02-C 1
S EaFA-L10-1316-T03-C 1
S EaFA-L10-1316-T04-C 1
S EaFA-L10-1316-T05-C 1
S EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
1 .56E+05
3.06E+05
6.53E+05
6.77E+05
8.08E+05
1 .53E+05
2.90E+05
7.00E+05
6.78E+05
8.79E+05
1.49E+05
3.00E+05
7.08E+05
7.60E+05
9.11E+05
1.80E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.56E+05 1.4E+00 6.8E+00 2.2E+01
3.06E+05 1.1E+00 6.8E+00 2.2E+01 1000 100
6.53E+05 1.1E-01 6.8E+00 2.2E+01
6.77E+05 3.9E+00 6.8E+00 2.2E+01
8.08E+05 6.8E+00 6.8E+00 2.2E+01
1.53E+05 5.5E-01 6.8E+00 2.2E+01
2.90E+05 2.8E+00 6.8E+00 2.2E+01 1000 100
7.00E+05 2.7E+00 6.8E+00 2.2E+01
6.78E+05 5.8E-01 6.8E+00 2.2E+01
8.79E+05 3.1E-01 6.8E+00 2.2E+01
1.49E+05 7.7E-01 6.8E+00 2.2E+01
3.00E+05 1.7E+00 6.8E+00 2.2E+01 1000 100
7.08E+05 7.7E-01 6.8E+00 2.2E+01
7.60E+05 7.5E-01 6.8E+00 2.2E+01
9.11E+05 3.4E-01 6.8E+00 2.2E+01
1.80E+01 4.1E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
3.07E+05 84% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.90E+05 81% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
3.01E+05 86% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1188
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-L10-1316-T01-A 1
Tl EaFA-L10-1316-T02-A 1
Tl EaFA-L10-1316-T03-A 1
Tl EaFA-L10-1316-T04-A 1
Tl EaFA-L10-1316-T05-A 1
Tl EaFA-L10-1316-T01-B 1
Tl EaFA-L10-1316-T02-B 1
Tl EaFA-L10-1316-T03-B 1
Tl EaFA-L10-1316-T04-B 1
Tl EaFA-L10-1316-T05-B 1
Tl EaFA-L10-1316-T01-C 1
Tl EaFA-L10-1316-T02-C 1
Tl EaFA-L10-1316-T03-C 1
Tl EaFA-L10-1316-T04-C 1
Tl EaFA-L10-1316-T05-C 1
Tl EaFA-L10-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.01 E+01
2.30E+00 U1/2
2.30E+00 U1/2
1.03E+01 E
1 .55E+01
3.16E+01
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+01
1.52E+01
2.30E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 6.4E+02 4.6E+00 1.5E+01
2.30E+00 2.4E+03 4.6E+00 1.5E+01 10 300
2.30E+00 8.2E+02 4.6E+00 1.5E+01
2.30E+00 4.3E+02 4.6E+00 1.5E+01
2.01 E+01 5.9E+01 4.6E+00 1.5E+01
2.30E+00 2.5E+03 4.6E+00 1.5E+01
2.30E+00 5.6E+01 4.6E+00 1.5E+01 10 300
1.03E+01 5.9E+01 4.6E+00 1.5E+01
1.55E+01 5.4E+01 4.6E+00 1.5E+01
3.16E+01 7.1E+01 4.6E+00 1.5E+01
2.30E+00 4.7E+01 4.6E+00 1.5E+01
2.30E+00 1.0E+02 4.6E+00 1.5E+01 10 300
2.30E+00 1.5E+02 4.6E+00 1.5E+01
2.30E+01 2.5E+01 4.6E+00 1.5E+01
1.52E+01 3.7E+01 4.6E+00 1.5E+01
2.30E+00 1.4E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.77E+03 92% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.68E+03 89% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.87E+03 96% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1189
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L10-1316-T01-A 1
Ti EaFA-L10-1316-T02-A 1
Ti EaFA-L10-1316-T03-A 1
Ti EaFA-L10-1316-T04-A 1
Ti EaFA-L10-1316-T05-A 1
Ti EaFA-L10-1316-T01-B 1
Ti EaFA-L10-1316-T02-B 1
Ti EaFA-L10-1316-T03-B 1
Ti EaFA-L10-1316-T04-B 1
Ti EaFA-L10-1316-T05-B 1
Ti EaFA-L10-1316-T01-C 1
Ti EaFA-L10-1316-T02-C 1
Ti EaFA-L10-1316-T03-C 1
Ti EaFA-L10-1316-T04-C 1
Ti EaFA-L10-1316-T05-C 1
Ti EaFA-L10-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+OOU1/2
1.00E+OOU1/2
9.04E+00
1.00E+00 U1/2
1.00E+OOU1/2
1.00E+OOU1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+OOU1/2
1.00E+OOU1/2
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+OOU1/2
1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00 10 300
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
9.04E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00 10 300
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00
1.00E+00 2.4E+02 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00 10 300
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 4.5E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.59E+03 86% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.50E+03 83% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:02 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:56 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.69E+03 90% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1190
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFA-L10-1316-T01-A 1
V EaFA-L10-1316-T02-A 1
V EaFA-L10-1316-T03-A 1
V EaFA-L10-1316-T04-A 1
V EaFA-L10-1316-T05-A 1
V EaFA-L10-1316-T01-B 1
V EaFA-L10-1316-T02-B 1
V EaFA-L10-1316-T03-B 1
V EaFA-L10-1316-T04-B 1
V EaFA-L10-1316-T05-B 1
V EaFA-L10-1316-T01-C 1
V EaFA-L10-1316-T02-C 1
V EaFA-L10-1316-T03-C 1
V EaFA-L10-1316-T04-C 1
V EaFA-L10-1316-T05-C 1
V EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
1 .95E+02
2.21 E+02
3.64E+02
3.33E+02
2.53E+02
1 .85E+02
2.10E+02
2.81 E+02
3.34E+02
3.31 E+02
1.74E+02
2.15E+02
2.95E+02
3.66E+02
3.42E+02
6.82E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.95E+02 5.5E-01 1.5E+00 4.8E+00
2.21 E+02 7.3E-01 1.5E+00 4.8E+00 10 300
3.64E+02 2.0E+00 1.5E+00 4.8E+00
3.33E+02 4.2E+00 1.5E+00 4.8E+00
2.53E+02 8.2E+00 1.5E+00 4.8E+00
1.85E+02 7.0E-01 1.5E+00 4.8E+00
2.10E+02 3.5E+00 1.5E+00 4.8E+00 10 300
2.81 E+02 1.9E+00 1.5E+00 4.8E+00
3.34E+02 7.6E-01 1.5E+00 4.8E+00
3.31 E+02 1.3E+00 1.5E+00 4.8E+00
1.74E+02 1.9E+00 1.5E+00 4.8E+00
2.15E+02 1.9E+00 1.5E+00 4.8E+00 10 300
2.95E+02 6.8E-01 1.5E+00 4.8E+00
3.66E+02 7.3E-01 1.5E+00 4.8E+00
3.42E+02 7.1E-01 1.5E+00 4.8E+00
6.82E+00 3.1E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.83E+03 87% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.73E+03 84% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.92E+03 90% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1191
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn EaFA-L10-1316-T01-A 1
Zn EaFA-L10-1316-T02-A 1
Zn EaFA-L10-1316-T03-A 1
Zn EaFA-L10-1316-T04-A 1
Zn EaFA-L10-1316-T05-A 1
Zn EaFA-L10-1316-T01-B 1
Zn EaFA-L10-1316-T02-B 1
Zn EaFA-L10-1316-T03-B 1
Zn EaFA-L10-1316-T04-B 1
Zn EaFA-L10-1316-T05-B 1
Zn EaFA-L10-1316-T01-C 1
Zn EaFA-L10-1316-T02-C 1
Zn EaFA-L10-1316-T03-C 1
Zn EaFA-L10-1316-T04-C 1
Zn EaFA-L10-1316-T05-C 1
Zn EaFA-L10-1316-B01-A 1
Sample I
Cone. Qualifier 1
ug/L |
3.87E+01
4.84E+01
1.48E+01
6.95E+01
1 .64E+02
1.78E+01
2.57E+01
5.53E+01
2.43E+01
4.13E+01
2.80E+01
2.22E+01
2.69E+01
2.69E+01
4.26E+01
1.51E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.87E+01 1.5E+00 1.0E+00 3.2E+00
4.84E+01 9.5E-01 1.0E+00 3.2E+00 10 300
1.48E+01 5.6E+00 1.0E+00 3.2E+00
6.95E+01 4.0E+00 1.0E+00 3.2E+00
1.64E+02 8.4E+00 1.0E+00 3.2E+00
1.78E+01 3.9E+00 1.0E+00 3.2E+00
2.57E+01 2.2E+00 1.0E+00 3.2E+00 10 300
5.53E+01 2.4E+00 1.0E+00 3.2E+00
2.43E+01 1.5E+00 1.0E+00 3.2E+00
4.13E+01 1.8E+00 1.0E+00 3.2E+00
2.80E+01 1.3E+00 1.0E+00 3.2E+00
2.22E+01 3.5E+00 1.0E+00 3.2E+00 10 300
2.69E+01 2.8E+00 1.0E+00 3.2E+00
2.69E+01 1.5E+00 1.0E+00 3.2E+00
4.26E+01 3.0E+00 1.0E+00 3.2E+00
1.51E+01 3.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 7/1/10 12:49 PM EPA Interlab L10 1313-1316 EaFA
2.87E+03 94% VU ICP-OES 7/1/10 12:50 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:52 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:53 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:55 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:57 PM EPA Interlab L10 1313-1316 EaFA
2.76E+03 91% VU ICP-OES 7/1/10 12:58 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:00 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:02PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:56PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:05 PM EPA Interlab L10 1313-1316 EaFA
2.96E+03 98% VU ICP-OES 7/1/10 1:07 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:08 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:10 PM EPA Interlab L10 1313-1316 EaFA
VUICP-OES 7/1/10 1:48 PM EPA Interlab L10 1313-1316 EaFA
VU ICP-OES 7/1/10 12:44 PM EPA Interlab L10 1313-1316 EaFA
                                                                                                                                                                         1-1192
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al EaFA-L11-1316-T01-A 1
Al EaFA-L11-1316-T02-A 1
Al EaFA-L11-1316-T03-A 1
Al EaFA-L11-1316-T04-A 1
Al EaFA-L11-1316-T05-A
Al EaFA-L11-1316-T01-B 1
Al EaFA-L11-1316-T02-B 1
Al EaFA-L11-1316-T03-B 1
Al EaFA-L11-1316-T04-B 1
Al EaFA-L11-1316-T05-B
Al EaFA-L11-1316-T01-C 1
Al EaFA-L11-1316-T02-C 1
Al EaFA-L11-1316-T03-C 1
Al EaFA-L11-1316-T04-C 1
Al EaFA-L11-1316-T05-C
Al EaFA-L11-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
893.862
760.171
693.455
367.286

952.221
730.072
714.221
342.661

795.626
856.763
647.976
330.266

0.5 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.94E+02 0.263915 1.0E+00 3.2E+00
7.60E+02 0.768147 1.0E+00 3.2E+00 1000 100
6.93E+02 1.30853 1.0E+00 3.2E+00
3.67E+02 1.70069 1.0E+00 3.2E+00

9.52E+02 0.750216 1.0E+00 3.2E+00
7.30E+02 0.589479 1.0E+00 3.2E+00 1000 100
7.14E+02 0.448981 1.0E+00 3.2E+00
3.43E+02 2.12117 1.0E+00 3.2E+00

7.96E+02 1.20347 1.0E+00 3.2E+00
8.57E+02 0.716155 1.0E+00 3.2E+00 1000 100
6.48E+02 1.44898 1.0E+00 3.2E+00
3.30E+02 2.33855 1.0E+00 3.2E+00

5.00E-01 59.1082 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1741.83 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1771.24 104% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1851.61 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                                  1-1193
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb EaFA-L11-1316-T01-A 1
Sb EaFA-L11-1316-T02-A 1
Sb EaFA-L11-1316-T03-A 1
Sb EaFA-L11-1316-T04-A 1
Sb EaFA-L11-1316-T05-A
Sb EaFA-L11-1316-T01-B 1
Sb EaFA-L11-1316-T02-B 1
Sb EaFA-L11-1316-T03-B 1
Sb EaFA-L11-1316-T04-B 1
Sb EaFA-L11-1316-T05-B
Sb EaFA-L11-1316-T01-C 1
Sb EaFA-L11-1316-T02-C 1
Sb EaFA-L11-1316-T03-C 1
Sb EaFA-L11-1316-T04-C 1
Sb EaFA-L11-1316-T05-C
Sb EaFA-L11-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
100.052
165.379
183.996
410.459

120.638
151.015
201.161
452.922

89.757
136.325
200.079
420.564

19.184 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+02 18.8048 7.5E+00 2.4E+01
1.65E+02 20.6404 7.5E+00 2.4E+01 10 325
1.84E+02 7.7251 7.5E+00 2.4E+01
4.10E+02 7.6617 7.5E+00 2.4E+01

1.21E+02 11.6424 7.5E+00 2.4E+01
1.51E+02 19.4992 7.5E+00 2.4E+01 10 325
2.01E+02 14.2944 7.5E+00 2.4E+01
4.53E+02 16.995 7.5E+00 2.4E+01

8.98E+01 0.590429 7.5E+00 2.4E+01
1.36E+02 14.1151 7.5E+00 2.4E+01 10 325
2.00E+02 8.56931 7.5E+00 2.4E+01
4.21 E+02 2.55048 7.5E+00 2.4E+01

1.92E+01 33.7122 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3383.78 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3535.93 104% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3442.34 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1194
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As EaFA-L11-1316-T01-A 1
As EaFA-L11-1316-T02-A 1
As EaFA-L11-1316-T03-A 1
As EaFA-L11-1316-T04-A 1
As EaFA-L11-1316-T05-A
As EaFA-L11-1316-T01-B 1
As EaFA-L11-1316-T02-B 1
As EaFA-L11-1316-T03-B 1
As EaFA-L11-1316-T04-B 1
As EaFA-L11-1316-T05-B
As EaFA-L11-1316-T01-C 1
As EaFA-L11-1316-T02-C 1
As EaFA-L11-1316-T03-C 1
As EaFA-L11-1316-T04-C 1
As EaFA-L11-1316-T05-C
As EaFA-L11-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
129.403
1 1 1 .08
127.735
82.439

130.793
143.635
150.353
49.512

155.186
129.359
132.233
59.908

5.5 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.29E+02 15.2451 1.1E+01 3.5E+01
1.11E+02 18.0703 1.1E+01 3.5E+01 10 325
1.28E+02 6.22284 1.1E+01 3.5E+01
8.24E+01 50.3843 1.1E+01 3.5E+01

1.31E+02 6.98758 1.1E+01 3.5E+01
1.44E+02 14.2176 1.1E+01 3.5E+01 10 325
1.50E+02 16.1344 1.1E+01 3.5E+01
4.95E+01 83.4805 1.1E+01 3.5E+01

1.55E+02 2.05315 1.1E+01 3.5E+01
1.29E+02 4.45335 1.1E+01 3.5E+01 10 325
1.32E+02 9.42833 1.1E+01 3.5E+01
5.99E+01 20.6251 1.1E+01 3.5E+01

5.50E+00 48.7135 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3435.69 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3500.35 103% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3460.8 103% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1195
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qua
ug/L
B EaFA-L11-1316-T01-A 1 4060.04
B EaFA-L11-1316-T02-A 1 7659.26
B EaFA-L11-1316-T03-A 1 16165.6
B EaFA-L11-1316-T04-A 1 31363.2
B EaFA-L11-1316-T05-A
B EaFA-L11-1316-T01-B 1 4176.17
B EaFA-L11-1316-T02-B 1 7724.71
B EaFA-L11-1316-T03-B 1 16247.3
B EaFA-L11-1316-T04-B 1 33597.8
B EaFA-L11-1316-T05-B
B EaFA-L11-1316-T01-C 1 4228.04
B EaFA-L11-1316-T02-C 1 7889.76
B EaFA-L11-1316-T03-C 1 16682.7
B EaFA-L11-1316-T04-C 1 34551
B EaFA-L11-1316-T05-C
B EaFA-L11-1316-B01-A 1 12.339
Internal ICP-OES Spike Sol'n
ifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.06E+03 0.877445 1.0E+00 3.2E+00
7.66E+03 0.674971 1.0E+00 3.2E+00 1000 100
1.62E+04 1.24227 1.0E+00 3.2E+00
3.14E+04 2.35418 1.0E+00 3.2E+00

4.18E+03 0.778882 1.0E+00 3.2E+00
7.72E+03 1.3032 1.0E+00 3.2E+00 1000 100
1.62E+04 1.54927 1.0E+00 3.2E+00
3.36E+04 3.08961 1.0E+00 3.2E+00

4.23E+03 1.4278 1.0E+00 3.2E+00
7.89E+03 0.985866 1.0E+00 3.2E+00 1000 100
1.67E+04 1.1462 1.0E+00 3.2E+00
3.46E+04 0.885031 1.0E+00 3.2E+00

1.23E+01 5.37264 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
8533.62 87% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
8631.99 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
8808.14 92% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:13 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:15 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/1 1 3:23 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1196
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba EaFA-L11-1316-T01-A 1
Ba EaFA-L11-1316-T02-A 1
Ba EaFA-L11-1316-T03-A 1
Ba EaFA-L11-1316-T04-A 1
Ba EaFA-L11-1316-T05-A
Ba EaFA-L11-1316-T01-B 1
Ba EaFA-L11-1316-T02-B 1
Ba EaFA-L11-1316-T03-B 1
Ba EaFA-L11-1316-T04-B 1
Ba EaFA-L11-1316-T05-B
Ba EaFA-L11-1316-T01-C 1
Ba EaFA-L11-1316-T02-C 1
Ba EaFA-L11-1316-T03-C 1
Ba EaFA-L11-1316-T04-C 1
Ba EaFA-L11-1316-T05-C
Ba EaFA-L11-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
313.36
282.366
254.655
278.6

320.35
276.015
245.767
285.612

310.427
284.547
252.749
303.598

3.254
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.13E+02 0.263242 1.0E+00 3.2E+00
2.82E+02 0.200762 1.0E+00 3.2E+00 10 325
2.55E+02 1.59994 1.0E+00 3.2E+00
2.79E+02 0.543939 1.0E+00 3.2E+00

3.20E+02 0.842249 1.0E+00 3.2E+00
2.76E+02 0.895822 1.0E+00 3.2E+00 10 325
2.46E+02 0.638829 1.0E+00 3.2E+00
2.86E+02 0.244231 1.0E+00 3.2E+00

3.10E+02 0.684597 1.0E+00 3.2E+00
2.85E+02 0.993593 1.0E+00 3.2E+00 10 325
2.53E+02 0.575564 1.0E+00 3.2E+00
3.04E+02 0.380059 1.0E+00 3.2E+00

3.25E+00 18.0254 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3275.86 92% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3383.73 96% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3306.08 93% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:13 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:15 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/1 1 3:23 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:25 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:27 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:28 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/1 1 3:08 PM EPA Interlab L1 1 1313-1316 EaFA
                                                                                                                                                                         1-1197
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be EaFA-L11-1316-T01-A 1
Be EaFA-L11-1316-T02-A 1
Be EaFA-L11-1316-T03-A 1
Be EaFA-L11-1316-T04-A 1
Be EaFA-L11-1316-T05-A
Be EaFA-L11-1316-T01-B 1
Be EaFA-L11-1316-T02-B 1
Be EaFA-L11-1316-T03-B 1
Be EaFA-L11-1316-T04-B 1
Be EaFA-L11-1316-T05-B
Be EaFA-L11-1316-T01-C 1
Be EaFA-L11-1316-T02-C 1
Be EaFA-L11-1316-T03-C 1
Be EaFA-L11-1316-T04-C 1
Be EaFA-L11-1316-T05-C
Be EaFA-L11-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
0.95 U1/2
0.95 U1/2
0.95 U1/2
0.95 U1/2

0.95 U1/2
0.95 U1/2
0.95 U1/2
0.95 U1/2

0.95 U1/2
0.95 U1/2
0.95 U1/2
0.95 U1/2

0.95 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 66.7529 1.9E+00 6.0E+00
9.50E-01 40.4365 1.9E+00 6.0E+00 10 325
9.50E-01 223.881 1.9E+00 6.0E+00
9.50E-01 1632.4 1.9E+00 6.0E+00

9.50E-01 678.644 1.9E+00 6.0E+00
9.50E-01 258.104 1.9E+00 6.0E+00 10 325
9.50E-01 47.2553 1.9E+00 6.0E+00
9.50E-01 63.163 1.9E+00 6.0E+00

9.50E-01 42.9655 1.9E+00 6.0E+00
9.50E-01 190.473 1.9E+00 6.0E+00 10 325
9.50E-01 266.514 1.9E+00 6.0E+00
9.50E-01 370.674 1.9E+00 6.0E+00

9.50E-01 108.837 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3286.69 101% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3416.87 105% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3332.27 103% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1198
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 ug/L |
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd EaFA-L11-1316-T01-A 1 1.1 U1/2 1.10E+00 142.407 2.2E+00 7.0E+00
Cd EaFA-L11-1316-T02-A 1 1.1 U1/2 1.10E+00 138.799 2.2E+00 7.0E+00 10 325
Cd EaFA-L11-1316-T03-A 1 1.1 U1/2 1.10E+00 118.902 2.2E+00 7.0E+00
Cd EaFA-L11-1316-T04-A 1 2.37 E
Cd EaFA-L11-1316-T05-A
2.37E+00 37.9181 2.2E+00 7.0E+00

Cd EaFA-L11-1316-T01-B 1 1.1 U1/2 1.10E+00 181.041 2.2E+00 7.0E+00
Cd EaFA-L11-1316-T02-B 1 1.1 U1/2 1.10E+00 112.594 2.2E+00 7.0E+00 10 325
Cd EaFA-L11-1316-T03-B 1 1.1 U1/2 1.10E+00 177.969 2.2E+00 7.0E+00
Cd EaFA-L11-1316-T04-B 1 4.465 E
Cd EaFA-L11-1316-T05-B
4.47E+00 3.89756 2.2E+00 7.0E+00

Cd EaFA-L11-1316-T01-C 1 1.1 U1/2 1.10E+00 23.0744 2.2E+00 7.0E+00
Cd EaFA-L11-1316-T02-C 1 1.1 U1/2 1.10E+00 3182.28 2.2E+00 7.0E+00 10 325
Cd EaFA-L11-1316-T03-C 1 1.1 U1/2 1.10E+00 179.778 2.2E+00 7.0E+00
Cd EaFA-L11-1316-T04-C 1 4.808 E
Cd EaFA-L11-1316-T05-C
4.81E+00 25.1486 2.2E+00 7.0E+00

Cd EaFA-L11-1316-B01-A 1 1.1 U1/2 1.10E+00 39.8185 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3214.33 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3356.22 103% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3260.07 100% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1199
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
1 1 ug/L
Ca EaFA-L11-1316-T01-A 1 142136
Ca EaFA-L11-1316-T02-A 1 282438
Ca EaFA-L11-1316-T03-A 1 682815
Ca EaFA-L11-1316-T04-A 1 566074
Ca EaFA-L11-1316-T05-A
Ca EaFA-L11-1316-T01-B 1 142346
Ca EaFA-L11-1316-T02-B 1 282298
Ca EaFA-L11-1316-T03-B 1 682441
Ca EaFA-L11-1316-T04-B 1 540783
Ca EaFA-L11-1316-T05-B
Ca EaFA-L11-1316-T01-C 1 141864
Ca EaFA-L11-1316-T02-C 1 285031
Ca EaFA-L11-1316-T03-C 1 678878
Ca EaFA-L11-1316-T04-C 1 559830
Ca EaFA-L11-1316-T05-C
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.42E+05 0.119897 2.6E+00 8.3E+00
2.82E+05 1.0463 2.6E+00 8.3E+00 1000 100
6.83E+05 1.20318 2.6E+00 8.3E+00
5.66E+05 0.678374 2.6E+00 8.3E+00

1.42E+05 0.843683 2.6E+00 8.3E+00
2.82E+05 1.10484 2.6E+00 8.3E+00 1000 100
6.82E+05 0.565621 2.6E+00 8.3E+00
5.41 E+05 0.048435 2.6E+00 8.3E+00

1.42E+05 1.52646 2.6E+00 8.3E+00
2.85E+05 1.28235 2.6E+00 8.3E+00 1000 100
6.79E+05 0.769051 2.6E+00 8.3E+00
5.60E+05 0.450978 2.6E+00 8.3E+00

Ca EaFA-L11-1316-B01-A 1 1.3U1/2 1.30E+00 9.35462 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
283368 93% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
283174 88% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
285925 89% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1200
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr EaFA-L11-1316-T01-A 1
Cr EaFA-L11-1316-T02-A 1
Cr EaFA-L11-1316-T03-A 1
Cr EaFA-L11-1316-T04-A 1
Cr EaFA-L11-1316-T05-A
Cr EaFA-L11-1316-T01-B 1
Cr EaFA-L11-1316-T02-B 1
Cr EaFA-L11-1316-T03-B 1
Cr EaFA-L11-1316-T04-B 1
Cr EaFA-L11-1316-T05-B
Cr EaFA-L11-1316-T01-C 1
Cr EaFA-L11-1316-T02-C 1
Cr EaFA-L11-1316-T03-C 1
Cr EaFA-L11-1316-T04-C 1
Cr EaFA-L11-1316-T05-C
Cr EaFA-L11-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
315.402
537.232
957.154
204.225

321.532
539.171
976.954
85.529

318.341
542.257
958.676
85.02

0.6 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.15E+02 0.388233 1.2E+00 3.8E+00
5.37E+02 0.819347 1.2E+00 3.8E+00 10 325
9.57E+02 1.63057 1.2E+00 3.8E+00
2.04E+02 1.67282 1.2E+00 3.8E+00

3.22E+02 0.351263 1.2E+00 3.8E+00
5.39E+02 1.84432 1.2E+00 3.8E+00 10 325
9.77E+02 0.61846 1.2E+00 3.8E+00
8.55E+01 0.781066 1.2E+00 3.8E+00

3.18E+02 0.629303 1.2E+00 3.8E+00
5.42E+02 1.09523 1.2E+00 3.8E+00 10 325
9.59E+02 0.971424 1.2E+00 3.8E+00
8.50E+01 0.952107 1.2E+00 3.8E+00

6.00E-01 346.453 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3624.65 95% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3780.43 100% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3679.97 97% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA InterlabLH 1313-1316 EaFA
2/22/11 3:12 PM EPA InterlabLH 1313-1316 EaFA
2/22/11 3:13 PM EPA InterlabLH 1313-1316 EaFA
2/22/11 3:15 PM EPA InterlabLH 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1201
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co EaFA-L11-1316-T01-A 1
Co EaFA-L11-1316-T02-A 1
Co EaFA-L11-1316-T03-A 1
Co EaFA-L11-1316-T04-A 1
Co EaFA-L11-1316-T05-A
Co EaFA-L11-1316-T01-B 1
Co EaFA-L11-1316-T02-B 1
Co EaFA-L11-1316-T03-B 1
Co EaFA-L11-1316-T04-B 1
Co EaFA-L11-1316-T05-B
Co EaFA-L11-1316-T01-C 1
Co EaFA-L11-1316-T02-C 1
Co EaFA-L11-1316-T03-C 1
Co EaFA-L11-1316-T04-C 1
Co EaFA-L11-1316-T05-C
Co EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.901 E
0.9 U1/2
7.769
79.051

3.992 E
5.019 E
3.613 E
169.272

0.9 U1/2
4.578 E
5.656 E
174.09

0.9 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.90E+00 64.9828 1.8E+00 5.7E+00
9.00E-01 140.982 1.8E+00 5.7E+00 10 325
7.77E+00 14.0136 1.8E+00 5.7E+00
7.91E+01 6.15924 1.8E+00 5.7E+00

3.99E+00 110.531 1.8E+00 5.7E+00
5.02E+00 67.4448 1.8E+00 5.7E+00 10 325
3.61 E+00 72.2268 1.8E+00 5.7E+00
1.69E+02 3.57476 1.8E+00 5.7E+00

9.00E-01 13.5318 1.8E+00 5.7E+00
4.58E+00 64.3016 1.8E+00 5.7E+00 10 325
5.66E+00 77.6353 1.8E+00 5.7E+00
1.74E+02 2.86592 1.8E+00 5.7E+00

9.00E-01 67.5446 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3121.04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3271.79 101% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3176.53 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1202
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu EaFA-L11-1316-T01-A 1
Cu EaFA-L11-1316-T02-A 1
Cu EaFA-L11-1316-T03-A 1
Cu EaFA-L11-1316-T04-A 1
Cu EaFA-L11-1316-T05-A
Cu EaFA-L11-1316-T01-B 1
Cu EaFA-L11-1316-T02-B 1
Cu EaFA-L11-1316-T03-B 1
Cu EaFA-L11-1316-T04-B 1
Cu EaFA-L11-1316-T05-B
Cu EaFA-L11-1316-T01-C 1
Cu EaFA-L11-1316-T02-C 1
Cu EaFA-L11-1316-T03-C 1
Cu EaFA-L11-1316-T04-C 1
Cu EaFA-L11-1316-T05-C
Cu EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
17.715
22.771
24.257
22.878

12.109
1 1 .608 E
17.079
19.631

13.511
20.422
19.268
31.556

1.85 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+01 34.6117 3.7E+00 1.2E+01
2.28E+01 28.3511 3.7E+00 1.2E+01 10 325
2.43E+01 18.6996 3.7E+00 1.2E+01
2.29E+01 7.97491 3.7E+00 1.2E+01

1.21E+01 34.0558 3.7E+00 1.2E+01
1.16E+01 43.8654 3.7E+00 1.2E+01 10 325
1.71E+01 11.6577 3.7E+00 1.2E+01
1.96E+01 37.1987 3.7E+00 1.2E+01

1.35E+01 59.2357 3.7E+00 1.2E+01
2.04E+01 31.4759 3.7E+00 1.2E+01 10 325
1.93E+01 43.6449 3.7E+00 1.2E+01
3.16E+01 21.1697 3.7E+00 1.2E+01

1.85E+00 102.361 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3228.71 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3378.17 104% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3252.54 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1203
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe EaFA-L11-1316-T01-A 1
Fe EaFA-L11-1316-T02-A 1
Fe EaFA-L11-1316-T03-A 1
Fe EaFA-L11-1316-T04-A 1
Fe EaFA-L11-1316-T05-A
Fe EaFA-L11-1316-T01-B 1
Fe EaFA-L11-1316-T02-B 1
Fe EaFA-L11-1316-T03-B 1
Fe EaFA-L11-1316-T04-B 1
Fe EaFA-L11-1316-T05-B
Fe EaFA-L11-1316-T01-C 1
Fe EaFA-L11-1316-T02-C 1
Fe EaFA-L11-1316-T03-C 1
Fe EaFA-L11-1316-T04-C 1
Fe EaFA-L11-1316-T05-C
Fe EaFA-L11-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1 U1/2
1 U1/2
1 U1/2
1 U1/2

1 U1/2
1 U1/2
1 U1/2
1 U1/2

1 U1/2
1 U1/2
1 U1/2
1 U1/2

1 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.1016 2.0E+00 6.4E+00
1.00E+00 35.2947 2.0E+00 6.4E+00 1000 100
1.00E+00 91.6685 2.0E+00 6.4E+00
1.00E+00 17.9276 2.0E+00 6.4E+00

1.00E+00 25.9161 2.0E+00 6.4E+00
1.00E+00 31.8301 2.0E+00 6.4E+00 1000 100
1.00E+00 22.9146 2.0E+00 6.4E+00
1.00E+00 44.3095 2.0E+00 6.4E+00

1.00E+00 18.3098 2.0E+00 6.4E+00
1.00E+00 14.6757 2.0E+00 6.4E+00 1000 100
1.00E+00 14.8727 2.0E+00 6.4E+00
1.00E+00 13.1303 2.0E+00 6.4E+00

1.00E+00 12.8135 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1016.18 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1061.01 106% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1027.36 103% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1204
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb EaFA-L11-1316-T01-A 1
Pb EaFA-L11-1316-T02-A 1
Pb EaFA-L11-1316-T03-A 1
Pb EaFA-L11-1316-T04-A 1
Pb EaFA-L11-1316-T05-A
Pb EaFA-L11-1316-T01-B 1
Pb EaFA-L11-1316-T02-B 1
Pb EaFA-L11-1316-T03-B 1
Pb EaFA-L11-1316-T04-B 1
Pb EaFA-L11-1316-T05-B
Pb EaFA-L11-1316-T01-C 1
Pb EaFA-L11-1316-T02-C 1
Pb EaFA-L11-1316-T03-C 1
Pb EaFA-L11-1316-T04-C 1
Pb EaFA-L11-1316-T05-C
Pb EaFA-L11-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
3.4 U1/2
3.4 U1/2
3.4 U1/2
3.4 U1/2

3.4 U1/2
3.4 U1/2
3.4 U1/2
3.4 U1/2

3.4 U1/2
3.4 U1/2
3.4 U1/2
3.4 U1/2

3.4 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 1062.85 6.8E+00 2.2E+01
3.40E+00 40.6074 6.8E+00 2.2E+01 10 325
3.40E+00 226.672 6.8E+00 2.2E+01
3.40E+00 152.099 6.8E+00 2.2E+01

3.40E+00 91.4065 6.8E+00 2.2E+01
3.40E+00 33.8529 6.8E+00 2.2E+01 10 325
3.40E+00 35.0406 6.8E+00 2.2E+01
3.40E+00 109.16 6.8E+00 2.2E+01

3.40E+00 159.243 6.8E+00 2.2E+01
3.40E+00 22.4408 6.8E+00 2.2E+01 10 325
3.40E+00 88.4961 6.8E+00 2.2E+01
3.40E+00 83.9348 6.8E+00 2.2E+01

3.40E+00 109.273 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3131.4 96% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3290.75 101% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
31 77.38 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1205
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
1 1 ug/L
Li EaFA-L11-1316-T01-A 1 3483.77
Li EaFA-L11-1316-T02-A 1 6878.42
Li EaFA-L11-1316-T03-A 1 14764.5
Li EaFA-L11-1316-T04-A 1 32904
Li EaFA-L11-1316-T05-A
Li EaFA-L11-1316-T01-B 1 3492.27
Li EaFA-L11-1316-T02-B 1 6870.36
Li EaFA-L11-1316-T03-B 1 14794.6
Li EaFA-L11-1316-T04-B 1 33121
Li EaFA-L11-1316-T05-B
Li EaFA-L11-1316-T01-C 1 3471.65
Li EaFA-L11-1316-T02-C 1 6879.09
Li EaFA-L11-1316-T03-C 1 15044.3
Li EaFA-L11-1316-T04-C 1 34172.4
Li EaFA-L11-1316-T05-C
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.48E+03 0.532814 1.9E+00 6.0E+00
6.88E+03 0.245674 1.9E+00 6.0E+00 10 325
1.48E+04 0.919607 1.9E+00 6.0E+00
3.29E+04 0.87682 1.9E+00 6.0E+00

3.49E+03 0.99103 1.9E+00 6.0E+00
6.87E+03 1.1849 1.9E+00 6.0E+00 10 325
1.48E+04 0.588684 1.9E+00 6.0E+00
3.31 E+04 0.08216 1.9E+00 6.0E+00

3.47E+03 0.921124 1.9E+00 6.0E+00
6.88E+03 0.720342 1.9E+00 6.0E+00 10 325
1.50E+04 0.820499 1.9E+00 6.0E+00
3.42E+04 0.347893 1.9E+00 6.0E+00

Li EaFA-L11-1316-B01-A 1 0.95 U1/2 9.50E-01 23.1718 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9667.47 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
9692.7 87% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
9629.37 85% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA InterlabLH 1313-1316 EaFA
2/22/11 3:12 PM EPA InterlabLH 1313-1316 EaFA
2/22/11 3:13 PM EPA InterlabLH 1313-1316 EaFA
2/22/11 3:15 PM EPA InterlabLH 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1206
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. Qu<
1 1 ug/L |
Mn EaFA-L11-1316-T01-A 1 30.205
Mn EaFA-L11-1316-T02-A 1 52.644
Mn EaFA-L11-1316-T03-A 1 116.742
Mn EaFA-L11-1316-T04-A 1 900.11
Mn EaFA-L11-1316-T05-A
Mn EaFA-L11-1316-T01-B 1 29.593
Mn EaFA-L11-1316-T02-B 1 49.673
Mn EaFA-L11-1316-T03-B 1 100.923
Mn EaFA-L11-1316-T04-B 1 1619.74
Mn EaFA-L11-1316-T05-B
Mn EaFA-L11-1316-T01-C 1 30.287
Mn EaFA-L11-1316-T02-C 1 54.84
Mn EaFA-L11-1316-T03-C 1 108.692
Mn EaFA-L11-1316-T04-C 1 1679.77
Mn EaFA-L11-1316-T05-C
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.02E+01 1.10517 2.0E+00 6.4E+00
5.26E+01 0.785902 2.0E+00 6.4E+00 10 325
1.17E+02 0.900684 2.0E+00 6.4E+00
9.00E+02 0.737251 2.0E+00 6.4E+00

2.96E+01 0.573992 2.0E+00 6.4E+00
4.97E+01 1.00997 2.0E+00 6.4E+00 10 325
1.01E+02 0.599695 2.0E+00 6.4E+00
1.62E+03 2.0561 2.0E+00 6.4E+00

3.03E+01 1.24741 2.0E+00 6.4E+00
5.48E+01 1.24385 2.0E+00 6.4E+00 10 325
1.09E+02 0.711228 2.0E+00 6.4E+00
1.68E+03 0.629526 2.0E+00 6.4E+00

Mn EaFA-L11-1316-B01-A 1 1 U1/2 1.00E+00 13.738 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3239.84 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3376.98 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3281.71 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1207
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg EaFA-L11-1316-T01-A 1
Mg EaFA-L11-1316-T02-A 1
Mg EaFA-L11-1316-T03-A 1
Mg EaFA-L11-1316-T04-A 1
Mg EaFA-L11-1316-T05-A
Mg EaFA-L11-1316-T01-B 1
Mg EaFA-L11-1316-T02-B 1
Mg EaFA-L11-1316-T03-B 1
Mg EaFA-L11-1316-T04-B 1
Mg EaFA-L11-1316-T05-B
Mg EaFA-L11-1316-T01-C 1
Mg EaFA-L11-1316-T02-C 1
Mg EaFA-L11-1316-T03-C 1
Mg EaFA-L11-1316-T04-C 1
Mg EaFA-L11-1316-T05-C
Mg EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
6005.59
11761.2
28894.9
63924.1

5967.54
11710.1
28594.4
67183.6

5968.88
11617.9
29594.8
69688.2

0.5 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.01 E+03 0.905157 1.0E+00 3.2E+00
1.18E+04 0.371251 1.0E+00 3.2E+00 1000 100
2.89E+04 1.31276 1.0E+00 3.2E+00
6.39E+04 1.11193 1.0E+00 3.2E+00

5.97E+03 1.46837 1.0E+00 3.2E+00
1.17E+04 1.27192 1.0E+00 3.2E+00 1000 100
2.86E+04 1.36425 1.0E+00 3.2E+00
6.72E+04 0.951056 1.0E+00 3.2E+00

5.97E+03 1.07608 1.0E+00 3.2E+00
1.16E+04 1.46157 1.0E+00 3.2E+00 1000 100
2.96E+04 0.228855 1.0E+00 3.2E+00
6.97E+04 0.523743 1.0E+00 3.2E+00

5.00E-01 14.5818 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
12754.2 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
12734.9 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
12647.3 103% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1208
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 ug/L
Mo EaFA-L11-1316-T01-A 1 2677.58
Mo EaFA-L11-1316-T02-A 1 5116.07
Mo EaFA-L11-1316-T03-A 1 11515.9
Mo EaFA-L11-1316-T04-A 1 21653.3
Mo EaFA-L11-1316-T05-A
Mo EaFA-L11-1316-T01-B 1 2816.93
Mo EaFA-L11-1316-T02-B 1 5197.22
Mo EaFA-L11-1316-T03-B 1 11597.8
Mo EaFA-L11-1316-T04-B 1 20431.3
Mo EaFA-L11-1316-T05-B
Mo EaFA-L11-1316-T01-C 1 2803.08
Mo EaFA-L11-1316-T02-C 1 5181.73
Mo EaFA-L11-1316-T03-C 1 11569.7
Mo EaFA-L11-1316-T04-C 1 21032.5
Mo EaFA-L11-1316-T05-C
Mo EaFA-L11-1316-B01-A 1 9.759
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.68E+03 0.432666 1.2E+00 3.8E+00
5.12E+03 1.46622 1.2E+00 3.8E+00 10 325
1.15E+04 1.09509 1.2E+00 3.8E+00
2.17E+04 0.5755 1.2E+00 3.8E+00

2.82E+03 0.062872 1.2E+00 3.8E+00
5.20E+03 1.46151 1.2E+00 3.8E+00 10 325
1.16E+04 0.507237 1.2E+00 3.8E+00
2.04E+04 0.417057 1.2E+00 3.8E+00

2.80E+03 1.37263 1.2E+00 3.8E+00
5.18E+03 0.840544 1.2E+00 3.8E+00 10 325
1.16E+04 0.498529 1.2E+00 3.8E+00
2.10E+04 0.744689 1.2E+00 3.8E+00

9.76E+00 25.4768 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
7983.54 88% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
8061.28 88% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
7961.2 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1209
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni EaFA-L11-1316-T01-A 1
Ni EaFA-L11-1316-T02-A 1
Ni EaFA-L11-1316-T03-A 1
Ni EaFA-L11-1316-T04-A 1
Ni EaFA-L11-1316-T05-A
Ni EaFA-L11-1316-T01-B 1
Ni EaFA-L11-1316-T02-B 1
Ni EaFA-L11-1316-T03-B 1
Ni EaFA-L11-1316-T04-B 1
Ni EaFA-L11-1316-T05-B
Ni EaFA-L11-1316-T01-C 1
Ni EaFA-L11-1316-T02-C 1
Ni EaFA-L11-1316-T03-C 1
Ni EaFA-L11-1316-T04-C 1
Ni EaFA-L11-1316-T05-C
Ni EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
10.807
15.646
26.97
202.668

6.997
17.285
18.251
377.999

10.651
16.361
25.52
391.17

0.9 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+01 72.0127 1.8E+00 5.7E+00
1.56E+01 26.2746 1.8E+00 5.7E+00 10 325
2.70E+01 36.0655 1.8E+00 5.7E+00
2.03E+02 1.95336 1.8E+00 5.7E+00

7.00E+00 45.4502 1.8E+00 5.7E+00
1.73E+01 39.7357 1.8E+00 5.7E+00 10 325
1.83E+01 25.3972 1.8E+00 5.7E+00
3.78E+02 0.360396 1.8E+00 5.7E+00

1.07E+01 35.895 1.8E+00 5.7E+00
1.64E+01 51.4675 1.8E+00 5.7E+00 10 325
2.55E+01 48.711 1.8E+00 5.7E+00
3.91 E+02 2.45553 1.8E+00 5.7E+00

9.00E-01 58.2892 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3217.63 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3350.16 103% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3254.11 100% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1210
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P EaFA-L11-1316-T01-A 1
P EaFA-L11-1316-T02-A 1
P EaFA-L11-1316-T03-A 1
P EaFA-L11-1316-T04-A 1
P EaFA-L11-1316-T05-A
P EaFA-L11-1316-T01-B 1
P EaFA-L11-1316-T02-B 1
P EaFA-L11-1316-T03-B 1
P EaFA-L11-1316-T04-B 1
P EaFA-L11-1316-T05-B
P EaFA-L11-1316-T01-C 1
P EaFA-L11-1316-T02-C 1
P EaFA-L11-1316-T03-C 1
P EaFA-L11-1316-T04-C 1
P EaFA-L11-1316-T05-C
P EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
39.875
72.195
240.966
290.667

75.116
73.964
219.135
150.576

62.831
79.962
272.014
155.42

12.85
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.99E+01 21.0545 3.7E+00 1.2E+01
7.22E+01 16.0896 3.7E+00 1.2E+01 1000 100
2.41 E+02 5.55384 3.7E+00 1.2E+01
2.91 E+02 5.37928 3.7E+00 1.2E+01

7.51E+01 11.5102 3.7E+00 1.2E+01
7.40E+01 11.9926 3.7E+00 1.2E+01 1000 100
2.19E+02 5.45495 3.7E+00 1.2E+01
1.51 E+02 7.43081 3.7E+00 1.2E+01

6.28E+01 13.3311 3.7E+00 1.2E+01
8.00E+01 13.9011 3.7E+00 1.2E+01 1000 100
2.72E+02 5.47372 3.7E+00 1.2E+01
1.55E+02 9.14687 3.7E+00 1.2E+01

1.29E+01 71.2321 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1123.95 105% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1193.72 112% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1145.26 107% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1211
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K EaFA-L11-1316-T01-A 1
K EaFA-L11-1316-T02-A 1
K EaFA-L11-1316-T03-A 1
K EaFA-L11-1316-T04-A 1
K EaFA-L11-1316-T05-A
K EaFA-L11-1316-T01-B 1
K EaFA-L11-1316-T02-B 1
K EaFA-L11-1316-T03-B 1
K EaFA-L11-1316-T04-B 1
K EaFA-L11-1316-T05-B
K EaFA-L11-1316-T01-C 1
K EaFA-L11-1316-T02-C 1
K EaFA-L11-1316-T03-C 1
K EaFA-L11-1316-T04-C 1
K EaFA-L11-1316-T05-C
K EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
14030
27712.2
68777.1
183468

14057.5
27631.6
68494.6
206413

13991.3
28188.2
68927.3
212627

37.975
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.40E+04 0.616861 1.6E+00 5.1E+00
2.77E+04 1.43628 1.6E+00 5.1E+00 1000 100
6.88E+04 0.627447 1.6E+00 5.1E+00
1.83E+05 0.628656 1.6E+00 5.1E+00

1.41E+04 0.569827 1.6E+00 5.1E+00
2.76E+04 1.02545 1.6E+00 5.1E+00 1000 100
6.85E+04 0.328139 1.6E+00 5.1E+00
2.06E+05 0.114094 1.6E+00 5.1E+00

1.40E+04 0.943113 1.6E+00 5.1E+00
2.82E+04 1.6639 1.6E+00 5.1E+00 1000 100
6.89E+04 0.631062 1.6E+00 5.1E+00
2.13E+05 0.410507 1.6E+00 5.1E+00

3.80E+01 4.77753 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
28615 90% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
28542.8 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
29047.5 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:13 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:15 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:18 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/1 1 3:23 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:25 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:27 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:28 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/1 1 3:08 PM EPA Interlab L1 1 1313-1316 EaFA
                                                                                                                                                                         1-1212
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
1 ug/L
Se EaFA-L11-1316-T01-A 1 1008.61
Se EaFA-L11-1316-T02-A 1 1214.31
Se EaFA-L11-1316-T03-A 1 1499.42
Se EaFA-L11-1316-T04-A 1 1475.26
Se EaFA-L11-1316-T05-A
Se EaFA-L11-1316-T01-B 1 1019.85
Se EaFA-L11-1316-T02-B 1 1153.53
Se EaFA-L11-1316-T03-B 1 1639.52
Se EaFA-L11-1316-T04-B 1 1377.46
Se EaFA-L11-1316-T05-B
Se EaFA-L11-1316-T01-C 1 967.964
Se EaFA-L11-1316-T02-C 1 1211.68
Se EaFA-L11-1316-T03-C 1 1562.42
Se EaFA-L11-1316-T04-C 1 1329.11
Se EaFA-L11-1316-T05-C
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.01E+03 3.13533 1.5E+01 4.8E+01
1.21E+03 1.53033 1.5E+01 4.8E+01 10 325
1.50E+03 2.90192 1.5E+01 4.8E+01
1.48E+03 2.14462 1.5E+01 4.8E+01

1.02E+03 4.10181 1.5E+01 4.8E+01
1.15E+03 5.23526 1.5E+01 4.8E+01 10 325
1.64E+03 3.64835 1.5E+01 4.8E+01
1.38E+03 2.43762 1.5E+01 4.8E+01

9.68E+02 1.49279 1.5E+01 4.8E+01
1.21E+03 2.96007 1.5E+01 4.8E+01 10 325
1.56E+03 0.884472 1.5E+01 4.8E+01
1.33E+03 2.51272 1.5E+01 4.8E+01

Se EaFA-L11-1316-B01-A 1 30.964 E 3.10E+01 64.9878 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
4337.45 96% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
4466.35 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
4366.12 97% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:13 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:15 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/1 1 3:23 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1213
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si EaFA-L11-1316-T01-A 1
Si EaFA-L11-1316-T02-A 1
Si EaFA-L11-1316-T03-A 1
Si EaFA-L11-1316-T04-A 1
Si EaFA-L11-1316-T05-A
Si EaFA-L11-1316-T01-B 1
Si EaFA-L11-1316-T02-B 1
Si EaFA-L11-1316-T03-B 1
Si EaFA-L11-1316-T04-B 1
Si EaFA-L11-1316-T05-B
Si EaFA-L11-1316-T01-C 1
Si EaFA-L11-1316-T02-C 1
Si EaFA-L11-1316-T03-C 1
Si EaFA-L11-1316-T04-C 1
Si EaFA-L11-1316-T05-C
Si EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
612.515
699.255
805.9
1567.81

639.274
708.053
829.697
1951.18

649.866
673.42
820.333
2023.59

0.55 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.13E+02 1.39283 1.1E+00 3.5E+00
6.99E+02 1.19497 1.1E+00 3.5E+00 1000 100
8.06E+02 0.968886 1.1E+00 3.5E+00
1.57E+03 0.676624 1.1E+00 3.5E+00

6.39E+02 0.51867 1.1E+00 3.5E+00
7.08E+02 1.34987 1.1E+00 3.5E+00 1000 100
8.30E+02 0.656836 1.1E+00 3.5E+00
1.95E+03 0.64659 1.1E+00 3.5E+00

6.50E+02 0.787813 1.1E+00 3.5E+00
6.73E+02 1.21528 1.1E+00 3.5E+00 1000 100
8.20E+02 0.349339 1.1E+00 3.5E+00
2.02E+03 0.375631 1.1E+00 3.5E+00

5.50E-01 52.0401 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1660.62 96% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1702.76 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1652.09 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1214
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone.
Na EaFA-L11-1316-T01-A 1 4113.03
Na EaFA-L11-1316-T02-A 1 8291.46
Na EaFA-L11-1316-T03-A 1 21438.2
Na EaFA-L11-1316-T04-A 1 40997.2
Na EaFA-L11-1316-T05-A
Na EaFA-L11-1316-T01-B 1 4055.5
Na EaFA-L11-1316-T02-B 1 8285.65
Na EaFA-L11-1316-T03-B 1 21245.6
Na EaFA-L11-1316-T04-B 1 41479.9
Na EaFA-L11-1316-T05-B
Na EaFA-L11-1316-T01-C 1 4065.32
Na EaFA-L11-1316-T02-C 1 8321.59
Na EaFA-L11-1316-T03-C 1 21210
Na EaFA-L11-1316-T04-C 1 42367.6
Na EaFA-L11-1316-T05-C
Na EaFA-L11-1316-B01-A 1 23.097
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.11E+03 0.934119 2.5E+00 8.0E+00
8.29E+03 0.430637 2.5E+00 8.0E+00 1000 100
2.14E+04 1.2498 2.5E+00 8.0E+00
4.10E+04 0.526562 2.5E+00 8.0E+00

4.06E+03 1.19866 2.5E+00 8.0E+00
8.29E+03 1.21707 2.5E+00 8.0E+00 1000 100
2.12E+04 0.131332 2.5E+00 8.0E+00
4.15E+04 0.382972 2.5E+00 8.0E+00

4.07E+03 0.817813 2.5E+00 8.0E+00
8.32E+03 1.38855 2.5E+00 8.0E+00 1000 100
2.12E+04 0.953447 2.5E+00 8.0E+00
4.24E+04 1.62488 2.5E+00 8.0E+00

2.31 E+01 3.84468 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
9360.3 107% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
9313.87 103% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
9345.31 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1215
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone.
EaFA-L11-1316-T01-A 1 1820.32
EaFA-L11-1316-T02-A 1 2919.57
EaFA-L11-1316-T03-A 1 5376.77
EaFA-L11-1316-T04-A 1 7264.32
EaFA-L11-1316-T05-A
EaFA-L11-1316-T01-B 1 1823.8
EaFA-L11-1316-T02-B 1 2957.99
EaFA-L11-1316-T03-B 1 5136.73
EaFA-L11-1316-T04-B 1 8924.87
EaFA-L11-1316-T05-B
EaFA-L11-1316-T01-C 1 1830.9
EaFA-L11-1316-T02-C 1 3061.46
EaFA-L11-1316-T03-C 1 5306.19
EaFA-L11-1316-T04-C 1 8995.52
EaFA-L11-1316-T05-C
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.82E+03 0.599407 1.0E+00 3.2E+00
2.92E+03 0.59003 1.0E+00 3.2E+00 1000 100
5.38E+03 2.16434 1.0E+00 3.2E+00
7.26E+03 1.45962 1.0E+00 3.2E+00

1.82E+03 0.962685 1.0E+00 3.2E+00
2.96E+03 0.535358 1.0E+00 3.2E+00 1000 100
5.14E+03 0.454804 1.0E+00 3.2E+00
8.92E+03 1.99201 1.0E+00 3.2E+00

1.83E+03 1.61228 1.0E+00 3.2E+00
3.06E+03 0.846235 1.0E+00 3.2E+00 1000 100
5.31 E+03 0.303608 1.0E+00 3.2E+00
9.00E+03 1.01228 1.0E+00 3.2E+00

EaFA-L11-1316-B01-A 1 0.5 U1/2 5.00E-01 243275 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3838.34 92% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3833.23 88% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3949.91 89% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:13 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:15 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/1 1 3:23 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1216
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
1 ug/L
S EaFA-L11-1316-T01-A 1 143243
S EaFA-L11-1316-T02-A 1 281738
S EaFA-L11-1316-T03-A 1 668728
S EaFA-L11-1316-T04-A 1 765992
S EaFA-L11-1316-T05-A
S EaFA-L11-1316-T01-B 1 143722
S EaFA-L11-1316-T02-B 1 284299
S EaFA-L11-1316-T03-B 1 667913
S EaFA-L11-1316-T04-B 1 773385
S EaFA-L11-1316-T05-B
S EaFA-L11-1316-T01-C 1 143410
S EaFA-L11-1316-T02-C 1 287660
S EaFA-L11-1316-T03-C 1 675917
S EaFA-L11-1316-T04-C 1 797883
S EaFA-L11-1316-T05-C
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.43E+05 0.144451 6.8E+00 2.2E+01
2.82E+05 0.972749 6.8E+00 2.2E+01 1000 100
6.69E+05 0.745685 6.8E+00 2.2E+01
7.66E+05 0.456406 6.8E+00 2.2E+01

1.44E+05 0.438072 6.8E+00 2.2E+01
2.84E+05 1.40204 6.8E+00 2.2E+01 1000 100
6.68E+05 0.254033 6.8E+00 2.2E+01
7.73E+05 0.465961 6.8E+00 2.2E+01

1.43E+05 0.801036 6.8E+00 2.2E+01
2.88E+05 1.49908 6.8E+00 2.2E+01 1000 100
6.76E+05 0.486994 6.8E+00 2.2E+01
7.98E+05 0.429076 6.8E+00 2.2E+01

S EaFA-L11-1316-B01-A 1 11.06 E 1.11E+01 61.779 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
372228 90% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
370352 86% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
370898 83% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:13 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:15 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:18 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1217
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl EaFA-L11-1316-T01-A 1
Tl EaFA-L11-1316-T02-A 1
Tl EaFA-L11-1316-T03-A 1
Tl EaFA-L11-1316-T04-A 1
Tl EaFA-L11-1316-T05-A
Tl EaFA-L11-1316-T01-B 1
Tl EaFA-L11-1316-T02-B 1
Tl EaFA-L11-1316-T03-B 1
Tl EaFA-L11-1316-T04-B 1
Tl EaFA-L11-1316-T05-B
Tl EaFA-L11-1316-T01-C 1
Tl EaFA-L11-1316-T02-C 1
Tl EaFA-L11-1316-T03-C 1
Tl EaFA-L11-1316-T04-C 1
Tl EaFA-L11-1316-T05-C
Tl EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.3 U1/2
2.3 U1/2
2.3 U1/2
13.765 E

2.3 U1/2
2.3 U1/2
2.3 U1/2
22.262

2.3 U1/2
2.3 U1/2
2.3 U1/2
21.055

2.3 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 89.0619 4.6E+00 1 .5E+01
2.30E+00 879.407 4.6E+00 1 .5E+01 10 325
2.30E+00 2850.49 4.6E+00 1 .5E+01
1.38E+01 85.7597 4.6E+00 1 .5E+01

2.30E+00 92.0115 4.6E+00 1 .5E+01
2.30E+00 94.9131 4.6E+00 1 .5E+01 10 325
2.30E+00 135.882 4.6E+00 1 .5E+01
2.23E+01 77.045 4.6E+00 1 .5E+01

2.30E+00 193.718 4.6E+00 1 .5E+01
2.30E+00 253.176 4.6E+00 1 .5E+01 10 325
2.30E+00 260.484 4.6E+00 1 .5E+01
2.11E+01 70.2968 4.6E+00 1 .5E+01

2.30E+00 57.1781 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3161.97 97% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3288.18 101% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3171.36 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:13 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:15 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/1 1 3:23 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:27 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1218
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti EaFA-L11-1316-T01-A 1
Ti EaFA-L11-1316-T02-A 1
Ti EaFA-L11-1316-T03-A 1
Ti EaFA-L11-1316-T04-A 1
Ti EaFA-L11-1316-T05-A
Ti EaFA-L11-1316-T01-B 1
Ti EaFA-L11-1316-T02-B 1
Ti EaFA-L11-1316-T03-B 1
Ti EaFA-L11-1316-T04-B 1
Ti EaFA-L11-1316-T05-B
Ti EaFA-L11-1316-T01-C 1
Ti EaFA-L11-1316-T02-C 1
Ti EaFA-L11-1316-T03-C 1
Ti EaFA-L11-1316-T04-C 1
Ti EaFA-L11-1316-T05-C
Ti EaFA-L11-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1 U1/2
1 U1/2
1 U1/2
1 U1/2

1 U1/2
1 U1/2
1 U1/2
1 U1/2

1 U1/2
1 U1/2
1 U1/2
1 U1/2

1 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 41.819 2.0E+00 6.4E+00
1.00E+00 10.2312 2.0E+00 6.4E+00 10 325
1.00E+00 96.0468 2.0E+00 6.4E+00
1.00E+00 29.3904 2.0E+00 6.4E+00

1.00E+00 41.3342 2.0E+00 6.4E+00
1.00E+00 190.868 2.0E+00 6.4E+00 10 325
1.00E+00 103.337 2.0E+00 6.4E+00
1.00E+00 59.0268 2.0E+00 6.4E+00

1.00E+00 97.7126 2.0E+00 6.4E+00
1.00E+00 182.226 2.0E+00 6.4E+00 10 325
1.00E+00 81.0124 2.0E+00 6.4E+00
1.00E+00 70.8312 2.0E+00 6.4E+00

1.00E+00 772.29 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3189.15 98% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3319.15 102% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3212.52 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:1 7PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1219
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V EaFA-L11-1316-T01-A 1
V EaFA-L11-1316-T02-A 1
V EaFA-L11-1316-T03-A 1
V EaFA-L11-1316-T04-A 1
V EaFA-L11-1316-T05-A
V EaFA-L11-1316-T01-B 1
V EaFA-L11-1316-T02-B 1
V EaFA-L11-1316-T03-B 1
V EaFA-L11-1316-T04-B 1
V EaFA-L11-1316-T05-B
V EaFA-L11-1316-T01-C 1
V EaFA-L11-1316-T02-C 1
V EaFA-L11-1316-T03-C 1
V EaFA-L11-1316-T04-C 1
V EaFA-L11-1316-T05-C
V EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
142.54
162.163
220.4
223.503

147.851
152.771
214.3
227.141

138.055
161.53
212.163
229.91

4.673 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.43E+02 1.84977 1.5E+00 4.8E+00
1.62E+02 4.0324 1.5E+00 4.8E+00 10 325
2.20E+02 3.25198 1.5E+00 4.8E+00
2.24E+02 1.88814 1.5E+00 4.8E+00

1.48E+02 1.19955 1.5E+00 4.8E+00
1.53E+02 2.60016 1.5E+00 4.8E+00 10 325
2.14E+02 1.92128 1.5E+00 4.8E+00
2.27E+02 1.06881 1.5E+00 4.8E+00

1.38E+02 1.85939 1.5E+00 4.8E+00
1.62E+02 1.81809 1.5E+00 4.8E+00 10 325
2.12E+02 1.04353 1.5E+00 4.8E+00
2.30E+02 0.201894 1.5E+00 4.8E+00

4.67E+00 21.8858 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3277.3 96% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3410.2 100% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3322.65 97% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/1 1 3:20 PM EPA Interlab L1 1 1313-1316 EaFA
2/22/1 1 3:22 PM EPA Interlab L1 1 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1220
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn EaFA-L11-1316-T01-A 1
Zn EaFA-L11-1316-T02-A 1
Zn EaFA-L11-1316-T03-A 1
Zn EaFA-L11-1316-T04-A 1
Zn EaFA-L11-1316-T05-A
Zn EaFA-L11-1316-T01-B 1
Zn EaFA-L11-1316-T02-B 1
Zn EaFA-L11-1316-T03-B 1
Zn EaFA-L11-1316-T04-B 1
Zn EaFA-L11-1316-T05-B
Zn EaFA-L11-1316-T01-C 1
Zn EaFA-L11-1316-T02-C 1
Zn EaFA-L11-1316-T03-C 1
Zn EaFA-L11-1316-T04-C 1
Zn EaFA-L11-1316-T05-C
Zn EaFA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
5.272
2.295 E
5.802
15.268

5.37
4.694
6.974
26.204

3.765
2.091 E
6.366
19.05

0.5 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.27E+00 6.45146 1.0E+00 3.2E+00
2.30E+00 7.16154 1.0E+00 3.2E+00 10 325
5.80E+00 20.4762 1.0E+00 3.2E+00
1.53E+01 8.43378 1.0E+00 3.2E+00

5.37E+00 30.1232 1.0E+00 3.2E+00
4.69E+00 34.7608 1.0E+00 3.2E+00 10 325
6.97E+00 56.6351 1.0E+00 3.2E+00
2.62E+01 5.7933 1.0E+00 3.2E+00

3.77E+00 21.375 1.0E+00 3.2E+00
2.09E+00 26.0894 1.0E+00 3.2E+00 10 325
6.37E+00 6.27961 1.0E+00 3.2E+00
1.91E+01 0.658378 1.0E+00 3.2E+00

5.00E-01 64.2724 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
3245.5 100% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3371.72 104% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
3269.32 101% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
Date/Time Filename
2/22/11 3:10 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:12 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:13 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:15 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:17 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:18 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:20 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:22 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:23 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:25 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:27 PM EPA Interlab L11 1313-1316 EaFA
2/22/11 3:28 PM EPA Interlab L11 1313-1316 EaFA

2/22/11 3:08 PM EPA Interlab L11 1313-1316 EaFA
                                                                                                                                                                         1-1221
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample Internal
Sample Dilution Cone. Qualifier Review
I I ug/L I I
EaFA-LRef-1316-T01-A 1 2.02E+02
EaFA-LRef-1316-T02-A 1 1.86E+02
EaFA-LRef-1316-T03-A 1 2.79E+02
EaFA-LRef-1316-T04-A 1 4.31E+02
EaFA-LRef-1316-T05-A
EaFA-LRef-1316-T01-B 1 2.24E+02
EaFA-LRef-1316-T02-B 1 1.91E+02
EaFA-LRef-1316-T03-B 1 2.93E+02
EaFA-LRef-1316-T04-B 1 4.43E+02
EaFA-LRef-1316-T05-B
EaFA-LRef-1316-T01-C 1 2.60E+02
EaFA-LRef-1316-T02-C 1 1.83E+02
EaFA-LRef-1316-T03-C 1 2.74E+02
EaFA-LRef-1316-T04-C 1 4.34E+02
EaFA-LRef-1316-T05-C
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.02E+02 3.2E+00 1.0E+00 3.2E+00
1.86E+02 8.1E-02 1.0E+00 3.2E+00 1000 100
2.79E+02 5.1E+00 1.0E+00 3.2E+00
4.31 E+02 1.2E+00 1.0E+00 3.2E+00

2.24E+02 1.0E+00 1.0E+00 3.2E+00
1.91 E+02 1.9E+00 1.0E+00 3.2E+00
2.93E+02 5.5E+00 1.0E+00 3.2E+00
4.43E+02 2.0E+00 1.0E+00 3.2E+00

2.60E+02 1.7E+00 1.0E+00 3.2E+00
1.83E+02 2.2E+00 1.0E+00 3.2E+00
2.74E+02 1.1E+00 1.0E+00 3.2E+00
4.34E+02 2.4E+00 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.03E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES

Date/Time Filename
5/6/1 08:26 AM EPA Interlab LRefA-C 1313-1316 EaFA
5/7/103:41 PM EPA Interlab LRefA-C 1313-1316 EaFA
5/7/10 3:43 PM EPA Interlab LRefA-C 1313-1316 EaFA
5/7/10 3:45 PM EPA Interlab LRefA-C 1313-1316 EaFA

5/6/10 8:49 AM EPA Interlab LRefA-C 1313-1316 EaFA
5/7/10 3:46 PM EPA Interlab LRefA-C 1313-1316 EaFA
5/7/10 3:48 PM EPA Interlab LRefA-C 1313-1316 EaFA
5/7/10 3:50 PM EPA Interlab LRefA-C 1313-1316 EaFA

5/6/10 9:13 AM EPA Interlab LRefA-C 1313-1316 EaFA
5/7/103:51 PM EPA Interlab LRefA-C 1313-1316 EaFA
5/7/10 3:53 PM EPA Interlab LRefA-C 1313-1316 EaFA
5/7/10 3:54 PM EPA Interlab LRefA-C 1313-1316 EaFA

                                                                                                                                                                                   1-1222
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone.
1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L ML
Sb EaFA-LRef-1316-T01-A 1 1.48E+02 1.48E+02 2.0E+01 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T02-A 1 4.20E+02 4.20E+02 7.6E+00 7.5E+00 2.4E+01 10 325
Sb EaFA-LRef-1316-T03-A 1 5.03E+02 5.03E+02 1.2E+01 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T04-A 1 7.41E+02 7.41E+02 5.5E+00 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T05-A

Sb EaFA-LRef-1316-T01-B 1 1.28E+02 1.28E+02 7.1E+00 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T02-B 1 4.72E+02 4.72E+02 6.8E+00 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T03-B 1 5.40E+02 5.40E+02 7.3E+00 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T04-B 1 6.87E+02 6.87E+02 1.2E+01 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T05-B

Sb EaFA-LRef-1316-T01-C 1 1.17E+02 1.17E+02 2.3E+01 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T02-C 1 3.63E+02 3.63E+02 9.6E+00 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T03-C 1 5.00E+02 5.00E+02 9.1E+00 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T04-C 1 6.81E+02 6.81E+02 7.8E+00 7.5E+00 2.4E+01
Sb EaFA-LRef-1316-T05-C

Splke Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.53E+03 96% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1223
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dili]
As EaFA-LRef-1316-T01-A
As EaFA-LRef-1316-T02-A
As EaFA-LRef-1316-T03-A
As EaFA-LRef-1316-T04-A
As EaFA-LRef-1316-T05-A
As EaFA-LRef-1316-T01-B
As EaFA-LRef-1316-T02-B
As EaFA-LRef-1316-T03-B
As EaFA-LRef-1316-T04-B
As EaFA-LRef-1316-T05-B
As EaFA-LRef-1316-T01-C
As EaFA-LRef-1316-T02-C
As EaFA-LRef-1316-T03-C
As EaFA-LRef-1316-T04-C
As EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 7.84E+01
1 1.72E+02
1 2.21E+02
1 1.86E+02

1 6.43E+01
1 1.80E+02
1 1.53E+02
1 2.13E+02

1 7.23E+01
1 1.73E+02
1 1.46E+02
1 1.82E+02

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
7.84E+01 3.4E+01 1.1E+01 3.5E+01
1.72E+02 1.3E+01 1.1E+01 3.5E+01 10 325
2.21E+02 2.6E+01 1.1E+01 3.5E+01
1.86E+02 1.1E+01 1.1E+01 3.5E+01

6.43E+01 1.9E+01 1.1E+01 3.5E+01
1.80E+02 2.9E+01 1.1E+01 3.5E+01
1.53E+02 1.4E+01 1.1E+01 3.5E+01
2.13E+02 7.5E+00 1.1E+01 3.5E+01

7.23E+01 1.4E+01 1.1E+01 3.5E+01
1.73E+02 2.7E+01 1.1E+01 3.5E+01
1.46E+02 3.5E+01 1.1E+01 3.5E+01
1.82E+02 2.2E+01 1.1E+01 3.5E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.37E+03 98% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1224
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dili]
B EaFA-LRef-1316-T01-A
B EaFA-LRef-1316-T02-A
B EaFA-LRef-1316-T03-A
B EaFA-LRef-1316-T04-A
B EaFA-LRef-1316-T05-A
B EaFA-LRef-1316-T01-B
B EaFA-LRef-1316-T02-B
B EaFA-LRef-1316-T03-B
B EaFA-LRef-1316-T04-B
B EaFA-LRef-1316-T05-B
B EaFA-LRef-1316-T01-C
B EaFA-LRef-1316-T02-C
B EaFA-LRef-1316-T03-C
B EaFA-LRef-1316-T04-C
B EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 4.62E+03
1 8.16E+03
1 1.82E+04
1 3.76E+04

1 4.47E+03
1 9.00E+03
1 2.07E+04
1 3.43E+04

1 4.43E+03
1 7.93E+03
1 1.88E+04
1 3.18E+04

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
4.62E+03 2.2E+00 1.0E+00 3.2E+00
8.16E+03 1.4E+00 1.0E+00 3.2E+00 1000 100
1.82E+04 1.9E+00 1.0E+00 3.2E+00
3.76E+04 7.5E-01 1.0E+00 3.2E+00

4.47E+03 7.8E-01 1.0E+00 3.2E+00
9.00E+03 1.2E+00 1.0E+00 3.2E+00
2.07E+04 4.6E-01 1.0E+00 3.2E+00
3.43E+04 1.5E+00 1.0E+00 3.2E+00

4.43E+03 1.6E-01 1.0E+00 3.2E+00
7.93E+03 4.4E-01 1.0E+00 3.2E+00
1.88E+04 1.1E+00 1.0E+00 3.2E+00
3.18E+04 1.4E+00 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
9.05E+03 89% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1225
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone.
ug/L
Ba EaFA-LRef-1316-T01-A 1 2.60E+02
Ba EaFA-LRef-1316-T02-A 1 1.82E+02
Ba EaFA-LRef-1316-T03-A 1 1.95E+02
Ba EaFA-LRef-1316-T04-A 1 1.79E+02
Ba EaFA-LRef-1316-T05-A
Ba EaFA-LRef-1316-T01-B 1 2.46E+02
Ba EaFA-LRef-1316-T02-B 1 2.01E+02
Ba EaFA-LRef-1316-T03-B 1 2.01E+02
Ba EaFA-LRef-1316-T04-B 1 1.65E+02
Ba EaFA-LRef-1316-T05-B
Ba EaFA-LRef-1316-T01-C 1 2.44E+02
Ba EaFA-LRef-1316-T02-C 1 1.79E+02
Ba EaFA-LRef-1316-T03-C 1 1.84E+02
Ba EaFA-LRef-1316-T04-C 1 1.61E+02
Ba EaFA-LRef-1316-T05-C
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L. M9/L ML
2.60E+02 5.7E-01 1.0E+00 3.2E+00
1.82E+02 1.3E+00 1.0E+00 3.2E+00 10 325
1.95E+02 6.9E-01 1.0E+00 3.2E+00
1.79E+02 9.5E-01 1.0E+00 3.2E+00

2.46E+02 5.6E-01 1.0E+00 3.2E+00
2.01 E+02 8.8E-01 1.0E+00 3.2E+00
2.01 E+02 2.9E-01 1.0E+00 3.2E+00
1.65E+02 7.6E-01 1.0E+00 3.2E+00

2.44E+02 8.6E-02 1.0E+00 3.2E+00
1.79E+02 1.1E+00 1.0E+00 3.2E+00
1.84E+02 4.1E-01 1.0E+00 3.2E+00
1.61E+02 2.1E-01 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.22E+03 94% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1226
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dili]
Be EaFA-LRef-1316-T01-A
Be EaFA-LRef-1316-T02-A
Be EaFA-LRef-1316-T03-A
Be EaFA-LRef-1316-T04-A
Be EaFA-LRef-1316-T05-A
Be EaFA-LRef-1316-T01-B
Be EaFA-LRef-1316-T02-B
Be EaFA-LRef-1316-T03-B
Be EaFA-LRef-1316-T04-B
Be EaFA-LRef-1316-T05-B
Be EaFA-LRef-1316-T01-C
Be EaFA-LRef-1316-T02-C
Be EaFA-LRef-1316-T03-C
Be EaFA-LRef-1316-T04-C
Be EaFA-LRef-1316-T05-C
Sample Inter
tlon Cone. Qualifier Rev
ug/L
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2

1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2

1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2

nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
9.50E-01 6.4E+00 1.9E+00 6.0E+00
9.50E-01 3.7E+02 1.9E+00 6.0E+00 10 325
9.50E-01 4.2E+02 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00

9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 4.3E+01 1.9E+00 6.0E+00

9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 3.9E+01 1.9E+00 6.0E+00
9.50E-01 3.1E+02 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/108:26AM EPA Interlab LRef A-C 1313-1316 EaFA
3.11E+03 96% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1227
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dili]
Cd EaFA-LRef-1316-T01-A
Cd EaFA-LRef-1316-T02-A
Cd EaFA-LRef-1316-T03-A
Cd EaFA-LRef-1316-T04-A
Cd EaFA-LRef-1316-T05-A
Cd EaFA-LRef-1316-T01-B
Cd EaFA-LRef-1316-T02-B
Cd EaFA-LRef-1316-T03-B
Cd EaFA-LRef-1316-T04-B
Cd EaFA-LRef-1316-T05-B
Cd EaFA-LRef-1316-T01-C
Cd EaFA-LRef-1316-T02-C
Cd EaFA-LRef-1316-T03-C
Cd EaFA-LRef-1316-T04-C
Cd EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 4.67E+00 E
1 3.56E+00 E

1 1.10E+OOU1/2
1 3.38E+00 E
1 6.60E+00 E
1 1.10E+OOU1/2

1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 4.40E+00 E
1 1.10E+OOU1/2

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L. M9/L ML
1.10E+00 3.5E+01 2.2E+00 7.0E+00
1.10E+00 9.1E+01 2.2E+00 7.0E+00 10 325
4.67E+00 3.1E+01 2.2E+00 7.0E+00
3.56E+00 2.7E+01 2.2E+00 7.0E+00

1.10E+00 5.5E+01 2.2E+00 7.0E+00
3.38E+00 2.4E+01 2.2E+00 7.0E+00
6.60E+00 2.2E+01 2.2E+00 7.0E+00
1.10E+00 4.6E+01 2.2E+00 7.0E+00

1.10E+00 1.4E+01 2.2E+00 7.0E+00
1.10E+00 1.4E+03 2.2E+00 7.0E+00
4.40E+00 4.8E+01 2.2E+00 7.0E+00
1.10E+00 2.4E+02 2.2E+00 7.0E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. %
VU ICP-OES 5/6/108:26AM EPA Interlab LRef A-C 1313-1316 EaFA
3.62E+03 111% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/1 0 3:43 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:45 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1228
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dili]
Ca EaFA-LRef-1316-T01-A
Ca EaFA-LRef-1316-T02-A
Ca EaFA-LRef-1316-T03-A
Ca EaFA-LRef-1316-T04-A
Ca EaFA-LRef-1316-T05-A
Ca EaFA-LRef-1316-T01-B
Ca EaFA-LRef-1316-T02-B
Ca EaFA-LRef-1316-T03-B
Ca EaFA-LRef-1316-T04-B
Ca EaFA-LRef-1316-T05-B
Ca EaFA-LRef-1316-T01-C
Ca EaFA-LRef-1316-T02-C
Ca EaFA-LRef-1316-T03-C
Ca EaFA-LRef-1316-T04-C
Ca EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 1.55E+05
1 2.94E+05
1 6.45E+05
1 4.46E+05

1 1.47E+05
1 3.10E+05
1 7.30E+05
1 4.95E+05

1 1.41E+05
1 2.61 E+05
1 6.49E+05
1 4.53E+05

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
1.55E+05 1.0E+00 2.6E+00 8.3E+00
2.94E+05 1.5E-01 2.6E+00 8.3E+00 1000 100
6.45E+05 6.2E-01 2.6E+00 8.3E+00
4.46E+05 7.6E-01 2.6E+00 8.3E+00

1.47E+05 6.3E-01 2.6E+00 8.3E+00
3.10E+05 3.0E-01 2.6E+00 8.3E+00
7.30E+05 6.9E-01 2.6E+00 8.3E+00
4.95E+05 1.2E+00 2.6E+00 8.3E+00

1.41 E+05 3.2E-01 2.6E+00 8.3E+00
2.61 E+05 1.5E+00 2.6E+00 8.3E+00
6.49E+05 4.0E-01 2.6E+00 8.3E+00
4.53E+05 6.0E-01 2.6E+00 8.3E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
2.95E+05 93% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1229
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dili]
Cr EaFA-LRef-1316-T01-A
Cr EaFA-LRef-1316-T02-A
Cr EaFA-LRef-1316-T03-A
Cr EaFA-LRef-1316-T04-A
Cr EaFA-LRef-1316-T05-A
Cr EaFA-LRef-1316-T01-B
Cr EaFA-LRef-1316-T02-B
Cr EaFA-LRef-1316-T03-B
Cr EaFA-LRef-1316-T04-B
Cr EaFA-LRef-1316-T05-B
Cr EaFA-LRef-1316-T01-C
Cr EaFA-LRef-1316-T02-C
Cr EaFA-LRef-1316-T03-C
Cr EaFA-LRef-1316-T04-C
Cr EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 4.22E+01
1 1.39E+01
1 1.60E+01
1 2.59E+01

1 5.43E+01
1 1.51E+01
1 1.93E+01
1 2.80E+01

1 6.01E+01
1 1.66E+01
1 1.97E+01
1 3.00E+01

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
4.22E+01 2.7E+00 1.2E+00 3.8E+00
1.39E+01 2.7E+01 1.2E+00 3.8E+00 10 325
1.60E+01 2.2E+01 1.2E+00 3.8E+00
2.59E+01 3.2E+00 1.2E+00 3.8E+00

5.43E+01 3.1E+00 1.2E+00 3.8E+00
1.51E+01 3.8E+01 1.2E+00 3.8E+00
1.93E+01 6.5E+00 1.2E+00 3.8E+00
2.80E+01 1.0E+01 1.2E+00 3.8E+00

6.01 E+01 2.5E+00 1.2E+00 3.8E+00
1.66E+01 1.7E+01 1.2E+00 3.8E+00
1.97E+01 3.6E+01 1.2E+00 3.8E+00
3.00E+01 1.0E+01 1.2E+00 3.8E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.61 E+03 111% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1230
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone.
ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
Co EaFA-LRef-1316-T01-A 1 2.93E+01 2.93E+01 3.4E+00 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T02-A 1 7.79E+01 7.79E+01 4.5E+00 1.8E+00 5.7E+00 10 325
Co EaFA-LRef-1316-T03-A 1 1.81E+02 1.81E+02 2.4E-01 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T04-A 1 1.08E+02 1.08E+02 1.4E+00 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T05-A

Co EaFA-LRef-1316-T01-B 1 2.13E+01 2.13E+01 2.0E+01 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T02-B 1 9.63E+01 9.63E+01 5.4E+00 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T03-B 1 1.92E+02 1.92E+02 2.2E+00 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T04-B 1 1.14E+02 1.14E+02 1.0E+01 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T05-B

Co EaFA-LRef-1316-T01-C 1 2.03E+01 2.03E+01 1.5E+01 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T02-C 1 7.78E+01 7.78E+01 4.5E+00 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T03-C 1 1.87E+02 1.87E+02 4.1E+00 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T04-C 1 9.26E+01 9.26E+01 1.1E+01 1.8E+00 5.7E+00
Co EaFA-LRef-1316-T05-C

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.68E+03 111% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1231
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dili]
Cu EaFA-LRef-1316-T01-A
Cu EaFA-LRef-1316-T02-A
Cu EaFA-LRef-1316-T03-A
Cu EaFA-LRef-1316-T04-A
Cu EaFA-LRef-1316-T05-A
Cu EaFA-LRef-1316-T01-B
Cu EaFA-LRef-1316-T02-B
Cu EaFA-LRef-1316-T03-B
Cu EaFA-LRef-1316-T04-B
Cu EaFA-LRef-1316-T05-B
Cu EaFA-LRef-1316-T01-C
Cu EaFA-LRef-1316-T02-C
Cu EaFA-LRef-1316-T03-C
Cu EaFA-LRef-1316-T04-C
Cu EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 1.85E+OOU1/2
1 1.39E+01
1 2.07E+01
1 2.67E+01

1 3.85E+00 E
1 1.60E+01
1 2.25E+01
1 2.62E+01

1 5.17E+OOE
1 2.37E+01
1 2.69E+01
1 3.34E+01

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
1.85E+00 1.6E+02 3.7E+00 1.2E+01
1.39E+01 2.4E+01 3.7E+00 1.2E+01 10 325
2.07E+01 1.2E+01 3.7E+00 1.2E+01
2.67E+01 3.7E+01 3.7E+00 1.2E+01

3.85E+00 1.3E+02 3.7E+00 1.2E+01
1.60E+01 4.3E+01 3.7E+00 1.2E+01
2.25E+01 2.0E+01 3.7E+00 1.2E+01
2.62E+01 4.1E+01 3.7E+00 1.2E+01

5.17E+00 9.6E+01 3.7E+00 1.2E+01
2.37E+01 1.8E+01 3.7E+00 1.2E+01
2.69E+01 2.6E+01 3.7E+00 1.2E+01
3.34E+01 9.1E+00 3.7E+00 1.2E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/108:26AM EPA Interlab LRef A-C 1313-1316 EaFA
3.65E+03 112% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/1 0 3:43 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:45 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

VU ICP-OES 5/6/108:49AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/1 0 3:46 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:48 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:50 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

VU ICP-OES 5/6/109:13AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:53 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:54 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

                                                                                                                                                                         1-1232
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Sample Dili]
EaFA-LRef-1316-T01-A
EaFA-LRef-1316-T02-A
EaFA-LRef-1316-T03-A
EaFA-LRef-1316-T04-A
EaFA-LRef-1316-T05-A
EaFA-LRef-1316-T01-B
EaFA-LRef-1316-T02-B
EaFA-LRef-1316-T03-B
EaFA-LRef-1316-T04-B
EaFA-LRef-1316-T05-B
EaFA-LRef-1316-T01-C
EaFA-LRef-1316-T02-C
EaFA-LRef-1316-T03-C
EaFA-LRef-1316-T04-C
EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L. M9/L ML
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 3.2E+02 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00

1.00E+00 7.9E+00 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00

1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 5.5E+01 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/108:26AM EPA Interlab LRef A-C 1313-1316 EaFA
1.09E+03 109% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1233
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dili]
Pb EaFA-LRef-1316-T01-A
Pb EaFA-LRef-1316-T02-A
Pb EaFA-LRef-1316-T03-A
Pb EaFA-LRef-1316-T04-A
Pb EaFA-LRef-1316-T05-A
Pb EaFA-LRef-1316-T01-B
Pb EaFA-LRef-1316-T02-B
Pb EaFA-LRef-1316-T03-B
Pb EaFA-LRef-1316-T04-B
Pb EaFA-LRef-1316-T05-B
Pb EaFA-LRef-1316-T01-C
Pb EaFA-LRef-1316-T02-C
Pb EaFA-LRef-1316-T03-C
Pb EaFA-LRef-1316-T04-C
Pb EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2

1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2

1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
3.40E+00 5.4E+01 6.8E+00 2.2E+01
3.40E+00 5.7E+00 6.8E+00 2.2E+01 10 325
3.40E+00 1.9E+01 6.8E+00 2.2E+01
3.40E+00 3.1E+00 6.8E+00 2.2E+01

3.40E+00 2.0E+01 6.8E+00 2.2E+01
3.40E+00 2.6E+00 6.8E+00 2.2E+01
3.40E+00 3.6E+00 6.8E+00 2.2E+01
3.40E+00 2.2E+00 6.8E+00 2.2E+01

3.40E+00 1.3E+01 6.8E+00 2.2E+01
3.40E+00 1.4E+01 6.8E+00 2.2E+01
3.40E+00 1.0E+01 6.8E+00 2.2E+01
3.40E+00 9.0E+00 6.8E+00 2.2E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/108:26AM EPA Interlab LRef A-C 1313-1316 EaFA
3.23E+03 99% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1234
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Li EaFA-LRef-1316-T01-A 1 3.24E+03 3.24E+03 3.5E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T02-A 1 6.70E+03 6.70E+03 1.1E+00 1.9E+00 6.0E+00 10 325
Li EaFA-LRef-1316-T03-A 1 1.54E+04 1.54E+04 5.4E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T04-A 1 3.36E+04 3.36E+04 5.3E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T05-A

Li EaFA-LRef-1316-T01-B 1 3.06E+03 3.06E+03 2.9E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T02-B 1 7.18E+03 7.18E+03 6.2E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T03-B 1 1.74E+04 1.74E+04 3.9E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T04-B 1 3.08E+04 3.08E+04 6.7E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T05-B

Li EaFA-LRef-1316-T01-C 1 2.98E+03 2.98E+03 3.7E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T02-C 1 6.00E+03 6.00E+03 8.3E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T03-C 1 1.56E+04 1.56E+04 3.6E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T04-C 1 2.84E+04 2.84E+04 4.0E-01 1.9E+00 6.0E+00
Li EaFA-LRef-1316-T05-C

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/108:26AM EPA Interlab LRef A-C 1313-1316 EaFA
9.68E+03 92% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/1 0 3:43 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:45 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

VU ICP-OES 5/6/108:49AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/1 0 3:46 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:48 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:50 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

VU ICP-OES 5/6/109:13AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:53 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:54 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

                                                                                                                                                                         1-1235
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Win Sample Dilution Cone.
1 ug/L
Mn EaFA-LRef-1316-T01-A 1 2.68E+02
Mn EaFA-LRef-1316-T02-A 1 6.83E+02
Mn EaFA-LRef-1316-T03-A 1 1.50E+03
Mn EaFA-LRef-1316-T04-A 1 1.62E+03
Mn EaFA-LRef-1316-T05-A
Mn EaFA-LRef-1316-T01-B 1 2.19E+02
Mn EaFA-LRef-1316-T02-B 1 7.69E+02
Mn EaFA-LRef-1316-T03-B 1 1.46E+03
Mn EaFA-LRef-1316-T04-B 1 1.67E+03
Mn EaFA-LRef-1316-T05-B
Mn EaFA-LRef-1316-T01-C 1 1.93E+02
Mn EaFA-LRef-1316-T02-C 1 6.15E+02
Mn EaFA-LRef-1316-T03-C 1 1.45E+03
Mn EaFA-LRef-1316-T04-C 1 1.53E+03
Mn EaFA-LRef-1316-T05-C
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L. M9/L ML
2.68E+02 5.8E-01 2.0E+00 6.4E+00
6.83E+02 8.3E-01 2.0E+00 6.4E+00 10 325
1.50E+03 6.2E-01 2.0E+00 6.4E+00
1.62E+03 1.1E+00 2.0E+00 6.4E+00

2.19E+02 1.2E+00 2.0E+00 6.4E+00
7.69E+02 3.0E-01 2.0E+00 6.4E+00
1.46E+03 1.3E+00 2.0E+00 6.4E+00
1.67E+03 7.2E-01 2.0E+00 6.4E+00

1.93E+02 1.4E+00 2.0E+00 6.4E+00
6.15E+02 1.1E+00 2.0E+00 6.4E+00
1.45E+03 1.1E+00 2.0E+00 6.4E+00
1.53E+03 7.0E-01 2.0E+00 6.4E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
4.36E+03 113% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1236
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dili]
Mg EaFA-LRef-1316-T01-A
Mg EaFA-LRef-1316-T02-A
Mg EaFA-LRef-1316-T03-A
Mg EaFA-LRef-1316-T04-A
Mg EaFA-LRef-1316-T05-A
Mg EaFA-LRef-1316-T01-B
Mg EaFA-LRef-1316-T02-B
Mg EaFA-LRef-1316-T03-B
Mg EaFA-LRef-1316-T04-B
Mg EaFA-LRef-1316-T05-B
Mg EaFA-LRef-1316-T01-C
Mg EaFA-LRef-1316-T02-C
Mg EaFA-LRef-1316-T03-C
Mg EaFA-LRef-1316-T04-C
Mg EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 7.49E+03
1 1.29E+04
1 3.06E+04
1 5.44E+04

1 7.03E+03
1 1.39E+04
1 3.47E+04
1 5.79E+04

1 7.04E+03
1 1.17E+04
1 3.08E+04
1 5.30E+04

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
7.49E+03 7.3E-01 1.0E+00 3.2E+00
1.29E+04 1.9E+00 1.0E+00 3.2E+00 1000 100
3.06E+04 1.1E+00 1.0E+00 3.2E+00
5.44E+04 5.4E-01 1.0E+00 3.2E+00

7.03E+03 8.8E-01 1.0E+00 3.2E+00
1.39E+04 1.6E+00 1.0E+00 3.2E+00
3.47E+04 2.4E-01 1.0E+00 3.2E+00
5.79E+04 5.5E-01 1.0E+00 3.2E+00

7.04E+03 4.9E-01 1.0E+00 3.2E+00
1.17E+04 1.6E+00 1.0E+00 3.2E+00
3.08E+04 3.4E-01 1.0E+00 3.2E+00
5.30E+04 1.3E+00 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
1.38E+04 98% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1237
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dili]
Mo EaFA-LRef-1316-T01-A
Mo EaFA-LRef-1316-T02-A
Mo EaFA-LRef-1316-T03-A
Mo EaFA-LRef-1316-T04-A
Mo EaFA-LRef-1316-T05-A
Mo EaFA-LRef-1316-T01-B
Mo EaFA-LRef-1316-T02-B
Mo EaFA-LRef-1316-T03-B
Mo EaFA-LRef-1316-T04-B
Mo EaFA-LRef-1316-T05-B
Mo EaFA-LRef-1316-T01-C
Mo EaFA-LRef-1316-T02-C
Mo EaFA-LRef-1316-T03-C
Mo EaFA-LRef-1316-T04-C
Mo EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 3.32E+03
1 6.37E+03
1 1.30E+04
1 2.76E+04

1 3.20E+03
1 6.76E+03
1 1.46E+04
1 2.63E+04

1 3.17E+03
1 5.73E+03
1 1.32E+04
1 2.43E+04

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
3.32E+03 4.1E-01 1.2E+00 3.8E+00
6.37E+03 7.0E-01 1.2E+00 3.8E+00 10 325
1.30E+04 3.8E-01 1.2E+00 3.8E+00
2.76E+04 1.4E+00 1.2E+00 3.8E+00

3.20E+03 6.8E-01 1.2E+00 3.8E+00
6.76E+03 4.2E-01 1.2E+00 3.8E+00
1.46E+04 1.6E-01 1.2E+00 3.8E+00
2.63E+04 5.0E-01 1.2E+00 3.8E+00

3.17E+03 6.6E-01 1.2E+00 3.8E+00
5.73E+03 1.5E+00 1.2E+00 3.8E+00
1.32E+04 3.7E-01 1.2E+00 3.8E+00
2.43E+04 7.2E-01 1.2E+00 3.8E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
9.31E+03 91% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1238
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone.
1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L ML
Ni EaFA-LRef-1316-T01-A 1 6.46E+01 6.46E+01 2.3E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T02-A 1 1.86E+02 1.86E+02 5.3E+00 1.8E+00 5.7E+00 10 325
Ni EaFA-LRef-1316-T03-A 1 4.29E+02 4.29E+02 1.7E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T04-A 1 3.51E+02 3.51E+02 3.0E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T05-A

Ni EaFA-LRef-1316-T01-B 1 5.05E+01 5.05E+01 3.3E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T02-B 1 2.19E+02 2.19E+02 5.2E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T03-B 1 4.18E+02 4.18E+02 1.0E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T04-B 1 2.67E+02 2.67E+02 4.4E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T05-B

Ni EaFA-LRef-1316-T01-C 1 4.37E+01 4.37E+01 2.7E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T02-C 1 1.70E+02 1.70E+02 4.1E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T03-C 1 4.30E+02 4.30E+02 1.6E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T04-C 1 3.04E+02 3.04E+02 3.8E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T05-C

Splke Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.80E+03 111% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1239
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dili]
P EaFA-LRef-1316-T01-A
P EaFA-LRef-1316-T02-A
P EaFA-LRef-1316-T03-A
P EaFA-LRef-1316-T04-A
P EaFA-LRef-1316-T05-A
P EaFA-LRef-1316-T01-B
P EaFA-LRef-1316-T02-B
P EaFA-LRef-1316-T03-B
P EaFA-LRef-1316-T04-B
P EaFA-LRef-1316-T05-B
P EaFA-LRef-1316-T01-C
P EaFA-LRef-1316-T02-C
P EaFA-LRef-1316-T03-C
P EaFA-LRef-1316-T04-C
P EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 1.63E+01
1 4.13E+01
1 5.71E+01
1 6.17E+01

1 2.66E+01
1 3.14E+01
1 5.25E+01
1 5.58E+01

1 1.93E+01
1 4.27E+01
1 5.41E+01
1 6.35E+01

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
1.63E+01 4.8E+01 3.7E+00 1.2E+01
4.13E+01 5.1E+01 3.7E+00 1.2E+01 1000 100
5.71 E+01 1.6E+01 3.7E+00 1.2E+01
6.17E+01 7.2E+00 3.7E+00 1.2E+01

2.66E+01 8.0E+01 3.7E+00 1.2E+01
3.14E+01 1.6E+01 3.7E+00 1.2E+01
5.25E+01 3.5E+01 3.7E+00 1.2E+01
5.58E+01 3.8E+01 3.7E+00 1.2E+01

1.93E+01 1.1E+01 3.7E+00 1.2E+01
4.27E+01 4.3E+01 3.7E+00 1.2E+01
5.41 E+01 2.2E+01 3.7E+00 1.2E+01
6.35E+01 1.4E+01 3.7E+00 1.2E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
1.00E+03 96% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1240
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dili]
K EaFA-LRef-1316-T01-A
K EaFA-LRef-1316-T02-A
K EaFA-LRef-1316-T03-A
K EaFA-LRef-1316-T04-A
K EaFA-LRef-1316-T05-A
K EaFA-LRef-1316-T01-B
K EaFA-LRef-1316-T02-B
K EaFA-LRef-1316-T03-B
K EaFA-LRef-1316-T04-B
K EaFA-LRef-1316-T05-B
K EaFA-LRef-1316-T01-C
K EaFA-LRef-1316-T02-C
K EaFA-LRef-1316-T03-C
K EaFA-LRef-1316-T04-C
K EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 2.50E+04
1 4.28E+04
1 1.04E+05
1 2.02E+05

1 2.33E+04
1 4.63E+04
1 1.18E+05
1 1.85E+05

1 2.28E+04
1 3.84E+04
1 1.06E+05
1 1.71E+05

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
2.50E+04 6.4E-01 1.6E+00 5.1E+00
4.28E+04 7.2E-01 1.6E+00 5.1E+00 1000 100
1.04E+05 5.0E-01 1.6E+00 5.1E+00
2.02E+05 6.6E-01 1.6E+00 5.1E+00

2.33E+04 5.9E-01 1.6E+00 5.1E+00
4.63E+04 1.0E+00 1.6E+00 5.1E+00
1.18E+05 1.3E-01 1.6E+00 5.1E+00
1.85E+05 5.3E-01 1.6E+00 5.1E+00

2.28E+04 8.5E-01 1.6E+00 5.1E+00
3.84E+04 1.5E+00 1.6E+00 5.1E+00
1.06E+05 8.4E-01 1.6E+00 5.1E+00
1.71E+05 3.3E-01 1.6E+00 5.1E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
4.38E+04 91% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1241
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dili]
Se EaFA-LRef-1316-T01-A
Se EaFA-LRef-1316-T02-A
Se EaFA-LRef-1316-T03-A
Se EaFA-LRef-1316-T04-A
Se EaFA-LRef-1316-T05-A
Se EaFA-LRef-1316-T01-B
Se EaFA-LRef-1316-T02-B
Se EaFA-LRef-1316-T03-B
Se EaFA-LRef-1316-T04-B
Se EaFA-LRef-1316-T05-B
Se EaFA-LRef-1316-T01-C
Se EaFA-LRef-1316-T02-C
Se EaFA-LRef-1316-T03-C
Se EaFA-LRef-1316-T04-C
Se EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 9.22E+02
1 1.24E+03
1 1.40E+03
1 1.78E+03

1 8.42E+02
1 1.42E+03
1 1.50E+03
1 1.71E+03

1 9.26E+02
1 1.18E+03
1 1.27E+03
1 1.54E+03

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
9.22E+02 5.3E+00 1.5E+01 4.8E+01
1.24E+03 5.5E+00 1.5E+01 4.8E+01 10 325
1.40E+03 3.0E+00 1.5E+01 4.8E+01
1.78E+03 1.6E-01 1.5E+01 4.8E+01

8.42E+02 1.4E+00 1.5E+01 4.8E+01
1.42E+03 1.6E+00 1.5E+01 4.8E+01
1.50E+03 1.4E+00 1.5E+01 4.8E+01
1.71E+03 2.3E+00 1.5E+01 4.8E+01

9.26E+02 5.3E+00 1.5E+01 4.8E+01
1.18E+03 5.9E+00 1.5E+01 4.8E+01
1.27E+03 8.9E+00 1.5E+01 4.8E+01
1.54E+03 2.5E+00 1.5E+01 4.8E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
4.08E+03 87% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1242
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Sample
Sample Dilution Cone.
ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
EaFA-LRef-1316-T01-A 1 1.43E+03 1.43E+03 2.4E-01 1.1E+00 3.5E+00
EaFA-LRef-1316-T02-A 1 2.69E+03 2.69E+03 9.4E-01 1.1E+00 3.5E+00 1000 100
EaFA-LRef-1316-T03-A 1 2.79E+03 2.79E+03 9.1E-01 1.1E+00 3.5E+00
EaFA-LRef-1316-T04-A 1 2.62E+03 2.62E+03 1.2E+00 1.1E+00 3.5E+00
EaFA-LRef-1316-T05-A

EaFA-LRef-1316-T01-B 1 1.20E+03 1.20E+03 1.4E-01 1.1E+00 3.5E+00
EaFA-LRef-1316-T02-B 1 2.24E+03 2.24E+03 7.4E-01 1.1E+00 3.5E+00
EaFA-LRef-1316-T03-B 1 2.31E+03 2.31E+03 3.1E-01 1.1E+00 3.5E+00
EaFA-LRef-1316-T04-B 1 2.19E+03 2.19E+03 5.5E-01 1.1E+00 3.5E+00
EaFA-LRef-1316-T05-B

EaFA-LRef-1316-T01-C 1 1.24E+03 1.24E+03 4.5E-01 1.1E+00 3.5E+00
EaFA-LRef-1316-T02-C 1 2.52E+03 2.52E+03 1.2E+00 1.1E+00 3.5E+00
EaFA-LRef-1316-T03-C 1 2.75E+03 2.75E+03 2.4E-01 1.1E+00 3.5E+00
EaFA-LRef-1316-T04-C 1 1.91E+03 1.91E+03 3.3E-01 1.1E+00 3.5E+00
EaFA-LRef-1316-T05-C

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/108:26AM EPA Interlab LRef A-C 1313-1316 EaFA
3.72E+03 103% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/1 0 3:43 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:45 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

VU ICP-OES 5/6/108:49AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/1 0 3:46 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:48 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:50 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

VU ICP-OES 5/6/109:13AM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:53 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/1 0 3:54 PM EPA Interlab LRef A-C 131 3-1 31 6 EaFA

                                                                                                                                                                         1-1243
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dili]
Na EaFA-LRef-1316-T01-A
Na EaFA-LRef-1316-T02-A
Na EaFA-LRef-1316-T03-A
Na EaFA-LRef-1316-T04-A
Na EaFA-LRef-1316-T05-A
Na EaFA-LRef-1316-T01-B
Na EaFA-LRef-1316-T02-B
Na EaFA-LRef-1316-T03-B
Na EaFA-LRef-1316-T04-B
Na EaFA-LRef-1316-T05-B
Na EaFA-LRef-1316-T01-C
Na EaFA-LRef-1316-T02-C
Na EaFA-LRef-1316-T03-C
Na EaFA-LRef-1316-T04-C
Na EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
Mg/L
1 6.45E+03
1 1.13E+04
1 2.82E+04
1 5.99E+04

1 6.03E+03
1 1.22E+04
1 3.22E+04
1 5.49E+04

1 5.95E+03
1 1.01E+04
1 2.88E+04
1 5.03E+04

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
Mg/L % Mg/L Mg/L Mg/L ML
6.45E+03 3.4E-01 2.5E+00 8.0E+00
1.13E+04 7.0E-01 2.5E+00 8.0E+00 1000 100
2.82E+04 7.0E-01 2.5E+00 8.0E+00
5.99E+04 1.2E-01 2.5E+00 8.0E+00

6.03E+03 4.8E-01 2.5E+00 8.0E+00
1.22E+04 3.8E-01 2.5E+00 8.0E+00
3.22E+04 2.6E-01 2.5E+00 8.0E+00
5.49E+04 1.3E+00 2.5E+00 8.0E+00

5.95E+03 1.0E-01 2.5E+00 8.0E+00
1.01E+04 9.8E-01 2.5E+00 8.0E+00
2.88E+04 2.8E-01 2.5E+00 8.0E+00
5.03E+04 7.3E-01 2.5E+00 8.0E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % I I
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
1.22E+04 94% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1244
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dili]
Sr EaFA-LRef-1316-T01-A
Sr EaFA-LRef-1316-T02-A
Sr EaFA-LRef-1316-T03-A
Sr EaFA-LRef-1316-T04-A
Sr EaFA-LRef-1316-T05-A
Sr EaFA-LRef-1316-T01-B
Sr EaFA-LRef-1316-T02-B
Sr EaFA-LRef-1316-T03-B
Sr EaFA-LRef-1316-T04-B
Sr EaFA-LRef-1316-T05-B
Sr EaFA-LRef-1316-T01-C
Sr EaFA-LRef-1316-T02-C
Sr EaFA-LRef-1316-T03-C
Sr EaFA-LRef-1316-T04-C
Sr EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 2.54E+03
1 3.69E+03
1 7.22E+03
1 6.74E+03

1 2.42E+03
1 3.96E+03
1 8.22E+03
1 7.19E+03

1 2.38E+03
1 3.44E+03
1 7.33E+03
1 6.63E+03

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
2.54E+03 1.1E+00 1.0E+00 3.2E+00
3.69E+03 5.7E-01 1.0E+00 3.2E+00 1000 100
7.22E+03 3.6E-01 1.0E+00 3.2E+00
6.74E+03 1.2E+00 1.0E+00 3.2E+00

2.42E+03 8.8E-01 1.0E+00 3.2E+00
3.96E+03 4.8E-01 1.0E+00 3.2E+00
8.22E+03 1.1E+00 1.0E+00 3.2E+00
7.19E+03 9.6E-01 1.0E+00 3.2E+00

2.38E+03 7.8E-01 1.0E+00 3.2E+00
3.44E+03 1.2E+00 1.0E+00 3.2E+00
7.33E+03 9.9E-01 1.0E+00 3.2E+00
6.63E+03 1.2E+00 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
4.70E+03 102% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1245
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dili]
S EaFA-LRef-1316-T01-A
S EaFA-LRef-1316-T02-A
S EaFA-LRef-1316-T03-A
S EaFA-LRef-1316-T04-A
S EaFA-LRef-1316-T05-A
S EaFA-LRef-1316-T01-B
S EaFA-LRef-1316-T02-B
S EaFA-LRef-1316-T03-B
S EaFA-LRef-1316-T04-B
S EaFA-LRef-1316-T05-B
S EaFA-LRef-1316-T01-C
S EaFA-LRef-1316-T02-C
S EaFA-LRef-1316-T03-C
S EaFA-LRef-1316-T04-C
S EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 1.64E+05
1 3.09E+05
1 6.84E+05
1 7.73E+05

1 1.58E+05
1 3.30E+05
1 7.27E+05
1 7.05E+05

1 1.60E+05
1 2.74E+05
1 6.89E+05
1 7.43E+05

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
1.64E+05 8.6E-01 6.8E+00 2.2E+01
3.09E+05 1.2E+00 6.8E+00 2.2E+01 1000 100
6.84E+05 2.5E-01 6.8E+00 2.2E+01
7.73E+05 9.4E-01 6.8E+00 2.2E+01

1.58E+05 3.0E-01 6.8E+00 2.2E+01
3.30E+05 4.1E-01 6.8E+00 2.2E+01
7.27E+05 1.2E-01 6.8E+00 2.2E+01
7.05E+05 9.1E-01 6.8E+00 2.2E+01

1.60E+05 2.8E-01 6.8E+00 2.2E+01
2.74E+05 1.4E+00 6.8E+00 2.2E+01
6.89E+05 1.5E-01 6.8E+00 2.2E+01
7.43E+05 3.0E-01 6.8E+00 2.2E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.10E+05 99% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1246
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dili]
Tl EaFA-LRef-1316-T01-A
Tl EaFA-LRef-1316-T02-A
Tl EaFA-LRef-1316-T03-A
Tl EaFA-LRef-1316-T04-A
Tl EaFA-LRef-1316-T05-A
Tl EaFA-LRef-1316-T01-B
Tl EaFA-LRef-1316-T02-B
Tl EaFA-LRef-1316-T03-B
Tl EaFA-LRef-1316-T04-B
Tl EaFA-LRef-1316-T05-B
Tl EaFA-LRef-1316-T01-C
Tl EaFA-LRef-1316-T02-C
Tl EaFA-LRef-1316-T03-C
Tl EaFA-LRef-1316-T04-C
Tl EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2

1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2

1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 2.30E+00 U1/2

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 4.1E+01 4.6E+00 1.5E+01
2.30E+00 1.4E+01 4.6E+00 1.5E+01 10 325
2.30E+00 9.3E+00 4.6E+00 1.5E+01
2.30E+00 2.0E+01 4.6E+00 1.5E+01

2.30E+00 6.0E+01 4.6E+00 1.5E+01
2.30E+00 1.8E+01 4.6E+00 1.5E+01
2.30E+00 7.5E+00 4.6E+00 1.5E+01
2.30E+00 8.0E+00 4.6E+00 1.5E+01

2.30E+00 1.7E+02 4.6E+00 1.5E+01
2.30E+00 8.8E+00 4.6E+00 1.5E+01
2.30E+00 1.5E+01 4.6E+00 1.5E+01
2.30E+00 5.0E+00 4.6E+00 1.5E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.36E+03 103% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1247
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dili]
Ti EaFA-LRef-1316-T01-A
Ti EaFA-LRef-1316-T02-A
Ti EaFA-LRef-1316-T03-A
Ti EaFA-LRef-1316-T04-A
Ti EaFA-LRef-1316-T05-A
Ti EaFA-LRef-1316-T01-B
Ti EaFA-LRef-1316-T02-B
Ti EaFA-LRef-1316-T03-B
Ti EaFA-LRef-1316-T04-B
Ti EaFA-LRef-1316-T05-B
Ti EaFA-LRef-1316-T01-C
Ti EaFA-LRef-1316-T02-C
Ti EaFA-LRef-1316-T03-C
Ti EaFA-LRef-1316-T04-C
Ti EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+00 U1/2

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+03 2.0E+00 6.4E+00 10 325
1.00E+00 3.8E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00

1.00E+00 6.5E+01 2.0E+00 6.4E+00
1.00E+00 4.9E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00

1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+03 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.62E+03 111% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1248
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
ug/L
V EaFA-LRef-1316-T01-A 1 1.58E+02
V EaFA-LRef-1316-T02-A 1 3.16E+02
V EaFA-LRef-1316-T03-A 1 3.47E+02
V EaFA-LRef-1316-T04-A 1 4.01E+02
V EaFA-LRef-1316-T05-A
V EaFA-LRef-1316-T01-B 1 1.50E+02
V EaFA-LRef-1316-T02-B 1 3.32E+02
V EaFA-LRef-1316-T03-B 1 3.46E+02
V EaFA-LRef-1316-T04-B 1 3.65E+02
V EaFA-LRef-1316-T05-B
V EaFA-LRef-1316-T01-C 1 1.57E+02
V EaFA-LRef-1316-T02-C 1 2.85E+02
V EaFA-LRef-1316-T03-C 1 3.32E+02
V EaFA-LRef-1316-T04-C 1 3.91E+02
V EaFA-LRef-1316-T05-C
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L. M9/L ML
1.58E+02 2.6E+00 1.5E+00 4.8E+00
3.16E+02 1.9E+00 1.5E+00 4.8E+00 10 325
3.47E+02 1.2E+00 1.5E+00 4.8E+00
4.01 E+02 1.4E+00 1.5E+00 4.8E+00

1.50E+02 4.2E+00 1.5E+00 4.8E+00
3.32E+02 3.4E+00 1.5E+00 4.8E+00
3.46E+02 2.2E+00 1.5E+00 4.8E+00
3.65E+02 1.1E+00 1.5E+00 4.8E+00

1.57E+02 3.3E+00 1.5E+00 4.8E+00
2.85E+02 9.4E-01 1.5E+00 4.8E+00
3.32E+02 3.2E+00 1.5E+00 4.8E+00
3.91 E+02 1.1E+00 1.5E+00 4.8E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.93E+03 111% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1249
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Sample Dili]
EaFA-LRef-1316-T01-A
EaFA-LRef-1316-T02-A
EaFA-LRef-1316-T03-A
EaFA-LRef-1316-T04-A
EaFA-LRef-1316-T05-A
EaFA-LRef-1316-T01-B
EaFA-LRef-1316-T02-B
EaFA-LRef-1316-T03-B
EaFA-LRef-1316-T04-B
EaFA-LRef-1316-T05-B
EaFA-LRef-1316-T01-C
EaFA-LRef-1316-T02-C
EaFA-LRef-1316-T03-C
EaFA-LRef-1316-T04-C
EaFA-LRef-1316-T05-C
Sample
tlon Cone. Qualifier
ug/L
1 5.00E-01 U1/2
1 2.20E+01
1 9.71E+01
1 9.23E+01

1 5.00E-01 U1/2
1 4.29E+01
1 6.89E+01
1 1.24E+02

1 5.00E-01 U1/2
1 2.50E+01
1 8.25E+01
1 1.12E+02

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 2.0E+01 1.0E+00 3.2E+00
2.20E+01 4.6E+00 1.0E+00 3.2E+00 10 325
9.71E+01 2.1E+00 1.0E+00 3.2E+00
9.23E+01 2.7E+00 1.0E+00 3.2E+00

5.00E-01 3.6E+01 1.0E+00 3.2E+00
4.29E+01 7.1E+00 1.0E+00 3.2E+00
6.89E+01 7.5E+00 1.0E+00 3.2E+00
1.24E+02 1.7E+00 1.0E+00 3.2E+00

5.00E-01 9.5E+01 1.0E+00 3.2E+00
2.50E+01 9.4E+00 1.0E+00 3.2E+00
8.25E+01 1.1E+00 1.0E+00 3.2E+00
1.12E+02 5.1E-01 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/6/1 08:26 AM EPA Interlab LRef A-C 131 3-1 316 EaFA
3.70E+03 113% VU ICP-OES 5/7/103:41 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:43 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:45 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 08:49 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/10 3:46 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:48 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:50 PM EPA Interlab LRef A-C 1313-1316 EaFA

VU ICP-OES 5/6/1 09: 13 AM EPA Interlab LRef A-C 131 3-1 31 6 EaFA
VU ICP-OES 5/7/103:51 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:53 PM EPA Interlab LRef A-C 1313-1316 EaFA
VU ICP-OES 5/7/10 3:54 PM EPA Interlab LRef A-C 1313-1316 EaFA

                                                                                                                                                                         1-1250
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample Internal
Sample Dilution Cone. Qualifier Review
I I ug/L I I
EaFA-LRef-1316-T01-D 1 1.28E+02
EaFA-LRef-1316-T02-D 1 1.91E+02
EaFA-LRef-1316-T03-D 1 2.32E+02
EaFA-LRef-1316-T04-D 1 4.29E+02
EaFA-LRef-1316-T05-D
EaFA-LRef-1316-T01-E 1 1.28E+02
EaFA-LRef-1316-T02-E 1 1.82E+02
EaFA-LRef-1316-T03-E 1 2.14E+02
EaFA-LRef-1316-T04-E 1 4.31E+02
EaFA-LRef-1316-T05-E
EaFA-LRef-1316-T01-F 1 1.31E+02
EaFA-LRef-1316-T02-F 1 1.92E+02
EaFA-LRef-1316-T03-F 1 2.31E+02
EaFA-LRef-1316-T04-F 1 4.07E+02
EaFA-LRef-1316-T05-F
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.28E+02 1.7E+00 1.0E+00 3.2E+00
1.91E+02 3.8E+00 1.0E+00 3.2E+00 1000 100
2.32E+02 2.2E+00 1.0E+00 3.2E+00
4.29E+02 8.4E-01 1.0E+00 3.2E+00

1.28E+02 3.3E+00 1.0E+00 3.2E+00
1.82E+02 2.4E+00 1.0E+00 3.2E+00 1000 100
2.14E+02 4.5E+00 1.0E+00 3.2E+00
4.31 E+02 4.5E-01 1.0E+00 3.2E+00

1.31E+02 1.0E+00 1.0E+00 3.2E+00
1.92E+02 2.7E+00 1.0E+00 3.2E+00 1000 100
2.31 E+02 1.5E+00 1.0E+00 3.2E+00
4.07E+02 1.2E+00 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
1.18E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1.19E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES

VU ICP-OES
1.16E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES

Date/Time Filename
6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
6/7/1 0 1 1 :07 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
6/7/1 0 1 1 :08 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
6/7/1 0 1 1 : 1 0 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

6/7/1 0 1 1 : 1 2 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
6/7/1 0 1 1 : 1 5 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
6/7/1 0 1 1 : 1 7 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
6/7/1 0 1 1 :23 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

                                                                                                                                                                                   1-1251
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone.
1 ug/L
Sb EaFA-LRef-1316-T01-D 1 1.82E+02
Sb EaFA-LRef-1316-T02-D 1 2.07E+02
Sb EaFA-LRef-1316-T03-D 1 3.45E+02
Sb EaFA-LRef-1316-T04-D 1 4.82E+02
Sb EaFA-LRef-1316-T05-D
Sb EaFA-LRef-1316-T01-E 1 1.73E+02
Sb EaFA-LRef-1316-T02-E 1 2.05E+02
Sb EaFA-LRef-1316-T03-E 1 3.58E+02
Sb EaFA-LRef-1316-T04-E 1 4.43E+02
Sb EaFA-LRef-1316-T05-E
Sb EaFA-LRef-1316-T01-F 1 1.76E+02
Sb EaFA-LRef-1316-T02-F 1 2.07E+02
Sb EaFA-LRef-1316-T03-F 1 3.68E+02
Sb EaFA-LRef-1316-T04-F 1 4.84E+02
Sb EaFA-LRef-1316-T05-F
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L. M9/L ML
1.82E+02 1.5E+01 7.5E+00 2.4E+01
2.07E+02 1.4E+01 7.5E+00 2.4E+01 10 325
3.45E+02 7.8E+00 7.5E+00 2.4E+01
4.82E+02 4.4E+00 7.5E+00 2.4E+01

1.73E+02 2.0E+01 7.5E+00 2.4E+01
2.05E+02 6.5E+00 7.5E+00 2.4E+01 10 325
3.58E+02 2.3E+00 7.5E+00 2.4E+01
4.43E+02 2.2E+00 7.5E+00 2.4E+01

1.76E+02 1.4E+01 7.5E+00 2.4E+01
2.07E+02 1.0E+01 7.5E+00 2.4E+01 10 325
3.68E+02 3.9E+00 7.5E+00 2.4E+01
4.84E+02 7.5E+00 7.5E+00 2.4E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.45E+03 100% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.53E+03 102% VU ICP-OES 6/7/1 01:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.42E+03 99% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1252
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone.
ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L M9/L ug/L. ML
As EaFA-LRef-1316-T01-D 1 1.05E+02 1.05E+02 8.6E+00 1.1E+01 3.5E+01
As EaFA-LRef-1316-T02-D 1 7.01E+01 7.01E+01 1.1E+01 1.1E+01 3.5E+01 10 325
As EaFA-LRef-1316-T03-D 1 8.30E+01 8.30E+01 2.8E+01 1.1E+01 3.5E+01
As EaFA-LRef-1316-T04-D 1 1.47E+02 1.47E+02 1.8E+00 1.1E+01 3.5E+01
As EaFA-LRef-1316-T05-D

As EaFA-LRef-1316-T01-E 1 1.20E+02 1.20E+02 1.3E+01 1.1E+01 3.5E+01
As EaFA-LRef-1316-T02-E 1 7.01E+01 7.01E+01 5.8E+00 1.1E+01 3.5E+01 10 325
As EaFA-LRef-1316-T03-E 1 6.15E+01 6.15E+01 5.3E+01 1.1E+01 3.5E+01
As EaFA-LRef-1316-T04-E 1 9.56E+01 9.56E+01 1.8E+01 1.1E+01 3.5E+01
As EaFA-LRef-1316-T05-E

As EaFA-LRef-1316-T01-F 1 1.11E+02 1.11E+02 1.9E+01 1.1E+01 3.5E+01
As EaFA-LRef-1316-T02-F 1 8.42E+01 8.42E+01 3.2E+01 1.1E+01 3.5E+01 10 325
As EaFA-LRef-1316-T03-F 1 8.74E+01 8.74E+01 2.9E+00 1.1E+01 3.5E+01
As EaFA-LRef-1316-T04-F 1 7.90E+01 7.90E+01 1.1E+01 1.1E+01 3.5E+01
As EaFA-LRef-1316-T05-F

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/101:23PM EPA Interlab LRef D-F 1313-1316 EaFA
3.26E+03 98% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.87E+03 117% VU ICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.69E+03 111% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1253
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone.
ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
B EaFA-LRef-1316-T01-D 1 4.15E+03 4.15E+03 5.8E-01 1.0E+00 3.2E+00
B EaFA-LRef-1316-T02-D 1 8.32E+03 8.32E+03 2.6E+00 1.0E+00 3.2E+00 1000 100
B EaFA-LRef-1316-T03-D 1 1.94E+04 1.94E+04 2.0E+00 1.0E+00 3.2E+00
B EaFA-LRef-1316-T04-D 1 3.35E+04 3.35E+04 8.0E-01 1.0E+00 3.2E+00
B EaFA-LRef-1316-T05-D

B EaFA-LRef-1316-T01-E 1 4.70E+03 4.70E+03 2.1E+00 1.0E+00 3.2E+00
B EaFA-LRef-1316-T02-E 1 8.23E+03 8.23E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
B EaFA-LRef-1316-T03-E 1 1.95E+04 1.95E+04 2.8E+00 1.0E+00 3.2E+00
B EaFA-LRef-1316-T04-E 1 3.33E+04 3.33E+04 1.1E-01 1.0E+00 3.2E+00
B EaFA-LRef-1316-T05-E

B EaFA-LRef-1316-T01-F 1 4.23E+03 4.23E+03 1.9E+00 1.0E+00 3.2E+00
B EaFA-LRef-1316-T02-F 1 8.30E+03 8.30E+03 2.1E+00 1.0E+00 3.2E+00 1000 100
B EaFA-LRef-1316-T03-F 1 1.94E+04 1.94E+04 1.7E+00 1.0E+00 3.2E+00
B EaFA-LRef-1316-T04-F 1 3.31E+04 3.31E+04 9.7E-01 1.0E+00 3.2E+00
B EaFA-LRef-1316-T05-F

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/101:23PM EPA Interlab LRef D-F 1313-1316 EaFA
9.20E+03 88% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
9.26E+03 104% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
9.27E+03 96% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1254
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone.
ug/L
Ba EaFA-LRef-1316-T01-D 1 2.77E+02
Ba EaFA-LRef-1316-T02-D 1 2.04E+02
Ba EaFA-LRef-1316-T03-D 1 1.78E+02
Ba EaFA-LRef-1316-T04-D 1 2.08E+02
Ba EaFA-LRef-1316-T05-D
Ba EaFA-LRef-1316-T01-E 1 2.83E+02
Ba EaFA-LRef-1316-T02-E 1 1.95E+02
Ba EaFA-LRef-1316-T03-E 1 1.51E+02
Ba EaFA-LRef-1316-T04-E 1 2.06E+02
Ba EaFA-LRef-1316-T05-E
Ba EaFA-LRef-1316-T01-F 1 2.84E+02
Ba EaFA-LRef-1316-T02-F 1 2.01E+02
Ba EaFA-LRef-1316-T03-F 1 1.74E+02
Ba EaFA-LRef-1316-T04-F 1 2.13E+02
Ba EaFA-LRef-1316-T05-F
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L. M9/L ML
2.77E+02 7.7E-01 1.0E+00 3.2E+00
2.04E+02 4.7E-01 1.0E+00 3.2E+00 10 325
1.78E+02 6.4E-01 1.0E+00 3.2E+00
2.08E+02 8.5E-01 1.0E+00 3.2E+00

2.83E+02 9.7E-01 1.0E+00 3.2E+00
1.95E+02 4.7E-01 1.0E+00 3.2E+00 10 325
1.51E+02 6.0E+00 1.0E+00 3.2E+00
2.06E+02 1.9E-01 1.0E+00 3.2E+00

2.84E+02 3.2E-01 1.0E+00 3.2E+00
2.01E+02 7.5E-01 1.0E+00 3.2E+00 10 325
1.74E+02 2.6E-01 1.0E+00 3.2E+00
2.13E+02 4.7E-01 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. %
VU ICP-OES 6/7/101:23PM EPA Interlab LRef D-F 1313-1316 EaFA
3.30E+03 95% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.34E+03 97% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/101:26PM EPA Interlab LRef D-F 1313-1316 EaFA
3.25E+03 94% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/101:29PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1255
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dili]
Be EaFA-LRef-1316-T01-D
Be EaFA-LRef-1316-T02-D
Be EaFA-LRef-1316-T03-D
Be EaFA-LRef-1316-T04-D
Be EaFA-LRef-1316-T05-D
Be EaFA-LRef-1316-T01-E
Be EaFA-LRef-1316-T02-E
Be EaFA-LRef-1316-T03-E
Be EaFA-LRef-1316-T04-E
Be EaFA-LRef-1316-T05-E
Be EaFA-LRef-1316-T01-F
Be EaFA-LRef-1316-T02-F
Be EaFA-LRef-1316-T03-F
Be EaFA-LRef-1316-T04-F
Be EaFA-LRef-1316-T05-F
Sample Inter
tlon Cone. Qualifier Rev
ug/L
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2

1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2

1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2
1 9.50E-01 U1/2

nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00 10 325
9.50E-01 4.2E+03 1.9E+00 6.0E+00
9.50E-01 5.4E+01 1.9E+00 6.0E+00

9.50E-01 1.1E+01 1.9E+00 6.0E+00
9.50E-01 7.2E+01 1.9E+00 6.0E+00 10 325
9.50E-01 9.5E+01 1.9E+00 6.0E+00
9.50E-01 6.9E+01 1.9E+00 6.0E+00

9.50E-01 2.5E+02 1.9E+00 6.0E+00
9.50E-01 5.4E+04 1.9E+00 6.0E+00 10 325
9.50E-01 1.7E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/1 01:23PM EPA Interlab LRef D-F 131 3-1 316 EaFA
3.47E+03 107% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 0 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/1 0 1 1 : 1 2 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
3.57E+03 110% VU ICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 5 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 7 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/10 1:26PM EPA Interlab LRef D-F 1313-1316 EaFA
3.46E+03 106% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 :23 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

                                                                                                                                                                         1-1256
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dili]
Cd EaFA-LRef-1316-T01-D
Cd EaFA-LRef-1316-T02-D
Cd EaFA-LRef-1316-T03-D
Cd EaFA-LRef-1316-T04-D
Cd EaFA-LRef-1316-T05-D
Cd EaFA-LRef-1316-T01-E
Cd EaFA-LRef-1316-T02-E
Cd EaFA-LRef-1316-T03-E
Cd EaFA-LRef-1316-T04-E
Cd EaFA-LRef-1316-T05-E
Cd EaFA-LRef-1316-T01-F
Cd EaFA-LRef-1316-T02-F
Cd EaFA-LRef-1316-T03-F
Cd EaFA-LRef-1316-T04-F
Cd EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 2.65E+00 E
1 1.10E+OOU1/2

1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 3.16E+OOE
1 1.10E+OOU1/2

1 1.10E+OOU1/2
1 1.10E+OOU1/2
1 3.45E+00 E
1 1.10E+OOU1/2

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L. M9/L ML
1.10E+00 1.7E+02 2.2E+00 7.0E+00
1.10E+00 1.7E+02 2.2E+00 7.0E+00 10 325
2.65E+00 2.0E+01 2.2E+00 7.0E+00
1.10E+00 8.1E+01 2.2E+00 7.0E+00

1.10E+00 9.0E+01 2.2E+00 7.0E+00
1.10E+00 3.3E+01 2.2E+00 7.0E+00 10 325
3.16E+00 1.4E+01 2.2E+00 7.0E+00
1.10E+00 4.4E+01 2.2E+00 7.0E+00

1.10E+00 1.7E+02 2.2E+00 7.0E+00
1.10E+00 3.8E+01 2.2E+00 7.0E+00 10 325
3.45E+00 5.2E+01 2.2E+00 7.0E+00
1.10E+00 2.7E+01 2.2E+00 7.0E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/1 01:23PM EPA Interlab LRef D-F 131 3-1 316 EaFA
3.42E+03 105% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/1 0 1 1 : 1 2 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
3.47E+03 107% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 5 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 7 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/10 1:26PM EPA Interlab LRef D-F 1313-1316 EaFA
3.36E+03 103% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 :23 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

                                                                                                                                                                         1-1257
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dili]
Ca EaFA-LRef-1316-T01-D
Ca EaFA-LRef-1316-T02-D
Ca EaFA-LRef-1316-T03-D
Ca EaFA-LRef-1316-T04-D
Ca EaFA-LRef-1316-T05-D
Ca EaFA-LRef-1316-T01-E
Ca EaFA-LRef-1316-T02-E
Ca EaFA-LRef-1316-T03-E
Ca EaFA-LRef-1316-T04-E
Ca EaFA-LRef-1316-T05-E
Ca EaFA-LRef-1316-T01-F
Ca EaFA-LRef-1316-T02-F
Ca EaFA-LRef-1316-T03-F
Ca EaFA-LRef-1316-T04-F
Ca EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 1.47E+05
1 3.01 E+05
1 6.93E+05
1 5.39E+05

1 1.53E+05
1 2.93E+05
1 6.95E+05
1 5.37E+05

1 1.46E+05
1 2.93E+05
1 6.69E+05
1 5.20E+05

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
1.47E+05 1.1E+00 2.6E+00 8.3E+00
3.01 E+05 3.2E-01 2.6E+00 8.3E+00 1000 100
6.93E+05 1.1E-01 2.6E+00 8.3E+00
5.39E+05 7.4E-01 2.6E+00 8.3E+00

1.53E+05 5.2E-01 2.6E+00 8.3E+00
2.93E+05 6.2E-01 2.6E+00 8.3E+00 1000 100
6.95E+05 6.0E+00 2.6E+00 8.3E+00
5.37E+05 2.9E-01 2.6E+00 8.3E+00

1.46E+05 3.6E-01 2.6E+00 8.3E+00
2.93E+05 8.2E-01 2.6E+00 8.3E+00 1000 100
6.69E+05 1.1E-01 2.6E+00 8.3E+00
5.20E+05 1.5E-01 2.6E+00 8.3E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.02E+05 83% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
2.93E+05 92% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
2.94E+05 86% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1258
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dili]
Cr EaFA-LRef-1316-T01-D
Cr EaFA-LRef-1316-T02-D
Cr EaFA-LRef-1316-T03-D
Cr EaFA-LRef-1316-T04-D
Cr EaFA-LRef-1316-T05-D
Cr EaFA-LRef-1316-T01-E
Cr EaFA-LRef-1316-T02-E
Cr EaFA-LRef-1316-T03-E
Cr EaFA-LRef-1316-T04-E
Cr EaFA-LRef-1316-T05-E
Cr EaFA-LRef-1316-T01-F
Cr EaFA-LRef-1316-T02-F
Cr EaFA-LRef-1316-T03-F
Cr EaFA-LRef-1316-T04-F
Cr EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 1.60E+01
1 4.35E+01
1 4.27E+01
1 7.94E+01

1 1.76E+01
1 4.27E+01
1 4.29E+01
1 8.36E+01

1 1.87E+01
1 4.34E+01
1 4.28E+01
1 6.10E+01

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
1.60E+01 1.6E+01 1.2E+00 3.8E+00
4.35E+01 3.6E+00 1.2E+00 3.8E+00 10 325
4.27E+01 2.7E+00 1.2E+00 3.8E+00
7.94E+01 7.5E-01 1.2E+00 3.8E+00

1.76E+01 5.8E+00 1.2E+00 3.8E+00
4.27E+01 3.4E+00 1.2E+00 3.8E+00 10 325
4.29E+01 4.6E+00 1.2E+00 3.8E+00
8.36E+01 1.7E+00 1.2E+00 3.8E+00

1.87E+01 5.8E+00 1.2E+00 3.8E+00
4.34E+01 1.5E+00 1.2E+00 3.8E+00 10 325
4.28E+01 4.5E+00 1.2E+00 3.8E+00
6.10E+01 1.5E+00 1.2E+00 3.8E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.34E+03 101% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.41 E+03 104% VU ICP-OES 6/7/1 01:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.32E+03 101% VU ICP-OES 6/7/1 01:28PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1259
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dili]
Co EaFA-LRef-1316-T01-D
Co EaFA-LRef-1316-T02-D
Co EaFA-LRef-1316-T03-D
Co EaFA-LRef-1316-T04-D
Co EaFA-LRef-1316-T05-D
Co EaFA-LRef-1316-T01-E
Co EaFA-LRef-1316-T02-E
Co EaFA-LRef-1316-T03-E
Co EaFA-LRef-1316-T04-E
Co EaFA-LRef-1316-T05-E
Co EaFA-LRef-1316-T01-F
Co EaFA-LRef-1316-T02-F
Co EaFA-LRef-1316-T03-F
Co EaFA-LRef-1316-T04-F
Co EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 3.95E+01
1 6.10E+01
1 1.38E+02
1 7.08E+01

1 3.88E+01
1 5.55E+01
1 1.42E+02
1 7.50E+01

1 4.08E+01
1 6.03E+01
1 1.42E+02
1 9.09E+01

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
3.95E+01 6.7E-01 1.8E+00 5.7E+00
6.10E+01 2.4E+00 1.8E+00 5.7E+00 10 325
1.38E+02 3.5E+00 1.8E+00 5.7E+00
7.08E+01 4.3E+00 1.8E+00 5.7E+00

3.88E+01 3.0E+00 1.8E+00 5.7E+00
5.55E+01 5.0E+00 1.8E+00 5.7E+00 10 325
1.42E+02 6.9E+00 1.8E+00 5.7E+00
7.50E+01 3.6E+00 1.8E+00 5.7E+00

4.08E+01 6.6E+00 1.8E+00 5.7E+00
6.03E+01 3.6E+00 1.8E+00 5.7E+00 10 325
1.42E+02 1.4E+00 1.8E+00 5.7E+00
9.09E+01 2.1E+00 1.8E+00 5.7E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.35E+03 101% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.40E+03 103% VU ICP-OES 6/7/1 01:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.33E+03 101% VU ICP-OES 6/7/1 01:28PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1260
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dili]
Cu EaFA-LRef-1316-T01-D
Cu EaFA-LRef-1316-T02-D
Cu EaFA-LRef-1316-T03-D
Cu EaFA-LRef-1316-T04-D
Cu EaFA-LRef-1316-T05-D
Cu EaFA-LRef-1316-T01-E
Cu EaFA-LRef-1316-T02-E
Cu EaFA-LRef-1316-T03-E
Cu EaFA-LRef-1316-T04-E
Cu EaFA-LRef-1316-T05-E
Cu EaFA-LRef-1316-T01-F
Cu EaFA-LRef-1316-T02-F
Cu EaFA-LRef-1316-T03-F
Cu EaFA-LRef-1316-T04-F
Cu EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 8.42E+00 E
1 1.26E+01
1 1.83E+01
1 1.66E+01

1 7.60E+00 E
1 7.02E+00 E
1 1.83E+01
1 1.76E+01

1 9.02E+00 E
1 8.84E+00 E
1 1.06E+01 E
1 2.20E+01

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
8.42E+00 1.7E+01 3.7E+00 1.2E+01
1.26E+01 2.7E+01 3.7E+00 1.2E+01 10 325
1.83E+01 3.2E+01 3.7E+00 1.2E+01
1.66E+01 1.4E+01 3.7E+00 1.2E+01

7.60E+00 1.6E+01 3.7E+00 1.2E+01
7.02E+00 2.0E+01 3.7E+00 1.2E+01 10 325
1.83E+01 2.8E+01 3.7E+00 1.2E+01
1.76E+01 3.8E+01 3.7E+00 1.2E+01

9.02E+00 5.7E+01 3.7E+00 1.2E+01
8.84E+00 5.9E+01 3.7E+00 1.2E+01 10 325
1.06E+01 1.4E+01 3.7E+00 1.2E+01
2.20E+01 1.1E+01 3.7E+00 1.2E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.08E+03 94% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.10E+03 95% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.08E+03 94% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 :23 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

                                                                                                                                                                         1-1261
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Sample Dili]
EaFA-LRef-1316-T01-D
EaFA-LRef-1316-T02-D
EaFA-LRef-1316-T03-D
EaFA-LRef-1316-T04-D
EaFA-LRef-1316-T05-D
EaFA-LRef-1316-T01-E
EaFA-LRef-1316-T02-E
EaFA-LRef-1316-T03-E
EaFA-LRef-1316-T04-E
EaFA-LRef-1316-T05-E
EaFA-LRef-1316-T01-F
EaFA-LRef-1316-T02-F
EaFA-LRef-1316-T03-F
EaFA-LRef-1316-T04-F
EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L. M9/L ML
1.00E+00 3.0E+00 2.0E+00 6.4E+00
1.00E+00 6.1E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 8.1E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00

1.00E+00 5.0E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00 1000 100
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+00 2.0E+00 6.4E+00

1.00E+00 7.2E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+00 2.0E+00 6.4E+00 1000 100
1.00E+00 6.5E+00 2.0E+00 6.4E+00
1.00E+00 5.1E+01 2.0E+00 6.4E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/1 01:23PM EPA Interlab LRef D-F 131 3-1 316 EaFA
1.00E+03 100% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 0 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/1 0 1 1 : 1 2 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
1.04E+03 104% VU ICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 5 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 7 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/10 1:26PM EPA Interlab LRef D-F 1313-1316 EaFA
1.09E+03 109% VU ICP-OES 6/7/101:28PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 :23 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

                                                                                                                                                                         1-1262
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dili]
Pb EaFA-LRef-1316-T01-D
Pb EaFA-LRef-1316-T02-D
Pb EaFA-LRef-1316-T03-D
Pb EaFA-LRef-1316-T04-D
Pb EaFA-LRef-1316-T05-D
Pb EaFA-LRef-1316-T01-E
Pb EaFA-LRef-1316-T02-E
Pb EaFA-LRef-1316-T03-E
Pb EaFA-LRef-1316-T04-E
Pb EaFA-LRef-1316-T05-E
Pb EaFA-LRef-1316-T01-F
Pb EaFA-LRef-1316-T02-F
Pb EaFA-LRef-1316-T03-F
Pb EaFA-LRef-1316-T04-F
Pb EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2

1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2

1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2
1 3.40E+00 U1/2

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
3.40E+00 1.4E+02 6.8E+00 2.2E+01
3.40E+00 7.5E+01 6.8E+00 2.2E+01 10 325
3.40E+00 2.0E+02 6.8E+00 2.2E+01
3.40E+00 2.5E+02 6.8E+00 2.2E+01

3.40E+00 1.3E+03 6.8E+00 2.2E+01
3.40E+00 2.4E+02 6.8E+00 2.2E+01 10 325
3.40E+00 2.3E+02 6.8E+00 2.2E+01
3.40E+00 4.5E+02 6.8E+00 2.2E+01

3.40E+00 4.0E+02 6.8E+00 2.2E+01
3.40E+00 8.1E+01 6.8E+00 2.2E+01 10 325
3.40E+00 3.7E+02 6.8E+00 2.2E+01
3.40E+00 6.2E+02 6.8E+00 2.2E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/1 01:23PM EPA Interlab LRef D-F 131 3-1 316 EaFA
3.39E+03 104% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 0 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/1 0 1 1 : 1 2 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
3.35E+03 103% VU ICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 5 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 7 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/10 1:26PM EPA Interlab LRef D-F 1313-1316 EaFA
3.69E+03 114% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 :23 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

                                                                                                                                                                         1-1263
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dili]
Li EaFA-LRef-1316-T01-D
Li EaFA-LRef-1316-T02-D
Li EaFA-LRef-1316-T03-D
Li EaFA-LRef-1316-T04-D
Li EaFA-LRef-1316-T05-D
Li EaFA-LRef-1316-T01-E
Li EaFA-LRef-1316-T02-E
Li EaFA-LRef-1316-T03-E
Li EaFA-LRef-1316-T04-E
Li EaFA-LRef-1316-T05-E
Li EaFA-LRef-1316-T01-F
Li EaFA-LRef-1316-T02-F
Li EaFA-LRef-1316-T03-F
Li EaFA-LRef-1316-T04-F
Li EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 3.24E+03
1 6.55E+03
1 1.51E+04
1 2.91 E+04

1 3.39E+03
1 6.23E+03
1 1.51 E+04
1 2.92E+04

1 3.25E+03
1 6.30E+03
1 1.48E+04
1 2.86E+04

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.24E+03 1.0E+00 1.9E+00 6.0E+00
6.55E+03 8.6E-01 1.9E+00 6.0E+00 10 325
1.51 E+04 6.9E-02 1.9E+00 6.0E+00
2.91E+04 1.1E+00 1.9E+00 6.0E+00

3.39E+03 1.0E+00 1.9E+00 6.0E+00
6.23E+03 4.1E-01 1.9E+00 6.0E+00 10 325
1.51 E+04 5.8E+00 1.9E+00 6.0E+00
2.92E+04 3.5E-01 1.9E+00 6.0E+00

3.25E+03 5.4E-01 1.9E+00 6.0E+00
6.30E+03 5.2E-01 1.9E+00 6.0E+00 10 325
1.48E+04 2.5E-01 1.9E+00 6.0E+00
2.86E+04 1.6E-01 1.9E+00 6.0E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/1 01:23PM EPA Interlab LRef D-F 131 3-1 316 EaFA
9.29E+03 84% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
9.19E+03 91%VUICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/1 01:26PM EPA Interlab LRef D-F 131 3-1 31 6 EaFA
9.17E+03 88% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 01:29PM EPA Interlab LRef D-F 131 3-1 31 6 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1264
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Win Sample Dilution Cone.
1 ug/L
Mn EaFA-LRef-1316-T01-D 1 3.51E+02
Mn EaFA-LRef-1316-T02-D 1 4.96E+02
Mn EaFA-LRef-1316-T03-D 1 1.15E+03
Mn EaFA-LRef-1316-T04-D 1 8.44E+02
Mn EaFA-LRef-1316-T05-D
Mn EaFA-LRef-1316-T01-E 1 3.45E+02
Mn EaFA-LRef-1316-T02-E 1 4.71E+02
Mn EaFA-LRef-1316-T03-E 1 1.18E+03
Mn EaFA-LRef-1316-T04-E 1 8.69E+02
Mn EaFA-LRef-1316-T05-E
Mn EaFA-LRef-1316-T01-F 1 3.41E+02
Mn EaFA-LRef-1316-T02-F 1 5.22E+02
Mn EaFA-LRef-1316-T03-F 1 1.12E+03
Mn EaFA-LRef-1316-T04-F 1 9.92E+02
Mn EaFA-LRef-1316-T05-F
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L. M9/L ML
3.51 E+02 3.4E-01 2.0E+00 6.4E+00
4.96E+02 8.5E-01 2.0E+00 6.4E+00 10 325
1.15E+03 1.8E+00 2.0E+00 6.4E+00
8.44E+02 1.5E+00 2.0E+00 6.4E+00

3.45E+02 1.2E+00 2.0E+00 6.4E+00
4.71 E+02 7.3E-01 2.0E+00 6.4E+00 10 325
1.18E+03 3.0E+00 2.0E+00 6.4E+00
8.69E+02 9.7E-01 2.0E+00 6.4E+00

3.41 E+02 1.2E+00 2.0E+00 6.4E+00
5.22E+02 2.0E-01 2.0E+00 6.4E+00 10 325
1.12E+03 1.9E+00 2.0E+00 6.4E+00
9.92E+02 1.0E+00 2.0E+00 6.4E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/101:23PM EPA Interlab LRef D-F 1313-1316 EaFA
3.33E+03 87% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.39E+03 90% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/101:26PM EPA Interlab LRef D-F 1313-1316 EaFA
3.34E+03 87% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/101:29PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1265
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Wig Sample Dili]
Mg EaFA-LRef-1316-T01-D
Mg EaFA-LRef-1316-T02-D
Mg EaFA-LRef-1316-T03-D
Mg EaFA-LRef-1316-T04-D
Mg EaFA-LRef-1316-T05-D
Mg EaFA-LRef-1316-T01-E
Mg EaFA-LRef-1316-T02-E
Mg EaFA-LRef-1316-T03-E
Mg EaFA-LRef-1316-T04-E
Mg EaFA-LRef-1316-T05-E
Mg EaFA-LRef-1316-T01-F
Mg EaFA-LRef-1316-T02-F
Mg EaFA-LRef-1316-T03-F
Mg EaFA-LRef-1316-T04-F
Mg EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 6.33E+03
1 1.37E+04
1 3.38E+04
1 6.07E+04

1 6.50E+03
1 1.34E+04
1 3.43E+04
1 6.11E+04

1 6.27E+03
1 1.35E+04
1 3.36E+04
1 6.01 E+04

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
6.33E+03 4.5E-01 1.0E+00 3.2E+00
1.37E+04 1.2E+00 1.0E+00 3.2E+00 1000 100
3.38E+04 1.2E+00 1.0E+00 3.2E+00
6.07E+04 8.7E-01 1.0E+00 3.2E+00

6.50E+03 5.0E-01 1.0E+00 3.2E+00
1.34E+04 2.1E-01 1.0E+00 3.2E+00 1000 100
3.43E+04 6.4E+00 1.0E+00 3.2E+00
6. 11 E+04 4.7E-01 1.0E+00 3.2E+00

6.27E+03 2.6E-01 1.0E+00 3.2E+00
1.35E+04 1.2E+00 1.0E+00 3.2E+00 1000 100
3.36E+04 4.3E-01 1.0E+00 3.2E+00
6.01 E+04 6.9E-01 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
1.46E+04 92% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.44E+04 93%VUICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
1.45E+04 96%VUICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1266
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dili]
Mo EaFA-LRef-1316-T01-D
Mo EaFA-LRef-1316-T02-D
Mo EaFA-LRef-1316-T03-D
Mo EaFA-LRef-1316-T04-D
Mo EaFA-LRef-1316-T05-D
Mo EaFA-LRef-1316-T01-E
Mo EaFA-LRef-1316-T02-E
Mo EaFA-LRef-1316-T03-E
Mo EaFA-LRef-1316-T04-E
Mo EaFA-LRef-1316-T05-E
Mo EaFA-LRef-1316-T01-F
Mo EaFA-LRef-1316-T02-F
Mo EaFA-LRef-1316-T03-F
Mo EaFA-LRef-1316-T04-F
Mo EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 3.10E+03
1 5.77E+03
1 1.25E+04
1 2.53E+04

1 3.20E+03
1 5.69E+03
1 1.26E+04
1 2.47E+04

1 3.13E+03
1 5.61 E+03
1 1.25E+04
1 2.41 E+04

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L. ML
3.10E+03 5.1E-01 1.2E+00 3.8E+00
5.77E+03 2.6E-01 1.2E+00 3.8E+00 10 325
1.25E+04 5.9E-01 1.2E+00 3.8E+00
2.53E+04 6.2E-01 1.2E+00 3.8E+00

3.20E+03 1.0E+00 1.2E+00 3.8E+00
5.69E+03 2.8E-01 1.2E+00 3.8E+00 10 325
1.26E+04 6.2E+00 1.2E+00 3.8E+00
2.47E+04 6.7E-01 1.2E+00 3.8E+00

3.13E+03 1.0E+00 1.2E+00 3.8E+00
5.61 E+03 5.8E-01 1.2E+00 3.8E+00 10 325
1.25E+04 3.8E-01 1.2E+00 3.8E+00
2.41 E+04 5.0E-01 1.2E+00 3.8E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
8.94E+03 98% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
8.90E+03 99% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
8.81E+03 98%VUICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1267
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone.
1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L ML
Ni EaFA-LRef-1316-T01-D 1 9.38E+01 9.38E+01 1.4E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T02-D 1 1.35E+02 1.35E+02 2.2E+00 1.8E+00 5.7E+00 10 325
Ni EaFA-LRef-1316-T03-D 1 3.05E+02 3.05E+02 8.1E-01 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T04-D 1 1.62E+02 1.62E+02 3.3E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T05-D

Ni EaFA-LRef-1316-T01-E 1 9.14E+01 9.14E+01 2.3E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T02-E 1 1.24E+02 1.24E+02 1.9E+00 1.8E+00 5.7E+00 10 325
Ni EaFA-LRef-1316-T03-E 1 3.14E+02 3.14E+02 6.4E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T04-E 1 1.72E+02 1.72E+02 9.4E-01 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T05-E

Ni EaFA-LRef-1316-T01-F 1 9.39E+01 9.39E+01 3.2E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T02-F 1 1.39E+02 1.39E+02 1.9E+00 1.8E+00 5.7E+00 10 325
Ni EaFA-LRef-1316-T03-F 1 3.08E+02 3.08E+02 2.0E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T04-F 1 1.89E+02 1.89E+02 2.2E+00 1.8E+00 5.7E+00
Ni EaFA-LRef-1316-T05-F

Splke Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.46E+03 102% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.50E+03 104% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.42E+03 101% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1268
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dili]
P EaFA-LRef-1316-T01-D
P EaFA-LRef-1316-T02-D
P EaFA-LRef-1316-T03-D
P EaFA-LRef-1316-T04-D
P EaFA-LRef-1316-T05-D
P EaFA-LRef-1316-T01-E
P EaFA-LRef-1316-T02-E
P EaFA-LRef-1316-T03-E
P EaFA-LRef-1316-T04-E
P EaFA-LRef-1316-T05-E
P EaFA-LRef-1316-T01-F
P EaFA-LRef-1316-T02-F
P EaFA-LRef-1316-T03-F
P EaFA-LRef-1316-T04-F
P EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 2.22E+01
1 6.21E+01
1 1.28E+02
1 3.12E+01

1 3.98E+01
1 7.68E+01
1 1.27E+02
1 1.60E+01

1 9.10E+01
1 5.97E+01
1 1.97E+02
1 1.48E+01

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
2.22E+01 3.2E+01 3.7E+00 1.2E+01
6.21E+01 3.0E+00 3.7E+00 1.2E+01 1000 100
1.28E+02 1.1E+01 3.7E+00 1.2E+01
3.12E+01 4.8E+01 3.7E+00 1.2E+01

3.98E+01 1.7E+01 3.7E+00 1.2E+01
7.68E+01 7.9E+00 3.7E+00 1.2E+01 1000 100
1.27E+02 1.4E+01 3.7E+00 1.2E+01
1.60E+01 8.4E+01 3.7E+00 1.2E+01

9.10E+01 4.0E+00 3.7E+00 1.2E+01
5.97E+01 1.1E+01 3.7E+00 1.2E+01 1000 100
1.97E+02 9.1E+00 3.7E+00 1.2E+01
1.48E+01 5.6E+01 3.7E+00 1.2E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/101:23PM EPA Interlab LRef D-F 1313-1316 EaFA
1.14E+03 108% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.14E+03 106% VU ICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
1.12E+03 106% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1269
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dili]
K EaFA-LRef-1316-T01-D
K EaFA-LRef-1316-T02-D
K EaFA-LRef-1316-T03-D
K EaFA-LRef-1316-T04-D
K EaFA-LRef-1316-T05-D
K EaFA-LRef-1316-T01-E
K EaFA-LRef-1316-T02-E
K EaFA-LRef-1316-T03-E
K EaFA-LRef-1316-T04-E
K EaFA-LRef-1316-T05-E
K EaFA-LRef-1316-T01-F
K EaFA-LRef-1316-T02-F
K EaFA-LRef-1316-T03-F
K EaFA-LRef-1316-T04-F
K EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 2.27E+04
1 4.97E+04
1 1.22E+05
1 1.94E+05

1 2.37E+04
1 4.78E+04
1 1.21E+05
1 1.96E+05

1 2.26E+04
1 4.84E+04
1 1.19E+05
1 1.89E+05

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
2.27E+04 9.2E-01 1.6E+00 5.1E+00
4.97E+04 1.2E+00 1.6E+00 5.1E+00 1000 100
1.22E+05 8.4E-01 1.6E+00 5.1E+00
1.94E+05 7.8E-01 1.6E+00 5.1E+00

2.37E+04 1.3E+00 1.6E+00 5.1E+00
4.78E+04 1.0E+00 1.6E+00 5.1E+00 1000 100
1.21E+05 5.5E+00 1.6E+00 5.1E+00
1.96E+05 1.2E+00 1.6E+00 5.1E+00

2.26E+04 1.4E+00 1.6E+00 5.1E+00
4.84E+04 4.2E-01 1.6E+00 5.1E+00 1000 100
1.19E+05 2.0E-01 1.6E+00 5.1E+00
1.89E+05 1.4E+00 1.6E+00 5.1E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/101:23PM EPA Interlab LRef D-F 1313-1316 EaFA
5.06E+04 93% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
4.88E+04 105% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
4.93E+04 90%VUICP-OES 6/7/101:28PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1270
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dili]
Se EaFA-LRef-1316-T01-D
Se EaFA-LRef-1316-T02-D
Se EaFA-LRef-1316-T03-D
Se EaFA-LRef-1316-T04-D
Se EaFA-LRef-1316-T05-D
Se EaFA-LRef-1316-T01-E
Se EaFA-LRef-1316-T02-E
Se EaFA-LRef-1316-T03-E
Se EaFA-LRef-1316-T04-E
Se EaFA-LRef-1316-T05-E
Se EaFA-LRef-1316-T01-F
Se EaFA-LRef-1316-T02-F
Se EaFA-LRef-1316-T03-F
Se EaFA-LRef-1316-T04-F
Se EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 9.95E+02
1 1.03E+03
1 1.19E+03
1 1.81E+03

1 1.04E+03
1 1.09E+03
1 1.11E+03
1 1.67E+03

1 1.05E+03
1 1.05E+03
1 1.19E+03
1 1.68E+03

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L Mg/L Mg/L ML
9.95E+02 1.7E+00 1.5E+01 4.8E+01
1.03E+03 4.5E+00 1.5E+01 4.8E+01 10 325
1.19E+03 2.7E+00 1.5E+01 4.8E+01
1.81E+03 2.9E+00 1.5E+01 4.8E+01

1.04E+03 1.8E+00 1.5E+01 4.8E+01
1.09E+03 1.6E+00 1.5E+01 4.8E+01 10 325
1.11E+03 3.0E+00 1.5E+01 4.8E+01
1.67E+03 3.3E+00 1.5E+01 4.8E+01

1.05E+03 2.2E-01 1.5E+01 4.8E+01
1.05E+03 2.8E+00 1.5E+01 4.8E+01 10 325
1.19E+03 1.7E+00 1.5E+01 4.8E+01
1.68E+03 2.4E+00 1.5E+01 4.8E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/101:23PM EPA Interlab LRef D-F 1313-1316 EaFA
3.90E+03 88% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
4.01E+03 90%VUICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/101:26PM EPA Interlab LRef D-F 1313-1316 EaFA
4.10E+03 94% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/101:29PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1271
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Sample Dili]
EaFA-LRef-1316-T01-D
EaFA-LRef-1316-T02-D
EaFA-LRef-1316-T03-D
EaFA-LRef-1316-T04-D
EaFA-LRef-1316-T05-D
EaFA-LRef-1316-T01-E
EaFA-LRef-1316-T02-E
EaFA-LRef-1316-T03-E
EaFA-LRef-1316-T04-E
EaFA-LRef-1316-T05-E
EaFA-LRef-1316-T01-F
EaFA-LRef-1316-T02-F
EaFA-LRef-1316-T03-F
EaFA-LRef-1316-T04-F
EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 2.14E+03
1 1.65E+03
1 1.88E+03
1 1.49E+03

1 2.17E+03
1 1.67E+03
1 1.87E+03
1 1.49E+03

1 2.18E+03
1 1.67E+03
1 1.85E+03
1 1.70E+03

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.14E+03 5.3E-01 1.1E+00 3.5E+00
1.65E+03 6.0E-01 1.1E+00 3.5E+00 1000 100
1.88E+03 4.9E-01 1.1E+00 3.5E+00
1.49E+03 6.4E-01 1.1E+00 3.5E+00

2.17E+03 1.4E+00 1.1E+00 3.5E+00
1.67E+03 5.1E-01 1.1E+00 3.5E+00 1000 100
1.87E+03 6.1E+00 1.1E+00 3.5E+00
1.49E+03 3.5E-01 1.1E+00 3.5E+00

2.18E+03 6.5E-01 1.1E+00 3.5E+00
1.67E+03 7.7E-01 1.1E+00 3.5E+00 1000 100
1.85E+03 1.2E-01 1.1E+00 3.5E+00
1.70E+03 4.6E-01 1.1E+00 3.5E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 6/7/1 01:23PM EPA Interlab LRef D-F 131 3-1 316 EaFA
2.59E+03 94% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
2.69E+03 102% VU ICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/1 01:26PM EPA Interlab LRef D-F 131 3-1 31 6 EaFA
2.56E+03 89% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 01:29PM EPA Interlab LRef D-F 131 3-1 31 6 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1272
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dili]
Na EaFA-LRef-1316-T01-D
Na EaFA-LRef-1316-T02-D
Na EaFA-LRef-1316-T03-D
Na EaFA-LRef-1316-T04-D
Na EaFA-LRef-1316-T05-D
Na EaFA-LRef-1316-T01-E
Na EaFA-LRef-1316-T02-E
Na EaFA-LRef-1316-T03-E
Na EaFA-LRef-1316-T04-E
Na EaFA-LRef-1316-T05-E
Na EaFA-LRef-1316-T01-F
Na EaFA-LRef-1316-T02-F
Na EaFA-LRef-1316-T03-F
Na EaFA-LRef-1316-T04-F
Na EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 4.61 E+03
1 1.02E+04
1 2.53E+04
1 4.23E+04

1 4.90E+03
1 9.58E+03
1 2.53E+04
1 4.25E+04

1 4.60E+03
1 9.64E+03
1 2.43E+04
1 4.11E+04

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
4.61 E+03 1.3E+00 2.5E+00 8.0E+00
1.02E+04 7.6E-01 2.5E+00 8.0E+00 1000 100
2.53E+04 7.4E-01 2.5E+00 8.0E+00
4.23E+04 8.0E-01 2.5E+00 8.0E+00

4.90E+03 1.6E+00 2.5E+00 8.0E+00
9.58E+03 4.1E-02 2.5E+00 8.0E+00 1000 100
2.53E+04 6.1E+00 2.5E+00 8.0E+00
4.25E+04 7.4E-01 2.5E+00 8.0E+00

4.60E+03 1.0E+00 2.5E+00 8.0E+00
9.64E+03 8.3E-01 2.5E+00 8.0E+00 1000 100
2.43E+04 1.0E-01 2.5E+00 8.0E+00
4.11E+04 3.1E-01 2.5E+00 8.0E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
1.13E+04 106% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
1.06E+04 101% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
1.07E+04 103% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1273
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr Sample Dili]
Sr EaFA-LRef-1316-T01-D
Sr EaFA-LRef-1316-T02-D
Sr EaFA-LRef-1316-T03-D
Sr EaFA-LRef-1316-T04-D
Sr EaFA-LRef-1316-T05-D
Sr EaFA-LRef-1316-T01-E
Sr EaFA-LRef-1316-T02-E
Sr EaFA-LRef-1316-T03-E
Sr EaFA-LRef-1316-T04-E
Sr EaFA-LRef-1316-T05-E
Sr EaFA-LRef-1316-T01-F
Sr EaFA-LRef-1316-T02-F
Sr EaFA-LRef-1316-T03-F
Sr EaFA-LRef-1316-T04-F
Sr EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 2.04E+03
1 3.96E+03
1 7.42E+03
1 7.50E+03

1 2.07E+03
1 3.84E+03
1 7.44E+03
1 7.47E+03

1 2.02E+03
1 3.93E+03
1 7.30E+03
1 7.27E+03

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
2.04E+03 5.6E-01 1.0E+00 3.2E+00
3.96E+03 8.2E-01 1.0E+00 3.2E+00 1000 100
7.42E+03 1.3E+00 1.0E+00 3.2E+00
7.50E+03 8.1E-01 1.0E+00 3.2E+00

2.07E+03 7.1E-01 1.0E+00 3.2E+00
3.84E+03 5.3E-01 1.0E+00 3.2E+00 1000 100
7.44E+03 4.6E+00 1.0E+00 3.2E+00
7.47E+03 1.4E+00 1.0E+00 3.2E+00

2.02E+03 7.3E-01 1.0E+00 3.2E+00
3.93E+03 7.1E-01 1.0E+00 3.2E+00 1000 100
7.30E+03 1.3E+00 1.0E+00 3.2E+00
7.27E+03 7.2E-01 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
4.86E+03 90% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
4.79E+03 95% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
4.85E+03 92% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1274
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dili]
S EaFA-LRef-1316-T01-D
S EaFA-LRef-1316-T02-D
S EaFA-LRef-1316-T03-D
S EaFA-LRef-1316-T04-D
S EaFA-LRef-1316-T05-D
S EaFA-LRef-1316-T01-E
S EaFA-LRef-1316-T02-E
S EaFA-LRef-1316-T03-E
S EaFA-LRef-1316-T04-E
S EaFA-LRef-1316-T05-E
S EaFA-LRef-1316-T01-F
S EaFA-LRef-1316-T02-F
S EaFA-LRef-1316-T03-F
S EaFA-LRef-1316-T04-F
S EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 1.42E+05
1 2.74E+05
1 6.39E+05
1 6.62E+05

1 1.41E+05
1 2.82E+05
1 6.47E+05
1 6.58E+05

1 1.42E+05
1 2.85E+05
1 6.53E+05
1 6.55E+05

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L. % ug/L ug/L ug/L. ML
1.42E+05 5.7E-01 6.8E+00 2.2E+01
2.74E+05 7.7E-01 6.8E+00 2.2E+01 1000 100
6.39E+05 6.6E-01 6.8E+00 2.2E+01
6.62E+05 9.1E-01 6.8E+00 2.2E+01

1.41E+05 8.8E-01 6.8E+00 2.2E+01
2.82E+05 3.9E-01 6.8E+00 2.2E+01 1000 100
6.47E+05 5.7E+00 6.8E+00 2.2E+01
6.58E+05 3.5E-01 6.8E+00 2.2E+01

1.42E+05 7.6E-01 6.8E+00 2.2E+01
2.85E+05 5.5E-01 6.8E+00 2.2E+01 1000 100
6.53E+05 2.2E-01 6.8E+00 2.2E+01
6.55E+05 7.9E-01 6.8E+00 2.2E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L. % I I
VU ICP-OES 6/7/101:23PM EPA Interlab LRef D-F 1313-1316 EaFA
2.75E+05 86% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
2.83E+05 85%VUICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
2.86E+05 91% VU ICP-OES 6/7/1 01:28PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1275
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dili]
Tl EaFA-LRef-1316-T01-D
Tl EaFA-LRef-1316-T02-D
Tl EaFA-LRef-1316-T03-D
Tl EaFA-LRef-1316-T04-D
Tl EaFA-LRef-1316-T05-D
Tl EaFA-LRef-1316-T01-E
Tl EaFA-LRef-1316-T02-E
Tl EaFA-LRef-1316-T03-E
Tl EaFA-LRef-1316-T04-E
Tl EaFA-LRef-1316-T05-E
Tl EaFA-LRef-1316-T01-F
Tl EaFA-LRef-1316-T02-F
Tl EaFA-LRef-1316-T03-F
Tl EaFA-LRef-1316-T04-F
Tl EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 2.30E+00 U1/2
1 7.55E+00 E
1 1.60E+01
1 2.21E+01

1 2.30E+00 U1/2
1 2.30E+00 U1/2
1 1.21E+01 E
1 1.97E+01

1 4.62E+00 E
1 6.22E+00 E
1 1.62E+01
1 2.66E+01

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 2.0E+02 4.6E+00 1.5E+01
7.55E+00 1.2E+02 4.6E+00 1.5E+01 10 325
1.60E+01 5.8E+01 4.6E+00 1.5E+01
2.21 E+01 1.8E+01 4.6E+00 1.5E+01

2.30E+00 1.0E+03 4.6E+00 1.5E+01
2.30E+00 5.5E+02 4.6E+00 1.5E+01 10 325
1.21 E+01 9.2E+01 4.6E+00 1.5E+01
1.97E+01 1.3E+01 4.6E+00 1.5E+01

4.62E+00 1.2E+02 4.6E+00 1.5E+01
6.22E+00 4.9E+01 4.6E+00 1.5E+01 10 325
1.62E+01 6.7E+01 4.6E+00 1.5E+01
2.66E+01 6.0E+01 4.6E+00 1.5E+01

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.30E+03 101% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 :08 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 0 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/1 0 1 1 : 1 2 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
3.37E+03 104% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 5 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 7 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.26E+03 100% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 :23 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

                                                                                                                                                                         1-1276
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dili]
Ti EaFA-LRef-1316-T01-D
Ti EaFA-LRef-1316-T02-D
Ti EaFA-LRef-1316-T03-D
Ti EaFA-LRef-1316-T04-D
Ti EaFA-LRef-1316-T05-D
Ti EaFA-LRef-1316-T01-E
Ti EaFA-LRef-1316-T02-E
Ti EaFA-LRef-1316-T03-E
Ti EaFA-LRef-1316-T04-E
Ti EaFA-LRef-1316-T05-E
Ti EaFA-LRef-1316-T01-F
Ti EaFA-LRef-1316-T02-F
Ti EaFA-LRef-1316-T03-F
Ti EaFA-LRef-1316-T04-F
Ti EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2
1 1.00E+OOU1/2

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.7E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00 10 325
1.00E+00 7.4E+01 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00

1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 8.0E+00 2.0E+00 6.4E+00 10 325
1.00E+00 2.1E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+00 2.0E+00 6.4E+00

1.00E+00 3.4E+02 2.0E+00 6.4E+00
1.00E+00 2.9E+02 2.0E+00 6.4E+00 10 325
1.00E+00 3.0E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/101:23PM EPA Interlab LRef D-F 1313-1316 EaFA
3.28E+03 101% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 :08 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 0 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/1 0 1 1 : 1 2 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
3.33E+03 102% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 5 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA
VU ICP-OES 6/7/1 0 1 1 : 1 7 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

VU ICP-OES 6/7/10 1:26PM EPA Interlab LRef D-F 1313-1316 EaFA
3.24E+03 100% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/1 0 1 1 :23 AM EPA Interlab LRef D-F 1 31 3-1 31 6 EaFA

                                                                                                                                                                         1-1277
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L ML
V EaFA-LRef-1316-T01-D 1 2.09E+02 2.09E+02 1.3E+00 1.5E+00 4.8E+00
V EaFA-LRef-1316-T02-D 1 1.80E+02 1.80E+02 1.0E+00 1.5E+00 4.8E+00 10 325
V EaFA-LRef-1316-T03-D 1 2.37E+02 2.37E+02 1.1E+00 1.5E+00 4.8E+00
V EaFA-LRef-1316-T04-D 1 2.46E+02 2.46E+02 2.6E+00 1.5E+00 4.8E+00
V EaFA-LRef-1316-T05-D

V EaFA-LRef-1316-T01-E 1 2.16E+02 2.16E+02 2.0E+00 1.5E+00 4.8E+00
V EaFA-LRef-1316-T02-E 1 1.74E+02 1.74E+02 5.5E-01 1.5E+00 4.8E+00 10 325
V EaFA-LRef-1316-T03-E 1 2.14E+02 2.14E+02 5.4E+00 1.5E+00 4.8E+00
V EaFA-LRef-1316-T04-E 1 2.37E+02 2.37E+02 1.5E+00 1.5E+00 4.8E+00
V EaFA-LRef-1316-T05-E

V EaFA-LRef-1316-T01-F 1 2.12E+02 2.12E+02 8.3E-01 1.5E+00 4.8E+00
V EaFA-LRef-1316-T02-F 1 1.74E+02 1.74E+02 6.0E-01 1.5E+00 4.8E+00 10 325
V EaFA-LRef-1316-T03-F 1 2.28E+02 2.28E+02 5.9E-01 1.5E+00 4.8E+00
V EaFA-LRef-1316-T04-F 1 2.49E+02 2.49E+02 2.6E-01 1.5E+00 4.8E+00
V EaFA-LRef-1316-T05-F

Splke Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/10 1:23 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.53E+03 103% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.58E+03 105% VU ICP-OES 6/7/10 1:24 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 1:26 PM EPA Interlab LRef D-F 1313-1316 EaFA
3.47E+03 101% VU ICP-OES 6/7/10 1:28 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1278
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Sample Dili]
EaFA-LRef-1316-T01-D
EaFA-LRef-1316-T02-D
EaFA-LRef-1316-T03-D
EaFA-LRef-1316-T04-D
EaFA-LRef-1316-T05-D
EaFA-LRef-1316-T01-E
EaFA-LRef-1316-T02-E
EaFA-LRef-1316-T03-E
EaFA-LRef-1316-T04-E
EaFA-LRef-1316-T05-E
EaFA-LRef-1316-T01-F
EaFA-LRef-1316-T02-F
EaFA-LRef-1316-T03-F
EaFA-LRef-1316-T04-F
EaFA-LRef-1316-T05-F
Sample
tlon Cone. Qualifier
ug/L
1 2.99E+01
1 3.06E+01
1 3.58E+01
1 6.44E+01

1 1.71E+01
1 2.68E+01
1 3.89E+01
1 7.42E+01

1 3.41E+01
1 7.11E+01
1 9.74E+01
1 3.06E+02

Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.99E+01 3.1E+00 1.0E+00 3.2E+00
3.06E+01 3.3E+00 1.0E+00 3.2E+00 10 325
3.58E+01 2.2E+00 1.0E+00 3.2E+00
6.44E+01 1.6E+00 1.0E+00 3.2E+00

1.71E+01 1.0E+01 1.0E+00 3.2E+00
2.68E+01 6.9E+00 1.0E+00 3.2E+00 10 325
3.89E+01 5.6E+00 1.0E+00 3.2E+00
7.42E+01 1.5E+00 1.0E+00 3.2E+00

3.41 E+01 1.3E+00 1.0E+00 3.2E+00
7.11E+01 9.7E-01 1.0E+00 3.2E+00 10 325
9.74E+01 9.5E-01 1.0E+00 3.2E+00
3.06E+02 8.7E-01 1.0E+00 3.2E+00

Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 6/7/1 01:23PM EPA Interlab LRef D-F 131 3-1 316 EaFA
3.44E+03 105% VU ICP-OES 6/7/10 11:07 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:08 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:10 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/10 11:12 AM EPA Interlab LRef D-F 1313-1316 EaFA
3.47E+03 106% VU ICP-OES 6/7/101:24PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:15 AM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:17 AM EPA Interlab LRef D-F 1313-1316 EaFA

VU ICP-OES 6/7/101:26PM EPA Interlab LRef D-F 1313-1316 EaFA
3.43E+03 103% VU ICP-OES 6/7/1 01:28PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 1:29 PM EPA Interlab LRef D-F 1313-1316 EaFA
VU ICP-OES 6/7/10 11:23 AM EPA Interlab LRef D-F 1313-1316 EaFA

                                                                                                                                                                         1-1279
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Dilution
Al SWA-L01-1316-T01-A 1
Al SWA-L01-1316-T02-A 1
Al SWA-L01-1316-T03-A 1
Al SWA-L01-1316-T04-A 1
Al SWA-L01-1316-T01-B 1
Al SWA-L01-1316-T02-B 1
Al SWA-L01-1316-T03-B 1
Al SWA-L01-1316-T04-B 1
Al SWA-L01-1316-T01-C 1
Al SWA-L01-1316-T02-C 1
Al SWA-L01-1316-T03-C 1
Al SWA-L01-1316-T04-C 1
Al SWA-L01-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.65E+04
4.32E+04
9.66E+04
1.77E+05
3.57E+04
4.25E+04
9.58E+04
1.68E+05
3.72E+04
4.59E+04
1.02E+05
1.64E+05
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.65E+04 2.1E-01 1.0E+00 3.2E+00
4.32E+04 4.7E-01 1.0E+00 3.2E+00 1000 100
9.66E+04 2.2E-01 1.0E+00 3.2E+00
1.77E+05 9.9E-01 1.0E+00 3.2E+00
3.57E+04 4.3E-01 1.0E+00 3.2E+00
4.25E+04 6.2E-01 1.0E+00 3.2E+00 1000 100
9.58E+04 3.6E-01 1.0E+00 3.2E+00
1.68E+05 1.2E+00 1.0E+00 3.2E+00
3.72E+04 8.6E-01 1.0E+00 3.2E+00
4.59E+04 7.8E-01 1.0E+00 3.2E+00 1000 100
1.02E+05 8.7E-01 1.0E+00 3.2E+00
1.64E+05 7.0E-01 1.0E+00 3.2E+00
5.00E-01 1.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
4.41E+04 86% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
4.33E+04 89% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
4.68E+04 89% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                                 1-1280
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L01-1316-T01-A 1
Sb SWA-L01-1316-T02-A 1
Sb SWA-L01-1316-T03-A 1
Sb SWA-L01-1316-T04-A 1
Sb SWA-L01-1316-T01-B 1
Sb SWA-L01-1316-T02-B 1
Sb SWA-L01-1316-T03-B 1
Sb SWA-L01-1316-T04-B 1
Sb SWA-L01-1316-T01-C 1
Sb SWA-L01-1316-T02-C 1
Sb SWA-L01-1316-T03-C 1
Sb SWA-L01-1316-T04-C 1
Sb SWA-L01-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.87E+03
3.06E+03
4.45E+03
4.27E+03
2.19E+03
3.31 E+03
4.65E+03
4.26E+03
3.10E+03
3.45E+03
5.39E+03
5.06E+03
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.87E+03 1.3E+00 7.5E+00 2.4E+01
3.06E+03 5.6E-01 7.5E+00 2.4E+01 10 100
4.45E+03 2.6E-01 7.5E+00 2.4E+01
4.27E+03 1.2E+00 7.5E+00 2.4E+01
2.19E+03 9.9E-01 7.5E+00 2.4E+01
3.31E+03 8.3E-01 7.5E+00 2.4E+01 10 100
4.65E+03 5.2E-01 7.5E+00 2.4E+01
4.26E+03 1.2E+00 7.5E+00 2.4E+01
3.10E+03 7.9E-01 7.5E+00 2.4E+01
3.45E+03 3.7E-01 7.5E+00 2.4E+01 10 100
5.39E+03 5.8E-01 7.5E+00 2.4E+01
5.06E+03 7.7E-01 7.5E+00 2.4E+01
3.75E+00 2.7E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
4.01E+03 95% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
4.24E+03 92% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
4.41E+03 95% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1281
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-L01-1316-T01-A 1
As SWA-L01-1316-T02-A 1
As SWA-L01-1316-T03-A 1
As SWA-L01-1316-T04-A 1
As SWA-L01-1316-T01-B 1
As SWA-L01-1316-T02-B 1
As SWA-L01-1316-T03-B 1
As SWA-L01-1316-T04-B 1
As SWA-L01-1316-T01-C 1
As SWA-L01-1316-T02-C 1
As SWA-L01-1316-T03-C 1
As SWA-L01-1316-T04-C 1
As SWA-L01-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.62E+03
8.06E+03
3.90E+04
9.33E+04
3.95E+03
9.06E+03
3.71 E+04
9.65E+04
4.45E+03
8.16E+03
4.08E+04
1.10E+05
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.62E+03 8.5E-01 1.1E+01 3.5E+01
8.06E+03 7.4E-01 1.1E+01 3.5E+01 10 100
3.90E+04 7.9E-01 1.1E+01 3.5E+01
9.33E+04 1.7E+00 1.1E+01 3.5E+01
3.95E+03 8.0E-01 1.1E+01 3.5E+01
9.06E+03 3.6E-01 1.1E+01 3.5E+01 10 100
3.71 E+04 1.6E+00 1.1E+01 3.5E+01
9.65E+04 7.8E-01 1.1E+01 3.5E+01
4.45E+03 1.4E+00 1.1E+01 3.5E+01
8.16E+03 1.4E+00 1.1E+01 3.5E+01 10 100
4.08E+04 9.0E-01 1.1E+01 3.5E+01
1.10E+05 6.8E-01 1.1E+01 3.5E+01
5.50E+00 9.6E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
9.15E+03 109% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
9.93E+03 88% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
9.06E+03 90% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1282
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-L01-1316-T01-A 1
B SWA-L01-1316-T02-A 1
B SWA-L01-1316-T03-A 1
B SWA-L01-1316-T04-A 1
B SWA-L01-1316-T01-B 1
B SWA-L01-1316-T02-B 1
B SWA-L01-1316-T03-B 1
B SWA-L01-1316-T04-B 1
B SWA-L01-1316-T01-C 1
B SWA-L01-1316-T02-C 1
B SWA-L01-1316-T03-C 1
B SWA-L01-1316-T04-C 1
B SWA-L01-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.10E+03
9.38E+02
6.73E+02
7.24E+02
1.12E+03
9.47E+02
6.75E+02
6.84E+02
1.10E+03
9.78E+02
6.80E+02
6.96E+02
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+03 4.9E-01 1.0E+00 3.2E+00
9.38E+02 7.2E-01 1.0E+00 3.2E+00 1000 100
6.73E+02 6.8E-01 1.0E+00 3.2E+00
7.24E+02 9.7E-01 1.0E+00 3.2E+00
1.12E+03 4.3E-01 1.0E+00 3.2E+00
9.47E+02 1.0E+00 1.0E+00 3.2E+00 1000 100
6.75E+02 1.0E+00 1.0E+00 3.2E+00
6.84E+02 1.3E+00 1.0E+00 3.2E+00
1.10E+03 1.1E+00 1.0E+00 3.2E+00
9.78E+02 1.1E+00 1.0E+00 3.2E+00 1000 100
6.80E+02 1.1E+00 1.0E+00 3.2E+00
6.96E+02 1.6E+00 1.0E+00 3.2E+00
5.00E-01 7.0E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
2.01E+03 107% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
2.02E+03 108% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
2.03E+03 106% VU ICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1283
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qua
ug/L
Ba SWA-L01-1316-T01-A 1 1.47E+02
Ba SWA-L01-1316-T02-A 1 1.39E+02
Ba SWA-L01-1316-T03-A 1 1.48E+02
Ba SWA-L01-1316-T04-A 1 1.24E+02
Ba SWA-L01-1316-T01-B 1 1.43E+02
Ba SWA-L01-1316-T02-B 1 1.33E+02
Ba SWA-L01-1316-T03-B 1 1.56E+02
Ba SWA-L01-1316-T04-B 1 1.12E+02
Ba SWA-L01-1316-T01-C 1 1.45E+02
Ba SWA-L01-1316-T02-C 1 1.42E+02
Ba SWA-L01-1316-T03-C 1 1.34E+02
Ba SWA-L01-1316-T04-C 1 1.09E+02
Ba SWA-L01-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
ifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.47E+02 5.0E-01 1.0E+00 3.2E+00
1.39E+02 2.9E-01 1.0E+00 3.2E+00 10 100
1.48E+02 3.3E+00 1.0E+00 3.2E+00
1.24E+02 1.5E+00 1.0E+00 3.2E+00
1.43E+02 6.1E-01 1.0E+00 3.2E+00
1.33E+02 7.6E-01 1.0E+00 3.2E+00 10 100
1.56E+02 3.3E+00 1.0E+00 3.2E+00
1.12E+02 4.5E-01 1.0E+00 3.2E+00
1.45E+02 9.1E-01 1.0E+00 3.2E+00
1.42E+02 1.8E-01 1.0E+00 3.2E+00 10 100
1.34E+02 1.6E+00 1.0E+00 3.2E+00
1.09E+02 3.5E+00 1.0E+00 3.2E+00
5.00E-01 7.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.00E+03 86% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
9.95E+02 86% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
9.89E+02 85% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1284
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L01-1316-T01-A 1
Be SWA-L01-1316-T02-A 1
Be SWA-L01-1316-T03-A 1
Be SWA-L01-1316-T04-A 1
Be SWA-L01-1316-T01-B 1
Be SWA-L01-1316-T02-B 1
Be SWA-L01-1316-T03-B 1
Be SWA-L01-1316-T04-B 1
Be SWA-L01-1316-T01-C 1
Be SWA-L01-1316-T02-C 1
Be SWA-L01-1316-T03-C 1
Be SWA-L01-1316-T04-C 1
Be SWA-L01-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.4E+02 1.9E+00 6.0E+00
9.50E-01 3.3E+01 1.9E+00 6.0E+00 10 100
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 3.9E+01 1.9E+00 6.0E+00
9.50E-01 3.0E+01 1.9E+00 6.0E+00 10 100
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 3.7E+01 1.9E+00 6.0E+00
9.50E-01 6.5E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00 10 100
9.50E-01 9.2E+00 1.9E+00 6.0E+00
9.50E-01 1.0E+01 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
9.47E+02 95% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
9.60E+02 96% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
9.45E+02 94% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 10/29/10 10:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1285
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L01-1316-T01-A 1 1.10E+OOU1/2 1.10E+00 2.6E+02 2.2E+00 7.0E+00
Cd SWA-L01-1316-T02-A 1 1.10E+OOU1/2 1.10E+00 1.4E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L01-1316-T03-A 1 1.10E+OOU1/2 1.10E+00 3.4E+01 2.2E+00 7.0E+00
Cd SWA-L01-1316-T04-A 1 1.10E+OOU1/2 1.10E+00 1.6E+02 2.2E+00 7.0E+00
Cd SWA-L01-1316-T01-B 1 1.10E+OOU1/2 1.10E+00 2.0E+02 2.2E+00 7.0E+00
Cd SWA-L01-1316-T02-B 1 1.10E+OOU1/2 1.10E+00 4.8E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L01-1316-T03-B 1 1.10E+OOU1/2 1.10E+00 7.1E+01 2.2E+00 7.0E+00
Cd SWA-L01-1316-T04-B 1 1.10E+OOU1/2 1.10E+00 2.6E+02 2.2E+00 7.0E+00
Cd SWA-L01-1316-T01-C 1 1.10E+OOU1/2 1.10E+00 1.8E+03 2.2E+00 7.0E+00
Cd SWA-L01-1316-T02-C 1 1.10E+OOU1/2 1.10E+00 5.4E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L01-1316-T03-C 1 1.10E+OOU1/2 1.10E+00 1.8E+02 2.2E+00 7.0E+00
Cd SWA-L01-1316-T04-C 1 1.10E+OOU1/2 1.10E+00 1.8E+03 2.2E+00 7.0E+00
Cd SWA-L01-1316-B01-A 1 1.10E+OOU1/2 1.10E+00 2.6E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
9.65E+02 96% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
9.65E+02 96% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
9.53E+02 95% VU ICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 10/29/10 11:01 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 10/29/10 10:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1286
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
1 1 ug/L
Ca SWA-L01-1316-T01-A 1 1.60E+04
Ca SWA-L01-1316-T02-A 1 1.13E+04
Ca SWA-L01-1316-T03-A 1 6.11E+03
Ca SWA-L01-1316-T04-A 1 4.59E+03
Ca SWA-L01-1316-T01-B 1 1.55E+04
Ca SWA-L01-1316-T02-B 1 1.10E+04
Ca SWA-L01-1316-T03-B 1 6.09E+03
Ca SWA-L01-1316-T04-B 1 4.73E+03
Ca SWA-L01-1316-T01-C 1 1.51E+04
Ca SWA-L01-1316-T02-C 1 1.14E+04
Ca SWA-L01-1316-T03-C 1 5.54E+03
Ca SWA-L01-1316-T04-C 1 4.31 E+03
Ca SWA-L01-1316-B01-A 1 3.27E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.60E+04 7.5E-01 2.6E+00 8.3E+00
1.13E+04 9.5E-02 2.6E+00 8.3E+00 1000 100
6.11E+03 2.8E+00 2.6E+00 8.3E+00
4.59E+03 1.8E+00 2.6E+00 8.3E+00
1.55E+04 6.7E-01 2.6E+00 8.3E+00
1.10E+04 6.9E-01 2.6E+00 8.3E+00 1000 100
6.09E+03 2.4E+00 2.6E+00 8.3E+00
4.73E+03 9.7E-01 2.6E+00 8.3E+00
1.51E+04 6.2E-01 2.6E+00 8.3E+00
1.14E+04 8.3E-01 2.6E+00 8.3E+00 1000 100
5.54E+03 2.4E+00 2.6E+00 8.3E+00
4.31 E+03 3.6E-01 2.6E+00 8.3E+00
3.27E+01 1.9E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.24E+04 102% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.20E+04 105% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.24E+04 101% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1287
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr SWA-L01-1316-T01-A 1
Cr SWA-L01-1316-T02-A 1
Cr SWA-L01-1316-T03-A 1
Cr SWA-L01-1316-T04-A 1
Cr SWA-L01-1316-T01-B 1
Cr SWA-L01-1316-T02-B 1
Cr SWA-L01-1316-T03-B 1
Cr SWA-L01-1316-T04-B 1
Cr SWA-L01-1316-T01-C 1
Cr SWA-L01-1316-T02-C 1
Cr SWA-L01-1316-T03-C 1
Cr SWA-L01-1316-T04-C 1
Cr SWA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.24E+03
1.77E+03
2.92E+03
3.06E+03
1.32E+03
1.55E+03
2.74E+03
3.67E+03
1.33E+03
1.67E+03
2.66E+03
3.76E+03
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.24E+03 2.2E-01 1.2E+00 3.8E+00
1.77E+03 1.7E-01 1.2E+00 3.8E+00 10 100
2.92E+03 2.5E+00 1.2E+00 3.8E+00
3.06E+03 8.3E-01 1.2E+00 3.8E+00
1.32E+03 6.8E-01 1.2E+00 3.8E+00
1.55E+03 1.2E+00 1.2E+00 3.8E+00 10 100
2.74E+03 1.0E+00 1.2E+00 3.8E+00
3.67E+03 1.0E+00 1.2E+00 3.8E+00
1.33E+03 1.5E+00 1.2E+00 3.8E+00
1.67E+03 1.0E+00 1.2E+00 3.8E+00 10 100
2.66E+03 1.8E+00 1.2E+00 3.8E+00
3.76E+03 4.6E-01 1.2E+00 3.8E+00
6.00E-01 2.0E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
2.67E+03 90% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
2.58E+03 103% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
2.69E+03 102% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1288
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co SWA-L01-1316-T01-A 1
Co SWA-L01-1316-T02-A 1
Co SWA-L01-1316-T03-A 1
Co SWA-L01-1316-T04-A 1
Co SWA-L01-1316-T01-B 1
Co SWA-L01-1316-T02-B 1
Co SWA-L01-1316-T03-B 1
Co SWA-L01-1316-T04-B 1
Co SWA-L01-1316-T01-C 1
Co SWA-L01-1316-T02-C 1
Co SWA-L01-1316-T03-C 1
Co SWA-L01-1316-T04-C 1
Co SWA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
3.03E+00 E
6.38E+00
9.00E-01 U1/2
9.00E-01 U1/2
2.18E+00 E
6.37E+00
9.00E-01 U1/2
9.00E-01 U1/2
2.32E+00 E
6.42E+00
9.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 7.7E+02 1.8E+00 5.7E+00
9.00E-01 6.9E+02 1.8E+00 5.7E+00 10 100
3.03E+00 3.3E+01 1.8E+00 5.7E+00
6.38E+00 2.4E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00 10 100
2.18E+00 5.9E+01 1.8E+00 5.7E+00
6.37E+00 5.5E+00 1.8E+00 5.7E+00
9.00E-01 2.2E+02 1.8E+00 5.7E+00
9.00E-01 8.9E+01 1.8E+00 5.7E+00 10 100
2.32E+00 2.2E+01 1.8E+00 5.7E+00
6.42E+00 2.0E+01 1.8E+00 5.7E+00
9.00E-01 2.7E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.05E+03 105% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.03E+03 103% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.01E+03 101% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 10/29/10 10:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1289
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu SWA-L01-1316-T01-A 1
Cu SWA-L01-1316-T02-A 1
Cu SWA-L01-1316-T03-A 1
Cu SWA-L01-1316-T04-A 1
Cu SWA-L01-1316-T01-B 1
Cu SWA-L01-1316-T02-B 1
Cu SWA-L01-1316-T03-B 1
Cu SWA-L01-1316-T04-B 1
Cu SWA-L01-1316-T01-C 1
Cu SWA-L01-1316-T02-C 1
Cu SWA-L01-1316-T03-C 1
Cu SWA-L01-1316-T04-C 1
Cu SWA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.85E+00 U1/2
6.34E+00 E
2.61E+01
6.07E+01
1.85E+00 U1/2
9.12E+00 E
2.69E+01
4.97E+01
1.85E+00 U1/2
7.61 E+00 E
2.05E+01
7.62E+01
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 2.4E+01 3.7E+00 1.2E+01
6.34E+00 2.7E+01 3.7E+00 1.2E+01 10 100
2.61 E+01 6.4E+00 3.7E+00 1.2E+01
6.07E+01 8.0E-01 3.7E+00 1.2E+01
1.85E+00 1.5E+02 3.7E+00 1.2E+01
9.12E+00 1.2E+01 3.7E+00 1.2E+01 10 100
2.69E+01 3.7E+00 3.7E+00 1.2E+01
4.97E+01 4.2E+00 3.7E+00 1.2E+01
1.85E+00 1.1E+02 3.7E+00 1.2E+01
7.61E+00 3.7E+01 3.7E+00 1.2E+01 10 100
2.05E+01 6.1E+00 3.7E+00 1.2E+01
7.62E+01 4.7E+00 3.7E+00 1.2E+01
1.85E+00 3.1 E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.04E+03 103% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.05E+03 104% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.02E+03 101% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 10/29/10 10:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1290
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe SWA-L01-1316-T01-A 1
Fe SWA-L01-1316-T02-A 1
Fe SWA-L01-1316-T03-A 1
Fe SWA-L01-1316-T04-A 1
Fe SWA-L01-1316-T01-B 1
Fe SWA-L01-1316-T02-B 1
Fe SWA-L01-1316-T03-B 1
Fe SWA-L01-1316-T04-B 1
Fe SWA-L01-1316-T01-C 1
Fe SWA-L01-1316-T02-C 1
Fe SWA-L01-1316-T03-C 1
Fe SWA-L01-1316-T04-C 1
Fe SWA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.10E+02
2.39E+02
7.73E+02
1.35E+03
1.07E+02
2.47E+02
7.36E+02
1.78E+03
1.08E+02
2.22E+02
6.62E+02
1.83E+03
1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+02 3.5E-01 2.0E+00 6.4E+00
2.39E+02 1.1E+00 2.0E+00 6.4E+00 1000 100
7.73E+02 1.7E+00 2.0E+00 6.4E+00
1.35E+03 1.0E+00 2.0E+00 6.4E+00
1.07E+02 4.5E-01 2.0E+00 6.4E+00
2.47E+02 5.0E-01 2.0E+00 6.4E+00 1000 100
7.36E+02 7.1E-01 2.0E+00 6.4E+00
1.78E+03 2.5E-01 2.0E+00 6.4E+00
1.08E+02 4.6E-01 2.0E+00 6.4E+00
2.22E+02 7.3E-01 2.0E+00 6.4E+00 1000 100
6.62E+02 7.7E-01 2.0E+00 6.4E+00
1.83E+03 7.2E-01 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.34E+03 110% VUICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.37E+03 112% VUICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.32E+03 110% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1291
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone.
1 1 ug/L
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Pb SWA-L01-1316-T01-A 1 1.73E+01 E 1.73E+01 1 .6E+01 6.8E+00 2.2E+01
Pb SWA-L01-1316-T02-A 1 3.73E+01
Pb SWA-L01-1316-T03-A 1 7.80E+01
Pb SWA-L01-1316-T04-A 1 1.69E+02
3.73E+01 9.9E+00 6.8E+00 2.2E+01 10 100
7.80E+01 3.2E+00 6.8E+00 2.2E+01
1.69E+02 5.4E+00 6.8E+00 2.2E+01
Pb SWA-L01-1316-T01-B 1 1.29E+01 E 1.29E+01 2.4E+01 6.8E+00 2.2E+01
Pb SWA-L01-1316-T02-B 1 3.49E+01
Pb SWA-L01-1316-T03-B 1 7.94E+01
Pb SWA-L01-1316-T04-B 1 1.88E+02
3.49E+01 8.3E+00 6.8E+00 2.2E+01 10 100
7.94E+01 7.7E+00 6.8E+00 2.2E+01
1.88E+02 3.4E+00 6.8E+00 2.2E+01
Pb SWA-L01-1316-T01-C 1 1.31E+01 E 1.31E+01 5.2E+01 6.8E+00 2.2E+01
Pb SWA-L01-1316-T02-C 1 2.74E+01
Pb SWA-L01-1316-T03-C 1 6.72E+01
Pb SWA-L01-1316-T04-C 1 2.01 E+02
2.74E+01 6.9E+00 6.8E+00 2.2E+01 10 100
6.72E+01 5.2E+00 6.8E+00 2.2E+01
2.01 E+02 1.2E+00 6.8E+00 2.2E+01
Pb SWA-L01-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 5.1E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
9.97E+02 96% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.00E+03 97% VUICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
9.81E+02 95% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1292
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Li SWA-L01-1316-T01-A 1 2.66E+00 E 2.66E+00 5.7E+00 1.9E+00 6.0E+00
Li SWA-L01-1316-T02-A 1 6.26E+00
Li SWA-L01-1316-T03-A 1 7.17E+00
Li SWA-L01-1316-T04-A 1 9.35E+00
6.26E+00 7.6E+00 1.9E+00 6.0E+00 10 100
7.17E+00 1.5E+01 1.9E+00 6.0E+00
9.35E+00 1.0E+01 1.9E+00 6.0E+00
Li SWA-L01-1316-T01-B 1 2.33E+00 E 2.33E+00 1.5E+01 1.9E+00 6.0E+00
Li SWA-L01-1316-T02-B 1 6.15E+00
Li SWA-L01-1316-T03-B 1 6.85E+00
Li SWA-L01-1316-T04-B 1 9.50E+00
6.15E+00 2.1E+01 1.9E+00 6.0E+00 10 100
6.85E+00 9.9E+00 1.9E+00 6.0E+00
9.50E+00 1.0E+01 1.9E+00 6.0E+00
Li SWA-L01-1316-T01-C 1 3.11E+OOE 3.11E+00 3.7E+00 1.9E+00 6.0E+00
Li SWA-L01-1316-T02-C 1 5.94E+00 E 5.94E+00 1.5E+01 1.9E+00 6.0E+00 10 100
Li SWA-L01-1316-T03-C 1 7.01 E+00
Li SWA-L01-1316-T04-C 1 8.47E+00
7.01 E+00 2.6E+01 1.9E+00 6.0E+00
8.47E+00 1.5E+01 1.9E+00 6.0E+00
Li SWA-L01-1316-B01-A 1 9.50E-01 U1/2 9.50E-01 5.0E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 2:03 PM EPA Interlab 1316 SWA Reruns
9.86E+02 98% VU ICP-OES 5/23/11 2:05 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:08 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:10 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:12 PM EPA Interlab 1316 SWA Reruns
9.99E+02 99% VU ICP-OES 5/23/11 2:15 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:17 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:19 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:21 PM EPA Interlab 1316 SWA Reruns
9.90E+02 98% VU ICP-OES 5/23/11 2:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:28 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:30 PM EPA Interlab 1316 SWA Reruns
                                                                                                                                                                         1-1293
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Mn SWA-L01-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 2.4E+01 2.0E+00 6.4E+00
Mn SWA-L01-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 1 .5E+01 2.0E+00 6.4E+00 10 100
Mn SWA-L01-1316-T03-A 1 2.36E+00 E
Mn SWA-L01-1316-T04-A 1 6.27E+00 E
2.36E+00 5.9E+00 2.0E+00 6.4E+00
6.27E+00 1.2E+00 2.0E+00 6.4E+00
Mn SWA-L01-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 8.3E+00 2.0E+00 6.4E+00
Mn SWA-L01-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 7.8E+00 2.0E+00 6.4E+00 10 100
Mn SWA-L01-1316-T03-B 1 2.20E+00 E
Mn SWA-L01-1316-T04-B 1 6.61 E+00
2.20E+00 4.1 E+00 2.0E+00 6.4E+00
6.61 E+00 3.6E+00 2.0E+00 6.4E+00
Mn SWA-L01-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 1 JE+01 2.0E+00 6.4E+00
Mn SWA-L01-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 9.4E+00 2.0E+00 6.4E+00 10 100
Mn SWA-L01-1316-T03-C 1 2.21E+00 E
Mn SWA-L01-1316-T04-C 1 5.24E+00 E
2.21 E+00 8.4E+00 2.0E+00 6.4E+00
5.24E+00 3.7E+00 2.0E+00 6.4E+00
Mn SWA-L01-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 2.1E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.01E+03 101% VUICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.01E+03 101% VUICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
9.97E+02 100% VU ICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1294
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg SWA-L01-1316-T01-A 1
Mg SWA-L01-1316-T02-A 1
Mg SWA-L01-1316-T03-A 1
Mg SWA-L01-1316-T04-A 1
Mg SWA-L01-1316-T01-B 1
Mg SWA-L01-1316-T02-B 1
Mg SWA-L01-1316-T03-B 1
Mg SWA-L01-1316-T04-B 1
Mg SWA-L01-1316-T01-C 1
Mg SWA-L01-1316-T02-C 1
Mg SWA-L01-1316-T03-C 1
Mg SWA-L01-1316-T04-C 1
Mg SWA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
3.64E+00
4.83E+00
7.54E+00
8.86E+00
2.71E+00 E
5.03E+00
7.40E+00
9.74E+00
2.74E+00 E
6.56E+00
5.59E+00
8.33E+00
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.64E+00 1.8E+02 1.0E+00 3.2E+00
4.83E+00 1.1E+02 1.0E+00 3.2E+00 1000 100
7.54E+00 5.4E+01 1.0E+00 3.2E+00
8.86E+00 1.5E+02 1.0E+00 3.2E+00
2.71 E+00 4.9E+01 1.0E+00 3.2E+00
5.03E+00 1.7E+02 1.0E+00 3.2E+00 1000 100
7.40E+00 4.6E+01 1.0E+00 3.2E+00
9.74E+00 6.6E+00 1.0E+00 3.2E+00
2.74E+00 5.2E+01 1.0E+00 3.2E+00
6.56E+00 4.2E+01 1.0E+00 3.2E+00 1000 100
5.59E+00 4.5E+01 1.0E+00 3.2E+00
8.33E+00 6.6E+01 1.0E+00 3.2E+00
5.00E-01 9.3E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.09E+03 109% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.10E+03 110% VUICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.09E+03 109% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1295
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 1 ug/L
Mo SWA-L01-1316-T01-A 1 1.69E+02
Mo SWA-L01-1316-T02-A 1 2.72E+02
Mo SWA-L01-1316-T03-A 1 7.69E+02
Mo SWA-L01-1316-T04-A 1 1.32E+03
Mo SWA-L01-1316-T01-B 1 1.61E+02
Mo SWA-L01-1316-T02-B 1 3.03E+02
Mo SWA-L01-1316-T03-B 1 7.40E+02
Mo SWA-L01-1316-T04-B 1 1.53E+03
Mo SWA-L01-1316-T01-C 1 1.68E+02
Mo SWA-L01-1316-T02-C 1 2.84E+02
Mo SWA-L01-1316-T03-C 1 7.24E+02
Mo SWA-L01-1316-T04-C 1 1.62E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.69E+02 1.2E+00 1.2E+00 3.8E+00
2.72E+02 1.0E+00 1.2E+00 3.8E+00 10 100
7.69E+02 6.9E-02 1.2E+00 3.8E+00
1.32E+03 6.4E-01 1.2E+00 3.8E+00
1.61E+02 3.1E-01 1.2E+00 3.8E+00
3.03E+02 7.3E-01 1.2E+00 3.8E+00 10 100
7.40E+02 5.3E-01 1.2E+00 3.8E+00
1.53E+03 1.0E+00 1.2E+00 3.8E+00
1.68E+02 3.6E-01 1.2E+00 3.8E+00
2.84E+02 9.3E-01 1.2E+00 3.8E+00 10 100
7.24E+02 6.2E-01 1.2E+00 3.8E+00
1.62E+03 1.2E+00 1.2E+00 3.8E+00
Mo SWA-L01-1316-B01-A 1 6.00E-01 U1/2 6.00E-01 5.1E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.39E+03 112% VUICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.42E+03 112% VUICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.38E+03 110% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1296
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni SWA-L01-1316-T01-A 1
Ni SWA-L01-1316-T02-A 1
Ni SWA-L01-1316-T03-A 1
Ni SWA-L01-1316-T04-A 1
Ni SWA-L01-1316-T01-B 1
Ni SWA-L01-1316-T02-B 1
Ni SWA-L01-1316-T03-B 1
Ni SWA-L01-1316-T04-B 1
Ni SWA-L01-1316-T01-C 1
Ni SWA-L01-1316-T02-C 1
Ni SWA-L01-1316-T03-C 1
Ni SWA-L01-1316-T04-C 1
Ni SWA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
2.24E+00 E
6.06E+00
9.00E-01 U1/2
9.00E-01 U1/2
3.74E+00 E
6.72E+00
9.00E-01 U1/2
9.00E-01 U1/2
2.69E+00 E
8.90E+00
9.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 5.3E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00 10 100
2.24E+00 1.8E+01 1.8E+00 5.7E+00
6.06E+00 1.3E+01 1.8E+00 5.7E+00
9.00E-01 9.5E+01 1.8E+00 5.7E+00
9.00E-01 2.4E+03 1.8E+00 5.7E+00 10 100
3.74E+00 2.0E+01 1.8E+00 5.7E+00
6.72E+00 1.8E+01 1.8E+00 5.7E+00
9.00E-01 6.1E+02 1.8E+00 5.7E+00
9.00E-01 4.2E+03 1.8E+00 5.7E+00 10 100
2.69E+00 3.5E+01 1.8E+00 5.7E+00
8.90E+00 1.5E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+03 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
8.74E+02 87% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
8.79E+02 88% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
8.65E+02 86% VU ICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316 SWA
VU ICP-OES 10/29/10 10:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1297
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone.
1 ug/L
P SWA-L01-1316-T01-A 1 1.80E+01
P SWA-L01-1316-T02-A 1 5.68E+01
P SWA-L01-1316-T03-A 1 3.39E+02
P SWA-L01-1316-T04-A 1 9.53E+02
P SWA-L01-1316-T01-B 1 1.83E+01
P SWA-L01-1316-T02-B 1 5.03E+01
P SWA-L01-1316-T03-B 1 3.23E+02
P SWA-L01-1316-T04-B 1 1.31E+03
P SWA-L01-1316-T01-C 1 1.66E+01
P SWA-L01-1316-T02-C 1 5.13E+01
P SWA-L01-1316-T03-C 1 3.16E+02
P SWA-L01-1316-T04-C 1 1.32E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.80E+01 4.8E+01 3.7E+00 1.2E+01
5.68E+01 7.0E+00 3.7E+00 1.2E+01 1000 100
3.39E+02 1.8E+00 3.7E+00 1.2E+01
9.53E+02 1.1E+00 3.7E+00 1.2E+01
1.83E+01 1.1E+01 3.7E+00 1.2E+01
5.03E+01 4.0E+01 3.7E+00 1.2E+01 1000 100
3.23E+02 4.2E+00 3.7E+00 1.2E+01
1.31E+03 7.3E-01 3.7E+00 1.2E+01
1.66E+01 7.2E+01 3.7E+00 1.2E+01
5.13E+01 5.2E+00 3.7E+00 1 .2E+01 1000 100
3.16E+02 3.4E+00 3.7E+00 1 .2E+01
1.32E+03 1.5E+00 3.7E+00 1 .2E+01
P SWA-L01-1316-B01-A 1 8.79E+00 E 8.79E+00 1 .6E+01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
9.34E+02 88% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
9.64E+02 91% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
9.28E+02 88% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1298
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
1 ug/L
K SWA-L01-1316-T01-A 1 2.68E+05
K SWA-L01-1316-T02-A 1 4.23E+05
K SWA-L01-1316-T03-A 1 1.77E+06
K SWA-L01-1316-T04-A 1 1.85E+06
K SWA-L01-1316-T01-B 1 2.62E+05
K SWA-L01-1316-T02-B 1 4.21E+05
K SWA-L01-1316-T03-B 1 1.74E+06
K SWA-L01-1316-T04-B 1 1.85E+06
K SWA-L01-1316-T01-C 1 2.60E+05
K SWA-L01-1316-T02-C 1 4.19E+05
K SWA-L01-1316-T03-C 1 1.76E+06
K SWA-L01-1316-T04-C 1 1.87E+06
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.68E+05 6.5E-01 1.6E+00 5.1E+00
4.23E+05 8.9E-01 1.6E+00 5.1E+00 1000 100
1.77E+06 6.5E-01 1.6E+00 5.1E+00
1.85E+06 2.3E+00 1.6E+00 5.1E+00
2.62E+05 9.1E-01 1.6E+00 5.1E+00
4.21E+05 6.6E-01 1.6E+00 5.1E+00 1000 100
1.74E+06 2.1E-01 1.6E+00 5.1E+00
1.85E+06 9.8E-01 1.6E+00 5.1E+00
2.60E+05 9.3E-01 1.6E+00 5.1E+00
4.19E+05 3.3E+00 1.6E+00 5.1E+00 1000 100
1.76E+06 4.7E-01 1.6E+00 5.1E+00
1.87E+06 8.0E-01 1.6E+00 5.1E+00
K SWA-L01-1316-B01-A 1 8.00E-01 U1/2 8.00E-01 5.6E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
4.24E+05 89% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
4.22E+05 89% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
4.20E+05 95% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1299
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se SWA-L01-1316-T01-A 1
Se SWA-L01-1316-T02-A 1
Se SWA-L01-1316-T03-A 1
Se SWA-L01-1316-T04-A 1
Se SWA-L01-1316-T01-B 1
Se SWA-L01-1316-T02-B 1
Se SWA-L01-1316-T03-B 1
Se SWA-L01-1316-T04-B 1
Se SWA-L01-1316-T01-C 1
Se SWA-L01-1316-T02-C 1
Se SWA-L01-1316-T03-C 1
Se SWA-L01-1316-T04-C 1
Se SWA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
9.63E+04
1.71E+05
4.63E+05
7.68E+05
9.58E+04
1.84E+05
4.48E+05
8.45E+05
9.64E+04
1.69E+05
4.42E+05
9.01 E+05
7.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.63E+04 7.9E-01 1.5E+01 4.8E+01
1.71 E+05 2.7E-01 1.5E+01 4.8E+01 10 100
4.63E+05 2.6E-01 1.5E+01 4.8E+01
7.68E+05 5.8E-01 1.5E+01 4.8E+01
9.58E+04 5.4E-01 1.5E+01 4.8E+01
1.84E+05 9.8E-01 1.5E+01 4.8E+01 10 100
4.48E+05 4.7E-01 1.5E+01 4.8E+01
8.45E+05 9.0E-01 1.5E+01 4.8E+01
9.64E+04 1.1E+00 1.5E+01 4.8E+01
1.69E+05 2.0E-01 1.5E+01 4.8E+01 10 100
4.42E+05 3.9E-01 1.5E+01 4.8E+01
9.01 E+05 8.4E-01 1.5E+01 4.8E+01
7.50E+00 2.3E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.72E+05 98%VUICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.85E+05 85% VUICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.70E+05 113% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1300
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qu
Si SWA-L01-1316-T01-A 1 2.06E+04
Si SWA-L01-1316-T02-A 1 2.33E+04
Si SWA-L01-1316-T03-A 1 3.14E+04
Si SWA-L01-1316-T04-A 1 5.23E+04
Si SWA-L01-1316-T01-B 1 2.07E+04
Si SWA-L01-1316-T02-B 1 2.21E+04
Si SWA-L01-1316-T03-B 1 3.22E+04
Si SWA-L01-1316-T04-B 1 5.75E+04
Si SWA-L01-1316-T01-C 1 2.33E+04
Si SWA-L01-1316-T02-C 1 2.44E+04
Si SWA-L01-1316-T03-C 1 2.96E+04
Si SWA-L01-1316-T04-C 1 5.42E+04
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.06E+04 6.7E-01 1.1E+00 3.5E+00
2.33E+04 2.0E-01 1.1E+00 3.5E+00 1000 100
3.14E+04 1.2E+00 1.1E+00 3.5E+00
5.23E+04 9.5E-01 1.1E+00 3.5E+00
2.07E+04 8.9E-01 1.1E+00 3.5E+00
2.21E+04 1.7E+00 1.1E+00 3.5E+00 1000 100
3.22E+04 8.3E-01 1.1E+00 3.5E+00
5.75E+04 3.6E-01 1.1E+00 3.5E+00
2.33E+04 1.1E+00 1.1E+00 3.5E+00
2.44E+04 2.1E+00 1.1E+00 3.5E+00 1000 100
2.96E+04 1.3E+00 1.1E+00 3.5E+00
5.42E+04 1.9E+00 1.1E+00 3.5E+00
Si SWA-L01-1316-B01-A 1 5.50E-01 U1/2 5.50E-01 3.8E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VUICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
2.43E+04 101% VUICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
2.32E+04 111% VUICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
2.55E+04 106% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1301
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na SWA-L01-1316-T01-A 1
Na SWA-L01-1316-T02-A 1
Na SWA-L01-1316-T03-A 1
Na SWA-L01-1316-T04-A 1
Na SWA-L01-1316-T01-B 1
Na SWA-L01-1316-T02-B 1
Na SWA-L01-1316-T03-B 1
Na SWA-L01-1316-T04-B 1
Na SWA-L01-1316-T01-C 1
Na SWA-L01-1316-T02-C 1
Na SWA-L01-1316-T03-C 1
Na SWA-L01-1316-T04-C 1
Na SWA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
4.89E+05
5.15E+05
5.27E+05
5.30E+05
4.83E+05
5.17E+05
5.30E+05
5.16E+05
4.75E+05
5.17E+05
5.26E+05
5.20E+05
3.53E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.89E+05 7.0E-01 2.5E+00 8.0E+00
5.15E+05 4.6E-01 2.5E+00 8.0E+00 1000 100
5.27E+05 9.4E-01 2.5E+00 8.0E+00
5.30E+05 6.4E-01 2.5E+00 8.0E+00
4.83E+05 6.8E-01 2.5E+00 8.0E+00
5.17E+05 2.1E+00 2.5E+00 8.0E+00 1000 100
5.30E+05 2.1E-01 2.5E+00 8.0E+00
5.16E+05 1.5E+00 2.5E+00 8.0E+00
4.75E+05 6.9E-01 2.5E+00 8.0E+00
5.17E+05 7.6E-01 2.5E+00 8.0E+00 1000 100
5.26E+05 2.7E-01 2.5E+00 8.0E+00
5.20E+05 5.8E-01 2.5E+00 8.0E+00
3.53E+01 2.1E+01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
5.16E+05 89% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
5.17E+05 85% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
5.18E+05 87% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1302
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qu
SWA-L01-1316-T01-A 1 4.94E+02
SWA-L01-1316-T02-A 1 4.69E+02
SWA-L01-1316-T03-A 1 4.76E+02
SWA-L01-1316-T04-A 1 5.14E+02
SWA-L01-1316-T01-B 1 4.59E+02
SWA-L01-1316-T02-B 1 4.59E+02
SWA-L01-1316-T03-B 1 4.73E+02
SWA-L01-1316-T04-B 1 5.56E+02
SWA-L01-1316-T01-C 1 4.33E+02
SWA-L01-1316-T02-C 1 4.48E+02
SWA-L01-1316-T03-C 1 4.66E+02
SWA-L01-1316-T04-C 1 5.23E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.94E+02 2.6E-01 1.0E+00 3.2E+00
4.69E+02 1.1E+00 1.0E+00 3.2E+00 1000 100
4.76E+02 8.6E-01 1.0E+00 3.2E+00
5.14E+02 2.5E+00 1.0E+00 3.2E+00
4.59E+02 5.7E-01 1.0E+00 3.2E+00
4.59E+02 3.4E-01 1.0E+00 3.2E+00 1000 100
4.73E+02 7.8E-01 1.0E+00 3.2E+00
5.56E+02 1.9E+00 1.0E+00 3.2E+00
4.33E+02 1.7E+00 1.0E+00 3.2E+00
4.48E+02 5.2E-01 1.0E+00 3.2E+00 1000 100
4.66E+02 9.8E-01 1.0E+00 3.2E+00
5.23E+02 5.7E-01 1.0E+00 3.2E+00
SWA-L01-1316-B01-A 1 5.00E-01 U1/2 5.00E-01 2.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VUICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.56E+03 109% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.52E+03 106% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.48E+03 104% VU ICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1303
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S SWA-L01-1316-T01-A 1
S SWA-L01-1316-T02-A 1
S SWA-L01-1316-T03-A 1
S SWA-L01-1316-T04-A 1
S SWA-L01-1316-T01-B 1
S SWA-L01-1316-T02-B 1
S SWA-L01-1316-T03-B 1
S SWA-L01-1316-T04-B 1
S SWA-L01-1316-T01-C 1
S SWA-L01-1316-T02-C 1
S SWA-L01-1316-T03-C 1
S SWA-L01-1316-T04-C 1
S SWA-L01-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
7.86E+05
5.30E+05
1.52E+06
2.01 E+06
7.91 E+05
5.67E+05
1.38E+06
2.00E+06
8.10E+05
5.43E+05
1.57E+06
2.12E+06
3.40E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.86E+05 9.0E-01 6.8E+00 2.2E+01
5.30E+05 1.5E-01 6.8E+00 2.2E+01 1000 100
1.52E+06 4.5E-01 6.8E+00 2.2E+01
2.01 E+06 1.0E+00 6.8E+00 2.2E+01
7.91 E+05 4.4E-01 6.8E+00 2.2E+01
5.67E+05 9.8E-01 6.8E+00 2.2E+01 1000 100
1.38E+06 3.9E-01 6.8E+00 2.2E+01
2.00E+06 1.3E+00 6.8E+00 2.2E+01
8.10E+05 1.2E+00 6.8E+00 2.2E+01
5.43E+05 3.5E-01 6.8E+00 2.2E+01 1000 100
1.57E+06 3.5E-01 6.8E+00 2.2E+01
2.12E+06 9.6E-01 6.8E+00 2.2E+01
3.40E+00 1.4E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
6.21E+05 91%VUICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
6.59E+05 91% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
6.29E+05 86% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1304
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L01-1316-T01-A 1 2.30E+00 U1/2 2.30E+00 7.1E+01 4.6E+00 1.5E+01
Tl SWA-L01-1316-T02-A 1 2.30E+00 U1/2 2.30E+00 4.8E+02 4.6E+00 1.5E+01 10 100
Tl SWA-L01-1316-T03-A 1 2.30E+00 U1/2 2.30E+00 3.2E+02 4.6E+00 1.5E+01
Tl SWA-L01-1316-T04-A 1 2.30E+00 U1/2 2.30E+00 4.3E+02 4.6E+00 1.5E+01
Tl SWA-L01-1316-T01-B 1 2.30E+00 U1/2 2.30E+00 3.6E+01 4.6E+00 1.5E+01
Tl SWA-L01-1316-T02-B 1 2.30E+00 U1/2 2.30E+00 4.9E+01 4.6E+00 1.5E+01 10 100
Tl SWA-L01-1316-T03-B 1 2.30E+00 U1/2 2.30E+00 5.7E+01 4.6E+00 1.5E+01
Tl SWA-L01-1316-T04-B 1 2.30E+00 U1/2 2.30E+00 7.1E+02 4.6E+00 1.5E+01
Tl SWA-L01-1316-T01-C 1 2.30E+00 U1/2 2.30E+00 4.4E+01 4.6E+00 1.5E+01
Tl SWA-L01-1316-T02-C 1 2.30E+00 U1/2 2.30E+00 6.0E+01 4.6E+00 1.5E+01 10 100
Tl SWA-L01-1316-T03-C 1 2.30E+00 U1/2 2.30E+00 5.8E+01 4.6E+00 1.5E+01
Tl SWA-L01-1316-T04-C 1 2.30E+00 U1/2 2.30E+00 2.3E+02 4.6E+00 1.5E+01
Tl SWA-L01-1316-B01-A 1 2.30E+00 U1/2 2.30E+00 2.4E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VUICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
8.77E+02 88% VUICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
8.76E+02 87% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
8.62E+02 86% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1305
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L01-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 2.4E+01 2.0E+00 6.4E+00
Ti SWA-L01-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 2.2E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L01-1316-T03-A 1 2.52E+00 E
Ti SWA-L01-1316-T04-A 1 6.06E+00 E
2.52E+00 7.7E+00 2.0E+00 6.4E+00
6.06E+00 1.0E+01 2.0E+00 6.4E+00
Ti SWA-L01-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 3.4E+01 2.0E+00 6.4E+00
Ti SWA-L01-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 2.3E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L01-1316-T03-B 1 2.34E+00 E
Ti SWA-L01-1316-T04-B 1 8.00E+00
2.34E+00 6.7E+00 2.0E+00 6.4E+00
8.00E+00 1.1E+01 2.0E+00 6.4E+00
Ti SWA-L01-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 2.2E+01 2.0E+00 6.4E+00
Ti SWA-L01-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 3.3E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L01-1316-T03-C 1 2.44E+00 E
Ti SWA-L01-1316-T04-C 1 6.76E+00
2.44E+00 1.1E+01 2.0E+00 6.4E+00
6.76E+00 4.0E+00 2.0E+00 6.4E+00
Ti SWA-L01-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 5.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.15E+03 115% VUICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.17E+03 117% VUICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.15E+03 115% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1306
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
V SWA-L01-1316-T01-A 1 3.31 E+02
V SWA-L01-1316-T02-A 1 4.88E+02
V SWA-L01-1316-T03-A 1 1.18E+03
V SWA-L01-1316-T04-A 1 1.99E+03
V SWA-L01-1316-T01-B 1 3.41 E+02
V SWA-L01-1316-T02-B 1 5.16E+02
V SWA-L01-1316-T03-B 1 1.13E+03
V SWA-L01-1316-T04-B 1 2.05E+03
V SWA-L01-1316-T01-C 1 3.68E+02
V SWA-L01-1316-T02-C 1 4.90E+02
V SWA-L01-1316-T03-C 1 1.27E+03
V SWA-L01-1316-T04-C 1 2.25E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.31 E+02 5.3E-01 1.5E+00 4.8E+00
4.88E+02 9.0E-01 1.5E+00 4.8E+00 10 100
1.18E+03 2.7E-01 1.5E+00 4.8E+00
1.99E+03 4.8E-01 1.5E+00 4.8E+00
3.41 E+02 1.0E+00 1.5E+00 4.8E+00
5.16E+02 8.6E-01 1.5E+00 4.8E+00 10 100
1.13E+03 9.2E-01 1.5E+00 4.8E+00
2.05E+03 3.1E-01 1.5E+00 4.8E+00
3.68E+02 1.7E+00 1.5E+00 4.8E+00
4.90E+02 7.5E-01 1.5E+00 4.8E+00 10 100
1.27E+03 1.8E-01 1.5E+00 4.8E+00
2.25E+03 5.4E-01 1.5E+00 4.8E+00
V SWA-L01-1316-B01-A 1 7.50E-01 U1/2 7.50E-01 3.5E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.52E+03 103% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.56E+03 105% VU ICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.52E+03 103% VU ICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1307
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qu
1 1 ug/L
Zn SWA-L01-1316-T01-A 1 1.23E+01
Zn SWA-L01-1316-T02-A 1 1.33E+01
Zn SWA-L01-1316-T03-A 1 1.64E+01
Zn SWA-L01-1316-T04-A 1 2.77E+01
Zn SWA-L01-1316-T01-B 1 1.29E+01
Zn SWA-L01-1316-T02-B 1 1.30E+01
Zn SWA-L01-1316-T03-B 1 1.47E+01
Zn SWA-L01-1316-T04-B 1 3.34E+01
Zn SWA-L01-1316-T01-C 1 1.34E+01
Zn SWA-L01-1316-T02-C 1 1.34E+01
Zn SWA-L01-1316-T03-C 1 1.46E+01
Zn SWA-L01-1316-T04-C 1 3.10E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.23E+01 2.1E+00 1.0E+00 3.2E+00
1.33E+01 1.7E+00 1.0E+00 3.2E+00 10 100
1.64E+01 1.6E+00 1.0E+00 3.2E+00
2.77E+01 2.1E+00 1.0E+00 3.2E+00
1.29E+01 4.1E+00 1.0E+00 3.2E+00
1.30E+01 3.7E+00 1.0E+00 3.2E+00 10 100
1.47E+01 3.0E+00 1.0E+00 3.2E+00
3.34E+01 2.2E-01 1.0E+00 3.2E+00
1.34E+01 7.6E-01 1.0E+00 3.2E+00
1.34E+01 2.6E+00 1.0E+00 3.2E+00 10 100
1.46E+01 4.9E+00 1.0E+00 3.2E+00
3.10E+01 3.2E+00 1.0E+00 3.2E+00
Zn SWA-L01-1316-B01-A 1 5.00E-01 U1/2 5.00E-01 7.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L % | |
VU ICP-OES 10/29/10 10:42 AM EPA Interlab L01 1313-1316 SWA
1.01E+03 100% VU ICP-OES 10/29/10 10:44 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:46 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:03 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/10 10:49 AM EPA Interlab L01 1313-1316 SWA
1.02E+03 101% VUICP-OES 10/29/10 10:51 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:53 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:55 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 10:56 AM EPA Interlab L01 1313-1316 SWA
1.00E+03 99% VUICP-OES 10/29/10 10:58 AM EPA Interlab L01 1313-1316 SWA
VUICP-OES 10/29/10 11:00 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1011:01 AM EPA Interlab L01 1313-1316SWA
VUICP-OES 10/29/1010:41 AM EPA Interlab L01 1313-1316 SWA
                                                                                                                                                                         1-1308
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al SWA-L02-1316-T01-A 1
Al SWA-L02-1316-T02-A 1
Al SWA-L02-1316-T03-A 1
Al SWA-L02-1316-T04-A 1
Al SWA-L02-1316-T05-A 1
Al SWA-L02-1316-T01-B 1
Al SWA-L02-1316-T02-B 1
Al SWA-L02-1316-T03-B 1
Al SWA-L02-1316-T04-B 1
Al SWA-L02-1316-T05-B 1
Al SWA-L02-1316-T01-C 1
Al SWA-L02-1316-T02-C 1
Al SWA-L02-1316-T03-C 1
Al SWA-L02-1316-T04-C 1
Al SWA-L02-1316-T05-C 1
Al SWA-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.51 E+04
6.80E+04
1.38E+05
2.05E+05
1.77E+05
4.33E+04
6.95E+04
1.28E+05
2.07E+05
1.83E+05
4.21 E+04
6.91 E+04
1.39E+05
1.96E+05
1.73E+05
2.85E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.51 E+04 9.6E-01 1.0E+00 3.2E+00
6.80E+04 7.1E-01 1.0E+00 3.2E+00 1000 125
1.38E+05 3.8E-01 1.0E+00 3.2E+00
2.05E+05 1.5E+00 1.0E+00 3.2E+00
1.77E+05 6.8E-01 1.0E+00 3.2E+00
4.33E+04 2.8E-01 1.0E+00 3.2E+00
6.95E+04 1.4E+00 1.0E+00 3.2E+00 1000 125
1.28E+05 1.4E+00 1.0E+00 3.2E+00
2.07E+05 6.1E-01 1.0E+00 3.2E+00
1.83E+05 7.6E-01 1.0E+00 3.2E+00
4.21 E+04 9.8E-01 1.0E+00 3.2E+00
6.91 E+04 4.5E-01 1.0E+00 3.2E+00 1000 125
1.39E+05 3.0E-01 1.0E+00 3.2E+00
1.96E+05 8.1E-01 1.0E+00 3.2E+00
1.73E+05 6.0E-01 1.0E+00 3.2E+00
2.85E+02 6.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
6.91E+04 87% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
7.09E+04 111% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
7.03E+04 98% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                                 1-1309
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L02-1316-T01-A 1
Sb SWA-L02-1316-T02-A 1
Sb SWA-L02-1316-T03-A 1
Sb SWA-L02-1316-T04-A 1
Sb SWA-L02-1316-T05-A 1
Sb SWA-L02-1316-T01-B 1
Sb SWA-L02-1316-T02-B 1
Sb SWA-L02-1316-T03-B 1
Sb SWA-L02-1316-T04-B 1
Sb SWA-L02-1316-T05-B 1
Sb SWA-L02-1316-T01-C 1
Sb SWA-L02-1316-T02-C 1
Sb SWA-L02-1316-T03-C 1
Sb SWA-L02-1316-T04-C 1
Sb SWA-L02-1316-T05-C 1
Sb SWA-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.85E+03
2.37E+03
3.62E+03
6.16E+03
6.70E+03
4.11E+03
2.67E+03
3.54E+03
6.31 E+03
6.88E+03
3.90E+03
2.74E+03
3.55E+03
6.02E+03
6.90E+03
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.85E+03 7.2E-01 7.5E+00 2.4E+01
2.37E+03 7.5E-01 7.5E+00 2.4E+01 10 125
3.62E+03 3.3E-01 7.5E+00 2.4E+01
6.16E+03 2.0E+00 7.5E+00 2.4E+01
6.70E+03 1.8E+00 7.5E+00 2.4E+01
4.11E+03 4.5E-01 7.5E+00 2.4E+01
2.67E+03 1.6E+00 7.5E+00 2.4E+01 10 125
3.54E+03 3.6E+00 7.5E+00 2.4E+01
6.31 E+03 5.5E-01 7.5E+00 2.4E+01
6.88E+03 3.6E-01 7.5E+00 2.4E+01
3.90E+03 1.4E+00 7.5E+00 2.4E+01
2.74E+03 1.2E+00 7.5E+00 2.4E+01 10 125
3.55E+03 1.0E+00 7.5E+00 2.4E+01
6.02E+03 2.5E+00 7.5E+00 2.4E+01
6.90E+03 1.3E+00 7.5E+00 2.4E+01
3.75E+00 2.2E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
3.61E+03 99% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
3.86E+03 95% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
3.98E+03 99% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1310
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-L02-1316-T01-A 1
As SWA-L02-1316-T02-A 1
As SWA-L02-1316-T03-A 1
As SWA-L02-1316-T04-A 1
As SWA-L02-1316-T05-A 1
As SWA-L02-1316-T01-B 1
As SWA-L02-1316-T02-B 1
As SWA-L02-1316-T03-B 1
As SWA-L02-1316-T04-B 1
As SWA-L02-1316-T05-B 1
As SWA-L02-1316-T01-C 1
As SWA-L02-1316-T02-C 1
As SWA-L02-1316-T03-C 1
As SWA-L02-1316-T04-C 1
As SWA-L02-1316-T05-C 1
As SWA-L02-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
5.04E+03
1.45E+04
3.76E+04
5.59E+04
1.61E+05
7.38E+03
1.50E+04
3.47E+04
5.71 E+04
8.00E+04
7.65E+03
1.52E+04
3.93E+04
4.88E+04
1.67E+05
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.04E+03 7.8E-01 1.1E+01 3.5E+01
1.45E+04 1.7E+00 1.1E+01 3.5E+01 10 125
3.76E+04 2.5E-01 1.1E+01 3.5E+01
5.59E+04 1.9E+00 1.1E+01 3.5E+01
1.61E+05 1.1E+00 1.1E+01 3.5E+01
7.38E+03 3.8E-01 1.1E+01 3.5E+01
1.50E+04 1.5E+00 1.1E+01 3.5E+01 10 125
3.47E+04 1.5E+00 1.1E+01 3.5E+01
5.71 E+04 9.0E-01 1.1E+01 3.5E+01
8.00E+04 1.6E+00 1.1E+01 3.5E+01
7.65E+03 4.3E-01 1.1E+01 3.5E+01
1.52E+04 1.2E+00 1.1E+01 3.5E+01 10 125
3.93E+04 4.1E-01 1.1E+01 3.5E+01
4.88E+04 7.6E-01 1.1E+01 3.5E+01
1.67E+05 1.9E+00 1.1E+01 3.5E+01
5.50E+00 1.1E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.55E+04 85% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.61 E+04 88% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.63E+04 91%VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1311
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qua
B SWA-L02-1316-T01-A 1 1.01E+03
B SWA-L02-1316-T02-A 1 9.61 E+02
B SWA-L02-1316-T03-A 1 6.29E+02
B SWA-L02-1316-T04-A 1 8.36E+02
B SWA-L02-1316-T05-A 1 9.53E+02
B SWA-L02-1316-T01-B 1 1.06E+03
B SWA-L02-1316-T02-B 1 9.86E+02
B SWA-L02-1316-T03-B 1 6.51 E+02
B SWA-L02-1316-T04-B 1 8.59E+02
B SWA-L02-1316-T05-B 1 9.94E+02
B SWA-L02-1316-T01-C 1 1.02E+03
B SWA-L02-1316-T02-C 1 9.93E+02
B SWA-L02-1316-T03-C 1 6.49E+02
B SWA-L02-1316-T04-C 1 8.14E+02
B SWA-L02-1316-T05-C 1 9.83E+02
B SWA-L02-1316-B01-A 1 1.98E+01
Internal ICP-OES Spike Sol'n
ifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.01E+03 1.4E+00 1.0E+00 3.2E+00
9.61E+02 1.5E+00 1.0E+00 3.2E+00 1000 125
6.29E+02 5.3E-01 1.0E+00 3.2E+00
8.36E+02 1.4E+00 1.0E+00 3.2E+00
9.53E+02 7.1E-01 1.0E+00 3.2E+00
1.06E+03 1.3E+00 1.0E+00 3.2E+00
9.86E+02 6.3E-01 1.0E+00 3.2E+00 1000 125
6.51 E+02 1.4E+00 1.0E+00 3.2E+00
8.59E+02 9.0E-01 1.0E+00 3.2E+00
9.94E+02 1.8E-01 1.0E+00 3.2E+00
1.02E+03 1.2E+00 1.0E+00 3.2E+00
9.93E+02 9.8E-01 1.0E+00 3.2E+00 1000 125
6.49E+02 1.9E-01 1.0E+00 3.2E+00
8.14E+02 1.2E+00 1.0E+00 3.2E+00
9.83E+02 7.0E-01 1.0E+00 3.2E+00
1.98E+01 4.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
2.13E+03 94% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
2.29E+03 104% VU ICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
2.29E+03 104% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1312
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qua
ug/L
Ba SWA-L02-1316-T01-A 1 1.60E+02
Ba SWA-L02-1316-T02-A 1 1.73E+02
Ba SWA-L02-1316-T03-A 1 1.65E+02
Ba SWA-L02-1316-T04-A 1 1.21E+02
Ba SWA-L02-1316-T05-A 1 1.55E+02
Ba SWA-L02-1316-T01-B 1 1.95E+02
Ba SWA-L02-1316-T02-B 1 1.79E+02
Ba SWA-L02-1316-T03-B 1 1.59E+02
Ba SWA-L02-1316-T04-B 1 1.18E+02
Ba SWA-L02-1316-T05-B 1 1.64E+02
Ba SWA-L02-1316-T01-C 1 1.80E+02
Ba SWA-L02-1316-T02-C 1 1.75E+02
Ba SWA-L02-1316-T03-C 1 1.68E+02
Ba SWA-L02-1316-T04-C 1 1.28E+02
Ba SWA-L02-1316-T05-C 1 1.50E+02
Ba SWA-L02-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
ifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.60E+02 5.5E-01 1.0E+00 3.2E+00
1.73E+02 5.7E-01 1.0E+00 3.2E+00 10 125
1.65E+02 5.6E-01 1.0E+00 3.2E+00
1.21E+02 7.9E-01 1.0E+00 3.2E+00
1.55E+02 4.6E-01 1.0E+00 3.2E+00
1.95E+02 3.3E-01 1.0E+00 3.2E+00
1.79E+02 1.2E+00 1.0E+00 3.2E+00 10 125
1.59E+02 1.6E+00 1.0E+00 3.2E+00
1.18E+02 6.0E-01 1.0E+00 3.2E+00
1.64E+02 4.8E-01 1.0E+00 3.2E+00
1.80E+02 1.4E+00 1.0E+00 3.2E+00
1.75E+02 4.5E-01 1.0E+00 3.2E+00 10 125
1.68E+02 4.5E-01 1.0E+00 3.2E+00
1.28E+02 7.0E-01 1.0E+00 3.2E+00
1.50E+02 5.1E-01 1.0E+00 3.2E+00
5.00E-01 7.4E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1 .24E+03 85% VU ICP-OES 1 1/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
1.35E+03 93% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.35E+03 94% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1313
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L02-1316-T01-A 1
Be SWA-L02-1316-T02-A 1
Be SWA-L02-1316-T03-A 1
Be SWA-L02-1316-T04-A 1
Be SWA-L02-1316-T05-A 1
Be SWA-L02-1316-T01-B 1
Be SWA-L02-1316-T02-B 1
Be SWA-L02-1316-T03-B 1
Be SWA-L02-1316-T04-B 1
Be SWA-L02-1316-T05-B 1
Be SWA-L02-1316-T01-C 1
Be SWA-L02-1316-T02-C 1
Be SWA-L02-1316-T03-C 1
Be SWA-L02-1316-T04-C 1
Be SWA-L02-1316-T05-C 1
Be SWA-L02-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 9.7E+01 1.9E+00 6.0E+00
9.50E-01 3.6E+01 1.9E+00 6.0E+00 10 125
9.50E-01 1.9E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+01 1.9E+00 6.0E+00
9.50E-01 8.0E+01 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 2.5E+01 1.9E+00 6.0E+00 10 125
9.50E-01 3.3E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+01 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 3.8E+01 1.9E+00 6.0E+00 10 125
9.50E-01 3.1E+01 1.9E+00 6.0E+00
9.50E-01 2.1E+01 1.9E+00 6.0E+00
9.50E-01 3.4E+01 1.9E+00 6.0E+00
9.50E-01 4.7E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.34E+03 107% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
1.47E+03 117% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.49E+03 119% VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1314
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L02-1316-T01-A 1 1.10E+OOU1/2 1.10E+00 3.7E+01 2.2E+00 7.0E+00
Cd SWA-L02-1316-T02-A 1 1.10E+OOU1/2 1.10E+00 1.0E+02 2.2E+00 7.0E+00 10 125
Cd SWA-L02-1316-T03-A 1 1.10E+OOU1/2 1.10E+00 1.4E+02 2.2E+00 7.0E+00
Cd SWA-L02-1316-T04-A 1 1.10E+OOU1/2 1.10E+00 2.9E+02 2.2E+00 7.0E+00
Cd SWA-L02-1316-T05-A 1 1.10E+OOU1/2 1.10E+00 3.3E+02 2.2E+00 7.0E+00
Cd SWA-L02-1316-T01-B 1 1.10E+OOU1/2 1.10E+00 1.5E+02 2.2E+00 7.0E+00
Cd SWA-L02-1316-T02-B 1 1.10E+OOU1/2 1.10E+00 5.7E+01 2.2E+00 7.0E+00 10 125
Cd SWA-L02-1316-T03-B 1 1.10E+OOU1/2 1.10E+00 4.5E+01 2.2E+00 7.0E+00
Cd SWA-L02-1316-T04-B 1 1.10E+OOU1/2 1.10E+00 1.6E+01 2.2E+00 7.0E+00
Cd SWA-L02-1316-T05-B 1 1.10E+OOU1/2 1.10E+00 5.7E+01 2.2E+00 7.0E+00
Cd SWA-L02-1316-T01-C 1 1.10E+OOU1/2 1.10E+00 5.0E+01 2.2E+00 7.0E+00
Cd SWA-L02-1316-T02-C 1 1.10E+OOU1/2 1.10E+00 2.0E+02 2.2E+00 7.0E+00 10 125
Cd SWA-L02-1316-T03-C 1 1.10E+OOU1/2 1.10E+00 3.9E+01 2.2E+00 7.0E+00
Cd SWA-L02-1316-T04-C 1 1.10E+OOU1/2 1.10E+00 7.0E+02 2.2E+00 7.0E+00
Cd SWA-L02-1316-T05-C 1 1.10E+OOU1/2 1.10E+00 2.5E+02 2.2E+00 7.0E+00
Cd SWA-L02-1316-B01-A 1 1.10E+OOU1/2 1.10E+00 3.5E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.21E+03 96% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
1.31E+03 105% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.32E+03 106% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1315
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca SWA-L02-1316-T01-A 1
Ca SWA-L02-1316-T02-A 1
Ca SWA-L02-1316-T03-A 1
Ca SWA-L02-1316-T04-A 1
Ca SWA-L02-1316-T05-A 1
Ca SWA-L02-1316-T01-B 1
Ca SWA-L02-1316-T02-B 1
Ca SWA-L02-1316-T03-B 1
Ca SWA-L02-1316-T04-B 1
Ca SWA-L02-1316-T05-B 1
Ca SWA-L02-1316-T01-C 1
Ca SWA-L02-1316-T02-C 1
Ca SWA-L02-1316-T03-C 1
Ca SWA-L02-1316-T04-C 1
Ca SWA-L02-1316-T05-C 1
Ca SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.53E+04
1.02E+04
6.52E+03
5.54E+03
5.25E+03
1.59E+04
1.06E+04
6.49E+03
5.42E+03
5.64E+03
1.52E+04
1.07E+04
6.65E+03
6.19E+03
5.49E+03
3.51 E+03
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+04 6.5E-01 2.6E+00 8.3E+00
1.02E+04 7.0E-01 2.6E+00 8.3E+00 1000 125
6.52E+03 1.6E+00 2.6E+00 8.3E+00
5.54E+03 6.8E-01 2.6E+00 8.3E+00
5.25E+03 1.7E+00 2.6E+00 8.3E+00
1.59E+04 6.3E-01 2.6E+00 8.3E+00
1.06E+04 1.1E+00 2.6E+00 8.3E+00 1000 125
6.49E+03 1.3E+00 2.6E+00 8.3E+00
5.42E+03 3.0E+00 2.6E+00 8.3E+00
5.64E+03 1.9E+00 2.6E+00 8.3E+00
1.52E+04 1.3E+00 2.6E+00 8.3E+00
1.07E+04 4.3E-01 2.6E+00 8.3E+00 1000 125
6.65E+03 8.8E-01 2.6E+00 8.3E+00
6.19E+03 1.7E+00 2.6E+00 8.3E+00
5.49E+03 6.2E-01 2.6E+00 8.3E+00
3.51 E+03 9.5E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time
ug/L %
VU ICP-OES 11/29/10 5:03 PM
Filename
EPA Interlab L02 1313-1316 SWA
1.13E+04 87% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 5:06 PM
VU ICP-OES 11/29/10 5:08 PM
VU ICP-OES 11/29/10 5:10 PM
VU ICP-OES 11/29/105:11 PM
1.17E+04 89% VU ICP-OES 11/29/10 5:13 PM
VU ICP-OES 11/29/10 5:14 PM
VU ICP-OES 11/29/10 5:16 PM
VU ICP-OES 11/29/10 5:18 PM
VU ICP-OES 11/29/10 5:19 PM
1.18E+04 92% VU ICP-OES 11/29/10 5:21 PM
VU ICP-OES 11/29/10 5:23 PM
VU ICP-OES 11/29/10 5:24 PM
VU ICP-OES 11/29/10 5:26 PM
VU ICP-OES 1 1/29/10 5:02 PM
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1316
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qu
1 1 ug/L
Cr SWA-L02-1316-T01-A 1 1.16E+03
Cr SWA-L02-1316-T02-A 1 2.09E+03
Cr SWA-L02-1316-T03-A 1 2.16E+03
Cr SWA-L02-1316-T04-A 1 2.54E+03
Cr SWA-L02-1316-T05-A 1 2.98E+03
Cr SWA-L02-1316-T01-B 1 1.41E+03
Cr SWA-L02-1316-T02-B 1 2.14E+03
Cr SWA-L02-1316-T03-B 1 2.06E+03
Cr SWA-L02-1316-T04-B 1 2.67E+03
Cr SWA-L02-1316-T05-B 1 2.84E+03
Cr SWA-L02-1316-T01-C 1 1.31E+03
Cr SWA-L02-1316-T02-C 1 2.13E+03
Cr SWA-L02-1316-T03-C 1 2.21 E+03
Cr SWA-L02-1316-T04-C 1 2.57E+03
Cr SWA-L02-1316-T05-C 1 2.96E+03
Cr SWA-L02-1316-B01-A 1 1.28E+OOE
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.16E+03 1.2E+00 1.2E+00 3.8E+00
2.09E+03 1.2E+00 1.2E+00 3.8E+00 10 125
2.16E+03 5.5E-01 1.2E+00 3.8E+00
2.54E+03 7.0E-01 1.2E+00 3.8E+00
2.98E+03 5.6E-01 1.2E+00 3.8E+00
1.41 E+03 8.7E-01 1.2E+00 3.8E+00
2.14E+03 1.5E+00 1.2E+00 3.8E+00 10 125
2.06E+03 1.6E+00 1.2E+00 3.8E+00
2.67E+03 1.7E-01 1.2E+00 3.8E+00
2.84E+03 1.1E+00 1.2E+00 3.8E+00
1.31 E+03 7.6E-01 1.2E+00 3.8E+00
2.13E+03 5.9E-01 1.2E+00 3.8E+00 10 125
2.21 E+03 6.2E-01 1.2E+00 3.8E+00
2.57E+03 6.0E-01 1.2E+00 3.8E+00
2.96E+03 1.3E+00 1.2E+00 3.8E+00
1.28E+00 1.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
3.24E+03 92% VU ICP-OES 1 1/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
3.45E+03 105% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
3.49E+03 109% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1317
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Co SWA-L02-1316-T01-A 1 9.00E-01 U1/2 9.00E-01 2.3E+02 1.8E+00 5.7E+00
Co SWA-L02-1316-T02-A 1 9.00E-01 U1/2 9.00E-01 1.7E+02 1.8E+00 5.7E+00 10 125
Co SWA-L02-1316-T03-A 1 2.39E+00 E
Co SWA-L02-1316-T04-A 1 2.81 E+00 E
Co SWA-L02-1316-T05-A 1 4.24E+00
2.39E+00 3.7E+01 1.8E+00 5.7E+00
2.81 E+00 6.2E+01 1.8E+00 5.7E+00
4.24E+00 5.8E+01 1.8E+00 5.7E+00
Co SWA-L02-1316-T01-B 1 9.00E-01 U1/2 9.00E-01 9.7E+00 1.8E+00 5.7E+00
Co SWA-L02-1316-T02-B 1 9.00E-01 U1/2 9.00E-01 3.9E+01 1.8E+00 5.7E+00 10 125
Co SWA-L02-1316-T03-B 1 2.48E+00 E
Co SWA-L02-1316-T04-B 1 3.01 E+00 E
Co SWA-L02-1316-T05-B 1 4.18E+00
2.48E+00 1.0E+02 1.8E+00 5.7E+00
3.01 E+00 1.2E+02 1.8E+00 5.7E+00
4.18E+00 6.9E+00 1.8E+00 5.7E+00
Co SWA-L02-1316-T01-C 1 9.00E-01 U1/2 9.00E-01 6.2E+01 1.8E+00 5.7E+00
Co SWA-L02-1316-T02-C 1 9.00E-01 U1/2 9.00E-01 2.1E+02 1.8E+00 5.7E+00 10 125
Co SWA-L02-1316-T03-C 1 2.75E+00 E
Co SWA-L02-1316-T04-C 1 2.23E+00 E
Co SWA-L02-1316-T05-C 1 3.14E+00
2.75E+00 3.3E+01 1.8E+00 5.7E+00
2.23E+00 2.2E+01 1.8E+00 5.7E+00
3.14E+00 2.6E+01 1.8E+00 5.7E+00
Co SWA-L02-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 8.0E+00 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.19E+03 95% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.29E+03 103% VU ICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.31E+03 105% VU ICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1318
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cu SWA-L02-1316-T01-A 1 1.85E+OOU1/2 1.85E+00 7.3E+01 3.7E+00 1.2E+01
Cu SWA-L02-1316-T02-A 1 5.43E+00 E
Cu SWA-L02-1316-T03-A 1 6.13E+00 E
Cu SWA-L02-1316-T04-A 1 5.79E+00 E
Cu SWA-L02-1316-T05-A 1 2.59E+01
5.43E+00 3.6E+01 3.7E+00 1.2E+01 10 125
6.13E+00 3.8E+01 3.7E+00 1.2E+01
5.79E+00 5.2E+01 3.7E+00 1.2E+01
2.59E+01 1.5E+00 3.7E+00 1.2E+01
Cu SWA-L02-1316-T01-B 1 1.85E+OOU1/2 1.85E+00 5.6E+01 3.7E+00 1.2E+01
Cu SWA-L02-1316-T02-B 1 6.89E+00 E
Cu SWA-L02-1316-T03-B 1 5.30E+00 E
Cu SWA-L02-1316-T04-B 1 6.16E+00 E
Cu SWA-L02-1316-T05-B 1 2.57E+01
6.89E+00 7.4E+01 3.7E+00 1.2E+01 10 125
5.30E+00 3.1E+01 3.7E+00 1.2E+01
6.16E+00 7.7E+01 3.7E+00 1.2E+01
2.57E+01 5.1E+00 3.7E+00 1.2E+01
Cu SWA-L02-1316-T01-C 1 1.85E+OOU1/2 1.85E+00 2.9E+02 3.7E+00 1.2E+01
Cu SWA-L02-1316-T02-C 1 5.77E+00 E
Cu SWA-L02-1316-T03-C 1 5.76E+00 E
Cu SWA-L02-1316-T04-C 1 6.80E+00 E
Cu SWA-L02-1316-T05-C 1 2.92E+01
5.77E+00 4.8E+01 3.7E+00 1.2E+01 10 125
5.76E+00 7.8E+01 3.7E+00 1.2E+01
6.80E+00 5.0E+01 3.7E+00 1.2E+01
2.92E+01 6.9E+00 3.7E+00 1.2E+01
Cu SWA-L02-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 2.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.23E+03 98% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.33E+03 106% VU ICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.35E+03 108% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1319
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone.
1 ug/L
Fe SWA-L02-1316-T01-A 1 1.68E+02
Fe SWA-L02-1316-T02-A 1 3.15E+02
Fe SWA-L02-1316-T03-A 1 8.33E+02
Fe SWA-L02-1316-T04-A 1 1.83E+03
Fe SWA-L02-1316-T05-A 1 1.45E+03
Fe SWA-L02-1316-T01-B 1 1.14E+02
Fe SWA-L02-1316-T02-B 1 3.08E+02
Fe SWA-L02-1316-T03-B 1 8.02E+02
Fe SWA-L02-1316-T04-B 1 2.00E+03
Fe SWA-L02-1316-T05-B 1 1.49E+03
Fe SWA-L02-1316-T01-C 1 1.25E+02
Fe SWA-L02-1316-T02-C 1 2.77E+02
Fe SWA-L02-1316-T03-C 1 8.57E+02
Fe SWA-L02-1316-T04-C 1 1.79E+03
Fe SWA-L02-1316-T05-C 1 1.44E+03
Fe SWA-L02-1316-B01-A 1 7.39E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.68E+02 1.4E+00 2.0E+00 6.4E+00
3.15E+02 5.6E-01 2.0E+00 6.4E+00 1000 125
8.33E+02 5.1E-01 2.0E+00 6.4E+00
1.83E+03 1.4E+00 2.0E+00 6.4E+00
1.45E+03 8.5E-01 2.0E+00 6.4E+00
1.14E+02 7.0E-01 2.0E+00 6.4E+00
3.08E+02 2.4E+00 2.0E+00 6.4E+00 1000 125
8.02E+02 1.4E+00 2.0E+00 6.4E+00
2.00E+03 5.0E-01 2.0E+00 6.4E+00
1.49E+03 1.3E+00 2.0E+00 6.4E+00
1.25E+02 1.5E+00 2.0E+00 6.4E+00
2.77E+02 4.7E-01 2.0E+00 6.4E+00 1000 125
8.57E+02 5.5E-01 2.0E+00 6.4E+00
1.79E+03 3.0E-01 2.0E+00 6.4E+00
1.44E+03 1.5E+00 2.0E+00 6.4E+00
7.39E+01 1.2E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.47E+03 92% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
1.49E+03 94% VU ICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.41E+03 91% VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1320
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone.
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Pb SWA-L02-1316-T01-A 1 1.83E+01 E 1.83E+01 2.3E+01 6.8E+00 2.2E+01
Pb SWA-L02-1316-T02-A 1 4.18E+01
Pb SWA-L02-1316-T03-A 1 7.19E+01
Pb SWA-L02-1316-T04-A 1 6.43E+01
Pb SWA-L02-1316-T05-A 1 1.61E+02
Pb SWA-L02-1316-T01-B 1 2.48E+01
Pb SWA-L02-1316-T02-B 1 4.26E+01
Pb SWA-L02-1316-T03-B 1 8.27E+01
Pb SWA-L02-1316-T04-B 1 6.60E+01
Pb SWA-L02-1316-T05-B 1 1.79E+02
Pb SWA-L02-1316-T01-C 1 2.78E+01
Pb SWA-L02-1316-T02-C 1 4.58E+01
Pb SWA-L02-1316-T03-C 1 9.08E+01
Pb SWA-L02-1316-T04-C 1 5.75E+01
Pb SWA-L02-1316-T05-C 1 1.54E+02
4.18E+01 1.5E+01 6.8E+00 2.2E+01 10 125
7.19E+01 1.2E+01 6.8E+00 2.2E+01
6.43E+01 3.3E+01 6.8E+00 2.2E+01
1.61E+02 3.6E+00 6.8E+00 2.2E+01
2.48E+01 1.3E+01 6.8E+00 2.2E+01
4.26E+01 2.1E+01 6.8E+00 2.2E+01 10 125
8.27E+01 3.1E+00 6.8E+00 2.2E+01
6.60E+01 7.7E+00 6.8E+00 2.2E+01
1.79E+02 6.3E+00 6.8E+00 2.2E+01
2.78E+01 1.7E+01 6.8E+00 2.2E+01
4.58E+01 8.7E+00 6.8E+00 2.2E+01 10 125
9.08E+01 1.1E+01 6.8E+00 2.2E+01
5.75E+01 9.3E+00 6.8E+00 2.2E+01
1.54E+02 5.9E+00 6.8E+00 2.2E+01
Pb SWA-L02-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 3.4E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.23E+03 95% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.34E+03 104% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.36E+03 105% VU ICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1321
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li SWA-L02-1316-T01-A 1
Li SWA-L02-1316-T02-A 1
Li SWA-L02-1316-T03-A 1
Li SWA-L02-1316-T04-A 1
Li SWA-L02-1316-T05-A 1
Li SWA-L02-1316-T01-B 1
Li SWA-L02-1316-T02-B 1
Li SWA-L02-1316-T03-B 1
Li SWA-L02-1316-T04-B 1
Li SWA-L02-1316-T05-B 1
Li SWA-L02-1316-T01-C 1
Li SWA-L02-1316-T02-C 1
Li SWA-L02-1316-T03-C 1
Li SWA-L02-1316-T04-C 1
Li SWA-L02-1316-T05-C 1
Li SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
4.00E+00 E
7.45E+00
9.12E+00
1.12E+01
1.23E+01
3.60E+00 E
7.38E+00
9.06E+00
1.27E+01
1.07E+01
4.07E+00 E
6.57E+00
1.02E+01
1.29E+01
1.27E+01
9.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.00E+00 8.6E+01 1.9E+00 6.0E+00
7.45E+00 1.1E+01 1.9E+00 6.0E+00 10 125
9.12E+00 4.4E+01 1.9E+00 6.0E+00
1.12E+01 3.8E+01 1.9E+00 6.0E+00
1.23E+01 3.9E+01 1.9E+00 6.0E+00
3.60E+00 1.5E+02 1.9E+00 6.0E+00
7.38E+00 1.6E+01 1.9E+00 6.0E+00 10 125
9.06E+00 1.0E+01 1.9E+00 6.0E+00
1.27E+01 2.7E+01 1.9E+00 6.0E+00
1.07E+01 3.0E+01 1.9E+00 6.0E+00
4.07E+00 2.2E+02 1.9E+00 6.0E+00
6.57E+00 8.3E+01 1.9E+00 6.0E+00 10 125
1.02E+01 3.8E+00 1.9E+00 6.0E+00
1.29E+01 2.3E+01 1.9E+00 6.0E+00
1.27E+01 4.2E+01 1.9E+00 6.0E+00
9.50E-01 4.5E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.10E+03 87% VU ICP-OES 1 1/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
1.17E+03 93% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.19E+03 94% VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1322
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Mn SWA-L02-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 2.3E-01 2.0E+00 6.4E+00
Mn SWA-L02-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 2.2E+00 2.0E+00 6.4E+00 10 125
Mn SWA-L02-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 9.2E-01 2.0E+00 6.4E+00
Mn SWA-L02-1316-T04-A 1 5.69E+00 E
Mn SWA-L02-1316-T05-A 1 4.40E+00 E
5.69E+00 7.7E-01 2.0E+00 6.4E+00
4.40E+00 4.0E-01 2.0E+00 6.4E+00
Mn SWA-L02-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 2.9E+00 2.0E+00 6.4E+00
Mn SWA-L02-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 2.7E+00 2.0E+00 6.4E+00 10 125
Mn SWA-L02-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 6.5E-01 2.0E+00 6.4E+00
Mn SWA-L02-1316-T04-B 1 5.48E+00 E
Mn SWA-L02-1316-T05-B 1 4.29E+00 E
5.48E+00 6.6E-01 2.0E+00 6.4E+00
4.29E+00 1.8E+00 2.0E+00 6.4E+00
Mn SWA-L02-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 3.0E+00 2.0E+00 6.4E+00
Mn SWA-L02-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 2.2E+00 2.0E+00 6.4E+00 10 125
Mn SWA-L02-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 1 .9E+00 2.0E+00 6.4E+00
Mn SWA-L02-1316-T04-C 1 6.90E+00
Mn SWA-L02-1316-T05-C 1 5.42E+00 E
6.90E+00 5.6E-01 2.0E+00 6.4E+00
5.42E+00 2.0E+00 2.0E+00 6.4E+00
Mn SWA-L02-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 2.9E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.18E+03 94% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.28E+03 103% VU ICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.29E+03 103% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1323
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg SWA-L02-1316-T01-A 1
Mg SWA-L02-1316-T02-A 1
Mg SWA-L02-1316-T03-A 1
Mg SWA-L02-1316-T04-A 1
Mg SWA-L02-1316-T05-A 1
Mg SWA-L02-1316-T01-B 1
Mg SWA-L02-1316-T02-B 1
Mg SWA-L02-1316-T03-B 1
Mg SWA-L02-1316-T04-B 1
Mg SWA-L02-1316-T05-B 1
Mg SWA-L02-1316-T01-C 1
Mg SWA-L02-1316-T02-C 1
Mg SWA-L02-1316-T03-C 1
Mg SWA-L02-1316-T04-C 1
Mg SWA-L02-1316-T05-C 1
Mg SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
7.30E+00
1.01E+01
9.09E+00
5.00E-01 U1/2
5.00E-01 U1/2
5.88E+00
1.06E+01
1.06E+01
5.00E-01 U1/2
5.00E-01 U1/2
6.91 E+00
9.49E+00
9.45E+00
2.72E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 2.3E+00 1.0E+00 3.2E+00
5.00E-01 1.6E+00 1.0E+00 3.2E+00 1000 125
7.30E+00 3.3E+00 1.0E+00 3.2E+00
1.01E+01 4.5E+00 1.0E+00 3.2E+00
9.09E+00 1.9E+00 1.0E+00 3.2E+00
5.00E-01 2.2E+01 1.0E+00 3.2E+00
5.00E-01 2.7E+00 1.0E+00 3.2E+00 1000 125
5.88E+00 2.0E+00 1.0E+00 3.2E+00
1.06E+01 1.8E+00 1.0E+00 3.2E+00
1.06E+01 3.0E+00 1.0E+00 3.2E+00
5.00E-01 2.4E+01 1.0E+00 3.2E+00
5.00E-01 3.5E+00 1.0E+00 3.2E+00 1000 125
6.91 E+00 3.1 E+00 1.0E+00 3.2E+00
9.49E+00 2.4E+00 1.0E+00 3.2E+00
9.45E+00 1.8E+00 1.0E+00 3.2E+00
2.72E+01 2.5E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 11/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.13E+03 90% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.17E+03 94% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.16E+03 93% VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1324
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qu
1 1 ug/L
Mo SWA-L02-1316-T01-A 1 2.34E+02
Mo SWA-L02-1316-T02-A 1 3.79E+02
Mo SWA-L02-1316-T03-A 1 7.28E+02
Mo SWA-L02-1316-T04-A 1 1.04E+03
Mo SWA-L02-1316-T05-A 1 1.08E+03
Mo SWA-L02-1316-T01-B 1 2.48E+02
Mo SWA-L02-1316-T02-B 1 4.00E+02
Mo SWA-L02-1316-T03-B 1 6.91 E+02
Mo SWA-L02-1316-T04-B 1 1.07E+03
Mo SWA-L02-1316-T05-B 1 1.14E+03
Mo SWA-L02-1316-T01-C 1 2.41 E+02
Mo SWA-L02-1316-T02-C 1 3.96E+02
Mo SWA-L02-1316-T03-C 1 7.63E+02
Mo SWA-L02-1316-T04-C 1 1.01E+03
Mo SWA-L02-1316-T05-C 1 1.12E+03
Mo SWA-L02-1316-B01-A 1 2.12E+00 E
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.34E+02 7.1E-01 1.2E+00 3.8E+00
3.79E+02 3.3E-01 1.2E+00 3.8E+00 10 125
7.28E+02 7.5E-01 1.2E+00 3.8E+00
1.04E+03 8.5E-01 1.2E+00 3.8E+00
1.08E+03 1.0E+00 1.2E+00 3.8E+00
2.48E+02 1.2E+00 1.2E+00 3.8E+00
4.00E+02 1.6E+00 1.2E+00 3.8E+00 10 125
6.91 E+02 1.2E+00 1.2E+00 3.8E+00
1.07E+03 9.9E-01 1.2E+00 3.8E+00
1.14E+03 1.1E+00 1.2E+00 3.8E+00
2.41 E+02 5.5E-01 1.2E+00 3.8E+00
3.96E+02 7.8E-01 1.2E+00 3.8E+00 10 125
7.63E+02 1.4E-01 1.2E+00 3.8E+00
1.01E+03 1.0E+00 1.2E+00 3.8E+00
1.12E+03 8.4E-01 1.2E+00 3.8E+00
2.12E+00 5.4E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.56E+03 95% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.52E+03 89% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.53E+03 91% VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1325
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni SWA-L02-1316-T01-A 1
Ni SWA-L02-1316-T02-A 1
Ni SWA-L02-1316-T03-A 1
Ni SWA-L02-1316-T04-A 1
Ni SWA-L02-1316-T05-A 1
Ni SWA-L02-1316-T01-B 1
Ni SWA-L02-1316-T02-B 1
Ni SWA-L02-1316-T03-B 1
Ni SWA-L02-1316-T04-B 1
Ni SWA-L02-1316-T05-B 1
Ni SWA-L02-1316-T01-C 1
Ni SWA-L02-1316-T02-C 1
Ni SWA-L02-1316-T03-C 1
Ni SWA-L02-1316-T04-C 1
Ni SWA-L02-1316-T05-C 1
Ni SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
9.00E-01 U1/2
1.87E+00 E
2.40E+00 E
9.46E+00
7.14E+00
9.00E-01 U1/2
3.08E+00 E
2.99E+00 E
1.17E+01
6.60E+00
9.00E-01 U1/2
2.57E+00 E
2.32E+00 E
9.12E+00
4.75E+00 E
9.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.1E+02 1.8E+00 5.7E+00
1.87E+00 1.7E+02 1.8E+00 5.7E+00 10 125
2.40E+00 2.7E+01 1.8E+00 5.7E+00
9.46E+00 3.3E+01 1.8E+00 5.7E+00
7.14E+00 4.2E+01 1.8E+00 5.7E+00
9.00E-01 2.2E+02 1.8E+00 5.7E+00
3.08E+00 1.5E+02 1.8E+00 5.7E+00 10 125
2.99E+00 4.7E+01 1.8E+00 5.7E+00
1.17E+01 2.5E+01 1.8E+00 5.7E+00
6.60E+00 4.0E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
2.57E+00 4.5E+01 1.8E+00 5.7E+00 10 125
2.32E+00 5.0E+01 1.8E+00 5.7E+00
9.12E+00 1.8E+01 1.8E+00 5.7E+00
4.75E+00 3.3E+01 1.8E+00 5.7E+00
9.00E-01 2.8E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.16E+03 93% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 11/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.26E+03 101% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.28E+03 102% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1326
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P SWA-L02-1316-T01-A 1
P SWA-L02-1316-T02-A 1
P SWA-L02-1316-T03-A 1
P SWA-L02-1316-T04-A 1
P SWA-L02-1316-T05-A 1
P SWA-L02-1316-T01-B 1
P SWA-L02-1316-T02-B 1
P SWA-L02-1316-T03-B 1
P SWA-L02-1316-T04-B 1
P SWA-L02-1316-T05-B 1
P SWA-L02-1316-T01-C 1
P SWA-L02-1316-T02-C 1
P SWA-L02-1316-T03-C 1
P SWA-L02-1316-T04-C 1
P SWA-L02-1316-T05-C 1
P SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
7.62E+01
1.47E+02
5.91 E+02
1.71E+03
1.12E+03
6.91E+01
1.53E+02
5.36E+02
1.75E+03
1.19E+03
7.99E+01
1.48E+02
5.75E+02
1.66E+03
1.13E+03
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.62E+01 5.0E+01 3.7E+00 1.2E+01
1.47E+02 7.0E+00 3.7E+00 1.2E+01 1000 125
5.91 E+02 3.1E+00 3.7E+00 1.2E+01
1.71E+03 2.2E+00 3.7E+00 1.2E+01
1.12E+03 2.3E+00 3.7E+00 1.2E+01
6.91E+01 3.5E+01 3.7E+00 1.2E+01
1.53E+02 3.3E+00 3.7E+00 1.2E+01 1000 125
5.36E+02 5.6E+00 3.7E+00 1.2E+01
1.75E+03 8.1E-01 3.7E+00 1.2E+01
1.19E+03 1.5E+00 3.7E+00 1.2E+01
7.99E+01 2.1E+01 3.7E+00 1.2E+01
1.48E+02 2.0E+01 3.7E+00 1 .2E+01 1000 125
5.75E+02 5.5E+00 3.7E+00 1 .2E+01
1.66E+03 2.0E+00 3.7E+00 1 .2E+01
1.13E+03 6.7E-01 3.7E+00 1 .2E+01
1.85E+00 5.4E+01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.32E+03 94% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
1.49E+03 107% VU ICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.42E+03 102% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1327
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K SWA-L02-1316-T01-A 1
K SWA-L02-1316-T02-A 1
K SWA-L02-1316-T03-A 1
K SWA-L02-1316-T04-A 1
K SWA-L02-1316-T05-A 1
K SWA-L02-1316-T01-B 1
K SWA-L02-1316-T02-B 1
K SWA-L02-1316-T03-B 1
K SWA-L02-1316-T04-B 1
K SWA-L02-1316-T05-B 1
K SWA-L02-1316-T01-C 1
K SWA-L02-1316-T02-C 1
K SWA-L02-1316-T03-C 1
K SWA-L02-1316-T04-C 1
K SWA-L02-1316-T05-C 1
K SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
3.69E+05
6.47E+05
1.19E+06
3.48E+06
3.45E+06
4.49E+05
6.51 E+05
1.08E+06
3.57E+06
3.57E+06
4.35E+05
6.59E+05
1.30E+06
3.49E+06
3.44E+06
2.21E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.69E+05 9.2E-01 1.6E+00 5.1E+00
6.47E+05 9.8E-01 1.6E+00 5.1E+00 1000 125
1.19E+06 1.0E+01 1.6E+00 5.1E+00
3.48E+06 5.4E-01 1.6E+00 5.1E+00
3.45E+06 1.1E+00 1.6E+00 5.1E+00
4.49E+05 3.9E-01 1.6E+00 5.1E+00
6.51 E+05 2.6E+00 1.6E+00 5.1E+00 1000 125
1.08E+06 1.7E+00 1.6E+00 5.1E+00
3.57E+06 9.9E-01 1.6E+00 5.1E+00
3.57E+06 2.4E-01 1.6E+00 5.1E+00
4.35E+05 1.0E+00 1.6E+00 5.1E+00
6.59E+05 1.9E-01 1.6E+00 5.1E+00 1000 125
1.30E+06 1.2E+01 1.6E+00 5.1E+00
3.49E+06 7.7E-01 1.6E+00 5.1E+00
3.44E+06 2.2E-01 1.6E+00 5.1E+00
2.21 E+02 8.4E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
6.48E+05 86% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
6.53E+05 91% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
6.60E+05 84% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1328
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se SWA-L02-1316-T01-A 1
Se SWA-L02-1316-T02-A 1
Se SWA-L02-1316-T03-A 1
Se SWA-L02-1316-T04-A 1
Se SWA-L02-1316-T05-A 1
Se SWA-L02-1316-T01-B 1
Se SWA-L02-1316-T02-B 1
Se SWA-L02-1316-T03-B 1
Se SWA-L02-1316-T04-B 1
Se SWA-L02-1316-T05-B 1
Se SWA-L02-1316-T01-C 1
Se SWA-L02-1316-T02-C 1
Se SWA-L02-1316-T03-C 1
Se SWA-L02-1316-T04-C 1
Se SWA-L02-1316-T05-C 1
Se SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.18E+05
2.49E+05
6.01 E+05
1.14E+06
8.03E+05
1.55E+05
2.54E+05
5.54E+05
1.15E+06
8.25E+05
1.51 E+05
2.54E+05
6.06E+05
1.09E+06
7.84E+05
1.57E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+05 1.1E+00 1.5E+01 4.8E+01
2.49E+05 7.5E-01 1.5E+01 4.8E+01 10 125
6.01 E+05 5.5E-01 1.5E+01 4.8E+01
1.14E+06 1.4E+00 1.5E+01 4.8E+01
8.03E+05 6.6E-01 1.5E+01 4.8E+01
1.55E+05 5.1E-01 1.5E+01 4.8E+01
2.54E+05 1.7E+00 1.5E+01 4.8E+01 10 125
5.54E+05 1.8E+00 1.5E+01 4.8E+01
1.15E+06 5.9E-01 1.5E+01 4.8E+01
8.25E+05 5.4E-01 1.5E+01 4.8E+01
1.51 E+05 7.2E-01 1.5E+01 4.8E+01
2.54E+05 3.4E-01 1.5E+01 4.8E+01 10 125
6.06E+05 2.5E-01 1.5E+01 4.8E+01
1.09E+06 6.2E-01 1.5E+01 4.8E+01
7.84E+05 7.0E-01 1.5E+01 4.8E+01
1.57E+01 2.4E+00 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
2.50E+05 88% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
2.55E+05 92% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
2.55E+05 96% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1329
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-L02-1316-T01-A 1
Si SWA-L02-1316-T02-A 1
Si SWA-L02-1316-T03-A 1
Si SWA-L02-1316-T04-A 1
Si SWA-L02-1316-T05-A 1
Si SWA-L02-1316-T01-B 1
Si SWA-L02-1316-T02-B 1
Si SWA-L02-1316-T03-B 1
Si SWA-L02-1316-T04-B 1
Si SWA-L02-1316-T05-B 1
Si SWA-L02-1316-T01-C 1
Si SWA-L02-1316-T02-C 1
Si SWA-L02-1316-T03-C 1
Si SWA-L02-1316-T04-C 1
Si SWA-L02-1316-T05-C 1
Si SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.31 E+04
2.62E+04
3.34E+04
4.54E+04
3.39E+04
2.40E+04
2.72E+04
3.46E+04
4.79E+04
3.74E+04
2.33E+04
2.87E+04
3.43E+04
4.76E+04
3.64E+04
2.40E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.31 E+04 1.0E+00 1.1E+00 3.5E+00
2.62E+04 1.2E+00 1.1E+00 3.5E+00 1000 125
3.34E+04 7.4E-01 1.1E+00 3.5E+00
4.54E+04 2.9E+00 1.1E+00 3.5E+00
3.39E+04 9.7E-01 1.1E+00 3.5E+00
2.40E+04 1.5E+00 1.1E+00 3.5E+00
2.72E+04 2.0E+00 1.1E+00 3.5E+00 1000 125
3.46E+04 1.1E+00 1.1E+00 3.5E+00
4.79E+04 7.0E-01 1.1E+00 3.5E+00
3.74E+04 1.1E+00 1.1E+00 3.5E+00
2.33E+04 7.3E-01 1.1E+00 3.5E+00
2.87E+04 7.0E-01 1.1E+00 3.5E+00 1000 125
3.43E+04 3.6E-01 1.1E+00 3.5E+00
4.76E+04 1.4E+00 1.1E+00 3.5E+00
3.64E+04 1.2E+00 1.1E+00 3.5E+00
2.40E+00 7.5E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
2.73E+04 87% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
2.84E+04 97% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
2.99E+04 90% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1330
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qu
1 1 ug/L
Na SWA-L02-1316-T01-A 1 5.68E+05
Na SWA-L02-1316-T02-A 1 7.99E+05
Na SWA-L02-1316-T03-A 1 1.05E+06
Na SWA-L02-1316-T04-A 1 1.12E+06
Na SWA-L02-1316-T05-A 1 1.10E+06
Na SWA-L02-1316-T01-B 1 6.62E+05
Na SWA-L02-1316-T02-B 1 8.13E+05
Na SWA-L02-1316-T03-B 1 1.02E+06
Na SWA-L02-1316-T04-B 1 1.16E+06
Na SWA-L02-1316-T05-B 1 1.14E+06
Na SWA-L02-1316-T01-C 1 6.40E+05
Na SWA-L02-1316-T02-C 1 8.13E+05
Na SWA-L02-1316-T03-C 1 1.07E+06
Na SWA-L02-1316-T04-C 1 1.13E+06
Na SWA-L02-1316-T05-C 1 1.09E+06
Na SWA-L02-1316-B01-A 1 8.59E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.68E+05 1.0E+00 2.5E+00 8.0E+00
7.99E+05 1.7E-01 2.5E+00 8.0E+00 1000 125
1.05E+06 1.1E+00 2.5E+00 8.0E+00
1.12E+06 5.2E-01 2.5E+00 8.0E+00
1.10E+06 1.3E+00 2.5E+00 8.0E+00
6.62E+05 4.6E-01 2.5E+00 8.0E+00
8.13E+05 7.2E-01 2.5E+00 8.0E+00 1000 125
1.02E+06 1.9E+00 2.5E+00 8.0E+00
1.16E+06 6.3E-01 2.5E+00 8.0E+00
1.14E+06 3.7E-01 2.5E+00 8.0E+00
6.40E+05 6.6E-01 2.5E+00 8.0E+00
8.13E+05 1.4E-01 2.5E+00 8.0E+00 1000 125
1.07E+06 6.4E-01 2.5E+00 8.0E+00
1.13E+06 9.6E-01 2.5E+00 8.0E+00
1.09E+06 3.2E-01 2.5E+00 8.0E+00
8.59E+02 3.5E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
8.01E+05 85% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
8.15E+05 88% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
8.14E+05 92% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1331
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-L02-1316-T01-A 1
SWA-L02-1316-T02-A 1
SWA-L02-1316-T03-A 1
SWA-L02-1316-T04-A 1
SWA-L02-1316-T05-A 1
SWA-L02-1316-T01-B 1
SWA-L02-1316-T02-B 1
SWA-L02-1316-T03-B 1
SWA-L02-1316-T04-B 1
SWA-L02-1316-T05-B 1
SWA-L02-1316-T01-C 1
SWA-L02-1316-T02-C 1
SWA-L02-1316-T03-C 1
SWA-L02-1316-T04-C 1
SWA-L02-1316-T05-C 1
SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
4.13E+02
4.64E+02
5.31 E+02
6.20E+02
5.50E+02
4.83E+02
4.79E+02
5.09E+02
6.44E+02
5.71 E+02
4.46E+02
4.62E+02
5.43E+02
6.04E+02
5.44E+02
1.66E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.13E+02 8.3E-01 1.0E+00 3.2E+00
4.64E+02 1.1E+00 1.0E+00 3.2E+00 1000 125
5.31 E+02 6.4E-01 1.0E+00 3.2E+00
6.20E+02 1.2E+00 1.0E+00 3.2E+00
5.50E+02 7.5E-01 1.0E+00 3.2E+00
4.83E+02 1.8E-01 1.0E+00 3.2E+00
4.79E+02 1.8E+00 1.0E+00 3.2E+00 1000 125
5.09E+02 1.0E+00 1.0E+00 3.2E+00
6.44E+02 9.8E-01 1.0E+00 3.2E+00
5.71 E+02 8.1E-01 1.0E+00 3.2E+00
4.46E+02 1.5E+00 1.0E+00 3.2E+00
4.62E+02 5.8E-01 1.0E+00 3.2E+00 1000 125
5.43E+02 1.0E+00 1.0E+00 3.2E+00
6.04E+02 3.2E-01 1.0E+00 3.2E+00
5.44E+02 1.0E+00 1.0E+00 3.2E+00
1.66E+01 2.5E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.73E+03 101% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
1.86E+03 110% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.89E+03 114% VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1332
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
S SWA-L02-1316-T01-A 1 6.32E+05
S SWA-L02-1316-T02-A 1 1.15E+06
S SWA-L02-1316-T03-A 1 1.89E+06
S SWA-L02-1316-T04-A 1 2.73E+06
S SWA-L02-1316-T05-A 1 2.22E+06
S SWA-L02-1316-T01-B 1 8.74E+05
S SWA-L02-1316-T02-B 1 1.22E+06
S SWA-L02-1316-T03-B 1 1.76E+06
S SWA-L02-1316-T04-B 1 2.76E+06
S SWA-L02-1316-T05-B 1 2.29E+06
S SWA-L02-1316-T01-C 1 7.22E+05
S SWA-L02-1316-T02-C 1 1.18E+06
S SWA-L02-1316-T03-C 1 1.92E+06
S SWA-L02-1316-T04-C 1 2.64E+06
S SWA-L02-1316-T05-C 1 2.06E+06
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.32E+05 1.6E+00 6.8E+00 2.2E+01
1.15E+06 1.2E+00 6.8E+00 2.2E+01 1000 125
1.89E+06 5.3E-01 6.8E+00 2.2E+01
2.73E+06 9.8E-01 6.8E+00 2.2E+01
2.22E+06 8.6E-01 6.8E+00 2.2E+01
8.74E+05 7.5E-01 6.8E+00 2.2E+01
1.22E+06 1.6E+00 6.8E+00 2.2E+01 1000 125
1.76E+06 2.1E+00 6.8E+00 2.2E+01
2.76E+06 7.1E-01 6.8E+00 2.2E+01
2.29E+06 5.3E-01 6.8E+00 2.2E+01
7.22E+05 2.6E+00 6.8E+00 2.2E+01
1.18E+06 5.4E-01 6.8E+00 2.2E+01 1000 125
1.92E+06 2.5E-01 6.8E+00 2.2E+01
2.64E+06 6.6E-01 6.8E+00 2.2E+01
2.06E+06 8.0E-01 6.8E+00 2.2E+01
S SWA-L02-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 4.2E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.15E+06 83% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
1.22E+06 85% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.18E+06 87% VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1333
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L02-1316-T01-A 1 2.30E+00 U1/2 2.30E+00 1 .2E+03 4.6E+00 1.5E+01
Tl SWA-L02-1316-T02-A 1 2.30E+00 U1/2 2.30E+00 2.9E+02 4.6E+00 1.5E+01 10 125
Tl SWA-L02-1316-T03-A 1 2.30E+00 U1/2 2.30E+00 1 JE+02 4.6E+00 1.5E+01
Tl SWA-L02-1316-T04-A 1 2.30E+00 U1/2 2.30E+00 5.0E+01 4.6E+00 1.5E+01
Tl SWA-L02-1316-T05-A 1 2.30E+00 U1/2 2.30E+00 1 .6E+02 4.6E+00 1.5E+01
Tl SWA-L02-1316-T01-B 1 2.30E+00 U1/2 2.30E+00 3.9E+02 4.6E+00 1.5E+01
Tl SWA-L02-1316-T02-B 1 2.30E+00 U1/2 2.30E+00 5.0E+01 4.6E+00 1.5E+01 10 125
Tl SWA-L02-1316-T03-B 1 2.30E+00 U1/2 2.30E+00 2.7E+01 4.6E+00 1.5E+01
Tl SWA-L02-1316-T04-B 1 2.30E+00 U1/2 2.30E+00 4.3E+01 4.6E+00 1.5E+01
Tl SWA-L02-1316-T05-B 1 2.30E+00 U1/2 2.30E+00 1 .8E+02 4.6E+00 1.5E+01
Tl SWA-L02-1316-T01-C 1 2.30E+00 U1/2 2.30E+00 2.5E+02 4.6E+00 1.5E+01
Tl SWA-L02-1316-T02-C 1 2.30E+00 U1/2 2.30E+00 1 .6E+02 4.6E+00 1.5E+01 10 125
Tl SWA-L02-1316-T03-C 1 2.30E+00 U1/2 2.30E+00 1.1E+02 4.6E+00 1.5E+01
Tl SWA-L02-1316-T04-C 1 2.30E+00 U1/2 2.30E+00 2.7E+02 4.6E+00 1.5E+01
Tl SWA-L02-1316-T05-C 1 2.30E+00 U1/2 2.30E+00 1 .3E+02 4.6E+00 1.5E+01
Tl SWA-L02-1316-B01-A 1 2.30E+00 U1/2 2.30E+00 2.9E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.14E+03 91% VUICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
1.13E+03 90% VUICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.16E+03 92% VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1334
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L02-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 8.3E-01 2.0E+00 6.4E+00
Ti SWA-L02-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 1.1E+00 2.0E+00 6.4E+00 10 125
Ti SWA-L02-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 6.4E-01 2.0E+00 6.4E+00
Ti SWA-L02-1316-T04-A 1 1.00E+OOU1/2 1.00E+00 1 .2E+00 2.0E+00 6.4E+00
Ti SWA-L02-1316-T05-A 1 3.29E+00 E
3.29E+00 7.5E-01 2.0E+00 6.4E+00
Ti SWA-L02-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 1.8E-01 2.0E+00 6.4E+00
Ti SWA-L02-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 1 .8E+00 2.0E+00 6.4E+00 10 125
Ti SWA-L02-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 1 .OE+00 2.0E+00 6.4E+00
Ti SWA-L02-1316-T04-B 1 1.00E+OOU1/2 1.00E+00 9.8E-01 2.0E+00 6.4E+00
Ti SWA-L02-1316-T05-B 1 4.89E+00 E
4.89E+00 8.1E-01 2.0E+00 6.4E+00
Ti SWA-L02-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 1 .5E+00 2.0E+00 6.4E+00
Ti SWA-L02-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 5.8E-01 2.0E+00 6.4E+00 10 125
Ti SWA-L02-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 1 .OE+00 2.0E+00 6.4E+00
Ti SWA-L02-1316-T04-C 1 1.00E+OOU1/2 1.00E+00 3.2E-01 2.0E+00 6.4E+00
Ti SWA-L02-1316-T05-C 1 4.54E+00 E
4.54E+00 1. OE+00 2.0E+00 6.4E+00
Ti SWA-L02-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 2.4E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.22E+03 98% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.31E+03 105% VU ICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.34E+03 107% VU ICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1335
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V SWA-L02-1316-T01-A 1
V SWA-L02-1316-T02-A 1
V SWA-L02-1316-T03-A 1
V SWA-L02-1316-T04-A 1
V SWA-L02-1316-T05-A 1
V SWA-L02-1316-T01-B 1
V SWA-L02-1316-T02-B 1
V SWA-L02-1316-T03-B 1
V SWA-L02-1316-T04-B 1
V SWA-L02-1316-T05-B 1
V SWA-L02-1316-T01-C 1
V SWA-L02-1316-T02-C 1
V SWA-L02-1316-T03-C 1
V SWA-L02-1316-T04-C 1
V SWA-L02-1316-T05-C 1
V SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
3.74E+02
7.51 E+02
1.46E+03
2.27E+03
1.86E+03
4.76E+02
7.75E+02
1.36E+03
2.29E+03
1.93E+03
4.59E+02
7.69E+02
1.47E+03
2.18E+03
1.83E+03
1.89E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.74E+02 9.8E-01 1.5E+00 4.8E+00
7.51E+02 1.1E+00 1.5E+00 4.8E+00 10 125
1.46E+03 5.0E-01 1.5E+00 4.8E+00
2.27E+03 9.9E-01 1.5E+00 4.8E+00
1.86E+03 7.6E-01 1.5E+00 4.8E+00
4.76E+02 1.2E+00 1.5E+00 4.8E+00
7.75E+02 1.7E+00 1.5E+00 4.8E+00 10 125
1.36E+03 1.6E+00 1.5E+00 4.8E+00
2.29E+03 7.3E-01 1.5E+00 4.8E+00
1.93E+03 8.5E-01 1.5E+00 4.8E+00
4.59E+02 1.7E-01 1.5E+00 4.8E+00
7.69E+02 6.1E-01 1.5E+00 4.8E+00 10 125
1.47E+03 2.3E-01 1.5E+00 4.8E+00
2.18E+03 7.1E-01 1.5E+00 4.8E+00
1.83E+03 1.5E+00 1.5E+00 4.8E+00
1.89E+00 5.4E+00 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
2.08E+03 107% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316 SWA
2.06E+03 103% VU ICP-OES 11/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
2.09E+03 106% VU ICP-OES 11/29/10 5:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1336
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-L02-1316-T01-A 1
Zn SWA-L02-1316-T02-A 1
Zn SWA-L02-1316-T03-A 1
Zn SWA-L02-1316-T04-A 1
Zn SWA-L02-1316-T05-A 1
Zn SWA-L02-1316-T01-B 1
Zn SWA-L02-1316-T02-B 1
Zn SWA-L02-1316-T03-B 1
Zn SWA-L02-1316-T04-B 1
Zn SWA-L02-1316-T05-B 1
Zn SWA-L02-1316-T01-C 1
Zn SWA-L02-1316-T02-C 1
Zn SWA-L02-1316-T03-C 1
Zn SWA-L02-1316-T04-C 1
Zn SWA-L02-1316-T05-C 1
Zn SWA-L02-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.72E+00 E
4.18E+00
8.73E+00
3.63E+01
1.94E+01
2.59E+00 E
4.69E+00
8.60E+00
3.90E+01
2.00E+01
2.28E+00 E
3.53E+00
1.02E+01
3.36E+01
1.98E+01
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.72E+00 1.5E+01 1.0E+00 3.2E+00
4.18E+00 4.4E+00 1.0E+00 3.2E+00 10 125
8.73E+00 1.9E+00 1.0E+00 3.2E+00
3.63E+01 4.1E+00 1.0E+00 3.2E+00
1.94E+01 4.6E-01 1.0E+00 3.2E+00
2.59E+00 2.1E+01 1.0E+00 3.2E+00
4.69E+00 9.7E+00 1.0E+00 3.2E+00 10 125
8.60E+00 1.3E+01 1.0E+00 3.2E+00
3.90E+01 3.1E+00 1.0E+00 3.2E+00
2.00E+01 3.1E+00 1.0E+00 3.2E+00
2.28E+00 1.7E+01 1.0E+00 3.2E+00
3.53E+00 9.9E+00 1.0E+00 3.2E+00 10 125
1.02E+01 6.0E+00 1.0E+00 3.2E+00
3.36E+01 9.1E-01 1.0E+00 3.2E+00
1.98E+01 3.6E+00 1.0E+00 3.2E+00
5.00E-01 1.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1 1/29/10 5:03 PM EPA Interlab L02 1313-1316 SWA
1.32E+03 105% VU ICP-OES 11/29/10 5:05 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:06 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:08 PM EPA Interlab L02 1313-1316 SWA
VU ICP-OES 1 1/29/10 5:10 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/105:11 PM EPA Interlab L02 1313-1316SWA
1.43E+03 114% VUICP-OES 1 1/29/10 5:13 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:14 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:16 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:18 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:19 PM EPA Interlab L02 1313-1316 SWA
1.36E+03 109% VUICP-OES 11/29/105:21 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 1 1/29/10 5:23 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:24 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:26 PM EPA Interlab L02 1313-1316 SWA
VUICP-OES 11/29/10 5:02 PM EPA Interlab L02 1313-1316 SWA
                                                                                                                                                                         1-1337
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al SWA-L04-1316-T01-A 1 3.65E+04
Al SWA-L04-1316-T02-A 1 5.72E+04
Al SWA-L04-1316-T03-A 1 8.32E+04
Al SWA-L04-1316-T04-A 1 1.66E+05
Al SWA-L04-1316-T01-B 1 4.05E+04
Al SWA-L04-1316-T02-B 1 5.89E+04
Al SWA-L04-1316-T03-B 1 9.57E+04
Al SWA-L04-1316-T04-B 1 1.62E+05
Al SWA-L04-1316-T01-C 1 3.69E+04
Al SWA-L04-1316-T02-C 1 5.89E+04
Al SWA-L04-1316-T03-C 1 7.97E+04
Al SWA-L04-1316-T04-C 1 1.64E+05
Al SWA-L04-1316-B01-A 1 5.00E-01 U1/2
Al SWA-L04-1316-B02-A 1 5.00E-01 U1/2
Al SWA-L04-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.65E+04 2.6E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
5.72E+04 1.2E+00 1 .OE+00 3.2E+00 1000 100 5.80E+04 85% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
8.32E+04 9.3E-01 1 .OE+00 3.2E+00
1.66E+05 8.2E-01 1 .OE+00 3.2E+00
4.05E+04 5.8E-01 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
5.89E+04 1.0E+00 1 .OE+00 3.2E+00 1000 100 5.98E+04 92% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
9.57E+04 3.4E-01 1 .OE+00 3.2E+00
1.62E+05 5.2E-01 1 .OE+00 3.2E+00
3.69E+04 6.7E-01 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
5.89E+04 7.8E-01 1 .OE+00 3.2E+00 1000 100 5.99E+04 96% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
7.97E+04 2.2E+01 1 .OE+00 3.2E+00
1.64E+05 4.1E-01 1 .OE+00 3.2E+00
5.00E-01 9.8E+00 1 .OE+00 3.2E+00
5.00E-01 6.9E+00 1 .OE+00 3.2E+00
5.00E-01 3.0E+01 1. OE+00 3.2E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                                 1-1338
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb SWA-L04-1316-T01-A 1 3.79E+03
Sb SWA-L04-1316-T02-A 1 1.02E+03
Sb SWA-L04-1316-T03-A 1 9.29E+03
Sb SWA-L04-1316-T04-A 1 7.65E+03
Sb SWA-L04-1316-T01-B 1 3.28E+03
Sb SWA-L04-1316-T02-B 1 9.16E+02
Sb SWA-L04-1316-T03-B 1 9.51E+03
Sb SWA-L04-1316-T04-B 1 8.08E+03
Sb SWA-L04-1316-T01-C 1 3.47E+03
Sb SWA-L04-1316-T02-C 1 5.65E+02
Sb SWA-L04-1316-T03-C 1 9.13E+03
Sb SWA-L04-1316-T04-C 1 8.01E+03
Sb SWA-L04-1316-B01-A 1 3.75E+00 U1/2
Sb SWA-L04-1316-B02-A 1 3.75E+00 U1/2
Sb SWA-L04-1316-B03-A 1 9.02E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.79E+03 9.4E-01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.02E+03 2.0E+00 7.5E+00 2.4E+01 10 100 2.13E+03 110% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
9.29E+03 4.4E-01 7.5E+00 2.4E+01
7.65E+03 8.0E-01 7.5E+00 2.4E+01
3.28E+03 7.6E-01 7.5E+00 2.4E+01
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
9.16E+02 3.6E+00 7.5E+00 2.4E+01 10 100 2.03E+03 112% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
9.51 E+03 5.2E-01 7.5E+00 2.4E+01
8.08E+03 3.3E-01 7.5E+00 2.4E+01
3.47E+03 8.0E-01 7.5E+00 2.4E+01
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
5.65E+02 4.6E+00 7.5E+00 2.4E+01 10 100 1.71E+03 114% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
9.13E+03 1.5E+00 7.5E+00 2.4E+01
8.01 E+03 1.7E+00 7.5E+00 2.4E+01
3.75E+00 2.1E+01 7.5E+00 2.4E+01
3.75E+00 6.1E+01 7.5E+00 2.4E+01
9.02E+00 7.0E+01 7.5E+00 2.4E+01
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1339
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
ug/L
As SWA-L04-1316-T01-A 1 4.62E+03
As SWA-L04-1316-T02-A 1 1.33E+04
As SWA-L04-1316-T03-A 1 4.50E+04
As SWA-L04-1316-T04-A 1 1.01E+05
As SWA-L04-1316-T01-B 1 5.89E+03
As SWA-L04-1316-T02-B 1 1.40E+04
As SWA-L04-1316-T03-B 1 4.53E+04
As SWA-L04-1316-T04-B 1 1.08E+05
As SWA-L04-1316-T01-C 1 5.00E+03
As SWA-L04-1316-T02-C 1 1.35E+04
As SWA-L04-1316-T03-C 1 3.86E+04
As SWA-L04-1316-T04-C 1 1.02E+05
As SWA-L04-1316-B01-A 1 5.50E+00 U1/2
As SWA-L04-1316-B02-A 1 5.50E+00 U1/2
As SWA-L04-1316-B03-A 1 5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.62E+03 2.0E-01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.33E+04 1.9E+00 1.1E+01 3.5E+01 10 100 1 .42E+04 95% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
4.50E+04 5.0E-01 1.1E+01 3.5E+01
1.01E+05 1.7E+00 1.1E+01 3.5E+01
5.89E+03 7.1E-01 1.1E+01 3.5E+01
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.40E+04 1.6E+00 1.1E+01 3.5E+01 10 100 1 .49E+04 87% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
4.53E+04 6.3E-01 1.1E+01 3.5E+01
1.08E+05 2.2E-01 1.1E+01 3.5E+01
5.00E+03 5.2E-01 1.1E+01 3.5E+01
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.35E+04 1.8E+00 1.1E+01 3.5E+01 10 100 1 .45E+04 97% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
3.86E+04 1.6E+00 1.1E+01 3.5E+01
1.02E+05 1.1E+00 1.1E+01 3.5E+01
5.50E+00 1.5E+02 7.5E+00 2.4E+01
5.50E+00 1.7E+02 7.5E+00 2.4E+01
5.50E+00 7.5E+01 7.5E+00 2.4E+01
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1340
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B SWA-L04-1316-T01-A 1 1.10E+03
B SWA-L04-1316-T02-A 1 1.79E+03
B SWA-L04-1316-T03-A 1 2.35E+03
B SWA-L04-1316-T04-A 1 1.20E+03
B SWA-L04-1316-T01-B 1 1.34E+03
B SWA-L04-1316-T02-B 1 2.01E+03
B SWA-L04-1316-T03-B 1 2.63E+03
B SWA-L04-1316-T04-B 1 1.84E+03
B SWA-L04-1316-T01-C 1 1.19E+03
B SWA-L04-1316-T02-C 1 1.97E+03
B SWA-L04-1316-T03-C 1 2.03E+03
B SWA-L04-1316-T04-C 1 1.71E+03
B SWA-L04-1316-B01-A 1 2.04E+01
B SWA-L04-1316-B02-A 1 1.65E+01
B SWA-L04-1316-B03-A 1 1.41E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+03 1.5E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.79E+03 1.2E+00 1 .OE+00 3.2E+00 1000 100 2.79E+03 100% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
2.35E+03 8.2E-01 1 .OE+00 3.2E+00
1.20E+03 6.9E-01 1 .OE+00 3.2E+00
1.34E+03 9.8E-01 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
2.01E+03 1.7E+00 1 .OE+00 3.2E+00 1000 100 3.04E+03 104% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
2.63E+03 3.8E-01 1 .OE+00 3.2E+00
1.84E+03 4.4E-01 1 .OE+00 3.2E+00
1.19E+03 5.6E-01 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.97E+03 4.1E-01 1 .OE+00 3.2E+00 1000 100 2.93E+03 96% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
2.03E+03 2.8E+01 1 .OE+00 3.2E+00
1.71E+03 2.9E-01 1 .OE+00 3.2E+00
2.04E+01 6.0E+00 1 .OE+00 3.2E+00
1.65E+01 4.5E+00 1 .OE+00 3.2E+00
1.41E+01 2.2E+00 1. OE+00 3.2E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1341
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba SWA-L04-1316-T01-A 1 1.87E+02
Ba SWA-L04-1316-T02-A 1 1.65E+02
Ba SWA-L04-1316-T03-A 1 5.08E+00
Ba SWA-L04-1316-T04-A 1 8.65E+01
Ba SWA-L04-1316-T01-B 1 1.52E+02
Ba SWA-L04-1316-T02-B 1 1.57E+02
Ba SWA-L04-1316-T03-B 1 5.47E+01
Ba SWA-L04-1316-T04-B 1 3.76E+01
Ba SWA-L04-1316-T01-C 1 1.64E+02
Ba SWA-L04-1316-T02-C 1 1.71E+02
Ba SWA-L04-1316-T03-C 1 4.92E+00
Ba SWA-L04-1316-T04-C 1 7.48E+01
Ba SWA-L04-1316-B01-A 1 5.00E-01 U1/2
Ba SWA-L04-1316-B02-A 1 5.00E-01 U1/2
Ba SWA-L04-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.87E+02 2.3E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.65E+02 4.8E-01 1 .OE+00 3.2E+00 10 100 1 .34E+03 117% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
5.08E+00 3.3E+00 1 .OE+00 3.2E+00
8.65E+01 7.3E+00 1 .OE+00 3.2E+00
1.52E+02 8.6E-01 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.57E+02 5.2E-01 1 .OE+00 3.2E+00 10 100 1 .36E+03 120% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
5.47E+01 1.8E+00 1 .OE+00 3.2E+00
3.76E+01 2.4E+00 1 .OE+00 3.2E+00
1.64E+02 6.7E-01 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.71E+02 7.3E-01 1 .OE+00 3.2E+00 10 100 1.34E+03 117% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
4.92E+00 2.4E+01 1. OE+00 3.2E+00
7.48E+01 6.7E+00 1. OE+00 3.2E+00
5.00E-01 1.0E+02 1. OE+00 3.2E+00
5.00E-01 4.8E+01 1. OE+00 3.2E+00
5.00E-01 2.0E+01 1. OE+00 3.2E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1342
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be SWA-L04-1316-T01-A 1 9.50E-01 U1/2
Be SWA-L04-1316-T02-A 1 9.50E-01 U1/2
Be SWA-L04-1316-T03-A 1 9.50E-01 U1/2
Be SWA-L04-1316-T04-A 1 9.50E-01 U1/2
Be SWA-L04-1316-T01-B 1 9.50E-01 U1/2
Be SWA-L04-1316-T02-B 1 9.50E-01 U1/2
Be SWA-L04-1316-T03-B 1 9.50E-01 U1/2
Be SWA-L04-1316-T04-B 1 9.50E-01 U1/2
Be SWA-L04-1316-T01-C 1 9.50E-01 U1/2
Be SWA-L04-1316-T02-C 1 9.50E-01 U1/2
Be SWA-L04-1316-T03-C 1 9.50E-01 U1/2
Be SWA-L04-1316-T04-C 1 9.50E-01 U1/2
Be SWA-L04-1316-B01-A 1 9.50E-01 U1/2
Be SWA-L04-1316-B02-A 1 9.50E-01 U1/2
Be SWA-L04-1316-B03-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.2E+02 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
9.50E-01 1.3E+02 1 .9E+00 6.0E+00 10 100 1.15E+03 114% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
9.50E-01 3.6E+01 1 .9E+00 6.0E+00
9.50E-01 7.7E+01 1 .9E+00 6.0E+00
9.50E-01 9.0E+01 1 .9E+00 6.0E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
9.50E-01 7.2E+01 1 .9E+00 6.0E+00 10 100 1.18E+03 118% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
9.50E-01 3.2E+02 1 .9E+00 6.0E+00
9.50E-01 8.3E+01 1 .9E+00 6.0E+00
9.50E-01 6.7E+02 1.9E+00 6.0E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
9.50E-01 1.5E+02 1.9E+00 6.0E+00 10 100 1.10E+03 110% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
9.50E-01 9.4E+01 1.9E+00 6.0E+00
9.50E-01 5.6E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 8.0E+00 1.9E+00 6.0E+00
9.50E-01 1.0E+02 1.9E+00 6.0E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1343
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cd Sample Dilution Cone. Qualifier Revi
ug/L
Cd SWA-L04-1316-T01-A 1 1.10E+OOU1/2
Cd SWA-L04-1316-T02-A 1 1.10E+OOU1/2
Cd SWA-L04-1316-T03-A 1 1.10E+OOU1/2
Cd SWA-L04-1316-T04-A 1 1.10E+OOU1/2
Cd SWA-L04-1316-T01-B 1 1.10E+OOU1/2
Cd SWA-L04-1316-T02-B 1 1.10E+OOU1/2
Cd SWA-L04-1316-T03-B 1 1.10E+OOU1/2
Cd SWA-L04-1316-T04-B 1 1.10E+OOU1/2
Cd SWA-L04-1316-T01-C 1 1.10E+OOU1/2
Cd SWA-L04-1316-T02-C 1 1.10E+OOU1/2
Cd SWA-L04-1316-T03-C 1 1.10E+OOU1/2
Cd SWA-L04-1316-T04-C 1 1.10E+OOU1/2
Cd SWA-L04-1316-B01-A 1 1.10E+OOU1/2
Cd SWA-L04-1316-B02-A 1 1.10E+OOU1/2
Cd SWA-L04-1316-B03-A 1 1.10E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.4E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.10E+00 4.3E+02 2.2E+00 7.0E+00 10 100 1.19E+03 119% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
1.10E+00 5.0E+02 2.2E+00 7.0E+00
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 9.4E+01 2.2E+00 7.0E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.10E+00 1.0E+02 2.2E+00 7.0E+00 10 100 1.12E+03 112% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
1.10E+00 2.0E+02 2.2E+00 7.0E+00
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 1.0E+02 2.2E+00 7.0E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.10E+00 2.7E+02 2.2E+00 7.0E+00 10 100 1.15E+03 114% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
1.10E+00 1.4E+02 2.2E+00 7.0E+00
1.10E+00 2.5E+01 2.2E+00 7.0E+00
1.10E+00 3.6E+02 2.2E+00 7.0E+00
1.10E+00 5.7E+02 2.2E+00 7.0E+00
1.10E+00 1.9E+02 2.2E+00 7.0E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1344
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca SWA-L04-1316-T01-A 1 1.42E+04
Ca SWA-L04-1316-T02-A 1 1.03E+04
Ca SWA-L04-1316-T03-A 1 2.22E+03
Ca SWA-L04-1316-T04-A 1 4.11E+03
Ca SWA-L04-1316-T01-B 1 1.26E+04
Ca SWA-L04-1316-T02-B 1 9.45E+03
Ca SWA-L04-1316-T03-B 1 4.05E+03
Ca SWA-L04-1316-T04-B 1 3.01 E+03
Ca SWA-L04-1316-T01-C 1 1.35E+04
Ca SWA-L04-1316-T02-C 1 9.84E+03
Ca SWA-L04-1316-T03-C 1 2.20E+03
Ca SWA-L04-1316-T04-C 1 3.99E+03
Ca SWA-L04-1316-B01-A 1 3.82E+01
Ca SWA-L04-1316-B02-A 1 3.32E+01
Ca SWA-L04-1316-B03-A 1 3.42E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.42E+04 9.3E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.03E+04 3.3E-01 2.6E+00 8.3E+00 1000 100 1.14E+04 104% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
2.22E+03 1.6E+00 2.6E+00 8.3E+00
4. 11 E+03 2.8E+00 2.6E+00 8.3E+00
1.26E+04 8.0E-01 2.6E+00 8.3E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
9.45E+03 3.0E-01 2.6E+00 8.3E+00 1000 100 1.06E+04 115% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
4.05E+03 8.8E-01 2.6E+00 8.3E+00
3.01 E+03 3.1E+00 2.6E+00 8.3E+00
1.35E+04 1.0E+00 2.6E+00 8.3E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
9.84E+03 7.8E-01 2.6E+00 8.3E+00 1000 100 1.08E+04 92% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
2.20E+03 2.0E+01 2.6E+00 8.3E+00
3.99E+03 2.7E+00 2.6E+00 8.3E+00
3.82E+01 3.0E+01 2.6E+00 8.3E+00
3.32E+01 1.8E+01 2.6E+00 8.3E+00
3.42E+01 1.5E+01 2.6E+00 8.3E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1345
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qualifier
ug/L
Cr SWA-L04-1316-T01-A 1 1.18E+03
Cr SWA-L04-1316-T02-A 1 1.82E+03
Cr SWA-L04-1316-T03-A 1 1.35E+03
Cr SWA-L04-1316-T04-A 1 3.19E+03
Cr SWA-L04-1316-T01-B 1 1.45E+03
Cr SWA-L04-1316-T02-B 1 1.99E+03
Cr SWA-L04-1316-T03-B 1 2.07E+03
Cr SWA-L04-1316-T04-B 1 2.21E+03
Cr SWA-L04-1316-T01-C 1 1.31E+03
Cr SWA-L04-1316-T02-C 1 1.91E+03
Cr SWA-L04-1316-T03-C 1 1.38E+03
Cr SWA-L04-1316-T04-C 1 2.70E+03
Cr SWA-L04-1316-B01-A 1 6.00E-01 U1/2
Cr SWA-L04-1316-B01-A 1 6.00E-01 U1/2
Cr SWA-L04-1316-B01-A 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+03 1.6E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.82E+03 7.8E-01 1 .2E+00 3.8E+00 10 100 2.77E+03 95% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
1.35E+03 5.9E-01 1.2E+00 3.8E+00
3.19E+03 1.9E+00 1.2E+00 3.8E+00
1.45E+03 2.6E-01 1.2E+00 3.8E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.99E+03 1.3E+00 1.2E+00 3.8E+00 10 100 3.00E+03 102% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
2.07E+03 7.3E-02 1.2E+00 3.8E+00
2.21 E+03 1.5E+00 1.2E+00 3.8E+00
1.31E+03 9.2E-01 1.2E+00 3.8E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.91E+03 1.3E+00 1.2E+00 3.8E+00 10 100 2.81E+03 89% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
1.38E+03 3.4E+00 1.2E+00 3.8E+00
2.70E+03 1.5E+00 1.2E+00 3.8E+00
6.00E-01 1.1 E+03 1.2E+00 3.8E+00
6.00E-01 5.0E+01 1.2E+00 3.8E+00
6.00E-01 1.2E+02 1.2E+00 3.8E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1346
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Co Sample Dilution Cone. Qualifier Revi
ug/L
Co SWA-L04-1316-T01-A 1 9.00E-01 U1/2
Co SWA-L04-1316-T02-A 1 9.00E-01 U1/2
Co SWA-L04-1316-T03-A 1 3.13E+00 E
Co SWA-L04-1316-T04-A 1 6.53E+00
Co SWA-L04-1316-T01-B 1 9.00E-01 U1/2
Co SWA-L04-1316-T02-B 1 9.00E-01 U1/2
Co SWA-L04-1316-T03-B 1 3.62E+00 E
Co SWA-L04-1316-T04-B 1 8.95E+00
Co SWA-L04-1316-T01-C 1 9.00E-01 U1/2
Co SWA-L04-1316-T02-C 1 9.00E-01 U1/2
Co SWA-L04-1316-T03-C 1 2.18E+00 E
Co SWA-L04-1316-T04-C 1 7.14E+00
Co SWA-L04-1316-B01-A 1 9.00E-01 U1/2
Co SWA-L04-1316-B02-A 1 9.00E-01 U1/2
Co SWA-L04-1316-B03-A 1 9.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.6E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
9.00E-01 2.1E+01 1.8E+00 5.7E+00 10 100 1.13E+03 112% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
3.13E+00 5.7E+01 1.8E+00 5.7E+00
6.53E+00 7.6E+00 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
9.00E-01 5.4E+01 1.8E+00 5.7E+00 10 100 1.16E+03 116% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
3.62E+00 3.0E+01 1.8E+00 5.7E+00
8.95E+00 3.0E+00 1.8E+00 5.7E+00
9.00E-01 6.3E+01 1.8E+00 5.7E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
9.00E-01 9.4E+01 1.8E+00 5.7E+00 10 100 1.08E+03 108% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
2.18E+00 4.2E+01 1.8E+00 5.7E+00
7.14E+00 4.1E+00 1.8E+00 5.7E+00
9.00E-01 5.6E+01 1.8E+00 5.7E+00
9.00E-01 2.8E+01 1.8E+00 5.7E+00
9.00E-01 8.2E+01 1.8E+00 5.7E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1347
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu SWA-L04-1316-T01-A 1 1.85E+OOU1/2
Cu SWA-L04-1316-T02-A 1 1.85E+OOU1/2
Cu SWA-L04-1316-T03-A 1 1.48E+01
Cu SWA-L04-1316-T04-A 1 4.27E+01
Cu SWA-L04-1316-T01-B 1 1.85E+OOU1/2
Cu SWA-L04-1316-T02-B 1 1.85E+OOU1/2
Cu SWA-L04-1316-T03-B 1 1.86E+01
Cu SWA-L04-1316-T04-B 1 3.40E+01
Cu SWA-L04-1316-T01-C 1 1.85E+OOU1/2
Cu SWA-L04-1316-T02-C 1 1.85E+OOU1/2
Cu SWA-L04-1316-T03-C 1 9.85E+00 E
Cu SWA-L04-1316-T04-C 1 3.12E+01
Cu SWA-L04-1316-B01-A 1 1.85E+OOU1/2
Cu SWA-L04-1316-B02-A 1 1.85E+OOU1/2
Cu SWA-L04-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 6.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.85E+00 4.0E+01 3.7E+00 1.2E+01 10 100 1.12E+03 112% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
1.48E+01 3.6E+01 3.7E+00 1.2E+01
4.27E+01 4.0E+00 3.7E+00 1.2E+01
1.85E+00 7.9E+01 3.7E+00 1.2E+01
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.85E+00 9.4E+01 3.7E+00 1.2E+01 10 100 1.15E+03 114% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
1.86E+01 1.1E+01 3.7E+00 1.2E+01
3.40E+01 9.9E+00 3.7E+00 1.2E+01
1.85E+00 1.1E+02 3.7E+00 1.2E+01
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.85E+00 1.1E+02 3.7E+00 1.2E+01 10 100 1.07E+03 107% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
9.85E+00 3.3E+01 3.7E+00 1.2E+01
3.12E+01 7.1E+00 3.7E+00 1.2E+01
1.85E+00 2.2E+02 3.7E+00 1.2E+01
1.85E+00 1.6E+02 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1348
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. Qualifier
ug/L
Fe SWA-L04-1316-T01-A 1 7.64E+01
Fe SWA-L04-1316-T02-A 1 1.73E+02
Fe SWA-L04-1316-T03-A 1 3.35E+02
Fe SWA-L04-1316-T04-A 1 1.18E+03
Fe SWA-L04-1316-T01-B 1 1.04E+02
Fe SWA-L04-1316-T02-B 1 1.82E+02
Fe SWA-L04-1316-T03-B 1 3.84E+02
Fe SWA-L04-1316-T04-B 1 1.14E+03
Fe SWA-L04-1316-T01-C 1 8.64E+01
Fe SWA-L04-1316-T02-C 1 1.73E+02
Fe SWA-L04-1316-T03-C 1 2.64E+02
Fe SWA-L04-1316-T04-C 1 1.15E+03
Fe SWA-L04-1316-B01-A 1 1.00E+OOU1/2
Fe SWA-L04-1316-B02-A 1 1.00E+OOU1/2
Fe SWA-L04-1316-B03-A 1 2.03E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.64E+01 1.3E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.73E+02 9.0E-01 2.0E+00 6.4E+00 1000 100 1.31E+03 114% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
3.35E+02 5.1E-01 2.0E+00 6.4E+00
1.18E+03 5.7E-01 2.0E+00 6.4E+00
1.04E+02 1.6E+00 2.0E+00 6.4E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.82E+02 5.3E-01 2.0E+00 6.4E+00 1000 100 1 .35E+03 117% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
3.84E+02 4.3E-01 2.0E+00 6.4E+00
1.14E+03 8.7E-01 2.0E+00 6.4E+00
8.64E+01 9.1E-01 2.0E+00 6.4E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.73E+02 4.6E-01 2.0E+00 6.4E+00 1000 100 1 .27E+03 110% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
2.64E+02 2.4E+00 2.0E+00 6.4E+00
1.15E+03 1.2E+00 2.0E+00 6.4E+00
1.00E+00 4.2E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
2.03E+00 1.3E+01 2.0E+00 6.4E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1349
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb SWA-L04-1316-T01-A 1 1.63E+01 E
Pb SWA-L04-1316-T02-A 1 4.02E+01
Pb SWA-L04-1316-T03-A 1 1.28E+01 E
Pb SWA-L04-1316-T04-A 1 1.34E+02
Pb SWA-L04-1316-T01-B 1 1.36E+01 E
Pb SWA-L04-1316-T02-B 1 3.26E+01
Pb SWA-L04-1316-T03-B 1 3.26E+01
Pb SWA-L04-1316-T04-B 1 1.06E+02
Pb SWA-L04-1316-T01-C 1 1.71E+01 E
Pb SWA-L04-1316-T02-C 1 3.42E+01
Pb SWA-L04-1316-T03-C 1 1.23E+01 E
Pb SWA-L04-1316-T04-C 1 1.37E+02
Pb SWA-L04-1316-B01-A 1 3.40E+00 U1/2
Pb SWA-L04-1316-B02-A 1 3.40E+00 U1/2
Pb SWA-L04-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.63E+01 2.9E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
4.02E+01 1.2E+01 6.8E+00 2.2E+01 10 100 1.15E+03 1 11% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
1.28E+01 1.9E+01 6.8E+00 2.2E+01
1.34E+02 5.1E+00 6.8E+00 2.2E+01
1.36E+01 9.8E+00 6.8E+00 2.2E+01
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
3.26E+01 3.4E+00 6.8E+00 2.2E+01 10 100 1.18E+03 1 15% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
3.26E+01 1.5E+01 6.8E+00 2.2E+01
1.06E+02 1.8E+00 6.8E+00 2.2E+01
1.71E+01 3.7E+01 6.8E+00 2.2E+01
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
3.42E+01 5.6E+00 6.8E+00 2.2E+01 10 100 1.11E+03 107% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
1.23E+01 2.6E+01 6.8E+00 2.2E+01
1.37E+02 2.3E+00 6.8E+00 2.2E+01
3.40E+00 6.5E+01 6.8E+00 2.2E+01
3.40E+00 5.1E+01 6.8E+00 2.2E+01
3.40E+00 1.9E+01 6.8E+00 2.2E+01
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1350
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li SWA-L04-1316-T01-A 1 2.66E+00 E
Li SWA-L04-1316-T02-A 1 6.26E+00
Li SWA-L04-1316-T03-A 1 9.17E+00
Li SWA-L04-1316-T04-A 1 9.35E+00
Li SWA-L04-1316-T01-B 1 2.39E+00 E
Li SWA-L04-1316-T02-B 1 5.44E+00 E
Li SWA-L04-1316-T03-B 1 8.29E+00
Li SWA-L04-1316-T04-B 1 9.26E+00
Li SWA-L04-1316-T01-C 1 2.75E+00 E
Li SWA-L04-1316-T02-C 1 5.92E+00 E
Li SWA-L04-1316-T03-C 1 8.87E+00
Li SWA-L04-1316-T04-C 1 9.34E+00
Li SWA-L04-1316-B01-A 1 9.50E-01 U1/2
Li SWA-L04-1316-B02-A 1 9.50E-01 U1/2
Li SWA-L04-1316-B03-A 1 9.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.66E+00 3.4E+01 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 2:39 PM EPA Interlab 1316 SWA Reruns
6.26E+00 3.8E+01 1 .9E+00 6.0E+00 10 100 9.14E+02 91% VU ICP-OES 5/23/11 2:41 PM EPA Interlab 1316 SWA Reruns
9.17E+00 9.5E-01 1.9E+00 6.0E+00
9.35E+00 1.8E+01 1.9E+00 6.0E+00
2.39E+00 1.5E+01 1.9E+00 6.0E+00
VU ICP-OES 5/23/11 2:43 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:46 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:48 PM EPA Interlab 1316 SWA Reruns
5.44E+00 1.8E+01 1.9E+00 6.0E+00 10 100 9.32E+02 93% VU ICP-OES 5/23/11 2:50 PM EPA Interlab 1316 SWA Reruns
8.29E+00 1.1E+01 1.9E+00 6.0E+00
9.26E+00 9.7E+00 1.9E+00 6.0E+00
2.75E+00 1.3E+01 1.9E+00 6.0E+00
VU ICP-OES 5/23/11 2:52 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:55 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 2:57 PM EPA Interlab 1316 SWA Reruns
5.92E+00 3.0E+01 1.9E+00 6.0E+00 10 100 9.00E+02 89% VU ICP-OES 5/23/11 2:59 PM EPA Interlab 1316 SWA Reruns
8.87E+00 5.3E+01 1.9E+00 6.0E+00
9.34E+00 1.8E+01 1.9E+00 6.0E+00
9.50E-01 5.9E+00 1.9E+00 6.0E+00
9.50E-01 1.9E+01 1.9E+00 6.0E+00
9.50E-01 8.2E+00 1.9E+00 6.0E+00
VU ICP-OES 5/23/11 3:01 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:03 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1351
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn SWA-L04-1316-T01-A 1 1.00E+OOU1/2
Mn SWA-L04-1316-T02-A 1 1.00E+OOU1/2
Mn SWA-L04-1316-T03-A 1 1.00E+OOU1/2
Mn SWA-L04-1316-T04-A 1 2.75E+00 E
Mn SWA-L04-1316-T01-B 1 1.00E+OOU1/2
Mn SWA-L04-1316-T02-B 1 1.00E+OOU1/2
Mn SWA-L04-1316-T03-B 1 1.00E+OOU1/2
Mn SWA-L04-1316-T04-B 1 1.00E+OOU1/2
Mn SWA-L04-1316-T01-C 1 1.00E+OOU1/2
Mn SWA-L04-1316-T02-C 1 1.00E+OOU1/2
Mn SWA-L04-1316-T03-C 1 1.00E+OOU1/2
Mn SWA-L04-1316-T04-C 1 2.53E+00 E
Mn SWA-L04-1316-B01-A 1 1.00E+OOU1/2
Mn SWA-L04-1316-B02-A 1 1.00E+OOU1/2
Mn SWA-L04-1316-B03-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 8.2E+00 2.0E+00 6.4E+00 10 100
1.00E+00 2.6E+01 2.0E+00 6.4E+00
2.75E+00 2.2E+00 2.0E+00 6.4E+00
1.00E+00 5.1E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00 10 100
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+00 2.0E+00 6.4E+00
1.00E+00 5.1E+00 2.0E+00 6.4E+00 10 100
1.00E+00 6.9E+01 2.0E+00 6.4E+00
2.53E+00 4.1E+00 2.0E+00 6.4E+00
1.00E+00 7.0E+01 2.0E+00 6.4E+00
1.00E+00 5.0E+03 2.0E+00 6.4E+00
1.00E+00 1.7E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.15E+03 115% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.19E+03 119% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.09E+03 109% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1352
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg SWA-L04-1316-T01-A 1 6.46E+00
Mg SWA-L04-1316-T02-A 1 8.47E+00
Mg SWA-L04-1316-T03-A 1 1.12E+01
Mg SWA-L04-1316-T04-A 1 1.17E+01
Mg SWA-L04-1316-T01-B 1 1.69E+01
Mg SWA-L04-1316-T02-B 1 1.81E+OOE
Mg SWA-L04-1316-T03-B 1 5.96E+00
Mg SWA-L04-1316-T04-B 1 6.84E+00
Mg SWA-L04-1316-T01-C 1 1.49E+01
Mg SWA-L04-1316-T02-C 1 1.06E+01
Mg SWA-L04-1316-T03-C 1 4.52E+00
Mg SWA-L04-1316-T04-C 1 1.24E+01
Mg SWA-L04-1316-B01-A 1 5.00E-01 U1/2
Mg SWA-L04-1316-B02-A 1 4.43E+00
Mg SWA-L04-1316-B03-A 1 1.43E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.46E+00 5.7E+01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
8.47E+00 6.9E+01 1 .OE+00 3.2E+00 1000 100 1.13E+03 113% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
1.12E+01 4.9E+01 1. OE+00 3.2E+00
1.17E+01 6.3E+01 1. OE+00 3.2E+00
1.69E+01 3.2E+01 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.81E+00 4.6E+02 1 .OE+00 3.2E+00 1000 100 1.16E+03 116% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
5.96E+00 1.4E+02 1 .OE+00 3.2E+00
6.84E+00 2.0E+02 1 .OE+00 3.2E+00
1.49E+01 8.4E+01 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.06E+01 4.9E+01 1. OE+00 3.2E+00 1000 100 1.06E+03 105% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
4.52E+00 2.7E+02 1. OE+00 3.2E+00
1.24E+01 2.8E+01 1. OE+00 3.2E+00
5.00E-01 1.3E+02 1. OE+00 3.2E+00
4.43E+00 1.5E+02 1. OE+00 3.2E+00
1.43E+00 5.7E+02 1. OE+00 3.2E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1353
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo SWA-L04-1316-T01-A 1 1.15E+02
Mo SWA-L04-1316-T02-A 1 1.71E+02
Mo SWA-L04-1316-T03-A 1 5.77E+02
Mo SWA-L04-1316-T04-A 1 1.12E+03
Mo SWA-L04-1316-T01-B 1 1.31E+02
Mo SWA-L04-1316-T02-B 1 1.90E+02
Mo SWA-L04-1316-T03-B 1 5.73E+02
Mo SWA-L04-1316-T04-B 1 1.22E+03
Mo SWA-L04-1316-T01-C 1 1.14E+02
Mo SWA-L04-1316-T02-C 1 1.57E+02
Mo SWA-L04-1316-T03-C 1 4.34E+02
Mo SWA-L04-1316-T04-C 1 1.12E+03
Mo SWA-L04-1316-B01-A 1 2.92E+00 E
Mo SWA-L04-1316-B02-A 1 2.82E+00 E
Mo SWA-L04-1316-B03-A 1 2.16E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.15E+02 2.5E+00 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.71E+02 1.0E+00 1.2E+00 3.8E+00 10 100 1 .30E+03 112% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
5.77E+02 7.6E-01 1 .2E+00 3.8E+00
1.12E+03 1.3E+00 1.2E+00 3.8E+00
1.31E+02 1.8E+00 1.2E+00 3.8E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.90E+02 1.2E+00 1 .2E+00 3.8E+00 10 100 1 .37E+03 117% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
5.73E+02 3.9E-01 1 .2E+00 3.8E+00
1.22E+03 6.5E-01 1 .2E+00 3.8E+00
1.14E+02 1.8E+00 1.2E+00 3.8E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.57E+02 6.4E-01 1 .2E+00 3.8E+00 10 100 1.26E+03 11 1% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
4.34E+02 2.9E+01 1.2E+00 3.8E+00
1.12E+03 5.9E-01 1.2E+00 3.8E+00
2.92E+00 2.1E+01 1.2E+00 3.8E+00
2.82E+00 1.6E+01 1.2E+00 3.8E+00
2.16E+00 4.0E+01 1.2E+00 3.8E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1354
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ni Sample Dilution Cone. Qualifier Revi
ug/L
Ni SWA-L04-1316-T01-A 1 9.00E-01 U1/2
Ni SWA-L04-1316-T02-A 1 2.15E+00 E
Ni SWA-L04-1316-T03-A 1 2.09E+00 E
Ni SWA-L04-1316-T04-A 1 5.95E+00
Ni SWA-L04-1316-T01-B 1 9.00E-01 U1/2
Ni SWA-L04-1316-T02-B 1 9.00E-01 U1/2
Ni SWA-L04-1316-T03-B 1 2.26E+00 E
Ni SWA-L04-1316-T04-B 1 4.13E+00 E
Ni SWA-L04-1316-T01-C 1 9.00E-01 U1/2
Ni SWA-L04-1316-T02-C 1 9.00E-01 U1/2
Ni SWA-L04-1316-T03-C 1 9.00E-01 U1/2
Ni SWA-L04-1316-T04-C 1 5.27E+00 E
Ni SWA-L04-1316-B01-A 1 2.09E+00 E
Ni SWA-L04-1316-B02-A 1 9.00E-01 U1/2
Ni SWA-L04-1316-B03-A 1 9.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.3E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
2.15E+00 5.2E+01 1.8E+00 5.7E+00 10 100 1.15E+03 115% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
2.09E+00 2.4E+01 1.8E+00 5.7E+00
5.95E+00 3.0E+01 1.8E+00 5.7E+00
9.00E-01 9.6E+01 1.8E+00 5.7E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
9.00E-01 3.1E+02 1.8E+00 5.7E+00 10 100 1.18E+03 118% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
2.26E+00 1.3E+02 1.8E+00 5.7E+00
4.13E+00 5.1E+01 1.8E+00 5.7E+00
9.00E-01 4.9E+02 1.8E+00 5.7E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
9.00E-01 3.0E+02 1.8E+00 5.7E+00 10 100 1.11E+03 111% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
9.00E-01 3.3E+03 1.8E+00 5.7E+00
5.27E+00 8.6E+00 1.8E+00 5.7E+00
2.09E+00 6.0E+01 1.8E+00 5.7E+00
9.00E-01 4.4E+01 1.8E+00 5.7E+00
9.00E-01 2.4E+02 1.8E+00 5.7E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1355
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P SWA-L04-1316-T01-A 1 4.84E+01
P SWA-L04-1316-T02-A 1 1.22E+02
P SWA-L04-1316-T03-A 1 4.76E+02
P SWA-L04-1316-T04-A 1 1.27E+03
P SWA-L04-1316-T01-B 1 5.31 E+01
P SWA-L04-1316-T02-B 1 1.05E+02
P SWA-L04-1316-T03-B 1 4.33E+02
P SWA-L04-1316-T04-B 1 1.31E+03
P SWA-L04-1316-T01-C 1 3.37E+01
P SWA-L04-1316-T02-C 1 9.48E+01
P SWA-L04-1316-T03-C 1 3.34E+02
P SWA-L04-1316-T04-C 1 1.25E+03
P SWA-L04-1316-B01-A 1 1.07E+01 E
P SWA-L04-1316-B02-A 1 1.85E+OOU1/2
P SWA-L04-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.84E+01 1.5E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.22E+02 8.6E+00 3.7E+00 1.2E+01 1000 100 1 .22E+03 109% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
4.76E+02 5.3E+00 3.7E+00 1.2E+01
1.27E+03 1.2E+00 3.7E+00 1.2E+01
5.31 E+01 1.4E+01 3.7E+00 1.2E+01
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.05E+02 2.2E+00 3.7E+00 1.2E+01 1000 100 1 .23E+03 112% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
4.33E+02 5.0E+00 3.7E+00 1.2E+01
1.31E+03 2.3E+00 3.7E+00 1.2E+01
3.37E+01 2.6E+01 3.7E+00 1.2E+01
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
9.48E+01 1.9E+01 3.7E+00 1.2E+01 1000 100 1 .20E+03 110% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
3.34E+02 3.4E+01 3.7E+00 1.2E+01
1.25E+03 9.2E-01 3.7E+00 1.2E+01
1.07E+01 6.7E+01 3.7E+00 1.2E+01
1.85E+00 9.2E+01 3.7E+00 1.2E+01
1.85E+00 4.7E+02 3.7E+00 1.2E+01
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1356
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K SWA-L04-1316-T01-A 1 2.84E+05
K SWA-L04-1316-T02-A 1 4.56E+05
K SWA-L04-1316-T03-A 1 7.62E+05
K SWA-L04-1316-T04-A 1 2.42E+06
K SWA-L04-1316-T01-B 1 2.98E+05
K SWA-L04-1316-T02-B 1 4.62E+05
K SWA-L04-1316-T03-B 1 7.49E+05
K SWA-L04-1316-T04-B 1 2.42E+06
K SWA-L04-1316-T01-C 1 2.86E+05
K SWA-L04-1316-T02-C 1 4.58E+05
K SWA-L04-1316-T03-C 1 6.97E+05
K SWA-L04-1316-T04-C 1 2.41E+06
K SWA-L04-1316-B01-A 1 2.99E+01
K SWA-L04-1316-B02-A 1 2.94E+01
K SWA-L04-1316-B03-A 1 2.78E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.84E+05 3.0E-01 1 .6E+00 5.1E+00
4.56E+05 2.6E+00 1 .6E+00 5.1E+00 1000 100
7.62E+05 2.4E+00 1 .6E+00 5.1E+00
2.42E+06 3.6E-01 1 .6E+00 5.1E+00
2.98E+05 6.8E-01 1 .6E+00 5.1E+00
4.62E+05 2.2E+00 1 .6E+00 5.1E+00 1000 100
7.49E+05 1.0E+00 1 .6E+00 5.1E+00
2.42E+06 3.5E-01 1 .6E+00 5.1E+00
2.86E+05 8.4E-01 1 .6E+00 5.1E+00
4.58E+05 1.0E+00 1 .6E+00 5.1E+00 1000 100
6.97E+05 3.1E+01 1 .6E+00 5.1E+00
2.41E+06 6.0E-01 1 .6E+00 5.1E+00
2.99E+01 5.3E+00 1 .6E+00 5.1E+00
2.94E+01 5.1E+00 1 .6E+00 5.1E+00
2.78E+01 7.3E+00 1 .6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
4.57E+05 93% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
4.63E+05 89% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
4.59E+05 95% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1357
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se SWA-L04-1316-T01-A 1 8.95E+04
Se SWA-L04-1316-T02-A 1 1.69E+05
Se SWA-L04-1316-T03-A 1 4.20E+05
Se SWA-L04-1316-T04-A 1 7.68E+05
Se SWA-L04-1316-T01-B 1 1.03E+05
Se SWA-L04-1316-T02-B 1 1.76E+05
Se SWA-L04-1316-T03-B 1 4.20E+05
Se SWA-L04-1316-T04-B 1 8.41 E+05
Se SWA-L04-1316-T01-C 1 9.62E+04
Se SWA-L04-1316-T02-C 1 1.72E+05
Se SWA-L04-1316-T03-C 1 3.13E+05
Se SWA-L04-1316-T04-C 1 7.65E+05
Se SWA-L04-1316-B01-A 1 7.50E+00 U1/2
Se SWA-L04-1316-B02-A 1 7.50E+00 U1/2
Se SWA-L04-1316-B03-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.95E+04 2.3E-01 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.69E+05 6.6E-01 1 .5E+01 4.8E+01 10 100 1 JOE+05 102% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
4.20E+05 7.2E-01 1 .5E+01 4.8E+01
7.68E+05 4.8E-01 1 .5E+01 4.8E+01
1.03E+05 6.6E-01 1 .5E+01 4.8E+01
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.76E+05 8.7E-01 1 .5E+01 4.8E+01 10 100 1 J7E+05 108% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
4.20E+05 8.2E-02 1 .5E+01 4.8E+01
8.41 E+05 3.8E-01 1 .5E+01 4.8E+01
9.62E+04 9.0E-01 1 .5E+01 4.8E+01
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.72E+05 7.7E-01 1 .5E+01 4.8E+01 10 100 1.74E+05 118% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
3.13E+05 3.6E+01 1.5E+01 4.8E+01
7.65E+05 1.5E-01 1.5E+01 4.8E+01
7.50E+00 4.5E+02 1.5E+01 4.8E+01
7.50E+00 2.4E+02 1.5E+01 4.8E+01
7.50E+00 1.2E+02 1.5E+01 4.8E+01
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1358
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si SWA-L04-1316-T01-A 1 2.58E+04
Si SWA-L04-1316-T02-A 1 3.66E+04
Si SWA-L04-1316-T03-A 1 2.84E+04
Si SWA-L04-1316-T04-A 1 5.76E+04
Si SWA-L04-1316-T01-B 1 2.83E+04
Si SWA-L04-1316-T02-B 1 3.91E+04
Si SWA-L04-1316-T03-B 1 4.69E+04
Si SWA-L04-1316-T04-B 1 5.52E+04
Si SWA-L04-1316-T01-C 1 2.63E+04
Si SWA-L04-1316-T02-C 1 3.85E+04
Si SWA-L04-1316-T03-C 1 2.56E+04
Si SWA-L04-1316-T04-C 1 5.88E+04
Si SWA-L04-1316-B01-A 1 6.20E+00
Si SWA-L04-1316-B02-A 1 5.61E+00
Si SWA-L04-1316-B03-A 1 1.69E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.58E+04 1.1E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
3.66E+04 6.9E-01 1.1E+00 3.5E+00 1000 100 3.75E+04 89% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
2.84E+04 3.4E-01 1.1E+00 3.5E+00
5.76E+04 7.7E-01 1.1E+00 3.5E+00
2.83E+04 8.4E-01 1.1E+00 3.5E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
3.91E+04 6.8E-01 1.1E+00 3.5E+00 1000 100 4.00E+04 93% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
4.69E+04 8.5E-02 1.1E+00 3.5E+00
5.52E+04 2.9E-01 1.1E+00 3.5E+00
2.63E+04 5.1E-01 1.1E+00 3.5E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
3.85E+04 1.2E+00 1.1E+00 3.5E+00 1000 100 3.95E+04 94% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
2.56E+04 3.2E+01 1.1E+00 3.5E+00
5.88E+04 8.3E-01 1.1E+00 3.5E+00
6.20E+00 4.0E+01 1.1E+00 3.5E+00
5.61E+00 8.0E+01 1.1E+00 3.5E+00
1.69E+01 4.2E+00 1.1E+00 3.5E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1359
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na SWA-L04-1316-T01-A 1 3.98E+05
Na SWA-L04-1316-T02-A 1 4.87E+05
Na SWA-L04-1316-T03-A 1 5.36E+05
Na SWA-L04-1316-T04-A 1 5.49E+05
Na SWA-L04-1316-T01-B 1 4.09E+05
Na SWA-L04-1316-T02-B 1 4.84E+05
Na SWA-L04-1316-T03-B 1 5.40E+05
Na SWA-L04-1316-T04-B 1 5.49E+05
Na SWA-L04-1316-T01-C 1 4.03E+05
Na SWA-L04-1316-T02-C 1 4.88E+05
Na SWA-L04-1316-T03-C 1 5.36E+05
Na SWA-L04-1316-T04-C 1 5.56E+05
Na SWA-L04-1316-B01-A 1 1.25E+OOU1/2
Na SWA-L04-1316-B02-A 1 1.25E+OOU1/2
Na SWA-L04-1316-B03-A 1 1.25E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.98E+05 1.7E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
4.87E+05 4.4E-01 2.5E+00 8.0E+00 1000 100 4.88E+05 91% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
5.36E+05 4.8E-01 2.5E+00 8.0E+00
5.49E+05 4.4E-01 2.5E+00 8.0E+00
4.09E+05 5.3E-01 2.5E+00 8.0E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
4.84E+05 7.5E-01 2.5E+00 8.0E+00 1000 100 4.85E+05 93% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
5.40E+05 1.2E+00 2.5E+00 8.0E+00
5.49E+05 4.4E-01 2.5E+00 8.0E+00
4.03E+05 1.4E-01 2.5E+00 8.0E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
4.88E+05 1.1E+00 2.5E+00 8.0E+00 1000 100 4.89E+05 86% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
5.36E+05 3.7E-01 2.5E+00 8.0E+00
5.56E+05 1.5E+00 2.5E+00 8.0E+00
1.25E+00 1.3E+02 2.5E+00 8.0E+00
1.25E+00 3.6E+02 2.5E+00 8.0E+00
1.25E+00 1.3E+02 2.5E+00 8.0E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1360
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
SWA-L04-1316-T01-A 1 3.27E+02
SWA-L04-1316-T02-A 1 3.07E+02
SWA-L04-1316-T03-A 1 1.02E+02
SWA-L04-1316-T04-A 1 3.97E+02
SWA-L04-1316-T01-B 1 3.00E+02
SWA-L04-1316-T02-B 1 2.94E+02
SWA-L04-1316-T03-B 1 2.48E+02
SWA-L04-1316-T04-B 1 3.38E+02
SWA-L04-1316-T01-C 1 3.15E+02
SWA-L04-1316-T02-C 1 3.01 E+02
SWA-L04-1316-T03-C 1 1.03E+02
SWA-L04-1316-T04-C 1 3.87E+02
SWA-L04-1316-B01-A 1 5.00E-01 U1/2
SWA-L04-1316-B02-A 1 5.00E-01 U1/2
SWA-L04-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.27E+02 2.7E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
3.07E+02 3.5E-01 1 .OE+00 3.2E+00 1000 100 1 .45E+03 114% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
1.02E+02 2.2E+00 1 .OE+00 3.2E+00
3.97E+02 4.7E-01 1 .OE+00 3.2E+00
3.00E+02 1.5E+00 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
2.94E+02 2.5E-01 1 .OE+00 3.2E+00 1000 100 1 .47E+03 118% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
2.48E+02 4.8E-01 1 .OE+00 3.2E+00
3.38E+02 5.1E-01 1 .OE+00 3.2E+00
3.15E+02 1. OE+00 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
3.01E+02 6.0E-01 1 .OE+00 3.2E+00 1000 100 1 .39E+03 109% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
1.03E+02 3.0E+01 1 .OE+00 3.2E+00
3.87E+02 5.3E-01 1 .OE+00 3.2E+00
5.00E-01 3.0E+01 1. OE+00 3.2E+00
5.00E-01 3.7E+01 1 .OE+00 3.2E+00
5.00E-01 1.6E+01 1. OE+00 3.2E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1361
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S SWA-L04-1316-T01-A 1 5.77E+05
S SWA-L04-1316-T02-A 1 1.19E+06
S SWA-L04-1316-T03-A 1 1.74E+06
S SWA-L04-1316-T04-A 1 2.29E+06
S SWA-L04-1316-T01-B 1 8.77E+05
S SWA-L04-1316-T02-B 1 1.24E+06
S SWA-L04-1316-T03-B 1 1.64E+06
S SWA-L04-1316-T04-B 1 2.39E+06
S SWA-L04-1316-T01-C 1 8.64E+05
S SWA-L04-1316-T02-C 1 1.39E+06
S SWA-L04-1316-T03-C 1 1.41E+06
S SWA-L04-1316-T04-C 1 2.31E+06
S SWA-L04-1316-B01-A 1 3.40E+00 U1/2
S SWA-L04-1316-B02-A 1 3.40E+00 U1/2
S SWA-L04-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.77E+05 4.4E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.19E+06 1.1E+00 6.8E+00 2.2E+01 1000 100 1 .28E+06 91%VUICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
1.74E+06 4.6E-01 6.8E+00 2.2E+01
2.29E+06 5.2E-01 6.8E+00 2.2E+01
8.77E+05 1.4E+00 6.8E+00 2.2E+01
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.24E+06 1.1E+00 6.8E+00 2.2E+01 1000 100 1 .33E+06 86% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
1.64E+06 1.9E-01 6.8E+00 2.2E+01
2.39E+06 1.9E-01 6.8E+00 2.2E+01
8.64E+05 1.9E+00 6.8E+00 2.2E+01
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.39E+06 1.7E+00 6.8E+00 2.2E+01 1000 100 1 .48E+06 89% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
1.41E+06 2.5E+01 6.8E+00 2.2E+01
2.31E+06 5.4E-01 6.8E+00 2.2E+01
3.40E+00 1.5E+01 6.8E+00 2.2E+01
3.40E+00 8.4E+00 6.8E+00 2.2E+01
3.40E+00 9.9E+00 6.8E+00 2.2E+01
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1362
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl SWA-L04-1316-T01-A 1 2.30E+00 U1/2
Tl SWA-L04-1316-T02-A 1 2.30E+00 U1/2
Tl SWA-L04-1316-T03-A 1 2.30E+00 U1/2
Tl SWA-L04-1316-T04-A 1 2.30E+00 U1/2
Tl SWA-L04-1316-T01-B 1 2.30E+00 U1/2
Tl SWA-L04-1316-T02-B 1 2.30E+00 U1/2
Tl SWA-L04-1316-T03-B 1 2.30E+00 U1/2
Tl SWA-L04-1316-T04-B 1 2.30E+00 U1/2
Tl SWA-L04-1316-T01-C 1 2.30E+00 U1/2
Tl SWA-L04-1316-T02-C 1 2.30E+00 U1/2
Tl SWA-L04-1316-T03-C 1 2.30E+00 U1/2
Tl SWA-L04-1316-T04-C 1 2.30E+00 U1/2
Tl SWA-L04-1316-B01-A 1 2.30E+00 U1/2
Tl SWA-L04-1316-B02-A 1 2.30E+00 U1/2
Tl SWA-L04-1316-B03-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 1.3E+03 4.6E+00 1.5E+01 10 100
2.30E+00 1.5E+01 4.6E+00 1.5E+01
2.30E+00 2.3E+02 4.6E+00 1.5E+01
2.30E+00 2.3E+02 4.6E+00 1.5E+01
2.30E+00 4.9E+02 4.6E+00 1.5E+01 10 100
2.30E+00 2.1E+02 4.6E+00 1.5E+01
2.30E+00 1.7E+02 4.6E+00 1.5E+01
2.30E+00 1.0E+02 4.6E+00 1.5E+01
2.30E+00 3.4E+02 4.6E+00 1.5E+01 10 100
2.30E+00 2.7E+01 4.6E+00 1.5E+01
2.30E+00 9.5E+01 4.6E+00 1.5E+01
2.30E+00 1.4E+02 4.6E+00 1.5E+01
2.30E+00 6.3E+01 4.6E+00 1.5E+01
2.30E+00 8.1E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.04E+03 104% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.07E+03 107% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.00E+03 100% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1363
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti SWA-L04-1316-T01-A 1 1.00E+OOU1/2
Ti SWA-L04-1316-T02-A 1 1.00E+OOU1/2
Ti SWA-L04-1316-T03-A 1 2.70E+00 E
Ti SWA-L04-1316-T04-A 1 4.51E+00 E
Ti SWA-L04-1316-T01-B 1 3.05E+00 E
Ti SWA-L04-1316-T02-B 1 1.00E+OOU1/2
Ti SWA-L04-1316-T03-B 1 1.00E+OOU1/2
Ti SWA-L04-1316-T04-B 1 1.00E+OOU1/2
Ti SWA-L04-1316-T01-C 1 1.00E+OOU1/2
Ti SWA-L04-1316-T02-C 1 1.00E+OOU1/2
Ti SWA-L04-1316-T03-C 1 1.00E+OOU1/2
Ti SWA-L04-1316-T04-C 1 2.36E+00 E
Ti SWA-L04-1316-B01-A 1 1.00E+OOU1/2
Ti SWA-L04-1316-B02-A 1 1.00E+OOU1/2
Ti SWA-L04-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.6E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
1.00E+00 3.0E+01 2.0E+00 6.4E+00 10 100 1.12E+03 1 12% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
2.70E+00 2.0E+01 2.0E+00 6.4E+00
4.51 E+00 8.9E+00 2.0E+00 6.4E+00
3.05E+00 1.2E+01 2.0E+00 6.4E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
1.00E+00 1.8E+01 2.0E+00 6.4E+00 10 100 1.18E+03 1 18% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
1.00E+00 3.3E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 4.9E+01 2.0E+00 6.4E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
1.00E+00 5.3E+01 2.0E+00 6.4E+00 10 100 1.08E+03 108% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
1.00E+00 5.1E+01 2.0E+00 6.4E+00
2.36E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 9.7E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+01 2.0E+00 6.4E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1364
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V SWA-L04-1316-T01-A 1 3.51 E+02
V SWA-L04-1316-T02-A 1 6.63E+02
V SWA-L04-1316-T03-A 1 1.33E+03
V SWA-L04-1316-T04-A 1 2.08E+03
V SWA-L04-1316-T01-B 1 4.38E+02
V SWA-L04-1316-T02-B 1 7.10E+02
V SWA-L04-1316-T03-B 1 1.38E+03
V SWA-L04-1316-T04-B 1 2.23E+03
V SWA-L04-1316-T01-C 1 3.87E+02
V SWA-L04-1316-T02-C 1 6.90E+02
V SWA-L04-1316-T03-C 1 1.20E+03
V SWA-L04-1316-T04-C 1 2.13E+03
V SWA-L04-1316-B01-A 1 7.50E-01 U1/2
V SWA-L04-1316-B02-A 1 7.50E-01 U1/2
V SWA-L04-1316-B03-A 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.51 E+02 9.1E-01 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
6.63E+02 1.4E+00 1 .5E+00 4.8E+00 10 100 1 J5E+03 109% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
1.33E+03 8.7E-01 1 .5E+00 4.8E+00
2.08E+03 1.5E+00 1 .5E+00 4.8E+00
4.38E+02 4.8E-01 1 .5E+00 4.8E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
7.10E+02 1.4E+00 1 .5E+00 4.8E+00 10 100 1 .83E+03 112% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
1.38E+03 7.2E-01 1 .5E+00 4.8E+00
2.23E+03 1.4E+00 1 .5E+00 4.8E+00
3.87E+02 9.1E-01 1 .5E+00 4.8E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
6.90E+02 9.2E-01 1 .5E+00 4.8E+00 10 100 1 J4E+03 105% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
1.20E+03 2.5E+00 1 .5E+00 4.8E+00
2.13E+03 5.0E-01 1 .5E+00 4.8E+00
7.50E-01 1.3E+02 1 .5E+00 4.8E+00
7.50E-01 3.3E+01 1 .5E+00 4.8E+00
7.50E-01 4.5E+01 1 .5E+00 4.8E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1365
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn SWA-L04-1316-T01-A 1 3.76E+00
Zn SWA-L04-1316-T02-A 1 4.39E+00
Zn SWA-L04-1316-T03-A 1 1.06E+OOE
Zn SWA-L04-1316-T04-A 1 1.63E+01
Zn SWA-L04-1316-T01-B 1 6.15E+00
Zn SWA-L04-1316-T02-B 1 7.34E+00
Zn SWA-L04-1316-T03-B 1 2.96E+00 E
Zn SWA-L04-1316-T04-B 1 1.52E+01
Zn SWA-L04-1316-T01-C 1 5.62E+00
Zn SWA-L04-1316-T02-C 1 8.60E+00
Zn SWA-L04-1316-T03-C 1 5.00E-01 U1/2
Zn SWA-L04-1316-T04-C 1 1.56E+01
Zn SWA-L04-1316-B01-A 1 2.85E+00 E
Zn SWA-L04-1316-B02-A 1 4.39E+00
Zn SWA-L04-1316-B03-A 1 2.96E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.76E+00 3.7E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/21/11 2:43 PM EPA Interlab L04 1313-1316 SWA
4.39E+00 2.5E+00 1 .OE+00 3.2E+00 10 100 1.16E+03 116% VU ICP-OES 3/21/11 2:44 PM EPA Interlab L04 1313-1316 SWA
1.06E+00 5.0E+01 1. OE+00 3.2E+00
1.63E+01 9.2E-01 1 .OE+00 3.2E+00
6.15E+00 5.4E+00 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:46 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:48 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:49 PM EPA Interlab L04 1313-1316 SWA
7.34E+00 3.6E+00 1 .OE+00 3.2E+00 10 100 1.10E+03 109% VU ICP-OES 3/21/11 2:51 PM EPA Interlab L04 1313-1316 SWA
2.96E+00 7.8E+00 1 .OE+00 3.2E+00
1.52E+01 1.1E+00 1. OE+00 3.2E+00
5.62E+00 9.0E+00 1 .OE+00 3.2E+00
VU ICP-OES 3/21/11 2:52 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:54 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:56 PM EPA Interlab L04 1313-1316 SWA
8.60E+00 1.8E+00 1 .OE+00 3.2E+00 10 100 1.01E+03 100% VU ICP-OES 3/21/11 2:57 PM EPA Interlab L04 1313-1316 SWA
5.00E-01 2.3E+01 1 .OE+00 3.2E+00
1.56E+01 1.6E+00 1. OE+00 3.2E+00
2.85E+00 1.2E+01 1 .OE+00 3.2E+00
4.39E+00 6.0E+00 1. OE+00 3.2E+00
2.96E+00 6.5E+00 1. OE+00 3.2E+00
VU ICP-OES 3/21/11 2:59 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 3:01 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:38 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:39 PM EPA Interlab L04 1313-1316 SWA
VU ICP-OES 3/21/11 2:41 PM EPA Interlab L04 1313-1316 SWA
                                                                                                                                                                         1-1366
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al SWA-L05-1316-T01-A 1
Al SWA-L05-1316-T02-A 1
Al SWA-L05-1316-T03-A 1
Al SWA-L05-1316-T04-A 1
Al SWA-L05-1316-T05-A 1
Al SWA-L05-1316-T01-B 1
Al SWA-L05-1316-T02-B 1
Al SWA-L05-1316-T03-B 1
Al SWA-L05-1316-T04-B 1
Al SWA-L05-1316-T05-B 1
Al SWA-L05-1316-T01-C 1
Al SWA-L05-1316-T02-C 1
Al SWA-L05-1316-T03-C 1
Al SWA-L05-1316-T04-C 1
Al SWA-L05-1316-T05-C 1
Al SWA-L05-1316-B01-A 1
Al SWA-L05-1316-B02-A 1
Al SWA-L05-1316-B03-A 1
Sample
Cone. Qualifier
ug/L
3.00E+04
4.32E+04
7.43E+04
1.04E+05
1.50E+05
2.96E+04
4.59E+04
7.44E+04
1.04E+05
1.49E+05
2.93E+04
4.35E+04
7.68E+04
1.02E+05
1.49E+05
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.00E+04 9.5E-01 1.0E+00 3.2E+00
4.32E+04 9.2E-02 1.0E+00 3.2E+00 1000 100
7.43E+04 7.2E-01 1.0E+00 3.2E+00
1.04E+05 8.4E+01 1.0E+00 3.2E+00
1.50E+05 3.7E-01 1.0E+00 3.2E+00
2.96E+04 3.9E-01 1.0E+00 3.2E+00
4.59E+04 1.0E+00 1.0E+00 3.2E+00 1000 100
7.44E+04 4.3E-01 1.0E+00 3.2E+00
1.04E+05 5.8E-01 1.0E+00 3.2E+00
1.49E+05 6.3E-01 1.0E+00 3.2E+00
2.93E+04 2.8E+00 1.0E+00 3.2E+00
4.35E+04 5.2E-01 1.0E+00 3.2E+00 1000 100
7.68E+04 1.4E+02 1.0E+00 3.2E+00
1.02E+05 1.2E+00 1.0E+00 3.2E+00
1.49E+05 1.0E+00 1.0E+00 3.2E+00
5.00E-01 4.7E+00 1.0E+00 3.2E+00
5.00E-01 5.0E+00 1.0E+00 3.2E+00
5.00E-01 4.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
4.41E+04 94% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
4.68E+04 85% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
4.44E+04 92% VUICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                                 1-1367
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L05-1316-T01-A 1
Sb SWA-L05-1316-T02-A 1
Sb SWA-L05-1316-T03-A 1
Sb SWA-L05-1316-T04-A 1
Sb SWA-L05-1316-T05-A 1
Sb SWA-L05-1316-T01-B 1
Sb SWA-L05-1316-T02-B 1
Sb SWA-L05-1316-T03-B 1
Sb SWA-L05-1316-T04-B 1
Sb SWA-L05-1316-T05-B 1
Sb SWA-L05-1316-T01-C 1
Sb SWA-L05-1316-T02-C 1
Sb SWA-L05-1316-T03-C 1
Sb SWA-L05-1316-T04-C 1
Sb SWA-L05-1316-T05-C 1
Sb SWA-L05-1316-B01-A 1
Sb SWA-L05-1316-B02-A 1
Sb SWA-L05-1316-B03-A 1
Sample
Cone. Qualifier
ug/L
5.71 E+03
8.29E+03
7.43E+03
8.21 E+03
6.99E+03
5.73E+03
9.28E+03
7.84E+03
8.32E+03
7.21 E+03
5.67E+03
8.33E+03
7.83E+03
8.89E+03
6.84E+03
9.36E+00 E
8.24E+00 E
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.71 E+03 3.0E-01 7.5E+00 2.4E+01
8.29E+03 5.3E-01 7.5E+00 2.4E+01 10 100
7.43E+03 1.5E+00 7.5E+00 2.4E+01
8.21E+03 8.7E+01 7.5E+00 2.4E+01
6.99E+03 4.8E-01 7.5E+00 2.4E+01
5.73E+03 5.1E-01 7.5E+00 2.4E+01
9.28E+03 2.0E+00 7.5E+00 2.4E+01 10 100
7.84E+03 1.5E+00 7.5E+00 2.4E+01
8.32E+03 4.3E-01 7.5E+00 2.4E+01
7.21 E+03 4.7E-01 7.5E+00 2.4E+01
5.67E+03 9.1E-01 7.5E+00 2.4E+01
8.33E+03 7.1E-01 7.5E+00 2.4E+01 10 100
7.83E+03 1.5E+02 7.5E+00 2.4E+01
8.89E+03 2.2E+00 7.5E+00 2.4E+01
6.84E+03 1.2E+00 7.5E+00 2.4E+01
9.36E+00 5.0E+01 7.5E+00 2.4E+01
8.24E+00 8.9E+00 7.5E+00 2.4E+01
3.75E+00 8.5E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
9.27E+03 98% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
1.02E+04 91%VUICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
9.28E+03 95% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:1 7PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1368
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-L05-1316-T01-A 1
As SWA-L05-1316-T02-A 1
As SWA-L05-1316-T03-A 1
As SWA-L05-1316-T04-A 1
As SWA-L05-1316-T05-A 1
As SWA-L05-1316-T01-B 1
As SWA-L05-1316-T02-B 1
As SWA-L05-1316-T03-B 1
As SWA-L05-1316-T04-B 1
As SWA-L05-1316-T05-B 1
As SWA-L05-1316-T01-C 1
As SWA-L05-1316-T02-C 1
As SWA-L05-1316-T03-C 1
As SWA-L05-1316-T04-C 1
As SWA-L05-1316-T05-C 1
As SWA-L05-1316-B01-A 1
As SWA-L05-1316-B02-A 1
As SWA-L05-1316-B03-A 1
Sample
Cone. Qualifier
ug/L
4.28E+03
1.09E+04
3.49E+04
6.00E+04
1.59E+05
4.47E+03
1.17E+04
3.46E+04
7.28E+04
1.54E+05
4.45E+03
1.09E+04
3.48E+04
7.46E+04
1.54E+05
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.28E+03 4.1E-01 1.1E+01 3.5E+01
1.09E+04 9.5E-01 1.1E+01 3.5E+01 10 100
3.49E+04 8.9E-01 1.1E+01 3.5E+01
6.00E+04 8.9E+01 1.1E+01 3.5E+01
1.59E+05 2.0E+00 1.1E+01 3.5E+01
4.47E+03 4.6E-01 1.1E+01 3.5E+01
1.17E+04 1.9E+00 1.1E+01 3.5E+01 10 100
3.46E+04 1.2E+00 1.1E+01 3.5E+01
7.28E+04 4.5E-01 1.1E+01 3.5E+01
1.54E+05 2.7E-01 1.1E+01 3.5E+01
4.45E+03 8.9E-01 1.1E+01 3.5E+01
1.09E+04 5.8E-01 1.1E+01 3.5E+01 10 100
3.48E+04 1.5E+02 1.1E+01 3.5E+01
7.46E+04 2.4E+00 1.1E+01 3.5E+01
1.54E+05 1.4E+00 1.1E+01 3.5E+01
5.50E+00 4.2E+01 1.1E+01 3.5E+01
5.50E+00 1.3E+02 1.1E+01 3.5E+01
5.50E+00 5.0E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.18E+04 91%VUICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
1.26E+04 88% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.18E+04 92%VUICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1369
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-L05-1316-T01-A 1
B SWA-L05-1316-T02-A 1
B SWA-L05-1316-T03-A 1
B SWA-L05-1316-T04-A 1
B SWA-L05-1316-T05-A 1
B SWA-L05-1316-T01-B 1
B SWA-L05-1316-T02-B 1
B SWA-L05-1316-T03-B 1
B SWA-L05-1316-T04-B 1
B SWA-L05-1316-T05-B 1
B SWA-L05-1316-T01-C 1
B SWA-L05-1316-T02-C 1
B SWA-L05-1316-T03-C 1
B SWA-L05-1316-T04-C 1
B SWA-L05-1316-T05-C 1
B SWA-L05-1316-B01-A 1
B SWA-L05-1316-B02-A 1
B SWA-L05-1316-B03-A 1
Sample
Cone. Qualifier
ug/L
8.15E+02
1.33E+03
2.52E+03
3.33E+03
4.22E+03
8.22E+02
1.44E+03
2.52E+03
3.39E+03
4.38E+03
8.05E+02
1.32E+03
2.58E+03
3.35E+03
4.35E+03
1.33E+00 E
1.76E+00 E
1.63E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.15E+02 9.3E-01 1.0E+00 3.2E+00
1.33E+03 5.8E-01 1.0E+00 3.2E+00 1000 100
2.52E+03 3.3E-01 1.0E+00 3.2E+00
3.33E+03 9.1E+01 1.0E+00 3.2E+00
4.22E+03 5.3E-01 1.0E+00 3.2E+00
8.22E+02 6.0E-01 1.0E+00 3.2E+00
1.44E+03 9.4E-01 1.0E+00 3.2E+00 1000 100
2.52E+03 5.2E-01 1.0E+00 3.2E+00
3.39E+03 8.6E-01 1.0E+00 3.2E+00
4.38E+03 3.5E-01 1.0E+00 3.2E+00
8.05E+02 5.6E-01 1.0E+00 3.2E+00
1.32E+03 1.1E+00 1.0E+00 3.2E+00 1000 100
2.58E+03 1.5E+02 1.0E+00 3.2E+00
3.35E+03 1.1E+00 1.0E+00 3.2E+00
4.35E+03 1.1E+00 1.0E+00 3.2E+00
1.33E+00 3.9E+01 1.0E+00 3.2E+00
1.76E+00 1.2E+02 1.0E+00 3.2E+00
1.63E+00 8.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
2.39E+03 107% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
2.30E+03 86% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
2.28E+03 96% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1370
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba SWA-L05-1316-T01-A 1
Ba SWA-L05-1316-T02-A 1
Ba SWA-L05-1316-T03-A 1
Ba SWA-L05-1316-T04-A 1
Ba SWA-L05-1316-T05-A 1
Ba SWA-L05-1316-T01-B 1
Ba SWA-L05-1316-T02-B 1
Ba SWA-L05-1316-T03-B 1
Ba SWA-L05-1316-T04-B 1
Ba SWA-L05-1316-T05-B 1
Ba SWA-L05-1316-T01-C 1
Ba SWA-L05-1316-T02-C 1
Ba SWA-L05-1316-T03-C 1
Ba SWA-L05-1316-T04-C 1
Ba SWA-L05-1316-T05-C 1
Ba SWA-L05-1316-B01-A 1
Ba SWA-L05-1316-B02-A 1
Ba SWA-L05-1316-B03-A 1
Sample
Cone. Qualifier
ug/L
9.25E+01
1.02E+02
1.34E+02
1.03E+02
1.24E+02
1.09E+02
1.00E+02
1.36E+02
1.47E+02
1.27E+02
1.04E+02
1.07E+02
1.22E+02
1.38E+02
1.28E+02
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.25E+01 1.2E+00 1.0E+00 3.2E+00
1.02E+02 2.7E-01 1.0E+00 3.2E+00 10 100
1.34E+02 9.6E-01 1.0E+00 3.2E+00
1.03E+02 8.5E+01 1.0E+00 3.2E+00
1.24E+02 7.1E-01 1.0E+00 3.2E+00
1.09E+02 1.8E-01 1.0E+00 3.2E+00
1.00E+02 8.6E-01 1.0E+00 3.2E+00 10 100
1.36E+02 8.7E-01 1.0E+00 3.2E+00
1.47E+02 9.9E-01 1.0E+00 3.2E+00
1.27E+02 1.2E-01 1.0E+00 3.2E+00
1.04E+02 1.5E+00 1.0E+00 3.2E+00
1.07E+02 4.4E-01 1.0E+00 3.2E+00 10 100
1.22E+02 1.4E+02 1.0E+00 3.2E+00
1.38E+02 7.8E-01 1.0E+00 3.2E+00
1.28E+02 1.3E+00 1.0E+00 3.2E+00
5.00E-01 3.0E+01 1.0E+00 3.2E+00
5.00E-01 2.8E+01 1.0E+00 3.2E+00
5.00E-01 4.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.04E+03 94%VUICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
9.97E+02 90% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.05E+03 95% VUICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1371
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L05-1316-T01-A 1
Be SWA-L05-1316-T02-A 1
Be SWA-L05-1316-T03-A 1
Be SWA-L05-1316-T04-A 1
Be SWA-L05-1316-T05-A 1
Be SWA-L05-1316-T01-B 1
Be SWA-L05-1316-T02-B 1
Be SWA-L05-1316-T03-B 1
Be SWA-L05-1316-T04-B 1
Be SWA-L05-1316-T05-B 1
Be SWA-L05-1316-T01-C 1
Be SWA-L05-1316-T02-C 1
Be SWA-L05-1316-T03-C 1
Be SWA-L05-1316-T04-C 1
Be SWA-L05-1316-T05-C 1
Be SWA-L05-1316-B01-A 1
Be SWA-L05-1316-B02-A 1
Be SWA-L05-1316-B03-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 3.1E+01 1.9E+00 6.0E+00 10 100
9.50E-01 2.4E+02 1.9E+00 6.0E+00
9.50E-01 6.3E+02 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 5.0E+02 1.9E+00 6.0E+00
9.50E-01 6.6E+02 1.9E+00 6.0E+00 10 100
9.50E-01 9.0E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00
9.50E-01 6.5E+02 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00 10 100
9.50E-01 2.3E+02 1.9E+00 6.0E+00
9.50E-01 3.2E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 3.6E+01 1.9E+00 6.0E+00
9.50E-01 4.0E+01 1.9E+00 6.0E+00
9.50E-01 7.3E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
9.41E+02 94% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
9.04E+02 90% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
9.23E+02 92% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1372
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L05-1316-T01-A 1 1.10E+OOU1/2 1.10E+00 8.1E+01 2.2E+00 7.0E+00
Cd SWA-L05-1316-T02-A 1 1.10E+OOU1/2 1.10E+00 2.2E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L05-1316-T03-A 1 1.10E+OOU1/2 1.10E+00 7.0E+01 2.2E+00 7.0E+00
Cd SWA-L05-1316-T04-A 1 1.10E+OOU1/2 1.10E+00 2.6E+02 2.2E+00 7.0E+00
Cd SWA-L05-1316-T05-A 1 1.10E+OOU1/2 1.10E+00 4.9E+02 2.2E+00 7.0E+00
Cd SWA-L05-1316-T01-B 1 1.10E+OOU1/2 1.10E+00 5.8E+01 2.2E+00 7.0E+00
Cd SWA-L05-1316-T02-B 1 1.10E+OOU1/2 1.10E+00 2.1E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L05-1316-T03-B 1 1.10E+OOU1/2 1.10E+00 9.0E+01 2.2E+00 7.0E+00
Cd SWA-L05-1316-T04-B 1 1.10E+OOU1/2 1.10E+00 1.0E+02 2.2E+00 7.0E+00
Cd SWA-L05-1316-T05-B 1 1.10E+OOU1/2 1.10E+00 2.5E+02 2.2E+00 7.0E+00
Cd SWA-L05-1316-T01-C 1 1.10E+OOU1/2 1.10E+00 6.6E+01 2.2E+00 7.0E+00
Cd SWA-L05-1316-T02-C 1 1.10E+OOU1/2 1.10E+00 3.1E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L05-1316-T03-C 1 1.10E+OOU1/2 1.10E+00 7.2E+02 2.2E+00 7.0E+00
Cd SWA-L05-1316-T04-C 1 1.10E+OOU1/2 1.10E+00 9.8E+01 2.2E+00 7.0E+00
Cd SWA-L05-1316-T05-C 1 1.10E+OOU1/2 1.10E+00 6.2E+01 2.2E+00 7.0E+00
Cd SWA-L05-1316-B01-A 1 1.10E+OOU1/2 1.10E+00 8.8E+02 2.2E+00 7.0E+00
Cd SWA-L05-1316-B02-A 1 1.10E+OOU1/2 1.10E+00 3.6E+02 2.2E+00 7.0E+00
Cd SWA-L05-1316-B03-A 1 1.10E+OOU1/2 1.10E+00 2.1E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
9.71E+02 97% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
9.37E+02 94% VU ICP-OES 3/7/1 1 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/1 1 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/1 1 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/1 1 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.01E+03 100% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1373
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
Ca SWA-L05-1316-T01-A 1 9.56E+03
Ca SWA-L05-1316-T02-A 1 7.81 E+03
Ca SWA-L05-1316-T03-A 1 3.34E+03
Ca SWA-L05-1316-T04-A 1 3.76E+03
Ca SWA-L05-1316-T05-A 1 3.56E+03
Ca SWA-L05-1316-T01-B 1 1.05E+04
Ca SWA-L05-1316-T02-B 1 7.60E+03
Ca SWA-L05-1316-T03-B 1 3.63E+03
Ca SWA-L05-1316-T04-B 1 3.79E+03
Ca SWA-L05-1316-T05-B 1 3.56E+03
Ca SWA-L05-1316-T01-C 1 9.84E+03
Ca SWA-L05-1316-T02-C 1 7.97E+03
Ca SWA-L05-1316-T03-C 1 3.38E+03
Ca SWA-L05-1316-T04-C 1 4.11E+03
Ca SWA-L05-1316-T05-C 1 3.36E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.56E+03 9.5E-01 2.6E+00 8.3E+00
7.81E+03 6.2E-01 2.6E+00 8.3E+00 1000 100
3.34E+03 3.0E+00 2.6E+00 8.3E+00
3.76E+03 8.5E+01 2.6E+00 8.3E+00
3.56E+03 2.2E+00 2.6E+00 8.3E+00
1.05E+04 3.5E-01 2.6E+00 8.3E+00
7.60E+03 6.3E-01 2.6E+00 8.3E+00 1000 100
3.63E+03 7.5E-01 2.6E+00 8.3E+00
3.79E+03 3.9E+00 2.6E+00 8.3E+00
3.56E+03 2.2E+00 2.6E+00 8.3E+00
9.84E+03 8.3E-01 2.6E+00 8.3E+00
7.97E+03 8.7E-01 2.6E+00 8.3E+00 1000 100
3.38E+03 1.5E+02 2.6E+00 8.3E+00
4.11 E+03 1.4E+00 2.6E+00 8.3E+00
3.36E+03 2.8E+00 2.6E+00 8.3E+00
Ca SWA-L05-1316-B01-A 1 1.30E+OOU1/2 1.30E+00 2.2E+02 2.6E+00 8.3E+00
Ca SWA-L05-1316-B02-A 1 1.30E+OOU1/2 1.30E+00 1 .5E+02 2.6E+00 8.3E+00
Ca SWA-L05-1316-B03-A 1 1.30E+OOU1/2 1.30E+00 3.2E+02 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
8.73E+03 92% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
8.51E+03 91% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
8.91E+03 94% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1374
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr SWA-L05-1316-T01-A 1
Cr SWA-L05-1316-T02-A 1
Cr SWA-L05-1316-T03-A 1
Cr SWA-L05-1316-T04-A 1
Cr SWA-L05-1316-T05-A 1
Cr SWA-L05-1316-T01-B 1
Cr SWA-L05-1316-T02-B 1
Cr SWA-L05-1316-T03-B 1
Cr SWA-L05-1316-T04-B 1
Cr SWA-L05-1316-T05-B 1
Cr SWA-L05-1316-T01-C 1
Cr SWA-L05-1316-T02-C 1
Cr SWA-L05-1316-T03-C 1
Cr SWA-L05-1316-T04-C 1
Cr SWA-L05-1316-T05-C 1
Cr SWA-L05-1316-B01-A 1
Cr SWA-L05-1316-B02-A 1
Cr SWA-L05-1316-B03-A 1
Sample I
Cone. Qualifier
ug/L I
9.42E+02
1.32E+03
1.76E+03
1.89E+03
2.88E+03
9.47E+02
1.56E+03
1.82E+03
1.92E+03
2.62E+03
8.64E+02
1.42E+03
1.70E+03
1.88E+03
2.92E+03
6.00E-01 U1/2
6.00E-01 U1/2
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.42E+02 1.5E+00 1.2E+00 3.8E+00
1.32E+03 6.6E-01 1.2E+00 3.8E+00 10 100
1.76E+03 9.8E-01 1.2E+00 3.8E+00
1.89E+03 8.5E+01 1.2E+00 3.8E+00
2.88E+03 4.3E-01 1.2E+00 3.8E+00
9.47E+02 9.1E-01 1.2E+00 3.8E+00
1.56E+03 9.5E-01 1.2E+00 3.8E+00 10 100
1.82E+03 1.4E+00 1.2E+00 3.8E+00
1.92E+03 1.1E+00 1.2E+00 3.8E+00
2.62E+03 1.0E+00 1.2E+00 3.8E+00
8.64E+02 5.7E+00 1.2E+00 3.8E+00
1.42E+03 4.2E-01 1.2E+00 3.8E+00 10 100
1.70E+03 1.4E+02 1.2E+00 3.8E+00
1.88E+03 1.4E+00 1.2E+00 3.8E+00
2.92E+03 9.8E-01 1.2E+00 3.8E+00
6.00E-01 2.6E+01 1.2E+00 3.8E+00
6.00E-01 6.6E+01 1.2E+00 3.8E+00
6.00E-01 1.1E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
2.31E+03 98% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
2.50E+03 94% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
2.40E+03 98% VUICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1375
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co SWA-L05-1316-T01-A 1
Co SWA-L05-1316-T02-A 1
Co SWA-L05-1316-T03-A 1
Co SWA-L05-1316-T04-A 1
Co SWA-L05-1316-T05-A 1
Co SWA-L05-1316-T01-B 1
Co SWA-L05-1316-T02-B 1
Co SWA-L05-1316-T03-B 1
Co SWA-L05-1316-T04-B 1
Co SWA-L05-1316-T05-B 1
Co SWA-L05-1316-T01-C 1
Co SWA-L05-1316-T02-C 1
Co SWA-L05-1316-T03-C 1
Co SWA-L05-1316-T04-C 1
Co SWA-L05-1316-T05-C 1
Co SWA-L05-1316-B01-A 1
Co SWA-L05-1316-B02-A 1
Co SWA-L05-1316-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
5.18E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
5.03E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
4.84E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 6.3E+02 1.8E+00 5.7E+00
9.00E-01 8.3E+02 1.8E+00 5.7E+00 10 100
9.00E-01 1.6E+01 1.8E+00 5.7E+00
9.00E-01 3.5E+02 1.8E+00 5.7E+00
5.18E+00 3.0E+01 1.8E+00 5.7E+00
9.00E-01 4.6E+01 1.8E+00 5.7E+00
9.00E-01 8.6E+02 1.8E+00 5.7E+00 10 100
9.00E-01 3.3E+01 1.8E+00 5.7E+00
9.00E-01 9.1E+00 1.8E+00 5.7E+00
5.03E+00 3.2E+01 1.8E+00 5.7E+00
9.00E-01 5.4E+01 1.8E+00 5.7E+00
9.00E-01 3.5E+02 1.8E+00 5.7E+00 10 100
9.00E-01 6.2E+04 1.8E+00 5.7E+00
9.00E-01 4.4E+01 1.8E+00 5.7E+00
4.84E+00 1.4E+01 1.8E+00 5.7E+00
9.00E-01 4.4E+01 1.8E+00 5.7E+00
9.00E-01 6.1E+01 1.8E+00 5.7E+00
9.00E-01 7.0E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
9.26E+02 92% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
8.91E+02 89%VUICP-OES 3/7/1 1 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/1 1 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/1 1 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
9.18E+02 92% VU ICP-OES 3/7/1 1 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/1 1 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/1 1 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1376
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu SWA-L05-1316-T01-A 1
Cu SWA-L05-1316-T02-A 1
Cu SWA-L05-1316-T03-A 1
Cu SWA-L05-1316-T04-A 1
Cu SWA-L05-1316-T05-A 1
Cu SWA-L05-1316-T01-B 1
Cu SWA-L05-1316-T02-B 1
Cu SWA-L05-1316-T03-B 1
Cu SWA-L05-1316-T04-B 1
Cu SWA-L05-1316-T05-B 1
Cu SWA-L05-1316-T01-C 1
Cu SWA-L05-1316-T02-C 1
Cu SWA-L05-1316-T03-C 1
Cu SWA-L05-1316-T04-C 1
Cu SWA-L05-1316-T05-C 1
Cu SWA-L05-1316-B01-A 1
Cu SWA-L05-1316-B02-A 1
Cu SWA-L05-1316-B03-A 1
Sample I
Cone. Qualifier
ug/L I
1.85E+00 U1/2
6.46E+00 E
1.21E+01
2.35E+01
7.85E+01
1.85E+00 U1/2
5.70E+00 E
1.10E+01 E
2.86E+01
7.35E+01
1.85E+00 U1/2
4.87E+00 E
1.11E+01 E
2.71E+01
8.07E+01
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 1.6E+02 3.7E+00 1.2E+01
6.46E+00 1.6E+01 3.7E+00 1.2E+01 10 100
1.21E+01 1.2E+01 3.7E+00 1.2E+01
2.35E+01 9.6E+01 3.7E+00 1.2E+01
7.85E+01 2.2E+00 3.7E+00 1.2E+01
1.85E+00 2.0E+01 3.7E+00 1.2E+01
5.70E+00 2.3E+01 3.7E+00 1.2E+01 10 100
1.10E+01 1.9E+01 3.7E+00 1.2E+01
2.86E+01 5.6E+00 3.7E+00 1.2E+01
7.35E+01 2.3E+00 3.7E+00 1.2E+01
1.85E+00 2.0E+01 3.7E+00 1.2E+01
4.87E+00 7.9E+01 3.7E+00 1.2E+01 10 100
1.11E+01 1.5E+02 3.7E+00 1.2E+01
2.71E+01 1.5E+01 3.7E+00 1.2E+01
8.07E+01 3.3E+00 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
1.85E+00 5.9E+01 3.7E+00 1.2E+01
1.85E+00 8.0E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
8.73E+02 87% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
8.60E+02 85% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
8.53E+02 85% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1377
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. Qu
1 1 ug/L
Fe SWA-L05-1316-T01-A 1 7.81 E+01
Fe SWA-L05-1316-T02-A 1 1.58E+02
Fe SWA-L05-1316-T03-A 1 2.95E+02
Fe SWA-L05-1316-T04-A 1 4.31 E+02
Fe SWA-L05-1316-T05-A 1 1.34E+03
Fe SWA-L05-1316-T01-B 1 7.16E+01
Fe SWA-L05-1316-T02-B 1 1.60E+02
Fe SWA-L05-1316-T03-B 1 2.92E+02
Fe SWA-L05-1316-T04-B 1 5.91 E+02
Fe SWA-L05-1316-T05-B 1 1.28E+03
Fe SWA-L05-1316-T01-C 1 7.77E+01
Fe SWA-L05-1316-T02-C 1 1.61 E+02
Fe SWA-L05-1316-T03-C 1 2.94E+02
Fe SWA-L05-1316-T04-C 1 6.53E+02
Fe SWA-L05-1316-T05-C 1 1.28E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
7.81 E+01 1.3E+00 2.0E+00 6.4E+00
1.58E+02 9.7E-01 2.0E+00 6.4E+00 1000 100
2.95E+02 1.8E+00 2.0E+00 6.4E+00
4.31 E+02 9.0E+01 2.0E+00 6.4E+00
1.34E+03 4.8E-01 2.0E+00 6.4E+00
7.16E+01 3.8E-01 2.0E+00 6.4E+00
1.60E+02 5.5E-01 2.0E+00 6.4E+00 1000 100
2.92E+02 9.7E-01 2.0E+00 6.4E+00
5.91 E+02 5.5E-01 2.0E+00 6.4E+00
1.28E+03 2.6E-01 2.0E+00 6.4E+00
7.77E+01 3.2E+00 2.0E+00 6.4E+00
1.61E+02 2.7E-01 2.0E+00 6.4E+00 1000 100
2.94E+02 1.6E+02 2.0E+00 6.4E+00
6.53E+02 1.6E+00 2.0E+00 6.4E+00
1.28E+03 9.9E-01 2.0E+00 6.4E+00
Fe SWA-L05-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 2.6E+00 2.0E+00 6.4E+00
Fe SWA-L05-1316-B02-A 1 1.00E+OOU1/2 1.00E+00 4.0E-01 2.0E+00 6.4E+00
Fe SWA-L05-1316-B03-A 1 1.00E+OOU1/2 1.00E+00 3.6E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.05E+03 90% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
1.04E+03 88% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.08E+03 92% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1378
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb SWA-L05-1316-T01-A 1
Pb SWA-L05-1316-T02-A 1
Pb SWA-L05-1316-T03-A 1
Pb SWA-L05-1316-T04-A 1
Pb SWA-L05-1316-T05-A 1
Pb SWA-L05-1316-T01-B 1
Pb SWA-L05-1316-T02-B 1
Pb SWA-L05-1316-T03-B 1
Pb SWA-L05-1316-T04-B 1
Pb SWA-L05-1316-T05-B 1
Pb SWA-L05-1316-T01-C 1
Pb SWA-L05-1316-T02-C 1
Pb SWA-L05-1316-T03-C 1
Pb SWA-L05-1316-T04-C 1
Pb SWA-L05-1316-T05-C 1
Pb SWA-L05-1316-B01-A 1
Pb SWA-L05-1316-B02-A 1
Pb SWA-L05-1316-B03-A 1
Sample I
Cone. Qualifier
ug/L I
3.40E+00 U1/2
1.12E+01 E
6.27E+01
1.06E+02
2.45E+02
3.40E+00 U1/2
1.70E+01 E
5.82E+01
1.25E+02
2.23E+02
3.40E+00 U1/2
1.60E+01 E
4.73E+01
1.18E+02
2.22E+02
3.40E+00 U1/2
3.40E+00 U1/2
3.40E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 6.4E+01 6.8E+00 2.2E+01
1.12E+01 1.1E+01 6.8E+00 2.2E+01 10 100
6.27E+01 1.1E+01 6.8E+00 2.2E+01
1.06E+02 9.6E+01 6.8E+00 2.2E+01
2.45E+02 1.9E+00 6.8E+00 2.2E+01
3.40E+00 2.7E+01 6.8E+00 2.2E+01
1.70E+01 3.0E+01 6.8E+00 2.2E+01 10 100
5.82E+01 3.6E+00 6.8E+00 2.2E+01
1.25E+02 4.9E+00 6.8E+00 2.2E+01
2.23E+02 1.3E+00 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
1.60E+01 1.1E+01 6.8E+00 2.2E+01 10 100
4.73E+01 1.6E+02 6.8E+00 2.2E+01
1.18E+02 2.7E+00 6.8E+00 2.2E+01
2.22E+02 2.5E+00 6.8E+00 2.2E+01
3.40E+00 2.2E+02 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01
3.40E+00 1.4E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
9.92E+02 98% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
9.61E+02 94% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
9.70E+02 95% VUICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1379
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qu<
Li SWA-L05-1316-T01-A 1 2.00E+00 E
Li SWA-L05-1316-T02-A 1 2.36E+00 E
Li SWA-L05-1316-T03-A 1 5.77E+00 E
Li SWA-L05-1316-T04-A 1 8.06E+00
Li SWA-L05-1316-T05-A 1 1.04E+01
Li SWA-L05-1316-T01-B 1 1.95E+OOE
Li SWA-L05-1316-T02-B 1 2.68E+00 E
Li SWA-L05-1316-T03-B 1 5.83E+00 E
Li SWA-L05-1316-T04-B 1 8.32E+00
Li SWA-L05-1316-T05-B 1 1.19E+01
Li SWA-L05-1316-T01-C 1 2.02E+00 E
Li SWA-L05-1316-T02-C 1 2.30E+00 E
Li SWA-L05-1316-T03-C 1 5.30E+00 E
Li SWA-L05-1316-T04-C 1 8.56E+00
Li SWA-L05-1316-T05-C 1 1.17E+01
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.00E+00 6.4E+00 1.9E+00 6.0E+00
2.36E+00 8.8E+00 1.9E+00 6.0E+00 10 100
5.77E+00 4.0E+00 1.9E+00 6.0E+00
8.06E+00 3.3E+01 1.9E+00 6.0E+00
1.04E+01 1.2E+01 1.9E+00 6.0E+00
1.95E+00 3.2E+00 1.9E+00 6.0E+00
2.68E+00 5.6E+00 1.9E+00 6.0E+00 10 100
5.83E+00 7.8E+00 1.9E+00 6.0E+00
8.32E+00 1.1E+01 1.9E+00 6.0E+00
1.19E+01 1.3E+01 1.9E+00 6.0E+00
2.02E+00 4.7E+00 1.9E+00 6.0E+00
2.30E+00 3.8E+00 1.9E+00 6.0E+00 10 100
5.30E+00 3.7E+01 1.9E+00 6.0E+00
8.56E+00 9.3E+00 1.9E+00 6.0E+00
1.17E+01 2.2E+01 1.9E+00 6.0E+00
Li SWA-L05-1316-B01-A 1 9.50E-01 U1/2 9.50E-01 9.2E+00 1.9E+00 6.0E+00
Li SWA-L05-1316-B02-A 1 9.50E-01 U1/2 9.50E-01 9.8E+00 1.9E+00 6.0E+00
Li SWA-L05-1316-B03-A 1 9.50E-01 U1/2 9.50E-01 3.9E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
8.95E+02 89% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
8.64E+02 86% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
8.71E+02 87% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1380
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Mn SWA-L05-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 2.8E+01 2.0E+00 6.4E+00
Mn SWA-L05-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 2.3E+01 2.0E+00 6.4E+00 10 100
Mn SWA-L05-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 1 .9E+01 2.0E+00 6.4E+00
Mn SWA-L05-1316-T04-A 1 1.00E+OOU1/2 1.00E+00 1 .OE+02 2.0E+00 6.4E+00
Mn SWA-L05-1316-T05-A 1 3.05E+00 E
3.05E+00 4.5E-01 2.0E+00 6.4E+00
Mn SWA-L05-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 5.7E+01 2.0E+00 6.4E+00
Mn SWA-L05-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 1 .9E+01 2.0E+00 6.4E+00 10 100
Mn SWA-L05-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 2.8E+01 2.0E+00 6.4E+00
Mn SWA-L05-1316-T04-B 1 1.00E+OOU1/2 1.00E+00 6.8E+00 2.0E+00 6.4E+00
Mn SWA-L05-1316-T05-B 1 3.12E+00 E
3.12E+00 2.9E+00 2.0E+00 6.4E+00
Mn SWA-L05-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 3.1E+01 2.0E+00 6.4E+00
Mn SWA-L05-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 3.0E+01 2.0E+00 6.4E+00 10 100
Mn SWA-L05-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 3.6E+02 2.0E+00 6.4E+00
Mn SWA-L05-1316-T04-C 1 1.00E+OOU1/2 1.00E+00 2.7E+00 2.0E+00 6.4E+00
Mn SWA-L05-1316-T05-C 1 3.05E+00 E
3.05E+00 6.4E+00 2.0E+00 6.4E+00
Mn SWA-L05-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 3.1E+00 2.0E+00 6.4E+00
Mn SWA-L05-1316-B02-A 1 1.00E+OOU1/2 1.00E+00 6.3E+02 2.0E+00 6.4E+00
Mn SWA-L05-1316-B03-A 1 1.00E+OOU1/2 1.00E+00 4.9E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
9.46E+02 94% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
9.13E+02 91% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
9.30E+02 93% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1381
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg SWA-L05-1316-T01-A 1
Mg SWA-L05-1316-T02-A 1
Mg SWA-L05-1316-T03-A 1
Mg SWA-L05-1316-T04-A 1
Mg SWA-L05-1316-T05-A 1
Mg SWA-L05-1316-T01-B 1
Mg SWA-L05-1316-T02-B 1
Mg SWA-L05-1316-T03-B 1
Mg SWA-L05-1316-T04-B 1
Mg SWA-L05-1316-T05-B 1
Mg SWA-L05-1316-T01-C 1
Mg SWA-L05-1316-T02-C 1
Mg SWA-L05-1316-T03-C 1
Mg SWA-L05-1316-T04-C 1
Mg SWA-L05-1316-T05-C 1
Mg SWA-L05-1316-B01-A 1
Mg SWA-L05-1316-B02-A 1
Mg SWA-L05-1316-B03-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 8.9E+00 1.0E+00 3.2E+00
5.00E-01 1.1E+02 1.0E+00 3.2E+00 1000 100
5.00E-01 7.2E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+02 1.0E+00 3.2E+00
5.00E-01 3.9E+01 1.0E+00 3.2E+00
5.00E-01 4.1E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00 1000 100
5.00E-01 2.0E+01 1.0E+00 3.2E+00
5.00E-01 3.8E+02 1.0E+00 3.2E+00
5.00E-01 2.0E+02 1.0E+00 3.2E+00
5.00E-01 7.4E+01 1.0E+00 3.2E+00
5.00E-01 5.5E+01 1.0E+00 3.2E+00 1000 100
5.00E-01 1.2E+02 1.0E+00 3.2E+00
5.00E-01 6.2E+01 1.0E+00 3.2E+00
5.00E-01 5.7E+01 1.0E+00 3.2E+00
5.00E-01 5.9E+01 1.0E+00 3.2E+00
5.00E-01 2.9E+01 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.01E+03 101% VUICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
9.29E+02 93% VUICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
9.91E+02 99% VUICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1382
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 1 ug/L
Mo SWA-L05-1316-T01-A 1 1.04E+02
Mo SWA-L05-1316-T02-A 1 1.86E+02
Mo SWA-L05-1316-T03-A 1 4.04E+02
Mo SWA-L05-1316-T04-A 1 6.47E+02
Mo SWA-L05-1316-T05-A 1 1.26E+03
Mo SWA-L05-1316-T01-B 1 9.99E+01
Mo SWA-L05-1316-T02-B 1 1.93E+02
Mo SWA-L05-1316-T03-B 1 3.97E+02
Mo SWA-L05-1316-T04-B 1 6.52E+02
Mo SWA-L05-1316-T05-B 1 1.22E+03
Mo SWA-L05-1316-T01-C 1 1.03E+02
Mo SWA-L05-1316-T02-C 1 1.85E+02
Mo SWA-L05-1316-T03-C 1 3.84E+02
Mo SWA-L05-1316-T04-C 1 6.89E+02
Mo SWA-L05-1316-T05-C 1 1.24E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.04E+02 1.0E+00 1.2E+00 3.8E+00
1.86E+02 1.2E+00 1.2E+00 3.8E+00 10 100
4.04E+02 3.9E-01 1.2E+00 3.8E+00
6.47E+02 9.0E+01 1.2E+00 3.8E+00
1.26E+03 5.9E-01 1.2E+00 3.8E+00
9.99E+01 2.2E+00 1.2E+00 3.8E+00
1.93E+02 4.3E-01 1.2E+00 3.8E+00 10 100
3.97E+02 6.6E-01 1.2E+00 3.8E+00
6.52E+02 1.0E+00 1.2E+00 3.8E+00
1.22E+03 6.1E-01 1.2E+00 3.8E+00
1.03E+02 3.1E+00 1.2E+00 3.8E+00
1.85E+02 2.0E+00 1.2E+00 3.8E+00 10 100
3.84E+02 1.4E+02 1.2E+00 3.8E+00
6.89E+02 1.2E+00 1.2E+00 3.8E+00
1.24E+03 7.5E-01 1.2E+00 3.8E+00
Mo SWA-L05-1316-B01-A 1 1.29E+OOE 1.29E+00 1.1E+02 1.2E+00 3.8E+00
Mo SWA-L05-1316-B02-A 1 6.00E-01 U1/2 6.00E-01 2.6E+02 1.2E+00 3.8E+00
Mo SWA-L05-1316-B03-A 1 6.00E-01 U1/2 6.00E-01 7.8E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.30E+03 111% VUICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
1.25E+03 106% VUICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.26E+03 107% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:1 7PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1383
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L05-1316-T01-A 1 9.00E-01 U1/2 9.00E-01 1.2E+02 1.8E+00 5.7E+00
Ni SWA-L05-1316-T02-A 1 9.00E-01 U1/2 9.00E-01 1.3E+02 1.8E+00 5.7E+00 10 100
Ni SWA-L05-1316-T03-A 1 2.54E+00 E
Ni SWA-L05-1316-T04-A 1 5.62E+00 E
Ni SWA-L05-1316-T05-A 1 9.37E+00
2.54E+00 7.5E+01 1.8E+00 5.7E+00
5.62E+00 1.3E+02 1.8E+00 5.7E+00
9.37E+00 1.1E+01 1.8E+00 5.7E+00
Ni SWA-L05-1316-T01-B 1 9.00E-01 U1/2 9.00E-01 1.4E+02 1.8E+00 5.7E+00
Ni SWA-L05-1316-T02-B 1 9.00E-01 U1/2 9.00E-01 2.0E+01 1.8E+00 5.7E+00 10 100
Ni SWA-L05-1316-T03-B 1 2.89E+00 E
Ni SWA-L05-1316-T04-B 1 6.24E+00
Ni SWA-L05-1316-T05-B 1 9.41 E+00
2.89E+00 1.8E+01 1.8E+00 5.7E+00
6.24E+00 2.1E+01 1.8E+00 5.7E+00
9.41 E+00 1.2E+01 1.8E+00 5.7E+00
Ni SWA-L05-1316-T01-C 1 9.00E-01 U1/2 9.00E-01 3.6E+02 1.8E+00 5.7E+00
Ni SWA-L05-1316-T02-C 1 9.00E-01 U1/2 9.00E-01 9.0E+01 1.8E+00 5.7E+00 10 100
Ni SWA-L05-1316-T03-C 1 2.85E+00 E
Ni SWA-L05-1316-T04-C 1 5.10E+00 E
Ni SWA-L05-1316-T05-C 1 1.10E+01
2.85E+00 2.7E+02 1.8E+00 5.7E+00
5.10E+00 2.9E+01 1.8E+00 5.7E+00
1.10E+01 1.8E+01 1.8E+00 5.7E+00
Ni SWA-L05-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 5.3E+03 1.8E+00 5.7E+00
Ni SWA-L05-1316-B02-A 1 9.00E-01 U1/2 9.00E-01 1.8E+03 1.8E+00 5.7E+00
Ni SWA-L05-1316-B03-A 1 9.00E-01 U1/2 9.00E-01 2.9E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
9.18E+02 92% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
8.85E+02 88% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
9.63E+02 96% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1384
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone.
1 ug/L
P SWA-L05-1316-T01-A 1 5.55E+01
P SWA-L05-1316-T02-A 1 1.14E+02
P SWA-L05-1316-T03-A 1 4.23E+02
P SWA-L05-1316-T04-A 1 1.02E+03
P SWA-L05-1316-T05-A 1 2.32E+03
P SWA-L05-1316-T01-B 1 5.15E+01
P SWA-L05-1316-T02-B 1 1.12E+02
P SWA-L05-1316-T03-B 1 4.40E+02
P SWA-L05-1316-T04-B 1 1.01E+03
P SWA-L05-1316-T05-B 1 2.31E+03
P SWA-L05-1316-T01-C 1 5.09E+01
P SWA-L05-1316-T02-C 1 1.15E+02
P SWA-L05-1316-T03-C 1 4.53E+02
P SWA-L05-1316-T04-C 1 1.01E+03
P SWA-L05-1316-T05-C 1 2.32E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
5.55E+01 1.2E+01 3.7E+00 1.2E+01
1.14E+02 1.0E+01 3.7E+00 1.2E+01 1000 100
4.23E+02 2.0E+00 3.7E+00 1.2E+01
1.02E+03 9.0E+01 3.7E+00 1.2E+01
2.32E+03 5.7E-01 3.7E+00 1.2E+01
5.15E+01 2.1E+01 3.7E+00 1.2E+01
1.12E+02 9.5E+00 3.7E+00 1.2E+01 1000 100
4.40E+02 4.7E+00 3.7E+00 1.2E+01
1.01E+03 1.2E+00 3.7E+00 1.2E+01
2.31 E+03 8.4E-01 3.7E+00 1.2E+01
5.09E+01 2.4E+01 3.7E+00 1.2E+01
1.15E+02 1.4E+01 3.7E+00 1 .2E+01 1000 100
4.53E+02 1.4E+02 3.7E+00 1 .2E+01
1.01 E+03 2.1E+00 3.7E+00 1 .2E+01
2.32E+03 1.7E+00 3.7E+00 1 .2E+01
P SWA-L05-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 7.1E+01 3.7E+00 1 .2E+01
P SWA-L05-1316-B02-A 1 1.85E+OOU1/2 1.85E+00 1.1E+04 3.7E+00 1 .2E+01
P SWA-L05-1316-B03-A 1 1.85E+OOU1/2 1.85E+00 5.3E+02 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.08E+03 96% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
1.10E+03 99% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.03E+03 91% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1385
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K SWA-L05-1316-T01-A 1
K SWA-L05-1316-T02-A 1
K SWA-L05-1316-T03-A 1
K SWA-L05-1316-T04-A 1
K SWA-L05-1316-T05-A 1
K SWA-L05-1316-T01-B 1
K SWA-L05-1316-T02-B 1
K SWA-L05-1316-T03-B 1
K SWA-L05-1316-T04-B 1
K SWA-L05-1316-T05-B 1
K SWA-L05-1316-T01-C 1
K SWA-L05-1316-T02-C 1
K SWA-L05-1316-T03-C 1
K SWA-L05-1316-T04-C 1
K SWA-L05-1316-T05-C 1
K SWA-L05-1316-B01-A 1
K SWA-L05-1316-B02-A 1
K SWA-L05-1316-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.43E+05
3.69E+05
6.86E+05
1.73E+06
2.53E+06
2.40E+05
3.73E+05
6.67E+05
2.39E+06
2.51 E+06
2.36E+05
3.67E+05
6.74E+05
2.40E+06
2.51 E+06
4.21E+01
4.15E+01
4.03E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.43E+05 1.0E+00 1.6E+00 5.1E+00
3.69E+05 1.2E-01 1.6E+00 5.1E+00 1000 100
6.86E+05 4.7E+00 1.6E+00 5.1E+00
1.73E+06 8.6E+01 1.6E+00 5.1E+00
2.53E+06 1.5E+00 1.6E+00 5.1E+00
2.40E+05 9.9E-01 1.6E+00 5.1E+00
3.73E+05 4.8E-01 1.6E+00 5.1E+00 1000 100
6.67E+05 1.3E+00 1.6E+00 5.1E+00
2.39E+06 1.2E+00 1.6E+00 5.1E+00
2.51E+06 7.5E-01 1.6E+00 5.1E+00
2.36E+05 2.7E+00 1.6E+00 5.1E+00
3.67E+05 4.6E-01 1.6E+00 5.1E+00 1000 100
6.74E+05 1.3E+02 1.6E+00 5.1E+00
2.40E+06 1.5E+00 1.6E+00 5.1E+00
2.51 E+06 5.3E-01 1.6E+00 5.1E+00
4.21E+01 2.1E+01 1.6E+00 5.1E+00
4.15E+01 2.3E+01 1.6E+00 5.1E+00
4.03E+01 2.4E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
3.70E+05 93% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
3.74E+05 94% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
3.68E+05 91% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1386
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se SWA-L05-1316-T01-A 1
Se SWA-L05-1316-T02-A 1
Se SWA-L05-1316-T03-A 1
Se SWA-L05-1316-T04-A 1
Se SWA-L05-1316-T05-A 1
Se SWA-L05-1316-T01-B 1
Se SWA-L05-1316-T02-B 1
Se SWA-L05-1316-T03-B 1
Se SWA-L05-1316-T04-B 1
Se SWA-L05-1316-T05-B 1
Se SWA-L05-1316-T01-C 1
Se SWA-L05-1316-T02-C 1
Se SWA-L05-1316-T03-C 1
Se SWA-L05-1316-T04-C 1
Se SWA-L05-1316-T05-C 1
Se SWA-L05-1316-B01-A 1
Se SWA-L05-1316-B02-A 1
Se SWA-L05-1316-B03-A 1
Sample I
Cone. Qualifier
ug/L I
6.84E+04
1.27E+05
2.77E+05
4.26E+05
8.94E+05
6.67E+04
1.32E+05
2.72E+05
4.61 E+05
8.68E+05
6.74E+04
1.28E+05
2.90E+05
4.85E+05
8.79E+05
7.50E+00 U1/2
7.50E+00 U1/2
7.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.84E+04 2.2E-01 1.5E+01 4.8E+01
1.27E+05 4.8E-01 1.5E+01 4.8E+01 10 100
2.77E+05 7.4E-01 1.5E+01 4.8E+01
4.26E+05 9.8E+01 1.5E+01 4.8E+01
8.94E+05 4.8E-01 1.5E+01 4.8E+01
6.67E+04 2.3E-01 1.5E+01 4.8E+01
1.32E+05 8.4E-01 1.5E+01 4.8E+01 10 100
2.72E+05 5.1E-01 1.5E+01 4.8E+01
4.61 E+05 8.2E-01 1.5E+01 4.8E+01
8.68E+05 3.1E-01 1.5E+01 4.8E+01
6.74E+04 7.7E-01 1.5E+01 4.8E+01
1.28E+05 4.8E-01 1.5E+01 4.8E+01 10 100
2.90E+05 1.4E+02 1.5E+01 4.8E+01
4.85E+05 5.9E-01 1.5E+01 4.8E+01
8.79E+05 1.2E+00 1.5E+01 4.8E+01
7.50E+00 5.8E+02 1.5E+01 4.8E+01
7.50E+00 9.5E+01 1.5E+01 4.8E+01
7.50E+00 1.2E+03 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.28E+05 88% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
1.33E+05 86%VUICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.29E+05 92% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:1 7PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1387
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qu
Si SWA-L05-1316-T01-A 1 2.02E+04
Si SWA-L05-1316-T02-A 1 3.02E+04
Si SWA-L05-1316-T03-A 1 5.42E+04
Si SWA-L05-1316-T04-A 1 7.59E+04
Si SWA-L05-1316-T05-A 1 1.03E+05
Si SWA-L05-1316-T01-B 1 2.02E+04
Si SWA-L05-1316-T02-B 1 3.25E+04
Si SWA-L05-1316-T03-B 1 5.60E+04
Si SWA-L05-1316-T04-B 1 7.58E+04
Si SWA-L05-1316-T05-B 1 1.03E+05
Si SWA-L05-1316-T01-C 1 1.98E+04
Si SWA-L05-1316-T02-C 1 3.01 E+04
Si SWA-L05-1316-T03-C 1 5.55E+04
Si SWA-L05-1316-T04-C 1 7.54E+04
Si SWA-L05-1316-T05-C 1 1.03E+05
Si SWA-L05-1316-B01-A 1 7.13E+00
Si SWA-L05-1316-B02-A 1 9.78E+00
Si SWA-L05-1316-B03-A 1 9.08E+00
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.02E+04 7.2E-01 1.1E+00 3.5E+00
3.02E+04 3.5E-01 1.1E+00 3.5E+00 1000 100
5.42E+04 8.3E-01 1.1E+00 3.5E+00
7.59E+04 8.9E+01 1.1E+00 3.5E+00
1.03E+05 1.0E+00 1.1E+00 3.5E+00
2.02E+04 1.0E+00 1.1E+00 3.5E+00
3.25E+04 1.1E+00 1.1E+00 3.5E+00 1000 100
5.60E+04 1.0E+00 1.1E+00 3.5E+00
7.58E+04 1.6E+00 1.1E+00 3.5E+00
1.03E+05 4.0E-01 1.1E+00 3.5E+00
1.98E+04 2.0E+00 1.1E+00 3.5E+00
3.01E+04 7.2E-01 1.1E+00 3.5E+00 1000 100
5.55E+04 1.2E+02 1.1E+00 3.5E+00
7.54E+04 2.1E+00 1.1E+00 3.5E+00
1.03E+05 1.2E+00 1.1E+00 3.5E+00
7.13E+00 3.7E+01 1.1E+00 3.5E+00
9.78E+00 6.6E+00 1.1E+00 3.5E+00
9.08E+00 3.0E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
3.11E+04 89% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
3.34E+04 90% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
3.10E+04 94% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:1 7PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1388
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone.
Na SWA-L05-1316-T01-A 1 3.84E+05
Na SWA-L05-1316-T02-A 1 4.78E+05
Na SWA-L05-1316-T03-A 1 5.93E+05
Na SWA-L05-1316-T04-A 1 4.59E+05
Na SWA-L05-1316-T05-A 1 6.15E+05
Na SWA-L05-1316-T01-B 1 3.81 E+05
Na SWA-L05-1316-T02-B 1 4.79E+05
Na SWA-L05-1316-T03-B 1 5.89E+05
Na SWA-L05-1316-T04-B 1 6.08E+05
Na SWA-L05-1316-T05-B 1 6.14E+05
Na SWA-L05-1316-T01-C 1 3.80E+05
Na SWA-L05-1316-T02-C 1 4.74E+05
Na SWA-L05-1316-T03-C 1 6.00E+05
Na SWA-L05-1316-T04-C 1 6.05E+05
Na SWA-L05-1316-T05-C 1 6.20E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.84E+05 1.3E-01 2.5E+00 8.0E+00
4.78E+05 2.0E-01 2.5E+00 8.0E+00 1000 100
5.93E+05 4.1E-01 2.5E+00 8.0E+00
4.59E+05 5.7E+01 2.5E+00 8.0E+00
6.15E+05 1.4E-01 2.5E+00 8.0E+00
3.81 E+05 3.2E-01 2.5E+00 8.0E+00
4.79E+05 1.8E-01 2.5E+00 8.0E+00 1000 100
5.89E+05 7.0E-01 2.5E+00 8.0E+00
6.08E+05 1.4E+00 2.5E+00 8.0E+00
6.14E+05 2.9E-01 2.5E+00 8.0E+00
3.80E+05 2.7E-01 2.5E+00 8.0E+00
4.74E+05 5.4E-01 2.5E+00 8.0E+00 1000 100
6.00E+05 6.1E+01 2.5E+00 8.0E+00
6.05E+05 3.7E-02 2.5E+00 8.0E+00
6.20E+05 2.3E-01 2.5E+00 8.0E+00
Na SWA-L05-1316-B01-A 1 1.25E+OOU1/2 1.25E+00 5.0E+01 2.5E+00 8.0E+00
Na SWA-L05-1316-B02-A 1 1.25E+OOU1/2 1.25E+00 5.6E+01 2.5E+00 8.0E+00
Na SWA-L05-1316-B03-A 1 1.25E+OOU1/2 1.25E+00 3.8E+01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
4.79E+05 84% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
4.80E+05 89% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
4.75E+05 87% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1389
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-L05-1316-T01-A 1
SWA-L05-1316-T02-A 1
SWA-L05-1316-T03-A 1
SWA-L05-1316-T04-A 1
SWA-L05-1316-T05-A 1
SWA-L05-1316-T01-B 1
SWA-L05-1316-T02-B 1
SWA-L05-1316-T03-B 1
SWA-L05-1316-T04-B 1
SWA-L05-1316-T05-B 1
SWA-L05-1316-T01-C 1
SWA-L05-1316-T02-C 1
SWA-L05-1316-T03-C 1
SWA-L05-1316-T04-C 1
SWA-L05-1316-T05-C 1
SWA-L05-1316-B01-A 1
SWA-L05-1316-B02-A 1
SWA-L05-1316-B03-A 1
Sample I
Cone. Qualifier
ug/L I
2.37E+02
2.50E+02
2.98E+02
3.41 E+02
4.12E+02
2.48E+02
2.43E+02
2.96E+02
3.41 E+02
4.01 E+02
2.36E+02
2.52E+02
2.94E+02
3.41 E+02
4.04E+02
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.37E+02 8.7E-01 1.0E+00 3.2E+00
2.50E+02 5.7E-01 1.0E+00 3.2E+00 1000 100
2.98E+02 4.6E-01 1.0E+00 3.2E+00
3.41 E+02 8.3E+01 1.0E+00 3.2E+00
4.12E+02 2.7E-01 1.0E+00 3.2E+00
2.48E+02 1.0E+00 1.0E+00 3.2E+00
2.43E+02 7.4E-01 1.0E+00 3.2E+00 1000 100
2.96E+02 1.1E+00 1.0E+00 3.2E+00
3.41 E+02 5.8E-01 1.0E+00 3.2E+00
4.01 E+02 7.8E-01 1.0E+00 3.2E+00
2.36E+02 5.5E-01 1.0E+00 3.2E+00
2.52E+02 3.6E-02 1.0E+00 3.2E+00 1000 100
2.94E+02 1.4E+02 1.0E+00 3.2E+00
3.41 E+02 1.4E+00 1.0E+00 3.2E+00
4.04E+02 1.1E+00 1.0E+00 3.2E+00
5.00E-01 9.1 E+02 1.0E+00 3.2E+00
5.00E-01 5.5E+01 1.0E+00 3.2E+00
5.00E-01 1.1E+03 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.15E+03 90% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
1.16E+03 92% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.18E+03 93% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1390
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
S SWA-L05-1316-T01-A 1 3.00E+05
S SWA-L05-1316-T02-A 1 4.62E+05
S SWA-L05-1316-T03-A 1 9.67E+05
S SWA-L05-1316-T04-A 1 1.57E+06
S SWA-L05-1316-T05-A 1 2.52E+06
S SWA-L05-1316-T01-B 1 3.04E+05
S SWA-L05-1316-T02-B 1 4.55E+05
S SWA-L05-1316-T03-B 1 9.56E+05
S SWA-L05-1316-T04-B 1 1.53E+06
S SWA-L05-1316-T05-B 1 2.48E+06
S SWA-L05-1316-T01-C 1 2.75E+05
S SWA-L05-1316-T02-C 1 4.70E+05
S SWA-L05-1316-T03-C 1 9.60E+05
S SWA-L05-1316-T04-C 1 1.59E+06
S SWA-L05-1316-T05-C 1 2.51E+06
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.00E+05 5.5E-01 6.8E+00 2.2E+01
4.62E+05 2.8E-01 6.8E+00 2.2E+01 1000 100
9.67E+05 7.2E-01 6.8E+00 2.2E+01
1.57E+06 9.4E+01 6.8E+00 2.2E+01
2.52E+06 3.3E-01 6.8E+00 2.2E+01
3.04E+05 5.3E-01 6.8E+00 2.2E+01
4.55E+05 8.7E-01 6.8E+00 2.2E+01 1000 100
9.56E+05 8.0E-01 6.8E+00 2.2E+01
1.53E+06 8.1E-01 6.8E+00 2.2E+01
2.48E+06 7.8E-01 6.8E+00 2.2E+01
2.75E+05 3.5E-01 6.8E+00 2.2E+01
4.70E+05 5.3E-01 6.8E+00 2.2E+01 1000 100
9.60E+05 1.4E+02 6.8E+00 2.2E+01
1.59E+06 5.2E-01 6.8E+00 2.2E+01
2.51E+06 1.0E+00 6.8E+00 2.2E+01
S SWA-L05-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 1.1E+01 6.8E+00 2.2E+01
S SWA-L05-1316-B02-A 1 3.40E+00 U1/2 3.40E+00 1 .6E+01 6.8E+00 2.2E+01
S SWA-L05-1316-B03-A 1 3.40E+00 U1/2 3.40E+00 1 .4E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
4.63E+05 88% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
4.56E+05 86% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
4.71E+05 85% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1391
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L05-1316-T01-A 1 2.30E+00 U1/2 2.30E+00 1 .4E+02 4.6E+00 1.5E+01
Tl SWA-L05-1316-T02-A 1 2.30E+00 U1/2 2.30E+00 6.5E+02 4.6E+00 1.5E+01 10 100
Tl SWA-L05-1316-T03-A 1 2.30E+00 U1/2 2.30E+00 1 .5E+02 4.6E+00 1.5E+01
Tl SWA-L05-1316-T04-A 1 2.30E+00 U1/2 2.30E+00 1 .4E+03 4.6E+00 1.5E+01
Tl SWA-L05-1316-T05-A 1 6.68E+00 E
6.68E+00 6.6E+01 4.6E+00 1 .5E+01
Tl SWA-L05-1316-T01-B 1 2.30E+00 U1/2 2.30E+00 1 .OE+02 4.6E+00 1 .5E+01
Tl SWA-L05-1316-T02-B 1 2.30E+00 U1/2 2.30E+00 2.4E+02 4.6E+00 1 .5E+01 10 100
Tl SWA-L05-1316-T03-B 1 2.30E+00 U1/2 2.30E+00 1 .2E+02 4.6E+00 1 .5E+01
Tl SWA-L05-1316-T04-B 1 2.30E+00 U1/2 2.30E+00 1 .6E+02 4.6E+00 1 .5E+01
Tl SWA-L05-1316-T05-B 1 6.17E+00 E
6.17E+00 1.3E+02 4.6E+00 1 .5E+01
Tl SWA-L05-1316-T01-C 1 2.30E+00 U1/2 2.30E+00 3.8E+02 4.6E+00 1 .5E+01
Tl SWA-L05-1316-T02-C 1 2.30E+00 U1/2 2.30E+00 8.7E+01 4.6E+00 1 .5E+01 10 100
Tl SWA-L05-1316-T03-C 1 2.30E+00 U1/2 2.30E+00 1 .6E+02 4.6E+00 1 .5E+01
Tl SWA-L05-1316-T04-C 1 2.30E+00 U1/2 2.30E+00 1 .8E+02 4.6E+00 1 .5E+01
Tl SWA-L05-1316-T05-C 1 6.65E+00 E
6.65E+00 8.3E+00 4.6E+00 1 .5E+01
Tl SWA-L05-1316-B01-A 1 2.30E+00 U1/2 2.30E+00 3.8E+02 4.6E+00 1 .5E+01
Tl SWA-L05-1316-B02-A 1 2.30E+00 U1/2 2.30E+00 1 .2E+01 4.6E+00 1 .5E+01
Tl SWA-L05-1316-B03-A 1 2.30E+00 U1/2 2.30E+00 2.8E+02 4.6E+00 1 .5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
9.76E+02 97% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
9.36E+02 93% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
9.50E+02 95% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1392
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L05-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 4.8E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 3.2E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L05-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 1 .3E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-T04-A 1 1.00E+OOU1/2 1.00E+00 3.6E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-T05-A 1 2.86E+00 E
2.86E+00 4.8E+00 2.0E+00 6.4E+00
Ti SWA-L05-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 2.5E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 1 .2E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L05-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 3.5E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-T04-B 1 1.00E+OOU1/2 1.00E+00 1 JE+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-T05-B 1 2.60E+00 E
2.60E+00 6.9E+00 2.0E+00 6.4E+00
Ti SWA-L05-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 2.2E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 4.4E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L05-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 2.1E+02 2.0E+00 6.4E+00
Ti SWA-L05-1316-T04-C 1 1.00E+OOU1/2 1.00E+00 2.4E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-T05-C 1 2.53E+00 E
2.53E+00 1.9E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 5.0E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-B02-A 1 1.00E+OOU1/2 1.00E+00 6.2E+01 2.0E+00 6.4E+00
Ti SWA-L05-1316-B03-A 1 1.00E+OOU1/2 1.00E+00 5.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.12E+03 112% VUICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
9.86E+02 99% VUICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.03E+03 103% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1393
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
V SWA-L05-1316-T01-A 1 3.14E+02
V SWA-L05-1316-T02-A 1 5.43E+02
V SWA-L05-1316-T03-A 1 1.10E+03
V SWA-L05-1316-T04-A 1 1.41E+03
V SWA-L05-1316-T05-A 1 2.84E+03
V SWA-L05-1316-T01-B 1 3.04E+02
V SWA-L05-1316-T02-B 1 5.80E+02
V SWA-L05-1316-T03-B 1 1.10E+03
V SWA-L05-1316-T04-B 1 1.69E+03
V SWA-L05-1316-T05-B 1 2.78E+03
V SWA-L05-1316-T01-C 1 2.98E+02
V SWA-L05-1316-T02-C 1 5.44E+02
V SWA-L05-1316-T03-C 1 1.06E+03
V SWA-L05-1316-T04-C 1 1.72E+03
V SWA-L05-1316-T05-C 1 2.82E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.14E+02 1.8E+00 1.5E+00 4.8E+00
5.43E+02 1.1E-01 1.5E+00 4.8E+00 10 100
1.10E+03 8.5E-01 1.5E+00 4.8E+00
1.41E+03 8.4E+01 1.5E+00 4.8E+00
2.84E+03 5.7E-01 1.5E+00 4.8E+00
3.04E+02 1.6E+00 1.5E+00 4.8E+00
5.80E+02 1.2E+00 1.5E+00 4.8E+00 10 100
1.10E+03 1.2E+00 1.5E+00 4.8E+00
1.69E+03 1.1E+00 1.5E+00 4.8E+00
2.78E+03 7.1E-01 1.5E+00 4.8E+00
2.98E+02 4.8E+00 1.5E+00 4.8E+00
5.44E+02 1.2E+00 1.5E+00 4.8E+00 10 100
1.06E+03 1.4E+02 1.5E+00 4.8E+00
1.72E+03 7.8E-01 1.5E+00 4.8E+00
2.82E+03 9.8E-01 1.5E+00 4.8E+00
V SWA-L05-1316-B01-A 1 7.50E-01 U1/2 7.50E-01 5.8E+01 1.5E+00 4.8E+00
V SWA-L05-1316-B02-A 1 2.02E+00 E 2.02E+00 5.3E+01 1.5E+00 4.8E+00
V SWA-L05-1316-B03-A 1 1.80E+OOE 1.80E+00 3.8E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.58E+03 104% VU ICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
1.52E+03 94% VU ICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
1.51E+03 97% VU ICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:17 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1394
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qu
1 1 ug/L
Zn SWA-L05-1316-T01-A 1 1.92E+OOE
Zn SWA-L05-1316-T02-A 1 2.76E+00 E
Zn SWA-L05-1316-T03-A 1 5.99E+00
Zn SWA-L05-1316-T04-A 1 1.22E+01
Zn SWA-L05-1316-T05-A 1 2.75E+01
Zn SWA-L05-1316-T01-B 1 1.45E+OOE
Zn SWA-L05-1316-T02-B 1 3.70E+00
Zn SWA-L05-1316-T03-B 1 6.12E+00
Zn SWA-L05-1316-T04-B 1 1.25E+01
Zn SWA-L05-1316-T05-B 1 3.02E+01
Zn SWA-L05-1316-T01-C 1 1.89E+OOE
Zn SWA-L05-1316-T02-C 1 3.08E+00 E
Zn SWA-L05-1316-T03-C 1 5.41 E+00
Zn SWA-L05-1316-T04-C 1 1.17E+01
Zn SWA-L05-1316-T05-C 1 3.13E+01
Zn SWA-L05-1316-B01-A 1 2.07E+00 E
Zn SWA-L05-1316-B02-A 1 1.45E+OOE
Zn SWA-L05-1316-B03-A 1 2.20E+00 E
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.92E+00 1.0E+01 1.0E+00 3.2E+00
2.76E+00 5.0E+00 1.0E+00 3.2E+00 10 100
5.99E+00 4.1 E+00 1.0E+00 3.2E+00
1.22E+01 8.7E+01 1.0E+00 3.2E+00
2.75E+01 4.3E+00 1.0E+00 3.2E+00
1.45E+00 1.9E+01 1.0E+00 3.2E+00
3.70E+00 2.6E+00 1.0E+00 3.2E+00 10 100
6.12E+00 6.4E+00 1.0E+00 3.2E+00
1.25E+01 4.5E-01 1.0E+00 3.2E+00
3.02E+01 2.6E+00 1.0E+00 3.2E+00
1.89E+00 1.4E+01 1.0E+00 3.2E+00
3.08E+00 9.0E+00 1.0E+00 3.2E+00 10 100
5.41 E+00 1.5E+02 1.0E+00 3.2E+00
1.17E+01 5.2E+00 1.0E+00 3.2E+00
3.13E+01 4.1E+00 1.0E+00 3.2E+00
2.07E+00 1.8E+01 1.0E+00 3.2E+00
1.45E+00 5.7E+00 1.0E+00 3.2E+00
2.20E+00 1.7E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/7/11 1:54 PM EPA Interlab LOS 1313-1316 SWA
1.01E+03 101% VUICP-OES 3/7/11 1:56 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:58 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:59 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 2:01 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:03 PM EPA Interlab LOS 1313-1316 SWA
9.75E+02 97% VUICP-OES 3/7/11 2:04 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:06 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:08 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:09 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:11 PM EPA Interlab LOS 1313-1316 SWA
9.95E+02 99% VUICP-OES 3/7/11 2:13 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:14 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:16 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 2:1 7PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:49 PM EPA Interlab LOS 1313-1316 SWA
VU ICP-OES 3/7/11 1:51 PM EPA Interlab LOS 1313-1316 SWA
VUICP-OES 3/7/11 1:53 PM EPA Interlab LOS 1313-1316 SWA
                                                                                                                                                                         1-1395
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al SWA-L06-1316-T01-A 1 3.87E+04
Al SWA-L06-1316-T02-A 1 5.78E+04
Al SWA-L06-1316-T03-A 1 7.12E+04
Al SWA-L06-1316-T04-A 1 1.55E+05
Al SWA-L06-1316-T01-B 1 3.84E+04
Al SWA-L06-1316-T02-B 1 5.82E+04
Al SWA-L06-1316-T03-B 1 7.36E+04
Al SWA-L06-1316-T04-B 1 1.55E+05
Al SWA-L06-1316-T01-C 1 3.81 E+04
Al SWA-L06-1316-T02-C 1 5.70E+04
Al SWA-L06-1316-T03-C 1 7.18E+04
Al SWA-L06-1316-T04-C 1 1.54E+05
Al SWA-L06-1316-B01-A 1 5.00E-01 U1/2
Al SWA-L06-1316-B01-B 1 5.00E-01 U1/2
Al SWA-L06-1316-B01-C 1 1.06E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.87E+04 5.8E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
5.78E+04 4.6E-01 1 .OE+00 3.2E+00 1000 100 5.86E+04 87% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
7.12E+04 3.7E-01 1 .OE+00 3.2E+00
1.55E+05 1.8E-01 1 .OE+00 3.2E+00
3.84E+04 5.7E-01 1 .OE+00 3.2E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
5.82E+04 1.1E+00 1 .OE+00 3.2E+00 1000 100 5.91E+04 93% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
7.36E+04 4.4E-01 1 .OE+00 3.2E+00
1.55E+05 1.1E+00 1. OE+00 3.2E+00
3.81 E+04 1.2E+00 1 .OE+00 3.2E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
5.70E+04 1.2E+00 1 .OE+00 3.2E+00 1000 100 5.79E+04 89% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
7.18E+04 7.4E-01 1 .OE+00 3.2E+00
1.54E+05 4.7E-01 1 .OE+00 3.2E+00
5.00E-01 1.9E+03 1 .OE+00 3.2E+00
5.00E-01 1.4E+02 1 .OE+00 3.2E+00
1.06E+00 7.9E+01 1 .OE+00 3.2E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                                 1-1396
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb SWA-L06-1316-T01-A 1 4.77E+03
Sb SWA-L06-1316-T02-A 1 3.28E+03
Sb SWA-L06-1316-T03-A 1 8.88E+03
Sb SWA-L06-1316-T04-A 1 8.61E+03
Sb SWA-L06-1316-T01-B 1 4.27E+03
Sb SWA-L06-1316-T02-B 1 3.86E+03
Sb SWA-L06-1316-T03-B 1 9.49E+03
Sb SWA-L06-1316-T04-B 1 8.85E+03
Sb SWA-L06-1316-T01-C 1 4.16E+03
Sb SWA-L06-1316-T02-C 1 3.23E+03
Sb SWA-L06-1316-T03-C 1 9.50E+03
Sb SWA-L06-1316-T04-C 1 8.92E+03
Sb SWA-L06-1316-B01-A 1 3.75E+00 U1/2
Sb SWA-L06-1316-B01-B 1 3.75E+00 U1/2
Sb SWA-L06-1316-B01-C 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.77E+03 8.6E-01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 3:49 PM EPA Interlab 1316 SWA Reruns
3.28E+03 9.5E-01 7.5E+00 2.4E+01 10 100 4.17E+03 89% VU ICP-OES 5/23/11 3:51 PM EPA Interlab 1316 SWA Reruns
8.88E+03 1.6E-01 7.5E+00 2.4E+01
8.61 E+03 4.7E-01 7.5E+00 2.4E+01
4.27E+03 6.2E-01 7.5E+00 2.4E+01
VU ICP-OES 5/23/11 3:53 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:56 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:58 PM EPA Interlab 1316 SWA Reruns
3.86E+03 4.0E+00 7.5E+00 2.4E+01 10 100 4.72E+03 86% VU ICP-OES 5/23/11 4:00 PM EPA Interlab 1316 SWA Reruns
9.49E+03 1.2E+00 7.5E+00 2.4E+01
8.85E+03 1.8E+00 7.5E+00 2.4E+01
4.16E+03 1.8E+00 7.5E+00 2.4E+01
VU ICP-OES 5/23/11 4:02 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:05 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:07 PM EPA Interlab 1316 SWA Reruns
3.23E+03 3.0E+00 7.5E+00 2.4E+01 10 100 4.16E+03 92% VU ICP-OES 5/23/11 4:09 PM EPA Interlab 1316 SWA Reruns
9.50E+03 1.1E+00 7.5E+00 2.4E+01
8.92E+03 9.6E-01 7.5E+00 2.4E+01
3.75E+00 2.4E+02 7.5E+00 2.4E+01
3.75E+00 2.2E+02 7.5E+00 2.4E+01
3.75E+00 2.3E+02 7.5E+00 2.4E+01
VU ICP-OES 5/23/11 4:12 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:14 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1397
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
ug/L
As SWA-L06-1316-T01-A 1 5.00E+03
As SWA-L06-1316-T02-A 1 1.27E+04
As SWA-L06-1316-T03-A 1 4.09E+04
As SWA-L06-1316-T04-A 1 1.04E+05
As SWA-L06-1316-T01-B 1 4.89E+03
As SWA-L06-1316-T02-B 1 1.17E+04
As SWA-L06-1316-T03-B 1 4.12E+04
As SWA-L06-1316-T04-B 1 1.09E+05
As SWA-L06-1316-T01-C 1 4.91 E+03
As SWA-L06-1316-T02-C 1 1.26E+04
As SWA-L06-1316-T03-C 1 4.13E+04
As SWA-L06-1316-T04-C 1 1.06E+05
As SWA-L06-1316-B01-A 1 5.50E+00 U1/2
As SWA-L06-1316-B01-B 1 5.50E+00 U1/2
As SWA-L06-1316-B01-C 1 5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E+03 6.6E-01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.27E+04 1.4E+00 1.1E+01 3.5E+01 10 100 1 .37E+04 92% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
4.09E+04 2.5E-01 1.1E+01 3.5E+01
1.04E+05 6.3E-01 1.1E+01 3.5E+01
4.89E+03 2.9E-01 1.1E+01 3.5E+01
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.17E+04 1.2E+00 1.1E+01 3.5E+01 10 100 1 .26E+04 90% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
4.12E+04 4.9E-01 1.1E+01 3.5E+01
1.09E+05 1.7E+00 1.1E+01 3.5E+01
4.91 E+03 1.1E+00 1.1E+01 3.5E+01
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.26E+04 1.7E+00 1.1E+01 3.5E+01 10 100 1 .34E+04 87% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
4.13E+04 1.2E+00 1.1E+01 3.5E+01
1.06E+05 5.3E-01 1.1E+01 3.5E+01
5.50E+00 1.9E+02 1.1E+01 3.5E+01
5.50E+00 2.2E+02 1.1E+01 3.5E+01
5.50E+00 1.1E+02 1.1E+01 3.5E+01
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1398
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B SWA-L06-1316-T01-A 1 1.16E+03
B SWA-L06-1316-T02-A 1 1.79E+03
B SWA-L06-1316-T03-A 1 2.08E+03
B SWA-L06-1316-T04-A 1 2.75E+03
B SWA-L06-1316-T01-B 1 1.15E+03
B SWA-L06-1316-T02-B 1 1.89E+03
B SWA-L06-1316-T03-B 1 2.31E+03
B SWA-L06-1316-T04-B 1 3.15E+03
B SWA-L06-1316-T01-C 1 1.13E+03
B SWA-L06-1316-T02-C 1 1.77E+03
B SWA-L06-1316-T03-C 1 2.09E+03
B SWA-L06-1316-T04-C 1 2.76E+03
B SWA-L06-1316-B01-A 1 4.53E+00
B SWA-L06-1316-B01-B 1 3.44E+00
B SWA-L06-1316-B01-C 1 4.75E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.16E+03 3.6E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.79E+03 8.7E-02 1 .OE+00 3.2E+00 1000 100 2.80E+03 101% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
2.08E+03 1.9E-01 1 .OE+00 3.2E+00
2.75E+03 5.3E-01 1 .OE+00 3.2E+00
1.15E+03 1.8E-01 1. OE+00 3.2E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.89E+03 1.6E+00 1 .OE+00 3.2E+00 1000 100 2.86E+03 97% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
2.31E+03 1.1E+00 1.0E+00 3.2E+00
3.15E+03 7.5E-01 1 .OE+00 3.2E+00
1.13E+03 1.1E+00 1.0E+00 3.2E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.77E+03 2.0E-01 1 .OE+00 3.2E+00 1000 100 2.95E+03 118% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
2.09E+03 4.4E-01 1 .OE+00 3.2E+00
2.76E+03 8.8E-01 1 .OE+00 3.2E+00
4.53E+00 4.9E+00 1 .OE+00 3.2E+00
3.44E+00 2.2E+01 1 .OE+00 3.2E+00
4.75E+00 6.9E+00 1 .OE+00 3.2E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1399
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba SWA-L06-1316-T01-A 1 2.36E+02
Ba SWA-L06-1316-T02-A 1 2.17E+02
Ba SWA-L06-1316-T03-A 1 4.76E+01
Ba SWA-L06-1316-T04-A 1 7.45E+01
Ba SWA-L06-1316-T01-B 1 2.39E+02
Ba SWA-L06-1316-T02-B 1 1.91E+02
Ba SWA-L06-1316-T03-B 1 6.91 E+01
Ba SWA-L06-1316-T04-B 1 7.25E+01
Ba SWA-L06-1316-T01-C 1 2.45E+02
Ba SWA-L06-1316-T02-C 1 2.16E+02
Ba SWA-L06-1316-T03-C 1 3.99E+01
Ba SWA-L06-1316-T04-C 1 7.28E+01
Ba SWA-L06-1316-B01-A 1 5.00E-01 U1/2
Ba SWA-L06-1316-B01-B 1 5.00E-01 U1/2
Ba SWA-L06-1316-B01-C 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.36E+02 6.4E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 3:49 PM EPA Interlab 1316 SWA Reruns
2.17E+02 2.7E-01 1 .OE+00 3.2E+00 10 100 1.16E+03 94% VU ICP-OES 5/23/11 3:51 PM EPA Interlab 1316 SWA Reruns
4.76E+01 4.8E+00 1 .OE+00 3.2E+00
7.45E+01 6.3E-01 1 .OE+00 3.2E+00
2.39E+02 8.1E-01 1 .OE+00 3.2E+00
VU ICP-OES 5/23/11 3:53 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:56 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:58 PM EPA Interlab 1316 SWA Reruns
1.91E+02 1.3E+00 1.0E+00 3.2E+00 10 100 1.12E+03 93% VU ICP-OES 5/23/11 4:00 PM EPA Interlab 1316 SWA Reruns
6.91 E+01 2.0E+00 1 .OE+00 3.2E+00
7.25E+01 2.1E-01 1 .OE+00 3.2E+00
2.45E+02 9.5E-01 1 .OE+00 3.2E+00
VU ICP-OES 5/23/11 4:02 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:05 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:07 PM EPA Interlab 1316 SWA Reruns
2.16E+02 1.0E+00 1 .OE+00 3.2E+00 10 100 1.15E+03 94% VU ICP-OES 5/23/11 4:09 PM EPA Interlab 1316 SWA Reruns
3.99E+01 1.8E+00 1. OE+00 3.2E+00
7.28E+01 5.0E-01 1. OE+00 3.2E+00
5.00E-01 4.9E+00 1. OE+00 3.2E+00
5.00E-01 3.0E+01 1. OE+00 3.2E+00
5.00E-01 3.2E+01 1. OE+00 3.2E+00
VU ICP-OES 5/23/11 4:12 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:14 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1400
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be SWA-L06-1316-T01-A 1 9.50E-01 U1/2
Be SWA-L06-1316-T02-A 1 9.50E-01 U1/2
Be SWA-L06-1316-T03-A 1 9.50E-01 U1/2
Be SWA-L06-1316-T04-A 1 9.50E-01 U1/2
Be SWA-L06-1316-T01-B 1 9.50E-01 U1/2
Be SWA-L06-1316-T02-B 1 9.50E-01 U1/2
Be SWA-L06-1316-T03-B 1 9.50E-01 U1/2
Be SWA-L06-1316-T04-B 1 9.50E-01 U1/2
Be SWA-L06-1316-T01-C 1 9.50E-01 U1/2
Be SWA-L06-1316-T02-C 1 9.50E-01 U1/2
Be SWA-L06-1316-T03-C 1 9.50E-01 U1/2
Be SWA-L06-1316-T04-C 1 9.50E-01 U1/2
Be SWA-L06-1316-B01-A 1 9.50E-01 U1/2
Be SWA-L06-1316-B01-B 1 9.50E-01 U1/2
Be SWA-L06-1316-B01-C 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 7.4E+01 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
9.50E-01 2.3E+02 1 .9E+00 6.0E+00 10 100 1.13E+03 113% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
9.50E-01 9.5E+01 1 .9E+00 6.0E+00
9.50E-01 2.2E+01 1 .9E+00 6.0E+00
9.50E-01 9.1E-01 1.9E+00 6.0E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
9.50E-01 1.9E+01 1.9E+00 6.0E+00 10 100 1.20E+03 119% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
9.50E-01 2.4E+01 1 .9E+00 6.0E+00
9.50E-01 6.9E+01 1 .9E+00 6.0E+00
9.50E-01 1.5E+01 1.9E+00 6.0E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
9.50E-01 2.2E+01 1.9E+00 6.0E+00 10 100 1.13E+03 113% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
9.50E-01 6.2E+02 1.9E+00 6.0E+00
9.50E-01 6.0E+01 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
9.50E-01 8.4E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1401
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cd Sample Dilution Cone. Qualifier Revi
ug/L
Cd SWA-L06-1316-T01-A 1 1.10E+OOU1/2
Cd SWA-L06-1316-T02-A 1 1.10E+OOU1/2
Cd SWA-L06-1316-T03-A 1 1.10E+OOU1/2
Cd SWA-L06-1316-T04-A 1 1.10E+OOU1/2
Cd SWA-L06-1316-T01-B 1 1.10E+OOU1/2
Cd SWA-L06-1316-T02-B 1 1.10E+OOU1/2
Cd SWA-L06-1316-T03-B 1 1.10E+OOU1/2
Cd SWA-L06-1316-T04-B 1 1.10E+OOU1/2
Cd SWA-L06-1316-T01-C 1 1.10E+OOU1/2
Cd SWA-L06-1316-T02-C 1 1.10E+OOU1/2
Cd SWA-L06-1316-T03-C 1 1.10E+OOU1/2
Cd SWA-L06-1316-T04-C 1 1.10E+OOU1/2
Cd SWA-L06-1316-B01-A 1 1.10E+OOU1/2
Cd SWA-L06-1316-B01-B 1 1.10E+OOU1/2
Cd SWA-L06-1316-B01-C 1 1.10E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 5.5E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.10E+00 7.8E+00 2.2E+00 7.0E+00 10 100 1.16E+03 116% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
1.10E+00 2.1E+03 2.2E+00 7.0E+00
1.10E+00 1.2E+03 2.2E+00 7.0E+00
1.10E+00 2.4E+02 2.2E+00 7.0E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.10E+00 8.0E+01 2.2E+00 7.0E+00 10 100 1.12E+03 112% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
1.10E+00 5.4E+01 2.2E+00 7.0E+00
1.10E+00 2.9E+02 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.10E+00 1.1E+02 2.2E+00 7.0E+00 10 100 1.15E+03 115% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
1.10E+00 4.0E+01 2.2E+00 7.0E+00
1.10E+00 5.1E+02 2.2E+00 7.0E+00
1.10E+00 5.1E+03 2.2E+00 7.0E+00
1.10E+00 9.3E+01 2.2E+00 7.0E+00
1.10E+00 4.7E+02 2.2E+00 7.0E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1402
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca SWA-L06-1316-T01-A 1 1.32E+04
Ca SWA-L06-1316-T02-A 1 1.04E+04
Ca SWA-L06-1316-T03-A 1 3.57E+03
Ca SWA-L06-1316-T04-A 1 6.68E+03
Ca SWA-L06-1316-T01-B 1 1.32E+04
Ca SWA-L06-1316-T02-B 1 1.02E+04
Ca SWA-L06-1316-T03-B 1 3.63E+03
Ca SWA-L06-1316-T04-B 1 6.65E+03
Ca SWA-L06-1316-T01-C 1 1.32E+04
Ca SWA-L06-1316-T02-C 1 1.03E+04
Ca SWA-L06-1316-T03-C 1 3.35E+03
Ca SWA-L06-1316-T04-C 1 7.02E+03
Ca SWA-L06-1316-B01-A 1 6.21E+00 E
Ca SWA-L06-1316-B01-B 1 1.30E+OOU1/2
Ca SWA-L06-1316-B01-C 1 5.34E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.32E+04 3.2E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 3:49 PM EPA Interlab 1316 SWA Reruns
1.04E+04 7.4E-01 2.6E+00 8.3E+00 1000 100 1.13E+04 92% VU ICP-OES 5/23/11 3:51 PM EPA Interlab 1316 SWA Reruns
3.57E+03 1.6E+00 2.6E+00 8.3E+00
6.68E+03 5.3E+00 2.6E+00 8.3E+00
1.32E+04 1.4E+00 2.6E+00 8.3E+00
VU ICP-OES 5/23/11 3:53 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:56 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:58 PM EPA Interlab 1316 SWA Reruns
1.02E+04 1.5E+00 2.6E+00 8.3E+00 1000 100 1.11E+04 88% VU ICP-OES 5/23/11 4:00 PM EPA Interlab 1316 SWA Reruns
3.63E+03 2.1E+00 2.6E+00 8.3E+00
6.65E+03 2.9E+00 2.6E+00 8.3E+00
1.32E+04 1.0E+00 2.6E+00 8.3E+00
VU ICP-OES 5/23/11 4:02 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:05 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:07 PM EPA Interlab 1316 SWA Reruns
1.03E+04 1.2E-01 2.6E+00 8.3E+00 1000 100 1.12E+04 93% VU ICP-OES 5/23/11 4:09 PM EPA Interlab 1316 SWA Reruns
3.35E+03 1.6E+00 2.6E+00 8.3E+00
7.02E+03 4.0E+00 2.6E+00 8.3E+00
6.21 E+00 1.1E+01 2.6E+00 8.3E+00
1.30E+00 1.2E+02 2.6E+00 8.3E+00
5.34E+00 7.3E+01 2.6E+00 8.3E+00
VU ICP-OES 5/23/11 4:12 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:14 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1403
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qualifier
ug/L
Cr SWA-L06-1316-T01-A 1 1.11E+03
Cr SWA-L06-1316-T02-A 1 1.79E+03
Cr SWA-L06-1316-T03-A 1 1.33E+03
Cr SWA-L06-1316-T04-A 1 2.02E+03
Cr SWA-L06-1316-T01-B 1 1.10E+03
Cr SWA-L06-1316-T02-B 1 1.83E+03
Cr SWA-L06-1316-T03-B 1 1.48E+03
Cr SWA-L06-1316-T04-B 1 2.03E+03
Cr SWA-L06-1316-T01-C 1 1.10E+03
Cr SWA-L06-1316-T02-C 1 1.77E+03
Cr SWA-L06-1316-T03-C 1 1.36E+03
Cr SWA-L06-1316-T04-C 1 2.06E+03
Cr SWA-L06-1316-B01-A 1 6.00E-01 U1/2
Cr SWA-L06-1316-B01-B 1 6.00E-01 U1/2
Cr SWA-L06-1316-B01-C 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.11E+03 8.5E-01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.79E+03 8.1E-01 1 .2E+00 3.8E+00 10 100 2.70E+03 91%VUICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
1.33E+03 7.0E-01 1.2E+00 3.8E+00
2.02E+03 2.4E-01 1.2E+00 3.8E+00
1.10E+03 1.2E+00 1.2E+00 3.8E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.83E+03 5.3E-01 1.2E+00 3.8E+00 10 100 2.76E+03 93% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
1.48E+03 8.8E-01 1.2E+00 3.8E+00
2.03E+03 1.0E+00 1.2E+00 3.8E+00
1.10E+03 7.3E-01 1.2E+00 3.8E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.77E+03 1.0E+00 1.2E+00 3.8E+00 10 100 2.85E+03 108% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
1.36E+03 9.3E-01 1.2E+00 3.8E+00
2.06E+03 1.3E+00 1.2E+00 3.8E+00
6.00E-01 4.9E+01 1.2E+00 3.8E+00
6.00E-01 8.9E+01 1.2E+00 3.8E+00
6.00E-01 7.6E+01 1.2E+00 3.8E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1404
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Co Sample Dilution Cone. Qualifier Revi
ug/L
Co SWA-L06-1316-T01-A 1 9.00E-01 U1/2
Co SWA-L06-1316-T02-A 1 9.00E-01 U1/2
Co SWA-L06-1316-T03-A 1 3.42E+00 E
Co SWA-L06-1316-T04-A 1 4.90E+00 E
Co SWA-L06-1316-T01-B 1 9.00E-01 U1/2
Co SWA-L06-1316-T02-B 1 9.00E-01 U1/2
Co SWA-L06-1316-T03-B 1 2.32E+00 E
Co SWA-L06-1316-T04-B 1 6.18E+00
Co SWA-L06-1316-T01-C 1 9.00E-01 U1/2
Co SWA-L06-1316-T02-C 1 9.00E-01 U1/2
Co SWA-L06-1316-T03-C 1 2.86E+00 E
Co SWA-L06-1316-T04-C 1 4.87E+00 E
Co SWA-L06-1316-B01-A 1 9.00E-01 U1/2
Co SWA-L06-1316-B01-B 1 9.00E-01 U1/2
Co SWA-L06-1316-B01-C 1 9.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.5E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
9.00E-01 1.5E+03 1.8E+00 5.7E+00 10 100 1.13E+03 113% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
3.42E+00 1.2E+01 1.8E+00 5.7E+00
4.90E+00 4.8E+00 1.8E+00 5.7E+00
9.00E-01 3.1E+02 1.8E+00 5.7E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
9.00E-01 6.9E+01 1.8E+00 5.7E+00 10 100 1.10E+03 110% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
2.32E+00 2.3E+01 1.8E+00 5.7E+00
6.18E+00 1.2E+01 1.8E+00 5.7E+00
9.00E-01 2.1E+03 1.8E+00 5.7E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
9.00E-01 2.9E+02 1.8E+00 5.7E+00 10 100 1.12E+03 112% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
2.86E+00 1.3E+01 1.8E+00 5.7E+00
4.87E+00 6.0E+00 1.8E+00 5.7E+00
9.00E-01 2.6E+01 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
9.00E-01 5.8E+01 1.8E+00 5.7E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1405
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cu Sample Dilution Cone. Qualifier Revi
ug/L
Cu SWA-L06-1316-T01-A 1 1.85E+OOU1/2
Cu SWA-L06-1316-T02-A 1 3.93E+00 E
Cu SWA-L06-1316-T03-A 1 1.06E+01 E
Cu SWA-L06-1316-T04-A 1 4.69E+01
Cu SWA-L06-1316-T01-B 1 1.85E+OOU1/2
Cu SWA-L06-1316-T02-B 1 4.25E+00 E
Cu SWA-L06-1316-T03-B 1 1.08E+01 E
Cu SWA-L06-1316-T04-B 1 4.49E+01
Cu SWA-L06-1316-T01-C 1 1.85E+OOU1/2
Cu SWA-L06-1316-T02-C 1 4.65E+00 E
Cu SWA-L06-1316-T03-C 1 1.05E+01 E
Cu SWA-L06-1316-T04-C 1 4.70E+01
Cu SWA-L06-1316-B01-A 1 1.85E+OOU1/2
Cu SWA-L06-1316-B01-B 1 1.85E+OOU1/2
Cu SWA-L06-1316-B01-C 1 1.85E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 1.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
3.93E+00 1.9E+01 3.7E+00 1.2E+01 10 100 1.11E+03 110% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
1.06E+01 1.4E+01 3.7E+00 1.2E+01
4.69E+01 4.8E-01 3.7E+00 1.2E+01
1.85E+00 1.7E+01 3.7E+00 1.2E+01
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
4.25E+00 9.7E+00 3.7E+00 1.2E+01 10 100 1.03E+03 103% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
1.08E+01 5.0E-01 3.7E+00 1.2E+01
4.49E+01 3.4E+00 3.7E+00 1.2E+01
1.85E+00 1.0E+01 3.7E+00 1.2E+01
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
4.65E+00 1.0E+02 3.7E+00 1.2E+01 10 100 1.13E+03 113% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
1.05E+01 6.7E+00 3.7E+00 1.2E+01
4.70E+01 1.5E+00 3.7E+00 1.2E+01
1.85E+00 2.4E+01 3.7E+00 1.2E+01
1.85E+00 3.5E+01 3.7E+00 1.2E+01
1.85E+00 5.2E+01 3.7E+00 1.2E+01
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1406
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. Qualifier
ug/L
Fe SWA-L06-1316-T01-A 1 7.92E+01
Fe SWA-L06-1316-T02-A 1 1.59E+02
Fe SWA-L06-1316-T03-A 1 2.55E+02
Fe SWA-L06-1316-T04-A 1 8.67E+02
Fe SWA-L06-1316-T01-B 1 7.91 E+01
Fe SWA-L06-1316-T02-B 1 1.62E+02
Fe SWA-L06-1316-T03-B 1 2.38E+02
Fe SWA-L06-1316-T04-B 1 9.18E+02
Fe SWA-L06-1316-T01-C 1 7.82E+01
Fe SWA-L06-1316-T02-C 1 1.59E+02
Fe SWA-L06-1316-T03-C 1 2.57E+02
Fe SWA-L06-1316-T04-C 1 8.84E+02
Fe SWA-L06-1316-B01-A 1 1.00E+OOU1/2
Fe SWA-L06-1316-B01-B 1 1.00E+OOU1/2
Fe SWA-L06-1316-B01-C 1 1.00E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.92E+01 6.4E-01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.59E+02 5.5E-01 2.0E+00 6.4E+00 1000 100 1 .30E+03 114% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
2.55E+02 2.3E-01 2.0E+00 6.4E+00
8.67E+02 3.8E-01 2.0E+00 6.4E+00
7.91E+01 5.5E-01 2.0E+00 6.4E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.62E+02 1.7E+00 2.0E+00 6.4E+00 1000 100 1 .26E+03 110% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
2.38E+02 5.5E-01 2.0E+00 6.4E+00
9.18E+02 1.2E+00 2.0E+00 6.4E+00
7.82E+01 8.9E-01 2.0E+00 6.4E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.59E+02 9.5E-01 2.0E+00 6.4E+00 1000 100 1 .30E+03 114% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
2.57E+02 7.0E-01 2.0E+00 6.4E+00
8.84E+02 6.3E-01 2.0E+00 6.4E+00
1.00E+00 9.8E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1407
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb SWA-L06-1316-T01-A 1 1.55E+01 E
Pb SWA-L06-1316-T02-A 1 3.00E+01
Pb SWA-L06-1316-T03-A 1 6.86E+00 E
Pb SWA-L06-1316-T04-A 1 1.38E+02
Pb SWA-L06-1316-T01-B 1 1.86E+01 E
Pb SWA-L06-1316-T02-B 1 3.05E+01
Pb SWA-L06-1316-T03-B 1 7.12E+00 E
Pb SWA-L06-1316-T04-B 1 1.19E+02
Pb SWA-L06-1316-T01-C 1 1.94E+01 E
Pb SWA-L06-1316-T02-C 1 3.14E+01
Pb SWA-L06-1316-T03-C 1 9.19E+00 E
Pb SWA-L06-1316-T04-C 1 1.39E+02
Pb SWA-L06-1316-B01-A 1 3.40E+00 U1/2
Pb SWA-L06-1316-B01-B 1 3.40E+00 U1/2
Pb SWA-L06-1316-B01-C 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.55E+01 2.5E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
3.00E+01 9.5E+00 6.8E+00 2.2E+01 10 100 1.16E+03 1 13% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
6.86E+00 4.3E+01 6.8E+00 2.2E+01
1.38E+02 8.0E+00 6.8E+00 2.2E+01
1.86E+01 3.2E+01 6.8E+00 2.2E+01
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
3.05E+01 1.4E+01 6.8E+00 2.2E+01 10 100 1.12E+03 109% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
7.12E+00 1.5E+01 6.8E+00 2.2E+01
1.19E+02 7.0E+00 6.8E+00 2.2E+01
1.94E+01 2.9E+01 6.8E+00 2.2E+01
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
3.14E+01 1.4E+01 6.8E+00 2.2E+01 10 100 1.16E+03 1 13% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
9.19E+00 2.5E+01 6.8E+00 2.2E+01
1.39E+02 2.8E+00 6.8E+00 2.2E+01
3.40E+00 1.2E+02 6.8E+00 2.2E+01
3.40E+00 9.2E+01 6.8E+00 2.2E+01
3.40E+00 4.7E+02 6.8E+00 2.2E+01
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1408
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Li Sample Dilution Cone. Qualifier Revi
ug/L
Li SWA-L06-1316-T01-A 1 3.25E+00 E
Li SWA-L06-1316-T02-A 1 4.53E+00 E
Li SWA-L06-1316-T03-A 1 5.60E+00 E
Li SWA-L06-1316-T04-A 1 9.62E+00
Li SWA-L06-1316-T01-B 1 2.96E+00 E
Li SWA-L06-1316-T02-B 1 4.66E+00 E
Li SWA-L06-1316-T03-B 1 5.83E+00 E
Li SWA-L06-1316-T04-B 1 9.34E+00
Li SWA-L06-1316-T01-C 1 2.62E+00 E
Li SWA-L06-1316-T02-C 1 4.61E+00 E
Li SWA-L06-1316-T03-C 1 5.71E+00 E
Li SWA-L06-1316-T04-C 1 8.48E+00
Li SWA-L06-1316-B01-A 1 9.50E-01 U1/2
Li SWA-L06-1316-B01-B 1 9.50E-01 U1/2
Li SWA-L06-1316-B01-C 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.25E+00 9.1E+00 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
4.53E+00 5.7E+00 1 .9E+00 6.0E+00 10 100 9.23E+02 92% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
5.60E+00 4.3E+00 1 .9E+00 6.0E+00
9.62E+00 4.2E+00 1 .9E+00 6.0E+00
2.96E+00 7.5E+00 1 .9E+00 6.0E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
4.66E+00 3.6E+00 1 .9E+00 6.0E+00 10 100 8.95E+02 89% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
5.83E+00 1.5E+00 1 .9E+00 6.0E+00
9.34E+00 8.2E+00 1 .9E+00 6.0E+00
2.62E+00 4.3E+00 1 .9E+00 6.0E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
4.61E+00 1.1E+01 1.9E+00 6.0E+00 10 100 9.22E+02 92% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
5.71 E+00 8.5E+00 1 .9E+00 6.0E+00
8.48E+00 8.1 E+00 1 .9E+00 6.0E+00
9.50E-01 4.7E+00 1.9E+00 6.0E+00
9.50E-01 5.6E+00 1.9E+00 6.0E+00
9.50E-01 4.5E+00 1.9E+00 6.0E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1409
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn SWA-L06-1316-T01-A 1 1.00E+OOU1/2
Mn SWA-L06-1316-T02-A 1 1.00E+OOU1/2
Mn SWA-L06-1316-T03-A 1 1.00E+OOU1/2
Mn SWA-L06-1316-T04-A 1 2.96E+00 E
Mn SWA-L06-1316-T01-B 1 1.00E+OOU1/2
Mn SWA-L06-1316-T02-B 1 1.00E+OOU1/2
Mn SWA-L06-1316-T03-B 1 1.00E+OOU1/2
Mn SWA-L06-1316-T04-B 1 2.39E+00 E
Mn SWA-L06-1316-T01-C 1 1.00E+OOU1/2
Mn SWA-L06-1316-T02-C 1 1.00E+OOU1/2
Mn SWA-L06-1316-T03-C 1 1.00E+OOU1/2
Mn SWA-L06-1316-T04-C 1 2.61E+OOE
Mn SWA-L06-1316-B01-A 1 1.00E+OOU1/2
Mn SWA-L06-1316-B01-B 1 1.00E+OOU1/2
Mn SWA-L06-1316-B01-C 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.3E+00 2.0E+00 6.4E+00
1.00E+00 1.5E+00 2.0E+00 6.4E+00 10 100
1.00E+00 1.9E+01 2.0E+00 6.4E+00
2.96E+00 5.2E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00 10 100
1.00E+00 3.8E+01 2.0E+00 6.4E+00
2.39E+00 3.1E+00 2.0E+00 6.4E+00
1.00E+00 4.8E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+00 2.0E+00 6.4E+00 10 100
1.00E+00 1.5E+01 2.0E+00 6.4E+00
2.61 E+00 6.2E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 5.2E+01 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.13E+03 113% VUICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.11E+03 111% VUICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.13E+03 113% VUICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1410
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg SWA-L06-1316-T01-A 1 6.40E+00
Mg SWA-L06-1316-T02-A 1 6.68E+00
Mg SWA-L06-1316-T03-A 1 1.14E+01
Mg SWA-L06-1316-T04-A 1 1.02E+01
Mg SWA-L06-1316-T01-B 1 6.09E+00
Mg SWA-L06-1316-T02-B 1 6.52E+00
Mg SWA-L06-1316-T03-B 1 8.59E+00
Mg SWA-L06-1316-T04-B 1 9.35E+00
Mg SWA-L06-1316-T01-C 1 5.93E+00
Mg SWA-L06-1316-T02-C 1 6.04E+00
Mg SWA-L06-1316-T03-C 1 1.06E+01
Mg SWA-L06-1316-T04-C 1 8.84E+00
Mg SWA-L06-1316-B01-A 1 2.58E+00 E
Mg SWA-L06-1316-B01-B 1 5.00E-01 U1/2
Mg SWA-L06-1316-B01-C 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.40E+00 7.3E+01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
6.68E+00 1.4E+02 1 .OE+00 3.2E+00 1000 100 1 .07E+03 106% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
1.14E+01 5.3E+01 1. OE+00 3.2E+00
1.02E+01 4.0E+01 1. OE+00 3.2E+00
6.09E+00 6.3E+00 1 .OE+00 3.2E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
6.52E+00 2.3E+01 1 .OE+00 3.2E+00 1000 100 1.01E+03 100% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
8.59E+00 2.1E+02 1 .OE+00 3.2E+00
9.35E+00 2.8E+01 1 .OE+00 3.2E+00
5.93E+00 4.7E+01 1 .OE+00 3.2E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
6.04E+00 8.8E+01 1 .OE+00 3.2E+00 1000 100 1.05E+03 104% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
1.06E+01 1.6E+02 1. OE+00 3.2E+00
8.84E+00 2.2E+02 1. OE+00 3.2E+00
2.58E+00 1.8E+02 1. OE+00 3.2E+00
5.00E-01 4.2E+02 1. OE+00 3.2E+00
5.00E-01 2.2E+03 1. OE+00 3.2E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1411
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo SWA-L06-1316-T01-A 1 1.29E+02
Mo SWA-L06-1316-T02-A 1 1.93E+02
Mo SWA-L06-1316-T03-A 1 5.24E+02
Mo SWA-L06-1316-T04-A 1 1.04E+03
Mo SWA-L06-1316-T01-B 1 1.29E+02
Mo SWA-L06-1316-T02-B 1 1.80E+02
Mo SWA-L06-1316-T03-B 1 5.27E+02
Mo SWA-L06-1316-T04-B 1 1.07E+03
Mo SWA-L06-1316-T01-C 1 1.26E+02
Mo SWA-L06-1316-T02-C 1 1.91E+02
Mo SWA-L06-1316-T03-C 1 5.23E+02
Mo SWA-L06-1316-T04-C 1 1.04E+03
Mo SWA-L06-1316-B01-A 1 6.00E-01 U1/2
Mo SWA-L06-1316-B01-B 1 6.00E-01 U1/2
Mo SWA-L06-1316-B01-C 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.29E+02 7.1E-01 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.93E+02 4.3E-01 1 .2E+00 3.8E+00 10 100 1 .37E+03 117% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
5.24E+02 6.6E-01 1 .2E+00 3.8E+00
1.04E+03 1.7E-01 1.2E+00 3.8E+00
1.29E+02 6.3E-01 1 .2E+00 3.8E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.80E+02 1.3E+00 1 .2E+00 3.8E+00 10 100 1 .30E+03 112% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
5.27E+02 1.1E+00 1 .2E+00 3.8E+00
1.07E+03 6.9E-01 1 .2E+00 3.8E+00
1.26E+02 1.1E+00 1.2E+00 3.8E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.91E+02 8.3E-01 1 .2E+00 3.8E+00 10 100 1.35E+03 116% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
5.23E+02 5.0E-01 1.2E+00 3.8E+00
1.04E+03 2.6E-01 1.2E+00 3.8E+00
6.00E-01 2.5E+02 1.2E+00 3.8E+00
6.00E-01 5.6E+02 1.2E+00 3.8E+00
6.00E-01 5.3E+01 1.2E+00 3.8E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1412
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ni Sample Dilution Cone. Qualifier Revi
ug/L
Ni SWA-L06-1316-T01-A 1 9.00E-01 U1/2
Ni SWA-L06-1316-T02-A 1 9.00E-01 U1/2
Ni SWA-L06-1316-T03-A 1 2.53E+00 E
Ni SWA-L06-1316-T04-A 1 4.63E+00 E
Ni SWA-L06-1316-T01-B 1 9.00E-01 U1/2
Ni SWA-L06-1316-T02-B 1 9.00E-01 U1/2
Ni SWA-L06-1316-T03-B 1 2.42E+00 E
Ni SWA-L06-1316-T04-B 1 5.43E+00 E
Ni SWA-L06-1316-T01-C 1 9.00E-01 U1/2
Ni SWA-L06-1316-T02-C 1 9.00E-01 U1/2
Ni SWA-L06-1316-T03-C 1 2.61E+00 E
Ni SWA-L06-1316-T04-C 1 4.15E+00 E
Ni SWA-L06-1316-B01-A 1 9.00E-01 U1/2
Ni SWA-L06-1316-B01-B 1 9.00E-01 U1/2
Ni SWA-L06-1316-B01-C 1 9.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 5.2E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
9.00E-01 2.5E+01 1.8E+00 5.7E+00 10 100 1.13E+03 113% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
2.53E+00 3.6E+01 1.8E+00 5.7E+00
4.63E+00 3.3E+01 1.8E+00 5.7E+00
9.00E-01 7.3E+01 1.8E+00 5.7E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
9.00E-01 3.5E+01 1.8E+00 5.7E+00 10 100 1.09E+03 109% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
2.42E+00 1.5E+02 1.8E+00 5.7E+00
5.43E+00 2.9E+01 1.8E+00 5.7E+00
9.00E-01 6.9E+01 1.8E+00 5.7E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
9.00E-01 3.7E+01 1.8E+00 5.7E+00 10 100 1.12E+03 112% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
2.61 E+00 4.2E+01 1.8E+00 5.7E+00
4.15E+00 5.1E+01 1.8E+00 5.7E+00
9.00E-01 2.7E+01 1.8E+00 5.7E+00
9.00E-01 1.2E+02 1.8E+00 5.7E+00
9.00E-01 1.0E+02 1.8E+00 5.7E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1413
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P SWA-L06-1316-T01-A 1 3.98E+01
P SWA-L06-1316-T02-A 1 1.14E+02
P SWA-L06-1316-T03-A 1 4.19E+02
P SWA-L06-1316-T04-A 1 1.41E+03
P SWA-L06-1316-T01-B 1 4.11E+01
P SWA-L06-1316-T02-B 1 1.04E+02
P SWA-L06-1316-T03-B 1 4.01 E+02
P SWA-L06-1316-T04-B 1 1.41E+03
P SWA-L06-1316-T01-C 1 4.25E+01
P SWA-L06-1316-T02-C 1 1.02E+02
P SWA-L06-1316-T03-C 1 4.15E+02
P SWA-L06-1316-T04-C 1 1.39E+03
P SWA-L06-1316-B01-A 1 1.85E+OOU1/2
P SWA-L06-1316-B01-B 1 1.85E+OOU1/2
P SWA-L06-1316-B01-C 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.98E+01 3.9E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.14E+02 3.6E+00 3.7E+00 1.2E+01 1000 100 1.17E+03 106% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
4.19E+02 6.9E+00 3.7E+00 1.2E+01
1.41E+03 1.8E+00 3.7E+00 1.2E+01
4.11E+01 2.5E+01 3.7E+00 1.2E+01
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.04E+02 1.4E+01 3.7E+00 1.2E+01 1000 100 1.10E+03 100% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
4.01 E+02 2.3E+00 3.7E+00 1.2E+01
1.41E+03 1.7E+00 3.7E+00 1.2E+01
4.25E+01 1.9E+01 3.7E+00 1.2E+01
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.02E+02 6.3E+00 3.7E+00 1.2E+01 1000 100 1.12E+03 102% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
4.15E+02 3.5E+00 3.7E+00 1.2E+01
1.39E+03 1.9E+00 3.7E+00 1.2E+01
1.85E+00 2.9E+02 3.7E+00 1.2E+01
1.85E+00 5.6E+01 3.7E+00 1.2E+01
1.85E+00 1.1E+03 3.7E+00 1.2E+01
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1414
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
ug/L
K SWA-L06-1316-T01-A 1 3.30E+05
K SWA-L06-1316-T02-A 1 4.95E+05
K SWA-L06-1316-T03-A 1 8.39E+05
K SWA-L06-1316-T04-A 1 3.12E+06
K SWA-L06-1316-T01-B 1 3.29E+05
K SWA-L06-1316-T02-B 1 4.94E+05
K SWA-L06-1316-T03-B 1 8.51 E+05
K SWA-L06-1316-T04-B 1 3.16E+06
K SWA-L06-1316-T01-C 1 3.28E+05
K SWA-L06-1316-T02-C 1 4.96E+05
K SWA-L06-1316-T03-C 1 9.13E+05
K SWA-L06-1316-T04-C 1 3.22E+06
K SWA-L06-1316-B01-A 1 2.17E+01
K SWA-L06-1316-B01-B 1 2.41E+01
K SWA-L06-1316-B01-C 1 2.52E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.30E+05 8.2E-01 1 .6E+00 5.1E+00
4.95E+05 1.9E+00 1 .6E+00 5.1E+00 1000 100
8.39E+05 1.8E+00 1 .6E+00 5.1E+00
3.12E+06 3.8E-01 1 .6E+00 5.1E+00
3.29E+05 9.3E-01 1 .6E+00 5.1E+00
4.94E+05 1.0E+00 1 .6E+00 5.1E+00 1000 100
8.51 E+05 2.7E+00 1 .6E+00 5.1E+00
3.16E+06 8.0E-01 1 .6E+00 5.1E+00
3.28E+05 7.7E-01 1 .6E+00 5.1E+00
4.96E+05 1.8E+00 1 .6E+00 5.1E+00 1000 100
9.13E+05 1.1E+01 1.6E+00 5.1E+00
3.22E+06 6.2E-01 1 .6E+00 5.1E+00
2.17E+01 3.2E+00 1 .6E+00 5.1E+00
2.41E+01 9.8E+00 1 .6E+00 5.1E+00
2.52E+01 1.4E+01 1 .6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
4.96E+05 86% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
4.95E+05 92% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
4.97E+05 91% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1415
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se SWA-L06-1316-T01-A 1 9.38E+04
Se SWA-L06-1316-T02-A 1 1.66E+05
Se SWA-L06-1316-T03-A 1 3.81 E+05
Se SWA-L06-1316-T04-A 1 7.12E+05
Se SWA-L06-1316-T01-B 1 9.26E+04
Se SWA-L06-1316-T02-B 1 1.66E+05
Se SWA-L06-1316-T03-B 1 3.88E+05
Se SWA-L06-1316-T04-B 1 7.44E+05
Se SWA-L06-1316-T01-C 1 9.20E+04
Se SWA-L06-1316-T02-C 1 1.63E+05
Se SWA-L06-1316-T03-C 1 3.84E+05
Se SWA-L06-1316-T04-C 1 7.10E+05
Se SWA-L06-1316-B01-A 1 7.50E+00 U1/2
Se SWA-L06-1316-B01-B 1 7.50E+00 U1/2
Se SWA-L06-1316-B01-C 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.38E+04 3.5E-01 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.66E+05 2.7E-01 1 .5E+01 4.8E+01 10 100 1 .66E+05 87% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
3.81 E+05 6.0E-01 1 .5E+01 4.8E+01
7.12E+05 1.7E-01 1 .5E+01 4.8E+01
9.26E+04 4.7E-01 1 .5E+01 4.8E+01
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.66E+05 1.6E+00 1 .5E+01 4.8E+01 10 100 1 .67E+05 96% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
3.88E+05 1.1E+00 1 .5E+01 4.8E+01
7.44E+05 7.6E-01 1 .5E+01 4.8E+01
9.20E+04 9.6E-01 1 .5E+01 4.8E+01
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.63E+05 9.7E-01 1 .5E+01 4.8E+01 10 100 1.64E+05 90% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
3.84E+05 5.9E-01 1.5E+01 4.8E+01
7.10E+05 2.3E-01 1.5E+01 4.8E+01
7.50E+00 7.4E+01 1.5E+01 4.8E+01
7.50E+00 5.8E+01 1.5E+01 4.8E+01
7.50E+00 1.7E+01 1.5E+01 4.8E+01
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1416
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si SWA-L06-1316-T01-A 1 2.65E+04
Si SWA-L06-1316-T02-A 1 3.66E+04
Si SWA-L06-1316-T03-A 1 2.24E+04
Si SWA-L06-1316-T04-A 1 7.31E+04
Si SWA-L06-1316-T01-B 1 2.64E+04
Si SWA-L06-1316-T02-B 1 3.76E+04
Si SWA-L06-1316-T03-B 1 2.13E+04
Si SWA-L06-1316-T04-B 1 6.99E+04
Si SWA-L06-1316-T01-C 1 2.60E+04
Si SWA-L06-1316-T02-C 1 3.64E+04
Si SWA-L06-1316-T03-C 1 2.27E+04
Si SWA-L06-1316-T04-C 1 7.34E+04
Si SWA-L06-1316-B01-A 1 5.50E-01 U1/2
Si SWA-L06-1316-B01-B 1 1.61E+OOE
Si SWA-L06-1316-B01-C 1 1.29E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.65E+04 3.0E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
3.66E+04 3.9E-01 1.1E+00 3.5E+00 1000 100 3.76E+04 97% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
2.24E+04 5.5E-01 1.1E+00 3.5E+00
7.31 E+04 6.7E-01 1.1E+00 3.5E+00
2.64E+04 3.8E-01 1.1E+00 3.5E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
3.76E+04 1.0E+00 1.1E+00 3.5E+00 1000 100 3.85E+04 90% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
2.13E+04 3.7E-01 1.1E+00 3.5E+00
6.99E+04 7.4E-02 1.1E+00 3.5E+00
2.60E+04 7.1E-01 1.1E+00 3.5E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
3.64E+04 9.7E-02 1.1E+00 3.5E+00 1000 100 3.73E+04 90% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
2.27E+04 7.1E-01 1.1E+00 3.5E+00
7.34E+04 3.5E-01 1.1E+00 3.5E+00
5.50E-01 5.3E+02 1.1E+00 3.5E+00
1.61E+00 1.6E+02 1.1E+00 3.5E+00
1.29E+00 4.4E+01 1.1E+00 3.5E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1417
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na SWA-L06-1316-T01-A 1 5.13E+05
Na SWA-L06-1316-T02-A 1 6.32E+05
Na SWA-L06-1316-T03-A 1 7.37E+05
Na SWA-L06-1316-T04-A 1 7.88E+05
Na SWA-L06-1316-T01-B 1 5.08E+05
Na SWA-L06-1316-T02-B 1 6.32E+05
Na SWA-L06-1316-T03-B 1 7.37E+05
Na SWA-L06-1316-T04-B 1 7.85E+05
Na SWA-L06-1316-T01-C 1 5.07E+05
Na SWA-L06-1316-T02-C 1 6.27E+05
Na SWA-L06-1316-T03-C 1 7.31 E+05
Na SWA-L06-1316-T04-C 1 7.77E+05
Na SWA-L06-1316-B01-A 1 6.81 E+01
Na SWA-L06-1316-B01-B 1 7.37E+01
Na SWA-L06-1316-B01-C 1 7.20E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.13E+05 4.4E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
6.32E+05 2.9E-01 2.5E+00 8.0E+00 1000 100 6.32E+05 86% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
7.37E+05 1.6E-01 2.5E+00 8.0E+00
7.88E+05 8.1E-01 2.5E+00 8.0E+00
5.08E+05 5.0E-01 2.5E+00 8.0E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
6.32E+05 4.4E-01 2.5E+00 8.0E+00 1000 100 6.32E+05 83% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
7.37E+05 2.3E-01 2.5E+00 8.0E+00
7.85E+05 1.6E+00 2.5E+00 8.0E+00
5.07E+05 3.7E-01 2.5E+00 8.0E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
6.27E+05 1.6E-01 2.5E+00 8.0E+00 1000 100 6.28E+05 95% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
7.31E+05 1.1E-01 2.5E+00 8.0E+00
7.77E+05 7.1E-01 2.5E+00 8.0E+00
6.81 E+01 6.3E+00 2.5E+00 8.0E+00
7.37E+01 9.0E+00 2.5E+00 8.0E+00
7.20E+01 3.1E+00 2.5E+00 8.0E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1418
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
SWA-L06-1316-T01-A 1 4.50E+02
SWA-L06-1316-T02-A 1 4.60E+02
SWA-L06-1316-T03-A 1 2.49E+02
SWA-L06-1316-T04-A 1 5.91 E+02
SWA-L06-1316-T01-B 1 4.42E+02
SWA-L06-1316-T02-B 1 4.48E+02
SWA-L06-1316-T03-B 1 2.77E+02
SWA-L06-1316-T04-B 1 4.72E+02
SWA-L06-1316-T01-C 1 4.40E+02
SWA-L06-1316-T02-C 1 4.49E+02
SWA-L06-1316-T03-C 1 2.11E+02
SWA-L06-1316-T04-C 1 5.41 E+02
SWA-L06-1316-B01-A 1 5.00E-01 U1/2
SWA-L06-1316-B01-B 1 5.00E-01 U1/2
SWA-L06-1316-B01-C 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.50E+02 6.5E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 3:49 PM EPA Interlab 1316 SWA Reruns
4.60E+02 1.5E-01 1 .OE+00 3.2E+00 1000 100 1 .46E+03 100% VU ICP-OES 5/23/11 3:51 PM EPA Interlab 1316 SWA Reruns
2.49E+02 1.7E+00 1 .OE+00 3.2E+00
5.91 E+02 6.9E-01 1 .OE+00 3.2E+00
4.42E+02 7.7E-01 1 .OE+00 3.2E+00
VU ICP-OES 5/23/11 3:53 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:56 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:58 PM EPA Interlab 1316 SWA Reruns
4.48E+02 8.7E-01 1 .OE+00 3.2E+00 1000 100 1 .42E+03 97% VU ICP-OES 5/23/11 4:00 PM EPA Interlab 1316 SWA Reruns
2.77E+02 5.1E-01 1 .OE+00 3.2E+00
4.72E+02 1.1E+00 1 .OE+00 3.2E+00
4.40E+02 4.7E-01 1 .OE+00 3.2E+00
VU ICP-OES 5/23/11 4:02 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:05 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:07 PM EPA Interlab 1316 SWA Reruns
4.49E+02 4.8E-01 1 .OE+00 3.2E+00 1000 100 1 .45E+03 100% VU ICP-OES 5/23/11 4:09 PM EPA Interlab 1316 SWA Reruns
2.11E+02 2.2E-01 1 .OE+00 3.2E+00
5.41 E+02 4.3E-01 1 .OE+00 3.2E+00
5.00E-01 1.4E+02 1 .OE+00 3.2E+00
5.00E-01 7.1E+01 1. OE+00 3.2E+00
5.00E-01 6.8E+01 1. OE+00 3.2E+00
VU ICP-OES 5/23/11 4:12 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:14 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1419
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S SWA-L06-1316-T01-A 1 8.95E+05
S SWA-L06-1316-T02-A 1 1.20E+06
S SWA-L06-1316-T03-A 1 1.44E+06
S SWA-L06-1316-T04-A 1 2.06E+06
S SWA-L06-1316-T01-B 1 9.04E+05
S SWA-L06-1316-T02-B 1 1.24E+06
S SWA-L06-1316-T03-B 1 1.48E+06
S SWA-L06-1316-T04-B 1 2.13E+06
S SWA-L06-1316-T01-C 1 9.07E+05
S SWA-L06-1316-T02-C 1 1.19E+06
S SWA-L06-1316-T03-C 1 1.46E+06
S SWA-L06-1316-T04-C 1 2.08E+06
S SWA-L06-1316-B01-A 1 3.40E+00 U1/2
S SWA-L06-1316-B01-B 1 7.74E+00 E
S SWA-L06-1316-B01-C 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.95E+05 1.0E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.20E+06 5.5E-01 6.8E+00 2.2E+01 1000 100 1 .30E+06 92% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
1.44E+06 4.5E-01 6.8E+00 2.2E+01
2.06E+06 2.7E-01 6.8E+00 2.2E+01
9.04E+05 1.5E+00 6.8E+00 2.2E+01
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.24E+06 1.6E+00 6.8E+00 2.2E+01 1000 100 1 .32E+06 82% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
1.48E+06 9.2E-01 6.8E+00 2.2E+01
2.13E+06 6.9E-01 6.8E+00 2.2E+01
9.07E+05 1.5E+00 6.8E+00 2.2E+01
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.19E+06 1.3E+00 6.8E+00 2.2E+01 1000 100 1 .28E+06 84% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
1.46E+06 6.2E-01 6.8E+00 2.2E+01
2.08E+06 9.2E-02 6.8E+00 2.2E+01
3.40E+00 4.1E+02 6.8E+00 2.2E+01
7.74E+00 1.6E+02 6.8E+00 2.2E+01
3.40E+00 5.2E+02 6.8E+00 2.2E+01
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1420
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl SWA-L06-1316-T01-A 1 2.30E+00 U1/2
Tl SWA-L06-1316-T02-A 1 2.30E+00 U1/2
Tl SWA-L06-1316-T03-A 1 2.30E+00 U1/2
Tl SWA-L06-1316-T04-A 1 2.30E+00 U1/2
Tl SWA-L06-1316-T01-B 1 2.30E+00 U1/2
Tl SWA-L06-1316-T02-B 1 2.30E+00 U1/2
Tl SWA-L06-1316-T03-B 1 2.30E+00 U1/2
Tl SWA-L06-1316-T04-B 1 2.30E+00 U1/2
Tl SWA-L06-1316-T01-C 1 2.30E+00 U1/2
Tl SWA-L06-1316-T02-C 1 2.30E+00 U1/2
Tl SWA-L06-1316-T03-C 1 2.30E+00 U1/2
Tl SWA-L06-1316-T04-C 1 2.30E+00 U1/2
Tl SWA-L06-1316-B01-A 1 2.30E+00 U1/2
Tl SWA-L06-1316-B01-B 1 2.30E+00 U1/2
Tl SWA-L06-1316-B01-C 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 3.5E+01 4.6E+00 1.5E+01
2.30E+00 2.2E+02 4.6E+00 1.5E+01 10 100
2.30E+00 1.9E+02 4.6E+00 1.5E+01
2.30E+00 7.2E+01 4.6E+00 1.5E+01
2.30E+00 4.0E+01 4.6E+00 1.5E+01
2.30E+00 9.7E+01 4.6E+00 1.5E+01 10 100
2.30E+00 6.5E+02 4.6E+00 1.5E+01
2.30E+00 5.4E+01 4.6E+00 1.5E+01
2.30E+00 1.6E+02 4.6E+00 1.5E+01
2.30E+00 1.3E+02 4.6E+00 1.5E+01 10 100
2.30E+00 9.0E+01 4.6E+00 1.5E+01
2.30E+00 2.1E+02 4.6E+00 1.5E+01
2.30E+00 1.3E+02 4.6E+00 1.5E+01
2.30E+00 4.2E+01 4.6E+00 1.5E+01
2.30E+00 2.9E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.01E+03 101% VUICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
9.71E+02 97% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:54PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:57PM EPA Interlab L06 1313-1316 SWA
1.01E+03 100% VU ICP-OES 3/30/11 1 :59 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1421
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti SWA-L06-1316-T01-A 1 1.00E+OOU1/2
Ti SWA-L06-1316-T02-A 1 1.00E+OOU1/2
Ti SWA-L06-1316-T03-A 1 1.00E+OOU1/2
Ti SWA-L06-1316-T04-A 1 1.00E+OOU1/2
Ti SWA-L06-1316-T01-B 1 1.00E+OOU1/2
Ti SWA-L06-1316-T02-B 1 1.00E+OOU1/2
Ti SWA-L06-1316-T03-B 1 1.00E+OOU1/2
Ti SWA-L06-1316-T04-B 1 1.00E+OOU1/2
Ti SWA-L06-1316-T01-C 1 1.00E+OOU1/2
Ti SWA-L06-1316-T02-C 1 1.00E+OOU1/2
Ti SWA-L06-1316-T03-C 1 1.00E+OOU1/2
Ti SWA-L06-1316-T04-C 1 1.00E+OOU1/2
Ti SWA-L06-1316-B01-A 1 1.00E+OOU1/2
Ti SWA-L06-1316-B01-B 1 1.00E+OOU1/2
Ti SWA-L06-1316-B01-C 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
1.00E+00 1.3E+01 2.0E+00 6.4E+00 10 100 1.12E+03 1 12% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
1.00E+00 8.7E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
1.00E+00 3.3E+00 2.0E+00 6.4E+00 10 100 1.07E+03 107% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
1.00E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
1.00E+00 9.2E+00 2.0E+00 6.4E+00 10 100 1.11E+03 111% VU ICP-OES 3/30/11 1 :59 PM EPA Interlab L06 1313-1316 SWA
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 8.9E+00 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+02 2.0E+00 6.4E+00
1.00E+00 6.9E+01 2.0E+00 6.4E+00
VUICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VUICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1422
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V SWA-L06-1316-T01-A 1 3.61 E+02
V SWA-L06-1316-T02-A 1 6.43E+02
V SWA-L06-1316-T03-A 1 1.24E+03
V SWA-L06-1316-T04-A 1 2.22E+03
V SWA-L06-1316-T01-B 1 3.61 E+02
V SWA-L06-1316-T02-B 1 6.48E+02
V SWA-L06-1316-T03-B 1 1.28E+03
V SWA-L06-1316-T04-B 1 2.32E+03
V SWA-L06-1316-T01-C 1 3.60E+02
V SWA-L06-1316-T02-C 1 6.38E+02
V SWA-L06-1316-T03-C 1 1.25E+03
V SWA-L06-1316-T04-C 1 2.26E+03
V SWA-L06-1316-B01-A 1 7.50E-01 U1/2
V SWA-L06-1316-B01-B 1 7.50E-01 U1/2
V SWA-L06-1316-B01-C 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.61 E+02 1.7E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
6.43E+02 5.3E-01 1 .5E+00 4.8E+00 10 100 1 J5E+03 11 1% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
1.24E+03 4.6E-01 1 .5E+00 4.8E+00
2.22E+03 3.5E-01 1 .5E+00 4.8E+00
3.61 E+02 2.4E+00 1 .5E+00 4.8E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
6.48E+02 8.1E-01 1 .5E+00 4.8E+00 10 100 1 J3E+03 108% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
1.28E+03 5.1E-01 1 .5E+00 4.8E+00
2.32E+03 8.4E-01 1 .5E+00 4.8E+00
3.60E+02 7.7E-01 1 .5E+00 4.8E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
6.38E+02 1.3E+00 1 .5E+00 4.8E+00 10 100 1 J9E+03 115% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
1.25E+03 6.7E-01 1 .5E+00 4.8E+00
2.26E+03 1.3E+00 1 .5E+00 4.8E+00
7.50E-01 5.5E+01 1 .5E+00 4.8E+00
7.50E-01 6.5E+01 1 .5E+00 4.8E+00
7.50E-01 4.5E+01 1.5E+00 4.8E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1423
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn SWA-L06-1316-T01-A 1 3.24E+00
Zn SWA-L06-1316-T02-A 1 4.84E+00
Zn SWA-L06-1316-T03-A 1 1.23E+OOE
Zn SWA-L06-1316-T04-A 1 1.14E+01
Zn SWA-L06-1316-T01-B 1 3.59E+00
Zn SWA-L06-1316-T02-B 1 3.73E+00
Zn SWA-L06-1316-T03-B 1 1.02E+OOE
Zn SWA-L06-1316-T04-B 1 1.24E+01
Zn SWA-L06-1316-T01-C 1 3.44E+00
Zn SWA-L06-1316-T02-C 1 4.79E+00
Zn SWA-L06-1316-T03-C 1 1.14E+OOE
Zn SWA-L06-1316-T04-C 1 1.13E+01
Zn SWA-L06-1316-B01-A 1 2.49E+00 E
Zn SWA-L06-1316-B01-B 1 2.81E+OOE
Zn SWA-L06-1316-B01-C 1 2.53E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.24E+00 9.5E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/30/11 1:42 PM EPA Interlab L06 1313-1316 SWA
4.84E+00 6.8E+00 1 .OE+00 3.2E+00 10 100 1.12E+03 11 1% VU ICP-OES 3/30/11 1:44 PM EPA Interlab L06 1313-1316 SWA
1.23E+00 2.1E+01 1. OE+00 3.2E+00
1.14E+01 4.6E+00 1. OE+00 3.2E+00
3.59E+00 3.5E+00 1 .OE+00 3.2E+00
VU ICP-OES 3/30/11 1:46 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:47 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:49 PM EPA Interlab L06 1313-1316 SWA
3.73E+00 8.7E+00 1 .OE+00 3.2E+00 10 100 1 .07E+03 107% VU ICP-OES 3/30/11 1:50 PM EPA Interlab L06 1313-1316 SWA
1.02E+00 2.3E+01 1 .OE+00 3.2E+00
1.24E+01 5.3E+00 1 .OE+00 3.2E+00
3.44E+00 2.0E+01 1 .OE+00 3.2E+00
VU ICP-OES 3/30/11 1:52 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:54 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:57 PM EPA Interlab L06 1313-1316 SWA
4.79E+00 3.4E+00 1 .OE+00 3.2E+00 10 100 1.11E+03 1 11% VU ICP-OES 3/30/11 1:59 PM EPA Interlab L06 1313-1316 SWA
1.14E+00 1.4E+02 1. OE+00 3.2E+00
1.13E+01 2.0E+00 1. OE+00 3.2E+00
2.49E+00 2.4E+01 1. OE+00 3.2E+00
2.81 E+00 5.9E+00 1. OE+00 3.2E+00
2.53E+00 5.4E+00 1. OE+00 3.2E+00
VU ICP-OES 3/30/11 2:00 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 2:02 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:37 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:39 PM EPA Interlab L06 1313-1316 SWA
VU ICP-OES 3/30/11 1:41 PM EPA Interlab L06 1313-1316 SWA
                                                                                                                                                                         1-1424
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al SWA-L07-1316-T01-A 1
Al SWA-L07-1316-T02-A 1
Al SWA-L07-1316-T03-A 1
Al SWA-L07-1316-T04-A 1
Al SWA-L07-1316-T01-B 1
Al SWA-L07-1316-T02-B 1
Al SWA-L07-1316-T03-B 1
Al SWA-L07-1316-T04-B 1
Al SWA-L07-1316-T01-C 1
Al SWA-L07-1316-T02-C 1
Al SWA-L07-1316-T03-C 1
Al SWA-L07-1316-T04-C 1
Al SWA-L07-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.80E+04
5.95E+04
8.55E+04
1.72E+05
3.74E+04
5.93E+04
9.09E+04
1.81E+05
3.69E+04
5.65E+04
9.64E+04
1.80E+05
6.28E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.80E+04 6.3E-01 1.0E+00 3.2E+00
5.95E+04 6.1E-01 1.0E+00 3.2E+00 1000 120
8.55E+04 7.2E-01 1.0E+00 3.2E+00
1.72E+05 1.1E+00 1.0E+00 3.2E+00
3.74E+04 5.9E-01 1.0E+00 3.2E+00
5.93E+04 9.0E-01 1.0E+00 3.2E+00 1000 120
9.09E+04 2.4E-01 1.0E+00 3.2E+00
1.81E+05 5.1E-01 1.0E+00 3.2E+00
3.69E+04 3.4E-01 1.0E+00 3.2E+00
5.65E+04 2.8E-01 1.0E+00 3.2E+00 1000 120
9.64E+04 8.4E-01 1.0E+00 3.2E+00
1.80E+05 8.3E-01 1.0E+00 3.2E+00
6.28E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
6.06E+04 91% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
6.05E+04 97% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
5.76E+04 96% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                                  1-1425
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L07-1316-T01-A 1
Sb SWA-L07-1316-T02-A 1
Sb SWA-L07-1316-T03-A 1
Sb SWA-L07-1316-T04-A 1
Sb SWA-L07-1316-T01-B 1
Sb SWA-L07-1316-T02-B 1
Sb SWA-L07-1316-T03-B 1
Sb SWA-L07-1316-T04-B 1
Sb SWA-L07-1316-T01-C 1
Sb SWA-L07-1316-T02-C 1
Sb SWA-L07-1316-T03-C 1
Sb SWA-L07-1316-T04-C 1
Sb SWA-L07-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
2.99E+03
1.54E+03
7.61 E+03
5.47E+03
2.76E+03
1.46E+03
8.18E+03
5.20E+03
2.54E+03
1.86E+03
7.19E+03
5.57E+03
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.99E+03 2.1E+00 7.5E+00 2.4E+01
1.54E+03 3.0E+00 7.5E+00 2.4E+01 10 120
7.61E+03 6.6E-01 7.5E+00 2.4E+01
5.47E+03 1.7E+00 7.5E+00 2.4E+01
2.76E+03 1.7E-01 7.5E+00 2.4E+01
1.46E+03 2.0E+00 7.5E+00 2.4E+01 10 120
8.18E+03 1.0E+00 7.5E+00 2.4E+01
5.20E+03 5.1E-01 7.5E+00 2.4E+01
2.54E+03 4.8E-01 7.5E+00 2.4E+01
1.86E+03 2.1E+00 7.5E+00 2.4E+01 10 120
7.19E+03 6.7E-01 7.5E+00 2.4E+01
5.57E+03 3.1E-01 7.5E+00 2.4E+01
3.75E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
2.54E+03 84% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
2.66E+03 100% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
3.12E+03 105% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1426
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-L07-1316-T01-A 1
As SWA-L07-1316-T02-A 1
As SWA-L07-1316-T03-A 1
As SWA-L07-1316-T04-A 1
As SWA-L07-1316-T01-B 1
As SWA-L07-1316-T02-B 1
As SWA-L07-1316-T03-B 1
As SWA-L07-1316-T04-B 1
As SWA-L07-1316-T01-C 1
As SWA-L07-1316-T02-C 1
As SWA-L07-1316-T03-C 1
As SWA-L07-1316-T04-C 1
As SWA-L07-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
4.42E+03
1.12E+04
4.13E+04
1.11E+05
4.50E+03
1.19E+04
4.07E+04
9.77E+04
4.22E+03
9.59E+03
3.67E+04
9.95E+04
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.42E+03 3.9E-01 1.1E+01 3.5E+01
1.12E+04 1.2E+00 1.1E+01 3.5E+01 10 120
4.13E+04 9.8E-01 1.1E+01 3.5E+01
1.11E+05 5.7E-01 1.1E+01 3.5E+01
4.50E+03 2.5E-01 1.1E+01 3.5E+01
1.19E+04 1.1E+00 1.1E+01 3.5E+01 10 120
4.07E+04 4.1E-01 1.1E+01 3.5E+01
9.77E+04 6.4E-01 1.1E+01 3.5E+01
4.22E+03 1.2E-01 1.1E+01 3.5E+01
9.59E+03 6.6E-01 1.1E+01 3.5E+01 10 120
3.67E+04 8.5E-01 1.1E+01 3.5E+01
9.95E+04 6.4E-01 1.1E+01 3.5E+01
5.50E+00 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.22E+04 84% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.32E+04 102% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.07E+04 92% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1427
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qua
ug/L
B SWA-L07-1316-T01-A 1 1.06E+03
B SWA-L07-1316-T02-A 1 1.26E+03
B SWA-L07-1316-T03-A 1 1.16E+03
B SWA-L07-1316-T04-A 1 1.03E+03
B SWA-L07-1316-T01-B 1 1.16E+03
B SWA-L07-1316-T02-B 1 1.58E+03
B SWA-L07-1316-T03-B 1 1.21E+03
B SWA-L07-1316-T04-B 1 1.04E+03
B SWA-L07-1316-T01-C 1 1.08E+03
B SWA-L07-1316-T02-C 1 1.51E+03
B SWA-L07-1316-T03-C 1 1.18E+03
B SWA-L07-1316-T04-C 1 1.09E+03
B SWA-L07-1316-B01-A 1 5.43E+00
Internal ICP-OES Spike Sol'n
ifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+03 1.1E+00 1.0E+00 3.2E+00
1.26E+03 5.6E-01 1.0E+00 3.2E+00 1000 120
1.16E+03 1.3E+00 1.0E+00 3.2E+00
1.03E+03 1.3E+00 1.0E+00 3.2E+00
1.16E+03 7.0E-01 1.0E+00 3.2E+00
1.58E+03 5.6E-01 1.0E+00 3.2E+00 1000 120
1.21E+03 4.5E-01 1.0E+00 3.2E+00
1.04E+03 2.9E-01 1.0E+00 3.2E+00
1.08E+03 1.8E-01 1.0E+00 3.2E+00
1.51E+03 7.0E-01 1.0E+00 3.2E+00 1000 120
1.18E+03 5.5E-01 1.0E+00 3.2E+00
1.09E+03 1.8E-01 1.0E+00 3.2E+00
5.43E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
2.35E+03 91% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
2.74E+03 96% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
2.72E+03 101% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1428
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qua
ug/L
Ba SWA-L07-1316-T01-A 1 1.83E+02
Ba SWA-L07-1316-T02-A 1 1.72E+02
Ba SWA-L07-1316-T03-A 1 3.16E+01
Ba SWA-L07-1316-T04-A 1 1.21E+02
Ba SWA-L07-1316-T01-B 1 2.03E+02
Ba SWA-L07-1316-T02-B 1 1.81E+02
Ba SWA-L07-1316-T03-B 1 3.66E+01
Ba SWA-L07-1316-T04-B 1 1.12E+02
Ba SWA-L07-1316-T01-C 1 2.14E+02
Ba SWA-L07-1316-T02-C 1 2.00E+02
Ba SWA-L07-1316-T03-C 1 3.38E+01
Ba SWA-L07-1316-T04-C 1 1.36E+02
Ba SWA-L07-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
ifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.83E+02 6.9E-01 1.0E+00 3.2E+00
1.72E+02 3.0E-01 1.0E+00 3.2E+00 10 120
3.16E+01 7.7E-01 1.0E+00 3.2E+00
1.21E+02 7.1E-01 1.0E+00 3.2E+00
2.03E+02 3.2E-01 1.0E+00 3.2E+00
1.81E+02 2.3E-01 1.0E+00 3.2E+00 10 120
3.66E+01 4.8E-01 1.0E+00 3.2E+00
1.12E+02 1.8E+00 1.0E+00 3.2E+00
2.14E+02 1.2E-01 1.0E+00 3.2E+00
2.00E+02 3.6E-01 1.0E+00 3.2E+00 10 120
3.38E+01 2.2E+00 1.0E+00 3.2E+00
1.36E+02 2.5E+00 1.0E+00 3.2E+00
5.00E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.20E+03 85% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.28E+03 91% VU ICP-OES 1 2/3/1 0 1 2 :39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.33E+03 94% VU ICP-OES 1 2/3/1 0 1 2 :45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1429
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L07-1316-T01-A 1
Be SWA-L07-1316-T02-A 1
Be SWA-L07-1316-T03-A 1
Be SWA-L07-1316-T04-A 1
Be SWA-L07-1316-T01-B 1
Be SWA-L07-1316-T02-B 1
Be SWA-L07-1316-T03-B 1
Be SWA-L07-1316-T04-B 1
Be SWA-L07-1316-T01-C 1
Be SWA-L07-1316-T02-C 1
Be SWA-L07-1316-T03-C 1
Be SWA-L07-1316-T04-C 1
Be SWA-L07-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.3E+01 1.9E+00 6.0E+00
9.50E-01 5.1E+01 1.9E+00 6.0E+00 10 120
9.50E-01 9.8E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 5.9E+01 1.9E+00 6.0E+00
9.50E-01 7.1E+02 1.9E+00 6.0E+00 10 120
9.50E-01 4.6E+02 1.9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 2.4E+02 1.9E+00 6.0E+00
9.50E-01 4.3E+01 1.9E+00 6.0E+00 10 120
9.50E-01 1.3E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.11E+03 92% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.19E+03 99% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.23E+03 102% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1430
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L07-1316-T01-A 1 1.10E+OOU1/2 1.10E+00 1.1E+02 2.2E+00 7.0E+00
Cd SWA-L07-1316-T02-A 1 1.10E+OOU1/2 1.10E+00 1.4E+03 2.2E+00 7.0E+00 10 120
Cd SWA-L07-1316-T03-A 1 1.10E+OOU1/2 1.10E+00 2.4E+02 2.2E+00 7.0E+00
Cd SWA-L07-1316-T04-A 1 1.10E+OOU1/2 1.10E+00 1.7E+02 2.2E+00 7.0E+00
Cd SWA-L07-1316-T01-B 1 1.10E+OOU1/2 1.10E+00 1.7E+02 2.2E+00 7.0E+00
Cd SWA-L07-1316-T02-B 1 1.10E+OOU1/2 1.10E+00 7.1E+01 2.2E+00 7.0E+00 10 120
Cd SWA-L07-1316-T03-B 1 1.10E+OOU1/2 1.10E+00 2.8E+01 2.2E+00 7.0E+00
Cd SWA-L07-1316-T04-B 1 1.10E+OOU1/2 1.10E+00 1.9E+02 2.2E+00 7.0E+00
Cd SWA-L07-1316-T01-C 1 1.10E+OOU1/2 1.10E+00 4.3E+02 2.2E+00 7.0E+00
Cd SWA-L07-1316-T02-C 1 1.10E+OOU1/2 1.10E+00 6.0E+01 2.2E+00 7.0E+00 10 120
Cd SWA-L07-1316-T03-C 1 1.10E+OOU1/2 1.10E+00 1.2E+02 2.2E+00 7.0E+00
Cd SWA-L07-1316-T04-C 1 1.10E+OOU1/2 1.10E+00 4.2E+02 2.2E+00 7.0E+00
Cd SWA-L07-1316-B01-A 1 1.10E+OOU1/2 1.10E+00 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
9.90E+02 82% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.06E+03 88% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/1012:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.10E+03 91% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1431
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca SWA-L07-1316-T01-A 1
Ca SWA-L07-1316-T02-A 1
Ca SWA-L07-1316-T03-A 1
Ca SWA-L07-1316-T04-A 1
Ca SWA-L07-1316-T01-B 1
Ca SWA-L07-1316-T02-B 1
Ca SWA-L07-1316-T03-B 1
Ca SWA-L07-1316-T04-B 1
Ca SWA-L07-1316-T01-C 1
Ca SWA-L07-1316-T02-C 1
Ca SWA-L07-1316-T03-C 1
Ca SWA-L07-1316-T04-C 1
Ca SWA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.47E+04
1.16E+04
3.46E+03
3.93E+03
1.42E+04
1.12E+04
3.23E+03
4.51 E+03
1.47E+04
1.18E+04
3.47E+03
5.05E+03
3.89E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.47E+04 6.9E-01 2.6E+00 8.3E+00
1.16E+04 5.0E-01 2.6E+00 8.3E+00 1000 120
3.46E+03 3.8E+00 2.6E+00 8.3E+00
3.93E+03 5.3E+00 2.6E+00 8.3E+00
1.42E+04 1.6E-01 2.6E+00 8.3E+00
1.12E+04 1.3E-01 2.6E+00 8.3E+00 1000 120
3.23E+03 1.6E+00 2.6E+00 8.3E+00
4.51E+03 2.8E+00 2.6E+00 8.3E+00
1.47E+04 3.6E-01 2.6E+00 8.3E+00
1.18E+04 1.4E-01 2.6E+00 8.3E+00 1000 120
3.47E+03 4.3E+00 2.6E+00 8.3E+00
5.05E+03 8.1E-01 2.6E+00 8.3E+00
3.89E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.27E+04 85% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.24E+04 93% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.29E+04 92% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1432
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qu
1 1 ug/L
Cr SWA-L07-1316-T01-A 1 1.11E+03
Cr SWA-L07-1316-T02-A 1 1.68E+03
Cr SWA-L07-1316-T03-A 1 1.36E+03
Cr SWA-L07-1316-T04-A 1 2.59E+03
Cr SWA-L07-1316-T01-B 1 1.16E+03
Cr SWA-L07-1316-T02-B 1 1.77E+03
Cr SWA-L07-1316-T03-B 1 1.33E+03
Cr SWA-L07-1316-T04-B 1 2.63E+03
Cr SWA-L07-1316-T01-C 1 1.06E+03
Cr SWA-L07-1316-T02-C 1 1.68E+03
Cr SWA-L07-1316-T03-C 1 1.47E+03
Cr SWA-L07-1316-T04-C 1 2.58E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.11E+03 1.3E+00 1.2E+00 3.8E+00
1.68E+03 8.5E-01 1.2E+00 3.8E+00 10 120
1.36E+03 5.4E-01 1.2E+00 3.8E+00
2.59E+03 9.2E-01 1.2E+00 3.8E+00
1.16E+03 2.0E-01 1.2E+00 3.8E+00
1.77E+03 6.0E-01 1.2E+00 3.8E+00 10 120
1.33E+03 5.6E-01 1.2E+00 3.8E+00
2.63E+03 2.0E+00 1.2E+00 3.8E+00
1.06E+03 2.8E-01 1.2E+00 3.8E+00
1.68E+03 2.1E-01 1.2E+00 3.8E+00 10 120
1.47E+03 9.5E-01 1.2E+00 3.8E+00
2.58E+03 1.5E+00 1.2E+00 3.8E+00
Cr SWA-L07-1316-B01-A 1 6.00E-01 U1/2 6.00E-01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
2.89E+03 101% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
2.95E+03 99% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
2.91E+03 103% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1433
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co SWA-L07-1316-T01-A 1
Co SWA-L07-1316-T02-A 1
Co SWA-L07-1316-T03-A 1
Co SWA-L07-1316-T04-A 1
Co SWA-L07-1316-T01-B 1
Co SWA-L07-1316-T02-B 1
Co SWA-L07-1316-T03-B 1
Co SWA-L07-1316-T04-B 1
Co SWA-L07-1316-T01-C
Co SWA-L07-1316-T02-C 1
Co SWA-L07-1316-T03-C 1
Co SWA-L07-1316-T04-C 1
Co SWA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
3.21 E+00 E
6.56E+00
9.00E-01 U1/2
9.00E-01 U1/2
3.60E+00 E
7.33E+00

9.00E-01 U1/2
3.05E+00 E
7.35E+00
9.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 4.8E+01 1.8E+00 5.7E+00 10 120
3.21 E+00 1.2E+01 1.8E+00 5.7E+00
6.56E+00 1.2E+01 1.8E+00 5.7E+00
9.00E-01 5.8E+02 1.8E+00 5.7E+00
9.00E-01 1.9E+02 1.8E+00 5.7E+00 10 120
3.60E+00 1.1E+01 1.8E+00 5.7E+00
7.33E+00 4.6E+00 1.8E+00 5.7E+00

9.00E-01 3.8E+02 1.8E+00 5.7E+00 10 120
3.05E+00 4.6E+01 1.8E+00 5.7E+00
7.35E+00 9.9E+00 1.8E+00 5.7E+00
9.00E-01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.00E+03 83% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.07E+03 89% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/1012:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.11E+03 93% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1434
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu SWA-L07-1316-T01-A 1
Cu SWA-L07-1316-T02-A 1
Cu SWA-L07-1316-T03-A 1
Cu SWA-L07-1316-T04-A 1
Cu SWA-L07-1316-T01-B 1
Cu SWA-L07-1316-T02-B 1
Cu SWA-L07-1316-T03-B 1
Cu SWA-L07-1316-T04-B 1
Cu SWA-L07-1316-T01-C 1
Cu SWA-L07-1316-T02-C 1
Cu SWA-L07-1316-T03-C 1
Cu SWA-L07-1316-T04-C 1
Cu SWA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.85E+00 U1/2
3.85E+00 E
8.91 E+00 E
4.41E+01
1.85E+00 U1/2
4.61 E+00 E
9.70E+00 E
4.03E+01
1.85E+00 U1/2
4.90E+00 E
1.22E+01
4.25E+01
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 3.5E+01 3.7E+00 1.2E+01
3.85E+00 5.2E+01 3.7E+00 1.2E+01 10 120
8.91 E+00 2.6E+01 3.7E+00 1.2E+01
4.41 E+01 6.4E+00 3.7E+00 1.2E+01
1.85E+00 5.7E+01 3.7E+00 1.2E+01
4.61E+00 4.0E+01 3.7E+00 1.2E+01 10 120
9.70E+00 1.6E+01 3.7E+00 1.2E+01
4.03E+01 8.2E+00 3.7E+00 1.2E+01
1.85E+00 1.6E+01 3.7E+00 1.2E+01
4.90E+00 2.0E+01 3.7E+00 1.2E+01 10 120
1.22E+01 2.6E+01 3.7E+00 1.2E+01
4.25E+01 2.3E+00 3.7E+00 1.2E+01
1.85E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
9.90E+02 82% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.05E+03 87% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.11E+03 92% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1435
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe SWA-L07-1316-T01-A 1
Fe SWA-L07-1316-T02-A 1
Fe SWA-L07-1316-T03-A 1
Fe SWA-L07-1316-T04-A 1
Fe SWA-L07-1316-T01-B 1
Fe SWA-L07-1316-T02-B 1
Fe SWA-L07-1316-T03-B 1
Fe SWA-L07-1316-T04-B 1
Fe SWA-L07-1316-T01-C 1
Fe SWA-L07-1316-T02-C 1
Fe SWA-L07-1316-T03-C 1
Fe SWA-L07-1316-T04-C 1
Fe SWA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
9.74E+01
1.91E+02
3.26E+02
1.20E+03
8.07E+01
1.84E+02
3.85E+02
1.33E+03
7.70E+01
1.58E+02
3.67E+02
1.42E+03
1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.74E+01 6.7E-02 2.0E+00 6.4E+00
1.91E+02 3.6E-01 2.0E+00 6.4E+00 1000 120
3.26E+02 3.2E-01 2.0E+00 6.4E+00
1.20E+03 7.7E-01 2.0E+00 6.4E+00
8.07E+01 6.6E-01 2.0E+00 6.4E+00
1.84E+02 5.2E-01 2.0E+00 6.4E+00 1000 120
3.85E+02 6.0E-01 2.0E+00 6.4E+00
1.33E+03 5.7E-01 2.0E+00 6.4E+00
7.70E+01 6.9E-01 2.0E+00 6.4E+00
1.58E+02 6.3E-01 2.0E+00 6.4E+00 1000 120
3.67E+02 1.1E+00 2.0E+00 6.4E+00
1.42E+03 9.2E-01 2.0E+00 6.4E+00
1.00E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.23E+03 87% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.30E+03 93% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.32E+03 97% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1436
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone.
1 1 ug/L
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Pb SWA-L07-1316-T01-A 1 1.32E+01 E 1.32E+01 2.7E+01 6.8E+00 2.2E+01
Pb SWA-L07-1316-T02-A 1 2.79E+01
2.79E+01 1.9E+01 6.8E+00 2.2E+01 10 120
Pb SWA-L07-1316-T03-A 1 1.36E+01 E 1.36E+01 2.0E+01 6.8E+00 2.2E+01
Pb SWA-L07-1316-T04-A 1 1.52E+02
1.52E+02 3.7E+00 6.8E+00 2.2E+01
Pb SWA-L07-1316-T01-B 1 1.19E+01 E 1.19E+01 1 .8E+01 6.8E+00 2.2E+01
Pb SWA-L07-1316-T02-B 1 3.50E+01
3.50E+01 6.7E+00 6.8E+00 2.2E+01 10 120
Pb SWA-L07-1316-T03-B 1 1.47E+01 E 1.47E+01 2.5E+01 6.8E+00 2.2E+01
Pb SWA-L07-1316-T04-B 1 1.79E+02
1.79E+02 1.6E+00 6.8E+00 2.2E+01
Pb SWA-L07-1316-T01-C 1 1.59E+01 E 1.59E+01 2.1E+01 6.8E+00 2.2E+01
Pb SWA-L07-1316-T02-C 1 3.94E+01
3.94E+01 2.3E+01 6.8E+00 2.2E+01 10 120
Pb SWA-L07-1316-T03-C 1 1.98E+01 E 1.98E+01 2.8E+01 6.8E+00 2.2E+01
Pb SWA-L07-1316-T04-C 1 1.72E+02
1.72E+02 3.7E+00 6.8E+00 2.2E+01
Pb SWA-L07-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.04E+03 84% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.12E+03 91% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.16E+03 93% VU ICP-OES 1 2/3/1 0 1 2 :45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1437
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Li SWA-L07-1316-T01-A 1 2.63E+00 E 2.63E+00 2.1E+01 1.9E+00 6.0E+00
Li SWA-L07-1316-T02-A 1 5.43E+00 E 5.43E+00 4.8E+01 1.9E+00 6.0E+00 10 120
Li SWA-L07-1316-T03-A 1 6.10E+00
Li SWA-L07-1316-T04-A 1 8.99E+00
6.10E+00 1.6E+01 1.9E+00 6.0E+00
8.99E+00 2.0E+01 1.9E+00 6.0E+00
Li SWA-L07-1316-T01-B 1 2.38E+00 E 2.38E+00 1.0E+02 1.9E+00 6.0E+00
Li SWA-L07-1316-T02-B 1 5.69E+00 E 5.69E+00 2.4E+01 1.9E+00 6.0E+00 10 120
Li SWA-L07-1316-T03-B 1 6.80E+00
Li SWA-L07-1316-T04-B 1 1.04E+01
6.80E+00 3.3E+01 1.9E+00 6.0E+00
1.04E+01 5.0E+01 1.9E+00 6.0E+00
Li SWA-L07-1316-T01-C 1 2.39E+00 E 2.39E+00 4.3E+01 1.9E+00 6.0E+00
Li SWA-L07-1316-T02-C 1 5.18E+00 E 5.18E+00 3.6E+00 1.9E+00 6.0E+00 10 120
Li SWA-L07-1316-T03-C 1 5.93E+00 E 5.93E+00 3.7E+01 1.9E+00 6.0E+00
Li SWA-L07-1316-T04-C 1 9.32E+00
9.32E+00 2.4E+01 1.9E+00 6.0E+00
Li SWA-L07-1316-B01-A 1 9.50E-01 U1/2 9.50E-01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
9.88E+02 82% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
9.98E+02 83% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
9.94E+02 82% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1438
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Mn SWA-L07-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 4.4E+00 2.0E+00 6.4E+00
Mn SWA-L07-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 1 .OE+01 2.0E+00 6.4E+00 10 120
Mn SWA-L07-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 7.7E+01 2.0E+00 6.4E+00
Mn SWA-L07-1316-T04-A 1 3.54E+00 E
3.54E+00 2.6E+00 2.0E+00 6.4E+00
Mn SWA-L07-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 3.4E+00 2.0E+00 6.4E+00
Mn SWA-L07-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 1 .8E+01 2.0E+00 6.4E+00 10 120
Mn SWA-L07-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 6.7E+00 2.0E+00 6.4E+00
Mn SWA-L07-1316-T04-B 1 3.78E+00 E
3.78E+00 5.7E+00 2.0E+00 6.4E+00
Mn SWA-L07-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00
Mn SWA-L07-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 7.9E-01 2.0E+00 6.4E+00 10 120
Mn SWA-L07-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 3.1E+01 2.0E+00 6.4E+00
Mn SWA-L07-1316-T04-C 1 4.37E+00 E
4.37E+00 9.3E-01 2.0E+00 6.4E+00
Mn SWA-L07-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.00E+03 84% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.08E+03 90% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.12E+03 93% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1439
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg SWA-L07-1316-T01-A 1
Mg SWA-L07-1316-T02-A 1
Mg SWA-L07-1316-T03-A 1
Mg SWA-L07-1316-T04-A 1
Mg SWA-L07-1316-T01-B 1
Mg SWA-L07-1316-T02-B 1
Mg SWA-L07-1316-T03-B 1
Mg SWA-L07-1316-T04-B 1
Mg SWA-L07-1316-T01-C 1
Mg SWA-L07-1316-T02-C 1
Mg SWA-L07-1316-T03-C 1
Mg SWA-L07-1316-T04-C 1
Mg SWA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
6.49E+00
9.71 E+00
1.06E+01
5.00E-01 U1/2
7.17E+00
1.02E+01
1.19E+01
5.00E-01 U1/2
7.33E+00
8.43E+00
9.33E+00
3.37E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 4.8E+01 1.0E+00 3.2E+00
6.49E+00 4.1E+02 1.0E+00 3.2E+00 1000 120
9.71 E+00 4.7E+01 1.0E+00 3.2E+00
1.06E+01 9.7E+01 1.0E+00 3.2E+00
5.00E-01 3.9E+01 1.0E+00 3.2E+00
7.17E+00 2.7E+01 1.0E+00 3.2E+00 1000 120
1.02E+01 4.3E+01 1.0E+00 3.2E+00
1.19E+01 5.8E+01 1.0E+00 3.2E+00
5.00E-01 1.4E+03 1.0E+00 3.2E+00
7.33E+00 7.6E+01 1.0E+00 3.2E+00 1000 120
8.43E+00 9.0E+01 1.0E+00 3.2E+00
9.33E+00 3.6E+01 1.0E+00 3.2E+00
3.37E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.00E+03 83% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.09E+03 90% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.13E+03 93% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1440
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 1 ug/L
Mo SWA-L07-1316-T01-A 1 9.52E+01
Mo SWA-L07-1316-T02-A 1 1.45E+02
Mo SWA-L07-1316-T03-A 1 6.67E+02
Mo SWA-L07-1316-T04-A 1 1.34E+03
Mo SWA-L07-1316-T01-B 1 8.75E+01
Mo SWA-L07-1316-T02-B 1 1.22E+02
Mo SWA-L07-1316-T03-B 1 6.31 E+02
Mo SWA-L07-1316-T04-B 1 1.33E+03
Mo SWA-L07-1316-T01-C 1 8.04E+01
Mo SWA-L07-1316-T02-C 1 1.29E+02
Mo SWA-L07-1316-T03-C 1 5.94E+02
Mo SWA-L07-1316-T04-C 1 1.35E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.52E+01 1.5E+00 1.2E+00 3.8E+00
1.45E+02 4.9E-01 1.2E+00 3.8E+00 10 120
6.67E+02 1.0E+00 1.2E+00 3.8E+00
1.34E+03 7.8E-01 1.2E+00 3.8E+00
8.75E+01 3.6E+00 1.2E+00 3.8E+00
1.22E+02 2.6E-01 1.2E+00 3.8E+00 10 120
6.31 E+02 7.7E-01 1.2E+00 3.8E+00
1.33E+03 5.9E-01 1.2E+00 3.8E+00
8.04E+01 2.0E+00 1.2E+00 3.8E+00
1.29E+02 1.6E+00 1.2E+00 3.8E+00 10 120
5.94E+02 3.7E-01 1.2E+00 3.8E+00
1.35E+03 8.1E-01 1.2E+00 3.8E+00
Mo SWA-L07-1316-B01-A 1 1.23E+OOE 1.23E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.25E+03 92% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.30E+03 99% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.31E+03 99% VU ICP-OES 1 2/3/1 0 1 2 :45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1441
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L07-1316-T01-A 1 9.00E-01 U1/2 9.00E-01 3.4E+02 1.8E+00 5.7E+00
Ni SWA-L07-1316-T02-A 1 9.00E-01 U1/2 9.00E-01 3.8E+01 1.8E+00 5.7E+00 10 120
Ni SWA-L07-1316-T03-A 1 9.00E-01 U1/2 9.00E-01 9.9E+01 1.8E+00 5.7E+00
Ni SWA-L07-1316-T04-A 1 4.31 E+00 E
4.31 E+00 4.0E+01 1.8E+00 5.7E+00
Ni SWA-L07-1316-T01-B 1 9.00E-01 U1/2 9.00E-01 6.6E+01 1.8E+00 5.7E+00
Ni SWA-L07-1316-T02-B 1 9.00E-01 U1/2 9.00E-01 2.8E+01 1.8E+00 5.7E+00 10 120
Ni SWA-L07-1316-T03-B 1 9.00E-01 U1/2 9.00E-01 1.3E+02 1.8E+00 5.7E+00
Ni SWA-L07-1316-T04-B 1 4.32E+00 E
4.32E+00 1.4E+01 1.8E+00 5.7E+00
Ni SWA-L07-1316-T01-C 1 9.00E-01 U1/2 9.00E-01 1.0E+02 1.8E+00 5.7E+00
Ni SWA-L07-1316-T02-C 1 9.00E-01 U1/2 9.00E-01 1.3E+02 1.8E+00 5.7E+00 10 120
Ni SWA-L07-1316-T03-C 1 9.00E-01 U1/2 9.00E-01 4.8E+01 1.8E+00 5.7E+00
Ni SWA-L07-1316-T04-C 1 4.61 E+00 E
4.61 E+00 4.0E+01 1.8E+00 5.7E+00
Ni SWA-L07-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
9.98E+02 83% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.07E+03 89% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/1012:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.11E+03 93% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1442
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P SWA-L07-1316-T01-A 1
P SWA-L07-1316-T02-A 1
P SWA-L07-1316-T03-A 1
P SWA-L07-1316-T04-A 1
P SWA-L07-1316-T01-B 1
P SWA-L07-1316-T02-B 1
P SWA-L07-1316-T03-B 1
P SWA-L07-1316-T04-B 1
P SWA-L07-1316-T01-C 1
P SWA-L07-1316-T02-C 1
P SWA-L07-1316-T03-C 1
P SWA-L07-1316-T04-C 1
P SWA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
7.09E+01
1.14E+02
3.92E+02
1.37E+03
5.77E+01
1.25E+02
3.78E+02
1.23E+03
5.83E+01
9.65E+01
3.62E+02
1.25E+03
6.62E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.09E+01 1.1E+01 3.7E+00 1.2E+01
1.14E+02 1.8E+01 3.7E+00 1.2E+01 1000 120
3.92E+02 3.9E+00 3.7E+00 1.2E+01
1.37E+03 2.5E+00 3.7E+00 1.2E+01
5.77E+01 7.5E+00 3.7E+00 1.2E+01
1.25E+02 1.3E+01 3.7E+00 1.2E+01 1000 120
3.78E+02 2.3E+00 3.7E+00 1.2E+01
1.23E+03 2.8E+00 3.7E+00 1.2E+01
5.83E+01 9.2E+00 3.7E+00 1.2E+01
9.65E+01 1.5E+01 3.7E+00 1 .2E+01 1000 120
3.62E+02 6.8E-01 3.7E+00 1 .2E+01
1.25E+03 1.6E+00 3.7E+00 1 .2E+01
6.62E+00 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.20E+03 90% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.28E+03 96% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.29E+03 100% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1443
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
K SWA-L07-1316-T01-A 1 3.04E+05
K SWA-L07-1316-T02-A 1 4.94E+05
K SWA-L07-1316-T03-A 1 2.23E+06
K SWA-L07-1316-T04-A 1 2.34E+06
K SWA-L07-1316-T01-B 1 3.04E+05
K SWA-L07-1316-T02-B 1 5.10E+05
K SWA-L07-1316-T03-B 1 2.21E+06
K SWA-L07-1316-T04-B 1 2.31E+06
K SWA-L07-1316-T01-C 1 3.02E+05
K SWA-L07-1316-T02-C 1 4.78E+05
K SWA-L07-1316-T03-C 1 2.19E+06
K SWA-L07-1316-T04-C 1 2.36E+06
K SWA-L07-1316-B01-A 1 5.98E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.04E+05 1.3E+00 1.6E+00 5.1E+00
4.94E+05 7.9E-01 1.6E+00 5.1E+00 1000 120
2.23E+06 6.1E-01 1.6E+00 5.1E+00
2.34E+06 7.5E-01 1.6E+00 5.1E+00
3.04E+05 6.6E-01 1.6E+00 5.1E+00
5.10E+05 2.6E+00 1.6E+00 5.1E+00 1000 120
2.21E+06 8.3E-01 1.6E+00 5.1E+00
2.31E+06 7.0E-01 1.6E+00 5.1E+00
3.02E+05 3.8E-01 1.6E+00 5.1E+00
4.78E+05 1.7E+00 1.6E+00 5.1E+00 1000 120
2.19E+06 1.3E+00 1.6E+00 5.1E+00
2.36E+06 4.7E-01 1.6E+00 5.1E+00
5.98E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
4.95E+05 87% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
5.11E+05 87% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
4.79E+05 94% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1444
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qu
Se SWA-L07-1316-T01-A 1 9.42E+04
Se SWA-L07-1316-T02-A 1 1.78E+05
Se SWA-L07-1316-T03-A 1 4.49E+05
Se SWA-L07-1316-T04-A 1 8.69E+05
Se SWA-L07-1316-T01-B 1 9.49E+04
Se SWA-L07-1316-T02-B 1 1.82E+05
Se SWA-L07-1316-T03-B 1 4.33E+05
Se SWA-L07-1316-T04-B 1 8.49E+05
Se SWA-L07-1316-T01-C 1 9.08E+04
Se SWA-L07-1316-T02-C 1 1.60E+05
Se SWA-L07-1316-T03-C 1 4.05E+05
Se SWA-L07-1316-T04-C 1 8.59E+05
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.42E+04 7.1E-01 1.5E+01 4.8E+01
1.78E+05 2.6E-01 1.5E+01 4.8E+01 10 120
4.49E+05 4.5E-01 1.5E+01 4.8E+01
8.69E+05 1.1E+00 1.5E+01 4.8E+01
9.49E+04 4.9E-01 1.5E+01 4.8E+01
1.82E+05 4.5E-01 1.5E+01 4.8E+01 10 120
4.33E+05 3.1E-01 1.5E+01 4.8E+01
8.49E+05 9.3E-02 1.5E+01 4.8E+01
9.08E+04 2.0E-01 1.5E+01 4.8E+01
1.60E+05 3.5E-01 1.5E+01 4.8E+01 10 120
4.05E+05 8.2E-01 1.5E+01 4.8E+01
8.59E+05 3.4E-01 1.5E+01 4.8E+01
Se SWA-L07-1316-B01-A 1 7.50E+00 U1/2 7.50E+00 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.79E+05 87% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.83E+05 98% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.61E+05 92% VU ICP-OES 1 2/3/1 0 1 2 :45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1445
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qu
Si SWA-L07-1316-T01-A 1 2.38E+04
Si SWA-L07-1316-T02-A 1 3.10E+04
Si SWA-L07-1316-T03-A 1 2.59E+04
Si SWA-L07-1316-T04-A 1 5.52E+04
Si SWA-L07-1316-T01-B 1 2.48E+04
Si SWA-L07-1316-T02-B 1 3.30E+04
Si SWA-L07-1316-T03-B 1 2.52E+04
Si SWA-L07-1316-T04-B 1 4.89E+04
Si SWA-L07-1316-T01-C 1 2.39E+04
Si SWA-L07-1316-T02-C 1 2.94E+04
Si SWA-L07-1316-T03-C 1 3.03E+04
Si SWA-L07-1316-T04-C 1 4.97E+04
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.38E+04 3.4E-01 1.1E+00 3.5E+00
3.10E+04 6.2E-01 1.1E+00 3.5E+00 1000 120
2.59E+04 2.4E-01 1.1E+00 3.5E+00
5.52E+04 4.8E-01 1.1E+00 3.5E+00
2.48E+04 2.7E-01 1.1E+00 3.5E+00
3.30E+04 2.7E-01 1.1E+00 3.5E+00 1000 120
2.52E+04 2.9E-01 1.1E+00 3.5E+00
4.89E+04 4.1E-01 1.1E+00 3.5E+00
2.39E+04 6.9E-01 1.1E+00 3.5E+00
2.94E+04 4.8E-01 1.1E+00 3.5E+00 1000 120
3.03E+04 1.2E+00 1.1E+00 3.5E+00
4.97E+04 4.7E-01 1.1E+00 3.5E+00
Si SWA-L07-1316-B01-A 1 5.50E-01 U1/2 5.50E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
3.20E+04 83% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
3.40E+04 82% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
3.04E+04 85% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1446
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qu
1 1 ug/L
Na SWA-L07-1316-T01-A 1 4.15E+05
Na SWA-L07-1316-T02-A 1 5.40E+05
Na SWA-L07-1316-T03-A 1 6.26E+05
Na SWA-L07-1316-T04-A 1 6.86E+05
Na SWA-L07-1316-T01-B 1 4.14E+05
Na SWA-L07-1316-T02-B 1 5.43E+05
Na SWA-L07-1316-T03-B 1 6.22E+05
Na SWA-L07-1316-T04-B 1 6.77E+05
Na SWA-L07-1316-T01-C 1 4.16E+05
Na SWA-L07-1316-T02-C 1 5.29E+05
Na SWA-L07-1316-T03-C 1 6.18E+05
Na SWA-L07-1316-T04-C 1 6.88E+05
Na SWA-L07-1316-B01-A 1 5.33E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.15E+05 6.2E-01 2.5E+00 8.0E+00
5.40E+05 4.3E-01 2.5E+00 8.0E+00 1000 120
6.26E+05 6.9E-01 2.5E+00 8.0E+00
6.86E+05 4.5E-01 2.5E+00 8.0E+00
4.14E+05 4.8E-01 2.5E+00 8.0E+00
5.43E+05 2.1E-01 2.5E+00 8.0E+00 1000 120
6.22E+05 8.2E-01 2.5E+00 8.0E+00
6.77E+05 7.1E-01 2.5E+00 8.0E+00
4.16E+05 1.6E-01 2.5E+00 8.0E+00
5.29E+05 1.2E-01 2.5E+00 8.0E+00 1000 120
6.18E+05 9.1E-01 2.5E+00 8.0E+00
6.88E+05 3.7E-01 2.5E+00 8.0E+00
5.33E+01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
5.41E+05 87% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
5.44E+05 84% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
5.30E+05 83% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1447
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-L07-1316-T01-A 1
SWA-L07-1316-T02-A 1
SWA-L07-1316-T03-A 1
SWA-L07-1316-T04-A 1
SWA-L07-1316-T01-B 1
SWA-L07-1316-T02-B 1
SWA-L07-1316-T03-B 1
SWA-L07-1316-T04-B 1
SWA-L07-1316-T01-C 1
SWA-L07-1316-T02-C 1
SWA-L07-1316-T03-C 1
SWA-L07-1316-T04-C 1
SWA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
3.73E+02
3.77E+02
1.63E+02
4.59E+02
3.78E+02
3.75E+02
1.78E+02
4.84E+02
3.82E+02
3.91 E+02
1.55E+02
4.97E+02
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.73E+02 1.5E-01 1.0E+00 3.2E+00
3.77E+02 4.8E-01 1.0E+00 3.2E+00 1000 120
1.63E+02 5.7E-01 1.0E+00 3.2E+00
4.59E+02 1.2E+00 1.0E+00 3.2E+00
3.78E+02 6.8E-01 1.0E+00 3.2E+00
3.75E+02 6.2E-01 1.0E+00 3.2E+00 1000 120
1.78E+02 8.3E-01 1.0E+00 3.2E+00
4.84E+02 7.0E-01 1.0E+00 3.2E+00
3.82E+02 3.2E-01 1.0E+00 3.2E+00
3.91E+02 1.0E+00 1.0E+00 3.2E+00 1000 120
1.55E+02 1.0E+00 1.0E+00 3.2E+00
4.97E+02 5.4E-01 1.0E+00 3.2E+00
5.00E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.40E+03 85% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.47E+03 91% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.52E+03 94% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1448
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
1 ug/L
S SWA-L07-1316-T01-A 1 1.02E+06
S SWA-L07-1316-T02-A 1 1.45E+06
S SWA-L07-1316-T03-A 1 1.76E+06
S SWA-L07-1316-T04-A 1 2.36E+06
S SWA-L07-1316-T01-B 1 1.10E+06
S SWA-L07-1316-T02-B 1 1.59E+06
S SWA-L07-1316-T03-B 1 1.68E+06
S SWA-L07-1316-T04-B 1 2.29E+06
S SWA-L07-1316-T01-C 1 1.08E+06
S SWA-L07-1316-T02-C 1 1.54E+06
S SWA-L07-1316-T03-C 1 1.62E+06
S SWA-L07-1316-T04-C 1 2.33E+06
S SWA-L07-1316-B01-A 1 9.49E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.02E+06 1.5E-01 6.8E+00 2.2E+01
1.45E+06 5.8E-01 6.8E+00 2.2E+01 1000 120
1.76E+06 5.7E-01 6.8E+00 2.2E+01
2.36E+06 1.4E+00 6.8E+00 2.2E+01
1.10E+06 8.4E-01 6.8E+00 2.2E+01
1.59E+06 1.1E+00 6.8E+00 2.2E+01 1000 120
1.68E+06 4.7E-01 6.8E+00 2.2E+01
2.29E+06 4.8E-01 6.8E+00 2.2E+01
1.08E+06 3.2E-01 6.8E+00 2.2E+01
1.54E+06 1.0E+00 6.8E+00 2.2E+01 1000 120
1.62E+06 6.5E-01 6.8E+00 2.2E+01
2.33E+06 1.5E-01 6.8E+00 2.2E+01
9.49E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.45E+06 86% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.59E+06 85% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.54E+06 88% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1449
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L07-1316-T01-A 1 2.30E+00 U1/2 2.30E+00 7.4E+01 4.6E+00 1.5E+01
Tl SWA-L07-1316-T02-A 1 2.30E+00 U1/2 2.30E+00 5.8E+01 4.6E+00 1.5E+01 10 120
Tl SWA-L07-1316-T03-A 1 2.30E+00 U1/2 2.30E+00 3.4E+01 4.6E+00 1.5E+01
Tl SWA-L07-1316-T04-A 1 2.30E+00 U1/2 2.30E+00 1 .6E+02 4.6E+00 1.5E+01
Tl SWA-L07-1316-T01-B 1 2.30E+00 U1/2 2.30E+00 2.9E+01 4.6E+00 1.5E+01
Tl SWA-L07-1316-T02-B 1 2.30E+00 U1/2 2.30E+00 3.3E+01 4.6E+00 1.5E+01 10 120
Tl SWA-L07-1316-T03-B 1 2.30E+00 U1/2 2.30E+00 6.6E+01 4.6E+00 1.5E+01
Tl SWA-L07-1316-T04-B 1 2.30E+00 U1/2 2.30E+00 8.9E+01 4.6E+00 1.5E+01
Tl SWA-L07-1316-T01-C 1 2.30E+00 U1/2 2.30E+00 1 .3E+02 4.6E+00 1.5E+01
Tl SWA-L07-1316-T02-C 1 2.30E+00 U1/2 2.30E+00 3.5E+01 4.6E+00 1.5E+01 10 120
Tl SWA-L07-1316-T03-C 1 2.30E+00 U1/2 2.30E+00 6.8E+01 4.6E+00 1.5E+01
Tl SWA-L07-1316-T04-C 1 2.30E+00 U1/2 2.30E+00 6.8E+02 4.6E+00 1.5E+01
Tl SWA-L07-1316-B01-A 1 2.30E+00 U1/2 2.30E+00 4.6E+00 1 .5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.11E+03 92% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.17E+03 97% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.19E+03 99% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1450
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L07-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 3.0E+01 2.0E+00 6.4E+00
Ti SWA-L07-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 2.0E+01 2.0E+00 6.4E+00 10 120
Ti SWA-L07-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 7.7E+01 2.0E+00 6.4E+00
Ti SWA-L07-1316-T04-A 1 3.03E+00 E
3.03E+00 1.1E+01 2.0E+00 6.4E+00
Ti SWA-L07-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 3.6E+01 2.0E+00 6.4E+00
Ti SWA-L07-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 4.7E+01 2.0E+00 6.4E+00 10 120
Ti SWA-L07-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 1 .4E+01 2.0E+00 6.4E+00
Ti SWA-L07-1316-T04-B 1 3.41E+00 E
3.41 E+00 8.7E+00 2.0E+00 6.4E+00
Ti SWA-L07-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 4.0E+01 2.0E+00 6.4E+00
Ti SWA-L07-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 3.6E+01 2.0E+00 6.4E+00 10 120
Ti SWA-L07-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 2.8E+01 2.0E+00 6.4E+00
Ti SWA-L07-1316-T04-C 1 3.72E+00 E
3.72E+00 1.4E+01 2.0E+00 6.4E+00
Ti SWA-L07-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.15E+03 96% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.25E+03 104% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.29E+03 108% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1451
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qu
V SWA-L07-1316-T01-A 1 3.63E+02
V SWA-L07-1316-T02-A 1 6.48E+02
V SWA-L07-1316-T03-A 1 1.32E+03
V SWA-L07-1316-T04-A 1 2.35E+03
V SWA-L07-1316-T01-B 1 3.59E+02
V SWA-L07-1316-T02-B 1 6.61 E+02
V SWA-L07-1316-T03-B 1 1.24E+03
V SWA-L07-1316-T04-B 1 2.00E+03
V SWA-L07-1316-T01-C 1 3.42E+02
V SWA-L07-1316-T02-C 1 5.62E+02
V SWA-L07-1316-T03-C 1 1.14E+03
V SWA-L07-1316-T04-C 1 2.03E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.63E+02 9.3E-02 1.5E+00 4.8E+00
6.48E+02 1.1E+00 1.5E+00 4.8E+00 10 120
1.32E+03 7.0E-01 1.5E+00 4.8E+00
2.35E+03 1.4E+00 1.5E+00 4.8E+00
3.59E+02 5.2E-01 1.5E+00 4.8E+00
6.61E+02 1.1E+00 1.5E+00 4.8E+00 10 120
1.24E+03 2.1E-01 1.5E+00 4.8E+00
2.00E+03 5.8E-01 1.5E+00 4.8E+00
3.42E+02 2.6E-01 1.5E+00 4.8E+00
5.62E+02 1.6E-01 1.5E+00 4.8E+00 10 120
1.14E+03 1.3E+00 1.5E+00 4.8E+00
2.03E+03 6.6E-01 1.5E+00 4.8E+00
V SWA-L07-1316-B01-A 1 7.50E-01 U1/2 7.50E-01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.64E+03 83% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.72E+03 88% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.66E+03 92% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1452
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-L07-1316-T01-A 1
Zn SWA-L07-1316-T02-A 1
Zn SWA-L07-1316-T03-A 1
Zn SWA-L07-1316-T04-A 1
Zn SWA-L07-1316-T01-B 1
Zn SWA-L07-1316-T02-B 1
Zn SWA-L07-1316-T03-B 1
Zn SWA-L07-1316-T04-B 1
Zn SWA-L07-1316-T01-C 1
Zn SWA-L07-1316-T02-C 1
Zn SWA-L07-1316-T03-C 1
Zn SWA-L07-1316-T04-C 1
Zn SWA-L07-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
6.48E+00
7.57E+00
5.00E-01 U1/2
5.00E-01 U1/2
7.19E+00
1.09E+01
5.00E-01 U1/2
5.00E-01 U1/2
7.53E+00
1.09E+01
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 2.3E+02 1.0E+00 3.2E+00
5.00E-01 1.9E+01 1.0E+00 3.2E+00 10 120
6.48E+00 7.5E+01 1.0E+00 3.2E+00
7.57E+00 2.8E+00 1.0E+00 3.2E+00
5.00E-01 1.4E+02 1.0E+00 3.2E+00
5.00E-01 4.1E+01 1.0E+00 3.2E+00 10 120
7.19E+00 9.0E+01 1.0E+00 3.2E+00
1.09E+01 4.3E+00 1.0E+00 3.2E+00
5.00E-01 9.3E+01 1.0E+00 3.2E+00
5.00E-01 1.8E+01 1.0E+00 3.2E+00 10 120
7.53E+00 1.2E+02 1.0E+00 3.2E+00
1.09E+01 8.2E+00 1.0E+00 3.2E+00
5.00E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/3/10 12:31 PM EPA Interlab L07 1313-1316 SWA
1.09E+03 91% VU ICP-OES 12/3/10 12:32 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:34 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:36 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:37 PM EPA Interlab L07 1313-1316 SWA
1.17E+03 98% VU ICP-OES 12/3/10 12:39 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:40 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:42 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:44 PM EPA Interlab L07 1313-1316 SWA
1.22E+03 101% VU ICP-OES 12/3/10 12:45 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:47 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:49 PM EPA Interlab L07 1313-1316 SWA
VU ICP-OES 12/3/10 12:29 PM EPA Interlab L07 1313-1316 SWA
                                                                                                                                                                         1-1453
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al SWA-L09-1316-T01-A 1
Al SWA-L09-1316-T02-A 1
Al SWA-L09-1316-T03-A 1
Al SWA-L09-1316-T04-A 1
Al SWA-L09-1316-T05-A 1
Al SWA-L09-1316-T01-B 1
Al SWA-L09-1316-T02-B 1
Al SWA-L09-1316-T03-B 1
Al SWA-L09-1316-T04-B 1
Al SWA-L09-1316-T05-B 1
Al SWA-L09-1316-T01-C 1
Al SWA-L09-1316-T02-C 1
Al SWA-L09-1316-T03-C 1
Al SWA-L09-1316-T04-C 1
Al SWA-L09-1316-T05-C 1
Al SWA-L09-1316-B01-A 1
Al SWA-L09-1316-B01-B 1
Al SWA-L09-1316-B01-C 1
Sample
Cone. Qualifier
ug/L
3.37E+04
5.03E+04
2.30E+04
1.05E+05
1.88E+05
3.06E+04
5.02E+04
2.56E+04
1.18E+05
1.93E+05
3.35E+04
5.03E+04
2.73E+04
1.19E+05
1.99E+05
2.14E+00 E
5.00E-01 U1/2
2.92E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.37E+04 8.8E-01 1.0E+00 3.2E+00
5.03E+04 3.4E-01 1.0E+00 3.2E+00
2.30E+04 3.5E-01 1.0E+00 3.2E+00
1.05E+05 4.9E-01 1.0E+00 3.2E+00
1.88E+05 4.1E-01 1.0E+00 3.2E+00
3.06E+04 1.5E+00 1.0E+00 3.2E+00
5.02E+04 2.6E-01 1.0E+00 3.2E+00 1000 100
2.56E+04 4.1E-01 1.0E+00 3.2E+00
1.18E+05 7.2E-01 1.0E+00 3.2E+00
1.93E+05 4.1E-01 1.0E+00 3.2E+00
3.35E+04 5.4E-01 1.0E+00 3.2E+00
5.03E+04 4.0E-02 1.0E+00 3.2E+00 1000 100
2.73E+04 7.4E-01 1.0E+00 3.2E+00
1.19E+05 1.1E+00 1.0E+00 3.2E+00
1.99E+05 2.2E-01 1.0E+00 3.2E+00
2.14E+00 2.4E+01 1.0E+00 3.2E+00
5.00E-01 9.4E+01 1.0E+00 3.2E+00
2.92E+00 4.9E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
5.12E+04 96% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
5.12E+04 97% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                                  1-1454
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L09-1316-T01-A 1
Sb SWA-L09-1316-T02-A 1
Sb SWA-L09-1316-T03-A 1
Sb SWA-L09-1316-T04-A 1
Sb SWA-L09-1316-T05-A 1
Sb SWA-L09-1316-T01-B 1
Sb SWA-L09-1316-T02-B 1
Sb SWA-L09-1316-T03-B 1
Sb SWA-L09-1316-T04-B 1
Sb SWA-L09-1316-T05-B 1
Sb SWA-L09-1316-T01-C 1
Sb SWA-L09-1316-T02-C 1
Sb SWA-L09-1316-T03-C 1
Sb SWA-L09-1316-T04-C 1
Sb SWA-L09-1316-T05-C 1
Sb SWA-L09-1316-B01-A 1
Sb SWA-L09-1316-B01-B 1
Sb SWA-L09-1316-B01-C 1
Sample
Cone. Qualifier
ug/L
4.49E+03
3.05E+03
6.97E+03
7.45E+03
6.25E+03
3.45E+03
2.96E+03
7.04E+03
7.17E+03
7.21 E+03
4.23E+03
3.14E+03
7.60E+03
7.70E+03
6.82E+03
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.49E+03 1.2E+00 7.5E+00 2.4E+01
3.05E+03 6.2E-01 7.5E+00 2.4E+01
6.97E+03 5.4E-01 7.5E+00 2.4E+01
7.45E+03 3.9E-01 7.5E+00 2.4E+01
6.25E+03 8.3E-01 7.5E+00 2.4E+01
3.45E+03 5.3E-01 7.5E+00 2.4E+01
2.96E+03 5.8E-01 7.5E+00 2.4E+01 10 100
7.04E+03 7.3E-01 7.5E+00 2.4E+01
7.17E+03 8.8E-01 7.5E+00 2.4E+01
7.21 E+03 6.4E-01 7.5E+00 2.4E+01
4.23E+03 1.3E-01 7.5E+00 2.4E+01
3.14E+03 8.0E-01 7.5E+00 2.4E+01 10 100
7.60E+03 1.2E+00 7.5E+00 2.4E+01
7.70E+03 8.1E-01 7.5E+00 2.4E+01
6.82E+03 3.8E-01 7.5E+00 2.4E+01
3.75E+00 6.2E+01 7.5E+00 2.4E+01
3.75E+00 7.4E+01 7.5E+00 2.4E+01
3.75E+00 2.0E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 4:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:27 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:30 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:32 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:34 PM EPA Interlab 1316 SWA Reruns
3.85E+03 88% VU ICP-OES 5/23/11 4:36 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:39 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:41 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:43 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:45 PM EPA Interlab 1316 SWA Reruns
4.06E+03 92% VU ICP-OES 5/23/11 4:48 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:50 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:52 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:55 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1455
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-L09-1316-T01-A 1
As SWA-L09-1316-T02-A 1
As SWA-L09-1316-T03-A 1
As SWA-L09-1316-T04-A 1
As SWA-L09-1316-T05-A 1
As SWA-L09-1316-T01-B 1
As SWA-L09-1316-T02-B 1
As SWA-L09-1316-T03-B 1
As SWA-L09-1316-T04-B 1
As SWA-L09-1316-T05-B 1
As SWA-L09-1316-T01-C 1
As SWA-L09-1316-T02-C 1
As SWA-L09-1316-T03-C 1
As SWA-L09-1316-T04-C 1
As SWA-L09-1316-T05-C 1
As SWA-L09-1316-B01-A 1
As SWA-L09-1316-B01-B 1
As SWA-L09-1316-B01-C 1
Sample
Cone. Qualifier
ug/L
3.96E+03
1.01E+04
2.47E+04
1.03E+05
2.62E+05
2.69E+03
9.72E+03
2.98E+04
9.10E+04
2.28E+05
3.93E+03
1.01E+04
3.26E+04
9.93E+04
2.29E+05
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.96E+03 7.0E-01 1.1E+01 3.5E+01
1.01E+04 3.2E+00 1.1E+01 3.5E+01
2.47E+04 3.5E-01 1.1E+01 3.5E+01
1.03E+05 3.7E-01 1.1E+01 3.5E+01
2.62E+05 1.6E+00 1.1E+01 3.5E+01
2.69E+03 7.9E-01 1.1E+01 3.5E+01
9.72E+03 2.2E+00 1.1E+01 3.5E+01 10 100
2.98E+04 1.3E+00 1.1E+01 3.5E+01
9.10E+04 6.3E-01 1.1E+01 3.5E+01
2.28E+05 9.1E-01 1.1E+01 3.5E+01
3.93E+03 6.1E-01 1.1E+01 3.5E+01
1.01E+04 2.3E-01 1.1E+01 3.5E+01 10 100
3.26E+04 5.5E-01 1.1E+01 3.5E+01
9.93E+04 1.2E+00 1.1E+01 3.5E+01
2.29E+05 1.1E+00 1.1E+01 3.5E+01
5.50E+00 1.5E+01 1.1E+01 3.5E+01
5.50E+00 8.5E+01 1.1E+01 3.5E+01
5.50E+00 2.5E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 4:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:27 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:30 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:32 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:34 PM EPA Interlab 1316 SWA Reruns
1.06E+04 92% VU ICP-OES 5/23/11 4:36 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:39 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:41 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:43 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:45 PM EPA Interlab 1316 SWA Reruns
1.10E+04 90% VU ICP-OES 5/23/11 4:48 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:50 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:52 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:55 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1456
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-L09-1316-T01-A 1
B SWA-L09-1316-T02-A 1
B SWA-L09-1316-T03-A 1
B SWA-L09-1316-T04-A 1
B SWA-L09-1316-T05-A 1
B SWA-L09-1316-T01-B 1
B SWA-L09-1316-T02-B 1
B SWA-L09-1316-T03-B 1
B SWA-L09-1316-T04-B 1
B SWA-L09-1316-T05-B 1
B SWA-L09-1316-T01-C 1
B SWA-L09-1316-T02-C 1
B SWA-L09-1316-T03-C 1
B SWA-L09-1316-T04-C 1
B SWA-L09-1316-T05-C 1
B SWA-L09-1316-B01-A 1
B SWA-L09-1316-B01-B 1
B SWA-L09-1316-B01-C 1
Sample
Cone. Qualifier
ug/L
7.97E+02
1.09E+03
1.12E+03
9.40E+02
2.38E+03
5.79E+02
1.04E+03
9.24E+02
7.72E+02
2.43E+03
7.83E+02
1.13E+03
1.31E+03
1.12E+03
1.77E+03
2.85E+01
2.05E+01
1.67E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.97E+02 7.8E-01 1.0E+00 3.2E+00
1.09E+03 5.7E-01 1.0E+00 3.2E+00
1.12E+03 7.0E-01 1.0E+00 3.2E+00
9.40E+02 2.8E-01 1.0E+00 3.2E+00
2.38E+03 1.0E+00 1.0E+00 3.2E+00
5.79E+02 3.6E-01 1.0E+00 3.2E+00
1.04E+03 6.3E-01 1.0E+00 3.2E+00 1000 100
9.24E+02 7.8E-01 1.0E+00 3.2E+00
7.72E+02 8.5E-01 1.0E+00 3.2E+00
2.43E+03 6.1E-01 1.0E+00 3.2E+00
7.83E+02 1.7E-01 1.0E+00 3.2E+00
1.13E+03 1.8E-01 1.0E+00 3.2E+00 1000 100
1.31E+03 4.0E-01 1.0E+00 3.2E+00
1.12E+03 1.0E+00 1.0E+00 3.2E+00
1.77E+03 2.2E-01 1.0E+00 3.2E+00
2.85E+01 2.4E+00 1.0E+00 3.2E+00
2.05E+01 5.5E+00 1.0E+00 3.2E+00
1.67E+01 5.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
2.02E+03 98% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
2.03E+03 90% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1457
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba SWA-L09-1316-T01-A 1
Ba SWA-L09-1316-T02-A 1
Ba SWA-L09-1316-T03-A 1
Ba SWA-L09-1316-T04-A 1
Ba SWA-L09-1316-T05-A 1
Ba SWA-L09-1316-T01-B 1
Ba SWA-L09-1316-T02-B 1
Ba SWA-L09-1316-T03-B 1
Ba SWA-L09-1316-T04-B 1
Ba SWA-L09-1316-T05-B 1
Ba SWA-L09-1316-T01-C 1
Ba SWA-L09-1316-T02-C 1
Ba SWA-L09-1316-T03-C 1
Ba SWA-L09-1316-T04-C 1
Ba SWA-L09-1316-T05-C 1
Ba SWA-L09-1316-B01-A 1
Ba SWA-L09-1316-B01-B 1
Ba SWA-L09-1316-B01-C 1
Sample
Cone. Qualifier
ug/L
2.26E+02
2.01 E+02
5.98E+01
6.71E+01
3.83E+01
2.49E+02
2.02E+02
6.49E+01
6.71 E+01
3.65E+01
2.24E+02
2.02E+02
1.85E+01
5.65E+01
3.72E+01
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.26E+02 7.6E-01 1.0E+00 3.2E+00
2.01 E+02 4.8E-01 1.0E+00 3.2E+00
5.98E+01 7.0E-01 1.0E+00 3.2E+00
6.71 E+01 7.7E-01 1.0E+00 3.2E+00
3.83E+01 9.3E-01 1.0E+00 3.2E+00
2.49E+02 8.2E-01 1.0E+00 3.2E+00
2.02E+02 8.3E-01 1.0E+00 3.2E+00 10 100
6.49E+01 1.2E+00 1.0E+00 3.2E+00
6.71 E+01 2.7E-01 1.0E+00 3.2E+00
3.65E+01 2.5E+00 1.0E+00 3.2E+00
2.24E+02 4.9E-01 1.0E+00 3.2E+00
2.02E+02 5.8E-01 1.0E+00 3.2E+00 10 100
1.85E+01 2.1E+00 1.0E+00 3.2E+00
5.65E+01 1.0E+00 1.0E+00 3.2E+00
3.72E+01 1.2E+00 1.0E+00 3.2E+00
5.00E-01 2.0E+02 1.0E+00 3.2E+00
5.00E-01 5.5E+00 1.0E+00 3.2E+00
5.00E-01 2.1E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 4:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:27 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:30 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:32 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:34 PM EPA Interlab 1316 SWA Reruns
1.07E+03 86% VU ICP-OES 5/23/11 4:36 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:39 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:41 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:43 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:45 PM EPA Interlab 1316 SWA Reruns
1.15E+03 95% VU ICP-OES 5/23/11 4:48 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:50 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:52 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:55 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1458
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L09-1316-T01-A 1
Be SWA-L09-1316-T02-A 1
Be SWA-L09-1316-T03-A 1
Be SWA-L09-1316-T04-A 1
Be SWA-L09-1316-T05-A 1
Be SWA-L09-1316-T01-B 1
Be SWA-L09-1316-T02-B 1
Be SWA-L09-1316-T03-B 1
Be SWA-L09-1316-T04-B 1
Be SWA-L09-1316-T05-B 1
Be SWA-L09-1316-T01-C 1
Be SWA-L09-1316-T02-C 1
Be SWA-L09-1316-T03-C 1
Be SWA-L09-1316-T04-C 1
Be SWA-L09-1316-T05-C 1
Be SWA-L09-1316-B01-A 1
Be SWA-L09-1316-B01-B 1
Be SWA-L09-1316-B01-C 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.0E+01 1.9E+00 6.0E+00
9.50E-01 3.5E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 8.2E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 6.7E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+01 1.9E+00 6.0E+00 10 100
9.50E-01 9.0E+01 1.9E+00 6.0E+00
9.50E-01 2.1E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+01 1.9E+00 6.0E+00
9.50E-01 2.6E+01 1.9E+00 6.0E+00
9.50E-01 3.6E+01 1.9E+00 6.0E+00 10 100
9.50E-01 3.2E+01 1.9E+00 6.0E+00
9.50E-01 4.2E+01 1.9E+00 6.0E+00
9.50E-01 9.5E+00 1.9E+00 6.0E+00
9.50E-01 4.3E+01 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 3.7E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
9.38E+02 94% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.02E+03 101% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1459
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L09-1316-T01-A 1 1.10E+OOU1/2 1.10E+00 2.0E+01 2.2E+00 7.0E+00
Cd SWA-L09-1316-T02-A 1 1.10E+OOU1/2 1.10E+00 1.2E+02 2.2E+00 7.0E+00
Cd SWA-L09-1316-T03-A 1 1.10E+OOU1/2 1.10E+00 7.5E+01 2.2E+00 7.0E+00
Cd SWA-L09-1316-T04-A 1 1.10E+OOU1/2 1.10E+00 1.9E+01 2.2E+00 7.0E+00
Cd SWA-L09-1316-T05-A 1 1.10E+OOU1/2 1.10E+00 3.5E+01 2.2E+00 7.0E+00
Cd SWA-L09-1316-T01-B 1 1.10E+OOU1/2 1.10E+00 1.9E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
Cd SWA-L09-1316-T02-B 1 1.10E+OOU1/2 1.10E+00 1.6E+02 2.2E+00 7.0E+00 10 100 9.24E+02 92% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
Cd SWA-L09-1316-T03-B 1 1.10E+OOU1/2 1.10E+00 1.3E+02 2.2E+00 7.0E+00
Cd SWA-L09-1316-T04-B 1 1.10E+OOU1/2 1.10E+00 1.2E+02 2.2E+00 7.0E+00
Cd SWA-L09-1316-T05-B 1 1.10E+OOU1/2 1.10E+00 5.8E+01 2.2E+00 7.0E+00
Cd SWA-L09-1316-T01-C 1 1.10E+OOU1/2 1.10E+00 4.6E+01 2.2E+00 7.0E+00
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
Cd SWA-L09-1316-T02-C 1 1.10E+OOU1/2 1.10E+00 2.6E+01 2.2E+00 7.0E+00 10 100 8.92E+02 89% VU ICP-OES 4/20/1 1 4:12 PM EPA Interlab L09 1313-1316 SWA
Cd SWA-L09-1316-T03-C 1 1.10E+OOU1/2 1.10E+00 7.9E+01 2.2E+00 7.0E+00
Cd SWA-L09-1316-T04-C 1 1.10E+OOU1/2 1.10E+00 1.2E+02 2.2E+00 7.0E+00
Cd SWA-L09-1316-T05-C 1 1.10E+OOU1/2 1.10E+00 5.4E+01 2.2E+00 7.0E+00
Cd SWA-L09-1316-B01-A 1 1.10E+OOU1/2 1.10E+00 1.4E+01 2.2E+00 7.0E+00
Cd SWA-L09-1316-B01-B 1 1.10E+OOU1/2 1.10E+00 1.3E+02 2.2E+00 7.0E+00
Cd SWA-L09-1316-B01-C 1 1.10E+OOU1/2 1.10E+00 7.7E+01 2.2E+00 7.0E+00
VU ICP-OES 4/20/1 1 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/1 1 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1460
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qu
1 1 ug/L
Ca SWA-L09-1316-T01-A 1 1.45E+04
Ca SWA-L09-1316-T02-A 1 1.12E+04
Ca SWA-L09-1316-T03-A 1 2.39E+03
Ca SWA-L09-1316-T04-A 1 3.70E+03
Ca SWA-L09-1316-T05-A 1 3.12E+03
Ca SWA-L09-1316-T01-B 1 1.66E+04
Ca SWA-L09-1316-T02-B 1 1.12E+04
Ca SWA-L09-1316-T03-B 1 2.65E+03
Ca SWA-L09-1316-T04-B 1 3.40E+03
Ca SWA-L09-1316-T05-B 1 3.73E+03
Ca SWA-L09-1316-T01-C 1 1.44E+04
Ca SWA-L09-1316-T02-C 1 1.11E+04
Ca SWA-L09-1316-T03-C 1 2.34E+03
Ca SWA-L09-1316-T04-C 1 3.37E+03
Ca SWA-L09-1316-T05-C 1 3.23E+03
Ca SWA-L09-1316-B01-A 1 2.60E+01
Ca SWA-L09-1316-B01-B 1 2.24E+01
Ca SWA-L09-1316-B01-C 1 3.11E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.45E+04 8.6E-01 2.6E+00 8.3E+00
1.12E+04 8.2E-01 2.6E+00 8.3E+00
2.39E+03 1.2E+00 2.6E+00 8.3E+00
3.70E+03 3.1E+00 2.6E+00 8.3E+00
3.12E+03 8.6E+00 2.6E+00 8.3E+00
1.66E+04 6.2E-01 2.6E+00 8.3E+00
1.12E+04 4.6E-01 2.6E+00 8.3E+00 1000 100
2.65E+03 6.4E+00 2.6E+00 8.3E+00
3.40E+03 5.4E+00 2.6E+00 8.3E+00
3.73E+03 1.1E+01 2.6E+00 8.3E+00
1.44E+04 2.7E-02 2.6E+00 8.3E+00
1.11E+04 6.2E-01 2.6E+00 8.3E+00 1000 100
2.34E+03 1.1E+00 2.6E+00 8.3E+00
3.37E+03 9.5E-01 2.6E+00 8.3E+00
3.23E+03 4.5E+00 2.6E+00 8.3E+00
2.60E+01 6.1E+00 2.6E+00 8.3E+00
2.24E+01 1.1E+01 2.6E+00 8.3E+00
3.11E+01 1.9E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 4:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:27 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:30 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:32 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:34 PM EPA Interlab 1316 SWA Reruns
1.21E+04 87% VU ICP-OES 5/23/11 4:36 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:39 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:41 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:43 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:45 PM EPA Interlab 1316 SWA Reruns
1.19E+04 89% VU ICP-OES 5/23/11 4:48 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:50 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:52 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:55 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1461
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone.
1 ug/L
Cr SWA-L09-1316-T01-A 1 1.03E+03
Cr SWA-L09-1316-T02-A 1 1.67E+03
Cr SWA-L09-1316-T03-A 1 9.40E+02
Cr SWA-L09-1316-T04-A 1 1.86E+03
Cr SWA-L09-1316-T05-A 1 2.62E+03
Cr SWA-L09-1316-T01-B 1 9.53E+02
Cr SWA-L09-1316-T02-B 1 1.75E+03
Cr SWA-L09-1316-T03-B 1 1.29E+03
Cr SWA-L09-1316-T04-B 1 2.42E+03
Cr SWA-L09-1316-T05-B 1 2.81 E+03
Cr SWA-L09-1316-T01-C 1 9.77E+02
Cr SWA-L09-1316-T02-C 1 1.60E+03
Cr SWA-L09-1316-T03-C 1 1.87E+02
Cr SWA-L09-1316-T04-C 1 1.86E+03
Cr SWA-L09-1316-T05-C 1 2.91 E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.03E+03 1.3E+00 1.2E+00 3.8E+00
1.67E+03 5.5E-01 1.2E+00 3.8E+00
9.40E+02 6.9E-01 1.2E+00 3.8E+00
1.86E+03 7.3E-01 1.2E+00 3.8E+00
2.62E+03 8.3E-01 1.2E+00 3.8E+00
9.53E+02 1.0E+00 1.2E+00 3.8E+00
1.75E+03 1.8E+00 1.2E+00 3.8E+00 10 100
1.29E+03 1.9E-01 1.2E+00 3.8E+00
2.42E+03 2.5E-01 1.2E+00 3.8E+00
2.81 E+03 1.3E+00 1.2E+00 3.8E+00
9.77E+02 1.1E+00 1.2E+00 3.8E+00
1.60E+03 6.7E-01 1.2E+00 3.8E+00 10 100
1.87E+02 6.6E-01 1.2E+00 3.8E+00
1.86E+03 9.9E-01 1.2E+00 3.8E+00
2.91 E+03 4.2E-01 1.2E+00 3.8E+00
Cr SWA-L09-1316-B01-A 1 6.00E-01 U1/2 6.00E-01 6.8E+01 1.2E+00 3.8E+00
Cr SWA-L09-1316-B01-B 1 6.00E-01 U1/2 6.00E-01 1.4E+02 1.2E+00 3.8E+00
Cr SWA-L09-1316-B01-C 1 6.00E-01 U1/2 6.00E-01 8.7E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 4:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:27 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:30 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:32 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:34 PM EPA Interlab 1316 SWA Reruns
2.64E+03 89% VU ICP-OES 5/23/11 4:36 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:39 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:41 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:43 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:45 PM EPA Interlab 1316 SWA Reruns
2.55E+03 95% VU ICP-OES 5/23/11 4:48 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:50 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:52 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:55 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1462
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Co SWA-L09-1316-T01-A 1 9.00E-01 U1/2 9.00E-01 2.0E+01 1.8E+00 5.7E+00
Co SWA-L09-1316-T02-A 1 9.00E-01 U1/2 9.00E-01 5.6E+01 1.8E+00 5.7E+00
Co SWA-L09-1316-T03-A 1 2.51 E+00 E
Co SWA-L09-1316-T04-A 1 7.18E+00
Co SWA-L09-1316-T05-A 1 9.61 E+00
2.51 E+00 3.2E+01 1.8E+00 5.7E+00
7.18E+00 1.2E+01 1.8E+00 5.7E+00
9.61 E+00 4.4E+00 1.8E+00 5.7E+00
Co SWA-L09-1316-T01-B 1 9.00E-01 U1/2 9.00E-01 1.1E+02 1.8E+00 5.7E+00
Co SWA-L09-1316-T02-B 1 9.00E-01 U1/2 9.00E-01 7.7E+01 1.8E+00 5.7E+00 10 100
Co SWA-L09-1316-T03-B 1 3.45E+00 E
Co SWA-L09-1316-T04-B 1 7.91 E+00
Co SWA-L09-1316-T05-B 1 9.86E+00
3.45E+00 2.9E+01 1.8E+00 5.7E+00
7.91 E+00 7.3E+00 1.8E+00 5.7E+00
9.86E+00 1.3E+01 1.8E+00 5.7E+00
Co SWA-L09-1316-T01-C 1 9.00E-01 U1/2 9.00E-01 8.2E+01 1.8E+00 5.7E+00
Co SWA-L09-1316-T02-C 1 9.00E-01 U1/2 9.00E-01 5.0E+01 1.8E+00 5.7E+00 10 100
Co SWA-L09-1316-T03-C 1 2.17E+00 E
Co SWA-L09-1316-T04-C 1 7.74E+00
Co SWA-L09-1316-T05-C 1 1.22E+01
2.17E+00 1.3E+01 1.8E+00 5.7E+00
7.74E+00 1.9E+01 1.8E+00 5.7E+00
1.22E+01 1.9E+00 1.8E+00 5.7E+00
Co SWA-L09-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 2.3E+02 1.8E+00 5.7E+00
Co SWA-L09-1316-B01-B 1 9.00E-01 U1/2 9.00E-01 1.6E+02 1.8E+00 5.7E+00
Co SWA-L09-1316-B01-C 1 9.00E-01 U1/2 9.00E-01 1.2E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
9.29E+02 93% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.00E+03 100% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1463
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cu SWA-L09-1316-T01-A 1 1.85E+OOU1/2 1.85E+00 7.5E+01 3.7E+00 1.2E+01
Cu SWA-L09-1316-T02-A 1 1.85E+OOU1/2 1.85E+00 4.9E+02 3.7E+00 1.2E+01
Cu SWA-L09-1316-T03-A 1 4.00E+00 E
Cu SWA-L09-1316-T04-A 1 3.83E+01
Cu SWA-L09-1316-T05-A 1 1.26E+02
4.00E+00 2.6E+01 3.7E+00 1.2E+01
3.83E+01 1.9E+00 3.7E+00 1.2E+01
1.26E+02 1.7E+00 3.7E+00 1.2E+01
Cu SWA-L09-1316-T01-B 1 1.85E+OOU1/2 1.85E+00 8.3E+01 3.7E+00 1.2E+01
Cu SWA-L09-1316-T02-B 1 1.85E+OOU1/2 1.85E+00 1.9E+03 3.7E+00 1.2E+01 10 100
Cu SWA-L09-1316-T03-B 1 3.79E+00 E
Cu SWA-L09-1316-T04-B 1 3.28E+01
Cu SWA-L09-1316-T05-B 1 1.27E+02
3.79E+00 1.3E+01 3.7E+00 1.2E+01
3.28E+01 1.2E+00 3.7E+00 1.2E+01
1.27E+02 3.2E+00 3.7E+00 1.2E+01
Cu SWA-L09-1316-T01-C 1 1.85E+OOU1/2 1.85E+00 1.1E+02 3.7E+00 1.2E+01
Cu SWA-L09-1316-T02-C 1 1.85E+OOU1/2 1.85E+00 1.5E+02 3.7E+00 1.2E+01 10 100
Cu SWA-L09-1316-T03-C 1 4.68E+00 E
Cu SWA-L09-1316-T04-C 1 4.27E+01
Cu SWA-L09-1316-T05-C 1 9.92E+01
4.68E+00 9.6E+00 3.7E+00 1.2E+01
4.27E+01 3.1E+00 3.7E+00 1.2E+01
9.92E+01 2.0E+00 3.7E+00 1.2E+01
Cu SWA-L09-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 9.0E+01 3.7E+00 1.2E+01
Cu SWA-L09-1316-B01-B 1 1.85E+OOU1/2 1.85E+00 8.3E+01 3.7E+00 1.2E+01
Cu SWA-L09-1316-B01-C 1 1.85E+OOU1/2 1.85E+00 1.4E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
9.23E+02 92% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.01E+03 101% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1464
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. Qu
1 1 ug/L
Fe SWA-L09-1316-T01-A 1 6.93E+01
Fe SWA-L09-1316-T02-A 1 1.40E+02
Fe SWA-L09-1316-T03-A 1 4.19E+01
Fe SWA-L09-1316-T04-A 1 7.85E+02
Fe SWA-L09-1316-T05-A 1 2.27E+03
Fe SWA-L09-1316-T01-B 1 5.16E+01
Fe SWA-L09-1316-T02-B 1 1.37E+02
Fe SWA-L09-1316-T03-B 1 5.71 E+01
Fe SWA-L09-1316-T04-B 1 6.99E+02
Fe SWA-L09-1316-T05-B 1 2.08E+03
Fe SWA-L09-1316-T01-C 1 6.87E+01
Fe SWA-L09-1316-T02-C 1 1.44E+02
Fe SWA-L09-1316-T03-C 1 5.25E+01
Fe SWA-L09-1316-T04-C 1 8.88E+02
Fe SWA-L09-1316-T05-C 1 2.12E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.93E+01 7.9E-01 2.0E+00 6.4E+00
1.40E+02 8.2E-01 2.0E+00 6.4E+00
4.19E+01 9.9E-01 2.0E+00 6.4E+00
7.85E+02 6.1E-02 2.0E+00 6.4E+00
2.27E+03 5.5E-01 2.0E+00 6.4E+00
5.16E+01 1.2E+00 2.0E+00 6.4E+00
1.37E+02 6.5E-01 2.0E+00 6.4E+00 1000 100
5.71 E+01 2.8E-01 2.0E+00 6.4E+00
6.99E+02 1.5E+00 2.0E+00 6.4E+00
2.08E+03 9.8E-01 2.0E+00 6.4E+00
6.87E+01 4.1E-02 2.0E+00 6.4E+00
1.44E+02 7.3E-01 2.0E+00 6.4E+00 1000 100
5.25E+01 1.6E+00 2.0E+00 6.4E+00
8.88E+02 8.8E-01 2.0E+00 6.4E+00
2.12E+03 3.1E-01 2.0E+00 6.4E+00
Fe SWA-L09-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 2.1E+01 2.0E+00 6.4E+00
Fe SWA-L09-1316-B01-B 1 1.00E+OOU1/2 1.00E+00 3.1E+01 2.0E+00 6.4E+00
Fe SWA-L09-1316-B01-C 1 1.00E+OOU1/2 1.00E+00 1 .8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
1.30E+03 116% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.21E+03 107% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1465
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qu
1 1 ug/L
Pb SWA-L09-1316-T01-A 1 1.41E+01 E
Pb SWA-L09-1316-T02-A 1 2.32E+01
Pb SWA-L09-1316-T03-A 1 2.78E+01
Pb SWA-L09-1316-T04-A 1 2.84E+01
Pb SWA-L09-1316-T05-A 1 1.14E+02
Pb SWA-L09-1316-T01-B 1 1.13E+01 E
Pb SWA-L09-1316-T02-B 1 2.40E+01
Pb SWA-L09-1316-T03-B 1 2.75E+01
Pb SWA-L09-1316-T04-B 1 3.16E+01
Pb SWA-L09-1316-T05-B 1 1.38E+02
Pb SWA-L09-1316-T01-C 1 1.52E+01 E
Pb SWA-L09-1316-T02-C 1 2.69E+01
Pb SWA-L09-1316-T03-C 1 2.96E+01
Pb SWA-L09-1316-T04-C 1 2.99E+01
Pb SWA-L09-1316-T05-C 1 1.69E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.41E+01 3.1E+01 6.8E+00 2.2E+01
2.32E+01 6.4E+00 6.8E+00 2.2E+01
2.78E+01 1.2E+02 6.8E+00 2.2E+01
2.84E+01 1.7E+01 6.8E+00 2.2E+01
1.14E+02 6.2E+00 6.8E+00 2.2E+01
1.13E+01 2.2E+01 6.8E+00 2.2E+01
2.40E+01 8.9E+00 6.8E+00 2.2E+01 10 100
2.75E+01 5.7E+01 6.8E+00 2.2E+01
3.16E+01 2.2E+01 6.8E+00 2.2E+01
1.38E+02 3.6E+00 6.8E+00 2.2E+01
1.52E+01 7.5E+00 6.8E+00 2.2E+01
2.69E+01 4.1E+00 6.8E+00 2.2E+01 10 100
2.96E+01 2.1E+01 6.8E+00 2.2E+01
2.99E+01 6.9E+00 6.8E+00 2.2E+01
1.69E+02 3.2E+00 6.8E+00 2.2E+01
Pb SWA-L09-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 4.0E+02 6.8E+00 2.2E+01
Pb SWA-L09-1316-B01-B 1 3.40E+00 U1/2 3.40E+00 6.3E+01 6.8E+00 2.2E+01
Pb SWA-L09-1316-B01-C 1 3.40E+00 U1/2 3.40E+00 6.1E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
9.14E+02 89% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.04E+03 101% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1466
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone.
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Li SWA-L09-1316-T01-A 1 3.24E+00 E 3.24E+00 3.5E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-T02-A 1 5.52E+00 E 5.52E+00 4.5E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-T03-A 1 6.00E+00 E 6.00E+00 4.2E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-T04-A 1 8.30E+00
Li SWA-L09-1316-T05-A 1 1.16E+01
8.30E+00 1.8E+01 1.9E+00 6.0E+00
1.16E+01 9.8E+00 1.9E+00 6.0E+00
Li SWA-L09-1316-T01-B 1 3.65E+00 E 3.65E+00 2.3E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-T02-B 1 6.07E+00
6.07E+00 5.0E+01 1.9E+00 6.0E+00 10 100
Li SWA-L09-1316-T03-B 1 5.67E+00 E 5.67E+00 4.2E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-T04-B 1 9.23E+00
Li SWA-L09-1316-T05-B 1 1.20E+01
9.23E+00 2.3E+01 1.9E+00 6.0E+00
1.20E+01 2.2E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-T01-C 1 3.71 E+00 E 3.71 E+00 1.8E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-T02-C 1 5.07E+00 E 5.07E+00 7.1E+00 1.9E+00 6.0E+00 10 100
Li SWA-L09-1316-T03-C 1 7.76E+00
Li SWA-L09-1316-T04-C 1 9.54E+00
Li SWA-L09-1316-T05-C 1 1.30E+01
7.76E+00 2.2E+01 1.9E+00 6.0E+00
9.54E+00 1.2E+01 1.9E+00 6.0E+00
1.30E+01 1.7E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-B01-A 1 3.13E+00 E 3.13E+00 2.1E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-B01-B 1 9.50E-01 U1/2 9.50E-01 2.4E+01 1.9E+00 6.0E+00
Li SWA-L09-1316-B01-C 1 2.49E+00 E 2.49E+00 3.4E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
8.92E+02 89% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
9.10E+02 91% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1467
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Mn SWA-L09-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 8.7E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 7.3E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 3.2E+01 2.0E+00 6.4E+00
Mn SWA-L09-1316-T04-A 1 1.00E+OOU1/2 1.00E+00 3.2E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T05-A 1 1.00E+OOU1/2 1.00E+00 3.1E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 6.7E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00 10 100
Mn SWA-L09-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 6.8E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T04-B 1 1.00E+OOU1/2 1.00E+00 4.9E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T05-B 1 1.00E+OOU1/2 1.00E+00 3.5E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 7.5E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 6.3E+00 2.0E+00 6.4E+00 10 100
Mn SWA-L09-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 9.7E+01 2.0E+00 6.4E+00
Mn SWA-L09-1316-T04-C 1 1.00E+OOU1/2 1.00E+00 6.6E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-T05-C 1 1.00E+OOU1/2 1.00E+00 3.0E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 3.0E+01 2.0E+00 6.4E+00
Mn SWA-L09-1316-B01-B 1 1.00E+OOU1/2 1.00E+00 4.8E+00 2.0E+00 6.4E+00
Mn SWA-L09-1316-B01-C 1 1.00E+OOU1/2 1.00E+00 1.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
9.17E+02 92% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
9.88E+02 99% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1468
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg SWA-L09-1316-T01-A 1
Mg SWA-L09-1316-T02-A 1
Mg SWA-L09-1316-T03-A 1
Mg SWA-L09-1316-T04-A 1
Mg SWA-L09-1316-T05-A 1
Mg SWA-L09-1316-T01-B 1
Mg SWA-L09-1316-T02-B 1
Mg SWA-L09-1316-T03-B 1
Mg SWA-L09-1316-T04-B 1
Mg SWA-L09-1316-T05-B 1
Mg SWA-L09-1316-T01-C 1
Mg SWA-L09-1316-T02-C 1
Mg SWA-L09-1316-T03-C 1
Mg SWA-L09-1316-T04-C 1
Mg SWA-L09-1316-T05-C 1
Mg SWA-L09-1316-B01-A 1
Mg SWA-L09-1316-B01-B 1
Mg SWA-L09-1316-B01-C 1
Sample I
Cone. Qualifier
ug/L I
8.66E+00
8.54E+00
1.24E+01
1.42E+01
1.63E+01
9.37E+00
7.55E+00
1.16E+01
1.13E+01
1.47E+01
1.11E+01
1.05E+01
1.29E+01
1.30E+01
1.08E+01
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.66E+00 6.8E+01 1.0E+00 3.2E+00
8.54E+00 8.4E+00 1.0E+00 3.2E+00
1.24E+01 1.0E+02 1.0E+00 3.2E+00
1.42E+01 2.1E+01 1.0E+00 3.2E+00
1.63E+01 7.0E+01 1.0E+00 3.2E+00
9.37E+00 4.7E+01 1.0E+00 3.2E+00
7.55E+00 3.4E+01 1.0E+00 3.2E+00 1000 100
1.16E+01 6.9E+01 1.0E+00 3.2E+00
1.13E+01 6.0E+01 1.0E+00 3.2E+00
1.47E+01 5.4E+01 1.0E+00 3.2E+00
1.11E+01 4.4E+01 1.0E+00 3.2E+00
1.05E+01 3.1E+00 1.0E+00 3.2E+00 1000 100
1.29E+01 1.0E+01 1.0E+00 3.2E+00
1.30E+01 7.8E+00 1.0E+00 3.2E+00
1.08E+01 6.0E+01 1.0E+00 3.2E+00
5.00E-01 5.0E+02 1.0E+00 3.2E+00
5.00E-01 4.6E+02 1.0E+00 3.2E+00
5.00E-01 4.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
9.41E+02 93% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.02E+03 101% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1469
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qu
1 1 ug/L
Mo SWA-L09-1316-T01-A 1 1.23E+02
Mo SWA-L09-1316-T02-A 1 1.82E+02
Mo SWA-L09-1316-T03-A 1 4.83E+02
Mo SWA-L09-1316-T04-A 1 9.84E+02
Mo SWA-L09-1316-T05-A 1 2.34E+03
Mo SWA-L09-1316-T01-B 1 1.10E+02
Mo SWA-L09-1316-T02-B 1 1.88E+02
Mo SWA-L09-1316-T03-B 1 4.73E+02
Mo SWA-L09-1316-T04-B 1 9.68E+02
Mo SWA-L09-1316-T05-B 1 2.03E+03
Mo SWA-L09-1316-T01-C 1 1.22E+02
Mo SWA-L09-1316-T02-C 1 1.77E+02
Mo SWA-L09-1316-T03-C 1 4.88E+02
Mo SWA-L09-1316-T04-C 1 1.00E+03
Mo SWA-L09-1316-T05-C 1 2.06E+03
Mo SWA-L09-1316-B01-A 1 1.29E+OOE
Mo SWA-L09-1316-B01-B 1 2.33E+00 E
Mo SWA-L09-1316-B01-C 1 1.79E+OOE
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.23E+02 8.6E-01 1.2E+00 3.8E+00
1.82E+02 2.0E-01 1.2E+00 3.8E+00
4.83E+02 1.2E+00 1.2E+00 3.8E+00
9.84E+02 4.1E-01 1.2E+00 3.8E+00
2.34E+03 1.6E+00 1.2E+00 3.8E+00
1.10E+02 1.8E-01 1.2E+00 3.8E+00
1.88E+02 1.7E-01 1.2E+00 3.8E+00 10 100
4.73E+02 3.2E-01 1.2E+00 3.8E+00
9.68E+02 5.7E-01 1.2E+00 3.8E+00
2.03E+03 8.1E-01 1.2E+00 3.8E+00
1.22E+02 5.4E-01 1.2E+00 3.8E+00
1.77E+02 9.1E-01 1.2E+00 3.8E+00 10 100
4.88E+02 7.6E-01 1.2E+00 3.8E+00
1.00E+03 1.0E+00 1.2E+00 3.8E+00
2.06E+03 1.2E+00 1.2E+00 3.8E+00
1.29E+00 7.1E+01 1.2E+00 3.8E+00
2.33E+00 6.2E+01 1.2E+00 3.8E+00
1.79E+00 8.3E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
1.07E+03 88%VUICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.21E+03 103% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1470
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L09-1316-T01-A 1 9.00E-01 U1/2 9.00E-01 1.2E+02 1.8E+00 5.7E+00
Ni SWA-L09-1316-T02-A 1 9.00E-01 U1/2 9.00E-01 3.8E+01 1.8E+00 5.7E+00
Ni SWA-L09-1316-T03-A 1 3.30E+00 E
Ni SWA-L09-1316-T04-A 1 4.97E+00 E
Ni SWA-L09-1316-T05-A 1 1.10E+01
3.30E+00 5.8E+01 1.8E+00 5.7E+00
4.97E+00 1.9E+01 1.8E+00 5.7E+00
1.10E+01 7.6E+00 1.8E+00 5.7E+00
Ni SWA-L09-1316-T01-B 1 9.00E-01 U1/2 9.00E-01 9.6E+01 1.8E+00 5.7E+00
Ni SWA-L09-1316-T02-B 1 9.00E-01 U1/2 9.00E-01 2.5E+01 1.8E+00 5.7E+00 10 100
Ni SWA-L09-1316-T03-B 1 3.29E+00 E
Ni SWA-L09-1316-T04-B 1 5.10E+00 E
Ni SWA-L09-1316-T05-B 1 7.20E+00
3.29E+00 1.3E+02 1.8E+00 5.7E+00
5.10E+00 2.5E+01 1.8E+00 5.7E+00
7.20E+00 1.9E+01 1.8E+00 5.7E+00
Ni SWA-L09-1316-T01-C 1 9.00E-01 U1/2 9.00E-01 4.4E+01 1.8E+00 5.7E+00
Ni SWA-L09-1316-T02-C 1 9.00E-01 U1/2 9.00E-01 1.3E+02 1.8E+00 5.7E+00 10 100
Ni SWA-L09-1316-T03-C 1 3.24E+00 E
Ni SWA-L09-1316-T04-C 1 4.12E+00 E
Ni SWA-L09-1316-T05-C 1 8.22E+00
3.24E+00 2.3E+01 1.8E+00 5.7E+00
4.12E+00 1.3E+00 1.8E+00 5.7E+00
8.22E+00 2.5E+01 1.8E+00 5.7E+00
Ni SWA-L09-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 8.6E+01 1.8E+00 5.7E+00
Ni SWA-L09-1316-B01-B 1 9.00E-01 U1/2 9.00E-01 2.0E+02 1.8E+00 5.7E+00
Ni SWA-L09-1316-B01-C 1 9.00E-01 U1/2 9.00E-01 2.5E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
8.51E+02 85% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
9.22E+02 92% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1471
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P SWA-L09-1316-T01-A 1
P SWA-L09-1316-T02-A 1
P SWA-L09-1316-T03-A 1
P SWA-L09-1316-T04-A 1
P SWA-L09-1316-T05-A 1
P SWA-L09-1316-T01-B 1
P SWA-L09-1316-T02-B 1
P SWA-L09-1316-T03-B 1
P SWA-L09-1316-T04-B 1
P SWA-L09-1316-T05-B 1
P SWA-L09-1316-T01-C 1
P SWA-L09-1316-T02-C 1
P SWA-L09-1316-T03-C 1
P SWA-L09-1316-T04-C 1
P SWA-L09-1316-T05-C 1
P SWA-L09-1316-B01-A 1
P SWA-L09-1316-B01-B 1
P SWA-L09-1316-B01-C 1
Sample I
Cone. Qualifier
ug/L I
3.61E+01
6.64E+01
1.49E+02
9.71 E+02
3.49E+03
2.90E+01
6.48E+01
1.59E+02
8.97E+02
3.24E+03
2.64E+01
6.53E+01
1.85E+02
9.74E+02
3.13E+03
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.61E+01 2.6E+01 3.7E+00 1.2E+01
6.64E+01 5.7E+00 3.7E+00 1.2E+01
1.49E+02 3.2E+00 3.7E+00 1.2E+01
9.71E+02 2.0E+00 3.7E+00 1.2E+01
3.49E+03 1.0E+00 3.7E+00 1.2E+01
2.90E+01 1.7E+01 3.7E+00 1.2E+01
6.48E+01 2.3E+01 3.7E+00 1.2E+01 1000 100
1.59E+02 4.3E+00 3.7E+00 1.2E+01
8.97E+02 5.5E-01 3.7E+00 1.2E+01
3.24E+03 1.5E+00 3.7E+00 1.2E+01
2.64E+01 2.7E+01 3.7E+00 1.2E+01
6.53E+01 6.1E+00 3.7E+00 1 .2E+01 1000 100
1.85E+02 1.6E+00 3.7E+00 1 .2E+01
9.74E+02 1.6E+00 3.7E+00 1 .2E+01
3.13E+03 2.1E-01 3.7E+00 1 .2E+01
1.85E+00 6.5E+02 3.7E+00 1 .2E+01
1.85E+00 1.6E+02 3.7E+00 1 .2E+01
1.85E+00 8.4E+00 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
1.01E+03 95% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
9.12E+02 85% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1472
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
K SWA-L09-1316-T01-A 1 2.64E+05
K SWA-L09-1316-T02-A 1 3.99E+05
K SWA-L09-1316-T03-A 1 7.27E+05
K SWA-L09-1316-T04-A 1 2.34E+06
K SWA-L09-1316-T05-A 1 2.53E+06
K SWA-L09-1316-T01-B 1 2.60E+05
K SWA-L09-1316-T02-B 1 3.97E+05
K SWA-L09-1316-T03-B 1 7.06E+05
K SWA-L09-1316-T04-B 1 2.32E+06
K SWA-L09-1316-T05-B 1 2.51E+06
K SWA-L09-1316-T01-C 1 2.68E+05
K SWA-L09-1316-T02-C 1 4.00E+05
K SWA-L09-1316-T03-C 1 7.25E+05
K SWA-L09-1316-T04-C 1 2.36E+06
K SWA-L09-1316-T05-C 1 2.47E+06
K SWA-L09-1316-B01-A 1 3.45E+01
K SWA-L09-1316-B01-B 1 3.35E+01
K SWA-L09-1316-B01-C 1 3.28E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.64E+05 4.7E-01 1.6E+00 5.1E+00
3.99E+05 4.1E-01 1.6E+00 5.1E+00
7.27E+05 1.2E+01 1.6E+00 5.1E+00
2.34E+06 3.6E-01 1.6E+00 5.1E+00
2.53E+06 6.6E-01 1.6E+00 5.1E+00
2.60E+05 8.6E-01 1.6E+00 5.1E+00
3.97E+05 3.9E-01 1.6E+00 5.1E+00 1000 100
7.06E+05 9.9E+00 1.6E+00 5.1E+00
2.32E+06 5.6E-01 1.6E+00 5.1E+00
2.51E+06 1.5E+00 1.6E+00 5.1E+00
2.68E+05 5.1E-01 1.6E+00 5.1E+00
4.00E+05 1.3E+00 1.6E+00 5.1E+00 1000 100
7.25E+05 9.9E+00 1.6E+00 5.1E+00
2.36E+06 9.9E-01 1.6E+00 5.1E+00
2.47E+06 9.7E-01 1.6E+00 5.1E+00
3.45E+01 6.8E+00 1.6E+00 5.1E+00
3.35E+01 6.6E+00 1.6E+00 5.1E+00
3.28E+01 8.0E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
3.98E+05 92% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
4.01E+05 109% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1473
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
1 ug/L
Se SWA-L09-1316-T01-A 1 7.27E+04
Se SWA-L09-1316-T02-A 1 1.25E+05
Se SWA-L09-1316-T03-A 1 3.22E+05
Se SWA-L09-1316-T04-A 1 6.83E+05
Se SWA-L09-1316-T05-A 1 1.39E+06
Se SWA-L09-1316-T01-B 1 6.42E+04
Se SWA-L09-1316-T02-B 1 1.26E+05
Se SWA-L09-1316-T03-B 1 3.17E+05
Se SWA-L09-1316-T04-B 1 6.44E+05
Se SWA-L09-1316-T05-B 1 1.24E+06
Se SWA-L09-1316-T01-C 1 7.33E+04
Se SWA-L09-1316-T02-C 1 1.24E+05
Se SWA-L09-1316-T03-C 1 3.28E+05
Se SWA-L09-1316-T04-C 1 6.56E+05
Se SWA-L09-1316-T05-C 1 1.24E+06
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
7.27E+04 9.1E-01 1.5E+01 4.8E+01
1.25E+05 7.5E-01 1.5E+01 4.8E+01
3.22E+05 4.6E-01 1.5E+01 4.8E+01
6.83E+05 1.7E-01 1.5E+01 4.8E+01
1.39E+06 9.9E-01 1.5E+01 4.8E+01
6.42E+04 9.6E-01 1.5E+01 4.8E+01
1.26E+05 6.0E-01 1.5E+01 4.8E+01 10 100
3.17E+05 4.1E-01 1.5E+01 4.8E+01
6.44E+05 3.3E-01 1.5E+01 4.8E+01
1.24E+06 1.4E+00 1.5E+01 4.8E+01
7.33E+04 2.9E-01 1.5E+01 4.8E+01
1.24E+05 5.2E-01 1.5E+01 4.8E+01 10 100
3.28E+05 2.5E-01 1.5E+01 4.8E+01
6.56E+05 7.2E-01 1.5E+01 4.8E+01
1.24E+06 6.6E-01 1.5E+01 4.8E+01
Se SWA-L09-1316-B01-A 1 7.50E+00 U1/2 7.50E+00 7.2E+01 1.5E+01 4.8E+01
Se SWA-L09-1316-B01-B 1 7.50E+00 U1/2 7.50E+00 7.0E+01 1.5E+01 4.8E+01
Se SWA-L09-1316-B01-C 1 7.50E+00 U1/2 7.50E+00 4.5E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
1.26E+05 92%VUICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.25E+05 101% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1474
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-L09-1316-T01-A 1
Si SWA-L09-1316-T02-A 1
Si SWA-L09-1316-T03-A 1
Si SWA-L09-1316-T04-A 1
Si SWA-L09-1316-T05-A 1
Si SWA-L09-1316-T01-B 1
Si SWA-L09-1316-T02-B 1
Si SWA-L09-1316-T03-B 1
Si SWA-L09-1316-T04-B 1
Si SWA-L09-1316-T05-B 1
Si SWA-L09-1316-T01-C 1
Si SWA-L09-1316-T02-C 1
Si SWA-L09-1316-T03-C 1
Si SWA-L09-1316-T04-C 1
Si SWA-L09-1316-T05-C 1
Si SWA-L09-1316-B01-A 1
Si SWA-L09-1316-B01-B 1
Si SWA-L09-1316-B01-C 1
Sample I
Cone. Qualifier
ug/L I
2.31 E+04
3.13E+04
9.33E+02
2.50E+04
4.86E+04
2.09E+04
3.11 E+04
7.28E+02
3.40E+04
5.58E+04
2.42E+04
3.17E+04
6.81 E+02
3.57E+04
5.50E+04
5.50E-01 U1/2
2.34E+00 E
5.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.31 E+04 5.9E-01 1.1E+00 3.5E+00
3.13E+04 1.7E+00 1.1E+00 3.5E+00
9.33E+02 1.1E+00 1.1E+00 3.5E+00
2.50E+04 5.1E-01 1.1E+00 3.5E+00
4.86E+04 7.3E-01 1.1E+00 3.5E+00
2.09E+04 1.2E+00 1.1E+00 3.5E+00
3.11E+04 4.7E-01 1.1E+00 3.5E+00 1000 100
7.28E+02 3.0E-01 1.1E+00 3.5E+00
3.40E+04 4.0E-01 1.1E+00 3.5E+00
5.58E+04 5.0E-01 1.1E+00 3.5E+00
2.42E+04 5.2E-01 1.1E+00 3.5E+00
3.17E+04 1.5E+00 1.1E+00 3.5E+00 1000 100
6.81 E+02 7.6E-01 1.1E+00 3.5E+00
3.57E+04 8.1E-01 1.1E+00 3.5E+00
5.50E+04 6.4E-01 1.1E+00 3.5E+00
5.50E-01 2.0E+01 1.1E+00 3.5E+00
2.34E+00 1.9E+01 1.1E+00 3.5E+00
5.50E-01 1.5E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
3.21E+04 104% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
3.27E+04 101% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1475
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qu
Na SWA-L09-1316-T01-A 1 4.68E+05
Na SWA-L09-1316-T02-A 1 5.70E+05
Na SWA-L09-1316-T03-A 1 6.62E+05
Na SWA-L09-1316-T04-A 1 6.95E+05
Na SWA-L09-1316-T05-A 1 6.69E+05
Na SWA-L09-1316-T01-B 1 4.64E+05
Na SWA-L09-1316-T02-B 1 5.72E+05
Na SWA-L09-1316-T03-B 1 6.71 E+05
Na SWA-L09-1316-T04-B 1 6.96E+05
Na SWA-L09-1316-T05-B 1 6.71 E+05
Na SWA-L09-1316-T01-C 1 4.72E+05
Na SWA-L09-1316-T02-C 1 5.68E+05
Na SWA-L09-1316-T03-C 1 6.68E+05
Na SWA-L09-1316-T04-C 1 6.90E+05
Na SWA-L09-1316-T05-C 1 7.01 E+05
Na SWA-L09-1316-B01-A 1 3.14E+01
Na SWA-L09-1316-B01-B 1 3.32E+01
Na SWA-L09-1316-B01-C 1 2.90E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.68E+05 1.4E-01 2.5E+00 8.0E+00
5.70E+05 2.3E-01 2.5E+00 8.0E+00
6.62E+05 3.6E-01 2.5E+00 8.0E+00
6.95E+05 8.6E-01 2.5E+00 8.0E+00
6.69E+05 2.3E+00 2.5E+00 8.0E+00
4.64E+05 7.4E-01 2.5E+00 8.0E+00
5.72E+05 1.8E-01 2.5E+00 8.0E+00 1000 100
6.71 E+05 1.0E+00 2.5E+00 8.0E+00
6.96E+05 2.1E+00 2.5E+00 8.0E+00
6.71E+05 2.3E+00 2.5E+00 8.0E+00
4.72E+05 4.5E-01 2.5E+00 8.0E+00
5.68E+05 2.3E-01 2.5E+00 8.0E+00 1000 100
6.68E+05 9.9E-01 2.5E+00 8.0E+00
6.90E+05 1.6E+00 2.5E+00 8.0E+00
7.01E+05 2.1E+00 2.5E+00 8.0E+00
3.14E+01 7.3E-01 2.5E+00 8.0E+00
3.32E+01 3.4E+00 2.5E+00 8.0E+00
2.90E+01 5.1E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
5.72E+05 90% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
5.69E+05 91% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1476
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone.
SWA-L09-1316-T01-A 1 4.20E+02
SWA-L09-1316-T02-A 1 3.59E+02
SWA-L09-1316-T03-A 1 2.29E+02
SWA-L09-1316-T04-A 1 3.57E+02
SWA-L09-1316-T05-A 1 4.72E+02
SWA-L09-1316-T01-B 1 4.15E+02
SWA-L09-1316-T02-B 1 3.72E+02
SWA-L09-1316-T03-B 1 2.57E+02
SWA-L09-1316-T04-B 1 3.69E+02
SWA-L09-1316-T05-B 1 4.22E+02
SWA-L09-1316-T01-C 1 4.27E+02
SWA-L09-1316-T02-C 1 3.55E+02
SWA-L09-1316-T03-C 1 2.08E+02
SWA-L09-1316-T04-C 1 3.44E+02
SWA-L09-1316-T05-C 1 5.00E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.20E+02 9.7E-01 1.0E+00 3.2E+00
3.59E+02 3.9E-01 1.0E+00 3.2E+00
2.29E+02 7.6E-01 1.0E+00 3.2E+00
3.57E+02 6.6E-01 1.0E+00 3.2E+00
4.72E+02 1.1E+00 1.0E+00 3.2E+00
4.15E+02 6.7E-01 1.0E+00 3.2E+00
3.72E+02 3.4E-01 1.0E+00 3.2E+00 1000 100
2.57E+02 2.2E+00 1.0E+00 3.2E+00
3.69E+02 6.0E-01 1.0E+00 3.2E+00
4.22E+02 1.4E+00 1.0E+00 3.2E+00
4.27E+02 6.3E-01 1.0E+00 3.2E+00
3.55E+02 5.9E-01 1.0E+00 3.2E+00 1000 100
2.08E+02 1.1E+00 1.0E+00 3.2E+00
3.44E+02 1.6E+00 1.0E+00 3.2E+00
5.00E+02 3.3E-01 1.0E+00 3.2E+00
SWA-L09-1316-B01-A 1 5.00E-01 U1/2 5.00E-01 4.2E+01 1.0E+00 3.2E+00
SWA-L09-1316-B01-B 1 5.00E-01 U1/2 5.00E-01 1 JE+01 1.0E+00 3.2E+00
SWA-L09-1316-B01-C 1 5.00E-01 U1/2 5.00E-01 4.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 4:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:27 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:30 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:32 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:34 PM EPA Interlab 1316 SWA Reruns
1.29E+03 92% VU ICP-OES 5/23/11 4:36 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:39 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:41 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:43 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:45 PM EPA Interlab 1316 SWA Reruns
1.34E+03 98% VU ICP-OES 5/23/11 4:48 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:50 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:52 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 4:55 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1477
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qu
S SWA-L09-1316-T01-A 1 3.70E+05
S SWA-L09-1316-T02-A 1 5.81 E+05
S SWA-L09-1316-T03-A 1 1.13E+06
S SWA-L09-1316-T04-A 1 2.06E+06
S SWA-L09-1316-T05-A 1 4.26E+06
S SWA-L09-1316-T01-B 1 4.25E+05
S SWA-L09-1316-T02-B 1 6.67E+05
S SWA-L09-1316-T03-B 1 1.17E+06
S SWA-L09-1316-T04-B 1 2.06E+06
S SWA-L09-1316-T05-B 1 3.83E+06
S SWA-L09-1316-T01-C 1 4.45E+05
S SWA-L09-1316-T02-C 1 5.73E+05
S SWA-L09-1316-T03-C 1 1.09E+06
S SWA-L09-1316-T04-C 1 2.16E+06
S SWA-L09-1316-T05-C 1 3.94E+06
S SWA-L09-1316-B01-A 1 7.31 E+01
S SWA-L09-1316-B01-B 1 9.58E+01
S SWA-L09-1316-B01-C 1 6.04E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.70E+05 7.9E-01 6.8E+00 2.2E+01
5.81 E+05 2.9E-01 6.8E+00 2.2E+01
1.13E+06 4.3E-01 6.8E+00 2.2E+01
2.06E+06 4.7E-01 6.8E+00 2.2E+01
4.26E+06 7.7E-01 6.8E+00 2.2E+01
4.25E+05 3.9E+00 6.8E+00 2.2E+01
6.67E+05 1.5E-01 6.8E+00 2.2E+01 1000 100
1.17E+06 1.7E-01 6.8E+00 2.2E+01
2.06E+06 7.3E-01 6.8E+00 2.2E+01
3.83E+06 6.0E-01 6.8E+00 2.2E+01
4.45E+05 3.5E+00 6.8E+00 2.2E+01
5.73E+05 5.1E-01 6.8E+00 2.2E+01 1000 100
1.09E+06 3.8E-01 6.8E+00 2.2E+01
2.16E+06 9.6E-01 6.8E+00 2.2E+01
3.94E+06 6.2E-01 6.8E+00 2.2E+01
7.31E+01 9.7E+00 6.8E+00 2.2E+01
9.58E+01 2.0E+00 6.8E+00 2.2E+01
6.04E+01 1.3E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
7.65E+05 98% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
6.58E+05 86% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1478
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L09-1316-T01-A 1 2.30E+00 U1/2 2.30E+00 7.5E+02 4.6E+00 1.5E+01
Tl SWA-L09-1316-T02-A 1 2.30E+00 U1/2 2.30E+00 2.8E+02 4.6E+00 1.5E+01
Tl SWA-L09-1316-T03-A 1 2.30E+00 U1/2 2.30E+00 5.4E+02 4.6E+00 1.5E+01
Tl SWA-L09-1316-T04-A 1 2.30E+00 U1/2 2.30E+00 5.1E+02 4.6E+00 1.5E+01
Tl SWA-L09-1316-T05-A 1 2.30E+00 U1/2 2.30E+00 6.2E+01 4.6E+00 1.5E+01
Tl SWA-L09-1316-T01-B 1 2.30E+00 U1/2 2.30E+00 7.0E+00 4.6E+00 1.5E+01
Tl SWA-L09-1316-T02-B 1 2.30E+00 U1/2 2.30E+00 2.1E+02 4.6E+00 1.5E+01 10 100
Tl SWA-L09-1316-T03-B 1 2.30E+00 U1/2 2.30E+00 3.3E+02 4.6E+00 1.5E+01
Tl SWA-L09-1316-T04-B 1 2.30E+00 U1/2 2.30E+00 3.2E+00 4.6E+00 1.5E+01
Tl SWA-L09-1316-T05-B 1 2.30E+00 U1/2 2.30E+00 8.2E+01 4.6E+00 1.5E+01
Tl SWA-L09-1316-T01-C 1 2.30E+00 U1/2 2.30E+00 1 .6E+01 4.6E+00 1.5E+01
Tl SWA-L09-1316-T02-C 1 2.30E+00 U1/2 2.30E+00 3.1E+05 4.6E+00 1.5E+01 10 100
Tl SWA-L09-1316-T03-C 1 2.30E+00 U1/2 2.30E+00 9.6E+01 4.6E+00 1.5E+01
Tl SWA-L09-1316-T04-C 1 2.30E+00 U1/2 2.30E+00 1 .8E+02 4.6E+00 1.5E+01
Tl SWA-L09-1316-T05-C 1 2.30E+00 U1/2 2.30E+00 6.5E+01 4.6E+00 1.5E+01
Tl SWA-L09-1316-B01-A 1 2.30E+00 U1/2 2.30E+00 8.2E+01 4.6E+00 1.5E+01
Tl SWA-L09-1316-B01-B 1 2.30E+00 U1/2 2.30E+00 2.7E+02 4.6E+00 1.5E+01
Tl SWA-L09-1316-B01-C 1 2.30E+00 U1/2 2.30E+00 6.9E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
9.12E+02 91% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
8.73E+02 87% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1479
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L09-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 4.6E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 1 JE+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T04-A 1 1.00E+OOU1/2 1.00E+00 1 .2E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T05-A 1 1.00E+OOU1/2 1.00E+00 8.7E+00 2.0E+00 6.4E+00
Ti SWA-L09-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 1 .6E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 1 .5E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L09-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 1 .6E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T04-B 1 1.00E+OOU1/2 1.00E+00 1 .8E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T05-B 1 1.00E+OOU1/2 1.00E+00 2.1E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 2.0E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L09-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 3.5E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T04-C 1 1.00E+OOU1/2 1.00E+00 4.0E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-T05-C 1 1.00E+OOU1/2 1.00E+00 1 .5E+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 4.4E+00 2.0E+00 6.4E+00
Ti SWA-L09-1316-B01-B 1 1.00E+OOU1/2 1.00E+00 1 JE+01 2.0E+00 6.4E+00
Ti SWA-L09-1316-B01-C 1 1.00E+OOU1/2 1.00E+00 8.1E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
1.02E+03 101% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.04E+03 104% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1480
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
V SWA-L09-1316-T01-A 1 2.98E+02
V SWA-L09-1316-T02-A 1 5.23E+02
V SWA-L09-1316-T03-A 1 9.54E+02
V SWA-L09-1316-T04-A 1 1.92E+03
V SWA-L09-1316-T05-A 1 3.84E+03
V SWA-L09-1316-T01-B 1 2.34E+02
V SWA-L09-1316-T02-B 1 5.01 E+02
V SWA-L09-1316-T03-B 1 9.41 E+02
V SWA-L09-1316-T04-B 1 1.85E+03
V SWA-L09-1316-T05-B 1 3.63E+03
V SWA-L09-1316-T01-C 1 3.03E+02
V SWA-L09-1316-T02-C 1 5.21E+02
V SWA-L09-1316-T03-C 1 8.91 E+02
V SWA-L09-1316-T04-C 1 1.99E+03
V SWA-L09-1316-T05-C 1 3.54E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.98E+02 1.3E+00 1.5E+00 4.8E+00
5.23E+02 9.1E-01 1.5E+00 4.8E+00
9.54E+02 5.0E-01 1.5E+00 4.8E+00
1.92E+03 8.3E-01 1.5E+00 4.8E+00
3.84E+03 4.2E-01 1.5E+00 4.8E+00
2.34E+02 9.6E-01 1.5E+00 4.8E+00
5.01E+02 1.4E+00 1.5E+00 4.8E+00 10 100
9.41 E+02 3.3E-01 1.5E+00 4.8E+00
1.85E+03 4.3E-01 1.5E+00 4.8E+00
3.63E+03 9.0E-01 1.5E+00 4.8E+00
3.03E+02 1.1E+00 1.5E+00 4.8E+00
5.21E+02 8.4E-01 1.5E+00 4.8E+00 10 100
8.91 E+02 3.3E-01 1.5E+00 4.8E+00
1.99E+03 6.6E-01 1.5E+00 4.8E+00
3.54E+03 4.6E-01 1.5E+00 4.8E+00
V SWA-L09-1316-B01-A 1 1.53E+OOE 1.53E+00 2.9E+01 1.5E+00 4.8E+00
V SWA-L09-1316-B01-B 1 7.50E-01 U1/2 7.50E-01 5.3E+01 1.5E+00 4.8E+00
V SWA-L09-1316-B01-C 1 7.50E-01 U1/2 7.50E-01 1.1E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
1.52E+03 102% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.46E+03 94% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1481
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qu
Zn SWA-L09-1316-T01-A 1 4.35E+00
Zn SWA-L09-1316-T02-A 1 4.82E+00
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.35E+00 4.9E+00 1.0E+00 3.2E+00
4.82E+00 4.8E+00 1.0E+00 3.2E+00
Zn SWA-L09-1316-T03-A 1 5.00E-01 U1/2 5.00E-01 5.7E+01 1.0E+00 3.2E+00
Zn SWA-L09-1316-T04-A 1 3.85E+00
Zn SWA-L09-1316-T05-A 1 2.18E+01
Zn SWA-L09-1316-T01-B 1 3.94E+00
Zn SWA-L09-1316-T02-B 1 4.97E+00
3.85E+00 1.7E+01 1.0E+00 3.2E+00
2.18E+01 2.6E+00 1.0E+00 3.2E+00
3.94E+00 7.5E+00 1.0E+00 3.2E+00
4.97E+00 3.5E+00 1.0E+00 3.2E+00 10 100
Zn SWA-L09-1316-T03-B 1 5.00E-01 U1/2 5.00E-01 1 .8E+02 1.0E+00 3.2E+00
Zn SWA-L09-1316-T04-B 1 3.57E+00
Zn SWA-L09-1316-T05-B 1 2.17E+01
Zn SWA-L09-1316-T01-C 1 4.40E+00
Zn SWA-L09-1316-T02-C 1 5.06E+00
3.57E+00 1.6E+01 1.0E+00 3.2E+00
2.17E+01 1.5E+00 1.0E+00 3.2E+00
4.40E+00 1.1E+01 1.0E+00 3.2E+00
5.06E+00 5.2E+00 1.0E+00 3.2E+00 10 100
Zn SWA-L09-1316-T03-C 1 5.00E-01 U1/2 5.00E-01 6.1E+01 1.0E+00 3.2E+00
Zn SWA-L09-1316-T04-C 1 3.77E+00
Zn SWA-L09-1316-T05-C 1 2.19E+01
Zn SWA-L09-1316-B01-A 1 3.11E+OOE
Zn SWA-L09-1316-B01-B 1 2.31 E+00 E
3.77E+00 9.0E+00 1.0E+00 3.2E+00
2.19E+01 4.1E-01 1.0E+00 3.2E+00
3.11 E+00 5.3E+00 1.0E+00 3.2E+00
2.31 E+00 4.8E+00 1.0E+00 3.2E+00
Zn SWA-L09-1316-B01-C 1 5.00E-01 U1/2 5.00E-01 1.1E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/20/11 3:56 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:19 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:57 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:59 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:01 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:02 PM EPA Interlab L09 1313-1316 SWA
1.04E+03 104% VU ICP-OES 4/20/11 4:04 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:05 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:07 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:09 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:10 PM EPA Interlab L09 1313-1316 SWA
1.08E+03 107% VU ICP-OES 4/20/11 4:12 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:14 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:15 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 4:17 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:51 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:52 PM EPA Interlab L09 1313-1316 SWA
VU ICP-OES 4/20/11 3:54 PM EPA Interlab L09 1313-1316 SWA
                                                                                                                                                                         1-1482
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al SWA-L10-1316-T01-A 1
Al SWA-L10-1316-T02-A 1
Al SWA-L10-1316-T03-A 1
Al SWA-L10-1316-T04-A 1
Al SWA-L10-1316-T01-B 1
Al SWA-L10-1316-T02-B 1
Al SWA-L10-1316-T03-B 1
Al SWA-L10-1316-T04-B 1
Al SWA-L10-1316-T01-C 1
Al SWA-L10-1316-T02-C 1
Al SWA-L10-1316-T03-C 1
Al SWA-L10-1316-T04-C 1
Al SWA-L10-1316-B03-A 1
Al SWA-L10-1316-B03-B 1
Al SWA-L10-1316-B03-C 1
Sample
Cone. Qualifier
ug/L
3.59E+04
5.56E+04
1.10E+05
1.76E+05
3.53E+04
5.58E+04
1.10E+05
1.76E+05
3.38E+04
5.68E+04
1.15E+05
1.76E+05
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.59E+04 5.9E-01 1.0E+00 3.2E+00
5.56E+04 9.3E-01 1.0E+00 3.2E+00 1000 100
1.10E+05 2.1E+00 1.0E+00 3.2E+00
1.76E+05 1.3E+00 1.0E+00 3.2E+00
3.53E+04 9.3E-01 1.0E+00 3.2E+00
5.58E+04 7.4E-01 1.0E+00 3.2E+00 1000 100
1.10E+05 5.6E-01 1.0E+00 3.2E+00
1.76E+05 3.5E-01 1.0E+00 3.2E+00
3.38E+04 7.6E-01 1.0E+00 3.2E+00
5.68E+04 5.0E-01 1.0E+00 3.2E+00 1000 100
1.15E+05 1.0E+00 1.0E+00 3.2E+00
1.76E+05 2.2E-01 1.0E+00 3.2E+00
5.00E-01 9.9E+01 1.0E+00 3.2E+00
5.00E-01 1.2E+02 1.0E+00 3.2E+00
5.00E-01 7.4E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
5.66E+04 92% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
5.68E+04 97% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
5.78E+04 103% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                                  1-1483
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L10-1316-T01-A 1
Sb SWA-L10-1316-T02-A 1
Sb SWA-L10-1316-T03-A 1
Sb SWA-L10-1316-T04-A 1
Sb SWA-L10-1316-T01-B 1
Sb SWA-L10-1316-T02-B 1
Sb SWA-L10-1316-T03-B 1
Sb SWA-L10-1316-T04-B 1
Sb SWA-L10-1316-T01-C 1
Sb SWA-L10-1316-T02-C 1
Sb SWA-L10-1316-T03-C 1
Sb SWA-L10-1316-T04-C 1
Sb SWA-L10-1316-B03-A 1
Sb SWA-L10-1316-B03-B 1
Sb SWA-L10-1316-B03-C 1
Sample
Cone. Qualifier
ug/L
5.72E+03
6.55E+03
8.38E+03
8.09E+03
5.48E+03
6.81 E+03
8.38E+03
7.96E+03
5.69E+03
6.97E+03
8.47E+03
8.20E+03
3.75E+00 U1/2
3.75E+00 U1/2
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.72E+03 2.3E-01 7.5E+00 2.4E+01
6.55E+03 6.8E-01 7.5E+00 2.4E+01 10 125
8.38E+03 2.0E+00 7.5E+00 2.4E+01
8.09E+03 1.3E+00 7.5E+00 2.4E+01
5.48E+03 1.2E+00 7.5E+00 2.4E+01
6.81E+03 5.0E-01 7.5E+00 2.4E+01 10 125
8.38E+03 9.9E-01 7.5E+00 2.4E+01
7.96E+03 7.3E-01 7.5E+00 2.4E+01
5.69E+03 3.5E-01 7.5E+00 2.4E+01
6.97E+03 7.0E-01 7.5E+00 2.4E+01 10 125
8.47E+03 1.4E+00 7.5E+00 2.4E+01
8.20E+03 2.3E-01 7.5E+00 2.4E+01
3.75E+00 8.9E+01 7.5E+00 2.4E+01
3.75E+00 7.0E+01 7.5E+00 2.4E+01
3.75E+00 9.8E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
7.81E+03 101% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
7.95E+03 92% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
8.13E+03 92% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1484
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-L10-1316-T01-A 1
As SWA-L10-1316-T02-A 1
As SWA-L10-1316-T03-A 1
As SWA-L10-1316-T04-A 1
As SWA-L10-1316-T01-B 1
As SWA-L10-1316-T02-B 1
As SWA-L10-1316-T03-B 1
As SWA-L10-1316-T04-B 1
As SWA-L10-1316-T01-C 1
As SWA-L10-1316-T02-C 1
As SWA-L10-1316-T03-C 1
As SWA-L10-1316-T04-C 1
As SWA-L10-1316-B03-A 1
As SWA-L10-1316-B03-B 1
As SWA-L10-1316-B03-C 1
Sample
Cone. Qualifier
ug/L
5.30E+03
1.22E+04
4.80E+04
1.20E+05
4.87E+03
1.30E+04
4.95E+04
1.25E+05
5.22E+03
1.35E+04
4.99E+04
1.31E+05
5.50E+00 U1/2
5.50E+00 U1/2
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.30E+03 6.0E-01 1.1E+01 3.5E+01
1.22E+04 4.2E-01 1.1E+01 3.5E+01 10 125
4.80E+04 2.3E+00 1.1E+01 3.5E+01
1.20E+05 2.1E+00 1.1E+01 3.5E+01
4.87E+03 1.1E+00 1.1E+01 3.5E+01
1.30E+04 2.2E-01 1.1E+01 3.5E+01 10 125
4.95E+04 1.0E+00 1.1E+01 3.5E+01
1.25E+05 6.4E-01 1.1E+01 3.5E+01
5.22E+03 9.6E-01 1.1E+01 3.5E+01
1.35E+04 8.4E-01 1.1E+01 3.5E+01 10 125
4.99E+04 7.6E-01 1.1E+01 3.5E+01
1.31E+05 9.2E-01 1.1E+01 3.5E+01
5.50E+00 8.8E+02 1.1E+01 3.5E+01
5.50E+00 2.1E+01 1.1E+01 3.5E+01
5.50E+00 2.9E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.34E+04 92% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.42E+04 90% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.48E+04 101% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1485
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-L10-1316-T01-A 1
B SWA-L10-1316-T02-A 1
B SWA-L10-1316-T03-A 1
B SWA-L10-1316-T04-A 1
B SWA-L10-1316-T01-B 1
B SWA-L10-1316-T02-B 1
B SWA-L10-1316-T03-B 1
B SWA-L10-1316-T04-B 1
B SWA-L10-1316-T01-C 1
B SWA-L10-1316-T02-C 1
B SWA-L10-1316-T03-C 1
B SWA-L10-1316-T04-C 1
B SWA-L10-1316-B03-A 1
B SWA-L10-1316-B03-B 1
B SWA-L10-1316-B03-C 1
Sample
Cone. Qualifier
ug/L
1.07E+03
1.14E+03
1.25E+03
9.61 E+02
9.78E+02
1.04E+03
9.38E+02
9.53E+02
1.08E+03
1.15E+03
1.22E+03
9.55E+02
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.07E+03 2.1E-01 1.0E+00 3.2E+00
1.14E+03 9.0E-01 1.0E+00 3.2E+00 1000 100
1.25E+03 2.7E+00 1.0E+00 3.2E+00
9.61 E+02 1.4E+00 1.0E+00 3.2E+00
9.78E+02 2.1E-01 1.0E+00 3.2E+00
1.04E+03 1.3E+00 1.0E+00 3.2E+00 1000 100
9.38E+02 5.6E-01 1.0E+00 3.2E+00
9.53E+02 8.8E-01 1.0E+00 3.2E+00
1.08E+03 1.3E+00 1.0E+00 3.2E+00
1.15E+03 6.2E-01 1.0E+00 3.2E+00 1000 100
1.22E+03 1.2E+00 1.0E+00 3.2E+00
9.55E+02 4.1E-01 1.0E+00 3.2E+00
5.00E-01 2.8E+00 1.0E+00 3.2E+00
5.00E-01 9.3E+00 1.0E+00 3.2E+00
5.00E-01 5.2E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
2.03E+03 88% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.95E+03 91% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
2.07E+03 93% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1486
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba SWA-L10-1316-T01-A 1
Ba SWA-L10-1316-T02-A 1
Ba SWA-L10-1316-T03-A 1
Ba SWA-L10-1316-T04-A 1
Ba SWA-L10-1316-T01-B 1
Ba SWA-L10-1316-T02-B 1
Ba SWA-L10-1316-T03-B 1
Ba SWA-L10-1316-T04-B 1
Ba SWA-L10-1316-T01-C 1
Ba SWA-L10-1316-T02-C 1
Ba SWA-L10-1316-T03-C 1
Ba SWA-L10-1316-T04-C 1
Ba SWA-L10-1316-B03-A 1
Ba SWA-L10-1316-B03-B 1
Ba SWA-L10-1316-B03-C 1
Sample
Cone. Qualifier
ug/L
9.79E+01
1.38E+02
1.32E+02
8.29E+01
9.77E+01
1.14E+02
1.16E+02
7.97E+01
9.78E+01
1.27E+02
1.20E+02
1.05E+02
5.00E-01 U1/2
5.00E-01 U1/2
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.79E+01 8.5E-01 1.0E+00 3.2E+00
1.38E+02 6.8E-01 1.0E+00 3.2E+00 10 125
1.32E+02 2.8E+00 1.0E+00 3.2E+00
8.29E+01 1.2E+00 1.0E+00 3.2E+00
9.77E+01 9.5E-01 1.0E+00 3.2E+00
1.14E+02 3.6E-01 1.0E+00 3.2E+00 10 125
1.16E+02 1.2E+00 1.0E+00 3.2E+00
7.97E+01 5.2E-01 1.0E+00 3.2E+00
9.78E+01 6.1E-01 1.0E+00 3.2E+00
1.27E+02 4.7E-01 1.0E+00 3.2E+00 10 125
1.20E+02 1.1E+00 1.0E+00 3.2E+00
1.05E+02 5.8E-01 1.0E+00 3.2E+00
5.00E-01 3.4E+02 1.0E+00 3.2E+00
5.00E-01 5.2E+01 1.0E+00 3.2E+00
5.00E-01 8.8E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.33E+03 95%VUICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.42E+03 104% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.36E+03 99%VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1487
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L10-1316-T01-A 1
Be SWA-L10-1316-T02-A 1
Be SWA-L10-1316-T03-A 1
Be SWA-L10-1316-T04-A 1
Be SWA-L10-1316-T01-B 1
Be SWA-L10-1316-T02-B 1
Be SWA-L10-1316-T03-B 1
Be SWA-L10-1316-T04-B 1
Be SWA-L10-1316-T01-C 1
Be SWA-L10-1316-T02-C 1
Be SWA-L10-1316-T03-C 1
Be SWA-L10-1316-T04-C 1
Be SWA-L10-1316-B03-A 1
Be SWA-L10-1316-B03-B 1
Be SWA-L10-1316-B03-C 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 5.8E+01 1.9E+00 6.0E+00 10 125
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00 10 125
9.50E-01 4.1E+01 1.9E+00 6.0E+00
9.50E-01 8.2E+02 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00 10 125
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 2.9E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+01 1.9E+00 6.0E+00
9.50E-01 8.7E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.37E+03 110% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.44E+03 115% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.47E+03 118% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1488
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L10-1316-T01-A 1 1.10E+OOU1/2 1.10E+00 5.6E+01 2.2E+00 7.0E+00
Cd SWA-L10-1316-T02-A 1 1.10E+OOU1/2 1.10E+00 3.7E+02 2.2E+00 7.0E+00 10 125
Cd SWA-L10-1316-T03-A 1 1.10E+OOU1/2 1.10E+00 1.2E+01 2.2E+00 7.0E+00
Cd SWA-L10-1316-T04-A 1 1.10E+OOU1/2 1.10E+00 2.4E+01 2.2E+00 7.0E+00
Cd SWA-L10-1316-T01-B 1 1.10E+OOU1/2 1.10E+00 6.7E+01 2.2E+00 7.0E+00
Cd SWA-L10-1316-T02-B 1 1.10E+OOU1/2 1.10E+00 1.0E+02 2.2E+00 7.0E+00 10 125
Cd SWA-L10-1316-T03-B 1 1.10E+OOU1/2 1.10E+00 1.0E+03 2.2E+00 7.0E+00
Cd SWA-L10-1316-T04-B 1 1.10E+OOU1/2 1.10E+00 8.3E+01 2.2E+00 7.0E+00
Cd SWA-L10-1316-T01-C 1 1.10E+OOU1/2 1.10E+00 1.6E+01 2.2E+00 7.0E+00
Cd SWA-L10-1316-T02-C 1 1.10E+OOU1/2 1.10E+00 4.6E+02 2.2E+00 7.0E+00 10 125
Cd SWA-L10-1316-T03-C 1 1.10E+OOU1/2 1.10E+00 7.4E+02 2.2E+00 7.0E+00
Cd SWA-L10-1316-T04-C 1 1.10E+OOU1/2 1.10E+00 7.3E+03 2.2E+00 7.0E+00
Cd SWA-L10-1316-B03-A 1 1.10E+OOU1/2 1.10E+00 6.0E+01 2.2E+00 7.0E+00
Cd SWA-L10-1316-B03-B 1 1.10E+OOU1/2 1.10E+00 3.8E+02 2.2E+00 7.0E+00
Cd SWA-L10-1316-B03-C 1 1.10E+OOU1/2 1.10E+00 2.7E+03 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.25E+03 100% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.39E+03 112% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:21 PM EPA Interlab L10 1313-1316 SWA
1.36E+03 109% VU ICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1489
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca SWA-L10-1316-T01-A 1
Ca SWA-L10-1316-T02-A 1
Ca SWA-L10-1316-T03-A 1
Ca SWA-L10-1316-T04-A 1
Ca SWA-L10-1316-T01-B 1
Ca SWA-L10-1316-T02-B 1
Ca SWA-L10-1316-T03-B 1
Ca SWA-L10-1316-T04-B 1
Ca SWA-L10-1316-T01-C 1
Ca SWA-L10-1316-T02-C 1
Ca SWA-L10-1316-T03-C 1
Ca SWA-L10-1316-T04-C 1
Ca SWA-L10-1316-B03-A 1
Ca SWA-L10-1316-B03-B 1
Ca SWA-L10-1316-B03-C 1
Sample I
Cone. Qualifier
ug/L I
1.29E+04
1.24E+04
9.02E+03
6.17E+03
1.21E+04
1.15E+04
8.67E+03
5.82E+03
1.27E+04
1.24E+04
9.11E+03
6.27E+03
4.13E+02
3.99E+02
4.10E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.29E+04 9.6E-01 2.6E+00 8.3E+00
1.24E+04 6.8E-01 2.6E+00 8.3E+00 1000 100
9.02E+03 2.2E+00 2.6E+00 8.3E+00
6.17E+03 1.1E+00 2.6E+00 8.3E+00
1.21E+04 6.1E-01 2.6E+00 8.3E+00
1.15E+04 6.0E-01 2.6E+00 8.3E+00 1000 100
8.67E+03 9.9E-01 2.6E+00 8.3E+00
5.82E+03 1.5E+00 2.6E+00 8.3E+00
1.27E+04 3.1E-01 2.6E+00 8.3E+00
1.24E+04 8.2E-02 2.6E+00 8.3E+00 1000 100
9.11E+03 1.3E+00 2.6E+00 8.3E+00
6.27E+03 1.9E+00 2.6E+00 8.3E+00
4.13E+02 7.5E-01 2.6E+00 8.3E+00
3.99E+02 1.2E+00 2.6E+00 8.3E+00
4.10E+02 3.9E+00 2.6E+00 8.3E+00
Spike Spike |
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.33E+04 92% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.24E+04 98% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.35E+04 112% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1490
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qu
Cr SWA-L10-1316-T01-A 1 8.52E+02
Cr SWA-L10-1316-T02-A 1 1.43E+03
Cr SWA-L10-1316-T03-A 1 1.92E+03
Cr SWA-L10-1316-T04-A 1 2.30E+03
Cr SWA-L10-1316-T01-B 1 8.27E+02
Cr SWA-L10-1316-T02-B 1 1.40E+03
Cr SWA-L10-1316-T03-B 1 1.90E+03
Cr SWA-L10-1316-T04-B 1 2.04E+03
Cr SWA-L10-1316-T01-C 1 8.07E+02
Cr SWA-L10-1316-T02-C 1 1.48E+03
Cr SWA-L10-1316-T03-C 1 2.04E+03
Cr SWA-L10-1316-T04-C 1 1.84E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
8.52E+02 3.8E-01 1.2E+00 3.8E+00
1.43E+03 5.3E-01 1.2E+00 3.8E+00 10 125
1.92E+03 1.3E+00 1.2E+00 3.8E+00
2.30E+03 1.1E+00 1.2E+00 3.8E+00
8.27E+02 1.1E+00 1.2E+00 3.8E+00
1.40E+03 9.2E-01 1.2E+00 3.8E+00 10 125
1.90E+03 5.7E-01 1.2E+00 3.8E+00
2.04E+03 4.0E-01 1.2E+00 3.8E+00
8.07E+02 7.9E-01 1.2E+00 3.8E+00
1.48E+03 8.1E-01 1.2E+00 3.8E+00 10 125
2.04E+03 8.3E-01 1.2E+00 3.8E+00
1.84E+03 7.2E-02 1.2E+00 3.8E+00
Cr SWA-L10-1316-B03-A 1 6.00E-01 U1/2 6.00E-01 3.7E+01 1.2E+00 3.8E+00
Cr SWA-L10-1316-B03-B 1 6.00E-01 U1/2 6.00E-01 1.2E+02 1.2E+00 3.8E+00
Cr SWA-L10-1316-B03-C 1 6.00E-01 U1/2 6.00E-01 4.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
2.79E+03 108% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
2.80E+03 112% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
2.84E+03 109% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1491
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Co SWA-L10-1316-T01-A 1 9.00E-01 U1/2 9.00E-01 1.7E+01 1.8E+00 5.7E+00
Co SWA-L10-1316-T02-A 1 9.00E-01 U1/2 9.00E-01 1.8E+01 1.8E+00 5.7E+00 10 125
Co SWA-L10-1316-T03-A 1 3.85E+00 E
Co SWA-L10-1316-T04-A 1 6.53E+00
3.85E+00 6.6E+01 1.8E+00 5.7E+00
6.53E+00 6.9E+01 1.8E+00 5.7E+00
Co SWA-L10-1316-T01-B 1 9.00E-01 U1/2 9.00E-01 3.7E+01 1.8E+00 5.7E+00
Co SWA-L10-1316-T02-B 1 9.00E-01 U1/2 9.00E-01 1.6E+02 1.8E+00 5.7E+00 10 125
Co SWA-L10-1316-T03-B 1 3.21 E+00 E
Co SWA-L10-1316-T04-B 1 6.51 E+00
3.21 E+00 3.1E+01 1.8E+00 5.7E+00
6.51 E+00 1.3E+01 1.8E+00 5.7E+00
Co SWA-L10-1316-T01-C 1 9.00E-01 U1/2 9.00E-01 3.9E+01 1.8E+00 5.7E+00
Co SWA-L10-1316-T02-C 1 9.00E-01 U1/2 9.00E-01 3.3E+01 1.8E+00 5.7E+00 10 125
Co SWA-L10-1316-T03-C 1 2.99E+00 E
Co SWA-L10-1316-T04-C 1 5.29E+00 E
2.99E+00 9.4E+01 1.8E+00 5.7E+00
5.29E+00 2.9E+01 1.8E+00 5.7E+00
Co SWA-L10-1316-B03-A 1 9.00E-01 U1/2 9.00E-01 1.6E+02 1.8E+00 5.7E+00
Co SWA-L10-1316-B03-B 1 9.00E-01 U1/2 9.00E-01 1.3E+03 1.8E+00 5.7E+00
Co SWA-L10-1316-B03-C 1 9.00E-01 U1/2 9.00E-01 3.3E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.17E+03 93% VUICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.39E+03 111% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:21 PM EPA Interlab L10 1313-1316 SWA
1.38E+03 110% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1492
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu SWA-L10-1316-T01-A 1
Cu SWA-L10-1316-T02-A 1
Cu SWA-L10-1316-T03-A 1
Cu SWA-L10-1316-T04-A 1
Cu SWA-L10-1316-T01-B 1
Cu SWA-L10-1316-T02-B 1
Cu SWA-L10-1316-T03-B 1
Cu SWA-L10-1316-T04-B 1
Cu SWA-L10-1316-T01-C 1
Cu SWA-L10-1316-T02-C 1
Cu SWA-L10-1316-T03-C 1
Cu SWA-L10-1316-T04-C 1
Cu SWA-L10-1316-B03-A 1
Cu SWA-L10-1316-B03-B 1
Cu SWA-L10-1316-B03-C 1
Sample I
Cone. Qualifier
ug/L I
1.85E+00 U1/2
6.20E+00 E
2.63E+01
5.22E+01
1.85E+00 U1/2
8.41 E+00 E
2.59E+01
4.61E+01
1.85E+00 U1/2
5.86E+00 E
3.19E+01
5.90E+01
1.85E+00 U1/2
1.85E+00 U1/2
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 1.6E+00 3.7E+00 1.2E+01
6.20E+00 1.7E-01 3.7E+00 1.2E+01 10 125
2.63E+01 3.2E+00 3.7E+00 1.2E+01
5.22E+01 2.2E+01 3.7E+00 1.2E+01
1.85E+00 2.2E+01 3.7E+00 1.2E+01
8.41E+00 8.5E+00 3.7E+00 1.2E+01 10 125
2.59E+01 6.7E+00 3.7E+00 1.2E+01
4.61 E+01 1.3E+00 3.7E+00 1.2E+01
1.85E+00 2.5E+00 3.7E+00 1.2E+01
5.86E+00 6.9E+00 3.7E+00 1.2E+01 10 125
3.19E+01 2.5E+00 3.7E+00 1.2E+01
5.90E+01 1.7E+00 3.7E+00 1.2E+01
1.85E+00 3.3E+01 3.7E+00 1.2E+01
1.85E+00 2.4E+01 3.7E+00 1.2E+01
1.85E+00 8.7E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.24E+03 99% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.31E+03 104% VU ICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.35E+03 107% VU ICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1493
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. Qu
1 1 ug/L
Fe SWA-L10-1316-T01-A 1 6.89E+01
Fe SWA-L10-1316-T02-A 1 1.37E+02
Fe SWA-L10-1316-T03-A 1 5.12E+02
Fe SWA-L10-1316-T04-A 1 1.16E+03
Fe SWA-L10-1316-T01-B 1 5.91 E+01
Fe SWA-L10-1316-T02-B 1 1.40E+02
Fe SWA-L10-1316-T03-B 1 5.23E+02
Fe SWA-L10-1316-T04-B 1 1.23E+03
Fe SWA-L10-1316-T01-C 1 5.03E+01
Fe SWA-L10-1316-T02-C 1 1.57E+02
Fe SWA-L10-1316-T03-C 1 5.20E+02
Fe SWA-L10-1316-T04-C 1 1.16E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.89E+01 5.9E-01 2.0E+00 6.4E+00
1.37E+02 4.1E-01 2.0E+00 6.4E+00 1000 100
5.12E+02 2.3E+00 2.0E+00 6.4E+00
1.16E+03 1.0E+00 2.0E+00 6.4E+00
5.91 E+01 1.1E+00 2.0E+00 6.4E+00
1.40E+02 9.0E-01 2.0E+00 6.4E+00 1000 100
5.23E+02 4.6E-01 2.0E+00 6.4E+00
1.23E+03 1.5E+00 2.0E+00 6.4E+00
5.03E+01 2.4E+00 2.0E+00 6.4E+00
1.57E+02 5.0E-01 2.0E+00 6.4E+00 1000 100
5.20E+02 1.1E+00 2.0E+00 6.4E+00
1.16E+03 4.5E-01 2.0E+00 6.4E+00
Fe SWA-L10-1316-B03-A 1 1.00E+OOU1/2 1.00E+00 7.3E+01 2.0E+00 6.4E+00
Fe SWA-L10-1316-B03-B 1 1.00E+OOU1/2 1.00E+00 6.2E+02 2.0E+00 6.4E+00
Fe SWA-L10-1316-B03-C 1 3.38E+00 E
3.38E+00 2.1E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.28E+03 114% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.32E+03 118% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.30E+03 115% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1494
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Pb Sample Dilution
Pb SWA-L10-1316-T01-A 1
Pb SWA-L10-1316-T02-A 1
Pb SWA-L10-1316-T03-A 1
Pb SWA-L10-1316-T04-A 1
Pb SWA-L10-1316-T01-B 1
Pb SWA-L10-1316-T02-B 1
Pb SWA-L10-1316-T03-B 1
Pb SWA-L10-1316-T04-B 1
Pb SWA-L10-1316-T01-C 1
Pb SWA-L10-1316-T02-C 1
Pb SWA-L10-1316-T03-C 1
Pb SWA-L10-1316-T04-C 1
Pb SWA-L10-1316-B03-A 1
Pb SWA-L10-1316-B03-B 1
Pb SWA-L10-1316-B03-C 1
Sample I
Cone. Qualifier
ug/L I
1.21E+01 E
2.43E+01
1.06E+02
2.04E+02
1.17E+01 E
3.29E+01
1.15E+02
2.09E+02
1.16E+01 E
3.12E+01
1.08E+02
2.28E+02
7.47E+00 E
3.40E+00 U1/2
3.40E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.21E+01 2.0E+00 6.8E+00 2.2E+01
2.43E+01 1.6E+00 6.8E+00 2.2E+01 10 125
1.06E+02 2.1E+01 6.8E+00 2.2E+01
2.04E+02 2.9E+01 6.8E+00 2.2E+01
1.17E+01 1.4E+02 6.8E+00 2.2E+01
3.29E+01 7.0E+00 6.8E+00 2.2E+01 10 125
1.15E+02 5.6E+00 6.8E+00 2.2E+01
2.09E+02 3.5E+00 6.8E+00 2.2E+01
1.16E+01 6.2E+01 6.8E+00 2.2E+01
3.12E+01 1.1E+01 6.8E+00 2.2E+01 10 125
1.08E+02 6.5E+00 6.8E+00 2.2E+01
2.28E+02 3.2E+00 6.8E+00 2.2E+01
7.47E+00 4.9E+01 6.8E+00 2.2E+01
3.40E+00 5.3E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.26E+03 99% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.36E+03 106% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.29E+03 101% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1495
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qu
Li SWA-L10-1316-T01-A 1 2.44E+00 E
Li SWA-L10-1316-T02-A 1 5.69E+00 E
Li SWA-L10-1316-T03-A 1 8.21E+00
Li SWA-L10-1316-T04-A 1 9.46E+00
Li SWA-L10-1316-T01-B 1 2.05E+00 E
Li SWA-L10-1316-T02-B 1 5.30E+00 E
Li SWA-L10-1316-T03-B 1 7.86E+00
Li SWA-L10-1316-T04-B 1 1.10E+01
Li SWA-L10-1316-T01-C 1 2.03E+00 E
Li SWA-L10-1316-T02-C 1 4.67E+00 E
Li SWA-L10-1316-T03-C 1 8.35E+00
Li SWA-L10-1316-T04-C 1 1.07E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.44E+00 1.7E+01 1.9E+00 6.0E+00
5.69E+00 5.0E+00 1.9E+00 6.0E+00 10 125
8.21 E+00 5.5E+00 1.9E+00 6.0E+00
9.46E+00 9.7E+00 1.9E+00 6.0E+00
2.05E+00 1.6E+01 1.9E+00 6.0E+00
5.30E+00 8.7E+00 1.9E+00 6.0E+00 10 125
7.86E+00 4.3E+00 1.9E+00 6.0E+00
1.10E+01 7.3E+00 1.9E+00 6.0E+00
2.03E+00 1.6E+00 1.9E+00 6.0E+00
4.67E+00 1.8E+01 1.9E+00 6.0E+00 10 125
8.35E+00 8.5E+00 1.9E+00 6.0E+00
1.07E+01 3.1 E+00 1.9E+00 6.0E+00
Li SWA-L10-1316-B03-A 1 9.50E-01 U1/2 9.50E-01 2.6E+04 1.9E+00 6.0E+00
Li SWA-L10-1316-B03-B 1 9.50E-01 U1/2 9.50E-01 6.7E+01 1.9E+00 6.0E+00
Li SWA-L10-1316-B03-C 1 9.50E-01 U1/2 9.50E-01 6.7E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.06E+03 84%VUICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.10E+03 87%VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1 :21 PM EPA Interlab L10 1313-1316 SWA
1.11E+03 89% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1496
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Mn SWA-L10-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 1.1E+00 2.0E+00 6.4E+00
Mn SWA-L10-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 7.0E+00 2.0E+00 6.4E+00 10 125
Mn SWA-L10-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 1 .9E+01 2.0E+00 6.4E+00
Mn SWA-L10-1316-T04-A 1 2.96E+00 E
2.96E+00 4.5E+01 2.0E+00 6.4E+00
Mn SWA-L10-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 7.1E+01 2.0E+00 6.4E+00
Mn SWA-L10-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 2.5E+01 2.0E+00 6.4E+00 10 125
Mn SWA-L10-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 6.3E+00 2.0E+00 6.4E+00
Mn SWA-L10-1316-T04-B 1 2.63E+00 E
2.63E+00 2.1E+00 2.0E+00 6.4E+00
Mn SWA-L10-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 6.1E+02 2.0E+00 6.4E+00
Mn SWA-L10-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00 10 125
Mn SWA-L10-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00
Mn SWA-L10-1316-T04-C 1 3.37E+00 E
3.37E+00 1.7E+00 2.0E+00 6.4E+00
Mn SWA-L10-1316-B03-A 1 1.00E+OOU1/2 1.00E+00 2.3E+01 2.0E+00 6.4E+00
Mn SWA-L10-1316-B03-B 1 1.00E+OOU1/2 1.00E+00 9.9E+01 2.0E+00 6.4E+00
Mn SWA-L10-1316-B03-C 1 1.00E+OOU1/2 1.00E+00 1.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.18E+03 94% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.36E+03 109% VU ICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.32E+03 106% VU ICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1497
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone.
1 ug/L
Mg SWA-L10-1316-T01-A 1 1.05E+01
Mg SWA-L10-1316-T02-A 1 1.11E+01
Mg SWA-L10-1316-T03-A 1 1.66E+01
Mg SWA-L10-1316-T04-A 1 3.30E+01
Mg SWA-L10-1316-T01-B 1 7.91 E+00
Mg SWA-L10-1316-T02-B 1 1.51E+01
Mg SWA-L10-1316-T03-B 1 1.86E+01
Mg SWA-L10-1316-T04-B 1 2.03E+01
Mg SWA-L10-1316-T01-C 1 1.10E+01
Mg SWA-L10-1316-T02-C 1 1.29E+01
Mg SWA-L10-1316-T03-C 1 2.37E+01
Mg SWA-L10-1316-T04-C 1 2.61 E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.05E+01 2.4E+01 1.0E+00 3.2E+00
1.11E+01 1.1E+02 1.0E+00 3.2E+00 1000 100
1.66E+01 1.4E+02 1.0E+00 3.2E+00
3.30E+01 7.9E+01 1.0E+00 3.2E+00
7.91 E+00 8.9E+01 1.0E+00 3.2E+00
1.51E+01 5.2E+01 1.0E+00 3.2E+00 1000 100
1.86E+01 1.1 E+01 1.0E+00 3.2E+00
2.03E+01 2.3E+01 1.0E+00 3.2E+00
1.10E+01 8.0E+01 1.0E+00 3.2E+00
1.29E+01 1.1E+02 1.0E+00 3.2E+00 1000 100
2.37E+01 2.1 E+01 1.0E+00 3.2E+00
2.61 E+01 6.5E+01 1.0E+00 3.2E+00
Mg SWA-L10-1316-B03-A 1 5.00E-01 U1/2 5.00E-01 7.3E+02 1.0E+00 3.2E+00
Mg SWA-L10-1316-B03-B 1 5.00E-01 U1/2 5.00E-01 8.8E+02 1.0E+00 3.2E+00
Mg SWA-L10-1316-B03-C 1 5.00E-01 U1/2 5.00E-01 5.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.15E+03 114% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.19E+03 117% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.10E+03 109% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1498
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo SWA-L10-1316-T01-A 1
Mo SWA-L10-1316-T02-A 1
Mo SWA-L10-1316-T03-A 1
Mo SWA-L10-1316-T04-A 1
Mo SWA-L10-1316-T01-B 1
Mo SWA-L10-1316-T02-B 1
Mo SWA-L10-1316-T03-B 1
Mo SWA-L10-1316-T04-B 1
Mo SWA-L10-1316-T01-C 1
Mo SWA-L10-1316-T02-C 1
Mo SWA-L10-1316-T03-C 1
Mo SWA-L10-1316-T04-C 1
Mo SWA-L10-1316-B03-A 1
Mo SWA-L10-1316-B03-B 1
Mo SWA-L10-1316-B03-C 1
Sample I
Cone. Qualifier
ug/L I
1.45E+02
2.45E+02
6.18E+02
1.21E+03
1.32E+02
2.52E+02
6.21 E+02
1.27E+03
1.40E+02
2.60E+02
6.03E+02
1.24E+03
2.02E+00 E
2.36E+00 E
2.81 E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.45E+02 2.0E-01 1.2E+00 3.8E+00
2.45E+02 5.3E-01 1.2E+00 3.8E+00 10 125
6.18E+02 1.4E+00 1.2E+00 3.8E+00
1.21E+03 3.0E+00 1.2E+00 3.8E+00
1.32E+02 3.1 E+00 1.2E+00 3.8E+00
2.52E+02 3.5E-01 1.2E+00 3.8E+00 10 125
6.21 E+02 9.5E-01 1.2E+00 3.8E+00
1.27E+03 4.8E-01 1.2E+00 3.8E+00
1.40E+02 9.4E-01 1.2E+00 3.8E+00
2.60E+02 9.4E-01 1.2E+00 3.8E+00 10 125
6.03E+02 1.3E+00 1.2E+00 3.8E+00
1.24E+03 3.2E-01 1.2E+00 3.8E+00
2.02E+00 3.6E+01 1.2E+00 3.8E+00
2.36E+00 7.2E+01 1.2E+00 3.8E+00
2.81 E+00 4.8E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.30E+03 84% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.36E+03 89%VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.39E+03 90%VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1499
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni SWA-L10-1316-T01-A 1
Ni SWA-L10-1316-T02-A 1
Ni SWA-L10-1316-T03-A 1
Ni SWA-L10-1316-T04-A 1
Ni SWA-L10-1316-T01-B 1
Ni SWA-L10-1316-T02-B 1
Ni SWA-L10-1316-T03-B 1
Ni SWA-L10-1316-T04-B 1
Ni SWA-L10-1316-T01-C 1
Ni SWA-L10-1316-T02-C 1
Ni SWA-L10-1316-T03-C 1
Ni SWA-L10-1316-T04-C 1
Ni SWA-L10-1316-B03-A 1
Ni SWA-L10-1316-B03-B 1
Ni SWA-L10-1316-B03-C 1
Sample I
Cone. Qualifier
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
6.28E+00
8.94E+00
9.00E-01 U1/2
9.00E-01 U1/2
7.31 E+00
9.38E+00
9.00E-01 U1/2
9.00E-01 U1/2
5.26E+00 E
7.53E+00
9.00E-01 U1/2
9.00E-01 U1/2
9.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.5E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+01 1.8E+00 5.7E+00 10 125
6.28E+00 5.8E+01 1.8E+00 5.7E+00
8.94E+00 8.7E+01 1.8E+00 5.7E+00
9.00E-01 2.1E+02 1.8E+00 5.7E+00
9.00E-01 2.7E+02 1.8E+00 5.7E+00 10 125
7.31 E+00 7.2E+01 1.8E+00 5.7E+00
9.38E+00 5.1E+01 1.8E+00 5.7E+00
9.00E-01 1.0E+04 1.8E+00 5.7E+00
9.00E-01 7.6E+01 1.8E+00 5.7E+00 10 125
5.26E+00 2.9E+01 1.8E+00 5.7E+00
7.53E+00 6.0E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
9.00E-01 5.0E+01 1.8E+00 5.7E+00
9.00E-01 5.5E+03 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.25E+03 100% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.38E+03 110% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:21 PM EPA Interlab L10 1313-1316 SWA
1.31E+03 105% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1500
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P SWA-L10-1316-T01-A 1
P SWA-L10-1316-T02-A 1
P SWA-L10-1316-T03-A 1
P SWA-L10-1316-T04-A 1
P SWA-L10-1316-T01-B 1
P SWA-L10-1316-T02-B 1
P SWA-L10-1316-T03-B 1
P SWA-L10-1316-T04-B 1
P SWA-L10-1316-T01-C 1
P SWA-L10-1316-T02-C 1
P SWA-L10-1316-T03-C 1
P SWA-L10-1316-T04-C 1
P SWA-L10-1316-B03-A 1
P SWA-L10-1316-B03-B 1
P SWA-L10-1316-B03-C 1
Sample I
Cone. Qualifier
ug/L I
8.66E+01
1.35E+02
4.93E+02
1.58E+03
7.12E+01
1.67E+02
4.91 E+02
1.65E+03
7.51E+01
1.78E+02
5.26E+02
1.80E+03
7.42E+00 E
1.82E+01
1.15E+01 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.66E+01 8.4E-01 3.7E+00 1.2E+01
1.35E+02 2.3E+00 3.7E+00 1.2E+01 1000 100
4.93E+02 4.0E+00 3.7E+00 1.2E+01
1.58E+03 9.6E+00 3.7E+00 1.2E+01
7.12E+01 7.5E+00 3.7E+00 1.2E+01
1.67E+02 7.9E+00 3.7E+00 1.2E+01 1000 100
4.91 E+02 1.7E+00 3.7E+00 1.2E+01
1.65E+03 3.4E-01 3.7E+00 1.2E+01
7.51E+01 4.3E+01 3.7E+00 1.2E+01
1.78E+02 4.6E+00 3.7E+00 1 .2E+01 1000 100
5.26E+02 8.5E+00 3.7E+00 1 .2E+01
1.80E+03 6.3E-01 3.7E+00 1 .2E+01
7.42E+00 2.4E+02 3.7E+00 1 .2E+01
1.82E+01 7.7E+01 3.7E+00 1 .2E+01
1.15E+01 5.2E+01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.23E+03 109% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.29E+03 113% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.22E+03 105% VU ICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1501
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone. Qu
K SWA-L10-1316-T01-A 1 3.49E+05
K SWA-L10-1316-T02-A 1 5.37E+05
K SWA-L10-1316-T03-A 1 1.06E+06
K SWA-L10-1316-T04-A 1 4.27E+06
K SWA-L10-1316-T01-B 1 3.45E+05
K SWA-L10-1316-T02-B 1 5.33E+05
K SWA-L10-1316-T03-B 1 1.04E+06
K SWA-L10-1316-T04-B 1 4.29E+06
K SWA-L10-1316-T01-C 1 3.58E+05
K SWA-L10-1316-T02-C 1 5.43E+05
K SWA-L10-1316-T03-C 1 1.05E+06
K SWA-L10-1316-T04-C 1 4.27E+06
K SWA-L10-1316-B03-A 1 3.57E+01
K SWA-L10-1316-B03-B 1 3.13E+01
K SWA-L10-1316-B03-C 1 3.28E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.49E+05 2.1E-01 1.6E+00 5.1E+00
5.37E+05 3.1E+00 1.6E+00 5.1E+00 1000 100
1.06E+06 3.3E+00 1.6E+00 5.1E+00
4.27E+06 8.1E-01 1.6E+00 5.1E+00
3.45E+05 8.4E-01 1.6E+00 5.1E+00
5.33E+05 4.5E-01 1.6E+00 5.1E+00 1000 100
1.04E+06 9.5E-01 1.6E+00 5.1E+00
4.29E+06 2.1E-01 1.6E+00 5.1E+00
3.58E+05 9.6E-01 1.6E+00 5.1E+00
5.43E+05 1.0E+00 1.6E+00 5.1E+00 1000 100
1.05E+06 3.3E+00 1.6E+00 5.1E+00
4.27E+06 2.7E-01 1.6E+00 5.1E+00
3.57E+01 1.5E+01 1.6E+00 5.1E+00
3.13E+01 1.2E+00 1.6E+00 5.1E+00
3.28E+01 6.2E-01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
5.38E+05 98% VUICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
5.34E+05 103% VU ICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
5.44E+05 112% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1502
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
Se SWA-L10-1316-T01-A 1 1.05E+05
Se SWA-L10-1316-T02-A 1 1.87E+05
Se SWA-L10-1316-T03-A 1 4.55E+05
Se SWA-L10-1316-T04-A 1 8.67E+05
Se SWA-L10-1316-T01-B 1 9.79E+04
Se SWA-L10-1316-T02-B 1 1.95E+05
Se SWA-L10-1316-T03-B 1 4.62E+05
Se SWA-L10-1316-T04-B 1 9.19E+05
Se SWA-L10-1316-T01-C 1 1.04E+05
Se SWA-L10-1316-T02-C 1 2.02E+05
Se SWA-L10-1316-T03-C 1 4.45E+05
Se SWA-L10-1316-T04-C 1 9.00E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.05E+05 1.8E-01 1.5E+01 4.8E+01
1.87E+05 4.3E-01 1.5E+01 4.8E+01 10 125
4.55E+05 2.1E+00 1.5E+01 4.8E+01
8.67E+05 1.5E+00 1.5E+01 4.8E+01
9.79E+04 1.1E+00 1.5E+01 4.8E+01
1.95E+05 4.4E-01 1.5E+01 4.8E+01 10 125
4.62E+05 9.5E-01 1.5E+01 4.8E+01
9.19E+05 3.4E-01 1.5E+01 4.8E+01
1.04E+05 9.1E-01 1.5E+01 4.8E+01
2.02E+05 5.8E-01 1.5E+01 4.8E+01 10 125
4.45E+05 8.7E-01 1.5E+01 4.8E+01
9.00E+05 4.0E-01 1.5E+01 4.8E+01
Se SWA-L10-1316-B03-A 1 7.50E+00 U1/2 7.50E+00 2.4E+01 1.5E+01 4.8E+01
Se SWA-L10-1316-B03-B 1 7.50E+00 U1/2 7.50E+00 1 .6E+01 1.5E+01 4.8E+01
Se SWA-L10-1316-B03-C 1 7.50E+00 U1/2 7.50E+00 1.1E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.88E+05 83% VUICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.96E+05 85%VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
2.03E+05 84% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1503
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone.
Si SWA-L10-1316-T01-A 1 2.53E+04
Si SWA-L10-1316-T02-A 1 3.09E+04
Si SWA-L10-1316-T03-A 1 4.64E+04
Si SWA-L10-1316-T04-A 1 6.65E+04
Si SWA-L10-1316-T01-B 1 2.27E+04
Si SWA-L10-1316-T02-B 1 3.13E+04
Si SWA-L10-1316-T03-B 1 4.87E+04
Si SWA-L10-1316-T04-B 1 6.43E+04
Si SWA-L10-1316-T01-C 1 2.72E+04
Si SWA-L10-1316-T02-C 1 3.23E+04
Si SWA-L10-1316-T03-C 1 5.11E+04
Si SWA-L10-1316-T04-C 1 6.57E+04
Si SWA-L10-1316-B03-A 1 5.23E+00
Si SWA-L10-1316-B03-B 1 3.75E+00
Si SWA-L10-1316-B03-C 1 3.73E+00
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.53E+04 1.9E+00 1.1E+00 3.5E+00
3.09E+04 2.0E+00 1.1E+00 3.5E+00 1000 100
4.64E+04 4.5E-01 1.1E+00 3.5E+00
6.65E+04 1.0E+00 1.1E+00 3.5E+00
2.27E+04 8.6E-01 1.1E+00 3.5E+00
3.13E+04 3.2E-01 1.1E+00 3.5E+00 1000 100
4.87E+04 2.3E+00 1.1E+00 3.5E+00
6.43E+04 2.3E+00 1.1E+00 3.5E+00
2.72E+04 7.4E-01 1.1E+00 3.5E+00
3.23E+04 2.2E-01 1.1E+00 3.5E+00 1000 100
5.11E+04 5.9E-01 1.1E+00 3.5E+00
6.57E+04 8.9E-01 1.1E+00 3.5E+00
5.23E+00 4.9E+00 1.1E+00 3.5E+00
3.75E+00 3.6E+01 1.1E+00 3.5E+00
3.73E+00 1.8E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
3.19E+04 103% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
3.23E+04 106% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
3.33E+04 101% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1504
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qu
Na SWA-L10-1316-T01-A 1 4.90E+05
Na SWA-L10-1316-T02-A 1 6.39E+05
Na SWA-L10-1316-T03-A 1 8.66E+05
Na SWA-L10-1316-T04-A 1 9.53E+05
Na SWA-L10-1316-T01-B 1 4.91 E+05
Na SWA-L10-1316-T02-B 1 6.33E+05
Na SWA-L10-1316-T03-B 1 8.62E+05
Na SWA-L10-1316-T04-B 1 9.73E+05
Na SWA-L10-1316-T01-C 1 5.01 E+05
Na SWA-L10-1316-T02-C 1 6.39E+05
Na SWA-L10-1316-T03-C 1 8.51 E+05
Na SWA-L10-1316-T04-C 1 9.54E+05
Na SWA-L10-1316-B03-A 1 3.52E+01
Na SWA-L10-1316-B03-B 1 2.44E+01
Na SWA-L10-1316-B03-C 1 3.52E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.90E+05 4.1E-01 2.5E+00 8.0E+00
6.39E+05 5.2E-01 2.5E+00 8.0E+00 1000 100
8.66E+05 2.0E+00 2.5E+00 8.0E+00
9.53E+05 4.4E-01 2.5E+00 8.0E+00
4.91 E+05 6.7E-01 2.5E+00 8.0E+00
6.33E+05 9.5E-01 2.5E+00 8.0E+00 1000 100
8.62E+05 8.4E-01 2.5E+00 8.0E+00
9.73E+05 4.0E+00 2.5E+00 8.0E+00
5.01 E+05 5.4E-01 2.5E+00 8.0E+00
6.39E+05 8.2E-01 2.5E+00 8.0E+00 1000 100
8.51 E+05 8.8E-01 2.5E+00 8.0E+00
9.54E+05 6.5E-01 2.5E+00 8.0E+00
3.52E+01 3.3E+00 2.5E+00 8.0E+00
2.44E+01 1.3E+01 2.5E+00 8.0E+00
3.52E+01 6.3E+00 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
6.40E+05 94% VUICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
6.34E+05 104% VU ICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
6.40E+05 93% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1505
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone.
SWA-L10-1316-T01-A 1 3.19E+02
SWA-L10-1316-T02-A 1 3.77E+02
SWA-L10-1316-T03-A 1 4.19E+02
SWA-L10-1316-T04-A 1 4.60E+02
SWA-L10-1316-T01-B 1 3.10E+02
SWA-L10-1316-T02-B 1 3.56E+02
SWA-L10-1316-T03-B 1 4.13E+02
SWA-L10-1316-T04-B 1 4.53E+02
SWA-L10-1316-T01-C 1 2.99E+02
SWA-L10-1316-T02-C 1 3.65E+02
SWA-L10-1316-T03-C 1 3.96E+02
SWA-L10-1316-T04-C 1 4.46E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.19E+02 4.1E-01 1.0E+00 3.2E+00
3.77E+02 3.8E-01 1.0E+00 3.2E+00 1000 100
4.19E+02 2.1E+00 1.0E+00 3.2E+00
4.60E+02 1.3E+00 1.0E+00 3.2E+00
3.10E+02 7.1E-01 1.0E+00 3.2E+00
3.56E+02 8.1E-01 1.0E+00 3.2E+00 1000 100
4.13E+02 1.0E+00 1.0E+00 3.2E+00
4.53E+02 7.6E-01 1.0E+00 3.2E+00
2.99E+02 1.6E+00 1.0E+00 3.2E+00
3.65E+02 1.2E+00 1.0E+00 3.2E+00 1000 100
3.96E+02 6.0E-01 1.0E+00 3.2E+00
4.46E+02 4.8E-01 1.0E+00 3.2E+00
SWA-L10-1316-B03-A 1 5.00E-01 U1/2 5.00E-01 1 .8E+02 1.0E+00 3.2E+00
SWA-L10-1316-B03-B 1 5.00E-01 U1/2 5.00E-01 3.4E+01 1.0E+00 3.2E+00
SWA-L10-1316-B03-C 1 5.00E-01 U1/2 5.00E-01 1.1E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.45E+03 108% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.45E+03 109% VU ICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.40E+03 104% VU ICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1506
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S SWA-L10-1316-T01-A 1
S SWA-L10-1316-T02-A 1
S SWA-L10-1316-T03-A 1
S SWA-L10-1316-T04-A 1
S SWA-L10-1316-T01-B 1
S SWA-L10-1316-T02-B 1
S SWA-L10-1316-T03-B 1
S SWA-L10-1316-T04-B 1
S SWA-L10-1316-T01-C 1
S SWA-L10-1316-T02-C 1
S SWA-L10-1316-T03-C 1
S SWA-L10-1316-T04-C 1
S SWA-L10-1316-B03-A 1
S SWA-L10-1316-B03-B 1
S SWA-L10-1316-B03-C 1
Sample I
Cone. Qualifier
ug/L I
3.47E+05
6.13E+05
1.17E+06
2.08E+06
3.28E+05
6.29E+05
1.18E+06
2.15E+06
3.65E+05
6.52E+05
1.16E+06
2.14E+06
3.03E+02
3.89E+02
3.62E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.47E+05 6.8E-02 6.8E+00 2.2E+01
6.13E+05 3.2E-01 6.8E+00 2.2E+01 1000 100
1.17E+06 2.0E+00 6.8E+00 2.2E+01
2.08E+06 9.8E-01 6.8E+00 2.2E+01
3.28E+05 7.0E-01 6.8E+00 2.2E+01
6.29E+05 5.6E-01 6.8E+00 2.2E+01 1000 100
1.18E+06 8.0E-01 6.8E+00 2.2E+01
2.15E+06 3.9E-01 6.8E+00 2.2E+01
3.65E+05 4.0E-01 6.8E+00 2.2E+01
6.52E+05 9.1E-01 6.8E+00 2.2E+01 1000 100
1.16E+06 9.4E-01 6.8E+00 2.2E+01
2.14E+06 3.4E-01 6.8E+00 2.2E+01
3.03E+02 9.8E+00 6.8E+00 2.2E+01
3.89E+02 7.8E+00 6.8E+00 2.2E+01
3.62E+02 1.0E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
6.14E+05 95% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
6.30E+05 93% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
6.53E+05 94% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1507
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L10-1316-T01-A 1 2.30E+00 U1/2 2.30E+00 2.1E+02 4.6E+00 1.5E+01
Tl SWA-L10-1316-T02-A 1 2.30E+00 U1/2 2.30E+00 1 .2E+02 4.6E+00 1.5E+01 10 125
Tl SWA-L10-1316-T03-A 1 2.30E+00 U1/2 2.30E+00 2.0E+03 4.6E+00 1.5E+01
Tl SWA-L10-1316-T04-A 1 7.18E+00 E
7.18E+00 4.5E+01 4.6E+00 1 .5E+01
Tl SWA-L10-1316-T01-B 1 2.30E+00 U1/2 2.30E+00 4.8E+01 4.6E+00 1 .5E+01
Tl SWA-L10-1316-T02-B 1 2.30E+00 U1/2 2.30E+00 1 .3E+02 4.6E+00 1 .5E+01 10 125
Tl SWA-L10-1316-T03-B 1 2.30E+00 U1/2 2.30E+00 3.2E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1316-T04-B 1 8.66E+00 E
8.66E+00 6.0E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1316-T01-C 1 2.30E+00 U1/2 2.30E+00 2.4E+01 4.6E+00 1 .5E+01
Tl SWA-L10-1316-T02-C 1 2.30E+00 U1/2 2.30E+00 3.3E+01 4.6E+00 1 .5E+01 10 125
Tl SWA-L10-1316-T03-C 1 2.30E+00 U1/2 2.30E+00 1 .6E+03 4.6E+00 1 .5E+01
Tl SWA-L10-1316-T04-C 1 9.03E+00 E
9.03E+00 1.3E+02 4.6E+00 1 .5E+01
Tl SWA-L10-1316-B03-A 1 2.30E+00 U1/2 2.30E+00 9.0E+01 4.6E+00 1 .5E+01
Tl SWA-L10-1316-B03-B 1 2.30E+00 U1/2 2.30E+00 7.8E+01 4.6E+00 1 .5E+01
Tl SWA-L10-1316-B03-C 1 2.30E+00 U1/2 2.30E+00 8.6E+01 4.6E+00 1 .5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.25E+03 100% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.29E+03 103% VU ICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.24E+03 99%VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1508
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L10-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 4.0E+00 2.0E+00 6.4E+00
Ti SWA-L10-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 1 .8E+01 2.0E+00 6.4E+00 10 125
Ti SWA-L10-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 6.0E+01 2.0E+00 6.4E+00
Ti SWA-L10-1316-T04-A 1 4.49E+00 E
4.49E+00 4.6E+01 2.0E+00 6.4E+00
Ti SWA-L10-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 4.6E+01 2.0E+00 6.4E+00
Ti SWA-L10-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 4.3E+03 2.0E+00 6.4E+00 10 125
Ti SWA-L10-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 2.0E+01 2.0E+00 6.4E+00
Ti SWA-L10-1316-T04-B 1 2.34E+00 E
2.34E+00 1.1E+02 2.0E+00 6.4E+00
Ti SWA-L10-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 1 .OE+03 2.0E+00 6.4E+00
Ti SWA-L10-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 5.4E+03 2.0E+00 6.4E+00 10 125
Ti SWA-L10-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 5.3E+01 2.0E+00 6.4E+00
Ti SWA-L10-1316-T04-C 1 3.11E+OOE
3.11E+00 9.8E+01 2.0E+00 6.4E+00
Ti SWA-L10-1316-B03-A 1 1.00E+OOU1/2 1.00E+00 8.3E+01 2.0E+00 6.4E+00
Ti SWA-L10-1316-B03-B 1 1.00E+OOU1/2 1.00E+00 3.6E+02 2.0E+00 6.4E+00
Ti SWA-L10-1316-B03-C 1 1.00E+OOU1/2 1.00E+00 8.1E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.25E+03 100% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.34E+03 107% VU ICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.39E+03 111% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1509
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
V SWA-L10-1316-T01-A 1 3.55E+02
V SWA-L10-1316-T02-A 1 5.74E+02
V SWA-L10-1316-T03-A 1 1.26E+03
V SWA-L10-1316-T04-A 1 2.21E+03
V SWA-L10-1316-T01-B 1 3.33E+02
V SWA-L10-1316-T02-B 1 6.02E+02
V SWA-L10-1316-T03-B 1 1.29E+03
V SWA-L10-1316-T04-B 1 2.24E+03
V SWA-L10-1316-T01-C 1 3.52E+02
V SWA-L10-1316-T02-C 1 6.17E+02
V SWA-L10-1316-T03-C 1 1.32E+03
V SWA-L10-1316-T04-C 1 2.35E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.55E+02 6.6E-01 1.5E+00 4.8E+00
5.74E+02 4.2E-01 1.5E+00 4.8E+00 10 125
1.26E+03 1.5E+00 1.5E+00 4.8E+00
2.21 E+03 1.3E+00 1.5E+00 4.8E+00
3.33E+02 8.6E-01 1.5E+00 4.8E+00
6.02E+02 6.4E-01 1.5E+00 4.8E+00 10 125
1.29E+03 8.2E-01 1.5E+00 4.8E+00
2.24E+03 7.2E-01 1.5E+00 4.8E+00
3.52E+02 2.5E-01 1.5E+00 4.8E+00
6.17E+02 3.5E-01 1.5E+00 4.8E+00 10 125
1.32E+03 3.8E-01 1.5E+00 4.8E+00
2.35E+03 4.5E-01 1.5E+00 4.8E+00
V SWA-L10-1316-B03-A 1 7.50E-01 U1/2 7.50E-01 1 .OE+03 1.5E+00 4.8E+00
V SWA-L10-1316-B03-B 1 7.50E-01 U1/2 7.50E-01 2.5E+03 1.5E+00 4.8E+00
V SWA-L10-1316-B03-C 1 7.50E-01 U1/2 7.50E-01 2.4E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.73E+03 92% VUICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.73E+03 90% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.81E+03 95% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1510
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-L10-1316-T01-A 1
Zn SWA-L10-1316-T02-A 1
Zn SWA-L10-1316-T03-A 1
Zn SWA-L10-1316-T04-A 1
Zn SWA-L10-1316-T01-B 1
Zn SWA-L10-1316-T02-B 1
Zn SWA-L10-1316-T03-B 1
Zn SWA-L10-1316-T04-B 1
Zn SWA-L10-1316-T01-C 1
Zn SWA-L10-1316-T02-C 1
Zn SWA-L10-1316-T03-C 1
Zn SWA-L10-1316-T04-C 1
Zn SWA-L10-1316-B03-A 1
Zn SWA-L10-1316-B03-B 1
Zn SWA-L10-1316-B03-C 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
3.08E+00 E
6.43E+00
1.77E+01
5.00E-01 U1/2
3.22E+00
9.08E+00
1.83E+01
5.00E-01 U1/2
1.72E+00 E
9.89E+00
1.33E+01
1.90E+00 E
3.21 E+00
8.36E+00
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 3.2E+00 1.0E+00 3.2E+00
3.08E+00 1.2E+00 1.0E+00 3.2E+00 10 125
6.43E+00 2.2E+01 1.0E+00 3.2E+00
1.77E+01 3.0E+01 1.0E+00 3.2E+00
5.00E-01 6.3E+01 1.0E+00 3.2E+00
3.22E+00 8.0E+00 1.0E+00 3.2E+00 10 125
9.08E+00 3.7E+00 1.0E+00 3.2E+00
1.83E+01 3.0E+00 1.0E+00 3.2E+00
5.00E-01 2.3E+02 1.0E+00 3.2E+00
1.72E+00 1.0E+00 1.0E+00 3.2E+00 10 125
9.89E+00 1.4E+00 1.0E+00 3.2E+00
1.33E+01 5.1E-01 1.0E+00 3.2E+00
1.90E+00 1.8E+01 1.0E+00 3.2E+00
3.21 E+00 4.2E+00 1.0E+00 3.2E+00
8.36E+00 3.4E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 12/8/10 1:08 PM EPA Interlab L10 1313-1316 SWA
1.40E+03 112% VU ICP-OES 12/8/10 1:10 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:11 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:13 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:15 PM EPA Interlab L10 1313-1316 SWA
1.45E+03 116% VUICP-OES 12/8/10 1:16 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:18 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:20 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/101:21 PM EPA Interlab L10 1313-1316 SWA
1.47E+03 118% VUICP-OES 12/8/10 1:23 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:25 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:26 PM EPA Interlab L10 1313-1316 SWA
VUICP-OES 12/8/10 1:03 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:05 PM EPA Interlab L10 1313-1316 SWA
VU ICP-OES 12/8/10 1:06 PM EPA Interlab L10 1313-1316 SWA
                                                                                                                                                                         1-1511
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al SWA-L11-1316-T01-A 1
Al SWA-L11-1316-T02-A 1
Al SWA-L11-1316-T03-A 1
Al SWA-L11-1316-T04-A 1
Al SWA-L11-1316-T01-B 1
Al SWA-L11-1316-T02-B 1
Al SWA-L11-1316-T03-B 1
Al SWA-L11-1316-T04-B 1
Al SWA-L11-1316-T01-C 1
Al SWA-L11-1316-T02-C 1
Al SWA-L11-1316-T03-C 1
Al SWA-L11-1316-T04-C 1
Al SWA-L11-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.30E+04
5.14E+04
9.03E+04
1.38E+05
3.24E+04
5.13E+04
8.66E+04
1.37E+05
3.42E+04
5.16E+04
8.61 E+04
1.32E+05
5.17E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.30E+04 4.7E-01 1.0E+00 3.2E+00
5.14E+04 6.6E-01 1.0E+00 3.2E+00 1000 100
9.03E+04 3.7E-01 1.0E+00 3.2E+00
1.38E+05 1.0E+00 1.0E+00 3.2E+00
3.24E+04 4.9E-01 1.0E+00 3.2E+00
5.13E+04 9.0E-01 1.0E+00 3.2E+00 1000 100
8.66E+04 7.2E-01 1.0E+00 3.2E+00
1.37E+05 5.8E-01 1.0E+00 3.2E+00
3.42E+04 4.4E-01 1.0E+00 3.2E+00
5.16E+04 9.7E-01 1.0E+00 3.2E+00 1000 100
8.61 E+04 7.4E-01 1.0E+00 3.2E+00
1.32E+05 1.7E-01 1.0E+00 3.2E+00
5.17E+00 2.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
5.23E+04 91%VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
5.23E+04 102% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
5.26E+04 94% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                                  1-1512
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-L11-1316-T01-A 1
Sb SWA-L11-1316-T02-A 1
Sb SWA-L11-1316-T03-A 1
Sb SWA-L11-1316-T04-A 1
Sb SWA-L11-1316-T01-B 1
Sb SWA-L11-1316-T02-B 1
Sb SWA-L11-1316-T03-B 1
Sb SWA-L11-1316-T04-B 1
Sb SWA-L11-1316-T01-C 1
Sb SWA-L11-1316-T02-C 1
Sb SWA-L11-1316-T03-C 1
Sb SWA-L11-1316-T04-C 1
Sb SWA-L11-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
4.86E+03
1.51E+03
3.32E+03
6.38E+03
4.59E+03
1.59E+03
3.76E+03
6.37E+03
4.74E+03
1.74E+03
3.26E+03
6.35E+03
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.86E+03 9.5E-01 7.5E+00 2.4E+01
1.51E+03 9.0E+00 7.5E+00 2.4E+01 10 100
3.32E+03 6.1E-01 7.5E+00 2.4E+01
6.38E+03 8.2E-01 7.5E+00 2.4E+01
4.59E+03 5.7E-01 7.5E+00 2.4E+01
1.59E+03 7.6E+00 7.5E+00 2.4E+01 10 100
3.76E+03 2.2E+00 7.5E+00 2.4E+01
6.37E+03 6.7E+00 7.5E+00 2.4E+01
4.74E+03 2.0E+00 7.5E+00 2.4E+01
1.74E+03 1.1E+01 7.5E+00 2.4E+01 10 100
3.26E+03 1.8E+00 7.5E+00 2.4E+01
6.35E+03 3.1E+00 7.5E+00 2.4E+01
3.75E+00 1.8E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 3:11 PM EPA Interlab 1316 SWA Reruns
2.38E+03 87% VU ICP-OES 5/23/11 3:14 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:16 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:18 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:21 PM EPA Interlab 1316 SWA Reruns
2.46E+03 88% VU ICP-OES 5/23/11 3:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:28 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:31 PM EPA Interlab 1316 SWA Reruns
2.67E+03 93% VU ICP-OES 5/23/11 3:33 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:35 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:38 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1513
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-L11-1316-T01-A 1
As SWA-L11-1316-T02-A 1
As SWA-L11-1316-T03-A 1
As SWA-L11-1316-T04-A 1
As SWA-L11-1316-T01-B 1
As SWA-L11-1316-T02-B 1
As SWA-L11-1316-T03-B 1
As SWA-L11-1316-T04-B 1
As SWA-L11-1316-T01-C 1
As SWA-L11-1316-T02-C 1
As SWA-L11-1316-T03-C 1
As SWA-L11-1316-T04-C 1
As SWA-L11-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
4.47E+03
1.19E+04
2.83E+04
6.49E+04
4.28E+03
1.17E+04
2.81 E+04
5.55E+04
4.74E+03
1.19E+04
2.56E+04
5.22E+04
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.47E+03 4.5E-01 1.1E+01 3.5E+01
1.19E+04 1.0E+00 1.1E+01 3.5E+01 10 100
2.83E+04 5.6E-01 1.1E+01 3.5E+01
6.49E+04 1.1E+00 1.1E+01 3.5E+01
4.28E+03 5.6E-01 1.1E+01 3.5E+01
1.17E+04 1.2E+00 1.1E+01 3.5E+01 10 100
2.81 E+04 1.7E+00 1.1E+01 3.5E+01
5.55E+04 4.6E-01 1.1E+01 3.5E+01
4.74E+03 5.8E-01 1.1E+01 3.5E+01
1.19E+04 1.0E+00 1.1E+01 3.5E+01 10 100
2.56E+04 1.3E+00 1.1E+01 3.5E+01
5.22E+04 1.1E+00 1.1E+01 3.5E+01
5.50E+00 7.1E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.29E+04 99%VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.27E+04 95% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.29E+04 93% VUICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1514
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qua
B SWA-L11-1316-T01-A 1 8.75E+02
B SWA-L11-1316-T02-A 1 9.35E+02
B SWA-L11-1316-T03-A 1 5.95E+02
B SWA-L11-1316-T04-A 1 6.29E+02
B SWA-L11-1316-T01-B 1 8.23E+02
B SWA-L11-1316-T02-B 1 9.35E+02
B SWA-L11-1316-T03-B 1 6.14E+02
B SWA-L11-1316-T04-B 1 6.44E+02
B SWA-L11-1316-T01-C 1 8.51 E+02
B SWA-L11-1316-T02-C 1 9.24E+02
B SWA-L11-1316-T03-C 1 5.98E+02
B SWA-L11-1316-T04-C 1 6.54E+02
B SWA-L11-1316-B01-A 1 1.89E+01
Internal ICP-OES Spike Sol'n
ifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.75E+02 7.8E-01 1.0E+00 3.2E+00
9.35E+02 5.3E-01 1.0E+00 3.2E+00 1000 100
5.95E+02 4.3E-01 1.0E+00 3.2E+00
6.29E+02 7.2E-01 1.0E+00 3.2E+00
8.23E+02 2.3E-01 1.0E+00 3.2E+00
9.35E+02 7.8E-01 1.0E+00 3.2E+00 1000 100
6.14E+02 4.8E-01 1.0E+00 3.2E+00
6.44E+02 7.0E-01 1.0E+00 3.2E+00
8.51 E+02 2.0E-01 1.0E+00 3.2E+00
9.24E+02 3.7E-01 1.0E+00 3.2E+00 1000 100
5.98E+02 3.9E-01 1.0E+00 3.2E+00
6.54E+02 2.0E-01 1.0E+00 3.2E+00
1.89E+01 2.9E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 3:11 PM EPA Interlab 1316 SWA Reruns
1.85E+03 91% VU ICP-OES 5/23/11 3:14 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:16 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:18 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:21 PM EPA Interlab 1316 SWA Reruns
1.84E+03 90% VU ICP-OES 5/23/11 3:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:28 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:31 PM EPA Interlab 1316 SWA Reruns
1.87E+03 94% VU ICP-OES 5/23/11 3:33 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:35 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:38 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1515
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qua
Ba SWA-L11-1316-T01-A 1 2.18E+02
Ba SWA-L11-1316-T02-A 1 2.33E+02
Ba SWA-L11-1316-T03-A 1 2.51E+02
Ba SWA-L11-1316-T04-A 1 2.02E+02
Ba SWA-L11-1316-T01-B 1 2.40E+02
Ba SWA-L11-1316-T02-B 1 2.56E+02
Ba SWA-L11-1316-T03-B 1 2.27E+02
Ba SWA-L11-1316-T04-B 1 1.79E+02
Ba SWA-L11-1316-T01-C 1 2.58E+02
Ba SWA-L11-1316-T02-C 1 2.40E+02
Ba SWA-L11-1316-T03-C 1 2.24E+02
Ba SWA-L11-1316-T04-C 1 1.83E+02
Ba SWA-L11-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
ifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.18E+02 1.2E-01 1.0E+00 3.2E+00
2.33E+02 6.2E-01 1.0E+00 3.2E+00 10 100
2.51 E+02 4.3E-01 1.0E+00 3.2E+00
2.02E+02 6.6E-01 1.0E+00 3.2E+00
2.40E+02 1.2E+00 1.0E+00 3.2E+00
2.56E+02 1.3E-01 1.0E+00 3.2E+00 10 100
2.27E+02 1.4E+00 1.0E+00 3.2E+00
1.79E+02 1.4E-01 1.0E+00 3.2E+00
2.58E+02 2.1E-01 1.0E+00 3.2E+00
2.40E+02 9.1E-01 1.0E+00 3.2E+00 10 100
2.24E+02 1.4E-01 1.0E+00 3.2E+00
1.83E+02 3.2E-01 1.0E+00 3.2E+00
5.00E-01 1.5E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 5:09 PM EPA Interlab L11 1313-1316 SWA
1.13E+03 90% VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.22E+03 96% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.24E+03 100% VUICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1516
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-L11-1316-T01-A 1
Be SWA-L11-1316-T02-A 1
Be SWA-L11-1316-T03-A 1
Be SWA-L11-1316-T04-A 1
Be SWA-L11-1316-T01-B 1
Be SWA-L11-1316-T02-B 1
Be SWA-L11-1316-T03-B 1
Be SWA-L11-1316-T04-B 1
Be SWA-L11-1316-T01-C 1
Be SWA-L11-1316-T02-C 1
Be SWA-L11-1316-T03-C 1
Be SWA-L11-1316-T04-C 1
Be SWA-L11-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 3.8E+02 1.9E+00 6.0E+00
9.50E-01 2.0E+02 1.9E+00 6.0E+00 10 100
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 7.4E+01 1.9E+00 6.0E+00
9.50E-01 4.7E+01 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00 10 100
9.50E-01 4.1E+02 1.9E+00 6.0E+00
9.50E-01 4.3E+02 1.9E+00 6.0E+00
9.50E-01 2.6E+02 1.9E+00 6.0E+00
9.50E-01 1.4E+02 1.9E+00 6.0E+00 10 100
9.50E-01 8.6E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
9.98E+02 100% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
9.95E+02 99% VU ICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
9.98E+02 100% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1517
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qu<
1 1 1 ug/L
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cd SWA-L11-1316-T01-A 1 1.10E+OOU1/2 1.10E+00 5.0E+01 2.2E+00 7.0E+00
Cd SWA-L11-1316-T02-A 1 1.10E+OOU1/2 1.10E+00 8.9E+01 2.2E+00 7.0E+00 10 100
Cd SWA-L11-1316-T03-A 1 1.10E+OOU1/2 1.10E+00 3.8E+03 2.2E+00 7.0E+00
Cd SWA-L11-1316-T04-A 1 1.10E+OOU1/2 1.10E+00 1.9E+02 2.2E+00 7.0E+00
Cd SWA-L11-1316-T01-B 1 1.10E+OOU1/2 1.10E+00 2.3E+02 2.2E+00 7.0E+00
Cd SWA-L11-1316-T02-B 1 1.10E+OOU1/2 1.10E+00 1.5E+02 2.2E+00 7.0E+00 10 100
Cd SWA-L11-1316-T03-B 1 1.10E+OOU1/2 1.10E+00 1.1E+02 2.2E+00 7.0E+00
Cd SWA-L11-1316-T04-B 1 1.10E+OOU1/2 1.10E+00 7.5E+01 2.2E+00 7.0E+00
Cd SWA-L11-1316-T01-C 1 1.10E+OOU1/2 1.10E+00 6.8E+01 2.2E+00 7.0E+00
Cd SWA-L11-1316-T02-C 1 1.10E+OOU1/2 1.10E+00 1.6E+03 2.2E+00 7.0E+00 10 100
Cd SWA-L11-1316-T03-C 1 1.10E+OOU1/2 1.10E+00 8.2E+01 2.2E+00 7.0E+00
Cd SWA-L11-1316-T04-C 1 1.10E+OOU1/2 1.10E+00 1.1E+02 2.2E+00 7.0E+00
Cd SWA-L11-1316-B01-A 1 1.10E+OOU1/2 1.10E+00 5.3E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA Interlab L11 1313-1316 SWA
9.18E+02 92% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
9.23E+02 92% VUICP-OES 4/7/1 1 5:17 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
9.24E+02 92% VUICP-OES 4/7/1 1 5:24 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1518
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ca Sample Dilution
Ca SWA-L11-1316-T01-A 1
Ca SWA-L11-1316-T02-A 1
Ca SWA-L11-1316-T03-A 1
Ca SWA-L11-1316-T04-A 1
Ca SWA-L11-1316-T01-B 1
Ca SWA-L11-1316-T02-B 1
Ca SWA-L11-1316-T03-B 1
Ca SWA-L11-1316-T04-B 1
Ca SWA-L11-1316-T01-C 1
Ca SWA-L11-1316-T02-C 1
Ca SWA-L11-1316-T03-C 1
Ca SWA-L11-1316-T04-C 1
Ca SWA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.29E+04
1.08E+04
8.11E+03
5.91 E+03
1.50E+04
1.11E+04
7.44E+03
5.34E+03
1.45E+04
1.10E+04
7.60E+03
5.39E+03
5.99E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.29E+04 3.1E-01 2.6E+00 8.3E+00
1.08E+04 2.2E-01 2.6E+00 8.3E+00 1000 100
8.11 E+03 3.7E-01 2.6E+00 8.3E+00
5.91 E+03 5.2E-01 2.6E+00 8.3E+00
1.50E+04 5.8E-01 2.6E+00 8.3E+00
1.11E+04 3.1E-02 2.6E+00 8.3E+00 1000 100
7.44E+03 1.0E+00 2.6E+00 8.3E+00
5.34E+03 8.5E-01 2.6E+00 8.3E+00
1.45E+04 4.0E-01 2.6E+00 8.3E+00
1.10E+04 4.7E-01 2.6E+00 8.3E+00 1000 100
7.60E+03 7.4E-01 2.6E+00 8.3E+00
5.39E+03 1.0E+00 2.6E+00 8.3E+00
5.99E+01 2.1E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time
ug/L %
VU ICP-OES 4/7/1 1 5:09 PM
1.18E+04 95% VU ICP-OES 4/7/11 5:11 PM
VU ICP-OES 4/7/11 5:12 PM
VU ICP-OES 4/7/11 5:14 PM
VU ICP-OES 4/7/11 5:15 PM
1.20E+04 91% VU ICP-OES 4/7/11 5:17 PM
VU ICP-OES 4/7/11 5:19 PM
VU ICP-OES 4/7/1 1 5:20 PM
VU ICP-OES 4/7/1 1 5:22 PM
1.19E+04 93% VU ICP-OES 4/7/11 5:24 PM
VU ICP-OES 4/7/1 1 5:25 PM
VU ICP-OES 4/7/1 1 5:27 PM
VU ICP-OES 4/7/1 1 5:04 PM
Filename
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
EPAInterlabLH 1313-1316 SWA
                                                                                                                                                                         1-1519
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone.
1 ug/L
Cr SWA-L11-1316-T01-A 1 9.08E+02
Cr SWA-L11-1316-T02-A 1 1.34E+03
Cr SWA-L11-1316-T03-A 1 1.80E+03
Cr SWA-L11-1316-T04-A 1 2.18E+03
Cr SWA-L11-1316-T01-B 1 9.03E+02
Cr SWA-L11-1316-T02-B 1 1.34E+03
Cr SWA-L11-1316-T03-B 1 1.81E+03
Cr SWA-L11-1316-T04-B 1 2.18E+03
Cr SWA-L11-1316-T01-C 1 9.23E+02
Cr SWA-L11-1316-T02-C 1 1.36E+03
Cr SWA-L11-1316-T03-C 1 1.79E+03
Cr SWA-L11-1316-T04-C 1 2.04E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.08E+02 1.3E+00 1.2E+00 3.8E+00
1.34E+03 1.2E+00 1.2E+00 3.8E+00 10 100
1.80E+03 4.3E-01 1.2E+00 3.8E+00
2.18E+03 9.9E-01 1.2E+00 3.8E+00
9.03E+02 6.6E-01 1.2E+00 3.8E+00
1.34E+03 1.3E+00 1.2E+00 3.8E+00 10 100
1.81E+03 1.6E+00 1.2E+00 3.8E+00
2.18E+03 2.2E-01 1.2E+00 3.8E+00
9.23E+02 1.2E+00 1.2E+00 3.8E+00
1.36E+03 1.3E+00 1.2E+00 3.8E+00 10 100
1.79E+03 6.8E-01 1.2E+00 3.8E+00
2.04E+03 5.2E-01 1.2E+00 3.8E+00
Cr SWA-L11-1316-B01-A 1 6.00E-01 U1/2 6.00E-01 2.5E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 3:11 PM EPA Interlab 1316 SWA Reruns
2.25E+03 92% VU ICP-OES 5/23/11 3:14 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:16 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:18 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:21 PM EPA Interlab 1316 SWA Reruns
2.21E+03 88% VU ICP-OES 5/23/11 3:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:28 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:31 PM EPA Interlab 1316 SWA Reruns
2.27E+03 91% VU ICP-OES 5/23/11 3:33 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:35 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:38 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1520
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Co SWA-L11-1316-T01-A 1 9.00E-01 U1/2 9.00E-01 1.0E+02 1.8E+00 5.7E+00
Co SWA-L11-1316-T02-A 1 9.00E-01 U1/2 9.00E-01 1.9E+01 1.8E+00 5.7E+00 10 100
Co SWA-L11-1316-T03-A 1 1.92E+OOE
Co SWA-L11-1316-T04-A 1 4.30E+00 E
1.92E+00 5.9E+01 1.8E+00 5.7E+00
4.30E+00 1.4E+00 1.8E+00 5.7E+00
Co SWA-L11-1316-T01-B 1 9.00E-01 U1/2 9.00E-01 6.2E+01 1.8E+00 5.7E+00
Co SWA-L11-1316-T02-B 1 9.00E-01 U1/2 9.00E-01 4.3E+01 1.8E+00 5.7E+00 10 100
Co SWA-L11-1316-T03-B 1 1.95E+OOE
Co SWA-L11-1316-T04-B 1 4.66E+00 E
1.95E+00 4.3E+01 1.8E+00 5.7E+00
4.66E+00 9.3E+00 1.8E+00 5.7E+00
Co SWA-L11-1316-T01-C 1 9.00E-01 U1/2 9.00E-01 6.9E+01 1.8E+00 5.7E+00
Co SWA-L11-1316-T02-C 1 9.00E-01 U1/2 9.00E-01 5.5E+01 1.8E+00 5.7E+00 10 100
Co SWA-L11-1316-T03-C 1 1.96E+OOE
Co SWA-L11-1316-T04-C 1 3.86E+00 E
1.96E+00 3.6E+01 1.8E+00 5.7E+00
3.86E+00 5.6E+00 1.8E+00 5.7E+00
Co SWA-L11-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 1.1E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA Interlab L11 1313-1316 SWA
9.92E+02 99% VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
9.91E+02 99% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
9.96E+02 100% VU ICP-OES 4/7/1 1 5:24 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1521
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Cu SWA-L11-1316-T01-A 1 1.85E+OOU1/2 1.85E+00 3.2E+01 3.7E+00 1.2E+01
Cu SWA-L11-1316-T02-A 1 1.85E+OOU1/2 1.85E+00 1.1E+02 3.7E+00 1.2E+01 10 100
Cu SWA-L11-1316-T03-A 1 1.85E+OOU1/2 1.85E+00 9.0E+01 3.7E+00 1.2E+01
Cu SWA-L11-1316-T04-A 1 1.85E+OOU1/2 1.85E+00 2.1E+01 3.7E+00 1.2E+01
Cu SWA-L11-1316-T01-B 1 1.85E+OOU1/2 1.85E+00 2.5E+02 3.7E+00 1.2E+01
Cu SWA-L11-1316-T02-B 1 1.85E+OOU1/2 1.85E+00 8.7E+01 3.7E+00 1.2E+01 10 100
Cu SWA-L11-1316-T03-B 1 1.85E+OOU1/2 1.85E+00 8.9E+01 3.7E+00 1.2E+01
Cu SWA-L11-1316-T04-B 1 1.85E+OOU1/2 1.85E+00 1.6E+04 3.7E+00 1.2E+01
Cu SWA-L11-1316-T01-C 1 1.85E+OOU1/2 1.85E+00 2.8E+03 3.7E+00 1.2E+01
Cu SWA-L11-1316-T02-C 1 1.85E+OOU1/2 1.85E+00 4.9E+02 3.7E+00 1.2E+01 10 100
Cu SWA-L11-1316-T03-C 1 1.85E+OOU1/2 1.85E+00 2.2E+02 3.7E+00 1.2E+01
Cu SWA-L11-1316-T04-C 1 1.85E+OOU1/2 1.85E+00 1.5E+02 3.7E+00 1.2E+01
Cu SWA-L11-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 2.3E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA Interlab L11 1313-1316 SWA
1.05E+03 105% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.04E+03 104% VU ICP-OES 4/7/1 1 5:17 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.02E+03 102% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L1 1 1313-1316 SWA
VU ICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1522
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone.
1 ug/L
Fe SWA-L11-1316-T01-A 1 6.56E+01
Fe SWA-L11-1316-T02-A 1 1.40E+02
Fe SWA-L11-1316-T03-A 1 3.41 E+02
Fe SWA-L11-1316-T04-A 1 8.30E+02
Fe SWA-L11-1316-T01-B 1 6.66E+01
Fe SWA-L11-1316-T02-B 1 1.35E+02
Fe SWA-L11-1316-T03-B 1 3.57E+02
Fe SWA-L11-1316-T04-B 1 9.69E+02
Fe SWA-L11-1316-T01-C 1 6.94E+01
Fe SWA-L11-1316-T02-C 1 1.38E+02
Fe SWA-L11-1316-T03-C 1 3.26E+02
Fe SWA-L11-1316-T04-C 1 8.90E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
6.56E+01 5.0E-01 2.0E+00 6.4E+00
1.40E+02 1.0E+00 2.0E+00 6.4E+00 1000 100
3.41 E+02 7.0E-01 2.0E+00 6.4E+00
8.30E+02 7.3E-01 2.0E+00 6.4E+00
6.66E+01 1.2E+00 2.0E+00 6.4E+00
1.35E+02 3.5E-01 2.0E+00 6.4E+00 1000 100
3.57E+02 1.3E+00 2.0E+00 6.4E+00
9.69E+02 4.7E-02 2.0E+00 6.4E+00
6.94E+01 5.7E-01 2.0E+00 6.4E+00
1.38E+02 4.9E-01 2.0E+00 6.4E+00 1000 100
3.26E+02 9.9E-01 2.0E+00 6.4E+00
8.90E+02 9.2E-01 2.0E+00 6.4E+00
Fe SWA-L11-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 2.4E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.13E+03 99% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.18E+03 104% VU ICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.27E+03 113% VUICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1523
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone.
1 1 ug/L
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Pb SWA-L11-1316-T01-A 1 1.60E+01 E 1.60E+01 9.7E+00 6.8E+00 2.2E+01
Pb SWA-L11-1316-T02-A 1 2.35E+01
Pb SWA-L11-1316-T03-A 1 8.98E+01
Pb SWA-L11-1316-T04-A 1 1.76E+02
2.35E+01 1.3E+01 6.8E+00 2.2E+01 10 100
8.98E+01 9.2E+00 6.8E+00 2.2E+01
1.76E+02 2.1E+00 6.8E+00 2.2E+01
Pb SWA-L11-1316-T01-B 1 1.52E+01 E 1.52E+01 3.7E+01 6.8E+00 2.2E+01
Pb SWA-L11-1316-T02-B 1 3.29E+01
Pb SWA-L11-1316-T03-B 1 6.85E+01
Pb SWA-L11-1316-T04-B 1 1.77E+02
3.29E+01 1.3E+01 6.8E+00 2.2E+01 10 100
6.85E+01 3.5E+00 6.8E+00 2.2E+01
1.77E+02 6.0E+00 6.8E+00 2.2E+01
Pb SWA-L11-1316-T01-C 1 1.46E+01 E 1.46E+01 4.7E+00 6.8E+00 2.2E+01
Pb SWA-L11-1316-T02-C 1 3.09E+01
Pb SWA-L11-1316-T03-C 1 7.72E+01
Pb SWA-L11-1316-T04-C 1 1.77E+02
3.09E+01 9.3E+00 6.8E+00 2.2E+01 10 100
7.72E+01 4.6E+00 6.8E+00 2.2E+01
1.77E+02 1.9E+00 6.8E+00 2.2E+01
Pb SWA-L11-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 2.3E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.14E+03 112% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.14E+03 111% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.17E+03 114% VUICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1524
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li SWA-L11-1316-T01-A 1
Li SWA-L11-1316-T02-A 1
Li SWA-L11-1316-T03-A 1
Li SWA-L11-1316-T04-A 1
Li SWA-L11-1316-T01-B 1
Li SWA-L11-1316-T02-B 1
Li SWA-L11-1316-T03-B 1
Li SWA-L11-1316-T04-B 1
Li SWA-L11-1316-T01-C 1
Li SWA-L11-1316-T02-C 1
Li SWA-L11-1316-T03-C 1
Li SWA-L11-1316-T04-C 1
Li SWA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.39E+00 E
5.93E+00 E
7.49E+00
1.04E+01
2.18E+00 E
6.11E+00
7.87E+00
1.12E+01
2.01 E+00 E
5.57E+00 E
7.66E+00
1.06E+01
9.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.39E+00 4.3E-01 1.9E+00 6.0E+00
5.93E+00 1.8E+00 1.9E+00 6.0E+00 10 100
7.49E+00 2.1E+00 1.9E+00 6.0E+00
1.04E+01 5.5E+00 1.9E+00 6.0E+00
2.18E+00 3.8E-01 1.9E+00 6.0E+00
6.11 E+00 1.8E+00 1.9E+00 6.0E+00 10 100
7.87E+00 2.9E+00 1.9E+00 6.0E+00
1.12E+01 3.4E+00 1.9E+00 6.0E+00
2.01 E+00 1.3E+00 1.9E+00 6.0E+00
5.57E+00 4.6E+00 1.9E+00 6.0E+00 10 100
7.66E+00 1.8E+00 1.9E+00 6.0E+00
1.06E+01 3.7E-01 1.9E+00 6.0E+00
9.50E-01 2.3E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/23/11 3:11 PM EPA Interlab 1316 SWA Reruns
8.58E+02 85% VU ICP-OES 5/23/11 3:14 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:16 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:18 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:21 PM EPA Interlab 1316 SWA Reruns
9.13E+02 91% VU ICP-OES 5/23/11 3:23 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:25 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:28 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:31 PM EPA Interlab 1316 SWA Reruns
8.78E+02 87% VU ICP-OES 5/23/11 3:33 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:35 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 5/23/11 3:38 PM EPA Interlab 1316 SWA Reruns
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1525
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mn Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Mn SWA-L11-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 8.8E+00 2.0E+00 6.4E+00
Mn SWA-L11-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 1.1E+01 2.0E+00 6.4E+00 10 100
Mn SWA-L11-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 1 .2E+01 2.0E+00 6.4E+00
Mn SWA-L11-1316-T04-A 1 3.15E+00 E
3.15E+00 4.0E+00 2.0E+00 6.4E+00
Mn SWA-L11-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 2.6E+00 2.0E+00 6.4E+00
Mn SWA-L11-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 1 .4E+01 2.0E+00 6.4E+00 10 100
Mn SWA-L11-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 4.6E+00 2.0E+00 6.4E+00
Mn SWA-L11-1316-T04-B 1 4.58E+00 E
4.58E+00 1.2E+00 2.0E+00 6.4E+00
Mn SWA-L11-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 1 .2E+01 2.0E+00 6.4E+00
Mn SWA-L11-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 7.1E+00 2.0E+00 6.4E+00 10 100
Mn SWA-L11-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 2.7E+00 2.0E+00 6.4E+00
Mn SWA-L11-1316-T04-C 1 3.69E+00 E
3.69E+00 1.5E+00 2.0E+00 6.4E+00
Mn SWA-L11-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 1.8E-01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.06E+03 106% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.06E+03 106% VU ICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.07E+03 107% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1526
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone.
1 ug/L
Mg SWA-L11-1316-T01-A 1 1.30E+01
Mg SWA-L11-1316-T02-A 1 1.96E+01
Mg SWA-L11-1316-T03-A 1 2.34E+01
Mg SWA-L11-1316-T04-A 1 2.73E+01
Mg SWA-L11-1316-T01-B 1 9.60E+00
Mg SWA-L11-1316-T02-B 1 1.76E+01
Mg SWA-L11-1316-T03-B 1 2.29E+01
Mg SWA-L11-1316-T04-B 1 2.97E+01
Mg SWA-L11-1316-T01-C 1 1.08E+01
Mg SWA-L11-1316-T02-C 1 2.66E+01
Mg SWA-L11-1316-T03-C 1 2.37E+01
Mg SWA-L11-1316-T04-C 1 2.66E+01
Mg SWA-L11-1316-B01-A 1 1.96E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.30E+01 1.6E+01 1.0E+00 3.2E+00
1.96E+01 4.9E+01 1.0E+00 3.2E+00 1000 100
2.34E+01 6.5E+00 1.0E+00 3.2E+00
2.73E+01 1.3E+02 1.0E+00 3.2E+00
9.60E+00 1.0E+01 1.0E+00 3.2E+00
1.76E+01 1.3E+01 1.0E+00 3.2E+00 1000 100
2.29E+01 1.5E+01 1.0E+00 3.2E+00
2.97E+01 1.0E+01 1.0E+00 3.2E+00
1.08E+01 6.2E+01 1.0E+00 3.2E+00
2.66E+01 2.0E+01 1.0E+00 3.2E+00 1000 100
2.37E+01 6.5E+01 1.0E+00 3.2E+00
2.66E+01 3.2E+01 1.0E+00 3.2E+00
1.96E+01 9.0E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
9.19E+02 90%VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
9.25E+02 91% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
9.74E+02 95% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1527
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 1 ug/L
Mo SWA-L11-1316-T01-A 1 1.01E+02
Mo SWA-L11-1316-T02-A 1 1.78E+02
Mo SWA-L11-1316-T03-A 1 3.64E+02
Mo SWA-L11-1316-T04-A 1 6.68E+02
Mo SWA-L11-1316-T01-B 1 1.04E+02
Mo SWA-L11-1316-T02-B 1 1.67E+02
Mo SWA-L11-1316-T03-B 1 3.57E+02
Mo SWA-L11-1316-T04-B 1 6.52E+02
Mo SWA-L11-1316-T01-C 1 1.07E+02
Mo SWA-L11-1316-T02-C 1 1.63E+02
Mo SWA-L11-1316-T03-C 1 3.24E+02
Mo SWA-L11-1316-T04-C 1 5.57E+02
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.01E+02 3.1E-01 1.2E+00 3.8E+00
1.78E+02 6.9E-01 1.2E+00 3.8E+00 10 100
3.64E+02 3.8E-01 1.2E+00 3.8E+00
6.68E+02 4.5E-01 1.2E+00 3.8E+00
1.04E+02 1.3E+00 1.2E+00 3.8E+00
1.67E+02 2.1E+00 1.2E+00 3.8E+00 10 100
3.57E+02 1.2E+00 1.2E+00 3.8E+00
6.52E+02 2.7E-01 1.2E+00 3.8E+00
1.07E+02 8.4E-01 1.2E+00 3.8E+00
1.63E+02 5.9E-01 1.2E+00 3.8E+00 10 100
3.24E+02 4.9E-01 1.2E+00 3.8E+00
5.57E+02 1.0E+00 1.2E+00 3.8E+00
Mo SWA-L11-1316-B01-A 1 6.00E-01 U1/2 6.00E-01 2.3E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.15E+03 98%VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.15E+03 98% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.16E+03 100% VUICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1528
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. (
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ni SWA-L11-1316-T01-A 1 9.00E-01 U1/2 9.00E-01 2.3E+02 1.8E+00 5.7E+00
Ni SWA-L11-1316-T02-A 1 9.00E-01 U1/2 9.00E-01 1.6E+02 1.8E+00 5.7E+00 10 100
Ni SWA-L11-1316-T03-A 1 9.00E-01 U1/2 9.00E-01 3.3E+02 1.8E+00 5.7E+00
Ni SWA-L11-1316-T04-A 1 4.55E+00 E
4.55E+00 4.5E+01 1.8E+00 5.7E+00
Ni SWA-L11-1316-T01-B 1 9.00E-01 U1/2 9.00E-01 2.1E+02 1.8E+00 5.7E+00
Ni SWA-L11-1316-T02-B 1 9.00E-01 U1/2 9.00E-01 5.7E+02 1.8E+00 5.7E+00 10 100
Ni SWA-L11-1316-T03-B 1 9.00E-01 U1/2 9.00E-01 3.0E+01 1.8E+00 5.7E+00
Ni SWA-L11-1316-T04-B 1 5.20E+00 E
5.20E+00 3.8E+01 1.8E+00 5.7E+00
Ni SWA-L11-1316-T01-C 1 9.00E-01 U1/2 9.00E-01 1.8E+02 1.8E+00 5.7E+00
Ni SWA-L11-1316-T02-C 1 9.00E-01 U1/2 9.00E-01 2.1E+01 1.8E+00 5.7E+00 10 100
Ni SWA-L11-1316-T03-C 1 9.00E-01 U1/2 9.00E-01 7.0E+01 1.8E+00 5.7E+00
Ni SWA-L11-1316-T04-C 1 3.31 E+00 E
3.31 E+00 3.4E+01 1.8E+00 5.7E+00
Ni SWA-L11-1316-B01-A 1 9.00E-01 U1/2 9.00E-01 7.8E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA Interlab L11 1313-1316 SWA
1.01E+03 101% VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.08E+03 107% VU ICP-OES 4/7/1 1 5:17 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.03E+03 103% VU ICP-OES 4/7/1 1 5:24 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1529
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone.
1 ug/L
P SWA-L11-1316-T01-A 1 2.58E+01
P SWA-L11-1316-T02-A 1 1.02E+02
P SWA-L11-1316-T03-A 1 3.53E+02
P SWA-L11-1316-T04-A 1 1.32E+03
P SWA-L11-1316-T01-B 1 3.20E+01
P SWA-L11-1316-T02-B 1 9.19E+01
P SWA-L11-1316-T03-B 1 3.80E+02
P SWA-L11-1316-T04-B 1 1.23E+03
P SWA-L11-1316-T01-C 1 3.67E+01
P SWA-L11-1316-T02-C 1 9.87E+01
P SWA-L11-1316-T03-C 1 3.61 E+02
P SWA-L11-1316-T04-C 1 1.27E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.58E+01 4.1E+01 3.7E+00 1.2E+01
1.02E+02 6.2E+00 3.7E+00 1.2E+01 1000 100
3.53E+02 3.0E+00 3.7E+00 1.2E+01
1.32E+03 4.3E+00 3.7E+00 1.2E+01
3.20E+01 7.4E+00 3.7E+00 1.2E+01
9.19E+01 5.4E+00 3.7E+00 1.2E+01 1000 100
3.80E+02 7.1E-01 3.7E+00 1.2E+01
1.23E+03 7.8E-01 3.7E+00 1.2E+01
3.67E+01 2.1E+01 3.7E+00 1.2E+01
9.87E+01 5.9E+00 3.7E+00 1 .2E+01 1000 100
3.61 E+02 1.9E+00 3.7E+00 1 .2E+01
1.27E+03 2.2E+00 3.7E+00 1 .2E+01
P SWA-L11-1316-B01-A 1 1.85E+OOU1/2 1.85E+00 4.6E+01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.21E+03 111% VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.18E+03 109% VU ICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.20E+03 110% VUICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1530
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone.
K SWA-L11-1316-T01-A 1 3.02E+05
K SWA-L11-1316-T02-A 1 4.73E+05
K SWA-L11-1316-T03-A 1 8.50E+05
K SWA-L11-1316-T04-A 1 2.99E+06
K SWA-L11-1316-T01-B 1 3.11E+05
K SWA-L11-1316-T02-B 1 4.82E+05
K SWA-L11-1316-T03-B 1 9.10E+05
K SWA-L11-1316-T04-B 1 2.96E+06
K SWA-L11-1316-T01-C 1 3.20E+05
K SWA-L11-1316-T02-C 1 4.84E+05
K SWA-L11-1316-T03-C 1 9.09E+05
K SWA-L11-1316-T04-C 1 2.91E+06
K SWA-L11-1316-B01-A 1 4.89E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.02E+05 2.5E-01 1.6E+00 5.1E+00
4.73E+05 4.1E-01 1.6E+00 5.1E+00 1000 100
8.50E+05 2.1E+00 1.6E+00 5.1E+00
2.99E+06 7.2E-01 1.6E+00 5.1E+00
3.11E+05 8.9E-01 1.6E+00 5.1E+00
4.82E+05 3.3E+00 1.6E+00 5.1E+00 1000 100
9.10E+05 1.3E+01 1.6E+00 5.1E+00
2.96E+06 7.3E-01 1.6E+00 5.1E+00
3.20E+05 2.6E-01 1.6E+00 5.1E+00
4.84E+05 2.2E+00 1.6E+00 5.1E+00 1000 100
9.09E+05 1.5E+01 1.6E+00 5.1E+00
2.91 E+06 3.2E-01 1.6E+00 5.1E+00
4.89E+01 1.3E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 5:09 PM EPA Interlab L11 1313-1316 SWA
4.74E+05 97% VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
4.83E+05 91%VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
4.85E+05 92% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1531
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se SWA-L11-1316-T01-A 1
Se SWA-L11-1316-T02-A 1
Se SWA-L11-1316-T03-A 1
Se SWA-L11-1316-T04-A 1
Se SWA-L11-1316-T01-B 1
Se SWA-L11-1316-T02-B 1
Se SWA-L11-1316-T03-B 1
Se SWA-L11-1316-T04-B 1
Se SWA-L11-1316-T01-C 1
Se SWA-L11-1316-T02-C 1
Se SWA-L11-1316-T03-C 1
Se SWA-L11-1316-T04-C 1
Se SWA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
7.33E+04
1.44E+05
3.17E+05
6.45E+05
7.67E+04
1.44E+05
3.25E+05
6.34E+05
8.52E+04
1.48E+05
3.04E+05
6.56E+05
7.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.33E+04 5.1E-01 1.5E+01 4.8E+01
1.44E+05 4.2E-01 1.5E+01 4.8E+01 10 100
3.17E+05 2.3E-01 1.5E+01 4.8E+01
6.45E+05 7.6E-01 1.5E+01 4.8E+01
7.67E+04 3.7E-01 1.5E+01 4.8E+01
1.44E+05 4.2E-01 1.5E+01 4.8E+01 10 100
3.25E+05 3.9E-01 1.5E+01 4.8E+01
6.34E+05 2.5E-01 1.5E+01 4.8E+01
8.52E+04 4.4E-01 1.5E+01 4.8E+01
1.48E+05 3.7E-01 1.5E+01 4.8E+01 10 100
3.04E+05 5.9E-01 1.5E+01 4.8E+01
6.56E+05 3.7E-01 1.5E+01 4.8E+01
7.50E+00 5.2E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.45E+05 109% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.45E+05 96% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.49E+05 87% VUICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1532
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-L11-1316-T01-A 1
Si SWA-L11-1316-T02-A 1
Si SWA-L11-1316-T03-A 1
Si SWA-L11-1316-T04-A 1
Si SWA-L11-1316-T01-B 1
Si SWA-L11-1316-T02-B 1
Si SWA-L11-1316-T03-B 1
Si SWA-L11-1316-T04-B 1
Si SWA-L11-1316-T01-C 1
Si SWA-L11-1316-T02-C 1
Si SWA-L11-1316-T03-C 1
Si SWA-L11-1316-T04-C 1
Si SWA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.32E+04
3.24E+04
4.82E+04
7.01 E+04
2.37E+04
3.25E+04
4.91 E+04
6.84E+04
2.32E+04
3.29E+04
4.74E+04
6.78E+04
1.32E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.32E+04 1.3E+00 1.1E+00 3.5E+00
3.24E+04 8.2E-01 1.1E+00 3.5E+00 1000 100
4.82E+04 1.5E+00 1.1E+00 3.5E+00
7.01 E+04 1.1E+00 1.1E+00 3.5E+00
2.37E+04 8.7E-01 1.1E+00 3.5E+00
3.25E+04 8.6E-01 1.1E+00 3.5E+00 1000 100
4.91 E+04 2.4E+00 1.1E+00 3.5E+00
6.84E+04 2.4E+00 1.1E+00 3.5E+00
2.32E+04 1.2E+00 1.1E+00 3.5E+00
3.29E+04 9.2E-01 1.1E+00 3.5E+00 1000 100
4.74E+04 1.4E+00 1.1E+00 3.5E+00
6.78E+04 6.9E-01 1.1E+00 3.5E+00
1.32E+01 2.2E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
3.35E+04 111% VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
3.35E+04 98% VU ICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
3.38E+04 94% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1533
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone.
Na SWA-L11-1316-T01-A 1 4.51 E+05
Na SWA-L11-1316-T02-A 1 5.66E+05
Na SWA-L11-1316-T03-A 1 6.60E+05
Na SWA-L11-1316-T04-A 1 7.01 E+05
Na SWA-L11-1316-T01-B 1 4.60E+05
Na SWA-L11-1316-T02-B 1 5.68E+05
Na SWA-L11-1316-T03-B 1 6.65E+05
Na SWA-L11-1316-T04-B 1 6.92E+05
Na SWA-L11-1316-T01-C 1 4.68E+05
Na SWA-L11-1316-T02-C 1 5.66E+05
Na SWA-L11-1316-T03-C 1 6.68E+05
Na SWA-L11-1316-T04-C 1 7.00E+05
Na SWA-L11-1316-B01-A 1 8.21E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.51 E+05 1.5E-01 2.5E+00 8.0E+00
5.66E+05 6.5E-02 2.5E+00 8.0E+00 1000 100
6.60E+05 8.6E-01 2.5E+00 8.0E+00
7.01E+05 2.6E+00 2.5E+00 8.0E+00
4.60E+05 3.9E-01 2.5E+00 8.0E+00
5.68E+05 2.3E-01 2.5E+00 8.0E+00 1000 100
6.65E+05 5.1E-01 2.5E+00 8.0E+00
6.92E+05 1.7E+00 2.5E+00 8.0E+00
4.68E+05 2.1E-01 2.5E+00 8.0E+00
5.66E+05 7.5E-01 2.5E+00 8.0E+00 1000 100
6.68E+05 2.9E-01 2.5E+00 8.0E+00
7.00E+05 1.8E+00 2.5E+00 8.0E+00
8.21 E+01 7.1E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 5:09 PM EPA Interlab L11 1313-1316 SWA
5.67E+05 90% VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
5.69E+05 87% VU ICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
5.67E+05 91% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1534
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-L11-1316-T01-A 1
SWA-L11-1316-T02-A 1
SWA-L11-1316-T03-A 1
SWA-L11-1316-T04-A 1
SWA-L11-1316-T01-B 1
SWA-L11-1316-T02-B 1
SWA-L11-1316-T03-B 1
SWA-L11-1316-T04-B 1
SWA-L11-1316-T01-C 1
SWA-L11-1316-T02-C 1
SWA-L11-1316-T03-C 1
SWA-L11-1316-T04-C 1
SWA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.76E+02
2.91 E+02
3.24E+02
3.52E+02
3.04E+02
2.91 E+02
3.06E+02
3.42E+02
3.12E+02
2.95E+02
3.10E+02
3.45E+02
1.27E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.76E+02 4.0E-01 1.0E+00 3.2E+00
2.91E+02 4.1E-01 1.0E+00 3.2E+00 1000 100
3.24E+02 6.6E-01 1.0E+00 3.2E+00
3.52E+02 8.1E-01 1.0E+00 3.2E+00
3.04E+02 2.5E-01 1.0E+00 3.2E+00
2.91E+02 6.4E-01 1.0E+00 3.2E+00 1000 100
3.06E+02 1.0E+00 1.0E+00 3.2E+00
3.42E+02 7.0E-01 1.0E+00 3.2E+00
3.12E+02 1.0E+00 1.0E+00 3.2E+00
2.95E+02 7.6E-01 1.0E+00 3.2E+00 1000 100
3.10E+02 1.4E-01 1.0E+00 3.2E+00
3.45E+02 6.4E-01 1.0E+00 3.2E+00
1.27E+00 2.3E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.46E+03 117% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.36E+03 107% VU ICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.36E+03 106% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1535
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
S Sample Dilution
S SWA-L11-1316-T01-A 1
S SWA-L11-1316-T02-A 1
S SWA-L11-1316-T03-A 1
S SWA-L11-1316-T04-A 1
S SWA-L11-1316-T01-B 1
S SWA-L11-1316-T02-B 1
S SWA-L11-1316-T03-B 1
S SWA-L11-1316-T04-B 1
S SWA-L11-1316-T01-C 1
S SWA-L11-1316-T02-C 1
S SWA-L11-1316-T03-C 1
S SWA-L11-1316-T04-C 1
S SWA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
7.30E+05
1.07E+06
1.87E+06
2.55E+06
8.08E+05
1.18E+06
1.84E+06
2.51 E+06
9.01 E+05
1.24E+06
1.77E+06
2.54E+06
1.18E+02
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.30E+05 1.0E+00 6.8E+00 2.2E+01
1.07E+06 1.1E+00 6.8E+00 2.2E+01 1000 100
1.87E+06 4.3E-01 6.8E+00 2.2E+01
2.55E+06 1.0E+00 6.8E+00 2.2E+01
8.08E+05 8.6E-01 6.8E+00 2.2E+01
1.18E+06 1.3E+00 6.8E+00 2.2E+01 1000 100
1.84E+06 7.8E-01 6.8E+00 2.2E+01
2.51 E+06 2.5E-01 6.8E+00 2.2E+01
9.01 E+05 4.5E-01 6.8E+00 2.2E+01
1.24E+06 1.2E+00 6.8E+00 2.2E+01 1000 100
1.77E+06 1.0E+00 6.8E+00 2.2E+01
2.54E+06 7.0E-01 6.8E+00 2.2E+01
1.18E+02 6.5E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.16E+06 91 %VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.27E+06 87% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.34E+06 96% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1536
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Tl Sample Dilution Cone. Qu<
Internal ICP-OES Spike Sol'n
ilifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Tl SWA-L11-1316-T01-A 1 2.30E+00 U1/2 2.30E+00 3.3E+01 4.6E+00 1.5E+01
Tl SWA-L11-1316-T02-A 1 2.30E+00 U1/2 2.30E+00 3.0E+01 4.6E+00 1.5E+01 10 100
Tl SWA-L11-1316-T03-A 1 2.30E+00 U1/2 2.30E+00 1 JE+02 4.6E+00 1.5E+01
Tl SWA-L11-1316-T04-A 1 2.30E+00 U1/2 2.30E+00 6.3E+01 4.6E+00 1.5E+01
Tl SWA-L11-1316-T01-B 1 2.30E+00 U1/2 2.30E+00 6.0E+01 4.6E+00 1.5E+01
Tl SWA-L11-1316-T02-B 1 2.30E+00 U1/2 2.30E+00 3.1E+01 4.6E+00 1.5E+01 10 100
Tl SWA-L11-1316-T03-B 1 2.30E+00 U1/2 2.30E+00 4.3E+01 4.6E+00 1.5E+01
Tl SWA-L11-1316-T04-B 1 2.30E+00 U1/2 2.30E+00 1 .4E+02 4.6E+00 1.5E+01
Tl SWA-L11-1316-T01-C 1 2.30E+00 U1/2 2.30E+00 1 .6E+01 4.6E+00 1.5E+01
Tl SWA-L11-1316-T02-C 1 2.30E+00 U1/2 2.30E+00 6.2E+01 4.6E+00 1.5E+01 10 100
Tl SWA-L11-1316-T03-C 1 2.30E+00 U1/2 2.30E+00 5.2E+01 4.6E+00 1.5E+01
Tl SWA-L11-1316-T04-C 1 2.30E+00 U1/2 2.30E+00 1 .2E+02 4.6E+00 1.5E+01
Tl SWA-L11-1316-B01-A 1 2.30E+00 U1/2 2.30E+00 4.4E+00 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 4/7/11 5:09 PM EPA Interlab L11 1313-1316 SWA
1.14E+03 114% VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.13E+03 112% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.13E+03 113% VUICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1537
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ti Sample Dilution Cone. (
1 1 ug/L
Internal ICP-OES Spike Sol'n
Qualifier Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
Ti SWA-L11-1316-T01-A 1 1.00E+OOU1/2 1.00E+00 1 .6E+01 2.0E+00 6.4E+00
Ti SWA-L11-1316-T02-A 1 1.00E+OOU1/2 1.00E+00 1 .OE+02 2.0E+00 6.4E+00 10 100
Ti SWA-L11-1316-T03-A 1 1.00E+OOU1/2 1.00E+00 9.6E+01 2.0E+00 6.4E+00
Ti SWA-L11-1316-T04-A 1 1.00E+OOU1/2 1.00E+00 4.2E+01 2.0E+00 6.4E+00
Ti SWA-L11-1316-T01-B 1 1.00E+OOU1/2 1.00E+00 1 .5E+01 2.0E+00 6.4E+00
Ti SWA-L11-1316-T02-B 1 1.00E+OOU1/2 1.00E+00 2.4E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L11-1316-T03-B 1 1.00E+OOU1/2 1.00E+00 3.1E+02 2.0E+00 6.4E+00
Ti SWA-L11-1316-T04-B 1 1.00E+OOU1/2 1.00E+00 1 .OE+00 2.0E+00 6.4E+00
Ti SWA-L11-1316-T01-C 1 1.00E+OOU1/2 1.00E+00 3.0E+01 2.0E+00 6.4E+00
Ti SWA-L11-1316-T02-C 1 1.00E+OOU1/2 1.00E+00 4.1E+01 2.0E+00 6.4E+00 10 100
Ti SWA-L11-1316-T03-C 1 1.00E+OOU1/2 1.00E+00 3.2E+01 2.0E+00 6.4E+00
Ti SWA-L11-1316-T04-C 1 1.00E+OOU1/2 1.00E+00 4.5E+00 2.0E+00 6.4E+00
Ti SWA-L11-1316-B01-A 1 1.00E+OOU1/2 1.00E+00 2.7E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
9.30E+02 93% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
9.75E+02 97% VU ICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
9.67E+02 97% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1538
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
V SWA-L11-1316-T01-A 1 2.82E+02
V SWA-L11-1316-T02-A 1 5.07E+02
V SWA-L11-1316-T03-A 1 9.79E+02
V SWA-L11-1316-T04-A 1 1.77E+03
V SWA-L11-1316-T01-B 1 2.67E+02
V SWA-L11-1316-T02-B 1 5.04E+02
V SWA-L11-1316-T03-B 1 9.87E+02
V SWA-L11-1316-T04-B 1 1.60E+03
V SWA-L11-1316-T01-C 1 2.98E+02
V SWA-L11-1316-T02-C 1 5.13E+02
V SWA-L11-1316-T03-C 1 9.39E+02
V SWA-L11-1316-T04-C 1 1.72E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.82E+02 1.2E+00 1.5E+00 4.8E+00
5.07E+02 1.6E+00 1.5E+00 4.8E+00 10 100
9.79E+02 6.9E-01 1.5E+00 4.8E+00
1.77E+03 1.0E+00 1.5E+00 4.8E+00
2.67E+02 4.7E-01 1.5E+00 4.8E+00
5.04E+02 8.7E-01 1.5E+00 4.8E+00 10 100
9.87E+02 1.9E+00 1.5E+00 4.8E+00
1.60E+03 6.7E-01 1.5E+00 4.8E+00
2.98E+02 2.0E+00 1.5E+00 4.8E+00
5.13E+02 1.1E+00 1.5E+00 4.8E+00 10 100
9.39E+02 1.3E+00 1.5E+00 4.8E+00
1.72E+03 2.8E-01 1.5E+00 4.8E+00
V SWA-L11-1316-B01-A 1 2.25E+00 E 2.25E+00 3.7E+01 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.44E+03 94% VU ICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.45E+03 94% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.45E+03 94% VU ICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1539
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-L11-1316-T01-A 1
Zn SWA-L11-1316-T02-A 1
Zn SWA-L11-1316-T03-A 1
Zn SWA-L11-1316-T04-A 1
Zn SWA-L11-1316-T01-B 1
Zn SWA-L11-1316-T02-B 1
Zn SWA-L11-1316-T03-B 1
Zn SWA-L11-1316-T04-B 1
Zn SWA-L11-1316-T01-C 1
Zn SWA-L11-1316-T02-C 1
Zn SWA-L11-1316-T03-C 1
Zn SWA-L11-1316-T04-C 1
Zn SWA-L11-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.54E+00 E
1.77E+00 E
4.16E+00
1.16E+01
1.06E+00 E
1.72E+00 E
3.86E+00
1.04E+01
1.64E+00 E
1.79E+00 E
4.35E+00
1.03E+01
1.67E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+00 6.3E+00 1.0E+00 3.2E+00
1.77E+00 1.3E+01 1.0E+00 3.2E+00 10 100
4.16E+00 9.1E+00 1.0E+00 3.2E+00
1.16E+01 6.6E+00 1.0E+00 3.2E+00
1.06E+00 6.8E+00 1.0E+00 3.2E+00
1.72E+00 1.1E+01 1.0E+00 3.2E+00 10 100
3.86E+00 6.2E+00 1.0E+00 3.2E+00
1.04E+01 3.2E+00 1.0E+00 3.2E+00
1.64E+00 3.5E+01 1.0E+00 3.2E+00
1.79E+00 1.3E+01 1.0E+00 3.2E+00 10 100
4.35E+00 1.2E+00 1.0E+00 3.2E+00
1.03E+01 2.5E+00 1.0E+00 3.2E+00
1.67E+00 1.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/7/11 5:09 PM EPA InterlabLH 1313-1316 SWA
1.17E+03 116% VUICP-OES 4/7/11 5:11 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:12 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:14 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:15 PM EPA Interlab L11 1313-1316 SWA
1.11E+03 111% VUICP-OES 4/7/11 5:17 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:19 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:20 PM EPA Interlab L11 1313-1316 SWA
VU ICP-OES 4/7/11 5:22 PM EPA Interlab L11 1313-1316 SWA
1.11E+03 111% VUICP-OES 4/7/11 5:24 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:25 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:27 PM EPA Interlab L11 1313-1316 SWA
VUICP-OES 4/7/11 5:04 PM EPA Interlab L11 1313-1316 SWA
                                                                                                                                                                         1-1540
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al SWA-LRef-1316-T01-A 1
Al SWA-LRef-1316-T02-A 1
Al SWA-LRef-1316-T03-A 1
Al SWA-LRef-1316-T04-A 1
Al SWA-LRef-1316-T01-B 1
Al SWA-LRef-1316-T02-B 1
Al SWA-LRef-1316-T03-B 1
Al SWA-LRef-1316-T04-B 1
Al SWA-LRef-1316-T01-C 1
Al SWA-LRef-1316-T02-C 1
Al SWA-LRef-1316-T03-C 1
Al SWA-LRef-1316-T04-C 1
Al SWA-LRef-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
3.48E+04
5.32E+04
1.00E+05
1.55E+05
3.30E+04
5.02E+04
9.49E+04
1.65E+05
2.21E+04
5.30E+04
1.01E+05
1.66E+05
2.31 E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.48E+04 6.2E-01 1.0E+00 3.2E+00
5.32E+04 3.4E-01 1.0E+00 3.2E+00 1000 100
1.00E+05 8.2E-01 1.0E+00 3.2E+00
1.55E+05 3.4E-01 1.0E+00 3.2E+00
3.30E+04 3.4E-01 1.0E+00 3.2E+00
5.02E+04 3.5E+00 1.0E+00 3.2E+00
9.49E+04 5.3E-01 1.0E+00 3.2E+00
1.65E+05 1.3E+00 1.0E+00 3.2E+00
2.21 E+04 6.7E+01 1.0E+00 3.2E+00
5.30E+04 4.1 E+00 1.0E+00 3.2E+00
1.01E+05 5.5E+00 1.0E+00 3.2E+00
1.66E+05 4.4E+00 1.0E+00 3.2E+00
2.31 E+00 6.3E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
5.42E+04 103% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                                 1-1541
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-LRef-1316-T01-A 1
Sb SWA-LRef-1316-T02-A 1
Sb SWA-LRef-1316-T03-A 1
Sb SWA-LRef-1316-T04-A 1
Sb SWA-LRef-1316-T01-B 1
Sb SWA-LRef-1316-T02-B 1
Sb SWA-LRef-1316-T03-B 1
Sb SWA-LRef-1316-T04-B 1
Sb SWA-LRef-1316-T01-C 1
Sb SWA-LRef-1316-T02-C 1
Sb SWA-LRef-1316-T03-C 1
Sb SWA-LRef-1316-T04-C 1
Sb SWA-LRef-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
5.24E+03
6.09E+03
6.33E+03
5.85E+03
4.67E+03
5.52E+03
6.43E+03
7.49E+03
4.39E+03
5.88E+03
7.26E+03
7.10E+03
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.24E+03 9.3E-01 7.5E+00 2.4E+01
6.09E+03 6.0E-01 7.5E+00 2.4E+01 10 100
6.33E+03 1.3E+00 7.5E+00 2.4E+01
5.85E+03 1.2E+00 7.5E+00 2.4E+01
4.67E+03 5.1E-01 7.5E+00 2.4E+01
5.52E+03 3.3E+00 7.5E+00 2.4E+01
6.43E+03 4.8E-01 7.5E+00 2.4E+01
7.49E+03 9.7E-01 7.5E+00 2.4E+01
4.39E+03 7.1E+01 7.5E+00 2.4E+01
5.88E+03 4.6E+00 7.5E+00 2.4E+01
7.26E+03 5.9E+00 7.5E+00 2.4E+01
7.10E+03 4.0E+00 7.5E+00 2.4E+01
3.75E+00 4.9E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
7.12E+03 104% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1542
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-LRef-1316-T01-A 1
As SWA-LRef-1316-T02-A 1
As SWA-LRef-1316-T03-A 1
As SWA-LRef-1316-T04-A 1
As SWA-LRef-1316-T01-B 1
As SWA-LRef-1316-T02-B 1
As SWA-LRef-1316-T03-B 1
As SWA-LRef-1316-T04-B 1
As SWA-LRef-1316-T01-C 1
As SWA-LRef-1316-T02-C 1
As SWA-LRef-1316-T03-C 1
As SWA-LRef-1316-T04-C 1
As SWA-LRef-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
4.43E+03
1.27E+04
4.19E+04
1.17E+05
4.18E+03
1.19E+04
4.54E+04
1.23E+05
4.04E+03
1.09E+04
4.28E+04
1.07E+05
5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.43E+03 6.9E-01 1.1E+01 3.5E+01
1.27E+04 2.6E-01 1.1E+01 3.5E+01 10 100
4.19E+04 6.7E-01 1.1E+01 3.5E+01
1.17E+05 7.4E-01 1.1E+01 3.5E+01
4.18E+03 5.8E-01 1.1E+01 3.5E+01
1.19E+04 3.7E+00 1.1E+01 3.5E+01
4.54E+04 4.1E-01 1.1E+01 3.5E+01
1.23E+05 9.4E-01 1.1E+01 3.5E+01
4.04E+03 7.0E+01 1.1E+01 3.5E+01
1.09E+04 4.4E+00 1.1E+01 3.5E+01
4.28E+04 6.7E+00 1.1E+01 3.5E+01
1.07E+05 4.5E+00 1.1E+01 3.5E+01
5.50E+00 1.6E+02 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.37E+04 100% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1543
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-LRef-1316-T01-A 1
B SWA-LRef-1316-T02-A 1
B SWA-LRef-1316-T03-A 1
B SWA-LRef-1316-T04-A 1
B SWA-LRef-1316-T01-B 1
B SWA-LRef-1316-T02-B 1
B SWA-LRef-1316-T03-B 1
B SWA-LRef-1316-T04-B 1
B SWA-LRef-1316-T01-C 1
B SWA-LRef-1316-T02-C 1
B SWA-LRef-1316-T03-C 1
B SWA-LRef-1316-T04-C 1
B SWA-LRef-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.02E+03
9.04E+02
6.95E+02
7.46E+02
1.03E+03
9.12E+02
6.25E+02
7.10E+02
1.10E+03
9.17E+02
6.68E+02
7.41 E+02
9.35E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.02E+03 2.5E-01 1.0E+00 3.2E+00
9.04E+02 6.4E-01 1.0E+00 3.2E+00 1000 100
6.95E+02 5.4E-01 1.0E+00 3.2E+00
7.46E+02 8.2E-01 1.0E+00 3.2E+00
1.03E+03 7.7E-01 1.0E+00 3.2E+00
9.12E+02 4.1E+00 1.0E+00 3.2E+00
6.25E+02 1.0E+00 1.0E+00 3.2E+00
7.10E+02 8.6E-01 1.0E+00 3.2E+00
1.10E+03 7.0E+01 1.0E+00 3.2E+00
9.17E+02 4.8E+00 1.0E+00 3.2E+00
6.68E+02 7.0E+00 1.0E+00 3.2E+00
7.41 E+02 4.3E+00 1.0E+00 3.2E+00
9.35E+00 3.3E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.80E+03 89% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1544
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba SWA-LRef-1316-T01-A 1
Ba SWA-LRef-1316-T02-A 1
Ba SWA-LRef-1316-T03-A 1
Ba SWA-LRef-1316-T04-A 1
Ba SWA-LRef-1316-T01-B 1
Ba SWA-LRef-1316-T02-B 1
Ba SWA-LRef-1316-T03-B 1
Ba SWA-LRef-1316-T04-B 1
Ba SWA-LRef-1316-T01-C 1
Ba SWA-LRef-1316-T02-C 1
Ba SWA-LRef-1316-T03-C 1
Ba SWA-LRef-1316-T04-C 1
Ba SWA-LRef-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.72E+02
1.49E+02
1.27E+02
1.67E+02
1.59E+02
1.40E+02
1.39E+02
1.29E+02
1.16E+02
1.51E+02
1.50E+02
1.24E+02
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.72E+02 3.1E-01 1.0E+00 3.2E+00
1.49E+02 5.3E-01 1.0E+00 3.2E+00 10 100
1.27E+02 1.5E+00 1.0E+00 3.2E+00
1.67E+02 2.1E+00 1.0E+00 3.2E+00
1.59E+02 1.8E-01 1.0E+00 3.2E+00
1.40E+02 4.0E+00 1.0E+00 3.2E+00
1.39E+02 4.2E+00 1.0E+00 3.2E+00
1.29E+02 5.6E-01 1.0E+00 3.2E+00
1.16E+02 6.8E+01 1.0E+00 3.2E+00
1.51E+02 3.5E+00 1.0E+00 3.2E+00
1.50E+02 5.8E+00 1.0E+00 3.2E+00
1.24E+02 7.7E+00 1.0E+00 3.2E+00
5.00E-01 3.0E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.00E+03 85% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1545
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-LRef-1316-T01-A 1
Be SWA-LRef-1316-T02-A 1
Be SWA-LRef-1316-T03-A 1
Be SWA-LRef-1316-T04-A 1
Be SWA-LRef-1316-T01-B 1
Be SWA-LRef-1316-T02-B 1
Be SWA-LRef-1316-T03-B 1
Be SWA-LRef-1316-T04-B 1
Be SWA-LRef-1316-T01-C 1
Be SWA-LRef-1316-T02-C 1
Be SWA-LRef-1316-T03-C 1
Be SWA-LRef-1316-T04-C 1
Be SWA-LRef-1316-B01-A 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 5.4E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+01 1.9E+00 6.0E+00 10 100
9.50E-01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 6.4E+01 1.9E+00 6.0E+00
9.50E-01 7.0E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
9.50E-01 6.4E+01 1.9E+00 6.0E+00
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 6.2E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
9.50E-01 8.5E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.12E+03 112% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1546
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd SWA-LRef-1316-T01-A 1
Cd SWA-LRef-1316-T02-A 1
Cd SWA-LRef-1316-T03-A 1
Cd SWA-LRef-1316-T04-A 1
Cd SWA-LRef-1316-T01-B 1
Cd SWA-LRef-1316-T02-B 1
Cd SWA-LRef-1316-T03-B 1
Cd SWA-LRef-1316-T04-B 1
Cd SWA-LRef-1316-T01-C 1
Cd SWA-LRef-1316-T02-C 1
Cd SWA-LRef-1316-T03-C 1
Cd SWA-LRef-1316-T04-C 1
Cd SWA-LRef-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 2.0E+02 2.2E+00 7.0E+00
1.10E+00 1.8E+02 2.2E+00 7.0E+00 10 100
1.10E+00 2.7E+02 2.2E+00 7.0E+00
1.10E+00 5.6E+01 2.2E+00 7.0E+00
1.10E+00 7.1E+01 2.2E+00 7.0E+00
1.10E+00 4.9E+01 2.2E+00 7.0E+00
1.10E+00 1.9E+02 2.2E+00 7.0E+00
1.10E+00 8.4E+01 2.2E+00 7.0E+00
1.10E+00 5.6E+01 2.2E+00 7.0E+00
1.10E+00 1.4E+02 2.2E+00 7.0E+00
1.10E+00 7.0E+01 2.2E+00 7.0E+00
1.10E+00 3.3E+02 2.2E+00 7.0E+00
1.10E+00 1.5E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.02E+03 102% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1547
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qu
1 1 ug/L
Ca SWA-LRef-1316-T01-A 1 1.58E+04
Ca SWA-LRef-1316-T02-A 1 1.11E+04
Ca SWA-LRef-1316-T03-A 1 5.76E+03
Ca SWA-LRef-1316-T04-A 1 6.61 E+03
Ca SWA-LRef-1316-T01-B 1 1.48E+04
Ca SWA-LRef-1316-T02-B 1 1.11E+04
Ca SWA-LRef-1316-T03-B 1 5.91 E+03
Ca SWA-LRef-1316-T04-B 1 5.07E+03
Ca SWA-LRef-1316-T01-C 1 1.01E+04
Ca SWA-LRef-1316-T02-C 1 9.83E+03
Ca SWA-LRef-1316-T03-C 1 6.67E+03
Ca SWA-LRef-1316-T04-C 1 4.88E+03
Ca SWA-LRef-1316-B01-A 1 5.03E+01
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.58E+04 6.5E-01 2.6E+00 8.3E+00
1.11E+04 3.8E-01 2.6E+00 8.3E+00 1000 100
5.76E+03 3.0E+00 2.6E+00 8.3E+00
6.61 E+03 5.1E-01 2.6E+00 8.3E+00
1.48E+04 5.2E-01 2.6E+00 8.3E+00
1.11E+04 4.0E+00 2.6E+00 8.3E+00
5.91 E+03 2.6E+00 2.6E+00 8.3E+00
5.07E+03 2.5E+00 2.6E+00 8.3E+00
1.01E+04 7.0E+01 2.6E+00 8.3E+00
9.83E+03 4.8E+00 2.6E+00 8.3E+00
6.67E+03 8.3E+00 2.6E+00 8.3E+00
4.88E+03 8.1E+00 2.6E+00 8.3E+00
5.03E+01 2.9E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.20E+04 86% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1548
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cr Sample Dilution
Cr SWA-LRef-1316-T01-A 1
Cr SWA-LRef-1316-T02-A 1
Cr SWA-LRef-1316-T03-A 1
Cr SWA-LRef-1316-T04-A 1
Cr SWA-LRef-1316-T01-B 1
Cr SWA-LRef-1316-T02-B 1
Cr SWA-LRef-1316-T03-B 1
Cr SWA-LRef-1316-T04-B 1
Cr SWA-LRef-1316-T01-C 1
Cr SWA-LRef-1316-T02-C 1
Cr SWA-LRef-1316-T03-C 1
Cr SWA-LRef-1316-T04-C 1
Cr SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.14E+03
1.82E+03
3.02E+03
2.61 E+03
1.17E+03
1.80E+03
2.44E+03
2.96E+03
1.17E+03
1.61 E+03
2.35E+03
2.74E+03
6.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.14E+03 1.1E+00 1.2E+00 3.8E+00
1.82E+03 4.0E-01 1.2E+00 3.8E+00 10 100
3.02E+03 2.9E-01 1.2E+00 3.8E+00
2.61 E+03 6.5E-01 1.2E+00 3.8E+00
1.17E+03 3.5E-01 1.2E+00 3.8E+00
1.80E+03 4.0E+00 1.2E+00 3.8E+00
2.44E+03 2.0E+00 1.2E+00 3.8E+00
2.96E+03 1.1E+00 1.2E+00 3.8E+00
1.17E+03 6.5E+01 1.2E+00 3.8E+00
1.61 E+03 4.6E+00 1.2E+00 3.8E+00
2.35E+03 9.5E+00 1.2E+00 3.8E+00
2.74E+03 1.0E+01 1.2E+00 3.8E+00
6.00E-01 7.1E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
2.67E+03 86% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1549
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co SWA-LRef-1316-T01-A 1
Co SWA-LRef-1316-T02-A 1
Co SWA-LRef-1316-T03-A 1
Co SWA-LRef-1316-T04-A 1
Co SWA-LRef-1316-T01-B 1
Co SWA-LRef-1316-T02-B 1
Co SWA-LRef-1316-T03-B 1
Co SWA-LRef-1316-T04-B 1
Co SWA-LRef-1316-T01-C 1
Co SWA-LRef-1316-T02-C 1
Co SWA-LRef-1316-T03-C 1
Co SWA-LRef-1316-T04-C 1
Co SWA-LRef-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
2.16E+00 E
3.41 E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
3.48E+00 E
5.50E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
2.27E+00 E
4.66E+00 E
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.4E+02 1.8E+00 5.7E+00
9.00E-01 8.2E+01 1.8E+00 5.7E+00 10 100
2.16E+00 4.8E+00 1.8E+00 5.7E+00
3.41E+00 2.9E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
9.00E-01 3.1E+01 1.8E+00 5.7E+00
3.48E+00 2.2E+01 1.8E+00 5.7E+00
5.50E+00 3.0E+01 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
9.00E-01 1.1E+02 1.8E+00 5.7E+00
2.27E+00 3.3E+01 1.8E+00 5.7E+00
4.66E+00 7.3E+00 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.03E+03 103% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1550
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu SWA-LRef-1316-T01-A 1
Cu SWA-LRef-1316-T02-A 1
Cu SWA-LRef-1316-T03-A 1
Cu SWA-LRef-1316-T04-A 1
Cu SWA-LRef-1316-T01-B 1
Cu SWA-LRef-1316-T02-B 1
Cu SWA-LRef-1316-T03-B 1
Cu SWA-LRef-1316-T04-B 1
Cu SWA-LRef-1316-T01-C 1
Cu SWA-LRef-1316-T02-C 1
Cu SWA-LRef-1316-T03-C 1
Cu SWA-LRef-1316-T04-C 1
Cu SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.85E+00 U1/2
5.18E+00 E
1.98E+01
4.82E+01
1.85E+00 U1/2
4.07E+00 E
1.57E+01
4.64E+01
1.85E+00 U1/2
4.40E+00 E
1.62E+01
5.05E+01
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 2.6E+02 3.7E+00 1.2E+01
5.18E+00 1.8E+01 3.7E+00 1.2E+01 10 100
1.98E+01 2.6E+00 3.7E+00 1 .2E+01
4.82E+01 7.1E+00 3.7E+00 1 .2E+01
1.85E+00 7.1E+00 3.7E+00 1 .2E+01
4.07E+00 2.7E+01 3.7E+00 1 .2E+01
1.57E+01 1.0E+01 3.7E+00 1 .2E+01
4.64E+01 8.3E+00 3.7E+00 1.2E+01
1.85E+00 1.3E+03 3.7E+00 1 .2E+01
4.40E+00 6.2E+01 3.7E+00 1 .2E+01
1.62E+01 8.1E+00 3.7E+00 1 .2E+01
5.05E+01 4.4E+00 3.7E+00 1 .2E+01
1.85E+00 3.7E+03 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.02E+03 101% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1551
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe SWA-LRef-1316-T01-A 1
Fe SWA-LRef-1316-T02-A 1
Fe SWA-LRef-1316-T03-A 1
Fe SWA-LRef-1316-T04-A 1
Fe SWA-LRef-1316-T01-B 1
Fe SWA-LRef-1316-T02-B 1
Fe SWA-LRef-1316-T03-B 1
Fe SWA-LRef-1316-T04-B 1
Fe SWA-LRef-1316-T01-C 1
Fe SWA-LRef-1316-T02-C 1
Fe SWA-LRef-1316-T03-C 1
Fe SWA-LRef-1316-T04-C 1
Fe SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
8.37E+01
1.81E+02
5.72E+02
1.21E+03
8.80E+01
1.77E+02
5.32E+02
1.32E+03
4.81E+01
1.47E+02
5.00E+02
1.16E+03
1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.37E+01 2.1E-01 2.0E+00 6.4E+00
1.81E+02 7.7E-01 2.0E+00 6.4E+00 1000 100
5.72E+02 1.6E+00 2.0E+00 6.4E+00
1.21E+03 1.0E+00 2.0E+00 6.4E+00
8.80E+01 2.7E-01 2.0E+00 6.4E+00
1.77E+02 4.8E+00 2.0E+00 6.4E+00
5.32E+02 9.8E-01 2.0E+00 6.4E+00
1.32E+03 1.3E+00 2.0E+00 6.4E+00
4.81 E+01 7.2E+01 2.0E+00 6.4E+00
1.47E+02 5.2E+00 2.0E+00 6.4E+00
5.00E+02 6.9E+00 2.0E+00 6.4E+00
1.16E+03 5.1E+00 2.0E+00 6.4E+00
1.00E+00 3.7E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.23E+03 105% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1552
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone.
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
Pb SWA-LRef-1316-T01-A 1 1.00E+01 E 1.00E+01 2.0E+01 6.8E+00 2.2E+01
Pb SWA-LRef-1316-T02-A 1 2.95E+01
Pb SWA-LRef-1316-T03-A 1 6.57E+01
Pb SWA-LRef-1316-T04-A 1 1.46E+02
2.95E+01 2.1E+01 6.8E+00 2.2E+01 10 100
6.57E+01 1.1E+00 6.8E+00 2.2E+01
1.46E+02 2.2E+00 6.8E+00 2.2E+01
Pb SWA-LRef-1316-T01-B 1 9.23E+00 E 9.23E+00 1 JE+01 6.8E+00 2.2E+01
Pb SWA-LRef-1316-T02-B 1 2.30E+01
Pb SWA-LRef-1316-T03-B 1 5.47E+01
Pb SWA-LRef-1316-T04-B 1 1.42E+02
2.30E+01 1.2E+01 6.8E+00 2.2E+01
5.47E+01 9.9E+00 6.8E+00 2.2E+01
1.42E+02 5.2E+00 6.8E+00 2.2E+01
Pb SWA-LRef-1316-T01-C 1 6.88E+00 E 6.88E+00 1 .6E+02 6.8E+00 2.2E+01
Pb SWA-LRef-1316-T02-C 1 2.92E+01
Pb SWA-LRef-1316-T03-C 1 6.87E+01
Pb SWA-LRef-1316-T04-C 1 1.51E+02
2.92E+01 4.6E+01 6.8E+00 2.2E+01
6.87E+01 1.0E+01 6.8E+00 2.2E+01
1.51E+02 4.6E+00 6.8E+00 2.2E+01
Pb SWA-LRef-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 2.1E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.04E+03 101% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1553
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li SWA-LRef-1316-T01-A 1
Li SWA-LRef-1316-T02-A 1
Li SWA-LRef-1316-T03-A 1
Li SWA-LRef-1316-T04-A 1
Li SWA-LRef-1316-T01-B 1
Li SWA-LRef-1316-T02-B 1
Li SWA-LRef-1316-T03-B 1
Li SWA-LRef-1316-T04-B 1
Li SWA-LRef-1316-T01-C 1
Li SWA-LRef-1316-T02-C 1
Li SWA-LRef-1316-T03-C 1
Li SWA-LRef-1316-T04-C 1
Li SWA-LRef-1316-B01-A 1
Sample
Cone. Qualifier
ug/L
1.94E+00 E
3.64E+00 E
8.04E+00
1.15E+01
2.24E+00 E
3.40E+00 E
8.29E+00
9.65E+00
2.00E+00 E
3.82E+00 E
8.44E+00
1.08E+01
9.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.94E+00 6.5E+00 1.9E+00 6.0E+00
3.64E+00 1.4E+01 1.9E+00 6.0E+00 10 100
8.04E+00 7.0E+00 1.9E+00 6.0E+00
1.15E+01 1.7E+01 1.9E+00 6.0E+00
2.24E+00 6.3E+00 1.9E+00 6.0E+00
3.40E+00 2.0E+01 1.9E+00 6.0E+00
8.29E+00 9.3E+00 1.9E+00 6.0E+00
9.65E+00 1.3E+01 1.9E+00 6.0E+00
2.00E+00 1.1E+01 1.9E+00 6.0E+00
3.82E+00 2.2E+01 1.9E+00 6.0E+00
8.44E+00 2.3E+01 1.9E+00 6.0E+00
1.08E+01 1.6E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
8.61E+02 86% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1554
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn SWA-LRef-1316-T01-A 1
Mn SWA-LRef-1316-T02-A 1
Mn SWA-LRef-1316-T03-A 1
Mn SWA-LRef-1316-T04-A 1
Mn SWA-LRef-1316-T01-B 1
Mn SWA-LRef-1316-T02-B 1
Mn SWA-LRef-1316-T03-B 1
Mn SWA-LRef-1316-T04-B 1
Mn SWA-LRef-1316-T01-C 1
Mn SWA-LRef-1316-T02-C 1
Mn SWA-LRef-1316-T03-C 1
Mn SWA-LRef-1316-T04-C 1
Mn SWA-LRef-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
2.17E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.11E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.41 E+00 E
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.7E+00 2.0E+00 6.4E+00
1.00E+00 2.6E+00 2.0E+00 6.4E+00 10 100
1.00E+00 4.8E+00 2.0E+00 6.4E+00
2.17E+00 3.8E+00 2.0E+00 6.4E+00
1.00E+00 4.9E+00 2.0E+00 6.4E+00
1.00E+00 8.4E+00 2.0E+00 6.4E+00
1.00E+00 8.0E+00 2.0E+00 6.4E+00
4.11 E+00 6.1E-01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
3.41 E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.01E+03 101% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1555
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg SWA-LRef-1316-T01-A 1
Mg SWA-LRef-1316-T02-A 1
Mg SWA-LRef-1316-T03-A 1
Mg SWA-LRef-1316-T04-A 1
Mg SWA-LRef-1316-T01-B 1
Mg SWA-LRef-1316-T02-B 1
Mg SWA-LRef-1316-T03-B 1
Mg SWA-LRef-1316-T04-B 1
Mg SWA-LRef-1316-T01-C 1
Mg SWA-LRef-1316-T02-C 1
Mg SWA-LRef-1316-T03-C 1
Mg SWA-LRef-1316-T04-C 1
Mg SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
6.75E+00
6.38E+00
5.00E-01 U1/2
5.00E-01 U1/2
1.46E+01
1.04E+01
5.00E-01 U1/2
5.00E-01 U1/2
4.72E+00
5.98E+00
1.68E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 6.2E+01 1.0E+00 3.2E+00
5.00E-01 4.6E+01 1.0E+00 3.2E+00 1000 100
6.75E+00 1.4E+02 1.0E+00 3.2E+00
6.38E+00 2.6E+03 1.0E+00 3.2E+00
5.00E-01 1.0E+02 1.0E+00 3.2E+00
5.00E-01 5.1E+01 1.0E+00 3.2E+00
1.46E+01 9.2E+01 1.0E+00 3.2E+00
1.04E+01 8.4E+01 1.0E+00 3.2E+00
5.00E-01 1.5E+02 1.0E+00 3.2E+00
5.00E-01 1.3E+03 1.0E+00 3.2E+00
4.72E+00 2.5E+02 1.0E+00 3.2E+00
5.98E+00 1.4E+02 1.0E+00 3.2E+00
1.68E+01 6.8E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.03E+03 103% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1556
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mo Sample Dilution
Mo SWA-LRef-1316-T01-A 1
Mo SWA-LRef-1316-T02-A 1
Mo SWA-LRef-1316-T03-A 1
Mo SWA-LRef-1316-T04-A 1
Mo SWA-LRef-1316-T01-B 1
Mo SWA-LRef-1316-T02-B 1
Mo SWA-LRef-1316-T03-B 1
Mo SWA-LRef-1316-T04-B 1
Mo SWA-LRef-1316-T01-C 1
Mo SWA-LRef-1316-T02-C 1
Mo SWA-LRef-1316-T03-C 1
Mo SWA-LRef-1316-T04-C 1
Mo SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
1.42E+02
2.67E+02
6.69E+02
1.30E+03
1.37E+02
2.53E+02
6.10E+02
1.28E+03
1.35E+02
2.45E+02
5.86E+02
1.17E+03
1.37E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.42E+02 7.0E-01 1.2E+00 3.8E+00
2.67E+02 5.9E-01 1.2E+00 3.8E+00 10 100
6.69E+02 4.8E-01 1.2E+00 3.8E+00
1.30E+03 3.6E-02 1.2E+00 3.8E+00
1.37E+02 9.0E-01 1.2E+00 3.8E+00
2.53E+02 4.1E+00 1.2E+00 3.8E+00
6.10E+02 8.2E-01 1.2E+00 3.8E+00
1.28E+03 7.8E-01 1.2E+00 3.8E+00
1.35E+02 6.8E+01 1.2E+00 3.8E+00
2.45E+02 4.1E+00 1.2E+00 3.8E+00
5.86E+02 5.3E+00 1.2E+00 3.8E+00
1.17E+03 4.8E+00 1.2E+00 3.8E+00
1.37E+00 8.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.31E+03 105% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1557
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni SWA-LRef-1316-T01-A 1
Ni SWA-LRef-1316-T02-A 1
Ni SWA-LRef-1316-T03-A 1
Ni SWA-LRef-1316-T04-A 1
Ni SWA-LRef-1316-T01-B 1
Ni SWA-LRef-1316-T02-B 1
Ni SWA-LRef-1316-T03-B 1
Ni SWA-LRef-1316-T04-B 1
Ni SWA-LRef-1316-T01-C 1
Ni SWA-LRef-1316-T02-C 1
Ni SWA-LRef-1316-T03-C 1
Ni SWA-LRef-1316-T04-C 1
Ni SWA-LRef-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
2.23E+00 E
5.43E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
2.04E+00 E
6.06E+00
9.00E-01 U1/2
9.00E-01 U1/2
2.33E+00 E
5.31 E+00 E
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 7.3E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00 10 100
2.23E+00 5.5E+00 1.8E+00 5.7E+00
5.43E+00 6.5E+01 1.8E+00 5.7E+00
9.00E-01 3.4E+02 1.8E+00 5.7E+00
9.00E-01 6.4E+01 1.8E+00 5.7E+00
2.04E+00 1.7E+02 1.8E+00 5.7E+00
6.06E+00 2.0E+01 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 7.2E+02 1.8E+00 5.7E+00
2.33E+00 4.3E+01 1.8E+00 5.7E+00
5.31E+00 2.6E+01 1.8E+00 5.7E+00
9.00E-01 7.2E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.03E+03 103% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1558
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone.
1 ug/L
P SWA-LRef-1316-T01-A 1 2.68E+01
P SWA-LRef-1316-T02-A 1 1.04E+02
P SWA-LRef-1316-T03-A 1 3.27E+02
P SWA-LRef-1316-T04-A 1 1.03E+03
P SWA-LRef-1316-T01-B 1 2.22E+01
P SWA-LRef-1316-T02-B 1 9.18E+01
P SWA-LRef-1316-T03-B 1 4.36E+02
P SWA-LRef-1316-T04-B 1 1.50E+03
P SWA-LRef-1316-T01-C 1 2.02E+01
P SWA-LRef-1316-T02-C 1 8.35E+01
P SWA-LRef-1316-T03-C 1 3.58E+02
P SWA-LRef-1316-T04-C 1 1.26E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.68E+01 1.6E+01 3.7E+00 1.2E+01
1.04E+02 9.4E+00 3.7E+00 1.2E+01 1000 100
3.27E+02 6.9E-01 3.7E+00 1.2E+01
1.03E+03 4.2E+00 3.7E+00 1.2E+01
2.22E+01 1.7E+01 3.7E+00 1.2E+01
9.18E+01 4.0E+00 3.7E+00 1.2E+01
4.36E+02 1.6E+00 3.7E+00 1.2E+01
1.50E+03 1.6E+00 3.7E+00 1.2E+01
2.02E+01 9.7E+01 3.7E+00 1.2E+01
8.35E+01 4.1E+00 3.7E+00 1 .2E+01
3.58E+02 4.8E+00 3.7E+00 1 .2E+01
1.26E+03 5.1E+00 3.7E+00 1 .2E+01
P SWA-LRef-1316-B01-A 1 2.18E+00 U1/2 2.18E+00 4.2E+01 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.18E+03 107% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1559
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
K Sample Dilution
K SWA-LRef-1316-T01-A 1
K SWA-LRef-1316-T02-A 1
K SWA-LRef-1316-T03-A 1
K SWA-LRef-1316-T04-A 1
K SWA-LRef-1316-T01-B 1
K SWA-LRef-1316-T02-B 1
K SWA-LRef-1316-T03-B 1
K SWA-LRef-1316-T04-B 1
K SWA-LRef-1316-T01-C 1
K SWA-LRef-1316-T02-C 1
K SWA-LRef-1316-T03-C 1
K SWA-LRef-1316-T04-C 1
K SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.72E+05
4.33E+05
1.75E+06
1.83E+06
2.63E+05
4.16E+05
1.89E+06
2.02E+06
2.64E+05
4.20E+05
1.85E+06
1.91E+06
2.81E+01
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.72E+05 1.3E+00 1.6E+00 5.1E+00
4.33E+05 4.6E-01 1.6E+00 5.1E+00 1000 100
1.75E+06 8.1E-01 1.6E+00 5.1E+00
1.83E+06 4.6E-01 1.6E+00 5.1E+00
2.63E+05 2.0E+00 1.6E+00 5.1E+00
4.16E+05 4.6E+00 1.6E+00 5.1E+00
1.89E+06 6.0E-01 1.6E+00 5.1E+00
2.02E+06 4.8E-01 1.6E+00 5.1E+00
2.64E+05 6.8E+01 1.6E+00 5.1E+00
4.20E+05 6.9E+00 1.6E+00 5.1E+00
1.85E+06 2.9E+00 1.6E+00 5.1E+00
1.91E+06 3.3E+00 1.6E+00 5.1E+00
2.81 E+01 5.0E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
4.34E+05 92% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1560
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Se Sample Dilution
Se SWA-LRef-1316-T01-A 1
Se SWA-LRef-1316-T02-A 1
Se SWA-LRef-1316-T03-A 1
Se SWA-LRef-1316-T04-A 1
Se SWA-LRef-1316-T01-B 1
Se SWA-LRef-1316-T02-B 1
Se SWA-LRef-1316-T03-B 1
Se SWA-LRef-1316-T04-B 1
Se SWA-LRef-1316-T01-C 1
Se SWA-LRef-1316-T02-C 1
Se SWA-LRef-1316-T03-C 1
Se SWA-LRef-1316-T04-C 1
Se SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
9.41 E+04
1.79E+05
4.22E+05
7.65E+05
9.00E+04
1.67E+05
4.55E+05
8.58E+05
9.57E+04
1.69E+05
4.06E+05
7.94E+05
7.50E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.41 E+04 5.6E-01 1.5E+01 4.8E+01
1.79E+05 3.9E-01 1.5E+01 4.8E+01 10 100
4.22E+05 7.1E-01 1.5E+01 4.8E+01
7.65E+05 1.5E-01 1.5E+01 4.8E+01
9.00E+04 3.0E-01 1.5E+01 4.8E+01
1.67E+05 4.3E+00 1.5E+01 4.8E+01
4.55E+05 9.6E-01 1.5E+01 4.8E+01
8.58E+05 7.2E-01 1.5E+01 4.8E+01
9.57E+04 7.0E+01 1.5E+01 4.8E+01
1.69E+05 4.1E+00 1.5E+01 4.8E+01
4.06E+05 5.4E+00 1.5E+01 4.8E+01
7.94E+05 4.5E+00 1.5E+01 4.8E+01
7.50E+00 7.7E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.80E+05 95% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1561
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-LRef-1316-T01-A 1
Si SWA-LRef-1316-T02-A 1
Si SWA-LRef-1316-T03-A 1
Si SWA-LRef-1316-T04-A 1
Si SWA-LRef-1316-T01-B 1
Si SWA-LRef-1316-T02-B 1
Si SWA-LRef-1316-T03-B 1
Si SWA-LRef-1316-T04-B 1
Si SWA-LRef-1316-T01-C 1
Si SWA-LRef-1316-T02-C 1
Si SWA-LRef-1316-T03-C 1
Si SWA-LRef-1316-T04-C 1
Si SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
2.30E+04
3.07E+04
3.97E+04
6.13E+04
2.12E+04
3.07E+04
4.42E+04
6.32E+04
2.30E+04
2.95E+04
4.17E+04
6.04E+04
5.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+04 4.7E-01 1.1E+00 3.5E+00
3.07E+04 1.1E+00 1.1E+00 3.5E+00 1000 100
3.97E+04 2.8E-01 1.1E+00 3.5E+00
6.13E+04 1.6E+00 1.1E+00 3.5E+00
2.12E+04 1.8E-01 1.1E+00 3.5E+00
3.07E+04 3.7E+00 1.1E+00 3.5E+00
4.42E+04 1.9E+00 1.1E+00 3.5E+00
6.32E+04 7.9E-01 1.1E+00 3.5E+00
2.30E+04 6.6E+01 1.1E+00 3.5E+00
2.95E+04 4.1E+00 1.1E+00 3.5E+00
4.17E+04 5.9E+00 1.1E+00 3.5E+00
6.04E+04 4.5E+00 1.1E+00 3.5E+00
5.50E-01 9.1E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
3.17E+04 97% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1562
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone.
Na SWA-LRef-1316-T01-A 1 3.59E+05
Na SWA-LRef-1316-T02-A 1 4.50E+05
Na SWA-LRef-1316-T03-A 1 5.27E+05
Na SWA-LRef-1316-T04-A 1 5.37E+05
Na SWA-LRef-1316-T01-B 1 3.55E+05
Na SWA-LRef-1316-T02-B 1 4.45E+05
Na SWA-LRef-1316-T03-B 1 5.12E+05
Na SWA-LRef-1316-T04-B 1 5.16E+05
Na SWA-LRef-1316-T01-C 1 2.86E+05
Na SWA-LRef-1316-T02-C 1 4.42E+05
Na SWA-LRef-1316-T03-C 1 5.13E+05
Na SWA-LRef-1316-T04-C 1 5.16E+05
Na SWA-LRef-1316-B01-A 1 2.06E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.59E+05 5.1E-01 2.5E+00 8.0E+00
4.50E+05 3.4E-01 2.5E+00 8.0E+00 1000 100
5.27E+05 6.4E-01 2.5E+00 8.0E+00
5.37E+05 9.3E-01 2.5E+00 8.0E+00
3.55E+05 6.2E-02 2.5E+00 8.0E+00
4.45E+05 3.4E+00 2.5E+00 8.0E+00
5.12E+05 5.0E-01 2.5E+00 8.0E+00
5.16E+05 3.0E-01 2.5E+00 8.0E+00
2.86E+05 5.7E+01 2.5E+00 8.0E+00
4.42E+05 3.3E+00 2.5E+00 8.0E+00
5.13E+05 3.4E+00 2.5E+00 8.0E+00
5.16E+05 2.9E+00 2.5E+00 8.0E+00
2.06E+01 6.2E+02 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
4.51E+05 94% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1563
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-LRef-1316-T01-A 1
SWA-LRef-1316-T02-A 1
SWA-LRef-1316-T03-A 1
SWA-LRef-1316-T04-A 1
SWA-LRef-1316-T01-B 1
SWA-LRef-1316-T02-B 1
SWA-LRef-1316-T03-B 1
SWA-LRef-1316-T04-B 1
SWA-LRef-1316-T01-C 1
SWA-LRef-1316-T02-C 1
SWA-LRef-1316-T03-C 1
SWA-LRef-1316-T04-C 1
SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
4.04E+02
3.68E+02
4.81 E+02
4.34E+02
3.92E+02
3.65E+02
3.93E+02
4.32E+02
2.95E+02
3.70E+02
3.84E+02
4.26E+02
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.04E+02 4.2E-02 1.0E+00 3.2E+00
3.68E+02 2.4E-01 1.0E+00 3.2E+00 1000 100
4.81 E+02 2.8E-01 1.0E+00 3.2E+00
4.34E+02 9.5E-01 1.0E+00 3.2E+00
3.92E+02 2.5E-01 1.0E+00 3.2E+00
3.65E+02 4.7E+00 1.0E+00 3.2E+00
3.93E+02 8.6E-01 1.0E+00 3.2E+00
4.32E+02 3.0E-01 1.0E+00 3.2E+00
2.95E+02 7.0E+01 1.0E+00 3.2E+00
3.70E+02 3.0E+00 1.0E+00 3.2E+00
3.84E+02 5.1E+00 1.0E+00 3.2E+00
4.26E+02 5.1E+00 1.0E+00 3.2E+00
5.00E-01 2.4E+03 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.40E+03 104% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1564
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qu
1 1 ug/L
S SWA-LRef-1316-T01-A 1 4.68E+05
S SWA-LRef-1316-T02-A 1 7.47E+05
S SWA-LRef-1316-T03-A 1 1.49E+06
S SWA-LRef-1316-T04-A 1 2.02E+06
S SWA-LRef-1316-T01-B 1 4.63E+05
S SWA-LRef-1316-T02-B 1 6.10E+05
S SWA-LRef-1316-T03-B 1 1.26E+06
S SWA-LRef-1316-T04-B 1 2.00E+06
S SWA-LRef-1316-T01-C 1 4.52E+05
S SWA-LRef-1316-T02-C 1 6.02E+05
S SWA-LRef-1316-T03-C 1 1.12E+06
S SWA-LRef-1316-T04-C 1 1.87E+06
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
4.68E+05 9.8E-01 6.8E+00 2.2E+01
7.47E+05 1.7E-01 6.8E+00 2.2E+01 1000 100
1.49E+06 3.0E-01 6.8E+00 2.2E+01
2.02E+06 6.9E-01 6.8E+00 2.2E+01
4.63E+05 3.7E-01 6.8E+00 2.2E+01
6.10E+05 4.2E+00 6.8E+00 2.2E+01
1.26E+06 8.9E-01 6.8E+00 2.2E+01
2.00E+06 8.2E-01 6.8E+00 2.2E+01
4.52E+05 6.5E+01 6.8E+00 2.2E+01
6.02E+05 4.2E+00 6.8E+00 2.2E+01
1.12E+06 5.2E+00 6.8E+00 2.2E+01
1.87E+06 4.0E+00 6.8E+00 2.2E+01
S SWA-LRef-1316-B01-A 1 3.40E+00 U1/2 3.40E+00 7.9E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
7.48E+05 84% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1565
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl SWA-LRef-1316-T01-A 1
Tl SWA-LRef-1316-T02-A 1
Tl SWA-LRef-1316-T03-A 1
Tl SWA-LRef-1316-T04-A 1
Tl SWA-LRef-1316-T01-B 1
Tl SWA-LRef-1316-T02-B 1
Tl SWA-LRef-1316-T03-B 1
Tl SWA-LRef-1316-T04-B 1
Tl SWA-LRef-1316-T01-C 1
Tl SWA-LRef-1316-T02-C 1
Tl SWA-LRef-1316-T03-C 1
Tl SWA-LRef-1316-T04-C 1
Tl SWA-LRef-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 3.7E+01 4.6E+00 1.5E+01
2.30E+00 2.4E+02 4.6E+00 1.5E+01 10 100
2.30E+00 8.0E+02 4.6E+00 1.5E+01
2.30E+00 1.1E+02 4.6E+00 1.5E+01
2.30E+00 6.6E+01 4.6E+00 1.5E+01
2.30E+00 3.4E+01 4.6E+00 1.5E+01
2.30E+00 1.3E+02 4.6E+00 1.5E+01
2.30E+00 1.7E+02 4.6E+00 1.5E+01
2.30E+00 1.2E+01 4.6E+00 1.5E+01
2.30E+00 4.5E+01 4.6E+00 1.5E+01
2.30E+00 1.0E+02 4.6E+00 1.5E+01
2.30E+00 1.2E+03 4.6E+00 1.5E+01
2.30E+00 5.5E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
9.35E+02 93% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1566
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti SWA-LRef-1316-T01-A 1
Ti SWA-LRef-1316-T02-A 1
Ti SWA-LRef-1316-T03-A 1
Ti SWA-LRef-1316-T04-A 1
Ti SWA-LRef-1316-T01-B 1
Ti SWA-LRef-1316-T02-B 1
Ti SWA-LRef-1316-T03-B 1
Ti SWA-LRef-1316-T04-B 1
Ti SWA-LRef-1316-T01-C 1
Ti SWA-LRef-1316-T02-C 1
Ti SWA-LRef-1316-T03-C 1
Ti SWA-LRef-1316-T04-C 1
Ti SWA-LRef-1316-B01-A 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.11E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.81 E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.02E+00 E
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00 10 100
1.00E+00 9.2E-02 2.0E+00 6.4E+00
3.11 E+00 8.5E+00 2.0E+00 6.4E+00
1.00E+00 3.6E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
1.00E+00 6.6E+00 2.0E+00 6.4E+00
4.81E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 6.1E+01 2.0E+00 6.4E+00
1.00E+00 3.4E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+00 2.0E+00 6.4E+00
3.02E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.01E+03 100% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1567
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone.
1 ug/L
V SWA-LRef-1316-T01-A 1 3.25E+02
V SWA-LRef-1316-T02-A 1 5.94E+02
V SWA-LRef-1316-T03-A 1 1.22E+03
V SWA-LRef-1316-T04-A 1 2.14E+03
V SWA-LRef-1316-T01-B 1 3.10E+02
V SWA-LRef-1316-T02-B 1 5.60E+02
V SWA-LRef-1316-T03-B 1 1.17E+03
V SWA-LRef-1316-T04-B 1 2.32E+03
V SWA-LRef-1316-T01-C 1 2.84E+02
V SWA-LRef-1316-T02-C 1 5.36E+02
V SWA-LRef-1316-T03-C 1 1.18E+03
V SWA-LRef-1316-T04-C 1 2.04E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.25E+02 7.3E-01 1.5E+00 4.8E+00
5.94E+02 1.4E-01 1.5E+00 4.8E+00 10 100
1.22E+03 9.3E-01 1.5E+00 4.8E+00
2.14E+03 8.0E-01 1.5E+00 4.8E+00
3.10E+02 9.5E-01 1.5E+00 4.8E+00
5.60E+02 4.3E+00 1.5E+00 4.8E+00
1.17E+03 2.5E-01 1.5E+00 4.8E+00
2.32E+03 1.0E+00 1.5E+00 4.8E+00
2.84E+02 6.9E+01 1.5E+00 4.8E+00
5.36E+02 3.9E+00 1.5E+00 4.8E+00
1.18E+03 6.3E+00 1.5E+00 4.8E+00
2.04E+03 4.2E+00 1.5E+00 4.8E+00
V SWA-LRef-1316-B01-A 1 7.50E-01 U1/2 7.50E-01 1 .OE+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.61E+03 101% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1568
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-LRef-1316-T01-A 1
Zn SWA-LRef-1316-T02-A 1
Zn SWA-LRef-1316-T03-A 1
Zn SWA-LRef-1316-T04-A 1
Zn SWA-LRef-1316-T01-B 1
Zn SWA-LRef-1316-T02-B 1
Zn SWA-LRef-1316-T03-B 1
Zn SWA-LRef-1316-T04-B 1
Zn SWA-LRef-1316-T01-C 1
Zn SWA-LRef-1316-T02-C 1
Zn SWA-LRef-1316-T03-C 1
Zn SWA-LRef-1316-T04-C 1
Zn SWA-LRef-1316-B01-A 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
2.41 E+00 E
3.81 E+00
1.15E+01
5.00E-01 U1/2
1.99E+00 E
4.01 E+00
1.38E+01
5.00E-01 U1/2
2.08E+00 E
5.16E+00
1.32E+01
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 3.9E+01 1.0E+00 3.2E+00
2.41E+00 1.1E+01 1.0E+00 3.2E+00 10 100
3.81 E+00 5.5E+00 1.0E+00 3.2E+00
1.15E+01 7.1E+00 1.0E+00 3.2E+00
5.00E-01 1.0E+02 1.0E+00 3.2E+00
1.99E+00 2.8E+00 1.0E+00 3.2E+00
4.01 E+00 1.8E+01 1.0E+00 3.2E+00
1.38E+01 4.0E+00 1.0E+00 3.2E+00
5.00E-01 9.9E+01 1.0E+00 3.2E+00
2.08E+00 7.6E+01 1.0E+00 3.2E+00
5.16E+00 1.0E+01 1.0E+00 3.2E+00
1.32E+01 6.7E+00 1.0E+00 3.2E+00
5.00E-01 2.1E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:26 PM EPA Interlab LRef 1313-1316 SWA
1.09E+03 108% VU ICP-OES 10/26/10 2:27 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:29 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:31 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:32 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:34 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:36 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:37 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:39 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:41 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:42 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:44 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:16 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1569
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Al Sample Dilution
Al SWA-LRef-1316-T01-D 1
Al SWA-LRef-1316-T02-D 1
Al SWA-LRef-1316-T03-D 1
Al SWA-LRef-1316-T04-D 1
Al SWA-LRef-1316-T01-E 1
Al SWA-LRef-1316-T02-E 1
Al SWA-LRef-1316-T03-E 1
Al SWA-LRef-1316-T04-E 1
Al SWA-LRef-1316-T01-F 1
Al SWA-LRef-1316-T02-F 1
Al SWA-LRef-1316-T03-F 1
Al SWA-LRef-1316-T04-F 1
Al SWA-LRef-1316-B01-D 1
Sample
Cone. Qualifier
ug/L
3.08E+04
5.30E+04
1.06E+05
1.71E+05
2.17E+04
5.10E+04
1.07E+05
1.68E+05
3.53E+04
5.04E+04
6.93E+04
1.67E+05
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.08E+04 4.4E+00 1.0E+00 3.2E+00
5.30E+04 1.3E+00 1.0E+00 3.2E+00 1000 100
1.06E+05 5.0E-01 1.0E+00 3.2E+00
1.71E+05 2.2E+00 1.0E+00 3.2E+00
2.17E+04 6.6E+01 1.0E+00 3.2E+00
5.10E+04 1.1E+00 1.0E+00 3.2E+00
1.07E+05 2.3E-01 1.0E+00 3.2E+00
1.68E+05 3.5E+00 1.0E+00 3.2E+00
3.53E+04 8.7E-01 1.0E+00 3.2E+00
5.04E+04 9.1E-01 1.0E+00 3.2E+00
6.93E+04 6.5E+01 1.0E+00 3.2E+00
1.67E+05 9.1E-01 1.0E+00 3.2E+00
5.00E-01 6.3E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
5.39E+04 90% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                                 1-1570
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sb Sample Dilution
Sb SWA-LRef-1316-T01-D 1
Sb SWA-LRef-1316-T02-D 1
Sb SWA-LRef-1316-T03-D 1
Sb SWA-LRef-1316-T04-D 1
Sb SWA-LRef-1316-T01-E 1
Sb SWA-LRef-1316-T02-E 1
Sb SWA-LRef-1316-T03-E 1
Sb SWA-LRef-1316-T04-E 1
Sb SWA-LRef-1316-T01-F 1
Sb SWA-LRef-1316-T02-F 1
Sb SWA-LRef-1316-T03-F 1
Sb SWA-LRef-1316-T04-F 1
Sb SWA-LRef-1316-B01-D 1
Sample
Cone. Qualifier
ug/L
5.64E+03
5.88E+03
5.93E+03
7.22E+03
5.16E+03
5.26E+03
6.22E+03
5.74E+03
5.99E+03
5.89E+03
5.81 E+03
5.63E+03
3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.64E+03 6.3E-01 7.5E+00 2.4E+01
5.88E+03 7.8E-01 7.5E+00 2.4E+01 10 100
5.93E+03 2.8E-01 7.5E+00 2.4E+01
7.22E+03 2.9E+00 7.5E+00 2.4E+01
5.16E+03 6.9E+01 7.5E+00 2.4E+01
5.26E+03 1.3E+00 7.5E+00 2.4E+01
6.22E+03 7.1E-01 7.5E+00 2.4E+01
5.74E+03 3.5E+00 7.5E+00 2.4E+01
5.99E+03 1.5E-01 7.5E+00 2.4E+01
5.89E+03 8.2E-01 7.5E+00 2.4E+01
5.81E+03 6.8E+01 7.5E+00 2.4E+01
5.63E+03 1.6E+00 7.5E+00 2.4E+01
3.75E+00 1.6E+02 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
6.86E+03 99% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1571
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
As Sample Dilution
As SWA-LRef-1316-T01-D 1
As SWA-LRef-1316-T02-D 1
As SWA-LRef-1316-T03-D 1
As SWA-LRef-1316-T04-D 1
As SWA-LRef-1316-T01-E 1
As SWA-LRef-1316-T02-E 1
As SWA-LRef-1316-T03-E 1
As SWA-LRef-1316-T04-E 1
As SWA-LRef-1316-T01-F 1
As SWA-LRef-1316-T02-F 1
As SWA-LRef-1316-T03-F 1
As SWA-LRef-1316-T04-F 1
As SWA-LRef-1316-B01-D 1
Sample
Cone. Qualifier
ug/L
4.89E+03
1.13E+04
3.93E+04
1.09E+05
4.74E+03
9.69E+03
3.84E+04
1.01E+05
5.12E+03
1.12E+04
2.73E+04
9.76E+04
1.36E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.89E+03 5.2E-01 1.1E+01 3.5E+01
1.13E+04 1.8E+00 1.1E+01 3.5E+01 10 100
3.93E+04 4.1E-01 1.1E+01 3.5E+01
1.09E+05 2.4E+00 1.1E+01 3.5E+01
4.74E+03 7.0E+01 1.1E+01 3.5E+01
9.69E+03 1.5E+00 1.1E+01 3.5E+01
3.84E+04 9.2E-01 1.1E+01 3.5E+01
1.01E+05 4.0E+00 1.1E+01 3.5E+01
5.12E+03 8.2E-01 1.1E+01 3.5E+01
1.12E+04 7.3E-01 1.1E+01 3.5E+01
2.73E+04 6.1E+01 1.1E+01 3.5E+01
9.76E+04 7.7E-01 1.1E+01 3.5E+01
1.36E+01 1.9E+02 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1 .23E+04 105% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1572
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
B Sample Dilution
B SWA-LRef-1316-T01-D 1
B SWA-LRef-1316-T02-D 1
B SWA-LRef-1316-T03-D 1
B SWA-LRef-1316-T04-D 1
B SWA-LRef-1316-T01-E 1
B SWA-LRef-1316-T02-E 1
B SWA-LRef-1316-T03-E 1
B SWA-LRef-1316-T04-E 1
B SWA-LRef-1316-T01-F 1
B SWA-LRef-1316-T02-F 1
B SWA-LRef-1316-T03-F 1
B SWA-LRef-1316-T04-F 1
B SWA-LRef-1316-B01-D 1
Sample
Cone. Qualifier
ug/L
1.13E+03
9.26E+02
6.42E+02
7.30E+02
1.03E+03
9.31 E+02
6.50E+02
6.98E+02
1.16E+03
9.19E+02
6.54E+02
7.27E+02
6.89E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.13E+03 8.5E-01 1.0E+00 3.2E+00
9.26E+02 1.3E+00 1.0E+00 3.2E+00 1000 100
6.42E+02 2.4E-01 1.0E+00 3.2E+00
7.30E+02 2.5E+00 1.0E+00 3.2E+00
1.03E+03 6.9E+01 1.0E+00 3.2E+00
9.31 E+02 1.6E+00 1.0E+00 3.2E+00
6.50E+02 7.3E-01 1.0E+00 3.2E+00
6.98E+02 4.0E+00 1.0E+00 3.2E+00
1.16E+03 1.2E+00 1.0E+00 3.2E+00
9.19E+02 1.2E+00 1.0E+00 3.2E+00
6.54E+02 6.8E+01 1.0E+00 3.2E+00
7.27E+02 6.9E-01 1.0E+00 3.2E+00
6.89E+00 8.6E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.98E+03 105% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1573
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ba Sample Dilution
Ba SWA-LRef-1316-T01-D 1
Ba SWA-LRef-1316-T02-D 1
Ba SWA-LRef-1316-T03-D 1
Ba SWA-LRef-1316-T04-D 1
Ba SWA-LRef-1316-T01-E 1
Ba SWA-LRef-1316-T02-E 1
Ba SWA-LRef-1316-T03-E 1
Ba SWA-LRef-1316-T04-E 1
Ba SWA-LRef-1316-T01-F 1
Ba SWA-LRef-1316-T02-F 1
Ba SWA-LRef-1316-T03-F 1
Ba SWA-LRef-1316-T04-F 1
Ba SWA-LRef-1316-B01-D 1
Sample
Cone. Qualifier
ug/L
1.35E+02
1.45E+02
1.41E+02
1.34E+02
1.08E+02
1.79E+02
1.52E+02
1.32E+02
1.62E+02
1.43E+02
1.32E+02
1.19E+02
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.35E+02 2.8E+01 1.0E+00 3.2E+00
1.45E+02 6.7E-01 1.0E+00 3.2E+00 10 100
1.41E+02 4.4E+00 1.0E+00 3.2E+00
1.34E+02 2.4E+00 1.0E+00 3.2E+00
1.08E+02 6.7E+01 1.0E+00 3.2E+00
1.79E+02 8.4E-01 1.0E+00 3.2E+00
1.52E+02 3.4E+00 1.0E+00 3.2E+00
1.32E+02 4.1E+00 1.0E+00 3.2E+00
1.62E+02 2.6E+00 1.0E+00 3.2E+00
1.43E+02 1.7E+00 1.0E+00 3.2E+00
1.32E+02 6.6E+01 1.0E+00 3.2E+00
1.19E+02 1.7E+00 1.0E+00 3.2E+00
5.00E-01 2.2E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1 .08E+03 93% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1574
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Be Sample Dilution
Be SWA-LRef-1316-T01-D 1
Be SWA-LRef-1316-T02-D 1
Be SWA-LRef-1316-T03-D 1
Be SWA-LRef-1316-T04-D 1
Be SWA-LRef-1316-T01-E 1
Be SWA-LRef-1316-T02-E 1
Be SWA-LRef-1316-T03-E 1
Be SWA-LRef-1316-T04-E 1
Be SWA-LRef-1316-T01-F 1
Be SWA-LRef-1316-T02-F 1
Be SWA-LRef-1316-T03-F 1
Be SWA-LRef-1316-T04-F 1
Be SWA-LRef-1316-B01-D 1
Sample Inter
Cone. Qualifier Revi
ug/L
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.2E+02 1.9E+00 6.0E+00
9.50E-01 7.6E+01 1.9E+00 6.0E+00 10 100
9.50E-01 2.5E+01 1.9E+00 6.0E+00
9.50E-01 5.6E+01 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 8.8E+01 1.9E+00 6.0E+00
9.50E-01 1.5E+02 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 7.1E+01 1.9E+00 6.0E+00
9.50E-01 6.5E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 9.9E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.11E+03 111% VU ICP-OES 10/26/102:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1575
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cd Sample Dilution
Cd SWA-LRef-1316-T01-D 1
Cd SWA-LRef-1316-T02-D 1
Cd SWA-LRef-1316-T03-D 1
Cd SWA-LRef-1316-T04-D 1
Cd SWA-LRef-1316-T01-E 1
Cd SWA-LRef-1316-T02-E 1
Cd SWA-LRef-1316-T03-E 1
Cd SWA-LRef-1316-T04-E 1
Cd SWA-LRef-1316-T01-F 1
Cd SWA-LRef-1316-T02-F 1
Cd SWA-LRef-1316-T03-F 1
Cd SWA-LRef-1316-T04-F 1
Cd SWA-LRef-1316-B01-D 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 1.6E+02 2.2E+00 7.0E+00
1.10E+00 9.1E+02 2.2E+00 7.0E+00 10 100
1.10E+00 4.1E+01 2.2E+00 7.0E+00
1.10E+00 1.5E+02 2.2E+00 7.0E+00
1.10E+00 4.2E+02 2.2E+00 7.0E+00
1.10E+00 8.5E+02 2.2E+00 7.0E+00
1.10E+00 2.8E+02 2.2E+00 7.0E+00
1.10E+00 6.5E+02 2.2E+00 7.0E+00
1.10E+00 1.2E+02 2.2E+00 7.0E+00
1.10E+00 8.1E+02 2.2E+00 7.0E+00
1.10E+00 1.9E+02 2.2E+00 7.0E+00
1.10E+00 8.1E+01 2.2E+00 7.0E+00
1.10E+00 3.0E+02 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.11E+03 111% VU ICP-OES 10/26/102:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/103:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1576
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone.
Ca SWA-LRef-1316-T01-D 1 1.04E+04
Ca SWA-LRef-1316-T02-D 1 1.12E+04
Ca SWA-LRef-1316-T03-D 1 6.54E+03
Ca SWA-LRef-1316-T04-D 1 5.08E+03
Ca SWA-LRef-1316-T01-E 1 8.89E+03
Ca SWA-LRef-1316-T02-E 1 1.21E+04
Ca SWA-LRef-1316-T03-E 1 6.43E+03
Ca SWA-LRef-1316-T04-E 1 4.61 E+03
Ca SWA-LRef-1316-T01-F 1 1.40E+04
Ca SWA-LRef-1316-T02-F 1 9.08E+03
Ca SWA-LRef-1316-T03-F 1 6.05E+03
Ca SWA-LRef-1316-T04-F 1 4.56E+03
Ca SWA-LRef-1316-B01-D 1 4.86E+01
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.04E+04 6.2E+00 2.6E+00 8.3E+00
1.12E+04 6.6E-01 2.6E+00 8.3E+00 1000 100
6.54E+03 4.1E+00 2.6E+00 8.3E+00
5.08E+03 4.9E-01 2.6E+00 8.3E+00
8.89E+03 6.9E+01 2.6E+00 8.3E+00
1.21E+04 5.2E-01 2.6E+00 8.3E+00
6.43E+03 2.5E+00 2.6E+00 8.3E+00
4.61 E+03 9.7E+00 2.6E+00 8.3E+00
1.40E+04 1.6E+00 2.6E+00 8.3E+00
9.08E+03 7.0E-01 2.6E+00 8.3E+00
6.05E+03 6.9E+01 2.6E+00 8.3E+00
4.56E+03 2.4E+00 2.6E+00 8.3E+00
4.86E+01 2.5E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.21E+04 90% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1577
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cr Sample Dilution Cone. Qu
1 1 ug/L
Cr SWA-LRef-1316-T01-D 1 9.14E+02
Cr SWA-LRef-1316-T02-D 1 2.03E+03
Cr SWA-LRef-1316-T03-D 1 2.88E+03
Cr SWA-LRef-1316-T04-D 1 3.16E+03
Cr SWA-LRef-1316-T01-E 1 9.54E+02
Cr SWA-LRef-1316-T02-E 1 1.59E+03
Cr SWA-LRef-1316-T03-E 1 2.48E+03
Cr SWA-LRef-1316-T04-E 1 2.68E+03
Cr SWA-LRef-1316-T01-F 1 1.12E+03
Cr SWA-LRef-1316-T02-F 1 1.94E+03
Cr SWA-LRef-1316-T03-F 1 2.46E+03
Cr SWA-LRef-1316-T04-F 1 2.95E+03
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.14E+02 1.0E+01 1.2E+00 3.8E+00
2.03E+03 7.7E-01 1.2E+00 3.8E+00 10 100
2.88E+03 4.1E+00 1.2E+00 3.8E+00
3.16E+03 3.8E+00 1.2E+00 3.8E+00
9.54E+02 6.5E+01 1.2E+00 3.8E+00
1.59E+03 2.7E+00 1.2E+00 3.8E+00
2.48E+03 1.5E+00 1.2E+00 3.8E+00
2.68E+03 1.3E+01 1.2E+00 3.8E+00
1.12E+03 3.0E+00 1.2E+00 3.8E+00
1.94E+03 3.5E+00 1.2E+00 3.8E+00
2.46E+03 6.1E+01 1.2E+00 3.8E+00
2.95E+03 4.4E+00 1.2E+00 3.8E+00
Cr SWA-LRef-1316-B01-D 1 6.00E-01 U1/2 6.00E-01 1 .OE+03 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
2.90E+03 87% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1578
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Co Sample Dilution
Co SWA-LRef-1316-T01-D 1
Co SWA-LRef-1316-T02-D 1
Co SWA-LRef-1316-T03-D 1
Co SWA-LRef-1316-T04-D 1
Co SWA-LRef-1316-T01-E 1
Co SWA-LRef-1316-T02-E 1
Co SWA-LRef-1316-T03-E 1
Co SWA-LRef-1316-T04-E 1
Co SWA-LRef-1316-T01-F 1
Co SWA-LRef-1316-T02-F 1
Co SWA-LRef-1316-T03-F 1
Co SWA-LRef-1316-T04-F 1
Co SWA-LRef-1316-B01-D 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
2.66E+00 E
6.53E+00
9.00E-01 U1/2
9.00E-01 U1/2
2.52E+00 E
5.16E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
2.51 E+00 E
5.18E+00 E
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 3.8E+02 1.8E+00 5.7E+00 10 100
2.66E+00 3.3E+01 1.8E+00 5.7E+00
6.53E+00 1.2E+01 1.8E+00 5.7E+00
9.00E-01 2.3E+03 1.8E+00 5.7E+00
9.00E-01 5.3E+01 1.8E+00 5.7E+00
2.52E+00 3.0E+01 1.8E+00 5.7E+00
5.16E+00 1.8E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
9.00E-01 5.6E+02 1.8E+00 5.7E+00
2.51 E+00 1.2E+02 1.8E+00 5.7E+00
5.18E+00 4.5E+00 1.8E+00 5.7E+00
9.00E-01 2.9E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.12E+03 112% VU ICP-OES 10/26/102:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1579
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Cu Sample Dilution
Cu SWA-LRef-1316-T01-D 1
Cu SWA-LRef-1316-T02-D 1
Cu SWA-LRef-1316-T03-D 1
Cu SWA-LRef-1316-T04-D 1
Cu SWA-LRef-1316-T01-E 1
Cu SWA-LRef-1316-T02-E 1
Cu SWA-LRef-1316-T03-E 1
Cu SWA-LRef-1316-T04-E 1
Cu SWA-LRef-1316-T01-F 1
Cu SWA-LRef-1316-T02-F 1
Cu SWA-LRef-1316-T03-F 1
Cu SWA-LRef-1316-T04-F 1
Cu SWA-LRef-1316-B01-D 1
Sample I
Cone. Qualifier
ug/L I
1.85E+00 U1/2
8.08E+00 E
2.51E+01
5.74E+01
1.85E+00 U1/2
6.18E+00 E
2.16E+01
5.82E+01
1.85E+00 U1/2
5.23E+00 E
2.64E+01
4.41E+01
1.85E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 5.6E+01 3.7E+00 1.2E+01
8.08E+00 1.5E+01 3.7E+00 1.2E+01 10 100
2.51 E+01 6.6E+00 3.7E+00 1.2E+01
5.74E+01 2.3E+00 3.7E+00 1.2E+01
1.85E+00 2.3E+02 3.7E+00 1.2E+01
6.18E+00 3.5E+00 3.7E+00 1.2E+01
2.16E+01 2.0E+00 3.7E+00 1.2E+01
5.82E+01 7.0E+00 3.7E+00 1 .2E+01
1.85E+00 2.4E+02 3.7E+00 1 .2E+01
5.23E+00 1.7E+01 3.7E+00 1 .2E+01
2.64E+01 7.2E+01 3.7E+00 1 .2E+01
4.41 E+01 3.7E+00 3.7E+00 1 .2E+01
1.85E+00 1.5E+02 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.12E+03 111% VU ICP-OES 10/26/102:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1580
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Fe Sample Dilution
Fe SWA-LRef-1316-T01-D 1
Fe SWA-LRef-1316-T02-D 1
Fe SWA-LRef-1316-T03-D 1
Fe SWA-LRef-1316-T04-D 1
Fe SWA-LRef-1316-T01-E 1
Fe SWA-LRef-1316-T02-E 1
Fe SWA-LRef-1316-T03-E 1
Fe SWA-LRef-1316-T04-E 1
Fe SWA-LRef-1316-T01-F 1
Fe SWA-LRef-1316-T02-F 1
Fe SWA-LRef-1316-T03-F 1
Fe SWA-LRef-1316-T04-F 1
Fe SWA-LRef-1316-B01-D 1
Sample I
Cone. Qualifier
ug/L I
4.79E+01
1.65E+02
5.84E+02
1.25E+03
3.98E+01
1.48E+02
5.75E+02
1.19E+03
8.86E+01
1.56E+02
5.72E+02
1.35E+03
1.00E+00 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.79E+01 2.1E+01 2.0E+00 6.4E+00
1.65E+02 5.0E-01 2.0E+00 6.4E+00 1000 100
5.84E+02 2.3E+00 2.0E+00 6.4E+00
1.25E+03 1.9E+00 2.0E+00 6.4E+00
3.98E+01 7.4E+01 2.0E+00 6.4E+00
1.48E+02 6.1E-01 2.0E+00 6.4E+00
5.75E+02 1.9E+00 2.0E+00 6.4E+00
1.19E+03 5.0E+00 2.0E+00 6.4E+00
8.86E+01 3.2E+00 2.0E+00 6.4E+00
1.56E+02 2.4E+00 2.0E+00 6.4E+00
5.72E+02 6.0E+01 2.0E+00 6.4E+00
1.35E+03 1.9E+00 2.0E+00 6.4E+00
1.00E+00 2.9E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.32E+03 115% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1581
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qu
1 1 ug/L
Pb SWA-LRef-1316-T01-D 1 9.12E+00 E
Pb SWA-LRef-1316-T02-D 1 1.90E+01 E
Pb SWA-LRef-1316-T03-D 1 6.83E+01
Pb SWA-LRef-1316-T04-D 1 1.62E+02
Pb SWA-LRef-1316-T01-E 1 8.06E+00 E
Pb SWA-LRef-1316-T02-E 1 2.90E+01
Pb SWA-LRef-1316-T03-E 1 9.01 E+01
Pb SWA-LRef-1316-T04-E 1 1.82E+02
Pb SWA-LRef-1316-T01-F 1 1.35E+01 E
Pb SWA-LRef-1316-T02-F 1 1.87E+01 E
Pb SWA-LRef-1316-T03-F 1 7.90E+01
Pb SWA-LRef-1316-T04-F 1 1.51E+02
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
9.12E+00 3.0E+01 6.8E+00 2.2E+01
1.90E+01 9.9E+00 6.8E+00 2.2E+01 10 100
6.83E+01 5.2E+00 6.8E+00 2.2E+01
1.62E+02 4.4E+00 6.8E+00 2.2E+01
8.06E+00 1.0E+03 6.8E+00 2.2E+01
2.90E+01 3.4E+00 6.8E+00 2.2E+01
9.01 E+01 3.0E+00 6.8E+00 2.2E+01
1.82E+02 5.7E+00 6.8E+00 2.2E+01
1.35E+01 1.1 E+01 6.8E+00 2.2E+01
1.87E+01 8.2E+01 6.8E+00 2.2E+01
7.90E+01 9.1 E+01 6.8E+00 2.2E+01
1.51E+02 4.9E+00 6.8E+00 2.2E+01
Pb SWA-LRef-1316-B01-D 1 3.40E+00 U1/2 3.40E+00 3.3E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.13E+03 111% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1582
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Li Sample Dilution
Li SWA-LRef-1316-T01-D 1
Li SWA-LRef-1316-T02-D 1
Li SWA-LRef-1316-T03-D 1
Li SWA-LRef-1316-T04-D 1
Li SWA-LRef-1316-T01-E 1
Li SWA-LRef-1316-T02-E 1
Li SWA-LRef-1316-T03-E 1
Li SWA-LRef-1316-T04-E 1
Li SWA-LRef-1316-T01-F 1
Li SWA-LRef-1316-T02-F 1
Li SWA-LRef-1316-T03-F 1
Li SWA-LRef-1316-T04-F 1
Li SWA-LRef-1316-B01-D 1
Sample
Cone. Qualifier
ug/L
2.83E+00 E
3.70E+00 E
8.20E+00
9.63E+00
2.19E+00 E
3.71 E+00 E
7.83E+00
9.34E+00
2.41 E+00 E
3.51 E+00 E
8.22E+00
9.90E+00
9.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.83E+00 1.3E+01 1.9E+00 6.0E+00
3.70E+00 2.4E+01 1.9E+00 6.0E+00 10 100
8.20E+00 1.7E+01 1.9E+00 6.0E+00
9.63E+00 1.9E+01 1.9E+00 6.0E+00
2.19E+00 3.4E+01 1.9E+00 6.0E+00
3.71 E+00 1.9E+01 1.9E+00 6.0E+00
7.83E+00 1.6E+01 1.9E+00 6.0E+00
9.34E+00 1.8E+01 1.9E+00 6.0E+00
2.41 E+00 9.1 E+00 1.9E+00 6.0E+00
3.51 E+00 8.7E+00 1.9E+00 6.0E+00
8.22E+00 2.6E+01 1.9E+00 6.0E+00
9.90E+00 2.7E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
8.34E+02 83% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1583
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mn Sample Dilution
Mn SWA-LRef-1316-T01-D 1
Mn SWA-LRef-1316-T02-D 1
Mn SWA-LRef-1316-T03-D 1
Mn SWA-LRef-1316-T04-D 1
Mn SWA-LRef-1316-T01-E 1
Mn SWA-LRef-1316-T02-E 1
Mn SWA-LRef-1316-T03-E 1
Mn SWA-LRef-1316-T04-E 1
Mn SWA-LRef-1316-T01-F 1
Mn SWA-LRef-1316-T02-F 1
Mn SWA-LRef-1316-T03-F 1
Mn SWA-LRef-1316-T04-F 1
Mn SWA-LRef-1316-B01-D 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.88E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
5.39E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
5.31 E+00 E
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 6.1E+02 2.0E+00 6.4E+00
1.00E+00 4.9E+00 2.0E+00 6.4E+00 10 100
1.00E+00 3.6E+00 2.0E+00 6.4E+00
3.88E+00 5.7E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 3.0E+00 2.0E+00 6.4E+00
1.00E+00 5.8E+00 2.0E+00 6.4E+00
5.39E+00 8.4E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+00 2.0E+00 6.4E+00
1.00E+00 2.7E+01 2.0E+00 6.4E+00
1.00E+00 7.7E+01 2.0E+00 6.4E+00
5.31 E+00 3.5E+00 2.0E+00 6.4E+00
1.00E+00 2.6E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.10E+03 110% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1584
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Mg Sample Dilution
Mg SWA-LRef-1316-T01-D 1
Mg SWA-LRef-1316-T02-D 1
Mg SWA-LRef-1316-T03-D 1
Mg SWA-LRef-1316-T04-D 1
Mg SWA-LRef-1316-T01-E 1
Mg SWA-LRef-1316-T02-E 1
Mg SWA-LRef-1316-T03-E 1
Mg SWA-LRef-1316-T04-E 1
Mg SWA-LRef-1316-T01-F 1
Mg SWA-LRef-1316-T02-F 1
Mg SWA-LRef-1316-T03-F 1
Mg SWA-LRef-1316-T04-F 1
Mg SWA-LRef-1316-B01-D 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
5.00E-01 U1/2
7.60E+00
7.44E+00
5.00E-01 U1/2
5.00E-01 U1/2
6.92E+00
7.91 E+00
5.00E-01 U1/2
5.00E-01 U1/2
7.69E+00
1.14E+01
2.18E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 2.4E+02 1.0E+00 3.2E+00
5.00E-01 1.1E+02 1.0E+00 3.2E+00 1000 100
7.60E+00 1.9E+03 1.0E+00 3.2E+00
7.44E+00 1.8E+03 1.0E+00 3.2E+00
5.00E-01 9.7E+01 1.0E+00 3.2E+00
5.00E-01 3.7E+01 1.0E+00 3.2E+00
6.92E+00 1.1E+02 1.0E+00 3.2E+00
7.91 E+00 6.4E+02 1.0E+00 3.2E+00
5.00E-01 2.7E+01 1.0E+00 3.2E+00
5.00E-01 8.0E+01 1.0E+00 3.2E+00
7.69E+00 4.5E+02 1.0E+00 3.2E+00
1.14E+01 9.2E+01 1.0E+00 3.2E+00
2.18E+00 4.4E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.12E+03 112% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1585
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone.
1 1 ug/L
Mo SWA-LRef-1316-T01-D 1 1.64E+02
Mo SWA-LRef-1316-T02-D 1 2.54E+02
Mo SWA-LRef-1316-T03-D 1 6.32E+02
Mo SWA-LRef-1316-T04-D 1 1.21E+03
Mo SWA-LRef-1316-T01-E 1 1.79E+02
Mo SWA-LRef-1316-T02-E 1 2.48E+02
Mo SWA-LRef-1316-T03-E 1 6.61 E+02
Mo SWA-LRef-1316-T04-E 1 1.20E+03
Mo SWA-LRef-1316-T01-F 1 1.62E+02
Mo SWA-LRef-1316-T02-F 1 2.58E+02
Mo SWA-LRef-1316-T03-F 1 6.21E+02
Mo SWA-LRef-1316-T04-F 1 1.30E+03
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.64E+02 1.8E+00 1.2E+00 3.8E+00
2.54E+02 8.9E-01 1.2E+00 3.8E+00 10 100
6.32E+02 1.6E-01 1.2E+00 3.8E+00
1.21E+03 2.0E+00 1.2E+00 3.8E+00
1.79E+02 6.7E+01 1.2E+00 3.8E+00
2.48E+02 8.7E-01 1.2E+00 3.8E+00
6.61 E+02 2.4E-01 1.2E+00 3.8E+00
1.20E+03 4.8E+00 1.2E+00 3.8E+00
1.62E+02 9.3E-02 1.2E+00 3.8E+00
2.58E+02 6.0E-01 1.2E+00 3.8E+00
6.21 E+02 6.7E+01 1.2E+00 3.8E+00
1.30E+03 1.6E+00 1.2E+00 3.8E+00
Mo SWA-LRef-1316-B01-D 1 6.00E-01 U1/2 6.00E-01 1 .2E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.39E+03 113% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1586
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ni Sample Dilution
Ni SWA-LRef-1316-T01-D 1
Ni SWA-LRef-1316-T02-D 1
Ni SWA-LRef-1316-T03-D 1
Ni SWA-LRef-1316-T04-D 1
Ni SWA-LRef-1316-T01-E 1
Ni SWA-LRef-1316-T02-E 1
Ni SWA-LRef-1316-T03-E 1
Ni SWA-LRef-1316-T04-E 1
Ni SWA-LRef-1316-T01-F 1
Ni SWA-LRef-1316-T02-F 1
Ni SWA-LRef-1316-T03-F 1
Ni SWA-LRef-1316-T04-F 1
Ni SWA-LRef-1316-B01-D 1
Sample Internal
Cone. Qualifier Review
ug/L I
9.00E-01 U1/2
9.00E-01 U1/2
1.82E+00 E
6.84E+00
9.00E-01 U1/2
9.00E-01 U1/2
3.06E+00 E
4.04E+00 E
9.00E-01 U1/2
9.00E-01 U1/2
2.37E+00 E
5.57E+00 E
9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 2.7E+02 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00 10 100
1.82E+00 8.0E+01 1.8E+00 5.7E+00
6.84E+00 2.1E+01 1.8E+00 5.7E+00
9.00E-01 5.1E+01 1.8E+00 5.7E+00
9.00E-01 1.7E+02 1.8E+00 5.7E+00
3.06E+00 4.2E+01 1.8E+00 5.7E+00
4.04E+00 3.6E+01 1.8E+00 5.7E+00
9.00E-01 3.8E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
2.37E+00 2.9E+02 1.8E+00 5.7E+00
5.57E+00 3.8E+01 1.8E+00 5.7E+00
9.00E-01 4.7E+02 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.12E+03 112% VU ICP-OES 10/26/102:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1587
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
P Sample Dilution
P SWA-LRef-1316-T01-D 1
P SWA-LRef-1316-T02-D 1
P SWA-LRef-1316-T03-D 1
P SWA-LRef-1316-T04-D 1
P SWA-LRef-1316-T01-E 1
P SWA-LRef-1316-T02-E 1
P SWA-LRef-1316-T03-E 1
P SWA-LRef-1316-T04-E 1
P SWA-LRef-1316-T01-F 1
P SWA-LRef-1316-T02-F 1
P SWA-LRef-1316-T03-F 1
P SWA-LRef-1316-T04-F 1
P SWA-LRef-1316-B01-D 1
Sample
Cone. Qualifier
ug/L
2.87E+01
8.41E+01
3.04E+02
1.30E+03
2.11E+01
7.44E+01
2.90E+02
1.19E+03
2.04E+01
7.84E+01
2.41 E+02
9.88E+02
4.81 E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.87E+01 1.6E+01 3.7E+00 1.2E+01
8.41E+01 1.6E+01 3.7E+00 1 .2E+01 1000 100
3.04E+02 1.5E+00 3.7E+00 1 .2E+01
1.30E+03 3.1 E+00 3.7E+00 1 .2E+01
2.11E+01 1.1E+02 3.7E+00 1 .2E+01
7.44E+01 8.0E+00 3.7E+00 1 .2E+01
2.90E+02 3.4E+00 3.7E+00 1 .2E+01
1.19E+03 3.4E+00 3.7E+00 1 .2E+01
2.04E+01 7.7E+00 3.7E+00 1 .2E+01
7.84E+01 2.6E+00 3.7E+00 1 .2E+01
2.41 E+02 6.8E+01 3.7E+00 1 .2E+01
9.88E+02 1.8E+00 3.7E+00 1 .2E+01
4.81 E+00 1.8E+02 3.7E+00 1 .2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.22E+03 113% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1588
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
K Sample Dilution Cone. Qu
1 1 ug/L
K SWA-LRef-1316-T01-D 1 2.70E+05
K SWA-LRef-1316-T02-D 1 4.28E+05
K SWA-LRef-1316-T03-D 1 1.70E+06
K SWA-LRef-1316-T04-D 1 1.99E+06
K SWA-LRef-1316-T01-E 1 2.63E+05
K SWA-LRef-1316-T02-E 1 4.30E+05
K SWA-LRef-1316-T03-E 1 1.72E+06
K SWA-LRef-1316-T04-E 1 1.96E+06
K SWA-LRef-1316-T01-F 1 2.74E+05
K SWA-LRef-1316-T02-F 1 4.38E+05
K SWA-LRef-1316-T03-F 1 1.69E+06
K SWA-LRef-1316-T04-F 1 1.81E+06
K SWA-LRef-1316-B01-D 1 6.57E+00
Internal ICP-OES Spike Sol'n
alifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
2.70E+05 7.0E-01 1.6E+00 5.1E+00
4.28E+05 2.3E+00 1.6E+00 5.1E+00 1000 100
1.70E+06 2.7E-01 1.6E+00 5.1E+00
1.99E+06 1.9E+00 1.6E+00 5.1E+00
2.63E+05 6.7E+01 1.6E+00 5.1E+00
4.30E+05 1.2E+00 1.6E+00 5.1E+00
1.72E+06 1.0E+00 1.6E+00 5.1E+00
1.96E+06 4.5E+00 1.6E+00 5.1E+00
2.74E+05 2.3E+00 1.6E+00 5.1E+00
4.38E+05 2.9E+00 1.6E+00 5.1E+00
1.69E+06 7.7E+01 1.6E+00 5.1E+00
1.81E+06 6.2E-01 1.6E+00 5.1E+00
6.57E+00 2.7E+02 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
4.29E+05 92% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1589
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone.
1 ug/L
Se SWA-LRef-1316-T01-D 1 1.07E+05
Se SWA-LRef-1316-T02-D 1 1.75E+05
Se SWA-LRef-1316-T03-D 1 4.01 E+05
Se SWA-LRef-1316-T04-D 1 8.11E+05
Se SWA-LRef-1316-T01-E 1 1.03E+05
Se SWA-LRef-1316-T02-E 1 1.72E+05
Se SWA-LRef-1316-T03-E 1 4.15E+05
Se SWA-LRef-1316-T04-E 1 8.07E+05
Se SWA-LRef-1316-T01-F 1 1.08E+05
Se SWA-LRef-1316-T02-F 1 1.79E+05
Se SWA-LRef-1316-T03-F 1 2.94E+05
Se SWA-LRef-1316-T04-F 1 7.64E+05
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
1.07E+05 4.9E-01 1.5E+01 4.8E+01
1.75E+05 1.0E+00 1.5E+01 4.8E+01 10 100
4.01 E+05 2.6E-01 1.5E+01 4.8E+01
8.11E+05 2.3E+00 1.5E+01 4.8E+01
1.03E+05 7.0E+01 1.5E+01 4.8E+01
1.72E+05 1.0E+00 1.5E+01 4.8E+01
4.15E+05 2.9E-01 1.5E+01 4.8E+01
8.07E+05 3.6E+00 1.5E+01 4.8E+01
1.08E+05 7.7E-01 1.5E+01 4.8E+01
1.79E+05 9.4E-01 1.5E+01 4.8E+01
2.94E+05 6.8E+01 1.5E+01 4.8E+01
7.64E+05 4.9E-01 1.5E+01 4.8E+01
Se SWA-LRef-1316-B01-D 1 7.50E+00 U1/2 7.50E+00 1 .3E+02 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.76E+05 99% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1590
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Si Sample Dilution
Si SWA-LRef-1316-T01-D 1
Si SWA-LRef-1316-T02-D 1
Si SWA-LRef-1316-T03-D 1
Si SWA-LRef-1316-T04-D 1
Si SWA-LRef-1316-T01-E 1
Si SWA-LRef-1316-T02-E 1
Si SWA-LRef-1316-T03-E 1
Si SWA-LRef-1316-T04-E 1
Si SWA-LRef-1316-T01-F 1
Si SWA-LRef-1316-T02-F 1
Si SWA-LRef-1316-T03-F 1
Si SWA-LRef-1316-T04-F 1
Si SWA-LRef-1316-B01-D 1
Sample
Cone. Qualifier
ug/L
2.37E+04
3.00E+04
4.05E+04
5.94E+04
2.31 E+04
2.74E+04
3.97E+04
5.83E+04
2.47E+04
2.96E+04
3.92E+04
5.75E+04
5.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.37E+04 6.2E+00 1.1E+00 3.5E+00
3.00E+04 3.1E-01 1.1E+00 3.5E+00 1000 100
4.05E+04 1.4E+00 1.1E+00 3.5E+00
5.94E+04 1.9E+00 1.1E+00 3.5E+00
2.31 E+04 6.5E+01 1.1E+00 3.5E+00
2.74E+04 6.1E-01 1.1E+00 3.5E+00
3.97E+04 5.4E-01 1.1E+00 3.5E+00
5.83E+04 3.9E+00 1.1E+00 3.5E+00
2.47E+04 1.0E+00 1.1E+00 3.5E+00
2.96E+04 8.5E-01 1.1E+00 3.5E+00
3.92E+04 6.3E+01 1.1E+00 3.5E+00
5.75E+04 4.1E-01 1.1E+00 3.5E+00
5.50E-01 2.6E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
3.09E+04 98% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1591
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Na Sample Dilution
Na SWA-LRef-1316-T01-D 1
Na SWA-LRef-1316-T02-D 1
Na SWA-LRef-1316-T03-D 1
Na SWA-LRef-1316-T04-D 1
Na SWA-LRef-1316-T01-E 1
Na SWA-LRef-1316-T02-E 1
Na SWA-LRef-1316-T03-E 1
Na SWA-LRef-1316-T04-E 1
Na SWA-LRef-1316-T01-F 1
Na SWA-LRef-1316-T02-F 1
Na SWA-LRef-1316-T03-F 1
Na SWA-LRef-1316-T04-F 1
Na SWA-LRef-1316-B01-D 1
Sample I
Cone. Qualifier
ug/L I
3.62E+05
4.39E+05
5.36E+05
5.14E+05
2.83E+05
4.42E+05
5.28E+05
5.17E+05
3.59E+05
4.45E+05
4.58E+05
5.24E+05
3.95E+00 E
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.62E+05 3.4E-01 2.5E+00 8.0E+00
4.39E+05 7.7E-01 2.5E+00 8.0E+00 1000 100
5.36E+05 2.4E-01 2.5E+00 8.0E+00
5.14E+05 1.8E+00 2.5E+00 8.0E+00
2.83E+05 5.5E+01 2.5E+00 8.0E+00
4.42E+05 2.0E-01 2.5E+00 8.0E+00
5.28E+05 9.2E-01 2.5E+00 8.0E+00
5.17E+05 2.6E+00 2.5E+00 8.0E+00
3.59E+05 6.5E-01 2.5E+00 8.0E+00
4.45E+05 7.7E-01 2.5E+00 8.0E+00
4.58E+05 4.7E+01 2.5E+00 8.0E+00
5.24E+05 9.1E-01 2.5E+00 8.0E+00
3.95E+00 6.2E+02 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
4.40E+05 84% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1592
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample Dilution
SWA-LRef-1316-T01-D 1
SWA-LRef-1316-T02-D 1
SWA-LRef-1316-T03-D 1
SWA-LRef-1316-T04-D 1
SWA-LRef-1316-T01-E 1
SWA-LRef-1316-T02-E 1
SWA-LRef-1316-T03-E 1
SWA-LRef-1316-T04-E 1
SWA-LRef-1316-T01-F 1
SWA-LRef-1316-T02-F 1
SWA-LRef-1316-T03-F 1
SWA-LRef-1316-T04-F 1
SWA-LRef-1316-B01-D 1
Sample
Cone. Qualifier
ug/L
3.52E+02
3.86E+02
4.26E+02
4.42E+02
3.45E+02
4.18E+02
4.47E+02
4.63E+02
3.84E+02
3.37E+02
4.27E+02
4.94E+02
5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.52E+02 5.5E+00 1.0E+00 3.2E+00
3.86E+02 7.5E-01 1.0E+00 3.2E+00 1000 100
4.26E+02 8.6E-01 1.0E+00 3.2E+00
4.42E+02 2.7E+00 1.0E+00 3.2E+00
3.45E+02 6.8E+01 1.0E+00 3.2E+00
4.18E+02 7.6E-01 1.0E+00 3.2E+00
4.47E+02 4.0E-01 1.0E+00 3.2E+00
4.63E+02 3.9E+00 1.0E+00 3.2E+00
3.84E+02 8.7E-01 1.0E+00 3.2E+00
3.37E+02 1.2E+00 1.0E+00 3.2E+00
4.27E+02 6.8E+01 1.0E+00 3.2E+00
4.94E+02 6.9E-01 1.0E+00 3.2E+00
5.00E-01 2.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.51E+03 113% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1593
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone.
1 ug/L
S SWA-LRef-1316-T01-D 1 3.83E+05
S SWA-LRef-1316-T02-D 1 6.37E+05
S SWA-LRef-1316-T03-D 1 1.38E+06
S SWA-LRef-1316-T04-D 1 1.93E+06
S SWA-LRef-1316-T01-E 1 3.29E+05
S SWA-LRef-1316-T02-E 1 6.22E+05
S SWA-LRef-1316-T03-E 1 1.47E+06
S SWA-LRef-1316-T04-E 1 1.91E+06
S SWA-LRef-1316-T01-F 1 3.97E+05
S SWA-LRef-1316-T02-F 1 6.31 E+05
S SWA-LRef-1316-T03-F 1 1.32E+06
S SWA-LRef-1316-T04-F 1 2.00E+06
Internal ICP-OES Spike Sol'n
3ualifier Review Cone. RSD MDL ML Cone. Volume
I ug/L % ug/L ug/L ug/L uL
3.83E+05 3.2E-01 6.8E+00 2.2E+01
6.37E+05 8.1E-01 6.8E+00 2.2E+01 1000 100
1.38E+06 2.0E-01 6.8E+00 2.2E+01
1.93E+06 2.4E+00 6.8E+00 2.2E+01
3.29E+05 6.6E+01 6.8E+00 2.2E+01
6.22E+05 5.7E-01 6.8E+00 2.2E+01
1.47E+06 1.6E-01 6.8E+00 2.2E+01
1.91E+06 3.2E+00 6.8E+00 2.2E+01
3.97E+05 7.1E-01 6.8E+00 2.2E+01
6.31E+05 4.8E-01 6.8E+00 2.2E+01
1.32E+06 6.0E+01 6.8E+00 2.2E+01
2.00E+06 1.5E+00 6.8E+00 2.2E+01
S SWA-LRef-1316-B01-D 1 3.40E+00 U1/2 3.40E+00 2.5E+02 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
6.38E+05 85% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1594
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Tl Sample Dilution
Tl SWA-LRef-1316-T01-D 1
Tl SWA-LRef-1316-T02-D 1
Tl SWA-LRef-1316-T03-D 1
Tl SWA-LRef-1316-T04-D 1
Tl SWA-LRef-1316-T01-E 1
Tl SWA-LRef-1316-T02-E 1
Tl SWA-LRef-1316-T03-E 1
Tl SWA-LRef-1316-T04-E 1
Tl SWA-LRef-1316-T01-F 1
Tl SWA-LRef-1316-T02-F 1
Tl SWA-LRef-1316-T03-F 1
Tl SWA-LRef-1316-T04-F 1
Tl SWA-LRef-1316-B01-D 1
Sample Internal
Cone. Qualifier Review
ug/L I
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 8.5E+01 4.6E+00 1.5E+01
2.30E+00 2.3E+01 4.6E+00 1.5E+01 10 100
2.30E+00 5.5E+01 4.6E+00 1.5E+01
2.30E+00 9.4E+02 4.6E+00 1.5E+01
2.30E+00 3.8E+01 4.6E+00 1.5E+01
2.30E+00 8.1E+01 4.6E+00 1.5E+01
2.30E+00 2.1E+01 4.6E+00 1.5E+01
2.30E+00 2.3E+02 4.6E+00 1.5E+01
2.30E+00 3.7E+01 4.6E+00 1.5E+01
2.30E+00 5.3E+02 4.6E+00 1.5E+01
2.30E+00 5.0E+01 4.6E+00 1.5E+01
2.30E+00 2.3E+02 4.6E+00 1.5E+01
2.30E+00 3.1E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.01E+03 100% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1595
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Ti Sample Dilution
Ti SWA-LRef-1316-T01-D 1
Ti SWA-LRef-1316-T02-D 1
Ti SWA-LRef-1316-T03-D 1
Ti SWA-LRef-1316-T04-D 1
Ti SWA-LRef-1316-T01-E 1
Ti SWA-LRef-1316-T02-E 1
Ti SWA-LRef-1316-T03-E 1
Ti SWA-LRef-1316-T04-E 1
Ti SWA-LRef-1316-T01-F 1
Ti SWA-LRef-1316-T02-F 1
Ti SWA-LRef-1316-T03-F 1
Ti SWA-LRef-1316-T04-F 1
Ti SWA-LRef-1316-B01-D 1
Sample Internal
Cone. Qualifier Review
ug/L I
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.55E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
3.03E+00 E
1.00E+00 U1/2
1.00E+00 U1/2
1.00E+00 U1/2
4.02E+00 E
1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00 10 100
1.00E+00 1.4E+01 2.0E+00 6.4E+00
3.55E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
3.03E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
4.02E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 8.6E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.07E+03 107% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1596
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
V Sample Dilution
V SWA-LRef-1316-T01-D 1
V SWA-LRef-1316-T02-D 1
V SWA-LRef-1316-T03-D 1
V SWA-LRef-1316-T04-D 1
V SWA-LRef-1316-T01-E 1
V SWA-LRef-1316-T02-E 1
V SWA-LRef-1316-T03-E 1
V SWA-LRef-1316-T04-E 1
V SWA-LRef-1316-T01-F 1
V SWA-LRef-1316-T02-F 1
V SWA-LRef-1316-T03-F 1
V SWA-LRef-1316-T04-F 1
V SWA-LRef-1316-B01-D 1
Sample I
Cone. Qualifier
ug/L I
3.62E+02
5.64E+02
1.17E+03
2.10E+03
3.16E+02
4.91 E+02
1.18E+03
1.90E+03
3.68E+02
5.47E+02
9.67E+02
2.04E+03
7.50E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.62E+02 1.7E+00 1.5E+00 4.8E+00
5.64E+02 1.4E+00 1.5E+00 4.8E+00 10 100
1.17E+03 7.0E-02 1.5E+00 4.8E+00
2.10E+03 1.9E+00 1.5E+00 4.8E+00
3.16E+02 6.8E+01 1.5E+00 4.8E+00
4.91 E+02 1.2E+00 1.5E+00 4.8E+00
1.18E+03 5.7E-01 1.5E+00 4.8E+00
1.90E+03 4.2E+00 1.5E+00 4.8E+00
3.68E+02 3.5E-01 1.5E+00 4.8E+00
5.47E+02 1.0E+00 1.5E+00 4.8E+00
9.67E+02 6.1E+01 1.5E+00 4.8E+00
2.04E+03 1.4E+00 1.5E+00 4.8E+00
7.50E-01 1.3E+02 1.5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.67E+03 111% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1597
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Zn Sample Dilution
Zn SWA-LRef-1316-T01-D 1
Zn SWA-LRef-1316-T02-D 1
Zn SWA-LRef-1316-T03-D 1
Zn SWA-LRef-1316-T04-D 1
Zn SWA-LRef-1316-T01-E 1
Zn SWA-LRef-1316-T02-E 1
Zn SWA-LRef-1316-T03-E 1
Zn SWA-LRef-1316-T04-E 1
Zn SWA-LRef-1316-T01-F 1
Zn SWA-LRef-1316-T02-F 1
Zn SWA-LRef-1316-T03-F 1
Zn SWA-LRef-1316-T04-F 1
Zn SWA-LRef-1316-B01-D 1
Sample I
Cone. Qualifier
ug/L I
5.00E-01 U1/2
3.39E+00
4.41 E+00
1.48E+01
5.00E-01 U1/2
4.73E+00
4.82E+00
1.86E+01
5.00E-01 U1/2
2.50E+00 E
3.96E+00
1.13E+01
5.00E-01 U1/2
nternal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 4.0E+01 1.0E+00 3.2E+00
3.39E+00 8.9E+00 1.0E+00 3.2E+00 10 100
4.41 E+00 1.2E+01 1.0E+00 3.2E+00
1.48E+01 3.9E+00 1.0E+00 3.2E+00
5.00E-01 7.7E+01 1.0E+00 3.2E+00
4.73E+00 6.7E+00 1.0E+00 3.2E+00
4.82E+00 9.9E+00 1.0E+00 3.2E+00
1.86E+01 7.0E+00 1.0E+00 3.2E+00
5.00E-01 2.5E+01 1.0E+00 3.2E+00
2.50E+00 1.2E+01 1.0E+00 3.2E+00
3.96E+00 2.6E+02 1.0E+00 3.2E+00
1.13E+01 2.0E+00 1.0E+00 3.2E+00
5.00E-01 2.9E+02 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 10/26/10 2:50 PM EPA Interlab LRef 1313-1316 SWA
1.08E+03 108% VU ICP-OES 10/26/10 2:52 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:54 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:55 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:57 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 2:59 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:00 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:02 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:04 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:05 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:07 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/10 3:09 PM EPA Interlab LRef 1313-1316 SWA
VU ICP-OES 10/26/102:21 PM EPA Interlab LRef 1313-1316 SWA
                                                                                                                                                                         1-1598
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al CFS-L01-1316-T01-A 1 4.94E+01
Al CFS-L01-1316-T02-A 1 4.88E+01
Al CFS-L01-1316-T03-A 1 5.23E+01
Al CFS-L01-1316-T04-A 1 5.48E+01
Al CFS-L01-1316-T05-A 1 5.49E+01
Al CFS-L01-1316-T01-B 1 4.13E+01
Al CFS-L01-1316-T02-B 1 4.39E+01
Al CFS-L01-1316-T03-B 1 4.81 E+01
Al CFS-L01-1316-T04-B 1 4.66E+01
Al CFS-L01-1316-T05-B 1 5.64E+01
Al CFS-L01-1316-T01-C 1 4.23E+01
Al CFS-L01-1316-T02-C 1 5.30E+01
Al CFS-L01-1316-T03-C 1 5.09E+01
Al CFS-L01-1316-T04-C 1 4.90E+01
Al CFS-L01-1316-T05-C 1 6.16E+01
Al CFS-L01-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.94E+01 6.6E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
4.88E+01 1.0E+01 1.0E+00 3.2E+00 1000 100 1.13E+03 108% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
5.23E+01 1.2E+01 1 .OE+00 3.2E+00
5.48E+01 1.1 E+01 1. OE+00 3.2E+00
5.49E+01 1.7E+01 1 .OE+00 3.2E+00
4.13E+01 7.1E+00 1. OE+00 3.2E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
4.39E+01 2.2E+01 1 .OE+00 3.2E+00 1000 100 1.17E+03 112% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
4.81 E+01 7.0E+00 1 .OE+00 3.2E+00
4.66E+01 1.6E+01 1 .OE+00 3.2E+00
5.64E+01 6.1E+00 1 .OE+00 3.2E+00
4.23E+01 1.4E+01 1 .OE+00 3.2E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
5.30E+01 1.1E+01 1.0E+00 3.2E+00 1000 100 1.14E+03 109% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
5.09E+01 7.7E+00 1 .OE+00 3.2E+00
4.90E+01 1.0E+01 1. OE+00 3.2E+00
6.16E+01 5.4E+00 1 .OE+00 3.2E+00
5.00E-01 4.1E+00 1. OE+00 3.2E+00
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                                 1-1599
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb CFS-L01-1316-T01-A 1 3.83E+01
Sb CFS-L01-1316-T02-A 1 3.74E+01
Sb CFS-L01-1316-T03-A 1 3.71E+01
Sb CFS-L01-1316-T04-A 1 5.63E+01
Sb CFS-L01-1316-T05-A 1 5.88E+01
Sb CFS-L01-1316-T01-B 1 3.00E+01
Sb CFS-L01-1316-T02-B 1 3.56E+01
Sb CFS-L01-1316-T03-B 1 3.81E+01
Sb CFS-L01-1316-T04-B 1 4.40E+01
Sb CFS-L01-1316-T05-B 1 6.73E+01
Sb CFS-L01-1316-T01-C 1 3.16E+01
Sb CFS-L01-1316-T02-C 1 3.46E+01
Sb CFS-L01-1316-T03-C 1 4.03E+01
Sb CFS-L01-1316-T04-C 1 5.21E+01
Sb CFS-L01-1316-T05-C 1 6.96E+01
Sb CFS-L01-1316-B01-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.83E+01 1.0E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
3.74E+01 1.1E+01 7.5E+00 2.4E+01 10 100 1.06E+03 102% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
3.71E+01 3.5E+01 7.5E+00 2.4E+01
5.63E+01 1.7E+01 7.5E+00 2.4E+01
5.88E+01 1.3E+01 7.5E+00 2.4E+01
3.00E+01 2.1E+01 7.5E+00 2.4E+01
VU ICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
3.56E+01 9.8E+00 7.5E+00 2.4E+01 10 100 1.04E+03 100% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
3.81 E+01 1.9E+01 7.5E+00 2.4E+01
4.40E+01 1.0E+01 7.5E+00 2.4E+01
6.73E+01 4.2E+00 7.5E+00 2.4E+01
3.16E+01 3.5E+01 7.5E+00 2.4E+01
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
3.46E+01 7.2E+00 7.5E+00 2.4E+01 10 100 1.06E+03 102% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
4.03E+01 2.7E+01 7.5E+00 2.4E+01
5.21E+01 1.4E+01 7.5E+00 2.4E+01
6.96E+01 7.2E+00 7.5E+00 2.4E+01
3.75E+00 3.9E+01 7.5E+00 2.4E+01
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1600
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
ug/L
As CFS-L01-1316-T01-A 1 2.57E+01 E
As CFS-L01-1316-T02-A 1 2.46E+01 E
As CFS-L01-1316-T03-A 1 3.49E+01 E
As CFS-L01-1316-T04-A 1 4.02E+01
As CFS-L01-1316-T05-A 1 5.63E+01
As CFS-L01-1316-T01-B 1 2.31E+01 E
As CFS-L01-1316-T02-B 1 2.76E+01 E
As CFS-L01-1316-T03-B 1 3.63E+01
As CFS-L01-1316-T04-B 1 4.68E+01
As CFS-L01-1316-T05-B 1 5.23E+01
As CFS-L01-1316-T01-C 1 1.98E+01 E
As CFS-L01-1316-T02-C 1 2.55E+01 E
As CFS-L01-1316-T03-C 1 3.87E+01
As CFS-L01-1316-T04-C 1 3.20E+01 E
As CFS-L01-1316-T05-C 1 4.44E+01
As CFS-L01-1316-B01-A 1 5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.57E+01 2.2E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
2.46E+01 2.4E+01 1.1E+01 3.5E+01 10 100 1 .05E+03 102% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
3.49E+01 1.9E+01 1.1E+01 3.5E+01
4.02E+01 3.8E+01 1.1E+01 3.5E+01
5.63E+01 1.5E+01 1.1E+01 3.5E+01
2.31E+01 6.0E+01 1.1E+01 3.5E+01
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
2.76E+01 3.2E+01 1.1E+01 3.5E+01 10 100 1 .09E+03 106% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
3.63E+01 1.8E+01 1.1E+01 3.5E+01
4.68E+01 2.6E+01 1.1E+01 3.5E+01
5.23E+01 3.3E+01 1.1E+01 3.5E+01
1.98E+01 4.5E+01 1.1E+01 3.5E+01
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
2.55E+01 3.7E+01 1.1E+01 3.5E+01 10 100 1 .07E+03 105% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
3.87E+01 4.2E+00 1.1E+01 3.5E+01
3.20E+01 5.1E+00 1.1E+01 3.5E+01
4.44E+01 5.4E+00 1.1E+01 3.5E+01
5.50E+00 5.9E+01 1.1E+01 3.5E+01
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1601
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B CFS-L01-1316-T01-A 1 1.51E+02
B CFS-L01-1316-T02-A 1 2.91E+02
B CFS-L01-1316-T03-A 1 6.29E+02
B CFS-L01-1316-T04-A 1 9.56E+02
B CFS-L01-1316-T05-A 1 1.50E+03
B CFS-L01-1316-T01-B 1 1.59E+02
B CFS-L01-1316-T02-B 1 2.96E+02
B CFS-L01-1316-T03-B 1 6.36E+02
B CFS-L01-1316-T04-B 1 9.76E+02
B CFS-L01-1316-T05-B 1 1.46E+03
B CFS-L01-1316-T01-C 1 1.60E+02
B CFS-L01-1316-T02-C 1 2.83E+02
B CFS-L01-1316-T03-C 1 6.01 E+02
B CFS-L01-1316-T04-C 1 9.72E+02
B CFS-L01-1316-T05-C 1 1.41E+03
B CFS-L01-1316-B01-A 1 4.51 E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.51 E+02 1.3E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
2.91E+02 8.9E-01 1 .OE+00 3.2E+00 1000 100 1 .24E+03 95% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
6.29E+02 1.3E+00 1 .OE+00 3.2E+00
9.56E+02 3.7E-01 1 .OE+00 3.2E+00
1.50E+03 6.2E-01 1 .OE+00 3.2E+00
1.59E+02 6.5E-01 1 .OE+00 3.2E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
2.96E+02 1.8E+00 1 .OE+00 3.2E+00 1000 100 1 .24E+03 95% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
6.36E+02 6.5E-01 1 .OE+00 3.2E+00
9.76E+02 2.0E-01 1 .OE+00 3.2E+00
1.46E+03 2.9E-01 1 .OE+00 3.2E+00
1.60E+02 1.1 E+00 1. OE+00 3.2E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
2.83E+02 4.6E-02 1 .OE+00 3.2E+00 1000 100 1.25E+03 97% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
6.01E+02 3.1E-01 1.0E+00 3.2E+00
9.72E+02 1.8E-01 1. OE+00 3.2E+00
1.41E+03 1.2E+00 1. OE+00 3.2E+00
4.51 E+00 2.2E+01 1. OE+00 3.2E+00
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1602
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba CFS-L01-1316-T01-A 1 8.84E+01
Ba CFS-L01-1316-T02-A 1 8.72E+01
Ba CFS-L01-1316-T03-A 1 7.71 E+01
Ba CFS-L01-1316-T04-A 1 6.53E+01
Ba CFS-L01-1316-T05-A 1 5.32E+01
Ba CFS-L01-1316-T01-B 1 9.26E+01
Ba CFS-L01-1316-T02-B 1 9.16E+01
Ba CFS-L01-1316-T03-B 1 7.80E+01
Ba CFS-L01-1316-T04-B 1 6.74E+01
Ba CFS-L01-1316-T05-B 1 5.38E+01
Ba CFS-L01-1316-T01-C 1 9.12E+01
Ba CFS-L01-1316-T02-C 1 8.78E+01
Ba CFS-L01-1316-T03-C 1 7.46E+01
Ba CFS-L01-1316-T04-C 1 6.28E+01
Ba CFS-L01-1316-T05-C 1 5.17E+01
Ba CFS-L01-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.84E+01 1.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
8.72E+01 5.1E-02 1 .OE+00 3.2E+00 10 100 1.04E+03 95% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
7.71 E+01 6.0E-01 1. OE+00 3.2E+00
6.53E+01 3.7E-01 1. OE+00 3.2E+00
5.32E+01 3.9E-01 1. OE+00 3.2E+00
9.26E+01 1.8E-01 1. OE+00 3.2E+00
VU ICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
9.16E+01 3.0E-01 1.0E+00 3.2E+00 10 100 1.02E+03 92% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
7.80E+01 2.8E-01 1. OE+00 3.2E+00
6.74E+01 3.8E-01 1. OE+00 3.2E+00
5.38E+01 1.9E-01 1. OE+00 3.2E+00
9.12E+01 4.0E-01 1. OE+00 3.2E+00
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
8.78E+01 2.1E-01 1.0E+00 3.2E+00 10 100 1.05E+03 96% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
7.46E+01 5.3E-01 1. OE+00 3.2E+00
6.28E+01 6.0E-01 1. OE+00 3.2E+00
5.17E+01 8.7E-01 1. OE+00 3.2E+00
5.00E-01 4.7E+00 1. OE+00 3.2E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1603
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be CFS-L01-1316-T01-A 1 9.50E-01 U1/2
Be CFS-L01-1316-T02-A 1 9.50E-01 U1/2
Be CFS-L01-1316-T03-A 1 9.50E-01 U1/2
Be CFS-L01-1316-T04-A 1 9.50E-01 U1/2
Be CFS-L01-1316-T05-A 1 9.50E-01 U1/2
Be CFS-L01-1316-T01-B 1 9.50E-01 U1/2
Be CFS-L01-1316-T02-B 1 9.50E-01 U1/2
Be CFS-L01-1316-T03-B 1 9.50E-01 U1/2
Be CFS-L01-1316-T04-B 1 9.50E-01 U1/2
Be CFS-L01-1316-T05-B 1 9.50E-01 U1/2
Be CFS-L01-1316-T01-C 1 9.50E-01 U1/2
Be CFS-L01-1316-T02-C 1 9.50E-01 U1/2
Be CFS-L01-1316-T03-C 1 9.50E-01 U1/2
Be CFS-L01-1316-T04-C 1 9.50E-01 U1/2
Be CFS-L01-1316-T05-C 1 9.50E-01 U1/2
Be CFS-L01-1316-B01-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.8E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
9.50E-01 4.4E+02 1.9E+00 6.0E+00 10 100 1.02E+03 102% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
9.50E-01 8.8E+01 1.9E+00 6.0E+00
9.50E-01 7.0E+01 1.9E+00 6.0E+00
9.50E-01 7.5E+01 1.9E+00 6.0E+00
9.50E-01 2.9E+01 1.9E+00 6.0E+00
VU ICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
9.50E-01 2.1E+02 1.9E+00 6.0E+00 10 100 1.09E+03 109% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
9.50E-01 1.9E+02 1.9E+00 6.0E+00
9.50E-01 6.2E+01 1.9E+00 6.0E+00
9.50E-01 6.0E+01 1.9E+00 6.0E+00
9.50E-01 2.8E+02 1.9E+00 6.0E+00
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/1 1 3:43 PM EPA Interlab L01 1313-1316 CFS
9.50E-01 9.8E+00 1.9E+00 6.0E+00 10 100 1.04E+03 104% VU ICP-OES 3/1/1 1 3:44 PM EPA Interlab L01 1313-1316 CFS
9.50E-01 1.3E+03 1.9E+00 6.0E+00
9.50E-01 4.6E+01 1.9E+00 6.0E+00
9.50E-01 3.1E+01 1.9E+00 6.0E+00
9.50E-01 4.5E+02 1.9E+00 6.0E+00
VU ICP-OES 3/1/1 1 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/1 1 3:48 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/1 1 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/1 1 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1604
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd CFS-L01-1316-T01-A 1 4.75E+03
Cd CFS-L01-1316-T02-A 1 6.69E+03
Cd CFS-L01-1316-T03-A 1 1.06E+04
Cd CFS-L01-1316-T04-A 1 1.22E+04
Cd CFS-L01-1316-T05-A 1 1.57E+04
Cd CFS-L01-1316-T01-B 1 4.95E+03
Cd CFS-L01-1316-T02-B 1 7.23E+03
Cd CFS-L01-1316-T03-B 1 1.04E+04
Cd CFS-L01-1316-T04-B 1 1.18E+04
Cd CFS-L01-1316-T05-B 1 1.51E+04
Cd CFS-L01-1316-T01-C 1 5.03E+03
Cd CFS-L01-1316-T02-C 1 7.00E+03
Cd CFS-L01-1316-T03-C 1 1.03E+04
Cd CFS-L01-1316-T04-C 1 1.22E+04
Cd CFS-L01-1316-T05-C 1 1.59E+04
Cd CFS-L01-1316-B01-A 1 1.10E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.75E+03 6.2E-01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
6.69E+03 3.9E-01 2.2E+00 7.0E+00 10 100 7.63E+03 95% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
1.06E+04 8.4E-01 2.2E+00 7.0E+00
1.22E+04 6.1E-01 2.2E+00 7.0E+00
1.57E+04 5.3E-01 2.2E+00 7.0E+00
4.95E+03 8.6E-01 2.2E+00 7.0E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
7.23E+03 1.1E+00 2.2E+00 7.0E+00 10 100 8.33E+03 110% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
1.04E+04 5.8E-01 2.2E+00 7.0E+00
1.18E+04 2.2E-01 2.2E+00 7.0E+00
1.51E+04 6.2E-01 2.2E+00 7.0E+00
5.03E+03 4.8E-01 2.2E+00 7.0E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
7.00E+03 2.6E-01 2.2E+00 7.0E+00 10 100 7.98E+03 98% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
1.03E+04 2.7E-01 2.2E+00 7.0E+00
1.22E+04 4.1E-01 2.2E+00 7.0E+00
1.59E+04 2.0E+00 2.2E+00 7.0E+00
1.10E+00 3.7E+03 2.2E+00 7.0E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1605
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca CFS-L01-1316-T01-A 1 6.71 E+05
Ca CFS-L01-1316-T02-A 1 6.38E+05
Ca CFS-L01-1316-T03-A 1 6.33E+05
Ca CFS-L01-1316-T04-A 1 5.95E+05
Ca CFS-L01-1316-T05-A 1 5.64E+05
Ca CFS-L01-1316-T01-B 1 6.93E+05
Ca CFS-L01-1316-T02-B 1 6.88E+05
Ca CFS-L01-1316-T03-B 1 6.34E+05
Ca CFS-L01-1316-T04-B 1 5.95E+05
Ca CFS-L01-1316-T05-B 1 5.67E+05
Ca CFS-L01-1316-T01-C 1 6.88E+05
Ca CFS-L01-1316-T02-C 1 6.72E+05
Ca CFS-L01-1316-T03-C 1 6.28E+05
Ca CFS-L01-1316-T04-C 1 5.90E+05
Ca CFS-L01-1316-T05-C 1 5.63E+05
Ca CFS-L01-1316-B01-A 1 7.32E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.71E+05 4.0E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
6.38E+05 7.7E-01 2.6E+00 8.3E+00 1000 100 6.39E+05 86% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
6.33E+05 4.0E-01 2.6E+00 8.3E+00
5.95E+05 5.1E-01 2.6E+00 8.3E+00
5.64E+05 9.1E-01 2.6E+00 8.3E+00
6.93E+05 7.9E-01 2.6E+00 8.3E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
6.88E+05 1.1E+00 2.6E+00 8.3E+00 1000 100 6.89E+05 83% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
6.34E+05 5.3E-01 2.6E+00 8.3E+00
5.95E+05 3.9E-01 2.6E+00 8.3E+00
5.67E+05 7.8E-01 2.6E+00 8.3E+00
6.88E+05 5.4E-01 2.6E+00 8.3E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
6.72E+05 5.5E-01 2.6E+00 8.3E+00 1000 100 6.73E+05 88% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
6.28E+05 6.6E-01 2.6E+00 8.3E+00
5.90E+05 2.9E-01 2.6E+00 8.3E+00
5.63E+05 1.3E+00 2.6E+00 8.3E+00
7.32E+01 3.5E+00 2.6E+00 8.3E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1606
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cr Sample Dilution Cone. Qualifier Revi
ug/L
Cr CFS-L01-1316-T01-A 1 6.00E-01 U1/2
Cr CFS-L01-1316-T02-A 1 6.00E-01 U1/2
Cr CFS-L01-1316-T03-A 1 6.00E-01 U1/2
Cr CFS-L01-1316-T04-A 1 6.00E-01 U1/2
Cr CFS-L01-1316-T05-A 1 6.00E-01 U1/2
Cr CFS-L01-1316-T01-B 1 6.00E-01 U1/2
Cr CFS-L01-1316-T02-B 1 6.00E-01 U1/2
Cr CFS-L01-1316-T03-B 1 6.00E-01 U1/2
Cr CFS-L01-1316-T04-B 1 6.00E-01 U1/2
Cr CFS-L01-1316-T05-B 1 6.00E-01 U1/2
Cr CFS-L01-1316-T01-C 1 6.00E-01 U1/2
Cr CFS-L01-1316-T02-C 1 6.00E-01 U1/2
Cr CFS-L01-1316-T03-C 1 6.00E-01 U1/2
Cr CFS-L01-1316-T04-C 1 6.00E-01 U1/2
Cr CFS-L01-1316-T05-C 1 6.00E-01 U1/2
Cr CFS-L01-1316-B01-A 1 6.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 3.4E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
6.00E-01 4.4E+02 1.2E+00 3.8E+00 10 100 9.76E+02 98% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
6.00E-01 5.4E+02 1.2E+00 3.8E+00
6.00E-01 1.1E+02 1.2E+00 3.8E+00
6.00E-01 1.8E+01 1.2E+00 3.8E+00
6.00E-01 1.2E+03 1.2E+00 3.8E+00
VU ICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
6.00E-01 5.4E+02 1.2E+00 3.8E+00 10 100 9.44E+02 94% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
6.00E-01 1.2E+02 1.2E+00 3.8E+00
6.00E-01 2.0E+03 1.2E+00 3.8E+00
6.00E-01 1.1E+02 1.2E+00 3.8E+00
6.00E-01 2.6E+02 1.2E+00 3.8E+00
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/1 1 3:43 PM EPA Interlab L01 1313-1316 CFS
6.00E-01 8.6E+01 1.2E+00 3.8E+00 10 100 9.77E+02 98% VU ICP-OES 3/1/1 1 3:44 PM EPA Interlab L01 1313-1316 CFS
6.00E-01 3.6E+02 1.2E+00 3.8E+00
6.00E-01 2.3E+02 1.2E+00 3.8E+00
6.00E-01 2.0E+02 1.2E+00 3.8E+00
6.00E-01 3.0E+01 1.2E+00 3.8E+00
VU ICP-OES 3/1/1 1 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/1 1 3:48 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/1 1 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/1 1 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1607
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co CFS-L01-1316-T01-A 1 9.90E+01
Co CFS-L01-1316-T02-A 1 1.73E+02
Co CFS-L01-1316-T03-A 1 3.40E+02
Co CFS-L01-1316-T04-A 1 4.64E+02
Co CFS-L01-1316-T05-A 1 7.04E+02
Co CFS-L01-1316-T01-B 1 1.03E+02
Co CFS-L01-1316-T02-B 1 1.86E+02
Co CFS-L01-1316-T03-B 1 3.40E+02
Co CFS-L01-1316-T04-B 1 4.45E+02
Co CFS-L01-1316-T05-B 1 6.82E+02
Co CFS-L01-1316-T01-C 1 1.07E+02
Co CFS-L01-1316-T02-C 1 1.78E+02
Co CFS-L01-1316-T03-C 1 3.40E+02
Co CFS-L01-1316-T04-C 1 4.67E+02
Co CFS-L01-1316-T05-C 1 7.21E+02
Co CFS-L01-1316-B01-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.90E+01 1.4E+00 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.73E+02 9.1E-01 1 .8E+00 5.7E+00 10 100 1.10E+03 93% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
3.40E+02 9.9E-01 1 .8E+00 5.7E+00
4.64E+02 6.4E-01 1 .8E+00 5.7E+00
7.04E+02 9.3E-01 2.0E+00 6.4E+00
1.03E+02 7.9E-01 2.0E+00 6.4E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
1.86E+02 1.0E+00 2.0E+00 6.4E+00 10 100 1.10E+03 92% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
3.40E+02 2.8E-01 2.0E+00 6.4E+00
4.45E+02 1.7E-01 2.0E+00 6.4E+00
6.82E+02 1.5E+00 2.0E+00 6.4E+00
1.07E+02 2.3E+00 2.0E+00 6.4E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.78E+02 2.9E-01 2.0E+00 6.4E+00 10 100 1.12E+03 94% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
3.40E+02 8.2E-01 2.0E+00 6.4E+00
4.67E+02 3.2E-01 2.0E+00 6.4E+00
7.21 E+02 8.5E-01 2.0E+00 6.4E+00
9.00E-01 3.1E+01 1.8E+00 5.7E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1608
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu CFS-L01-1316-T01-A 1 8.89E+02
Cu CFS-L01-1316-T02-A 1 1.09E+03
Cu CFS-L01-1316-T03-A 1 1.73E+03
Cu CFS-L01-1316-T04-A 1 2.19E+03
Cu CFS-L01-1316-T05-A 1 3.01 E+03
Cu CFS-L01-1316-T01-B 1 9.39E+02
Cu CFS-L01-1316-T02-B 1 8.85E+02
Cu CFS-L01-1316-T03-B 1 1.31 E+03
Cu CFS-L01-1316-T04-B 1 2.04E+03
Cu CFS-L01-1316-T05-B 1 3.09E+03
Cu CFS-L01-1316-T01-C 1 9.65E+02
Cu CFS-L01-1316-T02-C 1 8.92E+02
Cu CFS-L01-1316-T03-C 1 1.61 E+03
Cu CFS-L01-1316-T04-C 1 1.94E+03
Cu CFS-L01-1316-T05-C 1 3.13E+03
Cu CFS-L01-1316-B01-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.89E+02 1.5E-01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.09E+03 2.7E-01 3.7E+00 1.2E+01 10 100 2.01E+03 93% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
1.73E+03 1.2E+00 3.7E+00 1.2E+01
2.19E+03 6.0E-01 3.7E+00 1.2E+01
3.01E+03 7.1E-01 2.0E+00 6.4E+00
9.39E+02 9.3E-01 2.0E+00 6.4E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
8.85E+02 1.8E+00 2.0E+00 6.4E+00 10 100 1.84E+03 95% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
1.31 E+03 1.2E+00 2.0E+00 6.4E+00
2.04E+03 3.7E-02 2.0E+00 6.4E+00
3.09E+03 5.3E-01 2.0E+00 6.4E+00
9.65E+02 4.9E-01 2.0E+00 6.4E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
8.92E+02 6.5E-01 2.0E+00 6.4E+00 10 100 1.79E+03 90% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
1.61 E+03 4.2E-01 2.0E+00 6.4E+00
1.94E+03 2.5E-01 2.0E+00 6.4E+00
3.13E+03 1.6E+00 2.0E+00 6.4E+00
1.85E+00 9.7E+02 3.7E+00 1.2E+01
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1609
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe CFS-L01-1316-T01-A 1 1.00E+OOU1/2
Fe CFS-L01-1316-T02-A 1 1.00E+OOU1/2
Fe CFS-L01-1316-T03-A 1 1.00E+OOU1/2
Fe CFS-L01-1316-T04-A 1 1.00E+OOU1/2
Fe CFS-L01-1316-T05-A 1 1.00E+OOU1/2
Fe CFS-L01-1316-T01-B 1 1.00E+OOU1/2
Fe CFS-L01-1316-T02-B 1 1.00E+OOU1/2
Fe CFS-L01-1316-T03-B 1 1.00E+OOU1/2
Fe CFS-L01-1316-T04-B 1 1.00E+OOU1/2
Fe CFS-L01-1316-T05-B 1 1.00E+OOU1/2
Fe CFS-L01-1316-T01-C 1 1.00E+OOU1/2
Fe CFS-L01-1316-T02-C 1 1.00E+OOU1/2
Fe CFS-L01-1316-T03-C 1 1.00E+OOU1/2
Fe CFS-L01-1316-T04-C 1 1.00E+OOU1/2
Fe CFS-L01-1316-T05-C 1 1.00E+OOU1/2
Fe CFS-L01-1316-B01-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.9E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 9.3E+01 2.0E+00 6.4E+00 1000 100 1.01E+03 101% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 1.2E+02 2.0E+00 6.4E+00 1000 100 1.07E+03 107% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
1.00E+00 5.5E+02 2.0E+00 6.4E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 1.2E+02 2.0E+00 6.4E+00 1000 100 1.01E+03 101% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 7.6E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+02 2.0E+00 6.4E+00
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1610
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb CFS-L01-1316-T01-A 1 1.18E+03
Pb CFS-L01-1316-T02-A 1 1.27E+03
Pb CFS-L01-1316-T03-A 1 1.49E+03
Pb CFS-L01-1316-T04-A 1 1.44E+03
Pb CFS-L01-1316-T05-A 1 1.35E+03
Pb CFS-L01-1316-T01-B 1 1.24E+03
Pb CFS-L01-1316-T02-B 1 1.29E+03
Pb CFS-L01-1316-T03-B 1 1.32E+03
Pb CFS-L01-1316-T04-B 1 1.48E+03
Pb CFS-L01-1316-T05-B 1 1.40E+03
Pb CFS-L01-1316-T01-C 1 1.21E+03
Pb CFS-L01-1316-T02-C 1 1.09E+03
Pb CFS-L01-1316-T03-C 1 1.38E+03
Pb CFS-L01-1316-T04-C 1 1.40E+03
Pb CFS-L01-1316-T05-C 1 1.32E+03
Pb CFS-L01-1316-B01-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+03 6.0E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.27E+03 5.3E-01 6.8E+00 2.2E+01 10 100 2.14E+03 87% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
1.49E+03 1.3E+00 6.8E+00 2.2E+01
1.44E+03 4.1E-01 6.8E+00 2.2E+01
1.35E+03 3.4E-01 6.8E+00 2.2E+01
1.24E+03 8.5E-01 6.8E+00 2.2E+01
VU ICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
1.29E+03 5.1E-01 6.8E+00 2.2E+01 10 100 2.13E+03 83% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
1.32E+03 1.1E+00 6.8E+00 2.2E+01
1.48E+03 5.5E-01 6.8E+00 2.2E+01
1.40E+03 1.6E+00 6.8E+00 2.2E+01
1.21E+03 9.1E-01 6.8E+00 2.2E+01
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.09E+03 6.9E-01 6.8E+00 2.2E+01 10 100 1.95E+03 85% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
1.38E+03 4.9E-01 6.8E+00 2.2E+01
1.40E+03 8.4E-01 6.8E+00 2.2E+01
1.32E+03 1.4E+00 6.8E+00 2.2E+01
3.40E+00 1.4E+01 6.8E+00 2.2E+01
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1611
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li CFS-L01-1316-T01-A 1 9.77E+00
Li CFS-L01-1316-T02-A 1 1.09E+01
Li CFS-L01-1316-T03-A 1 4.49E+00 E
Li CFS-L01-1316-T04-A 1 8.54E+00
Li CFS-L01-1316-T05-A 1 2.12E+01
Li CFS-L01-1316-T01-B 1 8.88E+00
Li CFS-L01-1316-T02-B 1 7.59E+00
Li CFS-L01-1316-T03-B 1 4.91E+00 E
Li CFS-L01-1316-T04-B 1 8.23E+00
Li CFS-L01-1316-T05-B 1 2.04E+01
Li CFS-L01-1316-T01-C 1 9.03E+00
Li CFS-L01-1316-T02-C 1 1.07E+01
Li CFS-L01-1316-T03-C 1 4.38E+00 E
Li CFS-L01-1316-T04-C 1 9.96E+00
Li CFS-L01-1316-T05-C 1 2.16E+01
Li CFS-L01-1316-B01-A 1 9.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.77E+00 2.1E+01 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.09E+01 1.2E+01 1.9E+00 6.0E+00 10 100 8.34E+02 82% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
4.49E+00 1.5E+01 1 .9E+00 6.0E+00
8.54E+00 1.0E+01 1 .9E+00 6.0E+00
2.12E+01 7.7E+00 1 .9E+00 6.0E+00
8.88E+00 1.1E+01 1.9E+00 6.0E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
7.59E+00 1.5E+01 1.9E+00 6.0E+00 10 100 8.59E+02 85% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
4.91 E+00 1.1E+01 1.9E+00 6.0E+00
8.23E+00 1.5E+01 1.9E+00 6.0E+00
2.04E+01 6.2E+00 1.9E+00 6.0E+00
9.03E+00 2.5E+01 1.9E+00 6.0E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.07E+01 1.4E+01 1.9E+00 6.0E+00 10 100 8.47E+02 84% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
4.38E+00 1.0E+01 1.9E+00 6.0E+00
9.96E+00 7.7E+00 1.9E+00 6.0E+00
2.16E+01 1.5E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+01 1.9E+00 6.0E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1612
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn CFS-L01-1316-T01-A 1 1.58E+03
Mn CFS-L01-1316-T02-A 1 3.05E+03
Mn CFS-L01-1316-T03-A 1 6.82E+03
Mn CFS-L01-1316-T04-A 1 1.03E+04
Mn CFS-L01-1316-T05-A 1 1.79E+04
Mn CFS-L01-1316-T01-B 1 1.64E+03
Mn CFS-L01-1316-T02-B 1 3.30E+03
Mn CFS-L01-1316-T03-B 1 6.96E+03
Mn CFS-L01-1316-T04-B 1 9.98E+03
Mn CFS-L01-1316-T05-B 1 1.73E+04
Mn CFS-L01-1316-T01-C 1 1.71E+03
Mn CFS-L01-1316-T02-C 1 3.13E+03
Mn CFS-L01-1316-T03-C 1 6.85E+03
Mn CFS-L01-1316-T04-C 1 1.04E+04
Mn CFS-L01-1316-T05-C 1 1.79E+04
Mn CFS-L01-1316-B01-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.58E+03 1.6E+00 2.0E+00 6.4E+00
3.05E+03 3.8E-01 2.0E+00 6.4E+00 10 100
6.82E+03 8.4E-01 2.0E+00 6.4E+00
1.03E+04 7.1E-01 2.0E+00 6.4E+00
1.79E+04 5.6E-01 2.0E+00 6.4E+00
1.64E+03 4.9E-01 2.0E+00 6.4E+00
3.30E+03 9.4E-01 2.0E+00 6.4E+00 10 100
6.96E+03 7.9E-01 2.0E+00 6.4E+00
9.98E+03 2.3E-01 2.0E+00 6.4E+00
1.73E+04 1.2E+00 2.0E+00 6.4E+00
1.71E+03 1.2E+00 2.0E+00 6.4E+00
3.13E+03 3.0E-01 2.0E+00 6.4E+00 10 100
6.85E+03 1.1E+00 2.0E+00 6.4E+00
1.04E+04 4.9E-01 2.0E+00 6.4E+00
1.79E+04 1.2E+00 2.0E+00 6.4E+00
1.00E+00 7.4E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
4.04E+03 99% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
4.25E+03 95% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
4.18E+03 105% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1613
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg CFS-L01-1316-T01-A 1 6.18E+04
Mg CFS-L01-1316-T02-A 1 1.23E+05
Mg CFS-L01-1316-T03-A 1 2.76E+05
Mg CFS-L01-1316-T04-A 1 4.81 E+05
Mg CFS-L01-1316-T05-A 1 8.35E+05
Mg CFS-L01-1316-T01-B 1 6.38E+04
Mg CFS-L01-1316-T02-B 1 1.30E+05
Mg CFS-L01-1316-T03-B 1 2.85E+05
Mg CFS-L01-1316-T04-B 1 4.90E+05
Mg CFS-L01-1316-T05-B 1 8.39E+05
Mg CFS-L01-1316-T01-C 1 6.32E+04
Mg CFS-L01-1316-T02-C 1 1.22E+05
Mg CFS-L01-1316-T03-C 1 2.85E+05
Mg CFS-L01-1316-T04-C 1 4.88E+05
Mg CFS-L01-1316-T05-C 1 8.49E+05
Mg CFS-L01-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.18E+04 5.9E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.23E+05 6.3E-01 1 .OE+00 3.2E+00 1000 100 1.24E+05 92% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
2.76E+05 1. OE+00 1. OE+00 3.2E+00
4.81 E+05 4.9E-01 1. OE+00 3.2E+00
8.35E+05 1.3E+00 1. OE+00 3.2E+00
6.38E+04 1.6E-01 1. OE+00 3.2E+00
VU ICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
1.30E+05 9.1E-01 1.0E+00 3.2E+00 1000 100 1.31E+05 88% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
2.85E+05 7.8E-01 1. OE+00 3.2E+00
4.90E+05 3.2E-01 1. OE+00 3.2E+00
8.39E+05 1.2E+00 1. OE+00 3.2E+00
6.32E+04 9.4E-01 1. OE+00 3.2E+00
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.22E+05 1.2E+00 1.0E+00 3.2E+00 1000 100 1.23E+05 96% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
2.85E+05 1.3E+00 1. OE+00 3.2E+00
4.88E+05 1.9E-01 1. OE+00 3.2E+00
8.49E+05 1.1E+00 1. OE+00 3.2E+00
5.00E-01 3.6E+01 1. OE+00 3.2E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1614
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo CFS-L01-1316-T01-A 1 6.97E+00
Mo CFS-L01-1316-T02-A 1 1.21E+01
Mo CFS-L01-1316-T03-A 1 1.34E+01
Mo CFS-L01-1316-T04-A 1 1.70E+01
Mo CFS-L01-1316-T05-A 1 2.49E+01
Mo CFS-L01-1316-T01-B 1 7.95E+00
Mo CFS-L01-1316-T02-B 1 1.06E+01
Mo CFS-L01-1316-T03-B 1 1.49E+01
Mo CFS-L01-1316-T04-B 1 1.51E+01
Mo CFS-L01-1316-T05-B 1 2.05E+01
Mo CFS-L01-1316-T01-C 1 7.90E+00
Mo CFS-L01-1316-T02-C 1 1.01E+01
Mo CFS-L01-1316-T03-C 1 1.30E+01
Mo CFS-L01-1316-T04-C 1 1.56E+01
Mo CFS-L01-1316-T05-C 1 1.94E+01
Mo CFS-L01-1316-B01-A 1 1.74E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.97E+00 1.1E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.21E+01 7.4E+00 1.2E+00 3.8E+00 10 100 9.69E+02 96% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
1.34E+01 6.0E+00 1.2E+00 3.8E+00
1.70E+01 1.4E+01 1.2E+00 3.8E+00
2.49E+01 3.3E+00 1.2E+00 3.8E+00
7.95E+00 2.1E+01 1.2E+00 3.8E+00
VU ICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
1.06E+01 1.1E+01 1.2E+00 3.8E+00 10 100 9.54E+02 94% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
1.49E+01 8.7E+00 1.2E+00 3.8E+00
1.51E+01 5.6E+00 1.2E+00 3.8E+00
2.05E+01 8.8E+00 1.2E+00 3.8E+00
7.90E+00 1.5E+01 1.2E+00 3.8E+00
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.01E+01 2.9E+00 1.2E+00 3.8E+00 10 100 9.88E+02 98% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
1.30E+01 9.5E+00 1.2E+00 3.8E+00
1.56E+01 1.6E+01 1.2E+00 3.8E+00
1.94E+01 6.5E+00 1.2E+00 3.8E+00
1.74E+00 5.1E+01 1.2E+00 3.8E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1615
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni CFS-L01-1316-T01-A 1 2.24E+02
Ni CFS-L01-1316-T02-A 1 3.71 E+02
Ni CFS-L01-1316-T03-A 1 6.56E+02
Ni CFS-L01-1316-T04-A 1 8.47E+02
Ni CFS-L01-1316-T05-A 1 1.17E+03
Ni CFS-L01-1316-T01-B 1 2.40E+02
Ni CFS-L01-1316-T02-B 1 3.98E+02
Ni CFS-L01-1316-T03-B 1 6.43E+02
Ni CFS-L01-1316-T04-B 1 8.12E+02
Ni CFS-L01-1316-T05-B 1 1.15E+03
Ni CFS-L01-1316-T01-C 1 2.40E+02
Ni CFS-L01-1316-T02-C 1 3.81 E+02
Ni CFS-L01-1316-T03-C 1 6.60E+02
Ni CFS-L01-1316-T04-C 1 8.39E+02
Ni CFS-L01-1316-T05-C 1 1.22E+03
Ni CFS-L01-1316-B01-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.24E+02 7.9E-01 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
3.71E+02 6.2E-01 1 .8E+00 5.7E+00 10 100 1.32E+03 94% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
6.56E+02 6.8E-01 1 .8E+00 5.7E+00
8.47E+02 6.4E-01 1 .8E+00 5.7E+00
1.17E+03 6.9E-01 3.7E+00 1.2E+01
2.40E+02 6.7E-01 3.7E+00 1.2E+01
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
3.98E+02 1.3E+00 3.7E+00 1.2E+01 10 100 1.31E+03 91%VUICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
6.43E+02 9.4E-02 3.7E+00 1.2E+01
8.12E+02 3.8E-01 3.7E+00 1.2E+01
1.15E+03 6.2E-01 3.7E+00 1.2E+01
2.40E+02 1.6E+00 3.7E+00 1.2E+01
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
3.81E+02 9.6E-01 3.7E+00 1.2E+01 10 100 1.33E+03 95% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
6.60E+02 3.9E-01 3.7E+00 1.2E+01
8.39E+02 2.1E-01 3.7E+00 1.2E+01
1.22E+03 1.2E+00 3.7E+00 1.2E+01
9.00E-01 6.0E+02 1.8E+00 5.7E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1616
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P CFS-L01-1316-T01-A 1 1.83E+01
P CFS-L01-1316-T02-A 1 1.44E+01
P CFS-L01-1316-T03-A 1 2.84E+01
P CFS-L01-1316-T04-A 1 2.71E+01
P CFS-L01-1316-T05-A 1 3.83E+01
P CFS-L01-1316-T01-B 1 1.01E+01 E
P CFS-L01-1316-T02-B 1 3.31 E+01
P CFS-L01-1316-T03-B 1 2.52E+01
P CFS-L01-1316-T04-B 1 1.78E+01
P CFS-L01-1316-T05-B 1 1.82E+01
P CFS-L01-1316-T01-C 1 1.00E+01 E
P CFS-L01-1316-T02-C 1 1.44E+01
P CFS-L01-1316-T03-C 1 1.73E+01
P CFS-L01-1316-T04-C 1 3.08E+01
P CFS-L01-1316-T05-C 1 3.80E+01
P CFS-L01-1316-B01-A 1 4.13E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.83E+01 5.2E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.44E+01 4.8E+01 3.7E+00 1.2E+01 1000 100 1.11E+03 109% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
2.84E+01 2.7E+01 3.7E+00 1.2E+01
2.71E+01 5.8E+01 3.7E+00 1.2E+01
3.83E+01 3.9E+01 3.7E+00 1.2E+01
1.01 E+01 1.3E+02 3.7E+00 1.2E+01
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
3.31E+01 1.3E+02 3.7E+00 1.2E+01 1000 100 1.13E+03 1 10% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
2.52E+01 8.0E+01 3.7E+00 1.2E+01
1.78E+01 6.4E+01 3.7E+00 1.2E+01
1.82E+01 5.7E+01 3.7E+00 1.2E+01
1.00E+01 8.1 E+01 3.7E+00 1.2E+01
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.44E+01 1.8E+01 3.7E+00 1.2E+01 1000 100 1.11E+03 110% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
1.73E+01 6.9E+01 3.7E+00 1.2E+01
3.08E+01 5.2E+01 3.7E+00 1.2E+01
3.80E+01 4.6E+01 3.7E+00 1.2E+01
4.13E+00 1.3E+02 3.7E+00 1.2E+01
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1617
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
ug/L
K CFS-L01-1316-T01-A 1 9.04E+03
K CFS-L01-1316-T02-A 1 1.64E+04
K CFS-L01-1316-T03-A 1 3.35E+04
K CFS-L01-1316-T04-A 1 5.03E+04
K CFS-L01-1316-T05-A 1 8.00E+04
K CFS-L01-1316-T01-B 1 9.35E+03
K CFS-L01-1316-T02-B 1 1.74E+04
K CFS-L01-1316-T03-B 1 3.37E+04
K CFS-L01-1316-T04-B 1 5.06E+04
K CFS-L01-1316-T05-B 1 7.85E+04
K CFS-L01-1316-T01-C 1 9.24E+03
K CFS-L01-1316-T02-C 1 1.67E+04
K CFS-L01-1316-T03-C 1 3.30E+04
K CFS-L01-1316-T04-C 1 5.07E+04
K CFS-L01-1316-T05-C 1 7.89E+04
K CFS-L01-1316-B01-A 1 1.81E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.04E+03 7.7E-01 1 .6E+00 5.1E+00
1.64E+04 3.5E-01 1 .6E+00 5.1E+00 1000 100
3.35E+04 1.2E+00 1 .6E+00 5.1E+00
5.03E+04 7.5E-01 1 .6E+00 5.1E+00
8.00E+04 6.6E-01 1 .6E+00 5.1E+00
9.35E+03 8.1E-01 1 .6E+00 5.1E+00
1.74E+04 1.3E+00 1 .6E+00 5.1E+00 1000 100
3.37E+04 1.2E+00 1 .6E+00 5.1E+00
5.06E+04 1.3E-01 1 .6E+00 5.1E+00
7.85E+04 7.8E-01 1 .6E+00 5.1E+00
9.24E+03 4.0E-01 1 .6E+00 5.1E+00
1.67E+04 5.2E-01 1 .6E+00 5.1E+00 1000 100
3.30E+04 5.7E-01 1.6E+00 5.1E+00
5.07E+04 3.4E-01 1.6E+00 5.1E+00
7.89E+04 1.5E+00 1.6E+00 5.1E+00
1.81E+01 1.9E+01 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.73E+04 84% VUICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
1.83E+04 91%VUICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.76E+04 90% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1618
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se CFS-L01-1316-T01-A 1 7.19E+01
Se CFS-L01-1316-T02-A 1 1.34E+02
Se CFS-L01-1316-T03-A 1 2.50E+02
Se CFS-L01-1316-T04-A 1 4.51 E+02
Se CFS-L01-1316-T05-A 1 7.73E+02
Se CFS-L01-1316-T01-B 1 6.49E+01
Se CFS-L01-1316-T02-B 1 1.41 E+02
Se CFS-L01-1316-T03-B 1 2.73E+02
Se CFS-L01-1316-T04-B 1 4.54E+02
Se CFS-L01-1316-T05-B 1 7.77E+02
Se CFS-L01-1316-T01-C 1 8.07E+01
Se CFS-L01-1316-T02-C 1 1.28E+02
Se CFS-L01-1316-T03-C 1 2.78E+02
Se CFS-L01-1316-T04-C 1 4.49E+02
Se CFS-L01-1316-T05-C 1 8.13E+02
Se CFS-L01-1316-B01-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.19E+01 2.2E+01 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.34E+02 1.3E+01 1 .5E+01 4.8E+01 10 100 1.09E+03 96% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
2.50E+02 6.5E+00 1.5E+01 4.8E+01
4.51 E+02 1.4E+00 1.5E+01 4.8E+01
7.73E+02 1.8E+00 1.5E+01 4.8E+01
6.49E+01 2.7E+01 1.5E+01 4.8E+01
VU ICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
1.41 E+02 1.5E+01 1.5E+01 4.8E+01 10 100 1.10E+03 96% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
2.73E+02 3.2E+00 1.5E+01 4.8E+01
4.54E+02 5.6E-01 1.5E+01 4.8E+01
7.77E+02 2.7E+00 1.5E+01 4.8E+01
8.07E+01 2.4E+01 1.5E+01 4.8E+01
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.28E+02 4.6E+00 1.5E+01 4.8E+01 10 100 1.13E+03 101% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
2.78E+02 4.5E+00 1.5E+01 4.8E+01
4.49E+02 1.6E+00 1.5E+01 4.8E+01
8.13E+02 1.2E+00 1.5E+01 4.8E+01
7.50E+00 8.7E+01 1.5E+01 4.8E+01
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1619
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si CFS-L01-1316-T01-A 1 3.98E+03
Si CFS-L01-1316-T02-A 1 5.40E+03
Si CFS-L01-1316-T03-A 1 7.14E+03
Si CFS-L01-1316-T04-A 1 7.25E+03
Si CFS-L01-1316-T05-A 1 8.02E+03
Si CFS-L01-1316-T01-B 1 4.13E+03
Si CFS-L01-1316-T02-B 1 5.68E+03
Si CFS-L01-1316-T03-B 1 6.86E+03
Si CFS-L01-1316-T04-B 1 7.31E+03
Si CFS-L01-1316-T05-B 1 7.71E+03
Si CFS-L01-1316-T01-C 1 3.99E+03
Si CFS-L01-1316-T02-C 1 5.27E+03
Si CFS-L01-1316-T03-C 1 6.73E+03
Si CFS-L01-1316-T04-C 1 7.09E+03
Si CFS-L01-1316-T05-C 1 7.70E+03
Si CFS-L01-1316-B01-A 1 2.27E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.98E+03 5.2E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
5.40E+03 3.1E-02 1.1E+00 3.5E+00 1000 100 6.38E+03 98% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
7.14E+03 7.9E-01 1.1E+00 3.5E+00
7.25E+03 4.5E-01 1.1E+00 3.5E+00
8.02E+03 6.4E-01 1.1E+00 3.5E+00
4.13E+03 8.8E-01 1.1E+00 3.5E+00
VU ICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
5.68E+03 9.6E-01 1.1E+00 3.5E+00 1000 100 6.63E+03 95% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
6.86E+03 7.1E-01 1.1E+00 3.5E+00
7.31 E+03 1.2E-01 1.1E+00 3.5E+00
7.71 E+03 9.8E-01 1.1E+00 3.5E+00
3.99E+03 9.1E-01 1.1E+00 3.5E+00
VU ICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
5.27E+03 5.4E-01 1.1E+00 3.5E+00 1000 100 6.24E+03 96% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
6.73E+03 1.1E+00 1.1E+00 3.5E+00
7.09E+03 2.4E-01 1.1E+00 3.5E+00
7.70E+03 1.0E+00 1.1E+00 3.5E+00
2.27E+00 4.1E+01 1.1E+00 3.5E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1620
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na CFS-L01-1316-T01-A 1 1.71E+04
Na CFS-L01-1316-T02-A 1 3.34E+04
Na CFS-L01-1316-T03-A 1 6.88E+04
Na CFS-L01-1316-T04-A 1 1.03E+05
Na CFS-L01-1316-T05-A 1 1.53E+05
Na CFS-L01-1316-T01-B 1 1.78E+04
Na CFS-L01-1316-T02-B 1 3.34E+04
Na CFS-L01-1316-T03-B 1 6.96E+04
Na CFS-L01-1316-T04-B 1 1.02E+05
Na CFS-L01-1316-T05-B 1 1.52E+05
Na CFS-L01-1316-T01-C 1 1.79E+04
Na CFS-L01-1316-T02-C 1 3.25E+04
Na CFS-L01-1316-T03-C 1 7.02E+04
Na CFS-L01-1316-T04-C 1 1.03E+05
Na CFS-L01-1316-T05-C 1 1.55E+05
Na CFS-L01-1316-B01-A 1 1.25E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.71E+04 9.1E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
3.34E+04 4.7E-01 2.5E+00 8.0E+00 1000 100 3.43E+04 90% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
6.88E+04 1.1E+00 2.5E+00 8.0E+00
1.03E+05 9.6E-01 2.5E+00 8.0E+00
1.53E+05 1.2E+00 2.5E+00 8.0E+00
1.78E+04 5.5E-01 2.5E+00 8.0E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
3.34E+04 1.4E+00 2.5E+00 8.0E+00 1000 100 3.43E+04 88% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
6.96E+04 3.2E-01 2.5E+00 8.0E+00
1.02E+05 3.2E-01 2.5E+00 8.0E+00
1.52E+05 1.3E+00 2.5E+00 8.0E+00
1.79E+04 1.3E+00 2.5E+00 8.0E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
3.25E+04 4.6E-01 2.5E+00 8.0E+00 1000 100 3.34E+04 91% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
7.02E+04 3.2E-01 2.5E+00 8.0E+00
1.03E+05 1.8E-01 2.5E+00 8.0E+00
1.55E+05 1.6E+00 2.5E+00 8.0E+00
1.25E+00 6.0E+01 2.5E+00 8.0E+00
VU ICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1621
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L01-1316-T01-A 1 1.41E+03
CFS-L01-1316-T02-A 1 2.07E+03
CFS-L01-1316-T03-A 1 3.25E+03
CFS-L01-1316-T04-A 1 3.93E+03
CFS-L01-1316-T05-A 1 5.00E+03
CFS-L01-1316-T01-B 1 1.45E+03
CFS-L01-1316-T02-B 1 2.29E+03
CFS-L01-1316-T03-B 1 3.31 E+03
CFS-L01-1316-T04-B 1 4.13E+03
CFS-L01-1316-T05-B 1 5.04E+03
CFS-L01-1316-T01-C 1 1.43E+03
CFS-L01-1316-T02-C 1 2.12E+03
CFS-L01-1316-T03-C 1 3.17E+03
CFS-L01-1316-T04-C 1 4.07E+03
CFS-L01-1316-T05-C 1 4.80E+03
CFS-L01-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.41 E+03 3.7E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
2.07E+03 1.9E-01 1 .OE+00 3.2E+00 1000 100 2.92E+03 86% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
3.25E+03 6.0E-01 1 .OE+00 3.2E+00
3.93E+03 8.3E-01 1 .OE+00 3.2E+00
5.00E+03 7.7E-01 1 .OE+00 3.2E+00
1.45E+03 9.1E-01 1 .OE+00 3.2E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
2.29E+03 7.1E-01 1 .OE+00 3.2E+00 1000 100 3.13E+03 84% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
3.31 E+03 7.4E-01 1 .OE+00 3.2E+00
4.13E+03 3.5E-01 1 .OE+00 3.2E+00
5.04E+03 1.7E+00 1 .OE+00 3.2E+00
1.43E+03 7.1E-01 1 .OE+00 3.2E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
2.12E+03 7.8E-01 1 .OE+00 3.2E+00 1000 100 3.05E+03 92% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
3.17E+03 6.2E-01 1. OE+00 3.2E+00
4.07E+03 8.3E-01 1. OE+00 3.2E+00
4.80E+03 7.1E-01 1.0E+00 3.2E+00
5.00E-01 2.9E+01 1. OE+00 3.2E+00
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1622
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S CFS-L01-1316-T01-A 1 6.22E+05
S CFS-L01-1316-T02-A 1 7.06E+05
S CFS-L01-1316-T03-A 1 8.63E+05
S CFS-L01-1316-T04-A 1 1.09E+06
S CFS-L01-1316-T05-A 1 1.47E+06
S CFS-L01-1316-T01-B 1 6.17E+05
S CFS-L01-1316-T02-B 1 7.02E+05
S CFS-L01-1316-T03-B 1 8.75E+05
S CFS-L01-1316-T04-B 1 1.09E+06
S CFS-L01-1316-T05-B 1 1.47E+06
S CFS-L01-1316-T01-C 1 6.12E+05
S CFS-L01-1316-T02-C 1 6.84E+05
S CFS-L01-1316-T03-C 1 8.77E+05
S CFS-L01-1316-T04-C 1 1.09E+06
S CFS-L01-1316-T05-C 1 1.48E+06
S CFS-L01-1316-B01-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.22E+05 7.8E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
7.06E+05 7.7E-01 6.8E+00 2.2E+01 1000 100 7.07E+05 86% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
8.63E+05 1.0E+00 6.8E+00 2.2E+01
1.09E+06 6.6E-01 6.8E+00 2.2E+01
1.47E+06 4.0E-01 6.8E+00 2.2E+01
6.17E+05 7.3E-01 6.8E+00 2.2E+01
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
7.02E+05 1.1E+00 6.8E+00 2.2E+01 1000 100 7.02E+05 83% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
8.75E+05 4.2E-01 6.8E+00 2.2E+01
1.09E+06 8.6E-02 6.8E+00 2.2E+01
1.47E+06 7.4E-01 6.8E+00 2.2E+01
6.12E+05 5.9E-01 6.8E+00 2.2E+01
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
6.84E+05 4.2E-01 6.8E+00 2.2E+01 1000 100 6.85E+05 89% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
8.77E+05 8.9E-02 6.8E+00 2.2E+01
1.09E+06 1.5E-01 6.8E+00 2.2E+01
1.48E+06 1.2E+00 6.8E+00 2.2E+01
3.40E+00 3.6E+02 6.8E+00 2.2E+01
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1623
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
ug/L
Tl CFS-L01-1316-T01-A 1 3.32E+02
Tl CFS-L01-1316-T02-A 1 5.25E+02
Tl CFS-L01-1316-T03-A 1 8.91 E+02
Tl CFS-L01-1316-T04-A 1 1.13E+03
Tl CFS-L01-1316-T05-A 1 1.55E+03
Tl CFS-L01-1316-T01-B 1 3.54E+02
Tl CFS-L01-1316-T02-B 1 5.47E+02
Tl CFS-L01-1316-T03-B 1 8.86E+02
Tl CFS-L01-1316-T04-B 1 1.15E+03
Tl CFS-L01-1316-T05-B 1 1.51E+03
Tl CFS-L01-1316-T01-C 1 3.50E+02
Tl CFS-L01-1316-T02-C 1 5.00E+02
Tl CFS-L01-1316-T03-C 1 8.53E+02
Tl CFS-L01-1316-T04-C 1 1.12E+03
Tl CFS-L01-1316-T05-C 1 1.48E+03
Tl CFS-L01-1316-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.32E+02 2.3E+00 4.6E+00 1.5E+01
5.25E+02 7.3E-01 4.6E+00 1.5E+01 10 100
8.91 E+02 7.3E-01 4.6E+00 1.5E+01
1.13E+03 8.5E-01 4.6E+00 1.5E+01
1.55E+03 1.6E-01 1 .5E+00 4.8E+00
3.54E+02 5.3E-01 1 .5E+00 4.8E+00
5.47E+02 2.0E+00 1 .5E+00 4.8E+00 10 100
8.86E+02 1.3E+00 1 .5E+00 4.8E+00
1.15E+03 4.3E-01 1 .5E+00 4.8E+00
1.51E+03 7.1E-01 1.5E+00 4.8E+00
3.50E+02 3.0E+00 1 .5E+00 4.8E+00
5.00E+02 7.2E-01 1 .5E+00 4.8E+00 10 100
8.53E+02 5.3E-02 1.5E+00 4.8E+00
1.12E+03 5.4E-01 1.5E+00 4.8E+00
1.48E+03 4.7E-01 1.5E+00 4.8E+00
2.30E+00 2.7E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.39E+03 87% VUICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
1.43E+03 88% VUICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.41E+03 91%VUICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1624
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti CFS-L01-1316-T01-A 1 1.00E+OOU1/2
Ti CFS-L01-1316-T02-A 1 1.00E+OOU1/2
Ti CFS-L01-1316-T03-A 1 1.00E+OOU1/2
Ti CFS-L01-1316-T04-A 1 1.00E+OOU1/2
Ti CFS-L01-1316-T05-A 1 1.00E+OOU1/2
Ti CFS-L01-1316-T01-B 1 1.00E+OOU1/2
Ti CFS-L01-1316-T02-B 1 1.00E+OOU1/2
Ti CFS-L01-1316-T03-B 1 1.00E+OOU1/2
Ti CFS-L01-1316-T04-B 1 1.00E+OOU1/2
Ti CFS-L01-1316-T05-B 1 1.00E+OOU1/2
Ti CFS-L01-1316-T01-C 1 1.00E+OOU1/2
Ti CFS-L01-1316-T02-C 1 1.00E+OOU1/2
Ti CFS-L01-1316-T03-C 1 1.00E+OOU1/2
Ti CFS-L01-1316-T04-C 1 1.00E+OOU1/2
Ti CFS-L01-1316-T05-C 1 1.00E+OOU1/2
Ti CFS-L01-1316-B01-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.8E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 8.8E+01 2.0E+00 6.4E+00 10 100 9.54E+02 95% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 2.9E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+02 2.0E+00 6.4E+00
1.00E+00 3.5E+01 1.5E+00 4.8E+00
1.00E+00 1.7E+02 1.5E+00 4.8E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 7.4E+01 1.5E+00 4.8E+00 10 100 9.09E+02 91% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 2.3E+01 1.5E+00 4.8E+00
1.00E+00 1.1E+02 1.5E+00 4.8E+00
1.00E+00 4.2E+01 1.5E+00 4.8E+00
1.00E+00 5.4E+01 1.5E+00 4.8E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 5.8E+01 1.5E+00 4.8E+00 10 100 9.59E+02 96% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
1.00E+00 1.1E+02 1.5E+00 4.8E+00
1.00E+00 1.0E+01 1.5E+00 4.8E+00
1.00E+00 1.2E+02 1.5E+00 4.8E+00
1.00E+00 4.7E+01 1.5E+00 4.8E+00
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1625
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V CFS-L01-1316-T01-A 1 2.97E+01
V CFS-L01-1316-T02-A 1 2.98E+01
V CFS-L01-1316-T03-A 1 2.92E+01
V CFS-L01-1316-T04-A 1 2.65E+01
V CFS-L01-1316-T05-A 1 2.58E+01
V CFS-L01-1316-T01-B 1 3.09E+01
V CFS-L01-1316-T02-B 1 3.18E+01
V CFS-L01-1316-T03-B 1 3.42E+01
V CFS-L01-1316-T04-B 1 2.71E+01
V CFS-L01-1316-T05-B 1 2.57E+01
V CFS-L01-1316-T01-C 1 3.01 E+01
V CFS-L01-1316-T02-C 1 2.94E+01
V CFS-L01-1316-T03-C 1 2.82E+01
V CFS-L01-1316-T04-C 1 2.49E+01
V CFS-L01-1316-T05-C 1 2.58E+01
V CFS-L01-1316-B01-A 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.97E+01 5.3E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
2.98E+01 5.1E+00 1 .5E+00 4.8E+00 10 100 9.93E+02 96% VU ICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
2.92E+01 5.5E-01 1 .5E+00 4.8E+00
2.65E+01 2.1E+00 1 .5E+00 4.8E+00
2.58E+01 9.8E+00 1 .5E+00 4.8E+00
3.09E+01 5.0E+00 1 .5E+00 4.8E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
3.18E+01 3.1E+00 1.5E+00 4.8E+00 10 100 9.61E+02 93% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
3.42E+01 2.8E+00 1 .5E+00 4.8E+00
2.71E+01 2.5E+00 1 .5E+00 4.8E+00
2.57E+01 6.2E+00 1 .5E+00 4.8E+00
3.01 E+01 5.7E+00 1 .5E+00 4.8E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
2.94E+01 3.9E+00 1 .5E+00 4.8E+00 10 100 1.00E+03 97% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
2.82E+01 5.6E+00 1.5E+00 4.8E+00
2.49E+01 2.8E-01 1.5E+00 4.8E+00
2.58E+01 8.1E+00 1.5E+00 4.8E+00
7.50E-01 4.8E+01 1.5E+00 4.8E+00
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1626
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn CFS-L01-1316-T01-A 1 2.25E+04
Zn CFS-L01-1316-T02-A 1 3.14E+04
Zn CFS-L01-1316-T03-A 1 4.98E+04
Zn CFS-L01-1316-T04-A 1 6.01 E+04
Zn CFS-L01-1316-T05-A 1 7.52E+04
Zn CFS-L01-1316-T01-B 1 2.31E+04
Zn CFS-L01-1316-T02-B 1 3.31 E+04
Zn CFS-L01-1316-T03-B 1 4.86E+04
Zn CFS-L01-1316-T04-B 1 5.71 E+04
Zn CFS-L01-1316-T05-B 1 7.38E+04
Zn CFS-L01-1316-T01-C 1 2.40E+04
Zn CFS-L01-1316-T02-C 1 3.36E+04
Zn CFS-L01-1316-T03-C 1 4.97E+04
Zn CFS-L01-1316-T04-C 1 5.95E+04
Zn CFS-L01-1316-T05-C 1 7.85E+04
Zn CFS-L01-1316-B01-A 1 2.03E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.25E+04 8.3E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 3/1/11 3:26 PM EPA Interlab L01 1313-1316 CFS
3.14E+04 3.4E-01 1 .OE+00 3.2E+00 10 100 3.23E+04 91%VUICP-OES 3/1/11 3:28 PM EPA Interlab L01 1313-1316 CFS
4.98E+04 1.3E+00 1 .OE+00 3.2E+00
6.01 E+04 6.3E-01 1 .OE+00 3.2E+00
7.52E+04 3.5E-01 1 .OE+00 3.2E+00
2.31E+04 1.3E+00 1 .OE+00 3.2E+00
VUICP-OES 3/1/11 3:30 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 4:09 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:33 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:34 PM EPA Interlab L01 1313-1316 CFS
3.31E+04 7.0E-01 1 .OE+00 3.2E+00 10 100 3.40E+04 93% VU ICP-OES 3/1/11 3:36 PM EPA Interlab L01 1313-1316 CFS
4.86E+04 1.2E+00 1 .OE+00 3.2E+00
5.71 E+04 1.3E-01 1 .OE+00 3.2E+00
7.38E+04 1.3E+00 1 .OE+00 3.2E+00
2.40E+04 9.4E-01 1 .OE+00 3.2E+00
VUICP-OES 3/1/11 3:38 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:39 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/113:41 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:43 PM EPA Interlab L01 1313-1316 CFS
3.36E+04 3.7E-01 1 .OE+00 3.2E+00 10 100 3.45E+04 92% VU ICP-OES 3/1/11 3:44 PM EPA Interlab L01 1313-1316 CFS
4.97E+04 9.6E-01 1. OE+00 3.2E+00
5.95E+04 2.0E-01 1. OE+00 3.2E+00
7.85E+04 5.4E-01 1. OE+00 3.2E+00
2.03E+00 5.7E+00 1. OE+00 3.2E+00
VUICP-OES 3/1/11 3:46 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:48 PM EPA Interlab L01 1313-1316 CFS
VUICP-OES 3/1/11 3:49 PM EPA Interlab L01 1313-1316 CFS
VU ICP-OES 3/1/11 3:25 PM EPA Interlab L01 1313-1316 CFS
                                                                                                                                                                         1-1627
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al CFS-L04-1316-T01-A 1 4.42E+01
Al CFS-L04-1316-T02-A 1 6.42E+01
Al CFS-L04-1316-T03-A 1 1.23E+02
Al CFS-L04-1316-T04-A 1 5.37E+01
Al CFS-L04-1316-T05-A 1 5.60E+01
Al CFS-L04-1316-T01-B 1 4.57E+01
Al CFS-L04-1316-T02-B 1 4.58E+01
Al CFS-L04-1316-T03-B 1 4.95E+01
Al CFS-L04-1316-T04-B 1 5.40E+01
Al CFS-L04-1316-T05-B 1 6.35E+01
Al CFS-L04-1316-T01-C 1 4.34E+01
Al CFS-L04-1316-T02-C 1 4.70E+01
Al CFS-L04-1316-T03-C 1 5.33E+01
Al CFS-L04-1316-T04-C 1 5.55E+01
Al CFS-L04-1316-T05-C 1 5.02E+01
Al CFS-L04-1316-B01-A 1 1.08E+01
Al CFS-L04-1316-B02-A 1 2.81E+00 E
Al CFS-L04-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.42E+01 1.1E+00 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
6.42E+01 9.9E+00 1 .OE+00 3.2E+00 1000 100 1.16E+03 110% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
1.23E+02 1.9E+00 1 .OE+00 3.2E+00
5.37E+01 1.3E+01 1 .OE+00 3.2E+00
5.60E+01 8.8E+00 1 .OE+00 3.2E+00
4.57E+01 5.6E+00 1 .OE+00 3.2E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
4.58E+01 4.5E+00 1 .OE+00 3.2E+00 1000 100 1.18E+03 113% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
4.95E+01 5.9E+00 1 .OE+00 3.2E+00
5.40E+01 9.0E+00 1 .OE+00 3.2E+00
6.35E+01 1.1E+01 1. OE+00 3.2E+00
4.34E+01 4.9E+00 1 .OE+00 3.2E+00
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
4.70E+01 1.0E+01 1.0E+00 3.2E+00 1000 100 1.16E+03 11 1% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
5.33E+01 7.8E+00 1 .OE+00 3.2E+00
5.55E+01 5.6E+00 1 .OE+00 3.2E+00
5.02E+01 3.4E+00 1 .OE+00 3.2E+00
1.08E+01 5.1E+01 1. OE+00 3.2E+00
2.81E+00 3.4E+01 1 .OE+00 3.2E+00
5.00E-01 3.5E+01 1 .OE+00 3.2E+00
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                                 1-1628
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb CFS-L04-1316-T01-A 1 3.00E+01
Sb CFS-L04-1316-T02-A 1 3.72E+01
Sb CFS-L04-1316-T03-A 1 5.39E+01
Sb CFS-L04-1316-T04-A 1 6.27E+01
Sb CFS-L04-1316-T05-A 1 7.04E+01
Sb CFS-L04-1316-T01-B 1 1.97E+01 E
Sb CFS-L04-1316-T02-B 1 3.96E+01
Sb CFS-L04-1316-T03-B 1 3.48E+01
Sb CFS-L04-1316-T04-B 1 4.71E+01
Sb CFS-L04-1316-T05-B 1 6.29E+01
Sb CFS-L04-1316-T01-C 1 4.14E+01
Sb CFS-L04-1316-T02-C 1 4.02E+01
Sb CFS-L04-1316-T03-C 1 4.63E+01
Sb CFS-L04-1316-T04-C 1 5.54E+01
Sb CFS-L04-1316-T05-C 1 6.35E+01
Sb CFS-L04-1316-B01-A 1 8.16E+00 E
Sb CFS-L04-1316-B02-A 1 3.75E+00 U1/2
Sb CFS-L04-1316-B03-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.00E+01 2.3E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
3.72E+01 4.2E+01 7.5E+00 2.4E+01 10 100 1.07E+03 103% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
5.39E+01 7.0E+00 7.5E+00 2.4E+01
6.27E+01 1.2E+01 7.5E+00 2.4E+01
7.04E+01 1.2E+01 7.5E+00 2.4E+01
1.97E+01 3.2E+01 7.5E+00 2.4E+01
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
3.96E+01 2.3E+01 7.5E+00 2.4E+01 10 100 1.09E+03 105% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
3.48E+01 2.1E+01 7.5E+00 2.4E+01
4.71 E+01 1.4E+01 7.5E+00 2.4E+01
6.29E+01 1.9E+01 7.5E+00 2.4E+01
4.14E+01 1.1E+01 7.5E+00 2.4E+01
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
4.02E+01 1.9E+01 7.5E+00 2.4E+01 10 100 1.08E+03 104% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
4.63E+01 4.5E+01 7.5E+00 2.4E+01
5.54E+01 3.8E+00 7.5E+00 2.4E+01
6.35E+01 9.4E+00 7.5E+00 2.4E+01
8.16E+00 7.0E+01 7.5E+00 2.4E+01
3.75E+00 2.9E+02 7.5E+00 2.4E+01
3.75E+00 9.7E+01 7.5E+00 2.4E+01
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1629
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
ug/L
As CFS-L04-1316-T01-A 1 1.59E+01 E
As CFS-L04-1316-T02-A 1 5.70E+01
As CFS-L04-1316-T03-A 1 1.14E+02
As CFS-L04-1316-T04-A 1 4.56E+01
As CFS-L04-1316-T05-A 1 4.58E+01
As CFS-L04-1316-T01-B 1 2.90E+01 E
As CFS-L04-1316-T02-B 1 2.85E+01 E
As CFS-L04-1316-T03-B 1 2.90E+01 E
As CFS-L04-1316-T04-B 1 4.57E+01
As CFS-L04-1316-T05-B 1 5.15E+01
As CFS-L04-1316-T01-C 1 2.00E+01 E
As CFS-L04-1316-T02-C 1 2.95E+01 E
As CFS-L04-1316-T03-C 1 3.61 E+01
As CFS-L04-1316-T04-C 1 4.81 E+01
As CFS-L04-1316-T05-C 1 4.79E+01
As CFS-L04-1316-B01-A 1 1.62E+01 E
As CFS-L04-1316-B02-A 1 5.50E+00 U1/2
As CFS-L04-1316-B03-A 1 5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+01 1.4E+01 1.1 E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
5.70E+01 9.3E+00 1.1E+01 3.5E+01 10 100 1 .08E+03 102% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
1.14E+02 8.8E+00 1.1E+01 3.5E+01
4.56E+01 1.6E+01 1.1 E+01 3.5E+01
4.58E+01 1.3E+01 1.1 E+01 3.5E+01
2.90E+01 2.3E+01 1.1E+01 3.5E+01
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
2.85E+01 2.4E+01 1.1E+01 3.5E+01 10 100 1.11E+03 108% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
2.90E+01 3.5E+01 1.1 E+01 3.5E+01
4.57E+01 6.0E+00 1.1 E+01 3.5E+01
5.15E+01 6.3E+00 1.1E+01 3.5E+01
2.00E+01 2.8E+01 1.1E+01 3.5E+01
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
2.95E+01 2.0E+01 1.1E+01 3.5E+01 10 100 1.10E+03 107% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
3.61E+01 2.0E+01 1.1E+01 3.5E+01
4.81E+01 1.7E+01 1.1E+01 3.5E+01
4.79E+01 2.5E+01 1.1E+01 3.5E+01
1.62E+01 1.5E+01 1.1 E+01 3.5E+01
5.50E+00 2.2E+02 1.1 E+01 3.5E+01
5.50E+00 5.6E+01 1.1 E+01 3.5E+01
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1630
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B CFS-L04-1316-T01-A 1 1.34E+02
B CFS-L04-1316-T02-A 1 2.69E+02
B CFS-L04-1316-T03-A 1 5.94E+02
B CFS-L04-1316-T04-A 1 9.94E+02
B CFS-L04-1316-T05-A 1 1.70E+03
B CFS-L04-1316-T01-B 1 1.21E+02
B CFS-L04-1316-T02-B 1 2.48E+02
B CFS-L04-1316-T03-B 1 5.25E+02
B CFS-L04-1316-T04-B 1 8.40E+02
B CFS-L04-1316-T05-B 1 1.47E+03
B CFS-L04-1316-T01-C 1 1.34E+02
B CFS-L04-1316-T02-C 1 2.61E+02
B CFS-L04-1316-T03-C 1 5.50E+02
B CFS-L04-1316-T04-C 1 8.88E+02
B CFS-L04-1316-T05-C 1 1.61E+03
B CFS-L04-1316-B01-A 1 5.00E-01 U1/2
B CFS-L04-1316-B02-A 1 5.00E-01 U1/2
B CFS-L04-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.34E+02 1.9E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
2.69E+02 1.0E+00 1 .OE+00 3.2E+00 1000 100 1 .24E+03 97% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
5.94E+02 6.4E-01 1 .OE+00 3.2E+00
9.94E+02 8.8E-01 1 .OE+00 3.2E+00
1.70E+03 1.7E-01 1. OE+00 3.2E+00
1.21E+02 1.1E+00 1. OE+00 3.2E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
2.48E+02 2.1E+00 1 .OE+00 3.2E+00 1000 100 1 .24E+03 99% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
5.25E+02 1.1E+00 1 .OE+00 3.2E+00
8.40E+02 4.3E-01 1 .OE+00 3.2E+00
1.47E+03 1.3E+01 1 .OE+00 3.2E+00
1.34E+02 1.1E+00 1. OE+00 3.2E+00
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
2.61E+02 1.1E+00 1.0E+00 3.2E+00 1000 100 1.23E+03 97% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
5.50E+02 1.2E+00 1. OE+00 3.2E+00
8.88E+02 1.1E+00 1. OE+00 3.2E+00
1.61E+03 1.1E+00 1. OE+00 3.2E+00
5.00E-01 1.7E+01 1. OE+00 3.2E+00
5.00E-01 6.3E+00 1. OE+00 3.2E+00
5.00E-01 2.0E+00 1. OE+00 3.2E+00
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1631
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba CFS-L04-1316-T01-A 1 2.23E+02
Ba CFS-L04-1316-T02-A 1 2.79E+02
Ba CFS-L04-1316-T03-A 1 4.12E+02
Ba CFS-L04-1316-T04-A 1 6.05E+02
Ba CFS-L04-1316-T05-A 1 1.27E+03
Ba CFS-L04-1316-T01-B 1 2.11E+02
Ba CFS-L04-1316-T02-B 1 2.70E+02
Ba CFS-L04-1316-T03-B 1 4.00E+02
Ba CFS-L04-1316-T04-B 1 5.73E+02
Ba CFS-L04-1316-T05-B 1 1.36E+03
Ba CFS-L04-1316-T01-C 1 2.21E+02
Ba CFS-L04-1316-T02-C 1 2.69E+02
Ba CFS-L04-1316-T03-C 1 3.95E+02
Ba CFS-L04-1316-T04-C 1 5.99E+02
Ba CFS-L04-1316-T05-C 1 1.31E+03
Ba CFS-L04-1316-B01-A 1 5.00E-01 U1/2
Ba CFS-L04-1316-B02-A 1 5.00E-01 U1/2
Ba CFS-L04-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.23E+02 1.6E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
2.79E+02 1.2E-01 1 .OE+00 3.2E+00 10 100 1.15E+03 87% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
4.12E+02 3.2E-01 1. OE+00 3.2E+00
6.05E+02 4.6E-01 1. OE+00 3.2E+00
1.27E+03 4.4E-01 1. OE+00 3.2E+00
2.11E+02 3.0E-01 1.0E+00 3.2E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
2.70E+02 1.1E+00 1.0E+00 3.2E+00 10 100 1.17E+03 90% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
4.00E+02 7.2E-01 1. OE+00 3.2E+00
5.73E+02 6.0E-01 1. OE+00 3.2E+00
1.36E+03 1.0E+01 1. OE+00 3.2E+00
2.21E+02 8.5E-01 1.0E+00 3.2E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
2.69E+02 6.2E-01 1.0E+00 3.2E+00 10 100 1.16E+03 89% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
3.95E+02 1.1E+00 1. OE+00 3.2E+00
5.99E+02 5.1E-01 1. OE+00 3.2E+00
1.31E+03 1.5E+00 1. OE+00 3.2E+00
5.00E-01 5.6E+02 1. OE+00 3.2E+00
5.00E-01 3.8E+01 1. OE+00 3.2E+00
5.00E-01 6.5E+01 1. OE+00 3.2E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1632
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be CFS-L04-1316-T01-A 1 9.50E-01 U1/2
Be CFS-L04-1316-T02-A 1 9.50E-01 U1/2
Be CFS-L04-1316-T03-A 1 9.50E-01 U1/2
Be CFS-L04-1316-T04-A 1 9.50E-01 U1/2
Be CFS-L04-1316-T05-A 1 9.50E-01 U1/2
Be CFS-L04-1316-T01-B 1 9.50E-01 U1/2
Be CFS-L04-1316-T02-B 1 9.50E-01 U1/2
Be CFS-L04-1316-T03-B 1 9.50E-01 U1/2
Be CFS-L04-1316-T04-B 1 9.50E-01 U1/2
Be CFS-L04-1316-T05-B 1 9.50E-01 U1/2
Be CFS-L04-1316-T01-C 1 9.50E-01 U1/2
Be CFS-L04-1316-T02-C 1 9.50E-01 U1/2
Be CFS-L04-1316-T03-C 1 9.50E-01 U1/2
Be CFS-L04-1316-T04-C 1 9.50E-01 U1/2
Be CFS-L04-1316-T05-C 1 9.50E-01 U1/2
Be CFS-L04-1316-B01-A 1 9.50E-01 U1/2
Be CFS-L04-1316-B02-A 1 9.50E-01 U1/2
Be CFS-L04-1316-B03-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 6.1E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
9.50E-01 1.1E+02 1.9E+00 6.0E+00 10 100 1.05E+03 105% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
9.50E-01 4.9E+01 1.9E+00 6.0E+00
9.50E-01 2.2E+01 1.9E+00 6.0E+00
9.50E-01 4.9E+01 1.9E+00 6.0E+00
9.50E-01 8.3E+01 1.9E+00 6.0E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
9.50E-01 3.0E+01 1.9E+00 6.0E+00 10 100 1.05E+03 105% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
9.50E-01 5.5E+01 1.9E+00 6.0E+00
9.50E-01 8.1E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
9.50E-01 2.5E+02 1.9E+00 6.0E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
9.50E-01 2.1E+01 1.9E+00 6.0E+00 10 100 1.05E+03 105% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
9.50E-01 6.8E+01 1.9E+00 6.0E+00
9.50E-01 2.2E+01 1.9E+00 6.0E+00
9.50E-01 5.6E+01 1.9E+00 6.0E+00
9.50E-01 4.8E+01 1.9E+00 6.0E+00
9.50E-01 5.2E+01 1.9E+00 6.0E+00
9.50E-01 3.5E+02 1.9E+00 6.0E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/1 1 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/1 1 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1633
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd CFS-L04-1316-T01-A 1 4.60E+03
Cd CFS-L04-1316-T02-A 1 5.75E+03
Cd CFS-L04-1316-T03-A 1 9.71 E+03
Cd CFS-L04-1316-T04-A 1 1.14E+04
Cd CFS-L04-1316-T05-A 1 1.23E+04
Cd CFS-L04-1316-T01-B 1 4.16E+03
Cd CFS-L04-1316-T02-B 1 5.79E+03
Cd CFS-L04-1316-T03-B 1 8.34E+03
Cd CFS-L04-1316-T04-B 1 1.01E+04
Cd CFS-L04-1316-T05-B 1 1.17E+04
Cd CFS-L04-1316-T01-C 1 4.48E+03
Cd CFS-L04-1316-T02-C 1 6.32E+03
Cd CFS-L04-1316-T03-C 1 9.00E+03
Cd CFS-L04-1316-T04-C 1 1.09E+04
Cd CFS-L04-1316-T05-C 1 1.30E+04
Cd CFS-L04-1316-B01-A 1 7.97E+00
Cd CFS-L04-1316-B02-A 1 1.10E+OOU1/2
Cd CFS-L04-1316-B03-A 1 1.10E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.60E+03 3.6E-01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
5.75E+03 5.0E-01 2.2E+00 7.0E+00 10 100 6.64E+03 89% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
9.71E+03 3.5E-01 2.2E+00 7.0E+00
1.14E+04 5.6E-01 2.2E+00 7.0E+00
1.23E+04 1.2E-01 2.2E+00 7.0E+00
4.16E+03 2.5E-01 2.2E+00 7.0E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
5.79E+03 8.8E-01 2.2E+00 7.0E+00 10 100 6.75E+03 96% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
8.34E+03 4.9E-01 2.2E+00 7.0E+00
1.01E+04 5.1E-01 2.2E+00 7.0E+00
1.17E+04 1.2E+01 2.2E+00 7.0E+00
4.48E+03 8.3E-01 2.2E+00 7.0E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
6.32E+03 2.1E-01 2.2E+00 7.0E+00 10 100 7.25E+03 94% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
9.00E+03 9.9E-01 2.2E+00 7.0E+00
1.09E+04 2.7E-01 2.2E+00 7.0E+00
1.30E+04 8.7E-01 2.2E+00 7.0E+00
7.97E+00 2.7E+00 2.2E+00 7.0E+00
1.10E+00 1.7E+02 2.2E+00 7.0E+00
1.10E+00 1.0E+02 2.2E+00 7.0E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1634
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca CFS-L04-1316-T01-A 1 6.42E+05
Ca CFS-L04-1316-T02-A 1 6.41 E+05
Ca CFS-L04-1316-T03-A 1 6.06E+05
Ca CFS-L04-1316-T04-A 1 5.81 E+05
Ca CFS-L04-1316-T05-A 1 5.19E+05
Ca CFS-L04-1316-T01-B 1 6.31E+05
Ca CFS-L04-1316-T02-B 1 6.31 E+05
Ca CFS-L04-1316-T03-B 1 5.95E+05
Ca CFS-L04-1316-T04-B 1 5.52E+05
Ca CFS-L04-1316-T05-B 1 5.11E+05
Ca CFS-L04-1316-T01-C 1 6.42E+05
Ca CFS-L04-1316-T02-C 1 6.23E+05
Ca CFS-L04-1316-T03-C 1 5.85E+05
Ca CFS-L04-1316-T04-C 1 5.57E+05
Ca CFS-L04-1316-T05-C 1 5.08E+05
Ca CFS-L04-1316-B01-A 1 4.59E+02
Ca CFS-L04-1316-B02-A 1 4.90E+00 E
Ca CFS-L04-1316-B03-A 1 1.30E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.42E+05 3.5E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
6.41E+05 8.3E-02 2.6E+00 8.3E+00 1000 100 6.42E+05 92% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
6.06E+05 6.1E-01 2.6E+00 8.3E+00
5.81E+05 7.7E-01 2.6E+00 8.3E+00
5.19E+05 3.1E-01 2.6E+00 8.3E+00
6.31E+05 1.1E-01 2.6E+00 8.3E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
6.31E+05 5.8E-01 2.6E+00 8.3E+00 1000 100 6.32E+05 88% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
5.95E+05 6.3E-01 2.6E+00 8.3E+00
5.52E+05 2.7E-01 2.6E+00 8.3E+00
5. 11 E+05 1.2E+01 2.6E+00 8.3E+00
6.42E+05 6.4E-01 2.6E+00 8.3E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
6.23E+05 7.4E-01 2.6E+00 8.3E+00 1000 100 6.24E+05 89% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
5.85E+05 5.3E-01 2.6E+00 8.3E+00
5.57E+05 5.5E-01 2.6E+00 8.3E+00
5.08E+05 9.4E-01 2.6E+00 8.3E+00
4.59E+02 4.6E+00 2.6E+00 8.3E+00
4.90E+00 2.4E+02 2.6E+00 8.3E+00
1.30E+00 1.4E+02 2.6E+00 8.3E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1635
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cr Sample Dilution Cone. Qualifier Revi
ug/L
Cr CFS-L04-1316-T01-A 1 6.00E-01 U1/2
Cr CFS-L04-1316-T02-A 1 6.00E-01 U1/2
Cr CFS-L04-1316-T03-A 1 1.65E+OOE
Cr CFS-L04-1316-T04-A 1 6.00E-01 U1/2
Cr CFS-L04-1316-T05-A 1 1.39E+OOE
Cr CFS-L04-1316-T01-B 1 6.00E-01 U1/2
Cr CFS-L04-1316-T02-B 1 6.00E-01 U1/2
Cr CFS-L04-1316-T03-B 1 6.00E-01 U1/2
Cr CFS-L04-1316-T04-B 1 6.00E-01 U1/2
Cr CFS-L04-1316-T05-B 1 6.00E-01 U1/2
Cr CFS-L04-1316-T01-C 1 6.00E-01 U1/2
Cr CFS-L04-1316-T02-C 1 6.00E-01 U1/2
Cr CFS-L04-1316-T03-C 1 6.00E-01 U1/2
Cr CFS-L04-1316-T04-C 1 6.00E-01 U1/2
Cr CFS-L04-1316-T05-C 1 6.00E-01 U1/2
Cr CFS-L04-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L04-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L04-1316-B01-A 1 6.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 2.4E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
6.00E-01 1.6E+02 1.2E+00 3.8E+00 10 100 1.01E+03 101% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
1.65E+00 3.6E+01 1.2E+00 3.8E+00
6.00E-01 1.0E+02 1.2E+00 3.8E+00
1.39E+00 5.2E+01 1.2E+00 3.8E+00
6.00E-01 5.3E+01 1.2E+00 3.8E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
6.00E-01 3.2E+01 1.2E+00 3.8E+00 10 100 1.04E+03 104% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
6.00E-01 6.6E+01 1.2E+00 3.8E+00
6.00E-01 5.3E+01 1.2E+00 3.8E+00
6.00E-01 5.7E+01 1.2E+00 3.8E+00
6.00E-01 1.5E+02 1.2E+00 3.8E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
6.00E-01 2.1E+02 1.2E+00 3.8E+00 10 100 1.03E+03 103% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
6.00E-01 1.4E+02 1.2E+00 3.8E+00
6.00E-01 8.5E+01 1.2E+00 3.8E+00
6.00E-01 2.5E+01 1.2E+00 3.8E+00
6.00E-01 1.1E+01 1.2E+00 3.8E+00
6.00E-01 2.1E+02 1.2E+00 3.8E+00
6.00E-01 5.7E+01 1.2E+00 3.8E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/1 1 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/1 1 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1636
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co CFS-L04-1316-T01-A 1 1.02E+02
Co CFS-L04-1316-T02-A 1 1.46E+02
Co CFS-L04-1316-T03-A 1 3.36E+02
Co CFS-L04-1316-T04-A 1 4.37E+02
Co CFS-L04-1316-T05-A 1 5.20E+02
Co CFS-L04-1316-T01-B 1 8.72E+01
Co CFS-L04-1316-T02-B 1 1.54E+02
Co CFS-L04-1316-T03-B 1 2.73E+02
Co CFS-L04-1316-T04-B 1 3.65E+02
Co CFS-L04-1316-T05-B 1 4.71 E+02
Co CFS-L04-1316-T01-C 1 1.00E+02
Co CFS-L04-1316-T02-C 1 1.72E+02
Co CFS-L04-1316-T03-C 1 3.08E+02
Co CFS-L04-1316-T04-C 1 4.21E+02
Co CFS-L04-1316-T05-C 1 5.61 E+02
Co CFS-L04-1316-B01-A 1 9.00E-01 U1/2
Co CFS-L04-1316-B02-A 1 9.00E-01 U1/2
Co CFS-L04-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.02E+02 4.7E-01 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
1.46E+02 1.1E+00 1.8E+00 5.7E+00 10 100 1.14E+03 99% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
3.36E+02 1.4E-01 1 .8E+00 5.7E+00
4.37E+02 2.2E-02 1 .8E+00 5.7E+00
5.20E+02 5.6E-01 1 .8E+00 5.7E+00
8.72E+01 7.0E-01 1.8E+00 5.7E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.54E+02 4.5E-02 1.8E+00 5.7E+00 10 100 1.17E+03 102% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
2.73E+02 1.0E+00 1.8E+00 5.7E+00
3.65E+02 6.3E-01 1.8E+00 5.7E+00
4.71 E+02 1.2E+01 1.8E+00 5.7E+00
1.00E+02 5.5E-01 1.8E+00 5.7E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.72E+02 5.4E-01 1.8E+00 5.7E+00 10 100 1.18E+03 100% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
3.08E+02 6.1E-01 1.8E+00 5.7E+00
4.21 E+02 3.7E-01 1.8E+00 5.7E+00
5.61 E+02 1.2E+00 1.8E+00 5.7E+00
9.00E-01 7.1E+01 1.8E+00 5.7E+00
9.00E-01 1.1 E+02 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1637
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu CFS-L04-1316-T01-A 1 8.22E+02
Cu CFS-L04-1316-T02-A 1 8.33E+02
Cu CFS-L04-1316-T03-A 1 1.83E+03
Cu CFS-L04-1316-T04-A 1 1.94E+03
Cu CFS-L04-1316-T05-A 1 1.20E+03
Cu CFS-L04-1316-T01-B 1 6.94E+02
Cu CFS-L04-1316-T02-B 1 8.71 E+02
Cu CFS-L04-1316-T03-B 1 1.41E+03
Cu CFS-L04-1316-T04-B 1 1.79E+03
Cu CFS-L04-1316-T05-B 1 1.38E+03
Cu CFS-L04-1316-T01-C 1 7.64E+02
Cu CFS-L04-1316-T02-C 1 9.92E+02
Cu CFS-L04-1316-T03-C 1 1.55E+03
Cu CFS-L04-1316-T04-C 1 2.11E+03
Cu CFS-L04-1316-T05-C 1 1.71E+03
Cu CFS-L04-1316-B01-A 1 1.64E+02
Cu CFS-L04-1316-B02-A 1 1.85E+OOU1/2
Cu CFS-L04-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.22E+02 1.4E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
8.33E+02 8.1E-01 3.7E+00 1.2E+01 10 100 1.77E+03 94% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
1.83E+03 7.2E-01 3.7E+00 1.2E+01
1.94E+03 1.0E+00 3.7E+00 1.2E+01
1.20E+03 7.3E-01 3.7E+00 1.2E+01
6.94E+02 4.7E-01 3.7E+00 1.2E+01
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
8.71E+02 1.2E+00 3.7E+00 1.2E+01 10 100 1.83E+03 96% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
1.41E+03 1.3E+00 3.7E+00 1.2E+01
1.79E+03 4.9E-01 3.7E+00 1.2E+01
1.38E+03 1.1E+01 3.7E+00 1.2E+01
7.64E+02 9.9E-01 3.7E+00 1.2E+01
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
9.92E+02 7.4E-01 3.7E+00 1.2E+01 10 100 1.92E+03 92% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
1.55E+03 1.3E+00 3.7E+00 1.2E+01
2.11E+03 6.9E-01 3.7E+00 1.2E+01
1.71E+03 1.5E+00 3.7E+00 1.2E+01
1.64E+02 3.3E+00 3.7E+00 1.2E+01
1.85E+00 3.5E+01 3.7E+00 1.2E+01
1.85E+00 3.4E+01 3.7E+00 1.2E+01
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1638
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe CFS-L04-1316-T01-A 1 1.00E+OOU1/2
Fe CFS-L04-1316-T02-A 1 7.74E+01
Fe CFS-L04-1316-T03-A 1 3.03E+02
Fe CFS-L04-1316-T04-A 1 1.00E+OOU1/2
Fe CFS-L04-1316-T05-A 1 1.00E+OOU1/2
Fe CFS-L04-1316-T01-B 1 1.00E+OOU1/2
Fe CFS-L04-1316-T02-B 1 1.00E+OOU1/2
Fe CFS-L04-1316-T03-B 1 1.00E+OOU1/2
Fe CFS-L04-1316-T04-B 1 1.00E+OOU1/2
Fe CFS-L04-1316-T05-B 1 9.79E+00
Fe CFS-L04-1316-T01-C 1 1.00E+OOU1/2
Fe CFS-L04-1316-T02-C 1 1.00E+OOU1/2
Fe CFS-L04-1316-T03-C 1 1.00E+OOU1/2
Fe CFS-L04-1316-T04-C 1 1.00E+OOU1/2
Fe CFS-L04-1316-T05-C 1 1.00E+OOU1/2
Fe CFS-L04-1316-B01-A 1 3.94E+01
Fe CFS-L04-1316-B02-A 1 1.00E+OOU1/2
Fe CFS-L04-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.9E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
7.74E+01 5.5E+00 2.0E+00 6.4E+00 1000 100 9.90E+02 91% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
3.03E+02 3.1E+00 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00
1.00E+00 3.2E+01 2.0E+00 6.4E+00
1.00E+00 2.8E+01 2.0E+00 6.4E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 9.3E+00 2.0E+00 6.4E+00 1000 100 9.47E+02 95% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 3.8E+00 2.0E+00 6.4E+00
9.79E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 8.1E+00 2.0E+00 6.4E+00
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 7.1E+00 2.0E+00 6.4E+00 1000 100 9.41E+02 94% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 9.9E-01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00
3.94E+01 3.1E+00 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 2.0E+00 2.0E+00 6.4E+00
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1639
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb CFS-L04-1316-T01-A 1 1.15E+03
Pb CFS-L04-1316-T02-A 1 1.33E+03
Pb CFS-L04-1316-T03-A 1 1.67E+03
Pb CFS-L04-1316-T04-A 1 1.48E+03
Pb CFS-L04-1316-T05-A 1 2.11E+02
Pb CFS-L04-1316-T01-B 1 1.00E+03
Pb CFS-L04-1316-T02-B 1 1.14E+03
Pb CFS-L04-1316-T03-B 1 1.27E+03
Pb CFS-L04-1316-T04-B 1 1.30E+03
Pb CFS-L04-1316-T05-B 1 2.01E+02
Pb CFS-L04-1316-T01-C 1 1.05E+03
Pb CFS-L04-1316-T02-C 1 1.20E+03
Pb CFS-L04-1316-T03-C 1 1.33E+03
Pb CFS-L04-1316-T04-C 1 1.37E+03
Pb CFS-L04-1316-T05-C 1 1.53E+02
Pb CFS-L04-1316-B01-A 1 6.91E+00 E
Pb CFS-L04-1316-B02-A 1 3.40E+00 U1/2
Pb CFS-L04-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.15E+03 2.0E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
1.33E+03 4.8E-01 6.8E+00 2.2E+01 10 100 2.15E+03 82% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
1.67E+03 5.4E-01 6.8E+00 2.2E+01
1.48E+03 8.6E-01 6.8E+00 2.2E+01
2.11E+02 2.4E+00 6.8E+00 2.2E+01
1.00E+03 6.1E-01 6.8E+00 2.2E+01
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.14E+03 1.1E+00 6.8E+00 2.2E+01 10 100 2.01E+03 87% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
1.27E+03 1.6E-01 6.8E+00 2.2E+01
1.30E+03 6.5E-01 6.8E+00 2.2E+01
2.01E+02 1.1E+01 6.8E+00 2.2E+01
1.05E+03 4.7E-01 6.8E+00 2.2E+01
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.20E+03 2.2E-01 6.8E+00 2.2E+01 10 100 2.04E+03 84% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
1.33E+03 1.2E+00 6.8E+00 2.2E+01
1.37E+03 3.3E-01 6.8E+00 2.2E+01
1.53E+02 2.1E+00 6.8E+00 2.2E+01
6.91 E+00 3.1E+01 6.8E+00 2.2E+01
3.40E+00 2.4E+01 6.8E+00 2.2E+01
3.40E+00 1.1E+01 6.8E+00 2.2E+01
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1640
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li CFS-L04-1316-T01-A 1 1.77E+01
Li CFS-L04-1316-T02-A 1 1.93E+01
Li CFS-L04-1316-T03-A 1 1.73E+01
Li CFS-L04-1316-T04-A 1 1.57E+01
Li CFS-L04-1316-T05-A 1 2.49E+01
Li CFS-L04-1316-T01-B 1 1.82E+01
Li CFS-L04-1316-T02-B 1 1.79E+01
Li CFS-L04-1316-T03-B 1 1.44E+01
Li CFS-L04-1316-T04-B 1 1.18E+01
Li CFS-L04-1316-T05-B 1 1.86E+01
Li CFS-L04-1316-T01-C 1 1.68E+01
Li CFS-L04-1316-T02-C 1 1.66E+01
Li CFS-L04-1316-T03-C 1 1.48E+01
Li CFS-L04-1316-T04-C 1 1.38E+01
Li CFS-L04-1316-T05-C 1 2.26E+01
Li CFS-L04-1316-B01-A 1 6.76E+00
Li CFS-L04-1316-B02-A 1 8.06E+00
Li CFS-L04-1316-B03-A 1 7.60E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+01 2.3E+00 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
1.93E+01 3.3E+00 1 .9E+00 6.0E+00 10 100 8.81E+02 86% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
1.73E+01 7.7E+00 1 .9E+00 6.0E+00
1.57E+01 1.4E+01 1.9E+00 6.0E+00
2.49E+01 7.5E+00 1 .9E+00 6.0E+00
1.82E+01 1.7E+01 1.9E+00 6.0E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.79E+01 7.2E+00 1.9E+00 6.0E+00 10 100 8.97E+02 88% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
1.44E+01 6.6E+00 1.9E+00 6.0E+00
1.18E+01 1.3E+01 1.9E+00 6.0E+00
1.86E+01 1.2E+01 1.9E+00 6.0E+00
1.68E+01 1.3E+01 1.9E+00 6.0E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.66E+01 2.4E+00 1.9E+00 6.0E+00 10 100 8.99E+02 88% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
1.48E+01 2.9E+00 1.9E+00 6.0E+00
1.38E+01 9.7E+00 1.9E+00 6.0E+00
2.26E+01 3.0E+00 1.9E+00 6.0E+00
6.76E+00 4.7E+00 1.9E+00 6.0E+00
8.06E+00 1.3E+01 1.9E+00 6.0E+00
7.60E+00 7.0E+00 1.9E+00 6.0E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1641
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn CFS-L04-1316-T01-A 1 1.59E+03
Mn CFS-L04-1316-T02-A 1 2.68E+03
Mn CFS-L04-1316-T03-A 1 6.29E+03
Mn CFS-L04-1316-T04-A 1 9.25E+03
Mn CFS-L04-1316-T05-A 1 1.24E+04
Mn CFS-L04-1316-T01-B 1 1.34E+03
Mn CFS-L04-1316-T02-B 1 2.62E+03
Mn CFS-L04-1316-T03-B 1 5.14E+03
Mn CFS-L04-1316-T04-B 1 7.70E+03
Mn CFS-L04-1316-T05-B 1 1.09E+04
Mn CFS-L04-1316-T01-C 1 1.53E+03
Mn CFS-L04-1316-T02-C 1 2.83E+03
Mn CFS-L04-1316-T03-C 1 5.61E+03
Mn CFS-L04-1316-T04-C 1 8.61E+03
Mn CFS-L04-1316-T05-C 1 1.28E+04
Mn CFS-L04-1316-B01-A 1 5.71E+00 E
Mn CFS-L04-1316-B02-A 1 1.00E+OOU1/2
Mn CFS-L04-1316-B03-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+03 6.6E-01 2.0E+00 6.4E+00
2.68E+03 6.8E-01 2.0E+00 6.4E+00 10 100
6.29E+03 3.7E-01 2.0E+00 6.4E+00
9.25E+03 3.1E-01 2.0E+00 6.4E+00
1.24E+04 4.6E-01 2.0E+00 6.4E+00
1.34E+03 1.0E+00 2.0E+00 6.4E+00
2.62E+03 8.0E-01 2.0E+00 6.4E+00 10 100
5.14E+03 5.8E-01 2.0E+00 6.4E+00
7.70E+03 2.2E-01 2.0E+00 6.4E+00
1.09E+04 1.2E+01 2.0E+00 6.4E+00
1.53E+03 6.0E-01 2.0E+00 6.4E+00
2.83E+03 6.4E-01 2.0E+00 6.4E+00 10 100
5.61 E+03 9.1E-01 2.0E+00 6.4E+00
8.61 E+03 6.7E-01 2.0E+00 6.4E+00
1.28E+04 9.7E-01 2.0E+00 6.4E+00
5.71 E+00 4.1E+00 2.0E+00 6.4E+00
1.00E+00 8.4E+00 2.0E+00 6.4E+00
1.00E+00 2.4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
3.71E+03 103% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
3.72E+03 110% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
3.77E+03 94% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1642
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg CFS-L04-1316-T01-A 1 6.87E+04
Mg CFS-L04-1316-T02-A 1 1.36E+05
Mg CFS-L04-1316-T03-A 1 3.08E+05
Mg CFS-L04-1316-T04-A 1 5.69E+05
Mg CFS-L04-1316-T05-A 1 9.41 E+05
Mg CFS-L04-1316-T01-B 1 6.65E+04
Mg CFS-L04-1316-T02-B 1 1.36E+05
Mg CFS-L04-1316-T03-B 1 3.03E+05
Mg CFS-L04-1316-T04-B 1 5.24E+05
Mg CFS-L04-1316-T05-B 1 8.90E+05
Mg CFS-L04-1316-T01-C 1 6.96E+04
Mg CFS-L04-1316-T02-C 1 1.35E+05
Mg CFS-L04-1316-T03-C 1 3.06E+05
Mg CFS-L04-1316-T04-C 1 5.49E+05
Mg CFS-L04-1316-T05-C 1 9.19E+05
Mg CFS-L04-1316-B01-A 1 5.36E+01
Mg CFS-L04-1316-B02-A 1 5.00E-01 U1/2
Mg CFS-L04-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.87E+04 1.3E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
1.36E+05 1.4E+00 1 .OE+00 3.2E+00 1000 100 1.37E+05 94% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
3.08E+05 6.7E-01 1. OE+00 3.2E+00
5.69E+05 4.6E-01 1. OE+00 3.2E+00
9.41 E+05 1.1E+00 1. OE+00 3.2E+00
6.65E+04 6.6E-01 1. OE+00 3.2E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.36E+05 4.3E-01 1.0E+00 3.2E+00 1000 100 1.37E+05 105% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
3.03E+05 1.3E+00 1. OE+00 3.2E+00
5.24E+05 2.1E-01 1. OE+00 3.2E+00
8.90E+05 1.1E+01 1. OE+00 3.2E+00
6.96E+04 9.4E-01 1. OE+00 3.2E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.35E+05 3.9E-01 1.0E+00 3.2E+00 1000 100 1.36E+05 92% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
3.06E+05 1.1E+00 1. OE+00 3.2E+00
5.49E+05 1. OE+00 1. OE+00 3.2E+00
9.19E+05 4.7E-01 1. OE+00 3.2E+00
5.36E+01 1.7E+01 1. OE+00 3.2E+00
5.00E-01 7.4E+01 1. OE+00 3.2E+00
5.00E-01 5.0E+01 1. OE+00 3.2E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1643
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo CFS-L04-1316-T01-A 1 1.22E+01
Mo CFS-L04-1316-T02-A 1 1.43E+01
Mo CFS-L04-1316-T03-A 1 2.08E+01
Mo CFS-L04-1316-T04-A 1 1.93E+01
Mo CFS-L04-1316-T05-A 1 2.41E+01
Mo CFS-L04-1316-T01-B 1 9.82E+00
Mo CFS-L04-1316-T02-B 1 1.10E+01
Mo CFS-L04-1316-T03-B 1 1.63E+01
Mo CFS-L04-1316-T04-B 1 1.68E+01
Mo CFS-L04-1316-T05-B 1 2.27E+01
Mo CFS-L04-1316-T01-C 1 1.04E+01
Mo CFS-L04-1316-T02-C 1 1.39E+01
Mo CFS-L04-1316-T03-C 1 1.48E+01
Mo CFS-L04-1316-T04-C 1 1.77E+01
Mo CFS-L04-1316-T05-C 1 2.24E+01
Mo CFS-L04-1316-B01-A 1 2.93E+00 E
Mo CFS-L04-1316-B02-A 1 3.20E+00 E
Mo CFS-L04-1316-B03-A 1 1.98E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.22E+01 8.4E-01 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
1.43E+01 4.0E+00 1 .2E+00 3.8E+00 10 100 1.01E+03 100% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
2.08E+01 6.7E+00 1.2E+00 3.8E+00
1.93E+01 8.4E+00 1.2E+00 3.8E+00
2.41E+01 8.8E+00 1.2E+00 3.8E+00
9.82E+00 4.1E+00 1.2E+00 3.8E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.10E+01 1.4E+01 1.2E+00 3.8E+00 10 100 1.04E+03 103% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
1.63E+01 9.9E+00 1.2E+00 3.8E+00
1.68E+01 7.7E+00 1.2E+00 3.8E+00
2.27E+01 4.5E+00 1.2E+00 3.8E+00
1.04E+01 3.1E+00 1.2E+00 3.8E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.39E+01 2.4E+00 1.2E+00 3.8E+00 10 100 1.04E+03 103% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
1.48E+01 8.0E+00 1.2E+00 3.8E+00
1.77E+01 7.8E+00 1.2E+00 3.8E+00
2.24E+01 2.2E+00 1.2E+00 3.8E+00
2.93E+00 5.7E+00 1.2E+00 3.8E+00
3.20E+00 3.3E+01 1.2E+00 3.8E+00
1.98E+00 1.8E+01 1.2E+00 3.8E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1644
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni CFS-L04-1316-T01-A 1 2.08E+02
Ni CFS-L04-1316-T02-A 1 2.76E+02
Ni CFS-L04-1316-T03-A 1 5.91 E+02
Ni CFS-L04-1316-T04-A 1 7.16E+02
Ni CFS-L04-1316-T05-A 1 8.22E+02
Ni CFS-L04-1316-T01-B 1 1.72E+02
Ni CFS-L04-1316-T02-B 1 2.92E+02
Ni CFS-L04-1316-T03-B 1 4.77E+02
Ni CFS-L04-1316-T04-B 1 6.03E+02
Ni CFS-L04-1316-T05-B 1 7.47E+02
Ni CFS-L04-1316-T01-C 1 1.96E+02
Ni CFS-L04-1316-T02-C 1 3.39E+02
Ni CFS-L04-1316-T03-C 1 5.46E+02
Ni CFS-L04-1316-T04-C 1 7.03E+02
Ni CFS-L04-1316-T05-C 1 8.93E+02
Ni CFS-L04-1316-B01-A 1 9.00E-01 U1/2
Ni CFS-L04-1316-B02-A 1 9.00E-01 U1/2
Ni CFS-L04-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+02 6.0E-01 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
2.76E+02 1.1E+00 1 .8E+00 5.7E+00 10 100 1.26E+03 98% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
5.91 E+02 5.9E-01 1 .8E+00 5.7E+00
7.16E+02 1.1E+00 1.8E+00 5.7E+00
8.22E+02 4.3E-01 1 .8E+00 5.7E+00
1.72E+02 3.1E-01 1.8E+00 5.7E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
2.92E+02 1.7E+00 1.8E+00 5.7E+00 10 100 1.30E+03 101% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
4.77E+02 5.9E-01 1.8E+00 5.7E+00
6.03E+02 3.6E-01 1.8E+00 5.7E+00
7.47E+02 1.2E+01 1.8E+00 5.7E+00
1.96E+02 2.0E+00 1.8E+00 5.7E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
3.39E+02 8.8E-01 1.8E+00 5.7E+00 10 100 1.33E+03 99% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
5.46E+02 1.4E+00 1.8E+00 5.7E+00
7.03E+02 4.5E-01 1.8E+00 5.7E+00
8.93E+02 1.2E+00 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 7.0E+01 1.8E+00 5.7E+00
9.00E-01 9.0E+01 1.8E+00 5.7E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1645
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P CFS-L04-1316-T01-A 1 1.95E+01
P CFS-L04-1316-T02-A 1 3.08E+01
P CFS-L04-1316-T03-A 1 3.63E+01
P CFS-L04-1316-T04-A 1 4.80E+01
P CFS-L04-1316-T05-A 1 6.39E+01
P CFS-L04-1316-T01-B 1 5.19E+01
P CFS-L04-1316-T02-B 1 3.65E+01
P CFS-L04-1316-T03-B 1 3.85E+01
P CFS-L04-1316-T04-B 1 4.58E+01
P CFS-L04-1316-T05-B 1 5.68E+01
P CFS-L04-1316-T01-C 1 2.84E+01
P CFS-L04-1316-T02-C 1 5.41 E+01
P CFS-L04-1316-T03-C 1 3.32E+01
P CFS-L04-1316-T04-C 1 5.75E+01
P CFS-L04-1316-T05-C 1 7.74E+01
P CFS-L04-1316-B01-A 1 2.45E+01
P CFS-L04-1316-B02-A 1 1.87E+01
P CFS-L04-1316-B03-A 1 2.59E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.95E+01 5.2E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
3.08E+01 1.0E+01 3.7E+00 1.2E+01 1000 100 1 .04E+03 101% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
3.63E+01 1.9E+01 3.7E+00 1.2E+01
4.80E+01 1.0E+01 3.7E+00 1.2E+01
6.39E+01 1.4E+01 3.7E+00 1.2E+01
5.19E+01 8.0E+00 3.7E+00 1.2E+01
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
3.65E+01 2.0E+01 3.7E+00 1.2E+01 1000 100 1 .08E+03 105% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
3.85E+01 2.5E+01 3.7E+00 1.2E+01
4.58E+01 1.9E+01 3.7E+00 1.2E+01
5.68E+01 1.5E+01 3.7E+00 1.2E+01
2.84E+01 2.7E+01 3.7E+00 1.2E+01
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
5.41E+01 4.1E+01 3.7E+00 1.2E+01 1000 100 1.05E+03 99% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
3.32E+01 3.6E+01 3.7E+00 1.2E+01
5.75E+01 1.5E+01 3.7E+00 1.2E+01
7.74E+01 1.1E+01 3.7E+00 1.2E+01
2.45E+01 4.1E+01 3.7E+00 1.2E+01
1.87E+01 4.0E+01 3.7E+00 1.2E+01
2.59E+01 3.9E+00 3.7E+00 1.2E+01
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1646
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K CFS-L04-1316-T01-A 1 1.03E+04
K CFS-L04-1316-T02-A 1 1.95E+04
K CFS-L04-1316-T03-A 1 3.68E+04
K CFS-L04-1316-T04-A 1 5.87E+04
K CFS-L04-1316-T05-A 1 7.91 E+04
K CFS-L04-1316-T01-B 1 9.94E+03
K CFS-L04-1316-T02-B 1 1.83E+04
K CFS-L04-1316-T03-B 1 3.44E+04
K CFS-L04-1316-T04-B 1 5.37E+04
K CFS-L04-1316-T05-B 1 7.81 E+04
K CFS-L04-1316-T01-C 1 1.02E+04
K CFS-L04-1316-T02-C 1 1.85E+04
K CFS-L04-1316-T03-C 1 3.46E+04
K CFS-L04-1316-T04-C 1 5.42E+04
K CFS-L04-1316-T05-C 1 7.82E+04
K CFS-L04-1316-B01-A 1 1.25E+02
K CFS-L04-1316-B02-A 1 7.90E+01
K CFS-L04-1316-B03-A 1 7.79E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.03E+04 6.4E-01 1 .6E+00 5.1E+00
1.95E+04 4.3E-01 1 .6E+00 5.1E+00 1000 100
3.68E+04 2.6E-01 1 .6E+00 5.1E+00
5.87E+04 2.7E-01 1 .6E+00 5.1E+00
7.91 E+04 7.3E-01 1 .6E+00 5.1E+00
9.94E+03 1.9E-01 1 .6E+00 5.1E+00
1.83E+04 8.3E-01 1 .6E+00 5.1E+00 1000 100
3.44E+04 9.6E-01 1 .6E+00 5.1E+00
5.37E+04 9.9E-02 1 .6E+00 5.1E+00
7.81 E+04 1.2E+01 1 .6E+00 5.1E+00
1.02E+04 8.8E-01 1 .6E+00 5.1E+00
1.85E+04 2.8E-01 1 .6E+00 5.1E+00 1000 100
3.46E+04 9.2E-01 1.6E+00 5.1E+00
5.42E+04 4.8E-01 1.6E+00 5.1E+00
7.82E+04 8.1E-01 1.6E+00 5.1E+00
1.25E+02 3.8E+00 1.6E+00 5.1E+00
7.90E+01 2.0E+00 1.6E+00 5.1E+00
7.79E+01 2.3E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
2.04E+04 95% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.93E+04 100% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.94E+04 96% VUICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1647
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se CFS-L04-1316-T01-A 1 7.30E+01
Se CFS-L04-1316-T02-A 1 1.41E+02
Se CFS-L04-1316-T03-A 1 3.05E+02
Se CFS-L04-1316-T04-A 1 5.48E+02
Se CFS-L04-1316-T05-A 1 9.06E+02
Se CFS-L04-1316-T01-B 1 6.33E+01
Se CFS-L04-1316-T02-B 1 1.36E+02
Se CFS-L04-1316-T03-B 1 2.82E+02
Se CFS-L04-1316-T04-B 1 5.08E+02
Se CFS-L04-1316-T05-B 1 8.92E+02
Se CFS-L04-1316-T01-C 1 7.95E+01
Se CFS-L04-1316-T02-C 1 1.30E+02
Se CFS-L04-1316-T03-C 1 2.97E+02
Se CFS-L04-1316-T04-C 1 5.26E+02
Se CFS-L04-1316-T05-C 1 8.55E+02
Se CFS-L04-1316-B01-A 1 7.50E+00 U1/2
Se CFS-L04-1316-B02-A 1 7.50E+00 U1/2
Se CFS-L04-1316-B03-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.30E+01 1.6E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
1.41E+02 9.6E+00 1 .5E+01 4.8E+01 10 100 1.16E+03 102% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
3.05E+02 5.3E+00 1.5E+01 4.8E+01
5.48E+02 2.3E+00 1.5E+01 4.8E+01
9.06E+02 1.6E+00 1.5E+01 4.8E+01
6.33E+01 1.3E+01 1.5E+01 4.8E+01
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.36E+02 3.0E+00 1.5E+01 4.8E+01 10 100 1.18E+03 104% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
2.82E+02 7.3E+00 1.5E+01 4.8E+01
5.08E+02 7.1E-01 1.5E+01 4.8E+01
8.92E+02 1.1E+01 1.5E+01 4.8E+01
7.95E+01 2.5E+01 1.5E+01 4.8E+01
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.30E+02 6.5E+00 1.5E+01 4.8E+01 10 100 1.16E+03 103% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
2.97E+02 6.6E-01 1.5E+01 4.8E+01
5.26E+02 1.7E+00 1.5E+01 4.8E+01
8.55E+02 2.3E+00 1.5E+01 4.8E+01
7.50E+00 3.8E+01 1.5E+01 4.8E+01
7.50E+00 2.6E+02 1.5E+01 4.8E+01
7.50E+00 1.3E+02 1.5E+01 4.8E+01
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1648
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si CFS-L04-1316-T01-A 1 3.93E+03
Si CFS-L04-1316-T02-A 1 4.87E+03
Si CFS-L04-1316-T03-A 1 6.71E+03
Si CFS-L04-1316-T04-A 1 6.85E+03
Si CFS-L04-1316-T05-A 1 6.81E+03
Si CFS-L04-1316-T01-B 1 3.46E+03
Si CFS-L04-1316-T02-B 1 4.68E+03
Si CFS-L04-1316-T03-B 1 5.73E+03
Si CFS-L04-1316-T04-B 1 6.03E+03
Si CFS-L04-1316-T05-B 1 6.45E+03
Si CFS-L04-1316-T01-C 1 3.74E+03
Si CFS-L04-1316-T02-C 1 4.84E+03
Si CFS-L04-1316-T03-C 1 6.03E+03
Si CFS-L04-1316-T04-C 1 6.41E+03
Si CFS-L04-1316-T05-C 1 6.89E+03
Si CFS-L04-1316-B01-A 1 6.31E+01
Si CFS-L04-1316-B02-A 1 1.31E+01
Si CFS-L04-1316-B03-A 1 6.93E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.93E+03 7.1E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
4.87E+03 8.9E-01 1.1E+00 3.5E+00 1000 100 5.72E+03 85% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
6.71E+03 6.6E-01 1.1E+00 3.5E+00
6.85E+03 5.8E-01 1.1E+00 3.5E+00
6.81E+03 2.9E-01 1.1E+00 3.5E+00
3.46E+03 2.9E-01 1.1E+00 3.5E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
4.68E+03 1.8E+00 1.1E+00 3.5E+00 1000 100 5.63E+03 95% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
5.73E+03 1.2E+00 1.1E+00 3.5E+00
6.03E+03 2.8E-01 1.1E+00 3.5E+00
6.45E+03 1.2E+01 1.1E+00 3.5E+00
3.74E+03 7.4E-01 1.1E+00 3.5E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
4.84E+03 3.1E-01 1.1E+00 3.5E+00 1000 100 5.77E+03 93% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
6.03E+03 1.9E+00 1.1E+00 3.5E+00
6.41 E+03 3.8E-01 1.1E+00 3.5E+00
6.89E+03 7.3E-01 1.1E+00 3.5E+00
6.31 E+01 1.3E+01 1.1E+00 3.5E+00
1.31E+01 2.6E+01 1.1E+00 3.5E+00
6.93E+00 2.5E+01 1.1E+00 3.5E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1649
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na CFS-L04-1316-T01-A 1 2.06E+04
Na CFS-L04-1316-T02-A 1 3.77E+04
Na CFS-L04-1316-T03-A 1 8.02E+04
Na CFS-L04-1316-T04-A 1 1.26E+05
Na CFS-L04-1316-T05-A 1 1.93E+05
Na CFS-L04-1316-T01-B 1 2.04E+04
Na CFS-L04-1316-T02-B 1 3.75E+04
Na CFS-L04-1316-T03-B 1 7.84E+04
Na CFS-L04-1316-T04-B 1 1.24E+05
Na CFS-L04-1316-T05-B 1 1.90E+05
Na CFS-L04-1316-T01-C 1 2.05E+04
Na CFS-L04-1316-T02-C 1 3.77E+04
Na CFS-L04-1316-T03-C 1 7.59E+04
Na CFS-L04-1316-T04-C 1 1.20E+05
Na CFS-L04-1316-T05-C 1 1.88E+05
Na CFS-L04-1316-B01-A 1 7.33E+01
Na CFS-L04-1316-B02-A 1 1.61E+01
Na CFS-L04-1316-B03-A 1 1.33E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.06E+04 1.8E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
3.77E+04 5.4E-01 2.5E+00 8.0E+00 1000 100 3.86E+04 92% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
8.02E+04 1.5E-01 2.5E+00 8.0E+00
1.26E+05 3.1E-01 2.5E+00 8.0E+00
1.93E+05 4.1E-01 2.5E+00 8.0E+00
2.04E+04 7.5E-01 2.5E+00 8.0E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
3.75E+04 8.2E-01 2.5E+00 8.0E+00 1000 100 3.85E+04 102% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
7.84E+04 5.3E-02 2.5E+00 8.0E+00
1.24E+05 4.4E-01 2.5E+00 8.0E+00
1.90E+05 3.2E+00 2.5E+00 8.0E+00
2.05E+04 1.1E+00 2.5E+00 8.0E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
3.77E+04 1.1E+00 2.5E+00 8.0E+00 1000 100 3.87E+04 103% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
7.59E+04 3.9E-01 2.5E+00 8.0E+00
1.20E+05 3.7E-01 2.5E+00 8.0E+00
1.88E+05 6.3E-01 2.5E+00 8.0E+00
7.33E+01 3.7E+00 2.5E+00 8.0E+00
1.61E+01 1.4E+01 2.5E+00 8.0E+00
1.33E+01 1.6E+01 2.5E+00 8.0E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1650
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L04-1316-T01-A 1 1.54E+03
CFS-L04-1316-T02-A 1 2.65E+03
CFS-L04-1316-T03-A 1 3.48E+03
CFS-L04-1316-T04-A 1 4.55E+03
CFS-L04-1316-T05-A 1 5.10E+03
CFS-L04-1316-T01-B 1 1.49E+03
CFS-L04-1316-T02-B 1 2.30E+03
CFS-L04-1316-T03-B 1 3.45E+03
CFS-L04-1316-T04-B 1 4.32E+03
CFS-L04-1316-T05-B 1 5.00E+03
CFS-L04-1316-T01-C 1 1.53E+03
CFS-L04-1316-T02-C 1 2.23E+03
CFS-L04-1316-T03-C 1 3.34E+03
CFS-L04-1316-T04-C 1 4.09E+03
CFS-L04-1316-T05-C 1 4.75E+03
CFS-L04-1316-B01-A 1 5.00E-01 U1/2
CFS-L04-1316-B02-A 1 5.00E-01 U1/2
CFS-L04-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+03 7.5E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
2.65E+03 4.1E-01 1 .OE+00 3.2E+00 1000 100 3.57E+03 92% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
3.48E+03 1. OE+00 1 .OE+00 3.2E+00
4.55E+03 1.3E+00 1 .OE+00 3.2E+00
5.10E+03 1.1E+00 1.0E+00 3.2E+00
1.49E+03 5.9E-01 1 .OE+00 3.2E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
2.30E+03 1.5E+00 1 .OE+00 3.2E+00 1000 100 3.17E+03 87% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
3.45E+03 1.1E+00 1 .OE+00 3.2E+00
4.32E+03 7.8E-01 1 .OE+00 3.2E+00
5.00E+03 1.1E+01 1. OE+00 3.2E+00
1.53E+03 4.5E-01 1 .OE+00 3.2E+00
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
2.23E+03 5.2E-01 1 .OE+00 3.2E+00 1000 100 3.13E+03 91%VUICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
3.34E+03 1.4E+00 1. OE+00 3.2E+00
4.09E+03 1.2E+00 1. OE+00 3.2E+00
4.75E+03 1.2E+00 1. OE+00 3.2E+00
5.00E-01 5.7E+01 1. OE+00 3.2E+00
5.00E-01 7.5E+00 1. OE+00 3.2E+00
5.00E-01 1.8E+01 1. OE+00 3.2E+00
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1651
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S CFS-L04-1316-T01-A 1 6.20E+05
S CFS-L04-1316-T02-A 1 7.14E+05
S CFS-L04-1316-T03-A 1 9.19E+05
S CFS-L04-1316-T04-A 1 1.22E+06
S CFS-L04-1316-T05-A 1 1.58E+06
S CFS-L04-1316-T01-B 1 6.10E+05
S CFS-L04-1316-T02-B 1 7.03E+05
S CFS-L04-1316-T03-B 1 9.06E+05
S CFS-L04-1316-T04-B 1 1.16E+06
S CFS-L04-1316-T05-B 1 1.57E+06
S CFS-L04-1316-T01-C 1 6.35E+05
S CFS-L04-1316-T02-C 1 7.09E+05
S CFS-L04-1316-T03-C 1 8.99E+05
S CFS-L04-1316-T04-C 1 1.18E+06
S CFS-L04-1316-T05-C 1 1.56E+06
S CFS-L04-1316-B01-A 1 3.40E+00 U1/2
S CFS-L04-1316-B02-A 1 3.40E+00 U1/2
S CFS-L04-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.20E+05 7.0E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
7.14E+05 2.4E-01 6.8E+00 2.2E+01 1000 100 7.15E+05 87% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
9.19E+05 5.5E-01 6.8E+00 2.2E+01
1.22E+06 8.6E-01 6.8E+00 2.2E+01
1.58E+06 2.3E-01 6.8E+00 2.2E+01
6.10E+05 1.9E-01 6.8E+00 2.2E+01
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
7.03E+05 8.6E-01 6.8E+00 2.2E+01 1000 100 7.04E+05 90% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
9.06E+05 3.1E-01 6.8E+00 2.2E+01
1.16E+06 5.3E-01 6.8E+00 2.2E+01
1.57E+06 1.1E+01 6.8E+00 2.2E+01
6.35E+05 9.0E-01 6.8E+00 2.2E+01
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
7.09E+05 3.5E-01 6.8E+00 2.2E+01 1000 100 7.10E+05 94% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
8.99E+05 8.0E-01 6.8E+00 2.2E+01
1.18E+06 2.7E-01 6.8E+00 2.2E+01
1.56E+06 9.0E-01 6.8E+00 2.2E+01
3.40E+00 4.6E+02 6.8E+00 2.2E+01
3.40E+00 5.0E+00 6.8E+00 2.2E+01
3.40E+00 3.0E+00 6.8E+00 2.2E+01
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1652
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl CFS-L04-1316-T01-A 1 3.27E+02
Tl CFS-L04-1316-T02-A 1 4.96E+02
Tl CFS-L04-1316-T03-A 1 8.16E+02
Tl CFS-L04-1316-T04-A 1 1.11E+03
Tl CFS-L04-1316-T05-A 1 5.06E+02
Tl CFS-L04-1316-T01-B 1 2.95E+02
Tl CFS-L04-1316-T02-B 1 4.50E+02
Tl CFS-L04-1316-T03-B 1 7.18E+02
Tl CFS-L04-1316-T04-B 1 9.67E+02
Tl CFS-L04-1316-T05-B 1 4.06E+02
Tl CFS-L04-1316-T01-C 1 3.12E+02
Tl CFS-L04-1316-T02-C 1 4.72E+02
Tl CFS-L04-1316-T03-C 1 7.46E+02
Tl CFS-L04-1316-T04-C 1 1.01E+03
Tl CFS-L04-1316-T05-C 1 3.76E+02
Tl CFS-L04-1316-B01-A 1 2.30E+00 U1/2
Tl CFS-L04-1316-B02-A 1 2.30E+00 U1/2
Tl CFS-L04-1316-B03-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.27E+02 1.1E+00 4.6E+00 1.5E+01
4.96E+02 2.8E-01 4.6E+00 1.5E+01 10 100
8.16E+02 1.1E+00 4.6E+00 1.5E+01
1.11E+03 1.0E+00 4.6E+00 1.5E+01
5.06E+02 1.5E+00 4.6E+00 1.5E+01
2.95E+02 9.5E-01 4.6E+00 1.5E+01
4.50E+02 2.0E+00 4.6E+00 1.5E+01 10 100
7.18E+02 1.9E+00 4.6E+00 1.5E+01
9.67E+02 1.6E+00 4.6E+00 1.5E+01
4.06E+02 1.2E+01 4.6E+00 1.5E+01
3.12E+02 2.1E+00 4.6E+00 1.5E+01
4.72E+02 1.9E+00 4.6E+00 1.5E+01 10 100
7.46E+02 8.7E-01 4.6E+00 1.5E+01
1.01E+03 3.9E-01 4.6E+00 1.5E+01
3.76E+02 1.5E+00 4.6E+00 1.5E+01
2.30E+00 2.2E+02 4.6E+00 1.5E+01
2.30E+00 6.2E+01 4.6E+00 1.5E+01
2.30E+00 3.7E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
1.39E+03 89%VUICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.35E+03 90%VUICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.36E+03 89% VUICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1653
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti CFS-L04-1316-T01-A 1 1.00E+OOU1/2
Ti CFS-L04-1316-T02-A 1 1.00E+OOU1/2
Ti CFS-L04-1316-T03-A 1 1.00E+OOU1/2
Ti CFS-L04-1316-T04-A 1 1.00E+OOU1/2
Ti CFS-L04-1316-T05-A 1 1.00E+OOU1/2
Ti CFS-L04-1316-T01-B 1 1.00E+OOU1/2
Ti CFS-L04-1316-T02-B 1 1.00E+OOU1/2
Ti CFS-L04-1316-T03-B 1 1.00E+OOU1/2
Ti CFS-L04-1316-T04-B 1 1.00E+OOU1/2
Ti CFS-L04-1316-T05-B 1 1.00E+OOU1/2
Ti CFS-L04-1316-T01-C 1 1.00E+OOU1/2
Ti CFS-L04-1316-T02-C 1 1.00E+OOU1/2
Ti CFS-L04-1316-T03-C 1 1.00E+OOU1/2
Ti CFS-L04-1316-T04-C 1 1.00E+OOU1/2
Ti CFS-L04-1316-T05-C 1 1.00E+OOU1/2
Ti CFS-L04-1316-B01-A 1 1.00E+OOU1/2
Ti CFS-L04-1316-B02-A 1 1.00E+OOU1/2
Ti CFS-L04-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.4E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 2.4E+00 2.0E+00 6.4E+00 10 100 9.41E+02 94% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 4.4E+00 2.0E+00 6.4E+00
1.00E+00 1.7E+00 2.0E+00 6.4E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 8.7E+00 2.0E+00 6.4E+00 10 100 9.50E+02 95% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 3.6E+00 2.0E+00 6.4E+00
1.00E+00 1.1E+01 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 2.3E+00 2.0E+00 6.4E+00
VU ICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 1.8E+00 2.0E+00 6.4E+00 10 100 9.50E+02 95% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
1.00E+00 1.2E+01 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
1.00E+00 5.4E+00 2.0E+00 6.4E+00
1.00E+00 5.5E+00 2.0E+00 6.4E+00
VU ICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1654
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V CFS-L04-1316-T01-A 1 3.45E+01
V CFS-L04-1316-T02-A 1 3.29E+01
V CFS-L04-1316-T03-A 1 2.94E+01
V CFS-L04-1316-T04-A 1 2.88E+01
V CFS-L04-1316-T05-A 1 2.52E+01
V CFS-L04-1316-T01-B 1 3.23E+01
V CFS-L04-1316-T02-B 1 3.11E+01
V CFS-L04-1316-T03-B 1 3.01 E+01
V CFS-L04-1316-T04-B 1 2.77E+01
V CFS-L04-1316-T05-B 1 2.45E+01
V CFS-L04-1316-T01-C 1 3.25E+01
V CFS-L04-1316-T02-C 1 3.18E+01
V CFS-L04-1316-T03-C 1 2.94E+01
V CFS-L04-1316-T04-C 1 2.79E+01
V CFS-L04-1316-T05-C 1 2.52E+01
V CFS-L04-1316-B01-A 1 7.50E-01 U1/2
V CFS-L04-1316-B02-A 1 7.50E-01 U1/2
V CFS-L04-1316-B03-A 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.45E+01 2.3E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
3.29E+01 2.6E+00 1 .5E+00 4.8E+00 10 100 1 .04E+03 101% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
2.94E+01 2.0E+00 1 .5E+00 4.8E+00
2.88E+01 7.7E-01 1 .5E+00 4.8E+00
2.52E+01 3.0E+00 1 .5E+00 4.8E+00
3.23E+01 8.7E-01 1 .5E+00 4.8E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
3.11E+01 5.3E+00 1.5E+00 4.8E+00 10 100 1 .07E+03 103% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
3.01 E+01 1.9E+00 1.5E+00 4.8E+00
2.77E+01 1.5E+00 1 .5E+00 4.8E+00
2.45E+01 1.8E+01 1 .5E+00 4.8E+00
3.25E+01 3.5E+00 1 .5E+00 4.8E+00
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
3.18E+01 2.3E+00 1 .5E+00 4.8E+00 10 100 1.06E+03 103% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
2.94E+01 2.8E+00 1.5E+00 4.8E+00
2.79E+01 1.1E+00 1.5E+00 4.8E+00
2.52E+01 7.3E+00 1.5E+00 4.8E+00
7.50E-01 1.1E+02 1.5E+00 4.8E+00
7.50E-01 1.1E+02 1.5E+00 4.8E+00
7.50E-01 8.2E+01 1.5E+00 4.8E+00
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1655
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn CFS-L04-1316-T01-A 1 2.00E+04
Zn CFS-L04-1316-T02-A 1 2.17E+04
Zn CFS-L04-1316-T03-A 1 4.39E+04
Zn CFS-L04-1316-T04-A 1 4.98E+04
Zn CFS-L04-1316-T05-A 1 5.17E+04
Zn CFS-L04-1316-T01-B 1 1.77E+04
Zn CFS-L04-1316-T02-B 1 2.45E+04
Zn CFS-L04-1316-T03-B 1 3.64E+04
Zn CFS-L04-1316-T04-B 1 4.37E+04
Zn CFS-L04-1316-T05-B 1 4.75E+04
Zn CFS-L04-1316-T01-C 1 1.96E+04
Zn CFS-L04-1316-T02-C 1 2.82E+04
Zn CFS-L04-1316-T03-C 1 4.18E+04
Zn CFS-L04-1316-T04-C 1 5.02E+04
Zn CFS-L04-1316-T05-C 1 5.80E+04
Zn CFS-L04-1316-B01-A 1 1.39E+02
Zn CFS-L04-1316-B02-A 1 4.46E+00
Zn CFS-L04-1316-B03-A 1 4.17E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.00E+04 2.5E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/25/11 3:59 PM EPA Interlab L04 1313-1316 CFS
2.17E+04 1.8E+00 1 .OE+00 3.2E+00 10 100 2.28E+04 11 1% VU ICP-OES 5/25/11 4:01 PM EPA Interlab L04 1313-1316 CFS
4.39E+04 9.6E-01 1 .OE+00 3.2E+00
4.98E+04 7.8E-01 1 .OE+00 3.2E+00
5.17E+04 4.8E-01 1 .OE+00 3.2E+00
1.77E+04 1.3E+00 1 .OE+00 3.2E+00
VU ICP-OES 5/25/11 4:03 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:04 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:06 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:08 PM EPA Interlab L04 1313-1316 CFS
2.45E+04 7.9E-01 1 .OE+00 3.2E+00 10 100 2.55E+04 101% VU ICP-OES 5/25/11 4:09 PM EPA Interlab L04 1313-1316 CFS
3.64E+04 8.2E-01 1 .OE+00 3.2E+00
4.37E+04 1.8E-01 1 .OE+00 3.2E+00
4.75E+04 1.0E+01 1 .OE+00 3.2E+00
1.96E+04 9.2E-01 1 .OE+00 3.2E+00
VUICP-OES 5/25/11 4:11 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:13 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:14 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:16 PM EPA Interlab L04 1313-1316 CFS
2.82E+04 5.9E-01 1 .OE+00 3.2E+00 10 100 2.92E+04 94% VU ICP-OES 5/25/11 4:17 PM EPA Interlab L04 1313-1316 CFS
4.18E+04 1. OE+00 1. OE+00 3.2E+00
5.02E+04 1.2E+00 1. OE+00 3.2E+00
5.80E+04 1. OE+00 1. OE+00 3.2E+00
1.39E+02 2.8E+00 1. OE+00 3.2E+00
4.46E+00 4.9E+00 1. OE+00 3.2E+00
4.17E+00 6.3E+00 1.0E+00 3.2E+00
VUICP-OES 5/25/11 4:19 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 4:21 PM EPA Interlab L04 1313-1316 CFS
VU ICP-OES 5/25/11 4:22 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:54 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:56 PM EPA Interlab L04 1313-1316 CFS
VUICP-OES 5/25/11 3:58 PM EPA Interlab L04 1313-1316 CFS
                                                                                                                                                                         1-1656
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al CFS-L06-1316-T01-A 1 5.02E+01
Al CFS-L06-1316-T02-A 1 5.65E+01
Al CFS-L06-1316-T03-A 1 5.91 E+01
Al CFS-L06-1316-T04-A 1 1.18E+02
Al CFS-L06-1316-T05-A 1 7.96E+01
Al CFS-L06-1316-T01-B 1 4.83E+01
Al CFS-L06-1316-T02-B 1 5.19E+01
Al CFS-L06-1316-T03-B 1 1.18E+02
Al CFS-L06-1316-T04-B 1 7.19E+01
Al CFS-L06-1316-T05-B 1 6.74E+01
Al CFS-L06-1316-T01-C 1 4.95E+01
Al CFS-L06-1316-T02-C 1 5.15E+01
Al CFS-L06-1316-T03-C 1 5.74E+01
Al CFS-L06-1316-T04-C 1 5.85E+01
Al CFS-L06-1316-T05-C 1 6.02E+01
Al CFS-L06-1316-B01-A 1 5.00E-01 U1/2
Al CFS-L06-1316-B02-A 1 5.00E-01 U1/2
Al CFS-L06-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.02E+01 3.3E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
5.65E+01 1.6E+00 1 .OE+00 3.2E+00 1000 120 1.21E+03 96% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
5.91 E+01 2.8E+00 1 .OE+00 3.2E+00
1.18E+02 2.1E+00 1. OE+00 3.2E+00
7.96E+01 3.5E+00 1 .OE+00 3.2E+00
4.83E+01 5.0E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
5.19E+01 4.9E+00 1 .OE+00 3.2E+00 1000 120 1 .28E+03 102% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
1.18E+02 3.8E+00 1 .OE+00 3.2E+00
7.19E+01 6.8E+00 1 .OE+00 3.2E+00
6.74E+01 6.4E+00 1 .OE+00 3.2E+00
4.95E+01 4.7E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
5.15E+01 5.1E+00 1.0E+00 3.2E+00 1000 120 1 .27E+03 101% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
5.74E+01 4.3E+00 1 .OE+00 3.2E+00
5.85E+01 4.3E+00 1 .OE+00 3.2E+00
6.02E+01 1.0E+01 1. OE+00 3.2E+00
5.00E-01 9.1 E+01 1. OE+00 3.2E+00
5.00E-01 1.6E+02 1 .OE+00 3.2E+00
5.00E-01 1.0E+02 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                                 1-1657
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb CFS-L06-1316-T01-A 1 3.64E+01
Sb CFS-L06-1316-T02-A 1 3.16E+01
Sb CFS-L06-1316-T03-A 1 4.77E+01
Sb CFS-L06-1316-T04-A 1 6.67E+01
Sb CFS-L06-1316-T05-A 1 7.25E+01
Sb CFS-L06-1316-T01-B 1 3.54E+01
Sb CFS-L06-1316-T02-B 1 4.27E+01
Sb CFS-L06-1316-T03-B 1 5.82E+01
Sb CFS-L06-1316-T04-B 1 6.46E+01
Sb CFS-L06-1316-T05-B 1 7.29E+01
Sb CFS-L06-1316-T01-C 1 3.99E+01
Sb CFS-L06-1316-T02-C 1 4.94E+01
Sb CFS-L06-1316-T03-C 1 4.92E+01
Sb CFS-L06-1316-T04-C 1 5.62E+01
Sb CFS-L06-1316-T05-C 1 8.06E+01
Sb CFS-L06-1316-B01-A 1 3.75E+00 U1/2
Sb CFS-L06-1316-B02-A 1 8.33E+00 E
Sb CFS-L06-1316-B03-A 1 7.56E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.64E+01 1.5E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
3.16E+01 3.9E+01 7.5E+00 2.4E+01 10 120 1.19E+03 96% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
4.77E+01 1.1E+01 7.5E+00 2.4E+01
6.67E+01 1.3E+01 7.5E+00 2.4E+01
7.25E+01 1.9E+01 7.5E+00 2.4E+01
3.54E+01 1.1E+01 7.5E+00 2.4E+01
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
4.27E+01 1.2E+01 7.5E+00 2.4E+01 10 120 1.25E+03 101% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
5.82E+01 2.8E+01 7.5E+00 2.4E+01
6.46E+01 1.3E+01 7.5E+00 2.4E+01
7.29E+01 1.0E+01 7.5E+00 2.4E+01
3.99E+01 1.4E+01 7.5E+00 2.4E+01
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
4.94E+01 9.6E+00 7.5E+00 2.4E+01 10 120 1.26E+03 101% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
4.92E+01 1.5E+01 7.5E+00 2.4E+01
5.62E+01 1.8E+01 7.5E+00 2.4E+01
8.06E+01 7.0E+00 7.5E+00 2.4E+01
3.75E+00 1.2E+02 7.5E+00 2.4E+01
8.33E+00 5.7E+01 7.5E+00 2.4E+01
7.56E+00 8.3E+01 7.5E+00 2.4E+01
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1658
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
ug/L
As CFS-L06-1316-T01-A 1 2.47E+01 E
As CFS-L06-1316-T02-A 1 2.34E+01 E
As CFS-L06-1316-T03-A 1 4.42E+01
As CFS-L06-1316-T04-A 1 1.07E+02
As CFS-L06-1316-T05-A 1 6.36E+01
As CFS-L06-1316-T01-B 1 1.45E+01 E
As CFS-L06-1316-T02-B 1 3.66E+01
As CFS-L06-1316-T03-B 1 1.08E+02
As CFS-L06-1316-T04-B 1 4.65E+01
As CFS-L06-1316-T05-B 1 5.59E+01
As CFS-L06-1316-T01-C 1 2.54E+01 E
As CFS-L06-1316-T02-C 1 2.04E+01 E
As CFS-L06-1316-T03-C 1 4.23E+01
As CFS-L06-1316-T04-C 1 3.60E+01
As CFS-L06-1316-T05-C 1 6.16E+01
As CFS-L06-1316-B01-A 1 5.50E+00 U1/2
As CFS-L06-1316-B02-A 1 5.50E+00 U1/2
As CFS-L06-1316-B03-A 1 5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.47E+01 1.3E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
2.34E+01 2.2E+01 1.1E+01 3.5E+01 10 120 1.21E+03 99% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
4.42E+01 9.8E+00 1.1E+01 3.5E+01
1.07E+02 7.9E+00 1.1E+01 3.5E+01
6.36E+01 1.4E+01 1.1E+01 3.5E+01
1.45E+01 7.7E+01 1.1E+01 3.5E+01
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
3.66E+01 1.7E+01 1.1E+01 3.5E+01 10 120 1 .25E+03 102% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
1.08E+02 8.3E+00 1.1E+01 3.5E+01
4.65E+01 6.9E+00 1.1E+01 3.5E+01
5.59E+01 1.7E+01 1.1E+01 3.5E+01
2.54E+01 4.7E+01 1.1E+01 3.5E+01
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
2.04E+01 2.7E+01 1.1E+01 3.5E+01 10 120 1 .27E+03 104% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
4.23E+01 2.2E+01 1.1E+01 3.5E+01
3.60E+01 3.8E+01 1.1E+01 3.5E+01
6.16E+01 5.4E+00 1.1E+01 3.5E+01
5.50E+00 5.0E+01 1.1E+01 3.5E+01
5.50E+00 1.5E+02 1.1E+01 3.5E+01
5.50E+00 1.3E+02 1.1E+01 3.5E+01
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1659
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B CFS-L06-1316-T01-A 1 1.77E+02
B CFS-L06-1316-T02-A 1 3.07E+02
B CFS-L06-1316-T03-A 1 6.27E+02
B CFS-L06-1316-T04-A 1 1.03E+03
B CFS-L06-1316-T05-A 1 1.56E+03
B CFS-L06-1316-T01-B 1 1.94E+02
B CFS-L06-1316-T02-B 1 3.20E+02
B CFS-L06-1316-T03-B 1 6.28E+02
B CFS-L06-1316-T04-B 1 1.01E+03
B CFS-L06-1316-T05-B 1 1.57E+03
B CFS-L06-1316-T01-C 1 1.95E+02
B CFS-L06-1316-T02-C 1 3.22E+02
B CFS-L06-1316-T03-C 1 6.33E+02
B CFS-L06-1316-T04-C 1 1.04E+03
B CFS-L06-1316-T05-C 1 1.50E+03
B CFS-L06-1316-B01-A 1 8.49E+00
B CFS-L06-1316-B02-A 1 9.12E+00
B CFS-L06-1316-B03-A 1 6.91 E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+02 2.0E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
3.07E+02 1.2E+00 1 .OE+00 3.2E+00 1000 120 1 .43E+03 94% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
6.27E+02 7.8E-01 1 .OE+00 3.2E+00
1.03E+03 4.8E-01 1 .OE+00 3.2E+00
1.56E+03 2.4E-01 1 .OE+00 3.2E+00
1.94E+02 1.5E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
3.20E+02 8.3E-01 1 .OE+00 3.2E+00 1000 120 1 .48E+03 96% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
6.28E+02 5.6E-01 1 .OE+00 3.2E+00
1.01E+03 7.8E-01 1. OE+00 3.2E+00
1.57E+03 5.7E-01 1 .OE+00 3.2E+00
1.95E+02 9.5E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
3.22E+02 6.2E-01 1 .OE+00 3.2E+00 1000 120 1.49E+03 98% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
6.33E+02 6.0E-01 1. OE+00 3.2E+00
1.04E+03 8.9E-01 1. OE+00 3.2E+00
1.50E+03 4.6E-01 1. OE+00 3.2E+00
8.49E+00 2.2E+01 1. OE+00 3.2E+00
9.12E+00 7.3E+00 1. OE+00 3.2E+00
6.91 E+00 1.0E+01 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1660
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba CFS-L06-1316-T01-A 1 1.35E+02
Ba CFS-L06-1316-T02-A 1 1.24E+02
Ba CFS-L06-1316-T03-A 1 1.05E+02
Ba CFS-L06-1316-T04-A 1 9.04E+01
Ba CFS-L06-1316-T05-A 1 7.28E+01
Ba CFS-L06-1316-T01-B 1 1.34E+02
Ba CFS-L06-1316-T02-B 1 1.25E+02
Ba CFS-L06-1316-T03-B 1 1.08E+02
Ba CFS-L06-1316-T04-B 1 8.67E+01
Ba CFS-L06-1316-T05-B 1 7.85E+01
Ba CFS-L06-1316-T01-C 1 1.37E+02
Ba CFS-L06-1316-T02-C 1 1.24E+02
Ba CFS-L06-1316-T03-C 1 1.02E+02
Ba CFS-L06-1316-T04-C 1 8.60E+01
Ba CFS-L06-1316-T05-C 1 7.14E+01
Ba CFS-L06-1316-B01-A 1 5.00E-01 U1/2
Ba CFS-L06-1316-B02-A 1 5.00E-01 U1/2
Ba CFS-L06-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.35E+02 6.5E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.24E+02 1.4E+00 1 .OE+00 3.2E+00 10 120 1.37E+03 104% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
1.05E+02 9.6E-01 1. OE+00 3.2E+00
9.04E+01 4.4E-01 1. OE+00 3.2E+00
7.28E+01 4.3E-01 1. OE+00 3.2E+00
1.34E+02 3.9E-01 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.25E+02 2.9E-01 1.0E+00 3.2E+00 10 120 1.43E+03 109% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
1.08E+02 3.5E-01 1. OE+00 3.2E+00
8.67E+01 5.4E-01 1. OE+00 3.2E+00
7.85E+01 5.3E-01 1. OE+00 3.2E+00
1.37E+02 4.0E-01 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.24E+02 8.3E-01 1.0E+00 3.2E+00 10 120 1.42E+03 108% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
1.02E+02 8.4E-02 1. OE+00 3.2E+00
8.60E+01 5.6E-01 1. OE+00 3.2E+00
7.14E+01 9.9E-01 1. OE+00 3.2E+00
5.00E-01 3.5E+01 1. OE+00 3.2E+00
5.00E-01 6.0E+00 1. OE+00 3.2E+00
5.00E-01 1.4E+01 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1661
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be CFS-L06-1316-T01-A 1 9.50E-01 U1/2
Be CFS-L06-1316-T02-A 1 9.50E-01 U1/2
Be CFS-L06-1316-T03-A 1 9.50E-01 U1/2
Be CFS-L06-1316-T04-A 1 9.50E-01 U1/2
Be CFS-L06-1316-T05-A 1 9.50E-01 U1/2
Be CFS-L06-1316-T01-B 1 9.50E-01 U1/2
Be CFS-L06-1316-T02-B 1 9.50E-01 U1/2
Be CFS-L06-1316-T03-B 1 9.50E-01 U1/2
Be CFS-L06-1316-T04-B 1 9.50E-01 U1/2
Be CFS-L06-1316-T05-B 1 9.50E-01 U1/2
Be CFS-L06-1316-T01-C 1 9.50E-01 U1/2
Be CFS-L06-1316-T02-C 1 9.50E-01 U1/2
Be CFS-L06-1316-T03-C 1 9.50E-01 U1/2
Be CFS-L06-1316-T04-C 1 9.50E-01 U1/2
Be CFS-L06-1316-T05-C 1 9.50E-01 U1/2
Be CFS-L06-1316-B01-A 1 9.50E-01 U1/2
Be CFS-L06-1316-B02-A 1 9.50E-01 U1/2
Be CFS-L06-1316-B03-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.2E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
9.50E-01 1.2E+02 1.9E+00 6.0E+00 10 120 1.18E+03 98% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
9.50E-01 2.0E+02 1.9E+00 6.0E+00
9.50E-01 9.7E+01 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 8.3E+01 1.9E+00 6.0E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
9.50E-01 1.7E+02 1.9E+00 6.0E+00 10 120 1.23E+03 103% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
9.50E-01 7.5E+01 1.9E+00 6.0E+00
9.50E-01 8.4E+01 1.9E+00 6.0E+00
9.50E-01 1.3E+01 1.9E+00 6.0E+00
9.50E-01 1.1E+02 1.9E+00 6.0E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
9.50E-01 5.6E+01 1.9E+00 6.0E+00 10 120 1.23E+03 103% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
9.50E-01 6.9E+02 1.9E+00 6.0E+00
9.50E-01 5.8E+01 1.9E+00 6.0E+00
9.50E-01 7.5E+00 1.9E+00 6.0E+00
9.50E-01 9.5E+02 1.9E+00 6.0E+00
9.50E-01 3.2E+02 1.9E+00 6.0E+00
9.50E-01 9.0E+01 1.9E+00 6.0E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/1 1 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/1 1 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1662
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd CFS-L06-1316-T01-A 1 5.00E+03
Cd CFS-L06-1316-T02-A 1 6.59E+03
Cd CFS-L06-1316-T03-A 1 9.28E+03
Cd CFS-L06-1316-T04-A 1 1.19E+04
Cd CFS-L06-1316-T05-A 1 1.54E+04
Cd CFS-L06-1316-T01-B 1 4.87E+03
Cd CFS-L06-1316-T02-B 1 7.08E+03
Cd CFS-L06-1316-T03-B 1 9.45E+03
Cd CFS-L06-1316-T04-B 1 1.28E+04
Cd CFS-L06-1316-T05-B 1 1.53E+04
Cd CFS-L06-1316-T01-C 1 5.25E+03
Cd CFS-L06-1316-T02-C 1 7.08E+03
Cd CFS-L06-1316-T03-C 1 1.02E+04
Cd CFS-L06-1316-T04-C 1 1.31E+04
Cd CFS-L06-1316-T05-C 1 1.44E+04
Cd CFS-L06-1316-B01-A 1 1.10E+OOU1/2
Cd CFS-L06-1316-B02-A 1 1.10E+OOU1/2
Cd CFS-L06-1316-B03-A 1 1.10E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E+03 7.5E-01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
6.59E+03 8.3E-01 2.2E+00 7.0E+00 10 120 7.64E+03 88% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
9.28E+03 6.7E-01 2.2E+00 7.0E+00
1.19E+04 1.0E+00 2.2E+00 7.0E+00
1.54E+04 4.8E-01 2.2E+00 7.0E+00
4.87E+03 4.5E-01 2.2E+00 7.0E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
7.08E+03 9.3E-02 2.2E+00 7.0E+00 10 120 8.13E+03 87% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
9.45E+03 2.3E-01 2.2E+00 7.0E+00
1.28E+04 3.7E-01 2.2E+00 7.0E+00
1.53E+04 9.6E-01 2.2E+00 7.0E+00
5.25E+03 4.4E-01 2.2E+00 7.0E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
7.08E+03 3.9E-01 2.2E+00 7.0E+00 10 120 8.16E+03 90% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
1.02E+04 2.1E-01 2.2E+00 7.0E+00
1.31E+04 5.1E-01 2.2E+00 7.0E+00
1.44E+04 4.1E-01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
1.10E+00 4.6E+01 2.2E+00 7.0E+00
1.10E+00 1.4E+02 2.2E+00 7.0E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1663
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca CFS-L06-1316-T01-A 1 7.51 E+05
Ca CFS-L06-1316-T02-A 1 7.14E+05
Ca CFS-L06-1316-T03-A 1 6.70E+05
Ca CFS-L06-1316-T04-A 1 6.46E+05
Ca CFS-L06-1316-T05-A 1 6.09E+05
Ca CFS-L06-1316-T01-B 1 7.55E+05
Ca CFS-L06-1316-T02-B 1 7.47E+05
Ca CFS-L06-1316-T03-B 1 6.87E+05
Ca CFS-L06-1316-T04-B 1 6.48E+05
Ca CFS-L06-1316-T05-B 1 6.38E+05
Ca CFS-L06-1316-T01-C 1 7.64E+05
Ca CFS-L06-1316-T02-C 1 7.19E+05
Ca CFS-L06-1316-T03-C 1 6.64E+05
Ca CFS-L06-1316-T04-C 1 6.30E+05
Ca CFS-L06-1316-T05-C 1 5.93E+05
Ca CFS-L06-1316-B01-A 1 1.75E+01
Ca CFS-L06-1316-B02-A 1 2.36E+01
Ca CFS-L06-1316-B03-A 1 2.45E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.51E+05 5.7E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
7.14E+05 7.3E-01 2.6E+00 8.3E+00 1000 120 7.15E+05 85% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
6.70E+05 4.3E-01 2.6E+00 8.3E+00
6.46E+05 9.3E-01 2.6E+00 8.3E+00
6.09E+05 5.5E-01 2.6E+00 8.3E+00
7.55E+05 3.8E-01 2.6E+00 8.3E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
7.47E+05 1.1E-01 2.6E+00 8.3E+00 1000 120 7.48E+05 89% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
6.87E+05 8.2E-02 2.6E+00 8.3E+00
6.48E+05 5.5E-01 2.6E+00 8.3E+00
6.38E+05 5.5E-01 2.6E+00 8.3E+00
7.64E+05 4.1E-01 2.6E+00 8.3E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
7.19E+05 2.0E-01 2.6E+00 8.3E+00 1000 120 7.20E+05 85% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
6.64E+05 3.9E-01 2.6E+00 8.3E+00
6.30E+05 6.9E-01 2.6E+00 8.3E+00
5.93E+05 5.8E-01 2.6E+00 8.3E+00
1.75E+01 6.4E+01 2.6E+00 8.3E+00
2.36E+01 5.6E+01 2.6E+00 8.3E+00
2.45E+01 9.7E+00 2.6E+00 8.3E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1664
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cr Sample Dilution Cone. Qualifier Revi
ug/L
Cr CFS-L06-1316-T01-A 1 6.00E-01 U1/2
Cr CFS-L06-1316-T02-A 1 6.00E-01 U1/2
Cr CFS-L06-1316-T03-A 1 6.00E-01 U1/2
Cr CFS-L06-1316-T04-A 1 6.00E-01 U1/2
Cr CFS-L06-1316-T05-A 1 6.00E-01 U1/2
Cr CFS-L06-1316-T01-B 1 6.00E-01 U1/2
Cr CFS-L06-1316-T02-B 1 6.00E-01 U1/2
Cr CFS-L06-1316-T03-B 1 6.00E-01 U1/2
Cr CFS-L06-1316-T04-B 1 6.00E-01 U1/2
Cr CFS-L06-1316-T05-B 1 6.00E-01 U1/2
Cr CFS-L06-1316-T01-C 1 6.00E-01 U1/2
Cr CFS-L06-1316-T02-C 1 6.00E-01 U1/2
Cr CFS-L06-1316-T03-C 1 6.00E-01 U1/2
Cr CFS-L06-1316-T04-C 1 6.00E-01 U1/2
Cr CFS-L06-1316-T05-C 1 6.00E-01 U1/2
Cr CFS-L06-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L06-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L06-1316-B01-A 1 6.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 7.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
6.00E-01 9.3E+01 1.2E+00 3.8E+00 10 120 1.12E+03 94% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
6.00E-01 4.1E+02 1.2E+00 3.8E+00
6.00E-01 2.2E+02 1.2E+00 3.8E+00
6.00E-01 4.7E+02 1.2E+00 3.8E+00
6.00E-01 3.3E+02 1.2E+00 3.8E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
6.00E-01 7.4E+01 1.2E+00 3.8E+00 10 120 1.18E+03 98% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
6.00E-01 2.8E+02 1.2E+00 3.8E+00
6.00E-01 3.8E+02 1.2E+00 3.8E+00
6.00E-01 7.0E+01 1.2E+00 3.8E+00
6.00E-01 4.9E+02 1.2E+00 3.8E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
6.00E-01 1.8E+02 1.2E+00 3.8E+00 10 120 1.17E+03 98% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
6.00E-01 4.0E+01 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
6.00E-01 4.0E+01 1.2E+00 3.8E+00
6.00E-01 1.3E+02 1.2E+00 3.8E+00
6.00E-01 4.9E+01 1.2E+00 3.8E+00
6.00E-01 1.8E+02 1.2E+00 3.8E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/1 1 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/1 1 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1665
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co CFS-L06-1316-T01-A 1 1.06E+02
Co CFS-L06-1316-T02-A 1 1.67E+02
Co CFS-L06-1316-T03-A 1 2.91E+02
Co CFS-L06-1316-T04-A 1 4.18E+02
Co CFS-L06-1316-T05-A 1 6.92E+02
Co CFS-L06-1316-T01-B 1 1.01E+02
Co CFS-L06-1316-T02-B 1 1.74E+02
Co CFS-L06-1316-T03-B 1 2.88E+02
Co CFS-L06-1316-T04-B 1 4.52E+02
Co CFS-L06-1316-T05-B 1 6.57E+02
Co CFS-L06-1316-T01-C 1 1.13E+02
Co CFS-L06-1316-T02-C 1 1.80E+02
Co CFS-L06-1316-T03-C 1 3.28E+02
Co CFS-L06-1316-T04-C 1 4.90E+02
Co CFS-L06-1316-T05-C 1 5.98E+02
Co CFS-L06-1316-B01-A 1 9.00E-01 U1/2
Co CFS-L06-1316-B02-A 1 9.00E-01 U1/2
Co CFS-L06-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+02 9.0E-01 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.67E+02 1.5E+00 1 .8E+00 5.7E+00 10 120 1.25E+03 90% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
2.91E+02 5.5E-01 1 .8E+00 5.7E+00
4.18E+02 6.5E-01 1 .8E+00 5.7E+00
6.92E+02 4.8E-01 1 .8E+00 5.7E+00
1.01E+02 8.9E-01 1.8E+00 5.7E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.74E+02 9.4E-01 1.8E+00 5.7E+00 10 120 1.31E+03 95% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
2.88E+02 1.1E+00 1.8E+00 5.7E+00
4.52E+02 5.5E-01 1.8E+00 5.7E+00
6.57E+02 4.7E-01 1.8E+00 5.7E+00
1.13E+02 6.8E-01 1.8E+00 5.7E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.80E+02 7.7E-01 1.8E+00 5.7E+00 10 120 1.32E+03 95% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
3.28E+02 4.9E-01 1.8E+00 5.7E+00
4.90E+02 7.6E-01 1.8E+00 5.7E+00
5.98E+02 8.1E-01 1.8E+00 5.7E+00
9.00E-01 6.5E+02 1.8E+00 5.7E+00
9.00E-01 7.5E+01 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1666
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu CFS-L06-1316-T01-A 1 8.53E+02
Cu CFS-L06-1316-T02-A 1 1.04E+03
Cu CFS-L06-1316-T03-A 1 1.44E+03
Cu CFS-L06-1316-T04-A 1 2.22E+03
Cu CFS-L06-1316-T05-A 1 3.06E+03
Cu CFS-L06-1316-T01-B 1 8.34E+02
Cu CFS-L06-1316-T02-B 1 1.11E+03
Cu CFS-L06-1316-T03-B 1 1.74E+03
Cu CFS-L06-1316-T04-B 1 2.48E+03
Cu CFS-L06-1316-T05-B 1 3.04E+03
Cu CFS-L06-1316-T01-C 1 9.51E+02
Cu CFS-L06-1316-T02-C 1 1.16E+03
Cu CFS-L06-1316-T03-C 1 1.97E+03
Cu CFS-L06-1316-T04-C 1 2.84E+03
Cu CFS-L06-1316-T05-C 1 3.09E+03
Cu CFS-L06-1316-B01-A 1 1.85E+OOU1/2
Cu CFS-L06-1316-B02-A 1 1.85E+OOU1/2
Cu CFS-L06-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.53E+02 7.5E-01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.04E+03 2.0E+00 3.7E+00 1.2E+01 10 120 2.08E+03 87% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
1.44E+03 1.5E+00 3.7E+00 1.2E+01
2.22E+03 8.0E-01 3.7E+00 1.2E+01
3.06E+03 1.0E+00 3.7E+00 1.2E+01
8.34E+02 7.8E-01 3.7E+00 1.2E+01
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.11E+03 8.1E-01 3.7E+00 1.2E+01 10 120 2.16E+03 88% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
1.74E+03 1.9E+00 3.7E+00 1.2E+01
2.48E+03 1.2E+00 3.7E+00 1.2E+01
3.04E+03 1.4E+00 3.7E+00 1.2E+01
9.51 E+02 1.7E-01 3.7E+00 1.2E+01
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.16E+03 1.4E+00 3.7E+00 1.2E+01 10 120 2.25E+03 90% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
1.97E+03 8.7E-01 3.7E+00 1.2E+01
2.84E+03 9.1E-01 3.7E+00 1.2E+01
3.09E+03 6.3E-01 3.7E+00 1.2E+01
1.85E+00 9.9E+01 3.7E+00 1.2E+01
1.85E+00 1.1 E+02 3.7E+00 1.2E+01
1.85E+00 6.7E+01 3.7E+00 1.2E+01
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1667
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Fe Sample Dilution Cone. Qualifier
ug/L
Fe CFS-L06-1316-T01-A 1 1.00E+OOU1/2
Fe CFS-L06-1316-T02-A 1 5.73E+01
Fe CFS-L06-1316-T03-A 1 3.12E+00 E
Fe CFS-L06-1316-T04-A 1 2.43E+02
Fe CFS-L06-1316-T05-A 1 1.32E+01
Fe CFS-L06-1316-T01-B 1 9.53E+00
Fe CFS-L06-1316-T02-B 1 2.30E+00 E
Fe CFS-L06-1316-T03-B 1 2.89E+02
Fe CFS-L06-1316-T04-B 1 1.71E+01
Fe CFS-L06-1316-T05-B 1 1.19E+01
Fe CFS-L06-1316-T01-C 1 4.38E+00 E
Fe CFS-L06-1316-T02-C 1 1.30E+01
Fe CFS-L06-1316-T03-C 1 1.49E+01
Fe CFS-L06-1316-T04-C 1 6.51 E+00
Fe CFS-L06-1316-T05-C 1 4.93E+00 E
Fe CFS-L06-1316-B01-A 1 2.01 E+00 E
Fe CFS-L06-1316-B02-A 1 2.17E+00 E
Fe CFS-L06-1316-B03-A 1 2.85E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
5.73E+01 1.9E+00 2.0E+00 6.4E+00 1000 120 1.16E+03 92% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
3.12E+00 2.8E+01 2.0E+00 6.4E+00
2.43E+02 4.4E+00 2.0E+00 6.4E+00
1.32E+01 3.8E+00 2.0E+00 6.4E+00
9.53E+00 7.2E+00 2.0E+00 6.4E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
2.30E+00 1.1E+01 2.0E+00 6.4E+00 1000 120 1 .22E+03 102% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
2.89E+02 9.8E-01 2.0E+00 6.4E+00
1.71E+01 4.0E+00 2.0E+00 6.4E+00
1.19E+01 3.7E+00 2.0E+00 6.4E+00
4.38E+00 5.9E+00 2.0E+00 6.4E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.30E+01 1.0E+00 2.0E+00 6.4E+00 1000 120 1 .23E+03 101% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
1.49E+01 1.1E+01 2.0E+00 6.4E+00
6.51E+00 3.1E+00 2.0E+00 6.4E+00
4.93E+00 9.2E+00 2.0E+00 6.4E+00
2.01E+00 1.4E+01 2.0E+00 6.4E+00
2.17E+00 2.4E+01 2.0E+00 6.4E+00
2.85E+00 6.1E+00 2.0E+00 6.4E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1668
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb CFS-L06-1316-T01-A 1 1.19E+03
Pb CFS-L06-1316-T02-A 1 1.20E+03
Pb CFS-L06-1316-T03-A 1 1.25E+03
Pb CFS-L06-1316-T04-A 1 1.67E+03
Pb CFS-L06-1316-T05-A 1 1.41E+03
Pb CFS-L06-1316-T01-B 1 1.15E+03
Pb CFS-L06-1316-T02-B 1 1.26E+03
Pb CFS-L06-1316-T03-B 1 1.59E+03
Pb CFS-L06-1316-T04-B 1 1.44E+03
Pb CFS-L06-1316-T05-B 1 1.50E+03
Pb CFS-L06-1316-T01-C 1 1.20E+03
Pb CFS-L06-1316-T02-C 1 1.27E+03
Pb CFS-L06-1316-T03-C 1 1.22E+03
Pb CFS-L06-1316-T04-C 1 1.43E+03
Pb CFS-L06-1316-T05-C 1 1.50E+03
Pb CFS-L06-1316-B01-A 1 3.40E+00 U1/2
Pb CFS-L06-1316-B02-A 1 3.40E+00 U1/2
Pb CFS-L06-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.19E+03 1.6E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.20E+03 5.2E-01 6.8E+00 2.2E+01 10 120 2.20E+03 83% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
1.25E+03 4.6E-01 6.8E+00 2.2E+01
1.67E+03 7.3E-01 6.8E+00 2.2E+01
1.41E+03 5.3E-01 6.8E+00 2.2E+01
1.15E+03 6.1E-01 6.8E+00 2.2E+01
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.26E+03 4.2E-01 6.8E+00 2.2E+01 10 120 2.27E+03 84% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
1.59E+03 8.5E-01 6.8E+00 2.2E+01
1.44E+03 1.5E+00 6.8E+00 2.2E+01
1.50E+03 8.8E-01 6.8E+00 2.2E+01
1.20E+03 1.3E-01 6.8E+00 2.2E+01
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.27E+03 4.6E-01 6.8E+00 2.2E+01 10 120 2.32E+03 87% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
1.22E+03 6.0E-01 6.8E+00 2.2E+01
1.43E+03 9.3E-01 6.8E+00 2.2E+01
1.50E+03 5.7E-01 6.8E+00 2.2E+01
3.40E+00 4.7E+00 6.8E+00 2.2E+01
3.40E+00 2.6E+00 6.8E+00 2.2E+01
3.40E+00 3.7E+00 6.8E+00 2.2E+01
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1669
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li CFS-L06-1316-T01-A 1 4.15E+01
Li CFS-L06-1316-T02-A 1 3.87E+01
Li CFS-L06-1316-T03-A 1 3.38E+01
Li CFS-L06-1316-T04-A 1 3.59E+01
Li CFS-L06-1316-T05-A 1 5.64E+01
Li CFS-L06-1316-T01-B 1 4.14E+01
Li CFS-L06-1316-T02-B 1 4.28E+01
Li CFS-L06-1316-T03-B 1 3.47E+01
Li CFS-L06-1316-T04-B 1 3.37E+01
Li CFS-L06-1316-T05-B 1 5.42E+01
Li CFS-L06-1316-T01-C 1 4.04E+01
Li CFS-L06-1316-T02-C 1 3.78E+01
Li CFS-L06-1316-T03-C 1 3.32E+01
Li CFS-L06-1316-T04-C 1 3.72E+01
Li CFS-L06-1316-T05-C 1 5.48E+01
Li CFS-L06-1316-B01-A 1 2.77E+01
Li CFS-L06-1316-B02-A 1 2.68E+01
Li CFS-L06-1316-B03-A 1 2.79E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.15E+01 1.3E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
3.87E+01 1.0E+01 1.9E+00 6.0E+00 10 120 1.03E+03 83% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
3.38E+01 1.2E+00 1 .9E+00 6.0E+00
3.59E+01 3.3E+00 1 .9E+00 6.0E+00
5.64E+01 4.1E+00 1 .9E+00 6.0E+00
4.14E+01 4.1E+00 1.9E+00 6.0E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
4.28E+01 5.2E+00 1.9E+00 6.0E+00 10 120 1.08E+03 86% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
3.47E+01 1.3E+00 1.9E+00 6.0E+00
3.37E+01 5.3E+00 1.9E+00 6.0E+00
5.42E+01 1.1E+01 1.9E+00 6.0E+00
4.04E+01 4.6E+00 1.9E+00 6.0E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
3.78E+01 7.3E+00 1.9E+00 6.0E+00 10 120 1.07E+03 86% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
3.32E+01 1.9E+00 1.9E+00 6.0E+00
3.72E+01 9.0E+00 1.9E+00 6.0E+00
5.48E+01 6.9E+00 1.9E+00 6.0E+00
2.77E+01 4.7E+00 1.9E+00 6.0E+00
2.68E+01 7.7E+00 1.9E+00 6.0E+00
2.79E+01 4.4E+00 1.9E+00 6.0E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1670
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
ug/L
Mn CFS-L06-1316-T01-A 1 1.68E+03
Mn CFS-L06-1316-T02-A 1 2.86E+03
Mn CFS-L06-1316-T03-A 1 5.85E+03
Mn CFS-L06-1316-T04-A 1 9.24E+03
Mn CFS-L06-1316-T05-A 1 1.76E+04
Mn CFS-L06-1316-T01-B 1 1.62E+03
Mn CFS-L06-1316-T02-B 1 3.01E+03
Mn CFS-L06-1316-T03-B 1 5.65E+03
Mn CFS-L06-1316-T04-B 1 9.75E+03
Mn CFS-L06-1316-T05-B 1 1.69E+04
Mn CFS-L06-1316-T01-C 1 1.84E+03
Mn CFS-L06-1316-T02-C 1 3.18E+03
Mn CFS-L06-1316-T03-C 1 6.47E+03
Mn CFS-L06-1316-T04-C 1 1.05E+04
Mn CFS-L06-1316-T05-C 1 1.56E+04
Mn CFS-L06-1316-B01-A 1 1.00E+OOU1/2
Mn CFS-L06-1316-B02-A 1 1.00E+OOU1/2
Mn CFS-L06-1316-B03-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.68E+03 6.0E-01 2.0E+00 6.4E+00
2.86E+03 1.6E+00 2.0E+00 6.4E+00 10 120
5.85E+03 4.8E-01 2.0E+00 6.4E+00
9.24E+03 6.4E-01 2.0E+00 6.4E+00
1.76E+04 6.1E-01 2.0E+00 6.4E+00
1.62E+03 7.9E-01 2.0E+00 6.4E+00
3.01E+03 1.2E+00 2.0E+00 6.4E+00 10 120
5.65E+03 1.0E+00 2.0E+00 6.4E+00
9.75E+03 7.1E-01 2.0E+00 6.4E+00
1.69E+04 1.1E+00 2.0E+00 6.4E+00
1.84E+03 1.2E+00 2.0E+00 6.4E+00
3.18E+03 1.2E+00 2.0E+00 6.4E+00 10 120
6.47E+03 5.1E-01 2.0E+00 6.4E+00
1.05E+04 1.8E-01 2.0E+00 6.4E+00
1.56E+04 2.2E-01 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
1.00E+00 8.6E+00 2.0E+00 6.4E+00
1.00E+00 6.7E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
3.95E+03 91% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
4.07E+03 88% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
4.22E+03 86% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1671
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg CFS-L06-1316-T01-A 1 7.07E+04
Mg CFS-L06-1316-T02-A 1 1.33E+05
Mg CFS-L06-1316-T03-A 1 3.08E+05
Mg CFS-L06-1316-T04-A 1 5.50E+05
Mg CFS-L06-1316-T05-A 1 9.71 E+05
Mg CFS-L06-1316-T01-B 1 7.09E+04
Mg CFS-L06-1316-T02-B 1 1.36E+05
Mg CFS-L06-1316-T03-B 1 3.03E+05
Mg CFS-L06-1316-T04-B 1 5.24E+05
Mg CFS-L06-1316-T05-B 1 9.99E+05
Mg CFS-L06-1316-T01-C 1 7.36E+04
Mg CFS-L06-1316-T02-C 1 1.40E+05
Mg CFS-L06-1316-T03-C 1 2.97E+05
Mg CFS-L06-1316-T04-C 1 5.43E+05
Mg CFS-L06-1316-T05-C 1 9.46E+05
Mg CFS-L06-1316-B01-A 1 5.00E-01 U1/2
Mg CFS-L06-1316-B02-A 1 6.40E+00
Mg CFS-L06-1316-B03-A 1 2.38E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.07E+04 2.8E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.33E+05 6.6E-01 1 .OE+00 3.2E+00 1000 120 1.34E+05 95% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
3.08E+05 1.1E+00 1. OE+00 3.2E+00
5.50E+05 1.1E+00 1. OE+00 3.2E+00
9.71 E+05 3.7E-01 1. OE+00 3.2E+00
7.09E+04 3.9E-01 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.36E+05 5.3E-01 1.0E+00 3.2E+00 1000 120 1.37E+05 93% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
3.03E+05 1.5E+00 1. OE+00 3.2E+00
5.24E+05 6.2E-01 1. OE+00 3.2E+00
9.99E+05 6.1E-01 1. OE+00 3.2E+00
7.36E+04 6.9E-01 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.40E+05 8.1E-01 1.0E+00 3.2E+00 1000 120 1.41E+05 88% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
2.97E+05 1.2E+00 1. OE+00 3.2E+00
5.43E+05 1.2E+00 1. OE+00 3.2E+00
9.46E+05 2.4E-01 1. OE+00 3.2E+00
5.00E-01 1.4E+02 1. OE+00 3.2E+00
6.40E+00 1.1E+02 1. OE+00 3.2E+00
2.38E+01 3.8E+01 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1672
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo CFS-L06-1316-T01-A 1 1.04E+01
Mo CFS-L06-1316-T02-A 1 9.84E+00
Mo CFS-L06-1316-T03-A 1 1.64E+01
Mo CFS-L06-1316-T04-A 1 2.18E+01
Mo CFS-L06-1316-T05-A 1 2.44E+01
Mo CFS-L06-1316-T01-B 1 9.20E+00
Mo CFS-L06-1316-T02-B 1 1.08E+01
Mo CFS-L06-1316-T03-B 1 1.61E+01
Mo CFS-L06-1316-T04-B 1 1.81E+01
Mo CFS-L06-1316-T05-B 1 2.50E+01
Mo CFS-L06-1316-T01-C 1 9.39E+00
Mo CFS-L06-1316-T02-C 1 1.17E+01
Mo CFS-L06-1316-T03-C 1 1.64E+01
Mo CFS-L06-1316-T04-C 1 1.54E+01
Mo CFS-L06-1316-T05-C 1 2.48E+01
Mo CFS-L06-1316-B01-A 1 1.71E+OOE
Mo CFS-L06-1316-B02-A 1 2.00E+00 E
Mo CFS-L06-1316-B03-A 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.04E+01 6.3E+00 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
9.84E+00 1.3E+01 1 .2E+00 3.8E+00 10 120 1.12E+03 92% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
1.64E+01 2.7E+00 1.2E+00 3.8E+00
2.18E+01 1.1E+01 1.2E+00 3.8E+00
2.44E+01 4.1E+00 1.2E+00 3.8E+00
9.20E+00 1.2E+01 1.2E+00 3.8E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.08E+01 1.2E+01 1.2E+00 3.8E+00 10 120 1.18E+03 98% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
1.61E+01 8.2E+00 1.2E+00 3.8E+00
1.81E+01 2.5E+00 1.2E+00 3.8E+00
2.50E+01 9.4E+00 1.2E+00 3.8E+00
9.39E+00 7.2E+00 1.2E+00 3.8E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.17E+01 1.7E+01 1.2E+00 3.8E+00 10 120 1.18E+03 97% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
1.64E+01 2.0E+01 1.2E+00 3.8E+00
1.54E+01 5.8E+00 1.2E+00 3.8E+00
2.48E+01 7.8E+00 1.2E+00 3.8E+00
1.71E+00 7.8E+01 1.2E+00 3.8E+00
2.00E+00 6.4E+01 1.2E+00 3.8E+00
6.00E-01 2.7E+02 1.2E+00 3.8E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1673
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni CFS-L06-1316-T01-A 1 2.30E+02
Ni CFS-L06-1316-T02-A 1 3.44E+02
Ni CFS-L06-1316-T03-A 1 5.55E+02
Ni CFS-L06-1316-T04-A 1 7.59E+02
Ni CFS-L06-1316-T05-A 1 1.14E+03
Ni CFS-L06-1316-T01-B 1 2.26E+02
Ni CFS-L06-1316-T02-B 1 3.65E+02
Ni CFS-L06-1316-T03-B 1 5.60E+02
Ni CFS-L06-1316-T04-B 1 8.29E+02
Ni CFS-L06-1316-T05-B 1 1.09E+03
Ni CFS-L06-1316-T01-C 1 2.51E+02
Ni CFS-L06-1316-T02-C 1 3.84E+02
Ni CFS-L06-1316-T03-C 1 6.35E+02
Ni CFS-L06-1316-T04-C 1 8.98E+02
Ni CFS-L06-1316-T05-C 1 9.90E+02
Ni CFS-L06-1316-B01-A 1 9.00E-01 U1/2
Ni CFS-L06-1316-B02-A 1 9.00E-01 U1/2
Ni CFS-L06-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+02 7.3E-01 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
3.44E+02 1.4E+00 1 .8E+00 5.7E+00 10 120 1.46E+03 93% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
5.55E+02 7.1E-01 1 .8E+00 5.7E+00
7.59E+02 7.2E-01 1 .8E+00 5.7E+00
1.14E+03 3.9E-01 1 .8E+00 5.7E+00
2.26E+02 1.0E+00 1.8E+00 5.7E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
3.65E+02 7.1E-01 1.8E+00 5.7E+00 10 120 1.52E+03 97% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
5.60E+02 1.3E+00 1.8E+00 5.7E+00
8.29E+02 7.7E-01 1.8E+00 5.7E+00
1.09E+03 3.4E-01 1.8E+00 5.7E+00
2.51 E+02 1.0E+00 1.8E+00 5.7E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
3.84E+02 1.3E+00 1.8E+00 5.7E+00 10 120 1.55E+03 97% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
6.35E+02 1.7E-01 1.8E+00 5.7E+00
8.98E+02 8.9E-01 1.8E+00 5.7E+00
9.90E+02 1.1E+00 1.8E+00 5.7E+00
9.00E-01 1.6E+02 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 2.7E+02 1.8E+00 5.7E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1674
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P CFS-L06-1316-T01-A 1 1.85E+OOU1/2
P CFS-L06-1316-T02-A 1 1.85E+OOU1/2
P CFS-L06-1316-T03-A 1 1.22E+01
P CFS-L06-1316-T04-A 1 5.82E+00 E
P CFS-L06-1316-T05-A 1 2.93E+01
P CFS-L06-1316-T01-B 1 1.85E+OOU1/2
P CFS-L06-1316-T02-B 1 1.85E+OOU1/2
P CFS-L06-1316-T03-B 1 2.44E+01
P CFS-L06-1316-T04-B 1 1.77E+01
P CFS-L06-1316-T05-B 1 3.53E+01
P CFS-L06-1316-T01-C 1 1.85E+OOU1/2
P CFS-L06-1316-T02-C 1 1.85E+OOU1/2
P CFS-L06-1316-T03-C 1 2.34E+01
P CFS-L06-1316-T04-C 1 2.19E+01
P CFS-L06-1316-T05-C 1 2.24E+01
P CFS-L06-1316-B01-A 1 1.85E+OOU1/2
P CFS-L06-1316-B02-A 1 1.85E+OOU1/2
P CFS-L06-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 8.5E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.85E+00 7.4E+02 3.7E+00 1.2E+01 1000 120 1 .26E+03 105% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
1.22E+01 5.9E+01 3.7E+00 1.2E+01
5.82E+00 1.1E+02 3.7E+00 1.2E+01
2.93E+01 4.8E+01 3.7E+00 1.2E+01
1.85E+00 7.6E+01 3.7E+00 1.2E+01
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.85E+00 6.1E+01 3.7E+00 1.2E+01 1000 120 1 .36E+03 1 13% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
2.44E+01 4.5E+01 3.7E+00 1.2E+01
1.77E+01 2.0E+01 3.7E+00 1.2E+01
3.53E+01 6.3E+01 3.7E+00 1.2E+01
1.85E+00 1.3E+02 3.7E+00 1.2E+01
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.85E+00 6.6E+01 3.7E+00 1.2E+01 1000 120 1 .34E+03 1 12% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
2.34E+01 3.2E+01 3.7E+00 1.2E+01
2.19E+01 4.2E+01 3.7E+00 1.2E+01
2.24E+01 6.6E+01 3.7E+00 1.2E+01
1.85E+00 1.8E+02 3.7E+00 1.2E+01
1.85E+00 4.5E+02 3.7E+00 1.2E+01
1.85E+00 1.7E+02 3.7E+00 1.2E+01
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1675
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K CFS-L06-1316-T01-A 1 1.08E+04
K CFS-L06-1316-T02-A 1 1.80E+04
K CFS-L06-1316-T03-A 1 3.53E+04
K CFS-L06-1316-T04-A 1 5.69E+04
K CFS-L06-1316-T05-A 1 9.26E+04
K CFS-L06-1316-T01-B 1 1.08E+04
K CFS-L06-1316-T02-B 1 1.87E+04
K CFS-L06-1316-T03-B 1 3.53E+04
K CFS-L06-1316-T04-B 1 5.52E+04
K CFS-L06-1316-T05-B 1 9.39E+04
K CFS-L06-1316-T01-C 1 1.08E+04
K CFS-L06-1316-T02-C 1 1.83E+04
K CFS-L06-1316-T03-C 1 3.48E+04
K CFS-L06-1316-T04-C 1 5.52E+04
K CFS-L06-1316-T05-C 1 9.16E+04
K CFS-L06-1316-B01-A 1 3.75E+01
K CFS-L06-1316-B02-A 1 3.58E+01
K CFS-L06-1316-B03-A 1 4.11E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+04 7.0E-01 1 .6E+00 5.1E+00
1.80E+04 1.3E+00 1 .6E+00 5.1E+00 1000 120
3.53E+04 9.5E-01 1 .6E+00 5.1E+00
5.69E+04 6.4E-01 1 .6E+00 5.1E+00
9.26E+04 2.7E-01 1 .6E+00 5.1E+00
1.08E+04 2.5E-01 1 .6E+00 5.1E+00
1.87E+04 1.1E-01 1.6E+00 5.1E+00 1000 120
3.53E+04 1.4E+00 1 .6E+00 5.1E+00
5.52E+04 4.7E-01 1 .6E+00 5.1E+00
9.39E+04 4.3E-01 1 .6E+00 5.1E+00
1.08E+04 8.4E-01 1 .6E+00 5.1E+00
1.83E+04 3.2E-01 1 .6E+00 5.1E+00 1000 120
3.48E+04 6.8E-01 1.6E+00 5.1E+00
5.52E+04 1.1E+00 1.6E+00 5.1E+00
9.16E+04 5.4E-01 1.6E+00 5.1E+00
3.75E+01 9.6E+00 1.6E+00 5.1E+00
3.58E+01 3.9E+00 1.6E+00 5.1E+00
4.11E+01 3.7E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.92E+04 95%VUICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.98E+04 93%VUICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.95E+04 97% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1676
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se CFS-L06-1316-T01-A 1 9.70E+01
Se CFS-L06-1316-T02-A 1 1.51E+02
Se CFS-L06-1316-T03-A 1 3.15E+02
Se CFS-L06-1316-T04-A 1 5.50E+02
Se CFS-L06-1316-T05-A 1 9.36E+02
Se CFS-L06-1316-T01-B 1 1.15E+02
Se CFS-L06-1316-T02-B 1 1.44E+02
Se CFS-L06-1316-T03-B 1 2.97E+02
Se CFS-L06-1316-T04-B 1 5.19E+02
Se CFS-L06-1316-T05-B 1 9.77E+02
Se CFS-L06-1316-T01-C 1 1.04E+02
Se CFS-L06-1316-T02-C 1 1.59E+02
Se CFS-L06-1316-T03-C 1 3.07E+02
Se CFS-L06-1316-T04-C 1 5.22E+02
Se CFS-L06-1316-T05-C 1 9.36E+02
Se CFS-L06-1316-B01-A 1 7.50E+00 U1/2
Se CFS-L06-1316-B02-A 1 1.89E+01 E
Se CFS-L06-1316-B03-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.70E+01 1.2E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.51E+02 9.1E+00 1.5E+01 4.8E+01 10 120 1.24E+03 91%VUICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
3.15E+02 5.6E+00 1.5E+01 4.8E+01
5.50E+02 9.3E-01 1.5E+01 4.8E+01
9.36E+02 2.2E+00 1.5E+01 4.8E+01
1.15E+02 2.5E+01 1.5E+01 4.8E+01
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.44E+02 1.8E+01 1.5E+01 4.8E+01 10 120 1.32E+03 98% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
2.97E+02 8.4E+00 1.5E+01 4.8E+01
5.19E+02 1.9E+00 1.5E+01 4.8E+01
9.77E+02 1.2E+00 1.5E+01 4.8E+01
1.04E+02 9.0E+00 1.5E+01 4.8E+01
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.59E+02 5.9E+00 1.5E+01 4.8E+01 10 120 1.32E+03 97% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
3.07E+02 1.4E+00 1.5E+01 4.8E+01
5.22E+02 1.7E+00 1.5E+01 4.8E+01
9.36E+02 2.7E-01 1.5E+01 4.8E+01
7.50E+00 6.7E+01 1.5E+01 4.8E+01
1.89E+01 6.4E+01 1.5E+01 4.8E+01
7.50E+00 2.7E+02 1.5E+01 4.8E+01
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1677
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si CFS-L06-1316-T01-A 1 4.42E+03
Si CFS-L06-1316-T02-A 1 5.17E+03
Si CFS-L06-1316-T03-A 1 6.37E+03
Si CFS-L06-1316-T04-A 1 7.19E+03
Si CFS-L06-1316-T05-A 1 7.82E+03
Si CFS-L06-1316-T01-B 1 4.32E+03
Si CFS-L06-1316-T02-B 1 5.39E+03
Si CFS-L06-1316-T03-B 1 6.65E+03
Si CFS-L06-1316-T04-B 1 7.35E+03
Si CFS-L06-1316-T05-B 1 7.82E+03
Si CFS-L06-1316-T01-C 1 4.29E+03
Si CFS-L06-1316-T02-C 1 5.33E+03
Si CFS-L06-1316-T03-C 1 7.28E+03
Si CFS-L06-1316-T04-C 1 7.65E+03
Si CFS-L06-1316-T05-C 1 7.25E+03
Si CFS-L06-1316-B01-A 1 1.29E+01
Si CFS-L06-1316-B02-A 1 1.10E+01
Si CFS-L06-1316-B03-A 1 1.28E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.42E+03 5.9E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
5.17E+03 2.1E+00 1.1E+00 3.5E+00 1000 120 6.21E+03 87% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
6.37E+03 9.0E-01 1.1E+00 3.5E+00
7.19E+03 1.1E+00 1.1E+00 3.5E+00
7.82E+03 2.3E-01 1.1E+00 3.5E+00
4.32E+03 1.2E+00 1.1E+00 3.5E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
5.39E+03 8.2E-01 1.1E+00 3.5E+00 1000 120 6.41E+03 85% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
6.65E+03 5.0E-01 1.1E+00 3.5E+00
7.35E+03 6.4E-01 1.1E+00 3.5E+00
7.82E+03 5.7E-01 1.1E+00 3.5E+00
4.29E+03 2.4E-01 1.1E+00 3.5E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
5.33E+03 1.1E+00 1.1E+00 3.5E+00 1000 120 6.44E+03 93% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
7.28E+03 7.5E-01 1.1E+00 3.5E+00
7.65E+03 7.6E-01 1.1E+00 3.5E+00
7.25E+03 5.8E-01 1.1E+00 3.5E+00
1.29E+01 2.1E+01 1.1E+00 3.5E+00
1.10E+01 5.4E+00 1.1E+00 3.5E+00
1.28E+01 9.5E+00 1.1E+00 3.5E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1678
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na CFS-L06-1316-T01-A 1 7.37E+03
Na CFS-L06-1316-T02-A 1 1.42E+04
Na CFS-L06-1316-T03-A 1 3.39E+04
Na CFS-L06-1316-T04-A 1 6.07E+04
Na CFS-L06-1316-T05-A 1 9.34E+04
Na CFS-L06-1316-T01-B 1 7.37E+03
Na CFS-L06-1316-T02-B 1 1.47E+04
Na CFS-L06-1316-T03-B 1 3.32E+04
Na CFS-L06-1316-T04-B 1 6.07E+04
Na CFS-L06-1316-T05-B 1 9.62E+04
Na CFS-L06-1316-T01-C 1 7.65E+03
Na CFS-L06-1316-T02-C 1 1.48E+04
Na CFS-L06-1316-T03-C 1 3.31 E+04
Na CFS-L06-1316-T04-C 1 6.03E+04
Na CFS-L06-1316-T05-C 1 9.33E+04
Na CFS-L06-1316-B01-A 1 6.07E+00 E
Na CFS-L06-1316-B02-A 1 1.25E+OOU1/2
Na CFS-L06-1316-B03-A 1 5.15E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.37E+03 2.4E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.42E+04 2.0E-01 2.5E+00 8.0E+00 1000 120 1.54E+04 96% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
3.39E+04 6.3E-01 2.5E+00 8.0E+00
6.07E+04 4.7E-01 2.5E+00 8.0E+00
9.34E+04 6.9E-01 2.5E+00 8.0E+00
7.37E+03 6.9E-01 2.5E+00 8.0E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.47E+04 2.6E-01 2.5E+00 8.0E+00 1000 120 1.58E+04 94% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
3.32E+04 3.2E-01 2.5E+00 8.0E+00
6.07E+04 1.4E-01 2.5E+00 8.0E+00
9.62E+04 5.1E-01 2.5E+00 8.0E+00
7.65E+03 1.3E+00 2.5E+00 8.0E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.48E+04 3.9E-01 2.5E+00 8.0E+00 1000 120 1.59E+04 93% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
3.31 E+04 9.8E-01 2.5E+00 8.0E+00
6.03E+04 9.4E-01 2.5E+00 8.0E+00
9.33E+04 4.1E-01 2.5E+00 8.0E+00
6.07E+00 2.2E+00 2.5E+00 8.0E+00
1.25E+00 3.3E+00 2.5E+00 8.0E+00
5.15E+00 4.5E+00 2.5E+00 8.0E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1679
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L06-1316-T01-A 1 1.69E+03
CFS-L06-1316-T02-A 1 2.27E+03
CFS-L06-1316-T03-A 1 3.46E+03
CFS-L06-1316-T04-A 1 4.41 E+03
CFS-L06-1316-T05-A 1 5.42E+03
CFS-L06-1316-T01-B 1 1.64E+03
CFS-L06-1316-T02-B 1 2.35E+03
CFS-L06-1316-T03-B 1 3.48E+03
CFS-L06-1316-T04-B 1 4.12E+03
CFS-L06-1316-T05-B 1 5.72E+03
CFS-L06-1316-T01-C 1 1.58E+03
CFS-L06-1316-T02-C 1 2.17E+03
CFS-L06-1316-T03-C 1 3.10E+03
CFS-L06-1316-T04-C 1 3.91 E+03
CFS-L06-1316-T05-C 1 5.49E+03
CFS-L06-1316-B01-A 1 5.00E-01 U1/2
CFS-L06-1316-B02-A 1 5.00E-01 U1/2
CFS-L06-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.69E+03 8.2E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
2.27E+03 2.0E+00 1 .OE+00 3.2E+00 1000 120 3.35E+03 89% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
3.46E+03 1.1E+00 1 .OE+00 3.2E+00
4.41 E+03 1. OE+00 1 .OE+00 3.2E+00
5.42E+03 7.4E-01 1 .OE+00 3.2E+00
1.64E+03 8.8E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
2.35E+03 1.0E+00 1 .OE+00 3.2E+00 1000 120 3.49E+03 94% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
3.48E+03 1.5E+00 1 .OE+00 3.2E+00
4.12E+03 1.8E+00 1 .OE+00 3.2E+00
5.72E+03 2.1E+00 1 .OE+00 3.2E+00
1.58E+03 5.1E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
2.17E+03 7.1E-01 1 .OE+00 3.2E+00 1000 120 3.30E+03 94% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
3.10E+03 1. OE+00 1. OE+00 3.2E+00
3.91 E+03 3.7E-01 1. OE+00 3.2E+00
5.49E+03 3.0E-01 1. OE+00 3.2E+00
5.00E-01 5.7E+01 1. OE+00 3.2E+00
5.00E-01 8.0E+02 1. OE+00 3.2E+00
5.00E-01 8.5E+02 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1680
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S CFS-L06-1316-T01-A 1 6.42E+05
S CFS-L06-1316-T02-A 1 7.04E+05
S CFS-L06-1316-T03-A 1 8.88E+05
S CFS-L06-1316-T04-A 1 1.17E+06
S CFS-L06-1316-T05-A 1 1.61E+06
S CFS-L06-1316-T01-B 1 6.43E+05
S CFS-L06-1316-T02-B 1 7.28E+05
S CFS-L06-1316-T03-B 1 9.00E+05
S CFS-L06-1316-T04-B 1 1.15E+06
S CFS-L06-1316-T05-B 1 1.65E+06
S CFS-L06-1316-T01-C 1 6.56E+05
S CFS-L06-1316-T02-C 1 7.14E+05
S CFS-L06-1316-T03-C 1 8.90E+05
S CFS-L06-1316-T04-C 1 1.16E+06
S CFS-L06-1316-T05-C 1 1.56E+06
S CFS-L06-1316-B01-A 1 9.31 E+01
S CFS-L06-1316-B02-A 1 7.37E+01
S CFS-L06-1316-B03-A 1 6.47E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.42E+05 9.5E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
7.04E+05 1.0E+00 6.8E+00 2.2E+01 1000 120 7.05E+05 83% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
8.88E+05 3.1E-01 6.8E+00 2.2E+01
1.17E+06 5.6E-01 6.8E+00 2.2E+01
1.61E+06 1.3E-01 6.8E+00 2.2E+01
6.43E+05 4.4E-01 6.8E+00 2.2E+01
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
7.28E+05 4.1E-01 6.8E+00 2.2E+01 1000 120 7.29E+05 87% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
9.00E+05 5.9E-01 6.8E+00 2.2E+01
1.15E+06 4.7E-01 6.8E+00 2.2E+01
1.65E+06 5.0E-01 6.8E+00 2.2E+01
6.56E+05 5.9E-01 6.8E+00 2.2E+01
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
7.14E+05 1.2E-01 6.8E+00 2.2E+01 1000 120 7.15E+05 87% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
8.90E+05 8.6E-02 6.8E+00 2.2E+01
1.16E+06 8.8E-01 6.8E+00 2.2E+01
1.56E+06 6.2E-01 6.8E+00 2.2E+01
9.31 E+01 3.4E+00 6.8E+00 2.2E+01
7.37E+01 8.8E+00 6.8E+00 2.2E+01
6.47E+01 4.6E+01 6.8E+00 2.2E+01
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1681
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl CFS-L06-1316-T01-A 1 3.69E+02
Tl CFS-L06-1316-T02-A 1 5.21E+02
Tl CFS-L06-1316-T03-A 1 8.41 E+02
Tl CFS-L06-1316-T04-A 1 1.17E+03
Tl CFS-L06-1316-T05-A 1 1.61E+03
Tl CFS-L06-1316-T01-B 1 3.57E+02
Tl CFS-L06-1316-T02-B 1 5.38E+02
Tl CFS-L06-1316-T03-B 1 8.39E+02
Tl CFS-L06-1316-T04-B 1 1.16E+03
Tl CFS-L06-1316-T05-B 1 1.65E+03
Tl CFS-L06-1316-T01-C 1 3.64E+02
Tl CFS-L06-1316-T02-C 1 5.33E+02
Tl CFS-L06-1316-T03-C 1 8.37E+02
Tl CFS-L06-1316-T04-C 1 1.18E+03
Tl CFS-L06-1316-T05-C 1 1.58E+03
Tl CFS-L06-1316-B01-A 1 2.30E+00 U1/2
Tl CFS-L06-1316-B02-A 1 2.30E+00 U1/2
Tl CFS-L06-1316-B03-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.69E+02 1.9E+00 4.6E+00 1.5E+01
5.21E+02 1.6E+00 4.6E+00 1.5E+01 10 120
8.41 E+02 1.1E+00 4.6E+00 1.5E+01
1.17E+03 1.4E+00 4.6E+00 1.5E+01
1.61E+03 6.0E-01 4.6E+00 1.5E+01
3.57E+02 4.1E-01 4.6E+00 1.5E+01
5.38E+02 1.6E+00 4.6E+00 1.5E+01 10 120
8.39E+02 2.7E-01 4.6E+00 1.5E+01
1.16E+03 4.3E-01 4.6E+00 1.5E+01
1.65E+03 2.3E-01 4.6E+00 1.5E+01
3.64E+02 2.6E+00 4.6E+00 1.5E+01
5.33E+02 7.5E-01 4.6E+00 1.5E+01 10 120
8.37E+02 1.3E+00 4.6E+00 1.5E+01
1.18E+03 5.0E-01 4.6E+00 1.5E+01
1.58E+03 5.5E-01 4.6E+00 1.5E+01
2.30E+00 7.5E+00 4.6E+00 1.5E+01
2.30E+00 1.6E+01 4.6E+00 1.5E+01
2.30E+00 1.0E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.56E+03 86%VUICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.58E+03 87%VUICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.61E+03 90% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1682
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti CFS-L06-1316-T01-A 1 1.00E+OOU1/2
Ti CFS-L06-1316-T02-A 1 1.00E+OOU1/2
Ti CFS-L06-1316-T03-A 1 1.00E+OOU1/2
Ti CFS-L06-1316-T04-A 1 1.00E+OOU1/2
Ti CFS-L06-1316-T05-A 1 1.00E+OOU1/2
Ti CFS-L06-1316-T01-B 1 1.00E+OOU1/2
Ti CFS-L06-1316-T02-B 1 1.00E+OOU1/2
Ti CFS-L06-1316-T03-B 1 1.00E+OOU1/2
Ti CFS-L06-1316-T04-B 1 1.00E+OOU1/2
Ti CFS-L06-1316-T05-B 1 1.00E+OOU1/2
Ti CFS-L06-1316-T01-C 1 1.00E+OOU1/2
Ti CFS-L06-1316-T02-C 1 1.00E+OOU1/2
Ti CFS-L06-1316-T03-C 1 1.00E+OOU1/2
Ti CFS-L06-1316-T04-C 1 1.00E+OOU1/2
Ti CFS-L06-1316-T05-C 1 1.00E+OOU1/2
Ti CFS-L06-1316-B01-A 1 1.00E+OOU1/2
Ti CFS-L06-1316-B02-A 1 1.00E+OOU1/2
Ti CFS-L06-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.6E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
1.00E+00 7.3E+01 2.0E+00 6.4E+00 10 120 1.12E+03 93% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 9.2E+01 2.0E+00 6.4E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
1.00E+00 2.3E+01 2.0E+00 6.4E+00 10 120 1.18E+03 98% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
1.00E+00 8.8E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
1.00E+00 9.8E+00 2.0E+00 6.4E+00 10 120 1.18E+03 98% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
1.00E+00 8.1E+01 2.0E+00 6.4E+00
1.00E+00 9.6E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 6.1E+01 2.0E+00 6.4E+00
1.00E+00 6.8E+01 2.0E+00 6.4E+00
1.00E+00 6.2E+01 2.0E+00 6.4E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1683
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V CFS-L06-1316-T01-A 1 2.84E+01
V CFS-L06-1316-T02-A 1 2.85E+01
V CFS-L06-1316-T03-A 1 2.55E+01
V CFS-L06-1316-T04-A 1 2.60E+01
V CFS-L06-1316-T05-A 1 2.56E+01
V CFS-L06-1316-T01-B 1 3.04E+01
V CFS-L06-1316-T02-B 1 3.02E+01
V CFS-L06-1316-T03-B 1 2.71E+01
V CFS-L06-1316-T04-B 1 2.58E+01
V CFS-L06-1316-T05-B 1 2.56E+01
V CFS-L06-1316-T01-C 1 3.15E+01
V CFS-L06-1316-T02-C 1 2.83E+01
V CFS-L06-1316-T03-C 1 2.53E+01
V CFS-L06-1316-T04-C 1 2.54E+01
V CFS-L06-1316-T05-C 1 2.18E+01
V CFS-L06-1316-B01-A 1 7.50E-01 U1/2
V CFS-L06-1316-B02-A 1 7.50E-01 U1/2
V CFS-L06-1316-B03-A 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.84E+01 2.4E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
2.85E+01 1.4E+00 1 .5E+00 4.8E+00 10 120 1.14E+03 93% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
2.55E+01 5.8E+00 1 .5E+00 4.8E+00
2.60E+01 5.4E+00 1 .5E+00 4.8E+00
2.56E+01 6.9E+00 1 .5E+00 4.8E+00
3.04E+01 2.2E+00 1 .5E+00 4.8E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
3.02E+01 3.8E+00 1 .5E+00 4.8E+00 10 120 1 .20E+03 97% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
2.71E+01 6.4E+00 1 .5E+00 4.8E+00
2.58E+01 2.9E+00 1 .5E+00 4.8E+00
2.56E+01 7.1E-01 1 .5E+00 4.8E+00
3.15E+01 2.1E+00 1.5E+00 4.8E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
2.83E+01 6.3E+00 1 .5E+00 4.8E+00 10 120 1.20E+03 97% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
2.53E+01 1.4E+00 1.5E+00 4.8E+00
2.54E+01 1.3E+00 1.5E+00 4.8E+00
2.18E+01 3.3E+00 1.5E+00 4.8E+00
7.50E-01 9.4E+01 1.5E+00 4.8E+00
7.50E-01 5.6E+01 1.5E+00 4.8E+00
7.50E-01 8.4E+01 1.5E+00 4.8E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1684
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn CFS-L06-1316-T01-A 1 2.14E+04
Zn CFS-L06-1316-T02-A 1 2.75E+04
Zn CFS-L06-1316-T03-A 1 3.92E+04
Zn CFS-L06-1316-T04-A 1 5.04E+04
Zn CFS-L06-1316-T05-A 1 6.81 E+04
Zn CFS-L06-1316-T01-B 1 2.08E+04
Zn CFS-L06-1316-T02-B 1 3.03E+04
Zn CFS-L06-1316-T03-B 1 4.01 E+04
Zn CFS-L06-1316-T04-B 1 5.63E+04
Zn CFS-L06-1316-T05-B 1 6.58E+04
Zn CFS-L06-1316-T01-C 1 2.28E+04
Zn CFS-L06-1316-T02-C 1 3.04E+04
Zn CFS-L06-1316-T03-C 1 4.63E+04
Zn CFS-L06-1316-T04-C 1 5.95E+04
Zn CFS-L06-1316-T05-C 1 5.96E+04
Zn CFS-L06-1316-B01-A 1 5.30E+00
Zn CFS-L06-1316-B02-A 1 5.00E+00
Zn CFS-L06-1316-B03-A 1 3.98E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.14E+04 2.6E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/14/11 4:40 PM EPA Interlab L06 1313-1316 CFS
2.75E+04 1.2E+00 1 .OE+00 3.2E+00 10 120 2.86E+04 90% VU ICP-OES 4/14/11 4:41 PM EPA Interlab L06 1313-1316 CFS
3.92E+04 2.2E-01 1 .OE+00 3.2E+00
5.04E+04 7.4E-01 1 .OE+00 3.2E+00
6.81 E+04 7.7E-02 1 .OE+00 3.2E+00
2.08E+04 5.2E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/14/11 4:43 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:45 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:46 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:48 PM EPA Interlab L06 1313-1316 CFS
3.03E+04 7.8E-01 1 .OE+00 3.2E+00 10 120 3.14E+04 89% VU ICP-OES 4/14/11 4:50 PM EPA Interlab L06 1313-1316 CFS
4.01 E+04 4.6E-01 1 .OE+00 3.2E+00
5.63E+04 1.1E+00 1 .OE+00 3.2E+00
6.58E+04 7.0E-01 1 .OE+00 3.2E+00
2.28E+04 2.8E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/14/11 4:51 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:53 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:55 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:56 PM EPA Interlab L06 1313-1316 CFS
3.04E+04 9.3E-01 1 .OE+00 3.2E+00 10 120 3.16E+04 96% VU ICP-OES 4/14/11 4:58 PM EPA Interlab L06 1313-1316 CFS
4.63E+04 3.8E-01 1. OE+00 3.2E+00
5.95E+04 1.1E+00 1. OE+00 3.2E+00
5.96E+04 6.6E-01 1. OE+00 3.2E+00
5.30E+00 9.3E-01 1. OE+00 3.2E+00
5.00E+00 7.0E+00 1. OE+00 3.2E+00
3.98E+00 8.0E+00 1. OE+00 3.2E+00
VU ICP-OES 4/14/11 5:00 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:01 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 5:03 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:35 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:37 PM EPA Interlab L06 1313-1316 CFS
VU ICP-OES 4/14/11 4:38 PM EPA Interlab L06 1313-1316 CFS
                                                                                                                                                                         1-1685
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al CFS-L07-1316-T01-A 1 3.90E+01
Al CFS-L07-1316-T02-A 1 2.83E+01
Al CFS-L07-1316-T03-A 1 4.29E+01
Al CFS-L07-1316-T04-A 1 4.10E+01
Al CFS-L07-1316-T05-A 1 4.61 E+01
Al CFS-L07-1316-T01-B 1 3.96E+01
Al CFS-L07-1316-T02-B 1 3.73E+01
Al CFS-L07-1316-T03-B 1 4.16E+01
Al CFS-L07-1316-T04-B 1 4.84E+01
Al CFS-L07-1316-T05-B 1 5.00E-01 U1/2
Al CFS-L07-1316-T01-C 1 3.74E+01
Al CFS-L07-1316-T02-C 1 4.09E+01
Al CFS-L07-1316-T03-C 1 3.82E+01
Al CFS-L07-1316-T04-C 1 4.11E+01
Al CFS-L07-1316-T05-C 1 3.90E+01
Al CFS-L07-1316-B01-A 1 5.00E-01 U1/2
Al CFS-L07-1316-B02-A 1 5.00E-01 U1/2
Al CFS-L07-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.90E+01 3.0E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
2.83E+01 6.5E+01 1 .OE+00 3.2E+00 1000 100 1.12E+03 110% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
4.29E+01 8.2E+00 1 .OE+00 3.2E+00
4.10E+01 7.9E+00 1 .OE+00 3.2E+00
4.61 E+01 6.0E+00 7.5E+00 2.4E+01
3.96E+01 8.0E+00 7.5E+00 2.4E+01
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
3.73E+01 2.2E+00 7.5E+00 2.4E+01 1000 100 1.12E+03 109% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
4.16E+01 4.3E+00 7.5E+00 2.4E+01
4.84E+01 1.9E+00 7.5E+00 2.4E+01
5.00E-01 1.9E+02 7.5E+00 2.4E+01
3.74E+01 3.4E+00 7.5E+00 2.4E+01
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
4.09E+01 2.0E+00 7.5E+00 2.4E+01 1000 100 1.12E+03 108% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
3.82E+01 7.8E+00 7.5E+00 2.4E+01
4.11E+01 2.3E+00 7.5E+00 2.4E+01
3.90E+01 9.0E+00 7.5E+00 2.4E+01
5.00E-01 1.9E+01 7.5E+00 2.4E+01
5.00E-01 8.2E+00 7.5E+00 2.4E+01
5.00E-01 7.8E+00 7.5E+00 2.4E+01
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                                 1-1686
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb CFS-L07-1316-T01-A 1 4.38E+01
Sb CFS-L07-1316-T02-A 1 1.60E+01 E
Sb CFS-L07-1316-T03-A 1 4.78E+01
Sb CFS-L07-1316-T04-A 1 5.88E+01
Sb CFS-L07-1316-T05-A 1 6.63E+01
Sb CFS-L07-1316-T01-B 1 3.12E+01
Sb CFS-L07-1316-T02-B 1 4.26E+01
Sb CFS-L07-1316-T03-B 1 4.56E+01
Sb CFS-L07-1316-T04-B 1 4.79E+01
Sb CFS-L07-1316-T05-B 1 3.75E+00 U1/2
Sb CFS-L07-1316-T01-C 1 2.67E+01
Sb CFS-L07-1316-T02-C 1 3.82E+01
Sb CFS-L07-1316-T03-C 1 5.15E+01
Sb CFS-L07-1316-T04-C 1 5.18E+01
Sb CFS-L07-1316-T05-C 1 6.89E+01
Sb CFS-L07-1316-B01-A 1 3.75E+00 U1/2
Sb CFS-L07-1316-B02-A 1 3.75E+00 U1/2
Sb CFS-L07-1316-B03-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.38E+01 3.0E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.60E+01 8.5E+01 7.5E+00 2.4E+01 10 100 9.99E+02 98% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
4.78E+01 2.3E+01 7.5E+00 2.4E+01
5.88E+01 1.5E+01 7.5E+00 2.4E+01
6.63E+01 1.3E+01 7.5E+00 2.4E+01
3.12E+01 9.2E+00 7.5E+00 2.4E+01
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
4.26E+01 1.8E+01 7.5E+00 2.4E+01 10 100 1.01E+03 96% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
4.56E+01 2.6E+01 7.5E+00 2.4E+01
4.79E+01 2.0E+01 7.5E+00 2.4E+01
3.75E+00 2.9E+01 7.5E+00 2.4E+01
2.67E+01 3.3E+00 7.5E+00 2.4E+01
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
3.82E+01 1.3E+01 7.5E+00 2.4E+01 10 100 9.98E+02 96% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
5.15E+01 1.0E+01 7.5E+00 2.4E+01
5.18E+01 4.1E+00 7.5E+00 2.4E+01
6.89E+01 3.8E+00 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
3.75E+00 7.0E+01 7.5E+00 2.4E+01
3.75E+00 5.1E+02 7.5E+00 2.4E+01
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1687
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
As Sample Dilution Cone. Qualifier Revi
ug/L
As CFS-L07-1316-T01-A 1 2.07E+01 E
As CFS-L07-1316-T02-A 1 5.50E+00 U1/2
As CFS-L07-1316-T03-A 1 3.70E+01
As CFS-L07-1316-T04-A 1 3.78E+01
As CFS-L07-1316-T05-A 1 5.15E+01
As CFS-L07-1316-T01-B 1 1.59E+01 E
As CFS-L07-1316-T02-B 1 2.14E+01 E
As CFS-L07-1316-T03-B 1 3.10E+01 E
As CFS-L07-1316-T04-B 1 3.63E+01
As CFS-L07-1316-T05-B 1 5.50E+00 U1/2
As CFS-L07-1316-T01-C 1 2.17E+01 E
As CFS-L07-1316-T02-C 1 3.12E+01 E
As CFS-L07-1316-T03-C 1 3.18E+01 E
As CFS-L07-1316-T04-C 1 4.54E+01
As CFS-L07-1316-T05-C 1 4.22E+01
As CFS-L07-1316-B01-A 1 5.50E+00 U1/2
As CFS-L07-1316-B02-A 1 5.50E+00 U1/2
As CFS-L07-1316-B03-A 1 5.50E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+01 5.6E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
5.50E+00 1.9E+02 1.1E+01 3.5E+01 10 100 9.85E+02 98% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
3.70E+01 2.2E+01 1.1E+01 3.5E+01
3.78E+01 3.6E+01 1.1E+01 3.5E+01
5.15E+01 1.4E+01 1.1E+01 3.5E+01
1.59E+01 2.2E+01 1.1E+01 3.5E+01
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
2.14E+01 2.9E+01 1.1E+01 3.5E+01 10 100 9.98E+02 98% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
3.10E+01 2.8E+01 1.1E+01 3.5E+01
3.63E+01 2.2E+01 1.1E+01 3.5E+01
5.50E+00 7.9E+01 1.1E+01 3.5E+01
2.17E+01 1.6E+00 1.1E+01 3.5E+01
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
3.12E+01 5.5E+01 1.1E+01 3.5E+01 10 100 9.93E+02 96% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
3.18E+01 3.1E+01 1.1E+01 3.5E+01
4.54E+01 6.3E+00 1.1E+01 3.5E+01
4.22E+01 1.1E+01 1.1E+01 3.5E+01
5.50E+00 2.5E+02 1.1E+01 3.5E+01
5.50E+00 1.6E+02 1.1E+01 3.5E+01
5.50E+00 1.3E+02 1.1E+01 3.5E+01
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1688
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B CFS-L07-1316-T01-A 1 1.70E+02
B CFS-L07-1316-T02-A 1 1.87E+02
B CFS-L07-1316-T03-A 1 6.40E+02
B CFS-L07-1316-T04-A 1 1.03E+03
B CFS-L07-1316-T05-A 1 1.50E+03
B CFS-L07-1316-T01-B 1 1.77E+02
B CFS-L07-1316-T02-B 1 3.12E+02
B CFS-L07-1316-T03-B 1 6.25E+02
B CFS-L07-1316-T04-B 1 1.02E+03
B CFS-L07-1316-T05-B 1 9.79E+01
B CFS-L07-1316-T01-C 1 1.70E+02
B CFS-L07-1316-T02-C 1 3.11E+02
B CFS-L07-1316-T03-C 1 6.53E+02
B CFS-L07-1316-T04-C 1 1.08E+03
B CFS-L07-1316-T05-C 1 1.45E+03
B CFS-L07-1316-B01-A 1 3.32E+00
B CFS-L07-1316-B02-A 1 2.86E+00 E
B CFS-L07-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.70E+02 5.5E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.87E+02 7.7E+01 1 .OE+00 3.2E+00 1000 100 1 .23E+03 104% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
6.40E+02 4.9E-01 1 .OE+00 3.2E+00
1.03E+03 1.2E-01 1. OE+00 3.2E+00
1.50E+03 5.2E-01 1 .OE+00 3.2E+00
1.77E+02 1.1E-01 1. OE+00 3.2E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
3.12E+02 1.6E+00 1 .OE+00 3.2E+00 1000 100 1 .25E+03 93% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
6.25E+02 6.0E-01 1 .OE+00 3.2E+00
1.02E+03 3.6E+00 1 .OE+00 3.2E+00
9.79E+01 2.4E+01 1 .OE+00 3.2E+00
1.70E+02 2.9E+00 1 .OE+00 3.2E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
3.11E+02 3.9E-01 1 .OE+00 3.2E+00 1000 100 1.24E+03 93% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
6.53E+02 2.7E-01 1. OE+00 3.2E+00
1.08E+03 4.0E-01 1. OE+00 3.2E+00
1.45E+03 5.8E-01 1. OE+00 3.2E+00
3.32E+00 1.7E+01 1. OE+00 3.2E+00
2.86E+00 7.0E+00 1. OE+00 3.2E+00
5.00E-01 1.9E+02 1. OE+00 3.2E+00
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1689
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba CFS-L07-1316-T01-A 1 2.07E+02
Ba CFS-L07-1316-T02-A 1 1.45E+02
Ba CFS-L07-1316-T03-A 1 3.59E+02
Ba CFS-L07-1316-T04-A 1 5.17E+02
Ba CFS-L07-1316-T05-A 1 7.70E+02
Ba CFS-L07-1316-T01-B 1 2.02E+02
Ba CFS-L07-1316-T02-B 1 2.44E+02
Ba CFS-L07-1316-T03-B 1 3.48E+02
Ba CFS-L07-1316-T04-B 1 5.25E+02
Ba CFS-L07-1316-T05-B 1 4.64E+01
Ba CFS-L07-1316-T01-C 1 2.00E+02
Ba CFS-L07-1316-T02-C 1 2.40E+02
Ba CFS-L07-1316-T03-C 1 3.50E+02
Ba CFS-L07-1316-T04-C 1 5.11E+02
Ba CFS-L07-1316-T05-C 1 7.61 E+02
Ba CFS-L07-1316-B01-A 1 5.00E-01 U1/2
Ba CFS-L07-1316-B02-A 1 5.00E-01 U1/2
Ba CFS-L07-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+02 2.5E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.45E+02 7.9E+01 1 .OE+00 3.2E+00 10 100 1.22E+03 107% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
3.59E+02 7.7E-01 1. OE+00 3.2E+00
5.17E+02 7.9E-01 1. OE+00 3.2E+00
7.70E+02 8.8E-01 1. OE+00 3.2E+00
2.02E+02 5.0E-01 1. OE+00 3.2E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
2.44E+02 8.6E-01 1.0E+00 3.2E+00 10 100 1.23E+03 99% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
3.48E+02 8.2E-01 1. OE+00 3.2E+00
5.25E+02 6.7E+00 1. OE+00 3.2E+00
4.64E+01 2.4E+01 1. OE+00 3.2E+00
2.00E+02 4.7E-01 1. OE+00 3.2E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
2.40E+02 9.9E-01 1.0E+00 3.2E+00 10 100 1.21E+03 97% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
3.50E+02 9.8E-01 1. OE+00 3.2E+00
5.11 E+02 6.7E-01 1. OE+00 3.2E+00
7.61 E+02 5.3E-01 1. OE+00 3.2E+00
5.00E-01 1.6E+02 1. OE+00 3.2E+00
5.00E-01 1.5E+02 1. OE+00 3.2E+00
5.00E-01 2.5E+02 1. OE+00 3.2E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1690
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be CFS-L07-1316-T01-A 1 9.50E-01 U1/2
Be CFS-L07-1316-T02-A 1 9.50E-01 U1/2
Be CFS-L07-1316-T03-A 1 9.50E-01 U1/2
Be CFS-L07-1316-T04-A 1 9.50E-01 U1/2
Be CFS-L07-1316-T05-A 1 9.50E-01 U1/2
Be CFS-L07-1316-T01-B 1 9.50E-01 U1/2
Be CFS-L07-1316-T02-B 1 9.50E-01 U1/2
Be CFS-L07-1316-T03-B 1 9.50E-01 U1/2
Be CFS-L07-1316-T04-B 1 9.50E-01 U1/2
Be CFS-L07-1316-T05-B 1 9.50E-01 U1/2
Be CFS-L07-1316-T01-C 1 9.50E-01 U1/2
Be CFS-L07-1316-T02-C 1 9.50E-01 U1/2
Be CFS-L07-1316-T03-C 1 9.50E-01 U1/2
Be CFS-L07-1316-T04-C 1 9.50E-01 U1/2
Be CFS-L07-1316-T05-C 1 9.50E-01 U1/2
Be CFS-L07-1316-B01-A 1 9.50E-01 U1/2
Be CFS-L07-1316-B02-A 1 9.50E-01 U1/2
Be CFS-L07-1316-B03-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 7.0E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
9.50E-01 1.2E+03 1.9E+00 6.0E+00 10 100 1.01E+03 101% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 5.3E+01 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+02 1.9E+00 6.0E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
9.50E-01 2.4E+02 1.9E+00 6.0E+00 10 100 1.01E+03 101% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
9.50E-01 1.0E+02 1.9E+00 6.0E+00
9.50E-01 5.8E+01 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 4.3E+02 1.9E+00 6.0E+00
VU ICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
9.50E-01 1.4E+02 1.9E+00 6.0E+00 10 100 1.00E+03 100% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
9.50E-01 3.7E+01 1.9E+00 6.0E+00
9.50E-01 5.0E+01 1.9E+00 6.0E+00
9.50E-01 3.0E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+01 1.9E+00 6.0E+00
9.50E-01 5.9E+01 1.9E+00 6.0E+00
9.50E-01 3.5E+01 1.9E+00 6.0E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/1 1 4:38 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/1 1 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1691
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd CFS-L07-1316-T01-A 1 4.96E+03
Cd CFS-L07-1316-T02-A 1 4.33E+03
Cd CFS-L07-1316-T03-A 1 9.57E+03
Cd CFS-L07-1316-T04-A 1 1.07E+04
Cd CFS-L07-1316-T05-A 1 1.32E+04
Cd CFS-L07-1316-T01-B 1 4.79E+03
Cd CFS-L07-1316-T02-B 1 6.37E+03
Cd CFS-L07-1316-T03-B 1 8.87E+03
Cd CFS-L07-1316-T04-B 1 1.11E+04
Cd CFS-L07-1316-T05-B 1 8.68E+02
Cd CFS-L07-1316-T01-C 1 4.89E+03
Cd CFS-L07-1316-T02-C 1 6.99E+03
Cd CFS-L07-1316-T03-C 1 9.58E+03
Cd CFS-L07-1316-T04-C 1 1.22E+04
Cd CFS-L07-1316-T05-C 1 1.17E+04
Cd CFS-L07-1316-B01-A 1 1.10E+OOU1/2
Cd CFS-L07-1316-B02-A 1 1.10E+OOU1/2
Cd CFS-L07-1316-B03-A 1 1.10E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.96E+03 4.3E-01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
4.33E+03 7.5E+01 2.2E+00 7.0E+00 10 100 5.36E+03 103% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
9.57E+03 5.8E-01 2.2E+00 7.0E+00
1.07E+04 4.7E-01 2.2E+00 7.0E+00
1.32E+04 6.3E-01 2.2E+00 7.0E+00
4.79E+03 8.2E-01 2.2E+00 7.0E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
6.37E+03 6.7E-01 2.2E+00 7.0E+00 10 100 7.35E+03 98% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
8.87E+03 6.2E-01 2.2E+00 7.0E+00
1.11E+04 6.2E+00 2.2E+00 7.0E+00
8.68E+02 2.0E+01 2.2E+00 7.0E+00
4.89E+03 5.5E-01 2.2E+00 7.0E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
6.99E+03 8.1E-01 2.2E+00 7.0E+00 10 100 7.83E+03 85% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
9.58E+03 1.7E-01 2.2E+00 7.0E+00
1.22E+04 6.3E-01 2.2E+00 7.0E+00
1.17E+04 4.9E-01 2.2E+00 7.0E+00
1.10E+00 2.0E+01 2.2E+00 7.0E+00
1.10E+00 7.8E+00 2.2E+00 7.0E+00
1.10E+00 8.6E+00 2.2E+00 7.0E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1692
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca CFS-L07-1316-T01-A 1 7.29E+05
Ca CFS-L07-1316-T02-A 1 4.60E+05
Ca CFS-L07-1316-T03-A 1 6.45E+05
Ca CFS-L07-1316-T04-A 1 6.05E+05
Ca CFS-L07-1316-T05-A 1 5.77E+05
Ca CFS-L07-1316-T01-B 1 7.03E+05
Ca CFS-L07-1316-T02-B 1 6.72E+05
Ca CFS-L07-1316-T03-B 1 6.26E+05
Ca CFS-L07-1316-T04-B 1 6.24E+05
Ca CFS-L07-1316-T05-B 1 3.18E+04
Ca CFS-L07-1316-T01-C 1 7.07E+05
Ca CFS-L07-1316-T02-C 1 6.63E+05
Ca CFS-L07-1316-T03-C 1 6.18E+05
Ca CFS-L07-1316-T04-C 1 5.99E+05
Ca CFS-L07-1316-T05-C 1 5.68E+05
Ca CFS-L07-1316-B01-A 1 2.80E+01
Ca CFS-L07-1316-B02-A 1 2.41E+01
Ca CFS-L07-1316-B03-A 1 2.37E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.29E+05 6.8E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
4.60E+05 7.6E+01 2.6E+00 8.3E+00 1000 100 4.60E+05 87% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
6.45E+05 6.4E-01 2.6E+00 8.3E+00
6.05E+05 7.4E-01 2.6E+00 8.3E+00
5.77E+05 8.0E-01 2.6E+00 8.3E+00
7.03E+05 9.2E-01 2.6E+00 8.3E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
6.72E+05 8.2E-01 2.6E+00 8.3E+00 1000 100 6.73E+05 85% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
6.26E+05 2.5E-01 2.6E+00 8.3E+00
6.24E+05 6.4E+00 2.6E+00 8.3E+00
3.18E+04 2.4E+01 2.6E+00 8.3E+00
7.07E+05 9.4E-01 2.6E+00 8.3E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
6.63E+05 8.0E-01 2.6E+00 8.3E+00 1000 100 6.64E+05 89% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
6.18E+05 3.9E-01 2.6E+00 8.3E+00
5.99E+05 5.8E-01 2.6E+00 8.3E+00
5.68E+05 3.2E-01 2.6E+00 8.3E+00
2.80E+01 1.6E+01 2.6E+00 8.3E+00
2.41 E+01 9.6E+00 2.6E+00 8.3E+00
2.37E+01 1.4E+01 2.6E+00 8.3E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1693
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cr Sample Dilution Cone. Qualifier Revi
ug/L
Cr CFS-L07-1316-T01-A 1 6.00E-01 U1/2
Cr CFS-L07-1316-T02-A 1 6.00E-01 U1/2
Cr CFS-L07-1316-T03-A 1 6.00E-01 U1/2
Cr CFS-L07-1316-T04-A 1 6.00E-01 U1/2
Cr CFS-L07-1316-T05-A 1 1.28E+OOE
Cr CFS-L07-1316-T01-B 1 6.00E-01 U1/2
Cr CFS-L07-1316-T02-B 1 6.00E-01 U1/2
Cr CFS-L07-1316-T03-B 1 6.00E-01 U1/2
Cr CFS-L07-1316-T04-B 1 6.00E-01 U1/2
Cr CFS-L07-1316-T05-B 1 6.00E-01 U1/2
Cr CFS-L07-1316-T01-C 1 6.00E-01 U1/2
Cr CFS-L07-1316-T02-C 1 6.00E-01 U1/2
Cr CFS-L07-1316-T03-C 1 6.00E-01 U1/2
Cr CFS-L07-1316-T04-C 1 6.00E-01 U1/2
Cr CFS-L07-1316-T05-C 1 6.00E-01 U1/2
Cr CFS-L07-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L07-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L07-1316-B01-A 1 6.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 2.9E+03 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
6.00E-01 5.3E+01 1.2E+00 3.8E+00 10 100 9.71E+02 97% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
6.00E-01 4.9E+01 1.2E+00 3.8E+00
6.00E-01 4.2E+02 1.2E+00 3.8E+00
1.28E+00 9.3E+01 1.2E+00 3.8E+00
6.00E-01 5.7E+03 1.2E+00 3.8E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
6.00E-01 3.5E+02 1.2E+00 3.8E+00 10 100 9.85E+02 98% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
6.00E-01 5.9E+01 1.2E+00 3.8E+00
6.00E-01 9.6E+01 1.2E+00 3.8E+00
6.00E-01 2.4E+01 1.2E+00 3.8E+00
6.00E-01 9.7E+02 1.2E+00 3.8E+00
VU ICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
6.00E-01 2.7E+03 1.2E+00 3.8E+00 10 100 9.69E+02 97% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
6.00E-01 2.3E+02 1.2E+00 3.8E+00
6.00E-01 1.5E+02 1.2E+00 3.8E+00
6.00E-01 8.7E+02 1.2E+00 3.8E+00
6.00E-01 3.1E+01 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
6.00E-01 1.1E+01 1.2E+00 3.8E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/1 1 4:36 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/1 1 4:38 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/1 1 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1694
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co CFS-L07-1316-T01-A 1 1.01E+02
Co CFS-L07-1316-T02-A 1 1.08E+02
Co CFS-L07-1316-T03-A 1 3.09E+02
Co CFS-L07-1316-T04-A 1 3.93E+02
Co CFS-L07-1316-T05-A 1 5.39E+02
Co CFS-L07-1316-T01-B 1 9.56E+01
Co CFS-L07-1316-T02-B 1 1.61E+02
Co CFS-L07-1316-T03-B 1 2.87E+02
Co CFS-L07-1316-T04-B 1 4.03E+02
Co CFS-L07-1316-T05-B 1 3.05E+01
Co CFS-L07-1316-T01-C 1 1.03E+02
Co CFS-L07-1316-T02-C 1 1.89E+02
Co CFS-L07-1316-T03-C 1 3.22E+02
Co CFS-L07-1316-T04-C 1 4.61 E+02
Co CFS-L07-1316-T05-C 1 4.33E+02
Co CFS-L07-1316-B01-A 1 9.00E-01 U1/2
Co CFS-L07-1316-B02-A 1 9.00E-01 U1/2
Co CFS-L07-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.01 E+02 5.2E-01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.08E+02 7.7E+01 1 .8E+00 5.7E+00 10 100 1.09E+03 98% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
3.09E+02 8.9E-01 1 .8E+00 5.7E+00
3.93E+02 3.8E-01 1 .8E+00 5.7E+00
5.39E+02 7.2E-01 1 .8E+00 5.7E+00
9.56E+01 8.9E-01 1.8E+00 5.7E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
1.61 E+02 1.5E+00 1.8E+00 5.7E+00 10 100 1.10E+03 94% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
2.87E+02 4.8E-01 1.8E+00 5.7E+00
4.03E+02 5.5E+00 1.8E+00 5.7E+00
3.05E+01 2.5E+01 1.8E+00 5.7E+00
1.03E+02 1.2E+00 1.8E+00 5.7E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.89E+02 8.6E-01 1.8E+00 5.7E+00 10 100 1.10E+03 91% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
3.22E+02 4.8E-01 1.8E+00 5.7E+00
4.61 E+02 7.3E-01 1.8E+00 5.7E+00
4.33E+02 9.5E-02 1.8E+00 5.7E+00
9.00E-01 1.8E+01 1.8E+00 5.7E+00
9.00E-01 1.5E+01 1.8E+00 5.7E+00
9.00E-01 2.8E+00 1.8E+00 5.7E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1695
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu CFS-L07-1316-T01-A 1 9.15E+02
Cu CFS-L07-1316-T02-A 1 8.76E+02
Cu CFS-L07-1316-T03-A 1 1.56E+03
Cu CFS-L07-1316-T04-A 1 1.85E+03
Cu CFS-L07-1316-T05-A 1 2.49E+03
Cu CFS-L07-1316-T01-B 1 8.84E+02
Cu CFS-L07-1316-T02-B 1 9.88E+02
Cu CFS-L07-1316-T03-B 1 1.38E+03
Cu CFS-L07-1316-T04-B 1 1.80E+03
Cu CFS-L07-1316-T05-B 1 1.75E+02
Cu CFS-L07-1316-T01-C 1 1.05E+03
Cu CFS-L07-1316-T02-C 1 1.19E+03
Cu CFS-L07-1316-T03-C 1 1.78E+03
Cu CFS-L07-1316-T04-C 1 2.24E+03
Cu CFS-L07-1316-T05-C 1 2.08E+03
Cu CFS-L07-1316-B01-A 1 1.85E+OOU1/2
Cu CFS-L07-1316-B02-A 1 1.85E+OOU1/2
Cu CFS-L07-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.15E+02 3.1E-01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
8.76E+02 7.4E+01 3.7E+00 1.2E+01 10 100 1.87E+03 99% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
1.56E+03 1.3E+00 3.7E+00 1.2E+01
1.85E+03 4.2E-01 3.7E+00 1.2E+01
2.49E+03 4.3E-01 3.7E+00 1.2E+01
8.84E+02 7.4E-01 3.7E+00 1.2E+01
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
9.88E+02 1.2E+00 3.7E+00 1.2E+01 10 100 1.85E+03 86% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
1.38E+03 1.0E+00 3.7E+00 1.2E+01
1.80E+03 4.0E+00 3.7E+00 1.2E+01
1.75E+02 1.9E+01 3.7E+00 1.2E+01
1.05E+03 1.7E+00 3.7E+00 1.2E+01
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.19E+03 1.0E+00 3.7E+00 1.2E+01 10 100 2.07E+03 88% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
1.78E+03 3.1E-01 3.7E+00 1.2E+01
2.24E+03 8.3E-01 3.7E+00 1.2E+01
2.08E+03 6.9E-01 3.7E+00 1.2E+01
1.85E+00 1.5E+03 3.7E+00 1.2E+01
1.85E+00 1.8E+03 3.7E+00 1.2E+01
1.85E+00 4.7E+01 3.7E+00 1.2E+01
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1696
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe CFS-L07-1316-T01-A 1 1.00E+OOU1/2
Fe CFS-L07-1316-T02-A 1 1.00E+OOU1/2
Fe CFS-L07-1316-T03-A 1 1.00E+OOU1/2
Fe CFS-L07-1316-T04-A 1 5.41E+00 E
Fe CFS-L07-1316-T05-A 1 3.40E+00 E
Fe CFS-L07-1316-T01-B 1 1.00E+OOU1/2
Fe CFS-L07-1316-T02-B 1 1.00E+OOU1/2
Fe CFS-L07-1316-T03-B 1 1.00E+OOU1/2
Fe CFS-L07-1316-T04-B 1 2.17E+00 E
Fe CFS-L07-1316-T05-B 1 1.00E+OOU1/2
Fe CFS-L07-1316-T01-C 1 1.00E+OOU1/2
Fe CFS-L07-1316-T02-C 1 1.00E+OOU1/2
Fe CFS-L07-1316-T03-C 1 1.00E+OOU1/2
Fe CFS-L07-1316-T04-C 1 1.00E+OOU1/2
Fe CFS-L07-1316-T05-C 1 1.00E+OOU1/2
Fe CFS-L07-1316-B01-A 1 6.78E+00
Fe CFS-L07-1316-B02-A 1 1.00E+OOU1/2
Fe CFS-L07-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 7.1E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 2.2E+01 2.0E+00 6.4E+00 1000 100 9.99E+02 100% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 5.1E+01 2.0E+00 6.4E+00
5.41 E+00 3.4E+00 2.0E+00 6.4E+00
3.40E+00 6.7E+00 2.0E+00 6.4E+00
1.00E+00 2.0E+01 2.0E+00 6.4E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 2.8E+01 2.0E+00 6.4E+00 1000 100 1.01E+03 101% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 1.8E+01 2.0E+00 6.4E+00
2.17E+00 3.5E+01 2.0E+00 6.4E+00
1.00E+00 4.4E+00 2.0E+00 6.4E+00
1.00E+00 8.6E+00 2.0E+00 6.4E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 1.3E+02 2.0E+00 6.4E+00 1000 100 9.94E+02 99% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 5.3E+00 2.0E+00 6.4E+00
1.00E+00 3.5E+00 2.0E+00 6.4E+00
1.00E+00 1.3E+01 2.0E+00 6.4E+00
6.78E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1697
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb CFS-L07-1316-T01-A 1 1.41E+03
Pb CFS-L07-1316-T02-A 1 9.60E+02
Pb CFS-L07-1316-T03-A 1 1.57E+03
Pb CFS-L07-1316-T04-A 1 1.63E+03
Pb CFS-L07-1316-T05-A 1 1.49E+03
Pb CFS-L07-1316-T01-B 1 1.42E+03
Pb CFS-L07-1316-T02-B 1 1.41E+03
Pb CFS-L07-1316-T03-B 1 1.49E+03
Pb CFS-L07-1316-T04-B 1 1.60E+03
Pb CFS-L07-1316-T05-B 1 9.82E+01
Pb CFS-L07-1316-T01-C 1 1.41E+03
Pb CFS-L07-1316-T02-C 1 1.56E+03
Pb CFS-L07-1316-T03-C 1 1.62E+03
Pb CFS-L07-1316-T04-C 1 1.68E+03
Pb CFS-L07-1316-T05-C 1 1.42E+03
Pb CFS-L07-1316-B01-A 1 3.40E+00 U1/2
Pb CFS-L07-1316-B02-A 1 3.40E+00 U1/2
Pb CFS-L07-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.41E+03 1.5E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
9.60E+02 7.5E+01 6.8E+00 2.2E+01 10 100 1.82E+03 86% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
1.57E+03 1.1E+00 6.8E+00 2.2E+01
1.63E+03 1.1E-01 6.8E+00 2.2E+01
1.49E+03 2.8E-01 6.8E+00 2.2E+01
1.42E+03 1.1E+00 6.8E+00 2.2E+01
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
1.41E+03 6.8E-01 6.8E+00 2.2E+01 10 100 2.36E+03 95% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
1.49E+03 7.5E-01 6.8E+00 2.2E+01
1.60E+03 4.3E+00 6.8E+00 2.2E+01
9.82E+01 2.1E+01 6.8E+00 2.2E+01
1.41E+03 1.1E+00 6.8E+00 2.2E+01
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.56E+03 1.6E+00 6.8E+00 2.2E+01 10 100 2.48E+03 92% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
1.62E+03 4.3E-01 6.8E+00 2.2E+01
1.68E+03 2.8E-01 6.8E+00 2.2E+01
1.42E+03 8.5E-01 6.8E+00 2.2E+01
3.40E+00 4.9E+01 6.8E+00 2.2E+01
3.40E+00 1.5E+02 6.8E+00 2.2E+01
3.40E+00 4.5E+01 6.8E+00 2.2E+01
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1698
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li CFS-L07-1316-T01-A 1 2.07E+01
Li CFS-L07-1316-T02-A 1 1.93E+01
Li CFS-L07-1316-T03-A 1 1.65E+01
Li CFS-L07-1316-T04-A 1 1.57E+01
Li CFS-L07-1316-T05-A 1 2.74E+01
Li CFS-L07-1316-T01-B 1 2.12E+01
Li CFS-L07-1316-T02-B 1 1.95E+01
Li CFS-L07-1316-T03-B 1 1.55E+01
Li CFS-L07-1316-T04-B 1 1.45E+01
Li CFS-L07-1316-T05-B 1 1.15E+01
Li CFS-L07-1316-T01-C 1 2.03E+01
Li CFS-L07-1316-T02-C 1 1.68E+01
Li CFS-L07-1316-T03-C 1 1.60E+01
Li CFS-L07-1316-T04-C 1 1.50E+01
Li CFS-L07-1316-T05-C 1 2.33E+01
Li CFS-L07-1316-B01-A 1 6.09E+00
Li CFS-L07-1316-B02-A 1 5.57E+00 E
Li CFS-L07-1316-B03-A 1 7.35E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+01 6.5E+00 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.93E+01 2.2E+01 1 .9E+00 6.0E+00 10 100 8.78E+02 86% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
1.65E+01 1.5E+01 1.9E+00 6.0E+00
1.57E+01 6.3E+00 1 .9E+00 6.0E+00
2.74E+01 7.4E+00 1 .9E+00 6.0E+00
2.12E+01 1.3E+01 1.9E+00 6.0E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
1.95E+01 1.4E+01 1.9E+00 6.0E+00 10 100 8.87E+02 87% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
1.55E+01 6.0E+00 1.9E+00 6.0E+00
1.45E+01 1.9E+00 1.9E+00 6.0E+00
1.15E+01 5.6E+00 1.9E+00 6.0E+00
2.03E+01 1.6E+01 1.9E+00 6.0E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.68E+01 2.1E+01 1.9E+00 6.0E+00 10 100 8.98E+02 88% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
1.60E+01 8.0E+00 1.9E+00 6.0E+00
1.50E+01 1.7E+01 1.9E+00 6.0E+00
2.33E+01 5.1E+00 1.9E+00 6.0E+00
6.09E+00 5.6E-01 1.9E+00 6.0E+00
5.57E+00 5.2E+00 1.9E+00 6.0E+00
7.35E+00 8.0E+00 1.9E+00 6.0E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1699
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn CFS-L07-1316-T01-A 1 1.76E+03
Mn CFS-L07-1316-T02-A 1 2.50E+03
Mn CFS-L07-1316-T03-A 1 6.77E+03
Mn CFS-L07-1316-T04-A 1 9.73E+03
Mn CFS-L07-1316-T05-A 1 1.53E+04
Mn CFS-L07-1316-T01-B 1 1.68E+03
Mn CFS-L07-1316-T02-B 1 3.14E+03
Mn CFS-L07-1316-T03-B 1 6.47E+03
Mn CFS-L07-1316-T04-B 1 1.01E+04
Mn CFS-L07-1316-T05-B 1 1.01E+03
Mn CFS-L07-1316-T01-C 1 1.83E+03
Mn CFS-L07-1316-T02-C 1 3.62E+03
Mn CFS-L07-1316-T03-C 1 6.90E+03
Mn CFS-L07-1316-T04-C 1 1.11E+04
Mn CFS-L07-1316-T05-C 1 1.26E+04
Mn CFS-L07-1316-B01-A 1 1.00E+OOU1/2
Mn CFS-L07-1316-B02-A 1 1.00E+OOU1/2
Mn CFS-L07-1316-B03-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.76E+03 9.6E-01 2.0E+00 6.4E+00
2.50E+03 7.2E+01 2.0E+00 6.4E+00 10 100
6.77E+03 9.6E-01 2.0E+00 6.4E+00
9.73E+03 1.1E-01 2.0E+00 6.4E+00
1.53E+04 1.1E+00 2.0E+00 6.4E+00
1.68E+03 1.2E+00 2.0E+00 6.4E+00
3.14E+03 1.3E+00 2.0E+00 6.4E+00 10 100
6.47E+03 5.7E-01 2.0E+00 6.4E+00
1.01E+04 4.6E+00 2.0E+00 6.4E+00
1.01E+03 1.6E+01 2.0E+00 6.4E+00
1.83E+03 1.0E+00 2.0E+00 6.4E+00
3.62E+03 1.1E+00 2.0E+00 6.4E+00 10 100
6.90E+03 7.4E-01 2.0E+00 6.4E+00
1.11E+04 1.3E+00 2.0E+00 6.4E+00
1.26E+04 4.9E-01 2.0E+00 6.4E+00
1.00E+00 6.3E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
3.38E+03 88% VUICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
4.08E+03 93% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
4.56E+03 95% VUICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1700
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg CFS-L07-1316-T01-A 1 7.48E+04
Mg CFS-L07-1316-T02-A 1 7.48E+04
Mg CFS-L07-1316-T03-A 1 3.16E+05
Mg CFS-L07-1316-T04-A 1 5.61 E+05
Mg CFS-L07-1316-T05-A 1 9.73E+05
Mg CFS-L07-1316-T01-B 1 7.31E+04
Mg CFS-L07-1316-T02-B 1 1.40E+05
Mg CFS-L07-1316-T03-B 1 3.08E+05
Mg CFS-L07-1316-T04-B 1 5.69E+05
Mg CFS-L07-1316-T05-B 1 6.02E+04
Mg CFS-L07-1316-T01-C 1 7.54E+04
Mg CFS-L07-1316-T02-C 1 1.40E+05
Mg CFS-L07-1316-T03-C 1 3.24E+05
Mg CFS-L07-1316-T04-C 1 5.76E+05
Mg CFS-L07-1316-T05-C 1 9.48E+05
Mg CFS-L07-1316-B01-A 1 5.00E-01 U1/2
Mg CFS-L07-1316-B02-A 1 5.00E-01 U1/2
Mg CFS-L07-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.48E+04 1.0E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
7.48E+04 8.6E+01 1 .OE+00 3.2E+00 1000 100 7.57E+04 93% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
3.16E+05 1.9E+00 1. OE+00 3.2E+00
5.61E+05 6.1E-01 1.0E+00 3.2E+00
9.73E+05 3.5E-01 1. OE+00 3.2E+00
7.31 E+04 4.9E-01 1. OE+00 3.2E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
1.40E+05 1.4E+00 1.0E+00 3.2E+00 1000 100 1.41E+05 97% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
3.08E+05 3.1E-01 1. OE+00 3.2E+00
5.69E+05 3.1E+00 1. OE+00 3.2E+00
6.02E+04 2.4E+01 1. OE+00 3.2E+00
7.54E+04 6.2E-01 1. OE+00 3.2E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.40E+05 7.6E-01 1.0E+00 3.2E+00 1000 100 1.41E+05 87% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
3.24E+05 1.6E+00 1. OE+00 3.2E+00
5.76E+05 9.6E-01 1. OE+00 3.2E+00
9.48E+05 7.2E-01 1. OE+00 3.2E+00
5.00E-01 1.3E+02 1. OE+00 3.2E+00
5.00E-01 1.9E+02 1. OE+00 3.2E+00
5.00E-01 6.8E+02 1. OE+00 3.2E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1701
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo CFS-L07-1316-T01-A 1 1.08E+01
Mo CFS-L07-1316-T02-A 1 6.90E+00
Mo CFS-L07-1316-T03-A 1 1.64E+01
Mo CFS-L07-1316-T04-A 1 1.87E+01
Mo CFS-L07-1316-T05-A 1 2.65E+01
Mo CFS-L07-1316-T01-B 1 1.05E+01
Mo CFS-L07-1316-T02-B 1 1.26E+01
Mo CFS-L07-1316-T03-B 1 1.69E+01
Mo CFS-L07-1316-T04-B 1 1.86E+01
Mo CFS-L07-1316-T05-B 1 6.00E-01 U1/2
Mo CFS-L07-1316-T01-C 1 9.32E+00
Mo CFS-L07-1316-T02-C 1 1.27E+01
Mo CFS-L07-1316-T03-C 1 1.53E+01
Mo CFS-L07-1316-T04-C 1 1.91E+01
Mo CFS-L07-1316-T05-C 1 2.77E+01
Mo CFS-L07-1316-B01-A 1 1.74E+OOE
Mo CFS-L07-1316-B02-A 1 6.00E-01 U1/2
Mo CFS-L07-1316-B03-A 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+01 1.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
6.90E+00 8.6E+01 1 .2E+00 3.8E+00 10 100 9.50E+02 94% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
1.64E+01 7.9E+00 1.2E+00 3.8E+00
1.87E+01 7.3E+00 1.2E+00 3.8E+00
2.65E+01 7.7E+00 1.2E+00 3.8E+00
1.05E+01 6.8E+00 1.2E+00 3.8E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
1.26E+01 6.0E+00 1.2E+00 3.8E+00 10 100 9.71E+02 96% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
1.69E+01 6.1E+00 1.2E+00 3.8E+00
1.86E+01 5.9E+00 1.2E+00 3.8E+00
6.00E-01 2.7E+01 1.2E+00 3.8E+00
9.32E+00 1.3E+01 1.2E+00 3.8E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.27E+01 5.0E+00 1.2E+00 3.8E+00 10 100 9.56E+02 94% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
1.53E+01 1.2E+01 1.2E+00 3.8E+00
1.91E+01 6.2E+00 1.2E+00 3.8E+00
2.77E+01 8.0E+00 1.2E+00 3.8E+00
1.74E+00 6.7E+01 1.2E+00 3.8E+00
6.00E-01 2.0E+02 1.2E+00 3.8E+00
6.00E-01 2.8E+01 1.2E+00 3.8E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1702
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni CFS-L07-1316-T01-A 1 2.14E+02
Ni CFS-L07-1316-T02-A 1 2.16E+02
Ni CFS-L07-1316-T03-A 1 5.66E+02
Ni CFS-L07-1316-T04-A 1 6.68E+02
Ni CFS-L07-1316-T05-A 1 8.64E+02
Ni CFS-L07-1316-T01-B 1 2.03E+02
Ni CFS-L07-1316-T02-B 1 3.17E+02
Ni CFS-L07-1316-T03-B 1 5.21E+02
Ni CFS-L07-1316-T04-B 1 6.87E+02
Ni CFS-L07-1316-T05-B 1 5.37E+01
Ni CFS-L07-1316-T01-C 1 2.17E+02
Ni CFS-L07-1316-T02-C 1 3.70E+02
Ni CFS-L07-1316-T03-C 1 5.87E+02
Ni CFS-L07-1316-T04-C 1 7.89E+02
Ni CFS-L07-1316-T05-C 1 7.00E+02
Ni CFS-L07-1316-B01-A 1 9.00E-01 U1/2
Ni CFS-L07-1316-B02-A 1 9.00E-01 U1/2
Ni CFS-L07-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.14E+02 1.8E+00 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
2.16E+02 7.5E+01 1 .8E+00 5.7E+00 10 100 1.24E+03 102% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
5.66E+02 5.2E-01 1 .8E+00 5.7E+00
6.68E+02 3.1E-01 1 .8E+00 5.7E+00
8.64E+02 5.9E-01 1 .8E+00 5.7E+00
2.03E+02 1.4E+00 1.8E+00 5.7E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
3.17E+02 1.7E+00 1.8E+00 5.7E+00 10 100 1.25E+03 93% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
5.21E+02 4.1E-01 1.8E+00 5.7E+00
6.87E+02 5.7E+00 1.8E+00 5.7E+00
5.37E+01 2.1E+01 1.8E+00 5.7E+00
2.17E+02 7.7E-01 1.8E+00 5.7E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
3.70E+02 2.3E+00 1.8E+00 5.7E+00 10 100 1.25E+03 88% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
5.87E+02 1.2E-01 1.8E+00 5.7E+00
7.89E+02 4.1E-01 1.8E+00 5.7E+00
7.00E+02 5.1E-01 1.8E+00 5.7E+00
9.00E-01 2.3E+01 1.8E+00 5.7E+00
9.00E-01 2.2E+01 1.8E+00 5.7E+00
9.00E-01 5.4E+01 1.8E+00 5.7E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1703
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P CFS-L07-1316-T01-A 1 4.92E+00 E
P CFS-L07-1316-T02-A 1 2.42E+01
P CFS-L07-1316-T03-A 1 3.37E+01
P CFS-L07-1316-T04-A 1 2.67E+01
P CFS-L07-1316-T05-A 1 1.55E+01
P CFS-L07-1316-T01-B 1 8.13E+00 E
P CFS-L07-1316-T02-B 1 2.25E+01
P CFS-L07-1316-T03-B 1 1.58E+01
P CFS-L07-1316-T04-B 1 2.15E+01
P CFS-L07-1316-T05-B 1 1.85E+OOU1/2
P CFS-L07-1316-T01-C 1 1.85E+OOU1/2
P CFS-L07-1316-T02-C 1 5.27E+00 E
P CFS-L07-1316-T03-C 1 1.52E+01
P CFS-L07-1316-T04-C 1 3.57E+01
P CFS-L07-1316-T05-C 1 3.26E+01
P CFS-L07-1316-B01-A 1 1.80E+01
P CFS-L07-1316-B02-A 1 1.19E+01
P CFS-L07-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.92E+00 1.8E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
2.42E+01 8.1E+01 3.7E+00 1.2E+01 1000 100 9.85E+02 96% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
3.37E+01 6.4E+00 3.7E+00 1.2E+01
2.67E+01 2.9E+01 3.7E+00 1.2E+01
1.55E+01 5.1E+01 3.7E+00 1.2E+01
8.13E+00 1.1E+02 3.7E+00 1.2E+01
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
2.25E+01 1.2E+02 3.7E+00 1.2E+01 1000 100 1 .02E+03 100% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
1.58E+01 8.6E+01 3.7E+00 1.2E+01
2.15E+01 5.4E+01 3.7E+00 1.2E+01
1.85E+00 6.0E+01 3.7E+00 1.2E+01
1.85E+00 5.4E+02 3.7E+00 1.2E+01
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
5.27E+00 5.6E+01 3.7E+00 1.2E+01 1000 100 9.96E+02 99% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
1.52E+01 5.2E+01 3.7E+00 1.2E+01
3.57E+01 3.9E+01 3.7E+00 1.2E+01
3.26E+01 4.0E+01 3.7E+00 1.2E+01
1.80E+01 2.5E+01 3.7E+00 1.2E+01
1.19E+01 3.1E+01 3.7E+00 1.2E+01
1.85E+00 1.9E+04 3.7E+00 1.2E+01
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1704
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K CFS-L07-1316-T01-A 1 1.07E+04
K CFS-L07-1316-T02-A 1 1.16E+04
K CFS-L07-1316-T03-A 1 3.70E+04
K CFS-L07-1316-T04-A 1 5.71 E+04
K CFS-L07-1316-T05-A 1 9.18E+04
K CFS-L07-1316-T01-B 1 1.08E+04
K CFS-L07-1316-T02-B 1 1.90E+04
K CFS-L07-1316-T03-B 1 3.73E+04
K CFS-L07-1316-T04-B 1 5.79E+04
K CFS-L07-1316-T05-B 1 4.31 E+03
K CFS-L07-1316-T01-C 1 1.03E+04
K CFS-L07-1316-T02-C 1 1.90E+04
K CFS-L07-1316-T03-C 1 3.60E+04
K CFS-L07-1316-T04-C 1 6.01 E+04
K CFS-L07-1316-T05-C 1 8.88E+04
K CFS-L07-1316-B01-A 1 9.57E+00
K CFS-L07-1316-B02-A 1 3.72E+00 E
K CFS-L07-1316-B03-A 1 8.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.07E+04 5.1E-01 1.6E+00 5.1E+00
1.16E+04 8.0E+01 1.6E+00 5.1E+00 1000 100
3.70E+04 1.4E+00 1 .6E+00 5.1E+00
5.71 E+04 7.2E-01 1 .6E+00 5.1E+00
9.18E+04 2.2E-01 1 .6E+00 5.1E+00
1.08E+04 9.5E-01 1 .6E+00 5.1E+00
1.90E+04 6.7E-01 1 .6E+00 5.1E+00 1000 100
3.73E+04 4.4E-01 1 .6E+00 5.1E+00
5.79E+04 5.5E+00 1 .6E+00 5.1E+00
4.31 E+03 2.9E+01 1 .6E+00 5.1E+00
1.03E+04 6.2E-01 1 .6E+00 5.1E+00
1.90E+04 9.7E-01 1 .6E+00 5.1E+00 1000 100
3.60E+04 4.4E-01 1.6E+00 5.1E+00
6.01 E+04 7.8E-01 1.6E+00 5.1E+00
8.88E+04 4.4E-01 1.6E+00 5.1E+00
9.57E+00 4.6E+00 1.6E+00 5.1E+00
3.72E+00 7.2E+01 1.6E+00 5.1E+00
8.00E-01 1.9E+02 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.27E+04 104% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
2.00E+04 100% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.99E+04 92% VUICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1705
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se CFS-L07-1316-T01-A 1 8.53E+01
Se CFS-L07-1316-T02-A 1 1.01E+02
Se CFS-L07-1316-T03-A 1 3.04E+02
Se CFS-L07-1316-T04-A 1 5.29E+02
Se CFS-L07-1316-T05-A 1 9.33E+02
Se CFS-L07-1316-T01-B 1 8.67E+01
Se CFS-L07-1316-T02-B 1 1.42E+02
Se CFS-L07-1316-T03-B 1 2.94E+02
Se CFS-L07-1316-T04-B 1 5.25E+02
Se CFS-L07-1316-T05-B 1 4.90E+01
Se CFS-L07-1316-T01-C 1 8.04E+01
Se CFS-L07-1316-T02-C 1 1.40E+02
Se CFS-L07-1316-T03-C 1 2.92E+02
Se CFS-L07-1316-T04-C 1 5.50E+02
Se CFS-L07-1316-T05-C 1 9.31 E+02
Se CFS-L07-1316-B01-A 1 7.50E+00 U1/2
Se CFS-L07-1316-B02-A 1 7.50E+00 U1/2
Se CFS-L07-1316-B03-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.53E+01 2.1E+01 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.01 E+02 7.9E+01 1.5E+01 4.8E+01 10 100 1.10E+03 100% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
3.04E+02 3.8E+00 1.5E+01 4.8E+01
5.29E+02 1.1E+00 1.5E+01 4.8E+01
9.33E+02 1.4E+00 1.5E+01 4.8E+01
8.67E+01 5.2E+00 1.5E+01 4.8E+01
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
1.42E+02 7.8E+00 1.5E+01 4.8E+01 10 100 1.09E+03 95% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
2.94E+02 3.1E+00 1.5E+01 4.8E+01
5.25E+02 7.4E+00 1.5E+01 4.8E+01
4.90E+01 2.5E+01 1.5E+01 4.8E+01
8.04E+01 2.0E+01 1.5E+01 4.8E+01
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.40E+02 9.8E+00 1.5E+01 4.8E+01 10 100 1.09E+03 95% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
2.92E+02 4.3E+00 1.5E+01 4.8E+01
5.50E+02 4.6E+00 1.5E+01 4.8E+01
9.31 E+02 2.2E+00 1.5E+01 4.8E+01
7.50E+00 2.2E+02 1.5E+01 4.8E+01
7.50E+00 3.7E+01 1.5E+01 4.8E+01
7.50E+00 1.1 E+02 1.5E+01 4.8E+01
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1706
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si CFS-L07-1316-T01-A 1 4.41E+03
Si CFS-L07-1316-T02-A 1 4.11E+03
Si CFS-L07-1316-T03-A 1 6.92E+03
Si CFS-L07-1316-T04-A 1 7.03E+03
Si CFS-L07-1316-T05-A 1 7.35E+03
Si CFS-L07-1316-T01-B 1 4.23E+03
Si CFS-L07-1316-T02-B 1 5.29E+03
Si CFS-L07-1316-T03-B 1 6.53E+03
Si CFS-L07-1316-T04-B 1 6.99E+03
Si CFS-L07-1316-T05-B 1 4.67E+02
Si CFS-L07-1316-T01-C 1 4.09E+03
Si CFS-L07-1316-T02-C 1 5.76E+03
Si CFS-L07-1316-T03-C 1 7.14E+03
Si CFS-L07-1316-T04-C 1 7.67E+03
Si CFS-L07-1316-T05-C 1 6.99E+03
Si CFS-L07-1316-B01-A 1 4.63E+00
Si CFS-L07-1316-B02-A 1 5.50E-01 U1/2
Si CFS-L07-1316-B03-A 1 8.28E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.41 E+03 5.3E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
4.11E+03 7.5E+01 1.1E+00 3.5E+00 1000 100 5.02E+03 91%VUICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
6.92E+03 1.0E+00 1.1E+00 3.5E+00
7.03E+03 3.3E-01 1.1E+00 3.5E+00
7.35E+03 5.7E-01 1.1E+00 3.5E+00
4.23E+03 7.5E-01 1.1E+00 3.5E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
5.29E+03 8.3E-01 1.1E+00 3.5E+00 1000 100 6.14E+03 86% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
6.53E+03 2.3E-01 1.1E+00 3.5E+00
6.99E+03 3.7E+00 1.1E+00 3.5E+00
4.67E+02 2.3E+01 1.1E+00 3.5E+00
4.09E+03 1.1E+00 1.1E+00 3.5E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
5.76E+03 1.2E+00 1.1E+00 3.5E+00 1000 100 6.68E+03 92% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
7.14E+03 8.1E-01 1.1E+00 3.5E+00
7.67E+03 7.2E-01 1.1E+00 3.5E+00
6.99E+03 4.1E-01 1.1E+00 3.5E+00
4.63E+00 6.2E+01 1.1E+00 3.5E+00
5.50E-01 1.1E+02 1.1E+00 3.5E+00
8.28E+00 8.5E+01 1.1E+00 3.5E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1707
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na CFS-L07-1316-T01-A 1 2.15E+04
Na CFS-L07-1316-T02-A 1 2.35E+04
Na CFS-L07-1316-T03-A 1 8.39E+04
Na CFS-L07-1316-T04-A 1 1.29E+05
Na CFS-L07-1316-T05-A 1 1.96E+05
Na CFS-L07-1316-T01-B 1 2.23E+04
Na CFS-L07-1316-T02-B 1 4.05E+04
Na CFS-L07-1316-T03-B 1 8.01 E+04
Na CFS-L07-1316-T04-B 1 1.28E+05
Na CFS-L07-1316-T05-B 1 3.36E+04
Na CFS-L07-1316-T01-C 1 2.17E+04
Na CFS-L07-1316-T02-C 1 4.09E+04
Na CFS-L07-1316-T03-C 1 8.63E+04
Na CFS-L07-1316-T04-C 1 1.33E+05
Na CFS-L07-1316-T05-C 1 1.95E+05
Na CFS-L07-1316-B01-A 1 2.95E+01
Na CFS-L07-1316-B02-A 1 7.77E+01
Na CFS-L07-1316-B03-A 1 1.91E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.15E+04 7.8E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
2.35E+04 7.1E+01 2.5E+00 8.0E+00 1000 100 2.44E+04 97% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
8.39E+04 5.0E-01 2.5E+00 8.0E+00
1.29E+05 5.9E-01 2.5E+00 8.0E+00
1.96E+05 5.5E-01 2.5E+00 8.0E+00
2.23E+04 6.3E-01 2.5E+00 8.0E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
4.05E+04 9.9E-01 2.5E+00 8.0E+00 1000 100 4.14E+04 90% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
8.01 E+04 2.9E-01 2.5E+00 8.0E+00
1.28E+05 2.0E+00 2.5E+00 8.0E+00
3.36E+04 2.3E+01 2.5E+00 8.0E+00
2.17E+04 7.1E-01 2.5E+00 8.0E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
4.09E+04 7.2E-01 2.5E+00 8.0E+00 1000 100 4.19E+04 92% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
8.63E+04 6.1E-01 2.5E+00 8.0E+00
1.33E+05 1.1E+00 2.5E+00 8.0E+00
1.95E+05 9.6E-02 2.5E+00 8.0E+00
2.95E+01 6.5E+00 2.5E+00 8.0E+00
7.77E+01 3.7E+00 2.5E+00 8.0E+00
1.91E+01 2.4E+01 2.5E+00 8.0E+00
VU ICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VU ICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1708
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L07-1316-T01-A 1 1.68E+03
CFS-L07-1316-T02-A 1 1.76E+03
CFS-L07-1316-T03-A 1 3.66E+03
CFS-L07-1316-T04-A 1 4.69E+03
CFS-L07-1316-T05-A 1 5.71 E+03
CFS-L07-1316-T01-B 1 1.71 E+03
CFS-L07-1316-T02-B 1 2.53E+03
CFS-L07-1316-T03-B 1 3.64E+03
CFS-L07-1316-T04-B 1 4.79E+03
CFS-L07-1316-T05-B 1 5.30E+02
CFS-L07-1316-T01-C 1 1.52E+03
CFS-L07-1316-T02-C 1 2.30E+03
CFS-L07-1316-T03-C 1 3.22E+03
CFS-L07-1316-T04-C 1 4.25E+03
CFS-L07-1316-T05-C 1 5.83E+03
CFS-L07-1316-B01-A 1 5.00E-01 U1/2
CFS-L07-1316-B02-A 1 5.00E-01 U1/2
CFS-L07-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.68E+03 4.3E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.76E+03 7.5E+01 1 .OE+00 3.2E+00 1000 100 2.74E+03 98% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
3.66E+03 1.3E+00 1 .OE+00 3.2E+00
4.69E+03 5.5E-01 1 .OE+00 3.2E+00
5.71 E+03 9.1E-01 1 .OE+00 3.2E+00
1.71 E+03 6.8E-01 1 .OE+00 3.2E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
2.53E+03 9.1E-01 1 .OE+00 3.2E+00 1000 100 3.54E+03 101% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
3.64E+03 3.5E-01 1 .OE+00 3.2E+00
4.79E+03 3.7E+00 1 .OE+00 3.2E+00
5.30E+02 2.3E+01 1 .OE+00 3.2E+00
1.52E+03 1.1E+00 1. OE+00 3.2E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
2.30E+03 1.7E+00 1 .OE+00 3.2E+00 1000 100 3.18E+03 88% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
3.22E+03 7.3E-01 1. OE+00 3.2E+00
4.25E+03 1. OE+00 1. OE+00 3.2E+00
5.83E+03 8.2E-01 1. OE+00 3.2E+00
5.00E-01 1.7E+01 1. OE+00 3.2E+00
5.00E-01 6.2E+01 1. OE+00 3.2E+00
5.00E-01 7.4E+01 1. OE+00 3.2E+00
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1709
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S CFS-L07-1316-T01-A 1 6.66E+05
S CFS-L07-1316-T02-A 1 4.33E+05
S CFS-L07-1316-T03-A 1 9.26E+05
S CFS-L07-1316-T04-A 1 1.20E+06
S CFS-L07-1316-T05-A 1 1.62E+06
S CFS-L07-1316-T01-B 1 6.57E+05
S CFS-L07-1316-T02-B 1 7.20E+05
S CFS-L07-1316-T03-B 1 9.01 E+05
S CFS-L07-1316-T04-B 1 1.22E+06
S CFS-L07-1316-T05-B 1 1.11E+05
S CFS-L07-1316-T01-C 1 6.61 E+05
S CFS-L07-1316-T02-C 1 7.28E+05
S CFS-L07-1316-T03-C 1 9.30E+05
S CFS-L07-1316-T04-C 1 1.23E+06
S CFS-L07-1316-T05-C 1 1.59E+06
S CFS-L07-1316-B01-A 1 3.40E+00 U1/2
S CFS-L07-1316-B02-A 1 3.40E+00 U1/2
S CFS-L07-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.66E+05 2.0E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
4.33E+05 7.7E+01 6.8E+00 2.2E+01 1000 100 4.34E+05 88% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
9.26E+05 6.2E-01 6.8E+00 2.2E+01
1.20E+06 4.5E-01 6.8E+00 2.2E+01
1.62E+06 5.5E-01 6.8E+00 2.2E+01
6.57E+05 8.7E-01 6.8E+00 2.2E+01
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
7.20E+05 9.8E-01 6.8E+00 2.2E+01 1000 100 7.21E+05 82% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
9.01 E+05 4.6E-01 6.8E+00 2.2E+01
1.22E+06 5.8E+00 6.8E+00 2.2E+01
1.11 E+05 1.6E+01 6.8E+00 2.2E+01
6.61 E+05 4.4E-01 6.8E+00 2.2E+01
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
7.28E+05 1.2E+00 6.8E+00 2.2E+01 1000 100 7.29E+05 90% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
9.30E+05 4.4E-01 6.8E+00 2.2E+01
1.23E+06 7.1E-01 6.8E+00 2.2E+01
1.59E+06 4.1E-01 6.8E+00 2.2E+01
3.40E+00 4.6E+01 6.8E+00 2.2E+01
3.40E+00 3.6E+01 6.8E+00 2.2E+01
3.40E+00 3.8E+01 6.8E+00 2.2E+01
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1710
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
ug/L
Tl CFS-L07-1316-T01-A 1 3.77E+02
Tl CFS-L07-1316-T02-A 1 3.47E+02
Tl CFS-L07-1316-T03-A 1 9.05E+02
Tl CFS-L07-1316-T04-A 1 1.20E+03
Tl CFS-L07-1316-T05-A 1 1.59E+03
Tl CFS-L07-1316-T01-B 1 3.72E+02
Tl CFS-L07-1316-T02-B 1 5.42E+02
Tl CFS-L07-1316-T03-B 1 8.67E+02
Tl CFS-L07-1316-T04-B 1 1.18E+03
Tl CFS-L07-1316-T05-B 1 9.82E+01
Tl CFS-L07-1316-T01-C 1 3.80E+02
Tl CFS-L07-1316-T02-C 1 5.71 E+02
Tl CFS-L07-1316-T03-C 1 9.02E+02
Tl CFS-L07-1316-T04-C 1 1.26E+03
Tl CFS-L07-1316-T05-C 1 1.54E+03
Tl CFS-L07-1316-B01-A 1 2.30E+00 U1/2
Tl CFS-L07-1316-B02-A 1 2.30E+00 U1/2
Tl CFS-L07-1316-B03-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.77E+02 1.7E+00 4.6E+00 1.5E+01
3.47E+02 7.9E+01 4.6E+00 1.5E+01 10 100
9.05E+02 2.5E+00 4.6E+00 1.5E+01
1.20E+03 8.0E-01 4.6E+00 1.5E+01
1.59E+03 3.4E-01 4.6E+00 1.5E+01
3.72E+02 1.8E+00 4.6E+00 1.5E+01
5.42E+02 2.5E-01 4.6E+00 1.5E+01 10 100
8.67E+02 3.2E-01 4.6E+00 1.5E+01
1.18E+03 5.8E+00 4.6E+00 1.5E+01
9.82E+01 2.5E+01 4.6E+00 1.5E+01
3.80E+02 1.6E+00 4.6E+00 1.5E+01
5.71E+02 2.3E+00 4.6E+00 1.5E+01 10 100
9.02E+02 2.0E+00 4.6E+00 1.5E+01
1.26E+03 8.2E-01 4.6E+00 1.5E+01
1.54E+03 5.8E-01 4.6E+00 1.5E+01
2.30E+00 9.1E+00 4.6E+00 1.5E+01
2.30E+00 6.5E+00 4.6E+00 1.5E+01
2.30E+00 1.3E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.31E+03 96%VUICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
1.53E+03 99% VUICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.53E+03 96% VUICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1711
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti CFS-L07-1316-T01-A 1 1.00E+OOU1/2
Ti CFS-L07-1316-T02-A 1 1.00E+OOU1/2
Ti CFS-L07-1316-T03-A 1 1.00E+OOU1/2
Ti CFS-L07-1316-T04-A 1 1.00E+OOU1/2
Ti CFS-L07-1316-T05-A 1 1.00E+OOU1/2
Ti CFS-L07-1316-T01-B 1 1.00E+OOU1/2
Ti CFS-L07-1316-T02-B 1 1.00E+OOU1/2
Ti CFS-L07-1316-T03-B 1 1.00E+OOU1/2
Ti CFS-L07-1316-T04-B 1 1.00E+OOU1/2
Ti CFS-L07-1316-T05-B 1 1.00E+OOU1/2
Ti CFS-L07-1316-T01-C 1 1.00E+OOU1/2
Ti CFS-L07-1316-T02-C 1 1.00E+OOU1/2
Ti CFS-L07-1316-T03-C 1 1.00E+OOU1/2
Ti CFS-L07-1316-T04-C 1 1.00E+OOU1/2
Ti CFS-L07-1316-T05-C 1 1.00E+OOU1/2
Ti CFS-L07-1316-B01-A 1 1.00E+OOU1/2
Ti CFS-L07-1316-B02-A 1 1.00E+OOU1/2
Ti CFS-L07-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.4E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 3.4E+02 2.0E+00 6.4E+00 10 100 9.80E+02 98% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 1.4E+03 2.0E+00 6.4E+00
1.00E+00 7.9E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+01 2.0E+00 6.4E+00
1.00E+00 9.5E+01 2.0E+00 6.4E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 1.1E+03 2.0E+00 6.4E+00 10 100 9.92E+02 99% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 2.9E+02 2.0E+00 6.4E+00
1.00E+00 7.4E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 3.1E+02 2.0E+00 6.4E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 4.9E+01 2.0E+00 6.4E+00 10 100 9.78E+02 98% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
1.00E+00 5.3E+01 2.0E+00 6.4E+00
1.00E+00 2.7E+02 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 3.2E+02 2.0E+00 6.4E+00
1.00E+00 3.1E+02 2.0E+00 6.4E+00
1.00E+00 2.3E+01 2.0E+00 6.4E+00
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1712
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V CFS-L07-1316-T01-A 1 3.57E+01
V CFS-L07-1316-T02-A 1 2.14E+01
V CFS-L07-1316-T03-A 1 3.10E+01
V CFS-L07-1316-T04-A 1 2.79E+01
V CFS-L07-1316-T05-A 1 2.69E+01
V CFS-L07-1316-T01-B 1 3.39E+01
V CFS-L07-1316-T02-B 1 3.35E+01
V CFS-L07-1316-T03-B 1 2.94E+01
V CFS-L07-1316-T04-B 1 3.04E+01
V CFS-L07-1316-T05-B 1 7.50E-01 U1/2
V CFS-L07-1316-T01-C 1 3.49E+01
V CFS-L07-1316-T02-C 1 3.18E+01
V CFS-L07-1316-T03-C 1 3.00E+01
V CFS-L07-1316-T04-C 1 2.92E+01
V CFS-L07-1316-T05-C 1 2.71E+01
V CFS-L07-1316-B01-A 1 7.50E-01 U1/2
V CFS-L07-1316-B02-A 1 7.50E-01 U1/2
V CFS-L07-1316-B03-A 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.57E+01 2.6E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
2.14E+01 7.4E+01 1 .5E+00 4.8E+00 10 100 9.72E+02 95% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
3.10E+01 3.4E+00 1 .5E+00 4.8E+00
2.79E+01 1.3E+00 1 .5E+00 4.8E+00
2.69E+01 3.1E+00 1 .5E+00 4.8E+00
3.39E+01 3.0E+00 1 .5E+00 4.8E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
3.35E+01 4.1E+00 1 .5E+00 4.8E+00 10 100 9.79E+02 95% VU ICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
2.94E+01 1.1E+00 1.5E+00 4.8E+00
3.04E+01 7.5E+00 1 .5E+00 4.8E+00
7.50E-01 4.5E+01 1 .5E+00 4.8E+00
3.49E+01 4.5E+00 1 .5E+00 4.8E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
3.18E+01 3.7E+00 1 .5E+00 4.8E+00 10 100 9.66E+02 93% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
3.00E+01 4.9E+00 1.5E+00 4.8E+00
2.92E+01 6.9E+00 1.5E+00 4.8E+00
2.71E+01 2.2E+00 1.5E+00 4.8E+00
7.50E-01 4.8E+02 1.5E+00 4.8E+00
7.50E-01 1.5E+02 1.5E+00 4.8E+00
7.50E-01 1.0E+02 1.5E+00 4.8E+00
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1713
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn CFS-L07-1316-T01-A 1 2.03E+04
Zn CFS-L07-1316-T02-A 1 2.01E+04
Zn CFS-L07-1316-T03-A 1 3.99E+04
Zn CFS-L07-1316-T04-A 1 4.33E+04
Zn CFS-L07-1316-T05-A 1 5.27E+04
Zn CFS-L07-1316-T01-B 1 1.88E+04
Zn CFS-L07-1316-T02-B 1 2.45E+04
Zn CFS-L07-1316-T03-B 1 3.60E+04
Zn CFS-L07-1316-T04-B 1 4.51 E+04
Zn CFS-L07-1316-T05-B 1 3.39E+03
Zn CFS-L07-1316-T01-C 1 2.11E+04
Zn CFS-L07-1316-T02-C 1 2.93E+04
Zn CFS-L07-1316-T03-C 1 4.14E+04
Zn CFS-L07-1316-T04-C 1 5.18E+04
Zn CFS-L07-1316-T05-C 1 4.35E+04
Zn CFS-L07-1316-B01-A 1 2.83E+00 E
Zn CFS-L07-1316-B02-A 1 1.78E+OOE
Zn CFS-L07-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.03E+04 1.1E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/18/11 4:41 PM EPA Interlab L07 1313-1316 CFS
2.01E+04 7.3E+01 1 .OE+00 3.2E+00 10 100 2.10E+04 90% VU ICP-OES 5/18/11 4:43 PM EPA Interlab L07 1313-1316 CFS
3.99E+04 7.4E-01 1 .OE+00 3.2E+00
4.33E+04 9.4E-01 1 .OE+00 3.2E+00
5.27E+04 6.6E-01 1 .OE+00 3.2E+00
1.88E+04 1.5E+00 1 .OE+00 3.2E+00
VU ICP-OES 5/18/11 4:45 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:46 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:48 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:50 PM EPA Interlab L07 1313-1316 CFS
2.45E+04 1.2E+00 1 .OE+00 3.2E+00 10 100 2.54E+04 91%VUICP-OES 5/18/11 4:51 PM EPA Interlab L07 1313-1316 CFS
3.60E+04 9.4E-01 1 .OE+00 3.2E+00
4.51 E+04 4.6E+00 1 .OE+00 3.2E+00
3.39E+03 2.5E+01 1 .OE+00 3.2E+00
2.11E+04 1.2E+00 1.0E+00 3.2E+00
VUICP-OES 5/18/11 4:53 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:54 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:56 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:58 PM EPA Interlab L07 1313-1316 CFS
2.93E+04 6.6E-01 1 .OE+00 3.2E+00 10 100 3.02E+04 86% VU ICP-OES 5/18/11 4:59 PM EPA Interlab L07 1313-1316 CFS
4.14E+04 1.9E-01 1. OE+00 3.2E+00
5.18E+04 8.5E-01 1. OE+00 3.2E+00
4.35E+04 2.9E-01 1. OE+00 3.2E+00
2.83E+00 5.3E+00 1. OE+00 3.2E+00
1.78E+00 1.6E+01 1. OE+00 3.2E+00
5.00E-01 2.0E+02 1. OE+00 3.2E+00
VUICP-OES 5/18/11 5:01 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:03 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 5:04 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:36 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:38 PM EPA Interlab L07 1313-1316 CFS
VUICP-OES 5/18/11 4:40 PM EPA Interlab L07 1313-1316 CFS
                                                                                                                                                                         1-1714
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al CFS-L09-1316-T01-A 1 5.07E+01
Al CFS-L09-1316-T02-A 1 4.83E+01
Al CFS-L09-1316-T03-A 1 5.26E+01
Al CFS-L09-1316-T04-A 1 5.67E+01
Al CFS-L09-1316-T05-A 1 6.00E+01
Al CFS-L09-1316-T01-B 1 5.38E+01
Al CFS-L09-1316-T02-B 1 5.00E+01
Al CFS-L09-1316-T03-B 1 5.35E+01
Al CFS-L09-1316-T04-B 1 6.05E+01
Al CFS-L09-1316-T05-B 1 5.88E+01
Al CFS-L09-1316-T01-C 1 5.09E+01
Al CFS-L09-1316-T02-C 1 5.14E+01
Al CFS-L09-1316-T03-C 1 5.99E+01
Al CFS-L09-1316-T04-C 1 5.98E+01
Al CFS-L09-1316-T05-C 1 6.24E+01
Al CFS-L09-1316-B01-A 1 2.97E+00 E
Al CFS-L09-1316-B02-A 1 5.00E-01 U1/2
Al CFS-L09-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.07E+01 8.2E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
4.83E+01 6.6E+00 1 .OE+00 3.2E+00 1000 100 1 .08E+03 103% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
5.26E+01 9.8E+00 1 .OE+00 3.2E+00
5.67E+01 6.1E+00 1 .OE+00 3.2E+00
6.00E+01 5.6E+00 1 .OE+00 3.2E+00
5.38E+01 5.3E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
5.00E+01 8.2E+00 1 .OE+00 3.2E+00 1000 100 1 .04E+03 99% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
5.35E+01 3.6E+00 1 .OE+00 3.2E+00
6.05E+01 5.4E+00 1 .OE+00 3.2E+00
5.88E+01 3.6E+00 1 .OE+00 3.2E+00
5.09E+01 9.5E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
5.14E+01 5.4E+00 1 .OE+00 3.2E+00 1000 100 1 .05E+03 100% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
5.99E+01 7.4E+00 1 .OE+00 3.2E+00
5.98E+01 8.0E+00 1 .OE+00 3.2E+00
6.24E+01 2.6E+00 1 .OE+00 3.2E+00
2.97E+00 4.6E+01 1 .OE+00 3.2E+00
5.00E-01 2.0E+02 1 .OE+00 3.2E+00
5.00E-01 5.5E+01 1 .OE+00 3.2E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                                  1-1715
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb CFS-L09-1316-T01-A 1 5.60E+01
Sb CFS-L09-1316-T02-A 1 3.45E+01
Sb CFS-L09-1316-T03-A 1 4.06E+01
Sb CFS-L09-1316-T04-A 1 5.48E+01
Sb CFS-L09-1316-T05-A 1 5.58E+01
Sb CFS-L09-1316-T01-B 1 2.87E+01
Sb CFS-L09-1316-T02-B 1 2.95E+01
Sb CFS-L09-1316-T03-B 1 4.38E+01
Sb CFS-L09-1316-T04-B 1 4.10E+01
Sb CFS-L09-1316-T05-B 1 5.60E+01
Sb CFS-L09-1316-T01-C 1 2.69E+01
Sb CFS-L09-1316-T02-C 1 3.90E+01
Sb CFS-L09-1316-T03-C 1 4.94E+01
Sb CFS-L09-1316-T04-C 1 5.39E+01
Sb CFS-L09-1316-T05-C 1 5.79E+01
Sb CFS-L09-1316-B01-A 1 3.75E+00 U1/2
Sb CFS-L09-1316-B02-A 1 3.75E+00 U1/2
Sb CFS-L09-1316-B03-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.60E+01 9.0E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
3.45E+01 1.3E+01 7.5E+00 2.4E+01 10 100 1.05E+03 102% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
4.06E+01 1.6E+01 7.5E+00 2.4E+01
5.48E+01 1.3E+01 7.5E+00 2.4E+01
5.58E+01 2.1E+01 7.5E+00 2.4E+01
2.87E+01 2.3E+01 7.5E+00 2.4E+01
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
2.95E+01 3.0E+01 7.5E+00 2.4E+01 10 100 1.06E+03 103% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
4.38E+01 1.4E+01 7.5E+00 2.4E+01
4.10E+01 7.7E+00 7.5E+00 2.4E+01
5.60E+01 1.3E+01 7.5E+00 2.4E+01
2.69E+01 5.5E+00 7.5E+00 2.4E+01
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
3.90E+01 3.0E+01 7.5E+00 2.4E+01 10 100 1.05E+03 101% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
4.94E+01 6.0E+00 7.5E+00 2.4E+01
5.39E+01 1.2E+01 7.5E+00 2.4E+01
5.79E+01 7.3E+00 7.5E+00 2.4E+01
3.75E+00 4.6E+00 7.5E+00 2.4E+01
3.75E+00 7.3E+01 7.5E+00 2.4E+01
3.75E+00 7.8E+01 7.5E+00 2.4E+01
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1716
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
ug/L
As CFS-L09-1316-T01-A 1 2.38E+01 E
As CFS-L09-1316-T02-A 1 2.58E+01 E
As CFS-L09-1316-T03-A 1 2.80E+01 E
As CFS-L09-1316-T04-A 1 3.89E+01
As CFS-L09-1316-T05-A 1 4.41 E+01
As CFS-L09-1316-T01-B 1 2.83E+01 E
As CFS-L09-1316-T02-B 1 1.99E+01 E
As CFS-L09-1316-T03-B 1 3.65E+01
As CFS-L09-1316-T04-B 1 4.16E+01
As CFS-L09-1316-T05-B 1 5.02E+01
As CFS-L09-1316-T01-C 1 1.85E+01 E
As CFS-L09-1316-T02-C 1 3.10E+01 E
As CFS-L09-1316-T03-C 1 3.27E+01 E
As CFS-L09-1316-T04-C 1 3.82E+01
As CFS-L09-1316-T05-C 1 4.25E+01
As CFS-L09-1316-B01-A 1 5.50E+00 U1/2
As CFS-L09-1316-B02-A 1 5.50E+00 U1/2
As CFS-L09-1316-B03-A 1 5.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.38E+01 9.8E+00 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
2.58E+01 4.6E+01 1.1E+01 3.5E+01 10 100 1 .04E+03 101% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
2.80E+01 3.3E+01 1.1E+01 3.5E+01
3.89E+01 2.1E+01 1.1E+01 3.5E+01
4.41E+01 6.1E+00 1.1E+01 3.5E+01
2.83E+01 2.2E+01 1.1E+01 3.5E+01
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.99E+01 2.6E+01 1.1E+01 3.5E+01 10 100 1 .05E+03 103% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
3.65E+01 1.5E+01 1.1 E+01 3.5E+01
4.16E+01 1.1E+01 1.1E+01 3.5E+01
5.02E+01 8.9E+00 1.1 E+01 3.5E+01
1.85E+01 5.8E+01 1.1 E+01 3.5E+01
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
3.10E+01 1.4E+01 1.1E+01 3.5E+01 10 100 1 .05E+03 101% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
3.27E+01 1.8E+01 1.1 E+01 3.5E+01
3.82E+01 2.6E+01 1.1E+01 3.5E+01
4.25E+01 2.5E+01 1.1E+01 3.5E+01
5.50E+00 2.7E+02 1.1 E+01 3.5E+01
5.50E+00 3.3E+01 1.1 E+01 3.5E+01
5.50E+00 1.1E+02 1.1 E+01 3.5E+01
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1717
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B CFS-L09-1316-T01-A 1 1.53E+02
B CFS-L09-1316-T02-A 1 2.71E+02
B CFS-L09-1316-T03-A 1 5.67E+02
B CFS-L09-1316-T04-A 1 9.00E+02
B CFS-L09-1316-T05-A 1 1.25E+03
B CFS-L09-1316-T01-B 1 1.65E+02
B CFS-L09-1316-T02-B 1 2.73E+02
B CFS-L09-1316-T03-B 1 5.57E+02
B CFS-L09-1316-T04-B 1 8.31 E+02
B CFS-L09-1316-T05-B 1 1.24E+03
B CFS-L09-1316-T01-C 1 1.66E+02
B CFS-L09-1316-T02-C 1 2.88E+02
B CFS-L09-1316-T03-C 1 5.81 E+02
B CFS-L09-1316-T04-C 1 8.90E+02
B CFS-L09-1316-T05-C 1 1.24E+03
B CFS-L09-1316-B01-A 1 5.00E-01 U1/2
B CFS-L09-1316-B02-A 1 5.00E-01 U1/2
B CFS-L09-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+02 6.8E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
2.71E+02 1.1E+00 1.0E+00 3.2E+00 1000 100 1 .29E+03 102% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
5.67E+02 1.3E+00 1 .OE+00 3.2E+00
9.00E+02 4.4E-01 1 .OE+00 3.2E+00
1.25E+03 3.5E-01 1 .OE+00 3.2E+00
1.65E+02 1.3E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
2.73E+02 2.8E-01 1 .OE+00 3.2E+00 1000 100 1.31E+03 104% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
5.57E+02 8.6E-01 1 .OE+00 3.2E+00
8.31 E+02 3.7E-01 1 .OE+00 3.2E+00
1.24E+03 2.7E-01 1 .OE+00 3.2E+00
1.66E+02 3.3E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
2.88E+02 2.8E-01 1 .OE+00 3.2E+00 1000 100 1.31E+03 102% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
5.81 E+02 6.6E-01 1. OE+00 3.2E+00
8.90E+02 2.7E-01 1. OE+00 3.2E+00
1.24E+03 2.0E-01 1. OE+00 3.2E+00
5.00E-01 5.9E+01 1. OE+00 3.2E+00
5.00E-01 5.8E+01 1. OE+00 3.2E+00
5.00E-01 2.4E+01 1. OE+00 3.2E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1718
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba CFS-L09-1316-T01-A 1 1.28E+02
Ba CFS-L09-1316-T02-A 1 1.14E+02
Ba CFS-L09-1316-T03-A 1 9.65E+01
Ba CFS-L09-1316-T04-A 1 8.19E+01
Ba CFS-L09-1316-T05-A 1 6.18E+01
Ba CFS-L09-1316-T01-B 1 1.28E+02
Ba CFS-L09-1316-T02-B 1 1.23E+02
Ba CFS-L09-1316-T03-B 1 1.00E+02
Ba CFS-L09-1316-T04-B 1 8.27E+01
Ba CFS-L09-1316-T05-B 1 6.29E+01
Ba CFS-L09-1316-T01-C 1 1.29E+02
Ba CFS-L09-1316-T02-C 1 1.20E+02
Ba CFS-L09-1316-T03-C 1 9.88E+01
Ba CFS-L09-1316-T04-C 1 8.20E+01
Ba CFS-L09-1316-T05-C 1 6.42E+01
Ba CFS-L09-1316-B01-A 1 5.00E-01 U1/2
Ba CFS-L09-1316-B02-A 1 5.00E-01 U1/2
Ba CFS-L09-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.28E+02 1.4E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.14E+02 6.1E-01 1.0E+00 3.2E+00 10 100 1.18E+03 107% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
9.65E+01 1.1E+00 1. OE+00 3.2E+00
8.19E+01 5.9E-01 1. OE+00 3.2E+00
6.18E+01 9.2E-01 1. OE+00 3.2E+00
1.28E+02 1.6E-01 1. OE+00 3.2E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.23E+02 7.8E-01 1.0E+00 3.2E+00 10 100 1.20E+03 108% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
1.00E+02 2.4E-01 1. OE+00 3.2E+00
8.27E+01 1.1E+00 1. OE+00 3.2E+00
6.29E+01 5.2E-02 1. OE+00 3.2E+00
1.29E+02 2.1E-01 1. OE+00 3.2E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.20E+02 7.1E-01 1.0E+00 3.2E+00 10 100 1.18E+03 106% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
9.88E+01 4.7E-01 1. OE+00 3.2E+00
8.20E+01 2.9E-01 1. OE+00 3.2E+00
6.42E+01 3.8E-01 1. OE+00 3.2E+00
5.00E-01 3.9E+01 1. OE+00 3.2E+00
5.00E-01 1.3E+01 1. OE+00 3.2E+00
5.00E-01 5.2E+01 1. OE+00 3.2E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1719
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be CFS-L09-1316-T01-A 1 9.50E-01 U1/2
Be CFS-L09-1316-T02-A 1 9.50E-01 U1/2
Be CFS-L09-1316-T03-A 1 9.50E-01 U1/2
Be CFS-L09-1316-T04-A 1 9.50E-01 U1/2
Be CFS-L09-1316-T05-A 1 9.50E-01 U1/2
Be CFS-L09-1316-T01-B 1 9.50E-01 U1/2
Be CFS-L09-1316-T02-B 1 9.50E-01 U1/2
Be CFS-L09-1316-T03-B 1 9.50E-01 U1/2
Be CFS-L09-1316-T04-B 1 9.50E-01 U1/2
Be CFS-L09-1316-T05-B 1 9.50E-01 U1/2
Be CFS-L09-1316-T01-C 1 9.50E-01 U1/2
Be CFS-L09-1316-T02-C 1 9.50E-01 U1/2
Be CFS-L09-1316-T03-C 1 9.50E-01 U1/2
Be CFS-L09-1316-T04-C 1 9.50E-01 U1/2
Be CFS-L09-1316-T05-C 1 9.50E-01 U1/2
Be CFS-L09-1316-B01-A 1 9.50E-01 U1/2
Be CFS-L09-1316-B02-A 1 9.50E-01 U1/2
Be CFS-L09-1316-B03-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.9E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
9.50E-01 1.8E+01 1.9E+00 6.0E+00 10 100 1.07E+03 107% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
9.50E-01 2.2E+01 1.9E+00 6.0E+00
9.50E-01 4.9E+01 1.9E+00 6.0E+00
9.50E-01 2.0E+01 1.9E+00 6.0E+00
9.50E-01 8.5E+01 1.9E+00 6.0E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
9.50E-01 4.9E+01 1.9E+00 6.0E+00 10 100 1.06E+03 106% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
9.50E-01 7.4E+01 1.9E+00 6.0E+00
9.50E-01 3.4E+01 1.9E+00 6.0E+00
9.50E-01 2.9E+01 1.9E+00 6.0E+00
9.50E-01 4.4E+01 1.9E+00 6.0E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
9.50E-01 7.1E+01 1.9E+00 6.0E+00 10 100 1.05E+03 105% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
9.50E-01 4.3E+01 1.9E+00 6.0E+00
9.50E-01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 4.9E+01 1.9E+00 6.0E+00
9.50E-01 3.8E+01 1.9E+00 6.0E+00
9.50E-01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 3.4E+01 1.9E+00 6.0E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/1 1 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/1 1 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1720
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd CFS-L09-1316-T01-A 1 4.46E+03
Cd CFS-L09-1316-T02-A 1 6.32E+03
Cd CFS-L09-1316-T03-A 1 9.03E+03
Cd CFS-L09-1316-T04-A 1 1.14E+04
Cd CFS-L09-1316-T05-A 1 1.31E+04
Cd CFS-L09-1316-T01-B 1 4.48E+03
Cd CFS-L09-1316-T02-B 1 6.12E+03
Cd CFS-L09-1316-T03-B 1 8.72E+03
Cd CFS-L09-1316-T04-B 1 1.03E+04
Cd CFS-L09-1316-T05-B 1 1.26E+04
Cd CFS-L09-1316-T01-C 1 4.39E+03
Cd CFS-L09-1316-T02-C 1 6.33E+03
Cd CFS-L09-1316-T03-C 1 8.95E+03
Cd CFS-L09-1316-T04-C 1 1.09E+04
Cd CFS-L09-1316-T05-C 1 1.28E+04
Cd CFS-L09-1316-B01-A 1 1.10E+OOU1/2
Cd CFS-L09-1316-B02-A 1 1.10E+OOU1/2
Cd CFS-L09-1316-B03-A 1 1.10E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.46E+03 9.1E-01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
6.32E+03 7.6E-01 2.2E+00 7.0E+00 10 100 7.20E+03 88% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
9.03E+03 1.2E+00 2.2E+00 7.0E+00
1.14E+04 2.8E-01 2.2E+00 1.0E+00
1.31E+04 5.1E-01 2.2E+00 1.0E+00
4.48E+03 4.6E-01 2.2E+00 1.0E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
6.12E+03 9.1E-01 2.2E+00 1.0E+00 10 100 7.08E+03 96% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
8.72E+03 2.2E-01 2.2E+00 1.0E+00
1.03E+04 9.9E-01 2.2E+00 1.0E+00
1.26E+04 1.5E+00 2.2E+00 1.0E+00
4.39E+03 4.0E-01 2.2E+00 1.0E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
6.33E+03 6.0E-01 2.2E+00 1.0E+00 10 100 7.27E+03 94% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
8.95E+03 2.3E-01 2.2E+00 1.0E+00
1.09E+04 3.6E-01 2.2E+00 1.0E+00
1.28E+04 1.1E+00 2.2E+00 1.0E+00
1.10E+00 7.5E+01 2.2E+00 1.0E+00
1.10E+00 6.4E+01 2.2E+00 7.0E+00
1.10E+00 1.0E+02 2.2E+00 7.0E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1721
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca CFS-L09-1316-T01-A 1 6.86E+05
Ca CFS-L09-1316-T02-A 1 6.61 E+05
Ca CFS-L09-1316-T03-A 1 6.14E+05
Ca CFS-L09-1316-T04-A 1 5.86E+05
Ca CFS-L09-1316-T05-A 1 5.25E+05
Ca CFS-L09-1316-T01-B 1 6.96E+05
Ca CFS-L09-1316-T02-B 1 6.69E+05
Ca CFS-L09-1316-T03-B 1 6.29E+05
Ca CFS-L09-1316-T04-B 1 5.87E+05
Ca CFS-L09-1316-T05-B 1 5.23E+05
Ca CFS-L09-1316-T01-C 1 6.80E+05
Ca CFS-L09-1316-T02-C 1 6.67E+05
Ca CFS-L09-1316-T03-C 1 6.30E+05
Ca CFS-L09-1316-T04-C 1 5.80E+05
Ca CFS-L09-1316-T05-C 1 5.38E+05
Ca CFS-L09-1316-B01-A 1 2.57E+01
Ca CFS-L09-1316-B02-A 1 3.20E+01
Ca CFS-L09-1316-B03-A 1 2.25E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.86E+05 1.3E+00 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
6.61E+05 8.5E-01 2.6E+00 8.3E+00 1000 100 6.62E+05 90% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
6.14E+05 1.4E+00 2.6E+00 8.3E+00
5.86E+05 4.0E-01 2.6E+00 8.3E+00
5.25E+05 6.1E-01 2.6E+00 8.3E+00
6.96E+05 2.4E-01 2.6E+00 8.3E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
6.69E+05 8.7E-01 2.6E+00 8.3E+00 1000 100 6.70E+05 87% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
6.29E+05 5.6E-01 2.6E+00 8.3E+00
5.87E+05 1.0E+00 2.6E+00 8.3E+00
5.23E+05 6.1E-01 2.6E+00 8.3E+00
6.80E+05 1.1E+00 2.6E+00 8.3E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
6.67E+05 5.3E-01 2.6E+00 8.3E+00 1000 100 6.68E+05 92% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
6.30E+05 3.4E-01 2.6E+00 8.3E+00
5.80E+05 4.5E-01 2.6E+00 8.3E+00
5.38E+05 1.5E-01 2.6E+00 8.3E+00
2.57E+01 8.4E+00 2.6E+00 8.3E+00
3.20E+01 6.7E+00 2.6E+00 8.3E+00
2.25E+01 5.1E+00 2.6E+00 8.3E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1722
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cr Sample Dilution Cone. Qualifier Revi
ug/L
Cr CFS-L09-1316-T01-A 1 6.00E-01 U1/2
Cr CFS-L09-1316-T02-A 1 6.00E-01 U1/2
Cr CFS-L09-1316-T03-A 1 6.00E-01 U1/2
Cr CFS-L09-1316-T04-A 1 6.00E-01 U1/2
Cr CFS-L09-1316-T05-A 1 6.00E-01 U1/2
Cr CFS-L09-1316-T01-B 1 6.00E-01 U1/2
Cr CFS-L09-1316-T02-B 1 6.00E-01 U1/2
Cr CFS-L09-1316-T03-B 1 6.00E-01 U1/2
Cr CFS-L09-1316-T04-B 1 6.00E-01 U1/2
Cr CFS-L09-1316-T05-B 1 6.00E-01 U1/2
Cr CFS-L09-1316-T01-C 1 6.00E-01 U1/2
Cr CFS-L09-1316-T02-C 1 6.00E-01 U1/2
Cr CFS-L09-1316-T03-C 1 6.00E-01 U1/2
Cr CFS-L09-1316-T04-C 1 6.00E-01 U1/2
Cr CFS-L09-1316-T05-C 1 6.00E-01 U1/2
Cr CFS-L09-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L09-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L09-1316-B01-A 1 6.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 7.9E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
6.00E-01 2.3E+01 1.2E+00 3.8E+00 10 100 1.02E+03 102% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
6.00E-01 7.7E+02 1.2E+00 3.8E+00
6.00E-01 5.4E+02 1.2E+00 3.8E+00
6.00E-01 8.3E+01 1.2E+00 3.8E+00
6.00E-01 2.4E+01 1.2E+00 3.8E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
6.00E-01 8.2E+02 1.2E+00 3.8E+00 10 100 1.04E+03 104% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
6.00E-01 6.1E+01 1.2E+00 3.8E+00
6.00E-01 5.5E+02 1.2E+00 3.8E+00
6.00E-01 8.1E+01 1.2E+00 3.8E+00
6.00E-01 1.3E+03 1.2E+00 3.8E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
6.00E-01 2.7E+01 1.2E+00 3.8E+00 10 100 1.02E+03 102% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
6.00E-01 2.9E+02 1.2E+00 3.8E+00
6.00E-01 1.2E+02 1.2E+00 3.8E+00
6.00E-01 3.0E+01 1.2E+00 3.8E+00
6.00E-01 6.6E+02 1.2E+00 3.8E+00
6.00E-01 1.0E+04 1.2E+00 3.8E+00
6.00E-01 8.6E+01 1.2E+00 3.8E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/1 1 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/1 1 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1723
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co CFS-L09-1316-T01-A 1 9.95E+01
Co CFS-L09-1316-T02-A 1 1.64E+02
Co CFS-L09-1316-T03-A 1 3.04E+02
Co CFS-L09-1316-T04-A 1 4.38E+02
Co CFS-L09-1316-T05-A 1 5.44E+02
Co CFS-L09-1316-T01-B 1 1.03E+02
Co CFS-L09-1316-T02-B 1 1.65E+02
Co CFS-L09-1316-T03-B 1 2.95E+02
Co CFS-L09-1316-T04-B 1 3.93E+02
Co CFS-L09-1316-T05-B 1 5.22E+02
Co CFS-L09-1316-T01-C 1 1.02E+02
Co CFS-L09-1316-T02-C 1 1.72E+02
Co CFS-L09-1316-T03-C 1 3.12E+02
Co CFS-L09-1316-T04-C 1 4.30E+02
Co CFS-L09-1316-T05-C 1 5.23E+02
Co CFS-L09-1316-B01-A 1 9.00E-01 U1/2
Co CFS-L09-1316-B02-A 1 9.00E-01 U1/2
Co CFS-L09-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.95E+01 3.6E-01 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.64E+02 1.1E+00 1.8E+00 5.7E+00 10 100 1.14E+03 98% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
3.04E+02 5.3E-01 1 .8E+00 5.7E+00
4.38E+02 3.0E-01 1 .8E+00 5.7E+00
5.44E+02 9.5E-02 1 .8E+00 5.7E+00
1.03E+02 1.2E+00 1.8E+00 5.7E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.65E+02 6.2E-01 1.8E+00 5.7E+00 10 100 1.16E+03 100% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
2.95E+02 4.6E-01 1.8E+00 5.7E+00
3.93E+02 1.2E+00 1.8E+00 5.7E+00
5.22E+02 1.4E-01 1.8E+00 5.7E+00
1.02E+02 5.8E-01 1.8E+00 5.7E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.72E+02 1.3E+00 1.8E+00 5.7E+00 10 100 1.15E+03 98% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
3.12E+02 4.2E-01 1.8E+00 5.7E+00
4.30E+02 4.7E-01 1.8E+00 5.7E+00
5.23E+02 4.3E-01 1.8E+00 5.7E+00
9.00E-01 2.0E+02 1.8E+00 5.7E+00
9.00E-01 4.2E+02 1.8E+00 5.7E+00
9.00E-01 1.8E+02 1.8E+00 5.7E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1724
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu CFS-L09-1316-T01-A 1 7.67E+02
Cu CFS-L09-1316-T02-A 1 1.01E+03
Cu CFS-L09-1316-T03-A 1 1.48E+03
Cu CFS-L09-1316-T04-A 1 2.24E+03
Cu CFS-L09-1316-T05-A 1 3.00E+03
Cu CFS-L09-1316-T01-B 1 7.56E+02
Cu CFS-L09-1316-T02-B 1 9.67E+02
Cu CFS-L09-1316-T03-B 1 1.46E+03
Cu CFS-L09-1316-T04-B 1 2.18E+03
Cu CFS-L09-1316-T05-B 1 2.86E+03
Cu CFS-L09-1316-T01-C 1 7.50E+02
Cu CFS-L09-1316-T02-C 1 1.09E+03
Cu CFS-L09-1316-T03-C 1 1.55E+03
Cu CFS-L09-1316-T04-C 1 2.28E+03
Cu CFS-L09-1316-T05-C 1 2.90E+03
Cu CFS-L09-1316-B01-A 1 1.85E+OOU1/2
Cu CFS-L09-1316-B02-A 1 1.85E+OOU1/2
Cu CFS-L09-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.67E+02 1.7E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.01E+03 5.5E-01 3.7E+00 1.2E+01 10 100 1.97E+03 95% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
1.48E+03 2.1E+00 3.7E+00 1.2E+01
2.24E+03 9.1E-01 3.7E+00 1.2E+01
3.00E+03 1.3E+00 3.7E+00 1.2E+01
7.56E+02 6.0E-01 3.7E+00 1.2E+01
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
9.67E+02 5.9E-01 3.7E+00 1.2E+01 10 100 1.95E+03 98% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
1.46E+03 1.0E+00 3.7E+00 1.2E+01
2.18E+03 1.6E+00 3.7E+00 1.2E+01
2.86E+03 3.3E-01 3.7E+00 1.2E+01
7.50E+02 4.7E-01 3.7E+00 1.2E+01
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.09E+03 8.7E-01 3.7E+00 1.2E+01 10 100 2.02E+03 93% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
1.55E+03 3.0E-01 3.7E+00 1.2E+01
2.28E+03 6.6E-01 3.7E+00 1.2E+01
2.90E+03 1.3E+00 3.7E+00 1.2E+01
1.85E+00 2.5E+01 3.7E+00 1.2E+01
1.85E+00 9.3E+01 3.7E+00 1.2E+01
1.85E+00 5.4E+02 3.7E+00 1.2E+01
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1725
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe CFS-L09-1316-T01-A 1 1.00E+OOU1/2
Fe CFS-L09-1316-T02-A 1 1.00E+OOU1/2
Fe CFS-L09-1316-T03-A 1 1.00E+OOU1/2
Fe CFS-L09-1316-T04-A 1 1.00E+OOU1/2
Fe CFS-L09-1316-T05-A 1 2.49E+00 E
Fe CFS-L09-1316-T01-B 1 1.00E+OOU1/2
Fe CFS-L09-1316-T02-B 1 1.00E+OOU1/2
Fe CFS-L09-1316-T03-B 1 1.00E+OOU1/2
Fe CFS-L09-1316-T04-B 1 1.00E+OOU1/2
Fe CFS-L09-1316-T05-B 1 2.36E+00 E
Fe CFS-L09-1316-T01-C 1 2.58E+00 E
Fe CFS-L09-1316-T02-C 1 1.00E+OOU1/2
Fe CFS-L09-1316-T03-C 1 3.06E+00 E
Fe CFS-L09-1316-T04-C 1 3.33E+00 E
Fe CFS-L09-1316-T05-C 1 2.14E+00 E
Fe CFS-L09-1316-B01-A 1 1.00E+OOU1/2
Fe CFS-L09-1316-B02-A 1 1.00E+OOU1/2
Fe CFS-L09-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.7E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 4.7E+01 2.0E+00 6.4E+00 1000 100 1 .05E+03 105% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+01 2.0E+00 6.4E+00
2.49E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 2.6E+01 2.0E+00 6.4E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 5.6E+01 2.0E+00 6.4E+00 1000 100 1.07E+03 107% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00
2.36E+00 2.6E+01 2.0E+00 6.4E+00
2.58E+00 1.2E+01 2.0E+00 6.4E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 3.3E+01 2.0E+00 6.4E+00 1000 100 1.05E+03 105% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
3.06E+00 1.8E+01 2.0E+00 6.4E+00
3.33E+00 8.6E+00 2.0E+00 6.4E+00
2.14E+00 1.9E+01 2.0E+00 6.4E+00
1.00E+00 1.8E+01 2.0E+00 6.4E+00
1.00E+00 7.6E+01 2.0E+00 6.4E+00
1.00E+00 8.0E+01 2.0E+00 6.4E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1726
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb CFS-L09-1316-T01-A 1 1.22E+03
Pb CFS-L09-1316-T02-A 1 1.30E+03
Pb CFS-L09-1316-T03-A 1 1.41E+03
Pb CFS-L09-1316-T04-A 1 1.50E+03
Pb CFS-L09-1316-T05-A 1 1.47E+03
Pb CFS-L09-1316-T01-B 1 1.24E+03
Pb CFS-L09-1316-T02-B 1 1.35E+03
Pb CFS-L09-1316-T03-B 1 1.46E+03
Pb CFS-L09-1316-T04-B 1 1.48E+03
Pb CFS-L09-1316-T05-B 1 1.46E+03
Pb CFS-L09-1316-T01-C 1 1.29E+03
Pb CFS-L09-1316-T02-C 1 1.35E+03
Pb CFS-L09-1316-T03-C 1 1.48E+03
Pb CFS-L09-1316-T04-C 1 1.48E+03
Pb CFS-L09-1316-T05-C 1 1.47E+03
Pb CFS-L09-1316-B01-A 1 3.40E+00 U1/2
Pb CFS-L09-1316-B02-A 1 3.40E+00 U1/2
Pb CFS-L09-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.22E+03 1.2E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.30E+03 1.1E+00 6.8E+00 2.2E+01 10 100 2.24E+03 94% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
1.41E+03 8.1E-01 6.8E+00 2.2E+01
1.50E+03 3.7E-01 6.8E+00 2.2E+01
1.47E+03 7.5E-01 6.8E+00 2.2E+01
1.24E+03 3.5E-01 6.8E+00 2.2E+01
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.35E+03 1.3E+00 6.8E+00 2.2E+01 10 100 2.27E+03 93% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
1.46E+03 6.7E-02 6.8E+00 2.2E+01
1.48E+03 6.0E-01 6.8E+00 2.2E+01
1.46E+03 2.0E-01 6.8E+00 2.2E+01
1.29E+03 3.6E-01 6.8E+00 2.2E+01
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.35E+03 8.7E-01 6.8E+00 2.2E+01 10 100 2.29E+03 94% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
1.48E+03 6.1E-01 6.8E+00 2.2E+01
1.48E+03 2.2E-01 6.8E+00 2.2E+01
1.47E+03 2.5E-01 6.8E+00 2.2E+01
3.40E+00 2.6E+01 6.8E+00 2.2E+01
3.40E+00 1.9E+02 6.8E+00 2.2E+01
3.40E+00 1.2E+02 6.8E+00 2.2E+01
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1727
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li CFS-L09-1316-T01-A 1 9.52E+00
Li CFS-L09-1316-T02-A 1 7.06E+00
Li CFS-L09-1316-T03-A 1 5.11E+OOE
Li CFS-L09-1316-T04-A 1 6.98E+00
Li CFS-L09-1316-T05-A 1 1.78E+01
Li CFS-L09-1316-T01-B 1 9.52E+00
Li CFS-L09-1316-T02-B 1 8.93E+00
Li CFS-L09-1316-T03-B 1 6.23E+00
Li CFS-L09-1316-T04-B 1 5.22E+00 E
Li CFS-L09-1316-T05-B 1 1.35E+01
Li CFS-L09-1316-T01-C 1 1.07E+01
Li CFS-L09-1316-T02-C 1 6.55E+00
Li CFS-L09-1316-T03-C 1 4.57E+00 E
Li CFS-L09-1316-T04-C 1 4.64E+00 E
Li CFS-L09-1316-T05-C 1 1.28E+01
Li CFS-L09-1316-B01-A 1 9.50E-01 U1/2
Li CFS-L09-1316-B02-A 1 9.50E-01 U1/2
Li CFS-L09-1316-B03-A 1 9.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.52E+00 1.3E+01 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
7.06E+00 2.8E+01 1 .9E+00 6.0E+00 10 100 8.71E+02 86% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
5.11E+00 3.7E+01 1.9E+00 6.0E+00
6.98E+00 3.8E+01 1 .9E+00 6.0E+00
1.78E+01 5.0E+00 1 .9E+00 6.0E+00
9.52E+00 4.1E+01 1.9E+00 6.0E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
8.93E+00 2.5E+01 1.9E+00 6.0E+00 10 100 8.70E+02 86% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
6.23E+00 2.6E+01 1.9E+00 6.0E+00
5.22E+00 5.6E+01 1.9E+00 6.0E+00
1.35E+01 8.0E+00 1.9E+00 6.0E+00
1.07E+01 1.4E+01 1.9E+00 6.0E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
6.55E+00 3.5E+01 1.9E+00 6.0E+00 10 100 8.40E+02 83% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
4.57E+00 3.4E+01 1.9E+00 6.0E+00
4.64E+00 2.0E+01 1.9E+00 6.0E+00
1.28E+01 1.7E+01 1.9E+00 6.0E+00
9.50E-01 3.4E+02 1.9E+00 6.0E+00
9.50E-01 8.2E+01 1.9E+00 6.0E+00
9.50E-01 7.2E+02 1.9E+00 6.0E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1728
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn CFS-L09-1316-T01-A 1 1.57E+03
Mn CFS-L09-1316-T02-A 1 2.87E+03
Mn CFS-L09-1316-T03-A 1 6.00E+03
Mn CFS-L09-1316-T04-A 1 9.56E+03
Mn CFS-L09-1316-T05-A 1 1.26E+04
Mn CFS-L09-1316-T01-B 1 1.70E+03
Mn CFS-L09-1316-T02-B 1 2.90E+03
Mn CFS-L09-1316-T03-B 1 5.85E+03
Mn CFS-L09-1316-T04-B 1 8.59E+03
Mn CFS-L09-1316-T05-B 1 1.20E+04
Mn CFS-L09-1316-T01-C 1 1.67E+03
Mn CFS-L09-1316-T02-C 1 2.98E+03
Mn CFS-L09-1316-T03-C 1 6.25E+03
Mn CFS-L09-1316-T04-C 1 9.36E+03
Mn CFS-L09-1316-T05-C 1 1.21E+04
Mn CFS-L09-1316-B01-A 1 1.00E+OOU1/2
Mn CFS-L09-1316-B02-A 1 1.00E+OOU1/2
Mn CFS-L09-1316-B03-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.57E+03 1.2E+00 2.0E+00 6.4E+00
2.87E+03 1.0E+00 2.0E+00 6.4E+00 10 100
6.00E+03 2.3E+00 2.0E+00 6.4E+00
9.56E+03 1.2E+00 2.0E+00 6.4E+00
1.26E+04 1.0E+00 2.0E+00 6.4E+00
1.70E+03 1.3E+00 2.0E+00 6.4E+00
2.90E+03 9.6E-01 2.0E+00 6.4E+00 10 100
5.85E+03 4.8E-01 2.0E+00 6.4E+00
8.59E+03 1.4E+00 2.0E+00 6.4E+00
1.20E+04 6.9E-01 2.0E+00 6.4E+00
1.67E+03 2.9E-01 2.0E+00 6.4E+00
2.98E+03 1.3E+00 2.0E+00 6.4E+00 10 100
6.25E+03 4.6E-01 2.0E+00 6.4E+00
9.36E+03 5.5E-01 2.0E+00 6.4E+00
1.21E+04 2.0E-01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 8.9E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
3.76E+03 89% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
3.81E+03 91% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
3.85E+03 87% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1729
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg CFS-L09-1316-T01-A 1 6.57E+04
Mg CFS-L09-1316-T02-A 1 1.23E+05
Mg CFS-L09-1316-T03-A 1 2.92E+05
Mg CFS-L09-1316-T04-A 1 5.17E+05
Mg CFS-L09-1316-T05-A 1 8.38E+05
Mg CFS-L09-1316-T01-B 1 6.99E+04
Mg CFS-L09-1316-T02-B 1 1.28E+05
Mg CFS-L09-1316-T03-B 1 2.91E+05
Mg CFS-L09-1316-T04-B 1 4.82E+05
Mg CFS-L09-1316-T05-B 1 8.25E+05
Mg CFS-L09-1316-T01-C 1 7.22E+04
Mg CFS-L09-1316-T02-C 1 1.32E+05
Mg CFS-L09-1316-T03-C 1 3.03E+05
Mg CFS-L09-1316-T04-C 1 5.13E+05
Mg CFS-L09-1316-T05-C 1 8.41 E+05
Mg CFS-L09-1316-B01-A 1 5.00E-01 U1/2
Mg CFS-L09-1316-B02-A 1 5.00E-01 U1/2
Mg CFS-L09-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.57E+04 1.0E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.23E+05 1.2E+00 1 .OE+00 3.2E+00 1000 100 1.24E+05 85% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
2.92E+05 1.5E+00 1. OE+00 3.2E+00
5.17E+05 8.2E-01 1. OE+00 3.2E+00
8.38E+05 1.4E+00 1. OE+00 3.2E+00
6.99E+04 1.5E+00 1. OE+00 3.2E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.28E+05 3.7E-01 1.0E+00 3.2E+00 1000 100 1.29E+05 87% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
2.91 E+05 6.1E-01 1. OE+00 3.2E+00
4.82E+05 2.1E+00 1. OE+00 3.2E+00
8.25E+05 6.0E-01 1. OE+00 3.2E+00
7.22E+04 6.6E-01 1. OE+00 3.2E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.32E+05 8.8E-01 1.0E+00 3.2E+00 1000 100 1.33E+05 92% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
3.03E+05 9.3E-01 1. OE+00 3.2E+00
5.13E+05 7.7E-01 1. OE+00 3.2E+00
8.41 E+05 2.4E-01 1. OE+00 3.2E+00
5.00E-01 1.1E+03 1. OE+00 3.2E+00
5.00E-01 3.5E+01 1. OE+00 3.2E+00
5.00E-01 2.1E+02 1. OE+00 3.2E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1730
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo CFS-L09-1316-T01-A 1 1.06E+01
Mo CFS-L09-1316-T02-A 1 1.26E+01
Mo CFS-L09-1316-T03-A 1 1.25E+01
Mo CFS-L09-1316-T04-A 1 1.65E+01
Mo CFS-L09-1316-T05-A 1 1.81E+01
Mo CFS-L09-1316-T01-B 1 8.36E+00
Mo CFS-L09-1316-T02-B 1 1.24E+01
Mo CFS-L09-1316-T03-B 1 1.47E+01
Mo CFS-L09-1316-T04-B 1 1.58E+01
Mo CFS-L09-1316-T05-B 1 1.81E+01
Mo CFS-L09-1316-T01-C 1 9.77E+00
Mo CFS-L09-1316-T02-C 1 1.22E+01
Mo CFS-L09-1316-T03-C 1 1.28E+01
Mo CFS-L09-1316-T04-C 1 1.65E+01
Mo CFS-L09-1316-T05-C 1 1.81E+01
Mo CFS-L09-1316-B01-A 1 6.00E-01 U1/2
Mo CFS-L09-1316-B02-A 1 2.24E+00 E
Mo CFS-L09-1316-B03-A 1 1.46E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+01 1.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.26E+01 1.5E+01 1.2E+00 3.8E+00 10 100 1.00E+03 99% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
1.25E+01 3.8E+00 1.2E+00 3.8E+00
1.65E+01 7.5E+00 1.2E+00 3.8E+00
1.81E+01 1.0E+01 1.2E+00 3.8E+00
8.36E+00 2.0E+01 1.2E+00 3.8E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.24E+01 1.2E+01 1.2E+00 3.8E+00 10 100 1.02E+03 101% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
1.47E+01 7.8E+00 1.2E+00 3.8E+00
1.58E+01 1.1E+01 1.2E+00 3.8E+00
1.81E+01 1.7E+00 1.2E+00 3.8E+00
9.77E+00 1.5E+01 1.2E+00 3.8E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.22E+01 2.9E+00 1.2E+00 3.8E+00 10 100 1.01E+03 99% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
1.28E+01 1.0E+01 1.2E+00 3.8E+00
1.65E+01 1.9E+01 1.2E+00 3.8E+00
1.81E+01 5.1E+00 1.2E+00 3.8E+00
6.00E-01 1.4E+02 1.2E+00 3.8E+00
2.24E+00 5.6E+02 1.2E+00 3.8E+00
1.46E+00 3.8E+01 1.2E+00 3.8E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1731
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni CFS-L09-1316-T01-A 1 2.15E+02
Ni CFS-L09-1316-T02-A 1 3.29E+02
Ni CFS-L09-1316-T03-A 1 5.60E+02
Ni CFS-L09-1316-T04-A 1 7.57E+02
Ni CFS-L09-1316-T05-A 1 9.20E+02
Ni CFS-L09-1316-T01-B 1 2.16E+02
Ni CFS-L09-1316-T02-B 1 3.31 E+02
Ni CFS-L09-1316-T03-B 1 5.42E+02
Ni CFS-L09-1316-T04-B 1 6.83E+02
Ni CFS-L09-1316-T05-B 1 8.78E+02
Ni CFS-L09-1316-T01-C 1 2.14E+02
Ni CFS-L09-1316-T02-C 1 3.46E+02
Ni CFS-L09-1316-T03-C 1 5.70E+02
Ni CFS-L09-1316-T04-C 1 7.38E+02
Ni CFS-L09-1316-T05-C 1 8.82E+02
Ni CFS-L09-1316-B01-A 1 9.00E-01 U1/2
Ni CFS-L09-1316-B02-A 1 9.00E-01 U1/2
Ni CFS-L09-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.15E+02 1.5E+00 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
3.29E+02 1.3E+00 1 .8E+00 5.7E+00 10 100 1.30E+03 97% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
5.60E+02 1.8E+00 1 .8E+00 5.7E+00
7.57E+02 5.8E-01 1 .8E+00 5.7E+00
9.20E+02 3.6E-01 1 .8E+00 5.7E+00
2.16E+02 1.4E+00 1.8E+00 5.7E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
3.31E+02 1.1E+00 1.8E+00 5.7E+00 10 100 1.31E+03 98% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
5.42E+02 1.0E+00 1.8E+00 5.7E+00
6.83E+02 1.1E+00 1.8E+00 5.7E+00
8.78E+02 1.2E-01 1.8E+00 5.7E+00
2.14E+02 1.2E+00 1.8E+00 5.7E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
3.46E+02 4.0E-01 1.8E+00 5.7E+00 10 100 1.32E+03 97% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
5.70E+02 2.7E-01 1.8E+00 5.7E+00
7.38E+02 2.4E-01 1.8E+00 5.7E+00
8.82E+02 6.1E-01 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
9.00E-01 5.4E+02 1.8E+00 5.7E+00
9.00E-01 5.6E+01 1.8E+00 5.7E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1732
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P CFS-L09-1316-T01-A 1 7.08E+00 E
P CFS-L09-1316-T02-A 1 8.40E+00 E
P CFS-L09-1316-T03-A 1 2.08E+01
P CFS-L09-1316-T04-A 1 2.35E+01
P CFS-L09-1316-T05-A 1 2.08E+01
P CFS-L09-1316-T01-B 1 1.29E+01
P CFS-L09-1316-T02-B 1 8.29E+00 E
P CFS-L09-1316-T03-B 1 1.45E+01
P CFS-L09-1316-T04-B 1 2.85E+01
P CFS-L09-1316-T05-B 1 3.22E+01
P CFS-L09-1316-T01-C 1 7.09E+00 E
P CFS-L09-1316-T02-C 1 1.30E+01
P CFS-L09-1316-T03-C 1 1.49E+01
P CFS-L09-1316-T04-C 1 3.27E+01
P CFS-L09-1316-T05-C 1 3.59E+01
P CFS-L09-1316-B01-A 1 1.02E+01 E
P CFS-L09-1316-B02-A 1 1.85E+OOU1/2
P CFS-L09-1316-B03-A 1 1.18E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.08E+00 1.5E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
8.40E+00 7.4E+01 3.7E+00 1.2E+01 1000 100 1 .04E+03 103% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
2.08E+01 1.9E+01 3.7E+00 1.2E+01
2.35E+01 2.1E+01 3.7E+00 1.2E+01
2.08E+01 8.6E+01 3.7E+00 1.2E+01
1.29E+01 6.7E+01 3.7E+00 1.2E+01
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
8.29E+00 3.1E+02 3.7E+00 1.2E+01 1000 100 1 .07E+03 106% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
1.45E+01 3.2E+01 3.7E+00 1.2E+01
2.85E+01 3.6E+01 3.7E+00 1.2E+01
3.22E+01 1.9E+01 3.7E+00 1.2E+01
7.09E+00 2.0E+02 3.7E+00 1.2E+01
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.30E+01 4.4E+01 3.7E+00 1.2E+01 1000 100 1 .05E+03 104% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
1.49E+01 3.1E+01 3.7E+00 1.2E+01
3.27E+01 3.8E+01 3.7E+00 1.2E+01
3.59E+01 8.2E+00 3.7E+00 1.2E+01
1.02E+01 3.7E+01 3.7E+00 1.2E+01
1.85E+00 1.5E+03 3.7E+00 1.2E+01
1.18E+01 4.3E+01 3.7E+00 1.2E+01
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1733
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K CFS-L09-1316-T01-A 1 9.24E+03
K CFS-L09-1316-T02-A 1 1.63E+04
K CFS-L09-1316-T03-A 1 3.11E+04
K CFS-L09-1316-T04-A 1 4.93E+04
K CFS-L09-1316-T05-A 1 6.80E+04
K CFS-L09-1316-T01-B 1 9.69E+03
K CFS-L09-1316-T02-B 1 1.63E+04
K CFS-L09-1316-T03-B 1 3.28E+04
K CFS-L09-1316-T04-B 1 4.66E+04
K CFS-L09-1316-T05-B 1 6.80E+04
K CFS-L09-1316-T01-C 1 9.70E+03
K CFS-L09-1316-T02-C 1 1.67E+04
K CFS-L09-1316-T03-C 1 3.27E+04
K CFS-L09-1316-T04-C 1 4.88E+04
K CFS-L09-1316-T05-C 1 6.94E+04
K CFS-L09-1316-B01-A 1 2.64E+01
K CFS-L09-1316-B02-A 1 2.59E+01
K CFS-L09-1316-B03-A 1 2.57E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.24E+03 8.8E-01 1 .6E+00 5.1E+00
1.63E+04 7.7E-01 1 .6E+00 5.1E+00 1000 100
3.11E+04 1.6E+00 1.6E+00 5.1E+00
4.93E+04 6.1E-01 1 .6E+00 5.1E+00
6.80E+04 2.8E-01 1 .6E+00 5.1E+00
9.69E+03 5.7E-01 1 .6E+00 5.1E+00
1.63E+04 7.6E-01 1 .6E+00 5.1E+00 1000 100
3.28E+04 6.2E-01 1 .6E+00 5.1E+00
4.66E+04 1.2E+00 1 .6E+00 5.1E+00
6.80E+04 2.4E-01 1 .6E+00 5.1E+00
9.70E+03 4.7E-01 1 .6E+00 5.1E+00
1.67E+04 4.5E-01 1 .6E+00 5.1E+00 1000 100
3.27E+04 9.4E-01 1.6E+00 5.1E+00
4.88E+04 2.4E-01 1.6E+00 5.1E+00
6.94E+04 3.6E-01 1.6E+00 5.1E+00
2.64E+01 5.5E+00 1.6E+00 5.1E+00
2.59E+01 9.8E+00 1.6E+00 5.1E+00
2.57E+01 8.6E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.72E+04 90%VUICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.72E+04 93%VUICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.76E+04 89% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1734
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se CFS-L09-1316-T01-A 1 7.89E+01
Se CFS-L09-1316-T02-A 1 1.49E+02
Se CFS-L09-1316-T03-A 1 2.79E+02
Se CFS-L09-1316-T04-A 1 4.77E+02
Se CFS-L09-1316-T05-A 1 7.63E+02
Se CFS-L09-1316-T01-B 1 9.58E+01
Se CFS-L09-1316-T02-B 1 1.38E+02
Se CFS-L09-1316-T03-B 1 2.82E+02
Se CFS-L09-1316-T04-B 1 4.38E+02
Se CFS-L09-1316-T05-B 1 7.62E+02
Se CFS-L09-1316-T01-C 1 8.57E+01
Se CFS-L09-1316-T02-C 1 1.48E+02
Se CFS-L09-1316-T03-C 1 2.85E+02
Se CFS-L09-1316-T04-C 1 4.82E+02
Se CFS-L09-1316-T05-C 1 7.64E+02
Se CFS-L09-1316-B01-A 1 7.50E+00 U1/2
Se CFS-L09-1316-B02-A 1 7.50E+00 U1/2
Se CFS-L09-1316-B03-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.89E+01 4.0E+00 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.49E+02 7.8E+00 1 .5E+01 4.8E+01 10 100 1.16E+03 101% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
2.79E+02 4.6E+00 1.5E+01 4.8E+01
4.77E+02 2.4E+00 1.5E+01 4.8E+01
7.63E+02 4.7E-01 1.5E+01 4.8E+01
9.58E+01 1.3E+01 1.5E+01 4.8E+01
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.38E+02 9.3E+00 1.5E+01 4.8E+01 10 100 1.15E+03 101% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
2.82E+02 6.5E+00 1.5E+01 4.8E+01
4.38E+02 3.3E+00 1.5E+01 4.8E+01
7.62E+02 9.7E-01 1.5E+01 4.8E+01
8.57E+01 1.7E+01 1.5E+01 4.8E+01
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.48E+02 7.0E+00 1.5E+01 4.8E+01 10 100 1.14E+03 100% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
2.85E+02 3.0E+00 1.5E+01 4.8E+01
4.82E+02 4.2E+00 1.5E+01 4.8E+01
7.64E+02 2.3E+00 1.5E+01 4.8E+01
7.50E+00 8.3E+01 1.5E+01 4.8E+01
7.50E+00 9.5E+01 1.5E+01 4.8E+01
7.50E+00 1.1E+02 1.5E+01 4.8E+01
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1735
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si CFS-L09-1316-T01-A 1 3.58E+03
Si CFS-L09-1316-T02-A 1 4.62E+03
Si CFS-L09-1316-T03-A 1 5.78E+03
Si CFS-L09-1316-T04-A 1 6.29E+03
Si CFS-L09-1316-T05-A 1 6.37E+03
Si CFS-L09-1316-T01-B 1 3.74E+03
Si CFS-L09-1316-T02-B 1 4.73E+03
Si CFS-L09-1316-T03-B 1 5.89E+03
Si CFS-L09-1316-T04-B 1 6.10E+03
Si CFS-L09-1316-T05-B 1 6.43E+03
Si CFS-L09-1316-T01-C 1 3.58E+03
Si CFS-L09-1316-T02-C 1 4.90E+03
Si CFS-L09-1316-T03-C 1 6.09E+03
Si CFS-L09-1316-T04-C 1 6.26E+03
Si CFS-L09-1316-T05-C 1 6.48E+03
Si CFS-L09-1316-B01-A 1 5.50E-01 U1/2
Si CFS-L09-1316-B02-A 1 5.50E-01 U1/2
Si CFS-L09-1316-B03-A 1 5.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.58E+03 2.2E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
4.62E+03 1.6E+00 1.1E+00 3.5E+00 1000 100 5.58E+03 97% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
5.78E+03 1.5E+00 1.1E+00 3.5E+00
6.29E+03 5.1E-01 1.1E+00 3.5E+00
6.37E+03 3.6E-01 1.1E+00 3.5E+00
3.74E+03 1.1E+00 1.1E+00 3.5E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
4.73E+03 1.4E+00 1.1E+00 3.5E+00 1000 100 5.61E+03 88% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
5.89E+03 6.0E-01 1.1E+00 3.5E+00
6.10E+03 6.2E-01 1.1E+00 3.5E+00
6.43E+03 1.6E-01 1.1E+00 3.5E+00
3.58E+03 4.3E-01 1.1E+00 3.5E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
4.90E+03 9.9E-01 1.1E+00 3.5E+00 1000 100 5.75E+03 85% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
6.09E+03 2.5E-01 1.1E+00 3.5E+00
6.26E+03 2.9E-01 1.1E+00 3.5E+00
6.48E+03 2.1E-01 1.1E+00 3.5E+00
5.50E-01 3.1E+01 1.1E+00 3.5E+00
5.50E-01 7.6E+01 1.1E+00 3.5E+00
5.50E-01 2.7E+01 1.1E+00 3.5E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1736
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na CFS-L09-1316-T01-A 1 9.40E+03
Na CFS-L09-1316-T02-A 1 1.79E+04
Na CFS-L09-1316-T03-A 1 4.20E+04
Na CFS-L09-1316-T04-A 1 7.35E+04
Na CFS-L09-1316-T05-A 1 1.09E+05
Na CFS-L09-1316-T01-B 1 1.00E+04
Na CFS-L09-1316-T02-B 1 1.78E+04
Na CFS-L09-1316-T03-B 1 4.17E+04
Na CFS-L09-1316-T04-B 1 7.00E+04
Na CFS-L09-1316-T05-B 1 1.09E+05
Na CFS-L09-1316-T01-C 1 9.86E+03
Na CFS-L09-1316-T02-C 1 1.83E+04
Na CFS-L09-1316-T03-C 1 4.28E+04
Na CFS-L09-1316-T04-C 1 7.41 E+04
Na CFS-L09-1316-T05-C 1 1.11E+05
Na CFS-L09-1316-B01-A 1 2.09E+01
Na CFS-L09-1316-B02-A 1 2.11E+01
Na CFS-L09-1316-B03-A 1 2.11E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.40E+03 2.3E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.79E+04 9.0E-01 2.5E+00 8.0E+00 1000 100 1.88E+04 88% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
4.20E+04 7.3E-01 2.5E+00 8.0E+00
7.35E+04 6.8E-01 2.5E+00 8.0E+00
1.09E+05 2.1E-01 2.5E+00 8.0E+00
1.00E+04 5.9E-01 2.5E+00 8.0E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.78E+04 4.5E-01 2.5E+00 8.0E+00 1000 100 1.87E+04 93% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
4.17E+04 5.7E-01 2.5E+00 8.0E+00
7.00E+04 2.5E-01 2.5E+00 8.0E+00
1.09E+05 5.9E-01 2.5E+00 8.0E+00
9.86E+03 4.5E-01 2.5E+00 8.0E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.83E+04 2.2E-01 2.5E+00 8.0E+00 1000 100 1.92E+04 91% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
4.28E+04 8.6E-01 2.5E+00 8.0E+00
7.41 E+04 4.7E-01 2.5E+00 8.0E+00
1.11E+05 1.3E-01 2.5E+00 8.0E+00
2.09E+01 1.3E+00 2.5E+00 8.0E+00
2.11E+01 1.7E+00 2.5E+00 8.0E+00
2.11E+01 1.6E+00 2.5E+00 8.0E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1737
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L09-1316-T01-A 1 1.52E+03
CFS-L09-1316-T02-A 1 2.13E+03
CFS-L09-1316-T03-A 1 3.13E+03
CFS-L09-1316-T04-A 1 3.85E+03
CFS-L09-1316-T05-A 1 4.25E+03
CFS-L09-1316-T01-B 1 1.55E+03
CFS-L09-1316-T02-B 1 2.20E+03
CFS-L09-1316-T03-B 1 3.28E+03
CFS-L09-1316-T04-B 1 3.94E+03
CFS-L09-1316-T05-B 1 4.30E+03
CFS-L09-1316-T01-C 1 1.52E+03
CFS-L09-1316-T02-C 1 2.13E+03
CFS-L09-1316-T03-C 1 3.29E+03
CFS-L09-1316-T04-C 1 3.90E+03
CFS-L09-1316-T05-C 1 4.40E+03
CFS-L09-1316-B01-A 1 5.00E-01 U1/2
CFS-L09-1316-B02-A 1 5.00E-01 U1/2
CFS-L09-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.52E+03 1.9E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
2.13E+03 1.4E+00 1 .OE+00 3.2E+00 1000 100 3.08E+03 95% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
3.13E+03 2.0E+00 1 .OE+00 3.2E+00
3.85E+03 4.6E-01 1 .OE+00 3.2E+00
4.25E+03 1.3E+00 1 .OE+00 3.2E+00
1.55E+03 8.1E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
2.20E+03 7.1E-01 1 .OE+00 3.2E+00 1000 100 3.09E+03 89% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
3.28E+03 8.8E-01 1 .OE+00 3.2E+00
3.94E+03 1.4E+00 1 .OE+00 3.2E+00
4.30E+03 4.9E-01 1 .OE+00 3.2E+00
1.52E+03 7.8E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
2.13E+03 6.1E-01 1 .OE+00 3.2E+00 1000 100 3.02E+03 90% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
3.29E+03 2.3E-01 1. OE+00 3.2E+00
3.90E+03 8.5E-01 1. OE+00 3.2E+00
4.40E+03 1.1E+00 1. OE+00 3.2E+00
5.00E-01 1.2E+02 1. OE+00 3.2E+00
5.00E-01 1.7E+02 1. OE+00 3.2E+00
5.00E-01 7.0E+01 1. OE+00 3.2E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1738
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S CFS-L09-1316-T01-A 1 6.06E+05
S CFS-L09-1316-T02-A 1 6.71 E+05
S CFS-L09-1316-T03-A 1 8.53E+05
S CFS-L09-1316-T04-A 1 1.11E+06
S CFS-L09-1316-T05-A 1 1.40E+06
S CFS-L09-1316-T01-B 1 6.16E+05
S CFS-L09-1316-T02-B 1 6.78E+05
S CFS-L09-1316-T03-B 1 8.65E+05
S CFS-L09-1316-T04-B 1 1.06E+06
S CFS-L09-1316-T05-B 1 1.39E+06
S CFS-L09-1316-T01-C 1 6.07E+05
S CFS-L09-1316-T02-C 1 6.82E+05
S CFS-L09-1316-T03-C 1 8.64E+05
S CFS-L09-1316-T04-C 1 1.08E+06
S CFS-L09-1316-T05-C 1 1.41E+06
S CFS-L09-1316-B01-A 1 3.40E+00 U1/2
S CFS-L09-1316-B02-A 1 3.40E+00 U1/2
S CFS-L09-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.06E+05 1.2E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
6.71E+05 6.3E-01 6.8E+00 2.2E+01 1000 100 6.72E+05 83% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
8.53E+05 1.4E+00 6.8E+00 2.2E+01
1.11E+06 3.2E-01 6.8E+00 2.2E+01
1.40E+06 4.1E-01 6.8E+00 2.2E+01
6.16E+05 3.5E-01 6.8E+00 2.2E+01
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
6.78E+05 8.8E-01 6.8E+00 2.2E+01 1000 100 6.78E+05 86% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
8.65E+05 4.2E-01 6.8E+00 2.2E+01
1.06E+06 9.0E-01 6.8E+00 2.2E+01
1.39E+06 2.9E-01 6.8E+00 2.2E+01
6.07E+05 7.0E-01 6.8E+00 2.2E+01
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
6.82E+05 5.7E-01 6.8E+00 2.2E+01 1000 100 6.83E+05 84% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
8.64E+05 3.5E-01 6.8E+00 2.2E+01
1.08E+06 2.7E-01 6.8E+00 2.2E+01
1.41E+06 2.6E-01 6.8E+00 2.2E+01
3.40E+00 3.7E+00 6.8E+00 2.2E+01
3.40E+00 3.0E+00 6.8E+00 2.2E+01
3.40E+00 4.9E+00 6.8E+00 2.2E+01
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1739
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
ug/L
Tl CFS-L09-1316-T01-A 1 3.08E+02
Tl CFS-L09-1316-T02-A 1 4.66E+02
Tl CFS-L09-1316-T03-A 1 7.37E+02
Tl CFS-L09-1316-T04-A 1 1.01E+03
Tl CFS-L09-1316-T05-A 1 1.27E+03
Tl CFS-L09-1316-T01-B 1 3.29E+02
Tl CFS-L09-1316-T02-B 1 4.73E+02
Tl CFS-L09-1316-T03-B 1 7.52E+02
Tl CFS-L09-1316-T04-B 1 9.62E+02
Tl CFS-L09-1316-T05-B 1 1.26E+03
Tl CFS-L09-1316-T01-C 1 3.29E+02
Tl CFS-L09-1316-T02-C 1 4.76E+02
Tl CFS-L09-1316-T03-C 1 7.71 E+02
Tl CFS-L09-1316-T04-C 1 9.99E+02
Tl CFS-L09-1316-T05-C 1 1.27E+03
Tl CFS-L09-1316-B01-A 1 2.30E+00 U1/2
Tl CFS-L09-1316-B02-A 1 2.30E+00 U1/2
Tl CFS-L09-1316-B03-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.08E+02 2.6E+00 4.6E+00 1.5E+01
4.66E+02 2.0E-01 4.6E+00 1.5E+01 10 100
7.37E+02 2.4E+00 4.6E+00 1.5E+01
1.01E+03 4.1E-01 4.6E+00 1.5E+01
1.27E+03 2.3E-01 4.6E+00 1.5E+01
3.29E+02 3.7E-01 4.6E+00 1.5E+01
4.73E+02 2.4E-01 4.6E+00 1.5E+01 10 100
7.52E+02 2.7E-01 4.6E+00 1.5E+01
9.62E+02 3.4E-01 4.6E+00 1.5E+01
1.26E+03 6.0E-01 4.6E+00 1.5E+01
3.29E+02 9.2E-01 4.6E+00 1.5E+01
4.76E+02 1.1E+00 4.6E+00 1.5E+01 10 100
7.71 E+02 1.3E+00 4.6E+00 1.5E+01
9.99E+02 3.0E-01 4.6E+00 1.5E+01
1.27E+03 4.7E-01 4.6E+00 1.5E+01
2.30E+00 7.3E+02 4.6E+00 1.5E+01
2.30E+00 8.6E+01 4.6E+00 1.5E+01
2.30E+00 1.3E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.38E+03 91%VUICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.40E+03 93%VUICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.40E+03 92% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1740
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti CFS-L09-1316-T01-A 1 1.00E+OOU1/2
Ti CFS-L09-1316-T02-A 1 1.00E+OOU1/2
Ti CFS-L09-1316-T03-A 1 1.00E+OOU1/2
Ti CFS-L09-1316-T04-A 1 1.00E+OOU1/2
Ti CFS-L09-1316-T05-A 1 1.00E+OOU1/2
Ti CFS-L09-1316-T01-B 1 1.00E+OOU1/2
Ti CFS-L09-1316-T02-B 1 1.00E+OOU1/2
Ti CFS-L09-1316-T03-B 1 1.00E+OOU1/2
Ti CFS-L09-1316-T04-B 1 1.00E+OOU1/2
Ti CFS-L09-1316-T05-B 1 1.00E+OOU1/2
Ti CFS-L09-1316-T01-C 1 1.00E+OOU1/2
Ti CFS-L09-1316-T02-C 1 1.00E+OOU1/2
Ti CFS-L09-1316-T03-C 1 1.00E+OOU1/2
Ti CFS-L09-1316-T04-C 1 1.00E+OOU1/2
Ti CFS-L09-1316-T05-C 1 1.00E+OOU1/2
Ti CFS-L09-1316-B01-A 1 1.00E+OOU1/2
Ti CFS-L09-1316-B02-A 1 1.00E+OOU1/2
Ti CFS-L09-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.4E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 9.6E+01 2.0E+00 6.4E+00 10 100 1 .03E+03 103% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 8.7E+01 2.0E+00 6.4E+00
1.00E+00 4.3E+01 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 8.2E+01 2.0E+00 6.4E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 5.5E+01 2.0E+00 6.4E+00 10 100 1.04E+03 104% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 2.5E+01 2.0E+00 6.4E+00
1.00E+00 1.4E+02 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
1.00E+00 7.7E+01 2.0E+00 6.4E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 6.1E+01 2.0E+00 6.4E+00 10 100 1.03E+03 103% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
1.00E+00 5.4E+01 2.0E+00 6.4E+00
1.00E+00 2.1E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 6.2E+01 2.0E+00 6.4E+00
1.00E+00 5.0E+01 2.0E+00 6.4E+00
1.00E+00 7.5E+01 2.0E+00 6.4E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1741
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V CFS-L09-1316-T01-A 1 2.46E+01
V CFS-L09-1316-T02-A 1 2.52E+01
V CFS-L09-1316-T03-A 1 2.23E+01
V CFS-L09-1316-T04-A 1 2.12E+01
V CFS-L09-1316-T05-A 1 1.99E+01
V CFS-L09-1316-T01-B 1 2.53E+01
V CFS-L09-1316-T02-B 1 2.46E+01
V CFS-L09-1316-T03-B 1 2.28E+01
V CFS-L09-1316-T04-B 1 2.21E+01
V CFS-L09-1316-T05-B 1 1.84E+01
V CFS-L09-1316-T01-C 1 2.48E+01
V CFS-L09-1316-T02-C 1 2.45E+01
V CFS-L09-1316-T03-C 1 2.26E+01
V CFS-L09-1316-T04-C 1 2.15E+01
V CFS-L09-1316-T05-C 1 1.96E+01
V CFS-L09-1316-B01-A 1 1.60E+OOE
V CFS-L09-1316-B02-A 1 7.50E-01 U1/2
V CFS-L09-1316-B03-A 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.46E+01 5.5E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
2.52E+01 1.9E+00 1 .5E+00 4.8E+00 10 100 1 .02E+03 100% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
2.23E+01 2.2E+00 1 .5E+00 4.8E+00
2.12E+01 3.8E+00 1 .5E+00 4.8E+00
1.99E+01 3.5E+00 1 .5E+00 4.8E+00
2.53E+01 2.5E+00 1 .5E+00 4.8E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
2.46E+01 3.5E+00 1 .5E+00 4.8E+00 10 100 1 .03E+03 101% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
2.28E+01 2.3E+00 1 .5E+00 4.8E+00
2.21E+01 6.2E+00 1 .5E+00 4.8E+00
1.84E+01 4.5E+00 1 .5E+00 4.8E+00
2.48E+01 1.3E+00 1 .5E+00 4.8E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
2.45E+01 2.6E+00 1 .5E+00 4.8E+00 10 100 1.02E+03 99% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
2.26E+01 6.5E+00 1.5E+00 4.8E+00
2.15E+01 5.9E+00 1.5E+00 4.8E+00
1.96E+01 2.8E+00 1.5E+00 4.8E+00
1.60E+00 2.6E+01 1.5E+00 4.8E+00
7.50E-01 2.1E+01 1.5E+00 4.8E+00
7.50E-01 5.1E+01 1.5E+00 4.8E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1742
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn CFS-L09-1316-T01-A 1 2.04E+04
Zn CFS-L09-1316-T02-A 1 2.80E+04
Zn CFS-L09-1316-T03-A 1 4.17E+04
Zn CFS-L09-1316-T04-A 1 5.35E+04
Zn CFS-L09-1316-T05-A 1 6.17E+04
Zn CFS-L09-1316-T01-B 1 2.05E+04
Zn CFS-L09-1316-T02-B 1 2.74E+04
Zn CFS-L09-1316-T03-B 1 4.01 E+04
Zn CFS-L09-1316-T04-B 1 4.82E+04
Zn CFS-L09-1316-T05-B 1 5.95E+04
Zn CFS-L09-1316-T01-C 1 2.04E+04
Zn CFS-L09-1316-T02-C 1 2.90E+04
Zn CFS-L09-1316-T03-C 1 4.22E+04
Zn CFS-L09-1316-T04-C 1 5.25E+04
Zn CFS-L09-1316-T05-C 1 5.94E+04
Zn CFS-L09-1316-B01-A 1 4.21E+00
Zn CFS-L09-1316-B02-A 1 3.15E+00 E
Zn CFS-L09-1316-B03-A 1 3.04E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.04E+04 8.1E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/19/11 5:00 PM EPA Interlab L09 1313-1316 CFS
2.80E+04 1.6E+00 1 .OE+00 3.2E+00 10 100 2.88E+04 88% VU ICP-OES 4/19/11 5:02 PM EPA Interlab L09 1313-1316 CFS
4.17E+04 1.6E+00 1 .OE+00 3.2E+00
5.35E+04 5.6E-01 1 .OE+00 3.2E+00
6.17E+04 1.6E+00 1 .OE+00 3.2E+00
2.05E+04 8.3E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/19/11 5:04 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:05 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:07 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:08 PM EPA Interlab L09 1313-1316 CFS
2.74E+04 7.6E-01 1 .OE+00 3.2E+00 10 100 2.83E+04 96% VU ICP-OES 4/19/11 5:10 PM EPA Interlab L09 1313-1316 CFS
4.01E+04 2.7E-01 1 .OE+00 3.2E+00
4.82E+04 1.2E+00 1 .OE+00 3.2E+00
5.95E+04 6.3E-01 1 .OE+00 3.2E+00
2.04E+04 3.3E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/19/11 5:12 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:13 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:15 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:17 PM EPA Interlab L09 1313-1316 CFS
2.90E+04 1.4E+00 1 .OE+00 3.2E+00 10 100 2.99E+04 89% VU ICP-OES 4/19/11 5:18 PM EPA Interlab L09 1313-1316 CFS
4.22E+04 1.7E-01 1. OE+00 3.2E+00
5.25E+04 2.3E-01 1. OE+00 3.2E+00
5.94E+04 4.0E-01 1. OE+00 3.2E+00
4.21 E+00 7.1E+00 1. OE+00 3.2E+00
3.15E+00 1.1E+01 1.0E+00 3.2E+00
3.04E+00 7.6E+00 1. OE+00 3.2E+00
VU ICP-OES 4/19/11 5:20 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:22 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/19/11 5:23 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:33 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:35 PM EPA Interlab L09 1313-1316 CFS
VU ICP-OES 4/20/11 2:36 PM EPA Interlab L09 1313-1316 CFS
                                                                                                                                                                         1-1743
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al CFS-L10-1316-T01-A 1 4.71 E+01
Al CFS-L10-1316-T02-A 1 4.72E+01
Al CFS-L10-1316-T03-A 1 4.89E+01
Al CFS-L10-1316-T04-A 1 5.06E+01
Al CFS-L10-1316-T05-A 1 5.15E+01
Al CFS-L10-1316-T01-B 1 4.78E+01
Al CFS-L10-1316-T02-B 1 4.58E+01
Al CFS-L10-1316-T03-B 1 5.01 E+01
Al CFS-L10-1316-T04-B 1 5.11E+01
Al CFS-L10-1316-T05-B 1 6.08E+01
Al CFS-L10-1316-T01-C 1 5.00E+01
Al CFS-L10-1316-T02-C 1 5.11E+01
Al CFS-L10-1316-T03-C 1 5.74E+01
Al CFS-L10-1316-T04-C 1 5.43E+01
Al CFS-L10-1316-T05-C 1 5.85E+01
Al CFS-L10-1316-B01-A 1 5.00E-01 U1/2
Al CFS-L10-1316-B02-A 1 5.00E-01 U1/2
Al CFS-L10-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.71 E+01 4.3E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
4.72E+01 1.9E+00 1 .OE+00 3.2E+00 1000 100 1 .22E+03 117% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
4.89E+01 6.3E+00 1 .OE+00 3.2E+00
5.06E+01 7.8E+00 1 .OE+00 3.2E+00
5.15E+01 4.9E+00 1 .OE+00 3.2E+00
4.78E+01 3.6E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
4.58E+01 7.8E+00 1 .OE+00 3.2E+00 1000 100 1 .05E+03 100% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
5.01 E+01 9.9E+00 1 .OE+00 3.2E+00
5. 11 E+01 4.6E-01 1. OE+00 3.2E+00
6.08E+01 4.8E+00 1 .OE+00 3.2E+00
5.00E+01 8.8E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
5.11E+01 5.0E+00 1.0E+00 3.2E+00 1000 100 1.19E+03 114% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
5.74E+01 6.4E+00 1 .OE+00 3.2E+00
5.43E+01 6.2E+00 1 .OE+00 3.2E+00
5.85E+01 1.1 E+01 1. OE+00 3.2E+00
5.00E-01 1.5E+02 1 .OE+00 3.2E+00
5.00E-01 5.3E+01 1 .OE+00 3.2E+00
5.00E-01 1.6E+02 1 .OE+00 3.2E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                                  1-1744
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb CFS-L10-1316-T01-A 1 3.28E+01
Sb CFS-L10-1316-T02-A 1 4.32E+01
Sb CFS-L10-1316-T03-A 1 3.44E+01
Sb CFS-L10-1316-T04-A 1 5.15E+01
Sb CFS-L10-1316-T05-A 1 6.64E+01
Sb CFS-L10-1316-T01-B 1 2.95E+01
Sb CFS-L10-1316-T02-B 1 3.04E+01
Sb CFS-L10-1316-T03-B 1 3.38E+01
Sb CFS-L10-1316-T04-B 1 5.09E+01
Sb CFS-L10-1316-T05-B 1 5.66E+01
Sb CFS-L10-1316-T01-C 1 3.01E+01
Sb CFS-L10-1316-T02-C 1 3.25E+01
Sb CFS-L10-1316-T03-C 1 3.80E+01
Sb CFS-L10-1316-T04-C 1 4.91E+01
Sb CFS-L10-1316-T05-C 1 5.41E+01
Sb CFS-L10-1316-B01-A 1 3.75E+00 U1/2
Sb CFS-L10-1316-B02-A 1 3.75E+00 U1/2
Sb CFS-L10-1316-B03-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.28E+01 9.4E+00 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
4.32E+01 1.6E+01 7.5E+00 2.4E+01 10 100 1.15E+03 110% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
3.44E+01 7.1E+00 7.5E+00 2.4E+01
5.15E+01 7.0E+00 7.5E+00 2.4E+01
6.64E+01 1.4E+00 7.5E+00 2.4E+01
2.95E+01 3.1E+01 7.5E+00 2.4E+01
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
3.04E+01 3.4E+01 7.5E+00 2.4E+01 10 100 9.99E+02 97% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
3.38E+01 1.9E+00 7.5E+00 2.4E+01
5.09E+01 5.6E+00 7.5E+00 2.4E+01
5.66E+01 1.8E+01 7.5E+00 2.4E+01
3.01 E+01 8.9E+00 7.5E+00 2.4E+01
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
3.25E+01 1.5E+01 7.5E+00 2.4E+01 10 100 1.09E+03 105% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
3.80E+01 7.1E+00 7.5E+00 2.4E+01
4.91 E+01 1.3E+01 7.5E+00 2.4E+01
5.41 E+01 8.1E+00 7.5E+00 2.4E+01
3.75E+00 1.6E+02 7.5E+00 2.4E+01
3.75E+00 2.7E+03 7.5E+00 2.4E+01
3.75E+00 3.3E+01 7.5E+00 2.4E+01
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1745
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
As Sample Dilution Cone. Qualifier Revi
ug/L
As CFS-L10-1316-T01-A 1 1.94E+01 E
As CFS-L10-1316-T02-A 1 1.17E+01 E
As CFS-L10-1316-T03-A 1 1.92E+01 E
As CFS-L10-1316-T04-A 1 3.51 E+01
As CFS-L10-1316-T05-A 1 4.22E+01
As CFS-L10-1316-T01-B 1 1.54E+01 E
As CFS-L10-1316-T02-B 1 1.49E+01 E
As CFS-L10-1316-T03-B 1 2.78E+01 E
As CFS-L10-1316-T04-B 1 2.96E+01 E
As CFS-L10-1316-T05-B 1 4.12E+01
As CFS-L10-1316-T01-C 1 1.63E+01 E
As CFS-L10-1316-T02-C 1 1.49E+01 E
As CFS-L10-1316-T03-C 1 2.47E+01 E
As CFS-L10-1316-T04-C 1 3.30E+01 E
As CFS-L10-1316-T05-C 1 3.84E+01
As CFS-L10-1316-B01-A 1 5.50E+00 U1/2
As CFS-L10-1316-B02-A 1 5.50E+00 U1/2
As CFS-L10-1316-B03-A 1 5.50E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.94E+01 1.8E+01 1.1 E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.17E+01 6.7E+01 1.1E+01 3.5E+01 10 100 1.14E+03 1 13% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
1.92E+01 4.3E+01 1.1 E+01 3.5E+01
3.51E+01 3.1E-01 1.1E+01 3.5E+01
4.22E+01 2.7E+01 1.1E+01 3.5E+01
1.54E+01 4.7E+01 1.1 E+01 3.5E+01
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.49E+01 4.6E+01 1.1E+01 3.5E+01 10 100 1 .OOE+03 99% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
2.78E+01 5.5E+01 1.1E+01 3.5E+01
2.96E+01 2.5E+01 1.1E+01 3.5E+01
4.12E+01 5.9E+00 1.1E+01 3.5E+01
1.63E+01 5.2E+01 1.1 E+01 3.5E+01
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.49E+01 2.0E+01 1.1E+01 3.5E+01 10 100 1 .09E+03 108% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
2.47E+01 5.6E+01 1.1E+01 3.5E+01
3.30E+01 4.5E+00 1.1 E+01 3.5E+01
3.84E+01 1.7E+01 1.1 E+01 3.5E+01
5.50E+00 5.8E+01 1.1 E+01 3.5E+01
5.50E+00 2.4E+02 1.1 E+01 3.5E+01
5.50E+00 1.1E+02 1.1 E+01 3.5E+01
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1746
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B CFS-L10-1316-T01-A 1 1.53E+02
B CFS-L10-1316-T02-A 1 2.62E+02
B CFS-L10-1316-T03-A 1 5.35E+02
B CFS-L10-1316-T04-A 1 8.64E+02
B CFS-L10-1316-T05-A 1 1.33E+03
B CFS-L10-1316-T01-B 1 1.68E+02
B CFS-L10-1316-T02-B 1 2.79E+02
B CFS-L10-1316-T03-B 1 5.43E+02
B CFS-L10-1316-T04-B 1 8.86E+02
B CFS-L10-1316-T05-B 1 1.30E+03
B CFS-L10-1316-T01-C 1 1.64E+02
B CFS-L10-1316-T02-C 1 2.66E+02
B CFS-L10-1316-T03-C 1 5.23E+02
B CFS-L10-1316-T04-C 1 8.61 E+02
B CFS-L10-1316-T05-C 1 1.31E+03
B CFS-L10-1316-B01-A 1 1.35E+01
B CFS-L10-1316-B02-A 1 1.10E+01
B CFS-L10-1316-B03-A 1 9.79E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+02 9.3E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
2.62E+02 1.7E+00 1 .OE+00 3.2E+00 1000 100 1 .22E+03 95% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
5.35E+02 1.3E+00 1 .OE+00 3.2E+00
8.64E+02 8.8E-01 1 .OE+00 3.2E+00
1.33E+03 1.2E+00 1 .OE+00 3.2E+00
1.68E+02 1. OE+00 1 .OE+00 3.2E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
2.79E+02 8.0E-01 1 .OE+00 3.2E+00 1000 100 1.21E+03 93% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
5.43E+02 7.0E-01 1 .OE+00 3.2E+00
8.86E+02 7.8E-01 1 .OE+00 3.2E+00
1.30E+03 6.2E-01 1 .OE+00 3.2E+00
1.64E+02 2.3E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
2.66E+02 9.4E-01 1 .OE+00 3.2E+00 1000 100 1.19E+03 93% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
5.23E+02 1. OE+00 1. OE+00 3.2E+00
8.61 E+02 2.8E-01 1. OE+00 3.2E+00
1.31E+03 7.0E-01 1. OE+00 3.2E+00
1.35E+01 9.1E+00 1. OE+00 3.2E+00
1.10E+01 1.0E+01 1. OE+00 3.2E+00
9.79E+00 1.3E+01 1. OE+00 3.2E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1747
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba CFS-L10-1316-T01-A 1 1.06E+02
Ba CFS-L10-1316-T02-A 1 9.52E+01
Ba CFS-L10-1316-T03-A 1 8.14E+01
Ba CFS-L10-1316-T04-A 1 6.96E+01
Ba CFS-L10-1316-T05-A 1 6.38E+01
Ba CFS-L10-1316-T01-B 1 1.07E+02
Ba CFS-L10-1316-T02-B 1 9.15E+01
Ba CFS-L10-1316-T03-B 1 7.63E+01
Ba CFS-L10-1316-T04-B 1 6.33E+01
Ba CFS-L10-1316-T05-B 1 5.31 E+01
Ba CFS-L10-1316-T01-C 1 9.47E+01
Ba CFS-L10-1316-T02-C 1 9.06E+01
Ba CFS-L10-1316-T03-C 1 7.70E+01
Ba CFS-L10-1316-T04-C 1 6.32E+01
Ba CFS-L10-1316-T05-C 1 5.25E+01
Ba CFS-L10-1316-B01-A 1 5.00E-01 U1/2
Ba CFS-L10-1316-B02-A 1 5.00E-01 U1/2
Ba CFS-L10-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+02 6.1E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
9.52E+01 9.4E-01 1 .OE+00 3.2E+00 10 100 1.14E+03 105% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
8.14E+01 8.1E-01 1.0E+00 3.2E+00
6.96E+01 4.7E-01 1. OE+00 3.2E+00
6.38E+01 4.7E-01 1. OE+00 3.2E+00
1.07E+02 6.2E-01 1. OE+00 3.2E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
9.15E+01 1.4E+00 1.0E+00 3.2E+00 10 100 1.14E+03 105% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
7.63E+01 9.0E-01 1. OE+00 3.2E+00
6.33E+01 7.7E-01 1. OE+00 3.2E+00
5.31 E+01 8.6E-01 1. OE+00 3.2E+00
9.47E+01 2.8E-01 1. OE+00 3.2E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
9.06E+01 7.2E-01 1.0E+00 3.2E+00 10 100 1.07E+03 98% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
7.70E+01 1.2E+00 1. OE+00 3.2E+00
6.32E+01 6.8E-01 1. OE+00 3.2E+00
5.25E+01 1.2E+00 1. OE+00 3.2E+00
5.00E-01 2.8E+01 1. OE+00 3.2E+00
5.00E-01 1.8E+01 1. OE+00 3.2E+00
5.00E-01 1.0E+01 1. OE+00 3.2E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1748
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be CFS-L10-1316-T01-A 1 9.50E-01 U1/2
Be CFS-L10-1316-T02-A 1 9.50E-01 U1/2
Be CFS-L10-1316-T03-A 1 9.50E-01 U1/2
Be CFS-L10-1316-T04-A 1 9.50E-01 U1/2
Be CFS-L10-1316-T05-A 1 9.50E-01 U1/2
Be CFS-L10-1316-T01-B 1 9.50E-01 U1/2
Be CFS-L10-1316-T02-B 1 9.50E-01 U1/2
Be CFS-L10-1316-T03-B 1 9.50E-01 U1/2
Be CFS-L10-1316-T04-B 1 9.50E-01 U1/2
Be CFS-L10-1316-T05-B 1 9.50E-01 U1/2
Be CFS-L10-1316-T01-C 1 9.50E-01 U1/2
Be CFS-L10-1316-T02-C 1 9.50E-01 U1/2
Be CFS-L10-1316-T03-C 1 9.50E-01 U1/2
Be CFS-L10-1316-T04-C 1 9.50E-01 U1/2
Be CFS-L10-1316-T05-C 1 9.50E-01 U1/2
Be CFS-L10-1316-B01-A 1 9.50E-01 U1/2
Be CFS-L10-1316-B02-A 1 9.50E-01 U1/2
Be CFS-L10-1316-B03-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.4E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
9.50E-01 2.0E+02 1.9E+00 6.0E+00 10 100 1.16E+03 116% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
9.50E-01 2.3E+02 1.9E+00 6.0E+00
9.50E-01 6.5E+01 1.9E+00 6.0E+00
9.50E-01 2.7E+01 1.9E+00 6.0E+00
9.50E-01 4.2E+03 1.9E+00 6.0E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
9.50E-01 1.1E+02 1.9E+00 6.0E+00 10 100 1.01E+03 101% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
9.50E-01 4.1E+01 1.9E+00 6.0E+00
9.50E-01 9.1E+02 1.9E+00 6.0E+00
9.50E-01 2.9E+01 1.9E+00 6.0E+00
9.50E-01 3.5E+02 1.9E+00 6.0E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
9.50E-01 4.9E+01 1.9E+00 6.0E+00 10 100 1.10E+03 110% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
9.50E-01 2.5E+02 1.9E+00 6.0E+00
9.50E-01 6.9E+01 1.9E+00 6.0E+00
9.50E-01 2.9E+01 1.9E+00 6.0E+00
9.50E-01 2.1E+02 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 2.2E+02 1.9E+00 6.0E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VUICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VUICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1749
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd CFS-L10-1316-T01-A 1 4.16E+03
Cd CFS-L10-1316-T02-A 1 5.90E+03
Cd CFS-L10-1316-T03-A 1 8.88E+03
Cd CFS-L10-1316-T04-A 1 1.11E+04
Cd CFS-L10-1316-T05-A 1 1.28E+04
Cd CFS-L10-1316-T01-B 1 4.37E+03
Cd CFS-L10-1316-T02-B 1 6.45E+03
Cd CFS-L10-1316-T03-B 1 9.24E+03
Cd CFS-L10-1316-T04-B 1 1.16E+04
Cd CFS-L10-1316-T05-B 1 1.37E+04
Cd CFS-L10-1316-T01-C 1 4.26E+03
Cd CFS-L10-1316-T02-C 1 5.88E+03
Cd CFS-L10-1316-T03-C 1 8.64E+03
Cd CFS-L10-1316-T04-C 1 1.15E+04
Cd CFS-L10-1316-T05-C 1 1.36E+04
Cd CFS-L10-1316-B01-A 1 1.10E+OOU1/2
Cd CFS-L10-1316-B02-A 1 1.10E+OOU1/2
Cd CFS-L10-1316-B03-A 1 1.10E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.16E+03 4.6E-01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
5.90E+03 1.3E+00 2.2E+00 7.0E+00 10 100 6.89E+03 99% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
8.88E+03 6.4E-01 2.2E+00 7.0E+00
1.11E+04 9.0E-01 2.2E+00 7.0E+00
1.28E+04 8.3E-01 2.2E+00 7.0E+00
4.37E+03 3.6E-01 2.2E+00 7.0E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
6.45E+03 9.9E-01 2.2E+00 7.0E+00 10 100 7.39E+03 95% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
9.24E+03 2.8E-01 2.2E+00 7.0E+00
1.16E+04 8.6E-01 2.2E+00 7.0E+00
1.37E+04 2.8E-01 2.2E+00 7.0E+00
4.26E+03 8.2E-01 2.2E+00 7.0E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
5.88E+03 2.0E-01 2.2E+00 7.0E+00 10 100 6.85E+03 96% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
8.64E+03 8.8E-01 2.2E+00 7.0E+00
1.15E+04 3.6E-01 2.2E+00 7.0E+00
1.36E+04 8.5E-01 2.2E+00 7.0E+00
1.10E+00 1.4E+01 2.2E+00 7.0E+00
1.10E+00 1.4E+02 2.2E+00 7.0E+00
1.10E+00 3.8E+00 2.2E+00 7.0E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1750
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca CFS-L10-1316-T01-A 1 6.53E+05
Ca CFS-L10-1316-T02-A 1 6.23E+05
Ca CFS-L10-1316-T03-A 1 5.91 E+05
Ca CFS-L10-1316-T04-A 1 5.69E+05
Ca CFS-L10-1316-T05-A 1 5.46E+05
Ca CFS-L10-1316-T01-B 1 6.68E+05
Ca CFS-L10-1316-T02-B 1 6.21E+05
Ca CFS-L10-1316-T03-B 1 5.66E+05
Ca CFS-L10-1316-T04-B 1 5.27E+05
Ca CFS-L10-1316-T05-B 1 5.03E+05
Ca CFS-L10-1316-T01-C 1 6.10E+05
Ca CFS-L10-1316-T02-C 1 5.94E+05
Ca CFS-L10-1316-T03-C 1 5.56E+05
Ca CFS-L10-1316-T04-C 1 5.26E+05
Ca CFS-L10-1316-T05-C 1 4.99E+05
Ca CFS-L10-1316-B01-A 1 2.04E+01
Ca CFS-L10-1316-B02-A 1 2.10E+01
Ca CFS-L10-1316-B03-A 1 1.63E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.53E+05 4.7E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
6.23E+05 1.3E+00 2.6E+00 8.3E+00 1000 100 6.24E+05 91% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
5.91E+05 1.1E+00 2.6E+00 8.3E+00
5.69E+05 8.4E-01 2.6E+00 8.3E+00
5.46E+05 1.0E+00 2.6E+00 8.3E+00
6.68E+05 5.1E-01 2.6E+00 8.3E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
6.21E+05 8.3E-01 2.6E+00 8.3E+00 1000 100 6.22E+05 85% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
5.66E+05 1.7E-01 2.6E+00 8.3E+00
5.27E+05 9.2E-01 2.6E+00 8.3E+00
5.03E+05 4.9E-01 2.6E+00 8.3E+00
6.10E+05 9.5E-01 2.6E+00 8.3E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
5.94E+05 8.6E-01 2.6E+00 8.3E+00 1000 100 5.95E+05 89% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
5.56E+05 8.4E-01 2.6E+00 8.3E+00
5.26E+05 7.1E-01 2.6E+00 8.3E+00
4.99E+05 1.4E+00 2.6E+00 8.3E+00
2.04E+01 1.3E+01 2.6E+00 8.3E+00
2.10E+01 1.9E+01 2.6E+00 8.3E+00
1.63E+01 2.3E+01 2.6E+00 8.3E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1751
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cr Sample Dilution Cone. Qualifier Revi
ug/L
Cr CFS-L10-1316-T01-A 1 6.00E-01 U1/2
Cr CFS-L10-1316-T02-A 1 6.00E-01 U1/2
Cr CFS-L10-1316-T03-A 1 6.00E-01 U1/2
Cr CFS-L10-1316-T04-A 1 6.00E-01 U1/2
Cr CFS-L10-1316-T05-A 1 6.00E-01 U1/2
Cr CFS-L10-1316-T01-B 1 6.00E-01 U1/2
Cr CFS-L10-1316-T02-B 1 6.00E-01 U1/2
Cr CFS-L10-1316-T03-B 1 6.00E-01 U1/2
Cr CFS-L10-1316-T04-B 1 6.00E-01 U1/2
Cr CFS-L10-1316-T05-B 1 6.00E-01 U1/2
Cr CFS-L10-1316-T01-C 1 6.00E-01 U1/2
Cr CFS-L10-1316-T02-C 1 6.00E-01 U1/2
Cr CFS-L10-1316-T03-C 1 6.00E-01 U1/2
Cr CFS-L10-1316-T04-C 1 6.00E-01 U1/2
Cr CFS-L10-1316-T05-C 1 6.00E-01 U1/2
Cr CFS-L10-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L10-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L10-1316-B01-A 1 6.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 1.9E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
6.00E-01 1.2E+02 1.2E+00 3.8E+00 10 100 1.13E+03 113% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
6.00E-01 2.3E+02 1.2E+00 3.8E+00
6.00E-01 6.9E+02 1.2E+00 3.8E+00
6.00E-01 2.6E+02 1.2E+00 3.8E+00
6.00E-01 2.4E+02 1.2E+00 3.8E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
6.00E-01 3.4E+02 1.2E+00 3.8E+00 10 100 9.73E+02 97% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
6.00E-01 4.5E+02 1.2E+00 3.8E+00
6.00E-01 1.2E+02 1.2E+00 3.8E+00
6.00E-01 9.8E+01 1.2E+00 3.8E+00
6.00E-01 6.5E+02 1.2E+00 3.8E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
6.00E-01 1.6E+01 1.2E+00 3.8E+00 10 100 1.09E+03 109% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
6.00E-01 8.8E+01 1.2E+00 3.8E+00
6.00E-01 2.2E+02 1.2E+00 3.8E+00
6.00E-01 8.4E+01 1.2E+00 3.8E+00
6.00E-01 3.7E+02 1.2E+00 3.8E+00
6.00E-01 1.9E+02 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VUICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VUICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1752
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co CFS-L10-1316-T01-A 1 9.21E+01
Co CFS-L10-1316-T02-A 1 1.54E+02
Co CFS-L10-1316-T03-A 1 2.86E+02
Co CFS-L10-1316-T04-A 1 4.00E+02
Co CFS-L10-1316-T05-A 1 4.86E+02
Co CFS-L10-1316-T01-B 1 9.89E+01
Co CFS-L10-1316-T02-B 1 1.73E+02
Co CFS-L10-1316-T03-B 1 3.12E+02
Co CFS-L10-1316-T04-B 1 4.46E+02
Co CFS-L10-1316-T05-B 1 5.71 E+02
Co CFS-L10-1316-T01-C 1 1.00E+02
Co CFS-L10-1316-T02-C 1 1.63E+02
Co CFS-L10-1316-T03-C 1 3.01 E+02
Co CFS-L10-1316-T04-C 1 4.44E+02
Co CFS-L10-1316-T05-C 1 5.71 E+02
Co CFS-L10-1316-B01-A 1 9.00E-01 U1/2
Co CFS-L10-1316-B02-A 1 9.00E-01 U1/2
Co CFS-L10-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.21E+01 2.1E-01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.54E+02 1.9E+00 1 .8E+00 5.7E+00 10 100 1.08E+03 93% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
2.86E+02 1.2E+00 1 .8E+00 5.7E+00
4.00E+02 1.0E+00 1 .8E+00 5.7E+00
4.86E+02 7.3E-01 1 .8E+00 5.7E+00
9.89E+01 7.7E-01 1.8E+00 5.7E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.73E+02 1.3E+00 1.8E+00 5.7E+00 10 100 1.11E+03 94% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
3.12E+02 6.9E-01 1.8E+00 5.7E+00
4.46E+02 7.7E-01 1.8E+00 5.7E+00
5.71 E+02 7.7E-01 1.8E+00 5.7E+00
1.00E+02 1.8E+00 1.8E+00 5.7E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.63E+02 7.4E-01 1.8E+00 5.7E+00 10 100 1.03E+03 87% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
3.01 E+02 1.5E+00 1.8E+00 5.7E+00
4.44E+02 5.1E-01 1.8E+00 5.7E+00
5.71 E+02 8.7E-01 1.8E+00 5.7E+00
9.00E-01 2.1 E+02 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
9.00E-01 4.6E+01 1.8E+00 5.7E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1753
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu CFS-L10-1316-T01-A 1 7.45E+02
Cu CFS-L10-1316-T02-A 1 1.06E+03
Cu CFS-L10-1316-T03-A 1 1.68E+03
Cu CFS-L10-1316-T04-A 1 2.20E+03
Cu CFS-L10-1316-T05-A 1 2.32E+03
Cu CFS-L10-1316-T01-B 1 8.36E+02
Cu CFS-L10-1316-T02-B 1 1.20E+03
Cu CFS-L10-1316-T03-B 1 1.97E+03
Cu CFS-L10-1316-T04-B 1 2.22E+03
Cu CFS-L10-1316-T05-B 1 2.75E+03
Cu CFS-L10-1316-T01-C 1 8.73E+02
Cu CFS-L10-1316-T02-C 1 1.08E+03
Cu CFS-L10-1316-T03-C 1 1.54E+03
Cu CFS-L10-1316-T04-C 1 2.29E+03
Cu CFS-L10-1316-T05-C 1 2.64E+03
Cu CFS-L10-1316-B01-A 1 1.85E+OOU1/2
Cu CFS-L10-1316-B02-A 1 1.85E+OOU1/2
Cu CFS-L10-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.45E+02 9.5E-01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.06E+03 1.1E+00 3.7E+00 1.2E+01 10 100 2.02E+03 96% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
1.68E+03 1.3E+00 3.7E+00 1.2E+01
2.20E+03 7.3E-01 3.7E+00 1.2E+01
2.32E+03 4.0E-01 3.7E+00 1.2E+01
8.36E+02 5.9E-01 3.7E+00 1.2E+01
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.20E+03 1.9E+00 3.7E+00 1.2E+01 10 100 2.05E+03 85% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
1.97E+03 1.4E-01 3.7E+00 1.2E+01
2.22E+03 7.1E-01 3.7E+00 1.2E+01
2.75E+03 7.4E-01 3.7E+00 1.2E+01
8.73E+02 3.9E-01 3.7E+00 1.2E+01
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.08E+03 5.9E-01 3.7E+00 1.2E+01 10 100 2.06E+03 97% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
1.54E+03 6.5E-01 3.7E+00 1.2E+01
2.29E+03 1.1E+00 3.7E+00 1.2E+01
2.64E+03 7.1E-01 3.7E+00 1.2E+01
1.85E+00 2.2E+01 3.7E+00 1.2E+01
1.85E+00 4.6E+01 3.7E+00 1.2E+01
1.85E+00 3.6E+00 3.7E+00 1.2E+01
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1754
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe CFS-L10-1316-T01-A 1 1.00E+OOU1/2
Fe CFS-L10-1316-T02-A 1 1.00E+OOU1/2
Fe CFS-L10-1316-T03-A 1 1.00E+OOU1/2
Fe CFS-L10-1316-T04-A 1 1.00E+OOU1/2
Fe CFS-L10-1316-T05-A 1 1.00E+OOU1/2
Fe CFS-L10-1316-T01-B 1 1.00E+OOU1/2
Fe CFS-L10-1316-T02-B 1 1.00E+OOU1/2
Fe CFS-L10-1316-T03-B 1 1.00E+OOU1/2
Fe CFS-L10-1316-T04-B 1 1.00E+OOU1/2
Fe CFS-L10-1316-T05-B 1 1.00E+OOU1/2
Fe CFS-L10-1316-T01-C 1 1.00E+OOU1/2
Fe CFS-L10-1316-T02-C 1 1.00E+OOU1/2
Fe CFS-L10-1316-T03-C 1 1.00E+OOU1/2
Fe CFS-L10-1316-T04-C 1 1.00E+OOU1/2
Fe CFS-L10-1316-T05-C 1 1.00E+OOU1/2
Fe CFS-L10-1316-B01-A 1 1.00E+OOU1/2
Fe CFS-L10-1316-B02-A 1 1.00E+OOU1/2
Fe CFS-L10-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.4E-01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 4.7E+00 2.0E+00 6.4E+00 1000 100 1.15E+03 1 15% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 4.9E+00 2.0E+00 6.4E+00
1.00E+00 7.1E+00 2.0E+00 6.4E+00
1.00E+00 5.4E+00 2.0E+00 6.4E+00
1.00E+00 4.8E+00 2.0E+00 6.4E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 3.4E+00 2.0E+00 6.4E+00 1000 100 1.05E+03 105% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 9.3E+01 2.0E+00 6.4E+00
1.00E+00 4.2E+01 2.0E+00 6.4E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 5.8E+01 2.0E+00 6.4E+00 1000 100 1.10E+03 110% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 2.1E+01 2.0E+00 6.4E+00
1.00E+00 4.1E+01 2.0E+00 6.4E+00
1.00E+00 6.5E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 5.7E+00 2.0E+00 6.4E+00
1.00E+00 2.2E+00 2.0E+00 6.4E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1755
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb CFS-L10-1316-T01-A 1 8.61 E+02
Pb CFS-L10-1316-T02-A 1 9.16E+02
Pb CFS-L10-1316-T03-A 1 1.01E+03
Pb CFS-L10-1316-T04-A 1 1.12E+03
Pb CFS-L10-1316-T05-A 1 1.34E+03
Pb CFS-L10-1316-T01-B 1 8.95E+02
Pb CFS-L10-1316-T02-B 1 9.41 E+02
Pb CFS-L10-1316-T03-B 1 1.03E+03
Pb CFS-L10-1316-T04-B 1 1.09E+03
Pb CFS-L10-1316-T05-B 1 1.27E+03
Pb CFS-L10-1316-T01-C 1 8.26E+02
Pb CFS-L10-1316-T02-C 1 9.14E+02
Pb CFS-L10-1316-T03-C 1 1.02E+03
Pb CFS-L10-1316-T04-C 1 1.12E+03
Pb CFS-L10-1316-T05-C 1 1.24E+03
Pb CFS-L10-1316-B01-A 1 3.40E+00 U1/2
Pb CFS-L10-1316-B02-A 1 3.40E+00 U1/2
Pb CFS-L10-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.61 E+02 7.4E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
9.16E+02 1.4E+00 6.8E+00 2.2E+01 10 100 1.85E+03 93% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
1.01E+03 8.2E-01 6.8E+00 2.2E+01
1.12E+03 9.0E-01 6.8E+00 2.2E+01
1.34E+03 1.3E+00 6.8E+00 2.2E+01
8.95E+02 1.1E+00 6.8E+00 2.2E+01
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
9.41E+02 1.0E+00 6.8E+00 2.2E+01 10 100 1.83E+03 89% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
1.03E+03 5.0E-01 6.8E+00 2.2E+01
1.09E+03 1.5E+00 6.8E+00 2.2E+01
1.27E+03 1.1E+00 6.8E+00 2.2E+01
8.26E+02 6.2E-01 6.8E+00 2.2E+01
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
9.14E+02 6.8E-01 6.8E+00 2.2E+01 10 100 1.90E+03 98% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
1.02E+03 1.3E+00 6.8E+00 2.2E+01
1.12E+03 1.4E+00 6.8E+00 2.2E+01
1.24E+03 2.8E-01 6.8E+00 2.2E+01
3.40E+00 1.1E+01 6.8E+00 2.2E+01
3.40E+00 4.3E+00 6.8E+00 2.2E+01
3.40E+00 1.2E+00 6.8E+00 2.2E+01
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1756
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li CFS-L10-1316-T01-A 1 1.06E+01
Li CFS-L10-1316-T02-A 1 5.14E+00 E
Li CFS-L10-1316-T03-A 1 5.32E+00 E
Li CFS-L10-1316-T04-A 1 5.57E+00 E
Li CFS-L10-1316-T05-A 1 1.66E+01
Li CFS-L10-1316-T01-B 1 8.28E+00
Li CFS-L10-1316-T02-B 1 8.49E+00
Li CFS-L10-1316-T03-B 1 5.29E+00 E
Li CFS-L10-1316-T04-B 1 7.68E+00
Li CFS-L10-1316-T05-B 1 1.94E+01
Li CFS-L10-1316-T01-C 1 1.21E+01
Li CFS-L10-1316-T02-C 1 7.77E+00
Li CFS-L10-1316-T03-C 1 5.38E+00 E
Li CFS-L10-1316-T04-C 1 6.35E+00
Li CFS-L10-1316-T05-C 1 1.85E+01
Li CFS-L10-1316-B01-A 1 9.50E-01 U1/2
Li CFS-L10-1316-B02-A 1 9.50E-01 U1/2
Li CFS-L10-1316-B03-A 1 1.99E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+01 1.1E+01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
5.14E+00 2.4E+00 1 .9E+00 6.0E+00 10 100 8.84E+02 88% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
5.32E+00 1.4E+00 1 .9E+00 6.0E+00
5.57E+00 5.4E+00 1 .9E+00 6.0E+00
1.66E+01 3.8E+00 1 .9E+00 6.0E+00
8.28E+00 1.6E+00 1.9E+00 6.0E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
8.49E+00 2.5E+00 1.9E+00 6.0E+00 10 100 8.62E+02 85% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
5.29E+00 2.9E+00 1.9E+00 6.0E+00
7.68E+00 4.2E+00 1.9E+00 6.0E+00
1.94E+01 6.8E+00 1.9E+00 6.0E+00
1.21E+01 4.5E+00 1.9E+00 6.0E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
7.77E+00 2.2E+00 1.9E+00 6.0E+00 10 100 8.42E+02 83% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
5.38E+00 2.9E+00 1.9E+00 6.0E+00
6.35E+00 1.2E+00 1.9E+00 6.0E+00
1.85E+01 6.7E+00 1.9E+00 6.0E+00
9.50E-01 3.2E+00 1.9E+00 6.0E+00
9.50E-01 3.8E+00 1.9E+00 6.0E+00
1.99E+00 3.5E+00 1.9E+00 6.0E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1757
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn CFS-L10-1316-T01-A 1 1.46E+03
Mn CFS-L10-1316-T02-A 1 2.62E+03
Mn CFS-L10-1316-T03-A 1 5.50E+03
Mn CFS-L10-1316-T04-A 1 8.35E+03
Mn CFS-L10-1316-T05-A 1 1.15E+04
Mn CFS-L10-1316-T01-B 1 1.59E+03
Mn CFS-L10-1316-T02-B 1 2.92E+03
Mn CFS-L10-1316-T03-B 1 5.81E+03
Mn CFS-L10-1316-T04-B 1 8.98E+03
Mn CFS-L10-1316-T05-B 1 1.28E+04
Mn CFS-L10-1316-T01-C 1 1.56E+03
Mn CFS-L10-1316-T02-C 1 2.77E+03
Mn CFS-L10-1316-T03-C 1 5.53E+03
Mn CFS-L10-1316-T04-C 1 8.75E+03
Mn CFS-L10-1316-T05-C 1 1.27E+04
Mn CFS-L10-1316-B01-A 1 1.00E+OOU1/2
Mn CFS-L10-1316-B02-A 1 1.00E+OOU1/2
Mn CFS-L10-1316-B03-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.46E+03 8.8E-01 2.0E+00 6.4E+00
2.62E+03 1.6E+00 2.0E+00 6.4E+00 10 100
5.50E+03 1.5E+00 2.0E+00 6.4E+00
8.35E+03 1.4E+00 2.0E+00 6.4E+00
1.15E+04 6.4E-01 2.0E+00 6.4E+00
1.59E+03 7.8E-01 2.0E+00 6.4E+00
2.92E+03 1.4E+00 2.0E+00 6.4E+00 10 100
5.81 E+03 1.5E-01 2.0E+00 6.4E+00
8.98E+03 7.4E-01 2.0E+00 6.4E+00
1.28E+04 6.3E-01 2.0E+00 6.4E+00
1.56E+03 2.0E+00 2.0E+00 6.4E+00
2.77E+03 6.2E-01 2.0E+00 6.4E+00 10 100
5.53E+03 1.5E-01 2.0E+00 6.4E+00
8.75E+03 5.3E-01 2.0E+00 6.4E+00
1.27E+04 1.4E+00 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00
1.00E+00 4.0E+01 2.0E+00 6.4E+00
1.00E+00 4.5E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
3.63E+03 101% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
3.92E+03 100% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
3.80E+03 104% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1758
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg CFS-L10-1316-T01-A 1 6.47E+04
Mg CFS-L10-1316-T02-A 1 1.22E+05
Mg CFS-L10-1316-T03-A 1 2.75E+05
Mg CFS-L10-1316-T04-A 1 5.10E+05
Mg CFS-L10-1316-T05-A 1 9.00E+05
Mg CFS-L10-1316-T01-B 1 6.79E+04
Mg CFS-L10-1316-T02-B 1 1.26E+05
Mg CFS-L10-1316-T03-B 1 2.79E+05
Mg CFS-L10-1316-T04-B 1 5.02E+05
Mg CFS-L10-1316-T05-B 1 8.78E+05
Mg CFS-L10-1316-T01-C 1 6.14E+04
Mg CFS-L10-1316-T02-C 1 1.22E+05
Mg CFS-L10-1316-T03-C 1 2.67E+05
Mg CFS-L10-1316-T04-C 1 4.81 E+05
Mg CFS-L10-1316-T05-C 1 8.72E+05
Mg CFS-L10-1316-B01-A 1 5.00E-01 U1/2
Mg CFS-L10-1316-B02-A 1 5.00E-01 U1/2
Mg CFS-L10-1316-B03-A 1 1.83E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.47E+04 7.9E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.22E+05 1.1E+00 1.0E+00 3.2E+00 1000 100 1.23E+05 91%VUICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
2.75E+05 6.9E-01 1. OE+00 3.2E+00
5.10E+05 1.2E+00 1. OE+00 3.2E+00
9.00E+05 1.3E+00 1. OE+00 3.2E+00
6.79E+04 1.3E+00 1. OE+00 3.2E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.26E+05 6.7E-01 1.0E+00 3.2E+00 1000 100 1.26E+05 87% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
2.79E+05 6.1E-01 1. OE+00 3.2E+00
5.02E+05 1.1E+00 1. OE+00 3.2E+00
8.78E+05 1. OE+00 1. OE+00 3.2E+00
6.14E+04 1.1E+00 1. OE+00 3.2E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.22E+05 5.2E-01 1.0E+00 3.2E+00 1000 100 1.22E+05 91% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
2.67E+05 1.6E+00 1. OE+00 3.2E+00
4.81 E+05 1.3E+00 1. OE+00 3.2E+00
8.72E+05 8.5E-01 1. OE+00 3.2E+00
5.00E-01 3.7E+02 1. OE+00 3.2E+00
5.00E-01 2.0E+03 1. OE+00 3.2E+00
1.83E+00 7.2E+01 1. OE+00 3.2E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1759
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo CFS-L10-1316-T01-A 1 9.48E+00
Mo CFS-L10-1316-T02-A 1 9.38E+00
Mo CFS-L10-1316-T03-A 1 1.33E+01
Mo CFS-L10-1316-T04-A 1 1.37E+01
Mo CFS-L10-1316-T05-A 1 2.09E+01
Mo CFS-L10-1316-T01-B 1 7.62E+00
Mo CFS-L10-1316-T02-B 1 8.17E+00
Mo CFS-L10-1316-T03-B 1 1.08E+01
Mo CFS-L10-1316-T04-B 1 1.35E+01
Mo CFS-L10-1316-T05-B 1 1.93E+01
Mo CFS-L10-1316-T01-C 1 6.96E+00
Mo CFS-L10-1316-T02-C 1 7.36E+00
Mo CFS-L10-1316-T03-C 1 1.15E+01
Mo CFS-L10-1316-T04-C 1 1.24E+01
Mo CFS-L10-1316-T05-C 1 1.56E+01
Mo CFS-L10-1316-B01-A 1 1.78E+OOE
Mo CFS-L10-1316-B02-A 1 1.54E+OOE
Mo CFS-L10-1316-B03-A 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.48E+00 1.5E+01 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
9.38E+00 7.4E+00 1 .2E+00 3.8E+00 10 100 1.07E+03 106% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
1.33E+01 5.2E+00 1.2E+00 3.8E+00
1.37E+01 1.4E+00 1.2E+00 3.8E+00
2.09E+01 3.0E+00 1.2E+00 3.8E+00
7.62E+00 7.9E+00 1.2E+00 3.8E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
8.17E+00 1.1E+01 1.2E+00 3.8E+00 10 100 9.83E+02 97% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
1.08E+01 1.2E+01 1.2E+00 3.8E+00
1.35E+01 1.7E+01 1.2E+00 3.8E+00
1.93E+01 9.7E+00 1.2E+00 3.8E+00
6.96E+00 1.1E+01 1.2E+00 3.8E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
7.36E+00 2.0E+01 1.2E+00 3.8E+00 10 100 1.06E+03 105% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
1.15E+01 1.6E+01 1.2E+00 3.8E+00
1.24E+01 1.1E+01 1.2E+00 3.8E+00
1.56E+01 1.5E+01 1.2E+00 3.8E+00
1.78E+00 3.6E+01 1.2E+00 3.8E+00
1.54E+00 3.4E+01 1.2E+00 3.8E+00
6.00E-01 1.1E+02 1.2E+00 3.8E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1760
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni CFS-L10-1316-T01-A 1 1.97E+02
Ni CFS-L10-1316-T02-A 1 3.19E+02
Ni CFS-L10-1316-T03-A 1 5.53E+02
Ni CFS-L10-1316-T04-A 1 7.30E+02
Ni CFS-L10-1316-T05-A 1 8.49E+02
Ni CFS-L10-1316-T01-B 1 2.14E+02
Ni CFS-L10-1316-T02-B 1 3.59E+02
Ni CFS-L10-1316-T03-B 1 6.05E+02
Ni CFS-L10-1316-T04-B 1 8.18E+02
Ni CFS-L10-1316-T05-B 1 1.01E+03
Ni CFS-L10-1316-T01-C 1 2.14E+02
Ni CFS-L10-1316-T02-C 1 3.36E+02
Ni CFS-L10-1316-T03-C 1 5.67E+02
Ni CFS-L10-1316-T04-C 1 8.12E+02
Ni CFS-L10-1316-T05-C 1 1.01E+03
Ni CFS-L10-1316-B01-A 1 9.00E-01 U1/2
Ni CFS-L10-1316-B02-A 1 9.00E-01 U1/2
Ni CFS-L10-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.97E+02 1.1E+00 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
3.19E+02 2.1E+00 1 .8E+00 5.7E+00 10 100 1.30E+03 98% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
5.53E+02 8.8E-01 1 .8E+00 5.7E+00
7.30E+02 1.0E+00 1 .8E+00 5.7E+00
8.49E+02 7.0E-01 1 .8E+00 5.7E+00
2.14E+02 7.4E-01 1.8E+00 5.7E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
3.59E+02 6.9E-01 1.8E+00 5.7E+00 10 100 1.30E+03 94% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
6.05E+02 5.0E-01 1.8E+00 5.7E+00
8.18E+02 8.0E-01 1.8E+00 5.7E+00
1.01E+03 4.7E-01 1.8E+00 5.7E+00
2.14E+02 7.8E-01 1.8E+00 5.7E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
3.36E+02 6.9E-01 1.8E+00 5.7E+00 10 100 1.32E+03 98% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
5.67E+02 5.7E-01 1.8E+00 5.7E+00
8.12E+02 9.5E-01 1.8E+00 5.7E+00
1.01E+03 5.0E-01 1.8E+00 5.7E+00
9.00E-01 2.6E+02 1.8E+00 5.7E+00
9.00E-01 1.1E+03 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1761
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
P Sample Dilution Cone. Qualifier Revi
ug/L
P CFS-L10-1316-T01-A 1 1.85E+OOU1/2
P CFS-L10-1316-T02-A 1 1.85E+OOU1/2
P CFS-L10-1316-T03-A 1 6.27E+00 E
P CFS-L10-1316-T04-A 1 9.05E+00 E
P CFS-L10-1316-T05-A 1 1.41E+01
P CFS-L10-1316-T01-B 1 1.85E+OOU1/2
P CFS-L10-1316-T02-B 1 1.85E+OOU1/2
P CFS-L10-1316-T03-B 1 4.30E+00 E
P CFS-L10-1316-T04-B 1 8.12E+00 E
P CFS-L10-1316-T05-B 1 1.47E+01
P CFS-L10-1316-T01-C 1 1.85E+OOU1/2
P CFS-L10-1316-T02-C 1 1.85E+OOU1/2
P CFS-L10-1316-T03-C 1 7.43E+00 E
P CFS-L10-1316-T04-C 1 1.04E+01 E
P CFS-L10-1316-T05-C 1 2.22E+01
P CFS-L10-1316-B01-A 1 1.85E+OOU1/2
P CFS-L10-1316-B02-A 1 1.85E+OOU1/2
P CFS-L10-1316-B03-A 1 1.85E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 6.2E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.85E+00 1.8E+02 3.7E+00 1.2E+01 1000 100 1.11E+03 1 11% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
6.27E+00 2.1E+02 3.7E+00 1.2E+01
9.05E+00 3.8E+02 3.7E+00 1.2E+01
1.41E+01 5.1E+02 3.7E+00 1.2E+01
1.85E+00 6.2E+03 3.7E+00 1.2E+01
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.85E+00 1.2E+02 3.7E+00 1.2E+01 1000 100 1.05E+03 104% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
4.30E+00 2.0E+02 3.7E+00 1.2E+01
8.12E+00 1.7E+02 3.7E+00 1.2E+01
1.47E+01 9.8E+01 3.7E+00 1.2E+01
1.85E+00 4.5E+02 3.7E+00 1.2E+01
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.85E+00 7.7E+01 3.7E+00 1.2E+01 1000 100 1.14E+03 114% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
7.43E+00 4.8E+01 3.7E+00 1.2E+01
1.04E+01 2.7E+02 3.7E+00 1.2E+01
2.22E+01 5.0E+01 3.7E+00 1.2E+01
1.85E+00 1.1E+02 3.7E+00 1.2E+01
1.85E+00 1.5E+02 3.7E+00 1.2E+01
1.85E+00 5.0E+02 3.7E+00 1.2E+01
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1762
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
ug/L
K CFS-L10-1316-T01-A 1 9.02E+03
K CFS-L10-1316-T02-A 1 1.52E+04
K CFS-L10-1316-T03-A 1 3.00E+04
K CFS-L10-1316-T04-A 1 4.74E+04
K CFS-L10-1316-T05-A 1 7.36E+04
K CFS-L10-1316-T01-B 1 9.09E+03
K CFS-L10-1316-T02-B 1 1.56E+04
K CFS-L10-1316-T03-B 1 2.91E+04
K CFS-L10-1316-T04-B 1 4.58E+04
K CFS-L10-1316-T05-B 1 6.89E+04
K CFS-L10-1316-T01-C 1 8.40E+03
K CFS-L10-1316-T02-C 1 1.47E+04
K CFS-L10-1316-T03-C 1 2.77E+04
K CFS-L10-1316-T04-C 1 4.42E+04
K CFS-L10-1316-T05-C 1 7.00E+04
K CFS-L10-1316-B01-A 1 9.73E+01
K CFS-L10-1316-B02-A 1 9.40E+01
K CFS-L10-1316-B03-A 1 8.52E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.02E+03 4.4E-01 1 .6E+00 5.1E+00
1.52E+04 1.8E+00 1 .6E+00 5.1E+00 1000 100
3.00E+04 1.3E+00 1 .6E+00 5.1E+00
4.74E+04 7.9E-01 1 .6E+00 5.1E+00
7.36E+04 8.8E-01 1 .6E+00 5.1E+00
9.09E+03 4.9E-01 1 .6E+00 5.1E+00
1.56E+04 7.9E-01 1 .6E+00 5.1E+00 1000 100
2.91E+04 5.3E-01 1 .6E+00 5.1E+00
4.58E+04 1.2E+00 1 .6E+00 5.1E+00
6.89E+04 5.5E-01 1 .6E+00 5.1E+00
8.40E+03 5.0E-01 1 .6E+00 5.1E+00
1.47E+04 4.0E-01 1 .6E+00 5.1E+00 1000 100
2.77E+04 6.3E-01 1.6E+00 5.1E+00
4.42E+04 5.5E-01 1.6E+00 5.1E+00
7.00E+04 6.3E-01 1.6E+00 5.1E+00
9.73E+01 2.8E+00 1.6E+00 5.1E+00
9.40E+01 3.3E+00 1.6E+00 5.1E+00
8.52E+01 1.4E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.62E+04 96%VUICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.65E+04 91%VUICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.56E+04 98% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1763
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se CFS-L10-1316-T01-A 1 8.72E+01
Se CFS-L10-1316-T02-A 1 1.30E+02
Se CFS-L10-1316-T03-A 1 2.69E+02
Se CFS-L10-1316-T04-A 1 4.77E+02
Se CFS-L10-1316-T05-A 1 8.43E+02
Se CFS-L10-1316-T01-B 1 7.99E+01
Se CFS-L10-1316-T02-B 1 1.45E+02
Se CFS-L10-1316-T03-B 1 2.63E+02
Se CFS-L10-1316-T04-B 1 4.90E+02
Se CFS-L10-1316-T05-B 1 8.00E+02
Se CFS-L10-1316-T01-C 1 9.48E+01
Se CFS-L10-1316-T02-C 1 1.24E+02
Se CFS-L10-1316-T03-C 1 2.53E+02
Se CFS-L10-1316-T04-C 1 4.45E+02
Se CFS-L10-1316-T05-C 1 8.08E+02
Se CFS-L10-1316-B01-A 1 7.50E+00 U1/2
Se CFS-L10-1316-B02-A 1 7.50E+00 U1/2
Se CFS-L10-1316-B03-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.72E+01 8.6E+00 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.30E+02 1.6E+01 1.5E+01 4.8E+01 10 100 1.18E+03 105% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
2.69E+02 4.6E+00 1.5E+01 4.8E+01
4.77E+02 3.2E+00 1.5E+01 4.8E+01
8.43E+02 7.0E-01 1.5E+01 4.8E+01
7.99E+01 1.1E+01 1.5E+01 4.8E+01
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.45E+02 1.8E+00 1.5E+01 4.8E+01 10 100 1.08E+03 93% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
2.63E+02 4.5E+00 1.5E+01 4.8E+01
4.90E+02 4.5E+00 1.5E+01 4.8E+01
8.00E+02 1.5E+00 1.5E+01 4.8E+01
9.48E+01 1.5E+01 1.5E+01 4.8E+01
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.24E+02 8.3E+00 1.5E+01 4.8E+01 10 100 1.13E+03 101% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
2.53E+02 5.9E+00 1.5E+01 4.8E+01
4.45E+02 3.4E+00 1.5E+01 4.8E+01
8.08E+02 2.1E+00 1.5E+01 4.8E+01
7.50E+00 9.6E+01 1.5E+01 4.8E+01
7.50E+00 1.2E+02 1.5E+01 4.8E+01
7.50E+00 7.9E+01 1.5E+01 4.8E+01
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1764
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si CFS-L10-1316-T01-A 1 3.48E+03
Si CFS-L10-1316-T02-A 1 4.41E+03
Si CFS-L10-1316-T03-A 1 5.76E+03
Si CFS-L10-1316-T04-A 1 6.26E+03
Si CFS-L10-1316-T05-A 1 6.53E+03
Si CFS-L10-1316-T01-B 1 3.57E+03
Si CFS-L10-1316-T02-B 1 4.59E+03
Si CFS-L10-1316-T03-B 1 5.84E+03
Si CFS-L10-1316-T04-B 1 6.29E+03
Si CFS-L10-1316-T05-B 1 6.41E+03
Si CFS-L10-1316-T01-C 1 3.46E+03
Si CFS-L10-1316-T02-C 1 4.36E+03
Si CFS-L10-1316-T03-C 1 5.56E+03
Si CFS-L10-1316-T04-C 1 6.24E+03
Si CFS-L10-1316-T05-C 1 6.36E+03
Si CFS-L10-1316-B01-A 1 1.03E+01
Si CFS-L10-1316-B02-A 1 1.14E+01
Si CFS-L10-1316-B03-A 1 1.57E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.48E+03 5.8E-01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
4.41E+03 9.5E-01 1.1E+00 3.5E+00 1000 100 5.34E+03 93% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
5.76E+03 1.3E+00 1.1E+00 3.5E+00
6.26E+03 7.7E-01 1.1E+00 3.5E+00
6.53E+03 7.6E-01 1.1E+00 3.5E+00
3.57E+03 1.1E+00 1.1E+00 3.5E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
4.59E+03 1.5E+00 1.1E+00 3.5E+00 1000 100 5.47E+03 88% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
5.84E+03 2.4E-01 1.1E+00 3.5E+00
6.29E+03 9.6E-01 1.1E+00 3.5E+00
6.41 E+03 3.1E-01 1.1E+00 3.5E+00
3.46E+03 8.1E-01 1.1E+00 3.5E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
4.36E+03 1.7E+00 1.1E+00 3.5E+00 1000 100 5.24E+03 88% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
5.56E+03 6.6E-01 1.1E+00 3.5E+00
6.24E+03 6.2E-01 1.1E+00 3.5E+00
6.36E+03 8.0E-01 1.1E+00 3.5E+00
1.03E+01 1.5E+01 1.1E+00 3.5E+00
1.14E+01 1.3E+01 1.1E+00 3.5E+00
1.57E+01 1.1E+01 1.1E+00 3.5E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1765
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na CFS-L10-1316-T01-A 1 1.74E+04
Na CFS-L10-1316-T02-A 1 3.31 E+04
Na CFS-L10-1316-T03-A 1 7.10E+04
Na CFS-L10-1316-T04-A 1 1.12E+05
Na CFS-L10-1316-T05-A 1 1.72E+05
Na CFS-L10-1316-T01-B 1 1.81 E+04
Na CFS-L10-1316-T02-B 1 3.50E+04
Na CFS-L10-1316-T03-B 1 7.24E+04
Na CFS-L10-1316-T04-B 1 1.13E+05
Na CFS-L10-1316-T05-B 1 1.67E+05
Na CFS-L10-1316-T01-C 1 1.73E+04
Na CFS-L10-1316-T02-C 1 3.26E+04
Na CFS-L10-1316-T03-C 1 6.60E+04
Na CFS-L10-1316-T04-C 1 1.09E+05
Na CFS-L10-1316-T05-C 1 1.67E+05
Na CFS-L10-1316-B01-A 1 3.14E+01
Na CFS-L10-1316-B02-A 1 1.86E+01
Na CFS-L10-1316-B03-A 1 2.09E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.74E+04 7.0E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
3.31E+04 1.3E+00 2.5E+00 8.0E+00 1000 100 3.40E+04 95% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
7.10E+04 3.8E-01 2.5E+00 8.0E+00
1.12E+05 5.1E-01 2.5E+00 8.0E+00
1.72E+05 8.0E-01 2.5E+00 8.0E+00
1.81 E+04 1.5E-01 2.5E+00 8.0E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
3.50E+04 1.4E+00 2.5E+00 8.0E+00 1000 100 3.60E+04 97% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
7.24E+04 6.3E-01 2.5E+00 8.0E+00
1.13E+05 3.5E-01 2.5E+00 8.0E+00
1.67E+05 1.7E+00 2.5E+00 8.0E+00
1.73E+04 4.3E-01 2.5E+00 8.0E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
3.26E+04 3.2E-01 2.5E+00 8.0E+00 1000 100 3.35E+04 91% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
6.60E+04 6.3E-01 2.5E+00 8.0E+00
1.09E+05 4.0E-01 2.5E+00 8.0E+00
1.67E+05 8.0E-01 2.5E+00 8.0E+00
3.14E+01 6.0E+00 2.5E+00 8.0E+00
1.86E+01 3.0E+00 2.5E+00 8.0E+00
2.09E+01 5.1E+00 2.5E+00 8.0E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1766
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L10-1316-T01-A 1 1.39E+03
CFS-L10-1316-T02-A 1 1.78E+03
CFS-L10-1316-T03-A 1 2.67E+03
CFS-L10-1316-T04-A 1 3.62E+03
CFS-L10-1316-T05-A 1 4.80E+03
CFS-L10-1316-T01-B 1 1.34E+03
CFS-L10-1316-T02-B 1 1.72E+03
CFS-L10-1316-T03-B 1 2.47E+03
CFS-L10-1316-T04-B 1 3.15E+03
CFS-L10-1316-T05-B 1 4.11E+03
CFS-L10-1316-T01-C 1 1.22E+03
CFS-L10-1316-T02-C 1 1.70E+03
CFS-L10-1316-T03-C 1 2.46E+03
CFS-L10-1316-T04-C 1 3.10E+03
CFS-L10-1316-T05-C 1 4.10E+03
CFS-L10-1316-B01-A 1 5.00E-01 U1/2
CFS-L10-1316-B02-A 1 5.00E-01 U1/2
CFS-L10-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.39E+03 3.5E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.78E+03 7.2E-01 1 .OE+00 3.2E+00 1000 100 2.83E+03 105% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
2.67E+03 1.8E+00 1 .OE+00 3.2E+00
3.62E+03 5.2E-01 1 .OE+00 3.2E+00
4.80E+03 1.8E-01 1 .OE+00 3.2E+00
1.34E+03 7.3E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.72E+03 1.5E+00 1 .OE+00 3.2E+00 1000 100 2.79E+03 107% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
2.47E+03 1.4E-01 1 .OE+00 3.2E+00
3.15E+03 5.6E-01 1 .OE+00 3.2E+00
4.11E+03 1. OE+00 1. OE+00 3.2E+00
1.22E+03 7.6E-01 1 .OE+00 3.2E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.70E+03 1.2E+00 1 .OE+00 3.2E+00 1000 100 2.81E+03 11 1% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
2.46E+03 5.1E-01 1.0E+00 3.2E+00
3.10E+03 9.4E-01 1. OE+00 3.2E+00
4.10E+03 6.3E-01 1. OE+00 3.2E+00
5.00E-01 8.3E+01 1. OE+00 3.2E+00
5.00E-01 8.8E+01 1. OE+00 3.2E+00
5.00E-01 4.2E+02 1. OE+00 3.2E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1767
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S CFS-L10-1316-T01-A 1 5.78E+05
S CFS-L10-1316-T02-A 1 6.34E+05
S CFS-L10-1316-T03-A 1 8.14E+05
S CFS-L10-1316-T04-A 1 1.08E+06
S CFS-L10-1316-T05-A 1 1.48E+06
S CFS-L10-1316-T01-B 1 5.91 E+05
S CFS-L10-1316-T02-B 1 6.44E+05
S CFS-L10-1316-T03-B 1 8.07E+05
S CFS-L10-1316-T04-B 1 1.05E+06
S CFS-L10-1316-T05-B 1 1.43E+06
S CFS-L10-1316-T01-C 1 5.39E+05
S CFS-L10-1316-T02-C 1 6.09E+05
S CFS-L10-1316-T03-C 1 7.67E+05
S CFS-L10-1316-T04-C 1 1.02E+06
S CFS-L10-1316-T05-C 1 1.43E+06
S CFS-L10-1316-B01-A 1 6.12E+01
S CFS-L10-1316-B02-A 1 5.31 E+01
S CFS-L10-1316-B03-A 1 6.19E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.78E+05 4.2E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
6.34E+05 1.9E+00 6.8E+00 2.2E+01 1000 100 6.35E+05 95% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
8.14E+05 5.7E-01 6.8E+00 2.2E+01
1.08E+06 1.0E+00 6.8E+00 2.2E+01
1.48E+06 6.8E-01 6.8E+00 2.2E+01
5.91 E+05 3.0E-01 6.8E+00 2.2E+01
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
6.44E+05 1.2E+00 6.8E+00 2.2E+01 1000 100 6.45E+05 86% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
8.07E+05 2.3E-01 6.8E+00 2.2E+01
1.05E+06 7.0E-01 6.8E+00 2.2E+01
1.43E+06 4.0E-01 6.8E+00 2.2E+01
5.39E+05 3.7E-01 6.8E+00 2.2E+01
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
6.09E+05 3.2E-01 6.8E+00 2.2E+01 1000 100 6.10E+05 94% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
7.67E+05 9.6E-01 6.8E+00 2.2E+01
1.02E+06 5.3E-01 6.8E+00 2.2E+01
1.43E+06 6.5E-01 6.8E+00 2.2E+01
6.12E+01 1.6E+01 6.8E+00 2.2E+01
5.31E+01 2.6E+01 6.8E+00 2.2E+01
6.19E+01 5.9E+00 6.8E+00 2.2E+01
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1768
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl CFS-L10-1316-T01-A 1 2.85E+02
Tl CFS-L10-1316-T02-A 1 4.20E+02
Tl CFS-L10-1316-T03-A 1 6.93E+02
Tl CFS-L10-1316-T04-A 1 9.61 E+02
Tl CFS-L10-1316-T05-A 1 1.45E+03
Tl CFS-L10-1316-T01-B 1 2.82E+02
Tl CFS-L10-1316-T02-B 1 4.33E+02
Tl CFS-L10-1316-T03-B 1 6.88E+02
Tl CFS-L10-1316-T04-B 1 9.75E+02
Tl CFS-L10-1316-T05-B 1 1.34E+03
Tl CFS-L10-1316-T01-C 1 2.70E+02
Tl CFS-L10-1316-T02-C 1 4.17E+02
Tl CFS-L10-1316-T03-C 1 6.65E+02
Tl CFS-L10-1316-T04-C 1 9.54E+02
Tl CFS-L10-1316-T05-C 1 1.33E+03
Tl CFS-L10-1316-B01-A 1 2.30E+00 U1/2
Tl CFS-L10-1316-B02-A 1 2.30E+00 U1/2
Tl CFS-L10-1316-B03-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.85E+02 2.2E+00 4.6E+00 1.5E+01
4.20E+02 1.8E+00 4.6E+00 1.5E+01 10 100
6.93E+02 1.8E+00 4.6E+00 1.5E+01
9.61 E+02 1.4E+00 4.6E+00 1.5E+01
1.45E+03 4.8E-01 4.6E+00 1.5E+01
2.82E+02 3.5E-01 4.6E+00 1.5E+01
4.33E+02 1.1E+00 4.6E+00 1.5E+01 10 100
6.88E+02 9.9E-01 4.6E+00 1.5E+01
9.75E+02 3.0E-01 4.6E+00 1.5E+01
1.34E+03 2.5E-01 4.6E+00 1.5E+01
2.70E+02 7.9E-01 4.6E+00 1.5E+01
4.17E+02 9.6E-01 4.6E+00 1.5E+01 10 100
6.65E+02 7.1E-01 4.6E+00 1.5E+01
9.54E+02 3.1E-01 4.6E+00 1.5E+01
1.33E+03 1.7E-01 4.6E+00 1.5E+01
2.30E+00 9.3E+00 4.6E+00 1.5E+01
2.30E+00 6.3E+00 4.6E+00 1.5E+01
2.30E+00 1.5E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.37E+03 95%VUICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.30E+03 86%VUICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.33E+03 91% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1769
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti CFS-L10-1316-T01-A 1 1.00E+OOU1/2
Ti CFS-L10-1316-T02-A 1 1.00E+OOU1/2
Ti CFS-L10-1316-T03-A 1 1.00E+OOU1/2
Ti CFS-L10-1316-T04-A 1 1.00E+OOU1/2
Ti CFS-L10-1316-T05-A 1 1.00E+OOU1/2
Ti CFS-L10-1316-T01-B 1 1.00E+OOU1/2
Ti CFS-L10-1316-T02-B 1 1.00E+OOU1/2
Ti CFS-L10-1316-T03-B 1 1.00E+OOU1/2
Ti CFS-L10-1316-T04-B 1 1.00E+OOU1/2
Ti CFS-L10-1316-T05-B 1 1.00E+OOU1/2
Ti CFS-L10-1316-T01-C 1 1.00E+OOU1/2
Ti CFS-L10-1316-T02-C 1 1.00E+OOU1/2
Ti CFS-L10-1316-T03-C 1 1.00E+OOU1/2
Ti CFS-L10-1316-T04-C 1 1.00E+OOU1/2
Ti CFS-L10-1316-T05-C 1 1.00E+OOU1/2
Ti CFS-L10-1316-B01-A 1 1.00E+OOU1/2
Ti CFS-L10-1316-B02-A 1 1.00E+OOU1/2
Ti CFS-L10-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 3.8E+01 2.0E+00 6.4E+00 10 100 1.11E+03 1 10% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 9.1E+01 2.0E+00 6.4E+00
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 8.8E+02 2.0E+00 6.4E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 1.1E+02 2.0E+00 6.4E+00 10 100 9.78E+02 98% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 3.3E+02 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 5.6E+01 2.0E+00 6.4E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 3.9E+03 2.0E+00 6.4E+00 10 100 1.05E+03 105% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 7.0E+01 2.0E+00 6.4E+00
1.00E+00 6.4E+01 2.0E+00 6.4E+00
1.00E+00 1.9E+02 2.0E+00 6.4E+00
1.00E+00 7.9E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1770
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V CFS-L10-1316-T01-A 1 2.77E+01
V CFS-L10-1316-T02-A 1 2.57E+01
V CFS-L10-1316-T03-A 1 2.50E+01
V CFS-L10-1316-T04-A 1 2.43E+01
V CFS-L10-1316-T05-A 1 2.40E+01
V CFS-L10-1316-T01-B 1 2.87E+01
V CFS-L10-1316-T02-B 1 2.76E+01
V CFS-L10-1316-T03-B 1 2.52E+01
V CFS-L10-1316-T04-B 1 2.32E+01
V CFS-L10-1316-T05-B 1 2.17E+01
V CFS-L10-1316-T01-C 1 2.50E+01
V CFS-L10-1316-T02-C 1 2.51E+01
V CFS-L10-1316-T03-C 1 2.40E+01
V CFS-L10-1316-T04-C 1 2.23E+01
V CFS-L10-1316-T05-C 1 2.12E+01
V CFS-L10-1316-B01-A 1 7.50E-01 U1/2
V CFS-L10-1316-B02-A 1 7.50E-01 U1/2
V CFS-L10-1316-B03-A 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.77E+01 4.7E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
2.57E+01 2.0E-01 1 .5E+00 4.8E+00 10 100 1.13E+03 110% VU ICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
2.50E+01 5.5E+00 1 .5E+00 4.8E+00
2.43E+01 5.0E+00 1 .5E+00 4.8E+00
2.40E+01 5.2E+00 1 .5E+00 4.8E+00
2.87E+01 3.6E+00 1 .5E+00 4.8E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
2.76E+01 1.7E+00 1 .5E+00 4.8E+00 10 100 9.86E+02 96% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
2.52E+01 1.5E+00 1 .5E+00 4.8E+00
2.32E+01 4.9E-01 1 .5E+00 4.8E+00
2.17E+01 6.2E+00 1 .5E+00 4.8E+00
2.50E+01 5.9E+00 1 .5E+00 4.8E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
2.51E+01 3.7E+00 1 .5E+00 4.8E+00 10 100 1.08E+03 105% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
2.40E+01 9.7E-01 1.5E+00 4.8E+00
2.23E+01 4.6E+00 1.5E+00 4.8E+00
2.12E+01 4.4E+00 1.5E+00 4.8E+00
7.50E-01 4.9E+01 1.5E+00 4.8E+00
7.50E-01 6.4E+01 1.5E+00 4.8E+00
7.50E-01 3.8E+01 1.5E+00 4.8E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1771
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn CFS-L10-1316-T01-A 1 1.93E+04
Zn CFS-L10-1316-T02-A 1 2.79E+04
Zn CFS-L10-1316-T03-A 1 4.25E+04
Zn CFS-L10-1316-T04-A 1 5.22E+04
Zn CFS-L10-1316-T05-A 1 5.34E+04
Zn CFS-L10-1316-T01-B 1 2.10E+04
Zn CFS-L10-1316-T02-B 1 3.22E+04
Zn CFS-L10-1316-T03-B 1 4.69E+04
Zn CFS-L10-1316-T04-B 1 5.81 E+04
Zn CFS-L10-1316-T05-B 1 6.55E+04
Zn CFS-L10-1316-T01-C 1 2.14E+04
Zn CFS-L10-1316-T02-C 1 2.92E+04
Zn CFS-L10-1316-T03-C 1 4.36E+04
Zn CFS-L10-1316-T04-C 1 5.77E+04
Zn CFS-L10-1316-T05-C 1 6.49E+04
Zn CFS-L10-1316-B01-A 1 2.25E+00 E
Zn CFS-L10-1316-B02-A 1 3.68E+00
Zn CFS-L10-1316-B03-A 1 2.89E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.93E+04 9.0E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 4/13/11 3:44 PM EPA Interlab L10 1313-1316 CFS
2.79E+04 7.8E-01 1 .OE+00 3.2E+00 10 100 2.88E+04 91%VUICP-OES 4/13/11 3:45 PM EPA Interlab L10 1313-1316 CFS
4.25E+04 1.4E+00 1 .OE+00 3.2E+00
5.22E+04 2.5E-01 1 .OE+00 3.2E+00
5.34E+04 1.2E+00 1 .OE+00 3.2E+00
2.10E+04 1.6E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/13/11 3:47 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:49 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:50 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:52 PM EPA Interlab L10 1313-1316 CFS
3.22E+04 1.3E+00 1 .OE+00 3.2E+00 10 100 3.30E+04 86% VU ICP-OES 4/13/11 3:53 PM EPA Interlab L10 1313-1316 CFS
4.69E+04 5.5E-01 1 .OE+00 3.2E+00
5.81 E+04 1.2E+00 1 .OE+00 3.2E+00
6.55E+04 2.2E-01 1 .OE+00 3.2E+00
2.14E+04 1.2E+00 1 .OE+00 3.2E+00
VU ICP-OES 4/13/11 3:55 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:57 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:58 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:00 PM EPA Interlab L10 1313-1316 CFS
2.92E+04 5.8E-01 1 .OE+00 3.2E+00 10 100 3.01E+04 94% VU ICP-OES 4/13/11 4:02 PM EPA Interlab L10 1313-1316 CFS
4.36E+04 4.0E-01 1. OE+00 3.2E+00
5.77E+04 8.0E-01 1. OE+00 3.2E+00
6.49E+04 5.0E-01 1. OE+00 3.2E+00
2.25E+00 8.5E+00 1. OE+00 3.2E+00
3.68E+00 1.3E+01 1. OE+00 3.2E+00
2.89E+00 2.3E+00 1. OE+00 3.2E+00
VU ICP-OES 4/13/11 4:03 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:05 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 4:07 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:39 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:40 PM EPA Interlab L10 1313-1316 CFS
VU ICP-OES 4/13/11 3:42 PM EPA Interlab L10 1313-1316 CFS
                                                                                                                                                                         1-1772
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al CFS-L11-1316-T01-A 1 5.00E+01
Al CFS-L11-1316-T02-A 1 3.86E+01
Al CFS-L11-1316-T03-A 1 4.83E+01
Al CFS-L11-1316-T04-A 1 2.92E+01
Al CFS-L11-1316-T05-A 1 5.41 E+01
Al CFS-L11-1316-T01-B 1 4.95E+01
Al CFS-L11-1316-T02-B 1 4.77E+01
Al CFS-L11-1316-T03-B 1 5.21E+01
Al CFS-L11-1316-T04-B 1 5.35E+01
Al CFS-L11-1316-T05-B 1 5.45E+01
Al CFS-L11-1316-T01-C 1 5.15E+01
Al CFS-L11-1316-T02-C 1 4.74E+01
Al CFS-L11-1316-T03-C 1 4.63E+01
Al CFS-L11-1316-T04-C 1 5.35E+01
Al CFS-L11-1316-T05-C 1 5.36E+01
Al CFS-L11-1316-B01-A 1 5.00E-01 U1/2
Al CFS-L11-1316-B02-A 1 5.00E-01 U1/2
Al CFS-L11-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E+01 3.9E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
3.86E+01 6.9E+01 1 .OE+00 3.2E+00 1000 100 1.11E+03 107% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
4.83E+01 2.8E+00 1 .OE+00 3.2E+00
2.92E+01 1.0E+02 1 .OE+00 3.2E+00
5.41 E+01 8.0E+00 1 .OE+00 3.2E+00
4.95E+01 5.9E+00 1 .OE+00 3.2E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
4.77E+01 4.8E+00 1 .OE+00 3.2E+00 1000 100 1.15E+03 110% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
5.21 E+01 2.6E+00 1 .OE+00 3.2E+00
5.35E+01 8.9E+00 1 .OE+00 3.2E+00
5.45E+01 6.2E+00 1 .OE+00 3.2E+00
5.15E+01 2.4E+00 1 .OE+00 3.2E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
4.74E+01 6.4E+00 1 .OE+00 3.2E+00 1000 100 1.16E+03 11 1% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
4.63E+01 6.1E+00 1 .OE+00 3.2E+00
5.35E+01 1.0E+01 1. OE+00 3.2E+00
5.36E+01 3.1E+00 1 .OE+00 3.2E+00
5.00E-01 2.5E+01 1 .OE+00 3.2E+00
5.00E-01 2.8E+01 1 .OE+00 3.2E+00
5.00E-01 9.0E+00 1 .OE+00 3.2E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:OOAM EPA Interlab L11 1313-1316CFS
                                                                                                                                                                                  1-1773
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb CFS-L11-1316-T01-A 1 2.55E+01
Sb CFS-L11-1316-T02-A 1 1.27E+01 E
Sb CFS-L11-1316-T03-A 1 3.28E+01
Sb CFS-L11-1316-T04-A 1 1.64E+01 E
Sb CFS-L11-1316-T05-A 1 4.71E+01
Sb CFS-L11-1316-T01-B 1 2.19E+01 E
Sb CFS-L11-1316-T02-B 1 2.97E+01
Sb CFS-L11-1316-T03-B 1 4.28E+01
Sb CFS-L11-1316-T04-B 1 4.63E+01
Sb CFS-L11-1316-T05-B 1 4.72E+01
Sb CFS-L11-1316-T01-C 1 3.04E+01
Sb CFS-L11-1316-T02-C 1 2.72E+01
Sb CFS-L11-1316-T03-C 1 3.35E+01
Sb CFS-L11-1316-T04-C 1 3.43E+01
Sb CFS-L11-1316-T05-C 1 4.05E+01
Sb CFS-L11-1316-B01-A 1 3.75E+00 U1/2
Sb CFS-L11-1316-B02-A 1 3.75E+00 U1/2
Sb CFS-L11-1316-B03-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.55E+01 1.7E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
1.27E+01 1.1E+02 7.5E+00 2.4E+01 10 100 8.86E+02 87% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
3.28E+01 1.9E+01 7.5E+00 2.4E+01
1.64E+01 1.7E+02 7.5E+00 2.4E+01
4.71E+01 1.2E+01 7.5E+00 2.4E+01
2.19E+01 1.9E+01 7.5E+00 2.4E+01
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
2.97E+01 2.4E+01 7.5E+00 2.4E+01 10 100 9.16E+02 89% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
4.28E+01 1.8E+01 7.5E+00 2.4E+01
4.63E+01 2.0E+01 7.5E+00 2.4E+01
4.72E+01 2.7E+00 7.5E+00 2.4E+01
3.04E+01 4.2E+01 7.5E+00 2.4E+01
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
2.72E+01 2.2E+01 7.5E+00 2.4E+01 10 100 9.16E+02 89% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
3.35E+01 5.0E+01 7.5E+00 2.4E+01
3.43E+01 2.5E+01 7.5E+00 2.4E+01
4.05E+01 1.4E+01 7.5E+00 2.4E+01
3.75E+00 7.8E+01 7.5E+00 2.4E+01
3.75E+00 1.3E+02 7.5E+00 2.4E+01
3.75E+00 1.7E+02 7.5E+00 2.4E+01
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1774
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
As Sample Dilution Cone. Qualifier Revi
ug/L
As CFS-L11-1316-T01-A 1 1.88E+01 E
As CFS-L11-1316-T02-A 1 1.54E+01 E
As CFS-L11-1316-T03-A 1 3.04E+01 E
As CFS-L11-1316-T04-A 1 1.99E+01 E
As CFS-L11-1316-T05-A 1 2.67E+01 E
As CFS-L11-1316-T01-B 1 2.51E+01 E
As CFS-L11-1316-T02-B 1 2.49E+01 E
As CFS-L11-1316-T03-B 1 2.70E+01 E
As CFS-L11-1316-T04-B 1 3.64E+01
As CFS-L11-1316-T05-B 1 3.88E+01
As CFS-L11-1316-T01-C 1 2.52E+01 E
As CFS-L11-1316-T02-C 1 3.02E+01 E
As CFS-L11-1316-T03-C 1 2.80E+01 E
As CFS-L11-1316-T04-C 1 2.93E+01 E
As CFS-L11-1316-T05-C 1 3.27E+01 E
As CFS-L11-1316-B01-A 1 5.50E+00 U1/2
As CFS-L11-1316-B02-A 1 5.50E+00 U1/2
As CFS-L11-1316-B03-A 1 5.50E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.88E+01 8.9E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
1.54E+01 5.6E+01 1.1E+01 3.5E+01 10 100 9.07E+02 89% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
3.04E+01 1.4E+01 1.1E+01 3.5E+01
1.99E+01 1.2E+02 1.1E+01 3.5E+01
2.67E+01 1.5E+01 1.1E+01 3.5E+01
2.51E+01 2.4E+01 1.1E+01 3.5E+01
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
2.49E+01 1.9E+01 1.1E+01 3.5E+01 10 100 9.28E+02 90% VU ICP-OES 5/31/11 11:11 AM EPA Interlab L11 1313-1316 CFS
2.70E+01 4.3E+01 1.1E+01 3.5E+01
3.64E+01 2.7E+01 1.1E+01 3.5E+01
3.88E+01 3.4E+01 1.1E+01 3.5E+01
2.52E+01 3.6E+01 1.1E+01 3.5E+01
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
3.02E+01 4.9E+01 1.1E+01 3.5E+01 10 100 9.26E+02 90% VU ICP-OES 5/31/11 11 :19 AM EPA Interlab L11 1313-1316 CFS
2.80E+01 3.4E+01 1.1E+01 3.5E+01
2.93E+01 3.5E+01 1.1E+01 3.5E+01
3.27E+01 1.2E+01 1.1E+01 3.5E+01
5.50E+00 1.6E+02 1.1E+01 3.5E+01
5.50E+00 6.1E+01 1.1E+01 3.5E+01
5.50E+00 1.6E+02 1.1E+01 3.5E+01
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:OOAM EPA Interlab L11 1313-1316CFS
                                                                                                                                                                         1-1775
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B CFS-L11-1316-T01-A 1 6.27E+01
B CFS-L11-1316-T02-A 1 5.89E+01
B CFS-L11-1316-T03-A 1 3.79E+02
B CFS-L11-1316-T04-A 1 2.47E+02
B CFS-L11-1316-T05-A 1 1.05E+03
B CFS-L11-1316-T01-B 1 7.11E+01
B CFS-L11-1316-T02-B 1 1.51E+02
B CFS-L11-1316-T03-B 1 3.80E+02
B CFS-L11-1316-T04-B 1 5.93E+02
B CFS-L11-1316-T05-B 1 1.03E+03
B CFS-L11-1316-T01-C 1 7.15E+01
B CFS-L11-1316-T02-C 1 1.65E+02
B CFS-L11-1316-T03-C 1 3.67E+02
B CFS-L11-1316-T04-C 1 6.56E+02
B CFS-L11-1316-T05-C 1 1.05E+03
B CFS-L11-1316-B01-A 1 5.00E-01 U1/2
B CFS-L11-1316-B02-A 1 5.00E-01 U1/2
B CFS-L11-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.27E+01 2.4E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
5.89E+01 2.0E+02 1 .OE+00 3.2E+00 1000 100 9.82E+02 92% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
3.79E+02 6.7E-01 1 .OE+00 3.2E+00
2.47E+02 1.8E+02 1 .OE+00 3.2E+00
1.05E+03 8.9E-01 1 .OE+00 3.2E+00
7.11E+01 2.6E+00 1. OE+00 3.2E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
1.51E+02 6.7E-01 1 .OE+00 3.2E+00 1000 100 1 .02E+03 87% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
3.80E+02 1.3E+00 1 .OE+00 3.2E+00
5.93E+02 9.0E-01 1 .OE+00 3.2E+00
1.03E+03 1.3E+00 1 .OE+00 3.2E+00
7.15E+01 3.2E+00 1 .OE+00 3.2E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
1.65E+02 4.3E+00 1 .OE+00 3.2E+00 1000 100 1.03E+03 87% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
3.67E+02 1.7E+00 1. OE+00 3.2E+00
6.56E+02 9.6E-01 1. OE+00 3.2E+00
1.05E+03 4.8E-01 1. OE+00 3.2E+00
5.00E-01 2.4E+00 1. OE+00 3.2E+00
5.00E-01 1.8E+00 1. OE+00 3.2E+00
5.00E-01 6.9E-01 1. OE+00 3.2E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1776
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba CFS-L11-1316-T01-A 1 2.26E+02
Ba CFS-L11-1316-T02-A 1 1.37E+02
Ba CFS-L11-1316-T03-A 1 3.85E+02
Ba CFS-L11-1316-T04-A 1 2.56E+02
Ba CFS-L11-1316-T05-A 1 8.11E+02
Ba CFS-L11-1316-T01-B 1 2.30E+02
Ba CFS-L11-1316-T02-B 1 2.67E+02
Ba CFS-L11-1316-T03-B 1 3.91 E+02
Ba CFS-L11-1316-T04-B 1 5.39E+02
Ba CFS-L11-1316-T05-B 1 8.20E+02
Ba CFS-L11-1316-T01-C 1 2.35E+02
Ba CFS-L11-1316-T02-C 1 2.68E+02
Ba CFS-L11-1316-T03-C 1 3.71 E+02
Ba CFS-L11-1316-T04-C 1 5.48E+02
Ba CFS-L11-1316-T05-C 1 8.18E+02
Ba CFS-L11-1316-B01-A 1 5.00E-01 U1/2
Ba CFS-L11-1316-B02-A 1 5.00E-01 U1/2
Ba CFS-L11-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.26E+02 3.2E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
1.37E+02 9.9E+01 1 .OE+00 3.2E+00 10 100 9.74E+02 84% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
3.85E+02 5.7E-01 1. OE+00 3.2E+00
2.56E+02 1.4E+02 1. OE+00 3.2E+00
8. 11 E+02 8.9E-01 1. OE+00 3.2E+00
2.30E+02 7.5E-01 1. OE+00 3.2E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
2.67E+02 5.4E-01 1.0E+00 3.2E+00 10 100 1.20E+03 94% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
3.91 E+02 9.0E-01 1. OE+00 3.2E+00
5.39E+02 1.3E-01 1. OE+00 3.2E+00
8.20E+02 1.1E+00 1. OE+00 3.2E+00
2.35E+02 5.6E-01 1. OE+00 3.2E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316 CFS
2.68E+02 2.5E+00 1.0E+00 3.2E+00 10 100 1.20E+03 93% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
3.71 E+02 3.7E+00 1. OE+00 3.2E+00
5.48E+02 1.4E-01 1. OE+00 3.2E+00
8.18E+02 3.2E-01 1. OE+00 3.2E+00
5.00E-01 2.3E+02 1. OE+00 3.2E+00
5.00E-01 5.8E+02 1. OE+00 3.2E+00
5.00E-01 6.7E+01 1. OE+00 3.2E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1777
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be CFS-L11-1316-T01-A 1 9.50E-01 U1/2
Be CFS-L11-1316-T02-A 1 9.50E-01 U1/2
Be CFS-L11-1316-T03-A 1 9.50E-01 U1/2
Be CFS-L11-1316-T04-A 1 9.50E-01 U1/2
Be CFS-L11-1316-T05-A 1 9.50E-01 U1/2
Be CFS-L11-1316-T01-B 1 9.50E-01 U1/2
Be CFS-L11-1316-T02-B 1 9.50E-01 U1/2
Be CFS-L11-1316-T03-B 1 9.50E-01 U1/2
Be CFS-L11-1316-T04-B 1 9.50E-01 U1/2
Be CFS-L11-1316-T05-B 1 9.50E-01 U1/2
Be CFS-L11-1316-T01-C 1 9.50E-01 U1/2
Be CFS-L11-1316-T02-C 1 9.50E-01 U1/2
Be CFS-L11-1316-T03-C 1 9.50E-01 U1/2
Be CFS-L11-1316-T04-C 1 9.50E-01 U1/2
Be CFS-L11-1316-T05-C 1 9.50E-01 U1/2
Be CFS-L11-1316-B01-A 1 9.50E-01 U1/2
Be CFS-L11-1316-B02-A 1 9.50E-01 U1/2
Be CFS-L11-1316-B03-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.5E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
9.50E-01 2.0E+02 1.9E+00 6.0E+00 10 100 8.57E+02 86% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
9.50E-01 1.8E+01 1.9E+00 6.0E+00
9.50E-01 1.6E+02 1.9E+00 6.0E+00
9.50E-01 2.5E+01 1.9E+00 6.0E+00
9.50E-01 6.2E+01 1.9E+00 6.0E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:10 AM EPA Interlab L11 1313-1316 CFS
9.50E-01 5.4E+02 1.9E+00 6.0E+00 10 100 8.89E+02 89% VU ICP-OES 5/31/11 11:11 AM EPA Interlab L11 1313-1316 CFS
9.50E-01 4.2E+01 1.9E+00 6.0E+00
9.50E-01 2.6E+01 1.9E+00 6.0E+00
9.50E-01 4.2E+01 1.9E+00 6.0E+00
9.50E-01 4.1E+01 1.9E+00 6.0E+00
VUICP-OES 5/31/11 11:13 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:14 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316 CFS
9.50E-01 7.2E+01 1.9E+00 6.0E+00 10 100 8.96E+02 89% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
9.50E-01 6.7E+01 1.9E+00 6.0E+00
9.50E-01 3.8E+01 1.9E+00 6.0E+00
9.50E-01 2.3E+01 1.9E+00 6.0E+00
9.50E-01 1.8E+02 1.9E+00 6.0E+00
9.50E-01 1.3E+02 1.9E+00 6.0E+00
9.50E-01 6.8E+01 1.9E+00 6.0E+00
VU ICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VU ICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VU ICP-OES 5/31/1 1 10:58 AM EPA Interlab L1 1 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1778
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd CFS-L11-1316-T01-A 1 2.96E+03
Cd CFS-L11-1316-T02-A 1 2.45E+03
Cd CFS-L11-1316-T03-A 1 6.05E+03
Cd CFS-L11-1316-T04-A 1 3.45E+03
Cd CFS-L11-1316-T05-A 1 1.11E+04
Cd CFS-L11-1316-T01-B 1 3.09E+03
Cd CFS-L11-1316-T02-B 1 4.20E+03
Cd CFS-L11-1316-T03-B 1 6.00E+03
Cd CFS-L11-1316-T04-B 1 6.93E+03
Cd CFS-L11-1316-T05-B 1 1.11E+04
Cd CFS-L11-1316-T01-C 1 3.07E+03
Cd CFS-L11-1316-T02-C 1 4.14E+03
Cd CFS-L11-1316-T03-C 1 5.86E+03
Cd CFS-L11-1316-T04-C 1 8.51 E+03
Cd CFS-L11-1316-T05-C 1 1.12E+04
Cd CFS-L11-1316-B01-A 1 1.10E+OOU1/2
Cd CFS-L11-1316-B02-A 1 1.10E+OOU1/2
Cd CFS-L11-1316-B03-A 1 1.10E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.96E+03 1.3E-01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
2.45E+03 8.6E+01 2.2E+00 7.0E+00 10 100 3.43E+03 98% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
6.05E+03 2.5E-01 2.2E+00 7.0E+00
3.45E+03 1.4E+02 2.2E+00 7.0E+00
1.11E+04 6.1E-01 2.2E+00 7.0E+00
3.09E+03 7.3E-02 2.2E+00 7.0E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
4.20E+03 1.6E-01 2.2E+00 7.0E+00 10 100 5.18E+03 99% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
6.00E+03 9.5E-01 2.2E+00 7.0E+00
6.93E+03 4.6E-01 2.2E+00 7.0E+00
1.11E+04 8.7E-01 2.2E+00 7.0E+00
3.07E+03 8.7E-01 2.2E+00 7.0E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
4.14E+03 1.8E+00 2.2E+00 7.0E+00 10 100 5.17E+03 103% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
5.86E+03 1.1E+00 2.2E+00 7.0E+00
8.51 E+03 6.7E-01 2.2E+00 7.0E+00
1.12E+04 5.4E-01 2.2E+00 7.0E+00
1.10E+00 3.2E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+01 2.2E+00 7.0E+00
1.10E+00 1.1E+02 2.2E+00 7.0E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:OOAM EPA Interlab L11 1313-1316CFS
                                                                                                                                                                         1-1779
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca CFS-L11-1316-T01-A 1 6.33E+05
Ca CFS-L11-1316-T02-A 1 3.71 E+05
Ca CFS-L11-1316-T03-A 1 5.93E+05
Ca CFS-L11-1316-T04-A 1 2.68E+05
Ca CFS-L11-1316-T05-A 1 5.13E+05
Ca CFS-L11-1316-T01-B 1 6.53E+05
Ca CFS-L11-1316-T02-B 1 6.21E+05
Ca CFS-L11-1316-T03-B 1 6.01 E+05
Ca CFS-L11-1316-T04-B 1 5.46E+05
Ca CFS-L11-1316-T05-B 1 5.10E+05
Ca CFS-L11-1316-T01-C 1 6.56E+05
Ca CFS-L11-1316-T02-C 1 6.23E+05
Ca CFS-L11-1316-T03-C 1 5.84E+05
Ca CFS-L11-1316-T04-C 1 5.43E+05
Ca CFS-L11-1316-T05-C 1 5.05E+05
Ca CFS-L11-1316-B01-A 1 1.55E+01
Ca CFS-L11-1316-B02-A 1 1.06E+01
Ca CFS-L11-1316-B03-A 1 1.51E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.33E+05 4.8E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
3.71E+05 8.3E+01 2.6E+00 8.3E+00 1000 100 3.72E+05 82% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
5.93E+05 5.8E-01 2.6E+00 8.3E+00
2.68E+05 1.4E+02 2.6E+00 8.3E+00
5.13E+05 5.1E-01 2.6E+00 8.3E+00
6.53E+05 3.7E-01 2.6E+00 8.3E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
6.21E+05 1.6E-01 2.6E+00 8.3E+00 1000 100 6.22E+05 92% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
6.01 E+05 9.0E-01 2.6E+00 8.3E+00
5.46E+05 6.9E-01 2.6E+00 8.3E+00
5.10E+05 1.1E+00 2.6E+00 8.3E+00
6.56E+05 9.1E-01 2.6E+00 8.3E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
6.23E+05 2.0E+00 2.6E+00 8.3E+00 1000 100 6.24E+05 90% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
5.84E+05 3.2E-01 2.6E+00 8.3E+00
5.43E+05 6.9E-02 2.6E+00 8.3E+00
5.05E+05 3.8E-01 2.6E+00 8.3E+00
1.55E+01 5.8E+01 2.6E+00 8.3E+00
1.06E+01 1.5E+01 2.6E+00 8.3E+00
1.51E+01 5.5E+01 2.6E+00 8.3E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:OOAM EPA Interlab L11 1313-1316CFS
                                                                                                                                                                         1-1780
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cr Sample Dilution Cone. Qualifier Revi
ug/L
Cr CFS-L11-1316-T01-A 1 6.00E-01 U1/2
Cr CFS-L11-1316-T02-A 1 6.00E-01 U1/2
Cr CFS-L11-1316-T03-A 1 6.00E-01 U1/2
Cr CFS-L11-1316-T04-A 1 6.00E-01 U1/2
Cr CFS-L11-1316-T05-A 1 1.70E+OOE
Cr CFS-L11-1316-T01-B 1 6.00E-01 U1/2
Cr CFS-L11-1316-T02-B 1 6.00E-01 U1/2
Cr CFS-L11-1316-T03-B 1 6.00E-01 U1/2
Cr CFS-L11-1316-T04-B 1 6.00E-01 U1/2
Cr CFS-L11-1316-T05-B 1 2.02E+00 E
Cr CFS-L11-1316-T01-C 1 6.00E-01 U1/2
Cr CFS-L11-1316-T02-C 1 6.00E-01 U1/2
Cr CFS-L11-1316-T03-C 1 6.00E-01 U1/2
Cr CFS-L11-1316-T04-C 1 6.00E-01 U1/2
Cr CFS-L11-1316-T05-C 1 1.80E+OOE
Cr CFS-L11-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L11-1316-B01-A 1 6.00E-01 U1/2
Cr CFS-L11-1316-B01-A 1 6.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 5.9E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
6.00E-01 5.9E+01 1.2E+00 3.8E+00 10 100 8.87E+02 89% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
6.00E-01 4.4E+01 1.2E+00 3.8E+00
6.00E-01 1.1E+02 1.2E+00 3.8E+00
1.70E+00 9.9E+00 1.2E+00 3.8E+00
6.00E-01 2.3E+01 1.2E+00 3.8E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:10 AM EPA Interlab L11 1313-1316 CFS
6.00E-01 1.7E+01 1.2E+00 3.8E+00 10 100 9.15E+02 91% VU ICP-OES 5/31/11 11:11 AM EPA Interlab L11 1313-1316 CFS
6.00E-01 2.1E+01 1.2E+00 3.8E+00
6.00E-01 8.5E+01 1.2E+00 3.8E+00
2.02E+00 1.5E+01 1.2E+00 3.8E+00
6.00E-01 4.8E+01 1.2E+00 3.8E+00
VUICP-OES 5/31/11 11:13 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:14 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316 CFS
6.00E-01 1.2E+02 1.2E+00 3.8E+00 10 100 9.23E+02 92% VU ICP-OES 5/31/1 1 11:19 AM EPA Interlab L1 1 1313-1316 CFS
6.00E-01 8.6E+01 1.2E+00 3.8E+00
6.00E-01 4.0E+01 1.2E+00 3.8E+00
1.80E+00 1.8E+01 1.2E+00 3.8E+00
6.00E-01 3.9E+01 1.2E+00 3.8E+00
6.00E-01 1.1E+02 1.2E+00 3.8E+00
6.00E-01 3.0E+01 1.2E+00 3.8E+00
VU ICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:24 AM EPA Interlab L11 1313-1316 CFS
VU ICP-OES 5/31/1 1 10:56 AM EPA Interlab L1 1 1313-1316 CFS
VU ICP-OES 5/31/1 1 10:58 AM EPA Interlab L1 1 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1781
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co CFS-L11-1316-T01-A 1 8.07E+01
Co CFS-L11-1316-T02-A 1 8.00E+01
Co CFS-L11-1316-T03-A 1 2.41E+02
Co CFS-L11-1316-T04-A 1 1.45E+02
Co CFS-L11-1316-T05-A 1 5.95E+02
Co CFS-L11-1316-T01-B 1 8.48E+01
Co CFS-L11-1316-T02-B 1 1.34E+02
Co CFS-L11-1316-T03-B 1 2.40E+02
Co CFS-L11-1316-T04-B 1 3.02E+02
Co CFS-L11-1316-T05-B 1 5.90E+02
Co CFS-L11-1316-T01-C 1 8.41E+01
Co CFS-L11-1316-T02-C 1 1.36E+02
Co CFS-L11-1316-T03-C 1 2.30E+02
Co CFS-L11-1316-T04-C 1 4.05E+02
Co CFS-L11-1316-T05-C 1 6.01 E+02
Co CFS-L11-1316-B01-A 1 9.00E-01 U1/2
Co CFS-L11-1316-B02-A 1 9.00E-01 U1/2
Co CFS-L11-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.07E+01 2.7E-01 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
8.00E+01 8.4E+01 1 .8E+00 5.7E+00 10 100 1.09E+03 101% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
2.41E+02 4.6E-01 1 .8E+00 5.7E+00
1.45E+02 1.4E+02 1 .8E+00 5.7E+00
5.95E+02 1.0E+00 1 .8E+00 5.7E+00
8.48E+01 7.6E-01 1.8E+00 5.7E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
1.34E+02 9.4E-01 1.8E+00 5.7E+00 10 100 1.12E+03 99% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
2.40E+02 8.7E-01 1.8E+00 5.7E+00
3.02E+02 5.1E-02 1.8E+00 5.7E+00
5.90E+02 1.6E+00 1.8E+00 5.7E+00
8.41 E+01 2.7E+00 1.8E+00 5.7E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
1.36E+02 4.9E-01 1.8E+00 5.7E+00 10 100 1.13E+03 100% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
2.30E+02 1.2E+00 1.8E+00 5.7E+00
4.05E+02 2.8E-01 1.8E+00 5.7E+00
6.01 E+02 4.0E-01 1.8E+00 5.7E+00
9.00E-01 5.2E+01 1.8E+00 5.7E+00
9.00E-01 3.4E+01 1.8E+00 5.7E+00
9.00E-01 1.4E+02 1.8E+00 5.7E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1782
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu CFS-L11-1316-T01-A 1 7.67E+02
Cu CFS-L11-1316-T02-A 1 7.95E+02
Cu CFS-L11-1316-T03-A 1 1.49E+03
Cu CFS-L11-1316-T04-A 1 8.55E+02
Cu CFS-L11-1316-T05-A 1 2.71E+03
Cu CFS-L11-1316-T01-B 1 7.98E+02
Cu CFS-L11-1316-T02-B 1 1.06E+03
Cu CFS-L11-1316-T03-B 1 1.44E+03
Cu CFS-L11-1316-T04-B 1 1.69E+03
Cu CFS-L11-1316-T05-B 1 2.87E+03
Cu CFS-L11-1316-T01-C 1 7.88E+02
Cu CFS-L11-1316-T02-C 1 1.09E+03
Cu CFS-L11-1316-T03-C 1 1.29E+03
Cu CFS-L11-1316-T04-C 1 2.21E+03
Cu CFS-L11-1316-T05-C 1 2.63E+03
Cu CFS-L11-1316-B01-A 1 1.85E+OOU1/2
Cu CFS-L11-1316-B02-A 1 1.85E+OOU1/2
Cu CFS-L11-1316-B03-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.67E+02 1.1E+00 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
7.95E+02 7.4E+01 3.7E+00 1.2E+01 10 100 1.92E+03 112% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
1.49E+03 1.9E+00 3.7E+00 1.2E+01
8.55E+02 1.3E+02 3.7E+00 1.2E+01
2.71E+03 7.4E-01 3.7E+00 1.2E+01
7.98E+02 8.8E-01 3.7E+00 1.2E+01
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
1.06E+03 6.5E-01 3.7E+00 1.2E+01 10 100 1.95E+03 88% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
1.44E+03 4.6E-01 3.7E+00 1.2E+01
1.69E+03 3.4E-01 3.7E+00 1.2E+01
2.87E+03 5.3E-01 3.7E+00 1.2E+01
7.88E+02 1.6E+00 3.7E+00 1.2E+01
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
1.09E+03 2.6E+00 3.7E+00 1.2E+01 10 100 1.98E+03 89% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
1.29E+03 4.1E-01 3.7E+00 1.2E+01
2.21 E+03 6.3E-01 3.7E+00 1.2E+01
2.63E+03 2.3E-01 3.7E+00 1.2E+01
1.85E+00 7.8E+01 3.7E+00 1.2E+01
1.85E+00 1.9E+01 3.7E+00 1.2E+01
1.85E+00 2.5E+01 3.7E+00 1.2E+01
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:OOAM EPA Interlab L11 1313-1316CFS
                                                                                                                                                                         1-1783
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe CFS-L11-1316-T01-A 1 1.00E+OOU1/2
Fe CFS-L11-1316-T02-A 1 1.00E+OOU1/2
Fe CFS-L11-1316-T03-A 1 1.00E+OOU1/2
Fe CFS-L11-1316-T04-A 1 1.00E+OOU1/2
Fe CFS-L11-1316-T05-A 1 1.00E+OOU1/2
Fe CFS-L11-1316-T01-B 1 1.00E+OOU1/2
Fe CFS-L11-1316-T02-B 1 1.00E+OOU1/2
Fe CFS-L11-1316-T03-B 1 1.00E+OOU1/2
Fe CFS-L11-1316-T04-B 1 1.00E+OOU1/2
Fe CFS-L11-1316-T05-B 1 1.00E+OOU1/2
Fe CFS-L11-1316-T01-C 1 1.00E+OOU1/2
Fe CFS-L11-1316-T02-C 1 1.00E+OOU1/2
Fe CFS-L11-1316-T03-C 1 1.00E+OOU1/2
Fe CFS-L11-1316-T04-C 1 1.00E+OOU1/2
Fe CFS-L11-1316-T05-C 1 1.00E+OOU1/2
Fe CFS-L11-1316-B01-A 1 1.00E+OOU1/2
Fe CFS-L11-1316-B02-A 1 1.00E+OOU1/2
Fe CFS-L11-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.8E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
1.00E+00 2.1E+02 2.0E+00 6.4E+00 1000 100 8.89E+02 89% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
1.00E+00 2.5E+00 2.0E+00 6.4E+00
1.00E+00 7.7E+01 2.0E+00 6.4E+00
1.00E+00 3.9E+01 2.0E+00 6.4E+00
1.00E+00 4.4E+01 2.0E+00 6.4E+00
VUICP-OES 5/31/11 11:05 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10 AM EPA Interlab L11 1313-1316CFS
1.00E+00 5.2E+00 2.0E+00 6.4E+00 1000 100 9.08E+02 91% VU ICP-OES 5/31/11 11:11 AM EPA Interlab L11 1313-1316 CFS
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 3.8E+01 2.0E+00 6.4E+00
1.00E+00 8.1E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
VUICP-OES 5/31/11 11:13 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:14 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316CFS
1.00E+00 5.8E+00 2.0E+00 6.4E+00 1000 100 9.12E+02 91% VU ICP-OES 5/31/11 1 1:19 AM EPA Interlab L11 1313-1316 CFS
1.00E+00 2.2E+01 2.0E+00 6.4E+00
1.00E+00 6.0E+01 2.0E+00 6.4E+00
1.00E+00 1.6E+01 2.0E+00 6.4E+00
1.00E+00 9.4E+00 2.0E+00 6.4E+00
1.00E+00 3.7E+00 2.0E+00 6.4E+00
1.00E+00 7.6E+00 2.0E+00 6.4E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316CFS
                                                                                                                                                                         1-1784
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb CFS-L11-1316-T01-A 1 7.37E+02
Pb CFS-L11-1316-T02-A 1 4.70E+02
Pb CFS-L11-1316-T03-A 1 9.60E+02
Pb CFS-L11-1316-T04-A 1 4.91 E+02
Pb CFS-L11-1316-T05-A 1 1.06E+03
Pb CFS-L11-1316-T01-B 1 7.79E+02
Pb CFS-L11-1316-T02-B 1 8.50E+02
Pb CFS-L11-1316-T03-B 1 9.94E+02
Pb CFS-L11-1316-T04-B 1 1.03E+03
Pb CFS-L11-1316-T05-B 1 1.08E+03
Pb CFS-L11-1316-T01-C 1 8.27E+02
Pb CFS-L11-1316-T02-C 1 8.91 E+02
Pb CFS-L11-1316-T03-C 1 9.20E+02
Pb CFS-L11-1316-T04-C 1 1.02E+03
Pb CFS-L11-1316-T05-C 1 9.65E+02
Pb CFS-L11-1316-B01-A 1 3.40E+00 U1/2
Pb CFS-L11-1316-B02-A 1 3.40E+00 U1/2
Pb CFS-L11-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.37E+02 9.4E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
4.70E+02 8.8E+01 6.8E+00 2.2E+01 10 100 1.52E+03 105% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
9.60E+02 5.7E-01 6.8E+00 2.2E+01
4.91 E+02 1.4E+02 6.8E+00 2.2E+01
1.06E+03 1.5E+00 6.8E+00 2.2E+01
7.79E+02 6.1E-01 6.8E+00 2.2E+01
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
8.50E+02 2.4E-01 6.8E+00 2.2E+01 10 100 1.75E+03 90% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
9.94E+02 7.0E-01 6.8E+00 2.2E+01
1.03E+03 2.9E-01 6.8E+00 2.2E+01
1.08E+03 1.3E+00 6.8E+00 2.2E+01
8.27E+02 1.2E+00 6.8E+00 2.2E+01
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316 CFS
8.91E+02 2.1E+00 6.8E+00 2.2E+01 10 100 1.85E+03 96% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
9.20E+02 1.5E+00 6.8E+00 2.2E+01
1.02E+03 6.0E-01 6.8E+00 2.2E+01
9.65E+02 3.6E-01 6.8E+00 2.2E+01
3.40E+00 6.5E+01 6.8E+00 2.2E+01
3.40E+00 8.0E+01 6.8E+00 2.2E+01
3.40E+00 3.6E+01 6.8E+00 2.2E+01
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1785
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li CFS-L11-1316-T01-A 1 1.94E+01
Li CFS-L11-1316-T02-A 1 1.69E+01
Li CFS-L11-1316-T03-A 1 1.63E+01
Li CFS-L11-1316-T04-A 1 1.39E+01
Li CFS-L11-1316-T05-A 1 2.40E+01
Li CFS-L11-1316-T01-B 1 1.78E+01
Li CFS-L11-1316-T02-B 1 1.80E+01
Li CFS-L11-1316-T03-B 1 1.75E+01
Li CFS-L11-1316-T04-B 1 1.43E+01
Li CFS-L11-1316-T05-B 1 2.57E+01
Li CFS-L11-1316-T01-C 1 1.89E+01
Li CFS-L11-1316-T02-C 1 2.03E+01
Li CFS-L11-1316-T03-C 1 1.67E+01
Li CFS-L11-1316-T04-C 1 1.48E+01
Li CFS-L11-1316-T05-C 1 2.26E+01
Li CFS-L11-1316-B01-A 1 6.07E+00
Li CFS-L11-1316-B02-A 1 6.02E+00
Li CFS-L11-1316-B03-A 1 5.51E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.94E+01 3.9E+00 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
1.69E+01 1.8E+01 1.9E+00 6.0E+00 10 100 8.62E+02 85% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
1.63E+01 2.3E+00 1 .9E+00 6.0E+00
1.39E+01 4.2E+00 1 .9E+00 6.0E+00
2.40E+01 4.4E+00 1 .9E+00 6.0E+00
1.78E+01 9.5E+00 1.9E+00 6.0E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
1.80E+01 3.1E+00 1.9E+00 6.0E+00 10 100 8.87E+02 87% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
1.75E+01 1.8E+00 1.9E+00 6.0E+00
1.43E+01 4.6E+00 1.9E+00 6.0E+00
2.57E+01 3.2E+00 1.9E+00 6.0E+00
1.89E+01 3.3E+00 1.9E+00 6.0E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
2.03E+01 4.1E+00 1.9E+00 6.0E+00 10 100 8.91E+02 87% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
1.67E+01 4.1E+00 1.9E+00 6.0E+00
1.48E+01 2.0E+00 1.9E+00 6.0E+00
2.26E+01 1.4E+01 1.9E+00 6.0E+00
6.07E+00 2.2E+01 1.9E+00 6.0E+00
6.02E+00 2.2E+01 1.9E+00 6.0E+00
5.51 E+00 2.2E+01 1.9E+00 6.0E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:OOAM EPA Interlab L11 1313-1316CFS
                                                                                                                                                                         1-1786
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
ug/L
Mn CFS-L11-1316-T01-A 1 1.12E+03
Mn CFS-L11-1316-T02-A 1 1.48E+03
Mn CFS-L11-1316-T03-A 1 4.10E+03
Mn CFS-L11-1316-T04-A 1 2.88E+03
Mn CFS-L11-1316-T05-A 1 1.12E+04
Mn CFS-L11-1316-T01-B 1 1.16E+03
Mn CFS-L11-1316-T02-B 1 2.07E+03
Mn CFS-L11-1316-T03-B 1 4.06E+03
Mn CFS-L11-1316-T04-B 1 5.61E+03
Mn CFS-L11-1316-T05-B 1 1.11E+04
Mn CFS-L11-1316-T01-C 1 1.16E+03
Mn CFS-L11-1316-T02-C 1 2.09E+03
Mn CFS-L11-1316-T03-C 1 4.00E+03
Mn CFS-L11-1316-T04-C 1 7.20E+03
Mn CFS-L11-1316-T05-C 1 1.13E+04
Mn CFS-L11-1316-B01-A 1 1.00E+OOU1/2
Mn CFS-L11-1316-B02-A 1 2.30E+00 E
Mn CFS-L11-1316-B03-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.12E+03 3.5E-02 2.0E+00 6.4E+00
1.48E+03 7.1E+01 2.0E+00 6.4E+00 10 100
4.10E+03 4.2E-01 2.0E+00 6.4E+00
2.88E+03 1.2E+02 2.0E+00 6.4E+00
1.12E+04 3.3E-01 2.0E+00 6.4E+00
1.16E+03 5.5E-01 2.0E+00 6.4E+00
2.07E+03 3.0E-01 2.0E+00 6.4E+00 10 100
4.06E+03 1.1E+00 2.0E+00 6.4E+00
5.61 E+03 6.3E-01 2.0E+00 6.4E+00
1.11E+04 1.3E+00 2.0E+00 6.4E+00
1.16E+03 1.4E+00 2.0E+00 6.4E+00
2.09E+03 1.6E+00 2.0E+00 6.4E+00 10 100
4.00E+03 2.4E+00 2.0E+00 6.4E+00
7.20E+03 1.1E+00 2.0E+00 6.4E+00
1.13E+04 6.8E-01 2.0E+00 6.4E+00
1.00E+00 5.6E+00 2.0E+00 6.4E+00
2.30E+00 1.5E+00 2.0E+00 6.4E+00
1.00E+00 6.3E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA InterlabLH 1313-1316 CFS
2.52E+03 104% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
3.10E+03 103% VU ICP-OES 5/31/11 11:11 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316 CFS
3.02E+03 93% VUICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1787
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg CFS-L11-1316-T01-A 1 6.59E+04
Mg CFS-L11-1316-T02-A 1 8.06E+04
Mg CFS-L11-1316-T03-A 1 2.85E+05
Mg CFS-L11-1316-T04-A 1 2.34E+05
Mg CFS-L11-1316-T05-A 1 9.09E+05
Mg CFS-L11-1316-T01-B 1 6.76E+04
Mg CFS-L11-1316-T02-B 1 1.26E+05
Mg CFS-L11-1316-T03-B 1 2.90E+05
Mg CFS-L11-1316-T04-B 1 4.70E+05
Mg CFS-L11-1316-T05-B 1 9.10E+05
Mg CFS-L11-1316-T01-C 1 6.93E+04
Mg CFS-L11-1316-T02-C 1 1.30E+05
Mg CFS-L11-1316-T03-C 1 2.78E+05
Mg CFS-L11-1316-T04-C 1 5.05E+05
Mg CFS-L11-1316-T05-C 1 9.13E+05
Mg CFS-L11-1316-B01-A 1 5.00E-01 U1/2
Mg CFS-L11-1316-B02-A 1 1.91E+OOE
Mg CFS-L11-1316-B03-A 1 2.70E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.59E+04 1.7E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
8.06E+04 8.1E+01 1 .OE+00 3.2E+00 1000 100 8.16E+04 96% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
2.85E+05 5.1E-01 1.0E+00 3.2E+00
2.34E+05 1.3E+02 1. OE+00 3.2E+00
9.09E+05 5.5E-01 1. OE+00 3.2E+00
6.76E+04 4.1E-01 1.0E+00 3.2E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
1.26E+05 8.7E-01 1.0E+00 3.2E+00 1000 100 1.27E+05 99% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
2.90E+05 8.8E-01 1. OE+00 3.2E+00
4.70E+05 6.4E-01 1. OE+00 3.2E+00
9.10E+05 1.2E+00 1. OE+00 3.2E+00
6.93E+04 1.2E+00 1. OE+00 3.2E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316 CFS
1.30E+05 7.7E-01 1.0E+00 3.2E+00 1000 100 1.30E+05 95% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
2.78E+05 2.8E+00 1. OE+00 3.2E+00
5.05E+05 7.3E-01 1. OE+00 3.2E+00
9.13E+05 6.3E-01 1. OE+00 3.2E+00
5.00E-01 4.4E+02 1. OE+00 3.2E+00
1.91E+00 1.8E+00 1. OE+00 3.2E+00
2.70E+00 1.4E+02 1. OE+00 3.2E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1788
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo CFS-L11-1316-T01-A 1 1.03E+01
Mo CFS-L11-1316-T02-A 1 7.47E+00
Mo CFS-L11-1316-T03-A 1 1.46E+01
Mo CFS-L11-1316-T04-A 1 8.93E+00
Mo CFS-L11-1316-T05-A 1 1.79E+01
Mo CFS-L11-1316-T01-B 1 1.01E+01
Mo CFS-L11-1316-T02-B 1 9.78E+00
Mo CFS-L11-1316-T03-B 1 1.48E+01
Mo CFS-L11-1316-T04-B 1 1.64E+01
Mo CFS-L11-1316-T05-B 1 2.07E+01
Mo CFS-L11-1316-T01-C 1 1.01E+01
Mo CFS-L11-1316-T02-C 1 1.10E+01
Mo CFS-L11-1316-T03-C 1 1.27E+01
Mo CFS-L11-1316-T04-C 1 1.49E+01
Mo CFS-L11-1316-T05-C 1 1.78E+01
Mo CFS-L11-1316-B01-A 1 2.45E+00 E
Mo CFS-L11-1316-B02-A 1 2.24E+00 E
Mo CFS-L11-1316-B03-A 1 1.46E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.03E+01 1.2E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
7.47E+00 7.2E+01 1 .2E+00 3.8E+00 10 100 9.50E+02 94% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
1.46E+01 1.2E+01 1.2E+00 3.8E+00
8.93E+00 1.1E+02 1.2E+00 3.8E+00
1.79E+01 1.2E+01 1.2E+00 3.8E+00
1.01E+01 1.1E+01 1.2E+00 3.8E+00
VUICP-OES 5/31/11 11:05 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
9.78E+00 5.5E+00 1.2E+00 3.8E+00 10 100 9.88E+02 98% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
1.48E+01 7.9E+00 1.2E+00 3.8E+00
1.64E+01 8.1E+00 1.2E+00 3.8E+00
2.07E+01 3.6E+00 1.2E+00 3.8E+00
1.01E+01 9.5E+00 1.2E+00 3.8E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316 CFS
1.10E+01 1.2E+01 1.2E+00 3.8E+00 10 100 9.84E+02 97% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
1.27E+01 8.4E+00 1.2E+00 3.8E+00
1.49E+01 7.1E+00 1.2E+00 3.8E+00
1.78E+01 9.0E+00 1.2E+00 3.8E+00
2.45E+00 2.1E+01 1.2E+00 3.8E+00
2.24E+00 5.2E+01 1.2E+00 3.8E+00
1.46E+00 4.6E+01 1.2E+00 3.8E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1789
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni CFS-L11-1316-T01-A 1 1.40E+02
Ni CFS-L11-1316-T02-A 1 1.33E+02
Ni CFS-L11-1316-T03-A 1 3.73E+02
Ni CFS-L11-1316-T04-A 1 2.17E+02
Ni CFS-L11-1316-T05-A 1 8.82E+02
Ni CFS-L11-1316-T01-B 1 1.47E+02
Ni CFS-L11-1316-T02-B 1 2.24E+02
Ni CFS-L11-1316-T03-B 1 3.75E+02
Ni CFS-L11-1316-T04-B 1 4.52E+02
Ni CFS-L11-1316-T05-B 1 8.70E+02
Ni CFS-L11-1316-T01-C 1 1.47E+02
Ni CFS-L11-1316-T02-C 1 2.25E+02
Ni CFS-L11-1316-T03-C 1 3.59E+02
Ni CFS-L11-1316-T04-C 1 6.13E+02
Ni CFS-L11-1316-T05-C 1 8.89E+02
Ni CFS-L11-1316-B01-A 1 9.00E-01 U1/2
Ni CFS-L11-1316-B02-A 1 9.00E-01 U1/2
Ni CFS-L11-1316-B03-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.40E+02 2.4E+00 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
1.33E+02 8.7E+01 1 .8E+00 5.7E+00 10 100 1.03E+03 89% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
3.73E+02 1.1E+00 1 .8E+00 5.7E+00
2.17E+02 1.4E+02 1 .8E+00 5.7E+00
8.82E+02 8.5E-01 1 .8E+00 5.7E+00
1.47E+02 7.2E-01 1.8E+00 5.7E+00
VUICP-OES 5/31/11 11:05 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
2.24E+02 9.2E-01 1.8E+00 5.7E+00 10 100 1.17E+03 94% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
3.75E+02 3.9E-01 1.8E+00 5.7E+00
4.52E+02 1.1E+00 1.8E+00 5.7E+00
8.70E+02 1.0E+00 1.8E+00 5.7E+00
1.47E+02 4.1E-01 1.8E+00 5.7E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
2.25E+02 2.1E+00 1.8E+00 5.7E+00 10 100 1.17E+03 94% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
3.59E+02 1.2E+00 1.8E+00 5.7E+00
6.13E+02 4.2E-01 1.8E+00 5.7E+00
8.89E+02 2.4E-01 1.8E+00 5.7E+00
9.00E-01 5.4E+00 1.8E+00 5.7E+00
9.00E-01 5.9E+01 1.8E+00 5.7E+00
9.00E-01 1.8E+03 1.8E+00 5.7E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1790
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P CFS-L11-1316-T01-A 1 2.53E+01
P CFS-L11-1316-T02-A 1 3.68E+01
P CFS-L11-1316-T03-A 1 4.15E+01
P CFS-L11-1316-T04-A 1 2.40E+01
P CFS-L11-1316-T05-A 1 5.20E+01
P CFS-L11-1316-T01-B 1 3.64E+01
P CFS-L11-1316-T02-B 1 3.06E+01
P CFS-L11-1316-T03-B 1 5.10E+01
P CFS-L11-1316-T04-B 1 5.57E+01
P CFS-L11-1316-T05-B 1 3.37E+01
P CFS-L11-1316-T01-C 1 3.36E+01
P CFS-L11-1316-T02-C 1 3.00E+01
P CFS-L11-1316-T03-C 1 4.20E+01
P CFS-L11-1316-T04-C 1 3.92E+01
P CFS-L11-1316-T05-C 1 5.03E+01
P CFS-L11-1316-B01-A 1 3.47E+01
P CFS-L11-1316-B02-A 1 3.88E+01
P CFS-L11-1316-B03-A 1 3.27E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.53E+01 1.5E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
3.68E+01 2.9E+01 3.7E+00 1.2E+01 1000 100 9.92E+02 96% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
4.15E+01 2.5E+01 3.7E+00 1.2E+01
2.40E+01 7.1E+00 3.7E+00 1.2E+01
5.20E+01 2.1E+01 3.7E+00 1.2E+01
3.64E+01 3.9E+01 3.7E+00 1.2E+01
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
3.06E+01 2.7E+01 3.7E+00 1.2E+01 1000 100 9.66E+02 94% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
5.10E+01 1.6E+01 3.7E+00 1.2E+01
5.57E+01 1.1E+01 3.7E+00 1.2E+01
3.37E+01 5.5E+01 3.7E+00 1.2E+01
3.36E+01 5.8E+01 3.7E+00 1.2E+01
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
3.00E+01 3.2E+01 3.7E+00 1.2E+01 1000 100 9.95E+02 96% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
4.20E+01 2.3E+01 3.7E+00 1.2E+01
3.92E+01 1.6E+01 3.7E+00 1.2E+01
5.03E+01 2.8E+01 3.7E+00 1.2E+01
3.47E+01 1.2E+01 3.7E+00 1.2E+01
3.88E+01 2.8E+01 3.7E+00 1.2E+01
3.27E+01 3.7E+00 3.7E+00 1.2E+01
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1791
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K CFS-L11-1316-T01-A 1 9.25E+03
K CFS-L11-1316-T02-A 1 9.10E+03
K CFS-L11-1316-T03-A 1 3.17E+04
K CFS-L11-1316-T04-A 1 2.19E+04
K CFS-L11-1316-T05-A 1 7.11E+04
K CFS-L11-1316-T01-B 1 9.69E+03
K CFS-L11-1316-T02-B 1 1.62E+04
K CFS-L11-1316-T03-B 1 3.17E+04
K CFS-L11-1316-T04-B 1 4.65E+04
K CFS-L11-1316-T05-B 1 7.11E+04
K CFS-L11-1316-T01-C 1 9.70E+03
K CFS-L11-1316-T02-C 1 1.65E+04
K CFS-L11-1316-T03-C 1 3.07E+04
K CFS-L11-1316-T04-C 1 4.78E+04
K CFS-L11-1316-T05-C 1 7.09E+04
K CFS-L11-1316-B01-A 1 6.40E+01
K CFS-L11-1316-B02-A 1 7.31E+01
K CFS-L11-1316-B03-A 1 6.40E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.25E+03 1.7E-01 1 .6E+00 5.1E+00
9.10E+03 9.0E+01 1 .6E+00 5.1E+00 1000 100
3.17E+04 4.9E-01 1 .6E+00 5.1E+00
2.19E+04 1.5E+02 1 .6E+00 5.1E+00
7.11E+04 8.4E-01 1 .6E+00 5.1E+00
9.69E+03 1.6E-01 1 .6E+00 5.1E+00
1.62E+04 1.5E-01 1 .6E+00 5.1E+00 1000 100
3.17E+04 8.2E-01 1 .6E+00 5.1E+00
4.65E+04 2.2E-01 1 .6E+00 5.1E+00
7.11E+04 1.2E+00 1.6E+00 5.1E+00
9.70E+03 7.5E-01 1 .6E+00 5.1E+00
1.65E+04 2.0E+00 1 .6E+00 5.1E+00 1000 100
3.07E+04 3.9E-01 1.6E+00 5.1E+00
4.78E+04 6.9E-01 1.6E+00 5.1E+00
7.09E+04 5.5E-01 1.6E+00 5.1E+00
6.40E+01 4.8E+00 1.6E+00 5.1E+00
7.31 E+01 1.3E+00 1.6E+00 5.1E+00
6.40E+01 1.6E+00 1.6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA InterlabLH 1313-1316 CFS
1.02E+04 112% VUICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
1.72E+04 91%VUICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
1.75E+04 99% VUICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1792
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se CFS-L11-1316-T01-A 1 6.87E+01
Se CFS-L11-1316-T02-A 1 6.52E+01
Se CFS-L11-1316-T03-A 1 2.63E+02
Se CFS-L11-1316-T04-A 1 1.91E+02
Se CFS-L11-1316-T05-A 1 7.31 E+02
Se CFS-L11-1316-T01-B 1 7.53E+01
Se CFS-L11-1316-T02-B 1 1.22E+02
Se CFS-L11-1316-T03-B 1 2.56E+02
Se CFS-L11-1316-T04-B 1 3.98E+02
Se CFS-L11-1316-T05-B 1 7.35E+02
Se CFS-L11-1316-T01-C 1 8.05E+01
Se CFS-L11-1316-T02-C 1 1.16E+02
Se CFS-L11-1316-T03-C 1 2.55E+02
Se CFS-L11-1316-T04-C 1 4.27E+02
Se CFS-L11-1316-T05-C 1 7.58E+02
Se CFS-L11-1316-B01-A 1 7.50E+00 U1/2
Se CFS-L11-1316-B02-A 1 7.50E+00 U1/2
Se CFS-L11-1316-B03-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.87E+01 7.3E+00 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
6.52E+01 1.1E+02 1 .5E+01 4.8E+01 10 100 1.00E+03 94% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
2.63E+02 2.1E+00 1.5E+01 4.8E+01
1.91 E+02 1.5E+02 1.5E+01 4.8E+01
7.31 E+02 4.2E+00 1.5E+01 4.8E+01
7.53E+01 1.7E+01 1.5E+01 4.8E+01
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
1.22E+02 7.1E+00 1.5E+01 4.8E+01 10 100 1.05E+03 93% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
2.56E+02 5.1E+00 1.5E+01 4.8E+01
3.98E+02 1.8E+00 1.5E+01 4.8E+01
7.35E+02 2.6E+00 1.5E+01 4.8E+01
8.05E+01 1.4E+01 1.5E+01 4.8E+01
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316 CFS
1.16E+02 1.9E+01 1.5E+01 4.8E+01 10 100 1.04E+03 92% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
2.55E+02 4.2E+00 1.5E+01 4.8E+01
4.27E+02 3.1E+00 1.5E+01 4.8E+01
7.58E+02 5.6E+00 1.5E+01 4.8E+01
7.50E+00 2.8E+02 1.5E+01 4.8E+01
7.50E+00 9.9E+01 1.5E+01 4.8E+01
7.50E+00 7.4E+01 1.5E+01 4.8E+01
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1793
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si CFS-L11-1316-T01-A 1 3.26E+03
Si CFS-L11-1316-T02-A 1 3.24E+03
Si CFS-L11-1316-T03-A 1 5.49E+03
Si CFS-L11-1316-T04-A 1 2.78E+03
Si CFS-L11-1316-T05-A 1 6.74E+03
Si CFS-L11-1316-T01-B 1 3.43E+03
Si CFS-L11-1316-T02-B 1 4.28E+03
Si CFS-L11-1316-T03-B 1 5.47E+03
Si CFS-L11-1316-T04-B 1 5.59E+03
Si CFS-L11-1316-T05-B 1 6.68E+03
Si CFS-L11-1316-T01-C 1 3.39E+03
Si CFS-L11-1316-T02-C 1 4.39E+03
Si CFS-L11-1316-T03-C 1 5.55E+03
Si CFS-L11-1316-T04-C 1 6.22E+03
Si CFS-L11-1316-T05-C 1 6.70E+03
Si CFS-L11-1316-B01-A 1 5.58E+00
Si CFS-L11-1316-B02-A 1 2.38E+00 E
Si CFS-L11-1316-B03-A 1 5.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.26E+03 1.3E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
3.24E+03 7.7E+01 1.1E+00 3.5E+00 1000 100 4.22E+03 98% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
5.49E+03 1.5E+00 1.1E+00 3.5E+00
2.78E+03 1.4E+02 1.1E+00 3.5E+00
6.74E+03 7.2E-01 1.1E+00 3.5E+00
3.43E+03 1.2E+00 1.1E+00 3.5E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
4.28E+03 7.2E-02 1.1E+00 3.5E+00 1000 100 5.20E+03 92% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
5.47E+03 1.1E+00 1.1E+00 3.5E+00
5.59E+03 2.4E-01 1.1E+00 3.5E+00
6.68E+03 1.2E+00 1.1E+00 3.5E+00
3.39E+03 7.2E-01 1.1E+00 3.5E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316 CFS
4.39E+03 2.9E+00 1.1E+00 3.5E+00 1000 100 5.31E+03 92% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
5.55E+03 3.7E+00 1.1E+00 3.5E+00
6.22E+03 4.4E-01 1.1E+00 3.5E+00
6.70E+03 4.4E-01 1.1E+00 3.5E+00
5.58E+00 2.6E+01 1.1E+00 3.5E+00
2.38E+00 6.9E+01 1.1E+00 3.5E+00
5.50E-01 1.8E+02 1.1E+00 3.5E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1794
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na CFS-L11-1316-T01-A 1 2.35E+04
Na CFS-L11-1316-T02-A 1 2.50E+04
Na CFS-L11-1316-T03-A 1 9.17E+04
Na CFS-L11-1316-T04-A 1 6.26E+04
Na CFS-L11-1316-T05-A 1 2.12E+05
Na CFS-L11-1316-T01-B 1 2.43E+04
Na CFS-L11-1316-T02-B 1 4.46E+04
Na CFS-L11-1316-T03-B 1 9.17E+04
Na CFS-L11-1316-T04-B 1 1.34E+05
Na CFS-L11-1316-T05-B 1 2.12E+05
Na CFS-L11-1316-T01-C 1 2.39E+04
Na CFS-L11-1316-T02-C 1 4.31 E+04
Na CFS-L11-1316-T03-C 1 8.88E+04
Na CFS-L11-1316-T04-C 1 1.36E+05
Na CFS-L11-1316-T05-C 1 2.11E+05
Na CFS-L11-1316-B01-A 1 1.73E+01
Na CFS-L11-1316-B02-A 1 2.34E+01
Na CFS-L11-1316-B03-A 1 2.74E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.35E+04 7.8E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
2.50E+04 7.5E+01 2.5E+00 8.0E+00 1000 100 2.58E+04 88% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
9.17E+04 4.7E-01 2.5E+00 8.0E+00
6.26E+04 1.2E+02 2.5E+00 8.0E+00
2.12E+05 8.2E-01 2.5E+00 8.0E+00
2.43E+04 3.0E-01 2.5E+00 8.0E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
4.46E+04 7.7E-01 2.5E+00 8.0E+00 1000 100 4.55E+04 91%VUICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
9.17E+04 5.0E-01 2.5E+00 8.0E+00
1.34E+05 2.0E-01 2.5E+00 8.0E+00
2.12E+05 2.8E-01 2.5E+00 8.0E+00
2.39E+04 2.6E-01 2.5E+00 8.0E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:1 6 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
4.31E+04 1.8E+00 2.5E+00 8.0E+00 1000 100 4.41E+04 95% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
8.88E+04 2.2E-01 2.5E+00 8.0E+00
1.36E+05 1.2E+00 2.5E+00 8.0E+00
2.11E+05 3.8E-01 2.5E+00 8.0E+00
1.73E+01 1.6E+01 2.5E+00 8.0E+00
2.34E+01 1.3E+00 2.5E+00 8.0E+00
2.74E+01 4.9E+00 2.5E+00 8.0E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:OOAM EPA Interlab L11 1313-1316CFS
                                                                                                                                                                         1-1795
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-L11-1316-T01-A 1 1.50E+03
CFS-L11-1316-T02-A 1 1.51E+03
CFS-L11-1316-T03-A 1 3.23E+03
CFS-L11-1316-T04-A 1 2.03E+03
CFS-L11-1316-T05-A 1 4.15E+03
CFS-L11-1316-T01-B 1 1.55E+03
CFS-L11-1316-T02-B 1 2.10E+03
CFS-L11-1316-T03-B 1 3.31 E+03
CFS-L11-1316-T04-B 1 4.12E+03
CFS-L11-1316-T05-B 1 4.16E+03
CFS-L11-1316-T01-C 1 1.52E+03
CFS-L11-1316-T02-C 1 2.18E+03
CFS-L11-1316-T03-C 1 3.31 E+03
CFS-L11-1316-T04-C 1 3.59E+03
CFS-L11-1316-T05-C 1 4.15E+03
CFS-L11-1316-B01-A 1 5.00E-01 U1/2
CFS-L11-1316-B02-A 1 5.00E-01 U1/2
CFS-L11-1316-B03-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.50E+03 5.9E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
1.51E+03 8.0E+01 1.0E+00 3.2E+00 1000 100 2.55E+03 104% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
3.23E+03 1.4E+00 1 .OE+00 3.2E+00
2.03E+03 1.3E+02 1 .OE+00 3.2E+00
4.15E+03 3.9E-01 1 .OE+00 3.2E+00
1.55E+03 8.3E-01 1 .OE+00 3.2E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
2.10E+03 5.0E-01 1 .OE+00 3.2E+00 1000 100 3.01E+03 91%VUICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
3.31 E+03 9.1E-01 1 .OE+00 3.2E+00
4.12E+03 1.7E-01 1 .OE+00 3.2E+00
4.16E+03 8.1E-01 1 .OE+00 3.2E+00
1.52E+03 1.2E+00 1 .OE+00 3.2E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
2.18E+03 2.1E+00 1 .OE+00 3.2E+00 1000 100 3.23E+03 104% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
3.31 E+03 1.7E+00 1. OE+00 3.2E+00
3.59E+03 1.2E+00 1. OE+00 3.2E+00
4.15E+03 1.5E-01 1. OE+00 3.2E+00
5.00E-01 1.6E+01 1. OE+00 3.2E+00
5.00E-01 1.3E+01 1. OE+00 3.2E+00
5.00E-01 9.4E+00 1. OE+00 3.2E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1796
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S CFS-L11-1316-T01-A 1 5.98E+05
S CFS-L11-1316-T02-A 1 3.82E+05
S CFS-L11-1316-T03-A 1 8.54E+05
S CFS-L11-1316-T04-A 1 5.05E+05
S CFS-L11-1316-T05-A 1 1.50E+06
S CFS-L11-1316-T01-B 1 6.18E+05
S CFS-L11-1316-T02-B 1 6.73E+05
S CFS-L11-1316-T03-B 1 8.66E+05
S CFS-L11-1316-T04-B 1 1.04E+06
S CFS-L11-1316-T05-B 1 1.51E+06
S CFS-L11-1316-T01-C 1 6.22E+05
S CFS-L11-1316-T02-C 1 6.84E+05
S CFS-L11-1316-T03-C 1 8.37E+05
S CFS-L11-1316-T04-C 1 1.09E+06
S CFS-L11-1316-T05-C 1 1.52E+06
S CFS-L11-1316-B01-A 1 3.40E+00 U1/2
S CFS-L11-1316-B02-A 1 1.56E+01 E
S CFS-L11-1316-B03-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.98E+05 5.0E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
3.82E+05 8.8E+01 6.8E+00 2.2E+01 1000 100 3.83E+05 89% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
8.54E+05 3.2E-01 6.8E+00 2.2E+01
5.05E+05 1.4E+02 6.8E+00 2.2E+01
1.50E+06 5.6E-01 6.8E+00 2.2E+01
6.18E+05 1.5E-01 6.8E+00 2.2E+01
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
6.73E+05 2.9E-01 6.8E+00 2.2E+01 1000 100 6.74E+05 90% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
8.66E+05 1.1E+00 6.8E+00 2.2E+01
1.04E+06 5.2E-04 6.8E+00 2.2E+01
1.51E+06 1.1E+00 6.8E+00 2.2E+01
6.22E+05 9.2E-01 6.8E+00 2.2E+01
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
6.84E+05 1.7E+00 6.8E+00 2.2E+01 1000 100 6.85E+05 93% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
8.37E+05 9.0E-01 6.8E+00 2.2E+01
1.09E+06 4.7E-01 6.8E+00 2.2E+01
1.52E+06 3.6E-01 6.8E+00 2.2E+01
3.40E+00 3.0E+00 6.8E+00 2.2E+01
1.56E+01 1.1E+01 6.8E+00 2.2E+01
3.40E+00 2.7E+00 6.8E+00 2.2E+01
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1797
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl CFS-L11-1316-T01-A 1 2.31E+02
Tl CFS-L11-1316-T02-A 1 2.03E+02
Tl CFS-L11-1316-T03-A 1 5.71 E+02
Tl CFS-L11-1316-T04-A 1 3.59E+02
Tl CFS-L11-1316-T05-A 1 1.09E+03
Tl CFS-L11-1316-T01-B 1 2.40E+02
Tl CFS-L11-1316-T02-B 1 3.56E+02
Tl CFS-L11-1316-T03-B 1 5.86E+02
Tl CFS-L11-1316-T04-B 1 7.57E+02
Tl CFS-L11-1316-T05-B 1 1.12E+03
Tl CFS-L11-1316-T01-C 1 2.50E+02
Tl CFS-L11-1316-T02-C 1 3.61 E+02
Tl CFS-L11-1316-T03-C 1 5.54E+02
Tl CFS-L11-1316-T04-C 1 8.05E+02
Tl CFS-L11-1316-T05-C 1 1.10E+03
Tl CFS-L11-1316-B01-A 1 2.30E+00 U1/2
Tl CFS-L11-1316-B02-A 1 2.30E+00 U1/2
Tl CFS-L11-1316-B03-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.31E+02 1.3E+00 4.6E+00 1.5E+01
2.03E+02 8.8E+01 4.6E+00 1.5E+01 10 100
5.71 E+02 4.0E-01 4.6E+00 1.5E+01
3.59E+02 1.4E+02 4.6E+00 1.5E+01
1.09E+03 6.2E-01 4.6E+00 1.5E+01
2.40E+02 3.7E+00 4.6E+00 1.5E+01
3.56E+02 1.0E+00 4.6E+00 1.5E+01 10 100
5.86E+02 5.2E-01 4.6E+00 1.5E+01
7.57E+02 6.9E-01 4.6E+00 1.5E+01
1.12E+03 1.7E+00 4.6E+00 1.5E+01
2.50E+02 2.5E+00 4.6E+00 1.5E+01
3.61E+02 3.8E+00 4.6E+00 1.5E+01 10 100
5.54E+02 1.1E+00 4.6E+00 1.5E+01
8.05E+02 1.1E+00 4.6E+00 1.5E+01
1.10E+03 1.0E+00 4.6E+00 1.5E+01
2.30E+00 9.3E+01 4.6E+00 1.5E+01
2.30E+00 2.7E+01 4.6E+00 1.5E+01
2.30E+00 6.3E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA InterlabLH 1313-1316 CFS
1.11E+03 91%VUICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
1.26E+03 90% VUICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
1.26E+03 90% VUICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1798
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti CFS-L11-1316-T01-A 1 1.00E+OOU1/2
Ti CFS-L11-1316-T02-A 1 1.00E+OOU1/2
Ti CFS-L11-1316-T03-A 1 1.00E+OOU1/2
Ti CFS-L11-1316-T04-A 1 1.00E+OOU1/2
Ti CFS-L11-1316-T05-A 1 1.00E+OOU1/2
Ti CFS-L11-1316-T01-B 1 1.00E+OOU1/2
Ti CFS-L11-1316-T02-B 1 1.00E+OOU1/2
Ti CFS-L11-1316-T03-B 1 1.00E+OOU1/2
Ti CFS-L11-1316-T04-B 1 1.00E+OOU1/2
Ti CFS-L11-1316-T05-B 1 1.00E+OOU1/2
Ti CFS-L11-1316-T01-C 1 1.00E+OOU1/2
Ti CFS-L11-1316-T02-C 1 1.00E+OOU1/2
Ti CFS-L11-1316-T03-C 1 1.00E+OOU1/2
Ti CFS-L11-1316-T04-C 1 1.00E+OOU1/2
Ti CFS-L11-1316-T05-C 1 1.00E+OOU1/2
Ti CFS-L11-1316-B01-A 1 1.00E+OOU1/2
Ti CFS-L11-1316-B02-A 1 1.00E+OOU1/2
Ti CFS-L11-1316-B03-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 7.4E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
1.00E+00 1.4E+01 2.0E+00 6.4E+00 10 100 9.54E+02 95% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
1.00E+00 5.7E+00 2.0E+00 6.4E+00
1.00E+00 2.1E+00 2.0E+00 6.4E+00
1.00E+00 1.5E+01 2.0E+00 6.4E+00
1.00E+00 4.7E+00 2.0E+00 6.4E+00
VUICP-OES 5/31/11 11:05 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10 AM EPA Interlab L11 1313-1316CFS
1.00E+00 1.8E+01 2.0E+00 6.4E+00 10 100 9.50E+02 95% VU ICP-OES 5/31/11 11:11 AM EPA Interlab L11 1313-1316 CFS
1.00E+00 4.0E+00 2.0E+00 6.4E+00
1.00E+00 1.4E+01 2.0E+00 6.4E+00
1.00E+00 2.9E+00 2.0E+00 6.4E+00
1.00E+00 3.8E+00 2.0E+00 6.4E+00
VUICP-OES 5/31/11 11:13 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:14 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18 AM EPA Interlab L11 1313-1316CFS
1.00E+00 7.9E-01 2.0E+00 6.4E+00 10 100 9.59E+02 96% VU ICP-OES 5/31/11 1 1:19 AM EPA Interlab L11 1313-1316 CFS
1.00E+00 2.1E+00 2.0E+00 6.4E+00
1.00E+00 4.1E+00 2.0E+00 6.4E+00
1.00E+00 5.1E+00 2.0E+00 6.4E+00
1.00E+00 7.3E+00 2.0E+00 6.4E+00
1.00E+00 3.2E+00 2.0E+00 6.4E+00
1.00E+00 3.0E+00 2.0E+00 6.4E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:23 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316CFS
                                                                                                                                                                         1-1799
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V CFS-L11-1316-T01-A 1 4.25E+01
V CFS-L11-1316-T02-A 1 2.45E+01
V CFS-L11-1316-T03-A 1 3.95E+01
V CFS-L11-1316-T04-A 1 1.80E+01
V CFS-L11-1316-T05-A 1 3.27E+01
V CFS-L11-1316-T01-B 1 4.44E+01
V CFS-L11-1316-T02-B 1 4.09E+01
V CFS-L11-1316-T03-B 1 3.99E+01
V CFS-L11-1316-T04-B 1 3.61 E+01
V CFS-L11-1316-T05-B 1 3.44E+01
V CFS-L11-1316-T01-C 1 4.44E+01
V CFS-L11-1316-T02-C 1 4.26E+01
V CFS-L11-1316-T03-C 1 3.94E+01
V CFS-L11-1316-T04-C 1 3.55E+01
V CFS-L11-1316-T05-C 1 3.27E+01
V CFS-L11-1316-B01-A 1 7.50E-01 U1/2
V CFS-L11-1316-B02-A 1 7.50E-01 U1/2
V CFS-L11-1316-B03-A 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.25E+01 3.2E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
2.45E+01 8.6E+01 1 .5E+00 4.8E+00 10 100 1.01E+03 99% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
3.95E+01 2.0E+00 1 .5E+00 4.8E+00
1.80E+01 1.4E+02 1.5E+00 4.8E+00
3.27E+01 2.5E+00 1 .5E+00 4.8E+00
4.44E+01 7.9E-01 1 .5E+00 4.8E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
4.09E+01 9.0E-01 1 .5E+00 4.8E+00 10 100 1 .05E+03 101% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
3.99E+01 8.8E-01 1 .5E+00 4.8E+00
3.61 E+01 2.1E+00 1.5E+00 4.8E+00
3.44E+01 1.2E+00 1 .5E+00 4.8E+00
4.44E+01 4.0E+00 1 .5E+00 4.8E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
4.26E+01 4.7E+00 1 .5E+00 4.8E+00 10 100 1.05E+03 101% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
3.94E+01 2.8E+00 1.5E+00 4.8E+00
3.55E+01 2.4E+00 1.5E+00 4.8E+00
3.27E+01 2.5E+00 1.5E+00 4.8E+00
7.50E-01 2.8E+02 1.5E+00 4.8E+00
7.50E-01 7.7E+01 1.5E+00 4.8E+00
7.50E-01 8.0E+01 1.5E+00 4.8E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1800
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn CFS-L11-1316-T01-A 1 1.50E+04
Zn CFS-L11-1316-T02-A 1 1.51E+04
Zn CFS-L11-1316-T03-A 1 3.18E+04
Zn CFS-L11-1316-T04-A 1 1.96E+04
Zn CFS-L11-1316-T05-A 1 6.53E+04
Zn CFS-L11-1316-T01-B 1 1.60E+04
Zn CFS-L11-1316-T02-B 1 2.20E+04
Zn CFS-L11-1316-T03-B 1 3.14E+04
Zn CFS-L11-1316-T04-B 1 3.61 E+04
Zn CFS-L11-1316-T05-B 1 6.52E+04
Zn CFS-L11-1316-T01-C 1 1.56E+04
Zn CFS-L11-1316-T02-C 1 2.19E+04
Zn CFS-L11-1316-T03-C 1 3.07E+04
Zn CFS-L11-1316-T04-C 1 4.98E+04
Zn CFS-L11-1316-T05-C 1 6.57E+04
Zn CFS-L11-1316-B01-A 1 1.77E+OOE
Zn CFS-L11-1316-B02-A 1 1.61E+OOE
Zn CFS-L11-1316-B03-A 1 1.61E+OOE
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.50E+04 1.4E-01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 5/31/11 11:01 AM EPA Interlab L11 1313-1316 CFS
1.51 E+04 7.2E+01 1 .OE+00 3.2E+00 10 100 1 .60E+04 88% VU ICP-OES 5/31/11 11:03 AM EPA Interlab L11 1313-1316 CFS
3.18E+04 9.7E-01 1 .OE+00 3.2E+00
1.96E+04 1.1E+02 1 .OE+00 3.2E+00
6.53E+04 7.8E-01 1 .OE+00 3.2E+00
1.60E+04 7.2E-01 1 .OE+00 3.2E+00
VUICP-OES 5/31/11 11:05AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:06AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:08 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:10AM EPA Interlab L11 1313-1316CFS
2.20E+04 2.4E-01 1 .OE+00 3.2E+00 10 100 2.29E+04 90% VU ICP-OES 5/31/11 11:1 1 AM EPA Interlab L11 1313-1316 CFS
3.14E+04 9.0E-01 1 .OE+00 3.2E+00
3.61 E+04 9.3E-01 1 .OE+00 3.2E+00
6.52E+04 1.6E+00 1 .OE+00 3.2E+00
1.56E+04 7.1E-01 1 .OE+00 3.2E+00
VUICP-OES 5/31/11 11:13AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:14AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:16 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 11:18AM EPA Interlab L11 1313-1316CFS
2.19E+04 9.7E-01 1 .OE+00 3.2E+00 10 100 2.28E+04 94% VU ICP-OES 5/31/11 11:19 AM EPA Interlab L11 1313-1316 CFS
3.07E+04 1.6E+00 1. OE+00 3.2E+00
4.98E+04 6.0E-01 1. OE+00 3.2E+00
6.57E+04 2.2E-01 1. OE+00 3.2E+00
1.77E+00 1.7E+01 1. OE+00 3.2E+00
1.61E+00 3.5E+00 1. OE+00 3.2E+00
1.61E+00 2.5E+01 1. OE+00 3.2E+00
VUICP-OES 5/31/11 11:21 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:23AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 1 1:24 AM EPA Interlab L11 1313-1316CFS
VUICP-OES 5/31/11 10:56 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 10:58 AM EPA Interlab L11 1313-1316 CFS
VUICP-OES 5/31/11 11:00 AM EPA Interlab L11 1313-1316 CFS
                                                                                                                                                                         1-1801
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al CFS-LRef-1316-T01-A 1 4.85E+01
Al CFS-LRef-1316-T02-A 1 4.35E+01
Al CFS-LRef-1316-T03-A 1 4.07E+01
Al CFS-LRef-1316-T04-A 1 5.68E+01
Al CFS-LRef-1316-T01-B 1 4.33E+01
Al CFS-LRef-1316-T02-B 1 5.21E+01
Al CFS-LRef-1316-T03-B 1 5.38E+01
Al CFS-LRef-1316-T04-B 1 5.07E+01
Al CFS-LRef-1316-T01-C 1 4.18E+01
Al CFS-LRef-1316-T02-C 1 4.38E+01
Al CFS-LRef-1316-T03-C 1 5.64E+01
Al CFS-LRef-1316-T04-C 1 5.05E+01
Al CFS-LRef-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.85E+01 9.3E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
4.35E+01 5.3E+00 1 .OE+00 3.2E+00 1000 100 1.10E+03 106% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
4.07E+01 5.6E+01 1 .OE+00 3.2E+00
5.68E+01 3.3E+00 1 .OE+00 3.2E+00
4.33E+01 8.0E+00 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
5.21E+01 5.2E+00 1 .OE+00 3.2E+00 1000 100 1.01E+03 96% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
5.38E+01 2.0E+00 1 .OE+00 3.2E+00
5.07E+01 2.5E+00 1 .OE+00 3.2E+00
4.18E+01 3.6E+00 1 .OE+00 3.2E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
4.38E+01 3.5E+00 1 .OE+00 3.2E+00 1000 100 1.15E+03 11 1% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
5.64E+01 1.1E+01 1. OE+00 3.2E+00
5.05E+01 3.8E+00 1 .OE+00 3.2E+00
5.00E-01 1.6E+01 1. OE+00 3.2E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                                  1-1802
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb CFS-LRef-1316-T01-A 1 4.01E+01
Sb CFS-LRef-1316-T02-A 1 3.50E+01
Sb CFS-LRef-1316-T03-A 1 4.86E+01
Sb CFS-LRef-1316-T04-A 1 5.37E+01
Sb CFS-LRef-1316-T01-B 1 2.44E+01
Sb CFS-LRef-1316-T02-B 1 3.45E+01
Sb CFS-LRef-1316-T03-B 1 5.34E+01
Sb CFS-LRef-1316-T04-B 1 5.91E+01
Sb CFS-LRef-1316-T01-C 1 3.50E+01
Sb CFS-LRef-1316-T02-C 1 4.39E+01
Sb CFS-LRef-1316-T03-C 1 5.00E+01
Sb CFS-LRef-1316-T04-C 1 5.11E+01
Sb CFS-LRef-1316-B01-A 1 3.75E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.01E+01 1.1E+01 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
3.50E+01 2.8E+01 7.5E+00 2.4E+01 10 120 1 .35E+03 110% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
4.86E+01 6.0E+01 7.5E+00 2.4E+01
5.37E+01 2.3E+01 7.5E+00 2.4E+01
2.44E+01 3.2E+01 7.5E+00 2.4E+01
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
3.45E+01 1.1E+01 7.5E+00 2.4E+01 10 100 1 .03E+03 99% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
5.34E+01 1.9E+01 7.5E+00 2.4E+01
5.91E+01 2.2E+01 7.5E+00 2.4E+01
3.50E+01 2.3E+01 7.5E+00 2.4E+01
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
4.39E+01 9.4E+00 7.5E+00 2.4E+01 10 100 1.14E+03 109% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
5.00E+01 3.0E+01 7.5E+00 2.4E+01
5.11E+01 2.2E+01 7.5E+00 2.4E+01
3.75E+00 5.0E+03 7.5E+00 2.4E+01
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1803
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
As Sample Dilution Cone. Qualifier Revi
ug/L
As CFS-LRef-1316-T01-A 1 1.28E+01 E
As CFS-LRef-1316-T02-A 1 1.62E+01 E
As CFS-LRef-1316-T03-A 1 2.28E+01 E
As CFS-LRef-1316-T04-A 1 2.84E+01 E
As CFS-LRef-1316-T01-B 1 1.75E+01 E
As CFS-LRef-1316-T02-B 1 1.79E+01 E
As CFS-LRef-1316-T03-B 1 3.08E+01 E
As CFS-LRef-1316-T04-B 1 3.63E+01
As CFS-LRef-1316-T01-C 1 1.42E+01 E
As CFS-LRef-1316-T02-C 1 1.53E+01 E
As CFS-LRef-1316-T03-C 1 2.99E+01 E
As CFS-LRef-1316-T04-C 1 2.56E+01 E
As CFS-LRef-1316-B01-A 1 5.50E+00 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.28E+01 6.7E+01 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
1.62E+01 4.7E+01 1.1E+01 3.5E+01 10 120 1 .34E+03 1 10% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
2.28E+01 9.1E+01 1.1E+01 3.5E+01
2.84E+01 1.3E+01 1.1E+01 3.5E+01
1.75E+01 3.7E+01 1.1E+01 3.5E+01
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.79E+01 4.9E+01 1.1E+01 3.5E+01 10 100 1 .02E+03 100% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
3.08E+01 3.8E+01 1.1E+01 3.5E+01
3.63E+01 2.7E+01 1.1E+01 3.5E+01
1.42E+01 2.6E+01 1.1E+01 3.5E+01
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.53E+01 1.1E+01 1.1E+01 3.5E+01 10 100 1.12E+03 1 11% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
2.99E+01 3.1E+01 1.1E+01 3.5E+01
2.56E+01 2.4E+01 1.1E+01 3.5E+01
5.50E+00 8.1E+02 1.1E+01 3.5E+01
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1804
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B CFS-LRef-1316-T01-A 1 2.37E+02
B CFS-LRef-1316-T02-A 1 3.63E+02
B CFS-LRef-1316-T03-A 1 6.12E+02
B CFS-LRef-1316-T04-A 1 1.06E+03
B CFS-LRef-1316-T01-B 1 2.06E+02
B CFS-LRef-1316-T02-B 1 3.27E+02
B CFS-LRef-1316-T03-B 1 6.56E+02
B CFS-LRef-1316-T04-B 1 1.04E+03
B CFS-LRef-1316-T01-C 1 1.84E+02
B CFS-LRef-1316-T02-C 1 3.15E+02
B CFS-LRef-1316-T03-C 1 6.53E+02
B CFS-LRef-1316-T04-C 1 1.02E+03
B CFS-LRef-1316-B01-A 1 9.09E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.37E+02 8.6E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
3.63E+02 9.6E-01 1 .OE+00 3.2E+00 1000 100 1 .39E+03 102% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
6.12E+02 6.3E+01 1 .OE+00 3.2E+00
1.06E+03 1.1E-01 1. OE+00 3.2E+00
2.06E+02 1.8E+00 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
3.27E+02 2.0E+00 1 .OE+00 3.2E+00 1000 100 1 .26E+03 93% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
6.56E+02 1.5E+00 1 .OE+00 3.2E+00
1.04E+03 1.6E+00 1 .OE+00 3.2E+00
1.84E+02 2.0E+00 1 .OE+00 3.2E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
3.15E+02 1.2E+00 1 .OE+00 3.2E+00 1000 100 1.37E+03 106% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
6.53E+02 2.2E+00 1. OE+00 3.2E+00
1.02E+03 1.2E+00 1. OE+00 3.2E+00
9.09E+01 7.7E-01 1 .OE+00 3.2E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1805
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba CFS-LRef-1316-T01-A 1 9.73E+01
Ba CFS-LRef-1316-T02-A 1 8.78E+01
Ba CFS-LRef-1316-T03-A 1 6.22E+01
Ba CFS-LRef-1316-T04-A 1 6.17E+01
Ba CFS-LRef-1316-T01-B 1 9.48E+01
Ba CFS-LRef-1316-T02-B 1 8.64E+01
Ba CFS-LRef-1316-T03-B 1 7.36E+01
Ba CFS-LRef-1316-T04-B 1 6.09E+01
Ba CFS-LRef-1316-T01-C 1 9.40E+01
Ba CFS-LRef-1316-T02-C 1 8.75E+01
Ba CFS-LRef-1316-T03-C 1 7.59E+01
Ba CFS-LRef-1316-T04-C 1 6.03E+01
Ba CFS-LRef-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.73E+01 3.7E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
8.78E+01 6.3E-01 1 .OE+00 3.2E+00 10 120 1 .42E+03 11 1% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
6.22E+01 7.6E+01 1 .OE+00 3.2E+00
6.17E+01 7.3E-01 1 .OE+00 3.2E+00
9.48E+01 2.7E-01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
8.64E+01 2.4E+00 1 .OE+00 3.2E+00 10 100 1 .09E+03 100% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
7.36E+01 1.7E+00 1 .OE+00 3.2E+00
6.09E+01 1.1E+00 1. OE+00 3.2E+00
9.40E+01 5.0E-01 1 .OE+00 3.2E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
8.75E+01 1.0E+00 1 .OE+00 3.2E+00 10 100 1.21E+03 112% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
7.59E+01 1.6E+00 1. OE+00 3.2E+00
6.03E+01 5.9E-01 1. OE+00 3.2E+00
5.00E-01 2.0E+01 1. OE+00 3.2E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1806
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be CFS-LRef-1316-T01-A 1 9.50E-01 U1/2
Be CFS-LRef-1316-T02-A 1 9.50E-01 U1/2
Be CFS-LRef-1316-T03-A 1 9.50E-01 U1/2
Be CFS-LRef-1316-T04-A 1 9.50E-01 U1/2
Be CFS-LRef-1316-T01-B 1 9.50E-01 U1/2
Be CFS-LRef-1316-T02-B 1 9.50E-01 U1/2
Be CFS-LRef-1316-T03-B 1 9.50E-01 U1/2
Be CFS-LRef-1316-T04-B 1 9.50E-01 U1/2
Be CFS-LRef-1316-T01-C 1 9.50E-01 U1/2
Be CFS-LRef-1316-T02-C 1 9.50E-01 U1/2
Be CFS-LRef-1316-T03-C 1 9.50E-01 U1/2
Be CFS-LRef-1316-T04-C 1 9.50E-01 U1/2
Be CFS-LRef-1316-B01-A 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.5E+01 1 .9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 9.6E+01 1 .9E+00 6.0E+00 10 120 1.37E+03 114% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 6.0E+01 1 .9E+00 6.0E+00
9.50E-01 3.9E+01 1 .9E+00 6.0E+00
9.50E-01 1.2E+02 1 .9E+00 6.0E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 5.6E+01 1 .9E+00 6.0E+00 10 100 1.01E+03 101% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 1.1E+02 1.9E+00 6.0E+00
9.50E-01 6.6E+01 1 .9E+00 6.0E+00
9.50E-01 1.2E+02 1.9E+00 6.0E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 6.8E+01 1.9E+00 6.0E+00 10 100 1.13E+03 113% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 5.7E+01 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00
9.50E-01 7.5E+01 1.9E+00 6.0E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1807
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd CFS-LRef-1316-T01-A 1 5.19E+03
Cd CFS-LRef-1316-T02-A 1 7.46E+03
Cd CFS-LRef-1316-T03-A 1 1.11E+04
Cd CFS-LRef-1316-T04-A 1 1.33E+04
Cd CFS-LRef-1316-T01-B 1 5.20E+03
Cd CFS-LRef-1316-T02-B 1 7.40E+03
Cd CFS-LRef-1316-T03-B 1 1.08E+04
Cd CFS-LRef-1316-T04-B 1 1.35E+04
Cd CFS-LRef-1316-T01-C 1 5.30E+03
Cd CFS-LRef-1316-T02-C 1 7.64E+03
Cd CFS-LRef-1316-T03-C 1 1.11E+04
Cd CFS-LRef-1316-T04-C 1 1.34E+04
Cd CFS-LRef-1316-B01-A 1 1.10E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.19E+03 5.4E-01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
7.46E+03 8.9E-01 2.2E+00 7.0E+00 10 120 8.70E+03 103% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
1.11E+04 6.9E+01 2.2E+00 7.0E+00
1.33E+04 9.6E-01 2.2E+00 7.0E+00
5.20E+03 9.5E-01 2.2E+00 7.0E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
7.40E+03 2.3E+00 2.2E+00 7.0E+00 10 100 8.35E+03 95% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
1.08E+04 1.6E+00 2.2E+00 7.0E+00
1.35E+04 1.9E+00 2.2E+00 7.0E+00
5.30E+03 3.9E-01 2.2E+00 7.0E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
7.64E+03 5.4E-01 2.2E+00 7.0E+00 10 100 8.65E+03 101% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
1.11E+04 1.9E+00 2.2E+00 7.0E+00
1.34E+04 9.2E-01 2.2E+00 7.0E+00
1.10E+00 7.0E+01 2.2E+00 7.0E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1808
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca CFS-LRef-1316-T01-A 1 6.81E+05
Ca CFS-LRef-1316-T02-A 1 6.56E+05
Ca CFS-LRef-1316-T03-A 1 5.71 E+05
Ca CFS-LRef-1316-T04-A 1 5.77E+05
Ca CFS-LRef-1316-T01-B 1 6.74E+05
Ca CFS-LRef-1316-T02-B 1 6.48E+05
Ca CFS-LRef-1316-T03-B 1 6.12E+05
Ca CFS-LRef-1316-T04-B 1 5.83E+05
Ca CFS-LRef-1316-T01-C 1 6.77E+05
Ca CFS-LRef-1316-T02-C 1 6.52E+05
Ca CFS-LRef-1316-T03-C 1 6.26E+05
Ca CFS-LRef-1316-T04-C 1 5.78E+05
Ca CFS-LRef-1316-B01-A 1 3.57E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.81E+05 4.5E-01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
6.56E+05 7.6E-01 2.6E+00 8.3E+00 1000 100 6.57E+05 90% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
5.71 E+05 6.0E+01 2.6E+00 8.3E+00
5.77E+05 4.8E-01 2.6E+00 8.3E+00
6.74E+05 8.0E-01 2.6E+00 8.3E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
6.48E+05 2.4E+00 2.6E+00 8.3E+00 1000 100 6.49E+05 87% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
6.12E+05 1.8E+00 2.6E+00 8.3E+00
5.83E+05 1.2E+00 2.6E+00 8.3E+00
6.77E+05 3.2E-01 2.6E+00 8.3E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
6.52E+05 1.1E-01 2.6E+00 8.3E+00 1000 100 6.53E+05 89% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
6.26E+05 1.9E+00 2.6E+00 8.3E+00
5.78E+05 1.0E+00 2.6E+00 8.3E+00
3.57E+01 1.7E+01 2.6E+00 8.3E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1809
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cr Sample Dilution Cone. Qualifier Revi
ug/L
Cr CFS-LRef-1316-T01-A 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T02-A 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T03-A 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T04-A 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T01-B 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T02-B 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T03-B 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T04-B 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T01-C 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T02-C 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T03-C 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T04-C 1 6.00E-01 U1/2
Cr CFS-LRef-1316-B01-A 1 6.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 2.7E+02 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 9.6E+01 1.2E+00 3.8E+00 10 120 1.30E+03 109% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 8.6E+01 1.2E+00 3.8E+00
6.00E-01 1.7E+02 1.2E+00 3.8E+00
6.00E-01 6.7E+02 1.2E+00 3.8E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 9.2E+02 1.2E+00 3.8E+00 10 100 9.68E+02 97% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 4.8E+02 1.2E+00 3.8E+00
6.00E-01 6.9E+01 1.2E+00 3.8E+00
6.00E-01 1.8E+02 1.2E+00 3.8E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 4.8E+01 1.2E+00 3.8E+00 10 100 1.10E+03 110% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 5.0E+02 1.2E+00 3.8E+00
6.00E-01 3.7E+02 1.2E+00 3.8E+00
6.00E-01 1.5E+02 1.2E+00 3.8E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1810
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co CFS-LRef-1316-T01-A 1 1.22E+02
Co CFS-LRef-1316-T02-A 1 2.12E+02
Co CFS-LRef-1316-T03-A 1 3.94E+02
Co CFS-LRef-1316-T04-A 1 5.70E+02
Co CFS-LRef-1316-T01-B 1 1.18E+02
Co CFS-LRef-1316-T02-B 1 2.07E+02
Co CFS-LRef-1316-T03-B 1 3.97E+02
Co CFS-LRef-1316-T04-B 1 5.82E+02
Co CFS-LRef-1316-T01-C 1 1.21E+02
Co CFS-LRef-1316-T02-C 1 2.13E+02
Co CFS-LRef-1316-T03-C 1 4.00E+02
Co CFS-LRef-1316-T04-C 1 5.81 E+02
Co CFS-LRef-1316-B01-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.22E+02 4.3E-01 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
2.12E+02 3.9E-01 1 .8E+00 5.7E+00 10 120 1.47E+03 105% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
3.94E+02 6.6E+01 1.8E+00 5.7E+00
5.70E+02 2.7E-01 1.8E+00 5.7E+00
1.18E+02 5.1E-01 1.8E+00 5.7E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
2.07E+02 2.1E+00 1.8E+00 5.7E+00 10 100 1.14E+03 93% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
3.97E+02 1.7E+00 1.8E+00 5.7E+00
5.82E+02 1.3E+00 1.8E+00 5.7E+00
1.21 E+02 4.0E-01 1.8E+00 5.7E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
2.13E+02 7.1E-01 1.8E+00 5.7E+00 10 100 1.28E+03 107% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
4.00E+02 2.1E+00 1.8E+00 5.7E+00
5.81 E+02 8.8E-01 1.8E+00 5.7E+00
9.00E-01 1.3E+02 1.8E+00 5.7E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1811
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu CFS-LRef-1316-T01-A 1 1.08E+03
Cu CFS-LRef-1316-T02-A 1 1.38E+03
Cu CFS-LRef-1316-T03-A 1 2.44E+03
Cu CFS-LRef-1316-T04-A 1 3.81 E+03
Cu CFS-LRef-1316-T01-B 1 1.12E+03
Cu CFS-LRef-1316-T02-B 1 1.36E+03
Cu CFS-LRef-1316-T03-B 1 2.63E+03
Cu CFS-LRef-1316-T04-B 1 3.93E+03
Cu CFS-LRef-1316-T01-C 1 1.14E+03
Cu CFS-LRef-1316-T02-C 1 1.39E+03
Cu CFS-LRef-1316-T03-C 1 2.62E+03
Cu CFS-LRef-1316-T04-C 1 3.85E+03
Cu CFS-LRef-1316-B01-A 1 1.85E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+03 4.7E-01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
1.38E+03 2.1E+00 3.7E+00 1.2E+01 10 120 2.58E+03 100% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
2.44E+03 3.0E+01 3.7E+00 1.2E+01
3.81 E+03 1.7E+00 3.7E+00 1.2E+01
1.12E+03 9.3E-01 3.7E+00 1.2E+01
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.36E+03 2.3E+00 3.7E+00 1.2E+01 10 100 2.23E+03 87% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
2.63E+03 1.9E+00 3.7E+00 1.2E+01
3.93E+03 9.0E-01 3.7E+00 1.2E+01
1.14E+03 5.8E-01 3.7E+00 1.2E+01
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.39E+03 1.1E+00 3.7E+00 1.2E+01 10 100 2.44E+03 105% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
2.62E+03 1.3E+00 3.7E+00 1.2E+01
3.85E+03 1.3E+00 3.7E+00 1.2E+01
1.85E+00 8.3E+00 3.7E+00 1.2E+01
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1812
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe CFS-LRef-1316-T01-A 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T02-A 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T03-A 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T04-A 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T01-B 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T02-B 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T03-B 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T04-B 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T01-C 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T02-C 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T03-C 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T04-C 1 1.00E+OOU1/2
Fe CFS-LRef-1316-B01-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.4E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 4.2E+01 2.0E+00 6.4E+00 1000 100 1.10E+03 1 10% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 8.6E+01 2.0E+00 6.4E+00
1.00E+00 7.5E+02 2.0E+00 6.4E+00
1.00E+00 3.1E+01 2.0E+00 6.4E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 3.5E+00 2.0E+00 6.4E+00 1000 100 9.66E+02 96% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 1.1E+02 2.0E+00 6.4E+00
1.00E+00 4.9E+01 2.0E+00 6.4E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 5.8E+01 2.0E+00 6.4E+00 1000 100 1.10E+03 110% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 5.5E+01 2.0E+00 6.4E+00
1.00E+00 3.3E+01 2.0E+00 6.4E+00
1.00E+00 7.3E+00 2.0E+00 6.4E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1813
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb CFS-LRef-1316-T01-A 1 1.14E+03
Pb CFS-LRef-1316-T02-A 1 1.23E+03
Pb CFS-LRef-1316-T03-A 1 1.30E+03
Pb CFS-LRef-1316-T04-A 1 1.33E+03
Pb CFS-LRef-1316-T01-B 1 1.18E+03
Pb CFS-LRef-1316-T02-B 1 1.14E+03
Pb CFS-LRef-1316-T03-B 1 1.31E+03
Pb CFS-LRef-1316-T04-B 1 1.34E+03
Pb CFS-LRef-1316-T01-C 1 1.17E+03
Pb CFS-LRef-1316-T02-C 1 1.21E+03
Pb CFS-LRef-1316-T03-C 1 1.31E+03
Pb CFS-LRef-1316-T04-C 1 1.33E+03
Pb CFS-LRef-1316-B01-A 1 3.40E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.14E+03 2.3E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
1.23E+03 8.2E-01 6.8E+00 2.2E+01 10 120 2.36E+03 94% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
1.30E+03 6.6E+01 6.8E+00 2.2E+01
1.33E+03 8.9E-01 6.8E+00 2.2E+01
1.18E+03 1.1E+00 6.8E+00 2.2E+01
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.14E+03 2.0E+00 6.8E+00 2.2E+01 10 100 1 .97E+03 83% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
1.31E+03 2.0E+00 6.8E+00 2.2E+01
1.34E+03 1.0E+00 6.8E+00 2.2E+01
1.17E+03 3.4E-01 6.8E+00 2.2E+01
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.21E+03 1.2E+00 6.8E+00 2.2E+01 10 100 2.19E+03 98% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
1.31E+03 2.2E+00 6.8E+00 2.2E+01
1.33E+03 1.2E+00 6.8E+00 2.2E+01
3.40E+00 1.0E+02 6.8E+00 2.2E+01
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1814
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li CFS-LRef-1316-T01-A 1 1.07E+01
Li CFS-LRef-1316-T02-A 1 8.37E+00
Li CFS-LRef-1316-T03-A 1 5.06E+00 E
Li CFS-LRef-1316-T04-A 1 1.24E+01
Li CFS-LRef-1316-T01-B 1 9.99E+00
Li CFS-LRef-1316-T02-B 1 9.98E+00
Li CFS-LRef-1316-T03-B 1 4.80E+00 E
Li CFS-LRef-1316-T04-B 1 9.62E+00
Li CFS-LRef-1316-T01-C 1 1.09E+01
Li CFS-LRef-1316-T02-C 1 8.91 E+00
Li CFS-LRef-1316-T03-C 1 4.83E+00 E
Li CFS-LRef-1316-T04-C 1 1.47E+01
Li CFS-LRef-1316-B01-A 1 9.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.07E+01 2.0E+00 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
8.37E+00 3.2E+00 1 .9E+00 6.0E+00 10 120 1.24E+03 102% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
5.06E+00 3.3E+00 1.9E+00 6.0E+00
1.24E+01 5.6E+00 1.9E+00 6.0E+00
9.99E+00 8.4E+00 1.9E+00 6.0E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
9.98E+00 7.7E+00 1.9E+00 6.0E+00 10 100 8.93E+02 88% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
4.80E+00 1.6E+00 1.9E+00 6.0E+00
9.62E+00 3.2E+00 1.9E+00 6.0E+00
1.09E+01 6.7E+00 1.9E+00 6.0E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
8.91E+00 3.3E+00 1.9E+00 6.0E+00 10 100 9.82E+02 97% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
4.83E+00 1.6E+00 1.9E+00 6.0E+00
1.47E+01 9.6E+00 1.9E+00 6.0E+00
9.50E-01 2.8E+00 1.9E+00 6.0E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1815
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Mn CFS-LRef-1316-T01-A 1 1.77E+03
Mn CFS-LRef-1316-T02-A 1 3.46E+03
Mn CFS-LRef-1316-T03-A 1 7.13E+03
Mn CFS-LRef-1316-T04-A 1 1.14E+04
Mn CFS-LRef-1316-T01-B 1 1.76E+03
Mn CFS-LRef-1316-T02-B 1 3.33E+03
Mn CFS-LRef-1316-T03-B 1 7.29E+03
Mn CFS-LRef-1316-T04-B 1 1.15E+04
Mn CFS-LRef-1316-T01-C 1 1.79E+03
Mn CFS-LRef-1316-T02-C 1 3.39E+03
Mn CFS-LRef-1316-T03-C 1 7.25E+03
Mn CFS-LRef-1316-T04-C 1 1.16E+04
Mn CFS-LRef-1316-B01-A 1 1.00E+OOU1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+03 1.2E+00 2.0E+00 6.4E+00
3.46E+03 1.2E+00 2.0E+00 6.4E+00 10 120
7.13E+03 5.3E+01 2.0E+00 6.4E+00
1.14E+04 3.6E-01 2.0E+00 6.4E+00
1.76E+03 3.9E-01 2.0E+00 6.4E+00
3.33E+03 2.4E+00 2.0E+00 6.4E+00 10 100
7.29E+03 1.9E+00 2.0E+00 6.4E+00
1.15E+04 4.8E-01 2.0E+00 6.4E+00
1.79E+03 1.9E+00 2.0E+00 6.4E+00
3.39E+03 6.8E-01 2.0E+00 6.4E+00 10 100
7.25E+03 1.8E+00 2.0E+00 6.4E+00
1.16E+04 4.1E-01 2.0E+00 6.4E+00
1.00E+00 3.5E+00 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
4.56E+03 92% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
4.21E+03 88% VUICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
4.35E+03 96% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1816
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg CFS-LRef-1316-T01-A 1 6.52E+04
Mg CFS-LRef-1316-T02-A 1 1.24E+05
Mg CFS-LRef-1316-T03-A 1 2.76E+05
Mg CFS-LRef-1316-T04-A 1 4.95E+05
Mg CFS-LRef-1316-T01-B 1 6.36E+04
Mg CFS-LRef-1316-T02-B 1 1.19E+05
Mg CFS-LRef-1316-T03-B 1 2.85E+05
Mg CFS-LRef-1316-T04-B 1 5.11E+05
Mg CFS-LRef-1316-T01-C 1 6.28E+04
Mg CFS-LRef-1316-T02-C 1 1.22E+05
Mg CFS-LRef-1316-T03-C 1 2.94E+05
Mg CFS-LRef-1316-T04-C 1 5.08E+05
Mg CFS-LRef-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.52E+04 6.2E-01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
1.24E+05 1.6E+00 1 .OE+00 3.2E+00 1000 100 1 .25E+05 91%VUICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
2.76E+05 6.9E+01 1 .OE+00 3.2E+00
4.95E+05 3.2E-01 1 .OE+00 3.2E+00
6.36E+04 1.2E+00 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.19E+05 1.4E+00 1.0E+00 3.2E+00 1000 100 1 .20E+05 87% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
2.85E+05 1.3E+00 1 .OE+00 3.2E+00
5.11E+05 1.5E+00 1. OE+00 3.2E+00
6.28E+04 1.4E-01 1 .OE+00 3.2E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.22E+05 1.3E+00 1 .OE+00 3.2E+00 1000 100 1.23E+05 92% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
2.94E+05 2.4E+00 1. OE+00 3.2E+00
5.08E+05 9.8E-01 1. OE+00 3.2E+00
5.00E-01 2.2E+01 1. OE+00 3.2E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1817
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo CFS-LRef-1316-T01-A 1 1.31E+01
Mo CFS-LRef-1316-T02-A 1 1.27E+01
Mo CFS-LRef-1316-T03-A 1 1.18E+01
Mo CFS-LRef-1316-T04-A 1 1.50E+01
Mo CFS-LRef-1316-T01-B 1 9.82E+00
Mo CFS-LRef-1316-T02-B 1 1.24E+01
Mo CFS-LRef-1316-T03-B 1 1.36E+01
Mo CFS-LRef-1316-T04-B 1 1.62E+01
Mo CFS-LRef-1316-T01-C 1 9.37E+00
Mo CFS-LRef-1316-T02-C 1 1.11E+01
Mo CFS-LRef-1316-T03-C 1 1.32E+01
Mo CFS-LRef-1316-T04-C 1 1.45E+01
Mo CFS-LRef-1316-B01-A 1 6.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.31E+01 3.7E+00 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
1.27E+01 9.9E+00 1 .2E+00 3.8E+00 10 120 1 .33E+03 110% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
1.18E+01 7.7E+01 1.2E+00 3.8E+00
1.50E+01 8.8E+00 1 .2E+00 3.8E+00
9.82E+00 2.0E+01 1 .2E+00 3.8E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.24E+01 1.8E+01 1.2E+00 3.8E+00 10 100 9.96E+02 98% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
1.36E+01 1.4E+01 1.2E+00 3.8E+00
1.62E+01 4.0E+00 1 .2E+00 3.8E+00
9.37E+00 2.5E+01 1 .2E+00 3.8E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.11E+01 1.1E+01 1.2E+00 3.8E+00 10 100 1.12E+03 11 1% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
1.32E+01 9.0E+00 1.2E+00 3.8E+00
1.45E+01 1.4E+01 1.2E+00 3.8E+00
6.00E-01 9.3E+01 1.2E+00 3.8E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1818
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni CFS-LRef-1316-T01-A 1 2.74E+02
Ni CFS-LRef-1316-T02-A 1 4.49E+02
Ni CFS-LRef-1316-T03-A 1 7.79E+02
Ni CFS-LRef-1316-T04-A 1 1.05E+03
Ni CFS-LRef-1316-T01-B 1 2.73E+02
Ni CFS-LRef-1316-T02-B 1 4.43E+02
Ni CFS-LRef-1316-T03-B 1 7.75E+02
Ni CFS-LRef-1316-T04-B 1 1.06E+03
Ni CFS-LRef-1316-T01-C 1 2.76E+02
Ni CFS-LRef-1316-T02-C 1 4.55E+02
Ni CFS-LRef-1316-T03-C 1 7.82E+02
Ni CFS-LRef-1316-T04-C 1 1.07E+03
Ni CFS-LRef-1316-B01-A 1 9.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.74E+02 1.2E+00 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
4.49E+02 7.0E-01 1 .8E+00 5.7E+00 10 120 1.66E+03 101% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
7.79E+02 6.6E+01 1.8E+00 5.7E+00
1.05E+03 1.3E-01 1.8E+00 5.7E+00
2.73E+02 8.3E-01 1.8E+00 5.7E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
4.43E+02 1.9E+00 1.8E+00 5.7E+00 10 100 1.35E+03 90% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
7.75E+02 1.3E+00 1.8E+00 5.7E+00
1.06E+03 1.6E+00 1.8E+00 5.7E+00
2.76E+02 6.0E-01 1.8E+00 5.7E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
4.55E+02 6.0E-01 1.8E+00 5.7E+00 10 100 1.49E+03 104% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
7.82E+02 1.7E+00 1.8E+00 5.7E+00
1.07E+03 7.0E-01 1.8E+00 5.7E+00
9.00E-01 1.5E+02 1.8E+00 5.7E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1819
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P CFS-LRef-1316-T01-A 1 8.59E+00 E
P CFS-LRef-1316-T02-A 1 2.90E+01
P CFS-LRef-1316-T03-A 1 1.66E+01
P CFS-LRef-1316-T04-A 1 2.58E+01
P CFS-LRef-1316-T01-B 1 1.37E+01
P CFS-LRef-1316-T02-B 1 5.72E+01
P CFS-LRef-1316-T03-B 1 1.92E+01
P CFS-LRef-1316-T04-B 1 3.11E+01
P CFS-LRef-1316-T01-C 1 7.47E+00 E
P CFS-LRef-1316-T02-C 1 2.69E+01
P CFS-LRef-1316-T03-C 1 1.51E+01
P CFS-LRef-1316-T04-C 1 1.79E+01
P CFS-LRef-1316-B01-A 1 6.70E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.59E+00 1.4E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
2.90E+01 1.3E+02 3.7E+00 1.2E+01 1000 100 1.14E+03 1 12% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
1.66E+01 7.4E+01 3.7E+00 1.2E+01
2.58E+01 5.7E+01 3.7E+00 1.2E+01
1.37E+01 1.1E+02 3.7E+00 1.2E+01
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
5.72E+01 2.1E+01 3.7E+00 1.2E+01 1000 100 1 .04E+03 98% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
1.92E+01 4.5E+01 3.7E+00 1.2E+01
3.11E+01 3.5E+01 3.7E+00 1.2E+01
7.47E+00 1.6E+02 3.7E+00 1.2E+01
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
2.69E+01 1.1E+02 3.7E+00 1.2E+01 1000 100 1.14E+03 11 1% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
1.51E+01 3.3E+01 3.7E+00 1.2E+01
1.79E+01 6.8E+01 3.7E+00 1.2E+01
6.70E+00 1.7E+02 3.7E+00 1.2E+01
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1820
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K CFS-LRef-1316-T01-A 1 1.05E+04
K CFS-LRef-1316-T02-A 1 1.90E+04
K CFS-LRef-1316-T03-A 1 3.52E+04
K CFS-LRef-1316-T04-A 1 5.55E+04
K CFS-LRef-1316-T01-B 1 1.03E+04
K CFS-LRef-1316-T02-B 1 1.81E+04
K CFS-LRef-1316-T03-B 1 3.69E+04
K CFS-LRef-1316-T04-B 1 5.57E+04
K CFS-LRef-1316-T01-C 1 1.03E+04
K CFS-LRef-1316-T02-C 1 1.86E+04
K CFS-LRef-1316-T03-C 1 3.63E+04
K CFS-LRef-1316-T04-C 1 5.58E+04
K CFS-LRef-1316-B01-A 1 4.63E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.05E+04 6.9E-01 1 .6E+00 5.1E+00
1.90E+04 6.7E-01 1 .6E+00 5.1E+00 1000 100
3.52E+04 6.7E+01 1 .6E+00 5.1E+00
5.55E+04 4.7E-01 1 .6E+00 5.1E+00
1.03E+04 8.9E-01 1 .6E+00 5.1E+00
1.81E+04 2.2E+00 1 .6E+00 5.1E+00 1000 100
3.69E+04 1.7E+00 1 .6E+00 5.1E+00
5.57E+04 1.8E+00 1 .6E+00 5.1E+00
1.03E+04 1.3E-01 1.6E+00 5.1E+00
1.86E+04 7.6E-01 1 .6E+00 5.1E+00 1000 100
3.63E+04 2.8E+00 1.6E+00 5.1E+00
5.58E+04 1.2E+00 1.6E+00 5.1E+00
4.63E+01 2.1E+00 1 .6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
2.00E+04 103% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.91E+04 98% VUICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.97E+04 106% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1821
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se CFS-LRef-1316-T01-A 1 8.07E+01
Se CFS-LRef-1316-T02-A 1 1.40E+02
Se CFS-LRef-1316-T03-A 1 2.67E+02
Se CFS-LRef-1316-T04-A 1 4.82E+02
Se CFS-LRef-1316-T01-B 1 7.68E+01
Se CFS-LRef-1316-T02-B 1 1.48E+02
Se CFS-LRef-1316-T03-B 1 2.77E+02
Se CFS-LRef-1316-T04-B 1 4.99E+02
Se CFS-LRef-1316-T01-C 1 9.55E+01
Se CFS-LRef-1316-T02-C 1 1.44E+02
Se CFS-LRef-1316-T03-C 1 2.94E+02
Se CFS-LRef-1316-T04-C 1 4.86E+02
Se CFS-LRef-1316-B01-A 1 7.50E+00 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.07E+01 1.1E+01 1.5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
1.40E+02 4.7E+00 1 .5E+01 4.8E+01 10 120 1 .45E+03 109% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
2.67E+02 6.7E+01 1 .5E+01 4.8E+01
4.82E+02 5.0E+00 1 .5E+01 4.8E+01
7.68E+01 3.7E+00 1 .5E+01 4.8E+01
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.48E+02 8.2E+00 1 .5E+01 4.8E+01 10 100 1.12E+03 97% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
2.77E+02 3.4E+00 1 .5E+01 4.8E+01
4.99E+02 1.9E+00 1 .5E+01 4.8E+01
9.55E+01 9.9E+00 1 .5E+01 4.8E+01
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.44E+02 5.3E+00 1 .5E+01 4.8E+01 10 100 1.22E+03 108% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
2.94E+02 1.6E+00 1.5E+01 4.8E+01
4.86E+02 1.9E+00 1.5E+01 4.8E+01
7.50E+00 2.0E+02 1.5E+01 4.8E+01
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1822
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si CFS-LRef-1316-T01-A 1 4.57E+03
Si CFS-LRef-1316-T02-A 1 5.79E+03
Si CFS-LRef-1316-T03-A 1 7.00E+03
Si CFS-LRef-1316-T04-A 1 7.58E+03
Si CFS-LRef-1316-T01-B 1 4.59E+03
Si CFS-LRef-1316-T02-B 1 5.77E+03
Si CFS-LRef-1316-T03-B 1 7.13E+03
Si CFS-LRef-1316-T04-B 1 7.73E+03
Si CFS-LRef-1316-T01-C 1 4.58E+03
Si CFS-LRef-1316-T02-C 1 5.92E+03
Si CFS-LRef-1316-T03-C 1 7.31E+03
Si CFS-LRef-1316-T04-C 1 7.66E+03
Si CFS-LRef-1316-B01-A 1 1.00E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.57E+03 1.9E+00 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
5.79E+03 1.5E+00 1.1E+00 3.5E+00 1000 100 6.74E+03 95% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
7.00E+03 3.9E+01 1.1E+00 3.5E+00
7.58E+03 3.6E-02 1.1E+00 3.5E+00
4.59E+03 1.1E+00 1.1E+00 3.5E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
5.77E+03 2.6E+00 1.1E+00 3.5E+00 1000 100 6.70E+03 93% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
7.13E+03 1.7E+00 1.1E+00 3.5E+00
7.73E+03 1.2E+00 1.1E+00 3.5E+00
4.58E+03 1.6E+00 1.1E+00 3.5E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
5.92E+03 1.1E+00 1.1E+00 3.5E+00 1000 100 6.85E+03 94% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
7.31E+03 2.0E+00 1.1E+00 3.5E+00
7.66E+03 7.3E-01 1.1E+00 3.5E+00
1.00E+01 4.2E+01 1.1E+00 3.5E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1823
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na CFS-LRef-1316-T01-A 1 2.17E+04
Na CFS-LRef-1316-T02-A 1 4.08E+04
Na CFS-LRef-1316-T03-A 1 8.49E+04
Na CFS-LRef-1316-T04-A 1 1.27E+05
Na CFS-LRef-1316-T01-B 1 2.10E+04
Na CFS-LRef-1316-T02-B 1 3.90E+04
Na CFS-LRef-1316-T03-B 1 8.55E+04
Na CFS-LRef-1316-T04-B 1 1.30E+05
Na CFS-LRef-1316-T01-C 1 2.16E+04
Na CFS-LRef-1316-T02-C 1 4.06E+04
Na CFS-LRef-1316-T03-C 1 8.47E+04
Na CFS-LRef-1316-T04-C 1 1.30E+05
Na CFS-LRef-1316-B01-A 1 1.25E+OOU1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.17E+04 7.0E-01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
4.08E+04 7.6E-01 2.5E+00 8.0E+00 1000 100 4.16E+04 86% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
8.49E+04 6.6E+01 2.5E+00 8.0E+00
1.27E+05 3.4E-01 2.5E+00 8.0E+00
2.10E+04 1.7E+00 2.5E+00 8.0E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
3.90E+04 1.3E+00 2.5E+00 8.0E+00 1000 100 3.99E+04 85% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
8.55E+04 1.8E+00 2.5E+00 8.0E+00
1.30E+05 1.1E+00 2.5E+00 8.0E+00
2.16E+04 3.0E-01 2.5E+00 8.0E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
4.06E+04 1.3E+00 2.5E+00 8.0E+00 1000 100 4.15E+04 89% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
8.47E+04 1.2E+00 2.5E+00 8.0E+00
1.30E+05 5.2E-01 2.5E+00 8.0E+00
1.25E+00 9.7E+00 2.5E+00 8.0E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1824
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-LRef-1316-T01-A 1 1.48E+03
CFS-LRef-1316-T02-A 1 2.04E+03
CFS-LRef-1316-T03-A 1 2.94E+03
CFS-LRef-1316-T04-A 1 3.67E+03
CFS-LRef-1316-T01-B 1 1.41E+03
CFS-LRef-1316-T02-B 1 2.01E+03
CFS-LRef-1316-T03-B 1 3.06E+03
CFS-LRef-1316-T04-B 1 3.70E+03
CFS-LRef-1316-T01-C 1 1.43E+03
CFS-LRef-1316-T02-C 1 2.01E+03
CFS-LRef-1316-T03-C 1 3.03E+03
CFS-LRef-1316-T04-C 1 3.70E+03
CFS-LRef-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.48E+03 1.2E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
2.04E+03 9.6E-01 1 .OE+00 3.2E+00 1000 100 3.10E+03 106% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
2.94E+03 4.0E+01 1 .OE+00 3.2E+00
3.67E+03 3.1E-01 1 .OE+00 3.2E+00
1.41E+03 9.2E-01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
2.01E+03 2.2E+00 1 .OE+00 3.2E+00 1000 100 2.97E+03 95% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
3.06E+03 2.2E+00 1 .OE+00 3.2E+00
3.70E+03 5.1E-01 1 .OE+00 3.2E+00
1.43E+03 6.5E-01 1 .OE+00 3.2E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
2.01E+03 8.4E-01 1 .OE+00 3.2E+00 1000 100 2.99E+03 98% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
3.03E+03 1.3E+00 1. OE+00 3.2E+00
3.70E+03 5.4E-01 1. OE+00 3.2E+00
5.00E-01 6.2E+01 1. OE+00 3.2E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1825
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S CFS-LRef-1316-T01-A 1 5.80E+05
S CFS-LRef-1316-T02-A 1 6.45E+05
S CFS-LRef-1316-T03-A 1 7.84E+05
S CFS-LRef-1316-T04-A 1 1.03E+06
S CFS-LRef-1316-T01-B 1 5.69E+05
S CFS-LRef-1316-T02-B 1 6.30E+05
S CFS-LRef-1316-T03-B 1 8.14E+05
S CFS-LRef-1316-T04-B 1 1.05E+06
S CFS-LRef-1316-T01-C 1 5.70E+05
S CFS-LRef-1316-T02-C 1 6.37E+05
S CFS-LRef-1316-T03-C 1 8.33E+05
S CFS-LRef-1316-T04-C 1 1.05E+06
S CFS-LRef-1316-B01-A 1 8.35E+00 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.80E+05 5.1E-01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
6.45E+05 6.4E-01 6.8E+00 2.2E+01 1000 100 6.46E+05 88% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
7.84E+05 7.1E+01 6.8E+00 2.2E+01
1.03E+06 2.4E-01 6.8E+00 2.2E+01
5.69E+05 8.9E-01 6.8E+00 2.2E+01
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
6.30E+05 2.0E+00 6.8E+00 2.2E+01 1000 100 6.31E+05 86% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
8.14E+05 1.5E+00 6.8E+00 2.2E+01
1.05E+06 1.4E+00 6.8E+00 2.2E+01
5.70E+05 3.4E-01 6.8E+00 2.2E+01
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
6.37E+05 5.5E-01 6.8E+00 2.2E+01 1000 100 6.38E+05 89% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
8.33E+05 2.1E+00 6.8E+00 2.2E+01
1.05E+06 1.1E+00 6.8E+00 2.2E+01
8.35E+00 1.2E+01 6.8E+00 2.2E+01
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1826
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
Tl CFS-LRef-1316-T01-A 1 3.83E+02
Tl CFS-LRef-1316-T02-A 1 5.73E+02
Tl CFS-LRef-1316-T03-A 1 8.35E+02
Tl CFS-LRef-1316-T04-A 1 1.17E+03
Tl CFS-LRef-1316-T01-B 1 3.86E+02
Tl CFS-LRef-1316-T02-B 1 5.47E+02
Tl CFS-LRef-1316-T03-B 1 8.78E+02
Tl CFS-LRef-1316-T04-B 1 1.19E+03
Tl CFS-LRef-1316-T01-C 1 3.83E+02
Tl CFS-LRef-1316-T02-C 1 5.64E+02
Tl CFS-LRef-1316-T03-C 1 8.89E+02
Tl CFS-LRef-1316-T04-C 1 1.17E+03
Tl CFS-LRef-1316-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.83E+02 9.7E-01 4.6E+00 1.5E+01
5.73E+02 1.1E+00 4.6E+00 1.5E+01 10 120
8.35E+02 6.8E+01 4.6E+00 1.5E+01
1.17E+03 5.7E-01 4.6E+00 1.5E+01
3.86E+02 1.7E+00 4.6E+00 1.5E+01
5.47E+02 2.2E+00 4.6E+00 1.5E+01 10 100
8.78E+02 1.2E+00 4.6E+00 1.5E+01
1.19E+03 1.7E+00 4.6E+00 1.5E+01
3.83E+02 1.7E+00 4.6E+00 1.5E+01
5.64E+02 1.5E+00 4.6E+00 1.5E+01 10 100
8.89E+02 2.1E+00 4.6E+00 1.5E+01
1.17E+03 1.2E+00 4.6E+00 1.5E+01
2.30E+00 1.0E+01 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
1.71E+03 94% VUICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.42E+03 87% VUICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.53E+03 97% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1827
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti CFS-LRef-1316-T01-A 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T02-A 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T03-A 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T04-A 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T01-B 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T02-B 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T03-B 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T04-B 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T01-C 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T02-C 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T03-C 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T04-C 1 1.00E+OOU1/2
Ti CFS-LRef-1316-B01-A 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 8.0E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 2.1E+02 2.0E+00 6.4E+00 10 120 1 .29E+03 107% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 4.5E+01 2.0E+00 6.4E+00
1.00E+00 2.2E+02 2.0E+00 6.4E+00
1.00E+00 5.8E+01 2.0E+00 6.4E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 1.7E+01 2.0E+00 6.4E+00 10 100 9.67E+02 97% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 2.8E+02 2.0E+00 6.4E+00
1.00E+00 5.2E+02 2.0E+00 6.4E+00
1.00E+00 1.6E+02 2.0E+00 6.4E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 1.2E+02 2.0E+00 6.4E+00 10 100 1.08E+03 108% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 1.7E+03 2.0E+00 6.4E+00
1.00E+00 1.5E+02 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1828
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V CFS-LRef-1316-T01-A 1 3.46E+01
V CFS-LRef-1316-T02-A 1 3.32E+01
V CFS-LRef-1316-T03-A 1 2.81E+01
V CFS-LRef-1316-T04-A 1 2.82E+01
V CFS-LRef-1316-T01-B 1 3.48E+01
V CFS-LRef-1316-T02-B 1 3.24E+01
V CFS-LRef-1316-T03-B 1 3.07E+01
V CFS-LRef-1316-T04-B 1 2.96E+01
V CFS-LRef-1316-T01-C 1 3.44E+01
V CFS-LRef-1316-T02-C 1 3.32E+01
V CFS-LRef-1316-T03-C 1 3.14E+01
V CFS-LRef-1316-T04-C 1 3.00E+01
V CFS-LRef-1316-B01-A 1 7.50E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.46E+01 2.2E+00 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
3.32E+01 4.7E+00 1 .5E+00 4.8E+00 10 120 1 .36E+03 110% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
2.81E+01 6.9E+01 1 .5E+00 4.8E+00
2.82E+01 5.0E+00 1 .5E+00 4.8E+00
3.48E+01 2.1E+00 1 .5E+00 4.8E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
3.24E+01 4.7E+00 1 .5E+00 4.8E+00 10 100 1 .02E+03 98% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
3.07E+01 7.2E-01 1 .5E+00 4.8E+00
2.96E+01 2.8E+00 1 .5E+00 4.8E+00
3.44E+01 2.1E+00 1 .5E+00 4.8E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
3.32E+01 1.4E+00 1 .5E+00 4.8E+00 10 100 1.14E+03 11 1% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
3.14E+01 5.3E+00 1.5E+00 4.8E+00
3.00E+01 3.3E+00 1.5E+00 4.8E+00
7.50E-01 5.2E+01 1.5E+00 4.8E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1829
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn CFS-LRef-1316-T01-A 1 2.58E+04
Zn CFS-LRef-1316-T02-A 1 3.69E+04
Zn CFS-LRef-1316-T03-A 1 5.46E+04
Zn CFS-LRef-1316-T04-A 1 6.87E+04
Zn CFS-LRef-1316-T01-B 1 2.60E+04
Zn CFS-LRef-1316-T02-B 1 3.73E+04
Zn CFS-LRef-1316-T03-B 1 5.51 E+04
Zn CFS-LRef-1316-T04-B 1 7.10E+04
Zn CFS-LRef-1316-T01-C 1 2.65E+04
Zn CFS-LRef-1316-T02-C 1 3.82E+04
Zn CFS-LRef-1316-T03-C 1 5.61 E+04
Zn CFS-LRef-1316-T04-C 1 6.89E+04
Zn CFS-LRef-1316-B01-A 1 5.00E-01 U1/2
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.58E+04 1.3E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VUICP-OES 1/26/11 4:11 PM EPA Interlab LRef 1313-1316 CFS
3.69E+04 1.2E+00 1 .OE+00 3.2E+00 10 120 3.80E+04 88% VU ICP-OES 1/26/11 4:12 PM EPA Interlab LRef 1313-1316 CFS
5.46E+04 5.3E+01 1 .OE+00 3.2E+00
6.87E+04 2.6E-01 1 .OE+00 3.2E+00
2.60E+04 8.6E-01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:14 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:16 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:17 PM EPA Interlab LRef 1313-1316 CFS
3.73E+04 1.7E+00 1 .OE+00 3.2E+00 10 100 3.82E+04 84% VU ICP-OES 1/26/11 4:19 PM EPA Interlab LRef 1313-1316 CFS
5.51 E+04 2.1E+00 1 .OE+00 3.2E+00
7.10E+04 1.1E+00 1.0E+00 3.2E+00
2.65E+04 4.1E-01 1 .OE+00 3.2E+00
VUICP-OES 1/26/11 4:20 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:22 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:24 PM EPA Interlab LRef 1313-1316 CFS
3.82E+04 1.1E+00 1 .OE+00 3.2E+00 10 100 3.91E+04 93% VU ICP-OES 1/26/11 4:25 PM EPA Interlab LRef 1313-1316 CFS
5.61 E+04 1.3E+00 1. OE+00 3.2E+00
6.89E+04 1.2E+00 1. OE+00 3.2E+00
5.00E-01 1.8E+01 1. OE+00 3.2E+00
VUICP-OES 1/26/11 4:27 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:29 PM EPA Interlab LRef 1313-1316 CFS
VUICP-OES 1/26/11 4:09 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1830
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
QA-QC Spreadsheet 1316:
Sample
Al Sample Dilution Cone. Qualifier
ug/L
Al CFS-LRef-1316-T01-D 1 4.29E+01
Al CFS-LRef-1316-T02-D 1 4.58E+01
Al CFS-LRef-1316-T03-D 1 5.29E+01
Al CFS-LRef-1316-T04-D 1 4.82E+01
Al CFS-LRef-1316-T01-E 1 4.20E+01
Al CFS-LRef-1316-T02-E 1 5.45E+01
Al CFS-LRef-1316-T03-E 1 5.13E+01
Al CFS-LRef-1316-T04-E 1 4.96E+01
Al CFS-LRef-1316-T01-F 1 3.95E+01
Al CFS-LRef-1316-T02-F 1 5.38E+01
Al CFS-LRef-1316-T03-F 1 4.86E+01
Al CFS-LRef-1316-T04-F 1 4.93E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.29E+01 2.1E+01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
4.58E+01 1.8E+01 1 .OE+00 3.2E+00 1000 100 1.16E+03 11 1% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
5.29E+01 9.5E-01 1 .OE+00 3.2E+00
4.82E+01 2.1E+00 1 .OE+00 3.2E+00
4.20E+01 9.2E+00 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
5.45E+01 3.5E+00 1 .OE+00 3.2E+00 1000 100 1.18E+03 113% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
5.13E+01 6.3E+00 1 .OE+00 3.2E+00
4.96E+01 3.8E+00 1 .OE+00 3.2E+00
3.95E+01 1.8E+01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
5.38E+01 2.9E+00 1 .OE+00 3.2E+00 1000 100 1.14E+03 108% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
4.86E+01 1.3E+01 1 .OE+00 3.2E+00
4.93E+01 2.5E+02 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                                 1-1831
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Sb Sample Dilution Cone. Qualifier
ug/L
Sb CFS-LRef-1316-T01-D 1 3.05E+01
Sb CFS-LRef-1316-T02-D 1 3.38E+01
Sb CFS-LRef-1316-T03-D 1 4.49E+01
Sb CFS-LRef-1316-T04-D 1 4.92E+01
Sb CFS-LRef-1316-T01-E 1 2.92E+01
Sb CFS-LRef-1316-T02-E 1 3.54E+01
Sb CFS-LRef-1316-T03-E 1 4.21E+01
Sb CFS-LRef-1316-T04-E 1 4.70E+01
Sb CFS-LRef-1316-T01-F 1 2.83E+01
Sb CFS-LRef-1316-T02-F 1 3.59E+01
Sb CFS-LRef-1316-T03-F 1 4.91E+01
Sb CFS-LRef-1316-T04-F 1 5.09E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.05E+01 1.1E+03 7.5E+00 2.4E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
3.38E+01 4.8E+00 7.5E+00 2.4E+01 10 100 1.15E+03 11 1% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
4.49E+01 8.5E-01 7.5E+00 2.4E+01
4.92E+01 1.6E+01 7.5E+00 2.4E+01
2.92E+01 2.3E+01 7.5E+00 2.4E+01
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
3.54E+01 4.4E+01 7.5E+00 2.4E+01 10 100 1.17E+03 113% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
4.21E+01 1.6E+01 7.5E+00 2.4E+01
4.70E+01 8.9E+00 7.5E+00 2.4E+01
2.83E+01 5.0E+01 7.5E+00 2.4E+01
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
3.59E+01 5.8E+01 7.5E+00 2.4E+01 10 100 1.03E+03 100% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
4.91 E+01 1.5E+01 7.5E+00 2.4E+01
5.09E+01 2.5E+02 7.5E+00 2.4E+01
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1832
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
As Sample Dilution Cone. Qualifier
ug/L
As CFS-LRef-1316-T01-D 1 1.19E+01 E
As CFS-LRef-1316-T02-D 1 2.25E+01 E
As CFS-LRef-1316-T03-D 1 2.40E+01 E
As CFS-LRef-1316-T04-D 1 2.68E+01 E
As CFS-LRef-1316-T01-E 1 1.24E+01 E
As CFS-LRef-1316-T02-E 1 2.09E+01 E
As CFS-LRef-1316-T03-E 1 2.99E+01 E
As CFS-LRef-1316-T04-E 1 3.51 E+01
As CFS-LRef-1316-T01-F 1 1.28E+01 E
As CFS-LRef-1316-T02-F 1 1.36E+01 E
As CFS-LRef-1316-T03-F 1 2.83E+01 E
As CFS-LRef-1316-T04-F 1 3.06E+01 E
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.19E+01 2.8E+00 1.1E+01 3.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
2.25E+01 1.3E+01 1.1E+01 3.5E+01 10 100 1.13E+03 11 1% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
2.40E+01 1.8E+01 1.1E+01 3.5E+01
2.68E+01 1.7E+01 1.1E+01 3.5E+01
1.24E+01 6.9E+01 1.1 E+01 3.5E+01
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
2.09E+01 2.9E+01 1.1E+01 3.5E+01 10 100 1.15E+03 1 13% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
2.99E+01 3.5E+01 1.1E+01 3.5E+01
3.51 E+01 6.5E+00 1.1 E+01 3.5E+01
1.28E+01 5.0E+01 1.1 E+01 3.5E+01
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.36E+01 4.6E+01 1.1E+01 3.5E+01 10 100 1.01E+03 99% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
2.83E+01 1.5E+02 1.1 E+01 3.5E+01
3.06E+01 3.3E+02 1.1 E+01 3.5E+01
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1833
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
B Sample Dilution Cone. Qualifier
ug/L
B CFS-LRef-1316-T01-D 1 1.72E+02
B CFS-LRef-1316-T02-D 1 2.89E+02
B CFS-LRef-1316-T03-D 1 6.29E+02
B CFS-LRef-1316-T04-D 1 9.92E+02
B CFS-LRef-1316-T01-E 1 1.44E+02
B CFS-LRef-1316-T02-E 1 2.95E+02
B CFS-LRef-1316-T03-E 1 6.26E+02
B CFS-LRef-1316-T04-E 1 9.98E+02
B CFS-LRef-1316-T01-F 1 1.36E+02
B CFS-LRef-1316-T02-F 1 2.73E+02
B CFS-LRef-1316-T03-F 1 6.23E+02
B CFS-LRef-1316-T04-F 1 9.97E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.72E+02 5.1E+00 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
2.89E+02 1.3E+00 1 .OE+00 3.2E+00 1000 100 1.32E+03 103% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
6.29E+02 1.7E+00 1. OE+00 3.2E+00
9.92E+02 2.5E-01 1. OE+00 3.2E+00
1.44E+02 2.6E+00 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
2.95E+02 1.5E+00 1 .OE+00 3.2E+00 1000 100 1.37E+03 108% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
6.26E+02 2.4E+00 1 .OE+00 3.2E+00
9.98E+02 1.1E+00 1 .OE+00 3.2E+00
1.36E+02 1.9E+01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
2.73E+02 6.0E-01 1 .OE+00 3.2E+00 1000 100 1.24E+03 97% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
6.23E+02 2.0E+01 1 .OE+00 3.2E+00
9.97E+02 1.7E+02 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1834
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ba Sample Dilution Cone. Qualifier
ug/L
Ba CFS-LRef-1316-T01-D 1 9.20E+01
Ba CFS-LRef-1316-T02-D 1 8.85E+01
Ba CFS-LRef-1316-T03-D 1 7.35E+01
Ba CFS-LRef-1316-T04-D 1 6.04E+01
Ba CFS-LRef-1316-T01-E 1 8.80E+01
Ba CFS-LRef-1316-T02-E 1 8.77E+01
Ba CFS-LRef-1316-T03-E 1 7.51 E+01
Ba CFS-LRef-1316-T04-E 1 6.24E+01
Ba CFS-LRef-1316-T01-F 1 8.46E+01
Ba CFS-LRef-1316-T02-F 1 8.46E+01
Ba CFS-LRef-1316-T03-F 1 7.02E+01
Ba CFS-LRef-1316-T04-F 1 6.49E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.20E+01 1.2E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
8.85E+01 6.7E-01 1 .OE+00 3.2E+00 10 100 1.22E+03 113% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
7.35E+01 1. OE+00 1. OE+00 3.2E+00
6.04E+01 3.8E-01 1. OE+00 3.2E+00
8.80E+01 3.9E-01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
8.77E+01 1.2E+00 1 .OE+00 3.2E+00 10 100 1.24E+03 115% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
7.51 E+01 2.4E+00 1 .OE+00 3.2E+00
6.24E+01 8.7E-01 1 .OE+00 3.2E+00
8.46E+01 1.2E+01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
8.46E+01 2.4E-01 1 .OE+00 3.2E+00 10 100 1.10E+03 102% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
7.02E+01 2.3E+02 1 .OE+00 3.2E+00
6.49E+01 1.6E+02 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1835
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Be Sample Dilution Cone. Qualifier Revi
ug/L
Be CFS-LRef-1316-T01-D 1 9.50E-01 U1/2
Be CFS-LRef-1316-T02-D 1 9.50E-01 U1/2
Be CFS-LRef-1316-T03-D 1 9.50E-01 U1/2
Be CFS-LRef-1316-T04-D 1 9.50E-01 U1/2
Be CFS-LRef-1316-T01-E 1 9.50E-01 U1/2
Be CFS-LRef-1316-T02-E 1 9.50E-01 U1/2
Be CFS-LRef-1316-T03-E 1 9.50E-01 U1/2
Be CFS-LRef-1316-T04-E 1 9.50E-01 U1/2
Be CFS-LRef-1316-T01-F 1 9.50E-01 U1/2
Be CFS-LRef-1316-T02-F 1 9.50E-01 U1/2
Be CFS-LRef-1316-T03-F 1 9.50E-01 U1/2
Be CFS-LRef-1316-T04-F 1 9.50E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 1.1E+02 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 1.3E+02 1.9E+00 6.0E+00 10 100 1.16E+03 116% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 1.2E+01 1.9E+00 6.0E+00
9.50E-01 8.2E+01 1.9E+00 6.0E+00
9.50E-01 5.2E+01 1.9E+00 6.0E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 8.0E+01 1.9E+00 6.0E+00 10 100 1.17E+03 117% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 1.4E+01 1.9E+00 6.0E+00
9.50E-01 7.2E+01 1.9E+00 6.0E+00
9.50E-01 5.7E+01 1.9E+00 6.0E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 5.5E+01 1.9E+00 6.0E+00 10 100 1.01E+03 101% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
9.50E-01 3.7E+01 1.9E+00 6.0E+00
9.50E-01 3.6E+02 1.9E+00 6.0E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1836
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cd Sample Dilution Cone. Qualifier
ug/L
Cd CFS-LRef-1316-T01-D 1 4.63E+03
Cd CFS-LRef-1316-T02-D 1 7.02E+03
Cd CFS-LRef-1316-T03-D 1 1.06E+04
Cd CFS-LRef-1316-T04-D 1 1.31E+04
Cd CFS-LRef-1316-T01-E 1 4.78E+03
Cd CFS-LRef-1316-T02-E 1 7.20E+03
Cd CFS-LRef-1316-T03-E 1 1.09E+04
Cd CFS-LRef-1316-T04-E 1 1.30E+04
Cd CFS-LRef-1316-T01-F 1 4.62E+03
Cd CFS-LRef-1316-T02-F 1 6.77E+03
Cd CFS-LRef-1316-T03-F 1 1.03E+04
Cd CFS-LRef-1316-T04-F 1 1.33E+04
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.63E+03 1.1E+01 2.2E+00 7.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
7.02E+03 4.3E-01 2.2E+00 7.0E+00 10 100 7.99E+03 97% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
1.06E+04 1.1E+00 2.2E+00 7.0E+00
1.31E+04 5.4E-01 2.2E+00 7.0E+00
4.78E+03 4.1E-01 2.2E+00 7.0E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
7.20E+03 5.5E-01 2.2E+00 7.0E+00 10 100 8.15E+03 96% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
1.09E+04 3.0E+00 2.2E+00 7.0E+00
1.30E+04 6.6E-01 2.2E+00 7.0E+00
4.62E+03 1.3E+01 2.2E+00 7.0E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
6.77E+03 3.3E-01 2.2E+00 7.0E+00 10 100 7.67E+03 90% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
1.03E+04 7.7E+01 2.2E+00 7.0E+00
1.33E+04 1.6E+02 2.2E+00 7.0E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1837
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ca Sample Dilution Cone. Qualifier
ug/L
Ca CFS-LRef-1316-T01-D 1 6.41E+05
Ca CFS-LRef-1316-T02-D 1 6.54E+05
Ca CFS-LRef-1316-T03-D 1 6.29E+05
Ca CFS-LRef-1316-T04-D 1 5.72E+05
Ca CFS-LRef-1316-T01-E 1 6.57E+05
Ca CFS-LRef-1316-T02-E 1 6.69E+05
Ca CFS-LRef-1316-T03-E 1 6.38E+05
Ca CFS-LRef-1316-T04-E 1 5.85E+05
Ca CFS-LRef-1316-T01-F 1 6.38E+05
Ca CFS-LRef-1316-T02-F 1 6.33E+05
Ca CFS-LRef-1316-T03-F 1 6.25E+05
Ca CFS-LRef-1316-T04-F 1 5.81 E+05
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.41E+05 2.3E+01 2.6E+00 8.3E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
6.54E+05 6.8E-01 2.6E+00 8.3E+00 1000 100 6.55E+05 89% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
6.29E+05 1.4E+00 2.6E+00 8.3E+00
5.72E+05 1.1E+00 2.6E+00 8.3E+00
6.57E+05 7.1E-01 2.6E+00 8.3E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
6.69E+05 1.4E+00 2.6E+00 8.3E+00 1000 100 6.70E+05 88% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
6.38E+05 2.5E+00 2.6E+00 8.3E+00
5.85E+05 7.2E-01 2.6E+00 8.3E+00
6.38E+05 1.2E+01 2.6E+00 8.3E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
6.33E+05 3.3E-01 2.6E+00 8.3E+00 1000 100 6.34E+05 86% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
6.25E+05 8.4E+01 2.6E+00 8.3E+00
5.81E+05 1.6E+02 2.6E+00 8.3E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1838
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Cr Sample Dilution Cone. Qualifier Revi
ug/L
Cr CFS-LRef-1316-T01-D 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T02-D 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T03-D 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T04-D 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T01-E 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T02-E 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T03-E 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T04-E 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T01-F 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T02-F 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T03-F 1 6.00E-01 U1/2
Cr CFS-LRef-1316-T04-F 1 6.00E-01 U1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 2.7E+01 1.2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 8.9E+01 1.2E+00 3.8E+00 10 100 1.11E+03 11 1% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 1.9E+02 1.2E+00 3.8E+00
6.00E-01 5.9E+01 1.2E+00 3.8E+00
6.00E-01 8.2E+02 1.2E+00 3.8E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 1.0E+02 1.2E+00 3.8E+00 10 100 1.11E+03 111% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 2.7E+02 1.2E+00 3.8E+00
6.00E-01 1.6E+02 1.2E+00 3.8E+00
6.00E-01 1.5E+03 1.2E+00 3.8E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 1.7E+02 1.2E+00 3.8E+00 10 100 9.78E+02 98% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
6.00E-01 1.2E+01 1.2E+00 3.8E+00
6.00E-01 1.8E+01 1.2E+00 3.8E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1839
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Co Sample Dilution Cone. Qualifier
ug/L
Co CFS-LRef-1316-T01-D 1 1.13E+02
Co CFS-LRef-1316-T02-D 1 1.96E+02
Co CFS-LRef-1316-T03-D 1 3.90E+02
Co CFS-LRef-1316-T04-D 1 5.65E+02
Co CFS-LRef-1316-T01-E 1 1.09E+02
Co CFS-LRef-1316-T02-E 1 2.07E+02
Co CFS-LRef-1316-T03-E 1 3.95E+02
Co CFS-LRef-1316-T04-E 1 5.63E+02
Co CFS-LRef-1316-T01-F 1 1.04E+02
Co CFS-LRef-1316-T02-F 1 1.95E+02
Co CFS-LRef-1316-T03-F 1 3.93E+02
Co CFS-LRef-1316-T04-F 1 5.78E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.13E+02 1.8E+01 1.8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.96E+02 1.0E+00 1 .8E+00 5.7E+00 10 100 1.25E+03 105% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
3.90E+02 1.2E+00 1 .8E+00 5.7E+00
5.65E+02 6.3E-01 1 .8E+00 5.7E+00
1.09E+02 2.6E-01 1 .8E+00 5.7E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
2.07E+02 8.3E-01 1 .8E+00 5.7E+00 10 100 1.27E+03 107% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
3.95E+02 2.8E+00 1.8E+00 5.7E+00
5.63E+02 6.1E-01 1.8E+00 5.7E+00
1.04E+02 1.5E+01 1.8E+00 5.7E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.95E+02 9.2E-01 1 .8E+00 5.7E+00 10 100 1.14E+03 95% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
3.93E+02 9.8E+01 1 .8E+00 5.7E+00
5.78E+02 1.6E+02 1 .8E+00 5.7E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1840
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Cu Sample Dilution Cone. Qualifier
ug/L
Cu CFS-LRef-1316-T01-D 1 9.87E+02
Cu CFS-LRef-1316-T02-D 1 1.35E+03
Cu CFS-LRef-1316-T03-D 1 2.43E+03
Cu CFS-LRef-1316-T04-D 1 3.55E+03
Cu CFS-LRef-1316-T01-E 1 9.68E+02
Cu CFS-LRef-1316-T02-E 1 1.49E+03
Cu CFS-LRef-1316-T03-E 1 2.62E+03
Cu CFS-LRef-1316-T04-E 1 3.59E+03
Cu CFS-LRef-1316-T01-F 1 9.78E+02
Cu CFS-LRef-1316-T02-F 1 1.37E+03
Cu CFS-LRef-1316-T03-F 1 2.71E+03
Cu CFS-LRef-1316-T04-F 1 3.65E+03
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.87E+02 1.9E+01 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.35E+03 1.3E+00 3.7E+00 1.2E+01 10 100 2.28E+03 93% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
2.43E+03 9.0E-01 3.7E+00 1.2E+01
3.55E+03 4.8E-01 3.7E+00 1.2E+01
9.68E+02 4.7E-01 3.7E+00 1.2E+01
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.49E+03 1.9E+00 3.7E+00 1.2E+01 10 100 2.49E+03 99% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
2.62E+03 2.5E+00 3.7E+00 1.2E+01
3.59E+03 1.4E+00 3.7E+00 1.2E+01
9.78E+02 7.0E+00 3.7E+00 1.2E+01
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.37E+03 6.5E-01 3.7E+00 1.2E+01 10 100 2.25E+03 89% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
2.71E+03 1.0E+02 3.7E+00 1.2E+01
3.65E+03 1.5E+02 3.7E+00 1.2E+01
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1841
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Fe Sample Dilution Cone. Qualifier Revi
ug/L
Fe CFS-LRef-1316-T01-D 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T02-D 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T03-D 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T04-D 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T01-E 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T02-E 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T03-E 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T04-E 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T01-F 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T02-F 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T03-F 1 1.00E+OOU1/2
Fe CFS-LRef-1316-T04-F 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.4E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 8.2E+00 2.0E+00 6.4E+00 1000 100 1.10E+03 110% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 6.2E+01 2.0E+00 6.4E+00
1.00E+00 4.8E+01 2.0E+00 6.4E+00
1.00E+00 3.5E+01 2.0E+00 6.4E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 7.3E+00 2.0E+00 6.4E+00 1000 100 1.10E+03 1 10% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 7.8E+01 2.0E+00 6.4E+00
1.00E+00 3.0E+01 2.0E+00 6.4E+00
1.00E+00 1.7E+01 2.0E+00 6.4E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 1.9E+01 2.0E+00 6.4E+00 1000 100 9.76E+02 97% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 5.7E+00 2.0E+00 6.4E+00
1.00E+00 2.5E+01 2.0E+00 6.4E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1842
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Pb Sample Dilution Cone. Qualifier
ug/L
Pb CFS-LRef-1316-T01-D 1 1.17E+03
Pb CFS-LRef-1316-T02-D 1 1.18E+03
Pb CFS-LRef-1316-T03-D 1 1.28E+03
Pb CFS-LRef-1316-T04-D 1 1.31E+03
Pb CFS-LRef-1316-T01-E 1 1.07E+03
Pb CFS-LRef-1316-T02-E 1 1.23E+03
Pb CFS-LRef-1316-T03-E 1 1.30E+03
Pb CFS-LRef-1316-T04-E 1 1.30E+03
Pb CFS-LRef-1316-T01-F 1 1.02E+03
Pb CFS-LRef-1316-T02-F 1 1.09E+03
Pb CFS-LRef-1316-T03-F 1 1.31E+03
Pb CFS-LRef-1316-T04-F 1 1.30E+03
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.17E+03 8.1E+00 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.18E+03 5.4E-01 6.8E+00 2.2E+01 10 100 2.07E+03 89% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
1.28E+03 1.1E+00 6.8E+00 2.2E+01
1.31E+03 7.2E-01 6.8E+00 2.2E+01
1.07E+03 5.3E-01 6.8E+00 2.2E+01
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.23E+03 2.9E-01 6.8E+00 2.2E+01 10 100 2.15E+03 93% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
1.30E+03 2.9E+00 6.8E+00 2.2E+01
1.30E+03 7.2E-01 6.8E+00 2.2E+01
1.02E+03 1.4E+01 6.8E+00 2.2E+01
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.09E+03 3.9E-01 6.8E+00 2.2E+01 10 100 1.94E+03 85% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
1.31E+03 1.3E+02 6.8E+00 2.2E+01
1.30E+03 1.5E+02 6.8E+00 2.2E+01
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1843
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Li Sample Dilution Cone. Qualifier
ug/L
Li CFS-LRef-1316-T01-D 1 1.08E+01
Li CFS-LRef-1316-T02-D 1 8.98E+00
Li CFS-LRef-1316-T03-D 1 5.79E+00 E
Li CFS-LRef-1316-T04-D 1 9.60E+00
Li CFS-LRef-1316-T01-E 1 1.17E+01
Li CFS-LRef-1316-T02-E 1 8.13E+00
Li CFS-LRef-1316-T03-E 1 5.64E+00 E
Li CFS-LRef-1316-T04-E 1 1.12E+01
Li CFS-LRef-1316-T01-F 1 8.88E+00
Li CFS-LRef-1316-T02-F 1 9.10E+00
Li CFS-LRef-1316-T03-F 1 5.98E+00 E
Li CFS-LRef-1316-T04-F 1 9.23E+00
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+01 8.9E-01 1.9E+00 6.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
8.98E+00 3.6E+00 1 .9E+00 6.0E+00 10 100 1.02E+03 101% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
5.79E+00 8.7E+00 1 .9E+00 6.0E+00
9.60E+00 2.6E+00 1 .9E+00 6.0E+00
1.17E+01 3.8E+00 1.9E+00 6.0E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
8.13E+00 1.1E+01 1.9E+00 6.0E+00 10 100 1.03E+03 102% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
5.64E+00 4.4E+00 1.9E+00 6.0E+00
1.12E+01 7.7E+00 1.9E+00 6.0E+00
8.88E+00 1.1E+01 1.9E+00 6.0E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
9.10E+00 4.1E+00 1.9E+00 6.0E+00 10 100 8.91E+02 88% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
5.98E+00 7.7E+00 1 .9E+00 6.0E+00
9.23E+00 2.7E+00 1 .9E+00 6.0E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1844
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Mn Sample Dilution Cone. Qualifier Review
ug/L
Mn CFS-LRef-1316-T01-D 1 1.67E+03
Mn CFS-LRef-1316-T02-D 1 3.26E+03
Mn CFS-LRef-1316-T03-D 1 7.32E+03
Mn CFS-LRef-1316-T04-D 1 1.15E+04
Mn CFS-LRef-1316-T01-E 1 1.66E+03
Mn CFS-LRef-1316-T02-E 1 3.43E+03
Mn CFS-LRef-1316-T03-E 1 7.39E+03
Mn CFS-LRef-1316-T04-E 1 1.15E+04
Mn CFS-LRef-1316-T01-F 1 1.68E+03
Mn CFS-LRef-1316-T02-F 1 3.21E+03
Mn CFS-LRef-1316-T03-F 1 7.32E+03
Mn CFS-LRef-1316-T04-F 1 1.14E+04
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.67E+03 8.4E+01 2.0E+00 6.4E+00
3.26E+03 2.5E-01 2.0E+00 6.4E+00 10 100
7.32E+03 1.5E+00 2.0E+00 6.4E+00
1.15E+04 6.1E-01 2.0E+00 6.4E+00
1.66E+03 7.0E-01 2.0E+00 6.4E+00
3.43E+03 7.9E-01 2.0E+00 6.4E+00 10 100
7.39E+03 2.4E+00 2.0E+00 6.4E+00
1.15E+04 1.1E+00 2.0E+00 6.4E+00
1.68E+03 7.0E+00 2.0E+00 6.4E+00
3.21E+03 2.4E-01 2.0E+00 6.4E+00 10 100
7.32E+03 9.1E+00 2.0E+00 6.4E+00
1.14E+04 1.5E+02 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
4.19E+03 92% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
4.37E+03 95% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
4.11E+03 89% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1845
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mg Sample Dilution Cone. Qualifier
ug/L
Mg CFS-LRef-1316-T01-D 1 6.24E+04
Mg CFS-LRef-1316-T02-D 1 1.26E+05
Mg CFS-LRef-1316-T03-D 1 3.00E+05
Mg CFS-LRef-1316-T04-D 1 5.05E+05
Mg CFS-LRef-1316-T01-E 1 6.23E+04
Mg CFS-LRef-1316-T02-E 1 1.32E+05
Mg CFS-LRef-1316-T03-E 1 3.00E+05
Mg CFS-LRef-1316-T04-E 1 5.20E+05
Mg CFS-LRef-1316-T01-F 1 5.66E+04
Mg CFS-LRef-1316-T02-F 1 1.23E+05
Mg CFS-LRef-1316-T03-F 1 2.99E+05
Mg CFS-LRef-1316-T04-F 1 5.14E+05
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.24E+04 4.4E+01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.26E+05 5.5E-01 1 .OE+00 3.2E+00 1000 100 1.26E+05 96% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
3.00E+05 1.8E+00 1. OE+00 3.2E+00
5.05E+05 1.1E+00 1. OE+00 3.2E+00
6.23E+04 4.0E-01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.32E+05 4.4E-01 1 .OE+00 3.2E+00 1000 100 1.33E+05 92% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
3.00E+05 2.0E+00 1 .OE+00 3.2E+00
5.20E+05 1.7E+00 1 .OE+00 3.2E+00
5.66E+04 2.7E+01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.23E+05 1.8E-01 1 .OE+00 3.2E+00 1000 100 1.24E+05 86% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
2.99E+05 1.2E+02 1 .OE+00 3.2E+00
5.14E+05 1.6E+02 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1846
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Mo Sample Dilution Cone. Qualifier
ug/L
Mo CFS-LRef-1316-T01-D 1 7.75E+00
Mo CFS-LRef-1316-T02-D 1 1.43E+01
Mo CFS-LRef-1316-T03-D 1 1.55E+01
Mo CFS-LRef-1316-T04-D 1 1.69E+01
Mo CFS-LRef-1316-T01-E 1 8.40E+00
Mo CFS-LRef-1316-T02-E 1 1.11E+01
Mo CFS-LRef-1316-T03-E 1 1.28E+01
Mo CFS-LRef-1316-T04-E 1 1.76E+01
Mo CFS-LRef-1316-T01-F 1 7.52E+00
Mo CFS-LRef-1316-T02-F 1 1.08E+01
Mo CFS-LRef-1316-T03-F 1 1.17E+01
Mo CFS-LRef-1316-T04-F 1 1.74E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.75E+00 1.5E+01 1 .2E+00 3.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.43E+01 1.5E+01 1.2E+00 3.8E+00 10 100 1.12E+03 110% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
1.55E+01 1.8E+01 1.2E+00 3.8E+00
1.69E+01 9.0E+00 1.2E+00 3.8E+00
8.40E+00 1.1E+01 1.2E+00 3.8E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.11E+01 1.7E+01 1.2E+00 3.8E+00 10 100 1.15E+03 114% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
1.28E+01 6.4E+00 1 .2E+00 3.8E+00
1.76E+01 1.6E+01 1.2E+00 3.8E+00
7.52E+00 1.0E+01 1 .2E+00 3.8E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.08E+01 2.6E+01 1.2E+00 3.8E+00 10 100 9.98E+02 99% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
1.17E+01 2.4E+01 1.2E+00 3.8E+00
1.74E+01 2.5E+02 1 .2E+00 3.8E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1847
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Ni Sample Dilution Cone. Qualifier
ug/L
Ni CFS-LRef-1316-T01-D 1 2.60E+02
Ni CFS-LRef-1316-T02-D 1 4.18E+02
Ni CFS-LRef-1316-T03-D 1 7.50E+02
Ni CFS-LRef-1316-T04-D 1 1.02E+03
Ni CFS-LRef-1316-T01-E 1 2.62E+02
Ni CFS-LRef-1316-T02-E 1 4.42E+02
Ni CFS-LRef-1316-T03-E 1 7.58E+02
Ni CFS-LRef-1316-T04-E 1 1.01E+03
Ni CFS-LRef-1316-T01-F 1 2.63E+02
Ni CFS-LRef-1316-T02-F 1 4.02E+02
Ni CFS-LRef-1316-T03-F 1 7.52E+02
Ni CFS-LRef-1316-T04-F 1 1.03E+03
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.60E+02 4.7E+00 1 .8E+00 5.7E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
4.18E+02 3.0E-01 1 .8E+00 5.7E+00 10 100 1.43E+03 101% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
7.50E+02 1.1E+00 1 .8E+00 5.7E+00
1.02E+03 6.0E-01 1 .8E+00 5.7E+00
2.62E+02 2.0E-01 1 .8E+00 5.7E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
4.42E+02 3.5E-01 1 .8E+00 5.7E+00 10 100 1.46E+03 101% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
7.58E+02 2.9E+00 1.8E+00 5.7E+00
1.01E+03 9.4E-01 1.8E+00 5.7E+00
2.63E+02 1.6E+01 1 .8E+00 5.7E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
4.02E+02 4.3E-01 1 .8E+00 5.7E+00 10 100 1.32E+03 92% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
7.52E+02 7.4E+01 1 .8E+00 5.7E+00
1.03E+03 1.5E+02 1 .8E+00 5.7E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1848
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
P Sample Dilution Cone. Qualifier
ug/L
P CFS-LRef-1316-T01-D 1 1.33E+01
P CFS-LRef-1316-T02-D 1 2.21E+01
P CFS-LRef-1316-T03-D 1 1.88E+01
P CFS-LRef-1316-T04-D 1 2.68E+01
P CFS-LRef-1316-T01-E 1 1.21E+01
P CFS-LRef-1316-T02-E 1 1.87E+01
P CFS-LRef-1316-T03-E 1 1.81E+01
P CFS-LRef-1316-T04-E 1 2.71E+01
P CFS-LRef-1316-T01-F 1 9.08E+00 E
P CFS-LRef-1316-T02-F 1 1.45E+01
P CFS-LRef-1316-T03-F 1 1.78E+01
P CFS-LRef-1316-T04-F 1 2.90E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+01 1.5E+02 3.7E+00 1.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
2.21E+01 6.3E+01 3.7E+00 1.2E+01 1000 100 1.14E+03 11 1% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
1.88E+01 7.2E+00 3.7E+00 1.2E+01
2.68E+01 3.4E+01 3.7E+00 1.2E+01
1.21E+01 8.6E+01 3.7E+00 1.2E+01
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.87E+01 7.6E+01 3.7E+00 1.2E+01 1000 100 1.18E+03 116% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
1.81E+01 5.1E+01 3.7E+00 1.2E+01
2.71E+01 1.9E+01 3.7E+00 1.2E+01
9.08E+00 2.7E+02 3.7E+00 1.2E+01
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.45E+01 8.1E+01 3.7E+00 1.2E+01 1000 100 1.05E+03 104% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
1.78E+01 3.0E+02 3.7E+00 1.2E+01
2.90E+01 7.2E+01 3.7E+00 1.2E+01
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1849
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
K Sample Dilution Cone. Qualifier Review
1 1 ug/L | |
K CFS-LRef-1316-T01-D 1 9.65E+03
K CFS-LRef-1316-T02-D 1 1.81E+04
K CFS-LRef-1316-T03-D 1 3.62E+04
K CFS-LRef-1316-T04-D 1 5.50E+04
K CFS-LRef-1316-T01-E 1 9.78E+03
K CFS-LRef-1316-T02-E 1 1.88E+04
K CFS-LRef-1316-T03-E 1 3.70E+04
K CFS-LRef-1316-T04-E 1 5.61 E+04
K CFS-LRef-1316-T01-F 1 9.31E+03
K CFS-LRef-1316-T02-F 1 1.79E+04
K CFS-LRef-1316-T03-F 1 3.71 E+04
K CFS-LRef-1316-T04-F 1 5.72E+04
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.65E+03 9.8E+00 1 .6E+00 5.1E+00
1.81 E+04 6.9E-01 1 .6E+00 5.1E+00 1000 100
3.62E+04 1.1E+00 1.6E+00 5.1E+00
5.50E+04 3.6E-01 1.6E+00 5.1E+00
9.78E+03 2.8E-01 1 .6E+00 5.1E+00
1.88E+04 9.7E-01 1 .6E+00 5.1E+00 1000 100
3.70E+04 3.3E+00 1 .6E+00 5.1E+00
5.61 E+04 6.1E-01 1 .6E+00 5.1E+00
9.31 E+03 1.5E+01 1 .6E+00 5.1E+00
1.79E+04 4.4E-01 1 .6E+00 5.1E+00 1000 100
3.71 E+04 6.2E+01 1 .6E+00 5.1E+00
5.72E+04 1.6E+02 1 .6E+00 5.1E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.91 E+04 101% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.98E+04 103% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.88E+04 92% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1850
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Se Sample Dilution Cone. Qualifier
ug/L
Se CFS-LRef-1316-T01-D 1 8.42E+01
Se CFS-LRef-1316-T02-D 1 1.27E+02
Se CFS-LRef-1316-T03-D 1 2.90E+02
Se CFS-LRef-1316-T04-D 1 4.95E+02
Se CFS-LRef-1316-T01-E 1 7.64E+01
Se CFS-LRef-1316-T02-E 1 1.61E+02
Se CFS-LRef-1316-T03-E 1 2.80E+02
Se CFS-LRef-1316-T04-E 1 5.00E+02
Se CFS-LRef-1316-T01-F 1 8.52E+01
Se CFS-LRef-1316-T02-F 1 1.29E+02
Se CFS-LRef-1316-T03-F 1 2.86E+02
Se CFS-LRef-1316-T04-F 1 4.92E+02
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.42E+01 6.2E+01 1 .5E+01 4.8E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.27E+02 5.4E+00 1 .5E+01 4.8E+01 10 100 1.22E+03 109% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
2.90E+02 1.9E+00 1.5E+01 4.8E+01
4.95E+02 5.3E+00 1.5E+01 4.8E+01
7.64E+01 2.0E+01 1 .5E+01 4.8E+01
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.61E+02 3.1E+00 1.5E+01 4.8E+01 10 100 1.25E+03 109% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
2.80E+02 8.7E+00 1 .5E+01 4.8E+01
5.00E+02 4.6E+00 1 .5E+01 4.8E+01
8.52E+01 3.8E+01 1 .5E+01 4.8E+01
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.29E+02 1.8E+00 1 .5E+01 4.8E+01 10 100 1.13E+03 100% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
2.86E+02 3.9E+01 1 .5E+01 4.8E+01
4.92E+02 1.6E+02 1 .5E+01 4.8E+01
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1851
-------
Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Si Sample Dilution Cone. Qualifier
ug/L
Si CFS-LRef-1316-T01-D 1 4.10E+03
Si CFS-LRef-1316-T02-D 1 5.55E+03
Si CFS-LRef-1316-T03-D 1 7.06E+03
Si CFS-LRef-1316-T04-D 1 7.48E+03
Si CFS-LRef-1316-T01-E 1 4.07E+03
Si CFS-LRef-1316-T02-E 1 5.63E+03
Si CFS-LRef-1316-T03-E 1 7.08E+03
Si CFS-LRef-1316-T04-E 1 7.50E+03
Si CFS-LRef-1316-T01-F 1 4.03E+03
Si CFS-LRef-1316-T02-F 1 5.34E+03
Si CFS-LRef-1316-T03-F 1 7.06E+03
Si CFS-LRef-1316-T04-F 1 7.78E+03
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.10E+03 1.2E+01 1.1E+00 3.5E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
5.55E+03 8.3E-01 1.1E+00 3.5E+00 1000 100 6.53E+03 98% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
7.06E+03 1.4E+00 1.1E+00 3.5E+00
7.48E+03 3.7E-01 1.1E+00 3.5E+00
4.07E+03 8.3E-01 1.1E+00 3.5E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
5.63E+03 1.2E+00 1.1E+00 3.5E+00 1000 100 6.59E+03 96% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
7.08E+03 2.9E+00 1.1E+00 3.5E+00
7.50E+03 6.7E-01 1.1E+00 3.5E+00
4.03E+03 7.3E+00 1.1E+00 3.5E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
5.34E+03 3.4E-01 1.1E+00 3.5E+00 1000 100 6.20E+03 86% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
7.06E+03 8.0E+01 1.1E+00 3.5E+00
7.78E+03 1.6E+02 1.1E+00 3.5E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1852
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Na Sample Dilution Cone. Qualifier
ug/L
Na CFS-LRef-1316-T01-D 1 2.06E+04
Na CFS-LRef-1316-T02-D 1 3.92E+04
Na CFS-LRef-1316-T03-D 1 8.13E+04
Na CFS-LRef-1316-T04-D 1 1.27E+05
Na CFS-LRef-1316-T01-E 1 2.09E+04
Na CFS-LRef-1316-T02-E 1 3.98E+04
Na CFS-LRef-1316-T03-E 1 8.21E+04
Na CFS-LRef-1316-T04-E 1 1.27E+05
Na CFS-LRef-1316-T01-F 1 2.03E+04
Na CFS-LRef-1316-T02-F 1 4.03E+04
Na CFS-LRef-1316-T03-F 1 8.17E+04
Na CFS-LRef-1316-T04-F 1 1.27E+05
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.06E+04 1.7E+01 2.5E+00 8.0E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
3.92E+04 3.5E-01 2.5E+00 8.0E+00 1000 100 4.00E+04 86% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
8.13E+04 2.3E-01 2.5E+00 8.0E+00
1.27E+05 2.6E-01 2.5E+00 8.0E+00
2.09E+04 1.9E-01 2.5E+00 8.0E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
3.98E+04 8.1E-01 2.5E+00 8.0E+00 1000 100 4.07E+04 89% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
8.21 E+04 1.5E+00 2.5E+00 8.0E+00
1.27E+05 4.2E-01 2.5E+00 8.0E+00
2.03E+04 1.1E+01 2.5E+00 8.0E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
4.03E+04 7.2E-01 2.5E+00 8.0E+00 1000 100 4.11E+04 85% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
8.17E+04 1.5E+01 2.5E+00 8.0E+00
1.27E+05 1.5E+02 2.5E+00 8.0E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1853
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sample
Sample Dilution Cone. Qualifier
ug/L
CFS-LRef-1316-T01-D 1 1.44E+03
CFS-LRef-1316-T02-D 1 2.11E+03
CFS-LRef-1316-T03-D 1 3.11E+03
CFS-LRef-1316-T04-D 1 3.75E+03
CFS-LRef-1316-T01-E 1 1.43E+03
CFS-LRef-1316-T02-E 1 2.14E+03
CFS-LRef-1316-T03-E 1 3.17E+03
CFS-LRef-1316-T04-E 1 3.85E+03
CFS-LRef-1316-T01-F 1 1.48E+03
CFS-LRef-1316-T02-F 1 2.10E+03
CFS-LRef-1316-T03-F 1 3.17E+03
CFS-LRef-1316-T04-F 1 3.79E+03
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.44E+03 1.1E+01 1.0E+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
2.11E+03 5.4E-01 1 .OE+00 3.2E+00 1000 100 3.08E+03 97% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
3.11E+03 1.2E+00 1. OE+00 3.2E+00
3.75E+03 1.1E+00 1. OE+00 3.2E+00
1.43E+03 8.1E-01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
2.14E+03 1.1E+00 1.0E+00 3.2E+00 1000 100 3.07E+03 94% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
3.17E+03 2.5E+00 1 .OE+00 3.2E+00
3.85E+03 3.6E-01 1 .OE+00 3.2E+00
1.48E+03 7.1E+00 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
2.10E+03 6.2E-01 1 .OE+00 3.2E+00 1000 100 2.98E+03 88% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
3.17E+03 7.7E+01 1 .OE+00 3.2E+00
3.79E+03 1.6E+02 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1854
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
S Sample Dilution Cone. Qualifier
ug/L
S CFS-LRef-1316-T01-D 1 5.63E+05
S CFS-LRef-1316-T02-D 1 6.38E+05
S CFS-LRef-1316-T03-D 1 8.34E+05
S CFS-LRef-1316-T04-D 1 1.04E+06
S CFS-LRef-1316-T01-E 1 5.59E+05
S CFS-LRef-1316-T02-E 1 6.56E+05
S CFS-LRef-1316-T03-E 1 8.39E+05
S CFS-LRef-1316-T04-E 1 1.06E+06
S CFS-LRef-1316-T01-F 1 5.34E+05
S CFS-LRef-1316-T02-F 1 6.24E+05
S CFS-LRef-1316-T03-F 1 8.10E+05
S CFS-LRef-1316-T04-F 1 1.06E+06
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.63E+05 1.6E+01 6.8E+00 2.2E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
6.38E+05 4.2E-01 6.8E+00 2.2E+01 1000 100 6.39E+05 86% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
8.34E+05 1.2E+00 6.8E+00 2.2E+01
1.04E+06 6.6E-01 6.8E+00 2.2E+01
5.59E+05 5.6E-01 6.8E+00 2.2E+01
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
6.56E+05 5.9E-01 6.8E+00 2.2E+01 1000 100 6.56E+05 87% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
8.39E+05 2.8E+00 6.8E+00 2.2E+01
1.06E+06 5.5E-01 6.8E+00 2.2E+01
5.34E+05 1.4E+01 6.8E+00 2.2E+01
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
6.24E+05 4.1E-01 6.8E+00 2.2E+01 1000 100 6.24E+05 84% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
8.10E+05 9.9E+01 6.8E+00 2.2E+01
1.06E+06 1.5E+02 6.8E+00 2.2E+01
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1855
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Internal
Tl Sample Dilution Cone. Qualifier Review
ug/L
Tl CFS-LRef-1316-T01-D 1 3.30E+02
Tl CFS-LRef-1316-T02-D 1 5.38E+02
Tl CFS-LRef-1316-T03-D 1 8.61 E+02
Tl CFS-LRef-1316-T04-D 1 1.16E+03
Tl CFS-LRef-1316-T01-E 1 3.57E+02
Tl CFS-LRef-1316-T02-E 1 5.46E+02
Tl CFS-LRef-1316-T03-E 1 8.74E+02
Tl CFS-LRef-1316-T04-E 1 1.18E+03
Tl CFS-LRef-1316-T01-F 1 3.33E+02
Tl CFS-LRef-1316-T02-F 1 5.15E+02
Tl CFS-LRef-1316-T03-F 1 8.77E+02
Tl CFS-LRef-1316-T04-F 1 1.19E+03
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.30E+02 2.2E+01 4.6E+00 1.5E+01
5.38E+02 9.1E-01 4.6E+00 1.5E+01 10 100
8.61 E+02 1.4E+00 4.6E+00 1.5E+01
1.16E+03 8.9E-01 4.6E+00 1.5E+01
3.57E+02 1.5E+00 4.6E+00 1.5E+01
5.46E+02 1.0E+00 4.6E+00 1.5E+01 10 100
8.74E+02 2.2E+00 4.6E+00 1.5E+01
1.18E+03 3.5E-01 4.6E+00 1.5E+01
3.33E+02 1.6E+01 4.6E+00 1.5E+01
5.15E+02 2.2E+00 4.6E+00 1.5E+01 10 100
8.77E+02 9.0E+01 4.6E+00 1.5E+01
1.19E+03 1.5E+02 4.6E+00 1.5E+01
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.48E+03 94% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.50E+03 96% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.39E+03 88% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1856
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample Inter
Ti Sample Dilution Cone. Qualifier Revi
ug/L
Ti CFS-LRef-1316-T01-D 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T02-D 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T03-D 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T04-D 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T01-E 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T02-E 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T03-E 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T04-E 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T01-F 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T02-F 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T03-F 1 1.00E+OOU1/2
Ti CFS-LRef-1316-T04-F 1 1.00E+OOU1/2
nal ICP-OES Spike Sol'n
ew Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.0E+01 2.0E+00 6.4E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 1.9E+03 2.0E+00 6.4E+00 10 100 1.09E+03 109% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 1.2E+02 2.0E+00 6.4E+00
1.00E+00 8.5E+02 2.0E+00 6.4E+00
1.00E+00 1.8E+02 2.0E+00 6.4E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 6.7E+01 2.0E+00 6.4E+00 10 100 1.12E+03 1 12% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 1.0E+02 2.0E+00 6.4E+00
1.00E+00 8.5E+01 2.0E+00 6.4E+00
1.00E+00 2.5E+02 2.0E+00 6.4E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 8.7E+01 2.0E+00 6.4E+00 10 100 9.76E+02 97% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
1.00E+00 7.5E+01 2.0E+00 6.4E+00
1.00E+00 1.3E+02 2.0E+00 6.4E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1857
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
V Sample Dilution Cone. Qualifier
ug/L
V CFS-LRef-1316-T01-D 1 3.34E+01
V CFS-LRef-1316-T02-D 1 3.32E+01
V CFS-LRef-1316-T03-D 1 3.27E+01
V CFS-LRef-1316-T04-D 1 2.93E+01
V CFS-LRef-1316-T01-E 1 3.40E+01
V CFS-LRef-1316-T02-E 1 3.49E+01
V CFS-LRef-1316-T03-E 1 3.28E+01
V CFS-LRef-1316-T04-E 1 2.99E+01
V CFS-LRef-1316-T01-F 1 3.27E+01
V CFS-LRef-1316-T02-F 1 3.29E+01
V CFS-LRef-1316-T03-F 1 3.03E+01
V CFS-LRef-1316-T04-F 1 2.99E+01
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.34E+01 3.9E+01 1 .5E+00 4.8E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
3.32E+01 3.0E+00 1 .5E+00 4.8E+00 10 100 1.16E+03 112% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
3.27E+01 5.8E+00 1.5E+00 4.8E+00
2.93E+01 3.4E+00 1.5E+00 4.8E+00
3.40E+01 4.5E+00 1 .5E+00 4.8E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
3.49E+01 1.0E+00 1 .5E+00 4.8E+00 10 100 1.17E+03 114% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
3.28E+01 1.6E+00 1 .5E+00 4.8E+00
2.99E+01 6.0E-01 1 .5E+00 4.8E+00
3.27E+01 1.5E+01 1 .5E+00 4.8E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
3.29E+01 4.0E+00 1 .5E+00 4.8E+00 10 100 1.02E+03 99% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
3.03E+01 2.4E+02 1 .5E+00 4.8E+00
2.99E+01 1.6E+02 1 .5E+00 4.8E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1858
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Intel-laboratory Validation of LEAF Method 1313 and Method 1316
Sample
Zn Sample Dilution Cone. Qualifier
ug/L
Zn CFS-LRef-1316-T01-D 1 2.38E+04
Zn CFS-LRef-1316-T02-D 1 3.47E+04
Zn CFS-LRef-1316-T03-D 1 5.45E+04
Zn CFS-LRef-1316-T04-D 1 6.75E+04
Zn CFS-LRef-1316-T01-E 1 2.33E+04
Zn CFS-LRef-1316-T02-E 1 3.53E+04
Zn CFS-LRef-1316-T03-E 1 5.54E+04
Zn CFS-LRef-1316-T04-E 1 6.73E+04
Zn CFS-LRef-1316-T01-F 1 2.33E+04
Zn CFS-LRef-1316-T02-F 1 3.34E+04
Zn CFS-LRef-1316-T03-F 1 5.63E+04
Zn CFS-LRef-1316-T04-F 1 6.87E+04
Internal ICP-OES Spike Sol'n
Review Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.38E+04 8.3E+01 1 .OE+00 3.2E+00
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 1/26/11 4:39 PM EPA Interlab LRef 1313-1316 CFS
3.47E+04 3.2E-01 1 .OE+00 3.2E+00 10 100 3.57E+04 99% VU ICP-OES 1/26/11 4:40 PM EPA Interlab LRef 1313-1316 CFS
5.45E+04 1.4E+00 1. OE+00 3.2E+00
6.75E+04 1.9E-01 1. OE+00 3.2E+00
2.33E+04 6.3E-01 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:42 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:44 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:45 PM EPA Interlab LRef 1313-1316 CFS
3.53E+04 7.5E-01 1 .OE+00 3.2E+00 10 100 3.63E+04 100% VU ICP-OES 1/26/11 4:47 PM EPA Interlab LRef 1313-1316 CFS
5.54E+04 2.7E+00 1 .OE+00 3.2E+00
6.73E+04 1.6E+00 1 .OE+00 3.2E+00
2.33E+04 7.0E+00 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:48 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:50 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:52 PM EPA Interlab LRef 1313-1316 CFS
3.34E+04 7.4E-01 1 .OE+00 3.2E+00 10 100 3.42E+04 89% VU ICP-OES 1/26/11 4:53 PM EPA Interlab LRef 1313-1316 CFS
5.63E+04 3.5E+01 1 .OE+00 3.2E+00
6.87E+04 1.5E+02 1 .OE+00 3.2E+00
VU ICP-OES 1/26/11 4:55 PM EPA Interlab LRef 1313-1316 CFS
VU ICP-OES 1/26/11 4:57 PM EPA Interlab LRef 1313-1316 CFS
                                                                                                                                                                         1-1859
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